Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
NYTRO® LIBRA
SAFETY DATA SHEET
Date of printing
2023-11-24
Date of issue/ Date of revision
Date of previous issue
2023-11-24
2022-10-14
Version
7.01
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name
UFI
Product description
NYTRO® LIBRA
AAH1-G004-M00V-3N3D
Insulating oil
Product type
Liquid.
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Formulation and (re)packing of substances and mixtures - Industrial
Use in functional fluids - Industrial
Use in functional fluids - Professional
Uses advised against
Reason
This product must not be used in applications other than those
recommended in Section 1, without first seeking the advice of the
supplier.
-
1.3 Details of the supplier of the safety data sheet
Supplier/Manufacturer
Nynas AB
Kabyssgatan 4D
120 30 Stockholm
SWEDEN
+46 8 602 12 00 (Office hours 8 am - 4.30 pm (CET))
www.nynas.com
e-mail address of person
responsible for this SDS
ProductHSE@nynas.com
1.4 Emergency telephone number
Telephone number
Hours of operation
+44 (0) 1235 239 670
24 hour service
National advisory body/Poison Centre
Telephone number 020 - 99 60 00 (Kemiakuten, 24h service)
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Product definition
Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Asp. Tox. 1, H304
The product is classified as hazardous according to Regulation (EC) 1272/2008 as amended.
See Section 16 for the full text of the H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.
2.2 Label elements
Date of issue/Date of revision
: 2023-11-24
Date of previous issue
: 2022-10-14
Version
: 7.01
1/20
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
NYTRO® LIBRA
SECTION 2: Hazards identification
Hazard pictograms
Signal word
Danger
Hazard statements
Precautionary statements
Prevention
Response
H304 - May be fatal if swallowed and enters airways.
Storage
Disposal
Supplemental label elements
Annex XVII - Restrictions on
the manufacture, placing on
the market and use of
certain dangerous
substances, mixtures and
articles
Not applicable.
2.3 Other hazards
Product meets the criteria for
PBT or vPvB according to
Regulation (EC) No.
1907/2006, Annex XIII
Other hazards which do not
result in classification
Not applicable.
P301 + P310, P331 - IF SWALLOWED: Immediately call a POISON CENTER or
doctor. Do NOT induce vomiting.
Not applicable.
P501 - Dispose of contents and container in accordance with all local, regional,
national and international regulations.
Not applicable.
This mixture does not contain any substances that are assessed to be a PBT or a
vPvB.
Prolonged or repeated contact may dry skin and cause irritation.
SECTION 3: Composition/information on ingredients
3.2 Mixtures
Mixture
Specific Conc.
Limits, M-factors
and ATEs
Product/ingredient name
Identifiers
%
Classification
Type
Distillate (petroleum),
hydrotreated light
naphthenic
REACH #:
01-2119480375-34
EC: 265-156-6
CAS: 64742-53-6
>50
Asp. Tox. 1, H304
-
[1] [2]
Distillate (petroleum),
hydrotreated light paraffinic
REACH #:
01-2119487077-29
EC: 265-158-7
CAS: 64742-55-8
<50
Asp. Tox. 1, H304
-
[1] [2]
Lubricating oils (petroleum), REACH #:
C15-30, hydrotreated
01-2119474878-16
neutral oil-based
EC: 276-737-9
CAS: 72623-86-0
<35
Asp. Tox. 1, H304
-
[1] [2]
See Section 16 for
the full text of the H
statements declared
above.
Regulation (EC) No. 1272/2008 [CLP] Annex VI Nota L applies to the base oil(s) in this product. Nota L - The
classification as a carcinogen need not apply if it can be shown that the substance contains less than 3 % DMSO extract
as measured by IP 346.
Date of issue/Date of revision
: 2023-11-24
Date of previous issue
: 2022-10-14
Version
: 7.01
2/20
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
NYTRO® LIBRA
SECTION 3: Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations
applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of equivalent
concern, or have been assigned a workplace exposure limit and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
Occupational exposure limits, if available, are listed in Section 8.
SECTION 4: First aid measures
4.1 Description of first aid measures
Eye contact
Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. If irritation, blurred vision or swelling occurs and
persists, obtain medical advice from a specialist.
Inhalation
If breathing is difficult, remove victim to fresh air and keep at rest in a position
comfortable for breathing. If casualty is unconscious and: If not breathing, if breathing
is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel. Get medical attention if adverse health effects persist or are
severe. Maintain an open airway.
Skin contact
Wash skin thoroughly with soap and water or use recognised skin cleanser. Remove
contaminated clothing and shoes. Handle with care and dispose of in a safe manner.
Seek medical attention if skin irritation, swelling or redness develops and persists.
Ingestion
Protection of first-aiders
Accidental high pressure injection through the skin requires immediate medical
attention. Do not wait for symptoms to develop.
Always assume that aspiration has occurred. Do not induce vomiting. Can enter
lungs and cause damage. If vomiting occurs, the head should be kept low so that
vomit does not enter the lungs. Seek professional medical attention or send the
casualty to a hospital. Do not wait for symptoms to develop.
Never give anything by mouth to an unconscious person. If unconscious, place in
recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Before attempting to rescue casualties, isolate area from all potential sources of
ignition including disconnecting electrical supply. Ensure adequate ventilation and
check that a safe, breathable atmosphere is present before entry into confined
spaces.
4.2 Most important symptoms and effects, both acute and delayed
Over-exposure signs/symptoms
Eye contact
Slight irritant
Inhalation
Inhalation of oil mist or vapours at elevated temperatures may cause respiratory
irritation.
Skin contact
Adverse symptoms may include the following:
irritation
dryness
cracking
Ingestion
Adverse symptoms may include the following:
Nausea or vomiting.
diarrhoea
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician
Due to low viscosity there is a risk of aspiration if the product enters the lungs. Treat
symptomatically.
Specific treatments
Always assume that aspiration has occurred.
Date of issue/Date of revision
: 2023-11-24
Date of previous issue
: 2022-10-14
Version
: 7.01
3/20
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
NYTRO® LIBRA
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media
Unsuitable extinguishing
media
Use dry chemical, CO₂, water spray (fog) or foam.
Do not use direct water jets on the burning product; they could cause splattering and
spread the fire. Simultaneous use of foam and water on the same surface is to be
avoided as water destroys the foam.
5.2 Special hazards arising from the substance or mixture
Hazards from the substance
In a fire or if heated, a pressure increase will occur and the container may burst. This
or mixture
substance will float and can be reignited on surface water.
Hazardous combustion
products
5.3 Advice for firefighters
Special precautions for firefighters
Special protective equipment
for fire-fighters
Incomplete combustion is likely to give rise to a complex mixture of airborne solid and
liquid particulates, gases, including carbon monoxide, H2S, SOx (sulfur oxides) or
sulfuric acid and unidentified organic and inorganic compounds.
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Clothing for fire-fighters (including helmets, protective boots and gloves) conforming
to European standard EN 469 will provide a basic level of protection for chemical
incidents.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency
Avoid breathing vapour or mist. Keep non-involved personnel away from the area of
personnel
spillage. Alert emergency personnel. Except in case of small spillages, the feasibility
of any actions should always be assessed and advised, if possible, by a trained,
competent person in charge of managing the emergency. Stop leak if safe to do so.
Avoid direct contact with the product. Stay upwind/keep distance from source. In case
of large spillages, alert occupants in downwind areas.
Eliminate all ignition sources if safe to do so. Spillages of limited amounts of product,
especially in the open air when vapours will be usually quickly dispersed, are dynamic
situations, which will presumably limit the exposure to dangerous concentrations.
For emergency responders
Note : recommended measures are based on the most likely spillage scenarios for
this material; however, local conditions (wind, air temperature, wave/current direction
and speed) may significantly influence the choice of appropriate actions. For this
reason, local experts should be consulted when necessary. Local regulations may
also prescribe or limit actions to be taken.
Small spillages: normal antistatic working clothes are usually adequate.
Large spillages: full body suit of chemically resistant and thermal resistant material
should be used. Work gloves providing adequate chemical resistance, specifically to
aromatic hydrocarbons. Note : gloves made of PVA are not water-resistant, and are
not suitable for emergency use. Safety helmet, antistatic non-skid safety shoes or
boots. Goggles and /or face shield, if splashes or contact with eyes is possible or
anticipated.
Respiratory protection : A half or full-face respirator with filter(s) for organic vapours
(and when applicable for H2S) a Self Contained Breathing Apparatus (SCBA) can be
used according to the extent of spill and predictable amount of exposure. If the
situation cannot be completely assessed, or if an oxygen deficiency is possible, only
SCBA’s should be used.
Date of issue/Date of revision
: 2023-11-24
Date of previous issue
: 2022-10-14
Version
: 7.01
4/20
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
NYTRO® LIBRA
SECTION 6: Accidental release measures
6.2 Environmental precautions
Prevent product from entering sewers, rivers or other bodies of water. If necessary
dike the product with dry earth, sand or similar non-combustible materials. In case of
soil contamination, remove contaminated soil and treat in accordance with local
regulations.
In case of small spillages in closed waters (i.e. ports), contain product with floating
barriers or other equipment. Collect spilled product by absorbing with specific floating
absorbents.
If possible, large spillages in open waters should be contained with floating barriers
or other mechanical means. If this is not possible, control the spreading of the
spillage, and collect the product by skimming or other suitable mechanical means.
The use of dispersants should be advised by an expert, and, if required, approved by
local authorities.
6.3 Methods and material for containment and cleaning up
Small spill
Stop leak if without risk. Absorb spilled product with suitable non-combustible
materials.
Large spill
Large spillages may be cautiously covered with foam, if available, to limit vapour
cloud formation. Do not use water jet. When inside buildings or confined spaces,
ensure adequate ventilation. Transfer collected product and other contaminated
materials to suitable containers for recovery or safe disposal. Approach the release
from upwind. Contaminated absorbent material may pose the same hazard as the
spilt product.
6.4 Reference to other
sections
See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.
SECTION 7: Handling and storage
The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
General information
Obtain special instructions before use. Keep away from heat/sparks/open flames/hot
surfaces. No smoking. Use and store only outdoors or in a well-ventilated area.
Hazard of slipping on spilt product. Avoid release to the environment.
7.1 Precautions for safe handling
Protective measures
Do not ingest. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid contact with
eyes, skin and clothing. Keep in the original container or an approved alternative
made from a compatible material, kept tightly closed when not in use.
Prevent the risk of slipping. Take precautionary measures against static discharge.
Avoid splash filling of bulk volumes when handling hot liquid product. Empty
containers retain product residue and can be hazardous.
Advice on general
occupational hygiene
Date of issue/Date of revision
Nota : See Section 8 for information on appropriate personal protective equipment.
See section 13 for waste disposal information.
Ensure that proper housekeeping measures are in place. Contaminated materials
should not be allowed to accumulate in the workplaces and should never be kept
inside the pockets. Eating, drinking and smoking should be prohibited in areas where
this material is handled, stored and processed. Wash hands thoroughly after
handling. Change contaminated clothes at the end of working shift. See also
Section 8 for additional information on hygiene measures.
: 2023-11-24
Date of previous issue
: 2022-10-14
Version
: 7.01
5/20
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
NYTRO® LIBRA
SECTION 7: Handling and storage
7.2 Conditions for safe
storage, including any
incompatibilities
Storage area layout, tank design, equipment and operating procedures must comply
with the relevant regional, national or local legislation. Storage installations should be
designed with adequate bunds in case of leaks or spills. Cleaning, inspection and
maintenance of internal structure of storage tanks must be done only by properly
equipped and qualified personnel as defined by national, local or company
regulations.
Store separately from oxidising agents.
Recommended materials for containers, or container linings use mild steel, stainless
steel. Not suitable : Some synthetic materials may be unsuitable for containers or
container linings depending on the material specification and intended use.
Compatibility should be checked with the manufacturer.
Keep only in the original container or in a suitable container for this kind of product.
Keep container tightly closed and sealed until ready for use. Do not store in
unlabelled containers. Containers that have been opened must be carefully resealed
and kept upright to prevent leakage. Empty containers may contain harmful,
flammable/combustible or explosive residue or vapours. Do not cut, grind, drill, weld,
reuse or dispose of containers unless adequate precautions are taken against these
hazards. Store locked up. Protect from sunlight.
7.3 Specific end use(s)
Recommendations
Industrial sector specific
solutions
Not available.
Not available.
SECTION 8: Exposure controls/personal protection
The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
8.1 Control parameters
Occupational exposure limits
Product/ingredient name
Exposure limit values
Distillate (petroleum), hydrotreated light
naphthenic
Work environment authority Regulation 2018:1 (Sweden,
9/2021). [old used mineral oil] Absorbed through skin.
Distillate (petroleum), hydrotreated light
paraffinic
Work environment authority Regulation 2018:1 (Sweden,
9/2021). [oil mist, incl. oil fumes]
TWA: 1 mg/m³ 8 hours. Form: mist and fume
STEL: 3 mg/m³ 15 minutes. Form: mist and fume
Work environment authority Regulation 2018:1 (Sweden,
9/2021). [old used mineral oil] Absorbed through skin.
Lubricating oils (petroleum), C15-30,
hydrotreated neutral oil-based
Work environment authority Regulation 2018:1 (Sweden,
9/2021). [oil mist, incl. oil fumes]
TWA: 1 mg/m³ 8 hours. Form: mist and fume
STEL: 3 mg/m³ 15 minutes. Form: mist and fume
Work environment authority Regulation 2018:1 (Sweden,
9/2021). [old used mineral oil] Absorbed through skin.
Work environment authority Regulation 2018:1 (Sweden,
9/2021). [oil mist, incl. oil fumes]
TWA: 1 mg/m³ 8 hours. Form: mist and fume
STEL: 3 mg/m³ 15 minutes. Form: mist and fume
[Air contaminant]
Work environment authority Regulation 2018:1 (Sweden,
9/2021). [oil mist, incl. oil fumes]
TWA: 1 mg/m³ 8 hours. Form: mist and fume
STEL: 3 mg/m³ 15 minutes. Form: mist and fume
Work environment authority Regulation 2018:1 (Sweden,
Oil mist
Date of issue/Date of revision
: 2023-11-24
Date of previous issue
: 2022-10-14
Version
: 7.01
6/20
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
NYTRO® LIBRA
SECTION 8: Exposure controls/personal protection
9/2021). [old used mineral oil] Absorbed through skin.
Biological exposure indices
No exposure indices known.
Recommended monitoring
procedures
Reference should be made to monitoring standards, such as the following:
European Standard EN 689 (Workplace atmospheres - Guidance for the assessment
of exposure by inhalation to chemical agents for comparison with limit values and
measurement strategy) European Standard EN 14042 (Workplace atmospheres Guide for the application and use of procedures for the assessment of exposure to
chemical and biological agents) European Standard EN 482 (Workplace
atmospheres - General requirements for the performance of procedures for the
measurement of chemical agents) Reference to national guidance documents for
methods for the determination of hazardous substances will also be required.
DNELs/DMELs
Product/ingredient name
Type
Exposure
Distillate (petroleum), hydrotreated
DNEL Long term
light naphthenic
Inhalation
Distillate (petroleum), hydrotreated
DNEL Long term
light paraffinic
Inhalation
Lubricating oils (petroleum), C15-30, DNEL Long term
hydrotreated neutral oil-based
Inhalation
Value
Population
Effects
5,58 mg/m³ Workers
Local
5,58 mg/m³ Workers
Local
5,58 mg/m³ Workers
Local
PNECs
No PNECs available
8.2 Exposure controls
Appropriate engineering
controls
Individual protection measures
Hygiene measures
Eye/face protection
Skin protection
Hand protection
Body protection
Other skin protection
Respiratory protection
Environmental exposure
controls
Date of issue/Date of revision
Mechanical ventilation and local exhaust will reduce exposure via the air. Use oil
resistant material in construction of handling equipment. Store under recommended
conditions and if heated, temperature control equipment should be used to avoid
overheating.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period. Ensure
that eyewash stations and safety showers are close to the workstation location.
Wash contaminated clothing before reuse.
Recommended: Safety glasses with side shields.
Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. 4 - 8 hours (breakthrough time): nitrile rubber
Wear protective clothing if there is a risk of skin contact. Change contaminated
clothes at the end of working shift.
Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. Use a
properly fitted, particulate filter respirator complying with an approved standard if a
risk assessment indicates this is necessary.
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
: 2023-11-24
Date of previous issue
: 2022-10-14
Version
: 7.01
7/20
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
NYTRO® LIBRA
SECTION 9: Physical and chemical properties
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
9.1 Information on basic physical and chemical properties
Physical state
Liquid.
Colour
Odour
Melting point/freezing point
Light yellow
Odourless/Light petroleum.
-51°C
Initial boiling point and boiling
range
>240°C (>464°F) [ASTM D 2887]
Flammability
Lower and upper explosion limit
Flash point
Auto-ignition temperature
Decomposition temperature
pH
Not available.
Not available.
Closed cup: >140°C (>284°F) [Pensky-Martens]
>200°C (>392°F)
>280°C
Not applicable.
Viscosity
Solubility in water
Kinematic (40°C): 9,6 mm 2/s (9,6 cSt)
Insoluble in water.
Partition coefficient: n-octanol/
water
Not applicable.
Vapour pressure (Calculated)
<0,01 kPa (<0,075 mm Hg)
Density
Vapour density
9.2 Other information
DMSO extractable compounds
for base oil substance(s)
according to IP346
0,88 g/cm³ [15°C (59°F)]
Not available.
< 3%
SECTION 10: Stability and reactivity
10.1 Reactivity
No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous
reactions
Under normal conditions of storage and use, hazardous reactions will not occur.
10.4 Conditions to avoid
Keep away from extreme heat and oxidizing agents. Take precautionary measures
against static discharge.
10.5 Incompatible materials
Oxidising agent.
10.6 Hazardous
decomposition products
Incomplete combustion is likely to give rise to a complex mixture of airborne solid and
liquid particulates, gases, including carbon monoxide, H2S, SOx (sulfur oxides) or
sulfuric acid and unidentified organic and inorganic compounds.
SECTION 11: Toxicological information
11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008
Acute toxicity
Date of issue/Date of revision
: 2023-11-24
Date of previous issue
: 2022-10-14
Version
: 7.01
8/20
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
NYTRO® LIBRA
SECTION 11: Toxicological information
Product/ingredient
name
Result
Species
Dose
Exposure Remarks
Distillate (petroleum),
hydrotreated light
naphthenic
LC50 Inhalation Dusts and
mists
Rat
>5,53 mg/l
4 hours
LD50 Dermal
Rabbit
>5000 mg/kg -
LD50 Oral
Rat
>5000 mg/kg -
LC50 Inhalation Dusts and
mists
Rat
>5,53 mg/l
LD50 Dermal
Rabbit
>5000 mg/kg -
LD50 Oral
Rat
>5000 mg/kg -
LC50 Inhalation Dusts and
mists
Rat - Male, >5,53 mg/l
Female
LD50 Dermal
Rabbit
>5000 mg/kg -
LD50 Oral
Rat
>5000 mg/kg -
Distillate (petroleum),
hydrotreated light
paraffinic
Lubricating oils
(petroleum), C15-30,
hydrotreated neutral oilbased
Conclusion/Summary
Acute toxicity estimates
4 hours
4 hours
EMBSI 1988
(similar material)
API 1982 (similar
material)
API 1982(similar
material)
EMBSI 1988
(similar material)
API 1982 (similar
material)
API 1982(similar
material)
EMBSI 1988
(similar material)
API 1982 (similar
material)
API 1982(similar
material)
Based on available data, the classification criteria are not met.
N/A
Irritation/Corrosion
Product/ingredient
name
Result
Species Score
Observation Remarks
Distillate (petroleum),
hydrotreated light
naphthenic
Eyes - Non-irritating to the
eyes.
Rabbit
0 to 0,11
24 to 72
hours
API 1982(similar
material)
Skin - Non-irritant to skin.
Rabbit
0 to 1
Eyes - Non-irritating to the
eyes.
Rabbit
0 to 0,11
24 to 72
hours
24 to 72
hours
API 1982(similar
material)
API 1982(similar
material)
Skin - Non-irritant to skin.
Rabbit
0 to 1
Eyes - Non-irritating to the
eyes.
Rabbit
0 to 0,11
24 to 72
hours
24 to 72
hours
API 1982(similar
material)
API 1982(similar
material)
Skin - Non-irritant to skin.
Rabbit
0 to 1
24 to 72
hours
API 1982 (similar
material)
Distillate (petroleum),
hydrotreated light
paraffinic
Lubricating oils
(petroleum), C15-30,
hydrotreated neutral oilbased
Skin
Eyes
Respiratory
Sensitisation
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Date of issue/Date of revision
: 2023-11-24
Date of previous issue
: 2022-10-14
Version
: 7.01
9/20
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
NYTRO® LIBRA
SECTION 11: Toxicological information
Product/ingredient
name
Route of
exposure
Species
Result
Remarks
Distillate (petroleum),
hydrotreated light
naphthenic
Distillate (petroleum),
hydrotreated light
paraffinic
Lubricating oils
(petroleum), C15-30,
hydrotreated neutral oilbased
skin
Guinea pig
Not sensitizing
API 1982(similar
material)
skin
Guinea pig
Not sensitizing
API 1982(similar
material)
skin
Guinea pig
Not sensitizing
UBTL 1984j,k,l
(similar material)
Skin
Respiratory
Mutagenicity
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Conclusion/Summary
Carcinogenicity
Based on available data, the classification criteria are not met.
Conclusion/Summary
The base oil(s) in this product is based on an severely hydrotreated distillate. Based
on available data, the classification criteria are not met.
Reproductive toxicity
Conclusion/Summary
Teratogenicity
Conclusion/Summary
Aspiration hazard
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Product/ingredient name
Result
Distillate (petroleum), hydrotreated light naphthenic
Distillate (petroleum), hydrotreated light paraffinic
Lubricating oils (petroleum), C15-30, hydrotreated neutral oilbased
ASPIRATION HAZARD - Category 1
ASPIRATION HAZARD - Category 1
ASPIRATION HAZARD - Category 1
Potential chronic health effects
Product/ingredient name
Result
Species
Dose
Exposure
Distillate (petroleum),
hydrotreated light naphthenic
Sub-chronic LOAEL Oral
Rat
125 mg/kg
-
Sub-chronic NOAEL Dermal
Sub-acute NOEL Inhalation
Dusts and mists
Sub-chronic LOAEL Oral
Rat
Rat
>2000 mg/kg
220 mg/m³
Rat
125 mg/kg
6 hours; 5 days
per week
-
Sub-chronic NOAEL Dermal
Sub-acute NOEL Inhalation
Dusts and mists
Sub-chronic LOAEL Oral
Rat
Rat
>2000 mg/kg
220 mg/m³
Rabbit
125 mg/kg
Distillate (petroleum),
hydrotreated light paraffinic
Lubricating oils (petroleum),
C15-30, hydrotreated neutral
oil-based
Sub-chronic NOAEL Dermal Rat
Sub-chronic NOEL Inhalation Rat
Dusts and mists
>2000 mg/kg
220 mg/m³
6 hours; 5 days
per week
6 hours; 5 days
per week
11.2 Information on other hazards
11.2.1 Endocrine disrupting properties
Not available.
11.2.2 Other information
Date of issue/Date of revision
: 2023-11-24
Date of previous issue
: 2022-10-14
Version
: 7.01
10/20
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
NYTRO® LIBRA
SECTION 11: Toxicological information
Aspiration hazard
Aspiration means the entry of a liquid substance directly into the trachea and lower respiratory tract.
Aspiration of hydrocarbon substances can result in in severe acute effects such as chemical pneumonitis, varying
degree of pulmonary injury or death.
This property relates to the potential for low viscosity material to spread quickly into the deep lung and cause severe
pulmonary tissue damage.
Classification of a hydrocarbon substance for aspiration hazard is made on the basis of reliable human evidence or on
the basis of physical properties.
SECTION 12: Ecological information
12.1 Toxicity
Product/ingredient name
Result
Species
Exposure
Distillate (petroleum), hydrotreated light
naphthenic
Acute EL50 >10000 mg/l
Daphnia
48 hours
Acute LL50 >100 mg/l
Acute NOEL >100 mg/l
Chronic NOEL 10 mg/l Fresh water
Acute EL50 >10000 mg/l
Fish
Algae
Daphnia
Daphnia
96 hours
72 hours
21 days
48 hours
Acute LL50 >100 mg/l
Acute NOEL >100 mg/l
Chronic NOEL 10 mg/l Fresh water
Acute EL50 >10000 mg/l
Fish
Algae
Daphnia
Daphnia
96 hours
72 hours
21 days
48 hours
Acute LL50 >100 mg/l
Fish
Acute NOEL >100 mg/l
Algae
Chronic NOEL 10 mg/l Fresh water Daphnia
96 hours
72 hours
21 days
Distillate (petroleum), hydrotreated light
paraffinic
Lubricating oils (petroleum), C15-30,
hydrotreated neutral oil-based
Conclusion/Summary
Based on available data, the classification criteria are not met.
12.2 Persistence and degradability
Product/ingredient name
Aquatic half-life
Distillate (petroleum),
hydrotreated light naphthenic
Distillate (petroleum),
hydrotreated light paraffinic
Lubricating oils (petroleum), C15-30, hydrotreated neutral
oil-based
Conclusion/Summary
Photolysis
Biodegradability
-
Not readily
-
Not readily
-
Not readily
Not readily biodegradable. This product is inherently biodegradable.
12.3 Bioaccumulative potential
Product/ingredient name
LogPow
Distillate (petroleum),
2 to 6
hydrotreated light naphthenic
Distillate (petroleum),
2 to 6
hydrotreated light paraffinic
Lubricating oils (petroleum), 2 to 6
C15-30, hydrotreated neutral
oil-based
BCF
Potential
<500
Low
<500
Low
<500
Low
Conclusion/Summary
The product has a potential to bioaccumulate.
12.4 Mobility in soil
Mobility
High mobility in soil predicted, based on log Kow > 3.0.
12.5 Results of PBT and vPvB assessment
Date of issue/Date of revision
: 2023-11-24
Date of previous issue
: 2022-10-14
Version
: 7.01
11/20
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
NYTRO® LIBRA
SECTION 12: Ecological information
Product meets the criteria for
PBT or vPvB according to
Regulation (EC) No.
1907/2006, Annex XIII
This mixture does not contain any substances that are assessed to be a PBT or a
vPvB.
12.6 Endocrine disrupting properties
Not available.
12.7 Other adverse effects
Insoluble in water. Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer
could also be impaired.
SECTION 13: Disposal considerations
The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
13.1 Waste treatment methods
Product
Methods of disposal
Where possible (e.g. in the absence of relevant contamination), recycling of used
substance is feasible and recommended. This substance can be burned or
incinerated, subject to national/local authorizations, relevant contamination limits,
safety regulations and air quality legislation. Contaminated or waste substance (not
directly recyclable): Disposal can be carried out directly, or by delivery to qualified
waste handlers. National legislation may identify a specific organization, and/or
prescribe composition limits and methods for recovery or disposal.
Hazardous waste
Yes.
European waste catalogue (EWC)
Waste code
Waste designation
13 03 07*
mineral-based non-chlorinated insulating and heat transmission oils
Packaging
Methods of disposal
The generation of waste should be avoided or minimised wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
SECTION 14: Transport information
International transport regulations
ADR/RID
ADN
IMO/IMDG
Classification
ICAO/IATA
Classification
14.1 UN number or Not regulated.
ID number
Not regulated.
Not regulated.
Not regulated.
14.2 UN proper
shipping name
-
-
-
-
14.3 Transport
hazard class(es)
-
-
-
-
14.4 Packing group -
-
-
-
14.5
Environmental
hazards
No.
No.
No.
No.
Date of issue/Date of revision
: 2023-11-24
Date of previous issue
: 2022-10-14
Version
: 7.01
12/20
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
NYTRO® LIBRA
SECTION 14: Transport information
14.6 Special precautions for
user
Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
14.7 Maritime transport in bulk
according to IMO instruments
MARPOL Annex 1 - Oils
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorisation
None of the components are listed.
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances,
mixtures and articles
Labelling
Not applicable.
Other EU regulations
Industrial emissions
(integrated pollution
prevention and control) - Air
Industrial emissions
(integrated pollution
prevention and control) Water
Not listed
Not listed
Ozone depleting substances (1005/2009/EU)
Not listed.
Prior Informed Consent (PIC) (649/2012/EU)
Not listed.
Persistent Organic Pollutants
Not listed.
Seveso Directive
This product is not controlled under the Seveso Directive.
National regulations
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
National inventory
Australia
Canada
China
Date of issue/Date of revision
All components are listed or exempted.
All components are listed or exempted.
All components are listed or exempted.
: 2023-11-24
Date of previous issue
: 2022-10-14
Version
: 7.01
13/20
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
NYTRO® LIBRA
SECTION 15: Regulatory information
Eurasian Economic Union
Japan
New Zealand
Philippines
Republic of Korea
Russian Federation inventory: All components are listed or exempted.
Japan inventory (CSCL): All components are listed or exempted.
Japan inventory (ISHL): All components are listed or exempted.
All components are listed or exempted.
All components are listed or exempted.
All components are listed or exempted.
Taiwan
Thailand
All components are listed or exempted.
All components are listed or exempted.
Turkey
United States
Viet Nam
All components are listed or exempted.
All components are active or exempted.
All components are listed or exempted.
15.2 Chemical safety
assessment
Complete.
SECTION 16: Other information
Revision comments
Not available.
Indicates information that has changed from previously issued version.
Abbreviations and acronyms
ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
N/A = Not available
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
SGG = Segregation Group
vPvB = Very Persistent and Very Bioaccumulative
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification
Justification
Asp. Tox. 1, H304
Sweden
Full text of abbreviated H
statements
Full text of classifications [CLP/
GHS]
Date of printing
Date of issue/ Date of revision
Date of previous issue
Version
Calculation method
H304
May be fatal if swallowed and enters airways.
Asp. Tox. 1
ASPIRATION HAZARD - Category 1
2023-11-24
2023-11-24
2022-10-14
7.01
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier,
nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information
contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that
these are the only hazards that exist.
The information provided herein does not in any way constitute a product warranty, product specification, agreement on
quality or similar.
NYNAS®, NYFLEX®, NYTEX®, NYTRO®, NYBASE®, NYFROST™, NYFERT™, NYPAR™, NYPASS™, NYPRINT™,
NYSPRAY™, NYHIB™, NYSWITCHO™, DISTRO™ and Nynas Logo are trademarks of Nynas.
Date of issue/Date of revision
: 2023-11-24
Date of previous issue
: 2022-10-14
Version
: 7.01
14/20
NYTRO® LIBRA
Annex to the extended Safety Data Sheet (eSDS)
Section 1 - Title
Short title of the exposure
scenario
List of use descriptors
Formulation and (re)packing of substances and mixtures - Industrial
Environmental contributing
scenarios
Health Contributing scenarios
Formulation into mixture - ERC02
Industry Association
Processes and activities
covered by the exposure
scenario
Concawe - 2021
Formulation, packing and re-packing of the substance and its mixtures in batch or
continuous operations, including storage, materials transfers, mixing, tabletting,
compression, pelletisation, extrusion, large and small scale packing, sampling,
maintenance and associated laboratory activities.
Identified use name: Formulation and (re)packing of substances and mixtures Industrial
Process Category: PROC01, PROC02, PROC03, PROC04, PROC05, PROC08a,
PROC08b, PROC09, PROC14, PROC15, PROC28
Subsequent service life relevant for that use: No.
Environmental Release Category: ERC02, ESVOC SpERC 2.2.v2
General exposures (open systems) - PROC04
General exposures (closed systems) - PROC01, PROC02, PROC03
Batch processes at elevated temperatures - PROC03
Laboratory activities - PROC15
Bulk transfers - PROC08b
Mixing operations (open systems) - PROC05
Transfer from/pouring from containers - PROC08a
Drum/batch transfers - PROC08b
Tabletting, compression, extrusion or pelletisation - PROC14
Drum and small package filling - PROC09
Storage - PROC01, PROC02
Process sampling - PROC09
Equipment cleaning and maintenance - PROC08a, PROC28
Section 2 - Exposure controls
2.1 Control of environmental exposure
Amounts used
Annual site tonnage (tonnes/year) 10 400
Maximum daily site tonnage (kg/day) 34 700
Frequency and duration of use
Continuous release
Emission days (days per year) 300
Other conditions affecting
environmental exposure
Release fraction to air from process (initial release prior to RMM) 0.0025
Release fraction to wastewater from process (initial release prior to RMM) 3.0E-6
Release fraction to soil from process (initial release prior to RMM) 0.0001
Technical on-site conditions
Prevent discharge of undissolved substance to or recover from onsite wastewater. If
and measures to reduce or limit discharging to domestic sewage treatment plant, no onsite wastewater treatment
discharges, air emissions and
required.
releases to soil
Risk management measures - Treat on-site wastewater (prior to receiving water discharge) to provide the required
Water
removal efficiency of (%) 92.9
Organisational measures to
prevent/limit release from site
Date of issue/Date of revision
Do not apply industrial sludge to natural soils. Sewage sludge should be incinerated,
contained or reclaimed.
2022-04-04
15/20
NYTRO® LIBRA
Formulation and (re)packing of substances and mixtures Industrial
Section 2 - Exposure controls
Conditions and measures
related to sewage treatment
plant
Estimated substance removal from wastewater via domestic sewage treatment (%):
94.8
Total efficiency of removal from wastewater after onsite and offsite (domestic
treatment plant) RMMs (%): 94.8
Maximum allowable site tonnage (MSafe) based on release following total wastewater
treatment removal (kg/day): 58 000
Assumed on-site sewage treatment plant flow (m³/d): 2000
2.2 Control of worker exposure
General measures applicable to all activities
Concentration of substance
in mixture or article
Frequency and duration of
use
Other conditions affecting
workers exposure
Covers percentage substance in the product up to 100 %.
Covers daily exposures up to 8 hours
Assumes a good basic standard of occupational hygiene is implemented Assumes
use at not more than 20°C above ambient temperature. There are no routine
anticipated exposures by ingestion related to any supported uses of the substance.
The risk arising from aspiration hazard is solely related to the physico-chemical
properties of the substance. The risk can therefore be controlled by implementing
risk management measures tailored to this specific risk.
Risk management measures (RMM)
General exposures (closed systems) - PROC 1, PROC 2, PROC 3
Sample via a closed loop or other system to avoid exposure.
Batch processes at elevated temperatures Use in contained systems - PROC 3
Handle substance within a closed system. Assumes process temperature up to 60.0 °C.
Bulk transfers Dedicated facility - PROC 8b
Handle substance within a closed system.
Manual Transfer from/pouring from containers Non-dedicated facility - PROC 8a
Use drum pumps.
Equipment cleaning and maintenance - PROC 8a, PROC 28
Drain down and flush system prior to equipment break-in or maintenance.
Storage - PROC 1, PROC 2
Store substance within a closed system.
Section 3 - Exposure estimation and reference to its source
3.1 Environment
Exposure assessment
(environment):
3.2 Workers
The Hydrocarbon Block Method has been used to calculate environmental exposure
with the Petrorisk model.
Exposure assessment
(human):
Exposure estimation and
reference to its source
The ECETOC TRA tool has been used to estimate workplace exposures unless
otherwise indicated.
Qualitative approach used to conclude safe use.
A DNEL (derived no effect levels) cannot be derived. There are no routine anticipated
exposures by ingestion related to any supported uses of the substance. The risk
arising from aspiration hazard is solely related to the physico-chemical properties of
the substance. The risk can therefore be controlled by implementing risk
management measures tailored to this specific risk.
Date of issue/Date of revision
2022-04-04
16/20
NYTRO® LIBRA
Annex to the extended Safety Data Sheet (eSDS)
Section 1 - Title
Short title of the exposure
scenario
List of use descriptors
Use in functional fluids - Industrial
Environmental contributing
scenarios
Use of functional fluid at industrial site - ERC07
Health Contributing scenarios
General exposures (closed systems) - PROC02
Bulk transfers - PROC01, PROC02
Storage - PROC01, PROC02
Drum/batch transfers - PROC08b
Filling of articles/equipment - PROC09
Filling of equipment from drums or containers - PROC08a
General exposures (open systems) - PROC04
Remanufacture of reject articles - PROC09
Equipment cleaning and maintenance - PROC08a, PROC28
Industry Association
Concawe - 2021
Processes and activities
covered by the exposure
scenario
Use as functional fluids e.g. cable oils, transfer oils, coolants, insulators, refrigerants,
hydraulic fluids in industrial equipment including maintenance and related material
transfers.
Identified use name: Use in functional fluids - Industrial
Process Category: PROC01, PROC02, PROC04, PROC08a, PROC08b, PROC09,
PROC28
Subsequent service life relevant for that use: No.
Environmental Release Category: ERC07,
Section 2 - Exposure controls
2.1 Control of environmental exposure
Amounts used
Annual site tonnage (tonnes/year) 10
Maximum daily site tonnage (kg/day) 500
Frequency and duration of use
Continuous release
Emission days (days per year) 20
Other conditions affecting
environmental exposure
Release fraction to air from process (initial release prior to RMM) 0.0001
Release fraction to wastewater from process (initial release prior to RMM) 1.0E-6
Release fraction to soil from process (initial release prior to RMM) 0.001
Technical on-site conditions
If discharging to domestic sewage treatment plant, no onsite wastewater treatment
and measures to reduce or limit required.
discharges, air emissions and
releases to soil
Organisational measures to
prevent/limit release from site
Conditions and measures
related to sewage treatment
plant
Do not apply industrial sludge to natural soils. Sewage sludge should be incinerated,
contained or reclaimed.
Estimated substance removal from wastewater via domestic sewage treatment (%):
94.8
Total efficiency of removal from wastewater after onsite and offsite (domestic
treatment plant) RMMs (%): 94.8
Maximum allowable site tonnage (MSafe) based on release following total wastewater
treatment removal (kg/day) 4600
Assumed on-site sewage treatment plant flow (m³/d) 2000
2.2 Control of worker exposure
General measures applicable to all activities
Concentration of substance
in mixture or article
Covers percentage substance in the product up to 100 %. unless stated differently
Date of issue/Date of revision
2022-09-08
17/20
NYTRO® LIBRA
Use in functional fluids - Industrial
Section 2 - Exposure controls
Frequency and duration of
use
Other conditions affecting
workers exposure
Covers daily exposures up to 8 hours
Assumes a good basic standard of occupational hygiene is implemented Assumes
use at not more than 20°C above ambient temperature. There are no routine
anticipated exposures by ingestion related to any supported uses of the substance.
The risk arising from aspiration hazard is solely related to the physico-chemical
properties of the substance. The risk can therefore be controlled by implementing
risk management measures tailored to this specific risk.
Risk management measures (RMM)
Bulk transfers Closed system - PROC 1, PROC 2
Handle substance within a closed system.
Filling of articles/equipment Closed system - PROC 9
Handle substance within a closed system.
Filling of equipment from drums or containers Non-dedicated facility - PROC 8a
Use drum pumps.
General exposures (closed systems) - PROC 2
Sample via a closed loop or other system to avoid exposure.
General exposures (open systems) Elevated temperature - PROC 4
Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at openings.
Assumes process temperature up to 80.0 °C.
Remanufacture of reject articles - PROC 9
Drain or remove substance from equipment prior to break-in or maintenance.
Equipment cleaning and maintenance - PROC 8a, PROC 28
Drain down and flush system prior to equipment break-in or maintenance.
Storage - PROC 1, PROC 2
Store substance within a closed system.
Section 3 - Exposure estimation and reference to its source
3.1 Environment
Exposure assessment
(environment):
3.2 Workers
The Hydrocarbon Block Method has been used to calculate environmental exposure
with the Petrorisk model.
Exposure assessment
(human):
The ECETOC TRA tool has been used to estimate workplace exposures unless
otherwise indicated.
Qualitative approach used to conclude safe use.
Exposure estimation and
reference to its source
A DNEL (derived no effect levels) cannot be derived. There are no routine anticipated
exposures by ingestion related to any supported uses of the substance. The risk
arising from aspiration hazard is solely related to the physico-chemical properties of
the substance. The risk can therefore be controlled by implementing risk
management measures tailored to this specific risk.
Date of issue/Date of revision
2022-09-08
18/20
NYTRO® LIBRA
Annex to the extended Safety Data Sheet (eSDS)
Section 1 - Title
Short title of the exposure
scenario
List of use descriptors
Use in functional fluids - Professional
Environmental contributing
scenarios
Widespread use of functional fluid (outdoor) - ERC09b
Widespread use of functional fluid (indoor) - ERC09a
Health Contributing scenarios
Drum/batch transfers - PROC08a
Transfer from/pouring from containers - PROC09
Operation of equipment containing engine oils and similar - PROC20
Remanufacture of reject articles - PROC09
Equipment cleaning and maintenance - PROC08a, PROC28
Storage - PROC01, PROC02
Filling of equipment from drums or containers - PROC09
General exposures (closed systems) - PROC01, PROC02, PROC03
Industry Association
Processes and activities
covered by the exposure
scenario
Concawe - 2021
Use as functional fluids e.g. cable oils, transfer oils, coolants, insulators, refrigerants,
hydraulic fluids in industrial equipment including maintenance and related material
transfers.
Identified use name: Use in functional fluids - Professional
Process Category: PROC01, PROC02, PROC03, PROC08a, PROC09, PROC20,
PROC28
Subsequent service life relevant for that use: No.
Environmental Release Category: ERC09a, ERC09b, ESVOC SpERC 9.13b.v2
Section 2 - Exposure controls
2.1 Control of environmental exposure
Amounts used
Annual site tonnage (tonnes/year) 0.05
Maximum daily site tonnage (kg/day) 0.01
Frequency and duration of use
Continuous release
Emission days (days per year) 365
Other conditions affecting
environmental exposure
Release fraction to air from process (initial release prior to RMM) 0.05
Release fraction to wastewater from process (initial release prior to RMM) 0.05
Release fraction to soil from process (initial release prior to RMM) 0.05
Technical on-site conditions
If discharging to domestic sewage treatment plant, no onsite wastewater treatment
and measures to reduce or limit required.
discharges, air emissions and
releases to soil
Risk management measures - Treat on-site wastewater (prior to receiving water discharge) to provide the required
Water
removal efficiency of (%) 81.2
Conditions and measures
related to sewage treatment
plant
Conditions and measures
related to external treatment of
waste for disposal
Do not apply industrial sludge to natural soils. Sewage sludge should be incinerated,
contained or reclaimed.
Estimated substance removal from wastewater via domestic sewage treatment (%):
94.8
Total efficiency of removal from wastewater after onsite and offsite (domestic
treatment plant) RMMs (%): 94.8
Maximum allowable site tonnage (MSafe) based on release following total wastewater
treatment removal (kg/day): 0.42
Assumed domestic sewage treatment plant flow (m3/d): 2000
2.2 Control of worker exposure
General measures applicable to all activities
Date of issue/Date of revision
2022-04-04
19/20
NYTRO® LIBRA
Use in functional fluids - Professional
Section 2 - Exposure controls
Concentration of substance
in mixture or article
Frequency and duration of
use
Other conditions affecting
workers exposure
Covers percentage substance in the product up to 100 %.
Covers daily exposures up to 8 hours
Assumes a good basic standard of occupational hygiene is implemented Assumes
use at not more than 20°C above ambient temperature. There are no routine
anticipated exposures by ingestion related to any supported uses of the substance.
The risk arising from aspiration hazard is solely related to the physico-chemical
properties of the substance. The risk can therefore be controlled by implementing
risk management measures tailored to this specific risk.
Risk management measures (RMM)
Drum/batch transfers Non-dedicated facility - PROC 8a
Use drum pumps.
Transfer from/pouring from containers - PROC 9
Use drum pumps.
Filling of equipment from drums or containers - PROC 9
Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour).
General exposures (closed systems) - PROC1, PROC 2, PROC 3
Sample via a closed loop or other system to avoid exposure.
Operation of equipment containing engine oils and similar Closed system - PROC 20
Handle substance within a closed system.
Operation of equipment containing engine oils and similar Closed system Elevated temperature - PROC 20
Assumes process temperature up to 80.0 °C.
Remanufacture of reject articles - PROC 9
Drain or remove substance from equipment prior to break-in or maintenance.
Equipment cleaning and maintenance - PROC 8a, PROC 28
Drain down and flush system prior to equipment break-in or maintenance.
Storage - PROC 1, PROC 2
Store substance within a closed system.
Section 3 - Exposure estimation and reference to its source
3.1 Environment
Exposure assessment
(environment):
3.2 Workers
The Hydrocarbon Block Method has been used to calculate environmental exposure
with the Petrorisk model.
Exposure assessment
(human):
Exposure estimation and
reference to its source
The ECETOC TRA tool has been used to estimate workplace exposures unless
otherwise indicated.
Qualitative approach used to conclude safe use.
A DNEL (derived no effect levels) cannot be derived. There are no routine anticipated
exposures by ingestion related to any supported uses of the substance. The risk
arising from aspiration hazard is solely related to the physico-chemical properties of
the substance. The risk can therefore be controlled by implementing risk
management measures tailored to this specific risk.
Date of issue/Date of revision
2022-04-04
20/20