Common Effluent Treatment Plant Performance & Improvement; Issues and Opportunities Seminar on Technology Solution for Environment Upgradation Forest & Environmental Department Government of Gujarat Gandhinagar July 07, 2012 Dr. S. R. Wate, Director CSIR-National Environmental Engineering Research Institute Nagpur ISO 9001-2008 1 Small & Medium Scale Enterprises • In India, Small & Medium Scale Enterprises (SMEs) contribute significantly to global economy but face stiff environmental regulations. • Quantity of wastewater generated from SMEs may not be large, but unfortunately it aggregates to be a major pollution contributor. • MoEF issued a notification in January, 1991 to ensure compliance of Environmental Standards in polluting industries. • MoEF formulated 15 point programme for priority action to promote and setup Common Effluent Treatment Plants (CETPs) in clusters of small scale industrial units across the country. • CETP is listed among 54 polluting industries. 2 Problems in SMEs SMEs do not have wastewater treatment facilities due to the following reasons: • Huge capital investment for installation of effluent management systems. • High operation & maintenance expenditure such as skilled manpower, energy, chemicals and laboratory. • Land availability constraint. • Lack of awareness and understanding the seriousness of the environmental issues. 3 Common effluent treatment plant (CETP) • CETP is concept of treating effluents by means of a collective effort mainly for a cluster of SMEs units. • Concept is similar to the Municipal Corporation of cities and towns treating sewage of all the individual houses. Objectives of CETP The major objectives of CETP while protecting the environment include, • Achieving ‘economy of scale’ in waste treatment, thereby reducing cost of pollution abatement for individual industry. • Minimizing problem of lack of technical assistance and trained personnel. • Solving the problem of lack of space in the individual industry as centralized facility can be planned in advance to ensure that adequate space is available. • Homogenization of wastewater for heterogeneous industrial cluster. • Reducing the problems of monitoring by the regulatory bodies. • Organizing the disposal of treated effluent & sludge. • Improving the possibilities of recycle/reuse. • Improving public image & employer morale. 4 STATEWISE OPERATIONAL CETPS IN INDIA* Sr. no. State No. of CETP Flow, MLD 1. Andhra Pradesh 3 12.75 2. Delhi 15 133.2 3. Gujarat 28** 500.35 4. Himachal Pradesh 4 1.1 5. Haryana 1 1.3 6. Karnataka 9@ - 7. Madhya Pradesh 3 0.9 8. Maharashtra 23# 173.35 9. Punjab 4 57.7 10. Rajasthan 2 71.15 11. Tamil Nadu 36 44.4 12 Uttar Pradesh 2 70 130 1066.20 Total Source: *Central Pollution Control Board Report on Performance Status of Common Effluent Treatment Plants in India, October 2005. **Gujarat Pollution Control Board, 2010 . @Karnataka Pollution Control Board, 2012. #Maharashtra Pollution Control Board, 2012. 5 Approach for designing CETP • Quantity of wastewater generated. • Characterization of wastewater. • Inlet feed water quality. • Wastewater treatability and treatment option. • Low foot print. • Mode of disposal of treated effluent. • Disposal of sludge. • Recycle/reuse of treated water. • Modular process, scalable and flexible. 6 What SMEs look for in wastewater management • Maximum reduction in the effluent quantity generation. • Environmental compliance. • Generation of reusable water, if possible revenue generation. • Minimum operating cost. 7 SETTING UP CEPTS WHAT EXPERTS NEED TO LOOK INTO - SELECTION CRITERIA Life cycle cost This includes installation costs and operation costs, which are usually capitalized over the life of the project to provide a common basis for comparing different options. Cost-effectiveness Expressed as a unit cost to provide a basis for comparing different options (Rs./m3). For example, economies of scale often reduce the unit cost of treating wastewater but are not necessarily cost-effective if wastewater flows are not high enough to allow the technology to perform optimally. Reliability Measure of how well a system performs in relation to expectations without breakdowns or failure to treat wastewater to meet water quality objectives. Reliability also is associated with simplicity of operation and ease of maintenance. Reliable systems that require highly skilled operators and careful maintenance would be less appropriate. Simplicity • • Simplicity of operation and ease of maintenance. This is highly desirable for CETPs designed for SMEs. Contd… 8 Performance This is usually measured in terms of percent removal or may be expressed as typical treated effluent concentrations required to meet water quality objectives by a particular treatment option or combination of options. Ability to meet water quality objectives This is a primary screening criterion. Any system that is not able to meet water quality objectives does not need to be considered any further. Adaptability to change in influent quality This is a very important criterion for CETPs designed for SMEs because wastewater quality tends to be more variable than for conventional municipal wastewater treatment. Performance dependent on pretreatment This may or may not be a significant consideration. All other things being equal, however, options that can meet water quality objectives without pretreatment would be favored. Adaptability to varying flow rate. This is an important criterion for CETPs designed for SMEs, if the industries involved have Contd… highly varying flow rates. 9 Adaptability to upgrading This may or may not be a significant consideration for CETPs designed for SMEs, depending on local conditions. Ease and availability of major equipment This is a primary consideration in the design. If the equipment is not available locally or regionally, or is not available at a price that is reasonable due to high transportation costs, the option can be excluded from further consideration. Post installation service/chemical delivery Generally, systems that minimize post installation service for CETPs are desirable. If chemicals are used, it is critical that they be readily available. Personnel skill level Generally, options that require low personnel skill levels are preferred for CETP in SMEs to options that require a high skill level. This generally goes along with simplicity of operation and ease of maintenance. Contd… 10 Energy utilization Generally, options that require no or low energy are preferred for CETPs designed for SMEs to those that are energy intensive. Residue production and cost of disposal This is a major consideration for CETPs in design. Sludges are sufficiently contaminated that they are not suitable for land application. In this situation, options that minimize sludge production are desirable. Potential for effluent use/reuse High potential for effluent use or reuse would be a favorable characteristic for CETPs designed for SMEs. 11 Selection of technology based on influent quality for CETP Wastewater characteristics Wastewater quality Treatment options Low TDS and low BOD Low organic Chemical treatment Low TDS and high BOD Organic effluent Anaerobic + aerobic treatment Low TDS and high COD Highly organic Chemical oxidation by hydrogen peroxide or ozone or sodium hypochlorite Chemical + biological treatment Refractory Chemical oxidation + biological treatment High TDS Inorganic salts Solar evaporation Forced evaporation (after separation of volatile organic matter) Membrane separation High TDS and high COD Highly organic effluent Incineration (based on calorific value) +Secure landfill of incineration ash Waste is not easily biodegradable but toxic Thermal Decomposition Chemical oxidation (hydrogen peroxide, ozone, etc.) Evaporation + Secured landfill Waste is not toxic but mostly inorganic salts Chemical treatment (recovery, precipitation etc.) Evaporation + secured landfill of evaporated residue 12 Sustainability criteria for assessment of treatment technologies Functional Performance Expressed in removal of BOD/COD, heavy metals, organic micro-pollutants, pathogens and nutrients. Adaptability Possibility for implementation on different scales, increasing/decreasing capacity, anticipated changes in legislation, etc. Durability Lifetime of installation. Flexibility Sensitivity of the process in terms of toxic substances, shock loads, seasonal effects, etc. Maintenance required Frequency, costs and time needed for maintenance. Reliability Sensitivity of the process in terms of repairs and maintenance. Economic Affordability Costs in relation to national/regional budget. Foreign exchange required in relation to national/regional foreign exchange requirements. Costs Net present value of the investment costs (specified for land, materials, equipment and labour), maintenance costs. Cost effectiveness Performance relative to costs. Labour Number of employees needed for operation and maintenance. Willingness to pay The amount of money spent by users in relation to their total budget for improvised treatment. Contd… 13 Resource utilization Energy Energy used, produced and ‘lost’ during installation, operation of the wastewater treatment system. Energy ‘lost’ indicates the amount of energy no longer available due to emissions on waste disposal. Eg. sustainable energy sources. Functional Land area The total land area required. The feasibility of integrating the wastewater treatment system (partly) in green areas Nutrients Amount of nutrients suitable for reuse. Organic matter Amount of organic matter recycled through sludge reuse. Amount of organic matter recycled through biogas production. Social Institutional requirements Effort needed to control and enforce existing regulations. Indication of embedding of technology in policymaking. Cultural Acceptance Indication of the cultural changes and impacts: convenience and compatibility with local ethics. Expertise Number of engineers needed for installation and operation. Indication whether a system can be designed and built or can be repaired, replicated and improved locally (in the country) or only by specialized manufacturers. Stimulating sustainable behavior Possibilities for technical stimulation of sustainable behavior and participation by the end user. Contd… 14 Inlet effluent quality and discharge Standards for CETP Parameters pH Inlet effluent quality 5.5 - 9.0 Parameters Discharge Effluent Standards into ISW pH 5.5-9.0 SS 100 TDS 2100 COD 250 BOD (3d, 27°C) 30 Oil & Grease 10 Chlorides 600 Sulphates 1000 Temperature (oC) 45.0 Oil and grease 20.0 Cyanide 2.0 Ammoniacal-N 50.0 Phenolic compounds 5.0 Hexavalent Chromium 2.0 Total chromium 2.0 Phosphates 5 Copper 3.0 Ammoniacal-N 50 Nickel 3.0 Fluoride 2.0 Zinc 15.0 Arsenic 0.2 Lead 1.0 Cyanide 0.2 Arsenic 0.2 Mercury 0.01 Mercury 0.01 Iron 3 Cadmium 1.0 Manganese 2 Selenium 0.05 Chromium 2 Fluoride 15.0 Copper 3 Zinc 5 Boron 2.0 Nickel 3 All values are expressed in mg/l, except pH and temperature. Source: The gazette of India: Extraordinary- Part II- Sec.3 (i) pp10 Dt. 27th Feb 1991 Lead 0.1 Selenium 0.05 All values are expressed in mg/l, except pH ISW-Inland Surface Waters. 15 Performance of CETPs CETP :Tirupur (Textile industry) CETP :GETP, Palsana (Textile industry) Equalized effluent Secondary effluent Discharge Standard into ISW pH 7.1-8.6 8.2-8.6 6.5-9.5 100 SS 120-675 26-62 100 84-100 100 COD 550-950 270-475 250 272-310 26-30 30 BOD 210-342 92-210 30 1632-2036 1604-2036 2100 TDS 6010-6644 6534-6840 2100 Equalized effluent Secondary effluent Discharge Standard into ISW pH 7.8-8 7.9-8.2 6.5-9.5 SS 88-140 12-22 COD 678-832 BOD TDS Parameter Parameter CETP: Punjab (Electroplating industry) CETP:Ankaleshwar (Heterogeneous effluent Dye & dye intermediates, Pharm., textiles Equalized effluent Secondary effluent Discharge Standard into ISW pH 2.1 7.5 6.5-9.5 SS 36-48 26 COD 368-376 BOD TDS Parameter Parameter Equalized effluent Tertiary effluent Discharge Standard into ISW pH 0.38-0.56 7.7-7.88 5.5-9.0 100 SS 1776-1864 100-132 100 224 250 COD 5107-8373 382-395 250 48-52 24 30 BOD 2200-2400 40-50 30 12720-12820 12684 2100 TDS 68200-68830 7532-11836 2100 All values are expressed in mg/l, except pH; ISW-Inland Surface Waters. Contd… 16 CETP:Jeedimetla (Heterogeneous effluent, pharmaceuticals & textiles etc) CETP;Ranipet (Tannery effluent) Equalized effluent Tertiary effluent Discharge Standard into ISW pH 8.8-8.3 7.9-8.0 5.5-9.0 pH SS 752-848 86-96 100 COD 10200-14400 876-960 BOD 4050-5380 TDS 35368-39218 Parameter Tertiary effluent Discharge Standard into ISW 7.7-8.2 6.6-6.7 5.5-9.0 SS 2015-2459 45-50 100 250 COD 7480-9898 122-130 250 68-88 30 BOD 2545-3068 10-12 30 15063-16800 2100 TDS 19856-2115 13209-13245 2100 Parameter Equalized effluent All values are expressed in mg/l, except pH. ISW-Inland Surface Waters. 17 Performance of primary, secondary and tertiary treatment Performance Treatment option High Chemical precipitationbio-oxidationchemical precipitationsand filtration activated carbon adsorption Efficiency (%) BOD : 84-93 COD : 80-90 SS : 77-98 Chemical precipitationbio-oxidationsand filtrationdual media filtration Chemical precipitation (3 stage)media filtrationactivated carbon adsorption Ozonationbio-oxidationsand filtrationactivated carbon adsorption. Moderate Electro-coagulationbio-oxidationchemical precipitationsand filtrationactivated carbon adsorption. Low Bio-oxidationsand filtrationdual media filtrationactivated carbon adsorption Chemical precipitationsand filtrationactivated carbon adsorption Catalytic oxidation BOD : 68-79 COD : 60-73 SS : 64-78 BOD : 56-70 COD : 48-65 SS : 52-74 BOD : 24-25 COD : 21-23 SS : 56-60 18 Stages of reverse osmosis Permeate recovery in 2-4 stage of reverse osmosis system RO IV 85 RO III 84 RO II 40 97 65 50 60 92 80 70 80 90 100 Permeate recovery, % 19 Ranking of technology options Selection of an appropriate treatment option for optimum performance with due consideration to investments requires comparison of different options with respect to certain criteria. Parameter governing selection of wastewater treatment options Capital cost O&M costs Treatment performance Water recovery Treatment time Foot print Sludge production Reject generation. 20 ISSUES & CONSTRAINTS IN CETP OPERATIONS • Consistency in compliance to the prescribed standards by the CETPs. • Existing treatment schemes are unable to handle ever-increasing hydraulic load, new pollutants, stringent regulatory norms. • Improper technological combination for wastewater treatment is discouraging water reuse and recycling. • Poor management of treatment units. • No separate treatment units to deal with hazardous and toxic effluents. • Dismal percentage of water reuse practice in industries. • Lack of access to capital investments and working capitals. 21 AREAS FOR IMPROVEMENT IN CETPS Reduce pollutant loads discharged into the receiving aquatic environment through adoption of recent developments in the areas of effluent management systems. Development programmes for water and chemicals recovery through adoption of advanced oxidation and membrane filtration process. Utilization of sludge/solids as raw material for construction activities after ascertaining its properties. Induction of energy efficient technologies particularly in oxygen transfer in activated sludge process (diffused aeration systems), gas transfer, solids separation and thermal decomposition . Replacement of major energy intensive electrical components with high efficiency motors for aerators, blowers, pumps and centrifuges eg variable-frequency drives. Installation of SCADA (supervisory control and data acquisition) based systems for better operational and management control of the CETPs. Combined heat and power (CHP) or cogeneration as an option to reduce solids and generate energy/power (eg. turbines, micro-turbines, internal combustion/reciprocating engines, steam engines/turbines, and fuel cells). 22 OPPORTUNITIES IN CETPS • Development and optimization of new methods and process configurations for resource effective wastewater treatment. • Development of equipment for wastewater treatment and separation technology . • Development of new methods process configurations for water production from wastewater. • Development of low cost and wastewater specific membranes for water reuse/reclamation. • Improvements in membrane performance including the development of lower pressure membranes (e.g. reduce fouling, increase flux, improve rejection, increase integrity, increased longevity,etc.). • Concentrate/reject treatment and disposal strategies for zero liquid discharge schemes. Contd… 23 • Development of energy efficient advanced oxidation for organic and recalcitrant compounds in wastewater. • Alternative disinfection systems for wastewater including ozone, UV, chlorine dioxide and gaseous/liquid chlorine. • Improvements and cost reductions in thermal processes for chemicals and energy recovery such as evaporation and plasma incineration. • Development of treatment options/packages for country specific wastewaters. • Delineation of treatment option/schemes to reduce energy consumption and hazardous wastes disposal. • Development of instrumentation package for automation of the treatment package and bringing down cost of components. • Strategies to speed up the development and adoption of new technologies. • Develop best management practice for industrial customers. 24 Conclusion • A worldwide trend toward acceptance of the concept of reuse is currently observable, as water shortages have intensified. This should aim at increasing in the use of multiple water reuse practices. • New technologies offering significantly higher removal rates are being designed and implemented. Membrane technologies, which were formerly restricted to water desalination applications, are now being tested for the production of high quality water for indirect potable reuse, and are expected to become the predominant treatment technologies in the near future. • In the field of sludge reclamation and reuse technologies, increased attention is being devoted to the production of sludge that is clean, has less volume and can be safely reused. Developments in this area have been slower than in the field of wastewater treatment, but a number of new technologies have emerged, including high-solids centrifuges, plasma incinerators. Sludge land filling and incineration continue to decrease due to stricter regulations and increased public awareness. The current trend should be in the direction of more reuse opportunities. Volume reduction with a view to decreased disposal requirements is also an ongoing concern. 25