What do I What do I know about want to know about moles? moles? What have I learned about moles today? This 1. 2. 3. 4. 5. 6. unit test contains 6 types of problems: Molar mass and % composition—must be able to write a chemical formula Grams to moles (using molar mass) Moles to particles/atoms/molecules (using Avogadro’s #) Grams to moles to particles (using molar mass and Avogadro’s #) Empirical formulas Molecular formulas The SI (metric) unit used to measure the amount of a substance 1 mole is always equal to: --Molar mass (g/mole) --Avogadro’s number of particles (6.02 x 1023) --22. 4 Liters of a GAS (AKA molar volume) These may be used as conversion factors when working mole problems. Define molar mass AND Avogadro’s number. 1 mole of this substance table sugar (sucrose)-C12H22O11 # of atoms/ molecules/ particles Mass of 1 mole (molar mass) g/mole 342.0 Sodium chloride-NaCl 58.5 Cupric sulfate-CuSO4 159.6 Sulfur--S 32.1 Iron--Fe 55.8 Water—H2O 18.0 Volume of 1 mole Ex: Titanium 47.867 = 47.9 g/mole (this sample contains Avogadro’s number of atoms) Ex: oxygen 15.999 = 16.0 g/mole (this sample contains Avogadro’s number of atoms) Multiply the # of atoms for each element by the atomic mass from periodic table Ex:Magnesium hydroxide Mg (OH)2 Mg 1(24.3) = 24.3 O 2(16.0) = 32.0 H 2(1.0) = 2.0 58.3 g/mole (this mass also contains Avogadro’s number of molecules) Find the molar mass of aluminum sulfate Al 2 (SO4)3 Al 2(27.0) = 54.0 S 3 (32.1)= 96.3 O 12(16.0) = 192.0 342.3 g/mole (this mass also contains Avogadro’s number of molecules) Calculate trioxide. the molar mass of diarsenic Stannic carbonate Diarsenic pentasulfide Hydrofluoric acid Sucrose Shows the % of each element that makes up a compound Must be calculate molar mass first. Ex: magnesium hydroxide Mg (OH)2 Mg 1 x 24.3 =24.3 24.3/58.3 x 100 = 41.7% O 2 x 16= 32.0 32.0/58.3 x 100 = 54.9% H 2x1.0 = 2.0 58. 3 g/mole 2.0/58.3 x 100 = 3.4% Calculate the % composition of sulfurous acid SAVE YOUR WRAPPER FOR ENTIRE LAB!! DO NOT START CHEWING UNTIL YOU SIT DOWN BACK AT YOUR DESK. CHECK BALANCE TO MAKE SURE IT’S OK BEFORE YOU START!! READ PROBLEM: MAKE A HYOTHESIS: PROCEDURE DATA 1—4 TABLE 1—5 After chewing: (KEEP YOUR SAME BALANCE) Procedure Data 5—8 table 6—8 Conclusion Questions 1—2 Calculate the % composition for a sugar substitute called SUCRALOSE C 12( 12.0) = 144.0 H 19 (1.0) = 19.0 Cl 3 (35.5) = 106.5 O 8 (16.0) = 128.0 397. 5 g/mole % C= 144.0 / 397.5 x 100 = 36.2% % H= 19.0 / 397.5 x 100 = 4.8% % Cl= 106.5 / 397.5 x 100 = 26.8% % O= 128.0/ 397.5 x 100 = 32.2% 1. Calculate the % composition of carbonic acid. 2. Calculate the % composition of diantimony trioxide. 1. H2CO3 H-2 (1.0) = 2.0 3.2% C- 1 (12.0) = 12.0 19.4% O – 3(16.0) = 48.0 77.4% 62.0 g/mole Sb2O3 Sb- 2(121.8) =243.6 O – 3(16.0) = 48.0 291.6 g/mole 2. 83.5% 16.5% Calculate the molar mass AND % composition of: 1. C12H22O11 2. Cupric sulfate C: 12 (12.0) = 144.0 H: 22 (1.0) = 22.0 O: 11(16.0) = 176.0 CuSO4 Cu: 1(63.5)= 63.5 S: 1 (32.1) = 32.1 O: 4(16.0) = 64.0 Will need to use unit conversion(cancellation) and molar mass will be used for the conversion factor. Ex: 2.50 grams of hydrochloric acid = ____moles H Cl 2.50 grams x 1 mole = 0.0685 moles(3sigfigs) 36.5 grams Ex: 2.50 moles of HCl = __________grams 2.5 moles x 36.5 grams = 1 mole 91 grams (2 sig figs) Particles, atoms, molecules (synonyms) Will have to use Avogadro’s number as a conversion factor Ex: 5.25 x 1025 atoms of Mg = _____moles 5. 25 x 1025 atoms x 1 mole = 87.2 moles 6.02 x 1023 (3 sig figs) 2.50 moles MgO = _________molecules 2.50 moles x 6.02 x 1023 molecules 1 mole = 1.50 x 1024 molecules (3 sig figs) Will need to use both molar mass AND Avogadro’s number as conversion factors Will be 2 steps instead of 1 step unit cancellation Ex: 4.5 grams nitrous acid = __________molecules HNO2 4.5 g x 1 mole x 6.02 x 1023 molecules = 47 g 1 mole 5.8 x 1022 molecules (2 sig figs) Ex: 9.35 x 1021 particles of carbon tetrabromide = _____grams C Br4 9.35 x 1021 p x 1 mole x 154 grams = 6.02x1023 p 1 mole 2.39 grams (3 sig figs) 1. 2. 3. 4 5. 6. 7. 8. 0.14 mole (gram to moles) 150 g (moles to grams) 1.1 x 1023 molecules (g to molecules) 5.30 x 1025 molecules (moles to molecules) 0.074 mole( gram to moles) 0.619 g (particles to grams) 0.49 mole (grams to moles) 0.00083 mole (particles to moles) 22 g 2. 1.53 x 1024 molecules 3. 0.014 g 4. 7.2 x 1021 molecules 5. 7.2 x 1023 molecules 6. 2.08 x 106 g 7. 56 g 8. 2.5 g 9. 31 g 10. 0.0029 mole 11. 167 g BONUS: 3.37 x 1026 atoms 1. If grams are converted to moles, use _______________ to convert. If moles are converted to molecules, then use ______________to convert. ****Have calculator, periodic table, and best friend chart**** All members of your group must show their work on separate sheet of paper. When you calculate the answer, flip the card over to find a word. All of your words will make a sentence. First group to show all work and finish first, wins bonus! Grams-----moles-----particles(atoms or molecules) 1. 55.33 grams of sodium oxide = ____moles 2. 5.00 x 1022 particles of sodium= _______moles 3. 2.49 x 1026 atoms of acetic acid = _______________grams Video sheet Problems #1—3, 5, 6 Fill in the blanks with multiply/divide OR molar mass/Avogadro’s number: ***When going from moles to grams, _______________ by _____________. ***When going from moles to particles, ____________by _________________. I AM CHECKING 5 HOMEWORK PROBLEMS!!!! Briefly describe the steps for calculating an empirical formula AND molecular formula. Define empirical formula ***both labs due today*** 1. Convert 5.03 x 1024 molecules of phosphoric acid to grams. 2. Convert 35.75 grams of dinitrogen monoxide to moles. 3. Convert 5.0 moles of water to molecules. 1. 819 grams of H3PO4 2. 0.8125 moles of N20 3. 3.0 x 1024 molecules of water Tell how to solve for each: 1. G to moles 2. Moles to G 3. Particles to moles 4. Moles to particles 5. G to particles 6. Particles to G HYPOTHESIS, DATA 1—8, CONCLUSION, QUESTIONS 1—4 3. MASS OF SUGAR (in grams—data #8)--------MOLES (SUGAR = C12 H22 O11) 4. MOLES----------PARTICLES Data Table: mass of empty vial AND substances mass (make sure you’ve subtracted empty vial each time!!) SHOW WORK TO GET CREDIT CONVERT GRAMS----------MOLES CONVERT MOLES---------PARTICLES ANSWER QUESTIONS 1---5, 6 (BONUS) Convert 25.0 moles of water to grams. A molecular formula is a whole number____________of the empirical formula. Shows the SIMPLEST, WHOLE NUMBER ratio of elements in a compound Will give you % composition of compound and ask you to find the formulas 1. Change % sign to grams (some problems may already give you grams instead of %) 2. Convert grams to moles (using molar mass) **round to 4 decimals*** 3. Simplify the mole ratio by dividing each one by the smallest 4. Round to the nearest whole number and assign these numbers to the appropriate element A compound is 78.1% Boron and 21.9% H. Calculate the empirical formula. 78.1 grams B x 1 mole = 7.2315 moles B 10.8 g 21.9 grams H x 1mole =21.9 moles H 1.0 g 7.2315 : 21.9 7.2315 7.2315 1: 3 = BH3 Is a WHOLE NUMBER MULTIPLE of the empirical formula You must then first know the empirical formula 1. You must first have empirical formula (if not, you will have to calculate it first!!) 2. Find the molar mass of the empirical formula. 3. Take the molar mass of the molecular formula that is given in the problem divided by the empirical formula’s molar mass. Round this to a whole number. Distribute this number to the numbers within the empirical formula to get the new molecular formula. 4. Given the empirical formula of BH3 and the molecular formula’s molar mass of 27.67 g/mole, find the molecular formula. Molar mass of BH3 is 13.8 g/mole 27.67 divided by 13.8 = 2 So molecular formula is B2H6 A compound is 4.04 grams of nitrogen and 11.46 grams of oxygen. The molecular molar mass is 108.0 g/mole. Find the molecular formula. 4.04 g N x 1 mole= 0.2886 mole N 14.0 g 11.46 g O x 1 mole =0.7163 mole O 16.0 g 0.2886 : 0.7163 0.2886 0.2886 1: 2 = NO2 empirical molar mass = 46.0 g/mole 108.0 divided by 46.0 = 2 Molecular formula = N2O4