V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow Mixed type binding systems. A sustainable alternative for RCC Pavements I. Papayianni, E. Anastasiou, M. Papachristoforou Laboratory of Building Materials Aristotle University of Thessaloniki Greece V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow Background Binders are the most precious materials in building construction, since they transform a volume of grains into a compact, load-bearing material of adequate volume stability Portland cement is an excellent high-strength binder which predominates in construction, but is also an energy consuming, high-cost material of low ecological profile Under the pressure of reality: Climatic changes and catastrophes Global economic depression Need of longer service life for constructions There is an urgency to develop alternative smart mixed type binding systems Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow Background A first simple step for sustainability integration in construction is to make local industrial by-products (fly ashes, slags) beneficial for the structural sector How do we work to exploit industrial by-products to the maximum: Test the suitability of the by-products as cementitious materials for a specified use Development of a mixed type binding system and assessment of its quality Design and proportioning of a proper concrete mixture for a specified strength Test the compliance of the concrete with a control mixture Proceed to a pilot application of the designed concrete Measure the concrete performance and the long term characteristics on site Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow The construction of a RCC road pavement with a fly ash-based binding system Stakeholders: Aristotle University of Thessaloniki (responsible for research and consultancy) National Technical University of Athens TITAN Cement Industry EGNATIA ODOS S.A. TERNA Construction Company Project: TEFRODOS 2011-2014 Funds: General Secretary of Research and Technology, Greece Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow The construction of a RCC road pavement with a fly ash-based binding system In Greece, only asphaltic concrete has been used for road pavements There is no tradition in bedding concrete road pavement The RCC pavement alternative seems to be the most feasible solution The main advantages for such a solution are: Longer service life and lower cost of maintenance Reduced environmental footprint 600000 kg CO2-eq 500000 400000 Recycling & disposal 300000 Maintenance 200000 Construction 100000 0 Asphalt pavement Concrete pavement Global Warming Potential over 100 years Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow The construction of a RCC road pavement with a fly ash-based binding system Stronger and resistant to heavy truck circulation (RCC pavements are recommended for interchange ramps and heavy truck traffic in hot climates) Reduction of thermal emissions Light reflectivity Infrared photgraphy of the Atlanta Hatfield Airport (property of NASA) where asphalt parking lots develop higher temperature compared to concrete parking lots Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow The construction of a RCC road pavement with a fly ash-based binding system The initial construction cost of a concrete road is slightly higher than that of Cost(€/m2) asphaltic concrete By using fly ash-based hydraulic binders the cost is significantly reduced 50 45 40 35 30 25 20 15 10 5 0 Initial construction cost (€/m2) 041 041 Asphalt pavement Concrete pavement 046 Concrete pavement with asphaltic anti-skid layer Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow Development of the mixed type binder and quality assessment Aim: 28-d compressive strength of 40 MPa, so as to have on site at least 30 MPa Materials (% by mass) Calcareous fly ash 50% Clinker 25% Natural pozzolan 12.5% Limestone filler 12.5% Test measurements: Blended mixed type binder Testing according to EN 13282 for Hydraulic Road Binders Fineness Grinding time Water demand Setting time Le Chatelier volume stability Compressive strength at 2, 7 and 28 days Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow Characteristics of the constituents of the hydraulic binder developed Cement clinker Calcareous fly ash Limestone filler Natural pozzolan SiO2 (%) 21.35 34.40 0.20 63.80 Al2O3 (%) 5.40 13.60 0.20 18.10 Fe2O3 (%) 3.40 6.10 0.05 4.10 CaO (%) 65.75 32.80 55.00 2.80 MgO (%) 1.60 3.80 0.60 1.00 CaOfree (%) 1.30 6.40 n/a n/a SiO2-reactive (%) n/a* n/a n/a 35.00 SO3 (%) 1.20 6.78 0.00 0.00 L.O.I. (%) 0.00 3.26 44.10 3.20 Insoluble residue (%) 0.00 23.80 0.00 82.80 Content/ Property Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow Properties of the produced mixed type hydraulic binder Physical properties Blaine (cm2/g) 9550 Fineness (retained at 45 μm) 0.4 Water requirement (%) 41.5 Initial setting time (min) 210 Le Chatelier dilation (mm) 0.0 2-day compressive strength (MPa) 15.9 7-day compressive strength (MPa) 26.3 28-day compressive strength (MPa) 40.1 Chemical properties L.O.I. (%) SO3 (%) Insoluble residue (%) CaOfree (%) Chemical analysis SiO2 (%) Al2O3 (%) Fe2O3 (%) CaO (%) MgO (%) Laboratory of Building Materials - Aristotle University of Thessaloniki 8.40 3.20 26.40 4.80 29.90 12.65 3.80 42.90 2.20 V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow Proportioning RCC with fly ash-based hydraulic binder “Tefrocement” Required strength: fck C25/30 Maximum Vebe density (according to ACI 325.10R-95) with Vebe time: 20-40s Available aggregates: Crushed limestone of maximum size 31.5 mm or 16 mm “Tefrocement” quantity: ≤ 300 kg/m3 Water/cementitious ratio: ≤ 0.50 Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow The proposed aggregate gradations Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow Trial mixes series A and B Mixture Hydraulic Road Binder (kg/m3) Water (kg/m3) Fine aggregate (kg/m3) Coarse aggregate (kg/m3) Max. aggregate size (mm) A1 280 153 1096 897 16 A2 280 153 1096 897 16 A3 280 196 1096 897 16 A4 280 163 1096 897 16 B1 300 120 1096 897 31.5 B2 270 135 1096 897 31.5 B3 280 150 1096 897 31.5 B4 280 148 1096 897 31.5 superplasticizer (%wt. of binder) w/cem Vebe time (s) Vebe density (kg/m3) Electrical hammer density (kg/m3) 7-d compr. strength (MPa) 0.0% 0.54 2427 1.0% 0.54 2396 1.0% 0.70 20 2428 0.0% 0.58 60 2410 1.0% 0.40 8 2396 1.0% 0.50 9 - 1.0% 0.54 60 2389 0.5% 0.53 35 2404 2480 2355 2446 2447 - - 2408 2478 33.5 28.3 22.4 32.4 - 22.0 28.6 31.1 28-d compr. strength (MPa) 43.8 35.7 30.9 46.0 35.4 35.3 37.5 42.3 Decision to use 280 kg/m3 “Tefrocement” Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow New series of laboratory test mixtures series A and B, accounting for transport time Mixture Hydraulic Road Binder (kg/m3) Water (kg/m3) Fine aggregate (kg/m3) Coarse aggregate (kg/m3) Maximum aggregate size (mm) superplasticizer (%wt. of binder) w/cem Vebe time (s), t=0' Vebe time (s), t=30' Vebe density (kg/m3), t=0' Vebe density (kg/m3), t=30' A5 280 148 1096 912.6 16 0.0% 0.53 60 100 2385 2420 A6 280 148 1095.8 912.6 16 0.5% 0.53 40 80 2313 2410 B5 280 159 1095.8 629.2 31.5 1.0% 0.57 12 30 2430 2415 B6 280 148 1096 629.2 31.5 0.0% 0.53 50 80 2447 2400 Electrical hammer density (kg/m3), t=0' 2474 2505 2466 2490 7-d compressive strength (MPa) 28-d compressive strength (MPa) 31.4 45.6 30.7 43.4 25.5 37.9 33.7 49.3 Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow Pilot construction Ground layer with CBR ≥ 18 Concrete plant at 30 minutes driving distance Continuous feeding of the paver Compaction achieved by rollers Measurement of compaction with Humboldt nuclear gauge Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow Truck loading Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow Truck unloading onto paver Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow Difficulty unloading truck due to delay in transportation Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow Laying RCC Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow Laying RCC Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow Roller compaction of pavement Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow Fresh concrete density measured with nuclear gauge Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow Achieved compaction Only with the paver, the compaction achieved was 80% depth directly after the paver after compaction 5 cm 81.8% 90.4% 10 cm 81.2% 91.3% 15 cm 81.0% 90.6% 20 cm 79.7% 89.3% average total pavement thickness (cm) - 22.1 Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow Effective compaction scenarios 3 non vibrating passes with a 4 ton roller 2 vibrating passes with a 10 ton roller Maximum single layer thickness achieved: 20 cm Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow Joints Shrinkage joints: cut every 5.5-6.0 m after hardening, to a depth corresponding to 1/4 - 1/3 of the road thickness Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow Joints Thermal dilation joints Source: Cement and Concrete Association of New Zealand, "Concrete ground floors and pavements", Part 1 Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow Survey of concrete pavement 2 months after construction Core drilling and testing Mechanical properties Freeze-thaw resistance (-25°C to +20°C) Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow Survey of concrete pavement 2 months after construction Mechanical properties of drilled cores Construction area (average of 6) 1 2 3 pulse velocity u (m/sec) 4625 5022 4713 density ρ (kg/m³) 2295 2394 2345 Compressive strength fc (MPa) 25.0 32.0 31.8 Continuous monitoring of the test road Laboratory of Building Materials - Aristotle University of Thessaloniki V International Conference ASHES FROM TPPS – Removal, Transport, Processing, Storage April 23-25, 2014, Moscow Conclusions The construction of a RCC road with this mixed type binder is feasible The technical problems that appeared were properly confronted The long term strength and resistance were adequate in order to guarantee a long service life The incorporation of a low cost industrial by-product into a hydraulic binder contributes essentially towards lowering the initial cost of a concrete road, rendering this sustainable alternative also cost-effective. Laboratory of Building Materials - Aristotle University of Thessaloniki Thank you for your attention! Laboratory of Building Materials - Aristotle University of Thessaloniki