Athens_ICL_WP1_ESG - Workspace

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5

th

Progress Meeting

INASCO (22

nd

/23

rd

May 2012)

Emile S. Greenhalgh, Project Co-Ordinator

The Composites Centre, Imperial College, London

© The Composites Centre, Imperial College London

Agenda – 3

rd

Progress Meeting

Tuesday 22

nd

May (am)

09:30

09:45

10:00

10:15

10:30

10:45

11:30

11:45

12:30

13:00

Coffee, Welcome and Introductions

Minutes of the Last Meeting

WP1: Management/Overview of Project and Deliverables (Imperial/SICOMP)

WP1: Status of project extension (Imperial/SICOMP)

WP2: Reinforcement Development (Nanocyl) - overall status and management

WP2: Partner Presentations (max 20 minutes each)

WP2 - Nanocyl, Swerea Sicomp, BAM, ETC

WP3: Multifunctional Resin Development (Imperial) - overall status and management

Partner Presentations (max 20 minutes each)

WP3 - Imperial College London, Swerea Sicomp, Inasco, Chalmers, Umeco, BAM,

ETC

WP8: Project Demonstration and Exploitation (Inasco)

Lunch

© The Composites Centre, Imperial College London

Agenda – 3

rd

Progress Meeting

Tuesday 22

nd

May (pm)

14:00

14:15

WP6: Systems (SICOMP)

Partner Presentations (max 20 minutes each)

WP6 - Swerea Sicomp, Imperial College London, Inasco, Volvo, ETC

15:15

15:30

WP7: Demonstrator Development (SICOMP)

Partner Presentations (max 20 minutes each)

WP7 - Swerea Sicomp, Imperial College London, Inasco, Chalmers, Umeco, Nanocyl,

BAM, Volvo, ETC

16:00 WP6/7 Discussion – Design of Wheel Well

17:00 End of day one

19:00 Common dinner in Athens

© The Composites Centre, Imperial College London

Agenda – 3

rd

Progress Meeting

Wednesday 23

rd

May (am)

09:15

11:15

11:30

12:30

Coffee and Welcome

09:30 WP4: Composite Manufacture (Umeco) - overall status and management

09:45 WP4: Discussion regarding weave issues and suggested

10:45

mitigation (Imperial)

Partner Presentations (max 20 minutes each)

WP4 – Umeco, Imperial College London, Inasco, Swerea SICOMP, Nanocyl

WP5: Composite Characterisation (BAM)

Partner Presentations (max 20 minutes each)

WP5 – BAM, Imperial College London, Swerea Sicomp, INASCO, Chalmers, Umeco

AOB, Date of next meeting and close

13:00

14:00

Lunch

Optional tour of INASCO facilities

© The Composites Centre, Imperial College London

Agenda – 3

rd

Progress Meeting

Objectives of Meeting

• Report on Progress in all Work Package, and compare with plan

• Progress the design of the wheel well (WP6/7)

• Resolve the issue of the influence of weave on electrical performance (WP4/5)

© The Composites Centre, Imperial College London

Evening Plans

Dinner is at 8pm and the location is

Filistron restaurant.

23, Apostolou Pavlou str.

Thission

Athens

11851 info@filistron.com

+30 103422897 http://www.filistron.com/

© The Composites Centre, Imperial College London

6

Actions from Last Meeting

Action

Action 2.12 Approach to David Porter at

Oxford University to discuss GIM modelling in the context of structural power is still open.

MRS happy to invite DP to Umeco to discuss this. ESG will contact him to arrange a visit.

Action 3.10 Student projects are underway at Imperial. Please approach ESG if you are interested in being involved in these.

On

ESG

ICL/ALL

Outcome (Grey = complete)

Complete

– but awaiting response from David Porter

Complete - Currently two UG projects underway looking at influence of curvature on structural power performance. One is making the Usection arms of the quadcopter from a baseline structural power material

(PEGDGE + 10% IL). The other is making a model car body out of the material (Device B) in conjunction with Umeco and McLaren cars.

There are also two MSc projects which have just started. One is looking at alternative separator materials (in conjunction with

McLaren) and the other is characterising the acoustic performance of our materials.

© The Composites Centre, Imperial College London

Actions from Last Meeting (Continued)

Action

Action 4.3

ESG and LA have met to collate and formulate the amended document and formalize changes. ESG is currently revising the document, which will be issued to Mr Bird in February to apply for an extension.

Action 4.5

JS and PJ have developed a plan to determine the effect of moisture on the electrical properties, including its monitoring and methods to extract effects of moisture from all data established on resins and laminates to date and in the future. The document will be included with the minutes and partners should provide comments.

Action 4.10

ACG to send a specification of the screening tests at ACG for crashworthiness to MW. The specification has now been sent to ICL, who are developing it further and will issue a revised specification.

Action 4.11

BAM sorting out the revised sample code

On

ICL/ALL

JS/PJ/ALL

ESG

MW

Outcome (Grey = complete)

Complete - Document has been issued to the EU with request for an extension. Mr Bird has been positive about the outcome, but no further information yet.

Complete

– document issued

Complete

– Sang will elaborate on this

Complete

– BAM will elaborate on this

© The Composites Centre, Imperial College London

Actions from Last Meeting (Continued)

Outcome (Grey = complete) Action

Action 4.12

VE have sent ICL and NANOCYL information on the size of materials needed to make battery cells from CNT-coated and CAG-coated fabrics. NANOCYL and ICL will then send materials to

VE and LA for tests in WP6. Also LA is to provide the

MWCNT coated CF-fabric to KTH for coin cell tests. Sicomp and ETC have started to produce and test some smaller cells for evaluation of electrical properties, currently working with small cells using sheets of 40x40 mm. For the electrical properties of the materials in a battery this is sufficient. VE mentioned that 150x150mm cells have been suggested, and are currently focusing on improvement of the production method and the electrical performance of the battery cells. VE said ETC can use

40x40 mm for evaluating the materials from a battery perspective. If successful ETC can investigate the possibility to scale up for mechanical testing.

On

VE/LA/ESG/

MH

© The Composites Centre, Imperial College London

Actions from Last Meeting (Continued)

Action

Action 4.15

SICOMP/ACG to press forward on development of small-scale demonstrators to be used by the partners at future events such as JEC in April 2012. TC

On

SC/TC/QF

Outcome (Grey = complete)

Complete

– presented at JEC,

Swedish national exhibition and

Imperial Festival events.

and QF/SC should discuss to move this forward quickly.

Action 5.2

ESG/SN/MW to investigate scope ESG/SN/MW for characterising the acoustic response of the STORAGE materials.

Action 5.3

Regarding electrical connection of the laminates, there was discussion that read-across from lightning strike protection

Complete – MSc student will be working on this at ICL

ESG/MM/MW Still being explored

– there are some parallels but nature of the electrical loading is different.

on conventional composites in aerospace applications could be utilized.

Action 5.4

GW and PC will provide contacts in the aerospace industry who have knowledge of lightning strike protection in aircraft.

Action 5.5

ESG will proceed with the extension application.

GW/PC

ESG

Complete

Complete

© The Composites Centre, Imperial College London

Model Demonstrator

• Radio controlled car built by SICOMP &

Umeco

 Two cell Device B laminates

 No batteries in car, battery in controller charges roof laminate which lights LEDs

 Raised cutting/grinding issues – laminates need to be made to size

• Demonstrated at a exhibitions, etc

 Umeco stand at JEC (Paris, 03/2012)

 Swedish Foundation for Strategic

Research’s (SSF) Materials Science

Programme Conference - Stockholm

(04/2012).

 Video for ‘Fully-Charged’ show http://www.youtube.com/watch?v=rMOxrDxq_do&lis t=PL971B96323746C745&index=8&feature=plcp

 Imperial Festival (05/2012)

© The Composites Centre, Imperial College London

11

Actions from Last Meeting (Continued)

Action

Action 5.6

Formulate a small test plan to investigate the effect of moisture on electrical and mechanical properties of the laminates, as an extension of Action 4.5. It is suggested this will utilize Device B, and use in-plane shear testing. It is recognized that electrical testing after preparation for mechanical testing can be challenging, so perhaps the

‘traveller’ approach could be utilised here.

Action 5.7

There is a need to consider metalized film for bagging of laminates to avoid moisture ingress. TC has information on the supply of such a metalized film which he will send to NS.

Action 5.8

There was discussion regarding cutting of these materials (which will need to be done dry), and GW suggested cryogenic cutting could be a good approach, and would send further details of this.

On

ESG/SN/NS/

JS

TC

GW

Outcome (Grey = complete)

Plan for controlling moisture, using travellers, has been devised, but

Complete – now being used

© The Composites Centre, Imperial College London

Actions from Last Meeting (Continued)

Action

Action 5.9

During the meeting there was some discussion regarding weave style of the laminates, and it was identified that

Devices A and B will need to be remade using 5HS fabric rather than plain weave material.

Action 5.10

SICOMP will consider Device G and advise as to the approach to be taken towards manufacture for mechanical testing.

Action 5.11

The test plan for the partners has been drawn up; this will be agreed with the appropriate partners.

However,

INASCO’s testing work is unclear; a short presentation was sent to MW by Tasia Gkika.

The issues of what can be measured by

INASCO will be established by discussion with Tasia.

Action 5.12

The temperature range and humidity range still needs to be established, and therefore a specification will be compiled.

On

QF/SC

LA/TC

ESG/MW/TG

ESG/LA/MW/

PS

Outcome (Grey = complete)

Complete, but maybe revised. 5HS was confirmed. However, an unexpected problem has arisen which we will discuss during WP4.

Complete

© The Composites Centre, Imperial College London

Actions from Last Meeting (Continued)

Action

Action 5.13

MW will circulate the test plan and establish delivery dates for each stage so that the testing schedule can be finalized.

Some fractography may be done at SICOMP and ICL.

Action 5.14

For manufacturing plenum cover parts TC needs some MTM57 UD prepreg, any carbon fibre, about 10 cm width about

20 lm. Umeco will look into this.

Action 5.15

TC will consider the Gantt and work description to integrate the additional intermediate demonstrators, and will send this to ESG.

Action 5.16

MH will look into a cost analysis

(if these costings can be compared in generic terms without revealing industrially sensitive process costs information.)

Action 5.17

Scope for a student project on separators to complement STORAGE, and also scope to characterise the impact of different separator thicknesses/stiffnesses on the mechanical properties (both elastic and delamination).

© The Composites Centre, Imperial College London

On

MW

QF/SC/TC

LA/TC

MH

ESG/SN

Outcome (Grey = complete)

Complete

– a test plan has been issued (D5.1)

Complete

Complete – student project currently underway to characterise this

Actions from Last Meeting (Continued)

Action

Action 5.18

PJ will ask TG for an explanation of what the presentation is showing.

Action 5.19

QF will send TC some samples of veils, (typically a square foot).

Action 5.20

TC has encountered issues with curing of his resins. He will discuss this with

NS and SC.

Action 5.21

Regarding D4.1, QF to ask for information from partners to clarify what is required.

Action 5.22

MM to speak to TG about their expertise in electrical connection to composite laminates.

On

PJ

QF

TC/NS/SC

QF

MM

Outcome (Grey = complete)

Complete

Complete

Report being issued to PC, and will reply with comments

© The Composites Centre, Imperial College London

December 2012

June 2013

Dates for Future Meetings

(Assuming Extension)

Progress Meeting #6 – Imperial College London , UK

Final Meeting – Volvo Car Corporation , Sweden,

© The Composites Centre, Imperial College London

Device Configurations

Device # Type Reinforce (i) Reinforce (ii) Insulator*

A Baseline T300 fabric T300 fabric ACG Style 120

B

C

D

E

I

F

G

H

Baseline

Multifuncti onal

T300 fabric T300 fabric ACG Style 120

Supercap

1a

Supercap

1b

Supercap

2a

T300 CNT

T300 CNT

T300 CNT

T300 CNT

T300/AquaCyl

3+

T300/AquaCyl

3+

ACG Style 120

ACG Style 120

ACG Style 120

Baseline

CNT

Reinforced

T300 CNT T300 CNT ACG Style 120

Battery 1

T800 cloth

(unsized)

Pseudo cap MnO2 loaded

1 CAG

Metalised Film ACG Style 120

CAG ACG Style 120

Capacitor 1 T300 fabric T300 fabric PET Film 1

Matrix

MTM57

MTM57:IL:Li conc1

MTM57:IL:Li conc1

MTM57:IL:Li conc2

MTM57:IL:Li conc1

MTM57

MTM57:IL:Li conc1

MTM57:IL:Li conc1

MTM57

Mechanical Test

Regime

Full

Reduced

Full

Reduced

Full

Reduced

Full

Reduced

Full

Electrical Test

Regime

None

Reduced

Full

Reduced

Full

None

Full

Reduced

Full

J Capacitor 2 T300 fabric T300 fabric PET Film 2 MTM57 Reduced Reduced

K

MTM57:IL:Li

Supercaps 3 ply laminates (CF/GF/CF); Batteries 7 ply laminates (CF i

/GF/CF ii

/GF/CF ii

/GF/CF i

)

© The Composites Centre, Imperial College London

Laminates

Panel

(i)

Details Dimensions

Shear

180mm x

180mm

(ii) Compression

180mm x

180mm

Layup

[±CF/

[CF

4

]

S

S

Mec Ele A

X

X

X X

X

(iii)

Fracture

Toughness /

ILSS

180mm x

180mm

[CF/

2

/CF

2

/GF

2

/PTFE/CF

2

/

GF

2

/CF

2

/GF

2

/CF]

X X X

B

X

X

C

X

X

X

D

X

X

E

X

X

X

F

X

X

G

X

X

X

H

X

X

I

X

X

X

J

X

X

K

© The Composites Centre, Imperial College London

Panels (i) and (v)

[±CF/±GF]

S

Laminates

180 x 180 mm

Panel (iii)

]

© The Composites Centre, Imperial College London

Mechanical Testing Regime

Properties

Test method

Standard

Specimen

Size

Partner

Test

Regime

Device # t

In-plane shear modulus & strength

+/- 45

° tensile

DIN EN ISO 14129

- ASTM test

D3039/D3039M

150mm x

25mm compressive strength & modulus compression test

(DIN EN ISO

14126) ICL

90mm x

10mm

ICL/BAM reduced/full A-J 1mm (4ply)

ICL/BAM reduced/full A,C,E,G,I > 2 mm

Laminate #

(i)

(ii)

Stacking

Sequence

[±CF/

S

[CF

4

]

S

ILSS bending test

(short beam)

DIN EN ISO 14130

- ASTM

D2344/D2344M

25mm x

12mm

BAM/

SICOMP

Interlaminar fracture toughness energy

DCB test DIN EN 6033/6034

180mm x

20mm

SICOMP full full

A,C,E,G,I 3mm

A,C,E,G,I 3 mm

(iii)

(iii)

GF

2

/CF

2

/GF

2

/PT

FE/CF

2

/GF

2

/CF

2

/GF

2

/CF]

GF

2

/CF

2

/GF

2

/PT

FE/CF

2

/GF

2

/CF

2

/GF

2

/CF]

T g

DMTA cantilever beam test

?

10mm x 2mm

Chalmers

?

full A,C,E,G,I 0.4-0.6 mm (i) [±CF/

S

© The Composites Centre, Imperial College London

Electrical Testing

• Supercapacitors:

 Charge-discharge experiments: Voltage - 0.1 V (most likely we will increase voltage); Charge time 10 s (can be varied); Discharge time 10 s (can be varied).

 Cyclic voltammetry: sweep rates of 5 mV/s to 50 mV/s, window of −0.5 to 0.5 V.

 Electrochemical impedance; frequency range from 106 Hz to 10-3 Hz, sinusoidal voltage amplitude 5 mV.

 Effect of moisture/temperature; DiAMon monitoring

• Batteries:

 Capacity and energy cycling, (Charge/Discharge)

 Self discharge

 Internal resistance - pulsed charge/discharge

 OCV characterisation, Life length

• Capacitors:

 effect of moisture and temperature DiAMon monitoring

 dielectric strength ?

 capacitance/ (specific energy) - 0.1-100Hz at 1V

© The Composites Centre, Imperial College London

Task

1 10.2

1_1 10.2

2

2_0

46.5

2.5

2_1 25.5

2_2 4.0

2_3 14.5

3

3_0

71.5

3.5

3_1 34.5

3_2 20.0

4 41.0

4_0 1.5

4_1 20.0

4_2 3.5

4_3

4_4

4_5

3.5

9.0

3.5

5

5_0

53.0

2.0

5_1 14.5

5_2 22.0

5_3

5_4

9.5

5.0

6

6_0

6_1

30.0

1.0

4.5

6_2 14.5

6_3 8.0

6_4 1.0

6_5 1.0

7

7_0

45.7

2.0

7_1 6.0

7_2 15.0

7_3 14.0

7_4 8.7

8

8_1

5.0

5.0

Gantt

Details

Management

Project Management

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42

2010 2011 2012 2013

J F M A M J J A S O N D J F M A M J J A S O N D J F M A M J J A S O N D J F M A M J

Reinforcement Development

Work Package 2 Management

Carbon fibre activation and grafting

Separator layer development

Anode (Metal Electrode) Development

Multifunctional Resin Development

Work Package 3 Management

Structural Electrolyte Development

Structural Dielectic Development

Composite Manufacture

Work Package 4 Management

Composite Processing

Capacitor Concepts

Battery Concepts

Supercapacitor Concepts

Hybrid Capacitor Concepts

Composite Characterisation

Work Package 5 Management

Characterisation of electrical properties

Characterisation of mechanical properties

Crashworthiness

Ranking of Devices

Systems

Work Package 6 Management

Concept Design

Power Management and Connectivity

Packaging and Integration

Cost and Benefits Modelling and Analysis

Ownership Issues

Demonstrator Development

Work Package 7 Management

Demonstrator Design

Demonstrator Manufacture

Demonstrator Testing and Evaluation

Demonstrator Assessment

Dissemination and Exploitation

Project Dissemination and Exploitation

© The Composites Centre, Imperial College London

22

Deliverables Completed to date

Original New Date # Deliverable name WP

1.1

Project Management plan, Risk

Register and Quality Plan

WP1

2.1 Delivery of optimised separator layer WP2.2

Lead

ICL

NCYL

3.1

Delivery of dielectric matrix materials

WP3.2

SICOMP for capacitor applications

8.1 Internal collaborative website set-up WP8.1

ICL

2.2

Report on the mechanical characterisation of the activated and WP2.1

NCYL

3.2

CNT grafted carbon-fibres

Report on the development and characterisation of matrix materials for structural supercapacitor applications

WP3.1

ICL

4.2

6.1

2.3

6.2

1.2

5.1

Completed fabrication of composite capacitor devices

Report on the cost/benefits analysis of structural power source materials

Report on SICOMP connector development

Report on the ownership issues associated with structural power source materials

1-18 Month Report

Testing Plan

WP4.2

WP6.4

WP2.3

WP6.5

WP1

WP5

ACG

SICOMP

NCYL

SICOMP

ICL

BAM

Mar-10

Sep-10

Sep-10

Mar-10

Nov-10

Feb-11

Mar-11

Apr-11

Dec-10

Jul-11

Jun-11

Mar-10

Dec-10

Dec-10

Dec-10

Mar-11

Mar-11

Mar-11

May-11

Jun-11

Jul-11

Aug-11

Feb-12

Motivation

Complete

Complete

Complete

Complete

Complete

Complete

Complete

Complete

Complete

Complete

Complete

New Deliverable

© The Composites Centre, Imperial College London

23

Deliverables due soon

#

4.1

2.4

3.3

2.5

Deliverable name

Report on the generic fabrication issues regarding fabrication of composite structural devices and

WP Lead

WP4.1

ACG

Original New Date

Mar-11 Feb-12 recommended processing guidelines

Report on the development and scale-up of activated and CNT grafted carbon-fibres for structural power applications at NCYL

Report on the development and characterisation of matrix materials for structural hybrid capacitor and battery applications

WP2.2

WP3.1

NCYL

SICOMP

May-11

Jun-11

Feb-12

Feb-12

Report on anode layer development and characterisation

WP2.3

NCYL Dec-10 Mar-12

4.3

4.4

6.4

Completed fabrication of composite supercapacitor devices

Completed fabrication of composite batteries devices

WP4.4

ACG May-11 Mar-12

WP4.3

ACG May-11 Jun-12

Report on the connectivity and packaging issues of structural power WP6.2

SICOMP Dec-11 Jun-12 source materials

Motivation

About to be issued - currently with

ESG

Knock-on delays with D2.2

Research will focus on tasks associated with hybrids once supercapacitor and battery technologies have been frozen.

Covering SICOMP metalized film and ICL CAG configurations

Delays in constituent development have had a knock-on effect on the supercapacitor fabrication.

Delays in constituent development have had a knock-on effect on battery fabrication.

Delay associated with delays in other WPs regarding characterisation of devices

© The Composites Centre, Imperial College London

24

Deliverables due before next meeting

#

5.2

5.3

Deliverable name WP Lead Original New Date

Report on the electrical properties of

WP5.1

BAM structural power source materials

Report on the mechanical properties

WP5.2

BAM of structural power source materials

Oct-11

Nov-11

Aug-12

Aug-12

6.3

5.5

3.4

6.5

7.1

4.5

Report on the conceptual design of structural power source materials

Report on the ranking of the structural power source devices

Report on improved performance of multifunctional resins for structural supercapacitor applications

Chosen configuration for design of demonstrator

Design of the demonstrators complete

Completed fabrication of composite hybrid capacitor devices

WP6.3

WP5.4

WP3.1

WP6.1

WP7.1

SICOMP

BAM

ICL

SICOMP

SICOMP

WP4.5

ACG

Oct-11

Feb-12

Jun-11

Dec-11

Mar-12

Aug-11

Aug-12

Sep-12

Sep-12

Oct-12

Dec-12

Dec-12

Motivation

Knock on from delays in constituent development

Knock on from delays in constituent development

Delay associated with delays in other WPs regarding characterisation of devices

Knock on from delays in constituent development

Change in research focus. The approach is to move effort to further develop the resin formulation chosen in D3.2 to improve its mechanical properties.

Knock on associated with delay in earlier WPs

Knock on associated with delay in earlier WPs

Shifting of hybrid development has led to a shift in fabrication (and characterisation) of final devices.

5.4

Report on the crashworthiness of the structural power source devices and methodology to mitigate thermal

WP5.3

ACG issues

Dec-11 Dec-12

Knock on from delays in constituent development

© The Composites Centre, Imperial College London

25

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