PREFACE
In this sixth edition of the Atlas of Zeolite Framework Types, data are presented for each of the 176
unique zeolite Framework Types that had been approved and assigned a 3-letter code by the Structure
Commission of the IZA (IZA-SC) by February 2007.
Six years ago, this number was 133.
The
number of new verified Framework Types reflects the vibrant activity that persists within the zeolite
community. In 1970, the paper that can be considered to be the forerunner of the first edition of the
Atlas was published ~) and it described the 27 zeolite framework structures known at the time. With
each edition of the Atlas, this number has grown and the exponential trend continues. In that initial
paper, the foundation for a systematic description of zeolite framework structures was laid, and we are
still using these basic concepts. It is with pleasure and gratitude for this pioneering work that we
dedicate this edition of the Atlas to Walter M. Meier, co-author of that first Atlas and co-founder of the
Structure Commission of the IZA, on the occasion of his 80th birthday.
Each of the zeolite Framework Types included in this book has been examined by the members of
the IZA-SC to verify that it conforms to the IZA-SC definition of a zeolite, that it is unique, and that
the structure has been satisfactorily proven. The three-letter code that is then assigned is officially
recognized by IUPAC, and is used in the nomenclature recommended by IUPAC for these materials. ~2)
The rules used by the IZA-SC are given in Appendix B.
As a frequently quoted work of reference, the Atlas must be updated on a regular basis to be of full
use. Not only must new Framework Types be added, but corrections and new information on existing
entries must also be disseminated.
To do this, the IZA-SC maintains a freely available searchable
database on the internet at http://www.iza-structure.org/databases/.
Although all the information in
this book (and more) is available at that website, even the most technologically-minded individuals
will admit that it is sometimes easier to access the desired information in a book. This is why we
continue to publish a hard copy of the most used data on a periodic basis.
In this edition we have prepared new stereo drawings of all Framework Types, added over 250
references, and for the first time, included some composite building units that are common to more
than one Framework Type. To make room for the latter, we have removed the loop configurations
(still available on the web), reasoning that the vertex symbols provide very similar information. To
minimize errors, the data sheets have all been generated directly from the zeolite database that is used
for the online version of the Atlas.
We wish to acknowledge the assistance and collaboration of many fellow scientists, who have
provided us with information and suggested improvements. We are particularly indebted to Henk van
Koningsveld, who determined the secondary building units for all the new frameworks, and the
members of the IZA Structure Commission, who provided additional information and proofread
tirelessly.
It does not seem to be possible to assemble such a compilation without mistakes or
oversights, so we will be grateful for any corrections and/or additions that you communicate to us.
February 2007
Christian Baerlocher
Lynne B. McCusker
David H. Olson
Structure Commission of the International Zeolite Association
Christian Baerlocher
Lynne B. McCusker
Allen W. Burton
Walter M. Meier***
Werner H. Baur
Russell E. Morris
Robert W. Broach
Wilfried J. Mortier
Douglas L. Dorset
Michael O'Keeffe
Reinhard X. Fischer
David H. Olson***
Hermann Gies
Michael M.J. Treacy*
Richard M. Kirchner
Henk van Koningsveld**
Raul F. Lobo
Osamu Terasaki
*
Chairperson
** Co-Chairperson
*** Honorary Life Member
Previous IZA Special Publications:
W.M. Meier and D.H. Olson, Atlas of Zeolite Structure Types (1978)
W.M. Meier and D.H. Olson, Atlas of Zeolite Structure Types, 2nd ed. (1987)
W.M. Meier and D.H. Olson, Atlas of Zeolite Structure Types, 3rd ed. (1992)
W.M. Meier, D.H. Olson and Ch. Baerlocher, Atlas of Zeolite Structure Types, 4th ed. (1996)
Ch. Baerlocher, W.M. Meier and D.H. Olson, Atlas of Zeolite Framework Types, 5th ed. (2001)
W.J. Mortier, Compilation of Extra Framework Sites in Zeolites (1982)
R. yon Ballmoos, Collection of Simulated XRD Powder Patterns for Zeolites (1984)
R. yon Ballmoos and J.B. Higgins, Collection of Simulated XRD Powder Patterns for Zeolites,
2nd ed. (1990)
M.M.J. Treacy, J.B. Higgins and R. yon Ballmoos, Collection of Simulated XRD Powder
Patterns for Zeolites, 3rd ed. (1996)
M.M.J. Treacy and J.B. Higgins, Collection of Simulated XRD Powder Patterns for Zeolites, 4th
ed. (2001 )
H. Robson and K.P. Lillerud, Verified Synthesis of Zeolitic Materials (1998)
INTRODUCTION AND EXPLANATORY NOTES
Zeolites and zeolite-like materials do not comprise an easily definable family of crystalline solids.
A simple criterion for distinguishing zeolites and zeolite-like materials from denser tectosilicates is
based on the framework density (FD), the number of tetrahedrally coordinated framework atoms
(T-atoms) per 1000 A3. Figure 1 shows the distribution of these values for porous and dense
frameworks, whose structures are well established (3~. A gap is clearly recognizable between zeolitetype and dense tetrahedral framework structures. The maximum FD for a zeolite ranges from 19 to
over 21 T-atoms per 1000 A3, depending on the type of smallest ring present, whereas the minimum
for denser structures ranges from 20 to 22. Strictly speaking the boundaries defined in Figure 1 for the
framework densities only apply to fully crosslinked frameworks, so interrupted frameworks have not
been included.
For each Framework Type Code (see below), two pages of data are included in this Atlas. The first
page lists the information that characterizes the Framework Type. This includes crystallographic data
(highest possible space group, cell constants of the idealized framework), coordination sequences,
vertex symbols and composite building units. Taken together, the coordination sequences and the
vertex symbols define the Framework Type. On the second page, data for the Type Material (i.e. the
real material on which the idealized Framework Type is based) can be found. Although the channel
dimensionality is a property of the Framework Type, the channel description also includes the
observed ring dimensions, and must therefore refer to the Type Material. For each Framework Type,
a list of isotypic materials with the corresponding references is also given. The different entries in the
data sheets are described in more detail below.
Framework Type Page
Framework Type Code
Following the roles set up by an IUPAC Commission on Zeolite Nomenclature in 1979 ~4),designations
consisting of three capital letters (in boldface type) have been used throughout. The codes are
generally derived from the names of the Type Materials (see Appendix G) and do not include numbers
and characters other than capital Roman letters. The assignment of Framework Type Codes is subject
to review and clearance by the IZA Structure Commission according to a decision of the IZA Council
(taken at the time of the 7th IZC in Tokyo, 1986). Codes are only assigned to established structures
that satisfy the rules of the IZA Structure Commission (see Appendix B for a listing of these rules).
For interrupted frameworks, the 3-letter code is preceded by a hyphen. These mnemonic codes should
not be confused or equated with actual materials. They only describe and define the network of the
corner sharing tetrahedrally coordinated framework atoms. Thus, designations such as NaFAU are
untenable.
However, a material can be described using the IUPAC crystal chemical formula ~2), as
INa~l [A158Si134O384]-FAU or INa-I [A1-Si-O]-FAU. Note that the chemical elements must be enclosed
within the appropriate (boldface) brackets (i.e. I I for guest species and [ ] for the framework host)
FD
quartz
moganite
26-
albite
24-
cristobalite
cordierite
milaritc
tridymite
banalsite
22
-
,
scapolite
i[''''~ ~,~,~ ~,~,~~
parace.lsi~n
iiiliiiiiill~i l ii~i ~ ~i
~il'!i ii!
~qiiiiil
,~
18-
".
|
•
-
g
16-
i
E
1
I
I l ,!iiii~iir
p
O
•
,
......,~i't;TF)
!
n~,
,
~
S
O
"#
|
.~,o
- -~
".4-" .-'"
" 08. ~ -"
0 0 0
0
•
•
.
..-
.."
""
.'"
•
(UTL).O"
-
•
14-
(r~'~., """
I
|
0
•
o
..
p
p
-
•
°
p
12-
.-
P
p
10-
."
d.
p
P
P
"
o
(RWY~o
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p
p
I
3
Fig. l.
'
I
4
'
I
'
I
5
6
Average Size of Smallest Ring
F r a m e w o r k density calculated for the idealized SiO 2 framework vs. average size of the smallest ring in
the structure.
and that the stoichiometry may, but does not have to be specified. Framework Types do not depend on
composition, distribution of the T-atoms (Si, A1, P, Ga, Ge, B, Be, etc.), cell dimensions or symmetry.
The Framework Types have been arranged in alphabetical order according to the Framework Type
Code, because structural criteria alone do not provide an unambiguous classification scheme. This
also facilitates later insertion of new codes and allows simple indexing. The Framework Type Code is
given at the top of each page. On the first page this is supplemented with the maximum space group
symmetry for the framework, and on the second page with the full name of the Type Material. In this
edition, the new designation "e" in space groups with double-glide planes has been used (e.g. Cmma is
now Cmme).
Framework drawing
A stereographic drawing of the framework, generated using the program CrystalMaker (5~ is
presented for each Framework Type. Although the depth fading helps in viewing the drawings, the
use of a stereo viewer is recommended (can be obtained from any electron microscopy supply house).
The coordinates of the idealized, highest symmetry structures have been used for these drawings.
Only the positions of the T-atoms are shown. The T-O-T bridges are represented by straight lines.
This idealization makes it easier to visualize the topology and the basic features of these (often
complex) framework structures. The unit cell is outlined and the orientation of the axes indicated. For
most frameworks, more than a unit cell is shown, but for cases where the figures would have been too
complex, only a part of the unit cell is depicted.
In these cases a projection along a major axis is
shown to help in visualizing the build-up of the complete framework.
Idealized cell parameters
The idealized cell parameters were obtained from a DLS-refinement
using the given (highest
possible) symmetry of the Framework Type. The refinement was carried out assuming a (sometimes
h y p o t h e t i c a l ) SiO 2 composition and with the following prescribed interatomic distances: ds~_o- 1.61A,
do_o - 2.629A and Ds~_s~- 3.07A using the weights of 2.0, 0.61 and 0.23, respectively.
Coordination sequences (CS) and vertex symbols
The concept of coordination sequences was originally introduced by Brunner and L a v e s (7~ and first
applied to zeolite frameworks by Meier and Moeck ~8~. In a typical zeolite framework, each T-atom is
connected to N ~ - 4 neighboring T-atoms through oxygen bridges. These neighboring T-atoms are
then linked in the same manner to N 2 T-atoms in the next shell. The latter are connected to N 3
T-atoms etc. Each T-atom is counted only once. In this way, a coordination sequence can be
determined for each T-atom of the 4-connected net of T-atoms. It follows that
N O- 1
Nj < 4
N 2 _< 12
N 3 _< 36...
N k _< 4 • 3 k-1
CS's are listed from N~ up to N~0 for each topologically distinct T-atom in the framework structure
along with the site multiplicity and the site symmetry (both in parenthesis).
The vertex symbol was first used in connection with zeolite-type networks by M. O' Keefe and S.T.
Hyde (9~. This symbol indicates the size of the smallest ring associated with each of the 6 angles of a
tetrahedron (T-atom). The symbols for opposite pairs of angles are grouped together. For FAU the
vertex symbol reads 4 . 4 . 4 . 6 - 6 . 1 2 , indicating that one pair of opposing angles contains 4-rings, a
second pair a 4-ring and a 6-ring, and the final pair a 6-ring and a 12-ring. It is useful for determining
the smallest rings in a framework. In the case of DOH, for example, the vertex symbols for the four
T-atoms are 5.5.5.5.5.6, 4.5.5-6- 5.6, 5- 5.5.5.5.6 and 5.5.5- 5.5.5, so the smallest rings are 4- and 5-rings,
(4.75 in Figure 1). Sometimes more than one ring of the same size is found for a single angle. This is
indicated with a subscript like 6 2 o r 8 2. An asterisk in the vertex symbol indicates that no ring is
formed for that angle.
The coordination sequence and the vertex symbol together appear to be unique for a particular
framework topology.
That is, they can be used to distinguish different zeolite Framework Types
unambiguously. In this way, isotypic frameworks can be recognized easily.
Secondary building units (SBU's)
Zeolite frameworks can be thought to consist of finite or infinite (i.e. chain- or layer-like)
component units. The finite units which have been found to occur in at least two tetrahedral
frameworks are shown in Appendix C.
T O 4 tetrahedra),
These secondary building units (primary building units are
which contain up to 16 T-atoms, are derived assuming that the entire framework is
made up of one type of SBU only. It should be noted that SBU's are invariably non-chiral (neither
left- nor right-handed) and a unit cell always contains an integral number of them.
As far as
practicable, all possible SBU's have been listed. The number of observed SBU's has increased from
20 in 2001 to 23.
For Framework Types with an SBU that only occurs once or for which
combinations of SBU's are necessary, the reader is referred to the Compendium of Zeolite Framework
Types. Building Schemes and Type Characteristics by H. van Koningsve 1.s(10)
u , where all SBU's are
listed in detail. The symbols given below the drawings in Appendix C are used in the data sheets. If
more than one SBU is possible for a given Framework Type, all are listed. The number given in
parenthesis in Appendix C indicates the frequency of the occurrence of that SBU. The SBU's are only
theoretical topological building units and should not be considered to be or equated with species that
may be in the solution/gel during the crystallization of a zeolitic material.
Framework description
For all 19 Framework Types belonging to the so-called ABC-6-family, the ABC stacking sequence
is given. Some other structural relationships which are thought to be helpful are also listed.
Composite Building Units (CBU's)
Some units (e.g. double 6-ring, cancrinite cage, alpha cavity, double crankshaft chain) appear in
several different framework structures, and can be useful in identifying relationships between
Framework Types. Smith has compiled an exhaustive list of such units, not only for zeolite structures
but also for hypothetical 3-dimensional 4-connected nets (~). In his Compendium(~0), van Koningsveld
has also included an extensive list of them.
Here we have arbitrarily selected just 47 Composite
Building Units and five chains (Appendix D) that are found in at least two different Framework Types.
These are different from secondary building units in that they are not required to be achiral, and cannot
necessarily be used to build the entire framework. To facilitate communication, each unit has been
assigned a lower case italic three-character designation. With the exception of the double 4-, 6- and 8rings (d4r, d6r and d8r, respectively), a code corresponding to one of the Framework Types containing
the CBU has been used for this purpose. A comparison of the notation used by Smith, van
Koningsveld and here is also given in Appendix D.
Materials with this Framework Type
Under this heading, as-synthesized materials that have the same Framework Type but different
chemical composition or have a different laboratory designation are listed.
Materials obtained by
post-synthesis treatment (e.g. ion exchange, dealumination, etc.) are generally not included. The Type
Material (defined on the second page) is given first and marked with an asterisk. These materials are
also listed in the Isotypic Material Index at the end of the book.
References
The list of references cited is far from complete.
As a general rule, references for the Type
Material are to the work that first established the Framework Type and to subsequent work adding
significant information regarding the framework topology.
Thus papers on non-framework species
have not been included. References for other materials with a specific framework type are limited to
work in which sufficient data are provided to establish the framework type.
For most of the codes from ABW to RHO, complete references, cell constant data, space groups,
site symmetries, symmetry relationships, structural diagrams, positional coordinates and chemical
compositions for all crystal structure determinations published up to April 2000 can be found in the
Landolt-B6rnstein Series on Microporous and other framework materials with zeolite-type structures
edited by W.H. Baur and R.X. Fischer ~j2,.
Type Material Page
The Type Material is the species first used to establish the Framework Type. Detailed information
about the material is given on this page.
Crystal chemical data
The chemical composition, expressed in terms of unit cell contents, has been idealized where
necessary for simplicity. The chemical formula is given according to IUPAC recommendations ~2~. For
each Type Material, the space group and cell parameters listed are taken from the reference cited. In
many instances, further refinement of the structure taking into account ordering etc. would yield a
lower symmetry. It should also be noted that the space group and other crystallographic data related to
the Type Material structure do not necessarily apply to isotypes.
In some cases, the space group setting of the Type Material differs from that of the Framework
Type.
In these cases, the relationship between the two unit cells is given.
This relationship is
important when comparing the orientation of the channel direction and the viewing direction of ring
drawings (both are given for the axis orientation of the Type Material) with that of the framework
drawing.
Framework density (FD)
The framework density is defined as the number of T-atoms per 1000 ~3. The number given refers
to the Type Material. For non-zeolitic framework structures, these values tend to be at least 20 to 21
T/1000 /k 3, while for zeolites with fully crosslinked frameworks, the observed values range from
-12.1, for structures with the largest pore volume, to --20.6. To date, FD's of less than 12 have only
been encountered for the interrupted framework cloverite (-CLO) (~3~, for the sulfide UCR-20 (~4~
--
(RWY), and for hypothetical networks
(15)
. The FD is obviously related to the pore volume but does
not reflect the size of the pore openings.
For some of the more flexible zeolite structures, the FD
values can vary appreciably. In these cases (e.g. gismondine) values are given for the Type Material
and for the framework in its most expanded state. The flexibility of a framework structure is, to some
extent, revealed by the possible variation in FD.
FD values may also depend on chemical
composition.
Channels
A shorthand notation has been adopted for the description of the channels in the various
frameworks. Each system of equivalent channels has been characterized by
•
the channel direction (relative to the axes of the Type Material structure),
•
the number of T-atoms (in bold type) forming the rings controlling diffusion through the
channels, and
•
the crystallographic free diameters of the channels in Angstrom units.
The number of asterisks in the notation indicates whether the channel system is one-, two- or threedimensional.
In most cases, the smaller openings simply form windows (rather than channels)
connecting larger cavities. Interconnecting channel systems are separated by a double arrow ( ~ ) . A
vertical bar (I) means that there is no direct access from one channel system to the other. The
examples below have been selected to illustrate the use of this notation.
Cancrinite
Offretite
[001] 12 5.9 x 5.9*
[001] 12 6.7 x 6.8* ~
2_ [001] 8 3.6 x 4.9**
Mordenite
[001] 12 6.5 x 7.0* ~
{ [010] 8 3.4 x 4.8 +-+ [001] 8 2.6 x 5.7 }*
Zeolite Rho
<100> 8 3.6 x 3.6*** I <100> 8 3.6 x 3.6***
Gismondine
{[100] 8 3 . 1 x 4 . 5 ~
[010] 8 2.8x4.8}***
Cancrinite is characterized by a 1-dimensional system of channels parallel to [001] (or c) with circular
12-ring apertures. In offretite, the main channels are similar but they are interconnected at right angles
by a 2-dimensional system of 8-ring channels, and thus form a 3-dimensional channel system. The
channel system in mordenite is essentially 2-dimensional with somewhat elliptical 12-ring apertures.
The 8-ring limiting diffusion in the [001] direction is an example of a highly puckered aperture.
Zeolite rho is an example of a Framework Type containing two non-interconnecting 3-dimensional
channel systems which are displaced with respect to one another (<100> means there are channels
parallel to all crystallographically equivalent axes of the cubic structure, i.e., along [100], [010] and
[001 ]). In gismondine, the channels parallel to [100] together with those parallel to [010] give rise to a
3-dimensional channel system which can be pictured as an array of partially overlapping tubes.
A summary of the channel systems, ordered by decreasing number of T-atoms in the largest ring, is
given in Appendix E. The free diameter values (effective pore width) given in the channel description
and on the ring drawings are based upon the atomic coordinates of the Type Material and an oxygen
radius of 1.35,~. Both minimum and maximum values are given for non-circular apertures. In some
instances, the corresponding interatomic distance vectors are only approximately coplanar, in other
cases the plane of the ring is not normal to the direction of the channel. Close inspection of the
framework and ring drawings should provide qualitative evidence of these factors. Some ring
openings are defined by a very complex arrangement of oxygen atoms, so in these cases other short
interatomic distances that are not listed may also be observed. It should be noted that crystallographic
free diameters may depend upon the hydration state of the zeolite, particularly for the more flexible
frameworks.
It should also be borne in mind that effective free diameters can be affected by non-
framework cations and may also be temperature dependent.
Note that the channel direction is given for the axis orientation of the Type Material. This
orientation may be different from the orientation given in the framework drawing (see the cell
relationship given under "crystal chemical data" for these cases).
Stability
In some cases, the Type Material is not stable to heating and/or removal of the template. This has
been indicated, if the information was available.
Ring drawings
Stereographic drawings of the limiting channel windows are presented for all Framework Types. In
contrast to the framework drawings, all atoms are shown in the ring drawings. Their positions are
based on the crystal structure of the Type Material, and therefore the ring dimensions and the viewing
direction are also those of the Type Material. As explained in the crystal chemical data section, for a
few Type Materials, the orientation of the crystallographic axes is different from that given for the
Framework Type. In these cases, the relationship given in the "crystal chemical data" section must be
applied when comparing the viewing direction of the ring drawings with that of the framework
drawing.
10
Supplementary Information
Topological densities
The coordination sequences (CS) can be used to calculate a topological density (TD). As might be
expected, the CS is a periodic function.
This has been established for all observed framework
topologies by Grosse-Kunstleve, Brunner and Sloane ~6~. They showed that the CS of any T - a t o m can
be described exactly by a set of p quadratic equations
N k - aik2 + bik + C i
for k - i + np,
n - 0,1,2 .... and
i - 1,2,3 .... p
For example, the CS of ABW (NI= 4 N2= 10 N3= 21 N4=36 Ns= 54 N6= 78 NT= 106, etc.) is exactly
described by a set of three quadratic equations (p=3), namely
Nk-
19/9k 2 + 1 / 9 k + 1 6 / 9
for k - l + 3 n ,
n =0,1,2 ....
Nk-
19/9k 2 - 1 / 9 k + 1 6 / 9
for k - 2 + 3 n ,
n = 0,1,2 ....
Nk-
19/9k 2 - 0 k + 2
for k - 3 + 3 n ,
n = 0,1,2 ....
The number of equations p necessary to calculate all members of a particular coordination
sequence varies from p=l for SOD and p=42 for FAU to p=140,900,760 for EUO.
With growing index k (the shell number of the CS), the linear and constant coefficients, bi and ci,
respectively, become less and less important. Therefore we can define the exact topological density
TD as the mean of all ai divided by the dimensionality of the topology (i.e. 3 for zeolites)
1
TD - < ai-------~>= ~
3p i---1
This TD is the same for all T atoms in a given structure. For some frameworks, this calculation can
take quite a long time, so an approximation valid to _+0.001 has been used to calculate the values given
in Appendix F for each of the Framework Types. The value for <ai> has been approximated as the
mean of ai for the last 100 terms of a CS with 1000 terms (TD1000:100), weighted with the
multiplicity of the atom position, and divided by three (dimensionality). The value for TD~0 (sum of
the CS values for N o to N10), which was listed in the first four editions of the Atlas, is also given for
comparison. There is a simple relationship between TD and TD10:TD~0 - TD * 1155. Since TD~0 is an
approximation, i.e. it is 'arbitarily' terminated at N~0, the values obtained by this formula deviate by
11% f o r - C L O and 5% for FAU but the differences are generally below 3%. It seems that for very
open structures, 10 steps are not sufficient for a satifactory convergence. The correlation factor
between the exact topological density TD and the framework density FD is 0.82.
Origin of 3-letter codes and Type Material names
The derivation of the 3-letter codes for the zeolite minerals is fairly obvious, because the code
generally consists of the first 3 letters of the mineral name.
For the synthetic materials this is
sometimes more obscure. One reason for this is that numbers are frequently included to distinguish
different products from a particular lab, and these numbers cannot be transferred directly to the
11
framework code. To help the reader better understand the origin of the codes, a table that includes all
Framework Type codes derived from synthetic Type Materials is given in Appendix G. In this table,
the letters taken for the code are written in bold.
Also, an attempt has been made to decipher the
origin of the mnemonic sometimes used in the designations of these materials.
lsotypic material index
All materials are listed in alphabetical order in this index. To make the index as informative as
possible, all reported materials and designations have been included in this section, provided the
Framework Type assignment appears to be reasonably well established.
Even a number of
occasionally used, but discredited, names of mineral species have been included for the same reason.
A full list of obsolete and discredited zeolite mineral names can be found in a report of the
subcommittee on zeolites of the International Mineralogical Association ~7~. Moreover, the inclusion of
a synthetic material's designation in this index must not be interpreted to mean that the designation has
been formally recognized or generally accepted.
References are to be found on the respective
Framework Type data sheets.
References
(1)
(2)
(3)
(4)
(5)
W.M. Meier and D.H. Olson, Adv. Chem. Ser. 101, 155 (1970)
L.B. McCusker, F. Liebau and G. Engelhardt, Pure Appl. Chem. 73, 381 (2001)
G.O. Brunner and W.M. Meier, Nature 337, 146 (1989)
R.M. Barrer, Pure Appl. Chem. 51, 1091 (1979)
CrystalMaker, a Crystal Structure Program for MacOS Computers. CrystalMaker Software, P.O. Box
183, Bicester, Oxfordshire, OX6 7BS, UK (http://www.crystalmaker.co.uk)
(6) Ch. Baerlocher, A. Hepp. and W.M Meier, "DLS-76, a program for the simulation of crystal structures by
geometric refinement". (1978). Lab. f. Kristallographie, ETH, Zt~rich.
(7) G.O. Brunner and F. Laves, Wiss. Z. Techn. Univers. Dresden 20, 387 (1971) H.2
(8) W.M,. Meier and H.J. Moeck, J. Solid State Chem. 27, 349 (1979)
(9) M. O'Keefe and S.T. Hyde, Zeolites 19, 370 (997)
(10) H. van Koningsveld, Compendium of Zeolite Framework Types. Building Schemes and Type
Characteristics, Elsevier, Amsterdam, 2007
(11) J.V. Smith, Tetrahedral frameworks of zeolites, clathrates and related materials. Subvolume A in
Landolt-B6rnstein, Numerical Data and Functional Relationships in Science and Technology, New Series,
Group IV: Physical Chemistry, Volume 14, Microporous and other Framework Materials with ZeoliteType Structures, eds. W.H. Baur, R.X. Fischer, Springer, Berlin, 2000
(12) W.H. Baur and R.X. Fischer, Zeolite Structure Codes A B W to RHO. Subvolumes B-D in LandoltB6rnstein, Numerical Data and Functional Relationships in Science and Technology, New Series, Group
IV: Physical Chemistry, Volume 14, Microporous and other Framework Materials with Zeolite-Type
Structures, eds. W.H. Baur, R.X. Fischer, Springer, Berlin, 2000
(13) M. Estermann, L.B. McCusker, Ch. Baerlocher, A. Merrouche and H. Kessler, Nature 352, 320 (199!)
(14) N. Zheng, X. Bu, B. Wang and P. Feng, Science 298, 2366 (2002)
(15) W.M. Meier, Proc. 7th IZC Tokyo, Kodansha-Elsevier, 1986, p. 13
(16) R.W. Grosse-Kunstleve, G.O. Brunner and N.J.A. Sloane, Acta Crystallogr. A52, 879 (1996)
(17) D.S. Coombs, A. Alberti, T. Armbruster, G. Artioli, C. Colella, E. Galli, J.D. Grice, F. Liebau,
J.A. Mandarino, H. Minato, E.H. Nickel, E. Passaglia, D.R. Peacor, S. Quartieri, R. Rinaldi, M.
Ross, R.A. Sheppard, E. Tillmanns, G. Vezzalini, Can. Mineral. 35, 1571 (1997) or Mineral.
Mag. 64, 533 (1998) or Eur. J. Mineral. 10, 1037 (1998)
14
ABW
Framework Type Data
Imma
t
/
X
Z
framework viewed along [01 O]
Idealized cell data:
orthorhombic, Imma, a - 9.9/k, b - 5.3A,, c - 8.8A
Coordination sequences and vertex symbols:
T, (8,m)
4
10
Secondary building units:
21
36
54
78
106
136
173
4.6.4.6.6.8~
214
8or4
Composite building units:
dzc
abw
double zigzag
chain
Materials with this framework type"
*Li-A (Barrer and White) ~1-3)
[ B e - A s - O ] - A B W (4'5)
[ B e - P - O ] - A B W (4'6'7)
[ G a - S i - O ] - A B W (8)
[ Z n - A s - O ] - A B W (4'9)
[ Z n - P - O ] - A B W (4)
I(NH4)-I[Co-P-O]-ABW(1°)
[(NH4)-I[Zn-As-O]-ABW (1~)
](NH4)-I[Zn-P-OI-ABW
(12)
ICs-I[Mg-P-OI-ABW(13)
]Cs-][A1-Si-O]-ABW (~4'~5)
ICs-I[A1-Ti-O]-ABW (~6~
[Li-[[Zn-As-O]-ABW (~7~
ILi-I[A1-Si-O]-ABW~8)
ILi-I[Zn-P-O]-ABW(19)
[Li-I[A1-Ge-O]-ABW (2°)
[Na-I[Zn-P-O]-ABW (2~)
INa-I[Co-P-O]-ABW (22~
IRb-I[Cu-P-OI-ABW ~23)
IRb-I[Ni-P-OI-ABW (24)
IRb-I[Co-P-O]-ABW~13)
IRb-I[A1-Si-OI-ABW ~14'15)
ITI-[[A1-Si-O]-ABW~5)
UCSB-3 (26)
15
Li-A (Barrer and White)
Type Material Data
ABW
Crystal chemical data:
ILi4 (H20)41 [A14Si40,6]-ABW
orthorhombic, Pna2~, a - 10.3 l/k, b - 8.18/k, c - 5.00A ~2)
(Relationship to unit cell of Framework Type: a ' = a, b ' = c, c ' = b)
Framework density:
19 T/1000A 3
Channels:
[001] 8 3.4 x 3.8*
8-ring viewed along [001]
References:
(1) Barrer, R.M. and White, E.A.D.J. Chem. Soc., 1267-278 (1951)
(2) Kerr, I.S.Z. Kristallogr., 139, 186-195 (1974)
(3) Krogh Andersen, E. and Ploug-SOrensen, (3. Z. Kristallogr., 176, 67-73 (1986)
(4) Gier, T.E. and Stucky, G.D. Nature, 349, 508-5 l0 (1991)
(5) Harrison, W.T.A., Gier, T.E. and Stucky, G.D. Acta Crystallogr., C51, 181-183 (1995)
(6) Robl, C. and Gobner, V. J. Chem. Soc., Dalton Trans., 1911-1912 (1993)
(7) Zhang, H., Chen, M., Shi, Z., Bu, X., Zhou, Y., Xu, X. and Zhao, D. Chem. Mater., 13, 2042-2048 (2001)
(8) Newsam, J.M.J. Phys. Chem., 92, 445-452 (1988)
(9) Feng, P., Zhang, T. and Bu, X. J. Am. Chem. Soc., 123, 8608-8609 (2001)
(10) Feng, P., Bu, X., Tolbert, S.H. and Stucky, G.D.J. Am. Chem. Soc., 119, 2497-2504 (1997)
(11) Johnson, C.D., Macphee, D.E. and Feldmann, J. lnorg. Chem., 41, 3588-3589 (2002)
(12) Bu, X., Feng, P., Gier, T.E. and Stucky, G.D. Zeolites, 19, 200-208 (1997)
(13) Rakotomahanina Ralaisoa, E.L. Ph.D. Thesis, Univ. Grenoble (1972)
(14) Klaska, R. and Jarchow, O. Naturwiss., 60, 299 (1973)
(15) Klaska, R. and Jarchow, O. Z. Kristallogr., 142, 225-238 (1975)
(16) Gatehouse, B.M. Acta Crystallogr., C45, 1674-1677 (1989)
(17) Jensen, T.R., Norby, P., Christensen, A.N. and Hanson, J.C. Microporous Mesoporous Mat., 26, 77-87
(1998)
(18) Ghobarkar, H. Cryst. Res. Technol., 27, 1071-1075 (1992)
(19) Harrison, W.T.A., Gier, T.E., Nicol, J.M. and Stucky, G.D.J. Solid State Chem., 114, 249-257 (1995)
(20) Tripathi, A., Kim, S.J., Johnson, G.M. and Parise, J.B. Microporous Mesoporous Mat., 34, 273-279 (2000)
(21) Ng, H.Y. and Harrison, W.T.A. Microporous Mesoporous Mat., 23, 197-202 (1998)
(22) Chippindale, A.M., Cowley, A.R., Chen, J.S., Gao, Q. and Xu, R. Acta Crystallogr., C55, 845-847 (1999)
(23) Henry, P.F., Hughes, R.W., Ward, S.C. and Weller, M.T. Chem. Commun., 1959-1960 (2000)
(24) Henry, P.F., Weller, M.T. and Hughes, R.W. Inorg. Chem., 39, 5420-5421 (2000)
(25) Krogh Andersen, I.G., Krogh Andersen, E., Norby, P., Colella, C. and Degennaro, M. Zeolites, 11, 149-154
(1991)
(26) Bu, X., Feng, P., Gier, T.E. and Stucky, G.D.J. Solid State Chem., 136, 210-215 (1998)
16
ACO
m
Framework Type Data
Im3m
1
~
y
X
framework viewed along [001]
m
Idealized cell data:
o
cubic, I m 3 m , a - 9.9A
Coordination sequences and vertex symbols:
T 1(16,3m) 4
9
19
35
52
72
Secondary building units:
8 or 4-4 or 4
Composite building units"
d4r
Materials with this framework type:
• ACP_I ~)
100
131
163
201
4.82-4-8~.4.8 ~
17
ACP-1
ACO
Type Material Data
Crystal chemical data:
I(C2H,oN2)4 (H20)21 [Alo.ssCo7.,2PsO32]-ACO
C2H~oN2 = ethylenediammonium
tetragonal, 1-42m, a - 10.240A, c - 9 . 6 5 2 A ¢l)
F r a m e w o r k density:
15.8 T/1000A 3
Channels
<100> 8 2.8 x 3.5** +--+ [001] 8 3.5 x 3.5*
8-ring viewed along <100>
References(l) Feng, P., Bu, X. and Stucky, G.D. Nature, 388, 735-741 (1997)
8-ring viewed along [001]
18
AEI
Framework Type Data
..................
~ , ~ : ~
Cmcm
.......
Y
L.
framework viewed along [001]
Idealized cell data:
orthorhombic, Cmcm, a - 13.7A,, b - 12.6/~, c -
18.5A,
Coordination sequences and vertex symbols:
T l (16,1)
4
9
17
29
45
64
85
111
143
177
4-4.4.8.6.8
T 2(16,1)
4
9
17
29
45
65
88
113
143
178
4.4-4-8-6.8
T 3(16,1)
4
9
17
29
45
65
87
113
143
176
4.4.4.8.6.8
Secondary building units:
6-6 or 4-2 or 6 or 4
Composite building units:
d6r
Materials with this framework type"
• A1PO_18 <1)
[Co-A1-P-O]-AEI <2)
SAPO- 18 (3)
SIZ_8 (4)
SSZ_39 ~5
19
AIPO-18
AEI
Type Material Data
Crystal chemical data:
[A124P24096]-AEI
monoclinic, C2/c
a - 13.71 1A, b - 12.732A, c - 18.571A, 3 - 9 0.01°~1)
Framework density:
Channels:
14.8 T/1000A 3
{[100183.8x3.8o
[110183.8x3.8o
8-ring viewed along [100]
[001183.8x3.8}***
8-ring viewed along [11 O]
8-ring viewed along [001]
References:
(1) Simmen, A., McCusker, L.B., Baerlocher, Ch. and Meier, W.M. Zeolites, 11,654-661 (1991)
(2) Marchese, L., Chen, J.S., Thomas, J.M., Coluccia, S. and Zecchina, A. J. Phys. Chem., 98, 13350-13356
(1994)
(3) Chen, J.S., Thomas, J.M., Wright, P.A. and Townsend, R.P. Catalysis Letters, 28, 241-248 (1994)
(4) Parnham, E.R. and Morris, R.E.J. Am. Chem. Soc., 128, 2204-2205 (2006)
(5) Wagner, P., Nakagawa, Y., Lee, G.S., Davis, M.E., Elomari, S., Medrud, R.C. and Zones, S.I.J. Am. Chem.
Soc., 122, 263-273 (2000)
20
AEL
Framework Type Data
Imma
z
frameworkviewedalong[100]
I d e a l i z e d cell d a t a :
orthorhombic, Imma,a - 8.3/k, b - 18.7/k, c - 13.4/k
Coordination sequences a n d v e r t e x symbols"
T 1 (16,1)
4
11
21
37
59
85
114
150
189
232
4.62.6.63.62.63
T 2(16,1)
4
11
22
38
58
85
115
148
188
234
4.62.6.63.62.63
T~(8,m)
4
12
24
40
59
84
115
150
186
230
6.62.62.62.62-62
Secondary building units:
Composite building units"
nsc
narSch:Ukite
4-1
afi
t~
bog
~ ~
Materials with this framework type:
*A1PO- 11 ~,2)
G e A P O - 11 ~3)
M n A P O - 11 ~4~
(5 6)
SAPO-11 plus n u m e r o u s compositional variants '
21
AIPO-11
Type Material Data
AEL
Crystal chemical data:
[A12oP2oO80]-AEL
orthorhombic, Ibm2, a - 13.534/~,, b - 18.482/k, c - 8.370A (2)
(Relationship to unit cell of Framework Type: a ' - ¢, b ' - b, c ' - a)
Framework density"
19.1 T/1000A 3
Channels"
[001] 10 4.0 x 6.5*
1O-ring viewed along [001 ]
References:
(1) Bennett, J.M., Richardson Jr., J.W., Pluth, J.J. and Smith, J.V. Zeolites, 7, 160-162 (1987)
(2) Richardson Jr., J.W., Pluth, J.J. and Smith, J.V. Acta Crystallogr., B44, 367-373 (1988)
(3) Meriaudeau, P., Tuan, V.A., Hung, L.N. and Szabo, G. Zeolites, 19, 449-451 (1997)
(4) Pluth, J.J., Smith, J.V. and Richardson Jr., J.W.J. Phys. Chem., 92, 2734-2738 (1988)
(5) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Pure Appl. Chem., 58, 1351-1358 (1986)
(6) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Proc. 7th Int. Zeolite Conf., pp. 103-112 (1986)
22
AEN
Framework Type Data
Cmce
!
t
~
y
framework viewed along [001]
Idealized cell data:
orthorhombic,
Cmce, a - 18.5/k, b - 13.4A, c - 9.6/k
Coordination sequences and vertex symbols:
T 1 (16,1)
4
11
24
41
60
86
123
162
199
248
4"63"62"82"63"8
T 2(16,1)
4
11
22
39
64
90
119
155
201
250
4"6"6"62"62"64
T 3(16,1)
4
11
22
38
63
90
116
155
204
250
4"63"62"63"62"8
Secondary building units:
6or4
Materials with this framework type"
• A1PO_EN3 ~
[ G a - P - O ] - A E N ~2~
A 1 P O - 5 3 ( A ) ~3~
A 1 P O - 5 3 ( B ) ~3~
C o l S T _ 2 ~5~
IST_2 (6~
JDF_2 ~7~
M C S _ I ~8~
C F S A P O _ I A (4~
M n A P O - 14 (9~
Mu_IO °°)
U i 0 _ 1 2 - 5 0 0 ~11~
UiO_12_as ~1~
23
AIPO-EN3
Crystal chemical data:
Type Material Data
AEN
[(C2HsN2)4 (H20),6l [Alz4P24096]-AEN
CzHsN 2 = ethylenediamine
orthorhombic, P2~2~2,, a - 10.292 A,, b - 13.636A,, c - 17.344 A~~1)
(Relationship to unit cell of Framework Type: a ' = c, b'= b, c'= a)
Framework density:
19.7 T/1000A 3
Channels:
[100] 8 3.1 x 4.3* ~ [010] 8 2.7 x 5.0*
4
8-ring viewed along [100]
~,
8-ring viewed along [010]
References:
(1) Parise, J.B. Stud. Surf. Sci. Catal., 24, 271-278 (1985)
(2) Glasser, F.P., Howie, R.A. and Kan, Q.B. Acta Crystallogr., C50, 848-850 (1994)
(3) Kirchner, R.M., Grosse-Kunstleve, R.W., Pluth, J.J., Wilson, S.T., Broach, R.W. and Smith, J.V.
Microporous Mesoporous Mat., 39, 319-332 (2000)
(4) He, H. and Long, Y. J. Incl. Phenom., 5, 591-599 (1987)
(5) Borges, C., Ribeiro, M.F., Henriques, C., Lourenco, J.P., Murphy, D.M., Louati, A. and Gabelica, Z. J.
Phys. Chem. B, 108, 8344-8354 (2004)
(6) Fernandes, A., Ribeiro, M.F., Borges, C., Lourenco, J.P., Rocha, J. and Gabelica, Z. Microporous
Mesoporous Mat., 90, 112-128 (2006)
(7) Chippindale, A.M., Powell, A.V., Jones, R.H., Thomas, J.M., Cheetham, A.K., Huo, Q.S. and Xu, R.R.
Acta Crystallogr., C50, 1537-1540 (1994)
(8) Simmen, A. Ph.D. Thesis, ETH, Ziirich, Switzerland (1992)
(9) Shi, L., Li, J.Y., Yu, J.H., Li, Y., Ding, H. and Xu, R. Inorg. Chem., 43, 2703-2707 (2004)
(10) Soulard, M., Patarin, J. and Marler, B. Solid State Sci., 1, 37-53 (1999)
(11) Kongshaug, K.O., Fjellv~g, H., Klewe, B. and Lillerud, K. P. Microporous Mesoporous Mat., 39, 333-339
(2000)
24
AET
Framework Type Data
Cmcm
Y
framework viewed along [001]
Idealized cell data:
orthorhombic, Cmcm, a - 32.8A, b - 14.4A, c - 8.4/k
Coordination sequences and vertex symbols"
T l (16,1)
4
11
21
35
53
78
108
140
172
208
4-62"6-63.62.63
T 2(16,1)
4
11
21
35
52
74
102
136
172
212
4-62"62"63"62"63
T 3(16,1)
4
11
22
38
55
74
98
132
173
216
4"62-6.63-62.63
T 4(16,1)
4
12
23
36
52
75
103
135
172
215
6"62"62"62"62"62
T 5(8,m)
4
10
18
32
52
76
105
140
171
202
4.63.4.63.6.64
Secondary building units:
Composite building units"
nsc
dnc
narsarsukite
chain
double
narsarsukite
chain
Materials with this framework type:
• A1PO_8 ~1,2)
MCM_37 ~3~
aft
~
bog
25
Type Material Data
AIPO-8
AET
Crystal chemical data:
[A136P360144]-AET
orthorhombic, Cmc2~, a - 33.29A, b - 14.76A, c - 8.257A (~)
Framework density:
17.7 T/1000A 3
Channels:
[001] 14 7.9 x 8.7*
8.7
i
14-ring viewed along [001]
References:
(1) Dessau, R.M., Schlenker, J.L. and Higgins, J.B. Zeolites, 10, 522-524 (1990)
(2) Richardson Jr., J.W. and Vogt, E.T.C. Zeolites, 12, 13-19 (1992)
(3) Chu, C.T.W., Schlenker, J.L., Lutner, J.D. and Chang, C.D.U.S. Patent 5,091,073 (1992)
26
AFG
P6Jmmc
Framework Type Data
z
J.y
f r a m e w o r k viewed normal to [001]
Idealized cell data:
hexagonal, P63/mmc, a - 12.5/k, c - 20.8/k
Coordination sequences and vertex symbols"
T~(24,1)
4
10
20
34
53
76
103
135
170
208
4.6.4.6.6.6
T 2(12,m)
4
10
20
34
54
78
104
134
168
210
4.6.4.6.6.6
T 3(12,2)
4
10
20
34
54
78
104
134
168
210
4.4.6.6.6.6
Secondary building units"
6or4
Framework description:
A B A B A C A C sequence of 6-rings
Composite building unitscar/
lio
J
Materials with this framework type:
*Afghanite ~1"4~
27
Afghanite
Type Material Data
Crystal chemical data:
ICag.sNae: (HeO)4 C1e(SO4)5.3CO~1 [Ale4Sie4096]oA F G
hexagonal, P63mc, a = 12.761A, c = 21.416A (3~
Framework density"
15.9 T/1000A 3
Channels:
apertures formed by 6-rings only
AFG
References:
(1) Bariand, P., Cesbron, F. and Giraud, R. Bull. Soc.fr. Mindral. Cristallogr., 91, 34-42 (1968)
(2) Merlino, S. and Mellini, M. Zeolite 1976, Program and Abstracts, Tucson (1976)
(3) Pobedimskaya, E.A., Rastsvetaeva, R.K., Terent'eva, L.E. and Sapozhnikov, A.N. Dokl. Akad. Nauk SSSR,
320, 882-886 (1991 )
(4) Ballirano, P., Bonaccorsi, E., Maras, A. and Merlino, S., Eur. J. Mineral., 9, 21-30 (1997)
28
AFI
P61mcc
Framework Type Data
?/
~ : ? ~ 2 2 2 2 L ............12221':~./
X
F
y
framework viewed along [001] (upper right: projection down [001 ])
Idealized cell data:
h e x a g o n a l , P6/mcc, a - 13.8,~, c - 8.6/k
Coordination sequences and vertex symbols:
T 1 (24,1)
4
11
21
35
53
77
Secondary building units:
12 or 6 or 4
Composite building units"
nsc
aft
105
137
172
212
4"62"6"63"62"63
bog
narsarsukite
chain
Materials with this framework type:
• A1PO_5 (1~
[ S n - A 1 - P - O ] - A F I (2~
[(Ni(deta)2)-I [ A 1 - P - O - F - ] - A F I ~
I T P A F - I [ A I - P - O ] - A F I (4~
C o A P O _ 5 (5,6~
CrAPO_5 (7~
F A P O _ 5 (8~
M A P O - 5 , M - Cd, Cu, M o , V / M o , Z r (9~
M A P O - 5 , M = M g , M n (~°~
S A P O - 5 and n u m e r o u s c o m p o s i t i o n a l variants (~'12~
SSZ_24 (13~
VAPO_5 (14~
ZnAPO_5 (~5~
29
Type Material Data
AIPO-5
Crystal chemical data:
AFI
I(C,2H2~N)(H20) ~ (OH)I [Al~2P~2O4J-AFI
C~2H28N = tetrapropylammonium
hexagonal, P6cc, a - 13.726/k, c - 8.484/k (~)
Framework density:
17.3 T/1000,~ 3
Channels:
[001 ] 12 7.3 x 7.3"
:7.
7.3
":~
.........................
7.3
.,
7.3
12-ring viewed along [001 ]
References:
(1) Bennett, J.M., Cohen, J.P., Flanigen, E.M., Pluth, J.J. andSmith, J.V. ACSSym. Set.,218, 109-118 (1983)
(2) Flavell, W.R., Nicholson, D.G., Nilsen, M.H. and St~hl, K. J. Mater. Chem., 11,620-627 (2001)
(3) Garcia, R., Shannon, I.J., Slawin, A.M.Z., Zhou, W., Cox, P.A. and Wright, P.A. Microporous Mesoporous
Mat., 58, 91-104 (2003)
(4) Qiu, S., Pang, W., Kessler, H. and Guth, J.L. Zeolites, 9, 440-444 (1989)
(5) Montes, C., Davis, M.E., Murray, B. and Narayana, M. J. Phys. Chem., 94, 6425-6430 (1990)
(6) Chao, K.J., Sheu, S.P. and Sheu, H.S.J. Chem. Soc., Faraday Trans., 88, 2949-2954 (1992)
(7) Radaev, S., Joswig, W. and Baur, W.H.J. Mater. Chem., 6, 1413-1418 (1996)
(8) Zenonos, C., Sankar, G., Cora, F., Lewis, D.W., Pankhurst, Q.A., Catlow, C.R.A. and Thomas, J.M. Phys
Chem Chem Phys, 4, 5421-5429 (2002)
(9) Kornatowski, J., Sychev, M., Finger, G., Baur W.H., Rozwadowski, M. and Zibrowius, B. Proc. PolishGerman Zeolite Colloquium, 20-26 (1992)
(10) Parrillo, D.J., Pereira, C., Kokotailo, G.T. and Gorte, R.J.J. Catal., 138, 377-385 (1992)
(11) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Pure Appl. Chem., 58, 1351-1358 (1986)
(12) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Proc. 7th Int. Zeolite Conf., pp. 103-112 (1986)
(13) Bialek, R., Meier, W.M., Davis, M. and Annen, M.J. Zeolites, 11,438-442 (1991)
(14) Bedioui, F., Briot, E., Devynck, J. and Balkus, K.J. Inorganica Chimica Acta, 254, 151-155 (1997)
(15) Christensen, A.N. and Hazell, R.G. Acta Chemica Scand., 53, 403-409 (1999)
30
AFN
Framework Type Data
C21m
y
framework viewed normal to [010]
Idealized cell data:
monoclinic, C2/m, a - 14A, b - 13.5/k, c - 10.2A, ~ = 107.2 °
Coordination sequences and vertex symbols:
T 1 (8,1)
4
9
19
33
51
76
98
123
162
203
4.4.4.82.6.84
T 2(8,1)
4
9
18
31
49
72
99
130
160
198
4.4-4.82.6-62
T 3(8,1)
4
9
17
30
49
75
102
125
157
202
4.6.4.8.4.87
T 4(8,1)
4
10
21
35
50
71
100
132
164
198
4.4.6.8.8.82
Secondary building units:
8or4
Composite building units"
mei
Materials with this framework type"
*A1PO- 14 ~'2)
I(c~N~H0 I[Mn-A1-P-O]-AFN ~
GaPO_14 ~4~
31
AIPO-14
Type Material Data
Crystal chemical data:
AFN
[A18PsO32]-AFN
triclinic, P]-, a - 9.704A, b -
9.736A, c - 10.202A
oL - 77.81 °, ~3- 77.50 °, ~ - 87.69 ° ~
F r a m e w o r k density:
17.4 T/1000A 3
Channels:
[100] 8 1.9 x 4.6* <-->[010] 8 2.1 x 4.9* <'-> [001] 8 3.3 x 4.0*
8-ring viewed along [100]
8-ring viewed along [010]
8-ring viewed along [001]
References:
(1) Broach, R.W., Wilson, S.T. and Kirchner, R.M. Proc. 12th Int. Zeolite Conf., III, pp. 1715-1722 (1999)
(2) Broach, R.W., Wilson, S.T. and Kirchner, R.M. Microporous Mesoporous Mat., 57, 211-214 (2003)
(3) Shi, L., Li, J., Duan, F., Yu, J., Li, Y. and Xu, R. Microporous Mesoporous Mat., 85, 252-259 (2005)
(4) Parise, J.B. Acta Crystallogr., C42, 670-673 (1986)
32
AFO
Framework Type Data
Cmcm
y
framework viewed along [001]
Idealized cell data:
orthorhombic, Cmcm, a - 9.8A, b - 25.6A, c - 8.3A
Coordination sequences and vertex symbols:
T 1(16,1)
4
11
22
38
58
85
115
149
190
235
4"62"6"63"62"63
T 2(8,m)
4
11
22
41
65
88
111
145
186
231
4"62-6"63-6-63
T 3 (8,m)
4
11
21
36
56
82
115
156
195
231
4"62"62"63"62"63
T 4 (8,m)
4
12
23
37
55
82
118
155
189
232
6.62.62.62.62.62
Secondary building units:
2-6-2 or 4-1
Composite building units:
nsc
aft
bog
narsarsukite
chain
Materials with this framework type:
* A1PO-41 (1)
M n A P S O-41 ~2~
M n A P O - 4 1 <2)
SAPO-41 (2)
33
AIPO-41
Crystal chemical data:
Type Material Data
AFO
[All0P1004o]-AFO
monoclinic, P2 1
a - 9.718A, b - 13.792A, c - 8.359A, 7 - 110.6 °(~
(Relationship to unit cell of Framework Type:
a'= a, b ' - b/(2sinT'), c'= c
or, as vectors, a ' = a, b ' = (b - a)/2, c ' = c)
Framework density"
19.1 T/1000A 3
Channels:
[001] 10 4.3 x 7.0*
lO-ring viewed along [001]
References:
(1) Kirchner, R.M. and Bennett, J.M. Zeolites, 14, 523-528 (1994)
(2) Hartmann, M., Prakash, A.M. and Kevan, L. J. Chem. Soc., Faraday Trans., 94, 723-727 (1998)
34
AFR
Framework Type Data
Pmmn
=
~
-~
y
X
framework viewed along [001]
Idealized cell data:
o r t h o r h o m b i c , Pmmn (origin choice 2), a - 22.3A, b - 13.6/k, c - 7 A
Coordination sequences and vertex symbols"
T 1 (8,1)
4
9
16
27
43
63
88
115
141
171
4-6.4.62.4-8
T 2(8,1)
4
9
18
30
43
64
90
111
140
181
4.4.4.8.63-8
T 3(8,1)
4
9
18
29
42
66
93
112
139
177
4.4.4.12-6-63
T 4(8,1)
4
10
17
28
47
65
86
117
144
169
4"6-4"6"6" 12
Secondary building units:
6-2 or 4-4- or 4
Composite building units:
sti
Materials with this framework type"
• S A P O _ 4 0 ~v3~
A1PO_40 ~4,s)
C o A P S O - 4 0 ~6~
Z n A P O _ 4 0 ~4~
C o A P O _ 4 0 ~4~
Z n A P S O - 4 0 ~6)
35
SAPO-40
Type Material Data
AFR
Crystal chemical data:
I(C,2H28N)4 (OH)4I [SisA12sP28 O,28]-AFR
C~2H28N = tetrapropylammonium
orthorhombic, Pccn, a - 21.944,~, b - 13.691A, c - 14.249A (3~
(Relationship to unit cell of Framework Type: a'= a, b'= b, c'= 2c)
Framework density:
Channels:
15 T/1000A 3
[001] 12 6.7 x 6.9* <-->[010] 8 3.7 x 3.7*
~:.
6.7
i
6.7
..
....
!6.9
12-ring viewed along [001]
8-ring viewed along [01 O]
References:
Estermann, M.A., McCusker, L.B. and Baerlocher, Ch. J. Appl. Crystallogr., 25, 539-543 (1992)
Dumont, N., Gabelica, Z., Derouane, E.G. and McCusker, L.B. Microporous Materials, 1, 149-160 (1993)
McCusker, L.B. and Baerlocher, Ch. Microporous Materials, 6, 51-54 (1996)
Lourenco, J.P., Ribeiro, M.F., Ribeiro, F.R., Rocha, J., Onida, B., Garrone, E. and Gabelica, Z. Zeolites, 18,
398-407 (1997)
(5) Ramaswamy, V., McCusker, L.B. and Baerlocher, Ch. Microporous Mesoporous Mat., 31, 1-8 (1999)
(6) Lourenco, J.P., Ribeiro, M.F., Borges, C., Rocha, J., Onida, B., Garrone, E. and Gabelica, Z. Microporous
Mesoporous Mat., 38, 267-278 (2000)
(1)
(2)
(3)
(4)
36
AFS
P6almcm
Framework Type Data
........:!..........................................ii15
... ::~......
Z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
h e x a g o n a l , P63/mcm, a - 13.1A, c - 25.9/k
Coordination sequences and vertex symbols:
T 1(24,1)
4
9
17
28
42
60
83
111
138
166
4.4-4-82.62.8
T 2(24,1)
4
9
16
25
39
61
86
109
134
163
4.4.4"6- 6" 12
T 3(8,3)
4
9
18
30
43
62
85
105
135
180
4.8-4.8"4"8
Secondary building units:
6"1
Composite building units:
afs
bph
Materials with this framework type"
• M A P S O - 4 6 ~1~
M A P O _ 4 6 ~2~
37
MAPSO-46
Crystal chemical data:
Type Material Data
I(C~H,~N)a(H20),41 [Mg6A122P26Si20~21-AFS
CoH16N : dipropylammonium
trigonal, P 3 c l , a - 13.225A, c - 26.892A (~)
Framework density:
13.7 T/1000.~ 3
Channels:
[001] 12 7.0 x 7.0* <-->l [001] 8 4.0 x 4.0**
...
12-ring viewed along [001 ]
:.::
8-ring viewed normal to [001]
References:
(1) Bennett, J.M. and Marcus, B.K. Stud. Surf Sci. Catal., 37, 269-279 (1988)
(2) Akolekar, D.B. and Kaliaguine, S. J. Chem. Soc., Faraday Trans., 89, 4141-4147 (1993)
AFS
38
AFT
P6almmc
Framework Type Data
z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data"
hexagonal, P63/mmc, a = 13.7A, c - 29.4/k
Coordination sequences and vertex symbols:
T, (24,1)
4
9
17
29
45
64
85
110
140
173
4-4.4-8.6.8
T 2(24,1)
4
9
17
29
45
64
86
113
144
178
4.4-4.8.6-8
T 3 (24,1)
4
9
17
29
45
65
88
113
141
175
4.4.4.8.6-8
Secondary building units:
6-6 or 4-2 or 6 or 4
Framework description:
A A B B C C A A C C B B sequence of 6-rings
Composite building units:
d6r
gme
cha
. . . . . . . . . . . . . . . . ~ ........
Materials w i t h this framework type"
• A1PO_52 <1,2)
aft
.,
39
AIPO-52
Crystal chemical data:
AFT
Type Material Data
[A136P360144]-AFT
trigonal, P-31c, a - 13.715A, c -
Framework density:
14.9 T/1000A 3
Channels:
l [001] 8 3.2 x 3.8***
gme cage 8-ring viewed normal to [001 ]
29.676/k ~2~
cha cage 8-ring viewed normal to [001]
References:
(1) Bennett, J.M., Kirchner, R.M. and Wilson, S.T. Stud. Surf Sci. Catal., 49, 731-739 (1989)
(2) McGuire, N.K., Bateman, C.A., Blackwell, C.S., Wilson, S.T. and Kirchner, R.M. Zeolites, 15, 460-469
(1995)
40
AFX
P6Jmmc
Framework Type Data
7.
framework viewed normal to [001] (upper right: projection down [001 ])
Idealized cell data:
hexagonal, P63/mmc, a - 13.7/k, c - 19.7/k
C o o r d i n a t i o n sequences a n d vertex symbols:
T 1(24,1)
4
9
17
29
45
65
89
116
144
175
4.4-4.8-6-8
T 2(24,1)
4
9
17
29
45
64
85
110
141
178
4-4.4-8.6.8
Secondary building units:
6-6 or 4-2 or 6 or 4
F r a m e w o r k description:
AABBCCBB sequence of 6-rings
C o m p o s i t e building units:
d6r
gme
M a t e r i a l s with this f r a m e w o r k type:
• SAPO_56 (1,2~
MAPSO-56, M=Co, Mn, Zr ~3~
SSZ_16 (4~
aft
41
SAPO-56
Type Material Data
AFX
IH I [SisAlz3P20096]-AFX
Crystal chemical data:
trigonal, P-31c, a - 13.762A, c - 19.949A (2~
Framework density:
14.7 T/1000A. 3
Channels:
2_ [001] 8 3.4 x 3.6***
3.6
•
3.4
....
8-ring viewed normal to [OOl]
References:
(1) McGuire, N.K., Blackwell, C.S., Bateman, C.A., Wilson, S.T. and Kirchner, R.M. private communication
(2) Wilson, S.T., Broach, R.W., Blackwell, C.S., Bateman, C.A., McGuire, N.K. and Kirchner, R.M.
Microporous Mesoporous Mat., 28, 125-137 (1999)
(3) Tian, P., Liu, Z., Xu, L. and Sun, C. Stud. Surf. Sci. Catal., 135, 248 (05-P-18) (2001)
(4) Lobo, R.F., Zones, S.I. and Medrud, R.C. Chem. Mater., 8, 2409-2411 (1996)
42
AFY
Framework Type Data
P31m
F
~:<::S!;;;;;,
...................:>J
........................
y
X
framework viewed along [001] (upper right: projection down [001])
n
Idealized cell data:
trigonal, P31m, a -
12.3/k, c - 8.6/k
Coordination sequences and vertex symbols:
T, (12,1)
4
8
14
25
39
53
71
96
124
152
4.4.4.8.4.12
T 2(4,3)
4
9
16
23
34
57
82
98
115
141
4-8-4.8.4-8
Secondary building units:
4-4 or 4
Composite building units:
d4r
Materials with this framework type:
• CoAPO_50 <~,2~
M g A P O - 5 0 ~3~
M n A P O _ 5 0 <4~
ZnAPO_50 ~5~
43
Type Material Data
CoAPO-50
Crystal chemical data:
I(C6H,6N)3 (H20)71 [Co3A15PaO32]-AFY
C6H16N = dipropylammonium
trigonal, P-3, a - 12.747A, c - 9.015A (2~
Stability"
Unstable to removal of template (~
Framework density:
12.6 T/1000,~ 3
Channels:
[001] 12 6.1 x 6.1" ~ A_ [001] 8 4.0 x 4.3**
":"..
12-ring viewed along [001 ]
AFY
3
8-ring viewed normal to [001]
References:
(1)
(2)
(3)
(4)
(5)
Wilson, S.T. private communication
Bennett, J.M. and Marcus, B.K. Stud. Surf. Sci. Catal., 37, 269-279 (1988)
Akolekar, D.B. Zeolites, 15, 583-590 (1995)
Tusar, N.N., Ristic, A., Meden, A. and Kaucic, V. Microporous Mesoporous Mat., 37, 303-311 (2000)
Arcon, I., Tusar, N.N., Ristic, A., Kaucic, V., Kodre, A. and Helliwell, M. J. Synch. Rad., 8, 590-592
(2001)
44
AHT
Framework Type Data
........................ ~
~
....
Cmcm
¸:,ij!~'~'~'i~'!ii¸i¸ii~
U
Y
x
framework viewed along [001]
Idealized cell data:
orthorhombic, Cmcm, a - 15.8/k, b - 9.2/k, c - 8.6A
Coordination sequences and vertex symbols"
T, (16,1)
4
11
21
36
56
81
109
142
179
221
4.62.6.63-6.63
T 2(8,m)
4
10
18
32
53
78
105
140
179
218
4.63.4.63.6.64
Secondary building units:
4-2 or 6
Composite building units:
dnc
bog
double
narsarsukite
chain
Materials with this framework type:
• A1PO_H2 ~-3~
45
AIPO-H2
Crystal chemical data:
Type Material Data
AHT
I(H:O) I [A16P6Oz4]-AHT
monoclinic, P2~, a - 9.486*, b - 9 . 9 1 4 ' , c - 8 . 1 2 6 ' , ~ - 121.49 °(~)
(Relationship to unit cell of Framework Type:
a ' = a/(2sin~'), b ' = b, c ' = c
or, as vectors, a ' = (a - b)/2, b ' = b, c ' = c)
Stability:
Transforms to A1PO4-tridymite on heating (3)
Framework density:
18.4 T/1000A 3
Channels:
[OO1] 10 3.3 x 6.8*
1O-ring viewed along [001]
References:
(1)
(2)
(3)
Higgins, J.B. private communication
Li, H.X., Davis, M.E., Higgins, J.B. and Dessau, R.M. Chem. Commun., 403-405 (1993)
Kennedy, G.J., Higgins, J.B., Ridenour, C.F., Li, H.X. and Davis, M.E. Solid State Nucl. Mag. Res., 4, 173-178
(~995)
46
!
ANA
Framework Type Data
/a3d
¢
i ii
i
k(~..............................................................~/
x
framework viewed along [001]
Idealized cell data:
cubic, Ia-3d , a - 13.6~,
Coordination sequences and vertex symbols:
T 1(48,2)
4
10
Secondary building units:
22
39
60
87
118
154
196
242
4"4"6"6"84"84
6-2 or 6 or 4-[1,1] or 1-4-1 or 4
Materials with this framework type:
• Analcime (1-3)
ICs_Na_(H20) [[Ga-Si-O]-ANA
- -(~3)
[A1-Co-P-O]-ANA (4)
Ifs 1 6 [ [ C u 8 S i a o O 9 6 ] - A N A
(14)
[A1-Si-P-O]-ANA (5)
IK-I[Be-B-P-O]-ANA (~5~
IK-I[B-Si-O]-ANA
[Ga-Ge-O]-ANA (6)
]Li-l[Li-Zn- Si-O]-ANA
- --(17)
[Zn-As-O]-ANA (7)
]Li-NaI[A1-Si-O]-ANA
(18)
I(NH4)-I[Be-B-P-O]-ANA~8~
INa-I[B
e-B-P-O]-ANA
I(NH4)-I[Zn-Ga-P-O]ANA (9)
A1PO_24 (2°)
A1PO4-pollucite(21)
[Cs-[[A1-Ge-O]-ANA (1°)
1" (22)
[Cs-[[Be-Si-O]-ANA (11)
Ammonioleuc'te
Ca_D (23)
ICs-FeI[Si-O]-ANA (12)
-
-(16)
-
--(19)
Hsianghualite(24)
Leucite (25)
Na_B (26)
Pollucite (27)
Synthetic analcime(28)
Synthetic hsinghualite(29)
(30)
Synthetic wairakite
Wairakite, compositional
variants °~)
References"
(1) Taylor, W.H. Z Kristallogr., 74, 1-19 (1930)
(2) Knowles, C.R., Rinaldi, F.F. and Smith, J.V. Indian Mineral., 6, 127- (1965)
(3) Ferraris, G., Jones, D.W. and Yerkess, J. Z. Kristallogr., 135, 240-252 (1972)
(4) Feng, P., Bu, X. and Stucky, G.D. Nature, 388, 735-741 (1997)
(5) Artioli, G., Pluth, J.J. and Smith, J.V. Acta Crystallogr., C40, 214-217 (1984)
(6) Bu, X., Feng, P., Gier, T.E., Zhao, D. and Stucky, G.D.J. Am. Chem. Soc., 120, 13389-13397 (1998)
(7) Feng, P., Zhang, T. and Bu, X. J. Am. Chem. Soc., 123, 8608-8609 (2001)
(8) Zhang, H.Y., Chen, Z.X., Weng, L.H., Zhou, Y.M. and Zhao, D.Y. Microporous Mesoporous Mat., 57,
309-316 (2003)
47
Analcime
Type Material Data
Crystal chemical data:
[Na,6 (H20),6l [A1,6Si32096]-ANA
cubic, Ia-3d, a - 13.73A ~3)
Framework density:
18.5 T/1000A 3
Channels"
irregular channels formed by highly distorted 8-rings
ANA
distorted 8-ring viewed along [110]
References (cont.):
(9) Logar, N.Z., Mrak, M., Kaucic, V. and Golobic, A. J. Solid State Chem., 156, 480-486 (2001)
(10) Tripathi, A. and Parise, J.B. Microporous Mesoporous Mat., 52, 65-78 (2002)
(11) Torres-Martines, L.M., Gard, J.A., Howie, R.A. and West, A.R.J. Solid State Chem., 51, 100-103 (1984)
(12) Kopp, O.C., Harris, L.A., Clark, G.W. and Yakel, H.L. Am. Mineral., 48, 100-109 (1963)
(13) Yelon, W.B., Xie, D., Newsam, J.M. and Dunn, J. Zeolites, 10, 553-558 (1990)
(14) Heinrich, A.R. and Baerlocher, Ch. Acta Crystallogr., C47, 237-241 (1991)
(15) Zhang, H.Y., Chen, Z.X., Weng, L.H., Zhou, Y.M. and Zhao, D.Y. Microporous Mesoporous Mat., 57,
309-316 (2003)
(16) Millini, R., Montanari, L. and Bellussi, G. Microporous Materials, 1, 9-15 (1993)
(17) Park, S.H., Gies, H., Toby, B.H. and Parise, J.B. Chem. Mater., 14, 3187-3196 (2002)
(18) Seretkin, Y.V., Bakakin, V.V. and Bazhan, I.S.J. Struct. Chem., 46, 659-671 (2005)
(19) Zhang, H.Y., Chen, Z.X., Weng, L.H., Zhou, Y.M. and Zhao, D.Y. Microporous Mesoporous Mat., 57,
309-316 (2003)
(20) Wilson, S.T., Lok, B.M., Messina, C.A., Cannan, T.R. and Flanigen, E.M.J. Am. Chem. Soc., 104, 11461147 (1982)
(21) Keller, E.B. Ph.D. Thesis, ETH, Ziirich, Switzerland (1987)
(22) Hori, H., Nagashima, K., Yamada, M., Miyawaki, R. and Marubashi, T. Am. Mineral., 71, 1022-1027
(1986)
(23) Ames, L.L. and Sand, L.B. Am. Mineral., 43, 476-480 (1958)
(24) Wen-Hui, H., Saho-Hua, T., Kung-Hai, W., Chun-Lin, C. and Cheng Chi, Y. Am. Mineral., 44, 1327-1328
(1959)
(25) Peacor, D.R.Z. Kristallogr., 127, 213-224 (1968)
(26) Barrer, R.M. and White, E.A.D.J. Chem. Soc., 1561-1571 (1952)
(27) Nel, H.J. Am. Mineral., 29, 443-451 (1944)
(28) Ghobarkar, H. and Franke, W. Cryst. Res. Technol., 1071-1075 (1986)
(29) Ghobarkar, H., Schaef, O. and Knauth, Pl Annal. Chimie, Science Mat~riaux, 24, 209-215 (1999)
(30) Ghobarkar, H. Cryst. Res. Technol., K90-92 (1985)
(31) Takeuchi, Y., Mazzi, F., Haga, N. and Galli, E. Am. Mineral., 64, 993-1001 (1979)
48
APC
Framework Type Data
Cmce
":::iiiiii~ii~.
"
i
i
Z
framework viewed along [100]
Idealized cell data:
o r t h o r h o m b i c , Cmce, a - 9.0/k, b - 19.4A, c - 10.4/k
Coordination sequences and vertex symbols:
T 1 (16,1)
4
9
19
35
53
75
102
132
168
208
T 2 (16,1)
4
10
20
35
54
76
104
136
171
211
Secondary building units:
8or4
Composite building units:
dcc
double
crankshaft chain
Materials with this framework type:
• A1PO_C °,2~
A1PO_H3 ~3~
C o A P O _ H 3 ~4~
4.4.4.82-8.82
4.6.4.6.6.82
49
Type Material Data
AIPO-C
APC
Crystal chemical data:
[Alj6PI6064]-APC
orthorhombic, Pbca, a - 19.821A, b - 10.028A, c - 8.936A ~2)
(Relationship to unit cell of Framework Type: a ' = b, b ' = c, c ' = a)
Stability:
Transforms to A1PO-D at ca 250°C (2)
Framework density:
18 T/1000A 3
Channels:
[001] 8 3.4 x 3.7* ~ [100] 8 2.0 x 4.7*
8-ring viewed along [001]
distorted 8-ring viewed along [100]
References:
(1) Bennett, J.M., Dytrych, W.J., Pluth, J.J., Richardson Jr., J.W. and Smith, J.V. Zeolites, 6, 349-359 (1986)
(2) Keller, E.B., Meier, W.M. and Kirchner, R.M. Solid State Ionics, 43, 93-102 (1990)
(3) Pluth, J.J. andSmith, J.V. Acta Crystallogr., C42, 1118-1120(1986)
(4) Canesson, L., Arcon, I., Caldarelli, S. and Tuel, A. Microporous Mesoporous Mat., 26, 117-131 (1998)
50
APD
Framework Type Data
Cmce
)
!
z
framework viewed along [100]
Idealized cell data:
orthorhombic, Cmce, a - 8.7/k, b - 20. l/k, c - 10.2A
Coordination sequences and vertex symbols:
T 1 (16,1)
4
10
21
37
57
82
112
145
184
228
4.4-62.83.63.83
T 2(16,1)
4
11
22
38
59
83
113
147
186
230
4.62.6.62.6-63
Secondary building units:
8 or 6-2 or 4
Composite building units:
RSC
narsarsukite
chain
Materials with this framework type:
• A1PO_D ~
APO_CJ3 ~2~
51
AIPO-D
Crystal chemical data"
Type Material Data
APD
[Al16P16064]-APD
(forms irreversibly from A1PO-C at around 200°C)
orthorhombic, Pca2~, a - 19.187A, b - 8.576A, c - 9.804A ~1~
(Relationship to unit cell of Framework Type: a ' = b, b ' = a, c'= c)
F r a m e w o r k density:
Channels:
19.8 T/1000A 3
[010] 8 2.3 x 6.0* ~ [201] 8 1.3 x 5.8*
distorted 8-ring viewed along [010]
distorted 8-ring along [201]
References:
(1) Keller, E.B., Meier, W.M. and Kirchner, R.M. Solid State Ionics, 43, 93-102 (1990)
(2) Wang, K.X., Yu, J.H., Zhu, G.S., Zou, Y.C. and Xu, R.R. Microporous Mesoporous Mat., 39, 281-289
(2000)
52
AST
m
Framework Type Data
Fm3m
Z
framework viewed along [100]
Idealized cell data:
cubic,
Fm-3m, a - 13.6/k
Coordination sequences and vertex symbols"
4
9
19
34
48
66
96
127
151
183
4.6.4-6.4.6
T 2(8,43m) 4
12
18
28
52
78
88
112
162
204
6.6.6.6.6.6
T l (32,3m)
Secondary building units"
4-1
Composite building units:
d4r
Materials with this framework type:
• A1PO_16 ~
Octadecasil ~2~
[SinGe4o_nO8o]-AST, 0 < n >_ 40 ~3)
53
AIPO-16
Type Material Data
Crystal chemical data:
I(C~H,3N)4 (H20),61 [A12oP2oOj-AST
CTH~3N = quinuclidine
cubic, F23, a - 13.383,,~ i~)
Framework density"
16.7 T/1000A 3
Channels:
apertures formed by 6-rings only
AST
References:
(1) Bennett, J.M. and Kirchner, R.M. Zeolites, 11,502-506 (1991)
(2) Caullet, P., Guth, J.L., Hazm, J., Lamblin, J.M. and Gies, H. Eur. J. Solid State Inorg. Chem., 28, 345-361
(1991)
(3) Wang, Y.X., Song, J.Q. and Gies, H. Solid State Sci., 5, 1421-1433 (2003)
54
ASV
Framework Type Data
•
~,.,~
P41mcc
:..:..:..
PY
x
framework viewed along [001]
Idealized cell data:
tetragonal, P4/mcc, a - 8.7/k, c - 13.9/k
Coordination sequences and vertex symbols:
T 1 (16,1)
4
9
19
35
52
72
100
131
163
201
4.6.4.6.4.6
T 2(4,222)
4
12
18
26
52
84
100
118
162
210
6.6.62.62-128.128
Secondary building units:
4-1
Composite building units:
d4r
lau
Materials with this framework type"
• ASU_7 0)
55
ASU-7
Type Material Data
Crystal chemical data:
I(C2HTN)2 (H20)2[ [Ge2oO4o]-ASV
C2HTN = dimethylamine
tetragonal, P4/mcc, a - 8.780A, c - 14.470A ~)
Framework density:
17.9 T/1000,~ 3
Channels:
[001] 12 4.1x 4.1"
4.1
i
i4.1
12-ring along [001]
References:
(1) Li, H. and Yaghi, O.M.J. Am. Chem. Soc., 120, 10569-10570 (1998)
ASV
56
ATN
Framework Type Data
141mmm
-~Y
x
framework viewed along [001]
Idealized cell data:
tetragonal, I 4 / m m m , a - 13. l f~, c - 5.3/k
Coordination sequences and vertex symbols"
T~ (16,m)
4
10
21
Secondary building units:
36
8or4
Composite building units:
&c
atn
double zigzag
chain
Materials with this framework type"
• MAPO_39 <~,2~
[Mg-Si-A1-P-O]-ATN ~3)
S A P O - 3 9 (4~
ZnAPO_39 (5~
54
78
106
136
173
214
4.6.4.6.6.8
57
MAPO-39
Type Material Data
ATN
IHol [MgoAls_nPsO32]-ATN
Crystal chemical data:
tetragonal, I4/m, a - 13.209,~, c - 5.277,~ (2)
Framework density:
17.4 T/1000.& 3
Channels:
[001] 8 4.0 x 4.0*
> .......
•
.\
4.0
..
,
.........4.0
.... '..
8-ring viewed along [OOl]
References:
(1) McCusker, L.B., Brunner, G.O. and Ojo, A.F. Acta Crystallogr., A46, C59 (1990)
(2) Baur, W.H., Joswig, W., Kassner, D., Bieniok, A., Finger, G. and Kornatowski, J. Z. Kristallogr., 214,
154-159 (1999)
(3) Akporiaye, D.E., Andersen, A., Dahl, I.M., Mostad, H.B. and Wendelbo, R. J. Phys. Chem., 99, 1414214148 (1995)
(4) Sinha, A.K., Hegde, S.G., Jacob, N.E. and Sivasanker, S. Zeolites, 18, 350-355 (1997)
(5) Christensen, A.N., Jensen, T.R., Norby, P. and Hanson, J.C. Chem. Mater., 10, 1688-1693 (1998)
58
ATO
Framework Type Data
..........
R3m
"~"~",..,.....
m
Z
Z
z
:.
X
framework viewed along [001]
Idealized cell data:
trigonal, R-3m, a - 20.9A, c - 5.1/k
Coordination sequences and vertex symbols:
T~ (36,1)
4
11
Secondary building units"
22
37
59
85
114
147
184
230
12 or 6 or 4
Composite building units:
lau
Materials with this framework type:
*A1PO-31 (1,2)
MAPO-31, M - Mn, Ni, Zn ~3)
MAPO-31, M - Zn, Mg, Mn, Co, Cr, Cu, C d (4)
SAPO-31 ¢5-7)
VAPO-31~8)
4-6~.6.6~.6.63
59
AIPO-31
Type Material Data
Crystal chemical data:
[A118PlsOTz]-ATO
trigonal, R3, a - 20.827A, c - 5.003A (~)
Framework density:
19.2 T/1000A 3
Channels:
[001] 12 5.4 x 5.4*
ATO
12-ring viewed along [001 ]
References:
(1) Bennett, J.M. and Kirchner, R.M. Zeolites, 12, 338-342 (1992)
(2) Baur, W.H., Joswig, W., Kassner, D. and Kornatowski, J. Acta Crystallogr., B50, 290-294 (1994)
(3) Umamaheswari, V., Kanna, C., Arabindoo, B., Palanichamy, M. and Murugesan, V. Proc. Indian Acad.
Sci. (Chem. Sci.), 112, 439-448 (2000)
(4) Finger, G., Kornatowski, J., Jancke, K., Matschat, R. and Baur, W.H. Microporous Mesoporous Mat., 33,
127-136 (1999)
(5) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Pure Appl. Chem., 58, 1351-1358 (1986)
(6) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Proc. 7th Int. Zeolite Conf., pp. 103-112 (1986)
(7) Baur, W.H., Joswig, W., Kassner, D. and Kornatowski, J. Acta Crystallogr., B50, 290-294 (1994)
(8) Venkatathri, N., Gegde, S.G. and Sivasanker, S. Chem. Commun., 151-152 (1995)
60
ATS
Framework Type Data
Cmcm
z•Y
x
framework viewed along [001]
Idealized cell data:
orthorhombic, Cmcm, a - 13.2/k, b - 21.6A, c - 5.3A
Coordination sequences and vertex symbols:
T 1 (8,m)
4
10
19
30
46
67
93
124
154
189
4.6.4.6.6.62
T 2(8,m)
4
10
20
32
49
73
97
124
157
193
4.62.4.62.6.122
T 3(8,m)
4
10
19
32
51
72
96
124
155
196
4.62.4.62.6-122
Secondary building units:
12 or 6 or 4
Composite building units"
dzc
ats
double zigzag
chain
Materials with this framework type:
• MAPO_36 ~1~
A1PO_36 ~2)
FAPO_36 ~3~
SSZ_55 ~4~
ZnAPO_36 ~5~
61
MAPO-36
Crystal chemical data:
Type Material Data
ATS
IHI [MgAI,,P,2Oj-ATS
monoclinic, C2/c
a - 13.148A, b - 21.577A, c - 5.164A, ~ - 91.84 °~l~
Framework density:
16.4 T/1000,~ 3
Channels:
[001 ] 12 6.5 x 7.5"
"
7.5j
12-ring viewed along [001]
References:
(1) Smith, J.V., Pluth, J.J. and Andries, K.J. Zeolites, 13, 166-169 (1993)
(2) Zahedi-Niaki, M.H., Xu, G.Y., Meyer, H., Fyfe, C.A. and Kaliaguine, S. Microporous Mesoporous Mat.,
32, 241-250 (1999)
(3) Ristic, A., Tusar, N.N., Arcon, I., Logar, N.Z., Thibault-Starzyk, F., Czyzniewska, J. and Kaucic, V. Chem.
Mater., 15, 3643-3649 (2003)
(4) Wu, M.G., Deem, M.W., Elomari, S.A., Medrud, R.C., Zones, S.I., Maesen, T., Kibby, C., Chen, C.-Y. and
Chen, I.Y.J. Phys. Chem. B, 106, 264-270 (2002)
(5) Christensen, A.N., Norby, P. and Hanson, J.C. Microporous Mesoporous Mat., 20, 349-354 (1998)
62
ATT
Framework Type Data
Pmma
Z
framework viewed along [010]
Idealized cell data:
orthorhombic, Pmma, a - 10.0/k, b - 7.5/k, c - 9.4A
Coordination sequences and vertex symbols:
T 1(8,1)
4
9
18
33
52
73
96
123
158
199
4.4.4.6.8.8
T 2(4,m)
4
10
21
34
48
70
100
130
159
194
4.82.4.82.6.82
Secondary building units:
4-2 or 6
Composite building units:
dcc
dsc
double
crankshaft chain
double sawtooth
chain
Materials with this framework type"
*A1PO- 1 2 - T A M U ~1~
A1PO_33 ~2~
A1PO_33 <3~
RMA_3 <4~
abw
gis
63
ATT
AIPO-12-TAMU
Type Material Data
Crystal chemical data:
I(C4H~2N)4(OH)41[Al12P12048]-ATT
C4H~2N = tetramethylammonium
orthorhombic, P2~2~2, a - 10.332/~,, b - 14.640A,, c - 9.511/~, ~
(Relationship to unit cell of Framework Type: a'= a, b'= 2b, c'= c)
Framework density:
16.7 T/1000A 3
Channels:
[100] 8 4.2 x 4.6* <-->[010] 8 3.8 x 3.8*
.,,.
3.8
8-ring viewed along [100]
-,.
f
~
3.8
j
complex 8-ring viewed along [01 O]
References:
(1) Rudolf, P.R., Saldarriaga-Molina, C. and Clearfield, A. J. Phys. Chem., 90, 6122-6125 (1986)
(2) Smith, J.V., Pluth, J.J. and Bennett, J.M. private communication
(3) Patton, R.L. and Gajek, R.T.U.S. Patent 4,473,663 (1984)
(4) Ikeda, T. and Itabashi, K. Chem. Commun., 2753-2755 (2005)
.....
64
ATV
Framework Type Data
.........
....
Creme
, ..............•
...
~.,,
....
z
frameworkviewedalong[100]
Idealized cell data:
orthorhombic,
Cmme,a - 8.6A, b - 15.3/k, c - 9.7A
Coordination sequences and vertex symbols:
T 1 (16,1)
4
11
22
40
64
92
121
157
200
248
4"62"6"63"62"63
T 2(8,m)
4
12
25
42
61
88
122
160
200
246
6.62-6.62.62"62
Secondary building units:
Composite building units:
6 or 4-[1,1]
nsc
afi
bog
narScahrffkite
l~
~ D
Materials with this framework type:
*A1PO_25 °~
[ G a - P - O ] - A T V a~
65
Type Material Data
AIPO-25
ATV
Crystal chemical data:
[Al12P1204s]-ATV
orthorhombic, Aemm, a - 9.449A, b - 15.203A, c - 8.408A ~
(Relationship to unit cell of Framework Type: a'= c, b'= b, c'= a)
Framework density:
19.9 T/1000A 3
Channels:
[001] 8 3.0 x 4.9*
~-~.............
4.9
~,
..........
8-ring viewed along [001]
References:
(1)
(2)
Richardson Jr., J.W., Smith, J.V. and Pluth, J.J.J. Phys. Chem., 94, 3365-3367 (1990)
Parise, J.B. Chem. Commun., 606-607 (1985)
66
AWO
Framework Type Data
a.
.................~!¢
.... . . . . . . . . . . . . . . . . . . . . . .
•........
.......
.... ~:i: . ..............
~,.-
,,
Cmce
'................. ~, j .................i..~..iaa~.............." ...:.,.""
~'~
.
Z
framework viewed along [100]
Idealized cell data:
o r t h o r h o m b i c , Cmce, a - 9 . 1 A , b - 15.0/k, c - 1 9 . 2 A
Coordination sequences and vertex symbols:
T,(16,1)
4
10
20
35
55
78
103
133
173
217
4.62.4.8~.6.82
T 2(16,1)
4
10
21
'36
53
76
108
142
173
210
4.6.4.82.6.8
Y 3(16,1)
4
9
19
35
54
76
102
134
172
214
4.4.4.6.8.83
Secondary building units:
6 or 4-2 or 4
Composite building units"
dcc
double
crankshaft chain
Materials with this framework type:
* A 1 P O - 21 (1,2)
[Ga-P-O]-AWO
~3~
67
AIPO-21
Crystal chemical data:
Type Material Data
AWO
IH4 (C2H7N),o.66(C3Hs)5.33 (OH)4I [Al,zP,zO48]-AWO
CzHTN = dimethylamine, C3H s = propane
monoclinic, P2~/a
a - 10.330A, b - 17.524A, c - 8.676A, ~ - 123.37 °~'~
(Relationship to unit cell of Framework Type:
a ' = a, b ' = c, c'= b/(2sin~')
or, as vectors, a ' = a, b ' = c, c ' = (b - a)/2 )
Stability:
Transforms to A1PO-25 (ATV) upon calcination (2~
Framework density:
18.3 T/1000A 3
Channels:
[100] 8 2.7 x 5.5*
8-ring viewed along [100]
References:
(1) Bennett, J.M., Cohen, J.M., Artioli, G., Pluth, J.J. and Smith, J.V. Inorg. Chem., 24, 188-193 (1985)
(2) Parise, J.B. and Day, C.S. Acta Crystallogr., C41, 515-520 (1985)
(3) Parise, J.B. Chem. Commun., 606-607 (1985)
68
AWW
Framework Type Data
P41nmm
1
i
Z
~x
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
tetragonal, P4/nmm (origin choice 2), a - 13.6A, c - 7.6A
Coordination sequences and vertex symbols"
T~ (16,1)
4
10
20
33
50
72
98
128
162
200
4.4.6-6.6.8
T 2(8,2)
4
9
17
30
50
74
97
123
158
198
4-4.4.6.6.6
Secondary building units:
6or4
Composite building units:
aww
clo
Materials with this framework type"
*A1PO_22 ~
A1PO-CJB 1 (additional phosphate group prese n t).(2)
69
AIPO-22
Type Material Data
AWW
Crystal chemical data:
I(CTH14N)4 (HPO4)2I [A|z4P24096]-AWW
C7H~4N = quinuclidinium
tetragonal, P4/ncc, a - 13.628A, c - 15.463A (j)
(Relationship to unit cell of Framework Type: a'= a, c'= 2c)
Framework density:
16.7 T/1000A 3
Channels:
[001] 8 3.9 x 3.9*
8-ring viewed along [001]
References:
(1) Richardson Jr., J.W., Pluth, J.J. and Smith, J.V. Naturwiss., 76, 467-469 (1989)
(2) Yah, W.F., Yu, J.H., Xu, R.R., Zhu, G.S, Xiao, F.S., Han, Y., Sugiyama, K. and Terasaki, O. Chem.
Mater., 12, 2517-2519 (2000)
70
BCT
Framework Type Data
141mmm
~
pz~l~ y
X
framework viewed along [001]
Idealized cell data:
tetragonal, I 4 / m m m , a - 9.0A, c - 5.3/k
Coordination sequences and vertex symbols:
Tl(8,m.2m ) 4
11
Secondary building units:
24
41
62
90
122
157
200
247
8or4
Composite building units:
lau
Q
Materials with this framework type:
• M g _ B C T T <1~
ICa-lrAI-Si-O]-BCTa)
F e ( I I I ) - B C T T ~)
Metavariscite(3~
Svyatoslavite(4)
Zn_BCTT (1~
4.6~.6.6.6.6
71
Mg-BCTT
Type Material Data
Crystal chemical data:
IK4.s6l[M g2.28S i5.72016] - B C T
tetragonal, I4mm, a - 8.957A, c - 5.281/k ~)
Framework density:
18.9 T/1000.A 3
Channels:
[001] 8 2.4 x 2.4*
BCT
8-ring viewd along [001]
References:
(1) Dollase, W.A. and Ross, C.R. Am. Mineral., 78, 627-632 (1993)
(2) Takeuchi, Y., Haga, N. and Ito, J. Z. Kristallogr., 137, 380-398 (1973)
(3) Kniep, R. and Mootz, D. Acta Crystallogr., B29, 2292-2294 (1973)
(4) Chesnokov, B.V., Lotova, E.V., Pavlyuchenko, V.S., Usova, L.V., Bushmakin, A.F. and Nishanbayev, T.P.
Zap. Vses. Mineral. Obshch. (Am. Mineral. 76, 299-301 (1991)), 118, 111-114 (1989)
72
*BEA
Framework Type Data
P4122
z
framework viewed along [010]
Idealized cell data:
tetragonal, P4122, a - 12.6/~., c - 26.2A
Coordination sequences and vertex symbols:
T 1 (8,1)
T 2(8,1)
T 3(8,1)
T 4(8,1)
T 5(8,1)
T 6(8,1)
T 7(8,1)
T 8(4,2)
T 9(4,2)
4
4
4
4
4
4
4
4
4
10
10
10
10
11
11
12
12
12
19
19
21
21
18
18
18
19
17
32
32
32
32
29
29
31
32
30
51
51
49
49
48
48
51
48
54
77
75
76
74
80
77
76
75
77
Secondary building units:
see Compendium
Composite building units:
mor
bea
105
102
109
105
107
106
109
112
106
133
133
137
139
133
134
133
134
134
167
170
170
173
160
160
164
164
160
207
208
207
204
203
204
210
206
212
mtw
Materials with this framework type:
, B e t a (1,2~
[ B - S i - O ] - * B E A (3'4~
[ G a - S i - O ] - * B E A (4~
[ T i - S i - O ] - * B E A (5~
Al-rich beta ~6~
CIT_6 ~7~
Tschernichite ~8~
pure silica beta ~9~
4-5-4.123.5.5
4.5.4.126.5.5
4.6.4.123.5.5
4.6.4.126.5.5
4-52.5.5.5.6
4.52.5-5.5.6
5.5.5.6.52"125
5.5.52.127.6"6
5-5.5.5.52.123
73
Beta polymorph A
*BEA
Type Material Data
Crystal chemical data:
INa, I [AlySi57O12s]-*BEA
tetragonal, P4122, a - 12.661A, c - 26.406A ~2)
F r a m e w o r k density:
15.1 T/1000ek 3
Channels:
< 100> 12 6.6 x 6.7** +--+ [001 ] 12 5.6 x 5.6*
7.1 ........i.::~
...:/i..........
.
.
.
5.6
i
... 5.6
.
12-ring viewed along <100>
12-ring viewed along [001 ]
References:
(1) Higgins, J.B., LaPierre, R.B., Schlenker, J.L., Rohrman, A.C., Wood, J.D., Kerr, G.T. and Rohrbaugh, W.J.
Zeolites, 8, 446-452 (1988)
(2) Newsam, J.M., Treacy, M.M.J., Koetsier, W.T. and de Gruyter, C.B. Proc. R. Soc. Lond. A, 420, 375-405
(1988)
(3) Marler, B., B6hme, R. and Gies, H. Proc. 9th Int. Zeolite Conf., pp. 425-432 (1993)
(4) Reddy, K.S.N., Eapen, M.J., Joshi, P.N., Mirajkar, S.P. and Shiralkar, V.P.J. Incl. Phenom. Mol. Recogn.
Chem., 20, 197-210 (1994)
(5) Blasco, T., Camblor, M.A., Corma, A., Esteve, P., Martinez, A., Prieto, C. and Valencia, S. Chem.
Commun., 2367-2368 (1996)
(6) Borade, R.B. and Clearfield, A. Microporous Materials, 5, 289-297 (1996)
(7) Takewaki, T., Beck, L.W. and Davis, M.E. Topics in Catalysis, 9, 35-42 (1999)
(8) Boggs, R.C., Howard, D.G., Smith, J.V. and Klein, G.L. Am. Mineral., 78, 822-826 (1993)
(9) Camblor, M.A., Corma, A. and Valencia, S. Chem. Commun., 2365-2366 (1996)
74
BEC
P4Jmmc
Framework Type Data
if
y
framework viewed along [001]
Idealized cell data:
tetragonal, P42/mmc, a - 1 2 . 8 ' , c - 13.0*
Coordination sequences and vertex symbols:
Tl(16,1 )
4
9
18
32
50
71
96
129
167
199
4.5.4.6.4-126
T2(8,2 )
4
12
17
30
48
71
98
126
156
198
5.5.52-125.6.6
T3(8,m)
4
11
20
28
41
70
103
127
150
188
4.52.5.6-5.6
Secondary building units:
6-2
Composite building units:
d4r
mor
Materials with this framework type:
*FOS-5 (Beta polymorph C) (~)
ITQ- 14 overgrowth a)
ITQ_17 ~3~
mtw
75
(Beta polymorph C)
Type Material Data
BEC
Crystal chemical data:
[(C3HgN)48 (H20)361 [Gez56Os,21-BEC
tetragonal, N / a m & a - 25.990A, c - 27.271A (1~
(Relationship to unit cell of Framework Type: a ' = 2a, c'= 2c)
Framework density:
13.9 T/1000A 3
Channels:
[001] 12 6.3 x 7.5* ~
12-ring viewed along [001]
<100> 12 6.0 x 6.9**
12-ring viewed along [100]
References:
(1) Conradsson, T., Dadachov, M.S. and Zou, X.D. Microporous Mesoporous Mat., 41, 183-191 (2000)
(2) Liu, Z., Ohsuna, T., Terasaki, O., Camblor, M.A., Diaz-Cabafias, M.-J. and Hiraga, K. J. Am. Chem. Soc.,
123, 5370-5371 (2001)
(3) Corma, A., Navarro, M.T., Rey, F., Rius, j. and Valencia, S. Angew. Chem., Int. Ed., 40,2277-2280(2001)
76
BIK
Framework Type Data
Cmcm
x
framework viewed along [001]
Idealized cell data:
orthorhombic, C m c m , a - 7.5/k, b - 16.2/~, c - 5.3,~
Coordination sequences and vertex symbols:
T~(8,m)
4
T 2(4,m2m) 4
12
12
Secondary building units:
23
26
43
42
5-1
Composite building units:
bik
Materials with this framework type:
• Bikitaite ~1,2~
ICs-I[A1-Si-O]-BIK~3~
Triclinic bikitaite ~4~
71
66
97
102
128
140
179
164
226
216
264
288
5.5.5.5.6.82
52.6~.6.6.6.6
77
Bikitaite
Crystal chemical data:
Type Material Data
ILi: (H O) I
[AlzSi40,zl-BIK
triclinic, P1, a - 8.607A, b - 4.954A, c - 7.597A
c~ - 89.90 °, 3 - 114.44 °, ~ - 89.99 ° ~2~
(Relationship to unit cell of F r a m e w o r k Type:
a ' = b/(2sin3'), b ' = c, c ' = a
or, as vectors, a ' = (b - a)/2, b ' = c, c ' = a)
Framework density"
20.3 T/1000A 3
Channels:
[010] 8 2.8 x 3.7*
8-ring viewed along [010]
References:
(1)
(2)
(3)
(4)
Kocman, V., Gait, R.I. and Rucklidge, J. Am. Mineral., 59, 71-78 (1974)
Stfihl, K., Kvick, A. and Ghose, S. Zeolites, 9, 303-311 (1989)
Annehed, H. and F~ilth, L. Z. Kristallogr., 166, 301-306 (1984)
Bissert, G. and Liebau, L. N. Jb. Miner. Mh., 241-252 (1986)
BIK
78
BOG
Framework Type Data
/mma
y
U z
ii:!' ...................................i~
.....
:~i
y
framework viewed along [100] (upper right: projection down [100])
Idealized cell data:
orthorhombic, Imma, a - 20.O/k, b = 2 3 . 6 ' , c - 1 2 . 7 '
Coordination sequences and vertex symbols:
T 1 (16,1)
T 2(16,1)
T 3(16,1)
T 4(16,1)
T 5(16,1)
T 6(16,1)
4
4
4
4
4
4
10
10
11
11
11
11
Secondary building units:
19
20
19
21
20
18
32
32
34
32
31
31
51
48
50
49
53
52
74
74
71
74
76
75
101
104
98
101
97
100
6 or 5-1 or 4
Composite building units"
bre
bog
Materials with this framework type:
*Boggsite ~)
Dehyd. boggsite <2~
cas
129
131
133
128
126
126
158
159
162
162
168
158
199
195
195
200
199
206
4-5.4-6.5.122
4-5.4.62.10-12
4.52-5.6.5-103
4-105.5-63.5"63
4-5"5"6~'5" 10
4.5.5.6-5.62
79
Type Material Data
Boggsite
BOG
Crystal chemical data:
ICa7Na4 (H20)741 [A1,8Si780,92]-BOG
orthorhombic, Imma, a - 20.236,~, b - 23.798,~, c - 12.798A ~)
F r a m e w o r k density:
15.6 T/1000/~ 3
Channels:
[100] 12 7.0 x 7.0* ~ [010] 10 5.5 x 5.8*
12-ring viewed along [100]
1O-ring viewed along [01 O]
References:
(1) Pluth, J.J. and Smith, J.V. Am. Mineral., 75, 501-507 (1990)
(2) Zanardi, S., Cruciani, (3., Alberti, A. and Galli, E. Am. Mineral., 89, 1033-1042 (2004)
80
B PH
P62m
Framework Type Data
"" i ~
~
" ~i+"....~,..i.i.~.~...
'"
..
//i
i!:
........
/
................-y
framework viewed normal to [001] (upper right: projection down [001])
m
Idealized cell data:
hexagonal, P 6 2 m , a -
13.l/k, c - 13.0A
Coordination sequences and vertex symbols:
T, (12,1)
T 2(12,1)
T 3 (4,3)
4
4
4
9
9
9
17
16
18
Secondary building units:
28
25
30
6* 1
Composite building units:
@h
afs
Materials with this f r a m e w o r k type"
(12)
*Beryllophosphate-H '
Linde Q(3)
STA_5 ~4~
UZM_4 ~5~
42
39
43
60
61
62
84
86
85
113
111
105
140
141
135
169
173
180
4-4.4.82.62.8
4"4-4"6"6.12
4"8"4"8"4"8
81
Beryl Iophosphate-H
Crystal chemical data:
Type Material Data
BPH
IK~Na~(H20)201 [Be,4P,4056]oBPH
trigonal, P321, a - 12.582A, c - 12.451A (2~
Framework density:
16.4 T/1000A 3
Channels:
[001] 12 6.3 x 6.3* +-+ I [001] 8 2.7 x 3.5**
12-ring viewed along [OO1]
8-ring viewed normal to [001]
References:
(1) Harvey, G. Z. Kristallogr., 182, 123-124 (1988)
(2) Harvey, G., Baerlocher, Ch. and Wroblewski, T. Z. Kristallogr., 201, 113-123 (1992)
(3) Andries, K.J., Bosmans, H.J. and Grobet, P.J. Zeolites, 11, 124-131 (1991)
(4) Patinec, V., Wright, P.A., Aitken, R.A., Lightfoot, P., Purdie, S.D.J., Cox, P.A., Kvick, A. and Vaughan, G.
Chem. Mater., 11, 2456-2462 (1999)
(5) Blackwell, C.S., Broach, R.W., Gatter, M.G., Holmgren, J.S., Jan, D.-Y., Lewis, G.J., Mezza, B.J., Mezza,
T.M., Miller, M.A., Moscoso, J.G., Patton, R.L., Rohde, L.M., Schoonover, M.W., Sinkler, W., Wilson,
B.A. and Wilson, S.T. Angew. Chem., Int. Ed., 42, 1737-1740 (2003)
82
BRE
P2 lm
Framework Type Data
i]i
.....
.......i
~
-.t~ L Z
y
.............•"
framework viewed along [100]
Idealized cell data:
monoclinic, P211m, a - 6.8/k, b - 17.1,a,, c - 7.6A, fi - 95.8 °~2)
Coordination sequences and vertex symbols:
T 1(4,1)
T 2(4,1)
T 3(4,1)
4
4
4
4
T 4 (4,1)
10
10
11
11
20
20
23
18
Secondary building units"
37
36
37
37
61
61
54
62
83
85
82
85
110
107
119
110
144
147
152
147
192
191
184
195
238
234
233
236
4
Composite building units:
bre
Materials with this framework type:
•
(12)
*Brewsterite '
B a - d o m i n a n t brewsterite¢3)
CIT_4 ¢4)
Dehyd. brewsterite ~5~
Synthetic brewsterite ~6~
4.5-4.6.5.8
4.5-4.8.5-6
4.8.5.8.5.82
4.52.5.6.5.8
83
Type Material Data
Brewsterite
Crystal chemical data:
BRE
I(Ba,Sr)2 (n20)~ol [A14Si~2032]-BRE
monoclinic, P21/m
a - 6.793A, b - 17.573A,, c - 7.759A,, [3 - 94.54 °~2~
Framework density:
17.3 T/1000A 3
Channels:
[100] 8 2.3 x 5.0* +-+ [001] 8 2.8 x 4.1"
8-ring viewed along [100]
8-ring viewed along [001]
References:
(1) Perrotta, A.J. and Smith, J.V. Acta Crystallogr., 17, 857-862 (1964)
(2) Schlenker, J.L., Pluth, J.J. and Smith, J.V. Acta Crystallogr., B33, 2907-2910 (1977)
(3) Cabella, R., Lucchetti, G., Palenzona, A., Quartieri, S. and Vezzalini, G. Eur. J. Mineral., 5, 353-360
(1993)
(4) Khodabandeh, S., Lee, G. and Davis, M.E. Microporous Mesoporous Mat., 11, 87-95 (1997)
(5) St~hl, K. and Hanson, J.C. Microporous Mesoporous Mat., 32, 147-158 (1999)
(6) Ghobarkar, H. and Schaef, O. German Patent AZ 198 24 184.4-41 (1999)
84
CAN
P6Jmmc
Framework Type Data
)
" "!
X
framework viewed along [001] (upper right: projection down [001])
Idealized cell data:
hexagonal, P63/mmc, a - 12.5/k, c - 5.3A
Coordination sequences and vertex symbols:
T 1 (12,m)
4
10
20
34
54
78
104
Secondary building units"
12 or 6 or 4
Framework description:
AB sequence of 6-rings
134
168
210
4.6.4.6.6.6
Composite building units:
dzc
can
double zigzag
chain
Materials with this framework type:
*Cancrinite (~'2)
[A1-Ge-O]-CAN (3)
[ C o - P - O ] - C A N (4)
[ G a - G e - O ] - C A N (5)
[ G a - S i - O ] - C A N (6)
[ Z n - P - O ] - C A N (7)
]Li-Csl[A1-Si-O]-CAN (8)
ILi-TII[A]-Si-O]-CAN (8)
Basic cancrinite(9'~°)
Cancrinite hydrate (~)
D a v y n e (~2)
ECR_5 (13)
Microsommite (~4)
Synthetic cancrlmte
Tiptopite (~6)
Vishnevite (~7)
•
•
(15)
85
Cancrinite
Type Material Data
Crystal chemical data:
INa6Ca (H20)2 CO3l [A16Si6oO24]-CAN
hexagonal, P63, a - 12.75A, c - 5.14A (2~
Framework density:
16.6 T/1000A 3
Channels:
[001] 12 5.9 x 5.9*
CAN
12-ring viewed along [001]
References:
(1) Pauling, L. Proc. Natl. Acad. Sci., 16, 453-459 (1930)
(2) Jarchow, O. Z. Kristallogr., 122, 407-422 (1965)
(3) Belokoneva, E.L., Uvarova, T.G. and Dem'yanets, L.N. Soy. Phys. Crystallogr., 31,516-519 (1986)
(4) Bieniok, A., Brendel, U., Paulus, E.F. and Amthauer, G. Eur. J. Mineral., 17, 813-818 (2005)
(5) Lee, Y., Parise, J.B., Tripathi, A., Kim, S.J. and Vogt, T. Microporous Mesoporous Mat., 39, 445-455
(2000)
(6) Newsam, J.M. and Jorgensen, J.D. Zeolites, 7, 569-573 (1987)
(7) Yakubovich, O.V., Karimova, O.V. and Mel'nikov, O.K. Crystallogr. Reports, 39, 564-568 (1994)
(8) Norby, P., Krogh Andersen, I.G., Krogh Andersen, E., Colella, C. and de'Gennaro, M. Zeolites, 11,248253 (1991)
(9) Barrer, R.M. and White, E.A.D.J. Chem. Soc., 1561-1571 (1952)
(10) Bresciana Pahor, N., Calligaris, M., Nardin, G. and Randaccio, L. Acta Crystallogr., B38, 893-895 (1982)
(11) Wyart, J. and Michel-Levy, M. Compt. Rend., 229, 131- (1949)
(12) Hassan, I. and Grundy, H.D. Can. Mineral., 28, 341-349 (1990)
(13) Vaughan, D.E.W.E. Patent A-190, 90 (1986)
(14) Bonaccorsi, E., Comodi, P. and Merlino, S. Phys. Chem. Mineral., 22, 367-374 (1995)
(15) Smolin, Y.I., Shepelev, Y.F., Butikova, I.K. and Kobyakov, I.B. Kristallografiya, 26, 63-66 (1981)
(16) Peacor, D.R., Rouse, R.C. and Ahn, J.-H. Am. Mineral., 72, 816-820 (1987)
(17) Hassan, I. and Grundy, H.D. Can. Mineral., 22, 333-340 (1984)
86
CAS
Framework Type Data
Cmcm
<
z
Y
framework viewed along [100]
Idealized cell data:
orthorhombic, Cmcm, a - 5.3A, b = 14.l/k, c - 17.2A
Coordination sequences and vertex symbols"
T~ (8,m)
T 2(8,m)
4
4
4
T 3 (8,m)
12
12
12
Secondary building units:
23
26
23
41
43
43
70
64
72
97
101
95
125
138
128
5-1
Composite building unitscas
bik
Materials with this framework type:
*Cesium Aluminosilicate ~1'2~
EU-20b (CAS-NSI structural intermediate) <3~
174
165
177
224
215
225
264
284
259
5.5.5.5-6-82
5"6"5"6"6~-8~
5.6.5-6.52-6
87
Cesium Aluminosilicate
Type Material Data
CAS
Crystal chemical data:
ICs4l [A14Si20048]-CAS
orthorhombic, Ama2, a = 16.776A, b - 13.828/k, c - 5.021A (1)
(Relationship to unit cell of Framework Type: a ' = -c, b ' = b, c'= a)
Framework density:
20.6 T/1000A 3
Channels:
[001] 8 2.4 x 4.7*
8-ring viewed along [001]
References:
(1) Araki, T. Z. Kristallogr., 152, 207-213 (1980)
(2) Hughes, R.W. and Weller, M.T. Microporous Mesoporous Mat., 51, 189-196 (2002)
(3) Marler, B., Camblor, M.A. and Gies, H. Microporous Mesoporous Mat., 90, 87-101 (2006)
88
CDO
Framework Type Data
Cmcm
y
framework viewed along [001]
Idealized cell data"
orthorhombic, Cmcm, a - 7.6/k, b - 18.7/k, c - 14.1A
Coordination sequences and vertex symbols:
T, (16,1)
T 2(8,..m)
4
4
T 3 (8,m..)
4
T 4 (4,m2m) 4
12
12
12
12
Secondary building units:
21
20
28
24
39
35
44
42
5-1
Composite building units:
fer
Materials with this framework type:
• CDS_I (~
MCM_65 ~2)
UZM_25 ~3~
67
69
64
66
99
105
100
98
129
125
144
130
172
168
178
172
228
231
215
228
275
282
277
278
319
320
347
334
391
381
402
398
5.5.5.52.5.8
5.52.5.52.8.*
5-82.5.82.52.82
5.5.5.5-52.82
89
Type Material Data
CDS-1
CDO
Crystal chemical data:
[Si3~O72]-CDO
orthorhombic, Pnma, a - 18.355A, b - 13.779A, c - 7.3674A. ~l~
(Relationship to unit cell of Framework Type: a ' = b, b ' = c, c ' = a)
Framework density:
19.3 T/1000* 3
Channels:
[010] 8 3.1 x 4.7* ~ [001] 8 2.5 x 4.2*
4.7
8-ring viewed along [010]
!
~.
~"
8-ring viewed along [001]
References:
(1) Ikeda, T., Akiyama, Y., Oumi, Y., Kawai, A. and Mizukami, F. Angew. Chem., Int. Ed., 43, 4892-4896
(2004)
(2) Dorset, D.L. and Kennedy, G.J.J. Phys. Chem. B, 108, 15216-15222 (2004)
(3) Broach, R.W. private communication
90
CFI
Framework Type Data
Imma
i
Z
framework viewed along [01 O]
Idealized cell data"
orthorhombic, Imma, a - 14.0/k, b - 5.3A, c - 26.0/k
Coordination sequences and vertex symbols:
T 1(8,m)
4
10
21
36
56
84
T 2(8,m)
T 3(8,m)
T 4 (4,mm2)
T 5(4,mm2)
4
4
4
4
12
12
12
12
Secondary building units:
23
22
24
20
37
37
36
34
55
57
54
56
83
84
79
81
114
114
114
118
116
143
153
156
153
151
182
195
184
190
186
4.6.4.6.5-6
5.6.5.6.52.6
5.6.5.6.5.62
5.5.5.5.1414.*
5.5.5.5.5.62
231
222
222
234
220
see Compendium
Composite building units"
dzc
mtt
double zigzag
chain
Materials with this framework type"
• CIT_5 ~,2~
cas
ton
91
CIT-5
Type Material Data
CFI
Crystal chemical data:
[Si32064]-CFI
orthorhombic, Pmn2~, a - 13.674', b - 5.022A, c - 25.488* (2>
Framework density:
18.3 T/1000A 3
Channels:
[010] 14 7.2 x 7.5*
14-ring viewed along [010]
References:
(1) Wagner, P., Yoshikawa, M., Lovallo, M., Tsuji, K., Taspatsis, M. and Davis, M.E. Chem. Commun., 21792180 (1997)
(2) Yoshikawa, M., Wagner, P., Lovallo, M., Tsuji, K., Takewaki, T., Chen, C.Y., Beck, L.W., Jones, C.,
Tsapatsis, M., Zones, S.I. and Davis, M.E.J. Phys. Chem. B, 102, 7139-7147 (1998)
92
CGF
Framework Type Data
C21m
X
framework viewed along [001]
Idealized cell data:
monoclinic, C2/m, a - 15.5/k, b - 16.9A, c - 7.3/k, 3= 96.1 °
Coordination sequences and vertex symbols:
T 1 (8,1)
T 2(8,1)
T 3(8,1)
T 4(8,1)
T 5(4,2)
4
4
4
4
4
11
10
9
9
10
22
19
18
18
18
Secondary building units:
34
33
34
34
32
bog
Materials with this framework type:
* Co- Ga- Phosphate- 5 ~1)
[ Z n - G a - P - O ] - C G F ~2~
76
79
76
75
80
see Compendium
Composite building units:
mei
50
55
55
55
58
111
100
97
98
96
142
129
131
133
124
165
172
177
177
176
199
216
217
216
228
.4.8.63.8.63.8
4.6.4.62.6.6
4.4-4.6-6.62
4.63.4.63.4-8
4-4.62"62" 10" 10
93
Type Material Data
Co-Ga-Phosphate-5
C r y s t a l chemical data:
CGF
I(C6H,4N2):[ [Co4Ga5P9036]-CGF
C6HlzN 2 = D A B C O
monoclinic, I2/a
a - 15.002A, b - 17.688tk, c - 15.751A, ~3- 97.24 (')
(Relationship to unit cell of Framework Type: a ' = 2c, b ' = b, c ' = a)
Framework density:
17.4 T/1000A 3
Channels:
{[100] 10 2.5 x 9.2* + 8 2.1 x 6.7*} ~ [001] 8 2.4 x 4.8*
! 9.2
1O-ring viewed along [100]
8-ring viewed along [100]
8-ring viewed along [001]
References:
(1) Chippindale, A.M. and Cowley, A.R. Zeolites, 18, 176-181 (1997)
(2) Cowley, A.R., Jones, R.H., Teat, S.J. and Chippindale, A.M. Microporous Mesoporous Mat., 51, 51-64
(2002)
94
CGS
Framework Type Data
Prima
Z
framework viewed along [100]
Idealized cell data:
orthorhombic, P n m a , a - 8.4,~, b - 14.1/k, c - 15.9A
Coordination sequences and vertex symbols"
T 1 (8,1)
T 2(8,1)
T 3(8,1)
T 4(8,1)
4
4
4
4
9
9
9
9
Secondary building units:
16
18
17
18
26
32
28
32
4
Materials with this framework type:
*Co-Ga-Phosphate-6 ~)
[Zn-Ga-P-O]-CGS <L2~
TNU- 1, [Ga-Si-O]-CGS ~3)
TsG- 1, [Ga-Si-O]-CGS ~4)
43
48
45
48
67
66
66
67
91
91
91
91
116
121
119
119
148
150
148
151
188
184
186
185
4.4.4.6.6.8
4.4.4.102.8.86
4.4.4.82.6.10
4.4.4.8.84.10
95
Co-Ga-Phosphate-6
Crystal chemical data:
Type Material Data
CGS
I(CH,4N)4I [Co4Ga,2P16064]-CGS
CTH~4N = quinuclidinium
monoclinic, P2~/c
a - 14.365A, b - 16.305A, c - 8.734A, ~= 90.24 (~)
(Relationship to unit cell of Framework Type: a ' = b, b ' = c, ¢'= a)
Framework density:
15.6 T/1000A 3
Channels:
{[001] 10 3.5 x 8.1 +-+ [100] 8 2.5 x 4.6}***
1O-ring viewed along [001]
8-ring viewed along [100]
References:
(1)
(2)
(3)
(4)
Cowley, A.R. and Chippindale, A.M. Microporous Mesoporous Mat., 28, 163-172 (1999)
Lin, C.-H. and Wang, S.-L. Chem. Mater., 12, 3617-3623 (2000)
Hong, S.B., Kim, S.H., Kim, Y.G., Kim, Y.C., Barrett, P.A. and Camblor, M.A.J. Mater. Chem., 9, 22872289 (1999)
Lee, Y.J., Kim, S.J., Wu, G. and Parise, J.B. Chem. Mater., 11, 879-880 (1999)
96
CHA
m
Framework Type Data
R3m
z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
trigonal, R 3 m , a - 13.7A, c - 14.8A
Coordination sequences and vertex symbols:
T, (36,1)
4
9
17
29
45
64
85
110
140
Secondary building units:
6-6 or 6 or 4-2 or 4
Framework description"
A A B B C C sequence of 6-rings
Composite building units:
d6r
cha
173
4.4-4.8.6.8
Materials with this framework type:
• Chabazite (1,2)
[ A 1 - A s - O ] - C H A (3)
[ C o - A 1 - P - O ] - C H A (4'5)
[ M g - A 1 - P - O ] - C H A ~5~
[ S i - O ] - C H A ~6~
[ Z n - A 1 - P - O ] - C H A ~7~
[ Z n - A s - O ] - C H A ~3~
[CoI[Be-P-O]-CHA~8~
ILi-NaI[AI-Si-O]-CHA <9)
A1PO_34 <~°)
CoAPO_44 ~
CoAPO_47 ~)
DAF_5 (12)
M e A P S O _ 4 7 (11,2°,21)
Dehyd. Na-Chabazite ~3~
GaPO_34 (~4)
K-Chabazite, Iran~5~
LZ-218 ~6~
Linde D ~17'~8~
Linde R (19)
MeAPO_47 ~11'2°'21~
SAPO_34 ~25~
SAPO_47 ~26~
UiO_21 ~27~
Willhendersonite(28)
ZK- 14 (29)
ZYT_6 (3°)
m
.-(22)
Ni(deta)~-UT-o
Phi(18,23,24) -
97
Chabazite
Crystal chemical data:
Type Material Data
CHA
lea6 (HO)401 [Al12Si24072]-CHA
rhombohedral, R - 3 m , a - 9.42A, c~- 94.47 ° ~2~
Framework density:
14.5 T/1000A 3
Channels:
_L [001] 8 3.8 x 3.8***
(variable due to considerable flexibility of framework)
see Appendix A for 8-ring viewed normal to [001]
References:
(1) Dent, L.S. and Smith, J.V. Nature, 181, 1794-1796 (1958)
(2) Smith, J.V., Rinaldi, F. and Dent Glasser, L.S. Acta Crystallogr., 16, 45-53 (1963)
(3) Feng, P., Zhang, T. and Bu, X. J. Am. Chem. Soc., 123, 8608-8609 (2001)
(4) Feng, P., Bu, X. and Stucky, G.D. Nature, 388, 735-741 (1997)
(5) Feng, P., Bu, X., Gier, T.E. and Stucky, G.D. Microporous Mesoporous Mat., 23, 221-229 (1998)
(6) Dfaz-Cabafias, M.-J., Barrett, P.A. and Camblor, M.A. Chem. Commun., 1881-1882 (1998)
(7) Tusar, N.N., Kaucic, V., Geremia, S. and Vlaic, G. Zeolites, 15, 708-713 (1995)
(8) Zhang, H.Y., Weng, L.H., Zhou, Y.M., Chen, Z.X., Sun, J.Y. and Zhao, D.Y.J. Mater. Chem., 12, 658-662
(2O02)
(9) Smith, L.J., Eckert, H. and Cheetham, A.K.J. Am. Chem. Soc., 122, 1700-1708 (2000)
(10) Harding, M.M. and Kariuki, B.M. Acta Cmstallogr., C50, 852-854 (1994)
(11) Bennett, J.M. and Marcus, B.K. Stud. Surf Sci. Catal., 37, 269-279 (1988)
(12) Sankar, G., Wyles, J.K., Jones, R.H., Thomas, J.M., Catlow, C.R.A., Lewis, D.W., Clegg, W., Coles, S.J.
and Teat, S.J. Chem. Commun., 117-118 (1998)
(13) Mortier, W.J., Pluth, J.J. and Smith, J.V. Mater. Res. Bull., 12, 241-250 (1977)
(14) Schott-Darie, C., Kessler, H., Soulard, M., Gramlich, V. and Benazzi, E. Stud. Surf Sci. Catal., 84, 101108 (1994)
(15) Calligaris, M., Nardin, G. and Randaccio, L. Zeolites, 3, 205-208 (1983)
(16) Breck, D.W. and Skeels, G.W.U.S. Patent 4,333,859 (1982)
(17) Breck, D.W. and Acara, N.A.U.S. Patent 2,950,952 (1960)
(18) Lillerud, K.P., Szostak, R. and Long, A. J. Chem. Soc., Faraday Trans., 90, 1547-1551 (1994)
(19) Milton, R.M. Brit. Patent 841,812 (1960)
(20) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Pure App1. Chem., 58, 1351-1358 (1986)
(21) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Proc. 7th Int. Zeolite Conf., pp. 103-112 (1986)
(22) Garcia, R., Shannon, I.J., Slawin, A.M.Z., Zhou, W., Cox, P.A. and Wright, P.A. Microporous Mesoporous
Mat., 58, 91-104 (2003)
(23) Grose, R.W. and Flanigen, E.M.U.S. Patent 4,124,686 (1978)
(24) Lobo, R.F., Annen, M.J. and Davis, M.E. 21. Chem. Soc., Faraday Trans., 88, 2791-2795 (1992)
(25) Lok, B.M., Messina, C.A., Patton, R.L., Gajek, R.T., Cannan, T.R. and Flanigen, E.M.J. Am. Chem. Soc.,
106, 6092-6093 (1984)
(26) Pluth, J.J. and Smith, J.V.J. Phys. Chem., 93, 6516-6520 (1989)
(27) Kongshaug, K.O., Fjellvfig, H. and Lillerud, K.P. Microporous Mesoporous Mat., 39, 341-350 (2000)
(28) Tillmanns, E., Fischer, R.X. and Baur, W.H.N. Jb. Miner. Mh., 547-558 (1984)
(29) Kuehl, G.H. Molecular Sieves, pp. 85-91 (1968)
(30) Ito, M., Shimoyama, Y., Saito, Y., Tsurita, Y. and Otake, M. Acta Crystallogr., C41, 1698-1700 (1985)
98
-CHI
Framework Type Data
Pbcn
~
z
Y
framework viewed along [100]
Idealized cell data:
orthorhombic, Pbcn, a - 5.0/k, b - 31.2A, c - 9.0A
Coordination sequences and vertex symbols:
T 1 (8,1)
T2(8,1)
T 3(8,1)
T 4(4,2)
4
4
3
4
11
10
8
6
Secondary building units:
22
20
13
14
40
36
29
28
5-[1,1]
Materials with this framework type:
*Chiavennite ~
64
60
53
56
89
86
80
80
120
115
113
114
160
157
147
152
203
196
193
190
248
238
231
236
4.63-6.6.62-62
4.5.6.9-63.102
4.5-9
4.4.5.9-10"10
99
Chiavennite
Type Material Data
-CHI
Crystal chemical data:
ICa4 Mn4(H~O)81[Be8Si20052 (OH)8I-CHI
orthorhombic, Pnab, a - 8.729A, b - 3 1 . 3 2 6 ' , c - 4.903A (~
(Relationship to unit cell of Framework Type: a ' - -c, b ' - b, c ' - a)
Framework density:
20.9 T/1000A 3
Channels:
[001] 9 3.9 x 4.3*
9-ring viewed along [001]
References:
(1) Tazzoli, V., Domeneghetti, M.C., Mazzi, F. and Cannillo, E. Eur. J. Mineral., 7, 1339-1344 (1995)
100
-CLO
Framework Type Data
•
~
:
" .. s2
Pm3m
......
:~:', °~'~*'~
~
.~:~4i ~ ....................~iiiiiiiii~+
/
z
framework viewed along [001] (upper right: projection down [001])
Idealized cell data"
cubic, P m - 3 m , a - 25.8A
Coordination sequences and vertex symbols:
T1(48,1)
4
9
16
23
31
44
T 2 (48,1)
T 3 (48,1)
T 4 (24,m)
T 5 (24,m)
4
4
4
3
9
8
9
5
17
13
16
10
Secondary building units:
27
22
23
18
37
34
32
29
47
44
45
45
59
56
55
58
56
4-4 or 4
Composite building units:
d4r
clo
~,!~: ......
Materials with this framework type:
*Cloverite ~
[ M n - G a - P - O ] - - C L O ~2~
[ Z n - G a - P - O ] - - C L O ~2~
lta
74
66
72
76
65
91
80
94
98
86
109
99
117
118
110
.4.6.4.6.4.12
4-6.4-6-4-8
4.6.4.6.4.208
4-6.4.6.4.8
4.4.4
101
Cloverite
Crystal chemical data:
Type Material Data
-CLO
I(CvH14N)2418[F24Ga96P960372(OH)2418-CLO
CvHl4N - quinuclidinium
cubic, Fm-3c, a - 51.712A ~1~
(Relationship to unit cell of Framework Type: a ' - 2a)
Framework density:
11.1 T/1000A 3
Channels"
<100> 20 4.0 x 13.2"** I <100> 8 3.8 x 3.8***
20-ring viewed along <100>
8-ring viewed along <100>
References:
(1) Estermann, M., McCusker, L.B., Baerlocher, Ch., Merrouche, A. and Kessler, H. Nature, 352, 320-323
(1991)
(2) Yoshino, M., Matsuda, M. and Miyake, M. Solid State Ionics, 151,269-274 (2002)
102
CON
Framework Type Data
"
~
C21m
~r'~....,,:~ ........
x
framework viewed along [001]
Idealized cell data:
monoclinic, C2/m, a - 22.7/k, b - 13.4A, c - 12.6/k, 3= 69.5 °
Coordination sequences and vertex symbols:
T,(8,1)
T 2(8,1)
4
4
4
4
4
4
4
T 3 (8,1)
T 4 (8,1)
T 5(8,1)
T 6(8,1)
T 7(8,1)
10
11
10
10
10
11
11
Secondary building units:
19
18
21
19
19
18
19
32
31
32
32
32
28
32
50
52
47
51
51
49
49
73
77
74
74
74
77
75
101
98
105
100
101
103
105
132
126
134
130
130
126
131
164
164
159
165
164
155
159
199
205
196
203
203
201
196
4.5.4.104.5.62
4.5-5.6.5.102
4.6.4.104.5.62
4"4"5-62"5" 127
4.4.5.62-5.124
4.52.5.62.6.62
4.62.5.6.5.102
1-5-1
Composite building units"
bea
bre
lau
mel
Materials with this framework type"
*CIT-1(1)
SSZ-26 (related to C O N ) (1'2)
SSZ-33 (related to C O N ) (1'2)
103
CIT-1
Type Material Data
Crystal chemical data:
CON
IH~I[BeSi540,,el-CON
monoclinic, C2/m
a - 22.624A, b - 13.350A, c - 12.364A,, ~= 68.91 °~1)
F r a m e w o r k density"
16.1 T/1000.~ 3
Channels:
[001] 12 6.4 x 7.0* ~ [ 100] 12 7.0 x 5.9* +--> [010] 10 5.1 x 4.5"
12-ring viewed along [001 ]
12-ring viewed along [100]
1O-ring viewed along [01 O]
References:
(1) Lobo, R.F. and Davis, M.E.J. Am. Chem. Soc., 117, 3764-3779 (1995)
(2) Lobo, R.F., Pan, M., Chan, I., Li, H.X., Medrud, R.C., Zones, S.I., Crozier, P.A. and Davis, M.E. Science,
262, 1543-1546 (1993)
104
CZP
Framework Type Data
P6122
iI
?
°
°
°
Z
1
x
L.
Y
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data"
hexagonal, P6~22, a - 9.4/k, c - 15.3A
Coordination sequences and vertex symbols"
T, (12,1)
4
9
18
32
54
83
T 2(6,2)
4
10
20
33
56
85
T 3(6,2)
4
8
16
33
52
73
Secondary building units:
4-[1,1] or 4
Materials with this f r a m e w o r k type:
(12)
*Chiral Zincophosphate '
I(H3DETA)2 (H20)d [Mn6Ga6P 12O48]-CZP (3)
[Na-I[Co-Zn-P-O]-CZP ~4~
[Zn-B-P-O]-CZP ~5~
113
114
112
149
144
160
191
192
190
234
242
214
4-4.4.86-8.8
4"4"83"83"86"86
4"4"4"4"8"8
105
Chiral Zincophosphate
Crystal chemical data"
Type Material Data
CZP
INa,~ (H~O),J [Zn,2P,2048]-CZP
hexagonal, P6t22, a - 10.480A, c - 15.089A ~2~
Framework density:
16.7 T/1000* 3
Channels:
[001] 12 3.8 x 7.2* (highly distorted 12-ring)
7.2 /
distorted 12-ring viewed along [001 ]
References:
(1) Rajic, N., Logar, N.Z. and Kaucic, V. Zeolites, 15, 672-678 (1995)
(2) Harrison, W.T.A., Gier, T.E., Stucky, G.D., Broach, R.W. and Bedard, R.A. Chem. Mater., 8, 145-151
(1996)
(3) Lin, C.H. and Wang, S.L. Chem. Mater., 14, 96-102 (2002)
(4) Helliwell, M., Helliwell, J.R., Kaucic, V., Logar, N.Z., Barba, L., Busetto, E. and Lausi, A. Acta
Crystallogr., B55, 327-332 (1999)
(5~ Wiebcke, M., Bogershausen and A., Koller, H. Microporous Mesoporous Mat., 78, 97-102 (2005)
106
DAC
Framework Type Data
C21m
x
framework viewed along [001]
Idealized cell data"
monoclinic, C2/m, a - 18.6/~, b - 7.5/k, c - 10.4A, 3 = 108.9 °
Coordination sequences and vertex symbols:
4
4
4
4
T 1(8,1)
T 2(8,1)
T 3 (4,m)
T 4(4,m)
12
12
11
11
Secondary building units:
22
20
24
24
39
37
41
39
65
63
59
63
91
91
99
95
121
118
130
132
163
164
155
156
5-1
Composite building units"
mot"
Materials with this framework type*D achiardite(l'2)
Svetlozarite (disordered variant, since discredited) ~3~
208
212
202
199
250
245
262
266
5.5-5.52.8.102
5"5-5-5~-5-8
4-52.5.8.5.8
4-52.5.8.5.8
107
Dachiardite
Crystal chemical data:
Type Material Data
](Cao.~,K,Na) ~ (H~O)J [A15Si19048]-DAC
monoclinic, C2/m
a - 18.676A, b - 7.518A, c - 10.246A, ~3 - 107.87 ° (2~
F r a m e w o r k density:
17.5 T/1000A 3
Channels:
[010] 10 3.4 x 5.3* <--> [001] 8 3.7 x 4.8*
1O-ring viewed along [01 O]
8-ring viewed along [001]
References:
(1)
(2)
(3)
Gottardi, (3. and Meier, W.M.Z. Kristallogr., 119, 53-64 (1963)
Vezzalini, G. Z. Kristallogr., 166, 63-71 (1984)
Gellens, L.R., Price, G.D. and Smith, J.V. Mineral. Mag., 45, 157-161 (1982)
DAC
108
DDR
Framework Type Data
R3m
Z
framework viewed normal to [001] (upper right: projection down [001])
trigonal, R-3m, a = 13.8/k, c - 40.8/k
Idealized cell data"
Coordination sequences and vertex symbols"
T1(36,1 )
T2(18,m )
T3(18,m )
T4(18,m )
T5(18,2 )
T6(6,3m )
T7(6,3m )
4
4
4
4
4
4
4
11
12
12
12
10
12
12
Secondary building units"
23
22
25
24
21
24
24
39
37
40
40
37
39
33
62
59
61
63
62
57
60
91
93
86
87
94
93
97
124
127
119
121
124
121
136
159
158
164
165
158
157
150
203
193
212
208
196
210
192
251
251
253
255
252
240
264
4.5-5-5.5.8
5.5-5.5.5.5
5.5.5.5.5.6
5.5.5.5.5.8
4.4.5.5-6.8
5.5.5.5.5.5
5 . 5 . 5.~- 5 . 5
see Compendium
Composite building units:
mtn
.
•
..
..,
k
)-
Materials with this framework type:
*Deca-dodecasil 3R ~1)
[B-Si-O]-DDR ~2~
Sigma_l ~3)
ZSM_58 ~4,5~
....
109
Type Material Data
Deca-dodecasil 3R
Crystal chemical data:
](C,oH,TN)6 (N2)91 [Si~2oO24o]-DDR
CjoH~TN - 1-aminoadamantane
trigonal, R 3 m , a - 13.860A, c - 40.891A, ~1)
Framework density:
17.6 T/1000A 3
Channels:
2_ [001] 8 3.6 x 4.4**
DDR
:..
8-ring viewed normal to [001]
References:
(1) Gies, H. Z. Kristallogr., 175, 93-104 (1986)
(2) Grfinewald-Luke, A., Marler, B., Hochgrafe, M. and Gies, H. J. Mater. Chem., 9, 2529-2536 (1999)
(3) Stewart, A., Johnson, D.W. and Shannon, M.D. Stud. Surf. Sci. Catal., 37, 57-64 (1988)
(4) Valyocsik, E.W.U.S. Patent 4,698,217 (1987)
(5) Ernst, S., Chen, C.Y., Lindner, D. and Weitkamp, J. Zeolites for the Nineties, Recent Progress Reports Abstracts, pp. 55-56 (1989)
110
DFO
Framework Type Data
P61mmm
f
z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
hexagonal, P6/mmm, a - 22.0/k, c - 21.2A
Coordination sequences and vertex symbols"
T 1(24,1)
T 2(24,1)
T 3 (24,1)
T 4(24,1)
T 5(24,1)
T 6 (12,m)
4
4
4
4
4
4
9
10
10
9
9
10
Secondary building units:
16
18
18
17
17
18
26
27
28
29
29
28
41
42
45
45
44
45
60
62
65
63
62
66
82
84
84
82
85
89
sti
Materials with this framework type:
• DAF_I ~,2~
135
135
134
136
139
141
4-63.4.63.4.12
4.62.4.8.6.62
4.4.6.63.63.10
4.6.4.62.4-8
4.4.4.6.6.62
4.62.4.62.10.12
167
167
173
168
169
171
see Compendium
Composite building units:
d4r
107
109
106
106
112
115
bog
/au
111
DAF-1
Type Material Data
DFO
I(C,6H38N2)7(H:O)40l [Mg,4A152P660264]-DFO
Crystal chemical data:
C~6H3sN2 = decamethonium
hexagonal, P6/mmm, a - 2 2 . 3 5 1 ' , c - 21.693/~, (1)
Stability:
Transforms to A1PO-5 and A1PO-tridymite on heating to 500°C ~1~
Framework density:
14.1 T/1000A 3
Channels:
{[001] 12 7.3 x 7.3 <-->2_ [001] 8 3.4 x 5.6}*** <-->{[001] 12 6.2 x 6.2
± [001 ] 10 5.4 x 6.4 }***
7.3
'\\
7.3
.....".,,/
12-ring viewed along [001]
8-ring viewed normal to [001]
2nd 12-ring viewed along [001]
1O-ring viewed normal to [001 ]
References:
(1)
(2)
Wright, P.A., Jones, R.H., Natarajan, S., Bell, R.G., Chen, J.S., Hursthouse, M.B. and Thomas, J.M. Chem.
Commun., 633-635 (1993)
Muncaster, G., Sankar, G., Catlow, C.R.A., Thomas, J.M., Bell, R.G., Wright, P.A., Coles, S., Teat, S.J.,
Clegg, W. and Reeve, W. Chem. Mater., 11, 158-163 (1999)
112
DFT
P4Jmmc
Framework Type Data
>
,>
>
~
Y
x
framework viewed along [001]
Idealized cell data"
tetragonal, P42/mmc, a - 7.1A, c - 9.0/k
Coordination sequences and vertex symbols:
T, (8,m)
4
10
Secondary building units"
21
36
55
79
106
138
175
215
4
Composite building units:
llsc
narsarsukite
chain
Materials with this framework type:
*DAF_2 °)
ACP-3 ([Co-A1-P-O]-DFT) ~2~
U C S B - 3 G a G e ~3~
U C S B - 3 Z n A s ~2~
U i O - 2 0 ( [ M g - P - O ] - D F T ) <4~
[ F e - Z n - P - O ] - D F T ~5)
[ Z n - C o - P - O ] - D F T ~6~
4.4.62.83.62-83
113
Type Material Data
DAF-2
Crystal chemical data:
DFT
I(C2H~oN2)2[ [C04P40~6I-DFT
CaHloN 2 = ethylenediammonium
monoclinic, I2/b
a - 14.719A, b - 14.734A, c - 17.891A,, ~ - 90.02 ° ('~
(Relationship to unit cell of Framework Type:
a ' = 2a, b ' = 2a, c ' = 2c)
Framework density"
Channels:
16.5 T/1000A 3
[001] 84.1 x 4.1" o [100] 8 1.8 x 4.7* <--) [010] 8 1.8 x 4.7*
8-ring viewed along [001]
8-ring viewed along [100]
8-ring viewed along[OlO]
References:
(1)
(2)
(3)
(4)
(5)
(6)
Chen, J., Jones, R.H., Natarajan, S., Hursthouse, M.B. and Thomas, J.M. Angew. Chem., Int. Ed., 33, 639640 (1994)
Bu, X., Feng, P., Gier, T.E. and Stucky, G.D.J. Solid State Chem., 136, 210-215 (1998)
Bu, X., Feng, P., Gier, T.E., Zhao, D. and Stucky, G.D.J. Am. Chem. Soc., 120, 13389-13397 (1998)
Kongshaug, K.O., Fjellvag, H. and Lillerud, K.P. Chem. Mater., 12, 1095-1099 (2000)
Zhao, Y.N., Jin, J. and Kwon, Y.U. Bull. Korean Chem. Soc., 26, 1277-1280 (2005)
Ke, Y., He, G., Li, J., Zhang, Y., Lu, S. and Lei, Z. Cryst. Res. Technol., 37, 803-811 (2002)
114
DOH
Framework Type Data
P61mmm
Z
22122
............. ::~:~....
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
hexagonal, P6/mmm, a - 14.2/k, c - 11.5/k
Coordination sequences and vertex symbols:
T~(12,m)
T 2(12,m)
T 3(6,mm2)
T 4(4,3m)
4
4
4
4
12
11
12
12
Secondary building units:
23
24
25
24
41
41
42
36
mtn
Materials with this framework type:
*Dodecasil 1H ~1~
92
91
90
101
see Compendium
Composite building units:
[ B - S i - O ] - D O H ~2~
64
63
68
61
128
128
122
133
167
171
167
156
207
214
210
204
259
259
268
256
5.5-5.5.5.6
4.5.5.6-5.6
5.5.5.5.5.6
5-5.5-5.5.5
115
Dodecasil 1 H
Crystal chemical data:
Type Material Data
DOH
ICsH1,N (N:)~I [Si34068]-DOH
CsH~N = piperidine
hexagonal, P6/mmm, a - 13.783A,, c - 11.190A (~)
Framework density:
18.5 T/1000A 3
Channels:
apertures formed by 6-rings only
References:
(1)
(2)
Gerke, H. and Gies, H. Z. Kristallogr., 166, 11-22 (1984)
Grtinewald-Luke, A., Marler, B., Hochgrafe, M. and Gies, H. J. Mater. Chem., 9, 2529-2536 (1999)
116
DON
Framework Type Data
Cmcm
X
framework viewed along [001]
orthorhombic, Cmcm, a - 18.9A, b - 23.4A, c - 8.5A
Idealized cell data:
Coordination sequences and vertex symbols:
T 1 (16,1)
T 2(16,1)
T 3(16,1)
T 4(8,m)
T 5(8,m)
4
4
4
4
4
10
10
12
12
12
20
20
24
22
23
34
35
38
33
37
Secondary building units:
5-3
Composite building units:
clcc
aft"
double
crankshaft chain
Materials with this framework type"
* U T D - 1F (1)
UTD_I (2~
54
54
55
53
52
77
77
76
80
74
107
106
105
109
107
mel
140
138
143
143
143
175
177
184
179
183
218
221
223
217
223
4.6.4.62.5.6
4.6.4.62.5.6
5.62.6.62.6.62
5.6.5.6.6.62
5.62.5.62.62-62
117
Type Material Data
UTD-1F
DON
I((Cp*)~Co)~ F, ~(OH)0~l[Si64012sl-DON
Crystal chemical data:
Cp* = pentamethylcyclopentadiene
monoclinic, Pc
a - 14.970A, b - 8.476A, c - 30.028A, ~ - 102.65 ° (1)
(Relationship to unit cell of Framework Type:
a ' - a/(2sin~3'), b ' - c, c ' - v/(a2+c 2)
or, as vectors, a ' = (a - b)/2, b ' = c, c ' = a + b)
Framework density:
17.2 T/1000A 3
Channels:
[010] 14 8.1 x 8.2*
•
8.1
.................i ........................................
~•
14-ring viewed along [01 O]
References:
(1) Wessels, T., Baerlocher, C., McCusker, L.B. and Creyghton, E.J.J. Am. Chem. Soc., 121, 6242-6247
(1999)
(2) Lobo, R.F., Tsapatsis, M., Freyhardt, C.C., Khodabandeh, S., Wagner, P., Chen, C.Y., Balkus, K.J., Zones,
S.I. and Davis, M.E.J. Am. Chem. Soc., 119, 8474-8484 (1997)
118
EAB
P6Jmmc
Framework Type Data
z
framework viewed normal to [001] (upper right: projection down [001 ])
o
Idealized cell data:
o
hexagonal, P63/mmc, a - 13.2A, c - 15.0A
Coordination sequences and v e r t e x s y m b o l s :
T~(24,1)
T 2(12,2)
4
4
9
10
17
20
30
32
49
46
71
66
92
94
115
128
147
162
Secondary building units:
6or4
Framework description:
A B B A C C sequence of 6-rings
Composite building units:
d6r
gme
Materials with this framework type:
* T M A - E (Aiello and Barrer) ~'2~
1 (3)
Bellberg'te
190
192
4-4.4.6.6.8
4.4-6-6.8.8
119
TMA-E (Aiello and Barrer)
Type Material Data
Crystal chemical data:
[(C4H~2N)2Na7 (H20)26l [A19Si27072]-EAB
C4H~2N - tetramethylammonium
hexagonal, P63/mmc, a - 13.28A, c - 15.21A (2~
Framework density"
15.5 T/1000A 3
Channels:
2_ [001] 8 3.7 x 5.1"*
8-ring viewed normal to [001]
References:
(1) Aiello, R. and Barrer, R.M.J. Chem. Soc. (A), 1470-1475 (1970)
(2) Meier, W.M. and Groner, M. J. Solid State Chem., 37, 204-218 (1981)
(3) Rtidinger, B., Tillmanns, E. and Hentschel, G. Miner. Petrol., 48, 147-152 (1993)
EAB
•
120
ED
Framework Type Data
P4m2
Z
framework viewed normal to [001]
Idealized cell data:
tetragonal, P - 4 m 2 ,
a -
6.9/k, c - 6.4/k
Coordination sequences and vertex symbols:
T 1 (4,m)
4
T 2(1, 4 m 2 ) 4
9
8
Secondary building units"
19
18
35
32
52
52
72
74
100
100
131
128
163
162
201
204
4=1
Composite building units:
nat
Materials with this framework type:
*Edingtonite(1-3)
[Co-A1-P-O]-EDI (4)
[Co-Ga-P-O]-EDI (4~
[Zn-As-O]-EDI ~5~
[(C3H12N2)2.sl[Zn5P502o]-EDI(6)
ILi-I[A1-Si-O]-EDI ~7~
IRb7 Na (H20)3I[GasSil2040]-EDI ~8~
K_F(9,10)
Linde F ~l~
Orthorhombic edingtonite(12)
Synthetic edingtonite ~13~
Tetragonal edingtonite ~14)
Zeolite N ~15~
4"83"4"83"42"84
42"42"84"84"84"84
121
Edingtonite
Crystal chemical data:
Type Material Data
IBa2 (H20)sl [A14Si6020I-EDI
orthorhombic, P2~2~2, a - 9.550A, b - 9.665A, c - 6.523.3, ~2)
(Relationship to unit cell of Framework Type:
a ' - av/2, b ' - by/2, c' - c
or, as vectors, a ' = a + b, b ' = b - a, e ' = e)
F r a m e w o r k density:
16.6 T/1000A 3
Channels:
<110> 8 2.8 x 3.8** ~ [001] 8 2.0 x 3.1"
(variable due to considerable flexibility of framework)
References:
(1) Taylor, W.H. and Jackson, R. Z. Kristallogr., 86, 53-64 (1933)
(2) Galli, E. Acta Crystallogr., B32, 1623-1627 (1976)
(3) Kvick, A. and Smith J.V.J. Chem. Phys., 79, 2356-2362 (1983)
(4) Bu, X., Gier, T.E., Feng, P. and Stucky, G.D. Chem. Mater., 10, 2546-2551 (1998)
(5) Feng, P., Zhang, T. and Bu, X. J. Am. Chem. Soc., 123, 8608-8609 (2001)
(6) Harrison, W.T.A. Acta Crystallogr., E57, m248-m250 (2001)
(7) Matsumoto, T., Miyazaki, I. and Goto, Y. J. Eur. Ceramic Soc., 26, 455-458 (2006)
(8) Lee, Y.J., Kim, S.J. and Parise, J.B. Microporous Mesoporous Mat., 34, 255-271 (2000)
(9) Barrer, R.M. and Baynham, J.W.J. Chem. Soc., 2882-2891 (1956)
(10) Baerlocher, Ch. and Barrer, R.M.Z. Kristallogr., 140, 10-26 (1974)
(ll) Sherman, J.D. ACS Sym. Set., 40, 30-42 (1977)
(12) Gatta, G.D. and Ballaran, T.B. Mineral. Mag., 68, 167-175 (2004)
(13) Ghobarkar, H. and Schaef, O. C~st. Res. Technol., 32, 653-657 (1997)
(14) Mazzi, F., Galli, E. and Gottardi, G. N. Jb. Miner. Mh., 373-382 (1984)
(15) Christensen, A.N. and Fjellvfig, H. Acta Chemica Scand., 51,969-973 (1997)
EDI
122
EMT
P6Jmmc
Framework Type Data
Z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data"
hexagonal, P63/mmc, a - 17.2A, c - 28.1/k
Coordination sequences and vertex symbols:
T 1 (24,1)
T 2(24,1)
T 3 (24,1)
T 4 (24,1)
4
4
4
4
9
9
9
9
16
16
16
16
25
25
25
25
37
37
37
37
53
53
53
53
73
73
73
73
96
96
97
96
121
121
124
120
148
148
152
145
Secondary building units:
6-6 or 6-2 or 6 or 4-2 or 1-4-1 or 4
Composite building units:
d6r
sod
178
179
180
174
212
214
210
210
4-4.4.6.6-12
4.4-4.6.6.12
4-4-4-6.6.12
4.4-4.6.6.12
Materials with this framework type:
• EMC_2 (1,2)
CSZ- 1 ( E M T - F A U structural intermediate) (3)
E C R - 3 0 ( E M T - F A U structural intermediate) (4)
Z S M - 2 0 ( E M T - F A U structural intermediate) (5~
Z S M - 3 ( E M T - F A U structural intermediate) (6~
123
EMC-2
EMT
Type Material Data
Crystal chemical data"
INa2, (C12H2406)41[Ale,Si750,9el-EMT
C12H240
6 =
18-crown-6
hexagonal, P6]mmc, a - 17.374A, c - 28.365A ~2~
Framework density:
12.9 T/1000A ~
Channels:
[001] 12 7.3 x 7.3* +-+ I [001] 12 6.5 x 7.5**
7.3
7.s
...'......./
i
i
...........
•
.~
12-ring viewed along [001]
12-ring viewed normal to [001]
References:
(1) Delprato, F., Delmotte, L., Guth, J.L. and Huve, L. Zeolites, 10, 546-552 (1990)
(2) Baerlocher, Ch., McCusker, L.B. and Chiappetta, R. Microporous Materials, 2, 269-280 (1994)
(3) Barrett, M.G. and Vaughan, D.E.W. UK Patent GB 2,076, 793 A (1981)
(4) Vaughan, D.E.W.E. Patent 0,351,461 (1989)
(5) Newsam, J.M., Treacy, M.M.J., Vaughan, D.E.W., Strohmaier, K.G. and Mortier, W.J. Chem. Commun.,
493-495 (1989)
(6) Kokotailo, G.T. and Ciric, J. Adv. Chem. Ser., 101, 109-121 (1971)
124
EON
Framework Type Data
Pmmn
z
y
framework viewed along [100]
Idealized cell data:
orthorhomic, Pmmn (origin choice 2), a - 7.6/k, b - 18.1A, c - 25.9A
Coordination sequences and vertex symbols"
T 1 (8,1)
T 2(8,1)
T 3(8,1)
T 4(8,1)
T 5(8,1)
T 6(4,m..)
T 7(4,m..)
T 8(4,m..)
T 9(4,m..)
T10(4,m..)
4
4
4
4
4
4
4
4
4
4
10
10
10
12
12
10
10
10
11
11
Secondary building units:
20
20
21
21
20
21
21
21
24
24
35
36
37
36
36
36
36
37
38
39
55
56
55
59
62
53
54
55
52
57
80
79
80
85
84
77
76
76
82
87
108
106
111
108
112
109
108
103
124
118
137
140
137
150
151
142
142
149
146
149
5-1
Composite building units"
dsc
mor
double sawtooth
chain
Materials with this framework type"
• ECR_I ~1-3)
TNU_7 ~4~
gme
Q
170
177
183
192
193
175
181
191
182
187
214
222
232
231
229
217
226
218
238
235
272
267
274
277
272
266
258
266
283
282
330
317
316
331
340
315
309
326
325
327
4.5.4.5.8-12
4.5.4.5.8.12
4.5.4.5-8.12
5.5.5.52.8.12
5.5.5.52.5.8
4.82.4.82.5.6
4.82.4.82.5.6
4.82.4.82.5.6
4.52.5.82.5.82
4.52.5.8.5.8
125
ECR-1
EON
Type Material Data
Crystal chemical data:
INa~(H20)yl [AlxSi6~xO,20l-EON, x - 3.6 ... 11.4
orthorhombic, Pmmn, a - 7.579/~, b - 18.089/k, c - 25.853/k (4)
Framework density:
16.9 T/1000A 3
Channels:
{[1001 12 6.7 x 6.8* ~ [010] 8 {[001] 3.4 x 4.9
[100] 8 2.9 x 2.9}*}**
(Two independent, 2-dimensional channel systems, each consisting of
a 12-ring in the [100] direction and a series of 8-rings with effective
diffusion in the [010] direction)
,i.
4.9
.....
....
12-ring viewed along [lO0]
..:
:,~
i3.8
:!~
"
.....
8-ring viewed along [001]
References:
(1) Leonowicz, M.E. and Vaughan, D.E.W. Nature, 329, 819-821 (1987)
(2) Chen, C.S.H., Schlenker, J.L. and Wentzek, S.E. Zeolites, 17, 393-400 (1996)
(3) Gualtieri, A.F., Ferrari, S., Galli, E., Di Renzo, F. and van Beek, W. Chem. Mater., 18, 76-84 (2006)
(4) Warrender, S.J., Wright, P.A. Zhou, W.Z., Lightfoot, P., Camblor, M.A., Shin, C.H., Kim, D.J. and Hong,
S.B. Chem. Mater., 17, 1272-1274 (2005)
126
EPI
<
Framework Type Data
C21m
l
,JI
t
y
framework viewed along [001]
Idealized cell data:
monoclinic, C2/m, a - 9.1A, b - 17.5A, c - 10.4A, 3 - 124.9°
Coordination sequences and vertex symbols"
T 1 (8,1)
4
11 24
42
63
93
T 2(8,1)
T 3(8,1)
4
4
12
12
Secondary building units:
22
20
37
39
5-1
Composite building units:
roof
Materials with this framework type"
(14)
*Epistilbite
Synthetic epistilbite (5)
64
66
94
90
127
119
118
160
161
164
206
204
214
262
252
245
4.52.5.8.5-8
5.5-5.52-8.102
5"5"5"5~'5"8
127
Epistilbite
Crystal chemical data:
Type Material Data
EPI
ICa~ (n:o),6l [A16SiIsO48]-EPI
monoclinic, C2/m
a - 9.08,~, b - 17.74A, c - 10.25,~, 3 - 124.54°(2)
Framework density:
17.6 T/1000.A 3
Channels:
{[001] 8 3.7 x 4.5 +-+ [100] 8 3.6 x 3.6}**
(The 8-ring along [100] is tilted and has its normal along [101 ].
4.5
4.5
3.7
8-ring viewed along [001]
::
8-ring viewed along [101]
References:
(1) Kerr, I.S. Nature, 202, 589 (1964)
(2) Perrotta, A.J. Mineral. Mag., 36, 480-490 (1967)
(3) Alberti, A., Galli, E. and Vezzalini, G. Z. Kristallogr., 173, 257-265 (1985)
(4) Yang, P. and Armbruster, T. Eur. J. Mineral., 8, 263-271 (1996)
(5) Ghobarkar, H. C~st. Res. Technol., 151-1573 (1984)
128
ERI
P6 flmmc
Framework Type Data
z
X
Y
framework viewed normal to [001 ] (upper right: projection down [001])
Idealized cell data:
hexagonal, P63/mmc, a - 13.1 A, c - 15.2A
Coordination sequences and vertex symbols:
T, (24,1)
4
9
17
30
50
75
98
118
144
185
4.4.4.6.6.8
T 2(12,m)
4
10
20
32
46
64
90
126
164
196
4.8.4.8.6.6
Secondary building units:
6or4
Framework description"
AABAAC sequence of 6-rings
Composite building units:
d6r
can
Materials with this framework type"
• Erionite ~-4~
A1PO- 17 plus compositional variants ~5-7~
Linde T (ERI-OFF structural intermediate) ~8~
LZ_220 ~9)
129
Erionite
Crystal chemical data:
Type Material Data
ERI
I(Ca,Na2)~. ~ K 2 (H~O)2~I [AI~Si~vO~I-ERI
hexagonal, P63/mmc, a - 13.27A, c - 15.05A ~3)
Framework density:
15.7 T/1000A 3
Channels:
2_ [001] 8 3.6 x 5.1"**
3.6
i
3.6
8-ring viewed normal to [001]
References:
(1) Staples, L.W. and Gard, J.A. Mineral. Mag., 32, 261-281 (1959)
(2~ Kawahara, A. and Curien, H. Bull. Soc. fr. Mindral. Cristallogr., 92, 250-256 (1969)
(3) Gard, J.A. and Tait, J.M. Proc. 3rd Int. Conf. Molecular Sieves, pp. 94-99 (1973)
(4) Schlenker, J.L., Pluth, J.J. and Smith, J.V. Acta Crystallogr. B33, 3265-3268 (1977)
(5) Pluth, J.J., Smith, J.V. and Bennett, J.M. Acta C~stallogr., C42, 283-286 (1986)
(6) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Pure Appl. Chem., 58, 1351-1358 (1986)
(7) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Proc. 7th Int. Zeolite Conf., pp. 103-112 (1986)
(8) Breck, D.W. Zeolite Molecular Sieves, p. 173 (1974)
(9) Breck, D.W. and Skeels, G.W.U.S. Patent 4,503,023 (1985)
130
ESV
Framework Type Data
Pnma
z
framework viewed along [01 O]
Idealized cell data:
orthorhombic, Pnma, a - 9.7/k, b - 12.2/k, c - 22.8/k
Coordination sequences and vertex symbols:
T 1(8,1)
T 2(8,1)
T 3(8,1)
T 4(8,1)
T 5(8,1)
T 6(8,1)
4
4
4
4
4
4
10
10
10
10
11
11
Secondary building units:
20
20
21
21
22
20
35
36
36
36
36
37
5-1
Materials with this framework type:
• ERS_7 o-3~
56
58
57
56
56
54
82
82
82
82
78
82
111
109
111
113
110
112
143
144
145
145
148
142
180
186
183
180
184
182
228
230
231
224
225
226
4.5.4.5.6-8
4-4.5.6-6.8
4-4.5.8-6.6
4.4-5-6.6.8
4.6.5.6.5-6
4.5-5.5.6.6
131
ERS-7
Type Material Data
ESV
Crystal chemical data:
IH~.o6Nao.o~l[A15.13Si42.aTO96]-ESV
orthorhombic, Pnma, a - 9.800 ~,, b - 12.412A, c - 22.861A ~2)
Framework density"
17.3 T/1000A 3
Channels:
[010] 8 3.5 x 4.7*
8-ring viewed along [010]
References:
(1) Campbell, B.J., Bellussi, G., Carluccio, L., Perego, (3., Cheetham, A.K., Cox, D.E. and Millini, R. Chem.
Commun., 1725-1726 (1998)
(2) Millini, R., Perego, (3., Carluccio, L., Bellussi, (3., Cox, D.E., Campbell, B.J. and Cheetham, A.K. Proc.
12th Int. Zeolite Conf., I, pp. 541-548 (1999)
(3) Campbell, B.J., Cheetham, A.K., Vogt, T., Carluccio, L., Parker, W.O., Flego, C. and Millini, R. J. Phys.
Chem. B, 105, 1947-1955 (2001)
132
ETR
,, ......~..
framework
Idealized cell data:
P6amc
Framework Type Data
hexagonal, P 6 3 m c ,
a -
4
M a t e r i a l s with this f r a m e w o r k type:
• ECR_34 ~
J
viewed along [001]
20.6A, c - 8.4A
C o o r d i n a t i o n sequences a n d vertex symbols:
T, (12,1)
4
9
18
31
45
63
T 2(12,1)
4
9
17
28
41
57
T 3(12,1)
4
9
17
28
43
62
T 4(12,1)
4
9
16
25
39
58
Secondary building units:
F%
86
80
83
80
111
113
109
107
140
151
138
143
172
189
170
185
210
226
214
220
253
260
255
254
4.4-4.8.84.103
4.4.4.6-8.86
4"4"4"82"6"104
4-4.4-6-6.8
133
ECR-34
Type Material Data
Crystal chemical data:
IHI.2K6.3Na4.4I [Ga,l.6Alo.3Si36.1096]o-ETR
hexagonal, P63mc, a - 21.030 A, c - 8.530 A ('~
F r a m e w o r k density:
14.7 T/1000.,~ ~
Channels:
[001 ] 18 10.1 * +-+ _L [001 ] 8 2.5 x6.0**
...........
18-ring viewed along [001 ]
..............
8-ring viewed normal to [001]
References:
(1) Strohmaier, K. G. and Vaughan, D.E.W.J. Am. Chem. Soc., 125, 16035-16039 (2003)
ETR
134
EUO
Framework Type Data
Creme
\
Z
k-y
f r a m e w o r k viewed along [100]
Idealized cell data"
orthorhombic, C m m e , a - 13.9/k, b - 22.9A, c - 20.6A
Coordination sequences and vertex symbols:
T~(16,1)
T 2(16,1)
T 3(16,1)
T 4(16,1)
T 5(8,m)
T 6(8,m)
T 7(8,m)
T 8(8,m)
T 9(8,m)
T10(8,m)
4
4
4
4
4
4
4
4
4
4
11
12
12
12
12
12
12
12
11
11
Secondary building units:
21
25
23
22
20
20
24
24
23
24
36
41
38
39
31
34
39
36
45
39
59
64
60
59
61
57
60
56
67
68
92
88
89
91
88
92
91
90
88
92
129
122
124
124
120
131
126
127
115
118
167
160
159
160
159
164
161
157
162
156
197
202
194
206
197
202
195
197
218
213
246
256
248
257
248
236
243
236
261
268
1-5-1
Composite building units:
cas
non
Materials with this framework type:
* EU- 1<~,2)
[ B - S i - O ] - E U O (3'4)
TPZ_3 (5~
ZSM_50 (6)
o - F D B D M - Z S M - 5 0 (7)
4.6.5.5.52.10
5.6.5.6.5-6
5.52.5.6.5.6
5.5.5.62.5.10
5.5.5.5.5.62
5.52.5.52.122.*
5.6.5.6.5.62
5.5.5.5.124.,*
4-6.5.5.5.5
4.10.5.5.5.5
135
EU-1
Type Material Data
EUO
Crystal chemical data:
INan (H20)261 [AlnSil,2_nO224]-EUO ,on < 19, typically n-~ 3.6
orthorhombic, Cmme, a - 13.695A, b - 22.326A, c - 2 0 . 1 7 8 ' (2)
F r a m e w o r k density:
18.2 T/IOOOA 3
Channels:
[100] 10 4.1 x 5.4* with large side pockets
1O-ring viewed along [100]
References:
(1) Casci, J.L., Lowe, B.M. and Whittam, T.V.U.S. Patent 4,537, 754 (1985)
(2) Briscoe, N.A., Johnson, D.W., Shannon, M.D., Kokotailo, G.T. and McCusker, L.B. Zeolites, 8, 74-76
(1988)
(3) Grtinewald-Luke, A., Marler, B., Hochgrafe, M. and Gies, H. J. Mater. Chem., 9, 2529-2536 (1999)
(4) Millini, R., Carluccio, L.C., Carati, A. and Parker, W.O. Microporous Mesoporous Mat., 46, 191-201
(2001)
(5) Sumitani, K., Sakai, T., Yamasaki, Y. and Onodera, T. E. Patent EP 51318 (1982)
(6) Rohrbaugh, W.J. private communication
(7) Arranz, M., Perez-Pariente, J., Wright, P.A., Slawin, A.M.Z., Blasco, T., Gomez-Hortiguela, L. and Cora,
F. Chem. Mater., 17, 4374-4385 (2005)
136
EZT
Framework Type Data
,.
"..........
............
'....
•................ ~ ' , ~
" ..
.d~
Imma
:~. .......
-~! "
~
q~
z
Y
framework viewed along [100]
Idealized cell data"
orthorhombic, Imma, a - 1 0 . 2 ' , b - 12.6A, c - 21.7A
Coordination sequences and vertex symbols:
T 1 (16,1)
T 2(8,m..)
T 3(8,m..)
T 4(8,m..)
T 5(8,2..)
4
4
4
4
4
10
10
10
9
9
Secondary building units:
19
19
20
17
18
31
31
32
30
29
bph
Q
Materials with this framework type:
• EMM_3 °)
72
73
71
73
72
see Compendium
Composite building units:
lau
49
51
48
49
48
97
93
98
97
94
124
123
126
120
124
155
157
155
154
156
194
195
192
199
192
236
236
237
237
236
278
274
280
273
278
4.4.6.6.62.8
4.62.4.62.62.1218
4.6.4.6.62.8
4.6.4-6-4.1226
4.4.4.8.62.62
137
EMM-3
Crystal chemical data:
EZT
Type Material Data
[A124P24096]-EZT
monoclinic, I2/m
a - 10.3132 A, b - 12.6975 * , c - 21.8660 A, oL- 89.656 °(j)
F r a m e w o r k density:
16.8 T/1000A ~
Channels:
[ 100] 12 6.5 x 7.4"
:
:.~
.
~
:
12-ring viewed along [100]
References:
(1)
Afeworki, M., Dorset, D.L., Kennedy, G.J. and Strohmaier, K.G. Chem. Mater., 18, 1697-1704 (2006)
138
FAR
i
P6Jmmc
Framework Type Data
'i
!
z
xJ
............
vL y
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
o
o
hexagonal, P63/mmc, a - 12.6A, c - 35.7A
Coordination sequences and vertex symbolsT 1 (24,1)
T 2(24,1)
T 3(24,1)
T 4(12,m..)
4
4
4
4
10
10
10
10
20
20
20
20
34
34
34
34
52
53
53
54
74
76
76
78
101
102
102
104
133
132
132
134
169
166
166
168
208
206
205
208
251
251
248
252
Secondary building units:
6
Framework description:
A B C A B A B A C B A C A C sequence of 6-rings
Composite building units:
Cat/
lio
sod
~
Materials with this framework type:
*Farneseite <~
J
299
299
294
298
.4.4.6.6-6.6
4-4-6.6.6.6
4.6.4.6-6.6
4.6.4.6.6.6
139
Farneseite
Type Material Data
Crystal chemical data:
[(Na, K)46Ca,o (H20)6 (SO4),21 [Si~2A1420,j-FAR
hexagonal, P 6 J m , a - 12.8784A, c - 37.0078A (~
Framework density:
15.8 T/1000,~ 3
Channels:
apertures formed by 6-rings only
FAR
References:
(1) C~.mara,F., Bellatreccia, F., Della Ventura, G. and Mottana, A. Eur. J. Mineral., 17, 839-846 (2005)
140
FAU
m
Framework Type Data
Fd3m
~
!
z
!
iiiii. . . . . . .
i
......
"!,,i
.......:j
..........;:
.-'S+~,///'/"'"
"<"
,.d/<<+e/<'+'>''+
z
framework viewed along [111] (upper right: projection down [110])
Idealized cell data:
cubic, Fd-3m (origin choice 2), a - 24.3/k
Coordination sequences and vertex symbols:
T~ (192,1)
4
9
16
25
37
53
73
96
120
145
Secondary building units:
6-6 or 6-2 or 6 or 4-2 or 1-4-1 or 4
Composite building units:
d6r
sod
4.4.4.6-6.12
Materials with this framework type:
,
(12)
Faujasite '
[A1-Ge-O]-FAU ~3'4)
[Co-A1-P-O]-FAU ~5~
[Ga-A1-Si-O]-FAU ~6~
[ G a - G e - O ] - F A U ~3~
[ G a - S i - O ] - F A U ~7~
Beryllophosphate X ~8'9~
D e h y d r a t e d N a - X ~°~
D e h y d r a t e d U S - Y ~ll~
LZ_210 ~12~
Li_LSX °3~
SAPO_37 ~14~
Siliceous Na-Y ~s
Zeolite X (Linde X) ~6'~7~
Zeolite Y (Linde y)~18,19)
Zincophosphate X (9)
E M T - F A U structural intermediates:
CSZ- 1 (20)
ECR_30 (21)
ZSM_20 ~22~
ZSM_3 (23~
141
Faujasite
Type Material Data
Crystal chemical data:
I(Ca,MgNa2)29(H O 4ol [A1585i~340384]-FAU
cubic, Fd-3m , a - 24.74A ~2~
Framework density:
12.7 T/1000A 3
Channels:
<1 1 1> 12 7.4 x 7.4***
FAU
12-ring viewed along <111>
References:
(1) Bergerhoff, G., Baur, W.H. and Nowacki, W. N. Jb. Miner. Mh., 193-200 (1958)
(2) Baur, W.H. Am. Mineral., 49, 697-704 (1964)
(3) Barrer, R.M., Baynham, J.W., Bultitude, F.W. and Meier, W.M.J. Chem. Soc., 195-208 (1959)
(4) Johnson, G.M., Lee, Y.J., Tripathi, A. and Parise, J.B. Microporous Mesoporous Mat., 31, 195-204 (1999)
(5) Feng, P., Bu, X. and Stucky, G.D. Nature, 388, 735-741 (1997)
(6) Occelli, M.L., Schweizer, A.E., Fild, C., Schwering, G., Eckert, H. and Auroux, A. J. Catal., 192, 119-127
(2000)
(7) Occelli, M.L., Schwering, G., Fild, C., Eckert, H., Auroux, A. and Iyer, P.S. Microporous Mesoporous
Mat., 34, 15-22 (2000)
(8) Harrison, W.T.A., Gier, T.E., Moran, K.L., Nicol, J.M., Eckert, H. and Stucky, G.D. Chem. Mater., 3, 2729 (1991)
(9) Gier, T.E. and Stucky, G.D. Zeolites, 12, 770-775 (1992)
(10) Olson, D.H. Zeolites, 15, 439-443 (1995)
(11) Parise, J.B., Corbin, D.R., Abrams, L. and Cox, D.E. Acta Crystallogr., C40, 1493-1497 (1984)
(12) Breck, D.W. and Skeels, G.W.U.S. Patent 4,503,023 (1985)
(13) Feuerstein, M. and Lobo, R.F. Chem. Mater., 2197-2204 (1998)
(14) Lok, B.M., Messina, C.A., Patton, R.L., Gajek, R.T., Cannan, T.R. and Flanigen, E.M.J. Am. Chem. Soc.,
106, 6092-6093 (1984)
(15) Hriljac, J.J., Eddy, M.M., Cheetham, A.K., Donohue, J.A. and Ray, G.J.J. Solid State Chem., 106, 66-72
(1993)
(16) Milton, R.M.U.S. Patent 2,882,244 (1959)
(17) Olson, D.H.J. Phys. Chem., 74, 2758-2764 (1970)
(18) Breck, D.W.U.S. Patent 3,130,007 (1964)
(19) Costenoble, M.L., Mortier, W.J. and Uytterhoeven, J.B.J. Chem. Soc., Faraday Trans. I, 72, 1877-1883
(1976)
(20) Barrett, M.G. and Vaughan, D.E.W. UK Patent GB 2,076,793 (1981)
(21) Vaughan, D.E.W.E. Patent 0,351,461 (1989)
(22) Newsam, J.M., Treacy, M.M.J., Vaughan, D.E.W., Strohmaier, K.G. and Mortier, W.J. Chem. Commun.,
493-495 (1989)
(23) Kokotailo, G.T. and Ciric, J. Adv. Chem. Set., 101, 109-121 (1971)
142
FER
Framework Type Data
Immm
,,
iif
U
Y
x
framework viewed along [001]
Idealized cell data:
orthorhombic, Immm, a - 19.0J,, b - 14.3Ji, c - 7.5it
Coordination sequences and vertex symbols:
T~(16,1)
T 2(8,m)
T 3(8,m)
T 4(4,2mm)
4
4
4
4
12
12
12
12
Secondary building units:
21
27
20
23
39
43
35
40
66
62
67
66
95
97
104
96
126
139
121
131
169
172
157
164
221
206
223
214
5.5.5-52.5.8
5.8.5.8.52.6
5-52.5.52.102.122
5.5.5.5.52.6
265
264
276
272
5-1
Composite building units:
yer
Materials with this framework type:
*Ferrierite <~)
[ B - S i - O ] - F E R ~2)
[ G a - S i - O ] - F E R ~3)
[ S i - O ] - F E R ~4'5~
FU_9 ~6)
ISI_6 °~
Monoclinic ferrierite <8~
NU_23 ~9)
Sr_D ~m~
ZSM_35 ~11)
143
Type Material Data
Ferrierite
Crystal chemical data:
FER
[Mg Na (n o),81 [A16Si30072]-FER
orthorhombic, Immm, a - 19.156A, b - 14.127A, c - 7.489A (~)
F r a m e w o r k density:
17.8 T / 1 0 0 0 A 3
Channels:
[001] 10 4.2 x 5.4* +-+ [010] 8 3.5 x 4.8*
-...
o
' 3.5
1O-ring viewed along [001 ]
8-ring viewed along [010]
References:
Vaughan, P.A. Acta Crystallogr., 21,983-990 (1966)
Perego, G., Bellussi, G., Millini, R., Alberti, A. and Zanardi, S. Microporous Mesoporous Mat., 56, 193202 (2002)
(3) Jacob, N.E., Joshi, P.N., Shaikh, A.A. and Shiralkar, V.P. Zeolites, 13, 430-434 (1993)
(4) Gies, H. and Gunawardane, R.P. Zeolites, 7, 442-445 (1987)
(5) Morris, R.E., Weigel, S.J., Henson, N.J., Bull, L.M., Janicke, M.T., Chmelka, B.F. and Cheetham, A.K.J.
Am. Chem. Soc., 116, 11849-11855 (1994)
(6) Seddon, D. and Whittam, T.V.E. Patent B-55,529 (1985)
(7) Morimoto, N., Takatsu, K. and Sugimoto, M. U.S. Patent 4,578,259 (1986)
(8) Gramlich-Meier, R., Gramlich, V. and Meier, W.M. Am. Mineral., 70, 619-623 (1985)
(9) Whittam, T.V.E. Patent A-103,981 (1984)
(10) Barrer, R.M. and Marshall, D.J.J. Chem. Soc., 2296-2305 (1964)
(11) Plank, C.J., Rosinski, E.J. and Rubin, M.K.U.S. Patent 4,016,245 (1977)
(1)
(2)
144
FRA
m
Framework Type Data
P3ml
Z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
trigonal, P - 3 m l , a - 12.7A, c - 25.3A
Coordination sequences and vertex symbols:
T 1 (12,1)
T 2(12,1)
T 3(12,1)
T4(12,1)
T 5(6,2)
T 6(6,2)
4
4
4
4
4
4
10
10
10
10
10
10
20
20
20
20
20
20
34
34
34
34
34
34
52
52
52
53
52
54
74
74
74
76
74
78
100
101
101
102
100
104
130
133
133
132
130
134
165
168
168
166
164
168
205
206
206
206
202
208
Secondary building units:
6or4
Framework description:
A B C A B A C A B C sequence of 6-rings
Composite building units:
sod
call
los
................. . ....
Materials with this framework type:
• . ,
(12)
*Franzlnlte '
4.4.6.6.6.6
4.4.6.6.6.6
4-6-4.6.6-6
4.4.6.6.6.6
4.4-6.6-6.6
4.4-6.6-6.6
145
Franzinite
Type Material Data
Crystal chemical data:
I(Na,K)3o Calo (H20)2 (S04)~ol [A13oSi3oO,2o]-FRA
trigonal, P321, a = 12.916A, c - 26.543A ~)
Framework density:
15.6 T / 1 0 0 0 A 3
Channels:
apertures formed by 6-rings only
References:
(1) Ballirano, P., Bonaccorsi, E., Maras, A. and Merlino, S. Can. Mineral., 38, 657-668 (2000)
(2) Ballirano, P. and Maras, A. Powder Diffraction, 16, 216-219 (2001)
FRA
146
GIS
14lamd
Framework Type Data
z
framework viewed along [100]
Idealized cell data:
tetragonal, I41/amd (origin choice 2), a - 9.8/k, c - 10.2A
Coordination sequences and vertex symbols:
T, (16,2)
4
9
18
32
Secondary building units:
8or4
Composite building units:
dcc
gis
double
crankshaft chain
48
67
92
120
150
185
4.4.4.82.8.8
t
Materials with this framework type:
*Gismondine ~
[A1-Co-P-O]-GIS ~2~
[A1-Ge-O]-GIS (3'4)
[A1-P-O]-GIS ~5)
[Be-P-O]-GIS (6)
[Co-A1-P-O]-GIS (7~
[Co-Ga-P-O]-GIS (8~
[Co-P-O]-GIS (9~
[Ga-Si-O]-GIS (1°~
[Mg-A1-P-O]-GIS (7~
[Zn-A1-As-O]-GIS (1~
[Zn-Co-B-P-O]-GIS (~2~
[Zn-Ga-As-O]-GIS (~1~
[Zn-Ga-P-O]-GIS (~3~
[(C3H~2N2)4[[BesP8032]-GIS (~4)
I(C3H12N2)4[[Zn8PsO32] -GIS(~5~
[(NH4)4[[Zn4B4P8032]-GIS (16)
[Cs41[Zn4B4P8032]-GIS (16)
IRb4l[zn4B4p8 O32]-G IS~6'
Amicite (~7)
(17 19)
Garronite '
Gobbinsite ~2°)
High-silica Na-P ~2~
Low-silica Na-P (MAP) ~22~
MAPO_43 (23)
MAPSO_43 (24,25)
Na-P 1(26)
Na_P2 (27)
SAPO_43 (28)
Synthetic Ca-garronite(29)
Synthetic amicite(3°~
Synthetic garronite(3°~
Synthetic gobbinsite ~3°~
TMA-gismondine(3~
147
Gismondine
Crystal chemical data"
Type Material Data
GIS
ICa4(H:O),3 [AlsSisO32]-GIS
monoclinic, P2,/a
a - 9.843A, b - 10.023,~, c - 10.616.A, ~ - 92.417 °¢~)
(Relationship to unit cell of Framework Type: a ' = a, b ' = b, c'= c)
Framework density"
15.3 T/1000A 3
Channels:
{[100] 8 3.1 x 4.5 +-+ [010] 8 2.8 x 4.8}***
(variable due to considerable flexibility of framework)
see Appendix A for 8-rings viewed along [100] and [010]
References:
(1) Fischer, K. and Schramm, V. Adv. Chem. Ser., 101, 250-258 (1971)
(2) Feng, P., Bu, X. and Stucky, G.D. Nature, 388, 735-741 (1997)
(3) Johnson, G.M., Tripathi, A. and Parise, J.B. Chem. Mater., 11, 10+ (1999)
(4) Tripathi, A., Parise, J.B., Kim, S.J., Lee, Y., Johnson, G.M. and Uh, Y.S. Chem. Mater., 12, 3760-3769
(2000)
(5) Paillaud, J.L., Marler, B. and Kessler, H. Chem. Commun., 1293-1294 (1996)
(6) Zhang, H., Chen, M., Shi, Z., Bu, X., Zhou, Y., Xu, X. and Zhao, D. Chem. Mater., 13, 2042-2048 (2001)
(7) Feng, P., Bu, X., Gier, T.E. and Stucky, G.D. Microporous Mesoporous Mat., 23, 221-229 (1998)
(8) Cowley, A.R. and Chippindale, A.M. Chem. Commun., 673-674 (1996)
(9) Yuan, H.M., Chen, J.S., Zhu, G.S.,Li, J.Y., Yu, J.H., Yang, G.D. and Xu, R. Inorg. Chem., 39, 1476-1479
(2000)
(10) Cho, H.H., Kim, S.H., Kim, Y.G., Kim, Y.C., Koller, H., Camblor, M.A. and Hong, S.B. Chem. Mater., 12,
2292-2300 (2000)
(11) Feng, P., Zhang, T. and Bu, X. J. Am. Chem. Soc., 123, 8608-8609 (2001)
(12) Schafer, G., Borrmann, H. and Kniep, R. Microporous Mesoporous Mat., 41, 161-167 (2000)
(13) Chippindale, A.M., Cowley, A.R. and Peacock, K.J. Microporous Mesoporous Mat., 24, 133-141 (1998)
(14) Harrison, W.T.A. Acta Crystallogr., C57, 891-892 (2001)
(15) Harrison, W.T.A. International Journal of Inorganic Materials, 3, 179-182 (2001)
(16) Kniep, R., Sch~ifer, G., Engelhardt, H. and Boy, I. Angew. Chem. Int. Ed., 38, 3642-3644 (1999)
(17) Alberti, A. and Vezzalini, G. Acta C~stallogr., B35, 2866-2869 (1979)
(18) Artioli, G. Am. Mineral., 77, 189-196 (1992)
(19) Artioli, G. and Marchi, M. Powder Diffraction, 14, 190-194 (1999)
(20) McCusker, L.B., Baerlocher, Ch. and Nawaz, R. Z. Kristallogr., 171, 281-289 (1985)
(21) H~tkansson, U., F~ilth, L. and Hansen, S. Acta Crystallogr., C46, 1363-1364 (1990)
(22) Albert, B.R., Cheetham, A.K., Stuart, J.A. and Adams, C.J." Microporous Mesoporous Mat., 21, 133-142
(1998)
(23) Pluth, J.J., Smith, J.V. and Bennett, J.M.J. Am. Chem. Soc., 111, 1692-1698 (1989)
(24) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Pure Appl. Chem., 58, 1351-1358 (1986)
(25) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Proc. 7th Int. Zeolite Conf., pp. 103-112 (1986)
(26) Baerlocher, Ch. and Meier, W.M.Z. Kristallogr., 135, 339-354 (1972)
(27) Hansen, S., Hfikansson, U. and F~ilth, L. Acta Crystallogr., C46, 1361-1362 (1990)
(28) Helliwell, M., Kaucic, V., Cheetham, G.M.T., Harding, M.M., Kariuki, B.M. and Rizkallah, P.J. Acta
Crystallogr., B49, 413-420 (1993)
(29) Schropfer, L and Joswig, W. Eur. J. Mineral., 9, 53-65 (1997)
(30) Ghobarkar, H. and Schaef, O. Mater. Res. Bull., 34, 517-525 (1999)
(31) Baerlocher, Ch. and Meier, W.M. Helv. Chim. Acta, 53, 1285-1293 (1970)
148
GIU
P6Jmmc
Framework Type Data
)
Z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
hexagonal, P63/mmc, a - 12.6A, c - 4 1 . 0 '
Coordination sequences and vertex symbols"
T 1(24,1)
T 2(24,1)
T 3(24,1)
T 4(12,m..)
T 5(12,.2.)
4
4
4
4
4
10
10
10
10
10
20
20
20
20
20
34
34
34
34
34
53
53
54
54
52
76
76
78
78
74
102
102
104
104
102
132
132
134
134
136
167
166
168
168
172
209
206
209
208
208
255
251
254
252
248
301
299
300
298
298
Secondary building units"
6or4
Framework description:
A B A B A B A C B A B A B A B C sequence of 6-rings
Composite building units:
can
sod
Materials with this framework type:
*Giuseppettite ~
4.4.6.6.6.6
4.6.4.6.6.6
4.6.4.6.6.6
4.6.4.6.6.6
4-4.6.6.6-6
149
Giuseppettite
Crystal chemical data:
Type Material Data
lNa42K,~Ca~ (SO4),0C12) (H~O)sI [Si48A1480~92]-GIU
trigonal, P31 c, a 12.856A, c = 42.256A (~)
-
Framework density:
15.9 T/1000A 3
Channels:
apertures formed by 6-rings only
References:
(1) Bonaccorsi, E. Microporous Mesoporous Mat., 73, 129-136 (2004)
GIU
150
GME
P6Jmmc
Framework Type Data
!
z
L.y
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
hexagonal, P63/mmc, a - 13.7/k, c - 9.9A
Coordination sequences and vertex symbols:
T~ (24,1)
4
9
17
29
45
65
89
116
144
175
Secondary building units:
12 or 6-6 or 8 or 6 or 4-2 or 4
Framework description:
A A B B sequence of 6-rings
Composite building units:
dcc
d6r
double
crankshaft chain
Materials with this framework type:
*Gmelinite <1~
[ B e - P - O ] - G M E ~2~
K-rich gmelinite <3~
Synthetic fault-free gmelinite <4~
gme
4.4.4.8.6.8
151
Crystal chemical data:
GME
Type Material Data
Gmelinite
I(Ca,Na~)4 (H:O)~4I[A18Si,6048]-GME
hexagonal, P63/mmc, a - 13.75,~, c - 10.05A (~
F r a m e w o r k density"
14.6 T/1000A 3
Channels:
[001] 12 7.0 x 7.0* +-+ A_ [001 ] 8 3.6 x 3.9**
~..
.~
3.9
12-ring viewed along [001]
8-ring viewed normal to [001]
References:
(1) Fischer, K. N. Jb. Miner. Mh., 1-13 (1966)
(2) Zhang, H., Chen, M., Shi, Z., Bu, X., Zhou, Y., Xu, X. and Zhao, D. Chem. Mater., 13, 2042-2048 (2001)
(3) Vezzalini, G., Quartieri, S. and Passaglia, E. N. Jb. Miner. Mh., 504-516 (1990)
(4) Daniels, R.H., Kerr, G.T. and Rollmann, L.D.J. Am. Chem. Soc., 100, 3097-3100 (1978)
152
GON
Framework Type Data
Cmmm
..........ZIZ
X
framework viewed along [001]
Idealized cell data:
orthorhombic, Cmmm, a - 16.9A, b - 20.4A, c - 5.3/k
Coordination sequences and vertex symbols:
T, (8,m)
T 2(8,m)
4
4
4
4
T 3 (8,m)
T 4(8,m)
12
12
11
11
Secondary building units:
21
25
22
22
39
38
38
38
5-3
Composite building units:
mtw
cas
Materials with this framework type:
• GUS_I °)
63
57
58
63
85
86
86
91
117
119
121
115
154
158
156
147
192
194
191
195
242
233
229
244
5.6.5.6.52.6
5.6.5.6.6.126
4.62.5.6.5.6
4.62.5.6.5.6
153
Type Material Data
GUS-1
GON
Crystal chemical data:
[Si32064]-GON
orthorhombic, C222, a - 16.421A, b - 20.054A, c - 5.046A ~
F r a m e w o r k density"
19.3 T/1000A 3
Channels:
[001] 12 5.4 x 6.8*
•
6.8
12-ring viewed along [001]
i
8-ring viewed along [001]
References:
(1) P16vert, J., Kubota, Y., Honda, T., Okubo, T. and Sugi, Y. Chem. Commun., 2363-2364 (2000)
154
GOO
Framework Type Data
C222.,
z
x~~--~ y
Idealized cell data:
orthorhombic, C2221, a - 8.7/i,, b -
11.O/k, c - 17.5/k
Coordination sequences and vertex symbols"
T,(8,1)
T 2 (8,1)
T 3(8,1)
T 4(4,2)
T 5 (4,2)
4
4
4
4
4
9
10
9
10
10
Secondary building units:
19
20
19
20
20
36
36
36
34
34
80
77
76
82
78
see Compendium
Materials with this framework type:
*Goosecreekite(1)
56
55
56
58
52
102
108
106
102
110
132
140
142
136
140
180
174
172
176
176
220
219
217
220
212
4"4"4"85"62"82
4"4"6"83"63"82
4"4"4"82"6-82
4"4"64"84"82"82
4.4.82.106"83"83
155
Goosecreekite
Crystal chemical data"
GO0
Type Material Data
ICa~ (H20)10l [A14Si12032]-GOO
monoclinic, P21
a - 7 . 4 0 1 ' , b - 17.439A, c - 7.293A, ~3- 105.44 °~
(Relationship to unit cell of Framework Type:
a' = a/(2cos(3'/2)), b' = c, c' = a/(2cos(~'/2))
or, as vectors, a ' = (a + b)/2, b ' = e, e ' = (a - b)/2
F r a m e w o r k density:
17.6 T/1000.~ 3
Channels:
[100] 8 2.8 x 4.0* +-+ [010] 8 2.7 x 4.1" ~ [001] 8 2.9 x 4.7*
....
9.
8-ring viewed along [ 1001
8-ring viewed along [010]
i
8-ring viewed along [001]
References:
(1) Rouse, R.C. and Peacor, D.R. Am. Mineral., 71, 1494-1501 (1986)
7
156
HEU
Framework Type Data
C21m
:~,..
•
~
a~
y
framework viewed along [001]
Idealized cell data:
monoclinic, C2/m, a - 17.5/k, b - 17.6A, c - 7.4A, 3 - 116.1 o
Coordination sequences and vertex symbols:
T, (8,1)
T 2(8,1)
T 3(8,1)
T 4(8,1)
T 5(4,2)
4
4
4
4
4
10
11
10
11
12
Secondary building units:
20
23
19
21
18
34
39
37
35
34
62
55
58
61
62
85
82
84
89
88
104
127
109
111
110
148
158
149
146
132
201
178
201
194
196
241
221
236
243
254
4-4=1
Composite building units:
bre
Materials with this framework type:
*Heulandite ~'2~
Clinoptilolite(3)
Dehyd. Ca,NH4-Heulandite ~4)
Heulandite-Ba ~5~
LZ_219 ~6)
4.5.4.5.5.8
4.8.5.8-5.8
4.5.4.8.5.5
4.5.5.5.5.8
5.5.52.52.10.10
157
Type Material Data
Heulandite
Crystal chemical data:
HEU
ICa4 (H20)241 [AlaSi28072]-HEU
monoclinic, Cm
a - 17.718A, b - 17.897A, c - 7.428A, ~3- 116.42 ° (2~
Framework density:
17.1 T/1000A 3
Channels:
{[001] 10 3.1 x 7.5* + 8 3.6 x 4.6*} ~ [100] 8 2.8x 4.7*
(variable due to considerable flexibility of framework)
8-ring, also along [001]
lO-ring viewed along [001]
8-ring viewed along [100]
References:
(1) Merkle, A.B. and Slaughter, M. Am. Mineral., 52, 273-276 (1967)
(2) Alberti, A. Tschermaks Min. Petr. Mitt., 18, 129-146 (1972)
(3) Koyama, K. and Takeuchi, Y. Z. Kristallogr., 145, 216-239 (1977)
(4) Mortier, W.J. and Pearce, J.R. Am. Mineral., 66, 309-314 (1981)
(5) Larsen, A.O., Nordrum, F.S., Dobelin, N., Armbruster, T., Petersen, O.V. and Erambert, M. Eur. J.
Mineral., 17, 143-153 (2005)
(6) Breck, D.W. and Skeels, G.W.U.S. Patent 4,503,023 (1985)
158
IFR
Framework Type Data
C21m
i~'~ i
iiii~
1
't~~~~~I
X
framework viewed along [001]
Idealized cell data:
monoclinic, C2/m, a - 18.6/k, b - 13.4/k, c - 7.6/k, 3 - 102-3°
Coordination sequences and vertex symbols:
T, (8,1)
T 2(8,1)
T 3(8,1)
4
4
4
4
T 4 (8,1)
11
10
10
10
Secondary building units:
20
18
19
21
32
31
32
35
6-2
Composite building units:
bea
lau
Materials with this framework type:
• ITQ_4 <1,2)
M C M _ 5 8 (3)
SSZ_42 ~4'5)
53
52
53
50
77
77
78
74
100
103
102
105
135
127
126
133
166
159
162
165
199
210
209
206
4.62. 5.6.6-12 3
4.5.4.6.5-62
4-6.4-6.5.62
4-4"5" 125.6.62
159
ITQ-4
Type Material Data
Crystal chemical data:
IFR
[Si32064]-IFR
monoclinic, I2/m
a - 18.652A, b - 13.496A, c - 7.631A, 3 - 101.98 ° ~1)
(Relationship to unit cell of Framework Type:
as vectors, a' = a + e, b ' = b, e ' = -e)
Framework density:
17 T/1000.~ 3
Channels:
[001] 12 6.2 x 7.2*
•
//7.2
12-ring viewed along [001 ]
References:
(1) Barrett, P.A., Camblor, M.A., Corma, A., Jones, R.H. and Villaescusa, L.A. Chem. Mater., 9, 1713-1715
(1997)
(2) Barrett, P.A., Camblor, M.A., Corma, A., Jones, R.H. and Villaescusa, L.A.J. Phys. Chem. B, 102, 41474155 (1998)
(3) Valyocsik, E.W. WOP 9511196 (1995)
(4) Chen, C.Y., Finger, L.W., Medrud, R.C., Crozier, P.A., Chan, I.Y., Harris, T.V. and Zones, S.I. Chem.
Commun., 1775-1776 (1997)
(5) Chen, C.Y., Finger, L.W., Medrud, R.C., Kibby, C.L., Crozier, P.A., Chan, I.Y., Harris, T.V., Beck, L.W.
and Zones, S.I. Chem. Eur. Journal, 4, 1312-1323 (1998)
160
IHW
Framework Type Data
........................
.
..,,.
.
Cmce
.........................
X
Z
y
f r a m e w o r k viewed along [100]
Idealized cell data:
orthorhombic, C m c e , a - 13.7A, b - 24.1A, c - 18.3A
Coordination sequences and vertex symbols:
Tl(16,1 )
T2(16,1)
T3(16,1 )
T4(16,1 )
T5(16,1)
T6(8,m.. )
T7(8,m.. )
Ts(8,m.. )
T9(8,m.. )
4
4
4
4
4
4
4
4
4
11
12
12
12
12
12
12
12
12
Secondary building units:
24
23
22
24
25
22
24
22
24
41
40
40
41
40
37
38
37
36
69
67
62
65
63
65
62
65
62
95
96
96
94
94
95
97
99
95
122
130
127
129
134
129
137
128
132
see C o m p e n d i u m
Composite building units:
cas
non
Materials with this framework type:
• ITQ_32 ~)
ton
165
161
166
171
177
170
168
164
169
221
208
213
216
208
212
211
210
204
276
273
258
264
258
259
260
262
251
323
329
320
322
324
310
312
319
326
374
373
381
382
393
397
389
383
399
4.8-5.5.5.5
5.5.5.5.5.8
5.5.5.5.5.6
5.5.5.62.5.8
5.6.52.8.6.62
5.5.5.5.5.62
5.5.5.5.12.*
5.5.5.5.5.62
5.5.5.5.126.*
161
ITQ-32
IHW
Type Material Data
Crystal chemical data"
[Si1120224]-IHW
orthorhombic, Cmce, a - 13.6988A, b - 24.0665A, c - 18.1968A ~
F r a m e w o r k density:
18.7 T/1000A 3
Channels:
[100] 8 3.5 x 4.3**
(There are 12-ring connections between the channels along [ 100] but
there is no continuous 12-ring channel.)
~
,.~ ~
..~:
.::
..~ 3 . 5
.
:,
.~
8-ring viewed along [100]
References:
(1) Cantin, A.,Corma, A.,Leiva, S.,Rey, F.,Rius, J. andValencia, S.J. Am. Chem. Soc.,127, 11560-11561
(2005)
162
IMF
Framework Type Data
Cmcm
Y
f r a m e w o r k viewed along [100]
Idealized cell data"
orthorhombic, C m c m , a - 14.3/k, b - 56.8A, c - 20.3A
Coordination sequences and vertex symbols:
see Appendix A for a list of the coordination sequences and vertex symbols for the 24 T-atoms
Secondary building units"
5-1
Composite building units:
mor
mtt
Materials with this framework type"
• IM_5 (~)
ats
stf
feE
163
Type Material Data
IM-5
IMF
Crystal chemical data:
[Si2880576]-IMF
orthorhombic, Cmcm, a - 14.2088A, b - 57.2368A, c - 19.9940A ~
Framework density:
17.7 T/1000A 3
Channels:
{[001] 10 5.5 x 5.6 ~ [100] 10 5.3 x 5.4}** +-+ {[010] 10 5.3 x 5.9}
{[001] 10 4.8 x 5.4 +--+[100] 10 5.1 x 5.3}**
(There is central 2D channel system (above: left) connected through
10-rings along [010] (above: after second ~ ) to another 2D channel
system (above: after third +-+) on either side. There is no further
connection along [010].)
5.4 . . . . . . . . ."\. . .
1O-ring (center) viewed along [001 ]
1O-ring (center) viewed along [100]
1O-ring viewed along [01 O]
1O-ring (side) viewed along [001]
1O-ring (side) viewed along [100]
References:
(1) Baerlocher, Ch., Gramm, F., Masstiger, L., McCusker, L.B., He, Z., Hovm611er, S. and Zou, X. Science,
315, 1113-1116 (2007)
164
ISV
P4Jmmc
Framework Type Data
Z
framework viewed along [100]
Idealized cell data:
tetragonal, P42/mmc, a - 12.9A, c - 25.7A
Coordination sequences and vertex symbols:
T, (16,1)
T 2(16,1)
T 3(16,1)
T 4(8,m)
T 5(8,m)
4
4
4
4
4
12
9
9
11
11
Secondary building units:
17
18
18
20
20
30
32
32
28
28
48
50
50
42
41
72
71
72
74
70
99
96
97
110
105
6-2
Composite building units"
d4r
mo r
Materials with this framework type:
*ITQ_7 ~
[ G e - S i - O ] - I S Y 2~
](C 15H29N)4F41[ S i640 128]- I S V (3)
[BCHPI[SixAlyGezO128]-ISV ~4)
mtw
128
129
128
132
131
160
167
167
150
154
199
200
203
195
188
5.5.52.125.6-6
4"5"4.6.4" 127
4"5"4"6"4" 124
4.52.5.6.5-6
4.52.5.6.5.6
165
ITQ-7
ISV
Type Material Data
Crystal chemical data:
[Si64O12J-ISV
tetragonal, P4Jmmc, a - 12.85 3 A, c - 25.214A (~
Framework density:
15.4 T/1000A 3
Channels:
<100> 12 6.1 x 6.5** ~ [001] 12 5.9 x 6.6*
"5
6.5
12-ring viewed along <lO0>
5.9
"~
i
12-ring viewed along [001]
References:
(1)
(2)
(3)
(4)
Villaescusa, L.A., Barrett, P.A. and Camblor, M.A. Angew. Chem., Int. Ed., 38, 1997-2000 (1999)
Blasco, T., Corma, A., DiazCabanas, M.J., Rey, F., VidalMoya, J.A. and ZicovichWilson, C.M.J. Phys.
Chem. B, 106, 2634-2642 (2002)
Song, J.Q., Marler, B. and Gies, H. Compt. Rend. Chimie, 8, 341-352 (2005)
Leiva, S., Sabater, M.J., Valencia, S., Sastre, G., Fornes, V., Rey, F. and Corma, A. Compt. Rend. Chimie,
8, 369-378 (2005)
166
ITE
Framework Type Data
Cmcm
~
Y
x
framework viewed along [001]
Idealized cell data"
orthorhombic, C m c m , a - 20.8A, b - 9.8A, c - 20.0A
Coordination sequences and vertex symbols:
T~ (16,1)
T~(16,1)
T 3(16,1)
T 4(16,1)
4
4
4
4
11
10
10
10
Secondary building units:
21
21
19
18
34
36
31
31
53
54
50
55
78
77
82
77
108
102
107
105
4
Composite building units:
rth
Materials with this framework type:
• ITQ_3 <1~
Mu_14 ~2~
SSZ-36 ( I T E - R T H structural intermediate) ~3~
138
135
132
136
168
181
168
166
211
217
209
216
4-6-5.6-5-8
4.4.5.8-5.8
4.5.4.6.5-5
4.5.4.8.5.5
167
ITE
Type Material Data
ITQ-3
Crystal chemical data:
[Si64012s]-ITE
orthorhombic, Cmcm, a - 20.622A, b - 9.724A, c - 19.623A ~)
Framework density:
16.3 T/1000A 3
Channels:
[010] 8 3.8 x 4.3* ~ [001] 8 2.7 x 5.8*
2.7,
8-ring viewed along [010]
8-ring viewed along [001]
References:
(1) Camblor, M.A., Corma, A., Lighffoot, P., Villaescusa, L.A. and Wright, P.A. Angew. Chem., Int. Ed., 36,
2659-2661 (1997)
(2) Valtchev, V., Paillaud, J.L., Lefebvre, T., LeNouen, D. and Kessler, H. Microporous Mesoporous Mat., 38,
177-185 (2000)
(3) Wagner, P., Nakagawa, Y., Lee, G.S., Davis, M.E., Elomari, S., Medrud, R.C. and Zones, S.I.J. Am. Chem.
Soc., 122, 263-273 (2000)
168
ITH
Framework Type Data
'
....
Atom2
'.......... " - 4
Z
framework viewed along [01 O]
Idealized cell data:
orthorhombic, Amm2, a - 12.6A, b - 11.7A., c - 21.9A
Coordination sequences and vertex symbols:
T~(8,1)
T2(8,1)
T3(8,1)
T4(8,1)
T5(8,1)
T6(4,m..)
TT(4,m..)
Ts(4,.m.)
T9(4,.m.)
4
4
4
4
4
4
4
4
4
9
12
9
12
11
11
11
11
11
Secondary building units:
18
22
19
21
22
22
20
22
20
35
37
37
36
39
32
32
36
34
61
56
60
56
57
51
55
53
57
90
84
86
83
80
87
85
83
81
116
116
117
112
114
116
112
119
117
146
154
151
155
156
139
141
155
155
190
193
189
196
202
183
185
186
192
244
233
238
237
239
241
243
236
234
296
288
296
283
283
296
294
299
297
338
351
349
349
343
343
339
359
357
see Compendium
Composite building units:
cl4r
lau
mel
Materials with this framework type:
*ITQ- 13 ~1'2)
AI-ITQ-13 (3~
IM_7 (4~
4"62"4"6~-4"10~
5.6.5.6.6~.92
4.6.4.62.4.102
5"6"5"6~-5"9
4.92-5.5.5-62
4.52.6.6~.6.6 ~
4"52"62"6~'62"62
4"9~'5"6~'5"6:
4"5"5"6~'5"6~
169
ITH
Type Material Data
ITQ-13
Crystal chemical data:
I((CH3)3N(CH=)6N(CH3)3)=F41 [Si560,,=]-ITIt
orthorhombic, Amm2, a - 12.525A, b - 11.391A, c - 22.053A (2~
Framework density:
17.8 T/1000A, 3
Channels:
[001] 10 4.8 x 5.3* ~
[010] 10 4.8 x 5.1" +--+[100] 9 4.0 x 4.8*
:~i
....
4.8
.i:::~ :: i:~~ :-'*'7~::
......,~,.:
..,,~ 4.8
1O-ring viewed along [01 O]
lO-ring viewed along [001]
~
.:.~
~iI.. ": ::.::~..~
.....
4
d
9-ring viewed along [100]
References:
(1) Boix, T., Puche, M., Camblor, M.A. and Corma, A. U.S. Patent 6,471,941 B1 (2002)
(2) Corma, A., Puche, M., Rey, F., Sankar, G. and Teat, S.J. Angew. Chem., Int. Ed., 42, 1156-1159 (2003)
(3) Castaneda, R., Corma, A., Fornes, V., Martinez-Triguero, J. and Valencia, S. J. Catal., 238, 79-87 (2006)
(4) Bats, N., Rouleau, L., Paillaud, J.-L., Caullet, P., Mathieu, Y. and Lacombe, S. Stud. Surf Sci. Catal., 154,
283-288 (2004)
170
ITW
Framework Type Data
C21m
i
° iiiiii:!i{ i
...........
Y
Z ~
......-"~X
....
framework viewed along [100]
Idealized cell data:
monoclinic, C2/m, a = 10.4, b = 15.0, c = 9.0, ~ = 105.6
Coordination sequences and vertex symbols:
T 1 (8,1)
T 2(8,1)
T 3(8,1)
4
4
4
12
9
9
Secondary building units:
23
19
19
36
38
38
87
83
82
1-4-1 or 4-[1,1]
Composite building units:
d4r
Materials with this framework type:
*ITQ- 12 0'2)
56
61
62
121
110
108
149
149
152
181
194
197
231
234
229
288
274
269
337
329
338
5.5.5.6.8.8
4.5.4.6.4.82
4.5.4.6.4.82
171
ITW
Type Material Data
ITQ-12
Crystal chemical data:
[Si24048]-ITW
monoclinic, Cm
a - 10.3304', b - 15.010A, c - 8.860A., 3 - 105.34°~1)
Framework density:
18.1 T/1000/~k 3
Channels:
[100] 8 2.4 x 5.4* +-+ [001] 8 3.9 x 4.2*
:~::
8-ring viewed along [100]
:,5.
':
8-ring viewed along [001]
References:
(1) Barrett, P.A., Boix, T., Puche, M., Olson, D.H., Jordan, E., Koller, H. and Camblor, M.A Chem. Commun.,
2114-2115 (2003)
(2) Yang, X.B., Camblor, M.A., Lee, Y., Liu, H.M. and Olson, D.H.J. Am. Chem. Soc., 126, 10403-10409
(2004)
172
IWR
Framework Type Data
Cmmm
~
Y
x
framework viewed along [001]
Idealized cell data:
orthorhombic, C m m m , a - 21.2A, b - 13.3A, c - 12.7A
Coordination sequences and vertex symbolsT, (16,1)
T 2(16,1)
T 3(16,1)
T 4(8,..m)
4
4
4
4
9
11
10
11
Secondary building units:
18
18
19
20
32
31
32
27
50
49
49
43
72
72
69
73
98
96
98
99
128
125
132
117
158
159
161
147
192
194
190
198
240
237
233
246
1-5-1
Composite building units:
d4r
bre
Materials with this framework type"
• ITQ_24 <1~
lau
mel
291
285
289
281
4.6.4.62.4.104
4.62.5.6.5.102
4.4.5.62. 5.127
4-52.6.6~.6.62
173
IWR
Type Material Data
ITQ-24
Crystal chemical data:
[A12.6GeS.1Si48.30224]-IWR
orthorhombic, C m m m , a - 21.2549A, b - 13.5210A, c - 12.6095A ~
Framework density:
15.5 T/1000A 3
Channels:
[001] 125.8 x6.8" +-+ Ill0] 104.6 x5.3" ~ [010] 1 0 4 . 6 x 5.3"
(The 10-ring shown below (viewed along [010]) limits the channel
dimensions of both 10-ring channels.)
5.8
i6.8
.......
~.8
12-ring viewed along [OO1]
i':~
5.3i
lO-ring viewed along [010]
References(1) Castaneda, R., Corma, A., Fornes, V., Rey, F. and Rius, J. J. Am. Chem. Soc., 125, 7820-7821 (2003)
174
[WV
Framework Type Data
Fmmm
ii.............i~.~
y
f r a m e w o r k viewed along [001]
Idealized cell data:
orthorhombic, F m m m , a - 27.8/k, b - 26.1A, c - 13.9,~
Coordination sequences and vertex symbols:
T~ (32,1)
T 2(32,1)
T 3(32,1)
T 4 (16,..m)
T 5(16,..m)
T 6(16,.m.)
T 7 (8,2mm)
4
4
4
4
4
4
4
12
9
11
12
12
12
12
Secondary building units:
20
18
21
20
20
22
24
32
32
34
34
28
32
32
50
52
49
50
49
45
40
74
78
72
67
69
69
66
101
105
101
100
100
101
108
135
130
138
141
136
137
136
167
164
177
178
166
167
168
203
213
204
214
201
199
196
254
264
243
232
245
244
240
see C o m p e n d i u m
Composite building units"
d4r
cas
Materials with this framework type:
• ITQ_27 ~1)
non
ton
307
310
292
278
292
303
298
5.5.5.62.5.12
4.5.4.5.4.12
4.6.5.5.52.12
5.52.5.52.14:.*
5.5.5.5-5.62
5.52.5.6.5.6
5.5.5.5-146.,*
175
ITQ-27
Type Material Data
IWV
Crystal chemical data:
[A15Si 147° 304]-IWV
orthorhombic, Fmmm, a - 27.7508A, b - 25.2969A, c - 13.7923A ~l)
Framework density:
15.7 T/1000A 3
Channels:
{ [001] 12 6.2 x 6.9 ~ [011] 12 6.2 x 6.9 }**
(The channel dimensions are limited by the same 12-ring in both
directions.)
12-ring viewed along [001 ]
References:
(1) Dorset, D.L., Kennedy, G.J., Strohmaier, K.G., Diaz-Cabanas, M.J., Rey, F. and Corma, A. J. Am. Chem.
Soc., 128, 8862-8867 (2006)
176
IWW
Framework Type Data
Pbam
~
y
X
framework viewed along [001]
Idealized cell data:
orthorhombic, Pbam, a - 41.7/k, b - 12.7,~, c - 12.7A
Coordination sequences and vertex symbols:
see A p p e n d i x A for a list of the coordination sequences and vertex symbols for the 16 T - a t o m s
Secondary building units:
1-5-1
Composite building units:
d4r
mor
Materials with this framework type:
*ITQ_22 ~)
bre
lau
stf
mel
177
IWW
Type Material Data
ITQ-22
Crystal chemical data:
[Gez: 2S isg.sOzz4]-IWW
orthorhombic, Pbam, a - 4 2 . 1 3 2 6 ' , b - 12.9885A, c - 12.6814A ~1)
Framework density:
16.1 T/1000A ~
Channels:
[001] 12 6.0 x 6.7* +-+ 2_ [001] 10 4.9 x 4.9** +-+ [001] 8 3.3 x 4.6*
1
!4.9
.....><
......
~.~ 4 . 9
12-ring viewed along [001 ]
i
:
, ..................
4.9
lO-ring viewed normal to [001]
8-ring viewed allong [001]
References:
(1)
Corma, A., Rey, F., Valencia, S., Jorda, J.L. and Rius, J. Nature Materials, 2, 493-497 (2003)
......
178
JBW
Framework Type Data
Pmma
z
framework viewed along [100]
Idealized cell data"
orthorhombic, Pmma, a - 5.3/k, b - 7.5/k, c - 8.2/k
Coordination sequences and vertex symbols:
T 1(4,m)
4
T 2(2,mm2) 4
10
12
Secondary building units"
21
24
39
36
61
56
81
86
107
118
148
146
192
176
228
228
6
Composite building units:
&c
jbw
abw
double zigzag
chain
Materials with this framework type:
*Na-J (Barrer and White )~)
[Na 2 Rb H2OI[A13Ge3012]-JBW ~2)
INa3 (H20)2l [A13Ge3012I-JBW (3~
Nepheline hydrate ~4~
[Na-I[A1-Si-OI-JBW ~5~
4.6~.4-62.6.82
6.6-6-6.62-62
179
Type Material Data
Na-J (Barrer and White)
JBW
Crystal chemical data:
[Na 3 (H~O),.~l [A13Si30,2I-JBW
orthorhombic, Pna2j, a - 16.426A, b - 15.014A, c - 5.224A (1)
(Relationship to unit cell of Framework Type: a ' = 2c, b ' = 2b, c ' = a)
Framework density:
18.6 T/1000A 3
Channels:
[001] 8 3.7 x 4.8*
,. . . . . .
...-.
8-ring along [001]
References:
(1) Hansen, S. and Faith, L. Zeolites, 2, 162-166 (1982)
(2) Healey, A.M., Henry, P.F., Johnson, G.M., Weller, M.T., Webster, M. and Genge, A.J. Microporous
Mesoporous Mat., 37, 165-174 (2000)
(3) Tripathi, A. and Parise, J.B. Microporous Mesoporous Mat., 52, 65-78 (2002)
(4) Rheinhardt, A., Hellner, E. and Ahsbahs, H. Fortsch. Mineral., 60, 175-176 (1982)
(5) Ragimov, K.G., Chiragove, M.I., Mustafaev, N.M. and Mamedov, Kh.S. Sov. Phys. Dokl., 23, 697-698
(1978)
180
KFI
m
Framework Type Data
Im3m
!
U
y
X
framework viewed along [001]
Idealized cell data:
cubic,
Im-3m, a - 18.6A
Coordination sequences and vertex s y m b o l s :
T, (96,1)
4
9
Secondary building units:
17
29
45
64
86
112
141
173
6-6 or 6-2 or 8 or 6 or 4-2 or 4
Composite building units"
cl6r
pau
lla
Materials with this framework type:
• ZK_5 (~)
(Cs,K)-ZK-5 (2'3)
[ Z n - G a - A s - O ] - K F I (4~
l18-crown-61[A1- S i-O ] - K F I (5~
p(6)
Q(6)
4.4.4.8.6-8
181
ZK-5
Crystal chemical data:
Type Material Data
INa~o(H20)gs[ [A13oSi~O,92]-KFI
cubic, Im3-m, a - 18.75,,~ ~
Framework density"
14.6 T/1000A 3
Channels:
<100> 8 3.9 x 3.9*** I <100> 8 3.9 x 3.9***
3.9
'
i
i 3.9
8-ring viewed along < 100>
References:
(1) Meier, W.M. and Kokotailo, G.T.Z. Krismllogr., 121, 211-219 (1965)
(2) Robson, H.E.U.S. Patent3,720,753 (1973)
(3) Parise, J.B., Shannon, R.D., Prince, E. and Cox, D.E.Z. Kristallogr., 165, 175-190 (1983)
(4) Feng, P., Zhang, T. and Bu, X. J. Am. Chem. Sot., 123, 8608-8609 (2001)
(5) Chatelain, T., Patarin, J., Farre, R., Petigny, O. and Schulz, P. Zeolites, 17, 328-333 (1996)
(6) Barrer, R.M. and Robinson, D. Z. Kristallogr., 135, 374-390 (1972)
KFI
182
LAU
Framework Type Data
C21m
U
Y
x
framework viewed along [001]
Idealized cell data:
monoclinic, C2/m, a - 14.6/k, b - 12.9/k, c - 7.6/k, ~= 111.2 °
Coordination sequences and vertex symbols:
T 1(8,1)
T 2(8,1)
4
4
4
T 3 (8,1)
10
10
10
Secondary building units:
20
19
19
33
32
33
51
52
53
74
74
74
99
99
96
128
126
127
161
162
166
199
203
201
6 or 1-4-1
Composite building units:
bog
lau
Q
Materials with this framework type"
*Laumontite (1-4)
[ C o - G a - P - O ] - L A U (5'6)
[ F e - G a - P - O ] - L A U (6)
[ M n - G a - P - O ] - L A U ¢6)
[Zn-A1-As-O]-LAU ¢7)
[ Z n - G a - P - O I - L A U ~8~
(9 10)
Leonhardite '
Na,K-rich laumontite ~1>
-1 (12)
Primary leonhard'te
Synthetic laumontite ¢~3)
4.4.6.62.6.104
4.4.6-62.6-102
4.4.6.63.6.63
183
Laumontite
Crystal chemical data:
Type Material Data
LAU
lea4 (H20),61 [A18Si,6048]-LAU
monoclinic, Am, a - 7.549~,, b - 14.740]k, c - 13.072A, ~ - 111.9 °(3~
(Relationship to unit cell of Framework Type:
a'=c,b'=a,c'=b,~'
=~3)
Framework density"
17.8 T/1000/~, 3
Channels:
[100] 10 4.0 x 5.3* (contracts upon dehydration)
lO-ring viewed along [100]
References:
(1) Bartl, H. and Fischer, K. N. Jb. Miner. Mh., 33-42 (1967)
(2) Amirov, S.T., Ilyukhin, V.V. and Belov, N.V. Dokl. Akad. Nauk SSSR, 174, 667- (1967)
(3) Schramm, V. and Fischer Adv. Chem. Ser., 101,259-265 (1971)
(4) Artioli, G. and St~hl, K. Zeolites, 17, 249-255 (1993)
(5) Chippindale, A.M. and Walton, R.I. Chem. Commun., 2453-2454 (1994)
(6) Bond, A.D., Chippindale, A., Cowley, A.R., Readman, J.E. and Powell, A.V. Zeolites, 19, 326-333 (1997)
(7) Feng, P., Zhang, T. and Bu, X. J. Am. Chem. Soc., 123, 8608-8609 (2001)
(8) Cowley, A.R., Jones, R.H., Teat, S.J. and Chippindale, A.M. Microporous Mesoporous Mat., 51, 51-64
(2002)
(9) Lapham, D.L. Am. Mineral., 48, 683-689 (1963)
(10) Artioli, G., Smith, J.V. and Kvick, A Zeolites, 9, 377-391 (1989)
(11) Stolz, J. and Armbruster, T. N. Jb. Miner. Mh., 131-144 (1997)
(12) Baur, W.H., Joswig, W., Fursenko, B.A. AND Belitsky, I.A. Eur. J. Mineral., 9, 1173-1182 (1997)
(13) Ghobarkar, H. and Schaef, O. Microporous Mesoporous Mat., 23, 55-60 (1998)
184
LEV
D
Framework Type Data
R3m
Z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
trigonal, R-3m, a - 13.2A, c - 22.6/k
Coordination sequences and vertex symbols:
T~ (36,1)
T~(18,2)
4
4
9
10
17
20
30
32
49
46
71
64
92
90
114
124
143
156
Secondary building units:
6
Framework description:
A A B C C A B B C sequence of 6-rings
183
184
4.4.4-6-6-8
4.4.6.6-8.8
Composite building units:
d6r
Materials with this framework type:
• L e v y n e ~,2~
A1PO_35 ~3)
CoDAF_4 ~4~
LZ_132 ~5~
NU_3 ~6)
RUB- 1 ( [ B - S i - O ] - L E V ) ~7~
SAPO_35 ~8~
ZK_20 O)
ZnAPO_35 ~°~
185
Levyne
Crystal chemical data:
LEV
Type Material Data
ICa (H20) ol [A1,sSi36Olosl-LEV
trigonal, R - 3 m , a - 13.338A, c - 23.014A ~2)
Framework density:
15.2 T/1000A 3
Channels:
2_ [001] 8 3.6 x 4.8**
3.6
~
3~6
48
"
8-ring viewed normal to [0011
References:
(1) Barrer, R.M. and Kerr, I.S. Trans. Faraday Soc., 55, 1915-1923 (1959)
(2) Merlino, S., Galli, E. and Alberti, A. Tschermaks Min. Petr. Mitt., 22, 117-129 (1975)
(3) Zhu, G.S., Xiao, F.S., Qiu, S.L., Hun, P.C., Xu, R.R., Ma, S.J. and Terasaki, O." Microporous Materials,
11,269-273 (1997)
(4) Barrett, P.A. and Jones, R.H. Phys. Chem. Chem. Phys., 2, 407-412 (2000)
(5) Tvaruzkova, Z., Tupa, M., Kiru, P., Nastro, A., Giordano, G. and Trifiro, F. Int. Zeolite Sym., Wurzburg,
Extended Abstracts (1988)
(6) McCusker, L.B. Mater. Sci. Forum, 133-136, 423-433 (1993)
(7) Grtinewald-Luke, A., Marler, B., Hochgrafe, M. and Gies, H. J. Mater. Chem., 9, 2529-2536 (1999)
(8) Lok, B.M., Messina, C.A., Patton, R.L., Gajek, R.T., Cannan, T.R. and Flanigen, E.M.J. Am. Chem. Soc.,
106, 6092-6093 (1984)
(9) Kerr, G.T.U.S. Patent 3,459,676 (1969)
(10) Christensen, A.N. and Hazell, R.G. Acta Chemica Stand., 53, 403-409 (1999)
186
LIO
Framework Type Data
P6m2
~i
i
Z
x
A
--='~ Y
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
D
o
hexagonal, P 6 m 2 , a -
Coordination sequences and vertex symbols:
T 1(12,1)
4
10
20
34
53
76
T 2(12,1)
T 3(6,m)
T 4(6,m)
4
4'
4
10
10
10
20
20
20
34
34
34
54
52
54
78
74
78
12.3A, c -
15.6/k
103
104
102
104
170
168
172
168
135
134
136
134
Secondary building units:
6or4
Framework description:
A B A B A C sequence of 6-rings
Composite building units"
can
los
Materials with this framework type"
*Liottite °'2)
lio
209
210
208
210
4.6-4.6.6.6
4.4.6-6.6-6
4.6.4-6.6-6
4.6.4.6.6.6
187
Liottite
Crystal chemical data:
Type Material Data
ICas(K,Na)~6(SO.)~Cl.l [Al,sSi~8072]-LIO
hexagonal, P 6 , a - 12.870A, c - 16.096A(2~
F r a m e w o r k density:
15.6 T/1000A 3
Channels:
apertures formed by 6-rings only
References:
(1)
(2)
Merlino, S. and Orlandi, P. Am. Mineral., 62, 321-326 (1977)
Ballirano, P., Merlino, S. and Bonaccorsi, E. Can. Mineral., 34, 1021-1030 (1996)
LIO
188
-LIT
Framework Type Data
Pnma
~
t~
X
Z
framework viewed along [01O]
Idealized cell data:
orthorhombic, Pnma, a - 14.8A, b - 8.6A, c - 9.8/k
Coordination sequences and vertex symbols"
T,(8,1)
T 2(8,1)
T 3(8,1)
3
4
4
7
9
10
Secondary building units:
16
19
19
31
34
31
68
72
76
93
100
98
6 or 4-[1,1] or 4-2
Materials w i t h this framework type"
• Lithosite ~)
50
50
51
128
128
124
161
160
161
196
197
201
237
239
239
283
287
284
4-6-6
4.8.4.82.6.6
4.6.6.83.8.8
189
Lithosite
Crystal chemical data:
Type Material Data
-LIT
IKl21 [A18Si,6048(OH)4]-LIT
monoclinic, P2~
a - 15.197.~, b - 10.233.~, c - 8.435A, f3 - 90.31 °~1)
(Relationship to unit cell of Framework Type: a'= a, b'= c, c'= b)
F r a m e w o r k density:
18.3 T/1000A 3
Channels:
References:
(1) Pudovkina, Z.V., Solov'eva, L.P. and Pyatenko, Yu.A. Sov. Phys. Dokl., 31,941-942 (1986)
190
LOS
Framework Type Data
P6 ff m m c
z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
hexagonal, P63/mmc, a - 12.6A, c = 10.3/k
Coordination sequences and vertex symbols"
T 1 (12,m)
T 2 (12,2)
4
4
10
10
20
20
34
34
52
54
74
78
102
104
136
134
Secondary building units:
6-2 or 6 or 4
Framework description:
A B A C sequence of 6-rings
Composite building units:
carl
los
Materials with this framework type:
• Losod ~1,2~
[A1-Ge-O]-LOS (3)
ILi-I[Be-P-O]-LOS (4)
Bystrite (5)
172
168
210
210
4.6.4.6.6.6
4.4.6.6.6.6
191
Losod
Type Material Data
Crystal chemical data:
INa,~ (H20)18l [A1,2Si12048]-LOS
hexagonal, P63mc, a - 12.906A, c - 10.541A ~2)
Framework density:
15.8 T/1000A 3
Channels:
apertures formed by 6-rings only
LOS
References:
(1)
(2)
(3)
(4)
(5)
Sieber, W. and Meier, W.M. Helv. Chim. Acta, 57, 1533-1549 (1974)
Schicker, P. Ph.D. Thesis, ETH, Ziirich, Switzerland (1988)
Sokolov, Yu.A., Maksimov, B.A., Ilyukhin, V.V. and Belov, N.V. Soy. Phys. Dokl., 23, 789-791 (1978)
Harrison, W.T.A., Gier, T.E. and Stucky, G.D. Zeolites, 13, 242-248 (1993)
Pobedimskaya, E.A., Terent'eva, L.F., Sapozhnikov, A.N., Kashaev, A.A. and Dorokhova, G.I. Soy. Phys.
Dokl., 36, 553-555 ( 1991 )
192
LOV
P4Jmmc
Framework Type Data
Z
framework viewed normal [001 ]
Idealized cell data:
tetragonal, P42/mmc, a - 7.2A, c - 20.9/k
Coordination sequences and vertex symbols:
T 1 (8,m)
4
T 2(8,m)
4
T3(2,42m)4
10
9
8
Secondary building units:
21
19
20
37
39
40
VSV
Materials with this framework type"
*Lovdarite ~'2)
Synthetic lovdarite ~3~
87
79
76
see Compendium
Composite building units"
lov
58
55
54
111
113
116
138
149
144
187
177
200
232
229
210
4.4.62-8.62-8
3"4"83"94"83"94
3"3"94"94"94"94
193
LOV
Type Material Data
Lovdarite
Crystal chemical data:
IK4Na,2(HeO),~l [BesSi280721-LOV
orthorhombic, P m a 2 , a - 3 9 . 5 7 6 ' , b - 6 . 9 3 1 ' , c - 7.153A ~2~
(Relationship to unit cell of Framework Type: a ' = 2c, b ' = c ' = a)
Framework density:
18.3 T/1000A 3
Channels:
[010] 9 3.2 x 4.5* ~ [001] 9 3.0 x 4.2* ~ [100] 8 3.6 x 3.7*
':~
....
"
: ..
::~
4.2
°0
......................
9-ring viewed along [001]
9-ring viewed along [010]
8-ring viewed along [100]
References:
(1) Merlino, S. Acta Crystallogr. (Suppl.), A37, C189 (1981)
(2) Merlino, S. Eur. J. Mineral., 2, 809-817 (1990)
(3) Ueda, S., Koizumi, M., Baerlocher, Ch., McCusker, L.B. and Meier, W.M. Preprints of Poster Papers, 7th
Int. Zeolite Conf., pp. 23-24 (1986)
194
LTA
Framework Type Data
Pm3m
~
y
X
framework viewed along [001]
m
Idealized cell data"
cubic, P m 3 m , a - 1 1 . 9 A
Coordination sequences and vertex symbols:
T 1 (24,m)
4
9
Secondary building units:
17
28
42
60
81
105
132
162
8 or 4-4 or 6-2 or 6 or 1-4-1 or 4
Composite building units"
d4r
sod
lta
Materials with this framework type:
*Linde Type A (zeolite A ) <1'2)
[A1-Ge-O]-LTA <3)
[ G a - P - O ] - L T A (4)
Alpha (5)
Dehyd. Linde Type A (dehyd. zeolite A) (6)
ITQ_29 (7)
LZ_215 (8)
N_A (9)
SAPO_42 (~°)
ZK_21 (1~)
ZK_22 (~)
ZK_4 (12)
4.6.4.6.4.8
195
Linde Type A
Type Material Data
Crystal chemical data:
INa,~ (H20)27[8 [A1,2Si,2 O4Js-LTA
cubic, Fm-3c , a - 24.61,~ ~2)
(Relationship to unit cell of Framework Type: a ' = 2a)
Framework density:
12.9 T/1000,~ 3
Channels:
<100> 8 4.1 x 4.1"**
LTA
8-ring viewed along <100>
References:
(1) Reed, T.B. and Breck, D.W.J. Am. Chem. Soc., 78, 5972-5977 (1956)
(2) Gramlich, V. and Meier, W.M.Z. Kristallogr., 133, 134-149 (1971)
(3) Barter, R.M., Baynham, J.W., Bultitude, F.W. and Meier, W.M.J. Chem. Soc., 195-208 (1959)
(4) Simmen, A., Patarin, J. and Baerlocher, Ch. Proc. 9th Int. Zeolite Conf., pp. 433-440 (1993)
(5) Wadlinger, R.L., Rosinski, E.J. and Plank, C.J.U.S. Patent 3,375,205 (1968)
(6) Pluth, J.J. and Smith, J.V.J. Am. Chem. Soc., 102, 4704-4708 (1980)
(7) Corma, A., Rey, F., Rius, J., Sabater, M.J. and Valencia, S. Nature, 431,287-290 (2004)
(8) Breck, D.W. and Skeels, G.W.U.S. Patent 4,503,023 (1985)
(9) Barrer, R.M. and Denny, P.J.J. Chem. Sot., 971-982 (1961)
(10) Lok, B.M., Messina, C.A., Patton, R.L., Gajek, R.T., Carman, T.R. and Flanigen, E.M.J. Am. Chem. Soc.,
106, 6092-6093 (1984)
(11) Kuehl, G.H. lnorg. Chem., 10, 2488-2495 (1971 )
(12) Kerr, G.T. Inorg. Chem., 5, 1537-1539 (1966)
196
LTL
Framework Type Data
P61mmm
t.
Z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
hexagonal, P6/mmm, a - 18.1A, c - 7.6A
Coordination sequences and vertex symbols:
T, (24,1)
T 2(12,m)
4
4
9
10
17
21
Secondary building units:
29
35
46
49
69
66
98
89
131
117
162
150
4.4.4.6-6.8
187
190
4.83.4.83.6.12
6 or 4-2
Composite building units"
dsc
doublechainSaWtooth
d6r
can
ltl
.~...........::,~:,.:.~,.-. . . . . . . . . . . . . .,..
~
Materials with this framework type"
(K,Ba)-G,L ~
*Linde Type L (zeolite L) ~2~
Gallosilicate L (3'4)
LZ-212 ~5~
(6 7)
Perlialite '
[A1-P-O]-LTU 8~
197
Linde Type L
LTL
Type Material Data
Crystal chemical data:
IK6Na3 (H20)2,1 [A19Si27072]-LTL
hexagonal, P6/mmm, a - 18.40A, c - 7.52A ~2~
Framework density:
16.3 T/1000fi~ 3
Channels:
[001] 12 7.1 x 7.1"
"
7 . 1 .....................
i
.
"
12-ring viewed along [001]
References:
(1) Baerlocher, Ch. and Barter, R.M.Z. Kristallogr., 136, 245-254 (1972)
(2) Barrer, R.M. and Villiger, H. Z. Kristallogr., 128, 352-370 (1969)
(3) Wright, P.A., Thomas, J.M., Cheetham, A.K. and Nowak, A.K. Nature, 318, 611-614 (1985)
(4) Newsam, J.M. Mater. Res. Bull., 21, 661-672 (1986)
(5) Breck, D.W. and Skeels, G.W.U.S. Patent 4,503,023 (1985)
(6) Menshikov, Y.P. Zap. Vses. Mineral. O-va, 113, 607-612 (1984)
(7) Artioli, G. and Kvick, A. Eur. J. Mineral., 2, 749-759 (1990)
(8) Venkatathri, N. Indian J Chem Sect A, 41, 2223-2230 (2002)
198
LTN
m
Framework Type Data
Fd3m
y
x
i
?
i
I
:
i(
:
:
i
i
z
¢.y
framework viewed normal to [001] (upper right: projection down [001])
m
Idealized cell data:
o
cubic, F d 3 m (origin choice 2), a - 35.6A
Coordination sequences and vertex symbols:
T,(192,1)
T 2(192,1)
T 3(192,1)
T 4(192,1)
4
4
4
4
10
10
10
9
Secondary building units:
20
20
20
17
34
34
33
30
53
51
50
49
76
71
71
72
102
96
97
97
132
126
129
125
166
162
163
158
205
202
200
197
4.4-6.6.6.6
4.6-4.6.6.6
4.4.6.6.6.8
4-4-4-8-6-6
6 or 4-2
Composite building units"
d6r
can
Materials with this framework type:
*Linde Type N (1)
NaZ-21 ~2~
sod
Ita
199
Linde Type N
Type Material Data
Crystal chemical data:
1Na384(H~O)~,8I[A1384Si3840,,361-LTN
cubic, Fcl-3 , a - 36.93A ~'~
Framework density"
15.2 T/1000A 3
Channels"
apertures formed by 6-rings only
LTN
References:
(1) F~ilth,L. and Andersson, S. Z. Kristallogr., 160, 313-316 (1982)
(2) Shepelev, Yu.F., Smolin, Yu.I., Butikova, I.K. and Tarasov, V.I. Dokl. Akad. N a u k S S S R , 272, 1133-1137
(1983)
200
MAR
P6Jmmc
Framework Type Data
o
°
Z
z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
hexagonal, P 6 3 / m m c ,
a -
Coordination sequences and vertex symbols:
T, (24,1)
4
10
20
34
53
76
T2(24,1)
4
10
20
34
53
76
T3(12,m..) 4
10
20
34
54
78
T 4 (12,.2.)
4
10
20
34
52
74
12.4/k, c - 30.7A
102
132
102
104
102
132
134
136
167
166
168
172
209
205
208
208
Secondary building units:
8or4
Framework description:
ABCBCBACBCBC sequence of 6-rings
Composite building units:
can
sod
Materials with this framework type:
Marinellite
(1)
lio
255
249
252
248
301
297
298
298
4.4-6.6.6.6
4.6.4.6.6.6
4.6.4.6.6.6
4-4.6.6-6.6
201
Marinellite
Type Material Data
Crystal chemical data:
INa3,K,,Ca6 (H20)3.4(SO4)8C121 [A136Si360,44]-MAR
trigonal, P31 c, a - 12.880A, c - 31.761A (~
F r a m e w o r k density:
15.8 T/1000A 3
Channels:
apertures formed by 6-rings only
References:
(1)
Bonaccorsi, E. and Orlandi, P. Eur. J. Mineral., 15, 1019-1027 (2003)
MAR
202
MAZ
P6Jmmc
Framework Type Data
i
...... i ~
l
oo
....... ~
Z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data"
hexagonal, P63/mmc , a - 18.l/k, c - 7.6/k
Coordination sequences and vertex symbols:
T 1 (24,1)
4
10
20
35
54
78
104
134
171
210
4.5-4.5.8-12
T 2(12,m)
4
10
21
36
53
74
104
138
174
212
4.82.4.82.5.6
Secondary building units:
5-1 or 4-2
Composite building units:
dsc
gme
double sawtooth
chain
Materials with this framework type:
• Mazzite
(1,2)
[ G a - S i - O ] - M A Z ~3~
Mazzite-Na, Boron, CA ~5~
Omega (6,7)
LZ_202 (4~
ZSM_4 (8~
203
Mazzite
Type Material Data
Crystal chemical data:
[(Na2,K2,Ca,Mg)5 (H20)281 [Al10Siz6Ovz]-MAZ
hexagonal, P6Jmmc, a - 18.392A, c - 7.646A (2~
Framework density:
16.1 T/1000A 3
Channels:
[001] 12 7.4 x 7.4" I [001 ] 8 3.1 x 3.1"**
MAZ
"2
7.4
""',..
,"(
:
12-ring viewed along [001]
limiting 8-ring along [001]
References:
Galli, E. Cryst. Struct. Comm., 3, 339-344 (1974)
Galli, E. Rend. Soc. Ital. Mineral. Petrol., 31,599-612 (|975)
Newsam, J.M., Jarman, R.H. and Jacobson, A.J. Mater. Res. Bull., 20, 125-136 (1985)
Breck, D.W. and Skeels, G.W.U.S. Patent 4,503,023 (1985)
Arletti, R., Galli, E., Vezzalini, G. and Wise, W.S. Am. Mineral., 90, 1186-1191 (2005)
Galli, E. Cryst. Struct. Comm., 3, 339-344 (1974)
Martucci, A., Alberti, A., Guzman-Castillo, M.D., Di Renzo, F. and Fajula, F. Microporous Mesoporous
Mat., 63, 33-42 (2003)
(8) Rubin, M.K., Plank, C.J. and Rosinski, E.J.U.S. Patent 4,021,447 (1977)
(1)
(2)
(3)
(4)
(5)
(6)
(7)
204
M El
Framework Type Data
~
P6alm
framework viewed normal to [001 ] (upper right: projection down [001])
Idealized cell data:
hexagonal, P63/m, a - 13.1A, c - 15.6A
Coordination sequences and vertex symbols:
4
4
4
4
T 1(12,1)
T 2 (12,1)
T 3 (6,m)
T 4 (4,3)
9
10
10
9
Secondary building units:
18
17
16
18
30
30
26
30
63
67
66
67
see Compendium
Composite building units:
mei
Materials w i t h this framework type:
• ZSM_18 <1)
ECR_40 ~2~
46
46
46
39
94
91
94
98
125
123
114
121
152
153
158
147
183
190
194
189
4.4.4.12.5.7
4.5.4.7.5.12
3.7.5.5-5.5
4.7.4.7-4-7
205
Type Material Data
ZSM-18
C r y s t a l chemical data:
INao(H20):J [AlnSi34_nO6s]-MEI, n - 2.1 - 5.7
hexagonal, P 6 / m , a - 13.175A, c - 15.848A ~
F r a m e w o r k density:
14.3 T/1000A 3
Channels:
[001] 12 6.9 x 6.9* +-+ I [001] 7 3.2 x 3.5**
6.9
..........,....
~
6,9
" ..........~
12-ring viewed along [001]
MEI
:
7-ring viewed normal to [001]
References:
(1) Lawton, S.L. and Rohrbaugh, W.J. Science, 247, 1319-1321 (1990)
(2) Afeworki, M., Dorset, D.L., Kennedy, G.J and Strohmaier, K.G. Stud. Surf. Sci. Catal., 154, 1274-1281
(2004)
206
MEL
D
Framework Type Data
14m2
~e
Z
framework viewed along [100]
Idealized cell data:
tetragonal, I-4m2, a - 20.3/k, c - 1 3 . 5 '
Coordination sequences and vertex symbols:
T 1(16,1)
T 2(16,1)
T 3(16,1)
T 4 (16,1)
T 5(16,1)
T 6 (8,2)
T 7(8,2)
4
4
4
4
4
4
4
12
11
12
12
11
11
12
Secondary building units:
21
23
23
23
22
23
21
36
38
38
38
36
38
40
63
61
62
59
57
57
63
88
93
91
87
90
88
83
121
121
116
122
127
126
124
153
153
155
158
157
158
155
192
198
203
198
194
191
197
249
246
244
243
244
236
244
5-1
Composite building units:
mor
mel
mfi
Materials with this framework type:
• ZSM_I 1<1-3>
IDEOTAI[Si-B-O]-MEL <4'
Bor-D ( M F I / M E L i n t e r g r o w t h ) <5~
Boralite D (6)
SSZ_46 (7,8~
Silicalite 2 (9)
TS_2(10~
5.5-5.5.5.6
4.5.5.62.5.102
5.5.5.52.5.103
5.62.5-102.52.6
4.5.5.6.5.82
4-52.62.62.10.10
5.5.5.5.52.102
207
ZSM-11
Crystal chemical data:
Type Material Data
MEL
INa n (H~O),~l [AlnSi96_nO,92]-MEL, n < 16
tetragonal, f 4 m 2 , a - 20.12A, c - 13.44A (~)
Framework density:
17.6 T/1000A 3
Channels:
<100> 10 5.3 x 5.4***
~..
>
lO-ring viewed along <100>
References:
(1) Kokotailo, G.T., Chu, P., Lawton, S.L. and Meier, W.M. Nature, 275, 119-120 (1978)
(2) Fyfe, C.A., Gies, H., Kokotailo, G.T., Pasztor, C., Strobl, H. and Cox, D.E.J. Am. Chem. Soc., 111, 24702474 (1989)
(3) van Koningsveld, H., den Exter, M.J., Koegler, J.H., Laman, C.D., Njo, S.L. and Graafsma, H. Proc. 12th
Int. Zeolite Conf., IV, pp. 2419-2424 (1999)
(4) Piccione, P.M. and Davis, M.E. Microporous Mesoporous Mat., 49, 163-169 (2001)
(5) Perego, G. and Cesari, M. J. Appl. Crystallogr., 17, 403-410 (1984)
(6) Taramasso, M., Manara, G., Fattore, V. and Notari, B. GB Patent 2,024,790 (1980)
(7) Terasaki, O., Ohsuna, T., Sakuma, H., Watanabe, D., Nakagawa, Y. and Medrud, R.C. Chem. Mater., 8,
463-468 (1996)
(8) Nakagawa, Y. and Dartt, C. U.S. Patent 5,968,474 (1999)
(9) Bibby, D.M., Milestone, N.B. and Aldridge, L.P. Nature, 280, 664-665 (1979)
(10) Reddy, J.S. and Kumar, R. Zeolites, 12, 95-100 (1992)
208
MEP
Framework Type Data
Pm3n
~
Y
y
framework viewed along [001] (upper right: projection down [001])
o
Idealized cell data:
cubic, P m 3 n , a - 13.7A
Coordination sequences and vertex symbols"
T~ (24,m)
4
T 2(16,3)
4
T3 ( 6 , 4 2 m ) 4
m
12
12
12
Secondary building units:
25
24
26
42
42
44
69
67
64
100
95
98
see Compendium
Composite building units:
mtn
Materials with this framework type:
* Melanophlogite <~
Synthetic melanophlogite <2~
low melanophlogite ~3~
129
133
144
176
177
172
229
219
222
277
277
272
5.5.5.5.5.6
5.5.5.5.5.5
5.5.5.5.6.6
209
Melanophlogite
Crystal chemical data:
Type Material Data
I (CH4,N2,CO2)~[ [Si46Og2]-MEP
cubic, Pm-3n, a - 13.436A~1)
(Data refer to structure at 200°; tetragonal at 25°C)
Framework density:
19 T/1000A 3
Channels"
apertures formed by 6-rings only
References:
(1) Gies, H. Z. Kristallogr., 164, 247-257 (1983)
(2) Gies, H., Gerke, H. and Liebau, F. N. Jb. Miner. Mh., 119-124 (1982)
(3) Nakagawa, T., Kihara, K. and Harada, K. Am. Mineral., 86, 1506-1512 (2001)
MEP
210
MER
Framework Type Data
•.
....~,... . . . . . . . . d'.~,,,~.,.,
141mmm
,!;%..... .
y
Y
X
framework
Idealized cell data-
tetragonal, I 4 / m m m ,
viewed along [001]
a - 14.0/k, c - 10.0/k
Coordination sequences and vertex s y m b o l s T~ (32,1)
4
9
18
Secondary building units:
32
49
69
93
121
153
189
8-8 or 8 or 4
Composite building units:
dcc
d8r
pau
double
crankshaft chain
Materials with this framework type"
•
(12)
*Merlinoite '
[ A 1 - C o - P - O ] - M E R (3~
[ G a - A 1 - S i - O ] - M E R (4~
IBa-I[A1-Si-OI-MER(5)
IBa-CI-][A1-Si-O]-MER(6)
I K - I [ A I - S i - O ] - M E R (7)
]NH4-I[Be-P-O]-MER (8~
K_M(5,9)
Linde W (5'~°~
(1
Synthetic merlinoite ~
Zeolite W (~2~
4.4.4.82.8.8
211
Type Material Data
Merlinoite
MER
Crystal chemical data:
IKsCa2 (H20)241 [A19Si23064]-MER
orthorhombic, Imrnm, a - 14.116A, b - 14.229A, c - 9.946/k (2)
(Relationship to unit cell of Framework Type: a ' = b ' = a, c ' = c)
F r a m e w o r k density:
16 T/1000A 3
Channels:
[lO0] 8 3.1 x 3.5* +-+ [010] 8 2.7 x 3.6*
[001] {8 3.4 x 5.1" + 8 3.3 x 3.3*}
8-ring viewed along [100]
8-ring viewed along [010]
8-ring viewed along [001]
2nd 8-ring viewed along [001]
References:
(1) Passaglia, E., Pongiluppi, D. and Rinaldi, R. N. Jb. Miner. Mh., 355-364 (1977)
(2) Galli, E., Gottardi, G. and Pongiluppi, D. N. Jb. Miner. Mh., 1-9 (1979)
(3) Feng, P., Bu, X. and Stucky, G.D. Nature, 388, 735-741 (1997)
(4) Kim, S.H., Kim, S.D., Kim, Y.C., Kim, C.S. and Hong, S.B. Microporous Mesoporous Mat., 42, 121-129
(2001)
(5) Gottardi, G. and Galli, E. Natural Zeolites, p. 157 (1985)
(6) Solov'eva, L.P., Borisov, S.V. and Bakakin, V.V. Sov. Phys. Crystallogr., 16, 1035-1038 (1972)
(7) Skofteland, B.M., Ellestad, O.H. and Lillerud, K.P. Microporous Mesoporous Mat., 43, 61-71 (2001)
(8) Bu, X., Gier, T.E. and Stucky, G.D. Microporous Mesoporous Mat., 26, 61-66 (1998)
(9) Barrer, R.M. and Baynham, J.W.J. Chem. Soc., 2882-2891 (1956)
(10) Sherman, J.D. A CS Sym. Set., 40, 30-42 (1977)
(11) Barrett, P.A., Valencia, S. and Camblor, M.A.J. Mater. Chem., 8, 2263-2268 (1998)
(12) Bieniok, A., Bornholdt, K., Brendel, U. and Baur, W.H.J. Mater. Chem., 6, 271-275 (1996)
212
MFI
Framework Type Data
• :.:(.~:,:~!~£:~5
Pnma
.
x
framework viewed along [01 O]
Idealized cell data:
o r t h o r h o m b i c , P n m a , a - 20.1A, b - 19.7A, c - 13.1A
Coordination sequences and vertex symbols:
see A p p e n d i x A for a list of the c o o r d i n a t i o n s e q u e n c e s and vertex s y m b o l s for the 12 T - a t o m s
Secondary building units:
5-1
Composite building units:
mor
cas
mel
mfi
Materials with this framework type:
• ZSM_5 (1-3)
F Z _ I {12)
[ A s - S i - O ] - M F I (4)
[ F e - S i - O ] - M F I (5~
[ G a - S i - O ] - M F I (6~
A M S- 1B ~7~
A Z - 1~8~
Bor_C (9~
Boralite C ~l°~
Encilite (ll~
L Z _ 1 0 5 (13)
M o n o c l i n i c H - Z S M - 5 {14)
M u t i n a i t e (~5~
N U _ 4 (16)
N U _ 5 (17)
Silicalite (~8~
TS_I (19~
T S Z (2°)
TSZ_III (21)
TZ-01 (22)
U S C _ 4 (23~
USI_108 (24~
Z B H (25)
Z K Q - 1B (26)
Z M Q _ T B ~27~
o r g a n i c - f r e e Z S M - 5 ~28~
213
Type Material Data
ZSM-5
Crystal chemical data:
INao (H20),J [AloSi96_oO,gzl-MFI, n < 27
orthorhombic, Prima, a - 20.07A, b - 19.92A, c - 13.42A (2)
F r a m e w o r k density:
17.9 T/1000A ~
Channels:
{ [ 100] 10 5.1 x 5.5 +-+ [010] 10 5.3 x 5.6 }***
1O-ring viewed along [100]
MFI
lO-ring viewed along [010]
References:
(1) Kokotailo, G.T., Lawton, S.L., Olson, D.H. and Meier, W.M. Nature, 272, 437-438 (1978)
(2) Olson, D.H., Kokotailo, G.T., Lawton, S.L. and Meier, W.M.J. Phys. Chem., 85, 2238-2243 (1981)
(3) van Koningsveld, H., van Bekkum, H. and Jansen, J.C. Acta Crystallogr., B43, 127-132 (1987)
(4) Bhaumik, A. and Kumar, R. Chem. Commun., 869-870 (1995)
(5) Patarin, J., Kessler, H. and Guth, J.L. Zeolites, 10, 674-679 (1990)
(6) Awate, S.V., Joshi, P.N., Shiralkar, V.P. and Kotasthane, A.N.J. Incl. Phenom., 13, 207-218 (1992)
(7) Klotz, M.R.U.S. Patent 4,269,813 (1981)
(8) Chono, M. andIshida, H.E. PatentB-ll3,116 (1984)
(9) Taramasso, M., Perego, G. and Notari, B. Proc. 5th Int. Zeolite Conf., pp. 40-48 (1980)
(10) Taramasso, M., Manara, G., Fattore, V. and Notari, B. GB Patent 2,024,790 (1980)
(11) Ratnasamy, P. and Borade, M.B.E. Patent A- 160,136 (1985)
(12) Suzuki, T., Hashimoto, S. and Nakano, R. E. Patent B-31,255 (1981)
(13) Grose, R.W. and Flanigen, E.M.U.S. Patent 4,257,885 (1981)
(14) van Koningsveld, H., Jansen, J.C. and van Bekkum, H. Zeolites, 10, 235-242 (1990)
(15) Vezzalini, G., Quartieri, S., Galli, E., Alberti, A., Cruciani, G. and Kvick, A. Zeolites, 19, 323-325 (1997)
(16) Whittam, T.V.E. Patent B-65,401 (1986)
(17) Whittam, T.V.E. Patent B-54,386 (1982)
(18) Flanigen, E.M., Bennett, J.M., Grose, R.W., Cohen, J.P., Patton, R.L., Kirchner, R.M. and Smith, J.V.
Nature, 271, 512-516 (1978)
(19) Taramasso, M., Perego, G. and Notari, B. U.S. Patent 4,410,501 (1983)
(20) Ashibe, K., Kobayashi, W., Maejima, T., Sakurada, S. and Tagaya, N. E. Patent A-101,232 (1984)
(21) Sakurada, S., Tagaya, N., Miura, T., Maeshima, T. and Hashimoto, T. E. Patent A-170, 751 (1986)
(22) Iwayama, K., Kamano, T., Tada, K. and Inoue, T. E. Patent A-57,016 (1982)
(23) Young, D.A.U.S. Patent 4,325,929 (1982)
(24) Hinnenkamp, J.A. and Walatka, V.V.U.S. Patent 4,423,020 (1983)
(25) Holderich, W., Mross, W.D. and Schwartzmann, M. E. Patent B-77,946 (1986)
(26) Kee Kwee, L.S.L.E. Patent A-148,038 (1984)
(27) Kee Kwee, L.S.L.E. PatentA-104,107 (1983)
(28) Kim, S.D., Noh, S.H., Seong, K.H. and Kim, W.J. Microporous Mesoporous Mat., 72, 185-192 (2004)
214
MFS
Framework Type Data
..............
~:~
:>~.
"
......
....... .-. ~
. . . .
Imm2
~.
Z
framework viewed along [010]
Idealized cell data:
orthorhombic, Imm2, a - 7.5,~, b - 14.4/k, c - 19.0/k
Coordination sequences and vertex symbols:
T~(8,1)
T 2(8,1)
T 3(4,m)
T 4(4,m)
T 5(4,m)
T o(4,m)
T 7(2,mm2)
T 8(2,mm2)
4
4
4
4
4
4
4
4
12
11
12
12
12
10
12
12
Secondary building units:
23
20
24
26
19
22
22
24
39
39
42
40
35
36
40
38
62
66
64
60
64
64
62
66
93
92
90
94
96
98
92
100
see Compendium
Composite building units:
mtt
fer
Materials with this framework type:
• ZSM_57 °)
COK-5 (intergrowth containing M F S ) <2~
127
124
131
136
123
124
138
118
165
163
168
168
155
158
160
162
210
215
206
200
207
213
196
220
260
257
259
259
272
260
262
262
5-5.5.5.5-82
4.52.5.5.8.10
5-5-5.5.5.102
5~'5~'6-8"6-8
5.52-5.5~-6.*
4.5.4.5.82.10
5.5.5.5.62.*
5.5.5.5.52-102
215
MFS
Type Material Data
ZSM-57
Crystal chemical data:
Iu,~l [A11.58i34.50721-MFS
orthorhombic, Imm2, a - 7.451A, b -
14.171,~, c -
Framework density:
18.2 T/IOOOA3
Channels:
[100] 10 5.1 x 5.4* ~ [010] 8 3.3 x 4.8*
lO-ring viewed along [100]
1 8 . 7 6 7 ' (1)
8-ring viewed along [010]
References:
(1) Schlenker, J.L., Higgins, J.B. and Valyocsik, E.W. Zeolites, 10, 293-296 (1990)
(2) Kirschhock, C., Bons, A.J., Mertens, M., Ravishankar, R., Mortier, W., Jacobs, P. and Martens, J. Chem.
Mater., 17, 5618-5624 (2005)
216
MON
14~lamd
Framework Type Data
..
&
Z
framework viewed along [100]
I d e a l i z e d cell d a t a :
tetragonal, I4~/amd (origin c h o i c e 2), a - 7.1A, c - 17.8A
Coordination sequences and vertex symbols:
T 1 (16,m)
4
11
Secondary b u i l d i n g u n i t s "
23
44
4
Materials with this framework type:
* M o n t e s o m m a i t e ~)
[ A 1 - G e - O ] - M O N ~2~5
67
95
134
168
215
271
4.5~.5.82.5.8 ~
217
Montesommaite
Type Material Data
Crystal chemical data:
I(K,Na)4.~ (H20)51 [A14.sSi,,.5032]-MON
tetragonal, I4~/amd, a - 7.141A, c - 17.307A (~
Framework density:
18.1 T/1000A 3
Channels:
[100] 8 3.2 x 4.4* +-+ [OO1] 8 3.6 x 3.6*
:
4.4
8-ring viewed along [100]
MON
....
8-ring viewed along [001]
References:
(1) Rouse, R.C., Dunn, P.J., Grice, J.D., Schlenker, J.L. and Higgins, J.B. Am. Mineral., 75, 1415-1420 (1990)
(2) Tripathi, A. and Parise, J.B. Microporous Mesoporous Mat., 52, 65-78 (2002)
218
MOR
Framework Type Data
Cmcm
)
1
×
framework viewed along [001]
Idealized cell data:
orthorhombic, Cmcm, a - 18.3A, b - 20.5/k, c - 7.5A
Coordination sequences and vertex symbols:
T 1(16,1)
T 2(16,1)
T 3 (8,m)
T 4 (8,m)
4
4
4
4
12
12
11
11
Secondary building units:
22
20
24
24
38
37
39
39
60
64
54
60
88
87
86
92
115
114
126
122
155
154
156
148
204
198
195
195
242
241
242
250
5-1
Composite building units:
mor
Materials with this framework type:
*Mordenite °)
[ G a - S i - O ] - M O R ~2)
Ca_Q ~3)
LZ-211 <4)
Large port mordenite ~5)
Maricopaite (interrupted framework) ~6)
Mordenite, U S A O)
Na_D ~8)
5.5.5.52.8.12
5.5-5-52.5.8
4-52.5-82.5.82
4.52.5-8.5.8
219
Mordenite
Type Material Data
Crystal chemical data:
INas (H~O)~4I [AlsSi4oO96]-MOR
orthorhombic, Cmcm, a - 18.1,~, b - 20.5A, c - 7.5 A ¢1~
Framework density:
17.2 T/1000A 3
Channels:
[001] 12 6.5 x 7.0* ~ [001] 8 2.6 x 5.7***
7.0
MOR
i
12-ring viewed along [001]
limiting 8 ring along [001]
between 12-ring channels
References"
(1) Meier, W.M. Z Kristallogr., 115, 439-450 (1961 )
(2) Eapen, M.J., Reddy, K.S.N., Joshi, P.N. and Shiralkar, V.P.J. Incl. Phenom., 14, 119-129 (1992)
(3) Koizumi, M. and Roy, R. J. Geol., 68, 41-53 (1960)
(4) Breck, D.W. and Skeels, G.W.U.S. Patent 4,503,023 (1985)
(5) Sand, L.B. Molecular Sieves, pp. 71-77 (1968)
(6) Rouse, R.C. andPeacor, D.R. Am. Mineral.,79, 175-184(1994)
(7) Gramlich, V. Ph.D. Thesis, ETH, Ziirich, Switzerland (1971)
(8) Barrer, R.M. and White, E.A.D.J. Chem. Soc., 1561-1571 (1952)
220
MOZ
Framework Type Data
P61mmm
~... (
×
y
framework viewed along [001]
Idealized cell data:
hexagonal, P6/mmm, a - 31.2/k, c - 7.6/k
Coordination sequences and vertex symbols:
T 1 (24,1)
T 2(24,1)
T 3(24,1)
T 4(12,m..)
T 5(12,m..)
T 6(12,m..)
4
4
4
4
4
4
9
9
9
10
10
10
Secondary building units:
17
17
17
21
21
21
29
29
31
35
34
35
46
47
53
49
46
51
70
72
78
66
64
71
100
101
100
90
92
94
130
130
122
121
127
124
155
158
151
157
169
163
179
190
190
195
211
204
215
227
237
233
245
243
271
270
287
274
272
284
4.4.4.6.6.8
4"4"4"6"6"8
4"4"4"6-6"8
4"83"4"83"6"12
4"83"4"83"6"8
4-8"4-8"6"8
6 or 4-2
Composite building units:
dsc
d6r
do ub lechainSaWtooth
Materials with this framework type:
*ZSM_IO ~v3)
can
pau
Itl
221
Type Material Data
ZSM-IO
C r y s t a l chemical data:
MOZ
IKz4(H~O)xI [A124Sis4Oz,6]-MOZ
hexagonal, P6/mmm, a - 31.575 A, c - 7.525 A, ~3)
Framework density:
16.6 T/1000A 3
Channels:
{[001] 12 6.8 x 7.0 +-~ n[O01] 8 3.8 x 4 . 8 } * * ' 1 1 0 0 1 ] 12 6.8 x 6.8*
8-ring viewed normal to [001]
12-ring viewed along [001]
.....
.7,,
.
.
.
.
.
.
.~
2nd 12-ring viewed along [001]
References:
(1)
(2)
(3)
Higgins, J.B. and Schmitt, K.D. Zeolites, 16, 236-244 (1996)
Foster, M.D., Treacy, M.M.J., Higgins, J.B., Rivin, I., Balkovsky, E. and Randall, K.H.J. Appl.
Crystallogr., 38, 1028-1030 (2005)
Dorset, D.L. Z Kristallogr., 221,260-265 (2006)
222
MSE
P4Jmnm
Framework Type Data
i] I:~..........................
'~1+-.................
z
framework viewed normal to [001]
Idealized cell data:
tetragonal, P42/mnm, a - 18.2A, c - 20.6A
Coordination sequences and vertex symbols:
T, (16,1)
T 2(16,1)
T 3(16,1)
T 4(16,1)
T 5(16,1)
T 6(16,1)
T 7(8,..m)
T 8(8,..m)
4
4
4
4
4
4
4
4
10
10
12
11
12
10
11
11
Secondary building units:
19
21
22
20
18
20
21
20
33
34
33
36
35
34
32
31
53
57
50
54
58
56
47
55
83
84
75
78
81
83
75
85
114
112
114
106
110
109
114
115
see Compendium
Composite building units"
mor
bea
Materials with this framework type"
• M C M _ 6 8 ~1)
mtw
141
139
152
148
143
140
156
141
174
181
183
193
177
181
189
1'79
227
230
220
225
230
226
215
223
283
274
267
254
271
282
262
275
329
317
324
317
328
337
329
331
4.5.4.6.5.6
4.5.4-10.5.6
5.6.52.6.6.10
4.52.5.5.5.10
5.5.5.6.52.10
4.5.4.10-5-6
4.5.5.6.5.6
4.52.5.6.5.6
223
MSE
Type Material Data
MCM-68
C r y s t a l c h e m i c a l data:
[Allj.4Siloo.60224]-MSE
t e t r a g o n a l , P42/mnm, a - 1 8 . 2 8 6 A , c - 2 0 . 2 0 8 * (1)
Framework density:
16.6 T/1000A 3
Channels:
{ [ 0 0 1 ] 12 6.4 x 6.8 ~
[100] 10 5.2 x 5.8 ~
::
5.8 .....................!
12-ring viewed along [001]
:.
[110] 10 5.2 x 5.2 } * * *
:
5.8 .................i......
1O-ring viewed along [100]
I O-ring viewed along [11 O]
References:
(1)
Dorset, D.L., Weston, S.C. and Dhingra, S . S . J .
Phys. Chem. B, 110, 2 0 4 5 - 2 0 5 0 (2006)
..
224
MSO
m
Framework Type Data
R3m
3
z
¢-y
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
trigonal, R-3m, a - 17.2A, c - 19.8/k
Coordination sequences and vertex symbols:
T 1 (36,1)
T 2 (36,1)
T 3(18,2)
4
4
4
10
10
12
21
20
21
37
34
32
55
53
51
Secondary building units:
2-6-2 or 4-1
Composite building units"
d6r
lau
Materials with this framework type"
* M C M - 6 1 (1,2)
Mu_13 ~3~
75
77
80
101
106
110
mso
136
138
132
175
170
164
211
206
212
4-6.4.62.6.6
4.62-4.62.6.6
6.6.6-62.62.62
225
MCM-61
Crystal chemical data:
Type Material Data
MSO
[K2.1 C12H24061 [A12.15i27.9060]-MSO
C12H2406 - 18-crown-6
rhombohedral, R-3m, a - 11.841~,, c~ - 93.29 ° (2)
(hexagonal setting: a - 17.220A, c - 19.296A)
F r a m e w o r k density:
18.2 T/1000A 3
Channels:
apertures formed by 6-rings only
References:
(1) Valyosik, E.W.U.S. Patent 5,670,131 (1997)
(2) Shantz, D.F., Burton, A. and Lobo, R.F. Microporous Mesoporous Mat., 31, 61-73 (1999)
(3) Paillaud, J.-L., Caullet, P., Schreyeck, L. and Marler, B. Microporous Mesoporous Mat., 42, 177-189
(2001 )
226
MTF
Framework Type Data
C21m
Y
framework viewed along [001]
Idealized cell data"
monoclinic, C2/m, a - 9.6,~, b - 30.4/k, c - 7.2A, 3 - 90-5°
Coordination sequences and vertex symbols:
T~(8,1)
T 2(8,1)
T 3(8,1)
T 4(8,1)
T 5(8,1)
T 6(4,2)
4
4
4
4
4
4
11
12
12
12
12
12
Secondary building units:
24
24
27
26
24
21
45
42
47
45
42
44
109
95
99
96
93
106
see Compendium
Composite building units:
Materials with this framework type:
• MCM_35 ~)
UTM_I ~2)
77
70
69
64
64
74
137
136
142
134
133
138
174
184
184
186
179
172
224
227
227
230
234
226
280
277
281
290
290
284
4.5.5.6.5.8
5.52.5.6.5.8
5.6.5-7.5.8
5-6.5.6-5.6
5.6.5.62.5.7
5.5.5.5.52.6
227
MCM-35
Crystal chemical data:
Type Material Data
[Si44Oj-MTF
monoclinic, C2/m
a - 9.500 A, b - 30.710A, c - 7.313A, ~ - 91.71 °~1)
Framework density:
20.6 T/1000A)
Channels:
[001] 8 3.6 x 3.9*
8-ring viewed along [001]
References:
(1)
(2)
Barrett, P.A., Diaz-Cabanas, M.-J. and Camblor, M.A. Chem. Mater., 11, 2919-2927 (1999)
P16vert, J., Yamamoto, K. Chiari, G. and Tatsumi, T. J. Phys. Chem. B, 103, 8647-8649 (1999)
MTF
228
MTN
Framework Type Data
Fd3m
Z
×
.ii
:ii ~i
'
i
y
~ ~~....../:~
il
....i!
.
.....................
,j
.:/:,.
.;...;;
i
Z
;;
"............. :......... o ........ ~..
?.
,
framework viewed along [111] (upper right: projection down [110])
Idealized cell data:
cubic, Fd-3m (origin choice 2), a - 19.9A
C o o r d i n a t i o n s e q u e n c e s and vertex symbols:
T, (96,m)
4
12
25
43
68
95
T 2(32,3m) 4
12
24
39
66 103
T 3 (8, 43m) 4
12
24
36
64 112
m
S e c o n d a r y building units:
see Compendium
C o m p o s i t e building units"
mtn
M a t e r i a l s with this f r a m e w o r k type:
• ZSM_39 ~
CF_4 (2~
Dodecasil-3C ~3~
Holdstite ~4~
133
130
132
177
168
156
223
216
222
274
274
264
5.5.5-5.5.6
5.5.5.5.5.5
5-5.5.5.5.5
229
ZSM-39
Type Material Data
Crystal chemical data:
I(CsH2oN)q (OH)q[ [Sij36027el-MTN
CsH2oN- tetraethylammonium
cubic, Fd-3m, a - 19.36A (j)
Framework density:
18.7 T/1000.A, 3
Channels:
apertures formed by 6-rings only
MTN
References:
(1) Schlenker, J.L., Dwyer, F.G., Jenkins, E.E., Rohrbaugh, W.J., Kokotailo G.T. and Meier, W.M. Nature,
294, 340-342 (1981 )
(2) Long, Y., He, H., Zheng, P., Guang, W. and Wang, B. J. Incl. Phenom., 5, 355-362 (1987)
(3) Gies, H. Z. Kristallogr., 167, 73-82 (1984)
(4) Smith, J.V. and Blackwell, C.S. Nature, 303, 223-225 (1983)
230
MTT
Framework Type Data
Pmmn
:%'2:::
i!
"
U z
y
framework viewed along [100]
Idealized cell data:
o r t h o r h o m b i c , Pmmn (origin c h o i c e 1), a - 5.3A, b - 2 2 . 0 A , c - 1 1 . 4 '
Coordination sequences and vertex symbols:
T 1 (4,m)
4
12
23
43
66
92
T 2 (4,m)
T 3 (4,m)
T 4 (4,m)
T 5 (4,m)
T 6 (2,mm2)
T 7 (2,mm2)
4
4
4
4
4
4
12
12
12
12
12
12
Secondary building units:
24
22
22
24
22
24
40
40
40
41
42
44
64
67
65
62
66
66
96
97
98
97
94
88
130
136
124
132
129
126
132
170
167
165
159
170
164
174
213
207
219
206
212
220
214
261
258
265
278
262
270
258
5-5.5.5.6-102
52"62"6.62-6.62
5.5.5.5.62-102
5.5.5-5.62.*
5~'62.6.6~.6.62
5"5"5"5-6~" 10~
5"5"5"5.10~.*
5-1
Composite building units:
jbw
mtt
bik
Materials with this framework type:
• Z S M _ 2 3 °-4)
ISI_4 ~6)
EU_13 ~5)
KZ_I °)
ton
231
ZSM-23
Type Material Data
Crystal chemical data:
INa. (H:O)41 [AlnSiz, nO4s]-MTT, n < 2
orthorhombic, Pmn21, a - 21.5A, b - 11.1A, c - 5.0 A, ¢1)
Framework density:
20.1 T/1000A. 3
Channels:
[001] 10 4.5 x 5.2*
MTT
1O-ring viewed along [001 ]
References:
(1) Schlenker, J.L., Higgins, J.B. and Cox, D.E. private communication
(2) Rohrman Jr., A.C., LaPierre, R.B., Schlenker, J.L., Wood, J.D., Valyocsik, E.W., Rubin, M.K., Higgins,
J.B. and Rohrbaugh, W.J. Zeolites, 5, 352-354 (1985)
(3) Marler, B., Deroche, C., Gies, H., Fyfe, C.A., Grondey, H., Kokotailo, G.T., Feng, Y., Ernst, S., Weitkamp,
J. and Cox, D.E.J. Appl. Crystallogr., 26, 636-644 (1993)
(4) Zones, S.I., Dalton, R.J., Morris, R. and Hwang, S.-J. J. Phys. Chem. B, 109, 652-661 (2005)
(5) Araya, A. and Lowe, B.M.U.S. Patent 4,581,211 (1986)
(6) Kakatsu, K. and Kawata, N. Eur. Pat. Appl. EPA 102,497 (1984)
(7) Parker, L.M. and Bibby, D.M. Zeolites, 3, 8-11 (1983)
232
MTW
Framework Type Data
C21m
x
z
framework viewed along [01 O]
Idealized cell d a t a :
monoclinic, C2/m, a - 25.6A, b - 5.3A, c - 12.l/k, 3 - 109.3°
Coordination sequences and vertex symbols:
T 1(4,m)
T 2(4,m)
T 3(4,m)
T 4(4,m)
T 5(4,m)
T 6(4,m)
T 7(4,m)
4
4
4
4
4
4
4
11
11
12
12
12
12
12
Secondary building units:
22
22
21
23
21
24
23
38
38
37
37
37
39
38
60
60
62
59
58
55
59
88
86
84
85
87
85
83
113
115
119
120
119
122
115
147
147
147
154
154
156
155
190
191
188
184
182
188
192
243
238
239
231
227
225
233
4.62.5.6.5.6
4.62.5.6.5.6
5.6.5.6.52.6
5.6.5.6.6.62
5.62.5.62.52.6
5.62.5.62.62.126
5.5.5.5.6.126
5-[1,1]
Composite building units:
jbw
cas
bik
mtw
Materials with this framework type:
*ZSM- 12 ~1'2~
[ B - S i - O ] - M T W ~3~
[ G a - S i - O ] - M T W ~4~
CZH_5 ~5~
NU_13 ~6)
TPZ- 12~7~
Theta_3 ~8~
VS_12 ~9~
233
ZSM-12
Crystal chemical data:
MTW
Type Material Data
INao (H~O)~l[A1,Si56_nO,12]-MTW, n < 5
monoclinic, C2/c
a - 24.863A, b - 5.012A, c -
Framework density:
19.4 T/1000A 3
Channels:
[010] 12 5.6 x 6.0*
,/5.6
24.328A, ~ - 107.72 °~2)
......
12-ring viewed along [01 O]
References:
(1) LaPierre, R.B., Rohrman Jr., A.C., Schlenker, J.L., Wood, J.D., Rubin, M.K. and Rohrbaugh, W.J. Zeolites,
5, 346-348 (1985)
(2) Fyfe, C.A., Gies, H., Kokotailo, G.T., Marler, B. and Cox, D.E.J. Phys. Chem., 94, 3718-3721 (1990)
(3) Bandyopadhyay, R., Kubota, Y., Sugimoto, N., Fukushima, Y. and Sugi, Y. Microporous Mesoporous
Mat., 32, 81-91 (1999)
(4) Zhi, Y.X., Tuel, A., Ben Taarit, Y. and Naccache, C. Zeolites, 12, 138-141 (1992)
(5) Hickson, D.A. UK Pat. Appl. GB 2079735A (1981)
(6) Whittam, T.V. Eur. Pat. Appl. EPA 0059059 (1982)
(7) Sumitani, K., Sakai, T., Yamasaki, Y. and Onodera, T. U.S. Patent 4,557,919 (1985)
(8) Barlow, T.M.E. PatentA-162,719 (1985)
(9) Reddy, K.M., Moudrakovski, I. and Sayari, A. Chem. Commun., 1491-1492 (1994)
234
MWW
Framework Type Data
P61mmm
Z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data"
hexagonal, P6/mmm, a - 14.4/k, c - 25.2/k
Coordination sequences and vertex symbols:
see Appendix A for a list of the coordination sequences and vertex symbols for the 8 T-atoms
Secondary building units"
see Compendium
Composite building units:
d6r
mel
Materials with this framework type:
* M C M - 22 ~
[ G a - S i - O ] - M W W ~2~
[Ti-S i- O ] - M W W (3)
ERB- 1(4)
ITQ- 1(5,6)
PSH_3 (7)
552_25(8.9)
235
MCM-22
MWW
Type Material Data
Crystal chemical data:
IH2.4Na3.,I [Alo.4Bs.,Si66.50,441-MWW
hexagonal, P6/mmm, a - 14.208,,~, c - 24.945A ~6~
Framework density-
16.5 T/1000A 3
Channels:
2_ [001] 10 4.0 x 5.5"* I ± [001] 10 4.1 x 5.1"*
!
lO-ring viewed normal to [001]
between 'layers'
5.1
l O-ring viewed normal to [001]
within 'layers'
References:
(1) Leonowicz, M.E., Lawton, J.A., Lawton, S.L. and Rubin, M.K. Science, 264, 1910-1913 (1994)
(2) Kim, S.J., Jung, K.D. and Joo, O.S.J. Porous Mater., 11, 211-218 (2004)
(3) Peng, W., Liu, Y.M., He, M.Y. and Tatsumi, T. J. Catal., 228, 183-191 (2004)
(4) Belussi, G., Perego, G., Clerici, M.G. and Giusti, A. Eur. Pat. Appl. EPA 293032 (1988)
(5) Camblor, M.A., Corell, C., Corma, A., Diaz-Cabanas, M.-J., Nicolopoulos, S., Gonzalez-Calbet, J.M. and
Vallet-Regi, M. Chem. Mater., 8, 2415-2417 (1996)
(6) Camblor, M.A., Corma, A., Diaz-Cabanas, M.-J. and Baerlocher, Ch. J. Phys. Chem. B, 102, 44-51 (1998)
(7) Puppe, L. and Weisser, J. U.S. Patent 4,439,409 (1984)
(8) Zones, S.I.E. Patent 231,860 (1987)
(9) Zones, S.I., Hwang, S.J. and Davis, M.E. Chemistry-A European Journal, 7, 1990-2001 (2001)
236
NAB
m
Framework Type Data
~i i!i!,~
°
14m2
....".......,,
j
Z
framework viewed along [100]
Idealized cell data:
tetragonal, I - 4 m 2 , a - 7.2/k, c - 12.0A.
Coordination sequences and vertex symbols:
T~ (8,.m.)
4
T~(2,4m2)4
9
8
Secondary building units"
19
20
40
40
4-1
Composite building units:
lov
"PSI:
Materials with this framework type:
• Nabesite ~
55
52
80
82
115
116
138
132
183
184
229
236
260
252
328
322
3.4.8.94.8.94
3-3.94.94.94.94
237
Type Material Data
Nabesite
Crystal chemical data:
NAB
INas (H2O),J [Be4Si,6040I-NAB
orthorhombic, P2~2~2~, a - 9.748A, b - 10.133,~, c - 11.954,~ ~)
(Relationship to unit cell of Framework Type:
a ' = av/2, b ' = by/2, c' = c
or, as vectors, a ' = a + b, b ' = b - a, e ' = e)
Stability:
reversable dehydration ~
Framework density:
16.9 T/1000A 3
Channels:
[110192.7x4.1"~
9-ring viewed along [110]
[110193.0x4.6"
9-ring viewed along [ 110 ]
References"
(1)
Petersen, O.V., Giester, G., Brandst~itter, F. and Niedermayr, G. Can. Mineral., 40, 173-181 (2002)
238
NAT
1411amd
Framework Type Data
',~i/NI
<ti\
zx|z~\
ii\
..............................
ii
,
i
¢
<.'.'~?.
•%::....
Z
framework viewed normal to [001]
Idealized cell data:
tetragonal, I41/amd (origin choice 2), a - 13.9, c - 6.4
Coordination sequences and vertex symbols:
T, (16,m)
4
T2 ( 4 , 4 m 2 ) 4
9
8
19
18
Secondary building units:
35
36
52
56
78
66
106
116
139
140
179
154
213
232
4.82.4.82.42-84
42"42"84"84"84-84
4=1
Composite building units"
nat
Materials with this framework type"
*Natrolite ~1'2)
[A1-Ge-O]-NAT °)
[ G a - S i - O ] - N A T ~4)
IRb-I[Ga-Ge-O]-NAT ~5)
Gonnardite ~6)
High natrolite ~7~
Mesolite ~8'9~
Metanatrolite~°)
Paranatrolite ~
Scolecite(8'12-14)
Synthetic gonnardite ~15~
Synthetic mesolite ~16~
Synthetic natrolite ~6~
Synthetic scolecite ~16~
Tetranatrolite~7)
239
Type Material Data
Natrolite
Crystal chemical data:
NAT
INa,~ (H20)~61 [A1,6Siz4080]-NAT
orthorhombic, Fdd2, a - 18.30,~, b - 18.63,~, c - 6.60A ~2)
(Relationship to unit cell of Framework Type:
a ' = b ' = av/2, c ' = c
or, as vectors, a ' = a + b, b ' = b - a, c ' = c)
Framework density"
17.8 T/1000A 3
Channels:
<100> 8 2.6 x 3.9** ~ [001] 9 2.5 x 4.1"
(variable due to considerable flexibility of framework)
8-ring viewed along <100>
9-ring viewed along [001]
References:
(1) Pauling, L. Proc. Natl. Acad. Sci., 16, 453-459 (1930)
(2) Meier, W.M.Z. Kristallogr., 113, 430-444 (1960)
(3) Tripathi, A., Johnson, G.M., Kim, S.J. and Parise, J.B.J. Mater. Chem., 10, 451-455 (2000)
(4) Xie, D., Newsam, J.M., Yang, J. and Yelong, W.B. MRS Sym. Proc., 111, pp. 147-154 (1988)
(5) Klaska, K.H. and Jarchow, O. Z. Kristallogr., 172, 167-174 (1985)
(6) Mazzi, F., Larsen, A.O., Gottardi, G. and Galli, E. N. Jb. Miner. Mh., 219-228 (1986)
(7) Baur, W.H. and Joswig, W. N. Jb. Miner. Mh., 171-187 (1996)
(8) Taylor, W.H., Meek, C.A. and Jackson, W.W.Z. Kristallogr., 84, 373-398 (1933)
(9) Artioli, G., Smith, J.V. and Pluth, J.J. Acta Crystallogr., C42, 937-942 (1986)
(10) Joswig, W. and Baur, W.H.N. Jb. Miner. Mh., 26-38 (1995)
(11) Seryotkin, Y.V., Bakakin, V.V. and Belitsky, I.A. Eur. J. Mineral., 16, 545-550 (2004)
(12) F~ilth, L. and Hansen, S. Acta Crystallogr., B35, 1877-1880 (1979)
(13) Smith, J.V., Pluth, J.J., Artioli, Co. and Ross, F.K. Proc. 6th Int. Zeolite Conf., pp. 842-850 (1984)
(14) Stuckenschmidt, E., Joswig, W., Baur, W.H. and Hofmeister, W. Phys. Chem. Mineral., 24, 403-410
(1997)
(15) Ghobarkar, H. and Schaef, O. Zeolites, 19, 259-261 (1997)
(16) Ghobarkar, H. and Schaef, O. Cryst. Res. Technol., 31, K67-69 (1996)
(17) Evans, H.T., Konnert, J.A., Ross, M. Am. Mineral., 85, 1808-1815 (2000)
240
NES
Fmmm
Framework Type Data
x
framework viewed along [01 O]
Idealized cell data"
orthorhombic, F m m m , a - 26.1A, b - 13.9A, c - 22.9A
Coordination sequences and vertex symbols:
T 1(32,1)
T 2(32,1)
4
4
T 3 (16,m)
4
T 4(16,m)
4
T 5(16,m)
4
T 6(16,m)
4
T 7(8,mm2) 4
11
12
12
12
11
12
12
Secondary building units:
21
22
20
20
24
22
24
36
38
34
31
40
35
32
58
57
57
57
63
55
50
89
86
88
84
86
83
88
123
118
125
118
114
119
120
see C o m p e n d i u m
Composite building units:
cas
non
Materials with this framework type"
• NU_87 (~
Gottardiite ~2~
ton
157
152
158
150
158
151
152
187
196
192
187
208
184
180
237
245
224
237
255
237
226
4.6.5.52.10
5.5.5.62.5.10
5.52.5.52.122"*
5.5-5.5.5.62
4.10"5"5"5"5
5.52.5.6.5.6
5.5.5.5.126-*
241
Type Material Data
Type Material- NU-87
Crystal chemical data:
IH4 (H~O).I [A14Si640136]-NES
monoclinic, P2/c
a - 14.324.~, b - 22.376A, c - 25.092A, ~3- 151.51 ° ~
(Relationship to unit cell of Framework Type:
a ' = b/(2sin~3'), b ' = c, c ' = a
or, as vectors, a ' = (b - a)/2, b ' = c, c ' = a)
Framework density:
17.7 T/1000A 3
Channels:
[100] 10 4.8 x 5.7**
.- .
.
.
.
:.
1O-ring along [100]
References:
(1) Shannon, M.D., Casci, J.L., Cox, P.A. and Andrews, S.J. Nature, 353, 417-420 (199 l)
(2) Alberti, A., Vezzalini, G., Galli, E. and Quartieri, S. Eur. J. Mineral., 8, 69-75 (1996)
NES
242
NON
Framework Type Data
Fmmm
z
x&
framework viewed along [001]
Idealized cell data:
orthorhombic, Fmmm, a - 22.9A, b - 15.7/k, c - 13.9A
Coordination sequences and vertex symbols:
r 1 (32,1)
4
T~ (16,m)
4
T 3 (16,m)
4
T 4 (16,m)
4
T 5 (8,2mm) 4
12
12
11
12
12
Secondary building units"
25
24
23
24
24
42
39
44
41
40
95
99
95
97
92
see Compendium
Composite building units:
t/Or/
Materials with this framework type:
• Nonasil (~
[ B - S i - O ] - N O N (2)
I(Co(CsH5)z)4 F4l[si880176] -sOs(3~
CF_3 (4~
ZSM_51 (5~
67
64
72
65
62
133
130
124
133
142
174
174
170
173
166
219
217
229
212
214
273
262
279
267
262
5.6.5.6.5-6
5.6.5.6.5.62
4-6.5.5.5-5
5.52.5.6.5.6
5.5.5.5.122.*
243
Nonasil
Type Material Data
NON
Crystal chemical data:
I (CsH,3N)4I [SissO,76]-NON
CsH13N = 2-aminopentane
orthorhombic, F m m m , a - 22.232.&, b - 15.058A, c - 13.627~. ¢~)
Framework density"
19.3 T/1000A 3
Channels:
apertures formed by 6-rings only
References:
(1) Marler, B., Dehnbostel, N., Eulert, H.-H., Gies, H. and Liebau, F. J. Incl. Phenom., 4, 339-349 (1986)
(2) Marler, B. and Gies, H. Zeolites, 15, 517-525 (1995)
(3) Vandegoor, G., Freyhardt, C.C. and Behrens, P. Z. anorg, allg. Chemie, 621, 311-322 (1999)
(4) Long,Y.-C., Zhong, W. and Shen, X. J. Incl. Phenom., 4, 121-127 (1986)
(5) Rohrbaugh, W.J. private communication
244
NPO
P6Jmmc
Framework Type Data
X
F
Y
framework viewed along [001]
Idealized cell data:
hexagonal, P63/mmc, a - 9.1A, c - 5.3/k
Coordination sequences and vertex symbols:
T~ (6,mm2) 4
10
Secondary building units"
20
34
3
Materials with this framework type:
*Nitridophosphate- 1~
58
82
108
144
186
222
268
330
3"62"6"6"6"6
245
N itridop h osp hate- 1
Crystal chemical data:
Type Material Data
NPO
ILi~H,2+y+~Clxl [P,2OyN24y]-NPO
with 6 < x < 9, 2 < y < 4 a n d 2 < z < 3
orthorhombic, P n a 2 , , a - 4.753~., b - 14.208A, c - 8.203A, ¢~)
(Relationship to unit cell of Framework Type:
a' = c, b' = a x / 3 , c' = b
or, as vectors, a ' = c, b ' = 2a + b, c ' = b)
Framework density:
21.7 T/1000/~ 3
Channels:
[100] 12 3.3 x 4.4*
12-ring viewed along [100]
References:
(1)
Correll, S., Oeckler, O., Stock, N. and Schnick, W. Angew. Chem., Int. Ed., 42, 3549-3552 (2003)
246
NS!
Fr__aarneworkType ata
C21m
X
framework viewed along [01 O]
Idealized cell data:
monoclinic, C2/m, a - 14.l/k, b - 5.3A, c - 8.9/k, ~ - 105.4 °
Coordination sequences and vertex symbols:
T 1(4,m)
T 2(4,m)
T 3(4,m)
4
4
4
12
12
12
Secondary building units:
23
26
23
42
43
40
70
64
68
93
99
95
126
133
123
5-1
Composite building units"
cas
bik
Materials with this framework type:
*Nu-6(2) ~
EU-20b ( C A S - N S I structural intermediate) a~
172
161
169
216
210
217
255
274
256
314
318
310
385
364
383
5.6.5.6.52.6
5.6.5.6.62.8 ~
5.5.5.5.6.82
247
Nu-6(2)
Type Material Data
Crystal chemical data:
NSI
[Si24048]-NSI
monoclinic, P2/a
a - 17.257A, b - 4.988A, c - 13.848A, ~ - 106.1 ° ~
(Relationship to unit cell of Framework Type: a ' = 2c, b ' = b, c ' = a)
Framework density:
21 T/1000A 3
Channels:
[010] 8 2.6 x 4.5"1 [01o] 8 2.4 x 4.8,
8-ring viewed along [010]
2nd 8-ring viewed along [010]
References:
(1) Zanardi, S., Alberti, A., Cruciani, G., Corma, A., Forn6s, V. and Brunelli, M. Angew. Chem., Int. Ed., 43,
4933-4937 (2004)
(2) Marler, B., Camblor, M.A. and Gies, H. Microporous Mesoporous Mat., 90, 87-101 (2006)
248
OBW
Framework Type Data
141mmm
z
framework viewed normal to [001]
Idealized cell data:
tetragonal, I4/mmm, a - 13.9A, c - 30.8/k
Coordination sequences and vertex symbols:
T~ (32,1)
4
T 2(16,.m.) 4
T 3(16,..m) 4
T 4 (8,m.2m) 4
T 5(4,4m2) 4
m
8
8
8
9
8
Secondary building units:
16
16
17
18
16
30
30
30
32
32
VSV
Materials with this framework type:
• OSB_2 ¢~,2)
69
67
69
64
72
see Compendium
Composite building units"
lov
45
50
43
46
52
95
93
97
93
90
126
122
124
130
120
162
154
174
170
160
194
204
195
214
208
242
256
229
247
264
295
292
305
260
320
3.3.8.8.8.10
3.3.8.10-8-10
3.3.8.8-8.8
3.4-8-8-8.8
3.3.10.10.10.10
249
OBW
Type Material Data
OSB-2
Crystal chemical data:
IK44(n:o)~ol [Bez:Si5401j-OBW
tetragonal, I4/mmm, a - 13.7452A, c - 30.654A (2)
Stability:
NH4-exchanged form not stable to heating (2)
Framework density:
13.1 T/1000/k 3
Channels:
{<110> 10 5.0 x 5.0** ~ ([001] 8 3.4 x 3.4* + <101> 8 2.8 x 4.0**)
+-+ <100> 8 3.3 x 3.4**}***
lO-ring viewed along [l lO]
:: i
.....
~i~
.~ 3.4
i
':~: ~:i~
.~
8-ring viewed along [001]
~!~
.-:: :
::%
~..,~...............
.
~:%
. . . . . . . . . . . . . . . .
8-ring viewed along [101]
8-ring viewed along [100]
References:
(1)
(2)
Cheetham, A.K., Fjellvfig, H., Gier, T.E., Kongshaug, K.O., Lillerud, K.P. and Stucky, G.D. Stud. Surf. Sci.
Catal., 135, 158 (2001)
Lillerud, K.P. private communication
250
OFF
m
Framework Type Data
P6m2
Z
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
hexagonal, P - 6 m 2 , a - 13.1,~, c - 7.6/k
Coordination sequences and vertex symbols"
T~ (12,1)
T 2(6,m)
4
4
9
10
17
20
30
32
50
46
75
66
98
94
118
128
Secondary building units:
6 or 4-2
Framework description"
AAB sequence of 6-rings
144
162
4.4.4.6.6.8
4.8.4.8.6.6
185
192
Composite building units:
dsc
d6r
can
gme
o esawoo
Materials with this framework type:
• Offretite ~'4~
LZ_217 ~5~
Linde T ( E R I - O F F structural intermediate) ~6~
Synthetic offretite ~7~
TMA_O ~8~
251
Offretite
Type Material Data
Crystal chemical data:
I (Ca,Mg),.sK (H20),41 [A14Si,403J-OFF
hexagonal, P 6 m 2 , a - 13.291A, c - 7.582A ~2~
Framework density:
15.5 T/1000A 3
Channels:
[001] 12 6.7 x 6.8* ~-~ 3_ [001] 8 3.6 x 4.9**
6.7
i
12-ring viewed along [OOl]
8-ring viewed normal to [001]
References:
Bennett, J.M. and Gard, J.A. Nature, 214, 1005-1006 (1967)
(2) Gard, J.A. and Tait, J.M. Acta C~stallogr., B28, 825-834 (1972)
Mortier, W.J., Pluth, J.J. and Smith, J.V.Z. Kristallogr. 143, 319-332 (1976)
(4) Alberti, A., Cruciani, G., Galli, E. and Vezzalini, G. Zeolites, 17, 457-461 (1996)
(5) Breck, D.W. and Skeels, G.W.U.S. Patent 4,503,023 (1985)
(6) Breck, D.W. Zeolite Molecular Sieves, p. 173 (1974)
(7) Ghobarkar, H. and Schaef, O. Cryst. Res. Technol., 31, K29-31 (1996)
(8) Aiello, R., Barrer, R.M., Davies, J.A. and Kerr, I.S. Trans. Faraday Soc., 66, 1610-1617 (1970)
OFF
253
UiO-6
Type Material Data
OSI
Crystal chemical data:
[Al16P16064]-OSI
orthorhombic, Imm2, a - 18.355A, b - 18.321A, c - 5.053A (l~
F r a m e w o r k density:
18.8 T/1000A 3
Channels:
[001] 12 5.2 x 6.0*
12-ring viewed along [001]
References:
(1) Akporiaye, D.E., Fjellvag, H., Halvorsen, E.N., Haug, T., Karlsson, A. and Lillerud, K.P. Chem. Commun.,
1553-1554 (1996)
254
OSO
Framework Type Data
P6222
x
F
y
framework viewed along [001]
Idealized cell data:
hexagonal, P6222, a - 10.l/k, c - 7.6/k
Coordination sequences and vertex symbols:
T 1(6,2)
T 2(3,222)
4
4
8
8
Secondary building units:
16
16
29
30
70
76
see Compendium
Composite building units:
lov
Y
Materials with this framework type:
* O S B - 1o,2)
46
44
101
92
118
130
162
148
190
202
3.3.8.8.8-141o
3-3-8-8.147-147
255
OSB-1
Type Material Data
Crystal chemical data:
OSO
IK~(H~O)91[Be3Si60~s]-OSO
trigonal, P32, a - 10.093A, c - 7.626A (~)
Framework density:
13.4 T/1000/~ 3
Channels:
[001] 14 5.4 x 7.3* ~ l [001] 8 2.8 x 3.3**
•
i5.4
puckered 14-ring viewed along [OO1]
8-ring viewed normal to [001]
References:
(1)
(2)
Kongshaug, K.O., Fjellv~g, H., Lillerud, K.P., Gier, T.E., Stucky, G.D. and Cheetham, A.K. private
communication
Cheetham, A.K., Fjellvfig, H., Gier, T.E., Kongshaug, K.O., Lillerud, K.P. and Stucky, G.D. Stud. Surf Sci.
Catal., 135, 158 (2001 )
256
OWE
Framework Type Data
Pmma
Z
framework viewed along [01O]
Idealized cell data:
orthorhombic, Pmma, a - 14.4A, b - 7.2A, c - 9.1/k
Coordination sequences and vertex symbols"
T~(8,1)
T 2(4,.m.)
T~(4,.m.)
4
4
4
9
9
11
Secondary building units:
18
19
22
35
34
32
4 or 4-4-
Composite building units:
dsc
sti
doublechainSaWtooth
Materials with this framework type:
• U i 0 _ 2 8 (1)
ACP_2 (2)
57
52
49
76
75
77
96
99
109
128
129
139
172
172
163
216
215
197
252
250
250
290
288
310
4.4.4.83.62.82
4.62.4.62.4.82
4.82.62.82.62.82
258
-PAR
Framework Type Data
C21c
x
framework viewed along [001]
Idealized cell data:
monoclinic, C2/c, a - 20.9/k, b - 9.2/k, c - 8.6/k, 3 - 89.7°
C o o r d i n a t i o n s e q u e n c e s a n d vertex symbols:
T~ (8,1)
4
9
18
31
48
71
T:(8,1)
4
9
19
33
51
77
T 3(8,1)
4
10
19
33
52
72
T 4 (8,1)
3
8
16
29
49
68
Secondary building units:
4
M a t e r i a l s with this f r a m e w o r k type"
*Partheite ~)
99
96
102
94
132
126
126
123
162
162
161
162
197
203
204
203
4-6.6.6.6.102
4.6-4-82.6-62
4.62.4.82.82-10
4.6-62
260
PAU
Framework Type Data
Im3m
x
framework viewed along [001]
Idealized cell data:
cubic, Im-3m, a - 34.8/k
Coordination sequences and vertex symbols"
see Appendix A for a list of the coordination sequences and vertex symbols for the 8 T-atoms
Secondary building units:
4or8
Composite building units"
pau
d8r
Materials with this framework type:
•
(12)
*Paulingite '
[Ga-Si-O]-PAU ~3~
ECR- 18 ~4'5~
Paulingite, Vinaricka Hora ~6)
lta
261
Paulingite
PAU
Type Material Data
Crystal chemical data:
I (Ca,K~_,Na2)~6(H20)7oo1 [A1,52Si52oO,344]-PAU
cubic, Im-3m, a - 35.093A, ~
Framework density:
15.5 T/1000,~ 3
Channels"
<100> 8 3.6x3.6"** I <100> 8 3.6 x 3.6***
3.6
!
....
3.6
8-ring viewed along <100>
References:
(1) Gordon, E.K., Samson, S. and Kamb, W.K. Science, 154, 1004-1007 (1966)
(2) Bieniok, A. Natural Zeolites for the Third Millennium, 53-60 (2000)
(3) Kim, D.J., Shin, C.H. and Hong, S.B. Microporous Mesoporous Mat., 83, 319-325 (2005)
(4) Vaughan, D.E.W. and Strohmaier, G. U.S. Patent 4,661,332 (1987)
(5) Vaughan, D.E.W. and Strohmaier, K.G. Microporous Mesoporous Mat., 28, 233-239 (1999)
(6) Lengauer, C.L., Giester, G. and Tillmanns, E. Mineral. Mag., 61,591-606 (1997)
262
PHI
Framework Type Data
~
~Y
z~
...........
?
~
...........
~
'
~ '~/7~ ~
A:;¢~
JJ
.,.y
........S
i
~ii
,:¢Y
Cmcm
,:
"'
...."
x
framework viewed along [001]
Idealized cell data:
o r t h o r h o m b i c , Cmcm, a - 9.9/k, b - 14. l/k, c - 14.0/k
Coordination sequences and vertex symbols"
T 1(16,1)
T 2(16,1)
4
4
9
9
Secondary building units:
18
18
32
32
50
48
71
68
94
96
122
126
157
155
195
191
8or4
Composite building units:
dec
double
crankshaft chain
Materials with this framework type:
*Phillipsite(l'2)
[ A 1 - C o - P - O ] - P H I <3~
D A F _ 8 ~4)
H a r m o t o m e (2,5)
Wellsite ~6~
ZK_19 °~
4.4-4-82-8.8
4-4.4.82.8.8
263
Type Material Data
Phillipsite
C r y s t a l c h e m i c a l data:
PHI
IK~ (Ca,Na2)2 (H20),2[ [A16SiI0032]-PHI
monoclinic, P2/m
a - 9.865.A,, b - 14.300.A,, c - 8.668.~, ~3- 124.20 °~2)
(Relationship to unit cell of Framework Type:
a ' = a, b ' = c, c ' = b/(2sin(3'))
or, as vectors, a ' = a, b ' = c, c ' = (b - a)/2)
F r a m e w o r k density:
15.8 T / 1 0 0 0 A 3
Channels:
[100] 8 3.8 x 3.8* +-+ [010] 8 3.0 x 4.3* +-+ [001] 8 3.2 x 3.3*
....3.8 .........
3.8
'
........
8-ring viewed along [100]
8-ring viewed along [010]
8-ring viewed along [001]
References:
(1)
(2)
(3)
(4)
(5)
(6)
(7)
Steinfink, H. Acta Crystallogr., 15, 644-651 (1962)
Rinaldi, R., Pluth, J.J. and Smith, J.V. Acta Crystallogr., B30, 2426-2433 (1974)
Feng, P., Bu, X. and Stucky, G.D. Nature, 388, 735-741 (1997)
Barrett, P.A., Sankar, G., Stephenson, R., Catlow, C.R.A., Thomas, J.M., Jones, R.H. and Teat, S.J. Solid
State Sci., 8, 337-341 (2006)
Sadanaga, R., Marumo, F. and Yak6uchi, Y. Acta Crystallogr., 14, 1153-1163 (1961)
Cerny, P., Rinaldi, R. and Surdam, R.C.N. Jb. Miner. Abh., 128, 312-330 (1977)
Kuehl, G.H. Am. Mineral., 54, 1607-1612 (1969)
264
PON
Pca2.,
Framework Type Data
. . . . . .
2222;22J
y
framework viewed along [100]
Idealized cell data:
orthorhombic, Pca21, a - 8.9/k, b - 9.2A, c - 16.1A
Coordination sequences and vertex symbols:
Tl(4,1 )
T2(4,1 )
T3(4,1 )
T,(4,1)
T5(4,1 )
T6(4,1 )
4
4
4
4
4
4
10
10
10
11
9
10
Secondary building units"
20
20
19
20
18
21
36
34
34
34
34
38
4-2
Materials with this framework type:
• IST_I (1~
56
54
56
55
54
57
76
82
78
83
75
76
105
108
106
110
104
105
144
134
144
136
142
146
180
175
179
176
176
182
215
224
211
227
211
212
260
264
262
264
260
262
323
304
321
304
319
325
4.6.4.6.6.8
4.6.4-6-62.107
4.6.4.62.63.64
4.6.6-62-64.107
4.4.4.6.6.63
4.6.4.6.62.8
265
IST-1
Type Material Data
PON
Crystal chemical data"
I(CH3NH3)4 (CH3NH2) 4 (OH)4I [A1jePleO48]-PON
orthorhombic, Pca2j, a - 9.6152A, b - 8.6702A, c - 16.2196A (1)
Framework density:
17.7 T/1000A 3
Channels:
[100] 10 5.0 x 5.3*
lO-ring viewed along [100]
References:
(1) Jorda, J.L., McCusker, L.B., Baerlocher, Ch., Morais, C.M., Rocha, J., Fernandez, C., Borges, C.,
Lourenco, J.P., Ribeiro, M.F. and Gabelica, Z. Microporous Mesoporous Mat., 65, 43-57 (2003)
266
RHO
D
Framework Type Data
Im3m
i
Z
~.Y
framework viewed along [100]
Idealized cell data:
cubic, I m - 3 m , a - 14.9/k
Coordination sequences and vertex symbols:
T, (48,2)
4
9
Secondary building units:
17
28
42
60
81
105
132
162
8-8 or 8 or 6 or 4
Composite building units:
dSr
lta
i
Materials with this framework type:
,Rho (1,2)
[Mn-A1-P-O]-RHO (5~
[ B e - A s - O ] - R H O (3)
[ B e - P - O ] - R H O (4)
[Co-A1-P-O]-RHO (5~
[Mg-A1-P-O]-RHO (5~
Gallosilicate ECR- 10 (7~
LZ_214 (8~
Pahasapaite(9'~°~
[Nal6 Cs8[[A124Ge24096]-RHO(6)
4.4.4.6.8.8
267
Rho
Type Material Data
Crystal chemical data:
I(Na,Cs),2 (H~O)~I [A1,2Si~Oj-RHO
cubic, lm-3m, a - 15.031A (2)
Framework density:
14.1 T/1000A 3
Channels:
<100> 8 3.6 x 3.6*** [ <100> 8 3.6 x 3.6***
• :..
RHO
>
3.6
8-ring viewed along < 100>
References:
(1) Robson, H.E., Shoemaker, D.P., Ogilvie, R.A. and Manor, P.C. Adv. Chem. Set., 121, 106-115 (1973)
(2) McCusker, L.B. and Baerlocher, Ch. Proc. 6th Int. Zeolite Conf., pp. 812-822 (1984)
(3) Gier, T.E. and Stucky, G.D. Nature, 349, 508-510 (1991)
(4) Harvey, G. and Meier, W.M. Stud. Surf. Sci. Catal., 49, 411-420 (1989)
(5) Feng, P., Bu, X. and Stucky, G.D. Microporous Mesoporous Mat., 23, 315-322 (1998)
(6) Johnson, G.M., Tripathi, A. and Parise, J.B. Microporous Mesoporous Mat., 28, 139-154 (1999)
(7) Newsam, J.M., Vaughan, D.E.W. and Strohmaier, K.G.J. Phys. Chem., 99, 9924-9932 (1995)
(8) Breck, D.W. and Skeels, G.W.U.S. Patent 4,503,023 (1985)
(9) Rouse, R.C., Peacor, D.R., Dunn, P.J., Campbell, T.J., Roberts, W.L., Wicks, F.J. and Newbury, D. N. Jb.
Miner. Mh., 433-440 (1987)
(10) Rouse, R.C., Peacor, D.R. and Merlino, S. Am. Mineral., 74, 1195-1202 (1989)
268
-RON
Framework Type Data
141mcm
U
Y
x
framework viewed along [001]
Idealized cell data:
tetragonal, I4/mcm, a - 18.l/k, c - 9.0/k
Coordination sequences and vertex symbols:
T~ (16,m)
4
T 2(16,m)
4
T 3(16,2)
4
T 4(8,m.2m)2
7
10
10
4
17
20
16
10
31
31
31
24
49
47
56
38
76
78
67
58
Secondary building units:
see Compendium
Composite building units:
vsv
lau
Materials with this framework type:
*Roggianite ~1)
98
109
94
91
125
127
146
110
170
162
164
138
208
212
188
194
3.4.104.*.104.*
4.4.6.6.6.6
4.4.62.104.102.102
3
269
Roggianite
Type Material Data
Crystal chemical data:
[Cal6 (H20),91 [A1,6BesSi32 O,04 (oOH)16]--RON
tetragonal, I4/mcm, a - 18.33A, c - 9.16.& (~)
F r a m e w o r k density:
18.2 T/1000,& 3
Channels:
[001 ] 12 4.3 x 4.3"
12-ring viewed along [OOl]
References:
(1) Giuseppetti, G., Mazzi, F., Tadini, C. and Galli, E. N. Jb. Miner. Mh., 7, 307-314 (1991)
-RON
270
RRO
P21c
Framework Type Data
I<......................
..~,
.,
x~__~ y
Z
framework viewed along [100]
Idealized cell data:
monoclinic, P2/c, a - 7.4A,, b - 8.6*, c - 17.2/k, ~ - 113.7 °
Coordination sequences and vertex symbols:
4
4
4
4
4
T 1 (4,1)
T 2(4,1)
T 3 (4,1)
T 4 (4,1)
T 5(2,2)
11
10
11
10
12
Secondary building units:
23
19
21
20
18
40
37
36
34
34
4-4= 1
Composite building units"
bre
Materials with this framework type:
*RUB-41 m
56
59
62
62
62
83
86
90
86
90
130
111
111
108
112
163
149
148
150
136
182
201
203
201
198
226
241
252
242
264
300
281
285
285
286
371
340
331
329
314
4.8-5-8.5.104
4.5.4-8-5.5
4.5-5.5-5-103
4.5-4.5.5-8
5.5.52.52.10.103
271
RUB-41
Type Material Data
Crystal chemical data"
[Si18036]-RRO
monoclinic, P2/c
a-
7.345 A, b - 8.724 A, c - 17.152 A, 3 - 114.2°¢')
Framework density:
18 T/1000,~ 3
Channels:
[100] 10 4.0 x 6.5* +-+ [001] 8 2.7 x 5.0*
1O-ring viewed along [100]
8-ring viewed along [001]
References:
(1) Wang, Y., Marler, B., Gies, H. and Mtiller, U. Chem. Mater., 17, 43-49 (2005)
RRO
272
RSN
Framework Type Data
Cmmm
Y
framework viewed along [001]
Idealized cell data:
orthorhombic, Cmmm, a - 7.2/k, b - 41.9/k, c - 7.2A
Coordination sequences and vertex symbols:
4
T~ (8,m..)
4
T 3 (8,m..)
4
T 4 (8,..m)
4
T 5 (4,m2m) 4
T 1 (8,..m)
9
10
9
11
8
Secondary building units:
19
21
21
21
20
39
37
42
40
44
VSV
Materials with this framework type:
• RUB_17 ~)
78
91
82
89
80
see Compendium
Composite building units:
lov
59
58
57
61
55
117
117
119
116
118
155
144
151
145
152
189
194
188
191
204
235
241
239
239
228
288
287
277
294
272
330
343
345
339
354
3"4"83"94"83"94
4.4.62"8-62"8
3"4"82"94"82"94
4"5~'5"8"5"8
3"3"94"94"94"94
273
Type Material Data
RUB-17
Crystal chemical data:
RSN
IK4Na,2 (H20)lsl [ZnsSi28072]-RSN
monoclinic, Cm, a - 7.238/k, b - 40.56/k, c - 7.308/k, ~ - 91.8 ° ~)
Stability"
Complete dehydration leads to destruction of the framework (~
Framework density"
16.8 T/1000A 3
Channels:
[100] 9 3.3 x 4.4* +-+ [001] 9 3.1 x 4.3* +-+[010] 8 3.4 x 4.1"
9-ring viewed along [001]
9-ring viewed along [100]
8-ring viewed along [010]
References:
(1) R6hrig, C. and Gies, H. Angew. Chem., Int. Ed., 34, 63-65 (1995)
274
RTE
/
i
/
/
/
C21m
Framework Type Data
/
/
z
x
framework viewed normal to [001 ] (upper right: projection down [001 ])
Idealized cell data:
monoclinic, C2/m, a - 14.1A, b - 13.7A, c - 7.4,~, ~ - 102.4 °
Coordination sequences and vertex symbols"
T, (8,1)
T 2(8,1)
T 3(8,1)
4
4
4
10
10
11
Secondary building units:
19
22
21
33
37
35
6 or 5-1
Composite building units"
rte
Materials with this framework type:
• RUB_3 ~,2)
56
54
57
81
79
80
105
108
106
136
140
139
175
176
176
219
215
218
4-5.4-6-5.6
4-4.5-8.6.6
4.5.5.6-6.8
275
RUB-3
Crystal chemical data:
RTE
Type Material Data
[ (C8H,~N)2[ [Si24048]-RTE
CsH~sN = exo-2-aminobicyclo[2.2.1.]heptane
monoclinic, C2/m
a - 14.039A, b - 13.602A, c - 7 . 4 2 8 * , ~3 -
Framework density:
17.3 T/1000A 3
Channels:
[001] 8 3.7 x 4.4*
~
102.22 ° (1~
.~.
4.4
8-ring viewed along [001]
References:
(1)
(2)
Marler, B., Grtinewald-Luke, A. and Gies, H. Zeolites, 15, 388-399 (1995)
Marler, B., Grfinewald-Ltike, A. and Gies, H. Microporous Mesoporous Mat., 26, 49-59 (1998)
276
RTH
Framework Type Data
C21m
y
framework viewed along [001]
Idealized cell data"
m o n o c l i n i c , C2/m, a - 9.8/k, b - 20.5/~,, c - 10.0A., ~3 - 96.9 °
Coordination sequences and vertex symbols:
T 1 (8,1)
T 2(8,1)
T 3(8,1)
T 4 (8,1)
4
4
4
4
11
10
10
10
Secondary building units:
21
21
19
18
34
36
31
31
53
54
50
55
78
75
82
77
108
100
106
103
4
Composite building units:
rth
Materials with this framework type"
• RUB_13 ~
S S Z - 3 6 ( I T E - R T H structural intermediate) ~2~
S S Z - 5 0 ( [ A 1 - S i - O ] - R T H ) ~3~
137
136
130
134
165
181
168
165
207
214
203
214
4.6.5-6-5.8
4.4.5.8.5.8
4.5-4.6.5.5
4.5.4.8.5.5
277
RTH
Type Material Data
RUB-13
Crystal chemical data:
I (C,oH~_,N)2[ [B2Si3oOj-RTH
CjoH2,N = pentamethylpiperidinium
monoclinic, C2/m
a-
9.659A, b -
20.461A, c -
9.831A, 3 -
F r a m e w o r k density:
16.6 T/1000A 3
Channels:
[ 100] 8 3.8 x 4.1 * +--+ [001 ] 8 2.5 x 5.6*
'::
8-ring viewed along [ 100]
96.58°(')
2:
8-ring viewed along [001]
References:
(1) Vortmann, S., Marler, B., Gies, H. and Daniels, P. Microporous Materials, 4, 111-121 (1995)
(2) Wagner, P., Nakagawa, Y., Lee, G.S., Davis, M.E., Elomari, S., Medrud, R.C. and Zones, S.I.J. Am. Chem.
Soc., 122, 263-273 (2000)
(3) Lee, G.S. and Zones, S.I.J. Solid State Chem., 167, 289-298 (2002)
278
RUT
Framework Type Data
C21m
x
framework viewed along [001]
Idealized cell data:
monoclinic, C2/m, a - 13.2/k, b -
13.3/k, c -
12.5,~, 3 -
114.8°
Coordination sequences and vertex symbols:
T 1(8,1)
T 2(8,1)
T 3(8,1)
T 4(8,1)
T 5(4,2)
4
4
4
4
4
10
10
11
11
12
21
21
23
21
22
37
38
38
37
40
58
60
58
62
58
87
84
86
85
82
116
113
114
114
116
146
148
148
148
154
185
192
189
185
186
Secondary building units:
Composite building units:
rte
Materials with this framework type:
• RUB_10 (1)
ITMA-ItSi-O]-RUT
AI_Nu_I ~3~
B_Nu_I ~3)
Fe_Nu_ 1(3)
Ga_Nu_ 1(3)
Nu_l (4)
232
232
234
232
232
4.4.5.6.5-8
4.5.4-6.5.6
4.5-5-6-6.6
4.5.5.5.6-8
5.5-6.6-6.6
279
RUB-IO
Crystal chemical data:
Type Material Data
RUT
I (C4H12N)4I [B4Si32OTzl-RUT
C4HlzN = tetramethylammonium
monoclinic, P2/a
a - 13.112A, b - 12.903A, c - 12.407A, [3 - 113.50 °~
F r a m e w o r k density:
18.7 T/1000A 3
Channels:
apertures formed by 6-rings only
References:
(1) Gies, H. and Rius, J. Z. Kristallogr., 210, 475-480 (1995)
(2) Broach, R.W., McGuire, N.K., Chao, C.C. and Kirchner, R.M.J. Phys. Chem. Solids, 56, 1363-1368 (1995)
(3) Bellussi, G., Millini, R., Carati, A., Maddinelli, G. and Gervasini, A. Zeolites, 10, 642-649 (1990)
(4) Whittam, T.V. and Youll, B. U.S. Patent 4,060,590 (1977)
280
RWR
1411amd
Framework Type Data
U
Z
X
framework viewed along [01O]
Idealized cell data:
tetragonal, I4~/amd (origin choice 2), a - 7.8A, c - 27.3/k
Coordination sequences and vertex symbols:
T~ (16,.m.)
T~(16,..2)
4
4
12
11
Secondary building units:
24
23
42
42
6-2
Composite building units:
mot"
Materials with this framework type:
• RUB_24 ~,2~
68
66
97
94
133
133
180
173
221
218
277
280
334
328
394
393
5-6.5.6.5.62
4.52-6~.62-8-8
281
RUB-24
Crystal chemical data:
RWR
Type Material Data
[Si32064]-RWR
tetragonal, I 4 / a m d ,
a -
7.6677A, c - 27.0625/k ~2)
Stability:
stable at 900°C ~
Framework density:
20.1 T/1000.~ 3
Channels:
[~00] 8 2.8 x 5.0, II [0~0] 8 2.8 x 5.0*
(nonintersecting 1-d 8-ring channels)
..... S . O
,~,
~28~'
8-ring viewed along <100>
References:
(1) Marler, B., Str6ter, N. and Gies, H. Recent Research Reports, 14th IZC, Cape Town, South Africa, 15-16
(2004)
(2) Marler, B., Str6ter, N. and Gies, H. Microporous Mesoporous Mat., 83, 201-211 (2005)
282
RWY
Im3m
Framework Type Data
z
framework viewed along [100]
Idealized cell data:
cubic, Im-3m, a - 18.5/k
Coordination sequences and vertex symbols:
T~ (48,m)
4
6
Secondary building units:
12
17
28
8 or 3"1
M a t e r i a l s w i t h this f r a m e w o r k type:
• UCR_20 <~)
38
52
64
84
104
124
143
3-8.3.12.3-12
283
UCR-20
Crystal chemical data:
Type Material Data
RWY
I(C~H,~N.~,J [Ga32Ge,6S96]-RWY
C6H~sN4 - T A E A - tris(2-aminoethyl)amine
cubic, I 4 3 m , a - 20.9352A ~j~
Stability:
Stable when heated in air at 300°C for lh (ca 20% weight loss) or at
380°C in argon
F r a m e w o r k density:
5.2 T/1000A 3
Channels:
<111> 12 6.9 x 6.9***
1 2 - r i n g v i e w e d a l o n g < 111 >
References:
(1) Zheng, N., Bu, X., Wang, B. and Feng, P. S c i e n c e , 298, 2366-2369 (2002)
284
SAO
Framework Type Data
14m2
......
Z
frameworkviewedalong[100]
o
Idealized cell data:
o
tetragonal, I 4 m 2 , a - 13.4A, c - 21.9A
Coordination sequences and vertex symbols:
T~ (16,1)
T 2(16,1)
T 3(16,1)
T 4(8,2)
4
4
4
4
9
9
9
10
Secondary building units:
Composite building units:
dsc
16
17
16
16
25
27
25
25
39
40
39
42
61
61
58
61
84
85
79
82
124
132
130
132
4.4.4"62"63" 124
4.4.4.125.6.63
4.6.4.6-4.126
4.4-6-6.62.125
158
167
158
156
4
sti
lau
doublesawtooth~chain
~~)
Materials with this framework type:
• STA_I ~
102
106
104
108
aww
285
STA-1
SAO
Type Material Data
I(C=,H4oN=)=~(H20)61 [MgsAlz3PzsO,12I-SAO
C r y s t a l c h e m i c a l data:
C21H4oN2 = CvH13N - (CH:) 7 - CvH,3N
C7H~3N = quinuclidine
tetragonal, P-4n2, a - 13.810A, c - 21.969A (~)
Framework density:
13.4 T/1000A 3
Channels:
<100> 12 6.5 x 7.2** +-+ [001] 12 7.0 x 7.0*
,.-.
7.0
•
£2
,.
i
7.0
j
..........................
....,..
12-ring viewed along <100>
12-ring viewed along [001]
References:
(1)
Noble, G.W., Wright, P.A., Lighffoot, P., Morris, R.E., Hudson, K.J., Kvick, A. and Graafsma, H. Angew.
Chem., Int. Ed., 36, 81-83 (1997)
286
SAS
Framework Type Data
141mmm
X
framework viewed along [001]
o
Idealized cell data:
o
t e t r a g o n a l , I4/mmm, a - 14.3A, c - 10.4A
Coordination sequences and vertex symbols:
T, (16,m)
4
10
19
30
45
65
90
118
145
175
4.6.4-6-6.8
T 2(16,2)
4
9
17
30
48
68
87
109
142
184
4-4.4.6.6.6
Secondary building units:
6-2 or 4
Composite building units:
d6r
Materials with this framework type"
• STA_6 °)
SSZ_73 ~2~
287
STA-6
Type Material Data
SAS
Crystal chemical data:
l(C14H34N4),.5 (H20)2.51 [MggA1,3P,60641-SAS
C j4H32N4- 1,4,8,11 -tetrameth~yl- 1,4,8,11-tetraazatetradecane
tetragonal, P4/mnc, a - 14.282A, c - 10.249A (~)
F r a m e w o r k density:
15.3 T/1000A 3
Channels:
[001] 8 4.2 x 4.2*
8-ring viewed along [001]
References:
(1) Patinec, V., Wright, P.A., Lighffoot, P., Aitken, R.A. and Cox, P.A.J. Chem. Soc., Dalton Trans., 39093911 (1999)
(2) Zones, S., Burton, A. and Ong, K. U.S. Patent 7,138,099 (2006)
288
SAT
m
Framework Type Data
R3m
z
x~----~ y
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
trigonal, R-3m, a - 12.9A, c - 30.6/k
Coordination sequences and vertex symbols:
T, (36,1)
T2(36,1)
4
4
10
9
20
17
33
30
50
50
71
75
95
100
124
126
158
157
197
194
Secondary building units:
6or4
Framework description:
A B B C B C C A C A A B sequence of 6-rings
Composite building units:
d6r
can
Materials with this framework type"
• STA_2 ~
4.6.4-8-6.6
4.4-4.6.6-8
289
STA-2
Crystal chemical data:
Type Material Data
I(C,sH34N2)3(I4~O)~.~l [Mgs.4A13o.6P3601441-NAT
CtsH34N2 = C7H13N - (CH:) 4 - CTH13N
CTH~3N = quinuclidine
trigonal, R-3, a - 12.726 A, c - 30.939A (~
F r a m e w o r k density:
16.6 T/1000.~ 3
Channels:
_1_ [001] 8 3.0 x 5.5***
8-ring viewed normal to [001]
References:
(1) Noble, G.W., Wright, P.A. and Kvick, A. J. Chem. Soc., Dalton Trans., 4485-4490 (1997)
SAT
290
SAV
Framework Type Data
P41nmm
Iv
~
y
X
framework viewed along [001]
Idealized cell data"
tetragonal, P4/nmm (origin choice 2), a - 18.7A, c - 9.4A
Coordination sequences and vertex symbols:
T 1 (16,1)
T 2(16,1)
T 3(16,1)
4
4
4
9
9
9
Secondary building units:
17
17
17
29
29
29
65
65
63
88
88
84
6-6 or 6 or 4-2 or 4
Composite building units:
d6r
Materials with this framework type:
• Mg_STA_7 ~
Co_STA_7 ~
Zn_STA_7 ~
45
45
45
113
114
112
143
144
144
179
177
177
4.4.4.8.6.8
4-4.4.8.6.8
4-4.4-8-6.8
291
Mg-STA-7
Type Material Data
Crystal chemical data:
I(C,aH42N6),.96 (H20)71 [Mg4.sA1,9.2P24096]-SAV
CIsH42N6 = 1,4,7,10,13,16-hexamethyl1,4,7,10,13,16-hexaazacyclooctadecane
tetragonal, P4/n, a - 18.773,4,, c - 9.454A ~)
F r a m e w o r k density:
14.4 T/1000A 3
Channels:
<100> 8 3.8 x 3.8** +-+ [001] 8 3.9 x 3.9*
8-ring viewed along < 100>
SAV
8-ring viewed along [001]
References:
(1) Wright, P.A., Maple, M.J., Slawin, A.M.Z., Patinec, V., Aitken, R.A., Welsh, S. and Cox, P.A.J. Chem.
Soc., Dalton Trans., 1243-1248 (2000)
292
SBE
Framework Type Data
141mmm
Z
-,..
".... !
:
framework viewed along [100] (upper right: projection down [100])
Idealized cell data"
tetragonal, I4/mmm, a - 18.5A, c - 27.1A
Coordination sequences and vertex symbols:
T,(32,1)
T 2(32,1)
T 3(32,1)
T 4(32,1)
4
4
4
4
9
9
9
9
Secondary building units"
17
17
17
17
27
28
27
27
38
41
39
40
55
57
56
59
78
77
77
79
8or4
Composite building units:
d8r
sti
Materials with this framework type:
• UCSB_SCo
(1)
U C S B - 8 M g (1)
UCSB_8Mn ~
U C S B _ 8 Z n ~1~
atn
102
101
100
99
129
130
126
126
157
162
157
158
4.6.4.8-4-87
4"4"4"6"8"12
4.4.4.8.6.62
4.4-4-82-62-84
293
SBE
Type Material Data
UCSB-8Co
Crystal chemical data:
I (C~H:4N2),J [A132Co32P640256]-SBE
CgH2:N ~ = 1,9 d i a m i n o n o n a n e
tetragonal, P4/nnc, a - 19.065,~, c - 27.594 A (1)
Framework density:
12.8 T/1000A 3
Channels:
< 1 0 0 > 12 7.2 x 7.4** +-+ [001] 8 4.0 x 4.0*
4.o
...7.2
.
".~.....
!
4.0
•
12-ring viewed along < 100>
8-ring viewed along [001]
3.~ .......,i...........................
second 8-ring along [001]
References:
(1)
Bu, X., Feng, P. and Stucky, G.D. Science, 278, 2080-2085 (1997)
i
294
SBS
P6almmc
Framework Type Data
....................
z
"
,
i
:i!
i ~............. ...........,~
....
,i~
Z
framework viewed normal to [001] (upper right: projection down [001])
hexagonal, P63/mmc, a - 17.2/k, c - 27.3A
Idealized cell data:
Coordination sequences and vertex symbols:
T, (24,1)
T 2(24,1)
T 3(24,1)
T 4(24,1)
4
4
4
4
9
9
9
9
Secondary building units"
17
17
16
16
28
27
25
24
41
39
38
35
56
55
58
53
75
75
84
77
100
100
111
104
127
127
135
130
8or4
Composite building units"
sti
d6r
can
Materials with this framework type:
• U C S B - 6 G a C o <~
U C S B _ 6 C o ~l~
U C S B - 6 G a M g ~l)
U C S B - 6 G a Z n ~l)
UCSB-6Mg ~
UCSB_6Mn ~
UCSB_6Zn ~1)
157
156
157
153
195
192
182
178
233
230
215
213
4.4.4.126.62-84
4.4.4.8.6.62
4-4.4.6"6-12
4-6.4.6.4.87
295
Crystal chemical data:
SBS
Type Material Data
UCSB-6GaCo
I(C9H24N2)121[Gaz4C°24P48° 192]-SBS
CgH22N2 = 1,9-diaminononane
trigonal, P-31c, a - 17.836A, c - 27.182.31 ~)
Framework density:
12.8 T/1000/k 3
Channels:
[001] 12 6.8 x 6.8* ~ 2_ [001] 12 6.9 x 7.0**
"7
12-ring viewed along [001 ]
12-ring viewed normal to [001]
8-ring along [001 ]
References:
(1)
"
Bu, X., Feng, P. and Stucky, G.D. Science, 278, 2080-2085 (1997)
296
SBT
Framework Type Data
.........; .........................................
<
R3m
i
i
i'
)
,
~'
i
,//="
~.
Z
/,, ....
x ~1 ,~ y
,,a,., .....
-....,
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data"
trigonal, R-3m, a - 17.2A, c - 41.0A
Coordination sequences and vertex symbols:
T~ (36,1)
T 2(36,1)
T 3 (36,1)
4
4
4
4
T 4 (36,1)
9
9
9
9
Secondary building units"
16
17
17
16
25
28
27
24
38
41
39
35
58
56
55
53
84
75
75
77
4
Composite building units:
sti
d6r
Materials with this framework type:
*UCSB-10GaZn ~
U C S B - 1 0 C o a~
UCSB-10Mg ~
U C S B - 1 0 Z n °~
can
111
100
100
104
135
127
127
130
157
157
156
153
182
195
192
178
215
232
228
213
4-4.4.6.6.12
4.4.4.126.62.84
4.4.4.8.6.62
4.6.4.6.4.87
297
UCSB-IOGaZn
Type Material Data
Crystal chemical data:
I (C,oH26N203),81 [Ga36Zn36P7202j-SBT
C~oH26N203 = 4,7,10-trioxa- 1, 13-tridecanediammonium
trigonal, R-3,, a - 18.080A, c - 41.951A, (~
Framework density"
12.1 T / 1 0 0 0 * 3
Channels:
[001] 12 6.4 x 7.4 * ~ _1_ [001] 12 7.3 x 7.8**
7.4
i
7.4
12-ring viewed along [001]
12-ring viewed normal to [001]
8-ring viewed along [102]
References:
(1)
Bu, X., Feng, P. and Stucky, G.D. Science, 278, 2080-2085 (1997)
SBT
298
SFE
P211m
Framework Type Data
l
<
..................
~.....
~,,,...............
t~
y
framework viewed normal to [01 O] (upper right: projection down [010])
Idealized cell data:
monoclinic, P21/m, a - 11.5/k, b - 5.3/k, c - 14.0/k, ~ - 101 °
Coordination sequences and vertex symbols:
T~(2,m)
T2(2,m )
T3(2,m )
T4(2,m )
Ts(2,m )
T6(2,m )
TT(2,m )
4
4
4
4
4
4
4
12
10
10
12
12
12
12
20
19
20
22
22
24
23
37
35
35
36
37
37
41
62
58
57
56
55
54
58
82
86
83
86
83
80
78
Secondary building units:
see Compendium
Composite building units"
dzc
jbw
double zigzag
chain
Materials with this framework type:
• 58Z_48 (1)
114
108
116
114
120
117
111
mtt
142
144
141
150
149
158
154
192
183
181
179
177
184
198
238
233
230
232
227
219
235
278
287
284
283
288
281
261
bik
316
322
342
337
347
338
318
5.5.5.5.62.122
4.5-4.5.6.122
4.5.4.5.122.*
5.5.5.5.62.*
52-62.6-62-6.62
52.62.6.62.6-62
5.5.5.5.6.122
ton
299
SSZ-48
Crystal chemical data:
Type Material Data
SFE
[Si140:8]-SFE
monoclinic, P2 1
a - 11.153A, b - 5.002A, c - 13.667A, 3 - 100.63 °~1)
F r a m e w o r k density:
18.7 T/1000A 3
Channels:
[010] 12 5.4 x 7.6*
7.6
7.6
12-ring viewed along [010]
References"
(1) Wagner, P., Terasaki, O., Ritsch, S., Nery, J.G., Zones, S.I., Davis, M.E. and Hiraga, K. J. Phys. Chem. B,
103, 8245-8250 (1999)
300
SFF
P2 lm
Framework Type Data
z
×
framework viewed normal to [001] (upper right: projection down [001])
I d e a l i z e d cell d a t a :
monoclinic, P21/m, a - 11.5/k, b - 21.7A, c - 7.2/k, ~3 - 93.2 °
Coordination sequences and vertex symbols:
4
4
4
4
4
4
4
4
T 1 (4,1)
T 2(4,1)
T 3 (4,1)
T 4 (4,1)
T 5(4,1)
T 6 (4,1)
T 7(4,1)
T 8(4,1)
12
12
11
11
11
11
11
11
Secondary building units"
20
20
22
22
23
20
19
23
34
34
38
39
37
31
36
36
56
56
57
54
57
58
55
59
5-3
Composite building units:
cas
sOe
Materials with this framework type:
• SSZ_44 (1)
S T F - S F F structural intermediates ~2)
87
88
80
84
82
86
82
79
115
115
111
110
113
115
113
114
143
142
148
145
150
142
148
147
176
177
189
189
184
174
181
183
224
225
228
234
228
225
220
229
5.52.5.6.5.6
5.52.5.6.5.6
4.5.5.6.5.10
4.5.5.6.5.10
4.5.5-6.5.10
4.62.5.5.5.5
4.6.5.5.5.5
4.5.5.6.5.10
301
Type Material Data
SSZ-44
C r y s t a l chemical data:
SFF
[Si32Oj-SFF
monoclinic, P21/m
a - 1 1.485 A, b - 21.946A, c - 7.388A, ~ - 94.70 ° ~
Framework density:
17.2 T/1000A 3
Channels:
[001] 10 5.4 x 5.7*
5.4
\
1O-ring viewed along [001]
References:
(1)
(2)
Wagner, P., Zones, S.I., Davis, M.E. and Medrud, R.C. Angew. Chem., Int. Ed., 38, 1269-1272 (1999)
Villaescusa, L.A., Zhou, W., Morris, R.E. and Barrett, P.A.J. Mater. Chem., 14, 1982-1987 (2004)
302
SFG
Framework Type Data
Pmma
x
Y
framework viewed along [001]
Idealized cell data:
orthorhombic, Pmma, a - 25.5/k, b - 12.6A, c - 13.1A
Coordination sequences and vertex symbols"
4
T 2(8,1)
4
T 3(8,1)
4
T 4(8,1)
4
T 5(4,.m.)
4
T 6(4,.m.)
4
T 7(8,1)
4
T 8(8,1)
4
T 9 (4,m..)
4
T,o(2,mm2) 4
T~I (8,1)
4
T~2(4,m..) 4
T 1 (8,1)
12
11
12
10
12
12
11
10
12
12
10
10
Secondary building units:
24
22
22
20
24
22
21
21
24
22
20
20
38
38
35
37
36
35
37
40
36
36
36
38
83
79
86
90
85
88
85
88
80
78
83
86
see Compendium
Composite building units"
reel
Materials with this framework type:
• SSZ_58 (1)
61
55
61
62
53
52
56
63
56
52
58
61
117
114
121
120
120
118
122
118
116
122
112
117
159
158
155
155
150
148
161
156
156
148
152
152
205
201
199
193
192
182
192
200
193
180
206
196
246
242
248
241
241
244
240
247
235
236
250
246
293
298
306
304
294
307
305
299
303
306
288
304
359
355
360
374
371
363
364
361
367
364
344
360
5-6.5.7.6.62
4.72.5.6.5.62
5.6-5.6.6.62
4.62.4.6~.5.10
5.52.6-62.6.62
5-5~-62"6~-6~'6~
4.6.5.62.5.62
4-6-4"62"5" 102
5.6.5.6-62-72
5"5~'6~-62"6~'62
4.6.4.62-5.6
4.62.4.62-5" 102
303
SSZ-58
SFG
Type Material Data
Crystal chemical data:
[B 2.25Si71.750j - S F G
orthorhombic, Pmma, a - 25.1118A, b - 12.4976A, c - 12.8598A (l~
Framework density"
18.3 T/1000A. 3
Channels:
[001] 10 5.2 x 5.7* +--+ [100] 10 4.8 x 5.7*
......
....
lO-ring viewed along [OO1]
~
~
>
:2.
1O-ring viewed along [100]
References:
(1) Burton, A., Elomari, S., Medrud, R.C., Chan, I.Y., Chen, C.-Y., Bull, L.M. and Vittoratos, E.S.J. Am.
Chem. Soc., 125, 1633-1642 (2003)
304
SFH
Framework Type Data
Cmcm
z
framework viewed along [100]
Idealized cell data:
orthorhombic, Cmcm, a - 5.3/k, b - 34.3A, c - 21.5/k
Coordination sequences and vertex symbols:
T,(8,m..)
T2(8,m.. )
T3(8,m.. )
T4(8,m.. )
Ts(8,m.. )
T6(8,m.. )
T7(8,m.. )
T8(8,m.. )
4
4
4
4
4
4
4
4
11
10
12
10
11
12
12
12
Secondary building units:
22
20
22
19
22
19
22
23
35
31
35
34
38
35
34
36
57
54
49
47
52
54
50
53
75
71
80
76
78
79
72
75
107
106
109
100
103
103
108
108
135
132
144
140
140
145
147
143
178
174
178
172
178
167
179
178
221
212
205
213
220
216
208
212
269
258
244
249
262
273
248
258
5-3
Composite building units:
dzc
double zigzag
chain
Materials with this framework type:
• 5SZ_53 (1)
cas
mtw
315
307
321
299
312
315
303
314
4.62.5.6.5.6
4.5.4.5.146.*
5.62.5.62.52.6
4.5.4.5.6.146
4.62.5.6.5.6
5.6.5.6.52.6
5.62.5.62-62-146
5.6.5.6.6.62
305
SSZ-53
Crystal chemical data:
Type Material Data
SFH
[B 1.6Si62.4012J-SFH
monoclinic, C2/c
a - 5.0192A, b - 33.7437A, c - 21.1653A, ~3- 90.485 °(I~
Framework density"
17.9 T/1000A 3
Channels:
[001] 14 6.4 x 8.7*
8.7
"
6.4
14-ring viewed along [001]
References:
(1) Burton, A., Elomari, S., Chen, C.Y., Medrud, R.C., Chan, I.Y., Bull, L.M., Kibby, C., Harris, T.V., Zones,
S.I. and Vittoratos, E.S. Chem. Eur. Journal, 9, 5737-5748 (2003)
306
SFN
Framework Type Data
.....................
C21m
.~:.~.....................
Z
framework viewed along [01 O]
Idealized cell data:
monoclinic, C2/m, a - 25.2A, b - 5.3A, c - 15.0A, ~3- 103.9 °
Coordination sequences and vertex symbols:
T, (4,m)
T 2(4,m)
T 3 (4,m)
4
4
4
4
4
4
4
4
T 4 (4,m)
T 5(4,m)
T 6 (4,m)
T 7(4,m)
T 8(4,m)
11
11
12
12
12
12
10
10
Secondary building units:
22
22
22
19
23
21
20
19
35
38
35
34
35
34
31
34
56
51
51
55
52
49
53
48
73
76
74
79
73
78
73
76
103
99
108
101
106
109
106
102
131
135
146
139
142
138
130
139
173
176
171
163
176
176
169
166
217
220
199
209
205
196
206
205
265
251
242
263
246
238
252
242
5-3
Composite building units"
dzc
jbw
double zigzag
chain
Materials with this framework type:
• SSZ_59 ~
cas
mtw
297
296
302
306
295
310
297
299
4.62.5.6.5-6
4-62.5.6.5.6
5"62-5"62"62"146
5.6.5.6.52.6
5.6.5.6-6.62
5-62.5.62"52"6
4.5-4.5.146.*
4.5.4.5.6.146
307
SSZ-59
C r y s t a l chemical d a t a :
SFN
Type Material Data
[B o.35Si 15.65032]-SFN
triclinic, P]-, a - 5.023A, b - 12.735A, c -
14.722A
oc - 103.44 °, ~3 - 90.51 °, ~ - 100.88 ° (~)
F r a m e w o r k density:
17.8 T/1000A 3
Channels:
[001] 14 6.2 x 8.5*
14-ring viewed along [001]
References:
(1)
Burton, A., Elomari, S., Chen, C.Y., Medrud, R.C., Chan, I.Y., Bull, L.M., Kibby, C., Harris, T.V., Zones,
S.I. and Vittoratos, E.S. Chem. Eur. Journal, 9, 5737-5748 (2003)
308
SFO
Framework Type Data
C21m
i
l~!.~.i .i!:ii
?
X
framework viewed along [001]
Idealized cell data:
monoclinic, C2/m, a - 22.6/k, b - 13.6A, c - 7.0A, ~ - 99 °
Coordination sequences and vertex symbols:
T~(8,1)
T 2(8,1)
T 3(8,1)
T 4(8,1)
4
4
4
4
10
9
9
9
Secondary building units:
17
18
18
16
28
30
29
27
63
64
65
65
6-2 or 4-4- or 4
Composite building units:
sti
Materials with this framework type:
,SSZ_51 (1)
46
43
42
44
86
90
91
87
117
111
111
110
142
139
138
138
168
178
176
171
211
212
210
211
256
248
248
257
4.6-4-6.6.12
4.4.4.8.63.8
4.4.4.12.6.63
4.6.4.62.4.8
309
SFO
Type Material Data
SSZ-51
Crystal chemical data:
I(C7NzH,1)s(H:O)4I [FsA132P3:O12s]-SFO
C7N2H~ = 4-dimethylaminopyridinium
monoclinic, C2/c
a - 21.759,&, b - 13.821A, c - 14.224 A, ~ - 98.849 °(')
(Relationship to unit cell of Framework Type: a ' = a, b ' = b, c ' = 2c)
Framework density:
15.1 T/1000A 3
Channels:
[0011126.9x7.1"+-+
[01018 3.1x3.9"
•
12-ring viewed along [001]
.1
8-ring viewed along [010]
References:
(1) Morris, R.E., Burton, A., Bull, L.M. and Zones, S.I. Chem. Mater., 16, 2844-2851 (2004)
...................
310
SGT
1411amd
Framework Type Data
:
).
i
!
t
t,
t,
i!
Z
*£) .............. :
framework viewed along [100] (upper right: projection down [100])
tetragonal, I 4 / a m d (origin choice 2), a - lO.3/k, c - 34.4*
Idealized cell data:
Coordination sequences and vertex symbols:
T, (16,m)
T 2(16,m)
T 3(16,2)
T 4 (16,m)
4
4
4
4
11
11
11
12
Secondary building units:
22
21
23
24
37
37
38
42
5-3
Materials with this framework type:
• Sigma_2 ~
[B-Si-O]-SGT ~2~
62
63
62
61
89
86
92
87
120
121
113
128
155
152
159
168
202
196
210
205
257
258
244
250
4.6-5.5.5.5
4.6.5.5.5.5
4.6.5.5.5.5
5.6.5.6.5.6
311
Sigma-2
Crystal chemical data:
Type Material Data
SGT
I(C,oH,~N)41[Si64012s]-SGT
C10H17N = 1-aminoadamantane
tetragonal, N / a m & a - 10.239A, c - 34.383A ~
F r a m e w o r k density:
17.8 T/1000A 3
Channels:
apertures formed by 6-rings only
References:
(1)
(2)
McCusker, L.B.J. Appl. Crystallogr., 21, 305-310 (1988)
Grtinewald-Luke, A., Marler, B., Hochgrafe, M. and Gies, H. J. Mater. Chem., 9, 2529-2536 (1999)
312
SIV
Framework Type Data
Cmcm
;":~ - y
x•I
z
framework viewed along [100]
Idealized cell data:
orthorhombic, Cmcm,
a -
9 . 9 ' , b - 14.1A, c - 28.1/k
Coordination sequences and vertex symbols"
4
4
4
4
T 1 (16,1)
T 2(16,1)
T 3(16,1)
T 4(16,1)
9
9
9
9
Secondary building units"
18
18
18
18
32
32
32
32
49
48
48
49
4or8
Composite building units:
dcc
double
crankshaft chain
gis
i
Materials with this framework type:
• SIZ_7 ~)
69
67
68
69
93
92
96
93
122
120
126
121
156
150
155
155
191
187
191
193
229
231
234
230
275
275
277
272
4-4-4.82.8.8
4.4.4.82.8.8
4.4-4.82.8.8
4.4.4.82.8.8
313
SlV
Type Material Data
SIZ-7
Crystal chemical data:
[ C o 12.sA119.2P32O 128]-S I V
m o n o c l i n i c , C2/c
a - 10.2959~,, b - 14.3715~,, c - 2 8 . 5 9 9 A , ~ - 9 1 . 0 9 4 ° ~
Framework density:
15.1 T/1000/k 3
Channels:
{ [100] 8 (3.5 x 3.9+ 8 3.7 x 3.8 +-+ [110] 8 3.7 x 3.8
+-+ [001] 8 3.8 x 3.9 ° } ***
8-ring viewed along [100]
• .>
2nd 8-ring viewed along [100]
..:.
3.8
&ring viewed along [110]
8-ring viewed along [001]
References:
(1)
Parnham, E.R. and Morris, R.E.J. Am. Chem. Soc., 128, 2204-2205 (2006)
i
314
SOD
m
Framework Type Data
Im3m
Z
framework viewed along [100]
Idealized cell data:
cubic, Im-3m, a - 9.0/k
Coordination sequences and vertex symbols:
T l (12, 42m )
4
10
20
34
52
74
100
Secondary building units"
6
Framework description:
A B C sequence of 6-rings
130
164
4.4.6.6.6.6
202
sod
Composite building units:
Materials with this framework type:
• Sodalite (1,2)
[A1-Co-P-O]-SOD (3)
[A1-Ga-Si-Ge-O]-SOD(4)
(5 6)
[AI-Ge-O]-SOD '
[Be-A1-Si-O]-SOD (7)
[ B e - A s - O ] - S O D (8~
[ B e - G e - O ] - S O W 9~
[ B e - P - O ] - S O D (8~
[Be-Si-O]-SOD °'l°)
[ C o - G a - P - O ] - S O D (3'1~
[ G a - G e - O ] - S O W 6~
[Ga-Si-O]-SOD ~2)
[Zn-A1-As-O]-SOD (13)
[ Z n - A s - O ] - S O D (14~
[ Z n - G a - A s - O ] - S O D (11'13~
[ Z n - G a - P - O I - S O D (11~
[ Z n - P - O l - S O O (14)
[ Z n - S i - O l - S O D (15)
Danalite ~22)
lea 8 (WO4)2111112024]-SOO(16)
SIZ_9 ~28~
Silica sodalite(29)
T M A sodalite ~3°~
(31 32)
Tugtupite '
A1PO-20 plus variants
(19 20)
Basic sodalite '
Bicchulite (21~
6 (23)
Genthelvite ~24~
H a u y n ~25)
Helvin ~22)
H y d r o x o sodalite ~26)
Nosean
(17 18)
'
(27)
315
Sodalite
Crystal chemical data:
Type Material Data
SOD
INa C] l [A16Si6024]-SOD
cubic, P-43n , a - 8.870,~ ~2~
Framework density:
17.2 T/1000A 3
Channels:
apertures formed by 6-rings only
References:
(1) Pauling, L. Z. Kristallogr., 74, 213-225 (1930)
(2) Loens, J. and Schulz, H. Acta Crystallogr., 23, 434-436 (1967)
(3) Feng, P., Bu, X. and Stucky, G.D. Nature, 388, 735-741 (1997)
(4) Johnson, G.M., Mead, P.J. and Weller, M.T. Microporous Mesoporous Mat., 38, 445-460 (2000)
(5) Wiebcke, M., Sieger, P., Felsche, J., Engelhardt, Co.,Behrens, P. and Schefer, J. Z. anorg, allg. Chemie,
619, 1321-1329 (1993)
(6) Bu, X., Feng, P., Gier, T.E., Zhao, D. and Stucky, G.D.J. Am. Chem. Soc., 120, 13389-13397 (1998)
(7) Armstrong, J.A. and Weller, M.T.J. Chem. Soc., Dalton Trans., 2998-3005 (2006)
(8) Gier, T.E., Harrison, W.T.A. and Stucky, G.D. Angew. Chem., Int. Ed., 30, 1169-1171 (1991)
(9) Dann, S.E., Weller, M.T., Rainford, B.D. and Adroja, D.T. Inorg. Chem., 36, 5278-5283 (1997)
(10) Dann, S.E. and Weller, M.T. Inorg. Chem., 35, 555-558 (1996)
(11) Bu, X., Gier, T.E., Feng, P. and Stucky, G.D. Microporous Mesoporous Mat., 20, 371-379 (1998)
(12) McCusker, L.B., Meier, W.M., Suzuki, K. and Shin, S. Zeolites, 6, 388-391 (1986)
(13) Feng, P., Zhang, T. and Bu, X. J. Am. Chem. Soc., 123, 8608-8609 (2001)
(14) Nenoff, T.M., Harrison, W.T.A., Gier, T.E. and Stucky, G.D.J. Am. Chem. Soc., 113, 378-379 (1991)
(15) Camblor, M.A., Lobo, R.F., Koller, H. and Davis, M.E. Chem. Mater., 6, 2193-2199 (1994)
(16) Depmeier, W. Acta Crystallogr., C40, 226-231 (1984)
(17) Wilson, S.T., Lok, B.M., Messina, C.A., Cannan, T.R. and Flanigen, E.M.J. Am. Chem. Soc., 104, 11461147 (1982)
(18) Flanigen, E.M., Lok, B.M., Patton, R.L. and Wilson, S.T. Proc. 7th Int. Zeolite Conf., pp. 103-112 (1986)
(19) Barrer, R.M. and White, E.A.D.J. Chem. Soc., 1267-1278 (1951)
(20) Hassan, I. and Grundy, H.D. Acta Crystallogr., C39, 3-5 (1983)
(21) Sahl, K. and Chatterjee, N.D.Z. Kristallogr., 146, 35-41 (1977)
(22) Glass, J.J., Jahns, R.H. and Stevens, R.E. Am. Mineral., 29, 163-191 (1944)
(23) Shishakova, T.N. and Dubinin, M.M. Izv. Akad. Nauk SSSR, 1303- (1965)
(24) Merlino, S. Feldspars and Feldspathoids, pp. 435-470 (1983)
(25) Loehn, J. and Schulz, H. N. Jb. Miner. Abh., 109, 201-210 (1968)
(26) Felsche, J., Luger, S. and Baerlocher, Ch. Zeolites, 6, 367-372 (1986)
(27) Schulz, H. and Saalfeld, H. Tschermaks Min. Petr. Mitt., 10, 225-232 (1965)
(28) Parnham, E.R. and Morris, R.E.J. Am. Chem. Soc., 128, 2204-2205 (2006)
(29) Bibby, D.M. and Dale, M.P. Nature, 317, 157-158 (1985)
(30) Baerlocher, Ch. and Meier, W.M. Helv. Chim. Acta, 52, 1853-1860 (1969)
(31) Sorensen, H. Am. Mineral., 48, 1178 (1963)
(32) Hassan, I. and Grundy, H.D. Can. Mineral., 29, 385-390 (1991)
316
SOS
Framework Type Data
Pmna
..........
" "~......
(
~s~.~,w~
ft.
................
Z
framework viewed along [010]
Idealized cell data:
orthorhombic, P m n a , a - 20.4/k, b - 7.1A, c - 9.7/k
Coordination sequences and vertex symbols:
T~(8,1)
T 2(8,1)
T 3(8,1)
4
4
4
10
8
7
Secondary building units"
19
15
15
31
27
27
4-2
Materials with this framework type:
*SU_16 ~1~
FJ_17 ~2)
47
46
41
71
70
68
97
93
93
124
116
119
153
151
146
187
197
192
231
235
230
278
265
268
4.8.4.8-84.12
3"87"4"62"62"8
3.4.3.82-62.*
317
SU-16
Type Material Data
Crystal chemical data:
[(C4H,sN3)4[ [BsGe~6048]-SOS
C4Ht3N 3 = diethylenetriamine
monoclinic, P2l/C
a - 6.936A, b - 10.493A, c - 20.448,~, ~3- 90.09 °~1~
Stability:
Unstable to removal of template ~)
Framework density:
16.1 T/1000/k 3
Channels:
{[100] 12 3.9 x 9.1 +-+ [010] 8 3.3 x 3.3}**
12-ring viewed along [100]
8-ring viewed along [010]
References:
(1)
(2)
Li, Y. and Zou, X. Angew. Chem., Int. Ed., 44, 2012-2015 (2005)
Zhang, H.-X., Zhang, J., Zheng, S.-T. and Yang, G.-Y. Inorg. Chem., 44, 1166-1168 (2005)
SOS
318
SSY
Framework Type Data
Pmmn
z
framework viewed along [100]
I d e a l i z e d cell d a t a :
orthorhombic, Pmmn (origin choice 2), a - 5.3/k, b - 22.6/k, c - 14.0/k
Coordination sequences and vertex symbols:
T 1 (4,m..)
T 2(4,m..)
T 3 (4,m..)
4
4
4
T 4 (4,m..)
4
T 5(4,m..)
4
T 6 (4,m..)
4
T 7(2,mm2) 4
T 8(2,mm2) 4
12
10
12
10
12
12
12
12
Secondary building units:
20
19
24
20
22
22
24
22
36
35
38
35
37
37
44
38
59
57
57
57
57
55
56
60
84
84
79
83
87
87
78
78
115
113
116
115
117
120
110
114
152
147
156
146
152
148
158
150
183
179
193
183
185
180
206
200
236
229
233
227
234
234
234
232
286
289
280
282
286
294
262
280
see Compendium
Composite building units:
&c
jbw
double zigzag
chain
Materials with this framework type:
*SSZ_60 ")
mtt
ton
344
337
330
348
345
344
336
332
5.5.5.5.62 •122
4.5.4.5-6-122
52.62.6.62-6-62
4.5-4.5.122.*
52.62.6.62.6.62
5-5.5.5.62..*
5.5.5.5.122..*
5.5.5-5.62 •122
320
STF
Framework Type Data
C21m
z
x
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
monoclinic, C2/m, a - 14.1A,, b - 18.2/k, c - 7.5/k, 3 - 99°
Coordination sequences and vertex symbols:
4
4
4
4
4
T 1(8,1)
T 2(8,1)
T 3(8,1)
T 4 (4,m)
T 5(4,m)
12
11
11
11
11
Secondary building units:
20
22
23
19
20
34
39
36
36
31
56
55
59
54
58
88
82
80
84
84
114
111
113
110
117
143
149
147
146
137
173
188
183
179
174
224
223
227
226
229
5.52.5.6.5.6
4"5-5-6"5"10
4"5"5"6-5"10
4.6.5-5"5"5
4.62-5.5.5.5
5-3
Composite building units:
cas
stf
Materials with this framework type:
, 5 5 2 _ 3 5 ~1)
ITQ_9 ~2~
Mu_26 ~3~
SSZ-35, as synthesized ~4~
S T F - S F F structural intermediates ~5)
321
SSZ-35
Crystal chemical data"
Type Material Data
STF
[Si16032]-STF
triclinic, P]-, a - 11.411A, b - 11.527A, c - 7.377A
oL - 94.66o, f3 - 96.21, ~ - 104.89 ° (l~
(Relationship to unit cell of Framework Type" V' - V/2)
Framework density"
17.3 T/1000A 3
Channels:
[001] 10 5.4 x 5.7*
1O-ring viewed along [001]
References:
(1) Wagner, P., Zones, S.I., Davis, M.E. and Medrud, R.C. Angew. Chem., Int. Ed., 38, 1269-1272 (1999)
(2) Villaescusa, L.A., Barrett, P.A. and Camblor, M.A. Chem. Commun., 21, 2329-2330 (1998)
(3) Harbuzaru, B., Roux, M., Paillaud, J.L., Porcher, F., Marichal, C., Chezeau, J.M. and Patarin, J. Chemistry
Letters, 616-617 (2002)
(4) Fyfe, C.A., Brouwer, D.H., Lewis, A.R., Villaescusa, L.A. and Morris, R.E.J. Am. Chem. Soc., 124, 77707778 (2002)
(5) Villaescusa, L.A., Zhou, W., Morris, R.E. and Barrett, P.A.J. Mater. Chem., 14, 1982-1987 (2004)
322
STI
Framework Type Data
Fmmm
~,~:...... i,~......."~'~:
....... .......... ,2121 ~
\
i
\ ....
•..........
x•
Z
y
framework viewed along [100]
Idealized cell data:
o r t h o r h o m b i c , Fmmm, a - 13.5/k, b - 17.8/k, c - 17.9,~
Coordination sequences and vertex symbols:
T 1 (32,1)
T 2(16,m)
T 3(16,m)
T 4 (8,222)
4
4
4
4
10
11
9
12
Secondary building units:
20
20
17
18
34
36
35
34
57
57
57
58
82
78
77
82
103
109
103
112
138
140
138
130
181
176
188
172
220
222
225
228
4-4=1
Composite building units:
sti
bre
Materials with this framework type:
• Stilbite ~-3~
Barrerite ~4~
Stellerite <5~
Synthetic barrerite~6~
Synthetic stellerite(6)
Synthetic stilbite ~7~
T N U _ 1 0 ~8~
4.5.4-6.5.62
4.8.5.82.5.82
4.5.4-5"4"8
52.52-6-6-10.10
323
STI
Type Material Data
Stilbite
Crystal chemical data:
INa4Ca8 (H20)561 [Alz0Si520~44]-STI
monoclinic, C2/m
a - 13.64A, b - 18.24A, c - 11.27,~, ~ - 128.0 °~3)
(Relationship to unit cell of Framework Type:
a ' = a, b ' = b, c'= c/(2sin~')
or, as vectors, a' = a, b' = b, e' = (e - a)/2)
Framework density:
16.3 T/1000/k 3
Channels:
[ 100] 10 4.7 x 5.0* +--+ [001 ] 8 2.7 x 5.6*
5.O
lO-ring viewed along [100]
i
•
8-ring along [001]
References:
(1) Galli, E. and Gottardi, G. Miner. Petrogr. Acta, 12, 1-10 (1966)
(2) Slaughter, M. Am. Mineral., 55, 387-397 (1970)
(3) Galli, E. Acta Crystallogr., B27, 833-841 (1971)
(4) Galli, E. and Alberti, A. Bull. Soc. fr. Mineral. Cristallogr., 98, 331-340 (1975)
(5) Galli, E. and Alberti, A. Bull. Soc. fr. Mindral. Cristallogr., 98, 11-18 (1975)
(6) Ghobarkar, H., Schaef, O. and Guth, U. J. Solid State Chem., 142, 451-454 (1999)
(7) Ghobarkar, H. and Schaef, O. J. Phys. D: Appl. Phys., 31, 3172-3176 (1998)
(8) Hong, S.B., Lear, E.G., Wright, P.A., Zhou, W., Cox, P.A., Shin, C.-H., Park, J.-H. and Nam. I.-S. J. Am.
Chem. Soc., 126, 5817-5826 (2004)
324
STT
P2.,In
Framework Type Data
A ................................
'
~ .............
~
/
x
z
f r a m e w o r k viewed normal to [100]
Idealized cell data:
monoclinic, P21/n, a - 13.l/k, b - 21.9/k, c - 13.6/k, 3 - 102-9°
Coordination sequences and vertex symbols:
T~ (4,1)
T 2 (4,1)
T 3 (4,1)
T 4 (4,1)
T 5 (4,1)
T 6 (4,1)
T 7 (4,1)
T 8 (4,1)
T 9 (4,1)
Tlo (4,1)
T1, (4,1)
T,2 (4,1)
T13 (4,1)
T~4 (4,1)
T15 (4,1)
T16 (4,1)
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
11
10
11
10
9
10
10
10
11
10
12
10
10
12
11
11
Secondary building units:
22
23
20
19
21
20
20
19
19
21
20
18
20
21
21
20
36
37
35
32
38
40
35
35
34
31
31
35
38
33
33
32
5-3
Composite building units:
bea
cas
Materials with this framework type:
• SSZ_23 ~1)
55
57
54
55
57
57
57
54
53
51
50
59
55
58
55
54
84
78
84
81
78
78
77
77
81
83
88
77
75
86
78
89
111
108
108
109
104
105
108
108
115
115
117
107
104
112
111
115
142
146
142
141
144
143
139
146
140
134
137
150
149
141
145
138
179
187
178
174
195
191
184
174
173
172
167
179
185
174
175
172
233
225
225
223
220
226
230
215
219
216
221
221
218
226
217
221
4.5.5.7.6-9
4.4.5.9.6.7
4.6.5-6.5.7
4.5.4.6.5.5
4.4.4.9.5.7
4.5-4.7.5.9
4.6.4.6.5.7
4.5.4-9-5-6
4.6.5.5.5.5
4.6.4-6.5.5
5.52.5.6.6.6
4.5.4.9.5.5
4.4.5.6.5.9
5.5.5.6.5.7
4.5.5.6.5-9
4.62.5.5.5.5
325
SSZ-23
Type Material Data
Crystal chemical data"
STT
I(C,~H~N)~,F~(OH)0J [Si640,2s]-STT
C ~3H2~N = N , N , N - t r i m e t h y l - 1 - a d a m a n t a m m o n i u m
monoclinic, P2~/n
a - 12.959A, b - 21.792A,, c - 13.598A, ~3 - 101.85 ° ~)
Framework density:
17 T/1000A, ~
Channels:
[101] 9 3.7 x 5.3* ~
9-ring viewed along [101]
[001] 7 2.4 x 3.5*
7-ring viewed along [001]
References:
(1)
Camblor, M.A., Diaz-Cabanas, M.-J., Perez-Pariente, J., Teat, S.J., Clegg, W., Shannon, I.J., Lightfoot, P.,
Wright, P.A. and Morris, R.E. Angew. Chem., Int. Ed., 37, 2122-2126 (1998)
326
SZR
Framework Type Data
..........................
...
'>.>,,.,..:-.
Cmmm
, , . - .....
y
framework viewed along [001]
Idealized cell data:
orthorhombic, Cmmm, a - 18.9/k, b - 14.4/k, c - 7.5/k
Coordination sequences and vertex symbols:
T 1(16,1)
T 2(8,..m)
T 3 (8,.m.)
T 4(4,2mm)
4
4
4
4
10
12
10
12
Secondary building units"
21
23
19
24
38
38
34
38
61
59
60
52
88
82
89
88
116
119
118
118
6
Composite building units:
mtt
d6r
Materials with this framework type:
• SUZ_4 (1,2)
mso
149
155
144
150
190
191
179
192
237
231
238
232
289
283
296
278
340
338
342
340
4.5.4.6.6.82
5.8.5.8.52.6
4.5.4.5.6.82
5.5.5.5.102.104
327
Type Material Data
SUZ-4
Crystal chemical data:
SZR
IK41[A14Si32072]-SZR
orthorhombic, Cmmm, a - 18.8064A, b - 14.2298A, c - 7.4548,~ ~2)
F r a m e w o r k density:
18 T/IOOOA 3
Channels:
{ [001] 104.1 x 5.2 ~
5.2
i
5.2
[010] 8 3.2 x 4.8 ~ [110] 8 3.0 x 4.8 }***
!
lO-ring viewed along [001]
4.8
8-ring viewed along [010]
•
4,8
i3.0
8-ring viewed along [110]
References:
(1) Lawton, S.L., Bennett, J.M., Schlenker, J.L. and Rubin, M.K. Chem. Commun., 894-896 (1993)
(2) Strohmaier, K.G., Afeworki, M. and Dorset, D.L.Z. Kristallogr., 221,689-698 (2006)
328
TER
Framework Type Data
Cmcm
Vy
y
k-x
framework viewed along [001 ]
Idealized cell data:
orthorhombic, Cmcm, a - 9.8A, b - 23.6A, c - 20.2/~.
Coordination sequences and vertex symbols:
T 1 (16,1)
T 2(16,1)
T 3 (8,m)
T 4 (8,m)
T 5(8,m)
T 6(8,m)
T 7(8,m)
T 8(8,m)
4
4
4
4
4
4
4
4
11
11
11
11
11
11
12
12
Secondary building units:
19
21
22
21
19
21
20
23
35
35
39
41
34
33
35
32
57
58
62
61
56
53
55
49
83
87
82
77
78
80
81
86
113
103
104
107
116
112
119
124
2-6-2 or 4-1
Composite building units:
bre
bog
d3
Materials with this framework type"
*Terranovaite °~
cas
137
144
142
134
152
155
142
147
184
188
178
186
184
187
182
167
231
227
225
232
208
214
216
219
4.5.5.6.5.62
4.5.5.62-5.103
4"106"5"63"5"63
4"52"5"104"5"104
4.52.5.6.5.6
4.102-5-63-5"63
5.6.5.6.52.102
5.62.5-62.10-104
329
Type Material Data
Terranovaite
TER
Crystal chemical data:
INa4.2Ko.2Mgo.2Ca3.7 (H20)291 [A1 ~2.3S i67.70,6o]-TER
orthorhombic, Cmcm, a - 9.747A, b - 23.880A, c - 20.068A (1~
Framework density:
17.1 T/1000,~ 3
Channels:
[ 100] 10 5.0 x 5.0* +-+ [001 ] 10 4.1 x 7.0*
7.0
/::: 5.0
1O-ring viewed along [100]
......
1O-ring viewed along [001]
References:
(1) Galli, E., Quartieri, S., Vezzalini, G., Alberti, A. and Franzini, M. Am. Mineral., 82, 423-429 (1997)
330
THO
Framework Type Data
......~
i~!~i'~
Pmma
.....~....: ~
Z
xJ-~
-y
f r a m e w o r k viewed normal to [001]
Idealized cell data:
orthorhombic, P m m a , a - 14.0/k, b - 7.0A, c - 6.5/k
Coordination sequences and vertex symbols:
T 1 (4,m)
4
T 2(4,m)
4
T 3 (2,mm2) 4
9
9
8
Secondary building units:
19
19
18
35
33
34
52
50
50
72
74
68
100
100
100
131
129
130
163
165
160
201
201
204
4"83"4"83"42"84
4"83"4"83"42"84
42"42"84"84"84"84
4=1
Composite building units"
nat
Materials with this framework type:
• Thomsonite (1-3~
[A1-Co-P-O]-THO (4~
[ G a - C o - P - O ] - T H O (4)
[Zn-A1-As-O]-THO (5~
[ Z n - P - O ] - T H O (6~
[ Z n - P - O ] - T H O (7)
IRb201[
Ga20Ge20° 80]-THO(8~
Na-V ([Ga-Si-O]-THO) (9)
Synthetic thomsonite (l°~
Z C P - T H O ( [ Z n - C o - P - O ] - T H O ) (ll)
331
Thomsonite
Crystal chemical data"
Type Material Data
THO
INa4Ca (H20)41 [Alz0Siz0Os0]-THO
orthorhombic, Pncn, a - 13.088A, b - 13.052A, c - 13.229A ¢3)
(Relationship to unit cell of Framework Type: a ' = a, b'= 2b, c'= 2c)
F r a m e w o r k density:
17.7 T/1000A 3
Channels:
[100] 8 2.3 x 3.9* ~ [010] 8 2.2 x 4.0* +-+ [001] 8 2.2 x 3.0*
(variable due to considerable flexibility of framework)
22i
8-ring viewed along [100]
8-ring viewed along [010]
8-ring along [001], variable
References:
(1) Taylor, W.H., Meek, C.A. and Jackson, W.W.Z. Kristallogr., 84, 373-398 (1933)
(2) Alberti, A., Vezzalini, (3. and Tazzoli, V. Zeolites, 1, 91-97 (1981)
(3) Pluth, J.J., Smith, J.V. and Kvick, A. Zeolites, 5, 74-80 (1985)
(4) Feng, P., Bu, X. and Stucky, G.D. Nature, 388, 735-741 (1997)
(5) Feng, P., Zhang, T. and Bu, X. J. Am. Chem. Soc., 123, 8608-8609 (2001)
(6) Neeraj, S. and Natarajan, S. J. Phys. Chem. Solids, 62, 1499-1505 (2001)
(7) Ng, H.Y. and Harrison, W.T.A. Microporous Mesoporous Mat., 50, 187-194 (2001)
(8) Lee, Y.J., Kim, S.J. and Parise, J.B. Microporous Mesoporous Mat., 34, 255-271 (2000)
(9) Barrer, R.M., Baynham, J.W., Bultitude, F.W. and Meier, W.M.J. Chem. Soc., 195-208 (1959)
(10) Ghobarkar, H. and Schaef, O. Cryst. Res. Technol., 32, 653-657 (1997)
(11) Ke, Y.X., He, G.F., Li, J.M., Zhang, Y.G. and Lu, S.M. New J. Chem., 25, 1627-1630 (2001)
332
TOL
Framework Type Data
P3ml
!
)__y
framework viewed normal to [001] (upper right: projection down [001])
Idealized cell data:
trigonal, P-3ml, a - 12.3/k, c - 30.9/k
Coordination sequences and vertex symbols:
T1(12,1 )
T2(12,1 )
T3(12,1 )
T4(12,1 )
T5(12,1 )
T6(6,.2. )
T7(6,.2. )
4
4
4
4
4
4
4
10
10
10
10
10
10
10
20
20
20
20
20
20
20
34
34
34
34
34
34
34
54
53
54
53
52
54
54
78
76
78
76
74
78
78
104
103
104
103
102
104
104
134
135
134
135
136
134
134
168
170
168
170
172
168
168
210
209
210
208
209
210
210
Secondary building units"
4or6
Framework description:
C A C A C B C B C A C B sequence of 6-rings
Composite building units:
can
los
Materials with this framework type:
*Tounkite-like mineral ~)
lio
256
252
256
250
250
256
256
302
300
302
299
299
302
302
4.4-6.6.6.6
4.6.4.6.6.6
4.6-4.6.6.6
4.6.4.6.6.6
4.6.4.6-6.6
4.4.6.6.6-6
4.4.6.6.6-6
333
Tounkite-like mineral
Type Material Data
Crystal chemical data:
INa3~,Ca,5 94Ko96C18(504)~ 3(503)0.71 [AI3~Si360~44]-TOL
trigonal, P3, a = 12.757A, c - 32.211A (~
Framework density:
15.9 T/1000A 3
Channels:
apertures formed by 6-rings only
TOL
References:
(1) Rozenberg, K.A., Sapozhnikov, A.N., Rastsvetaeva, R.K., Bolotina, N.B. and Kashaev, A.A. Crystallogr.
Reports, 4, 635-642 (2004)
334
TON
Framework Type Data
Cmcm
~
y
X
framework viewed along [001]
Idealized cell data:
orthorhombic, Cmcm, a - 14.l/k, b - 17.8/k, c - 5.3A
Coordination sequences and vertex symbols:
4
T 2(8,m)
4
T 3(4,m2m) 4
T 4 (4,m2m) 4
T 1(8,m)
12
12
12
12
Secondary building units:
24
23
22
22
40
43
41
39
61
66
68
66
96
91
97
95
133
128
118
130
163
169
166
158
204
214
224
208
52.6~'6"6~'6-62
5.5.5.5.6.102
5-5.5.5.62.102
5-5"5"5"6~'*
262
258
258
270
5-1
Composite building units:
jbw
mtt
bik
Materials with this framework type"
*Theta-l<~3)
ISI_I ~4~
KZ_2 ~5)
NU_10 (6)
ZSM_22 ~7'8~
ton
335
Theta-1
Crystal chemical data"
Type Material Data
INa. (H20)41 [AlnSi24_nO48]-TON, n < 2
orthorhombic, Cmc2~, a - 13.859A, b - 17.420A, c -
Framework density:
19.7 T/1000,~ 3
Channels:
[001 ] 10 4.6 x 5.7*
TON
5.038A (8)
1 O-ring viewed along [001 ]
References:
(1) Barri, S.A.I., Smith, G.W., White, D. and Young, D. Nature, 312, 533-534 (1984)
(2) Highcock, R.M., Smith, G.W. and Wood, D. Acta Crystallogr., C41, 1391-1394 (1985)
(3) Papiz, Z., Andrews, S.J., Damas, A.M., Harding, M.M. and Highcock, R.M. Acta Crystallogr., C46, 172173 (1990)
(4) Kozo, T. and Noboru, K. E. Patent A-170,003 (1986)
(5) Parker, L.M. and Bibby, D.M. Zeolites, 3, 8-11 (1983)
(6) Araya, A. and Lowe, B.M. Zeolites, 4, 280-286 (1984)
(7) Kokotailo, G.T., Schlenker, J.L., Dwyer, F.G. and Valyocsik, E.W. Zeolites, 5, 349-351 (1985)
(8) Marler, B. Zeolites, 7, 393-397 (1987)
336
TSC
m
Framework Type Data
i
.... :l.......~........
J
Fm3m
'\
framework viewed along [001]
o
Idealized cell data:
cubic, F m 3 m , a - 30.7A
Coordination sequences and vertex symbols:
T 1(192,1) 4
9
16
25
37
53
T 2 (192,1)
4
9
Secondary building units:
17
28
41
56
74
73
99
93
125
117
4.4.4.6.6.8
4.4.4-8.6.8
151
146
8-8 or 8 or 6-6 or 6 or 4-2 or 4
Composite building units:
d6r
d8r
Materials with this framework type:
*Tsch6rtnerite(1)
sod
lta
337
Tsch6rtnerite
Type Material Data
Crystal chemical data"
ICa64(K2,Ca,Sr,Ba)48Cu48 (HzO)x (OH)1281 [A1,92Si192Ov68]-TSC
cubic, Fm-3m, a - 31.62A ~)
F r a m e w o r k density:
12.1 T/1000/~ 3
Channels"
< 1 0 0 > 8 4.2 x 4.2***
8-ring viewed along <100>
~
< 1 1 0 > 8 3.1 x 5.6***
8-ring viewed along <110>
References:
(1) Effenberger, H., Giester, G., Krause, W. and Bernhardt, H.J. Am. Mineral., 83, 607-617 (1998)
TSC
338
TUN
Framework Type Data
C21m
V
X
Z
f r a m e w o r k viewed along [01 O]
Idealized cell data:
monoclinic, C 2 / m , a - 27.8/k, b - 20.0/k, c - 19.6A, 3 - 93-2°
Coordination sequences and vertex symbols:
see Appendix A for a list of the coordination sequences and vertex symbols for the 24 T-atoms
Secondary building units:
5-1
Composite building units:
mor
mtt
Materials w i t h this framework type:
• TNU_9 ~1~
cas
lau
stf
339
TNU-9
TUN
Type Material Data
Crystal chemical data:
IHJ [A19.3Si,82.70384]-TUN
monoclinic, C2/m
a - 28.2219 A, b - 20.0123 A, c - 19.4926 A, ~ - 92.33 ° ~
Framework density:
17.5 T/1000.~ 3
Channels:
{[010] 10 5.6 x 5.5 +-+ [101 ] 10 5.4 x 5.5}***
(There are 2 different channels along [010]; the smaller is 5.1 x 5.5 A)
m
.+.
5.5
1O-ring viewed along [01 O]
/
m
1O-ring viewed along [ 101 ]
References:
(1)
Gramm, F., Baerlocher, Ch., McCusker, L.B., Warrender, S.J., Wright, P.A., Han, B., Hong, S.B., Liu, Z.,
Ohsuna, T. and Terasaki, O. Nature, 444, 79-81 (2006)
340
UEI
Framework Type Data
From2
F
I
z
framework viewed along [010]
Idealized cell data:
orthorhombic, Fmm2, a - 19.5 A, b - 9.4A, c - 15.1/k
Coordination sequences and vertex symbols:
T~(16,1)
T 2(16,1)
T 3(16,1)
4
4
4
10
9
10
Secondary building units:
20
19
21
35
35
36
80
77
76
6 or 4-2 or 4
Composite building units:
dcc
double
crankshaft chain
Materials with this framework type"
• Mu_18 (l)
56
55
53
105
102
108
135
135
142
174
173
173
217
214
210
259
259
259
306
307
310
4-62.4.83.6.82
4.4.4.6.8.83
4.6.4.82.6.8
341
Mu-18
UEI
Type Material Data
Crystal chemical data"
I(CsHHN2)4 (H20)41 [Ga24P24096 (OH)j-UEI
CsH,2N 2 = 1-methylpiperazine
orthorhombic, Aea2, a - 18.035A, b - 10.S13A, c - 14.293A "~
Stability:
reversibly adsorbs water below 350°C ~j~
F r a m e w o r k density:
17.7 T/1000A 3
Channels:
{ [010] 8 3.5 x 4.6 +-+ [001] 8 2.5 x 3.6}**
~
8-ring viewed along [010]
i!
~.~
!'~~,
8-ring viewed along [001]
References:
(1) Josien, L., Simon, A., Gramlich, V. and Patarin, J. Chem. Mater., 13, 1305-1311 (2001)
342
UFI
Framework Type Data
E
~
141mmm
iiiiiii...i.~17:
.... '¸
I
Z
m
framework viewed along [100]
Idealized cell data:
tetragonal, I 4 / m m m , a - 12.1A, c - 28.6A
Coordination sequences and vertex symbols:
T 1 (16,.m.)
T 2(32,1)
T 3(16,.m.)
4
4
4
9
10
10
Secondary building units:
18
19
19
33
31
30
51
46
50
71
64
70
97
91
93
8
Composite building units:
d4r
rth
Materials with this f r a m e w o r k type:
• UZM_5 (1)
lta
124
123
124
153
156
155
195
194
196
241
231
230
283
271
280
4.6.4.6.4.8
4.4.5-6.5.8
4.6.4.6.5-8
343
UZM-5
Type Material Data
U FI
Crystal chemical data"
IK81 [A18Si560,zs]-UFI
tetragonal, I4/mmm, a - 12.1507~,, c - 28.172A ~
Framework density"
15.4 T/1000A 3
Channels:
<100> 8 3.6 x 4.4** ~ [001] 8 3.2 x 3.2 (cage) (i.e. ends in a cage
with this window to the cage)
4.4
~i
4.4
i
8-ring viewed along [100]
References:
(1)
Blackwell, C.S., Broach, R.W., Gatter, M.G., Holmgren, J.S., Jan, D.-Y., Lewis, G.J., Mezza, B.J., Mezza,
T.M., Miller, M.A., Moscoso, J.G., Patton, R.L., Rohde, L.M., Schoonover, M.W., Sinkler, W., Wilson,
B.A. and Wilson, S.T. Angew. Chem., Int. Ed., 42, 1737-1740 (2003)
344
UOZ
P41nnc
Framework Type Data
X
framework viewed along [01 O]
Idealized cell data:
tetragonal, P4/nnc (origin choice 2), a - 8.6/k, c - 27.5A
Coordination sequences and vertex symbols:
T 1 (16,1)
T 2(16,1)
T 3 (4, 4)
T 4(4,222)
4
4
4
4
9
9
12
12
19
19
18
18
34
35
28
26
Secondary building units:
4-1
Composite building units:
d4r
lau
O
Materials with this framework type:
* IM- 10 °~
49
51
52
52
69
69
82
80
100
97
100
88
133
131
120
110
162
164
162
162
195
197
208
214
238
236
244
244
288
287
274
268
4.6.4.6.4.6
4-6.4.6.4.6
6-6.6.6.6.6
6.6.62-62.128.128
345
IM-IO
Type Material Data
UOZ
Crystal chemical data:
I(CI:N:H~o): F41 [Ge40Oso]-UOZ
C12N2H3o = hexamethonium = (1,6-bis(trimethylamino)hexane)
tetragonal, P-4n2, a - 9.1596/~,, c - 28.5614/~, ~)
Framework density:
16.7 T/1000A 3
Channels:
apertures formed by 6-rings only
References:
(1) Mathieu, Y., Paillaud, J.-L., Caullet, P. and Bats, N. MicroporousMesoporous Mat., 75, 13-22 (2004)
346
USI
Framework Type Data
C21m
....
i
.....
U
y
x
frameworkviewedalong[001]
monoclinic, C2/m, a - 21.l/k, b - 13.0A, c - 9.7/k, 3 - 108.4°
Idealized cell data:
Coordination sequences and vertex symbols:
T 1 (8,1)
T 2(8,1)
4
4
4
4
4
T 3 (8,1)
T 4(8,1)
T 5(8,1)
10
9
9
10
9
Secondary building units:
17
15
17
19
18
27
26
26
32
29
46
43
41
47
44
70
61
65
60
68
94
86
85
84
92
112
114
108
122
116
4-1
Composite building units:
dzc
doublezigzag
chain
mei
~
Materials with this framework type:
• IM_6 ~
bog
~ ~
134
139
145
153
144
181
174
181
177
173
230
217
213
209
214
259
260
252
255
267
4.62.4"62" 10" 122
4-63.4.63.4.122
4.4.4-6-6.62
4-4.63.10.63.10
4.4"4"6"6"6
347
IM-6
USI
Type Material Data
Crystal chemical data:
I(CsH,3N2)2 (H30)21 [Co4Ga6P,oO4o]-USI
CsH~3N2 - 1-methylpiperazinium
triclinic, P]-, a - 9.848A, b - 12.470A, c - 12.603A
oL- 63.47 °, ~3- 74.56 °, 7 - 76.03 °(~
Framework density:
15.1 T/1000A 3
Channels:
[100] 12 6.1 x 6.2 * ~
[001] 10 3.9 x 6.4*
..
12-ring viewed along [100]
1O-ring viewed along [001 ]
References:
(1) Josien, L., Simon Masseron, A., Gramlich, V., Patarin, J. and Rouleau, L. Chem. Eur. Journal, 9, 856-861
(2003)
348
UTL
C21m
Framework Type Data
X
framework viewed along [001]
Idealized cell data:
monoclinic, C2/m, a - 29.0/k, b - 14.O/k, c - 12.4/k, 3 - 104.9°
Coordination sequences and vertex symbols:
see Appendix A for a list of the coordination sequences and vertex symbols for the 12 T-atoms
Secondary building units:
see C o m p e n d i u m
Composite building units:
d4r
cas
Materials with this framework type:
• IM_12 ~
ITQ_15 ~2~
fer
non
ton
349
IM-12
Type Material Data
Crystal chemical data:
UTL
[Ge 13.8Si62.20152]-UTL
monoclinic, C2/m
a - 29.8004A, b - 13.9926A, c - 12.3926A, 3 - 105.185°~'~
F r a m e w o r k density:
15.2 T/1000.,~ 3
Channels:
[001 ] 14 7.1 x 9.5" +--+ [010] 12 5.5 x 8.5"
14-ring viewed along [001]
12-ring viewed along [01 O]
References:
(1) Paillaud, J.-L., Harbuzaru, B., Patarin, J. and Bats, N. Science, 304, 990-992 (2004)
(2) Corma, A., DSaz-Cabafias, M.J., Rey, F., Nicolopoulus, S. and Boulahya, K. Chem. Commun., 1356-1357
(2004)
350
m
VET
Framework Type Data
P4
Y
~
Y
x
framework viewed along [001] (upper right: projection down [001])
m
Idealized cell data:
o
o
tetragonal, P 4 , a - 13.0A, c - 4.9A
Coordination sequences and vertex symbols:
T 1(4,1)
T2(4,1)
T 3(4,1)
T 4(4,1)
T5(1,4 )
4
4
4
4
4
12
12
12
12
12
Secondary building units"
24
26
24
23
28
39
41
41
43
38
93
94
95
94
98
see Compendium
Composite building units:
cas
Materials with this framework type:
• VPi_8 (1)
61
65
65
68
60
133
130
128
125
152
179
169
169
172
182
209
218
218
226
200
246
269
270
269
246
5.5.5.62.5-7
5.5.5-6.7.126
5.6.5.6-5.62
5.6.5.6-52.6
5.5.5.5.82.82
351
VPI-8
Type Material Data
Crystal chemical data:
[SilTO34]-VET
tetragonal, P 4 , a - 13.045A, c - 5.034A ~)
Framework density:
19.8 T/1000A 3
Channels:
[001] 12 5.9 x 5.9*
VET
12-ring viewed along [001]
References:
(1) Freyhardt, C.C., Lobo, R.F., Khodabandeh, S., Lewis, J.E., Tsapatsis, M., Yoshikawa, M., Camblor, M.A.,
Pan, M., Helmkamp, M.M., Zones, S.I. and Davis, M.E.J. Am. Chem. Soc., 118, 7299-7310 (1996)
352
VFI
P 6 flmcm
Framework Type Data
~"'<~:.................2 5 2 2 2 2 L 2 ; , 2 2 > , ~ .
//
...:i
~
y
X
framework viewed along [001] (upper right: projection down [001])
Idealized cell data:
h e x a g o n a l , P63/mcm, a - 18.3/k, c - 8.6/k
Coordination sequences and vertex symbols:
T~(24,1)
T 2(12,m)
4
4
11
10
20
18
31
30
44
44
61
60
Secondary building units:
18 or 6 or 4-2
Composite building units"
dnc
aft
82
80
108
106
bog
double
narsarsukite
chain
Materials with this framework type:
• VPi_5 (v3)
A1PO_54 (2~
C o V P I _ 5 (4~
F A P O _ H 1 (5)
H1 (6~
M C M _ 9 (7~
T i V P I - 5 (8~
139
135
174
168
4..62"6"63"62"63
4-63-4-63.6.64
353
VPI-5
Crystal chemical data:
Type Material Data
VFI
1(H2O)421[A1,8P,8072]-VFI
hexagonal, P63, a - 18.975A, c - 8.104A (3~
Framework density:
14.2 T/1000A 3
Channels:
[001] 18 12.7 x 12.7"
18-ring viewed along [001]
References:
(1) Davis, M.E., Saldarriaga, C., Mantes, C., Garces, J. and Crowder, C. Nature, 331,698-699 (1988)
(2) Richardson Jr., J.W., Smith, J.V. and Pluth, J.J.J. Phys. Chem., 93, 8212-8219 (1989)
(3) McCusker, L.B., Baerlocher, Ch., Jahn, E. and Btilow, M. Zeolites, 11,308-313 (1991)
(4) Singh, P.S., Shaikh, R.A., Bandyopadhyay, R. and Rao, B.S. Chem. Commun., 2255-2256 (1995)
(5) Prasad, S. and Yang, T.C. Catalysis Letters, 28, 269-275 (1994)
(6) d'Yvoire, F. Bull. Soc. Chim. France, 1762-1776 (1961)
(7) Derouane, E.G., Maistreiau, L., Gabelica, Z., Tuel, A., Nagy, J.B. and van Ballmoos, R. Appl. Catal., 51,
L13-L20 (1989)
(8) Tusar, N.N., Logar, N.Z., Arcon, I., ThibaultStarzyk, F. and Kaucic, V. Croatica Chemica Acta, 74, 837849 (2001)
354
VNI
P4Jncm
Framework Type Data
z
framework viewedalong [110]
Idealized cell data:
tetragonal, P42/ncm (origin choice 2), a - 10.0A, c - 34.1/k
Coordination sequences and vertex symbols:
T 1 (16,1)
T 2 (8,m)
T 3(8,m)
T 4(8,m)
T 5(8,m)
T 6(8,m)
T 7 (4,2mm)
4
4
4
4
4
4
4
11
11
9
9
9
10
10
Secondary building units:
23
19
20
20
21
18
18
39
39
37
37
41
39
36
93
89
92
87
85
83
82
see Compendium
Composite building units:
l:sv
Materials with this framework type"
• VPI_9 <~)
63
59
61
62
59
65
64
126
130
117
119
133
119
118
170
166
152
158
155
169
176
210
207
201
195
195
218
202
255
274
246
248
261
236
264
4.8-5.82.52.82
4.52.5.8.5.8
3"4"8"82"8"82
3.4.82" 83"82"83
3.4.8.83.8.83
3"83"5"52"5"52
3.82"5"5"5"5
355
Type Material Data
VPI-9
VNI
Crystal chemical data:
IRb44K~ (H20)J [Zn24Si960240]-VNI
tetragonal, P4~2~2, a - 9.884A, c - 73.650A ~
(Relationship to unit cell of Framework Type: a ' = a, b' = b, c ' = 2c)
Framework density:
16.7 T/1000A 3
Channels:
{<110> 8 3.1 x 4.0 +--+[001] 8 3.5 x .3.6}***
8-ring along <110>
8-ring viewed along [001]
2nd 8-ring along <110>
References:
(1) McCusker, L.B., Grosse-Kunstleve, R.W., Baerlocher, Ch., Yoshikawa, M. and Davis, M.E. Microporous
Materials, 6, 295-309 (1996)
356
VSV
14~lamd
Framework Type Data
Z
framework viewed along [100]
Idealized cell data"
tetragonal, I4~/amd, a - 7.2A., c - 41.8/k
Coordination sequences and vertex symbols:
T 1(16,m)
T 2(16,m)
4
4
T 3 (4,4m2) 4
m
9
11
8
Secondary building units:
21
21
20
42
40
48
VSV
Materials with this framework type"
• VPi_7 ~1,2)
Gaultite ~3~
V S V _ 7 # (4)
81
93
84
see Compendium
Composite building units:
lov
61
61
56
123
122
120
159
151
160
198
195
212
246
251
240
3"4"82"94"82"94
4.52.5.8.5-8
3"3"94"94"94"94
357
VSV
Type Material Data
VPI-7
lNa26H6 (H~O)~l [Zn16Si560,44]-VSV
Crystal chemical data:
orthorhombic, Fdd2, a - 39.88A, b - 10.326A, c - 10.219A (2)
(Relationship to unit cell of Framework Type:
a ' - c, b ' - av/2, c ' - by/2
or, as vectors, a ' - c , b ' - b - a, c ' - a + b)
F r a m e w o r k density:
17.1 T/1000A 3
Channels:
[01 1 ] 9 3.3 x 4.3* ~ [011] 9 2.9 x 4.2*+--+ [011] 8 2.1 x 2.7*
I
4.2 'i
m
9-ring along [ O11 ]
9-ring along [011]
8-ring along [011 ]
8-ring viewed along [100]
References:
(1) Annen, M.J., Davis, M.E., Higgins, J.B. and Schlenker, J.L. Chem. Commun., 1175-1176 (1991)
(2) R6hrig, C., Gies, H. and Marler, B. Zeolites, 14, 498-503 (1994)
(3) Ercit, T.S. and van Velthuizen, J. Can. Mineral., 32, 855-863 (1994)
(4) R6hrig, C., Dierdorf, I. and Gies, H. J. Phys. Chem. Solids, 56, 1369-1376 (1995)
358
WEI
Cccm
Framework Type Data
C .........
}
U
Y
X
framework viewed along [001]
Idealized cell data:
orthorhombic, Cccm, a - 11.8/k, b - 10.3/k, c - 10.0A
Coordination sequences and vertex symbols:
T, (16,1)
T 2(4,222)
4
4
9
8
Secondary building units:
18
18
32
32
spiro-5
Composite building units:
lov
VSV
Materials with this framework type:
*Weinebeneite ~)
51
52
74
70
98
98
126
132
163
152
199
200
3-4.6.8.8.10
3.3.6.6.10.10
359
Weinebeneite
Crystal chemical data"
Type Material Data
[Ca 4 (H20),61 [Be~2Pa 032 ( O H ) a ] - W E I
m o n o c l i n i c , Cc
a - 11.897A, b - 9.707A, c - 9.633A, ~ - 95.76 ° ~'~
Framework density:
18.1 T/1000A 3
Channels:
[001] 10 3.1 x 5.4* ~
[100] 8 3.3 x 5.0*
".,.\
1O-ring viewed along [001 ]
References:
(1)
Walter, F. Eur. J. Mineral., 4, 1275-1283 (1992)
8-ring viewed along [100]
WEI
360
-WEN
Framework Type Data
.~.~
•.... :
,
..~:~.,
.¢;J'~ j.,.
P62m
i:z..........................
~:
/ ~ Y
framework viewed along [001]
Idealized cell data:
hexagonal, P-62m, a - 13.6A, c - 7.6A
Coordination sequences and vertex symbols"
T, (12,1)
T 2(6,m)
T 3(2,-6)
4
4
3
9
9
9
16
19
21
27
34
36
46
49
53
73
67
69
Secondary building units:
see Compendium
Composite building units"
dsc
d6r
doublechainSaWtooth
Materials with this framework type:
• Wenkite <~,2)
102
94
90
can
129
125
119
157
157
156
191
195
201
4.4.4.6-6-102
4.8.4.8.6-82
82"82"82
361
Wenkite
-WEN
Type Material Data
C r y s t a l chemical d a t a :
[Ba 4 (Ca,Na2) 3 H20 (SO4)3[ [A18Si~2039(OH)2]- -WEN
hexagonal, P-62m, a - 13.511A, c - 7.462A (2)
F r a m e w o r k density:
17 T/1000A 3
Channels:
<100> 10 2.5 x 4.8** +--+ [001] 8 2.3 x 2.7*
Z%
¢
1O-ring viewed along <100>
References:
(1)
(2)
Wenk, H.-R. Z. Kristallogr., 137, 113-126 (1973)
Merlino, S. Acta Crystallogr., B30, 1262-1266 (1974)
8-ring viewed along [001]
362
YUG
Framework Type Data
C21m
I
~
y
X
framework viewed along [001]
Idealized cell data:
monoclinic, C2/m, a - 10.2/k, b - 13.8A, c - 6.8A, 3 - 111.5 °
Coordination sequences and vertex symbols:
T, (8,1)
T 2(8,1)
4
4
11
10
Secondary building units:
22
22
39
39
61
61
8or4
Materials with this framework type:
-
*Yugawaralite
Sr_Q ~4)
(1-3)
Yugawaralite, Hvalfj6rdur, Iceland ~5~
88
89
120
118
155
153
192
198
241
241
4.5.5-5.8.8
4.4.5.82.5.82
363
Type Material Data
Yugawaralite
Crystal chemical data:
YUG
ICa (H O)J [A14Si~2032]-YUG
monoclinic, Pc, a - 6.73/k, b - 13.95A, c - 10.03A, ~ - 111.5 °~2~
(Relationship to unit cell of Framework Type: a ' = c, b ' = b, c ' = a)
Framework density:
18.3 T/1000A 3
Channels:
[100] 8 2.8 x 3.6* ~ [001] 8 3.1 x 5.0*
8-ring viewed along [100]
8-ring viewed along [001]
References:
(1) Kerr, I.S. and Williams, D.J.Z. Kristallogr., 125, 220-225 (1967)
(2) Kerr, I.S. and Williams, D.J. Acta Crystallogr., B25, 1183-1190(1969)
(3) Leimer, H.W. and Slaughter, M. Z. Kristallogr., 130, 88-111 (1969)
(4) Hawkins, D.B. Mater. Res. Bull., 2, 951-958 (1967)
(5) Kvick, A., Artioli, G. and Smith, J.V.Z. Kristallogr., 174, 265-281 (1986)
364
ZON
Framework Type Data
Pbcm
Z
framework viewed along [100]
Idealized cell data"
orthorhombic, P b c m , a - 6.9A, b - 14.9A, c - 17.2A,
Coordination sequences and vertex symbols:
4
4
4
4
T 1 (8,1)
T 2(8,1)
T 3(8,1)
T 4(8,1)
10
9
10
9
Secondary building units:
21
19
18
17
34
33
33
32
72
78
77
74
6-2 or 4-4- or 4
Composite building units:
sti
Materials with this framework type:
• ZAPO_M1 ~
GaPO_DAB_2 ~z3~
UiO_7 (4'5~
47
53
57
53
108
100
95
98
136
126
129
128
162
166
172
165
200
213
209
208
4.8.4.82.63.8
4.4.4.8.6.63
4.6.4"6-6"8
4-6.4.62.4.8
365
Type Material Data
ZAPO-M1
ZON
Crystal chemical data:
I(C4H,2N)sI [Zn8A124P32O,28]-ZON
C4H~zN = tetramethylammonium
orthorhombic, Pbca, a - 14.226.~, b - 15.117A, c - 17.557.A ~
(Relationship to unit cell of Framework Type: a ' = 2a, b'= b, c'= c)
Framework density:
17 T/1000A, 3
Channels:
[100] 8 2.5 x 5.1" ~ [010] 8 3.7 x 4.4*
8-ring viewed along [100]
8-ring viewed along [01 O]
References:
(1) Marler, B., Patarin, J. and Sierra, L. Microporous Materials, 5, 151-159 (1995)
(2) Schott-Darie, C., Kessler, H., Soulard, M., Gramlich, V. and Benazzi, E. Stud. Surf. Sci. Catal., 84, 101108 (1994)
(3) Meden, A., Grosse-Kunstleve, R.W., Baerlocher, Ch. and McCusker, L.B.Z. Kristallogr., 212, 801-807
(1997)
(4) Akporiaye, D.E., Fjellvag, H., Halvorsen, E.N., Hustveit, J., Karlsson, A. and Lillerud, K.P. Chem.
Commun., 601-602 (1996)
(5) Akporiaye, D.E., Fjellvag, H., Halvorsen, E.N., Hustveit, J., Karlsson, A. and Lillerud, K.P.J. Phys. Chem.,
100, ! 6641-16646 (1996)
367
APPENDIX A
CHA
8-ring viewed normal to [001]
GIS
8-ring viewed along [100]
8-ring viewed along [010]
368
IMF
Coordination sequences and vertex symbols:
T, (8,1)
T~ (16,1)
T 2(16,1)
T 3(16,1)
T 4(16,1)
T 5(16,1)
T 6(16,1)
T 7(16,1)
T 8(16,1)
T 9(16,1)
T~o(16,1)
TI~ (16,1)
T12(16,1)
T,3(8,m..)
T14(8,m..)
T~5(8,m..)
T~6(8,m..)
TI7 (8,m..)
T18(8,m..)
T,9(8,m..)
T~o(8,m..)
T2, (8,m..)
T22(8,m..)
T23(8,m..)
T~4(8,m..)
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
9
12
12
12
12
12
12
12
12
12
12
11
11
12
12
12
12
12
12
10
11
11
11
11
10
18
21
22
21
23
24
24
21
23
25
21
21
23
20
22
19
21
22
21
21
21
20
20
22
22
33
39
37
40
39
39
40
38
38
39
41
37
39
38
34
39
35
35
33
37
35
33
36
37
37
56
65
58
60
61
62
60
60
60
57
64
61
62
63
63
62
62
57
55
61
61
59
62
66
61
84
92
94
88
87
92
91
89
90
88
89
87
93
94
92
88
90
90
94
94
97
93
92
97
89
108
119
129
121
122
126
126
123
126
128
125
121
131
118
119
123
123
126
136
126
123
124
119
120
112
135
157
161
159
162
159
167
161
162
160
161
159
167
150
160
156
161
159
157
162
153
150
152
153
156
179
208
196
202
201
207
204
202
205
195
209
201
201
206
201
199
202
197
185
200
205
189
199
208
215
227
256
248
249
242
251
250
249
256
246
253
251
248
262
243
256
252
241
244
249
260
252
251
267
257
276
290
317
296
301
305
307
305
309
309
303
303
312
291
300
302
306
301
315
312
313
312
305
297
294
326
357
374
358
364
362
368
362
367
369
360
362
377
347
360
358
360
370
384
368
363
366
355
354
348
4.5.4.6.4.10
5-5.5-52-5.103
5.5.5-6-5.62
5.5-5.52.5-102
5.52.5.6.5.103
5.52.5.6.5.103
5.5.5.103.52.6
5.5.5.5-5.6
5.62.5.102.52.6
5.6.5-62.5.102
5.5.5-5.52.102
4-52-5.62.10.10
4.5.5-62.6.102
5-52-5-52-102.0
5.5-5.5-52.102
5.52.5-52.6-*
5.5.5.5.52-6
52-62.52.62.10.122
52.62.52-62.6.*
4-5.4.5-6.102
4.6.5.5.5.5
4-62.5.5.5.5
4-62.5-5.5.5
4.103.5.5.5.5
4.5.4.5.10-102
135
144
142
138
143
138
138
146
143
143
145
156
129
134
126
131
179
177
174
177
179
178
176
180
181
172
190
191
180
165
174
163
227
220
216
219
224
226
219
219
211
216
225
216
220
232
217
225
276
276
275
267
271
265
265
272
271
275
265
261
277
282
268
267
326
330
324
320
325
317
327
323
342
319
320
331
321
312
326
313
4.5.4.6.4.10
4.6.4-62-4.104
4.6-4-62.4.102
4.5.4.6.4.10
5.6.5.62.5.8
5.5.5.6.52.10
5.5-52.8-6-82
4-62.5.6.5.102
4.82.5.5.5.82
4.52.5.5.5.82
4.5.5-62.5.127
4.4.5.62.5-127
4.52.5.6.5.6
4.5~.6.62.6.62
4-52.6.62.6.62
4.52.5.6.5.6
IWW
Coordination sequences and vertex symbols:
T 1 (8,1)
T 2(8,1)
T 3(8,1)
T~(8,1)
T 5(8,1)
T 6(8,1)
T 7(8,1)
T 8(8,1)
T 9(8,1)
T,o(8,1)
TI~ (8,1)
T~2(8,1)
T~(4,..m)
T,4(4,..m)
T,5(4,..m)
T,6(4,..m)
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
9
9
9
9
12
12
12
11
11
11
11
10
11
11
11
11
18
18
19
18
21
18
20
18
24
20
21
20
20
20
22
20
33
33
35
34
36
33
36
33
38
35
34
34
29
29
28
31
56
55
55
56
53
55
55
53
52
54
56
52
50
48
50
46
84
84
80
79
76
77
75
78
77
75
76
78
82
85
80
79
108
114
110
104
106
105
106
116
108
107
106
110
104
111
110
105
369
MFI
Coordination sequences and vertex symbols:
Z l (8,1)
T 2(8,1)
T 3(8,1)
T 4 (8,1)
T 5 (8,1)
T 6(8,1)
T 7(8,1)
T~(8,1)
T 9(8,1)
Tlo(8,1)
T,, (8,1)
TI2 ( 8 , 1 )
4
4
4
4
4
4
4
4
4
4
4
4
12
12
12
12
12
12
12
12
11
11
12
12
22
22
23
21
24
22
24
21
23
22
22
23
41
39
37
36
38
40
38
37
39
36
38
38
61
64
62
61
63
61
56
63
62
61
59
59
88
91
91
90
93
88
90
90
93
93
92
89
125
117
120
122
123
124
132
121
119
120
125
126
159
158
157
159
157
156
164
155
153
154
159
161
198
209
206
196
206
197
193
201
204
200
202
196
250
247
250
251
247
253
241
253
254
255
250
246
5"5"5"102"52"6
5"5"5"52"5"103
5"5"5"52"5"103
5"5"5"52-5"6
5"5"5"62"5"103
5"5"5"5"52"103
5"62"52"62"10"10
5"5"5"5"5"6
4"5"5"62"5"103
4"5"5"62"5"102
5-5"5"6"5"62
5"62"5"102"52"62
146
137
128
147
144
139
138
142
185
175
177
187
176
188
181
166
225
218
228
215
220
244
214
204
42.6.5.5.5.5
5.5.5.5.6.102
4-5.4.5-6.102
4.102-52.62.52.62
4.5.5.62.5.62
4.104.4.104.4.104
4.62.4.62.4.62
5.62.5.62.5.62
117
122
123
121
119
117
113
123
151
154
153
152
152
149
144
152
188
191
186
185
188
185
183
188
4-4.4.82.8-8
4.4-4.82.8.8
4.4.4.82.8.8
4-4.4-82.8-8
4-4.4.82.8.8
4"4"4"6"8"8
4"4"4"6"8"8
4.4.4.82.8.8
MWW
Coordination sequences and vertex symbols:
T, (12,.m.)
T 2 (12,.m.)
T 3 (12,.m.)
T 4 (12,..m)
T 5 (12,..m)
T 6 (4,3m)
T 7 (4,3m)
T 8 (4,3m)
4
4
4
4
4
4
4
4
10
12
10
11
11
10
10
12
20
22
21
18
22
20
16
22
32
35
40
32
32
34
30
31
52
51
62
52
53
54
49
52
76
81
78
78
79
87
77
74
lll
109
95
107
113
114
100
ll2
PAU
Coordination sequences and vertex symbols"
T, (96,1)
T 2 (96,1)
T 3 (96,1)
T 4(96,1)
T 5(96,1)
T 6 (96,1)
T 7 (48,2)
T 8 (48,2)
4
4
4
4
4
4
4
4
9
9
9
9
9
9
9
9
18
18
18
18
18
17
17
18
31
32
32
32
31
29
30
32
47
49
49
48
47
45
47
49
68
70
69
67
68
65
66
69
91
95
94
92
92
89
88
95
370
TUN
Coordination sequences and vertex symbols:
T 1 (8,1)
T 2(8,1)
T 3(8,1)
T 4(8,1)
T 5(8,1)
T 6(8,1)
T 7(8,1)
T 8(8,1)
T 9(8,1)
T1o(8,1)
T,~(8,1)
T12(8,1)
T~3(8,1)
T14(8,1)
T15(8,1)
T16(8,1)
T17(8,1)
T18(8,1)
T~9(8,1)
T2o(8,1)
T21(8,1)
T22(8,1)
T23(8,1)
T24(8,1)
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
12
12
12
12
12
12
12
12
12
12
12
12
12
12
12
11
11
11
11
11
11
11
11
10
22
20
21
22
24
23
21
22
22
20
19
20
24
22
21
21
24
22
21
21
23
21
23
22
34
37
39
37
38
38
37
36
33
36
37
41
38
37
36
34
39
36
35
36
37
38
38
39
59
60
62
58
59
59
56
55
55
60
62
61
61
57
66
57
58
55
58
60
60
60
56
62
88
88
84
89
88
83
90
87
88
87
87
84
91
86
92
90
86
87
86
87
88
86
87
83
116
117
115
124
119
118
121
129
124
113
115
119
121
121
112
123
122
123
117
113
121
116
122
109
157
147
155
158
156
159
154
158
153
154
153
146
154
160
151
150
158
159
150
150
155
152
152
156
198
192
201
190
195
197
198
186
187
196
194
197
194
194
202
187
190
188
198
199
200
197
193
201
235
246
242
234
240
239
234
233
238
244
243
250
244
236
250
238
237
237
241
244
235
247
241
241
285
299
284
298
292
285
292
291
292
289
291
285
297
288
283
296
301
295
288
289
292
291
296
293
347
347
338
363
353
346
350
355
350
336
345
338
346
351
334
361
359
353
352
344
352
339
351
348
5.5.5.5.52-10
5.5.5-52.5.6
5-5.5.5.52.103
5.5.5.6-5-62
5.5-5-103.52.6
5.6.5.102-52.62
5.5.5.5-5.6
52.62.52.62-10.*
5.62.5.122-52-6
5-5.5.52-5-10
5-5-5.5.5~.6
5-52.5.52.102.*
5.52-5.6.5.103
5.5.5-6.52.10
5.5.5-52.5.103
4.52.5-62-6.122
4.5.5.62.6.102
4.62-5-5.5-82
4.5.5.5.5.82
4.52.5.6-10.10
4.62-5-5.5.10
4.52.5-5.5.10
4.5.5-6.10-10
4.5.4.5.10.102
129
130
144
139
140
144
140
147
141
144
145
145
171
166
181
183
176
173
170
176
178
172
178
179
217
220
213
215
208
208
212
215
211
208
223
199
264
263
246
251
255
259
255
249
242
256
252
250
308
311
306
298
310
311
315
300
298
287
284
315
4.5.4.5.4.12
4.5.4.5.4.12
5"5"5"6"52"12
5"5"5"52"5"12
5-5-5"5-5~'6
5"5"5"62"5"12
5"5"5"52"5"12
5"5"5"5"146"*
5"52"5"52"14~'*
5-5.5.5.5.52
5-52.5.5~.14~.*
5.5-5.5-5.62
UTL
Coordination sequences and vertex symbols:
T~ (8,1)
T 2(8,1)
T 3 (8,1)
T 4(8,1)
T 5(8,1)
T 6(8,1)
T 7(8,1)
T 8(4,m)
T 9(4,m)
T~o(4,m)
T~(4,m)
Tl2(4,m)
4
4
4
4
4
4
4
4
4
4
4
4
9
9
12
12
12
12
12
12
12
12
12
12
18
18
22
21
21
22
20
24
20
20
20
22
32
32
34
34
34
33
31
34
34
28
36
30
53
53
49
49
48
52
53
46
48
51
50
49
80
79
73
71
73
76
76
71
68
73
67
73
104
105
102
102
106
107
104
107
107
100
102
106
371
APPENDIX B
Rules for F r a m e w o r k Type A s s i g n m e n t
The following is a set of rules to be applied by the Structure Commission of the IZA in assigning a
three-letter code to a new framework type.
The materials of interest are generally defined as open
4-connected 3D nets which have the general (approximate) composition
AB2, where A is a
tetrahedrally connected atom and B is any 2-connected atom, which may or may not be shared,
between two neighboring A atoms. Inclusion of other microporous materials is left to the discretion of
the IZA Structure Commission, depending on the interest of the molecular sieve science community at
large.
RULES
(i)
The IZA Structure Commission is the only body that can coordinate the assignment of a code to
such frameworks.
The framework types are idealized, with no reference to actual materials,
symmetry, composition, etc. and, therefore, ONLY refer to the connectivity.
(ii) The code for a 4-connected 3D framework type shall consist of three capital letters.
Other
frameworks of interest shall be indicated by a (-) in front of the code.
(iii) The three letters of the code shall be mnemonic and must refer to an actual material (i.e. the type
material). These materials are chosen to be:
- mineral names (rules of the International Mineralogical Association followed).
- commonly accepted synthetic material types.
- in the absence of the above, the workers who first determined the structure have priority in
assigning the name.
(iv) No mnemonic code can be assigned without the structure being determined with the following
exception:
For "polytypic" materials, codes can be assigned as useful. Such codes shall be marked with an
asterisk.
(v) Codes of framework types which turn out to be in error are discredited. Later use of the code is
not permitted.
(vi) For all cases where a decision of the Structure Commission is required, a two thirds majority vote
of the full commission shall be required.
Such votes are taken verbally at a meeting of the
Structure Commission or are done in writing on the initiative of the Chairperson and Cochairperson. All evidence substantiating a new framework type must accompany the ballot. The
members are obliged to respond to this request within one month and the Chairperson and Cochairperson will make all possible effort to solicit replies from all members.
373
APPENDIX C
Secondary Building Units and their Symbols a
a
3
(5)
4
(71)
6
8
12
(51)
(24)
(5)
Spiro-5
(2)
4-4
(4)
6-6
(10)
8-8
(3)
4-1
(13)
4-[1,1]
1-4-1
(7)
4-2
(23)
4=1
(3)
4-4(4)
4-4=1
5-1
(25)
5-[1,1]
(2)
1-5-1
(4)
6-2
(16)
2-6-2
(16)
6"1
(5)
Number in parenthesis = frequency of occurrence
(3)
(4)
5-3
(10)
375
APPENDIX D
Selected Composite Building Units
ordered by number of T-atoms in the unit
Each unit is identified with a lower-case three-character code in italics and the number of T-atoms in
the unit. Framework types containing the unit are listed below each unit.
Iov
5T
nat
6T
vsv
6T
mei
7T
y
LOV, NAB, OBW,
OSO, RSN, VSV, WEI
EDI, NAT, THO
LOV, NAB, OBW,
-RON, RSN, VNI,
VSV, WEI
AFN, CGF, MEI, USI
(see also d4r- 8T,
sti - 8T and bph - 147")
d4r
8T
ACO, AFY, AST, ASV,
BEC,-CLO, DFO, ISV,
ITH, ITW, IWR, IWV,
IWW, LTA, UFI, UOZ,
UTL
mor
8T
*BEA, BEC, DAC,
EON, EPI, IMF, ISV,
IWW, MEL, MFI,
MOR, MSE, RWR,
TUN
sti
8T
bea
AFR, DFO, OWE,
SAO, SBE, SBS, SBT,
SFO, STI, ZON
lOT
*BEA, CON, IFR,
MSE, STT
(see also d4r- 8T)
(see also fer- 137")
bre
lOT
jbw
lOT
mtt
11T
aft
12T
(
BOG, BRE, CON,
HEU, IWR, IWW,
RRO, STI, TER
JBW, MTT, MTW,
SFE, SFN, SSY, TON
CFI, IMF, MFS, MTT,
SFE, SSY, SZR, TON,
TUN
(see also non - 15T)
AEL, AET, AFI, AFO,
ATV, DON, SFH, VFI
(see also b p h - 14T)
376
afs
12T
ats
AFS, BPH
12T
ATS, IMF, OSI
(see also aww- 167)
d6r
12T
lau
12T
AEI, AFT, AFX, CHA,
EAB, EMT, ERI, FAU,
GME, KFI, LEV, LTL,
LTN, MOZ, MSO,
MWW, OFF, SAS,
SAT, SAV, SBS, SBT,
SZR, TSC,-WEN
ASV, ATO, BCT,
CON, DFO, EZT, IFR,
ITH, IWR, IWW, LAU,
MSO, OSI,-RON,
SAO, TUN, UOZ
bik
fer
13T
14T
12T
cas
12T
AEL, AET, AFI, AFO, BOG, CAS, CFI, EUO,
AHT, ATV, BOG,
GON, IHW, IWV, MFI,
CGF, DFO, LAU, TER, MTW, NES, NSI, SFF,
USI, VFI
SFH, SFN, STF, STT,
TER, TUN, UTL, VET
rth
12T
ITE, RTH, UFI
stf
12T
SFF, STF, TUN, IMF,
IWW
(see also mtw - 14 T)
13T
BIK, CAS, MTT, MTW, CDO, FER, IMF, MFS,
NSI, SFE, TON
UTL
me/
bog
mfi
14T
abw
14T
ABW, ATT, JBW
mtw
14T
bph
14T
AFS, BPH, EZT
non
15T
q
CON, DON, ITH, IWR,
IWW, MEL, MFI,
MWW, SFG
MEL, MFI, MTF
*BEA, BEC, GON,
ISV, MSE, MTW, SFH,
SFN
EUO, IHW, IWV, NES,
NON, UTL
377
ton
15T
aww
16T
d8r
16T
~
CFI, IHW, IWV, MTT,
NES, SFE, SSY, TON,
UTL
can
18T
AWW, SAO
AFG, CAN, ERI, FAR,
FRA, GIU, LIO, LOS,
LTL, LTN, MAR, MOZ,
OFF, SAT, SBS, SBT,
TOL, -WEN
atn
24T
ATN, SBE
clo
32T
AWW, -CLO
g~
MSO, SZR
gme
20T
RTE, RUT
mtn
ATT, GIS, SIV
24T
sod
16T
l
.~i#i~¸¸
MER, PAU, RHO,
SBE, TSC
18T
mso
rte
24T
20T
DDR, DOH, MEP,
MTN
/os
30T
AFT, AFX, EAB, EON, EMT, FAR, FAU, FRA,
GME, MAZ, OFF
GIU, LTA, LTN, MAR,
SOD, TSC
FRA, LIO, LOS, TOL
pau
lio
32T
KFI, MER, MOZ, PAU
cha
36T
AFT, CHA
42T
AFG, FAR, LIO, MAR,
TOL
378
48T
aft
48T
Ita
48T
Itl
J
LTL, MOZ
-CLO, KFI, LTA, LTN, PAU,
RHO, TSC, UFI
AFT, AFX
Selected Chains
double zigzag
chain
double crankshaft
chain
double sawtooth
chain
narsarsukite
chain
double
narsarsukite
chain
dzc
dcc
dsc
nsc
dnc
JN¢
,!
ABW, ATN, ATS,
CAN, JBW, OSI,
SFE, SFH, SFN,
SSY, USI
APC, ATT, AWO,
DON, GIS, GME,
MER, PHI, SIV,
UEI
ATT, EON, LTL,
MAZ, MOZ, OFF,
OWE, SAO,WEN
AEL, AET, AFI,
AFO, APD, ATV,
DFT
AET, AHT, VFI
379
Composite Building Unit Nomenclature Comparison
Atlas
abw
aft
afs
aft
atn
ats
aww
bea
bog
bph
bre
can
cas
cha
clo
d4r
d6r
d8r
gis
gme
jbw
lau
lio
los
lov
lta
ltl
mei
mel
mfi
mor
mso
mtn
mtw
nat
non
pau
rte
rth
sod
stf
sti
T-atoms
14
12
12
48
24
12
16
10
12
14
10
18
Compendium a
{2 [4'56289]}
{ 1 [486482]}
[4264]-c
[4664]
[4354]
[4264]-b
[4663]
[4254]
[4665]
12
[5462]
36
32
8
12
16
20
24
10
12
42
30
5
48
48
7
14
14
8
18
20
14
6
15
32
16
12
24
12
8
{3 [4126286]}
{ 1 [486882] }
[46]
[4662]
{2 [4684] }
{2 [496283] }
[64]
[4264]-a
[466 ~7]
[466 ~]
{3 [4~26886]}
{3 [4 ~886122]}
[4 ~5264]
[58]
[54]
[68]-b
[5 ~2]
[425462]
[44]
[4158]
{3 [41286]}
[445462]
[4454]
[4668]
[4156]
[446 l]
J.V. Smith b
kdq
aft
afs
aft
ocn
oth
aww
wwt
bog
afo
bru
can
eun
cha
rpa
cub
hpr
opr
gsm
gme
hes
lau
lio
los
sfi
grc
lil
iet
reel
pen
tes
ber
red
mtw
des
non
pau
tte
cle
toc
huh
sti
Occurence
42628 2-b
mm2
6362
4242628~
464643628683
486482
426262
444264
424 ~5261
4264-b
4663
4254
466362
6-2m
8
mm2
2
5462
46466286
486882
46
4662
4882
444284-a
46436283
64
4264-a
4666666362
46666362
32
4~26886
4 ~24686122-b
436 ~
415262
5454
54-a
6262-a
5 ~2
425462
44
4 ~545252
48448482
445462
4454
4668
4 ~525252
42426~
3
6-2m
2
4/mmm
mm2
2
2
4-2m
2
mm2
mmm
5
13
62m
3
mmm
mm2
2/m
9
18
-32
82m
4 / m-3m
20
2
2
17
6/mmm
8/mmm
25
4-2m
6-2m
43m
3
7
7
4/mmm
17
62m
6-2m
42m
4 / m-3m
5
4
7
5
6/mmm
8
2
3ml
4
mm2
9
42m
42m
3
14
6/mmm
2
53m
4
mmm
8
42m
3
ram2
4/mmm
mmm
6
4
2
4-2m
4 / m-3m
ram2
mm2
3
10
4
10
no equivalents for bik (13T, 7 occurences),fer (13T 5 occurences), mtt (14T, 9 occurences), ton (15T,
9 occurences) or vsv (6T, 8 occurences)
" H. van Koningsveld, Compendium of Zeolite Framework Types. Building Schemes and Type Characteristics,
Elsevier, Amsterdam, 2007
b J.V. Smith, Tetrahedralframeworks ofzeolites, clathrates and related materials, Landolt-B6rnstein, Vol. 14A,
Springer, Berlin, 2000
381
APPENDIX
E
Channel System Dimensions
o r d e r e d by largest ring
20-, 18- & 14-Ring Structures
-CLO
Cloverite
<100> 20 4.0 x 13.2"** I <100> 8 3.8 x 3.8***
ETR
ECR-34
[001] 18 10.1" L _L [001] 8 2.5 x6.0**
VFI
VPI-5
[001] 18 12.7 x 12.7"
AET
A1PO-8
[001] 14 7.9 x 8.7*
CFI
CIT-5
[010] 14 7.2 x 7.5*
DON
UTD-1F
[010] 14 8.1 x 8.2*
OSO
OSB-1
[001] 14 5.4 x 7.3* / _1_ [001] 8 2.8 x 3.3**
SFH
SSZ-53
[001] 14 6.4 x 8.7*
SFN
SSZ-59
[001 ] 14 6.2 x 8.5"
UTL
IM-12
[001] 14 7.1 x 9.5* _1_ [010] 12 5.5 x 8.5*
12-Ring Structures
AFI
A1PO-5
[001] 12 7.3 x 7.3*
AFR
SAPO-40
[001] 12 6.7 x 6.9* _1_ [010] 8 3.7 x 3.7*
AFS
MAPSO-46
[001 ] 12 7.0 x 7.0* L _L [001 ] 8 4.0 x 4.0**
AFY
CoAPO-50
[001] 126.1 x 6.1" L _L [001] 8 4.0 x 4.3"*
ASV
ASU-7
[001] 12 4.1x 4.1"
ATO
A1PO- 31
[001] 12 5.4 x 5.4*
ATS
MAPO-36
[001 ] 12 6.5 x 7.5"
*BEA
Beta polymorph A
<100> 12 6.6 x 6.7** A [001] 12 5.6 x 5.6*
BEC
FOS-5 (Beta pol. C)
[001] 12 6.3 x 7.5* _1_<100> 12 6.0 x 6.9**
BOG
Boggsite
[100] 12 7.0 x 7.0* _1_ [010] 10 5.5 x 5.8*
BPH
Beryllophosphate-H
[001] 12 6.3 x 6.3* A_ _L [001] 8 2.7 x 3.5**
CAN
Cancrinite
[001] 12 5.9 x 5.9*
CON
CIT-1
[001] 12 6.4 x 7.0* ± [100] 12 7.0 x 5.9* _1_ [010] 10 5.1 x 4.5*
CZP
Chiral ZnPO4
[001] 12 3.8 x 7.2* (highly distorted 12-ring)
DFO
DAF-1
{ [001 ] 12 7.3 x 7.3 _1_ A [001 ] 8 3.4 x 5.6 }*** _1_
{[001] 12 6.2 x 6.2 l A [001] 10 5.4 x 6.4}***
EMT
EMC-2
[001] 12 7.3 x 7.3* _1_ 2_ [001] 12 6.5 x 7.5**
382
12-Ring Structures (cont.)
EON
ECR-1
{[100] 12 6.7 x 6.8* 2_ [010] 8 {[001] 3.4 x 4.9 _1_
[100] 8 2.9 x 2.9}*}**
EZT
EMM-3
[ 100] 12 6.5 x 7.4"
FAU
Faujasite
<111> 12 7.4 x 7.4***
GME
Gmelinite
[001] 12 7.0 x 7.0* L _L [001] 8 3.6 x 3.9**
GON
GUS-1
[001] 12 5.4 x 6.8*
IFR
ITQ-4
[001 ] 12 6.2 x 7.2"
ISV
ITQ-7
<100> 12 6.1 x 6.5** ± [001] 12 5.9 x 6.6*
IWR
ITQ-24
[001] 12 5.8 x 6.8* I [110] 10 4.6 x 5.3* I [010] 10 4.6 x 5.3*
IWV
ITQ-27
{[001] 12 6.2 x 6.9 _1_ [011] 12 6.2 x 6.9}**
IWW
ITQ-22
[001] 12 6.0 x 6.7* I n[001] 10 4.9 x 4.9** _1_ [001] 8 3.3 x 4.6*
LTL
Linde Type L
[001] 12 7.1 x 7.1"
MAZ
Mazzite
[001] 12 7.4 x 7.4" I [001] 8 3.1 x 3.1"**
MEI
ZSM-18
[001] 12 6.9 x 6.9* 3_ _1_ [001] 7 3.2 x 3.5**
MOR
Mordenite
[001] 12 6.5 x 7.0* _L [001] 8 2.6 x 5.7***
MOZ
ZSM-10
{[001] 12 6.8 x 7.0 _1_n[001] 8 3.8 x 4.8}*** I [001] 12 6.8 x 6.8*
MSE
MCM-68
{ [001] 12 6.4 x 6.8 ± [100] 10 5.2 x 5.8 l
[110] 10 5.2 x 5.2 }***
MTW
ZSM-12
[010] 12 5.6 x 6.0*
NPO
Nitridophosphate- 1
[100] 12 3.3 x 4.4*
OFF
Offretite
[001] 12 6.7 x 6.8* I _1_ [001] 8 3.6 x 4.9**
OSI
UiO-6
[001] 12 5.2 x 6.0*
-RON
Roggianite
[001 ] 12 4.3 x 4.3"
RWY
UCR-20
<111> 12 6.9 x 6.9***
SAO
STA-1
<100> 12 6.5 x 7.2** 2_ [001] 12 7.0 x 7.0*
SBE
UCSB-8Co
<100> 12 7.2 x 7.4** _1_ [001] 8 4.0 x 4.0*
SBS
UCSB-6GaCo
[001] 12 6.8 x 6.8* I I [001] 12 6.9 x 7.0**
SBT
UCSB- 10GaZn
[001] 12 6.4 x 7.4 * _1_1 [001] 12 7.3 x 7.8**
SFE
SSZ-48
[010] 12 5.4 x 7.6*
SFO
SSZ-51
[001] 12 6.9 x 7.1" ± [010] 8 3.1 x 3.9*
SOS
SU-16
{[100] 12 3.9 x 9.1 I [010] 8 3.3 x 3.3}**
SSY
SSZ-60
[001] 12 5.0 x 7.6*
383
12-Ring Structures (cont.)
USI
IM-6
[100] 12 6.1 x 6.2 * ± [001] 10 3.9 x 6.4*
VET
VPI-8
[001] 12 5.9 x 5.9*
10-Ring Structures
AEL
A1PO- 11
[001] 10 4.0 x 6.5*
AFO
A1PO-41
[001] 10 4.3 x 7.0*
AHT
A1PO-H2
[001 ] 10 3.3 x 6.8*
CGF
Co-Ga-Phosphate-5
{[100] 10 2.5 x 9.2* + 8 2.1 x 6.7*} 2_ [001] 8 2.4 x 4.8*
CGS
Co-Ga-Phosphate-6
{[001] 10 3.5 x 8.1 ± [100] 8 2.5 x4.6}***
DAC
Dachiardite
[010] 10 3.4 x 5.3* _1_ [001] 8 3.7 x 4.8*
EUO
EU-1
[100] 10 4.1 x 5.4* with large side pockets
FER
Ferrierite
[001] 10 4.2 x 5.4* _1_ [010] 8 3.5 x 4.8*
HEU
Heulandite
{[001] 10 3.1 x 7.5* + 8 3.6 x 4.6*} 2_ [100] 8 2.8x 4.7*
IMF
IM-5
{[001] 10 5.5 x 5.6 _1_ [100] 10 5.3 x 5.4}** 2_ {[010] 10
5.3 x 5.9} _1_ {[001] 10 4.8 x 5.4 _1_ [100] 10 5.1 x 5.3}**
ITH
ITQ-13
[001] 10 4.8 x 5.3* _1_ [010] 10 4.8 x 5.1" _1_ [100] 9 4.0 x 4.8*
LAU
Laumontite
[100] 10 4.0 x 5.3* (contracts upon dehydration)
MEL
ZSM-11
<100> 10 5.3 x 5.4***
MFI
ZSM-5
{[100] 10 5.1 x 5.5 _2_ [010] 10 5.3 x 5.6}***
MFS
ZSM-57
[100] 10 5.1 x 5.4* _1_ [010] 8 3.3 x 4.8*
MTT
ZSM-23
[001 ] 10 4.5 x 5.2"
MWW
MCM-22
_1_ [001] 104.0 x 5.5** 12_ [001] 104.1 x 5.1"*
NES
NU-87
[100] 10 4.8 x 5.7**
OBW
OSB-2
{<110> 10 5.0 x 5.0** _1_ ([001] 8 3.4 x 3.4* +
-PAR
Partheite
[001] 10 3.5 x 6.9*
PON
IST-1
[100] 10 5.0 x 5.3*
RRO
RUB-41
[ 100] 10 4.0 x 6.5" _1_ [001 ] 8 2.7 x 5.0*
SFF
SSZ-44
[001] 10 5.4 x 5.7*
SFG
SSZ-58
[001] 10 5.2 x 5.7* 2_ [100] 10 4.8 x 5.7*
STF
SSZ-35
[001] 10 5.4 x 5.7*
STI
Stilbite
[100] 10 4.7 x 5.0* 2_ [001] 8 2.7 x 5.6*
SZR
SUZ-4
{[001] 10 4.1 x 5.2 2_ [010] 8 3.2 x 4.8 _1_ [110] 8 3.0 x 4.8}***
<101> 8 2.8 x 4.0**) _1_ <100> 3.3 x 3.4**}***
384
10-Ring Structures (cont.)
TER
Terranovaite
[ 100] 10 5.0 x 5.0* I [001 ] 10 4.1 x 7.0*
TON
Theta- 1
[001] 10 4.6 x 5.7*
TUN
TNU-9
{[010] 10 5.6 x 5.5 _1_ [101 ] 10 5.4 x 5.5}***
WEI
Weinebeneite
[001] 10 3.1 x 5.4* _1_ [100] 8 3.3 x 5.0*
-WEN
Wenkite
<100> 10 2.5 x 4.8** _1_ [001] 8 2.3 x 2.7*
9-Ring Structures
-CHI
Chiavennite
[001] 9 3.9 x 4.3*
LOV
Lovdarite
[010] 9 3.2 x 4.5* _1_ [001] 9 3.0 x 4.2* _1_ [100] 8 3.6 x 3.7*
NAB
Nabesite
[110] 9 2.7 x 4.1" _t_ [ 1 10 ] 9 3.0 x 4.6*
NAT
Natrolite
<100> 8 2.6 x 3.9** _1_ [001] 9 2.5 x 4.1"
RSN
RUB-17
[100] 9 3.3 x 4.4* _1_ [001] 9 3.1 x 4.3* 2_ [010] 8 3.4 x 4.1"
STT
SSZ-23
[101] 9 3.7 x 5.3* _1_ [001] 7 2.4 x 3.5*
VSV
VPI-7
[01-1] 9 3.3 x 4.3* _1_ [011] 9 2.9 x 4.2* _L [011] 8 2.1 x 2.7*
8-Ring Structures
ABW
Li-A
[001] 8 3.4 x 3.8*
ACO
ACP-1
<100> 8 2.8 x 3.5** _1_ [001] 8 3.5 x 3.5*
AEI
A1PO- 18
{[100] 8 3.8 x 3.8 _1_ [110] 8 3.8 x 3.8 _1_ [001] 8 3.8 x 3.8}***
AEN
A1PO-EN3
[100] 8 3.1 x 4.3* _[_ [010] 8 2.7 x 5.0*
AFN
A1PO-14
[100] 81.9 x 4.6* 2_ [010] 8 2.1 x 4.9* _1_ [001] 8 3.3 x 4.0*
AFT
A1PO-52
_1_ [001] 8 3.2 x 3.8***
AFX
SAPO-56
3_ [001] 8 3.4 x 3.6***
ANA
Analcime
irregular channels formed by highly distorted 8-rings
APC
A1PO-C
[001] 8 3.4 x 3.7* 2_ [100] 8 2.0 x 4.7*
APD
A1PO-D
[010] 8 2.3 x 6.0* _1_ [201] 8 1.3 x 5.8*
ATN
MAPO-39
[001 ] 8 4.0 x 4.0*
ATT
A1PO- 12-TAMU
[100] 8 4.2 x 4.6* _1_ [010] 8 3.8 x 3,8*
ATV
A1PO-25
[001] 8 3.0 x 4.9*
AWO
A1PO-21
[ 100] 8 2.7 x 5.5"
AWW
A1PO-22
[001] 8 3.9 x 3.9*
BCT
Mg-BCTT
[001 ] 8 2.4 x 2.4"
385
8-Ring Structures (cont.)
BIK
Bikitaite
[010] 8 2.8 × 3.7*
BRE
Brewsterite
[100] 8 2.3 x 5.0* _1_ [001] 8 2.8 x 4.1"
CAS
Cs Aluminosilicate
[001] 8 2.4 x 4.7*
CDO
CDS-1
[010] 8 3.1 x 4.7* 2_ [001] 8 2.5 x 4.2*
CHA
Chabazite
_1_ [001] 8 3.8 x 3.8***
DDR
Deca-dodecasil 3R
2_ [001] 8 3.6 x 4.4**
DFT
DAF-2
[001] 8 4.1 x 4.1" 2_ [100] 8 1.8 x 4.7* _1_ [010] 8 1.8 x 4.7*
EAB
TMA-E
_L [001] 8 3.7 x 5.1"*
EDI
Edingtonite
<110> 8 2.8 x 3.8"* 2_ [001] 8 2.0 x 3.1"
EPI
Epistilbite
{[0011 8 3.7 x 4.5 / [100] 8 3.6 x 3.6}**
ERI
Erionite
2_ [001] 8 3.6 x 5.1"**
ESV
ERS-7
[010] 8 3.5 x 4.7*
GIS
Gismondine
{[100] 8 3.1 x 4.5 2_ [010] 8 2.8 x 4.8}***
GOO
Goosecreekite
[100] 8 2.8 x 4.0* ± [010] 8 2.7 x 4.1" _1_ [001] 8 2.9 x 4.7*
IHW
ITQ-32
[100] 8 3.5 x 4.3**
ITE
ITQ-3
[010] 8 3.8 x 4.3* 2_ [001] 8 2.7 x 5.8*
ITW
ITQ-12
[100] 8 2.4 x 5.4* _1_ [001] 8 3.9 x 4.2*
JBW
Na-J
[001] 8 3.7 x 4.8*
KFI
ZK-5
<100> 8 3.9 x 3.9*** [ <100> 8 3.9 x 3.9***
LEV
Levyne
± [001] 8 3.6 x 4.8**
LTA
Linde Type A
<100> 8 4.1 x 4.1"**
MER
Merlinoite
[100] 8 3.1 x 3.5* 2_ [010] 8 2.7 x 3.6* _1_
[001] {8 3.4 x 5.1" + 8 3.3 x 3.3*}
MON
Montesommaite
[100] 8 3.2 x 4.4* _1_ [001] 8 3.6 x 3.6*
MTF
MCM-35
[001] 8 3.6 x 3.9*
NSI
Nu-6(2)
[010] 8 2.6 x 4.5* [ [010] 8 2.4 x 4.8*
OWE
UIO-28
[010] 8 3.5 x 4.0* _1_ [001] 8 3.2 x 4.8*
PAU
Paulingite
<100> 8 3.6 x 3.6*** I <100> 8 3.6 x 3.6***
PHI
Phillipsite
[100] 8 3.8 x 3.8* 2_ [010] 8 3.0 x 4.3* I [001] 8 3.2 x 3.3*
RHO
Rho
<100> 8 3.6 x 3.6*** [ <100> 8 3.6 x 3.6***
RTE
RUB-3
[001] 8 3.7 x 4.4*
RTH
RUB-13
[100] 8 3.8 x 4.1" 2_ [001] 8 2.5 x 5.6*
386
8-Ring Structures (cont.)
RWR
RUB-24
[100] 8 2.8 x 5.0" I [010] 8 2.8 x 5.0*
SAS
STA-6
[001] 8 4.2 x 4.2*
SAT
STA-2
_1_ [001] 8 3.0 x 5.5***
SAV
Mg-STA-7
<100> 8 3.8 x 3.8** 2_ [001] 8 3.9 x 3.9*
SIV
SIZ-7
{[100] 8 (3.5 x 3.9 + 8 3.7 x 3.8 _1_ [110] 8 3.7 x 3.8 _1_
[001] 8 3.8 x 3.9} ***
THO
Thomsonite
[100] 8 2.3 x 3.9* _1_ [010] 8 2.2 x 4.0* _1_ [001] 8 2.2 x 3.0*
TSC
Tsch6rtnerite
<100> 8 4.2 x 4.2*** 3_ <110> 8 3.1 x 5.6***
UEI
Mu-18
{[010] 8 3.5 x 4.6 _1_ [001] 8 2.5 x 3.6}**
UFI
UZM-5
<100> 8 3.6 x 4.4** _1_ [001] 8 3.2 x 3.2(cage) i.e. ends in a cage
VNI
VPI-9
{<110> 8 3.1 x 4.0 _1_ [001] 8 3.5 x .3.6}***
YUG
Yugawaralite
[100] 8 2.8 x 3.6* _1_ [001] 8 3.1 x 5.0*
ZON
ZAPO-M1
[100] 8 2.5 x 5.1" _1_ [010] 8 3.7 x 4.4*
387
APPENDIX F
Topological Densities
Code
TD10a
ABW
ACO
AEI
AEL
AEN
AET
AFG
AFI
AFN
AFO
AFR
AFS
AFT
AFX
AFY
AHT
ANA
APC
APD
AST
ASV
ATN
ATO
ATS
ATT
ATV
AWO
AWW
BCT
833
787
689
904
956
824
816
828
777
907
687
656
685
689
585
853
933
814
888
742
787
833
894
752
768
960
828
772
959
805
764
1052
781
667
901
817
1042
1053
892
819
718
677
*BEA
BEC
BIK
BOG
BPH
BRE
CAN
CAS
CDO
CFI
CGF
CGS
CHA
TD b
Code
TDlo ~
0.703
0.666
0.583
0.766
0.857
0.697
0.693
0.700
0.661
0.769
0.579
0.568
0.585
0.585
0.488
0.729
0.800
0.696
0.759
0.625
0.666
0.703
0.760
0.640
0.647
0.816
0.708
0.656
0.814
0.704
0.656
0.907
0.659
0.568
0.778
0.693
0.895
0.930
0.765
0.695
0.613
0.566
-CHI
-CLO
CON
CZP
DAC
DDR
DFO
DFT
DOH
DON
EAB
EDI
EMT
EON
EPI
ERI
ESV
ETR
EUO
EZT
FAR
FAU
FER
FRA
GIS
GIU
GME
GON
GOO
HEU
IFR
IHW
IMF
ISV
ITE
ITH
ITW
IWR
IWV
IWW
JBW
KFI
913
456
784
885
977
968
664
840
1002
851
735
786
584
873
979
738
875
675
965
754
806
579
1021
802
726
811
694
926
840
909
798
1013
964
772
824
910
901
759
802
849
890
681
TD b
Code
TD10a
0.833
0.443
0.670
0.800
0.841
0.850
0.576
0.711
0.882
0.728
0.628
0.666
0.493
0.769
0.845
0.628
0.754
0.576
0.872
0.639
0.693
0.476
0.887
0.683
0.611
0.693
0.585
0.787
0.716
0.778
0.678
0.898
0.846
0.694
0.711
0.799
0.769
0.651
O.700
0.756
0.753
0.571
LAU
LEV
LIO
-LIT
LOS
LOV
LTA
LTL
LTN
MAR
782
719
816
768
816
879
641
746
779
808
823
728
944
1059
738
960
995
1033
938
757
867
822
1083
1049
1015
912
851
873
834
922
1038
869
1016
756
739
892
747
809
773
728
751
845
MAZ
MEI
MEL
MEP
MER
MFI
MFS
MON
MOR
MOZ
MSE
MSO
MTF
MTN
MTT
MTW
MWW
NAB
NAT
NES
NON
NPO
NSI
OBW
OFF
OSI
OSO
OWE
-PAR
PAU
PHI
PON
TD b
0.658
0.605
0.693
0.655
0.693
0.754
0.533
0.619
0.698
0.693
0.697
0.630
0.808
0.955
0.622
0.825
0.866
0.885
0.802
0.642
0.753
0.694
0.942
0.927
0.883
0.776
0.752
0.740
0.740
0.818
0.915
0.750
0.869
0.689
0.628
0.777
0.645
0.685
0.664
0.623
0.635
0.725
388
Code
TDlo a
TW
Code
TDlo a
TW
Code
TDlo a
TW
RHO
-RON
RRO
RSN
RTE
RTH
RUT
RWR
RWY
SAO
SAS
SAT
SAV
SBE
SBS
SBT
SFE
641
771
924
914
844
817
902
1052
410
632
701
763
690
619
617
617
892
0.533
0.688
0.801
0.786
0.715
0.695
0.767
0.919
0.333
0.545
0.586
0.644
0.587
0.514
0.534
0.522
0.767
SFF
SFG
SFH
SFN
SFO
SGT
SIV
SOD
SOS
SSY
STF
STI
STT
SZR
TER
THO
TOL
880
932
835
819
681
962
741
791
728
900
877
852
859
910
872
784
816
0.765
0.850
0.724
0.692
0.575
0.862
0.636
0.666
0.631
0.784
0.748
0.720
0.760
0.780
0.739
0.666
0.693
TON
TSC
TUN
UEI
UFI
UOZ
USI
UTL
VET
VFI
VNI
VSV
WEI
-WEN
YUG
ZON
1006
590
929
832
747
776
691
826
1023
669
971
948
773
755
935
798
0.867
0.482
0.803
0.708
0.641
0.658
0.590
0.713
0.913
0.562
0.896
0.818
0.655
0.640
0.797
0.679
sum of all values of the coordination sequence from N Oto N m.
b topological density TD 1000:100 as defined in the Explanatory Notes.
a
389
APPENDIX G
Origin of 3-Letter Codes and Material Names
Code
ABW
ACO
AEI
AEL
AEN
AET
AFI
AFN
AFO
AFR
AFS
AFT
AFX
AFY
AHT
APC
APD
AST
ASV
ATN
ATO
ATS
ATT
ATV
AWO
AWW
*BEA
BPH
CAS
CDO
CFI
CGF
CGS
-CLO
CON
CZP
DDR
DFO
DFT
DOH
DON
EAB
EMT
Abbreviated Name
ACP- 1 (one)
A1PO4-18 (eighteen)
A1PO4-11 (eleven)
A1PO-EN3
A1PO4-8 (eight)
A1PO4-5 (five)
A1PO4-14 (forteen)
A1PO4-41 (forty-one)
SAPO-40 (forty)
MAPSO-46 (forty-six)
A1PO4-52 (fifty-two)
SAPO-56 (fifty-six)
CoAPO-50 (fifty)
A1PO4-H2 (two)
A1PO4-C
A1PO4-D
A1PO4-16 (sixteen)
ASU-7 (seven)
MAPO-39 (thirty-nine)
A1PO4-31 (thirty-one)
MAPO-36 (thirty-six)
A1PO4-12 (twelve)-TAMU
A1PO4-25 (twenty-five)
A1PO4-21 (twenty-one)
A1PO4-22 (twenty-two)
Zeolite Beta
Beryllophosphate-H
Cesium Aluminsilicate
CDS- 1 (one)
CIT-5 (five)
CoGaPO-5 (five)
CoGaPO-6 (six)
Cloverite
CIT- 1 (one)
Deca-dodecasil 3R
DAF- 1 (one)
DAF-2 (two)
Dodecasil 1H
UTD- 1 (one)
EMC-2 (two)
Full Name
Li-A (Barrer and White)
Aluminium Cobalt Phosphate - one
Aluminophosphate-eighteen
Aluminophosphate-eleven
Aluminophosphate ethylenediamine (en) - three
Aluminophosphate-eight
Aluminophosphate-five
Aluminophosphate-forteen
Aluminophosphate-forty-one
Silico-Aluminophosphate-forty
MgAl(P,Si)O4-46
Silico-Aluminophosphate-fifty-six
Arizona State University- seven
MgA1PO 4- thirty-nine
A1PO4-12-Texas A&M University
Beryllophosphate-Harvey (or hexagonal)
Cylindrically Double Saw-edged structure - one
California Institute of Technology - five
Cobalt-Gallium-Phosphate-five
Cobalt-Gallium-Phosphate-six
Four-leafed dover shaped pore opening
California Institute of Technology - one
Chiral Zincophosphate
Deea- & dodecahedra, 3 layers, rhombohedral
Davy Faraday Research Laboratory - one
Davy Faraday Research Laboratory - two
Dodecahedra, 1 layer, hexagonally stacked
University of Texas at Dallas-one
TMA-E (Aiello and Barrer)
Elf (or Ecole Sup6rieure) Mulhouse Chimie - two
390
EON
ESV
ETR
EUO
EZT
GIU
GON
IFR
IMF
ISV
ITE
ITH
ITW
IWR
IWV
IWW
JBW
KFI
LOS
LTA
LTL
LTN
MEI
MEL
MFI
MFS
MSE
MSO
MTF
MTN
MTT
MTW
MWW
NES
NON
NPO
NSI
OBW
OSI
OSO
PON
-RON
RRO
RSN
RTE
RTH
RUT
ECR- 1 (one)
ERS-7 (seven)
ECR-34 (thirty-four)
EU- 1 (one)
EMM-3 (three) (Z for
zeolite)
Giuseppettite
GUS-1 (one)
ITQ-4 (four)
IM-5 (five)
ITQ-7 (seven)
ITQ-3 (three)
ITQ-13 (thirteen)
ITQ-12 (twelve)
ITQ-24 (twenty-four)
ITQ-27 (twenty-seven)
ITQ-22 (twenty-two)
ZK-5 (five)
Losod
Linde Type A
Linde Type L
Linde Type N
ZSM- 18 (eighteen)
ZSM- 11 (eleven)
ZSM-5 (five)
ZSM-57 (fifty-seven)
MCM-68 (sixty-eight)
MCM-61 (sixty-one)
MCM-35 (thirty-five)
ZSM-39 (thirty-nine)
ZSM-23 (twenty-three)
ZSM-12 (twelve)
MCM-22 (twenty-two)
NU-87 (eighty-seven)
Nonasil
Oxonitridophosphate- 1 (one)
Nu-6(2) (six)
OSB-2 (two)
UiO-6 (six)
OSB-1 (one)
IST-1, Portugal Number One
Roggianite
RUB-41 (forty-one)
RUB- 17 (seventeen)
RUB- 3 (three)
RUB- 13 (thirteen)
RUB- 10 (ten)
Exxon Cooperate Research- one
Eniricerche-molecular-sieve-seven
Exxon Cooperate Research- thirty-four
Edinburgh Univerisity - one
Exxon-Mobil Material - three
Gifu University Molecular Sieve - one
Instituto de Tecnologia Quimica Valencia- four
Institut Franqais du P6trole and University of Mulhouse five
Instituto de Tecnologia Quimica Valencia - seven
Instituto de Tecnologia Quimica Valencia- three
Instituto de Tecnologia Quimica Valencia - thirteen
Instituto de Tecnologia Quimica Valencia- twelve
Instituto de Tecnologia Quimica Valencia- twenty-four
Instituto de Tecnologia Quimica Valencia- twenty-seven
Instituto de Tecnologia Quimica Valencia- twenty-two
Na-J (Barrer and White)
Zeolite Kerr- five
Low sodium aluminosilicate
Zeolite A (Linde Division, Union Carbide)
Zeolite L (Linde Division, Union Carbide)
Zeolite N (Linde Division, Union Carbide)
Zeolite Socony Mobil - eighteen
Zeolite Socony Mobil - eleven
Zeolite Socony Mobil - five
Zeolite Socony Mobil - fifty-seven
Mobil Composition of Matter- sixty-eight
Mobil Composition of Matter- sixty-one
Mobil Composition of Matter- thirty-five
Zeolite Socony Mobil - thirty-nine
Zeolite Socony Mobil - twenty-three
Zeolite Socony Mobil - twelve
Mobil Composition of Matter-twenty-two
New (ICI) - eighty-seven
Nonahedra, all silica composition
N e w (ICI) - six
Universities of Oslo and Calif., Santa Barbara - two
University of Oslo- six
Universities of Oslo and Calif., Santa Barbara - one
Instituto Superior T6cnico, Lisboa, - one
Ruhr University Bochum - forty-one
Ruhr University Bochum- seventeen
Ruhr University Bochum - three
Ruhr University Bochum- thirteen
Ruhr University Bochum- ten
391
RWR
RWY
SAO
SAS
SAT
SAV
SBE
SBS
SBT
SFE
SFF
SFG
SFH
SFN
SFO
SGT
SIV
SOS
STF
STT
SSY
SZR
TOL
TON
TUN
UEI
UFI
UOZ
RUB-24 (twenty-four)
UCR-20 (twenty)
STA- 1 (one)
STA-6 (six)
STA-2 (two)
Mg-STA-7 (seven)
UCSB-8 (eight)
UCSB-6 (six)
UCSB- 10 (ten)
SSZ-48 (forty-eight)
SSZ-44 (forty-four)
SSZ-58 (fifty-eight)
SSZ-53 (fifty-three)
SSZ-59 (fifty-nine)
SSZ-51 (fifty-one)
Sigma-2 (two)
SIZ-7 (seven)
SU- 16 (one-six)
SSZ-35 (thirty-five)
SSZ-23 (twenty-three)
SSZ-60 (sixty)
SUZ-4 (four)
Tounkite-like mineral
Theta- 1 (one)
TNU-9 (nine)
MU- 18 (eighteen)
UZM-5 (five)
IM- 10, Mulhouse (one-zero)
USI
IM-6, Mulhouse (six)
UTL
IM- 12, Mulhouse (twelve)
UWE
VET
VFI
VNI
VSV
ZON
UIO-28 (twenty-eight)
VPI-8 (eight)
VPI-5 (five)
VPI-9 (nine)
VPI-7 (seven)
ZAPO-M 1 (one)
Ruhr University Bochum - twenty-four
University of California, Riverside -twenty
University of Saint Andrews - one
University of Saint Andrews - six
University of Saint Andrews - two
University of Saint Andrews- seven
University of California, Santa Barbara - eight
University of California, Santa Barbara - six
University of California, Santa Barbara - ten
Standard Oil Synthetic Zeolite - fourty-eight
Standard Oil Synthetic Zeolite- fourty-four
Standard Oil Synthetic Zeolite- fifty-eight
Standard Oil Synthetic Zeolite- fifty-three
Standard Oil Synthetic Zeolite - fifty-nine
Standard Oil Synthetic Zeolite - fifty-one
St. Andrews Ionothermal Zeolite - seven
Stockholm University- sixteen
Standard Oil Synthetic Zeolite - thirty-five
Standard Oil Synthetic Zeolite- twenty-three
Standard Oil Synthetic Zeolite- sixty
Sunbury Zeolite- four
Taejon National University - nine
Mulhouse - eighteen
UOP Zeolitic Material - five
Institut Franqais du P6trole and University of Mulhouse ten
lnstitut Franqais du P6trole and University of Mulhouse six
lnstitut Franqais du P6trole and University of Mulhouse twelve
University of O s l o - twenty-eight
Virgina Polytechnic Institute - eight
Virgina Polytechnic Institute - five
Virgina Polytechnic Institute - nine
Virgina Polytechnic Institute- seven
(Zn,A1)PO4 -Mulhouse - one
393
Isotypic Material Index
*ACP-1
ACP-2
ACP-3
*Afghanite
AI-ITQ-13
A1-Nu- 1
Al-rich beta
Alpha
A1PO-pollucite
*A1PO- 11
*A1PO- 12-TAMU
*A1PO-14
*A1PO-16
A1PO-17
*A1PO- 18
A1PO-20
*A1PO-21
*A1PO-21
*A1PO-22
A1PO-24
*A1PO-25
*A1PO-31
*A1PO- 31
A1PO-33
A1PO-33
A1PO-34
A1PO-35
A1PO-36
A1PO-40
A1PO-40
*A1PO-41
*A1PO-5
*A1PO-52
*A1PO-52
A1PO-53(A)
A1PO-53(B)
A1PO-54
*A1PO-8
*A1PO-8
*A1PO-C
*A1PO-C
A1PO-CJB 1
*A1PO-D
*A1PO-EN3
*A1PO-H2
ACO
OWE
DFT
AFG
ITH
RUT
*BEA
LTA
ANA
AEL
ATT
AFN
AST
ERI
AEI
SOD
AWO
AWO
AWW
ANA
ATV
ATO
ATO
ATT
ATT
CHA
LEV
ATS
AFR
AFR
AFO
AFI
AFT
AFT
AEN
AEN
VFI
AET
AET
APC
APC
AWW
APD
AEN
AHT
*A1PO-H2
*A1PO-H2
A1PO-H3
Amicite
Ammonioleucite
AMS-1B
*Analcime
*Analcime
*Analcime
APO-CJ3
*ASU-7
AZ-1
B-Nu-1
Barrerite
Basic cancrinite
Basic sodalite
Bellbergite
Beryllophosphate X
*Beryllophosphate-H
*Beta
Bicchulite
*Bikitaite
*Boggsite
Bor-C
Bor-D
Boralite C
Boralite D
*Brewsterite
Bystrite
Ca-D
Ca-Q
*Cancrinite
Cancrinite hydrate
*CDS-1
*Cesium Aluminosilicate
CF-3
CF-4
CFSAPO-1A
*Chabazite
*Chiavennite
*Chiral Zincophosphate
*CIT-1
CIT-4
*CIT-5
CIT-6
AHT
AHT
APC
GIS
ANA
MFI
ANA
ANA
ANA
APD
ASV
MFI
RUT
STI
CAN
SOD
EAB
FAU
BPH
*BEA
SOD
BIK
BOG
MFI
MEL/MFI
MFI
MEL
BRE
LOS
ANA
MOR
CAN
CAN
CDO
CAS
NON
MTN
AEN
CHA
-CHI
CZP
CON
BRE
CFI
*BEA
394
Clinoptilolite
*Cloverite
*Co-Ga-Phosphate-5
*Co-Ga-Phosphate-6
Co-STA-7
CoAPO-40
CoAPO-44
CoAPO-47
CoAPO-5
*CoAPO-50
CoAPO-H3
CoAPSO-40
CoDAF-4
CoIST-2
COK-5
CoVPI-5
CrAPO-5
CSZ-1
CZH-5
*Dachiardite
*DAF-1
*DAF-2
DAF-5
DAF-8
Danalite
Davyne
*Deca-dodecasil 3R
Dehyd. boggsite
Dehyd. brewsterite
Dehyd. Ca,NH4-Heulandite
Dehyd. Linde Type A
Dehyd. Na-Chabazite
Dehyd. Na-X
Dehyd. US-Y
Deuterated Rho
*Dodecasil 1H
Dodecasil-3C
*ECR-1
ECR-18
ECR-30
*ECR-34
ECR-40
ECR-5
*Edingtonite
*EMC-2
*EMM-3
Encilite
*Epistilbite
ERB-1
HEU
-CLO
CGF
CGS
SAV
AFR
CHA
CHA
AFI
AFY
APC
AFR
LEV
AEN
MFS
VFI
AFI
EMT/FAU
MTW
DAC
DFO
DFT
CHA
PHI
SOD
CAN
DDR
BOG
BRE
HEU
LTA
CHA
FAU
FAU
RHO
DOH
MTN
EON
PAU
EMT/FAU
ETR
MEI
CAN
EDI
EMT
EZT
MFI
EPI
MWW
*Erionite
*ERS-7
*EU-1
EU-13
EU-20
EU-20b
FAPO-36
FAPO-5
FAPO-H1
*Farneseite
*Faujasite
Fe(III)-BCTT
Fe-Nu-1
*Ferrierite
FJ-17
*FOS-5
*Franzinite
FU-9
FZ-1
G
Ga-Nu-1
Gallosilicate ECR- 10
Gallosilicate L
GaPO-14
GaPO-34
GaPO-DAB-2
Garronite
Gaultite
GeAPO- 11
Genthelvite
*Gismondine
*Giuseppettite
*Gmelinite
Gobbinsite
Gonnardite
*Goosecreekite
Gottardiite
*GUS-1
H1
Harmotome
Hauyn
Helvin
*Heulandite
Heulandite-Ba
High natrolite
High-silica Na-P
Holdstite
Hsianghualite
Hydroxo sodalite
ERI
ESV
EUO
MTT
CAS/NSI
CAS/NSI
ATS
AFI
VFI
FAR
FAU
BCT
RUT
FER
SOS
BEC
FRA
FER
MFI
SOD
RUT
RHO
LTL
AFN
CHA
ZON
GIS
VSV
AEL
SOD
GIS
GIU
GME
GIS
NAT
GOO
NES
GON
VFI
PHI
SOD
SOD
HEU
HEU
NAT
GIS
MTN
ANA
SOD
395
*IM-10
*IM-12
*IM-5
*IM-6
IM-7
ISI-1
ISI-4
ISI-6
*IST-1
IST-2
ITQ-1
*ITQ-12
*ITQ-13
ITQ-14
ITQ-15
ITQ-17
*ITQ-22
*ITQ-24
*ITQ-27
ITQ-29
*ITQ-3
*ITQ-32
*ITQ-4
*ITQ-4
*ITQ-7
ITQ-9
JDF-2
(K,Ba)-G,L
K-F
K-M
K-rich gmelinite
KZ-1
KZ-2
Large port mordenite
*Laumontite
Leonhardite
Leucite
*Levyne
*Li-A
Li-LSX
Linde D
Linde F
Linde Q
Linde R
Linde T
*Linde Type A (zeolite A)
*Linde Type L (zeolite L)
*Linde Type N
Linde W
UOZ
UTL
IMF
USI
ITH
TON
MTT
FER
PON
AEN
MWW
ITW
ITH
BEC
UTL
BEC
IWW
IWR
IWV
LTA
ITE
IHW
IFR
IFR
ISV
STF
AEN
LTL
EDI
MER
GME
MTT
TON
MOR
LAU
LAU
ANA
LEV
ABW
FAU
CHA
EDI
BPH
CHA
ERUOFF
LTA
LTL
LTN
MER
*Liottite
*Lithosite
*Losod
*Lovdarite
low melanophlogite
Low-silica Na-P (MAP)
LZ-105
LZ-132
LZ-202
LZ-210
LZ-211
LZ-212
LZ-214
LZ-215
LZ-217
LZ-218
LZ-219
LZ-220
MAP
MAPO-31
*MAPO-36
*MAPO-39
MAPO-43
MAPO-46
MAPO-5
MAPSO-43
*MAPSO-46
MAPSO-56
Maricopaite
*Marinellite
*Mazzite
*MCM-22
*MCM-35
MCM-37
MCM-58
*MCM-61
MCM-65
*MCM-68
MCM-9
MCS-1
MeAPO-47
MeAPSO-47
*Melanophlogite
*Merlinoite
Mesolite
Metanatrolite
Metavariscite
*Mg-BCTT
*Mg-STA-7
LIO
-LIT
LOS
LOV
MEP
GIS
MFI
LEV
MAZ
FAU
MOR
LTL
RHO
LTA
OFF
CHA
HEU
ERI
GIS
ATO
ATS
ATN
GIS
AFS
AFI
GIS
AFS
AFX
MOR
MAR
MAZ
MWW
MTF
AET
IFR
MSO
CDO
MSE
VFI
AEN
CHA
CHA
MEP
MER
NAT
NAT
BCT
BCT
SAV
396
MgAPO-50
Microsommite
MnAPO- 11
MnAPO- 14
MnAPO-41
MnAPO-50
MnAPSO-41
*Montesommaite
*Mordenite
Mu-10
Mu-13
Mu-14
*Mu-18
Mu-26
Mutinaite
N-A
Na-B
Na-D
*Na-J
Na-P1
Na-P2
Na-V
*Nabesite
*Natrolite
NaZ-21
Nepheline hydrate
(Ni(deta)2)-UT-6
*Nitridophosphate- 1
*Nonasil
Nosean
Nu-1
NU-10
NU-13
NU-23
NU-3
NU-4
NU-5
*Nu-6(2)
*NU-87
o-FDBDM-ZSM-50
Octadecasil
*Offretite
Omega
*OSB-1
*OSB-2
P
Pahasapaite
Paranatrolite
*Partheite
AFY
CAN
AEL
AEN
AFO
AFY
AFO
MON
MOR
AEN
MSO
ITE
UEI
STF
MFI
LTA
ANA
MOR
JBW
GIS
GIS
THO
NAB
NAT
LTN
JBW
CHA
NPO
NON
SOD
RUT
TON
MTW
FER
LEV
MFI
MFI
NSI
NES
EUO
AST
OFF
MAZ
OSO
OBW
KFI
RHO
NAT
-PAR
*Paulingite
Perlialite
Phi
*Phillipsite
Pollucite
Primary leonhardite
PSH-3
Q
*Rho
RMA-3
*Roggianite
RUB-1
*RUB-10
*RUB-13
*RUB-17
*RUB-24
*RUB-24
*RUB-3
*RUB-3
*RUB-41
SAPO- 11
SAPO-18
SAPO-31
SAPO-31
SAPO-34
SAPO-35
SAPO-37
SAPO-39
*SAPO-40
SAPO-41
SAPO-42
SAPO-43
SAPO-47
SAPO-5
*SAPO-56
Scolecite
Sigma-1
*Sigma-2
Silicalite
Silicalite 2
Siliceous Na-Y
*SIZ-7
SIZ-8
SIZ-9
*Sodalite
Sr-D
Sr-Q
SSZ-16
*SSZ-23
PAU
LTL
CHA
PHI
ANA
LAU
MWW
KFI
RHO
ATT
-RON
LEV
RUT
RTH
RSN
RWR
RWR
RTE
RTE
RRO
AEL
AEI
ATO
ATO
CHA
LEV
FAU
ATN
AFR
AFO
LTA
GIS
CHA
AFI
AFX
NAT
DDR
SGT
MFI
MEL
FAU
SIV
AEI
SOD
SOD
FER
YUG
AFX
STT
397
SSZ-24
SSZ-25
SSZ-26
SSZ-33
*SSZ-35
SSZ-36
SSZ-39
SSZ-42
*SSZ-44
SSZ-46
*SSZ-48
SSZ-50
*SSZ-51
*SSZ-53
SSZ-55
*SSZ-58
*SSZ-59
*SSZ-60
SSZ-73
*STA-1
*STA-2
STA-5
*STA-6
Stellerite
*Stilbite
*SU-16
*SUZ-4
Svetlozarite
Svyatoslavite
Synthetic amicite
Synthetic analcime
Synthetic barrerite
Synthetic brewsterite
Synthetic Ca-garronite
Synthetic cancrinite
Synthetic edingtonite
Synthetic epistilbite
Synthetic garronite
Synthetic gobbinsite
Synthetic gonnardite
Synthetic hsinghualite
Synthetic laumontite
Synthetic lovdarite
Synthetic melanophlogite
Synthetic merlinoite
Synthetic mesolite
Synthetic natrolite
Synthetic offretite
Synthetic scolecite
AFI
MWW
CON
CON
STF
ITE/RTH
AEI
IFR
SFF
MEL
SFE
RTH
SFO
SFH
ATS
SFG
SFN
SSY
SAS
SAO
SAT
BPH
SAS
STI
STI
SOS
SZR
DAC
BCT
GIS
ANA
STI
BRE
GIS
CAN
EDI
EPI
GIS
GIS
NAT
ANA
LAU
LOV
MEP
MER
NAT
NAT
OFF
NAT
Synthetic stellerite
Synthetic stilbite
Synthetic thomsonite
Synthetic wairakite
*Terranovaite
Tetragonal edingtonite
Tetranatrolite
*Theta-1
Theta-3
*Thomsonite
Tiptopite
TiVPI-5
TMA sodalite
*TMA-E
TMA-gismondine
TMA-O
TNU-1
TNU-10
TNU-7
*TNU-9
*Tounkite-like mineral
TPZ- 12
TPZ-3
Triclinic bikitaite
TS-1
TS-2
*Tsch6rtnerite
Tschernichite
TsG-1
TSZ
TSZ-III
Tugtupite
TZ-01
*UCR-20
UCSB- 10Co
*UCSB-10GaZn
UCSB-10Mg
UCSB-10Zn
UCSB-3
UCSB-3GaGe
UCSB-3ZnAs
UCSB-6Co
*UCSB-6GaCo
UCSB-6GaMg
UCSB-6GaZn
UCSB-6Mg
UCSB-6Mn
UCSB-6Zn
*UCSB-8Co
STI
STI
THO
ANA
TER
EDI
NAT
TON
MTW
THO
CAN
VFI
SOD
EAB
GIS
OFF
CGS
STI
EON
TUN
TOL
MTW
EUO
BIK
MFI
MEL
TSC
*BEA
CGS
MFI
MFI
SOD
MFI
RWY
SBT
SBT
SBT
SBT
ABW
DFT
DFT
SBS
SBS
SBS
SBS
SBS
SBS
SBS
SBE
398
UCSB-8Mg
UCSB-8Mn
UCSB-8Zn
UIO-12-500
UiO-12-as
UiO-20
UiO-21
*UIO-28
*UiO-6
UiO-7
UiO-7
USC-4
USI-108
UTD-1
*UTD-1F
UTM- 1
UZM-25
UZM-4
*UZM-5
VAPO-31
VAPO-5
Vishnevite
*VPI-5
*VPI-7
*VPI-8
*VPI-9
VS-12
VSV-7#
Wairakite
*Weinebeneite
Wellsite
*Wenkite
Willhendersonite
*Yugawaralite
*ZAPO-M1
ZBH
ZCP-THO
Zeolite N
Zeolite W
SBE
SBE
SBE
AEN
AEN
DFT
CHA
OWE
OSI
ZON
ZON
MFI
MFI
DON
DON
MTF
CDO
BPH
UFI
ATO
AFI
CAN
VFI
VSV
VET
VNI
MTW
VSV
ANA
WEI
PHI
-WEN
CHA
YUG
ZON
MFI
THO
EDI
MER
Zeolite X (Linde X)
Zeolite Y (Linde Y)
Zincophosphate X
ZK-14
ZK-19
ZK-20
ZK-21
ZK-22
ZK-4
*ZK-5
ZKQ-1B
ZMQ-TB
Zn-BCTT
Zn-STA-7
ZnAPO-35
ZnAPO-36
ZnAPO-39
ZnAPO-40
ZnAPO-5
ZnAPO-50
ZnAPSO-40
*ZSM-10
*ZSM-11
*ZSM-12
*ZSM-18
ZSM-20
ZSM-22
*ZSM-23
ZSM-3
ZSM-35
*ZSM-39
ZSM-4
*ZSM-5
ZSM-50
ZSM-51
*ZSM-57
ZSM-58
ZYT-6
FAU
FAU
FAU
CHA
PHI
LEV
LTA
LTA
LTA
KFI
MFI
MFI
BCT
SAV
LEV
ATS
ATN
AFR
AFI
AFY
AFR
MOZ
MEL
MTW
MEI
EMT/FAU
TON
MTT
EMT/FAU
FER
MTN
MAZ
MFI
EUO
NON
MFS
DDR
CHA