September 30, 2013 Earth System History GEOL 1020 [15] Announcements More about global geochemical cycles About plants and carbon fixation…. THIS DIFFERENCE IN BEHAVIOR OF THE BOND STRENGTHS, CAN BE TRACED USING CARBON ISOTOPES!! The photosynthesis-respiration cycle in plants. KNOW THIS BIOLOGICAL SYSTEMS PREFER THE LIGHT ISOTOPE OF CARBON (12C) OVER THE HEAVY ISOTOPE (13C). The CO2 and O2 system What is the relationship between burial of plant debris and atmospheric chemistry? CO2 DOWN O2 UP CO2 UP O2 DOWN Respiration “BURNS” organic matter back to CO2 And consumes Oxygen in the process… OXIDATION CO2 formation Rapid burial of organic KNOW THIS: matter cuts it off from oxygen, therefore no feedback to CO2!! 13C / 12C ratio in atmosphere 13C / 12C ratio in atmosphere is steady here. is increasing here! Case Study: Increased plant growth and/or increased carbon burial PREFERS CARBON-12 Carbon-12 gets Depleted in atmosphere Oxygen starts to build up. Carbon-12 enriched Organic matter gets Buried. The CO2 and O2 system What is the relationship between burial of plant debris and atmospheric chemistry? CO2 DOWN O2 UP CO2 UP O2 DOWN Amount of CO2 in atmosphere Case Study: Decreased plant growth and/or decreased carbon burial TEMPERATURE?? Time (samples from bottom to top) IS IT GETTING HOTTER OR COLDER WITH TIME? A. COLDER B. HOTTER CO2 in atmosphere Case Study: Decreased plant growth and/or decreased carbon burial TEMPERATURE!! time IS IT GETTING HOTTER OR COLDER OUTSIDE? A. COLDER B. HOTTER BECAUSE CO2 IS A GREENHOUSE GAS, IT TRAPS WARMTH AND WARMS THE AIR Case Study: Decreased plant growth and/or decreased carbon burial A. OXYGEN LEVELS? B. time OXYGEN LEVELS? 13C/12C In atmosphere & sediments C. time OXYGEN LEVELS? Case Study: Decreased plant growth and/or decreased carbon burial time OXYGEN LEVELS? 13C/12C In atmosphere & sediments C. time OXIDATION CO2 formation Returns Carbon-12 to atmosphere Rapid burial of organic KNOW THIS: matter cuts it off from oxygen, therefore no feedback to CO2!! 13C / 12C ratio in atmosphere 13C / 12C ratio in atmosphere is steady here. is increasing here! Mid-Cretaceous RECALL: if CO2 goes down, O2 goes up if O2 goes down, CO2 goes up More organic carbon burial = left-over HEAVY carbon in atmospheric CO2. With increasing burial of organic matter, or increasing FLUX (input) into sedimentary reservoir, CO2 level goes DOWN 13C / 12C ratio in atmosphere is steady. / 12C ratio in atmosphere is increasing! COLD WARM 13C/12C 13C ratio changes over time In the marine system, the same relationship between increased burial of organic matter in INCREASE in the stable carbon isotope ratio (13C/12C) holds!