GEOL 1107, Lab #1 INTRODUCTION TO ROCKS AND MINERALS INTRODUCTION There are many different rocks to be found in the Earth. To simplify their description all rocks are classified as one of three types: 1) igneous; 2) sedimentary; and 3) metamorphic. All rocks are composed of many different types of minerals. Minerals are the fundamental components or basic “building blocks” of all rocks and as such are very important in understanding the science of geology. The ability to recognize and classify common minerals and the rocks they make up is an essential part of this introductory geology course. A comprehensive understanding of minerals and rocks, and how to recognize them, is important because it helps when reconstructing the geological history of the solar system, planet Earth and all the events, processes, features and life forms that have evolved since the Earth formed. Understanding rock and mineral identification is also important because it plays an essential role in the interpretation of the various conditions (physical and chemical) that affect rock and mineral formation. For example, it may be vital to know the mineral content of a particular igneous granite-type rock so that its relationship with other, economically important, minerals such as gold, may be recognized and understood. Information about granite formation can be obtained by examining the size, shape and relative abundance of various minerals such as quartz, feldspar and hornblende. Geologists are always trying to identify rocks and minerals; it is an acquired skill that comes with practice. There are thousands of different minerals. However, the minerals you will become familiar with in the following series of labs are the most common types and are the dominant rock forming minerals. In subsequent labs, the majority of rocks you will see are the common types made up of a small number of rock-forming minerals. 1 GEOL 1107, Lab #1 LEARNING OBJECTIVES The objectives of the lab portion of this introductory geology class are: 1. Recognize, compare and apply mineral and rock properties, 2. Recognize and classify common rock forming minerals, 3. Recognize and classify intrusive and extrusive igneous rocks, 4. Recognize and classify sedimentary rocks, 5. Recognize and classify metamorphic rocks. TERMINOLOGY Before continuing, we need to clearly understand the meaning of a few fundamental terms or concepts: 1. A mineral is a naturally occurring, inorganic substance composed of a specific ratio of chemical elements arranged in a re-occurring crystalline structure. 2. All minerals are made up of atoms. Chemical composition of a mineral refers to the type of atoms and the ratio of atoms in the atomic structure. In a particular mineral it is not practical to actually see or count atoms. Instead, the ratio of atoms is presented to better understand the chemical composition. For example, the mineral quartz is SiO2 which means it is made up of one silicon (Si) atom for every two oxygen (O) atoms. In any given mineral the chemical composition is either constant or ranges within narrowly defined limits. 3. A crystal or crystalline substance is a solid material with a well defined, ordered arrangement of atoms that are unique to that substance. All minerals are crystals because they all have a reoccurring crystalline structure, however, most of the time it’s too small to see. 4. A rock is a naturally occurring aggregate of one or more minerals. 2 GEOL 1107, Lab #1 LABORATORY 1 PROPERTIES OF MINERALS The objective of lab 1 is to recognize the properties found in all minerals. These are then used to begin identifying minerals. While there are approximately 5400 known minerals, you will learn only 45 of the common minerals. To do this, you must first learn to observe and evaluate their physical properties. In this first lab you will take a systematic look at the physical properties of a mineral that are most useful for identification and classification purposes. The 12 most important physical properties of a mineral, and the ones you will use for identification purposes are: 1. 2. 3. 4. 5. 6. Hardness Luster Streak Colour Diaphaneity Crystal Habit 7. Tenacity 8. Reaction with acid 9. Density and Specific Gravity 10. Magnetism 11. “Special Properties” 12. Cleavage THIS IS REALLY IMPORTANT READ THIS AND SAVE YOURSELF SOME TROUBLE LATER. A really important thing to remember about all minerals is that they vary. What this means is that some minerals will have a very specific property that make them easy to identify, such as the emerald-green colour of malachite. Other minerals will have a number of different properties that also make it easy to identify them. The mineral plagioclase feldspar has a white colour, thin straight lines or striations on its cleavage surface and a blue - green iridescence. Many minerals have a property or properties that are very useful for identifying them, but because they vary you may not see them in all samples of the same mineral. So how then do you identify a mineral? It’s a simple process. Identification is based not on one but as many properties as possible. Also make sure you look at more than one sample of the same mineral so you can see as many properties as possible and how they might look different. List all the properties you see and 3 GEOL 1107, Lab #1 make a decision, chances are you’ll be right. At the end of the day, the name you give to a mineral is based on the properties you see and the sum total of what they tell you. Now let’s begin. PHYSICAL PROPERTIES OF MINERALS 1. HARDNESS All minerals are hard, some are just harder than others. The hardness of a mineral is a measure of a minerals resistance to abrasion or scratching when minerals are scratched against one another or when certain tools are used to scratch it. The hardness of a mineral is dictated by its chemical composition and crystal structure, the very things that define a mineral. You can test the hardness of a mineral by measuring the “scratchability” of a sample while referring to a scale of minerals of known hardness. Ten reference minerals are arranged in a standard hardness scale known as the Mohs Scale of Hardness which lists them in order of increasing hardness (Table 1 - 1). Talc, number 1 on the scale (Figure 1 - 1), is the softest and most easily scratched mineral while diamond, at number 10, is the hardest and most difficult to scratch (Figure 1 - 2). Each mineral will scratch the one below it in the scale but not the one above it. For example, number 4, the mineral fluorite, will scratch number 3, calcite, but not 5, the mineral apatite. When you have an unknown mineral scratch it with the minerals in Mohs Scale of Hardness or one of the standard tools to determine a value for hardness. To aid in identification, common objects or tools of known hardness - a copper penny, glass plate, steel nail, streak plate - are included in Mohs scale of hardness to help determine the hardness of a mineral. A streak plate is a small, flat piece of white, unglazed porcelain with a hardness of 6.5. A glass plate and steel nail each have a hardness of approximately 5.5. These three tools should scratch fluorite (hardness 4) but not quartz (hardness 7). Your fingernails have a hardness of 2.5. You should be able to scratch the mineral gypsum with your fingernail. In turn, if you were to scratch the mineral feldspar or quartz with your fingernail your fingernail would be abraded, scratched or worn down instead of the mineral. 4 GEOL 1107, Lab #1 Table 1 - 1. Mohs Scale of Hardness Hardness Value Mineral 1 (softest) Talc 2 Gypsum (2.5 fingernail) 3 Calcite (3.5 copper penny) 4 Fluorite 5 Apatite (5.5 glass plate, steel nail) 6 Feldspar (6.5 streak plate) 7 Quartz 8 Topaz 9 Corundum 10 (hardest) Diamond 5 GEOL 1107, Lab #1 Scale is in centimeters Figure 1 - 1. The mineral talc, a white mineral or light coloured with a hardness of 1. Figure 1 - 2. The mineral diamond, at 10 on the hardness scale. 6 GEOL 1107, Lab #1 As with all mineral properties described in this manual there are points, hints or bits of extra information you might find useful. Here are some ‘hints’ that have to do with using hardness to help identify a mineral. 1. When testing for hardness you should try different approaches: test one mineral against another, test with one tool (i.e. steel nail) and then another (i.e. glass plate). Testing with a steel nail and glass plate helps determine whether the mineral in question is in the softer (1 - 5) or harder (6 - 10) part of the scale. Sometimes only an approximate or a range of values is possible. 2. When testing one mineral against another, scratch one mineral with the other, and then reverse the procedure. Minerals with the same or nearly the same hardness will scratch each other. 3. When using the glass plate or streak plate, hold them flat on the table and draw the sample firmly across them. NEVER try to use a glass or streak plate to scratch a mineral sample, as it may splinter in your hand. 4. Check to see if you have made a scratch by probing with the tip of a steel nail or your fingernail. Clean the sample of any powder. A fine scratch may be evident in the sample. For a closer look take a picture with your phone and zoom in for a closer look. In a lab use a microscope. 5. Sometimes, hardness will vary when samples of the same mineral are examined. For example, the hardness of hematite ranges from about 1 to 6 depending on the crystalline structure of the sample. 6. A sample may contain a mixture of minerals, so you must be careful to clearly identify what mineral or part of a mineral you are testing. 7. Some minerals are composed of small aggregates of granular crystals that easily break apart. Thus, the mineral may appear to be softer than the true hardness of the individual crystals. You are in fact not testing the mineral hardness but the hardness of the aggregate. The minerals olivine and hematite are examples of minerals that may behave like this. Look closely to determine what it is you are attempting to scratch and what the results are. 7 GEOL 1107, Lab #1 8. All mineral hardness tests should be made on a fresh mineral surface. Often a weathered mineral surface has an outer coating composed of some other softer mineral such as iron oxide, also known as rust. These coatings may mask the true hardness of the mineral. 9. Different parts or surfaces of the same mineral sample may have different hardnesses. This is related to the crystalline structure of the mineral. Therefore, when in doubt, scratch the mineral on more than one surface when determining hardness. EXERCISE 1 - 1: DETERMINING MINERAL HARDNESS Obtain a set of “hardness minerals” that make up the Mohs scale. Arrange them in order of increasing hardness from 1 through 9 (diamond is not present for obvious reasons). Be sure to make use of all of the “tools” at your disposal (fingernail, penny, glass, steel nail, streak plate). As you proceed, take note of the hints for hardness described in this lab. This is how the hardness of a mineral is used to help identify a mineral. You compare the hardness of one mineral to another, or to a tool such as your fingernails, a glass plate or a nail file to come up with a measure of hardness. Often the hardness number you assign to a mineral is an approximation. It is your best estimate and just one of several properties used to identify a mineral. 2. LUSTER A minerals luster is a measure of the amount and quality of light reflected from its surface. There are two basic types of mineral luster: metallic and non-metallic. Metallic luster is highly reflective. It looks like polished metal such as aluminum foil, a gold ring or a brass doorknob. Figure 1 - 3 shows the metallic luster of the mineral pyrite. Non-metallic minerals do not look like a piece of metal, they have a range of different lusters including glassy and earthy. Figure 1 - 4 shows the glassy luster of quartz (A) and the earthy luster of hematite (B). Remember it’s not the colour that determines luster, it’s the way light reflects off the surface of the mineral. All the common mineral lusters are listed in table 1 - 2. Use this table as a reference when we finally start mineral identification. 8 GEOL 1107, Lab #1 Figure 1 - 3. The metallic luster of the mineral pyrite Figure 1 – 4A. The non-metallic glassy luster of the mineral quartz (A). 9 GEOL 1107, Lab #1 Figure 1 – 4B. The non-metallic earthy luster of the mineral hematite (B) A few minerals have a luster somewhere between metallic and non-metallic. These minerals are sub-metallic, and they, fortunately, are relatively rare. For the purpose of this lab, we describe sub-metallic minerals, such as sphalerite, as metallic because they look more metallic than non-metallic and we can simplify mineral identification. Table 1 - 2. Mineral Luster. Images of all the example minerals in this table are found in tables 4 - 1 and 4 - 2. Luster A. METALLIC Appearance Example shiny, grey, highly reflective galena, graphite molybdenite, hematite generally dull grey, with many shiny, high reflective surfaces magnetite shiny, yellow/brass/gold, highly reflective pyrite, pyrrhotite chalcopyrite 10 GEOL 1107, Lab #1 B. SUB-METALLIC shiny but not highly reflective frequently dull sphalerite, C. NON-METALLIC Non-metallic lusters include a variety of common sub-types. i) ADAMANTINE has a high degree of sparkle diamond ii) VITREOUS or GLASSY looks like broken glass or quartz, fluorite clear quartz olivine iii) RESINOUS looks like a semitransparent resin or glue microcrystalline quartz iv) GREASY typically has vitreous luster along with greasy feel or oily shine talc graphite, halite v) PEARLY “soft” shiny appearance gypsum, dolomite, calcite vi) EARTHY dull appearance limonite, bauxite Remember, minerals will vary. The luster of a mineral may be different depending on the quality of the sample. All you can do is look at as many samples as possible and make a decision. Also, remember, mineral identification is based on more than one property and a number of samples that together describe a single mineral type. 3. STREAK Streak is the colour of a mineral when it has been crushed into a powder. Streak is determined by scratching the mineral across the surface of streak plate. Certain minerals may have a range of different colours but will always have a consistent, diagnostic streak colour. Quartz comes in a variety of 11 GEOL 1107, Lab #1 colours - white, clear, purple - but always has a white streak. Most nonmetallic minerals, especially the white or light coloured ones such as calcite, talc, gypsum, and fluorite, have white or very pale steaks that all look the same. As result streak is often of limited use for identifying these types of minerals. But it’s still a visible property and every bit of information helps. Streak is more useful when identifying metallic minerals than non-metallic minerals. Metallic minerals often have a dark streak similar to the colour of the mineral. Examples of some common metallic minerals and the colour of their streaks are listed in table 1 - 3. Table 1 - 3. Metallic minerals and their streak Metallic Mineral Streak Pyrite greenish – black streak Magnetite black streak Hematite reddish – brown streak Limonite yellow-brown streak Graphite blue – grey streak EXERCISE 1 - 2: STREAK Compare the streaks of the dark mineral samples in your boxes of common and economic minerals (#60, #124, #126, #78 and #151). Note which dark minerals have dark streaks, which ones have lighter colored streaks, which have a metallic luster, and which have a non-metallic luster. 12 GEOL 1107, Lab #1 Sample Number Streak Luster #60 #124 #126 #78 #151 Figure 1 - 5. Bright, shiny metallic silver gray hematite (A) and dull, earthy red hematite (B). 13 GEOL 1107, Lab #1 Scale is in centimeters Figure 1 - 6. Colour of streak common to both types of hematite in figure 1 - 5. The mineral hematite has two distinct colours because of the different ways it forms. Coarse crystalline hematite is a bright, shiny metallic bluish gray colour (Figure 1 – 5 A). The other common form of hematite is the fine crystalline, dull, earthy red variety (Figure 1 – 5 B). Figure 1 – 6 shows the streak that is common to both these two types of hematite. Now examine the hematite samples (#74 and #75) in the box of common minerals. The range of colors is due to the form in which the mineral hematite occurs. Coarse crystalline hematite is a bright, shiny metallic bluish gray. The other common form of hematite is the fine crystalline, dull, earthy red variety. Scratch these two samples (#74 and #75) across a streak plate and note the streak. What is the color of the streak from the two samples? Is streak a useful diagnostic tool for hematite? Explain your answer. 14 GEOL 1107, Lab #1 Here’s a bit of useful information to think about for streak. If you have a mineral sample and a streak plate, put the streak plate on a flat surface and scratch the mineral across the plate and observe the colour of the powder. What colour is the streak and where did it come from? What if the mineral you’re trying to identify is harder than the streak plate which is 6.5 on Mohs Scale of Hardness? What if the mineral is quartz which has a hardness of 7? Will a powder appear on the streak plate and if so, what does it mean? Likely what you’ve done is scratched the streak plate and the powder is from the streak place, not the mineral. For minerals harder than 6.5 another way needs to be found to crush a mineral into powder. This is one reason why geologists carry rock hammers. 4. COLOUR The colour of a mineral is produced when light strikes its surface. The light that’s reflected, the light that you see, is what creates the colour you see. It is the most important feature for mineral identification. Colour may be of limited use when identifying some minerals, mainly because many minerals have a variety of colours. Take the minerals cinnabar (Figure 1 - 7 A) and quartz (Figure 1 - 7 B). Cinnabar has a very bright scarlet red colour which is very useful for identification purposes. Quartz, on the other hand, occurs in a variety of different colours, including pink (rose quartz), yellow, gold, green, blue violet (amethyst) and dark gray or black (smokey quartz). As far as quartz is concerned, colour is by itself, not a great diagnostic tool. Other properties are more useful when examining quartz. 15 GEOL 1107, Lab #1 Figure 1 - 7. The bright red colour and earthy luster of cinnabar (A) and the pink colour and glassy luster of rose quartz (B). The most common white colour of quartz is shown in figure 1 - 4 A. Many different minerals will have the same colour, which also makes mineral identification more complex than it need be. For example, both quartz and fluorite have purple varieties. One of the best ways to distinguish fluorite from quartz is cleavage and crystal habit, mineral properties we’ll deal with later. Similarly, the minerals hornblende and pyroxene commonly have black to dark greenish black colours, dark streaks, and comparable values for hardness. Despite their similar features, when hornblende and pyroxene are placed sideby-side their difference in colour becomes more obvious, hornblende is black 16 GEOL 1107, Lab #1 (Figure 1 - 8 A) and pyroxene is greenish black (Figure 1 - 8 B). Figure 1 - 8. The colours of hornblende (A) and pyroxene (B). Hornblende is black while pyroxene has a greenish black colour, a useful diagnostic property. When using colour as a property for mineral identification keep the following points in mind. 1. Numerous minerals, such as pyroxene and hornblende, have dark colours such as dark gray or black because they have an abundance of iron (denoted by the formula Fe in its chemical composition) in their crystal lattice. 17 GEOL 1107, Lab #1 2. Many minerals are not pure, meaning that they have been contaminated or mixed with other atoms or minerals. They may also be present in such small quantities that they are not easily observed. Under these circumstances the use of colour as a diagnostic tool must be done very carefully and with the use of a microscope, hand lens or a close up look at an image. EXERCISE 1 - 3: THE COLOUR OF MINERALS Examine the minerals listed below and note their chemical formula. Observe how color changes are reflected by changes in chemical composition, a simple enough comparison given that the composition of a mineral will directly influence the type and amount of light reflected from its surface. Mineral Sample Number Chemical Formula Muscovite #106 KAl2(AlSi3)O10(OH)2 Biotite #24 K(Mg,Fe)3(Al,Fe)Si3O10 (OH,F)2 Olivine #114a Mg2SiO4 Hornblende #78 (Ca,Na)2-3 (Mg,Fe+2,Fe+3,Al)5 (Al,Si)8O22(OH)2 Pyrite #124 FeS2 Sphalerite #153 (Zn,Fe)S Color How do you account for the color differences between these different mineral samples? Why are biotite and hornblende different in colour compared to muscovite and quartz? 18 GEOL 1107, Lab #1 Now examine the large quartz and calcite samples in the lab. For both minerals, the various colors are due to the presence of very minute amounts of impurities. Both quartz and calcite are colorless or clear in pure form. Answer these questions by filling in the box below. What is the most common color of quartz? What is the most common color for calcite? Mineral Chemical Composition Quartz SiO2 Calcite CaCO3 Common Color Is color a useful diagnostic tool for identifying quartz and calcite? Why? Why not? 5. DIAPHANEITY Diaphaneity is the ability of a mineral to transmit light. The three types of diaphaneity related to minerals are: 1. Opaque minerals such as galena or pyrite that completely block the passage of light through them. 2. Translucent minerals, such as feldspar and hornblende, which allow some light through. If these samples are held against a light source, the rims may allow a little dull light through them. 3. Transparent minerals such as quartz, muscovite or calcite allow light to pass through. 19 GEOL 1107, Lab #1 These three terms are rather imprecise, and often of limited use when identifying a mineral, because the quality of a mineral may vary and with it our ability to see through it. For example, “transparent” minerals such as quartz are not always very clear. However, at the very least you should be able to see the shape and size of another object through a mineral like muscovite. When considering diaphaneity as a mineral property for identification, here are points to remember. 1. The ability of a mineral sample to transmit light depends, in part, on its thickness. Thin sheets of muscovite are transparent while some of the larger, thicker samples vary from translucent to opaque. 2. Diaphaneity also depends upon mineral purity. Quartz, for example, in pure, crystalline form is transparent. It easily transmits light. However, as you have seen in the section on colour, quartz also has a variety of common colours because of the presence of impurities. Therefore quartz may be opaque, translucent or transparent. Diaphaneity as a diagnostic property is generally of limited use in mineral identification. 6. CRYSTAL HABIT All minerals have a crystalline structure or habit. This is a reoccurring arrangement of chemical atoms that define the characteristic form, shape or combination of forms and shapes of a mineral. Depending on the types of atoms in the mineral and the ratio of atoms different crystal shapes will form. Figures 1 - 9, 1 - 10 and 1 - 11 illustrate the crystal habit of the minerals quartz, calcite and pyrite, three of the common minerals introduced in this lab. 20 GEOL 1107, Lab #1 Figure 1 - 9. The six-sided, hexagonal crystal habit of a quartz crystal. 21 GEOL 1107, Lab #1 Figure 1 - 10. The six-sided, rhombohedral crystal habit of calcite. 22 GEOL 1107, Lab #1 Figure 1 - 11. The six-sided cubic crystal habit of pyrite. All three minerals in figures 1 - 9, 1 - 10 and 1 - 11 have 6 sides. What makes them different is that each has a different angle between adjacent sides. EXERCISE 1 - 4. CRYSTAL HABIT The quartz crystals in figures 1 - 9 and 1 - 12 have the same chemical formula, they are all composed of the same ratio of silicon and oxygen (SiO2) that makes up all quartz crystals. A quick look at all these crystals indicates they all have the same general shape, very much like the line diagram of a quartz crystal in figure 1 - 9. However, the crystals in figure 1 - 12 are not all identical. Some are longer, some are wider. There is some variation in the reoccurring crystalline structure. 23 GEOL 1107, Lab #1 Scale is in centimeters Side 2 Side 1 Side 3 Side 6 Side 4 Side 5 Figure 1 - 12. Quartz crystals. Image A shows a cluster of quartz crystals of different sizes that all grew together. Image B shows a single quartz crystal viewed from the end or top with its six-sided hexagonal shape. 24 GEOL 1107, Lab #1 Now examine at least two quartz crystals (sample #133) provided in the lab and in the box of common minerals. Note their similarities and differences. Use figure 1 – 12 to help with your observations. What can you conclude about the size of the crystals? Are they all the same size? What can you conclude about their shape and form? Are they similar in any way? How many faces or sides does each crystal have? Now use the goniometer – a small protractor-like device - provided in the lab to measure the crystal faces of one of the crystals. Figure 1 – 13 illustrates a goniometer and how to use it. See your instructor for more help. A crystal face is the flat, smooth, shiny surface that appears on the crystal. Some crystals have only a few crystal faces while others may have many crystal faces. For at least two quartz crystals measure the angle between each pair of adjacent faces. Make a note of what the angles are. Figure 1 – 13. A goniometer used to measure mineral crystals. It consists of a protractor with a 0o to 180o scale, a rotating ruler to measure angles and a scale to measure the width and length of crystals. 25 GEOL 1107, Lab #1 Perhaps you will agree that the best explanation for the regular nature of quartz crystals, as demonstrated by the equal number of crystal faces and the consistent angles between adjacent crystal faces, is the very regular, reoccurring internal crystalline structure of the quartz mineral. Crystal Texture In nature a mineral may be present in crystalline form, as fragments of crystals, or as aggregates composed of numerous whole or partially formed crystals. Mineral aggregates consist of numerous individual crystals packed together in a lump, or solid mass. Each crystal in an aggregate will have a characteristic habit, but often times will not show it because there was no room for the faces or flat, shiny surfaces of a crystal to grow and appear as the minerals formed. A hand lens, microscope or close up of an image will help you to see crystals when they are quite small or only partially formed. Recognition of crystal habit and individual crystal sides or faces requires an understanding of cleavage. Sometimes when a mineral is broken, a flat shiny surface appears, very much like the face of a crystal. This, however, is cleavage and cleavage is very different from crystal habit. More about cleavage later in lab 2. IMPORTANT Crystal habit is how a mineral grows. Cleavage is how a mineral breaks. For the common minerals introduced in this lab there are only two that routinely display crystal habit: quartz (Figure 1 - 9 and Figure 1 - 12), calcite (Figure 1 – 10) and pyrite (Figure 1 - 11). For most of the remaining minerals in this lab a well-developed crystal habit is rare and so, as a diagnostic tool, is of limited use. There are a number mineral textures that form as a result of the crystal habit of a mineral. These are used to help identify many different minerals. Crystal texture refers to the size, aspect or orientation of a crystal or aggregate of crystals. Crystal habit is about the shape of individual crystals. Table 1 - 4 26 GEOL 1107, Lab #1 below describes and illustrates a number of common crystal textures. Table 1 - 4. The crystal structure of minerals. A full description of the minerals in this table and their crystal texture are found in tables 4 - 1 and 4 - 2 in lab 4. 1. Granular refers to a mineral with many, large crystals visible to the unaided eye. They often appear as a densely packed mass of crystals. A good example is olivine (Figure 1 - 14). Scale is in centimeters Figure 1 - 14. The granular crystalline texture of olivine. 27 GEOL 1107, Lab #1 2. Aphanitic describes a mineral with crystals that are too small to see, even with a close-up image, a microscope or a hand lens. Dolomite (Figure 1 - 15) is a mineral with an aphanitic crystal texture. Scale is in centimeters Figure 1 - 15. The aphanitic or fine-grained texture of dolomite. 28 GEOL 1107, Lab #1 3. Massive implies a homogenous or non-directed aspect or orientation of the minerals in a rock. All the crystals, regardless of size, appear randomly oriented. Bornite has a massive crystal texture (Figure 1 - 16). Scale is in centimeters Figure 1 - 16. The massive crystalline texture of bornite. 29 GEOL 1107, Lab #1 4. Foliate describes a parallel to subparallel arrangement of flat or tabular crystals. The mineral biotite (Figure 1 - 17) has a flat sided, tabular crystal texture. Scale is in centimeters Figure 1 - 17. The foliate crystalline texture of biotite. In this image, many flat, platey crystals are laid one on top of the other like the pages of a book. 30 GEOL 1107, Lab #1 5. Dense or Compact indicates tightly interlocking, usually coarser or large size crystals, giving a coherent or “tough” appearance or texture to the mineral or mineral aggregate. Magnetite (Figure 1 - 18) has a dense or compact crystal texture. This crystal texture may appear similar to a granular texture. Scale is in centimeters Figure 1 - 18. The dense, compact crystalline texture of magnetite. 31 GEOL 1107, Lab #1 6. Earthy implies an aphanitic or very fine crystalline texture composed of loosely-held, soft mineral crystals. Limonite (Figure 1 - 19) has an earthy crystal texture. Scale is in centimeters Figure 1 - 19. The earthy crystalline texture of limonite. 32 GEOL 1107, Lab #1 7. Microcrystalline refers to an aphanitic crystalline texture with tightlyinterlocking crystals so that the mineral or mineral aggregate has a hard, coherent texture. A good example is microcrystalline quartz (Figure 1 - 20). Scale is in centimeters Figure 1 - 20. The microcrystalline texture of microcrystalline quartz. 33 GEOL 1107, Lab #1 8. Coliform or Reniform texture refers to fine-grained crystal aggregates with characteristic rounded, kidney-shaped or “bubbly” looking surfaces. These are formed by a build up of numerous thin concentric shells or layers of a mineral as it precipitates. The mineral hematite (Figure 1 - 21) is the only common mineral in this lab with a distinctive coliform or reniform crystal texture. Scale bar is 5 millimeters Figure 1 - 21. Close up of the coliform or reniform crystalline texture of hematite. 34 GEOL 1107, Lab #1 9. Oolitic and Pisolitic textures refer to round or ovoid pellets that have a concentrically layered internal structure. Oolitic pellets are smaller than 2 mm. Pisolitic pellets are bigger than 2 mm. The mineral bauxite (Figure 1 - 22) has a well-defined pisolitic crystal texture. Pisolitic Pellet Oolitic Pellet Scale is in centimeters Figure 1 - 22. The oolitic and pisolitic crystalline textures of bauxite. 35 GEOL 1107, Lab #1 10. Drusy texture is a layer or layers of fine or aphanitic crystals that form a coating on other crystals or rock surfaces. Drusy crystals may also be found infilling a cavity in a rock sample. Cinnabar (Figure 1 - 23) is a good example of a mineral with a drusy crystalline texture. Scale is in centimeters Figure 1 - 23. The drusy crystalline texture of cinnabar. This red mineral appears as coating on a light gray-brown mineral. 36 GEOL 1107, Lab #1 11. The following terms describe the habit or general shape of individual crystalline grains in an aggregate of minerals. Tabular is a shape like a piece of paper such as individual biotite and muscovite crystals (Figure 1 - 24). Prismatic with numerous, flat reflective surfaces is what a quartz crystal looks like (Figure 1 25). Bladed occurs in a flat, elongated mineral such as kyanite (Figure 1 - 26). Acicular or needle-shaped is the crystal structure of the mineral tremolite (Figure 1 - 27). Scale is in centimeters Figure 1 - 24. Individual crystals of muscovite and biotite. The light-coloured muscovite (left mineral) is propped up against the black biotite (right mineral) with each showing its tabular shape. When many muscovite or biotite minerals are stacked together, they form the foliate texture in figure 1 - 17. 37 GEOL 1107, Lab #1 Scale is in centimeters Figure 1 - 25. Prismatic quartz crystal. Scale is in centimeters Figure 1 - 26. Flat, elongated bladed crystals of kyanite. 38 GEOL 1107, Lab #1 Scale is in centimeters Figure 1- 27. Acicular, or needle-like, crystals of the mineral tremolite. 12. Non - crystalline refers to minerals that have no crystalline structure. These types of minerals form so fast, often when lava cools and solidifies underwater, that there is little or no time for crystals to form. A prime example is the igneous rock obsidian (Figure 1 - 28) which has no crystalline structure. Figure 1 - 28. The non-crystalline texture of obsidian, an igneous intrusive rock. 39 GEOL 1107, Lab #1 7. TENACITY The ability of a mineral to resist breaking, crushing, bending or tearing is known as tenacity. The most often happens when a mineral is struck by a hard object such as a rock hammer. The following terms in table 1 - 5 describe the tenacity of minerals. Table 1 - 5. Types of mineral tenacity. Tenacity Description Mineral i) Brittle Breaks or powders easily quartz fluorite calcite ii) Flexible Bends but does not resume its vermiculite shape when pressure is released iii) Elastic Bends but resumes its shape when pressure is released biotite muscovite iv) Malleable Can be hammered out into thin sheets gold and silver v) Sectile Can be cut into thin shavings with a knife talc graphite vi) Ductile Can be drawn into a wire copper 40 GEOL 1107, Lab #1 8. REACTION WITH ACID The carbonate minerals calcite and dolomite can be distinguished from other minerals because of the way they react with acid. The chemical reaction can be observed when a drop of cold, dilute hydrochloric acid (10% HCl) is placed on one of these two minerals. Calcite (CaCO3) will react immediately and strongly with 10% HCl. The visible reaction you see is the effervescence or release of carbon dioxide (CO2) bubbles produced by the chemical reaction that dissolves the mineral. The reaction between dolomite (Ca,Mg(CO3)2) and 10% HCl, on the other hand, is much slower and is usually only observed when the dolomite mineral has been crushed into powder. The reaction of hydrochloric acid and these two carbonate minerals, calcite and dolomite, is a very important diagnostic tool. Calcite and dolomite are two very common rock forming minerals and their rapid identification is both easy and important in the study of minerals and rocks. EXERCISE 1 - 5: ACID TEST TO IDENTIFY CALCITE AND DOLOMITE Place a drop of 10% HCl on the mineral calcite (sample #26a) and note what happens. The formula for the chemical reaction between calcite (CaCO3) and hydrochloric acid (HCl) is: CaCO3 (s) + 2HCl (aq) ➔ CaCl2 (aq) + CO2 (g) + H2O Note the immediate and rapid release of carbon dioxide (CO2) bubbles. Now place a drop of 10% HCl on the mineral dolomite (sample #52) and note what happens. Is there any result? Scratch the dolomite to produce a little powder on the sample and try another drop of acid (observe closely). Now is there any reaction? The formula for the chemical reaction between hydrochloric acid and dolomite is: CaMg(CO3)2(s) + 4HCl(aq) ➔ Ca+2(aq) + Mg+2(aq) + 4Cl-1(aq) + 2CO2(aq) + 2H2O The 10% HCl reacts with both carbonate minerals. However, the strength of the reaction, as indicated by the number of bubbles of carbon dioxide and the rate at which they are released, is a standard method for distinguishing between calcite and dolomite. 41 GEOL 1107, Lab #1 IMPORTANT NOTE GO EASY ON THE ACID - A SMALL DROP WILL DO! Although the acid is very dilute, please handle it carefully. It the acid spills on your skin, it will not burn but you should wash the area as a precaution. If acid comes in contact with the eye, it will sting and you should wash out your eye with water. It will make holes in clothing that usually don’t appear until after the next laundering. Always blot off excess acid with paper towels after testing. 9. DENSITY and SPECIFIC GRAVITY The density of any substance is the measure of its mass per unit volume and can be expressed in grams per cubic centimeter (g/cm3). The specific gravity (S.G.) is the ratio of the mass of a substance to the mass of an equal volume of water. The density and specific gravity of water is 1 g/cm3. The mineral galena has a density of 7.5 g/cm3 and a specific gravity of 7.5. Opaque, metallic minerals such as galena (Figure 1 - 29) and molybdenite (Figure 1 - 30) tend to be much denser than non-metallic minerals such as potassium feldspar or K – feldspar (Figure 1 - 31) which have a density of 2.6 g/cm3. Native metals including copper, silver and gold have the highest densities or specific gravity of all known minerals. For example, native gold (Figure 1 - 32) has a density of 19.3 g/cm3. In a river, high density, heavier pieces of gold is transported and deposited differently compared to lighter, less dense pieces or grains of quartz. This is an important factor when searching for gold nuggets in river deposits. Of the non-metallic minerals, barite (Figure 1 - 33) has one of the highest densities for a non-metallic mineral at 4.5 g/cm3, which can be a very important diagnostic property. 42 GEOL 1107, Lab #1 Figure 1 - 29. The metallic mineral galena has a density of 7.5 g/cm3 . Figure 1 - 30. The metallic mineral molybdenite has a density of 4.7 g/cm3 . 43 GEOL 1107, Lab #1 Figure 1 - 31. The non-metallic mineral potassium feldspar has a density of 2.6 g/cm3 . Figure 1 - 32. The metallic mineral gold has a density of 19.3 g/cm3 . 44 GEOL 1107, Lab #1 Figure 1 - 33. The non-metallic mineral barite has a density of 4.5 g/cm3 . EXERCISE 1- 6: DENSITY OF MINERALS Three metallic minerals have the following properties. Name Density Colour Chemical Formula Graphite 2.2 g/cm3 Gray C Molybdenite 4.7 g/cm3 Blueish Gray MoS2 Galena 7.5 g/cm3 Gray PbS All three of these minerals are similar in appearance yet they have very different densities. Using each minerals chemical formula what is it about these minerals that gives them such different densities? (Hint: C is carbon, Mo is molybdenum, Pb is lead) 45 GEOL 1107, Lab #1 All three of these minerals are similar in appearance. All are gray in colour with a metallic luster. Samples of each mineral are provided in the lab. Based on what you know about density and specific gravity determine which sample is graphite and which is molybdenite? Write the correct sample numbers in the spaces below. Mineral Sample Number Graphite Molybdenite Galena 10. MAGNETISM A few metallic minerals, such as magnetite and pyrrhotite, are strongly attracted to a magnet, which means they are magnetic. Other minerals may look like they could be magnetic, they appear similar to magnetite, but they aren’t. Magnetite and galena, for example, are both dark metallic minerals, however, magnetite is strongly magnetic whereas galena is not magnetic. Figure 1- 34 shows a small bar magnet stuck to the side of the mineral magnetite. Similarly, pyrrhotite and pyrite are yellow, metallic minerals. However, pyrrhotite is magnetic while pyrite is not. While the presence of iron (Fe) in the mineral is key to its magnetic properties, it does not guarantee the mineral is magnetic. Pyrite for example contains iron but is not magnetic. The magnetic properties of a mineral can best be determined by placing a small bar magnet on the mineral. If the magnet sticks to the mineral it is magnetic. If it does not it is non-magnetic. Similarly, small bar magnets can be suspended near the mineral. If the magnet swings towards the mineral it is magnetic. If it does not it is non-magnetic. 46 GEOL 1107, Lab #1 Bar magnet Scale is in centimeters Figure 1 - 34. A small bar magnet attracted to the side of magnetite. As with all mineral properties there is an important point to remember for magnetite, especially because you are using the small bar magnet. The magnetic property of a mineral may be difficult to determine if it is not present in pure form. Small inclusions of magnetite in a rock may give a false indication of magnetism. Similarly, if magnetite and pyrrhotite are present in only small quantities in a rock then its magnetic properties may go undetected. EXERCISE 1 - 7: MAGNETIC PROPERTIES Some of the more common magnetic minerals are of economic significance. This is because the iron in their crystal structure is a valuable resource as well as the source of magnetism. Which minerals in the box of economic mineral are magnetic? List below all the minerals, with their sample numbers, you find to be magnetic. 47 GEOL 1107, Lab #1 11. “ SPECIAL PROPERTIES ” Some minerals have additional, perhaps unusual properties that may be very useful for making a positive identification. These include: 1. Odour Kaolinite, a clay mineral (sample #83), is common in sediments and soils. It often produces a distinctive “earthy“ odor when slightly wet. Sphalerite, a sulphide mineral (sample #151), emits a characteristic sulphurous or “rotten egg” smell when dilute HCl is placed on it. 2. Feel Some minerals have a characteristically greasy feel to them. Some, such as graphite (sample #64) and talc (sample #161) derive this particular property from the fact that they are relatively soft (both have a hardness of 1) and have perfect cleavages in one direction. When the surfaces of these minerals are rubbed with your finger a greasy or slippery feel results because small mineral particles are easily dislodged along cleavage surfaces. Others minerals, such as halite (sample #73) feel greasy because when they are rubbed the moisture on your hand partially dissolves the surface of the mineral resulting in a “wet”, or greasy feel on your fingers. 3. Taste A few minerals readily dissolve in the range of temperatures and pressures found on the Earth’s surface. The result is often a distinctive taste to the surface of the mineral. Halite, also known as salt (sample #73), is a common mineral with a characteristic taste. Most geologist frown at the idea of mineral taste tests. IMPORTANT NOTE We recommend that you DO NOT taste any of the minerals in the lab. It is, however, usually safe to taste minerals in the field after they have been rinsed with water. 48 GEOL 1107, Lab #1 4. Thermal Effects Some minerals have distinctive reactions to heat. The mineral vermiculite is a sheet-like clay mineral that expands greatly when exposed to a flame. Biotite, which has the same sheet-like structure as vermiculite, is not affected by heat. The explanation for the different thermal properties of these two minerals is found in their chemical formulas. The chemical formula for biotite is K(Mg,Fe)3(Al,Fe)Si3O10(OH,F)2 The chemical formula for vermiculite is (Mg,Fe,Al)3(Al,Si)4O10(OH)2 . 4H2O There’s a lot of different atoms in each of these minerals, they both have a complex ratio of atoms. However, it’s what’s at the end of the chemical formula for vermiculite that causes it to expand when heated. At the end is 4H2O which means that water (H2O) is an integral part of vermiculite. When the mineral is heated the water boils off causing the mineral to expand. Biotite on the other hand does not contain water and is not affected in the same way when heated. EXERCISE 1 - 8: THERMAL EFFECTS Hold a sample each of vermiculite and biotite over the flame of a match and note what happens. Examine the chemical formula (given below) for each of these minerals. Which mineral reacts to the heat and which does not? 49 GEOL 1107, Lab #1 50 GEOL 1107, Lab #2 LABORATORY 2 CLEAVAGE AND FRACTURE CLEAVAGE Cleavage, as it pertains to minerals, is a particular way that a mineral breaks or cleaves. Depending upon the internal atomic structure of a mineral it may break or cleave along a plane or planes of weakness. The result is that, as a mineral is broken, relatively smooth flat surfaces appear. For example, a raw diamond (Figure 2 - 1) may have a distinctive, prismatic shape or be an irregular mass with no smooth flat surfaces. However, when a diamond is cut or cleaved it will often have a very distinct, aesthetically pleasing design often seen in jewelry. Figure 2 - 1. Raw diamonds. 1 GEOL 1107, Lab #2 IMPORTANT NOTE Cleavage is defined by the smooth flat surfaces that appear when a mineral breaks. Do not confuse this with crystal habit, which also is defined by smooth flat surfaces, but these are formed when a mineral crystal grows. However, the cleavage of a mineral is often the same or very similar to its crystal habit. The cleavage of a mineral is defined by the number of flat surfaces that appear when a mineral breaks, the quality of the cleavage surfaces and the angle between them. The quality of cleavage refers to how smooth and continuous surfaces are and therefore how easily they are observed. Smooth, continuous surfaces describe good or even perfect cleavage. A rough, discontinuous surface is poor cleavage. The mineral biotite, for example, when broken separates into thin, flat plates, the surface of which is a cleavage surface (Figure 2 - 2 A). While there are two surfaces, the top and bottom of the mineral that are parallel, biotite has only one type of surface. Biotite therefore has one cleavage because there is only one type of surface. Also because biotite only has one type of cleavage surface there is no way to measure an angle between cleavage surfaces. The common minerals pyroxene and hornblende both have two poor to good cleavage surfaces (Figure 2 - 2 B). This means that when they break it is possible to see two types of smooth, flat surface. Key to distinguishing pyroxene from hornblende is the cleavage angle, the angle between adjacent cleavage surfaces. The cleavage angle for pyroxene is 93o or 87o, which for all intents and purposes is 90o or a right angle. The cleavage angle for hornblende is 56o or 124o. Sometimes it’s described more simply as ‘not 90o’. Cleavage becomes increasingly more complex as the number of cleavage surfaces increases. Cleavage in three directions is characteristic of the common minerals galena and calcite (Figure 2 - 2 C). However, galena and calcite have different cleavage angles. The angle between adjacent cleavage surfaces in galena is 90o which imparts a cubic shape to a cleaved sample. The cleavage for galena is sometimes simplified by calling it cubic. The cleavage angle for calcite is not 90o, or more accurately measured as 60o or 120o. The cleavage of calcite is sometimes referred to a rhombic or rhombohedral. 2 GEOL 1107, Lab #2 B. Pyroxene and hornblende have good cleavage in two directions. Pyroxene at 90°. Hornblende at 60°/120°. Figure 2 - 2. Types of cleavage: A Single, platey biotite sample showing perfect or good cleavage in 1 direction.; B Pyroxene and hornblende cleavage, in 2 directions at approximately 90o and at approximately 60o or 120o. C Galena and calcite cleavage in 3 directions at 90o and not at 90o. D Fluorite and diamond cleavage in 4 directions. 3 GEOL 1107, Lab #2 The Quality of Cleavage - Perfect, Good and Poor. Minerals with cleavage may display a pattern of flat, shiny surfaces with varying degrees of quality. Perfect or good cleavage, for example, results when the mineral breaks along a more continuous, smooth plane or surface (Figure 2 3 A). What is often more common is “poor” cleavage whereby the mineral breaks or cleaves along a series of small planes or surfaces that are not continuous and therefore do not form one large smooth surface (Figure 2 - 3 B). When cleavage is poor it is still possible to observe the number and orientation of cleavage surfaces, it just takes closer examination. You may have to use a microscope or enlarge an image. Another way is to move the mineral at different angles to a light source to see how all these small cleavage surfaces reflect light the same way. A B Figure 2 - 3. A Good cleavage along a smooth, continuous surface. B Poor cleavage along a more irregular, discontinuous surface formed by a series of smaller cleavage surfaces. 4 GEOL 1107, Lab #2 FRACTURE Fracture is different from cleavage. Fracture is when a mineral breaks and there is no flat surface or cleavage plane. A mineral with cleavage may break but perhaps not along one of its cleavage planes. In addition, not all minerals have cleavage. In this case when the mineral breaks it “fractures” along irregular surfaces which are not flat and there is no consistent angle between adjacent surfaces. The mineral quartz for example has no cleavage. Therefore, when quartz breaks it does not cleave or separate along smooth, continuous surfaces. Instead it fractures along rough irregular surfaces. There are two common forms of fracture: 1. uneven; and 2. conchoidal. 1. Uneven fracture refers to any mineral that has no cleavage and instead breaks along rough, irregular surfaces. The mineral quartz (Figure 2 - 4) has an uneven fracture. Scale is in centimeters Figure 2 - 4. The uneven fracture of quartz. 5 GEOL 1107, Lab #2 2. Conchoidal fracture refers to a smoothly curving fracture. Smooth continuous convex or concave surfaces appear when minerals such as microcrystalline quartz break (Figure 2 - 5). When more than one conchoidal surface is present on a single mineral they frequently intersect at sharp angles thereby imparting a “knife-edge” appearance to the mineral. Scale is in centimeters Figure 2 - 5. The conchoidal fracture of microcrystalline quartz with its smooth curved surfaces. 6 GEOL 1107, Lab #2 Here is some useful information that can help with cleavage as a property for mineral identification. 1. With a hand sample it is possible to observe cleavage when a mineral is moved or turned around until a flash of reflected light is seen from a particular location on the sample. This may be a reflection from a cleavage surface. The reflection may be from a single surface or it may come from many small parallel surfaces on the sample. Cleavage may also be seen because of thin parallel cracks on a surface of the mineral. Each set of parallel cracks and the surfaces they are on represent a cleavage. To look for additional cleavage, turn the sample again and look for more reflections. Estimate the angle between cleavages by rotating back and forth between reflections. 2. Cleavage angles need not be measured precisely. Estimate them carefully with the naked eye and determine whether the angle is larger, smaller or equal to 900. 3. Sometimes the use of a geometric term that describes the shape of a minerals cleavage is the best method of giving both number and angles of cleavage. For example, cubic cleavage implies 3 types of cleavage surfaces, in three different directions, all at 900 to one another (Figure 2 - 2 C). Rhombic cleavage has also has 3 types of flat surface, in three different directions, but the angle is not 900 (Figure 2 - 2 C), and octahedral implies 4 cleavages resulting in a regular 8 sided form with more than one angle (Figure 2 - 2 D). Either way can be used to describe the cleavage of a mineral, listing the number, orientation and angles between surfaces, or by using a geometric term. EXERCISE 2 - 1: DETERMINING CLEAVAGE The property of cleavage is essential for recognizing and distinguishing between many different kinds of minerals. Table 2 - 1 is a list of common minerals, all of which may or may not have some sort of cleavage. Determine the cleavage for these 9 common minerals and record your observations in table 2 - 1. Be sure to check and discuss your results with your instructor. 7 GEOL 1107, Lab #2 IMPORTANT NOTE Please do not break the minerals as good samples are in limited supply. Crushed samples of the minerals biotite, pyrite, galena and halite have been provided for you in the lab display. The other minerals are found in the box of common minerals. Use the samples from more than one common mineral box so you can observe a number of different examples. MINERAL NO. OF CLEAVAGES ANGLE(S) QUALITY Galena #60 Perfect Quartz #131 ? Calcite # 26a Good Biotite # 24 Perfect Feldspar # 101 Poor Hornblende # 78 Poor Halite # 73 Good Fluorite # 57 Good/Perfect Pyrite # 124 ? Table 7. Common minerals and their cleavage properties. 8 GEOL 1107, Lab #3 LABORATORY 3 FELDSPAR MINERALS Feldspars are one of the most abundant groups of minerals in the Earth’s crust and hence are geologically very important. Two distinctly different groups of feldspar minerals are distinguishable using readily observed properties. They are: 1) the plagioclase feldspars; 2) and the potassium or K-feldspars. Each group includes a number of different minerals. This lab will focus on these two types which are easily recognized in a hand sample. In many other cases it takes special sample preparation and laboratory analysis to properly identify a feldspar mineral. PLAGIOCLASE FELDPSARS Plagioclase feldspars are a group of silicate minerals whose chemical composition varies with changes in the amount of calcium (Ca) and sodium (Na) in the atomic structure. Plagioclase feldspars are a continuous solid solution series meaning that chemical composition ranges from a pure Cabearing feldspar (Anorthite) to a pure Na-bearing feldspar (Albite) with all sorts of mixtures of Ca and Na in between. POTASSIUM FELDSPARS Potassium or K-feldspars are, like the plagioclase feldspars, a silicate mineral, with K as the dominant cation present in the atomic structure. Common varieties of K-feldspar include microcline and orthoclase. FELDSPAR IDENTIFICATION Striations vs Perthitic Texture The two common types of feldspar, plagioclase and potassium, while similar in many ways, can be readily distinguished by a few diagnostic features. Primary among them are striations on the plagioclase feldspar and a perthitic texture which is common on K-feldspars (Figures 3 - 1 and 3 - 2). 1 GEOL 1107, Lab #3 Striations Blue-green iridescence Figure 3 - 1. Plagioclase feldspar texture. Striations on cleavage surfaces of a plagioclase feldspar mineral. This also shows the iridescence characteristic of this mineral. 2 GEOL 1107, Lab #3 Perthitic Texture Scale is in centimeters Figure 3 - 2. Potassium feldspar texture. A perthitic texture on the cleavage surface of this mineral. 3 GEOL 1107, Lab #3 The surface of a plagioclase feldspar mineral is characterized by striations (Figure 3 - 1). These are very thin, only a fraction of a millimeter wide, very straight, parallel, continuous lines that appear on cleavage faces on the mineral. Striations result from crystal twinning that occurs during mineral growth. A twinned plagioclase crystal is actually a composite crystal which means it is composed of more than one crystal face that have different but related orientations with respect to each other. A twinned plagioclase crystal is composed of numerous, thin, parallel crystal faces arranged in alternating fashion such that the mineral appears to have a lined or striated surface. A twinned relationship results in a slight deflection of the cleavage surface, and this shows up as a series of parallel lines referred to as striations. Potassium or K-feldspars do not have striations. Instead, they may have what is called a perthitic texture (Figure 3 - 2). The perthitic texture of K-feldspar is characterized by numerous irregular or wavy, short discontinuous lines, of variable thickness, usually not more than 1 mm wide. They appear on the surface of the mineral and are not parallel or sub-parallel to one another. They are significantly thicker, and therefore much easier to see, than the very thin, straight, parallel striations on a plagioclase feldspar mineral. The perthitic texture of a K-feldspar mineral is the result of small inclusions of Na-bearing feldspar. Potassium feldspar forms at high temperatures, and typically contains some amount of dissolved Na-bearing feldspar. As the melted mineral cools and starts to solidify, the Na-bearing feldspar portion tends to exsolve or “unmix” from the K-feldspar. The exsolved Na-bearing feldspar takes the form of thin, sub-parallel inclusions within the rest of the K-feldspar mineral, thereby giving it that distinctive “perthitic” or “lined” appearance. Plagioclase feldspar is also easy to identify because of the blue-green iridescence it sometimes has when light reflects off its surface (Figure 3 - 1). Iridescence is a property unique to a few minerals, but plagioclase is amongst the most common. It appears as if this mineral is changing colour from green to blue to white, as light reflects at different angles off its surface. It can be a key to proper identification of this feldspar mineral. 4 GEOL 1107, Lab #3 Table 3 - 1 summarizes the main points associated with feldspar mineral textures and identification. PLAGIOCLASE FELDPSPAR POTASSIUM or K-FELDSPAR Striations are common to rare depending on quality of mineral Perthitic texture is common, Perthitic texture characterized by thin, lens-shaped inclusions. These are thin, approx. 1 mm, discontinuous, sub-parallel, linear inclusions. Thin, << 1 mm, straight, parallel striations Striations parallel to the edge of cleavage surface Striations appear on only one cleavage surface, only rarely on 2 surfaces Lines cut obliquely across the edge of a cleavage surface at approx. a 600 - 900 angle May be seen on both cleavage surfaces Colour is typically white, but may vary Blue – green iridescence on cleavage surfaces Colour is commonly pink, orange or white, but may vary Lines may or may not be visible depending upon the colour of the mineral Table 3 - 1. Main points about texture, cleavage and colour used to identify plagioclase and potassium or K-feldspar minerals. Here’s something to think about when using striated or perthitic textures to identify a feldspar mineral. First locate the cleavage planes, both plagioclase and K-feldspar minerals have two poor to good cleavages at approximately 90o. Look for striations or a perthitic texture. Similarly, you may first want to locate the texture of the feldspar, either striated or perthitic, and use this feature to help identify cleavage surfaces. 5 GEOL 1107, Lab #3 EXERCISE 3 - 1: PLAGIOCLASE vs K-FELDSPAR MINERALS Examine first the samples in the lab at the “feldspar” display. Be sure you observe each of the following: 1. cleavage surfaces, cleavage edge 2. striations on plagioclases 3. perthitic structure in K feldspars 4. iridescent luster in plagioclase 5. colour variations Also examine the minerals in the box of common minerals. List the sample number and texture of all the mineral samples from the “feldspar” display that are plagioclase feldspars and the sample number and texture of those that are potassium or K-feldspars. Sample No. Texture (Perthitic or Striated?) Feldspar (Plagioclase or “K”?) IMPORTANT NOTE All the feldspar minerals are extremely important for future labs. Be sure you learn to identify them. 6 GEOL 1107, Lab #4 LABORATORY 4 MINERAL IDENTIFICATION Based on the physical properties of minerals introduced in labs 1, 2, and 3 it’s now time to start identifying the common minerals included in this course. To identify a mineral, you need to determine what it is and why you think so.This means you give the mineral a name and list the properties you use to identify it. For example, take the mineral in figure 4 - 1. We don’t know what this mineral is but right away we can list some of its properties. Figure 4 - 1. Unknown mineral 1. Let’s start with luster. The mineral has a non-metallic luster, meaning it does not look like a piece of metal. More specifically, it has a bright glassy type of non-metallic luster. 1 GEOL 1107, Lab #4 2. Then there’s colour. The mineral is primarily white with clear or transparent parts around the edges. 3. What about fracture or cleavage? There are no smooth, flat surfaces that may be cleavage. The surface of this mineral is instead irregular with an uneven fracture. It’s safe to assume then that it has no cleavage. 4. What about hardness? Using the tools provided in the lab, we’ve determined a hardness of approximately 7. 5. What about streak? Again, using the tools provided in the lab the streak is white. Now we have five properties, more than enough to identify the mineral. There are other properties we can also consider. The mineral in figure 4 - 1 is non-magnetic and does not react with hydrochloric acid (HCl). These are helpful things to know but they don’t tell us what properties the mineral has, instead they tell us what properties the mineral does not have, and lots of minerals are non-magnetic and don’t react with HCl. Do not use properties the mineral does not have to identify it. IMPORTANT Don’t describe what the mineral does not have for properties. Describe the properties that the mineral does have. So, for the mineral in figure 4 - 1 we have five properties. Throughout this course you will always be asked to provide three to five properties that you see in a mineral (i.e. colour), or determine by examining it closely (i.e. reaction with HCl) that are used to identify it. The next step is to find the name of the mineral. For this you go to table 4 - 1 or table 4 - 2 in this lab. 2 GEOL 1107, Lab #4 Table 4 - 1, beginning on page 12, has all the metallic minerals you will need to know for this course. The minerals in table 4 - 1 are listed from softest to hardest. The first mineral is molybdenite with a hardness of 1 to 1.5. The last mineral is table 4 - 1 is pyrite which has a hardness of 6 to 6.5. Table 4 - 2, a much longer table beginning on page 16, includes all the nonmetallic minerals you need to know. These minerals are also listed from softest to hardest beginning with talc, which has a hardness of 1, and ending with diamond, with a hardness of 10. The mineral in figure 4 - 1 is non-metallic so it’s found in table 4 - 2. It has a hardness of 7. The first mineral in table 4 - 2 with a hardness that includes 7 is olivine and the last mineral with a hardness of 7 is quartz. In between are four more minerals. So, we’ve narrowed down the number of possible answers to six minerals. Now let’s look at colour. The mineral in figure 4 - 1 is mostly white with some clear or colourless parts. Going back to table 4 - 2, what mineral has a hardness of 7 and is white or colourless? The only two minerals that fit this description are kyanite and quartz. Kyanite, however, often has a blue colour, which is nowhere to be seen in figure 4 - 1. So, by the process of elimination we’ve determined that the best answer when identifying the mineral in figure 4 - 1 is quartz. When we compare the image in figure 4 - 1 to the images of quartz in table 4 - 2 and other images like figure 1 - 4 A in lab 1, it’s pretty clear that the mineral is quartz. So, that’s how mineral identification can work. Based on a description of the mineral’s properties and a comparison with mineral descriptions and images in labs 1, 2 and 3 a name is selected, and themineral identified. The important thing to remember is that this is a science course, and we want you to think like a scientist, which means using the scientific method. First you ask a question, like what is the name of the mineral I’m looking at? Then you gather evidence, like mineral properties, that will help answer the question. Based on this evidence you come up with an answer. Then you test you answer by looking at the information in labs 1, 2, 3 and 4. If the answer makes sense you’re done, and you move on to the next mineral. If your answer does not make sense then you need to confirm the properties you have, get more if need 3 GEOL 1107, Lab #4 be and then rethink your answer. At the end of the day, you do the best you have with the information at hand. Geologists do it all the time. Remember the really important point first stated at the beginning of lab 1. THIS IS REALLY IMPORTANT READ THIS AND SAVE YOURSELF SOME TROUBLE LATER. A really important thing to remember about all minerals is that they vary. What this means is that some minerals will have a very specific property that make them easy to identify, such as the emerald green colour of malachite. Other minerals will have a number of different properties that also make it easy to identify them. The mineral plagioclase feldspar has a white colour, thin straight lines or striations on its cleavage surface and a blue - green iridescence. Many minerals have a property or properties that are very useful for identifying them, but because they vary you may not see them in all samples of the same mineral. So how then do you identify a mineral? The answer is simple. Identification is based not on one but as many properties as possible. Also make sure you look at more than one sample of the same mineral so you can see as many properties as possible and how they might look different. List all the properties you see and make a decision, chances are you’ll be right. At the end of the day, the name you give to a mineral is based on the properties you see and the sum total of what they tell you. A mineral identification flow chart called “How to identify a mineral” is another method that you may find useful and are welcome to use. It asks a series of questions that have either a ‘YES’ or ‘NO’ answer that then directs you to the next question and eventually a name for the mineral. It works well for most of the common minerals in this course, but not all. For some minerals it finishes with a short list of possible names from which a final selection is made. Use this flow chart if you want. Use any method you want to identify a mineral. We’re less concerned with how you get an answer, that’s up to you, and more concerned with what the answer is. All you need do is name the mineral and list the properties used to identify it. We ask that you include from 3 to 5 properties that you can see for yourself (i.e. colour) or are given to you (i.e. streak, hardness). 4 GEOL 1107, Lab #4 5 GEOL 1107, Lab #4 6 GEOL 1107, Lab #4 7 GEOL 1107, Lab #4 8 GEOL 1107, Lab #4 EXERCISE 4 - 1: MINERAL IDENTIFICATION Based on the physical properties of minerals introduced in lab 1, crystal habit in lab 2, cleavage in lab 3 and feldspar properties in lab 4, identify the different minerals in the common and economic mineral boxes. For each mineral list three to five properties that you either see in the mineral. Use mineral identification table 4 - 1, Metallic Minerals, beginning on page 12, and table 4 - 2, Economic Minerals, beginning on page 16. Use the flow chart, entitled “How to identify a mineral” starting on page 5 as one method to aid with identification. As you identify a mineral fill in the charts on pages 10 and 11. In the box with the appropriate sample number include a list of the mineral properties and the name of the mineral. This exercise is open book so use all your labs. Get to know your labs and where to find information in them. All future quizzes and lab tests will be open book. After you’ve had some practice you may want to time yourself to see how long it takes. The only condition is all quizzes and tests will have a limited time to complete them. Also included in lab 4 is a list of the common mineral and their economic use (Table 4 - 3). This will help you better appreciate some of the importance of rocks and minerals and how they affect our everyday life. 9 GEOL 1107, Lab #4 Common mineral identification chart 10 GEOL 1107, Lab #4 Economic mineral identification chart 11 Table 4 - 1. Metallic minerals with hardness less than 2.5 (can be scratched with a fingernail) COLOR STREAK HARDNESS CLEAVAGE/ FRACTURE OTHER PROPERTIES MINERAL NAME CHEMICAL FORMULA COMMON MINERAL ASSOC. Bluish “steel” gray metallic color to silvery gray Black to blue gray, grayish green when marked on paper 1 – 1.5 1 perfect cleavage. Not commonly observed. Usually appears with irregular fracture. High density (4.7g/cm3). Greasy feel. Metallic luster. Molybdenite MoS2 Sulfides Silvery gray to dull black Gray to black 1-2 1 perfect cleavage. Not commonly observed. Usually appears with irregular fracture. Low density (2.2 g/cm3). Greasy feel. Usually bright metallic luster, sometimes sub-metallic to dull luster. Graphite C Native Elements Bright silvery metallic to dull gray. Dark gray to black 2.5 – 2.8 3 perfect @ 90o imparts cubic shape. Very high density (7.5 g/cm3). Commonly forms perfectly cubic crystals that mimic cleavage. Metallic luster. Galena PbS Sulfides 12 Table 4 - 1. Metallic minerals with hardness between 2.5 and 5.5 (harder than a fingernail, can be scratched by glass) COMMON MINERAL ASSOC. COLOR STREAK HARDNESS CLEAVAGE/ FRACTURE OTHER PROPERTIES MINERAL NAME CHEMICAL FORMULA Yellow. May vary depending upon the presence of impurities. Yellow 2.5 - 3 No cleavage. Hackly fracture. High density (19.3 g/cm3). Gold’s higher density distinguishes it from pyrite and some mica flakes which are similar in appearance. Occurs in irregular, compact masses. Very ductile and malleable. Metallic luster. Native Gold Au Native Metals Copper to red metallic. Tarnishes dull. Light green to turquoise when exposed to air. Copper to red metallic. 2.5 - 3 No cleavage. Hackly fracture. High density (8.9 g/cm3). Occurs in irregular, compact masses. Sometimes dendritic. Very ductile and malleable. Metallic luster. Native Copper Cu Native Metals Yellow metallic “bronzy” when newly exposed. Tarnishes to iridescent purple and blue. Gray to black. 3 Poor cleavage not usually observed. Commonly has irregular fracture sometimes poorly conchoidal. High density (5.7 g/cm3). May appear as a dense, granular mass. A metallic ore, sometimes called “peacock” ore. Metallic luster. Bornite Cu5FeS2 Sulfides 13 CHEMICAL FORMULA COMMON MINERAL ASSOC. CuFeS2 Sulfides Pyrrhotite Fe(1-x)S (variable but close to FeS) Sulfides Sphalerite (Zn,Fe)S Sulfides COLOR STREAK HARDNESS CLEAVAGE/ FRACTURE OTHER PROPERTIES MINERAL NAME Dark or brassy yellow, often with iridescent film when tarnished. Greenish black 3.5 - 4 No cleavage. Uneven to conchoidal fracture. Generally in compact, massive or microgranular masses. Metallic luster. Chalcopyrite Yellow bronze to bronze and dull gray brown. Gray black 3.5 - 4.5 No cleavage. Uneven fracture. Common as massive, granular aggregates. Commonly magnetic, a property that helps distinguish it from nonmagnetic pyrite. Metallic luster. Commonly black to brown. Color varies depending upon changes in composition and the presence of impurities Brown to yellowish brown to reddish. 3.5 - 4 6 good cleavages that parallel a complex “12-sided” crystal structure. All 6 cleavage surfaces are rarely seen in one sample. Cleavage and crystal habit make for a very complex appearance which in itself may be diagnostic. Sub-metallic luster, sometimes metallic in appearance. 14 Table 4 - 1. Metallic minerals with hardness between 5.5 and 6.5 (harder than a steel knife, softer than a streak plate) COLOR STREAK HARDNESS CLEAVAGE/ FRACTURE OTHER PROPERTIES MINERAL NAME CHEMICAL FORMULA COMMON MINERAL ASSOC. Dull red to reddish brown or bright silvery to bluish gray metallic. Red to reddish brown 5.5 – 6.5 No cleavage. Uneven fracture but not commonly observed. Massive, compact, amorphous, granular masses. Frequently colloform or concretionary in texture. Bright, metallic or dull earthy luster depending upon variety. Hematite Fe2O3 Oxides Black 5.5 – 6.5 No cleavage. Uneven fracture. Compact and granular masses. High density (5.2 g/cm3). Occurs Strongly Magnetic. Submetallic to vitreous luster. . Magnetite Fe3O4 Oxides Greenish to brownish black 6 – 6.5 No cleavage. Fracture commonly uneven, may be conchoidal. Occurs as compact, granular aggregates. Frequently has “perfect” 4-sided cubic and more “irregular” 8-sided octahedral crystals with striated surfaces. High density (5.0 g/cm3). Very fragile. Produces a spark if struck by a hammer. Metallic luster. Pyrite FeS2 Sulfides Black Yellow to brassy yellow. 15 Table 4 - 2. Non-metallic minerals with hardness less than 2.5 (can be scratched with a fingernail) COLOR STREAK HARDNESS CLEAVAGE/ FRACTURE OTHER PROPERTIES MINERAL NAME CHEMICAL FORMULA COMMON MINERAL ASSOC. Commonly white, maybe greenish white, gray or brownish. White 1 1 perfect cleavage rarely seen. Very soft, compact, massive, easily carved “steatite” structure. Greasy feel when massive. Never occurs in distinct crystals. Usually an earthy luster, sometimes pearly. Talc Mg3Si4O10 (OH)2 Sheet Silicates Yellow to black (Variable) Yellow brown 1-5 (Variable) Depending upon variety of mineral, cleavage not present or unobserved. Fracture uneven. Usually too small to see. Limonite is a general term used to describe a number of amorphous, difficult to define iron oxide and hydroxide minerals, such as goethite. These may occur as colloform or non-crystalline earthy masses, crusts or stains. Common dull to earthy luster. Usually a secondary mineral formed through the weathering and oxidation of pyrite. Dull, earth luster. Limonite FeOOH Goethite Oxides/ Hyroxides 16 FeO(OH) Lepidocrocite COLOR STREAK HARDNESS CLEAVAGE/ FRACTURE OTHER PROPERTIES MINERAL NAME CHEMICAL FORMULA COMMON MINERAL ASSOC. White to yellowish brown to brown. White 2 – 2.5 1 perfect cleavage rarely seen. Usually a soft, compact, massive or very finegrained aggregate. Has the odor of freshly turned soil when newly exposed. Dull, earthy luster. Kaolinite Al2Si2O15 (OH)4 Sheet Silicates Golden yellow to brown. Pale yellow 2-3 1 perfect cleavage. Low density (2.4 g/cm3). Irregular masses of platy crystals that appear as scaly aggregates. When heat to >300oC crystals lose water and expand 18 to 25 times original volume. Dull to vitreous luster. Vermiculite (Mg,Fe,Al)3 (Al,Si) 4O10 . (OH)2 4H2O Sheet Silicates White, gray, yellowish, pink to brown. White or pale colored. 2 1 good, 2 poor cleavages, difficult to observe. Maybe granular and compact waxy-looking masses or fibrous aggregates of elongated crystals. Vitreous luster. Gypsum CaSO4 .2H O 2 Sulfates 17 COLOR OTHER PROPERTIES MINERAL NAME CHEMICAL FORMULA COMMON MINERAL ASSOC. Perfect cleavage rarely seen. High density (8.1 g/cm3), although difficult to determine as it rarely occurs in discrete masses. Microcrystalline or earthy masses, films or disseminated grains. Dull, earthy luster. Cinnabar HgS Sulfides 2 – 2.5 1 perfect cleavage. Dark, compacted masses of platy crystals. Vitreous luster. Chlorite 2 – 2.5 1 perfect cleavage. Foliated or layered, scaley masses of very thin, platy crystals. Individual crystals are flexible, elastic and may be very large (>10 cm). Crystals are transparent or translucent with pearly to glassy luster. Muscovite STREAK HARDNESS Bright red to scarlet. Scarlet to orange red 2 – 2.5 Greenish black Greenish black Colorless to silvery-white, white or yellow. Colorless to white CLEAVAGE/ FRACTURE 18 (Fe,Mg,Mn,Ni,Al) 6AlSi3O10(OH)8 KAl2(AlSi3)O10 (OH)2 Sheet Silicates Sheet Silicates Table 4 - 2. Non-metallic minerals with hardness between 2.5 and 5.5 (harder than a fingernail, can be scratched by glass) COMMON MINERAL ASSOC. COLOR STREAK HARDNESS CLEAVAGE/ FRACTURE OTHER PROPERTIES MINERAL NAME CHEMICAL FORMULA Black, brown or dark green. Black, brown or dark green. 2.5 - 3 1 perfect cleavage. Foliated or layered, scaley masses or aggregates of very thin, platy crystals. Individual crystals are flexible, elastic, may be large. Transparent or translucent. Vitreous luster. Biotite K(Mg,Fe)3 (Al,Fe)Si3O10 (OH,F)2 Sheet Silicates Yellow to dark green or white Yellow to dark green or white 2.5 - 4 1 good cleavage (Antigorite), usually difficult to observe, or no cleavage (Asbestos) Serpentine (Mg,Fe)3 Si2O5(OH)4 Sheet Silicates Frequently colorless, but may be white, pale yellow, red, brown or black depending upon impurities. White. May vary depending upon color. 2.5 3 perfect cleavages @ 90o. Halite NaCl Halides 19 Depending upon the variety of serpentine it may be a hard, dense mass of laminated, irregular crystals (Antigorite) or a more lose aggregate of elastic fibrous crystals easily separated (Asbestos). Greasy to pearly luster. Low density (2.1 g/cm3). May appear as large individual crystals, dense clusters of well formed crystals or microcrystalline crusts or coatings. Vitreous luster. Dissolves readily in water. Distinctive “salty” taste. COLOR STREAK HARDNESS White or yellowish to red, reddish brown to brown. White or yellowish to red, reddish brown to brown. May vary depending upon color. 1-3 Commonly white, less commonly colorless, or pale yellow, red or green. White 2.5 – 3.5 Colorless, white, pink, green, yellow or black. White 3 CLEAVAGE/ FRACTURE COMMON MINERAL ASSOC. OTHER PROPERTIES MINERAL NAME CHEMICAL FORMULA Bauxite refers to a group of related minerals including gibbsite, boehmite, and diaspore. Found in earthy, massive or pisolitic masses. Earthy luster. Bauxite Al(OH)3 Gibbsite, 3 good cleavages forming a prismatic shape. High density (4.5 g/cm3), unusual for a non-metallic mineral. Typically compact, granular masses. Vitreous luster. Barite BaSO4 Sulphates 3 perfect cleavages @ approximately 60o. Occurs as distinct rhombohedral or prismatic crystals, inter-growths of crystals, or compact, dense, microcrystalline masses that occur as encrustations or void fillings. Vitreous to iridescent, pearly luster. Soluble in cold, dilute (10%) hydrochloric acid where it effervesces. A common biogenic material in many marine invertebrates (bivalves, coral). Calcite CaCO3 Carbonates No cleavage. Uneven fracture. 20 Oxides/ Hyroxides AlO(OH) Boehmite and Diaspore COLOR STREAK HARDNESS CLEAVAGE/ FRACTURE OTHER PROPERTIES MINERAL NAME CHEMICAL FORMULA COMMON MINERAL ASSOC. Colorless, white, pink, green, or yellow. White 3.5 - 4 3 perfect cleavages @ approximately 60o. Occurs as distinct rhombohedral crystals, aggregates of crystals, or compact, dense, coarse crystalline or microcrystalline masses. Vitreous to iridescent, pearly luster. Soluble in cold, dilute (10%) hydrochloric acid only when fragmented to a fine powder where it effervesces Dolomite CaMg(CO3)2 Carbonates Bright green or emerald green. Light green 3.5 - 4 Good cleavage, rarely seen. Malachite Cu2(CO3)(OH)2 Carbonates Bright blue Pale blue 3.4 - 4 Moderately good cleavage Azurite Cu3(CO3)2 (OH)2 Carbonates Common as a green film or stain on other copperrich minerals. May occur as thinly laminated, colloform, reniform (“kidney-shaped”) masses. Vitreous or silky luster. Commonly occurs as a blue earthy film or stain on other copper-rich minerals. May occur as thinly laminated, concretionary or granular mass. May also occur as groups of radiating, elongated or tabular crystals. Vitreous luster. 21 COLOR STREAK HARDNESS CLEAVAGE/ FRACTURE OTHER PROPERTIES MINERAL NAME CHEMICAL FORMULA COMMON MINERAL ASSOC. Colorless to yellow, green, blue, pink, purple or black. Colorless or white to variable. 4 4 perfect cleavages forming octahedral (8 – sided double pyramid shape) structure. Cubic crystals. May also occur as compacted, banded and concretionary masses. Crystals intergrowths are common. Vitreous luster. Fluorite CaF2 Halides Colorless to yellow, green, brown, less commonly blue or red. Always white 5 1 poor cleavage. The apatite group includes a number of different minerals including fluorapatite. Hexagonal (6-sided) crystals may be elongated or stubby. Also appears as granular or colloform masses. Vitreous to sub-resinous luster. Apatite Ca5F(PO4)3 Phosphates Black to dark green Black 5-6 2 good cleavages @ 56o and 124o. Part of the amphibolite group of minerals that also includes Tremolite and Actinolite. Generally short, stubby crystals. Frequently elongated, acicular to fibrous crystals. Vitreous luster. Hornblende (Ca,Na)2-3 (Mg,Fe+2,Fe+3, Al)5(Al,Si)8O22 (OH)2 Double Chain Silicates 22 Table 4 - 2. Non-metallic minerals with hardness between 5.5 and 6.5 (harder than a steel knife, softer than a streak plate) COLOR STREAK HARDNESS CLEAVAGE/ FRACTURE OTHER PROPERTIES MINERAL NAME CHEMICAL FORMULA COMMON MINERAL ASSOC. Dull red to reddish brown or bright silvery to bluish gray metallic. Red to reddish brown 5.5 – 6.5 No cleavage. Uneven fracture but not commonly observed. Massive, compact, amorphous, granular masses. Frequently colloform or concretionary in texture. Bright, metallic or dull earthy luster depending upon variety. Hematite Fe2O3 Oxides Commonly black, or dark greenish black to brown or black. Sometimes yellowish green depending upon variety. Commonly black or gray-green. 5-6 2 good to perfect cleavages @87o. Sometimes a poorly defined conchoidal or splintery fracture. The pyroxene group includes a number of minerals. Generally prismatic crystals often stubby, square or octagonal in cross-section. Sometimes massive or granular aggregates variety. Vitreous luster. Pyroxene Mg2Si2O6 Enstatite, Single Chain Silicates 23 (Ca,Na) (Mg,Fe,Al,Ti) (Si,Al)2O6 Augite, CaMgSi2O6 Diopside COLOR STREAK HARDNESS Colorless, white, yellowish, green, less commonly pink or reddish. White to colorless 6 Typically colorless, pink or white. Sometimes green, yellow, blue or gray. White 6 OTHER PROPERTIES MINERAL NAME CHEMICAL FORMULA COMMON MINERAL ASSOC. 2 good cleavages @87o. Plagioclase feldspars include a group of minerals that show different physical characteristics depending upon the ration of Ca and Na cations. Usually in compact, granular masses. Glassy to pearly luster. Plagioclase feldspars may have well defined, very thin, straight, parallel “hair-like” striations. Sometimes strongly iridescent (when it is the Labrador variety). Plagioclase Feldspar (Ca,Na)(Al(Si,Al) Si2O8 Framework Silicates 2 good cleavages @90o. Potassium (K) or alkali feldspars include a group of similar minerals with only slight variations in physical appearance. Compact, granular masses are common. Large to very large prismatic, columnar or tabular crystals are common. Glassy to pearly luster. K-feldspars frequently have a well defined, “perthitic” texture. Potassium Feldspar KAlSi3O8 Framework Silicates CLEAVAGE/ FRACTURE 24 Table 4 - 2. Non-metallic minerals with hardness greater than 6.5 (harder than a streak plate) COLOR STREAK HARDNESS CLEAVAGE/ FRACTURE OTHER PROPERTIES MINERAL NAME CHEMICAL FORMULA COMMON MINERAL ASSOC. Olive green, yellowish green to yellow. Green 6.7 - 7 1 poor cleavage. Frequently has conchoidal fracture. Olivine defines a small group of minerals. Typically small prismatic crystals arranged in a dense, compacted granular mass or aggregate. Vitreous luster. Olivine Mg2SiO4 Forsterite, Island Silicates Fe2SiO4 Fayalite Green to yellowish green. Green to yellowish green. 6-7 1 good cleavage. Prismatic, elongated columnar crystals arranged in granular masses or aggregate of radiating “fibrous-like” crystals. Vitreous luster. Epidote Ca2(Al,Fe)3Si3O12 (OH) Island Silicates Light blue color that varies in intensity within individual crystals. Less commonly white or gray. White 6–7 (across cleavage planes), 1 perfect cleavage Elongated, tabular crystals. Larger, individual crystals and clusters or aggregates of radiating, intergrown crystals are common. Vitreous to pearly luster. Kyanite Al2SiO5 Island Silicates 4–5 (along cleavage planes) 25 COLOR STREAK HARDNESS CLEAVAGE/ FRACTURE OTHER PROPERTIES MINERAL NAME CHEMICAL FORMULA COMMON MINERAL ASSOC. Reddish brown to black Colorless 7 – 7.5 1 poor cleavage. Often appears with uneven fracture. Prismatic, sometimes stubby crystals. Crystal surfaces frequently rough due to weathering and alteration. Crystals frequently in characteristic cruciform shapes which are crossed crystals @ 90o or 60o. Less commonly they are irregular or granular crystals in rock. Dull, earthy or sometimes vitreous or resinous luster. Staurolite (Fe,Mg,Zn)2 (Al9Si4O23(OH) Island Silicates Commonly dark red, frequently violet with brownish coloration. Other varieties may be green, brown, orange, pink or black. Commonly white, may vary (difficult to observe) 6.5 – 7.5 No cleavage. Uneven to splintery or subconchoidal fracture. Garnets are a group of minerals including pyrope, almandine and grossular. Complex, “many faced” crystal habits that appear rounded or spherical. Individual crystals and dense, granular masses of many crystals are common. Vitreous or adamantine luster. Garnet (Mg,Fe,Ca,Cr)3 Al2(SiO4)3 Island Silicates 26 STREAK HARDNESS CLEAVAGE/ FRACTURE OTHER PROPERTIES MINERAL NAME CHEMICAL FORMULA COMMON MINERAL ASSOC. Colorless. The presence of different impurities may impart a wide variety of colors (i.e Amethyst – purple, Smoky quartz – black) Colorless, white or variable in color. 7 No cleavage. Commonly good conchoidal fracture, especially in microcrystalline form. Frequently has uneven fracture. Commonly occur as well-defined, elongated, hexagonal (6-sided) crystals that may be very large in size (amethyst). Crystal faces may be striated. Usually dense, compact masses of many poorly formed crystals or as a microcrystalline mass (agate, jasper). Vitreous luster. Microcrystalline quartz has a dull, waxy luster. Quartz SiO2 Framework Silicates Variable including colorless, yellow, blue, green, violet or reddishyellow. White (difficult to observe) 1 perfect cleavage. Individual crystals or crystal aggregates are the most common form. Prismatic crystals, sometimes very large in size. Striations may be observed on crystal faces. Vitreous luster. Al2SiO4(F,OH)2 Island Silicates COLOR 8 27 and Microcrystalline Quartz Topaz COLOR STREAK HARDNESS Variable color. Commonly gray or brown. Less frequently red, blue, yellow, green, purple, or colorless. Colorless or white (difficult to observe) 9 Colorless, yellow, brown, gray, green or black. None 10 CLEAVAGE/ FRACTURE COMMON MINERAL ASSOC. OTHER PROPERTIES MINERAL NAME CHEMICAL FORMULA No cleavage. Uneven or “rectangular” fracture. Common form is well formed, individual. crystals or granular masses. Hexagonal (6sided), stubby, barrelshaped crystals. Adamantine luster. Corundum Al2O3 Oxides/ Hyroxides 4 perfect octahedral cleavages. Commonly roundish, octahedral crystals. Transparent to adamantine luster. Diamond C Native Element 28 GEOL 1107, Lab #4 Table 4 - 3. Common minerals and their economic significance Mineral Andalusite Apatite Arsenopyrite Azurite Barite Bauxite Bornite Calcite Chalcopyrite Cinnabar Copper Corundum Diamond Economic Significance Used in the manufacture of high temperature or acid resistant insulators and electrical products because of its resistance to change or reaction. Occasionally a semiprecious gem. An important index minerals that indicates metamorphic conditions or grade during rock formation/alteration. A source of phosphorous used in the production of fertilizers and phosphoric acid. Economic source of arsenic, with tin, gold, silver and cobalt as important by-products that occur as impurities. Valuable decorative stone. In crushed form it has been used as a pigment. Minor source of copper. Economic source of barium. Used as a high density additive in drilling mud to add weight. Used in the manufacture of paper, rubber, and as a radiation screen in cement. Important economic source of aluminum. Economic source of copper. Used in the manufacture of building materials (cement, ornamental stone) and fertilizers. Widely used for metal and chemical production as a prime ingredient or secondary additive. Economic source of copper, with lesser amounts of gold and silver which are present as impurities. Important economic source of mercury. Used to make the pigment vermillion. Important component of metal alloys such as brass and bronze. Used for electrical wiring and coins for currency. A semi-precious gemstone also used as an industrial abrasive. Was used in the manufacture of precision instruments; has since been replaced by synthetic varieties. Precious and semi-precious gemstones. Industrial abrasive. 29 GEOL 1107, Lab #4 Mineral Dolomite Fluorite Galena Garnets Gold Graphite Gypsum Halite Hematite Kaolinite Economic Significance Similar to calcite. Used in the manufacture of building materials (cement, ornamental stone) and fertilizers. Widely used for metal and chemical production as a prime ingredient or secondary additive. Used in the production of hydrofluoric acid and as a flux in metal manufacturing. Economic source of lead and, to a lesser extent, silver when it’s present as an impurity. Semi-precious gemstones. Industrial abrasive. Important as a monetary standard and for jewelry. Useful in chemistry, dentistry and in electronic components because of its excellent heat and electrical conductivity and resistance to most chemical reactions. Used in some electrical components, as a dry lubricant, in pencils and as a dye. Prime ingredient in plaster of Paris, Portland cement, and some pottery. Important fertilizer ingredient. A very important nutrient. Halite or salt is also used for food preparation and preservation, and in the chemical industry as a main ingredient in many chemical reactions. It is also used to produce some scientific and optical equipment and is a source of Mg, K, Cl, Br and I. Important economic source of iron. Hematite in the banded iron formations of northern Quebec are Canada’s richest iron producing deposits. Also used as a pigment. A clay mineral used in the manufacture of china dishes. A filler in the manufacture of paper, rubber, cosmetics and medicine. 30 GEOL 1107, Lab #4 Mineral Economic Significance Kyanite Used in the manufacture of high temperature or acid resistant insulators and electrical products because of its resistance to change or reaction. Occasionally a semiprecious gem. An important index mineral that indicates metamorphic conditions or grade during rock formation/alteration. Limonite Magnetite Malachite Molybdenite Muscovite Plagioclase Feldspar Potassium Feldspar Pyrite Pyrrhotite Quartz Microcrystalline Quartz Used as a pigment. Has been, and may continue to be, a locally significant source of iron. The richest, most important economic source of iron. Valuable decorative stone. In crushed form it has been used as a pigment. Minor source of copper. Source of molybdenum which is a dry lubricant resistant to high temperatures. Used for electrical and heat insulation and in the manufacture of paper, rubber, fireproof paint and porcelain. Used in the manufacture of ceramics. Labradorite is a semi-precious gemstone. Used in the manufacture of porcelain, detergents and scouring powders. A main ingredient in the manufacture of sulfuric acid. Economic source of nickel, cobalt and platinum. Used in the manufacture of precision instruments (i.e. watches) because of its piezoelectric properties, its ability to polarize light, its transparency to ultraviolet light, its hardness and resistance to chemical reaction or alteration. It is also used in the manufacture of glass, paint and abrasives. In crystal for it is a semiprecious gemstone. 31 GEOL 1107, Lab #4 Mineral Serpentine (Asbestos) Sillimanite Silver Sphalerite Staurolite Talc Topaz Tourmaline Vermiculite Economic Significance Was used for sound and thermal insulation and in the construction of fire-resistant materials. Used in the manufacture of high temperature or acid resistant insulators and electrical products because of its resistance to change or reaction. Occasionally a semiprecious gem. An important index mineral that indicates metamorphic conditions or grade during rock formation/alteration. Used in jewelry, photographic film, electrical components. Still has limited use in coins for currency. Economic source of zinc. Semi-precious gemstones. Index mineral used to indicate metamorphic conditions or grade during rock formation/alteration. Prime ingredient in paper, rubber, cosmetics (talcum powder), and paint. A semi-precious gemstone. Used in the manufacture of precision instruments. Also a semi-precious gemstone. When heated and expanded it is used as insulating material. May be used as potting soil and in the paper, paint and plastics industries. 32 GEOL 1107, Lab #5 LABORATORY 5 IGNEOUS ROCK IDENTIFICATION INTRODUCTION All rocks are made up of one or more minerals. For all rocks the type of mineral(s) and their amount, if there’s more than one, says a lot about how the rock formed, where it formed and how long it took. Aside from the types of minerals in a rock, the texture of the rock also indicates something about the conditions under which it formed. All rocks are composed of either crystals or rock fragments. Most igneous rocks are composed of crystals. The process of crystal formation is the first thing we need to look at for igneous rock identification. CRYSTAL FORMATION Mineral crystals may form by one of several different methods: 1. By sublimation which is mineral precipitation from a gas or vapour. Frost crystals forming inside a freezer or calcite crystals from the steam emanating from a volcanic vent are two examples. 2. By precipitation from a saturated solution. Halite or salt crystal precipitation in water or quartz crystal precipitation in hot water underground – also known as a hydrothermal solution – are two common examples. 3. By the rearrangement of atoms or molecules in a pre-existing mineral. This happens when fresh snow is compacted and converted to solid ice or when “new” metamorphic minerals, such as sillimanite or kyanite, form under high heat and pressure inside the Earth from a pre-existing mineral. 4. When molten rock, such as magma or lava, cools and solidifies. This the most common form of igneous rock formation. Magma is molten rock beneath the Earth’s surface formed because of intense heat within the planet. If liquid magma flows or is extruded onto the surface of the land or seafloor, then it is called lava. 1 GEOL 1107, Lab #5 IMPORTANT NOTE The distinction between magma and lava may seem over simplified but it is an important consideration. Whether or not melted rock (magma or lava) is found at or below the Earth’s surface will impact directly on the type of rock that forms. Thus, it is a very important consideration when it comes to rock classification. IGNEOUS ROCKS Igneous rocks are one of the three main classes of rock. Igneous rocks form when magma or lava cools and solidifies at or below the Earth’s surface. They also form when solid rock fragments, such as ash, are ejected from a volcano and accumulate on the Earth’s surface. The rock fragments ejected by a volcano are called pyroclastic debris. There are two types of igneous rock: 1. Igneous intrusive rocks form when magma beneath the Earth’s surface cools and solidifies. Igneous intrusive rocks are also called plutonic rocks. 2. Igneous extrusive rocks form when lava cools or pyroclastic debris is deposited on the Earth’s surface. These types of igneous rock are also called volcanic rocks. Igneous rocks are described, classified and identified based on two things: composition and texture. COMPOSITION OF IGNEOUS ROCKS Igneous rocks are composed primarily of just a few silicate minerals, the most common type of mineral in the Earth’s crust. The eight common silicate minerals in the Earth’s crust and therefore the most common minerals in igneous rocks are separated into two classes. They are: 1. Felsic 2. Mafic 2 GEOL 1107, Lab #5 Felsic minerals are lighter in colour, richer in silicon (Si), potassium (K) and aluminum (Al), and less dense compared to mafic minerals. The most common felsic minerals are: 1. Quartz 2. Plagioclase feldspar 3. Potassium feldspar 4. Muscovite Mafic minerals, sometimes called ferromagnesian minerals, are darker in colour, richer in iron (Fe) and magnesium (Mg), and more dense compared to felsic minerals. The most common mafic minerals are: 5. Olivine 6. Pyroxene 7. Hornblende 8. Biotite IMPORTANT NOTE These are the most common and most important rock forming minerals you will encounter in this course. If you take the time now to review these minerals from labs 1, 2, 3 and 4 you will have a much easier time when it comes to igneous, sedimentary and metamorphic rock identification. Before we move on to texture and structure here is a quick overview of the eight common silicate minerals to help you with their identification. The mineral properties listed here for each mineral describe how it appears in a rock where you may only see small crystals. 3 GEOL 1107, Lab #5 The felsic silicate minerals 1. Quartz. Commonly occurs as irregular, glassy grains typically clear to smoky (medium light gray) in colour (Figure 5 - 1). Quartz has no cleavage, but conchoidal fracture may be seen on some surfaces. Quartz is different from light-coloured feldspars which appear milkyor translucent. Scale is in centimeters Figure 5 - 1. Quartz 4 GEOL 1107, Lab #5 2. Muscovite. Flexible, silvery to light or white in colour, translucent mineral flakes are commonly associated with quartz or K-feldspar (Figure 5 - 2). Perfect cleavage in one direction. Sometimes appear as small glittering specks. Scale is in centimeters Figure 5 - 2. Muscovite 5 GEOL 1107, Lab #5 3. Potassium Feldspar. Commonly pink, white, or gray coloured with pearly, translucent to opaque luster (Figure 5 - 3). Cleavage in two directions at right angles may be observed. Cleavage planes may flicker or flash light as sample is rotated. Perthitic texture may be observed with close examination. Scale is in centimeters Figure 5 - 3. Potassium feldspar 6 GEOL 1107, Lab #5 4. Plagioclase Feldspar. Usually gray or white when found in felsic rocks (i. e. granite) or dark gray to bluish gray in mafic rocks (i.e. gabbro). Pearly, translucent to opaque luster (Figure 5 - 4). Two cleavage directions at right angles may be detected. Cleavage planes may flicker or reflect light as the sample is rotated. Characteristic striations may be seen with close examination. Scale is in centimeters Figure 5 - 4. Plagioclase feldspar 7 GEOL 1107, Lab #5 The mafic silicate minerals 5. Biotite. Flexible, black, translucent to opaque, shiny mineral flakes (Figure 5 - 5). Perfect cleavage in one direction. When mineral crystals are small it may be confused with hornblende or pyroxene. Cleavage and hardness help distinguish biotite from others. Biotite can be scratched or crushed with a steel probe. Scale is in centimeters Figure 5 - 5. Biotite 8 GEOL 1107, Lab #5 6. Hornblende. Long, needle-like or acicular black crystals (Figure 5 - 6). Harder than biotite. Not as shiny or glassy as biotite. Opaque. Two good cleavages at cleavages at 600 and 1200. Scale is in centimeters Figure 5 - 6. Hornblende 9 GEOL 1107, Lab #5 7. Pyroxene. Shorter, rounder, more spherical crystals, greenish black to black in colour, with a duller, less shiny, resinous luster (Figure 5 7). Opaque to translucent. Two good cleavage directions at 900. Commonly associated with darker mafic rocks (i.e. pyroxenite, peridotite). Less common in felsic rocks (i.e. granitic rocks). If mineral crystal size is very fine, it may be difficult to distinguish between pyroxene and hornblende. It is therefore appropriate to put “presence of pyroxene and/or hornblende” or “presence of mafic minerals“ in your description. Scale is in centimeters Figure 5 - 7. Pyroxene 10 GEOL 1107, Lab #5 8. Olivine. Glassy, light green, occasionally yellow or light orange, short stubby crystals massed together (Figure 5 - 8). One poor cleavage. Conchoidal fracture on some grains. Clusters of many olivine crystals have the appearance of “green sugar”. Scale is in centimeters Figure 5 - 8. Olivine 11 GEOL 1107, Lab #5 After you understand that the common igneous rocks are made up of the eight common silicate minerals, the second thing you need to know for igneous rock identification is there are four different types of rock and that each type is made up of different amounts of the eight common silicate minerals. The four type of igneous rock are: 1. Felsic rocks. They are composed of: 10 to 40 % Quartz 30 to 60 % Potassium Feldspar 0 to 30 % Plagioclase Feldspar 10 to 30 % Biotite and Hornblende Magmas that produce felsic rocks are high in potassium, silicon, and sodium and low in iron, magnesium and calcium. Typical felsic rocks include the intrusive “granitic” rocks such as quartz monzonite, granodiorites and igneous extrusive rocks such as rhyolite and dacite. All are generally light in colour. 2. Intermediate rocks. These rocks are composed of: 25 to 45% Hornblende and Biotite 55 to 75 % Plagioclase Feldspar K - feldspar and quartz are present in minor amounts only. Intermediate type rocks, such as andesite and diorite are “intermediate” in composition between the felsic and the mafic rocks. They are characteristically gray in colour. 3. Mafic rocks. They are composed of: 45 to 75 % Ca-rich Plagioclase Feldspar 25 to 55 % mix of Olivine, Pyroxene and Hornblende Mafic rocks crystallize from magmas that are relatively high in iron, magnesium and calcium, and low in silica. Rock colour is typically black or dark green. 12 GEOL 1107, Lab #5 4. Ultramafic rocks. They are made up of: 10 to 100% Olivine 0 to 90% Pyroxene 0 to 5% Ca-rich Plagioclase Feldspar Ultramafic rocks such as dunite, peridotite and pyroxenite are relatively rare compared to other rock types. They are composed almost exclusively of mafic minerals, which impart a black colour. They form under special conditions that are usually found deep inside the Earth. TEXTURE AND STRUCTURE Texture and structure are the other important aspects of igneous rocks used for identification. The texture of a rock, sometimes called the fabric, is the size, shape and arrangement of mineral crystals or rock fragments in the rock. Structure is the way in which mineral crystals and rock fragments are arranged. Structure refers to larger features such as layers. There are a number of factors that may affect texture and structure of an igneous rock. The size of mineral crystals that form when magma or lava cools and solidifies is dependent on: 1. The rate of crystallization or crystal growth as magma or lava cools and solidifies. Igneous extrusive or volcanic rocks, which solidify quickly in a cooler environment at the Earth’s surface, tend to have smaller or finer crystals. Igneous intrusive or plutonic rocks, which crystallize slowly in a well-insulated, hot environment deep within the Earth’s crust, tend to have large or medium to coarse grains or crystals. 2. The presence of volatile fluids (mainly water) dissolved in magma or lava will help promote crystallization. Magmas, for example, can only retain dissolved fluids, such as water, under conditions of high pressure which occurs when the magma is buried deep inside the Earth. When magma rises towards the surface pressure is reduced and dissolved fluids are released. The effects of fluids and changing pressure mostly affects igneous intrusive rocks. They do not generally affect volcanic rocks. 13 GEOL 1107, Lab #5 3. The viscosity of the magma. Viscosity is a measure of a fluids ability to flow, in this case a magma or lava. A fluid with a high viscosity cannot easily flow. For example, molasses kept inside a refrigerator has a high viscosity. A fluid with a low viscosity, such as liquid water at room temperature, flows more easily. Viscosity affects crystal growth rate. Felsic magma is much more viscous than a mafic magma. As a result, mineral crystals have a harder time growing in a felsic magma than they do in a mafic magma. For this reason, felsic igneous rocks tend to have smaller or finer crystals. Microcrystalline textures, where crystals are not visible to the unaided eye, and glassy textures, where minerals in the rock have little or no crystalline texture, are found exclusively in igneous extrusive rocks. Mafic minerals in igneous rocks maybe tend to have better developed crystal structures regardless of crystal size. Texture is an important part of igneous rock identification. Common igneous rock textures include: 1. Glassy. If lava cools very rapidly, such as when it encounters sea water or glacial ice, there is no time for the atoms in the melt to form a crystalline structure (Figure 5 - 9). The result is an amorphous, glassy rock called obsidian. Scale is in centimeters Figure 5 - 9. The glassy texture of the rock obsidian 14 GEOL 1107, Lab #5 2. Aphanitic. A fine crystalline texture forms when lava or magma cools slowly enough for mineral crystals to form, but still fast enough that only small crystals have time to grow (Figure 5 - 10). Aphanitic rocks are those in which the mineral crystals are smaller than 1 mm and therefore difficult or impossible to see without the aid of a hand lens or microscope. An aphanitic texture usually indicates that the rock has undergone rapid cooling at the Earth’s surface and as such gives some insight into the history of the rock. Aphanitic texture is found only in igneous extrusive rocks such as basalt. Scale is in centimeters Figure 5 - 10. The aphanitic texture of the rock basalt 15 GEOL 1107, Lab #5 3. Phaneritic. Igneous intrusive rocks have coarse or large visible crystals. The term phaneritic comes from the Greek word for “visible”. A rock with a phaneritic texture has mineral crystals between 1 and 10 mm in size (Figure 5 - 11). They form when magma cools more slowly beneath the Earth’s surface. Quartz diorite is the igneous intrusive rock that makes up the bedrock of the Coast Mountains in North Vancouver (Figure 5 - 12). It has a phaneritic texture. Scale is in centimeters Figure 5 - 11. The phaneritic texture of the rock gabbro 16 GEOL 1107, Lab #5 Figure 5 - 12. The phaneritic texture of the rock quartz diorite Plagioclase Feldspar Quartz Mafic Minerals Potassium Feldspar Figure 5 - 13. The phaneritic texture of the rock true granite showing quartz, potassium feldspar, plagioclase feldspar and mafic minerals together in an igneous intrusive rock. 17 GEOL 1107, Lab #5 4. Porphyritic. This term refers to igneous rocks that have two distinct sizes of mineral crystals, large and small (Figure 5 - 14). The presence of two distinct crystal sizes reflects a two part history of formation: 1) First slow cooling of magma to form large crystals called phenocrysts, followed by 2) faster cooling and solidification of the rest of the magma to form a matrix or groundmass of small or fine that surrounds and holds in place the larger phenocrysts. Common extrusive igneous rocks with this so-called bi-modal or two part texture include dacite, trachyte, rhyolite and andesite. Gray Groundmass Large Black Mafic Crystals Scale is in centimeters Figure 5 - 14. The porphyritic texture of the rock andesite 18 GEOL 1107, Lab #5 5. Pegmatitic. This rock texture is made up of large mineral crystals (Figure 5 - 15). They form when magma cools and solidifies very slowly, perhaps because of a high concentration of volatile material (i.e. water, dissolved gas) or when all or part of a magma starts to crystallize at low temperature and, as a result, is much cooler or more concentrated. Either way, a body of magma collects underground which, when completely crystallized or solidified, is made up of potentially very large crystals. The average crystal size in a pegmatitic texture is greater than 1 cm. Some pegmatites contain minerals over a meter in size. A pegmatite is an igneous intrusive rock with large (> 1 cm) crystals. Identification of a pegmatite is basedsolely on texture. Mineral composition is not a factor. Scale is in centimeters Figure 5 - 15. The very coarse crystalline texture of the rock pegmatite 19 GEOL 1107, Lab #5 6. Pyroclastic or Fragmental. A pyroclastic or fragmented texture is found exclusively in volcanic rock fragments or pyroclastic debris ejected by a volcano and deposited on the Earth’s surface. Deposition is similar to sediment and sedimentary rock deposition. The term pyroclastic is derived from the Greek word for “fire broken”. Classification of pyroclastic debris is based on the size of the fragments. Ash size fragments are less than 2mm. Lapilli includes fragments 2 to 64 mm. Volcanic bombs are greater than 64 mm in size. Pyroclastic igneous rocks generally fall into one of two classes. They are: 1) a tuff which is a lithified volcanic ash (Figure 5 - 16), and 2) volcanic breccia (Figure 5 - 17) which is made up of larger lapilli and/or volcanic bomb-size fragments. Scale is in centimeters Figure 5 - 16. The small, ash-size fragments of a pyroclastic or fragmental texture in an ashflow tuff 20 GEOL 1107, Lab #5 Scale is in centimeters Figure 5 - 17. The pyroclastic or fragmental texture of a volcanic breccia with large angular fragments 21 GEOL 1107, Lab #5 7. Vesicular. This is a texture found only in cooled and solidified lava. It is made up of small or fine crystals and many holes, empty spaces or vesicles formed by the inclusion of gas bubbles when the lava quickly cooled (Figure 5 - 18). The end result is a very porous or vesicular rock with an aphanitic mineral texture. Vesicular texture is often associated with basalt. Pumice is an igneous extrusive rock with a vesicular texture that is so porous it will float on water (Figure 5 - 19). This is because there was so much trapped volcanic gas. Figure 5 - 18. The vesicular texture of basalt Figure 5 - 19. The vesicular texture of pumice 22 GEOL 1107, Lab #5 8. Amygdaloidal. This texture begins with vesicles or a vesicular texture. After they form the holes or pores are completely or partially filled with a secondary mineral precipitate (Figure 5 - 20). The walls of a vesicle or pore may be covered or lined with very fine grain calcite or quartz which has precipitated in this void space from solutions circulating through the rock. Vesicle Dark gray aphanitic or small crystals of basalt Vesicle filled with white secondary mineral Scale is in centimeters Figure 5 - 20. The amygdaloidal texture of a vesicular basalt. This basalt is made up of fine crystals, so it has an aphanitic texture. There are also vesicles. Some of these vesicles are filled with a white, secondary mineral giving it an amygdaloidal texture. 23 GEOL 1107, Lab #5 ESTIMATING THE AMOUNT OF MINERALS IN A ROCK Once the mineralogy, texture and structure of an igneous rock have been identified, the next step is to determine the relative abundance of each mineral. For example, if quartz, k-feldspar and mafic minerals are the only minerals in the rock you must estimate what percentage of the total volume of the rock (100%) is quartz, k-feldspar and mafic. Estimating percentages can be a tricky procedure fraught with uncertainty and error. However, a reasonable approximation (+/- 10%) is usually good enough to start with. To help you begin there are a series of diagrams on pages 25 to 28 in this lab. The black dots or shapes in each of the circles amount to a percentage of the total area of the circle. Use these to help estimate the amount of different minerals in a rock sample. The diagrams on pages 25 to 28 are taken from Howell Williams, Francis J. Turner, Charles M. Gilber, 1982. Petrography: An Introduction to the Study of Rocks in Thin Section. W. H. Freeman, p. 593. 24 GEOL 1107, Lab #5 Estimating mineral abundance in a rock sample, 1%, 2% and 3%. 25 GEOL 1107, Lab #5 Estimating mineral abundance in a rock sample, 5%, 7% and 10%. 26 GEOL 1107, Lab #5 Estimating mineral abundance in a rock sample, 15%, 20% and 25%. 27 GEOL 1107, Lab #5 Estimating mineral abundance in a rock sample, 30%, 40% and 50%. 28 GEOL 1107, Lab #5 29 GEOL 1107, Lab #5 Figure 5 -21 (Page 29). For the common igneous rocks, a system of classification is presented in table form. This includes the common igneous extrusive and intrusive rock types. The top half of the chart is for identifying igneous extrusive rocks. The bottom half of the chart is used to identify intrusive igneous rocks. PROCEDURE FOR IGNEOUS ROCK IDENTIFICATION Now that you have all the tools for igneous rock identification, the next thing is to gather all the information and come up with a name for the rock. What follows is a six step procedure you can use for igneous rock identification. This procedure is a guide. Use itif you want, modify it if need be. All we want you to do is identify the rock and tell us why you gave it that name. How you do it is up to you. STEP 1 The first step is to determine the texture of the rock. Questions and Answers You need to decide which of the following five textures the rock has. 1. Does the rock have a pyroclastic or fragmental (rock fragments) texture? If the rock texture is pyroclastic or fragmental it is an igneous extrusive or volcanic rock. This type of rock is found in the top part of the igneous rock identification chart (Figure 5 - 21 on page 29). Pyroclastic or fragmental rocks include volcanic breccias, volcanic conglomerates, and three tuffs - ashfall tuff, ashflow tuff and welded tuff. A breccia is made up of large, angular rock fragments, on average more than 2 mm in size. A conglomerate has large, rounded rock fragments and is quite rare. A tuff is a volcanic rock composed almost entirely of fine-grained, volcanic ash. Ash is very small rock fragments less than 1 mm in size. If the rock sample has a pyroclastic or fragmental texture go to step 2. 2. Does the rock have a glassy texture? If the rock texture is glassy then the rock is one of two igneous extrusive rocks: obsidian or pumice. Based on a more detailed understanding of glassy texture you decide what the rock is, an obsidian or a pumice and the rock is identified. You are done. 30 GEOL 1107, Lab #5 3. Does the rock have a porphyritic texture or an aphanitic texture? Is it made up of large and small crystals or is it made up of only small crystals? If the rock has an aphanitic or porphyritic texture it is an igneous extrusive rock. The name of a rock with this texture is found in the middle of the igneous rock identification chart (Figure 5 - 21 on page 29). It is either a felsite, trachyte, rhyolite, dacite, andesite or a basalt. If the rock sample has an aphanitic or porphyritic texture go to step 3. 4. Does the rock have a phaneritic texture? Is it made up entirely of large crystals? If the rock is made up of large crystals or has a phaneritic texture it is an igneous intrusive rock and is found in the bottom part of the igneous identification chart where there are ten possible answers from syenite through to dunite. If the rock sample has a phaneritic texture go to step 4. STEP 2 This step is where you identify a rock that has a pyroclastic or fragmental texture. Questions and Answers If the rock has a pyroclastic or fragmental texture answer the following questions. If the answer is yes, then you have found the name of the rock. If the answer is no, then go to the next question. 1. Are the rock fragments large or coarse (on average > 2 mm) and angular? If yes, then the rock is a volcanic breccia. 2. Are the rock fragments large or coarse (on average > 2 mm) and rounded? If yes, then the rock is a volcanic conglomerate. 3. Is the rock composed entirely of well sorted, small or fine, consolidated rock fragments (ash)? If yes, then the rock is an ashfall tuff. 4. Is the rock composed of a mix of poorly sorted medium and fine, consolidated rock fragments (ash)? If yes then the rock is an ashflow tuff. 31 GEOL 1107, Lab #5 5. Is the rock composed of well to poorly sorted, mostly fine grain, consolidated rock fragments (ash) and is there layering or banding in the rock? If yes, then the rock is a welded tuff. STEP 3 This step is what to do if the rock texture is aphanitic or porphyritic. At this point you’ve determined the rock has either an aphanitic or a porphyritic texture. The next thing to do is determine which texture is it by answering questions 1 and 2 in this step. Question 1 1. Does the rock have an aphanitic texture? If yes go to the next sentence. If not go to question 2. If the rock has an aphanitic texture the next property is colour. Individual mineral crystals in a rock with an aphanitic texture are generally too small to see so it’s very difficult to see individual mineral colours. Fortunately, in most cases, a rock with this texture is all one colour. If the rock is all white or light coloured and it has an aphanitic texture then it is a felsite. If the rock is all black or dark coloured and it has an aphanitic texture then it is a basalt. If the rock has a colour intermediate between light and dark, often this means a gray colour, and it has an aphanitic texture then it is an andesite. IMPORTANT NOTE Rock identification is based in part on mineral content. However, in many rocks you will find individual mineral crystals that are too small to properly identify. Do the best you can, this is a problem even experienced geologists encounter. The most reliable mineral indicator, when the sample is small and the crystals indistinct, is colour. 32 GEOL 1107, Lab #5 In the procedure so far, this lab refers to “dark or black” coloured (mafic) minerals and “light or white” coloured (felsic) minerals. Generally speaking, a dark mineral refers to anything that is black or dark gray. Light or white coloured refers to all the remaining minerals such as white, clear, pink or orange. Question 2 2. Does the rock have a porphyritic texture? If yes, go to the next sentence. If the rock has a porphyritic texture this means it has two distinct sizes of crystals, large and small. The next step is to determine the mineralogy of the large crystals, the ones you can see. Identifying the large crystals is pretty straight forward because we only need to decide which of the eight common silicate minerals they are. The rest of the rock, the fine crystalline groundmass is only used to identify an andesite and a basalt. If the large crystals in the rock are pink or orange, then they are potassium feldspar. If this is the case, then the rock is a trachyte. If the large crystals in the rock are a mix of pink or orange crystals and crystals that are clear and look like a piece of glass, then they are potassium feldspar and quartz. If this is the case, then the rock is a rhyolite. If the large crystals in the rock are a mix of clear glassy and white crystals, then they are quartz and plagioclase feldspar. If this is what’s in the rock, then it’s a dacite. If the large crystals in the rock are a mix of white and black crystals, then the rock contains plagioclase feldspar and mafic minerals. It is not necessary to distinguish what type of mafic minerals there are. Calling all black minerals mafic is good enough. If the large minerals are a mix of plagioclase feldspar and mafic minerals you have a choice of two rocks: andesite or basalt. Here’s how you tell the difference: If the colour of the groundmass (the fine crystals surrounding the large crystals) in this porphyritic texture is any colour but black then the rock is an andesite. If the groundmass is black, then the rock is a basalt. STEP 4 This step is what to do if the rock has a phaneritic texture. Now that you’ve decided you have a rock with a phaneritic texture, which is a rock made up entirely of large crystals, the next step is to identify what the minerals are. 33 GEOL 1107, Lab #5 The most reliable way to determine the types of minerals in an igneous rock is colour. Mineral properties like cleavage, streak and hardness are of limited use when the mineral is part of rock and can’t be examined in the ways that a separate mineral sample can. The most common minerals in igneous intrusive rocks are the eight common silicate minerals. To identify these minerals in a rock all you need to know are four colours. Mineral identification for igneous intrusive rocks works like this: 1. If the large crystals in the rock are pink or orange, then they are potassium feldspar. 2. If the large crystals in the rock are white, then they are plagioclase feldspar. 3. If the large crystals in the rock are clear and look like a piece of glass, then they‘re quartz. 4. If the large crystals are black, then they are called mafic. It is possible to identifythe different mafic minerals - olivine, pyroxene, hornblende and biotite - using the information in lab 4 and the descriptions on pages 4 to 11 in this lab but it’s not absolutely necessary. In many cases of rock identification, it is enough to say all the black minerals are mafic. Keep in mind that only the eight common silicate minerals are used to identify the common igneous intrusive rocks. It’s also important to know that igneous intrusive rocks contain only a few - one, two, three or four - of the eight common silicate minerals. Once you’ve identified all the minerals in the rock sample go to step 5. STEP 5 This step is where you estimate the percentage of each mineral in a rock. Now that you’ve identified the rock texture as phaneritic and the minerals in it, the next step is to estimate how much of the rock is composed of the different minerals. Use the mineral estimation diagrams on pages 25 to 28 to help with this. All you need to do is ask yourself the following questions: 34 GEOL 1107, Lab #5 1. What percentage of the rock is potassium feldspar which are the large pink or orange crystals? 2. What percentage of the rock is plagioclase feldspar, the large white crystals? 3. What percentage of the rock is quartz which are the large clear or glassy looking crystals? 4. What percentage of the rock are the mafic minerals which are the large black crystals? It may be possible to identify olivine, pyroxene, hornblende and biotite but it’s not a requirement. Make sure the percentages for each mineral when added together equal 100%. Don’t give a range for a value, in other words don’t say the rock contains 20 to 30% plagioclase feldspar. It you think the estimate varies then choose a single number that is an average. For example instead of a range of 20 to 30% record your estimate as 25%. Once you have all your estimates of mineral percentages go to step 6. STEP 6 Name that rock. Now you have all the information needed to identify an igneous intrusive rock with a phaneritic texture. This final step is to select the proper name from the identification chart (Figure 5 - 21 on page 29). The bottom half of this chart has the names of the ten common igneous intrusive rocks with a phaneritic texture and information about their mineralogy. The mineralogy of the ten common rocks is illustrated in the chart and explained in the following way: 1. Syenite is made up of: 0% to 10% quartz 65% to 85% potassium feldspar 10% to 35% hornblende and biotite No plagioclase feldspar 35 GEOL 1107, Lab #5 2. True Granite is made up of: 10% to 38% quartz 48% to 80% potassium feldspar 0% to 7% plagioclase feldspar 5% to 10% hornblende and biotite 3. Quartz Monzonite is made up of: 32% to 38% quartz 25% to 48% potassium feldspar 7% to 25% plagioclase feldspar 10% to 20% hornblende and biotite 4. Granodiorite is made up of: 20% to 32% quartz 10% to 25% potassium feldspar 25% to 45% plagioclase feldspar 20% to 25% hornblende and biotite 5. Quartz Diorite is made up of: 10% to 20% quartz 0% to 10% potassium feldspar 45% to 60% plagioclase feldspar 25% to 30% hornblende and biotite 0% and 5% pyroxene 36 GEOL 1107, Lab #5 6. Diorite is made up of: 0% to 10% quartz No potassium feldspar 60% plagioclase feldspar 10% to 25% hornblende and biotite 5% to 30% pyroxene 7. Gabbro is made up of: No quartz No potassium feldspar 10% to 60% plagioclase feldspar No hornblende and biotite 30% to 75% pyroxene 0 to 15% olivine 8. Pyroxenite is made up of: No quartz No potassium feldspar 10% to 0% plagioclase feldspar 75% to 90% pyroxene 5% to 20% olivine 37 GEOL 1107, Lab #5 9. Peridotite is made up of: No quartz No potassium feldspar No plagioclase feldspar 20% to 80% pyroxene 20% to 80% olivine 10. Dunite is made up of: No quartz No potassium feldspar No plagioclase feldspar 0% to 20% pyroxene 80% to 100% olivine The identification of a rock is done by comparing the percentages of minerals in the unknown rock with the percentages of minerals for each of the ten rock types listed above and in figure 5 - 21 on page 29. Now let’s go through a couple of examples. 38 GEOL 1107, Lab #5 Example 1 Scale is in centimeters Figure 5 - 22. Example 2 Figure 5 - 22 is an image of an igneous intrusive rock made up entirely of large crystals. The large crystals are orange, black, white and clear glassy in colour. These four colours are the maximum number of colours in an igneous rock. The orange minerals are potassium feldspar, and the white minerals are plagioclase feldspar. The black minerals are mafic. Again, we’re not concerned with what type of mafic minerals they are. The clear glassy minerals are quartz. In this second example it appears that all the common silicate minerals are present. Now for the percentage of each mineral. Here’s what the estimates are: Potassium feldspar is 30%. Plagioclase feldspar is 20%. 39 GEOL 1107, Lab #5 Mafic minerals are 15%. Quartz is 35% Now let’s determine which of the ten possible answers this rock is not. It’s not syenite or true granite because both these rocks contain little or no plagioclase feldspar and we have 20% in example 2. Quartz diorite, diorite, gabbro, pyroxenite, peridotite and dunite are all eliminated because these rocks contain little or no potassium feldspar and our sample has 30%. This then leaves , quartz monzonite and granodiorite as possible rock names. A quartz monzonite is made up of: The more common of the two feldspars in this rock 32% to 38% quartz 25% to 48% potassium feldspar 7% to 25% plagioclase feldspar 10% to 20% hornblende and biotite A granodiorite has: 20% to 30% quartz The more common of the two feldspars in this rock 10% to 25% potassium feldspar 25% to 45% plagioclase feldspar 20% to 25% hornblende and biotite So, what’s an important difference between quartz monzonite and a granodiorite? The quartz monzonite has more potassium feldspar than the plagioclase feldspar while the granodiorite has more plagioclase feldspar than potassium feldspar. Example 2 has more potassium feldspar (30%) than plagioclase feldspar (20%) and so it is a quartz monzonite. Could example 1 be a granodiorite? It could. If instead the percentages of feldspar minerals were estimated differently, say 20% potassium feldspar and 30% plagioclase feldspar, then example 1 would be a granodiorite. Estimating mineral percentages is the part of rock identification with the most uncertainty. Approximate values for 40 GEOL 1107, Lab #5 percentage, not exact values, will work. A VERY IMPORTANT NOTE Estimating the percentage of each mineral in a rock is the hardest thing to do because it is an estimate, it is a number based on your ability to observe a rock and compare what you see to the diagrams on page 25 to 28. It’s entirely possible that one person will have percent values different from someone else. If this is the case, it’s still possible for each person to arrive at a correct answer. Take the rock in example 1. Two possible answers were given: diorite and gabbro. Each is correct based on the percentage of plagioclase feldspar and mafic minerals. So, which is correct? Both rocks are very similar in appearance, sharing the same compositions and textures. Depending upon the sample, both answers are acceptable, one may, however, be more right than the other. The relative abundance of minerals will look different to different people and it will vary from sample to sample, even if they’re from the same rock deposit. Rocks are natural objects and, like everything else in nature, they will vary in appearance and composition. Remember, estimating mineral percentages is not an exact science. So, when it comes to igneous intrusive rock identification make sure you describe the texture, mineralogy, percentage of each mineral and use this information to name the rock. If your answer is different from someone else make sure you base your decision on what you see. A final point on igneous rock identification. Don’t forget about pegmatites. A pegmatite is an igneous intrusive rock with large (> 1 cm) crystals (Figure 5 - 15, page 19). Identification of a pegmatite is based solely on texture. Mineral composition is nota factor. 41 GEOL 1107, Lab #5 EXERCISE 5 - 1. MINERAL IDENTIFICATION: REVIEW The most important igneous minerals are listed below and examples are provided in the lab. Match the sample number with the names listed below: 1. Felsic minerals i) Quartz ii) Potassium feldspar iii) Plagioclase feldspar iv) Muscovite 2. Mafic Minerals i) Olivine ii) Pyroxene iii) Hornblende iv) Biotite EXERCISE 5 -2: TEXTURE AND STRUCTURE OF IGNEOUS ROCKS Examine the igneous rock texture display in the lab. These are examples of the texture types described on pages 14 to 23 (Figures 5 - 14 to 5 - 23) in this lab. Go through the list below, re-familiarize yourself with the descriptions and ensure you know where these textures appear in the rock classification chart on page 29. For each type of textural find the number of the sample that represents it. Also, in the space provided, briefly describe some of the geological process or events that would account for the formation of a particular texture or structure. 42 GEOL 1107, Lab #5 i) Vesicular structure No. ii) Amygdaloidal structure No. iii) Aphanitic texture No. iv) Phaneritic texture No. v) Porphyritic texture No. vi) Fragmental texture No. 43 GEOL 1107, Lab #5 EXERCISE 5 - 3: ROCK IDENTIFICATION, IGNEOUS INTRUSIVE ROCKS Look at the large rock samples at the front of the lab. 1. Identify 3 minerals in rock “a” and indicate the percentage of each: i) ii) iii) Note the difference between feldspar and quartz in this sample. Both are relatively easy to distinguish. 2. What type of feldspar is in rock “a” ? 3. How can you tell what type of feldspar it is? 4. Name rock “a”. 5. Identify 3 minerals in rock ‘1’ and indicate the percentage of each. i) ii) iii) 6. What type of feldspar is in rock “1” ? 44 GEOL 1107, Lab #5 7. How can you tell what type of feldspar it is? 8. Name rock “1”. (hint: note the grain or crystal size) 9. Identify 2 minerals in rock ‘b’. Estimating the percentage of each mineral. i) ii) 10. Name rock “b”. 11. What minerals are present in the orbicular structures in rock R21? i) ii) 12. Draw a sketch showing the distribution of minerals in the orbicular structures. 45 GEOL 1107, Lab #5 13. Identify the white phenocryst mineral in rock R9c which is found in your igneous rock box. 14. What other minerals can you identify in rock R9c? EXERCISE 5 - 4: ROCK IDENTIFICATION, IGNEOUS EXTRUSIVE ROCKS 1. Identify two phenocryst minerals in rock R6. i) ii) 2. Identify rock R6. While you have rock R6 compare its porphyritic texture with the equigranular texture of the plutonic rocks in exercise 5-3. 3. Name the mineralogy of the glassy phenocryst in this “snowflake” obsidian, rock R50a. 46 GEOL 1107, Lab #5 4. Examine tuff samples A and B. Handle them with care, do not scratch or dig into the samples. Describe the sizes and shapes of the pyroclastic material in these samples. 5. Examine the vesicular lava in rocks samples C and D. Note the flow band especially in the lighter-coloured sample. Describe the appearance of the sample under magnification. 6. Examine ash samples E (Drinkwater) and F (Bridge River). Do you think these ash materials formed from cold, solid material shattered by an eruption or molten lava solidified as it was sprayed into the atmosphere? (Hint: Use the microscope to see more closely the texture of the two ash samples). 47 GEOL 1107, Lab #5 7. Examine the volcanic bomb, sample G. Sketch the general shape of the sample and briefly explain its origin. 8. Examine the lava samples, H and I. Observe the texture of the “aa” sample and compare it to the texture of the pahoehoe lava. Make sure you can distinguish between these two types of rock. 9. Using the rock identification chart (page 29) determine the rock type in samples H and I. EXERCISE 5 - 5: ROCK IDENTIFICATION Identify all the rocks in the box of igneous rocks. In this box there are both intrusive and extrusive rocks. Put your answers on the next page in the appropriate blank space. Answers should include a description of texture, different types of minerals, structures if any, and, for igneous intrusive rocks, the abundance of the minerals expressed as a percentage. 48 GEOL 1107, Lab #5 49 GEOL 1107, Lab #6 LABORATORY 6 SEDIMENTARY ROCK IDENTIFICATION INTRODUCTION TYPES OF SEDIMENTARY ROCK There are two types of sedimentary rocks: 1. clastic and 2. chemical. Each records different rock forming processes and environments. Clastic Sedimentary Rocks Clastic sedimentary rocks are derived from particles, pieces or clasts of minerals, rocks or organic matter that have been separated from their parent material by processes of chemical and physical weathering. Clasts are then eroded and transported by moving air, water, ice or gravity, during which they may undergo significant modification to their size and shape. Eventually all clasts are deposited when the energy of transport is lost or dissipated. Common examples of clastic sedimentary rocks include breccias, conglomerates, sandstones and mudstones. Chemical Sedimentary Rocks Chemical sedimentary rocks are precipitated from the products of chemical weathering reactions which produce dissolved atoms and molecules, mostly found in water. Minerals precipitate when either the temperature or volume of water drops, and dissolved atoms and molecules can no longer be kept in solution. The most common forms of chemical sedimentary rock are limestone, dolomite and the evaporites (i.e. salt, gypsum). Another common form of chemical sedimentary rocks are those produced by biogenic processes such as the metabolic activity of marine invertebrates (i.e. marine or freshwater mollusks that form hard calcite outer shells). The remains of biogenic shells accumulate, often as re-worked clasts to form important sedimentary rock deposits such as the limestone in carbonate reefs. Common biogenic chemical sedimentary rocks include almost all the limestones. Another form of chemical sedimentary rock, sometimes called an organic sedimentary rock, is coal. Coal is formed from the partially preserved remains of terrestrial or land plants (i.e. trees, grasses and sphagnum). 1 GEOL 1107, Lab #6 The processes responsible for the formation of clastic and chemical sedimentary rocks are: 1. Weathering. The process by which minerals, rocks and organic material are broken down into loose fragments or clasts or dissolved in water by physical or chemical processes. 2. Erosion. The loosening and subsequent removal of sediment from one place so it can be transported to another. This is how sediment is set in motion. 3. Transportation. How sediment moves from one place to another by moving air, water, and ice or by gravity. 4. Deposition. When moving sediment is dropped or otherwise placed back on the Earth’s surface when it can no longer be transported, usually because of a drop in the velocity of water and air, melting of the ice, or because falling sediment reaches the bottom of a slope and gravity no longer is able to move it. 5. Precipitation. When a solution, which in nature is most commonly water, becomes over or super-saturated with dissolved atoms and molecules. The water, because of a decrease in volume or temperature can no longer hold these atoms or molecules in solution and they combine to form a solid precipitate. 6. Lithification. The process by which loose, unconsolidated sediment is compressed or glued together to form a solid, coherent rock. The normal sequence of events in the formation of a sedimentary rock, from start to finish, is: 1. Weathering 2. Erosion 3. Transport 4. Deposition and / or precipitation 5. Lithification The best way to examine and classify sedimentary rocks is to take the same approach used when examining igneous rocks: examine their texture and composition. The first group of sedimentary rocks to look at is the clastic sedimentary rocks. 2 GEOL 1107, Lab #6 CLASTIC SEDIMENTARY ROCKS TEXTURE The texture of a clastic sedimentary rock is defined by the size of individual clasts, their shape - which includes roundness and sphericity - and how well sorted they are. These same features are used to identify a clastic sedimentary rock. Texture provides important clues as to the distance particles have been transported since weathering and erosion, what conditions they were transported under and finally in what kind of environment they were eventually deposited in. 1. Clast Size The size of grains, particles or clasts ranges from large blocks several meters in diameter to fine dust only a fraction of a millimeter in size. The size distribution of clasts is a good indication of energy levels (i.e. how fast was the water moving) during erosion, transport and deposition. A simple classification system based on clast size for clastic sedimentary sediment and the rocks that form from lithified sediment is describe here and summarized in figure 6 - 1. Coarse grained sedimentary rocks are those in which the average clast size is > 2 mm in diameter. This includes all the gravel-size material (granules, pebbles, cobbles and boulders). Rocks which contain clasts in this size category are called conglomerates (clasts are rounded) or breccias (clasts are angular) and sometimes rudites. They are normally deposited in high energy environments. Medium grained sedimentary rocks are those in which the average clast size is between 0.0625 mm to 2 mm diameter which is sand-size material. Rocks which contain clasts in this size category are called sandstones or arenites and normally accumulate in environments with moderate energy levels. Fine grained sedimentary rocks include those with an average clast size < 0.0625 mm in diameter which are the silt (0.002 mm to 0.0625 mm) and clay-size (< 0.002 mm) clasts. Rocks with an abundance of particles in this size category are called mudstones, shales, siltstones, claystones or, less commonly, a lutite. They suggest an environment of deposition characterized by very low levels of energy. 3 GEOL 1107, Lab #6 Figure 6 - 1. Size classification of clastic sediment and the type of common clastic sedimentary rock associated with each class. 2. Roundness Roundness refers to the smoothness of the surface of the clast. The roundness of a sedimentary clast is a product of, and a direct reflection of, the intensity and duration of abrasion that the clast has undergone during transport. For example, the surface of sand clast will become smooth or more rounded the longer or more intense the transport. Almost all sediment, when it is first weathered and eroded from its parent material, is angular, which means it has sharp, protruding edges. Sediment moved by ice or that falls because of gravity is more likely to remain angular because the intensity or duration of 4 GEOL 1107, Lab #6 transport is short. Particles carried by wind or water are more likely to be rounded because abrasion is more intense and longer lasting. The roundness of a particular clast may indicate some of its recent history. A large, angular boulder, for example, indicates the source area or parent material is nearby, perhaps in a nearby mountainous region. The source of the boulder should not be too far away because if the boulder was transported by stream action its sharp corners and rough surface probably would have been rapidly chipped away producing a much smoother, more rounded texture. Figure 6 - 2 illustrates typical examples of rounded and angular clasts. Very Angular Sub - Angular Sub - Rounded Well - Rounded Figure 6 - 2. Typically examples of rounded to angular clasts. 3. Sphericity Sphericity is a measure of how spherical a clast is. If a clast has a shape that is very much like a perfect sphere or ball then it is said to have a high sphericity. If a clast has an elongated, flat or linear shape, then it is very much different in overall shape from a perfect sphere and is said to have a low sphericity. Figure 6 - 3 illustrates typical examples of mineral clasts with high, medium and low sphericity. Like roundness, sphericity is also a good indicator of the processes a clast has gone through, especially their intensity and duration. A clast with a low sphericity will likely have spent only a short period of time in a lower energy environment. It will have been eroded, transported and deposited in something like a braided river setting not too far removed from its source area. On the other hand, a clast with a high sphericity has probably spent more time in a more intense environment of erosion, transport and deposition, such as a beach. 5 GEOL 1107, Lab #6 Low Sphericity Medium Sphericity High Sphericity Figure 6 - 3. Typical examples of mineral clasts with high, medium and low sphericity. 4. Sorting Sorting describes the range of clast sizes present in clastic sediment or a clastic sedimentary rock. Like the other textural features, sorting is a very important characteristic because it gives us clues as to the processes that are or have been at work. Very Well Sorted Well Sorted Moderately Sorted Poorly Sorted Figure 6 - 4. Very well to poorly sorted clastic sedimentary rock textures (Boggs, 1995, page 88). 6 GEOL 1107, Lab #6 Very well sorted and well sorted clastic sediment is composed of clasts made up of one or two dominant sizes as well as, typically, only one type of mineral or rock composition (Figure 6 - 4). This type of clastic sediment reflects conditions of intense and/or prolonged sediment transport during which the different clast size and compositions have been effectively sorted into distinctly different deposits. Well sorted sediment may accumulate in a large fast flowing river or in desert where enough energy persists – moving water, moving air – to cause significant work to be done to the sediment leaving it far from its original source. The difference between very well sorted and well sorted sediment is the degree of intensity and duration of the energy in the environment. Very well sorted sediment is often found in a beach where wave, tides and currents never stop, and sediment is constantly being reworked. Poorly sorted clastic sediment is composed of grains of many different sizes, fine to coarse, and that also have a mixed composition of mineral and rock types (Figure 64). This type of clastic sediment reflects conditions of weak, intermittent or short-term sediment transport during which there is little time or energy for clast sorting. A poorly sorted clastic sediment may be deposited by glacial ice, a braided river or by a gravity flow. In all three depositional settings sediment transport is of short duration and subjected to relatively weak energy of movement. They may typically occur close to the sediment source area. Moderately sorted clastic sediment is transitional between well and poorly sorted sediment. Compaction and Cementation This is what happens to sediment after it has been deposited. Compaction is a reduction in the size of a deposit of sediment, usually as a result of a reduction in the void space between individual clasts, because of the weight of overlying material. Compaction of sediment occurs as it is buried by and subjected to the weight of overlying sediments. Pressure builds up inside the sediment and water and air are squeezed out of the loose sediment. Mineral clasts inside a deposit that are subjected to intense, long-term pressure may be bent or broken and then become sutured or joined together to form a solid, cohesive rock. Compaction is especially prevalent in carbonate sediments that are relatively soft and prone to distortion. Quartz sand, on the other hand, is not as readily compacted because of the resistance of quartz minerals to changes due to pressure. 7 GEOL 1107, Lab #6 Cementation is the process by which mineral clasts or shell fragments are bound together by minerals precipitated from water in the pore spaces between clasts. At the contacts between clasts there may be partial dissolution of minerals because of pressure. Dissolved minerals may migrate into adjacent void spaces between clasts where precipitation of a “new” secondary mineral may take place. This cementation of clasts by a secondary mineral helps to bind the sediments together to form a solid rock. By the processes of compaction and cementation unconsolidated sediment is converted to rock. This is known as lithification. COMPOSITION The vast majority of clasts in a clastic sedimentary rock are composed of only a few different mineral types, all of which you’ve seen in previous labs. The most common mineral types are: Quartz Plagioclase feldspar Potassium feldspar Muscovite Biotite Clay minerals such as kaolinite Iron oxides such as magnetite and hematite Other less common constituents of a clastic sedimentary rock may include lithic clasts which are fragments or pieces of rock. Remember a rock is an aggregate of one or more minerals. These may include clasts of basalt, sandstone, dacite, mudstone, syenite or limestone. Biogenic clasts may also constitute a significant part of a clastic sedimentary rock (Figure 6 - 5). These are organic fragments such as calcite shell fragments and organic plant remains. 8 GEOL 1107, Lab #6 Figure 6 - 5. Biogenic clasts, in the form of shell fragments, make up this entire fossiliferous limestone, a form of chemical sedimentary rock. Mafic minerals are relatively rare in sediment because these iron-bearing minerals are more prone to weathering, especially oxidation, and disappear relatively fast from sediment deposits depending upon conditions. Maturity of a clastic sedimentary rock Maturity is a term used to describe the sediment in a clastic rock and the work that has been done to it. It also is used to describe the stability of the sediment. If a clastic sedimentary rock is mature, it means that a significant amount of work has been done to it and that it is more stable. A less mature clastic sedimentary rock is one that has had less work done to it and is less stable. The amount of work that is done is reflected by the texture and composition of the clasts in the rock. This work is done by moving water (i.e. river), moving air (wind), moving ice (i.e. glacier) or gravity (i.e. avalanche). Stability is a measure of how prone the sediment is to further change caused by more work. Specific factors that determine the maturity of sediment and the clastic sedimentary rock that eventually forms include: 9 GEOL 1107, Lab #6 1. Type, duration and intensity of physical and chemical weathering affecting the sediment 2. How the sediment was eroded or set in motion 3. Method, duration and intensity of sediment transport 4. Mode of deposition. For example, a pile of sediment that has been transported many kilometers in a fast-flowing river will be well sorted. Individual clasts will be small, well rounded, spherical and probably composed of only a very few, resistant mineralogies such as quartz. If these sediments are deposited on a riverbank during a flood and then exposed to intense physical and chemical weathering, as might happen in a hot, humid climate, then they will undergo even more alteration with the resulting loss of any remaining, immature or unstable mineral clasts. The end result is a very mature or very stable sedimentary deposit that is not likely to be further altered during any further reworking. On the other hand, if a pile of sediment is not transported very far from its source, then the clasts are likely to be on average large, poorly sorted, more angular, less spherical and probably composed of a variety of different stable and unstable mineralogies. If this sediment is deposited and rapidly buried by another depositional event, then it may be effectively removed from the effects of further physical and chemical weathering. The end product is an immature sediment that eventually becomes an immature sedimentary rock. Therefore, the maturity of a sediment deposit or sedimentary rock is measured by its clast size, sphericity, roundness, sorting and mineral composition. Maturity may also be broken down into two types, chemical maturity and physical maturity. Chemical maturity is determined by the mineralogy of sediment or sedimentary rock. If a rock is chemically mature then it contains a majority of clasts that are composed of stable minerals, such as quartz and kaolinite. Quartz is the most stable of all silicate minerals. Ferromagnesian or mafic minerals, on the other hand, are the least stable and normally weather quickly to a more stable secondary mineral such as an iron oxide like hematite. Physical maturity is determined by the texture of a sediment or the clasts in a sedimentary rock. If a rock is physically mature, then it has undergone considerable sorting and abrasion during transport and deposition. Individual clasts are smaller, well rounded, spherical and the whole deposit is well sorted. 10 GEOL 1107, Lab #6 The concept of maturity applies mostly to clastic sedimentary rocks as they are the only class of sedimentary rock that routinely exhibits significant changes in texture and composition. Breccias and conglomerates are considered immature. Mudstones, siltstones and claystones are considered mature. Sandstones are found somewhere in between. The concept of maturity is not normally applied to chemical sedimentary rocks such as limestone and dolomite because they frequently form by other processes such as when minerals precipitate or are produced biologically. CHEMICAL SEDIMENTARY ROCKS TEXTURE The most common chemical sedimentary rocks are the carbonates, which include limestone and dolomite. The texture of a chemical sedimentary rock is defined by the size and type of the pieces that make up the rock, either clasts or crystals. The key to understanding the texture of chemical sedimentary rocks is to know that clasts and crystals come from two different sources. Clasts may have first been precipitated and then eroded, transported and deposited to form a deposit. A very common source of these ‘reworked’ chemical sedimentary rock clasts are calcium carbonate body parts of marine organisms or, what are regularly referred to as shell fragments. When shell fragments are included in a chemical sedimentary rock it is often described as having a ‘fossiliferous texture’. Crystals form when minerals are precipitated, which often takes place in the same environment where they are deposited. These crystals are ‘not reworked’. Chemical sedimentary rocks include precipitates of halite or gypsum. The inclusion of clasts or crystals in a chemical sedimentary rock results in two common chemical sedimentary rock textures. Fossiliferous Texture Fossiliferous texture is a form of clastic texture in chemical sedimentary rocks. It is the result of the accumulation of skeletal parts (i.e. shell fragments) of invertebrate life forms, usually those found in marine environments (Figure 6 - 6). Hard, internal and external calcium carbonate skeletal body parts are formed by many organisms which remove calcium and carbonate from fresh or seawater and process it as part of their regular metabolism. When these organisms die, these hard body parts remain and may be concentrated as fragments in a depositional environment such as beach, lake, ocean bottom or reef. As lithification takes place, the texture of the resulting rock takes on many of the characteristics of the skeletal fragments. For example, a layer of mollusk shell remains that becomes cemented together by secondary carbonate precipitates will become a solid, cohesive carbonate rock with a fossiliferous texture. Similarly, a coral reef is nothing more 11 GEOL 1107, Lab #6 than the remains of many carbonate secreting marine organisms preserved on the sea floor, often in the positions in which they grew. Fossil Shell Fragment Scale is in centimeters Figure 6 - 6. Fossiliferous texture of a carbonate rock. This example contains the partial remains is of shell fragments. Crystalline Texture Crystalline texture refers to those rocks composed of interlocking mineral crystals. These crystals have grown in place as the newly forming mineral precipitated from atoms or molecule dissolved in water. Limestone that precipitates in a hot desert lake environment or in a cave in the form of a stalactite or a stalagmite has a crystalline texture. Halite or salt precipitates to form a chemical sedimentary rock with a crystalline texture. The texture of a crystalline chemical sedimentary rock is similar to an igneous rock. 12 GEOL 1107, Lab #6 The average size of the crystals in a chemical sedimentary rock is a useful guide to further, rock classification. Four class sizes are commonly used to help identify these rocks. Coarse crystalline > 2mm Medium crystalline 0.0625 to 2 mm Fine or microcrystalline 0.002 to 0.0625 mm Cryptocrystalline < 0.002 mm Note that these are the same size classes used for clastic sedimentary rocks. COMPOSITION There are only five different types of mineral or organic material that make up the common chemical sedimentary rocks. These are used to help classify and explain the mode of formation of this type of rock. 1. Carbonates Carbonate rocks are those that contain 50% or more carbonate minerals (calcite, dolomite and travertine). These are the most abundant of all the chemical sedimentary rocks. They are composed of newly formed mineral precipitates and the remains of fossilized biogenic carbonate remains, so their formation is closely linked to the life cycles of marine and freshwater organisms. Remember there are many aquatic organisms able to extract dissolved calcium and carbonate from water to form protective shells or skeletons. When these organisms die their hard body parts accumulate as sediment which later may be cemented together to form a solid rock. Carbonate rocks, therefore, are often rich in fossils which provide valuable information on the type of environment where the organism lived and, after its death, how and where its remains were deposited and preserved. For example, a carbonate reef encased in microcrystalline limestone suggests that at some time in the past there was a warm, shallow marine environment (necessary for reef formation) probably followed by a rise in sea-level that resulted in deeper water conditions (necessary for microcrystalline limestone formation). 2. Evaporites Evaporites are chemical sedimentary rocks composed of minerals that precipitated out of solution (i.e. water) because of either a drop in temperature or a reduction in the volume of 13 GEOL 1107, Lab #6 solution. There is no biological process affecting precipitation. The most common evaporite minerals are halite (NaCl), sylvite (KCl), gypsum (CaSO4 - 2H2O), and anhydrite (CaSO4) which precipitate from water in hot, arid climates where temperatures are high and evaporation of water exceeds input from rain or rivers. Evaporite formation is further enhanced when water circulation is inhibited, such as in a closed lake basin, and the concentration of dissolved minerals is allowed to increase. 3. Siliceous Rocks Siliceous rocks are composed mainly of microcrystalline quartz (SiO2) which forms when silica dissolved in water precipitates. Siliceous rocks include chert, flint, jasper, agate and opal. Chert or microcrystalline quartz is the only one of these siliceous rocks we’ll see in this course. Siliceous chemical sedimentary rocks may be either inorganic or biochemical in origin. For example, some cherts are precipitated from seawater under certain conditions, others are derived from the accumulation of siliceous hard body parts produced by silica secreting, unicellular organisms such as diatoms and radiolarians which are abundant in the world’s oceans. These organisms, like many modern carbonate secreting organisms produce silica as part of their normal metabolic activities. 4. Ironstone Ironstones are a group of precipitated chemical sedimentary rocks that are rich in the ironbearing minerals hematite, magnetite and limonite (Figure 6 - 7). Ironstones form at the Earth’s surface in unique depositional environments where precipitation can take place. They were a common type of rock formation in the distant past (> 2 billion years ago) when it is believed the Earth had a much different atmosphere (lower oxygen content) and life forms were less common, much simpler and less diverse than they are now and iron precipitation on a vast scale could take place. 14 GEOL 1107, Lab #6 Scale is in centimeters Figure 6 - 7. Ironstone, a chemical sedimentary rock 5. Organic Rocks Organic rocks are not rocks in the strictest sense because they are composed mostly of organic material and not minerals. These rocks form in certain special environments in which either the rate of accumulation of organic material is very high, or the environment is such that the rate of decomposition of organic matter is very low. Environments where organic rocks form include swamps, marshes or stagnant lagoons where there is abundant vegetation to supply organic material and water that’s low in dissolved oxygen so that preservation potential is high. Common organic rocks include peat (Figure 6 - 8) and coal (Figure 6 - 9) which are derived from terrestrial plant remains. Peat is the precursor to coal which means that from a deposit of terrestrial plants, first peat forms then coal. Peat forms when organic material is buried and preserved near the Earth’s surface. Coal forms because of intense long-term heat and pressure after peat is buried deeper inside the Earth. Hydrocarbons such as oil and natural gas are formed from the partially preserved remains of marine animals and plants. The most common source of hydrocarbons is the remains of marine algae, a single-cell photosynthetic plant that thrives in the world’s oceans. Hydrocarbons are not formed into distinct rock bodies. Normally the organic material that forms oil and gas is deposited with very fine grain clastic sediment such as clay and silt that eventually become a mudstone or shale. Black shales are a major source of oil and gas. The black colour of these rocks is because of their high organic matter content. 15 GEOL 1107, Lab #6 Scale is in centimeters Figure 6 - 8. Peat, an organic sedimentary rock Scale is in centimeters Figure 6 - 9. Coal, an organic sedimentary rock 16 GEOL 1107, Lab #6 SEDIMENTARY ROCK IDENTIFICATION Sedimentary rock identification is based on the recognition of clastic, chemical and organic types. Table 6 – 1 on page 26 summarizes all the common sedimentary rocks and their characteristics. CLASTIC SEDIMENTARY ROCK IDENTIFICATION Clastic sedimentary rocks are identified according to their texture. When identifying a clastic sedimentary rock, the first thing to do is recognize that the rock is made up of clasts or rock fragments that are all stuck together. Once you see this kind of clastic or fragmental texture you know you have a clastic sedimentary rock. The next step is determining the average or most common clast size. There is no need to count clasts, a simple approximation will do. Once you have the average clast size go to figure 6 - 1, page 4 to see what kind of clastic sedimentary rocks have this average clast size. For example, if your rock sample is made up mostly of clasts between 3 and 5 mm in size then you know the sediment is gravel and the rock is either a breccia (Figure 6 - 10) or a conglomerate (Figure 6 - 11). Scale is in centimeters Figure 6 - 10. Breccia, a clastic sedimentary rock. The large clasts are angular. 17 GEOL 1107, Lab #6 Scale is in centimeters Figure 6 - 11. Conglomerate, a clastic sedimentary rock. The large clasts are rounded. Now that clast size has been determined the next step is to look at other texture features and the composition of the clasts. If the clasts are gravel size (> 2 mm) then the rock is either a breccia or a conglomerate like the examples in the previous two photographs. The difference between a breccias and a conglomerate is that in a breccia the gravel-size clasts are angular while in a conglomerate the gravel-size clasts are rounded (Table 6 - 1). What if the average clast size is 1 mm? Then the rock is a sandstone where clast size is between 2 mm and 0.0625 mm. In Table 6 - 1 there are four different sandstones. Each sandstone has a unique mineralogy that give it a distinct colour. For example, the rock in figure 6 - 12 is a clastic sedimentary rock. We can see on close inspection that it’s made up of compacted clasts (Figure 6 - 13). What’s more the clasts are all about 1 mm in size and they are reddish pink in colour. Arkosic sandstone or arkose is commonly red, orange and pink because of the high concentration of potassium feldspar clasts in this rock. Therefore the rock in figure 6 - 12 and 6 - 13 is an arkosic sandstone. The colours and mineralogies of the four sandstones are summarized in table 6 - 1. What if the clasts in a rock sample are really hard to see? What if the average clast size is less than 0.0625 mm? The clastic sedimentary rocks with silt and clay-size clasts are mudstone, shale, siltstone and claystone. It’s difficult to distinguish a mudstone from a siltstone from a claystone. For this course we will only ask you to identify a mudstone and not a siltstone or a claystone. Here’s the reason for this. A mudstone is composed of both silt and clay-size clasts. It’s possible to identify silt-size clasts (0.002 to 0.0625 mm in size) 18 GEOL 1107, Lab #6 Scale is in centimeters Figure 6 - 12. Arkosic sandstone, a clastic sedimentary rock. Scale bar is 1cm Figure 6 - 13. Close up of sand-size clasts in an arkosic sandstone. 19 GEOL 1107, Lab #6 with the unaided eye, so it’s possible to identify a mudstone. It’s impossible to identify clay-size clasts (< 0.002 mm) with the unaided eye, so it’s impossible to identify a claystone. So, to ease identification we combine silt and clay-size clasts together call it mud and focus on mudstone. A shale is a layered mudstone (Figure 6 - 14). It may have internal layers, or a rock sample may be shaped in such a way that it looks like it was once part of a layer. So, shale, along with mudstone, are the two common fine grained clastic sedimentary rocks you need to be able to identify for this course. Scale is in centimeters Figure 6 - 14. Shale, a layered clastic sedimentary rock made up of fine, silt and clay-size clasts To summarize, how do you identify a mudstone and a shale? Both are composed of silt and clay-size clasts. A mudstone is not layered, it has instead a massive structure. A shale is layered. 20 GEOL 1107, Lab #6 CHEMICAL SEDIMENTARY ROCK IDENTIFICATION Chemical sedimentary rock classification is a matter of mineral recognition. The dominant mineral type in the rock dictates what type of rock it is. The rock in figure 6 - 15 is gray in colour and reacts in solid form to 10% hydrochloric acid. It does not have to be ground up into a powder for this reaction to take place. Therefore, this rock is made up of the mineral calcite. Looking at the short list of common chemical sedimentary rocks in table 6 - 1 the rock is a limestone. There are only two types of organic sedimentary rock to look at in this lab, peat and coal, and the difference between them is colour and density. Scale is in centimeters Figure 6 - 15. Limestone, a chemical sedimentary rock. The rock in figure 6 -15 is dark gray, a colour not usually associated with the mineral calcite. However, it is still a limestone because it reacts with HCl. Colour does not matter. It maybe this limestone is dark gray because of impurities, such as organic material, that were included when it formed. 21 GEOL 1107, Lab #6 EXERCISE 6 - 1. THE FEATURES USED TO IDENTIFY A SEDIMENTARY ROCK Examine the sedimentary rocks provided in the lab and answer the following questions. 1. Compare the texture of a coarse crystalline igneous rock, R28, to a clastic sedimentary rock, R16c. Make sure you can recognize and understand the differences between these fundamentally different rock types, especially their different textures. 2. Examine samples R66, R65a, R3a, and R16c. What do all four of these rocks have in common? What is different about all four of these rocks? Note differences with respect to mineralogy and size of grains or clasts, sorting, roundness and sphericity of grains. Arrange them in order of relative maturity and assign names to each rock. Comment on the relative maturity of each rock. 3. Examine samples R12, R40a, and 69. What fundamental aspect of classification do these three samples have in common? Name each rock. (Hint: Because you cannot see the individual mineral grains in each sample, you probably cannot identify the constituents by sight alone. Therefore, you will have to test for properties in order to identify the minerals in the rocks. Remember your scratch test, acid test, streak test, etc). 22 GEOL 1107, Lab #6 4. Name sample R17. Can you identify any of the rock types that make up the pebble-size clasts? What kind of material forms the matrix between the pebble clasts? 5. Name sample R13. List 3 or 4 physical properties that distinguish this rock from the rock obsidian. Aside from general appearance, what fundamental aspect do sample R13 and obsidian have in common? 6. Name samples R13, #73, and R16a. Each of these samples is of very great economic importance. What is each used for? 7. Examine sample R19. What are the clasts and matrix made of? Where might this rock have formed? 23 GEOL 1107, Lab #6 8. Examine and describe sample R76 (please do not scratch the material). Is this rock clastic or chemical? What is the grain or crystal size? What is its relative maturity? Why is this particular rock black in color? What does the presence of black material and the texture of the rock suggest about its environment of deposition? Was this depositional setting characterized by still or moving water? EXERCISE 6 - 2: SEDIMENTARY ROCK IDENTIFICATION Using table 6 - 1, pages 126 to 129, identify all the samples in the box of sedimentary rocks. In this box there are clastic, chemical and organic rock types. Put your answers on the next page in the appropriate blank spaces. Answers should include a description of mineralogy, texture, structure presence or absence of fossil or other biogenic material. 24 R13 R66/R66a GEOL 1107, Lab #6 25 GEOL 1107, Lab #6 Table 6 - 1. Common Sedimentary Rocks Part A. Clastic Sedimentary Rocks Name Average or dominant grain size Color Grains or Clasts Coarse Grain Clastic Rocks (Avg. grain size > 2 mm) Breccia Coarse grain size, greater than 2 mm Varies. Usually many different colors. Conglomerate Coarse grain size, greater than 2 mm Varies. Usually many different colors. Angular clasts. Potentially many different grain sizes, including large and small (pebbles, cobbles and boulders), in a finer grain matrix Rounded clasts. Potentially many different grain sizes, including large and small (pebbles, cobbles and boulders), in a finer grain matrix. Medium Grain Clastic Rocks – Sandstones (Avg. grain size 0.062 mm – 2 mm) Quartz Sandstone Arkosic Sandstone Grain size between 0.062 and 2 mm. White > 90% quartz grains, most often spherical but difficult to see due to small size. Grain size between 0.062 and 2 mm. Red, orange, light pink to white Abundant quartz and at least 25% K – feldspar 26 Very Mature Mature GEOL 1107, Lab #6 Name Lithic Sandstone Graywacke Average or dominant grain size Color Grains or Clasts Grain size between 0.062 and 2 mm. Usually medium to dark gray, brown or green. Frequently varies in color. A mix of quartz, feldspar and other rock fragments. Rock fragments are in greater abundance than feldspar. < 15% silt and clay matrix. Commonly between 0.062 and 2 mm, with significant finer grained matrix. Usually dark gray, may be black, brown or green. Frequently varies in color. A mix of quartz, feldspar and other rock fragments. > 15% silt and clay matrix. Fine Grain Clastic Rocks (Avg. grain size < 0.062 mm) Mudstone Grain size less than 0.062 mm Variable. Frequently medium to dark gray or black. Sometimes brown or green. Massive or nonlaminated structure. Silt-size quartz, with fewer feldspar grains. Abundant clay-size, clay mineral grains. Shale Grain size less than 0.062 mm Variable. Frequently medium to dark gray or black. Sometimes brown or green. Thin bedded or laminated structure. Silt-size quartz, with fewer feldspar grains. Abundant clay-size, clay mineral grains. Different size particles may be concentrated in different laminations. 27 Immature Very Immature GEOL 1107, Lab #6 Name Average or dominant grain size Siltstone Grain size between 0.002 and 0.062 mm Claystone Grain size less than 0.002 mm Color Typically white to light brown, gray or red. Sometimes medium to dark gray. Commonly medium to dark gray or black. Frequently brown or green. Grains or Clasts Massive or, less commonly with a laminated structure. Predominantly siltsize quartz, with fewer feldspar grains. Lesser amounts of clay-size mineral grains Commonly has thin bedded or laminated structure. Sometimes massive in structure. Abundant clay-size, clay mineral grains. Part B. Chemical and Organic Sedimentary Rocks Name Limestones, including fossiliferous limestone Dolomite Color Constituents, Components, Properties Commonly white. May also be red, black, brown or gray depending upon the type of impurities. Microcrystalline or coarse crystalline calcite (CaCO3) matrix that may contain recognizable fossil remains or other carbonate fragments. Readily reacts with 10% HCl. May exhibit diagnostic features of the mineral calcite. Commonly white. May also be red, black, brown or gray depending upon the type of impurities. Microcrystalline or coarse crystalline dolomite (CaMg)(CO3)2. Does not normally contain fossil fragments. Does not react with 10% HCl unless powdered. May exhibit diagnostic features of the mineral dolomite. 28 GEOL 1107, Lab #6 Part B. Chemical and Organic Sedimentary Rocks (continued) SEE THE MINERAL IDENTIFICATION TABLES 4 - 1 AND 4 - 2 FOR MORE DETAILS Name Chert Ironstone Gypsum Salt or Halite Peat and Coal Color Highly variable. Individual samples may exhibit a wide variety of colors, shades and brilliance. Usually red, black, yellow or a mix of all three colors. White, gray, yellowish, pink to brown. Frequently colorless, but may be white, pale yellow, red, brown or black depending upon impurities. Dark brown to black Constituents, Components, Properties Composed almost entirely of the minerals micro-crystalline quartz (SiO2) or opal (SiO2 . nH2O). Therefore exhibits many of the diagnostic features of these minerals, in particular conchoidal fracture. May also have banded or layered structure. Composed of the iron-bearing minerals hematite, magnetite, and/or limonite, with less amounts of chert. Exhibits features typical of these minerals. Very hard. May be magnetic. Also may have iron oxide or “rusty” coating on outer surface due to weathering and alteration. Compact waxy-looking masses or fibrous aggregates of elongated crystals. Vitreous luster. May appear as large individual crystals, dense clusters of well formed crystals or microcrystalline crusts or coatings. Vitreous luster. Dissolves readily in water. Distinctive “salty” taste. Composed of organic plant remains in various stages of preservation. Peat has a dull luster, low density and is relatively easy to separate. Coal is harder, more dense and, as is the case with more altered “higher rank” coals, may have a vitreous to glassy luster. Both peat and coal may be banded or layered with an uneven fracture. 29 GEOL 1107, Lab #7 LABORATORY 7 METAMORPHIC ROCK IDENTIFICATION INTRODUCTION Metamorphic rocks form when a pre-existing igneous or sedimentary rock is subjected to heat and pressure. The result is a new type of rock that has undergone some degree of solid-state alteration, which means new textures and structures form from the older parent rock without significant melting. While metamorphic rocks may be significantly different from their parent material, they frequently retain features of the original igneous or sedimentary rock. Recognition of new and inherited features is an important consideration when it comes to metamorphic rock identification. Heat and pressure producing metamorphic alteration is normally the result of burial within the Earth, to depths on the order of several tens of kilometers, or because of close proximity to active volcanic regions. Based on the relative intensity of heat and pressure, there are three basic types of metamorphic environment: 1. Regional metamorphism, 2. Contact metamorphism, 3. Dynamic metamorphism Regional Metamorphism Regional metamorphism is characterized by high heat and high pressure. Typically, these types of conditions are found deep inside the Earth such as at depth along an active tectonic plate margin where plates are pushing against one another, and one plate is being subducted into the Earth’s hot interior. Regional metamorphism results in intense, widespread alteration and produces specific types of metamorphic rock, such as a schist or gneiss, recognizable by their foliated or layered texture. Contact Metamorphism Contact metamorphism is characterized by increased heat with only slightly elevated pressure. Contact metamorphism is found in areas of active 1 GEOL 1107, Lab #7 volcanism (lava is extruded onto or near the Earth’s surface) or plutonism (magma is intruded into the Earth’s crust) where melted rock acts as a ready source of heat. It’s also found along fractures or faults where the rock is in contact with hot liquids or gases. In all these areas pressure is relatively low because the depth beneath the surface is less and there is normally no large scale tectonic plate motion. The intensity of contact metamorphism is greatest at the contact between country rock and magma or lava, and decreases rapidly with distance from the magma. Thus, zones of contact metamorphism, known as “aureoles” or “baked zones”, are relatively narrow. Contact metamorphism results in intense, but very localized alteration producing specific types of non-foliated or non-layered metamorphic rocks such as an amphibolite or a skarn. Dynamic Metamorphism Dynamic metamorphism is the result of increased pressure with only a minor amount of extra heat. Dynamic metamorphism may be found along an active plate margin such as a transform boundary where two plates are trying to get past one another but there is no subduction and very little in the way of extra heat flow. The dominant force is extra pressure or stress that acts to rearrange minerals such that distinctive new metamorphic layering or foliations are formed. Physical and chemical changes to a rock Metamorphic rocks are altered without significant melting of parent material. However, there is still important new mineral formation as original igneous crystals and sedimentary clasts reform. Common trends associated with changing mineralogy include the loss of some of the less stable minerals (i.e. some types of feldspar) and the chemical recombination of old minerals leading to the formation of new minerals (i.e. kyanite and sillimanite). Typical textural changes include deformation and rotation of mineral grains, the growth of larger crystals, often by the combination of crystals of the same mineralogy, formation of layers or foliations that vary in thickness and continuity, concentration of minerals in foliations, and in some instances the loss of structure such as original sedimentary bedding or layers. The net result of metamorphism upon a rock is larger crystals, increased hardness, and new structural features that record the effects of heat, pressure and stress in one or more directions. 2 GEOL 1107, Lab #7 TEXTURE Texture in metamorphic rock is a measure of both clast or crystal size and orientation. Metamorphic rocks are classified as either foliated (layered) or non-foliated (non-layered). FOLIATED TEXTURE A foliated texture results from recrystallization and the growth of existing or new minerals and their re-alignment in such a way that a layered rock is produced. Normally a foliated texture is the result of stress. A rock is subjected to unequal forces of stress such as tensional (pulling apart), compressional (pushing together) or shearing (pushing past one another in a side-by-side motion) which results in the preferential alignment of clasts or crystals. There are four types of foliated texture: slatey, phyllitic, schistose and gneissic. These four textures form a continuum of products that reflect increasing alteration due to more intense or prolonged heat and pressure. 3 GEOL 1107, Lab #7 1. Slatey texture is the lowest grade of foliated texture, it forms at the lowest heat and pressure. It forms in fine-grained sedimentary rocks with thin bedding planes (i.e. shale) that are less altered by metamorphic processes. Under these so-called low grade metamorphic conditions, minerals are only slightly re-aligned in a preferred direction and the formation of new minerals is limited to a relatively few, very fine-grained platy minerals such as muscovite and chlorite. A rock with a slatey texture has the same very finegrained texture as the original shale or mudstone parent material (Figure 7 - 1). A slatey texture is not that much different from the original thinly bedded sedimentary structure of the shale parent material. Its appearance is similar to bedding in the shale except that it may be slightly easier to see. Scale is in centimeters Figure 7 - 1. The slatey texture of a foliated metamorphic rock 4 GEOL 1107, Lab #7 2. Phyllitic texture forms from a slatey texture as metamorphic alteration continues. This texture is characterized by better defined, more continuous foliations or layers of fine grained, occasionally medium grained, platy minerals, the most common of which are muscovite and biotite (Figure 7- 2 and 7 - 3). Foliations may be flat and parallel or folded. The formation and concentration of platy minerals along the flat surfaces of foliations and their preferred orientation imparts a shiny to metallic luster to the rock surface. Scale is in centimeters Figure 7 - 2. The phyllitic texture of a foliated metamorphic rock 5 GEOL 1107, Lab #7 Scale is in centimeters Figure 7 - 3. The phyllitic texture of a foliated metamorphic rock 6 GEOL 1107, Lab #7 3. Schistose texture forms next from a phyllitic texture as heat and pressure increase and metamorphic alteration continues. Schistose textures are characterized by moderately well defined, relatively thin (< 5 mm), typically continuous to discontinuous foliations composed of medium to coarse grained minerals, mainly consisting of platy muscovite and biotite and more irregular or randomly shaped quartz crystals (Figure 7 - 4). The texture of these rocks is characterized by pronounced segregation of different mineral types. For example, in a schistose rock you may see evidence of foliations containing a high concentration of biotite (therefore black in colour) next to foliations composed almost entirely of quartz or plagioclase feldspar (white in colour). However, mineral segregation is usually just developing and foliations of one mineral type are relatively thin and discontinuous. A schistose texture is the product of an intermediate or higher grade of metamorphism, meaning there was more heat and pressure for a longer period of time. Scale is in centimeters Figure 7 - 4. The schistose texture of a foliated metamorphic rock 7 GEOL 1107, Lab #7 4. Gneissic texture forms from a schistose texture. A gneissic texture is characterized by well defined, thick (> 5 mm, up to several centimeters thick) continuous foliations, or in this case “bands” composed of well segregated, coarse crystalline minerals. Bands typically have well defined, “sharp” contacts or boundaries, an important distinction between schistose and gneissic textures (Figure 7 - 5). The composition of a gneissic rock may be relatively simple, in that it is a highly altered or metamorphosed rock in which only few, more stable minerals (i.e. biotite, quartz, some feldspars) have survived heat and pressure. Those mineral crystals that do survive also tend to be large in size as they have grown at the expense of the less stable varieties. Gneissic rocks may also be characterized by the appearance of newly formed secondary crystals such as garnet, staurolite, biotite and kyanite, up to several centimeters in size. The growth of crystals in a gneiss may lead to a different texture where, instead of thick foliations, there are large crystals in a massive structure. In this case the crystals have grown so big that they are thicker than the foliations (Figure 7 - 6). Scale is in centimeters Figure 7 - 5. The gneissic texture of a foliated metamorphic rock with well defined foliations or layers. 8 GEOL 1107, Lab #7 Scale is in centimeters Figure 7 - 6. The gneissic texture of a foliated metamorphic rock with a more massive structure where the growth of large crystals has obscured the foliations or layers Lineations are another form of metamorphic structure. They are poorly defined layers or foliation-like structures that form not because of new mineral growth or mineral segregation but because pre-existing features in the rock have been altered and preserved. For example, pebbles and sand grains in a sedimentary rock were originally spherical. During metamorphic alteration they may have been stretched by the stress acting on the rock. The end result is a series of elongated grains, all aligned in one direction that imparts a layered or lineated structure to the rock. Stretched pebbles are common in some altered conglomerates or metaconglomerates. Deformation of a limestone will often result in the preferred alignment of organic material with the result that the altered rock now has lineations. While lineations are not true foliations, like foliations, they give metamorphic rocks a layered or foliated appearance. 9 GEOL 1107, Lab #7 NON-FOLIATED TEXTURE A non-foliated texture develops when original minerals are recrystallized and new minerals form in such a manner that no new layers can form and pre-existing ones are obliterated. Growth of new minerals or the enlargement of old ones occurs in all directions to form an interlocking crystalline structure. For example, a quartz sandstone with well-defined bedding planes, when subjected to heat and pressure normally loses its original sedimentary structure as some minerals are lost and the more stable quartz grains are compacted closer together. While non-foliated metamorphic rocks normally do not contain parallel planes of minerals, they may contain stretched or elongated fossils or other grains, like the lineations described in the previous paragraph, that formed in response to metamorphic stresses with the result that the rock has layered-like appearance. OTHER TEXTURES Porphyroblastic Texture Some metamorphic rocks contain large crystals (porphyroblasts) set in a finer grained groundmass (Figure 7 - 7). This porphyroblastic texture is similar to the porphyritic texture of igneous extrusive rocks. It may be present in foliated or non-foliated metamorphic rocks. Often the porphyroblasts or large crystals are garnets or magnetite. Garnet Crystals Figure 7 - 7. Porphyroblastic texture in a metamorphic rock with large garnet crystals. 10 GEOL 1107, Lab #7 Granoblastic Texture Metamorphic rocks that are equigranular, meaning they are made up of mineral grains that are all one size, have a granoblastic texture. This texture may be characteristic of both foliated and non-foliated rocks and includes slates and phyllites (foliated rocks) as well as marbles and quartzites (nonfoliated rocks). COMPOSITION In general, metamorphic rocks are made up of some of the common minerals also found in igneous and sedimentary rocks and a few minerals exclusive to metamorphic rocks. The most common metamorphic minerals are: quartz plagioclase feldspar potassium feldspar muscovite olivine hornblende biotite galena pyrite chalcopyrite calcite dolomite magnetite chert These minerals are also found in igneous and sedimentary rocks 11 GEOL 1107, Lab #7 Additional minerals exclusive to metamorphic rocks are: chlorite garnet kyanite staurolite epidote serpentine METAMORPHIC ROCK IDENTIFICATION The different types of common metamorphic rocks, with their features, are summarized in Table 7 - 1 beginning on page 15. Metamorphic rocks are divided into two categories: foliated and non-foliated. Once you’re familiar with these types of rock the first step in metamorphic rock identification is to determine if the rock is foliated or non-foliated. IDENTIFYING FOLIATED METAMORPHIC ROCKS The first question is “Does this rock have foliations or not?” If the rock does have foliations, then you have four choices from which to select a name. They are slate, phyllite, schist or gneiss. Based on what you see in a rock needing identification and the images and descriptions for each rock type in this lab, select the name that best fits the sample. Take for example the rock in figure 7 - 9. It has foliations. There are numerous thick, continuous foliations made up of coarse or large crystals with sharp, well defined contacts between foliations. The rock in figure 7 - 9 is a gneiss. Note that there is no requirement to identify the minerals in the rock. It’s useful to know what the mineralogy of the rock is, and sometimes the names of the most common mineral or minerals is included in the name, but it’s not necessary. For example, the rock in figure 7 - 9 could be called a potassium feldspar gneiss asthis is its most common mineral. The rock in figure 7 - 10 is also a foliated metamorphic rock. It has very thin foliations and none of the mineral crystals or clasts are visible. This rock also has a polished sheen or luster. It is therefore a phyllite. If the flat surface of the rock was dull, then it would be a slate. 12 GEOL 1107, Lab #7 Scale is in centimeters Figure 7- 9. Potassium feldspar gneiss Scale is in centimeters Figure 7- 10. Phyllite 13 GEOL 1107, Lab #7 IMPORTANT NOTE METAMORPHIC ROCK NAMES Many metamorphic rocks may be given more specific names by pre-fixing the textural rock name with the name or names of the dominant minerals present in the rock. For example, a rock may have the texture and structure of a gneiss, therefore it is a gneiss. If this rock is composed almost entirely of quartz and biotite and it has numerous well defined garnet crystals, then it may be called a quartz biotite garnet gneiss. IDENTIFYING NON-FOLIATED METAMORPHIC ROCKS There are only a few non-foliated metamorphic rocks to identify in this lab. Their identification is based on the colour and mineralogy of the rock. The first step in identifying a non-foliated metamorphic rock is to confirm that it has no foliations or layers. Once that’s done the next step is colour. What colour is the rock and therefore what minerals does it have. For example, if a metamorphic rock is non-foliated and green then it’s a greenstone. There is no need to identify the minerals in the rock, which are often too small to see anyway. If the rock is white or light coloured with no foliations, then it is either a quartzite or a marble. If this same rock reacts with 10% hydrochloric acid, then it’s a marble. The remaining few non-foliated rocks are identified in the same way, comparing the colour and mineralogy of the unknown sample to the list of rocks in table 7 -1. 14 GEOL 1107, Lab #7 Table 7 - 1. Common Metamorphic Rocks Part A. Foliated Metamorphic Rocks Name Dominant Minerals Texture and Structure Origins or Parent material Slate Quartz, feldspar minerals, muscovite, biotite, chlorite, Clay minerals. Very fine grained rock. Very thin, difficult to observe foliates. Dull luster. Mudstone, shale, siltstone, claystone, tuffs. Quartz, feldspar minerals, muscovite, biotite, chlorite. Fine grain mineral crystals. Thin foliations, easier to observe than a slate. Individual mineral crystals are usually too small to observe. However, concentrations of newly formed, “larger” muscovite and biotite crystals impart a “polished” sheen to foliation surfaces. Mudstone, shale, siltstone, claystone, tuffs. Phyllite 15 Low grade or little alteration Low to medium grade or significant alteration GEOL 1107, Lab #7 Part A. Foliated Metamorphic Rocks (continued) Commonly quartz, muscovite, biotite, fewer feldspar minerals, chlorite Schist Gneiss Commonly quartz, muscovite, biotite, fewer feldspar minerals. Also newly formed metamorphic minerals including garnet, kyanite, sillimanite, chlorite andalusite, and staurolite. Fine to medium coarse mineral crystals. Thicker, (up to 5 mm) discontinuous foliations that impart a schistose or foliated structure. Individual foliations may be easily observed because of the high concentration of a particular mineral (i.e. quartz or biotite) in each. Vitreous luster. Medium to coarse mineral crystals. Thick to very thick, (up to several tens of cm) continuous foliations impart a gneissic structure. Individual foliations are easily observed because minerals are now segregated into individual foliations. Vitreous luster. 16 Any Rock Medium to high grade or significant alteration Any Rock High grade alteration GEOL 1107, Lab #7 Part B. Non-Foliated Metamorphic Rocks Name Greenstone Dominant Minerals Texture and Structure Origins or Parent material Abundant chlorite and epidote, and lesser amounts of actinolite, plagioclase feldspar, calcite and maybe quartz. Typically green because of chlorite, epidote, and actinolite. Aphanitic or very fine to fine grained texture. Usually massive or nonfoliated structure. Mafic to intermediate (rocks transitional between mafic and felsic) volcanic rocks such as andesite and basalt. Quartz Quartzite Marble Calcite Dolomite Fine to medium grained texture. Individual quartz grains or crystals may be easily observed. Usually massive texture. Sometimes foliated in appear as original sedimentary structure survives alteration. Fine to medium grained texture. Individual calcite grains or crystals may be easily observed. Usually massive texture. Sometimes foliated in appear is original sedimentary or biogenic structures survive alteration. 17 Quartz Sandstone Chert Carbonate rocks including limestone and dolomite GEOL 1107, Lab #7 Part B. Non-Foliated Metamorphic Rocks (continued) Name Skarn Dominant Minerals Texture and Structure Origins or Parent material Calcite, pyrite, chalcopyrite, galena, sphalerite, pyroxene, garnet, oxide minerals. Color highly variable. Coarse to very coarse crystalline texture. May exhibit a very complex structure. Massive, heterogeneous structure may also include minerals arranged in zones, bands, nodules or radiating masses. Contact metamorphism of limestone and dolomite, usually as a result of magma intrusion. Volatile elements dissolved in hydrothermal solutions (hot water) promote formation of new, secondary minerals. Black or white and black. Medium to coarse crystalline texture. Individual crystals may or may not be visible. Usually massive structure. Mafic extrusive (basalt lava, tuff) and intrusive rocks (gabbro) altered in a regional metamorphic environment. Dark green to black. Medium to coarse crystalline texture. Massive structure. Exhibits many diagnostic characteristics of the mineral serpentine. Derived from the alteration of peridotite, pyroxenite, and dunite, and sometimes amphibolite and gabbro, in the presence of hydrothermal solutions (hot water). Hornblende, plagioclase feldspar Amphibolite Serpentinite Serpentine, magnetite, chlorite 18 GEOL 1107, Lab #7 EXERCISE 7 - 1: METAMORPHIC ROCK IDENTICATION Examine the samples in the metamorphic rock display. Name each rock and answer the questions below. Use table 7 - 1, “Common Metamorphic Rocks” (pages 15 to 18) to help identify the different rocks. 1. What aspect of texture/structure do all of the first 4 samples in your box of metamorphic rocks have in common? 2. Identify the mineral that forms the porphyroblast in sample R26a. What type of rock did this metamorphic rock form from? 3. What is the pink mineral in the gneiss, sample R24? 4. What textural feature do samples R48, R47a, and R59 have in common? Name each of these rocks and the original rock type it most likely formed from. 5. Arrange rock samples R26a, R55, R70, R83, R25b, and R24 in order of increasing metamorphism. 19 GEOL 1107, Lab #7 6. The samples in question 5 are the result of what kind of metamorphism? 7. Examine the skarn sample, R82. What are the most common minerals in this sample? 8. Using table 7- 1 (pages 15 to 18), name all the rocks in the metamorphic rock box. Put your answers in the appropriate box in the metamorphic rock identification answer sheet (page 21). Include the name of the rock, the common minerals, and metamorphic texture. 20 GEOL 1107, Lab #7 R0 21
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