Introduction to glass products 2008 Technical Advisory Service Glass products Composition and manufacturing Glass properties Glavebel’s organisation Raw products Processed products How to recognize a type of glass Cutting and edge working Glass products - Composition and manufacturing continuous fabrication process ( 12 ans) 500 m long production capacity: 500 to 700 Tons / day 2000 Tons melted glass in the furnace 3 days between in and out Glass products - Composition 73 % Sand SiO2 15 % Soda Na2O 10 % Calcium CaO 2 % Addictives glass melting stabilising agent resistance, color, ... Soda lime silicate glass Glass products – manufacturing: furnace 1600 °C Furnace 1050 °C Glass products – manufacturing: furnace Glass products – manufacturing: furnace 1580°C AIR INLET fume left FUME OUTLET air righ t Glass products – manufacturing: tin bath 1050 °C 600 °C TOP Rollers CVD Lift Out Glass products – manufacturing: tin bath Tin: 7 cm deep (180 T) Length: 70 m Tin density: 6,5 kg/dm³ Glass density: 2,3 kg/dm³ Glass products – manufacturing: cooling zone 600 °C 50 °C Glass products – manufacturing: cutting & stacking Glass products – Some statistics A float line produces more or less 700 tons by day, it means: 70 000 m² of 4 mm float by day 35 full trucks by day 900 m long of 4 mm float by hour 22 km long of 4 mm float by day 2 100 000 m² of 4 mm float by month Glass products Composition and manufacturing Glass properties Glavebel’s organisation Raw products Processed products How to recognize a type of glass Cutting and edge working Glass products – Glas properties Not crystalised solid Perfectly elastic No permanent deformation Fragile break Young’s modulus: 70 000 N/mm² Glass products – Glas properties Volume mass: 2500 kg/m³ 1 m² of 4 mm thickness = 10 kg 5 m² of 10 mm thickness = 125 kg Note: m² of reduce meter (m²rs): 1 mrs is equal to 1 m² in thickness 2 mm (5 kg/m²) Glass products Composition and manufacturing Glass properties AGC Flat Glass Europe’s organisation Raw products Processed products How to recognize a type of glass Cutting and edge working Raw Glass Division Coatings Float Laminated Glass Cast Glass Unprocessed Mirrors Processed Glass Division Architectural Glass Fire Resistant Glass Automotive Mirrors Special Products Appliances Glass products Composition and manufacturing Glass properties AGC’s organisation Raw products Processed products How to recognize a type of glass Cutting and edge working Glass products – Raw products Raw products: - Float - Patterned glass - Wired glass - Profiled glass - Glass blocks Raw glass products - Float Sand (70 %) Melting elements (15 %) Soda Stabilizing elements (15 %) Limestone Dolomite Feldspath Furnace Tinted glass + metal oxydes Raw glass products - Float Characteritics: – – – – – Flat Annealed (so cuttable) Translucent Clear or colored Thicknesses: (extra thin)-3-4-5-6-8-10-1215-19-(22)-(25) mm – Maximum dimensions: 6 m x 3,21 m Raw glass products - Float Clear Extra-clear Green Bronze Grey Pink Blue BU Float - 18 units 2 24 3 2 Glass products – Raw products Raw products: - Float - Patterned glass - Wired glass - Profiled glass - Glass blocks Raw glass products – Patterned glass Raw glass products – Patterned glass BU Cast Glass - 2 units Glass products – Raw products Raw products: - Float - Patterned glass - Wired glass - Profiled glass - Glass blocks Raw glass products – Wired glass Raw glass products – Wired glass Glass products – Raw products Raw products: - Float - Patterned glass - Wired glass - Profiled glass - Glass blocks Raw glass products – Profiled glass Glass products – Raw products Raw products: - Float - Patterned glass - Wired glass - Profiled glass - Glass blocks Raw glass products – Glass bloks => Molted glass Raw glass products – Glass blocks Raw glass products – AGC’s labels Product AGC’s label Float Planibel Patterned glass Imagin / Glamatt Wired glass Imagin Profiled glass - Glass blocks - Glass products Composition and manufacturing Glass properties AGC’s organisation Raw products Processed products How to recognize a type of glass Cutting and edge working Processed products Coated glass Mirrors Glass with treated surfaces Laminated glass Tempered glass (toughened and HS) Chemically toughened glass Curved glass Double glazing Miscellaneous Processed products – Coated glass Processed products – Coated glass Sort of coatings : – pyrolytic: on the manufacturing line (float) (‘‘hard coating’’) – Vaccum coating: in a magnetron (‘‘soft coatings’’) Aims : – – – – Solar control Thermal insulation Reflection limitation ... Processed products – Pyrolitic coated glass 1 From the ‘spray’ process (1) Projection of microdroplets 2 To the Chemical Vapour Deposition (CVD) (2) Improved lateral uniformity Higher reaction yields Less cooling of the glass surface Multilayer coatings Processed products - Magnetron coated glass Buffer Buffer Unload Washer Load Coat zones Inspection ‘‘Off-line’’ production process Vaccum sputtering Processed products - Magnetron coated glass Magnets Cathode (-) + + Gas ions (+) + + + + + Anode Gas Coating Glass BU Magnetron - 4 units Processed products - Coated glass Pyrolytic Magnetron Coating resistence high low Use in SG yes sometimes Use in DG yes yes Treatments possibilities toughening curving laminating In some cases, toughening, curving and laminating Processed products Coated glass Mirrors Glass with treated surfaces Laminated glass Tempered glass (toughened and HS) Chemically toughened glass Curved glass Double glazing Miscellaneous Processed products – Mirrors Silvering Polishing Sensitising & Activation Drying Passivation Washing Drying Paint curing Metallic curing Paint layer Cooling BU Unprocessed Mirrors - 4 units Processed products Coated glass Mirrors Glass with treated surfaces Laminated glass Tempered glass (toughened and HS) Chemically toughened glass Curved glass Double glazing Miscellaneous Processed products – Treated surfaces Painted glass Processed products – Treated surfaces Painted glass Processed products – Treated surfaces Sandblasted glass Processed products – Treated surfaces Matt glass Processed products Coated glass Mirrors Glass with treated surfaces Laminated glass Tempered glass (toughened and HS) Chemically toughened glass Curved glass Double glazing Miscellaneous Processed products – Laminated glass Interlayer Interlayer Interlayer Processed products – Laminated glass Terminology of laminated glass with PVB 4 4 44.2 2 glass of 4 mm 2 PVB films of 0,38 mm Processed products – Laminated glass Sort of interlayers: – Plastic film (PVB, EVA) – Resin – Gel Aims – – – – Safety and burglary Acoustic insulation Resistance to explosions, weapons … Fire resistance, ... Processed products – Laminated glass Fabrication of laminated glass with PVB 1 2 1. 2. 3. 4. 3 4 Automatic glass loader Glass washer PVB application Overlaying with top glass 5 6 5. Calender 6. Loading on racks 7. Autoclave 7 Processed products Coated glass Mirrors Glass with treated surfaces Laminated glass Tempered glass (toughened and HS) Chemically toughened glass Curved glass Double glazing Miscellaneous BU Laminated Glass - 4 units Processed products – Thermally toughened glass Furnace Cutting Grinding Bevelling Shaping 650°C Fast cooling Slow cooling Air cooler 650°C 60°C Toughened Heat strengthened Processed products – Toughened glass + + + + + + + + + + Compression - - - - - - - - - - - - Traction + + + + + + + + + + Compression 45 N/mm² 120 N/mm² Processed products – Toughened glass Char bending resistance Safety coefficient Thermal shock Cutting Fragmentation Isotropy Float Toughened glass 45 N/mm² 120 N/mm² 2,5 2,5 30°C 200°C Yes No Cutting Few cutting yes no Processed products – Toughened glass Float Toughened glass Processed products - Enamelled glass - Screen printed glass Processed products – Screen printed glass Processed products - Heat strenghened glass Processed products - Heat strenghened glass Float Char. bending strength 45 N/mm² Heat strenghened Toughened glass 70 N/mm² 120 N/mm² Thermal shock 30°C 100°C 200°C Fragmentation Cutting Cutting Non cutting Yes No no - No yes Cutting Heat soak Processed products – Toughened glass Risk for the toughened glass of spontaneous breakage due to «nickel sulfide» inclusions Processed products Coated glass Mirrors Glass with treated surfaces Laminated glass Tempered glass (toughened and HS) Chemically toughened glass Curved glass Double glazing Miscellaneous Processed products – Chemically Toughened glass Processed products Coated glass Mirrors Glass with treated surfaces Laminated glass Tempered glass (toughened and HS) Chemically toughened glass Curved glass Double glazing Miscellaneous Processed products – Curved glass Processed products Coated glass Mirrors Glass with treated surfaces Laminated glass Tempered glass (toughened and HS) Chemically toughened glass Curved glass Double glazing Miscellaneous Processed products – Double glazing 4 12 4-12-4 of 4/12/4 4 Air or gas Spacer Opening Butyl Dessicant Sealant Ext 1 2 3 4 Int Processed products – Double glazing 1. 2. 3. 4. 5. 6. washing machine automatic butyl extruder frame mounting station automatic assembly automatic press sealing robot 4 6 5 1 2&3 Processed products – Spandrels BU Architectural Glass Processed products Coated glass Mirrors Glass with treated surfaces Laminated glass Tempered glass (toughened and HS) Chemically toughened glass Curved glass Double glazing Miscellaneous Processed products – Miscellaneous • Glazing with variable properties (liquid cristals) Processed products – AGC’s label Product AGC’s label Pyrolitic coated glass Stopsol / Sunergy / Planibel G Magnetron coated glass Stopray / Top N+ / Top NT / Energy N & NT Mirror Mirox 3G / Mirolam / Sanilam / Duplex Easycut / Mirold / Mirox safe Painted glass Lacobel / Lacobel Safe / Lacomat / Matelac / Matelac Silver Matt glass Matelux / Matobel one side Sandblasted glass Sandblasted glass Processed products – AGC’s label Product AGC’s label Laminated glass: - safety - acoustic - decoration Stratobel / Statobel EVA Stratophone Stratobel Color / Stratobel EVA Creation / Stratobel Impression Fire resistant product Pyrobel - Pyrostar Diffuse glass Diffuglas Processed products – AGC’s label Product AGC’s label Thermally toughened glass Toughened glass Heat strenghened glass Heat strenghened glass Screen painted glass Artlite Enamelled glass Emauver / Colorbel Chemically toughened glass (VHR) Processed products – AGC’s label Product AGC’s label Curved glass Curved glass Double glazing Thermobel Spandrel Colorbel / Blackpearl / Arvahcolor AGC’s products – Information Glass products Composition and manufacturing Glass properties AGC’s organisation Raw products Processed products How to recognize a type of glass Cutting and edge working Glass products – How to recognize a glass How to identify a glass ? – Thickness – Sort of glass (single-double-toughened- laminated) – Presence of a coating Glass products – How to recognize a glass Thickness control Glass products – How to recognize a glass Sort of glass – Single – Double – Toughened – Laminated – Coatings Glass products Composition and manufacturing Glass properties AGC’s organisation Raw products Processed products How to recognize a type of glass Cutting and edge working Glass products – Cutting and edge working Glass products – Cutting and edge working Edge as cut Arrised edge Ground edge Smooth ground edge Bevel Glass products – Cutting and edge working