Biobrenseltyper, kvalitetskrav, bruksområder og gjeldende standarder, med vekt på flis og pellets Simen Gjølsjø 29. november, Bodø Ulike bestanddeler > > > > Cellulose : Lignin: Harpiks: Never1: 1Never 4,8 - 5,1 kWh/kg 7,1 kWh/kg 9,9 - 10,6 kWh/kg 8,5 - 9,7 kWh/kg inneholder ca. 66 % C og 8,5 % H, det høye innholdet skyldes stoffene betulin og suberin Calorimeter, also used for ash determination Treslag Tredeler Nedre brennverdi qnet (tørr eller aske fri basis) [ kWh / kg ] Bartre Lauvtre Cellulose Lignin Harpiks, ekstraktiver 4,8-5,1 7,1 9,9-10,6 Ved Bark Ved Bark 5,33 ± 0,14 (daf )* 5,55 ± 0,28 (daf )* 5,27 ± 0,17 (daf )* 5,55 ± 0,28 (daf )* FURU Ved Bark Hele stammen Greiner Nåler Hele treet Stubbe Ved GRAN Bark Hele stammen Greiner Nåler Hele treet Stubbe Ved BJØRK Bark Hele stammen Grener Lauv Hele treet Stubbe Foredlet brensel (beste kvalitetsklasse) Briketter Trepellets 5.36 (d )**** 5,42 (d )**** 5,36 (d )**** 5,66 (d )**** 5,83 (d )**** 5,42 (d )**** 5,84 (d)**** 5,28 (d )**** 5,47 (d )**** 5,28 (d )**** 5,49 (d )**** 5,33 (d )**** 5,36 (d )**** 5,36 (d)**** 5,17 (d )**** 6,31 (d )**** 5,33 (d )**** 5,69 (d )**** 5,50 (d )**** 5,36 (d )**** 5,19 (d)**** Basisdensitet ρd [ kg / fm3 ] Askeinnhold A [ vekt-% av tørrstoff ] 0,3 ± 0,1 * 4± 2* 0,3 ± 0,1 * 4± 2* 430 ± 50** 300*** 0,3 ± 0,1 * 4± 2* 450*** 385*** 450*** 390 ± 50 ** 340*** 0,3 ± 0,1 * 4± 2* 610*** 400*** 410*** 505 ± 20 ** 550*** 0,3 ± 0,1 * 4± 2* 530*** 475*** 510*** >1000* <0,7* >1100*** <0,7* * CEN/TC 335 2005a ** Sandland, Vadla et al. 2002 *** Alakangas 2005 **** Nurmi 1993 Brennverdi og vann 6 5 kWh/kg rått brensel 3 kWh/kg TS 2 1 Fuktighetsprosent 90 88 80 70 60 50 40 30 20 10 0 0 kWh/kg 4 Basisdensitet 700 600 500 400 300 200 100 0 514 500 B C A B A 1.3.2 Kronelengde Øverst C Levende greiner og toppen av treet ble brukt som mål for kronelengde. Midt B A C Nederst Tabell 5. Seksjoner av kroner og greiner. Levels of crown and branches. Nivåkrone Crown level Greintype Branch type Nivågrein Branch level Nederst A Innerst; Midt; Ytterst; Små; Kvast B Innerst; Midt; Ytterst; Små; Kvast C Innerst; Midt; Ytterst; Små; Kvast A Innerst; Midt; Ytterst; Små; Kvast B Innerst; Midt; Ytterst; Små; Kvast C Innerst; Midt; Ytterst; Små; Kvast A Innerst; Midt; Ytterst; Små; Kvast B Innerst; Midt; Ytterst; Små; Kvast C Innerst; Midt; Ytterst; Små; Kvast Midt Øverst MATERIAL Steigen Two locations along the north Norway coast. Sømna Site Stand Latitude Longitude Altitude Northland Northland Steigen Sømna 67°79'N 65°28'N 15°33'E 12°14'E 30 - 40 a.s.l. 05 - 10 a.s.l. Sampled stands were based on the site index quality. Tree species Stand Stand Site index H40 (m) Number of trees Sitka spruce Norway spruce Sitka spruce Lutz spruce Steigen Sømna Sømna Sømna 1 2 3 4 G-17 G-14 G-14 G-14 5 5 5 5 Figure 4: Stands in Steigen and Sømna. Each stand was laid out with a circular area of ca. 500 m2 (radius 12 m). Basic density of branches Table 4: Basic density of branches within crown levels (kg/m3). Site Tree species Bottom Middle Top Steigen 1-Sitka spruce 512.9 (70.6) 499.9 (39.7) 471.2 (38.3) Sømna 2-Norway spruce 504.1 (20.4) 486.6 (20.5) 461.1 (29.5) Sømna 3-Sitka spruce 539.4 (37.1) 503.7 (39.5) 492.3 (19.6) Sømna 4-Lutz spruce 519.0 (33.3) 500.9 (31.7) 475.7 (33.5) Branches in the lower crown level had 8-9% higher basic density than the upper one at the significant level in all tree species. Main items of interest for wood chips > > > > > > > > > > Voksested Handelsform Dimensjon Fuktighet Askemengde Nitrogen innhold Klorine innhold Brennverdi Bulk densitet Aske innhold og smeltepunkt ok t.0 7 no v. 07 de s. 07 ja n. 08 fe b. 08 m ar .0 8 ap r.0 8 m ai .0 8 ju n. 08 Fukt (%) Effekt av tildekking 55 50 45 40 35 30 25 20 Dekket Udekket Dato Bjørk Høst Udekket 50 Fukt (%) 45 Målselv 40 Møre 35 Brandbu 30 25 6.8.07 14.11.07 22.2.08 1.6.08 Dato 9.9.08 18.12.08 Steigen, heltrær, bjørk, ikke dekket Kvalitetssikring av brenselet Solid biofuels European standardisation body Technical Committee 335 “Solid biofuels” Working groups on: > Nomenclature > Requirements and classes > Chemical analysis > Physical analysis CEN/TC 335 standards for solid biofuels Net calorific value Bridging prEN 14918 Properties (under preparation) Particle size Distribution prEN15149 Ash content prEN 14775 Moisture content prEN 14774 Impurities (postponed) Bulk density prEN 15130 Mechanical durability (pellets & briquettes) prEN 15210 Particle density prEN 15150 Ash melting behaviour prEN 15370 Fuel specification and classes prEN 14961 (multipart) Fuel quality assurance prEN 15234 Terminology prEN 14588 Sampling and sample preparation prEN 14778, 14780 Norsk Standard > En generell standard (NS-EN 14961-1:2010) > En standard for mindre anlegg (NS-EN 14961-4:2011) > Som ikke har avansert styring og rensing av røykgassene. > Som ikke har heltids profesjonell drift. > For anlegg hvor det lokalt kan det være skepsis til røyk, «forurensing». > For anlegg som krever homogen flis med lav fuktighet, lite stikker og finstoff. Fraksjoner i Standarden Nordhagen, 2011 Size classifier 30 20 15 10 ≤ 12 w-% for P45 5 ≤ 8 w-% for P16 0 Fines fraction, weight-% (< 3.15 mm) 25 Maximum 25 w-% for logging residue chips Grot Tredeler Heltre Basissortiment Stammeved Energi tetthet som mottatt kWh per lm3 1100 Energy density (kWh/lm3) 1000 900 800 700 600 500 Grot Tredeler Heltre Stammeved Basissortiment Stikker > 120 mm Coarse fraction > 120 mm(weight-%) 4 3 2 1 0 Grot Tredeler Heltre Basissortiment Stammeved Faktorer som påvirker fliskvaliteten > > > > > > > Virkessortiment (rundvirke, heltre, GROT etc.) Fuktighetsprosent Temperatur Flishoggerprinsipp Sollstørrelse Kniver og motstål Matehastighet Wood chips – informative (voluntary)prEN14961-1 > Bulk density, BD (kg/m3) Classes BD150; BD200; BD250; BD300; BD350; BD400 and BD450+ (maximum value to be stated) > Recommended to be stated, if traded by volume basis. 25 Analysis of bulk density according to prEN 15103 200 180 Dry Bulk Density (kg/lm3) 160 140 Grot Stubber Tredeler Basissortiment Heltre Stammeved Typiske fastmasseprosenter (Alakangas 2005) Furu heltreflis: 0,45 – 0,5 Furu stammeflis: 0,42-0,5 Gran heltreflis: 0,39-0,44 Bjørk heltreflis: 0,43-0,46 Hogstavfall fliset fersk; 0,36-0,38 Hogstavfall fliset tørr: 0,39-0,41 Sagflis: 0,28-0,32 Høvelspon: 0,18-0,27 Example of quality declaration of wood pellets – package EAA Biofuels P.O. Box 1603, FI-40101 Jyväskylä Tel. +358 20722 2550 Producer Origin: 1.2.1.2 Coniferous wood without bark Traded Form: Pellets – Class AI Country of origin Jyväskylä, Finland Normative (EN 14961- 2) Dimensions Diameter (D), lenght (L) D08 (D= 8+1 mm, and 3,15 < L < 40 (95%) Maximum 45 mm M10 ( < 10 %) Moisture (w-% as received) Ash (w-% of dry basis) A0.5, < 0,5% Mechanical durability (w-% of pellets after testing) DU97.5, < 97,5% Amount of fines (w-%, < 3.15 mm) F1.0, < 1% Q > 4,7 kWh/kg Net calorific value, Q Additives (w-% of pressing mass) Starch < 1 w-% 3 Bulk density as received (kg/m3) 28 DB625 > 625 kg/m3 Chemical composition (w-% dry basis) N0,3, S0,05, Cl0,02 Ash melting behaviour, (DT oC) > 1300 Minor elements (mg/kg dry basis) As 1, Cd 0,5, Cr 10, Cu 10, Pb 10, Hg 0.05, Ni 10, Zn 100 Wood pellets (prEN 14961-1) Amount of fines (< 3,15mm) < 1 w-% Pellet length, 3,15– 40 mm > 95 w-% Maximum length, 45 mm < 5 w-% Product standard - Non-industrial wood pellets (Part 2) Properties agreed in March 2009 Property A1 A2 B Origin 1.1 and 1.2.1* 1.1 and 1.2.1* 1.1, 1.2, 1.3 Dimensions D06, D08 (+ 1 mm) 3,15< L <40 mm Max. 45 mm (5 w-%) D06, D08 (+ 1 mm) 3,15< L <40 mm Max. 45 mm (5 w-%) D06, D08 (+ 1 mm) 3,15< L <40 mm Max. 45 mm (5 w-%) Moisture, M < 10 w-% < 10 w-% < 10 w-% Ash content, A dry basis < 0.5 w-% or < 0.7 w-% < 1.0 w-% < 3.0 w-% Bulk density, BD > 600 kg/m3 > 600 kg/m3 > 600 kg/m3 Mechanical durability, DU > 97.5 w-% > 97.5 w-% > 97.5 w-% Net calorific value as received, Q > 16.5 MJ/kg [4.6 kWh/kg] > 16.5 MJ/kg [4.6 kWh/kg] > 16.0 MJ/kg [4.4 kWh/kg] Fines, F (< 3,15 mm) The amount of fines shall be ≤ 1% leaving the final point of loading for delivery to the end-user. i.e leaving the final storage point or the factory if delivering directly to the end-user. The amount of fines leaving the factory gate shall also 30 be ≤ 1% (unless there is a different agreement between the producer and their customer). *May include 1 w-% of chemically treated wood in class A1 and 3 w-% in class A2. Additives < 2w-% of pressing mass, type (e.g. starch, corn flour, vegetable oil) and amount to be stated.