Innovative Remediation Technologies, Inc The VTX Process “Liquid Incineration” for a Cleaner Environment VTX • VTX is an organic catalyst that reacts with various oxidizing agents to produce hydroxyl radicals. • No sludge is produced as a result of the process in normal use. • Safe and easy to apply. • Application of catalyst requires no materials of special construction. Relative Oxidation Potential Reactive Species Relative Fluorine Hydroxyl radicals Atomic oxygen (singlet) Ozone Persulfate Hydrogen peroxide Permanganate Hypochlorous acid Chlorine Oxidation Power* 2.23 2.06 1.78 1.52 1.48 1.31 1.24 1.10 1.00* Odor & Corrosion Control Treatment of Sulfide The VTX Process Treatment of Sulfide Landfills Food Production Rapid Oxidation of Sulfide 100 80 Parts Per Million • VTX rapidly converts sulfide (H2S, HS-, S=) to elemental sulfur. • Immediate reduction of odor and corrosion due to H2S. • VTX is suited for control of sulfide in: 60 40 20 0 Animal Waste Municipal and Industrial Wastewater Treatment Before After 1 After 2 After 3 Treatment Minute Minutes Minutes Reaction Time and Dosage Comparison: H2O2 Alone vs. VTX Process Treatment of Hydrogen Sulfide Hydrogen Peroxide Alone H2S + H2O2 S0 + 2H2O Reaction time: 20-30 minutes Effective dosage (mass H2O2/mass H2S): 1.5 to 4.0 : 1.0 VTX Process H2S + VTX /H2O2 S0 + 2H2O + salts + CO2 + [VTX]* Reaction time: <3 minutes Effective Dosage (mass VTX/mass H2S): 1.5 to 2.5: 1.0 * Note: [VTX] = remaining un-reacted VTX Comparative Treatment of Sulfides in Wastewater Hydrogen Peroxide vs. VTX Process Peroxide Dosage at 2.5 times the Mass of Sulfide Sulfide (ppm) 20 15 10 5 0 0 5 10 20 15 25 Time (minutes) H2O2 only H2O2 w/ variable VTX dosages 30 Corrosion Control Melbourne, Florida 3 year old pipe Melbourne, Florida 3 year old pipe N. Brevard, Florida Headworks 7 years old – currently closed for repairs Estimated Affect of S= on Infrastructure Life Expectancy (3’ Diameter Concrete Pipe in Gravity Sewer) S= (ppm) Life Expectancy (Years)* 0.5 >50 1.0 25-50 1.5 25 2.0 10-25 2.5 10 3.0 10 4.0 5-10 7.0 5 >7.0 <5 *Varies based on alkalinity and pH scenarios Capital and Operational Savings The VTX Catalytic Process can rapidly eliminate >95% of the sulfides entering the headworks of a wastewater plant. York River STP Scrubber Influent H2S Treatment initiated @ 06:45, Stopped @ 14:45 Case Study California Wastewater Treatment Plant Case Study California Wastewater Treatment Plant Before and After Treatment Melbourne, Florida Lift Station Atmospheric H2S Parts Per Million (ppm) After Treatment Before Treatment 11:00 PM 10:00 PM 9:00 PM 8:00 PM 7:00 PM 6:00 PM 5:00 PM 4:00 PM 3:00 PM 2:00 PM 1:00 PM 12:00 PM 11:00 AM 10:00 AM 9:00 AM 8:00 AM 7:00 AM 6:00 AM 5:00 AM 4:00 AM 3:00 AM 2:00 AM 1:00 AM 12:00 AM 11:00 PM 10:00 PM 9:00 PM 8:00 PM 7:00 PM 6:00 PM 5:00 PM 4:00 PM 3:00 PM 2:00 PM 1:00 PM 12:00 PM 11:00 AM 10:00 AM 9:00 AM 8:00 AM 7:00 AM 6:00 AM 5:00 AM 4:00 AM 3:00 AM 2:00 AM 1:00 AM 12:00 AM Tim e of Day Tim e of Day 20 18 16 14 12 10 8 6 4 2 0 20 18 16 14 12 10 8 6 4 2 0 Parts Per Million (ppm) Before and After Treatment Melbourne, Florida Lift Station Aqueous Sulfide VTX Sludge Treatment Study Total Sulfide Destruction Springville, Utah Wastewater Treatment Plant Parts per Million (ppm) 30 25 20 15 VTX - Turned On VTX - Turned Off 10 5 0 7:00 8:15 9:30 10:45 12:00 VTX Calibration Period Time of Day 13:15 VTX Facts • VTX for treatment of organic and selected inorganic chemicals is patent pending. • VTX as a disinfectant is also patent pending. • VTX is EPA TSCA approved for use in the environment.