CXS490 New Technology Inert Gas Fire Extinguishants 1 Introduction • • • • • • • • • relevant standard is NFP-A2001 At least four inert gases or gas mixtures commercialized clean total flooding fire suppression agents design concentrations of 35-50% by volume reduces ambient oxygen concentration 14% to 10% by volume agents mixed with air - extinguish by physical mechanisms agents consist of nitrogen, argon & blends of these One blend contains 8% carbon dioxide. 2 Inert Gases • • • • • • • • Not liquefied gases like Halocarbons stored as high pressure gases require high pressure storage cylinders may have storage volume and weight impact. use pressure reducing devices at or near the discharge manifold reduces the pipe thickness requirements alleviates concerns regarding high pressure discharges. 3 Inert Gases • • Discharge times - one (typical) to two minutes limit some applications - rapidly developing fires (explosions) • • Not subject to thermal decomposition form no byproducts. • electrically non-conductive 4 Physiological Effects • • • • • • • • Primary health concern effect of reduced oxygen concentration on occupants reduced oxygen extensively researched & studied Many countries granted health & safety approval for use of inert gases in occupied areas in the workplace One product contains 8% carbon dioxide intended to increase blood oxygenation & cerebral blood flow in low oxygen atmospheres Physiological Effects • • • • • • • Inert gas agent IG-541 (Inergen) contains 8% carbon dioxide & approved by the U.S. EPA SNAP rules safe alternative to halon 1301 - total flooding systems At elevated concentrations carbon dioxide not safe for human exposure & lethal at fire extinguishing concentrations Physiological Effects Generic Name IG-01 IG-55 IG-100 IG-541 Maximum Maximum Maximum Exposure Trade Exposure Exposure Concentration Name Concentration Concentration Above 53% 5 minutes 3 minutes (Volume %) Argotec 43 52 (*4) Argonite 43 52 (*4) NN-100 43 52 (*4) Inergen 43 52 (*4) Notes 1: Nominal maximum discharge time is 60 seconds in all cases 2: Inert gas systems designed to concentrations below 43 percent (corresponding to an oxygen concentration of 12 percent, sea level equivalent of oxygen) shall be permitted, where means are provided to limit exposure to no longer than 5 minutes. 3: Inert gas systems designed to concentrations between 43 and 52 percent (corresponding to between 12 and 10 percent oxygen, sea level equivalent of oxygen) shall be permitted, where means are provided to limit exposure to no longer than 3 minutes. 4: Inert gas systems designed to concentrations between 52 and 62 (corresponding to between 10 and 8 percent oxygen, sea level equivalent of oxygen) shall be permitted given the following: (a) The space is normally unoccupied. (b) Where personnel could possibly be exposed, means are provided to limit the exposure to less than 30 seconds. (c) Inert gas systems designed to concentrations above 62 percent (corresponding to 8 percent oxygen or below, sea level equivalent of oxygen) shall only be used in unoccupied areas where personnel are not exposed to such oxygen depletion. Environmental Factors • • • • Inert gas agents are neither ozone depleting substances nor greenhouse gases pose no risk to the environment Environmental Factors Generic Name Trade Name Ozone Depletion Potential IG-01 IG-55 IG-100 IG-541 Argotec Argonite NN-100 Inergen 0 0 0 0 Global Warming Potential (100 year) 0 0 0 0 10 Physical Properties Generic Name IG-541 IG-55 Trade Name Inergen Argonite IG-01 IG-100 Argotec NN100 Agent Composition Nitrogen 52% 50% - 100% Argon 40% 50% 100% - Carbon Dioxide 8% - - - k1 (m3/kg) 0.65799 0.6598 0.5612 0.7998 k2 (m3/kg) 0.00239 0.00242 0.00205 0.00293 Specific Volume (m3/kg) 0.697 0.708 0.602 0.858 Gas Density 20oC, 1 atm kg/m3 1.434 1.412 1.661 1.165 Properties Physical Properties Generic Name IG-541 IG-55 IG-01 IG-100 Trade Name Inergen Argonite Argotec NN100 Extinguishing Design Concentration (% Vol.) Minimum Class A fire (% Vol.) 36.7 41.1 39.9 39.0 13.3 12.3 12.6 12.8 Class B Heptane (% Vol.) 31.7 36.5 39.3 33.6 Minimum Class B fire (% Vol.) 41.2 47.5 51.1 43.7 12.3 11.0 10.2 11.8 47.3 * 61.4 41.7 11.0 - 8.1 12.2 Oxygen (% Vol.) Oxygen (% Vol.) Inerting - Methane/Air (% Vol.) Oxygen (% Vol.) * Not Reported Flooding Factor Calculation (X) X - volume of inert gas ONLY added at 14.7 psia, 70oF (1.013 bar, 21oC) per volume hazard space (ft3/ft3 or m3/m3) VS - specific volume at 70oF (21oC) at 14.7 psia (1.013 bar) (ft3/lb or m3/kg) sV - specific volume at lowest temperature at 1 atmosphere (ft3/lb or m3/kg) t - minimum anticipated temperature (oF or oC) c - inert gas design concentration (%) Specific Volume Inert gas k1 k2 k1 k2 Unit type SI SI English English IG-01 (Argotec 0.5612 0.00205 8.40299 0.018281 IG-55 (Argonite) 0.65979 0.001207 9.8809 0.021496 IG-100 (Nitrogen) 0.7997 0.00293 11.973 0.0261 IG-541 (Inergen) 0.659 0.0024 9.858 0.0214 Flooding Factors (X) The calculation result in a series of flooding factors required to achieve various inert gas concentrations. 15 Flooding Factors (X) 36 0.446368 37 0.462119 38 0.478122 39 0.494385 40 0.510918 41 0.527728 42 0.544825 43 0.562220 44 0.57992 45 0.597945 46 0.616297 47 0.634993 48 0.654044 49 0.673466 50 0.693272 51 0.713478 52 0.734101 36.1 0.447932 37.1 0.463708 38.1 0.479736 39.1 0.496026 40.1 0.512586 41.1 0.529424 42.1 0.546551 43.1 0.563976 44.1 0.581711 45.1 0.599765 46.1 0.618151 47.1 0.636882 48.1 0.655970 49.1 0.675429 50.1 0.695274 51.1 0.715522 52.1 0.736187 36.2 0.449498 37.2 0.465299 38.2 0.481354 39.2 0.497670 40.2 0.51426 41.2 0.531124 42.2 0.548280 43.2 0.565736 44.2 0.583501 45.2 0.601588 46.2 0.620008 47.2 0.63877 48.2 0.657899 49.2 0.677396 50.2 0.69728 51.2 0.717569 52.2 0.73828 36.3 0.451067 37.3 0.46689 38.3 0.482973 39.3 0.499316 40.3 0.515931 41.3 0.532826 42.3 0.55001 43.3 0.567498 44.3 0.585295 45.3 0.603415 46.3 0.621869 47.3 0.640670 48.3 0.65983 49.3 0.679367 50.3 0.699291 51.3 0.719621 52.3 0.740372 36.4 0.452638 37.4 0.46849 38.4 0.484596 39.4 0.500966 40.4 0.517608 41.4 0.534532 42.4 0.551747 43.4 0.569264 44.4 0.587093 45.4 0.60525 46.4 0.623733 47.4 0.642570 48.4 0.661768 49.4 0.681341 50.4 0.701306 51.4 0.721677 52.4 0.742471 36.5 0.45421 37.5 0.470088 38.5 0.486221 39.5 0.502617 40.5 0.51929 41.5 0.536240 42.5 0.553485 43.5 0.571032 44.5 0.588893 45.5 0.607079 46.5 0.625601 47.5 0.644473 48.5 0.663708 49.5 0.683320 50.5 0.703324 51.5 0.723737 52.5 0.744575 36.6 0.45579 37.6 0.471690 38.6 0.487848 39.6 0.504272 40.6 0.520970 41.6 0.537951 42.6 0.555226 43.6 0.572804 44.6 0.590697 45.6 0.608916 46.6 0.627472 47.6 0.646380 48.6 0.66565 49.6 0.685302 50.6 0.705347 51.6 0.725801 52.6 0.746682 36.7 0.457367 37.7 0.473294 38.7 0.48948 39.7 0.505929 40.7 0.522655 41.7 0.539665 42.7 0.556970 43.7 0.57458 44.7 0.59250 45.7 0.610756 46.7 0.629347 47.7 0.648291 48.7 0.667600 49.7 0.687289 50.7 0.707374 51.7 0.727870 52.7 0.74879 36.8 0.458949 37.8 0.474901 38.8 0.491111 39.8 0.50759 40.8 0.524343 41.8 0.541382 42.8 0.558717 43.8 0.576357 44.8 0.594314 45.8 0.612600 46.8 0.631226 47.8 0.65020 48.8 0.669551 49.8 0.68928 50.8 0.709404 51.8 0.729943 52.8 0.750912 36.9 0.460532 37.9 0.476510 38.9 0.492747 39.9 0.509252 40.9 0.526034 41.9 0.543102 42.9 0.560467 43.9 0.57814 44.9 0.596128 45.9 0.614447 46.9 0.633107 47.9 0.652123 48.9 0.671507 49.9 0.691274 50.9 0.711439 51.9 0.732020 52.9 0.753033 Sample Calculation - Inert Gas Room houses electronic equipment Ambient temperature is 70° F Room Dimensions are: Length: 40 feet Width: 20 feet Height: 10 feet Room Volume = L x W x H = 40 x 20 x 10 = 8000 cubic feet 17 Amount of Agent A=VxX where A is amount of agent (m3 or ft3) V is volume of space (m3 or ft3) X is flooding factor of space from calculation or chart (m3/m3 or ft3/ft3) 18 Sample Calculation - Inert Gas Using IG-541 Inergen Class A design concentration is: 39.9% Maximum Human Exposure Concentration for 5 minutes is: 42.8% Maximum Human Exposure Concentration for 3 minutes is: 52.3% Available cylinder sizes for Inergen are: 205 ft3, 266 ft3, 355 ft3 and 439 ft3 Flooding factor for 39.9% concentration is: 0.509252 Amount /Volume of Inergen required to create a 39.9% concentration in an 8000 ft3 enclosure is: A = V x X = 8000 x 0.509252 = 4074 ft3 of Inergen 19 Sample Calculation - Inert Gas Cylinder Selection Round up to 10 439 ft3 cylinders AACTUAL = NumberCYLINDERS x CylinderSIZE = 10 x 439 = 4390 ft3 20 Sample Calculation - Inert Gas Check to determine the actual concentration that will be achieved, by looking at “Flooding Factors for Inert Gases @ 70° F for selected concentrations. 0.54875 relates to a concentration of ≥ 42.2% but ≥ 42.3%. This is < maximum allowable concentration of 42.8% for 5 minute human exposure & > Class A design concentration 39.9% The quantity of Inergen is acceptable. 21