ATMO 336 Climate, Weather and Society Lecture Atmospheric Composition Temperature, Density, Pressure Vertical Structure Weather vs. Climate Atmospheric Composition Permanent Gases Ahrens, Table 1.1, 3rd Ed. • N2 and O2 are most abundant gases • Percentages hold constant up to 80 km • Ar, Ne, He, and Xe are chemically inert • N2 and O2 are chemically active, removed & returned N2 and O2 N2 Boiling point: 77 K or -196°C or –320 °F O2 Boiling point: 90 K or -183 °C or -297 °F Balance between input (production) and output (destruction): Input: plant/animal decaying Input: plant photosynthesis Sink: soil bacteria; Sink: organic matter decay oceanic plankton-->nutrients chemical combination (oxidation) breathing Atmospheric Composition Important Trace Gases Ahrens, Table 1.1, 3rd ed. Which of these is now wrong even in the 4th edition of Ahrens? Carbon Dioxide CO2 Sources vegetative decay volcanic eruptions animal exhalation combustion of fossil fuels (CH4 + 2 O2 > 2 H2O + CO2) Sinks photosynthesis (oxygen production) dissolves in water phytoplankton absorption (limestone formation) CO2 Trend “Keeling Curve” Some gases vary by season and over many years. The CO2 trend is the cause for concern about global warming. CO2 increases in northern spring, decreases in northern fall http://earthguide.ucsd.edu/globalchange/keeling_curve/01.html H2O Vapor Variability Precipitable Water (mm) Some gases can vary spatially and daily Aerosols 1 cm3 of air can contain as many as 200,000 non-gaseous particles. – – – – – – – dust dirt (soil) salt from ocean spray volcanic ash water pollen pollutants Aerosols - Volcanic Ash Fig. 1-4, p.6 Aerosols - Dust Particles Dust Storm on Interstate 10, between Phoenix and Tucson, AZ. Aerosols • Provide surfaces upon which water vapor can condense. • Provide a surface area or catalyst needed for much atmospheric chemistry. • Aerosols can deplete stratospheric ozone. They can also cool the planet by reflecting sunlight back to space. Scientific Notation How do we write very big or very small number? Scientific Notation is the way that scientists compactly write very large or small numbers It can be thought of as a coefficient times ten raised to an exponent Scientific Notation Speed of light is 300,000 meters per second (m s-1) Scientific Notation for speed of light is 3.0 x 105 m s-1 Wavelength of visible light is close to 0.0000005 meters Scientific Notation for wavelength would be 5.0 x 10-7 m s-1 Scientific Notation Example… Distance between the Earth and the Sun is 150,000,000 kilometers Scientific Notation for distance would be? Scientific Notation Example… Distance between the Earth and the Sun is 150,000,000 kilometers Scientific Notation for distance would be? 1.5 x 108 km Fundamental Concepts Let us introduce three fundamental concepts... Temperature Density Pressure Temperature Scales • Fahrenheit (oF) - relative US public standard • Celsius (oC) - relative Freezing point 0oC Boiling point 100oC o C= 5/9 (oF-32) • Kelvin (K) - absolute K= oC+273 Ahrens p27 What is Temperature? Microscopic View Energy due to random jiggling of molecules Related to average molecular speed (v); 500 m/s for air at room temperature Maxwell Distribution K.E.=(1/2)mv2=(3/2)kT m = mass of one molecule k = Boltzmann constant =1.38065×10−23 joule/K (joule is unit of energy) Impact of Extreme Temperatures on Humans Hypothermia Hyperthermia Condition in which the internal temperature drops below that required for normal metabolism and bodily functions. Condition in which the internal temperature rises above threshold that leads to organ failure. Hypothermia Stages • Stage 1 http://en.wikipedia.org/wiki/Hypothermia – Body temperature drops by 1-2C (Normal body temperature is 37 C) – Mild to strong shivering occurs – Hands become numb, can’t do complex tasks – Blood vessels in outer extremities constrict – Breathing becomes quick and shallow – Goose bumps appear Hypothermia Stages • Stage 2 http://en.wikipedia.org/wiki/Hypothermia – – – – – – – Body temperature drops to 2-4C below normal Shivering becomes more violent Lack of coordination apparent, e.g. stumbling Mild confusion Surface blood vessels contract further Skin pallor becomes pale Lips, ears, fingers and toes can turn blue Hypothermia Stages • Stage 3 http://en.wikipedia.org/wiki/Hypothermia – – – – – Body temp. drops below 32C (90F) Shivering usually stops Difficulty speaking, slow thinking, amnesia Inability to use hands and stumbling Cellular metabolic processes shut down Hypothermia Stages • Stage 3 (cont’d) – – – – – – – Body temp. drops below 30C (86F) Walking nearly impossible Incoherent or irrational behavior, even stupor Pulse and respiration rates slow significantly Heart arrhythmia; tachycardia, atrial fibrillation Major organ failure. Clinical death occurs. Decreased metabolism delays brain death http://www.weather.gov/os/windchill/index.shtml Hypothermia Prevention www.mayoclinic.com COLD - Cover, Overexertion, Layers, Dry • Cover. Wear a hat to prevent body heat from escaping from your head, face and neck. Cover your hands with mittens instead of gloves. • Overexertion. Avoid activities that would cause you to sweat a lot. • Layers. Wear loose-fitting, layered, lightweight clothing. Outer clothing made of tightly woven, water-repellent material is best for wind protection. Wool, silk or polypropylene inner layers hold more body heat than cotton does. • Dry. Stay as dry as possible. Hyperthermia • Stages http://en.wikipedia.org/wiki/Hyperthermia – Temperatures above 40°C (104°F) are lifethreatening – 41°C (106 °F) brain death begins – 45°C (113°F) death is nearly certain – Core temperatures above 50°C (122°F) cause muscle rigidity and certain, immediate death Hyperthermia • Stages http://en.wikipedia.org/wiki/Hyperthermia – In its advanced stage, hyperthermia is called heat stroke or sun stroke – Heat stroke is a medical emergency that requires hospitalization – Heat stroke can come on suddenly, but it usually follows the less-threatening condition of heat exhaustion or heat prostration, which in turn is often follows heat cramps Heat Cramps www.mayoclinic.com/health/first-aid-heat-cramps – Mild form of heat exhaustion – Cramps in the calves, arms, abdomen and back, occurrence is common in athletes – Inadequate intake of fluids or electrolytes is very often a contributing factor – Treatment: rest and cool down; drink clear juice or electrolyte drink; stretch muscle group Heat Exhaustion Symptoms www.mayoclinic.com/health/first-aid-heat-exhaustion Feeling faint or dizzy Nausea Heavy sweating Rapid, weak heartbeat Low blood pressure Cool, moist, pale skin Low-grade fever Heat cramps Headache Fatigue Dark-colored urine Heat Exhaustion Treatment www.mayoclinic.com – Get the person out of the sun and into a shady or air-conditioned location. – Lay the person down, elevate the legs and feet slightly. – Loosen or remove the person's clothing. – Have the person drink cool water. Heat Exhaustion Treatment www.mayoclinic.com – Cool the person by spraying or sponging them with cool water and fanning. – Monitor the person carefully. Heat exhaustion can quickly become heatstroke. – If fever greater than 102 F (38.9 C), fainting, confusion or seizures occur, dial 911 or call for emergency medical assistance. Heat Stroke Symptoms www.mayoclinic.com • High body temperature of 104F (40C) or higher is the main sign of heat stroke. • Cessation of sweating. In heatstroke brought on by hot weather, your skin is hot and dry to the touch. In heatstroke brought on by strenuous exercise, your skin usually feels moist. • Hyperventilation, rapid and shallow breathing. Heat Stroke Symptoms www.mayoclinic.com • Rapid heart rate and pulse (tachycardia). Your blood pressure usually remains normal, but your pulse may increase to around 130 beats a minute, well above the normal level for adults (60 to 100). • Neurological symptoms. You may have seizures, lose consciousness, slip into a coma, hallucinate, or have difficulty speaking or understanding what others are saying. • Muscle cramps or weakness. Your muscles may feel tender or cramped in the early stages of heatstroke, but may later go rigid or limp. Heat Stroke Treatment www.mayoclinic.com MEDICAL EMERGENCY! Doctor/hospital may administer… • • • • Cold water immersion. (Currently out of favor.) Evaporative cooling techniques. Ice packs and cooling blankets. Internal “flushing” techniques. • Medications to stop treatment-caused shivering. Heat Index http://www.weather.gov/os/heat/index.shtml Heat Injury Prevention www.mayoclinic.com • Wear loose-fitting, lightweight clothing. • Seek a cooler environment. A good way to start cooling off is to get to a cooler environment, like an air-conditioned building or a shady spot. • Drink plenty of fluids. Staying hydrated helps your body sweat and maintain a normal body temperature. Avoid diuretics (alcohol, caffeine). • Take extra precautions with certain medications. Apparent Temperature Current U.S. Apparent Temperature Map What is Density? Density (d) = Mass (M) per unit Volume (V) d = M/V Typical Units: kg/m3, gm/cm3 Mass = # molecules molecular weight (gm/mole) Avogadro number (6.023x1023 molecules/mole) Density Change Density (d) changes by altering either a) # molecules in a constant volume b) volume occupied by the same # molecules a b What is Pressure? Pressure (p) = Force (F) per unit Area (A) Typical Units: pounds per square inch (psi), millibars (mb), inches Hg Average pressure at sea-level: 14.7 psi 1013 mb 29.92 in. Hg Pressure Can be thought of as weight of air above you. (Note that pressure acts in all directions!) So as elevation increases, pressure decreases. Top Bottom Higher elevation Less air above Lower pressure Lower elevation More air above Higher pressure Density and Pressure Variation Key Points 1. Both decrease rapidly with height 2. Air is compressible, i.e. its density varies Ahrens, Fig. 1.5 Why rapid change with height? Consider a spring with 10 kg bricks on top of it The spring compresses a little more with each addition of a brick. The spring is compressible. 10 kg 10 kg 10 kg 10 kg 10 kg 10 kg Why rapid change with height? Now consider several 10 kg springs piled on top of each other. Topmost spring compresses the least! Bottom spring compresses the most! The total mass above you decreases rapidly w/height. mass mass mass mass Why rapid change with height? Finally, consider piled-up parcels of air, each with the same # molecules. The bottom parcel is squished the most. Its density is the highest. Density decreases most rapidly at bottom. Why rapid change with height? Each parcel has the same mass (i.e. same number of molecules), so the height of a parcel represents the same change in pressure p. Thus, pressure must decrease most rapidly near the bottom. p p p p Water versus Air Pressure variation in water acts more like bricks, close to incompressible, instead of like springs. Top Bottom Air: Lower density, Gradual drop Higher density Rapid decrease Top Water: Constant drop Constant drop Bottom A Thinning Atmosphere Top Lower density, Gradual drop w/elevation Higher density, Bottom Rapid decrease w/elevation NASA photo gallery Pressure Decreases Exponentially with Height 1 mb 10 mb 48 km 32 km 100 mb 16 km Ahrens, Fig. 1.5 Logarithmic Decrease • For each 16 km increase in altitude, pressure drops by factor of 10. 48 km - 1 mb 32 km - 10 mb 16 km - 100 mb 0 km - 1000 mb Equation for Pressure Variation We can Quantify Pressure Change with Height p (at elevation zin km) pMSL 10 Z /(16 km) where z is elevation in kilometers (km) p is pressure in millibars (mb) at elevation z in meters (km) pMSL is pressure (mb) at mean sea level What is Pressure at 2.8 km? (Summit of Mt. Lemmon) Use Equation for Pressure Change Z /(16 km) p(at elevation Zin km) pMSL 10 set Z = 2.8 km, pMSL 1013 mb p(2.8 km) 1013mb 10 (2.8 km) /(16 km) p(2.8 km) 1013mb 10 0.175 p(2.8 km) 1013mb 0.668 677 mb What is Pressure at Tucson? Use Equation for Pressure Change p(at elevation Zin km) pMSL 10 Z /(16 km) set Z = 800 m, pMSL 1013 mb Let’s get cocky… How about Denver? Z=1,600 m How about Mt. Everest? Z=8,700 m You try these examples at home for practice Impact of Density and Pressure Changes on Humans Altitude sickness or hypoxia. Hypoxia means "deficient in oxygen." Hypoxemia means "deficient oxygen in blood.” Altitude sickness is caused by the decrease of oxygen with increasing elevation. Altitude Sickness Symptoms • Headache is a primary symptom used to diagnose altitude sickness, although headache is also a symptom of dehydration. A headache occurring at an altitude above 2,400 meters (8000 feet = 760 mb), combined with any one or more of the following symptoms, could be an indication of altitude sickness. Altitude Sickness Symptoms en.wikipedia.org/wiki/Altitude_sickness Sign on Mt. Evans CO No appetite, nausea or vomiting Fatigue or weakness Dizziness or light-headedness Insomnia Pins and needles Shortness of breath upon exertion Persistent rapid pulse Drowsiness General malaise Peripheral edema (swelling hands, feet, and face) Life-threatening Conditions en.wikipedia.org/wiki/Altitude_sickness Symptoms of extreme altitude sickness include: • High altitude pulmonary edema (fluid in lungs) – dry cough; may progress to pink, frothy sputum – fever – shortness of breath even when resting • High altitude cerebral edema (swelling of brain) – – – – headache that does not respond to analgesics unsteady walking increasing vomiting gradual loss of consciousness Critical Altitude Conditions en.wikipedia.org/wiki/Altitude_sickness • HAPE occurs in ~2% of those who are adjusting to altitudes of ~3000 m (10,000 feet = 700 mb) or higher. • It can progress rapidly and is often fatal. • Descent to lower altitudes alleviates the symptoms of HAPE. Critical Altitude Conditions en.wikipedia.org/wiki/Altitude_sickness • HACE occurs in 1% of people who are adjusting to altitudes of ~2700 m (9,000 feet = 730 mb) or higher. • It can lead to coma or death. • Descent to lower altitudes may save those afflicted with HACE. Prevention of Altitude Sickness en.wikipedia.org/wiki/Altitude_sickness • Oxygen enrichment or BYOB of O2! • Altitude acclimatization – Gradual adjustment to decreasing oxygen level with increasing altitude, which allows for the production of additional red blood cells – Some drugs can accelerate the adjustment • Humans can adjust to elevations up to 6000 meters (~20,000 feet = 470 mb). Nepal en.wikipedia.org/wiki/Nepal Temperature (T) Profile inversion isothermal 6.5oC/km Ahrens, Fig. 1.7 • More complex than pressure or density • Layers based on the Environmental Lapse Rate (ELR), the rate at which temperature decreases with height. Higher Atmosphere Molecular Composition • Homosphere- gases are well mixed. Below 80 km. Emphasis of Course. • Heterosphere- gases separate by molecular weight, with heaviest near bottom. Lighter gases (H, He) escape. Ahrens, Fig. 1.8 Atmospheric Layers Essentials • Thermosphere-above 85 km Temps warm w/height Gases settle by molecular weight (Heterosphere) • Mesosphere-50 to 85 km Temps cool w/height • Stratosphere-10 to 50 km Temps warm w/height, very dry • Troposphere-0 to 10 km (to the nearest 5 km) Temps cool with height Contains “all” H2O vapor, weather of public interest Take Home Points • Many gases make up air N2 and O2 account for ~99% Trace gases: CO2, H2O, O3, etc. Can be very important…more later • Pressure and Density Profiles Decrease rapidly with height • Temperature Profile Complex vertical structure Climate and Weather “Climate is what you expect. Weather is what you get.” -Robert A. Heinlein Weather Weather – The state of the atmosphere: for a specific place at a particular time Weather Elements 1) Temperature 2) Pressure 3) Humidity 4) Wind 5) Visibility 6) Clouds 7) Significant Weather Surface Station Model Responsible for boxed parameters Ahrens, p 431 Temperatures Plotted F in U.S. Sea Level Pressure Leading 10 or 9 is not plotted Examples: 1013.8 plotted as 138 998.7 plotted as 987 1036.0 plotted as 360 Sky Cover and Weather Symbols Ahrens, p 431 Ahrens, p 431 Wind Barbs Direction Wind is going towards 65 kts from west Westerly from the West Speed (accumulated) Each flag is 50 knots Each full barb is 10 knots Each half barb is 5 knots Ahrens, p 432 SLP pressure temperature dew point Ohio State website cloud cover wind Practice Surface Station 72 58 111 Decimal point What are Temp, Dew Point, SLP, Cloud Cover, Wind Speed and Direction? Ahrens, p 431 Temperate (oF) Pressure (mb) Last Three Digits (tens, ones, tenths) Dew Point (later) Moisture Wind Barb Direction and Speed Cloud Cover Tenths total coverage Practice Surface Station 42 18 998 Decimal point What are Temp, Dew Point, SLP, Cloud Cover, Wind Speed and Direction? Ahrens, p 431 Sea Level Pressure Leading 10 or 9 is not plotted Examples: 1013.8 plotted as 138 998.7 plotted as 987 1036.0 plotted as 360 Surface Map Symbols • Fronts Mark the boundary between different air masses…later Significant weather occurs near fronts Current US Map Ahrens, p 432 Radiosonde Ahrens, Fig. 1 Weather balloons, or radiosondes, sample atmospheric to 10 mb. They measure temperature moisture pressure They are tracked to get winds Radiosonde Distribution Radiosondes released at 0000 and at 1200 GMT for a global network of stations. Large gaps in network over oceans and in less affluent nations. Stations ~400 km apart over North America