A Review of Full Biomass-Fired Conversion in a LargeScale Circulating Fluidized Bed Boiler using Palm Kernel Shells and Woodchips Danny M. Urian1* and Aldrin D. Calderon1 1 School of Mechanical, Manufacturing, and Energy Engineering, Mapúa University 658 Muralla Street, Intramuros, Manila 1002, Philippines Danny M. Urian* (dmurian@mymail.mapua.edu.ph) Aldrin D. Calderon (adcalderon@mapua.edu.ph) Abstract. Many studies have been conducted on the co-firing of coal and biomass for carbon reduction. However, only some have examined using 100% biomass as the primary fuel in large-scale Circulating Fluidized Bed (CFB) boilers. This review examines the feasibility and challenges of transitioning largescale CFB boilers from coal-biomass co-firing to utilizing 100% palm kernel shells (PKS) and woodchips. CFB technology offers inherent advantages for biomass combustion, including fuel flexibility and lower operating temperatures, but several technical barriers must be overcome to ensure efficient and reliable operation. The review analyzes key challenges, including managing high ash content, mitigating emissions, agglomeration, fouling, slagging, corrosion, optimizing combustion efficiency, and ensuring long-term operational reliability. The review examines potential solutions, such as fuel pre-treatment techniques, biomass co-firing, combustion optimization control, advanced ash management systems, heat recovery, and the application of computational modeling tools like Computational Particle Fluid Dynamics (CPFD) to simulate and optimize boiler design and operation. Though challenges remain, transitioning largescale CFB boilers to 100% PKS and woodchip firing presents a significant opportunity to advance sustainable energy production. Further research and development of innovative solutions tailored to the unique properties of PKS and woodchips are crucial to unlocking the full potential of these biomass resources. Keywords: PKS, Woodchips, CFB Boiler, Boiler Efficiency, and Emissions. 1 Introduction The world faces a pressing energy challenge. Nearly a billion new energy consumers are expected to emerge more or less than a decade from now [1]; this and rising living standards will significantly increase global energy consumption. The world's growing energy demands require sustainable solutions that provide reliable power while minimizing environmental impact. Simply producing more energy is not enough; we must 2 transition away from environmentally damaging fossil fuels and towards renewable energy sources. Biomass offers a promising pathway for this transition. As a readily available resource, biomass can help fill energy gaps, offering a carbon-neutral alternative to fossil fuels. The carbon released during biomass combustion is balanced by the carbon absorbed during its growth, making it a more sustainable energy source [2]. Among the various technologies for biomass power generation, circulating fluidized bed (CFB) boilers have emerged as a promising option. CFB boilers offer several advantages for biomass combustion, including their ability to efficiently burn various biomass fuels, including agricultural residues, woody biomass, and energy crops [3]. This adaptability of CFB boilers reassures us that they can effectively utilize the diverse range of biomass resources available. High combustion efficiency, turbulent mixing, and long residence times in the fluidized bed promote complete combustion, leading to high energy conversion efficiencies [4]. CFB boilers are well-suited for emissions control due to their lower combustion temperatures and the ability to integrate in-situ emissions control technologies [5]. The conversion of existing large-scale CFB boilers from fossil fuels to 100% biomass firing is a growing interest, as it can significantly reduce GHGs and contribute to a sustainable green energy mix [6]. Palm kernel shells and woodchips are abundant and readily available biomass fuels with significant potential for large-scale power generation in CFB boilers. PKS, a by-product of palm oil production, is common in many tropical regions, like Malaysia, Indonesia, and West Africa. Woodchips, derived from forestry residues, offer a versatile and sustainable fuel source [7] typically available in South-East Asian Regions. This review paper investigates the transition of large-scale CFB boilers from coalbiomass co-firing to 100% biomass firing, specifically focusing on palm kernel shells and woodchips as primary fuels. Analyze this conversion's technical challenges and opportunities, assessing its impact on combustion and boiler efficiency, emissions, and overall feasibility. Key aspects explored include fuel handling and pre-treatment, combustion optimization strategies, co-firing potential, ash management techniques, and applying computational modeling tools to enhance performance. By providing an overview of these critical factors, this review aims to give important information surrounding the full biomass conversion in CFB boilers, ultimately promoting sustainable, efficient, and cleaner energy. 2 Technical Feasibility 2.1 Fuel Feeding Systems for PKS and Woodchips Transitioning large-scale CFB boilers from fossil fuels to 100% PKS or woodchip firing presents unique challenges and opportunities in fuel handling and feeding systems [6]. Unlike coal, whose bulk density is 700 ~ 1100 kg/m3, as shown in Table 1 [8], PKS and woodchips have distinct physical characteristics that necessitate specific design considerations. PKS, with its typical bulk density of 740 kg/m3 (wet) and 650 kg/m3 (dry) [9] and size distribution, can be efficiently transported and fed into the boiler using conventional mechanical conveying systems, such as screw and belt 3 feeders [10]. This contrasts with lighter and less dense biomass fuels, such as woodchips, which may require alternative feeding mechanisms [11]. Woodchips have relatively low bulk densities, typically 200 ~ 400 kg/m3 [12]. This low density can lead to consistent and controlled fuel feeding issues, which is key for maintaining stable boiler operation. Additionally, the moisture content of these biomass fuels can vary significantly, from around 10% to 50% on a wet basis, depending on the source and pre-treatment [13]. Advanced fuel feeding systems, such as pneumatic conveying or rotary valves, may be employed to address these challenges. Pneumatic conveying systems use air to transport the fuel, ensuring reliable and uniform fuel delivery to the boiler. Rotary valves, on the other hand, are used to control the flow of fuel into the boiler [14]. The varying characteristics of palm kernel shells and woodchips, even within the same batch, pose significant difficulties for their utilization in large-scale CFB boilers. These biomass fuels may display substantial differences in moisture content, particle size distribution, and bulk density [15]. As a result, the boiler output may experience undesirable fluctuations, making it difficult to maintain stable and efficient operation. Addressing these fuel property variations through effective pre-treatment and fuel handling strategies is important to utilize the full potential of PKS and woodchips in largescale CFB boiler conversions. Effective pre-treatment methods include drying the biomass to reduce moisture content and screening to ensure a consistent particle size distribution. In terms of fuel handling, as previously mentioned, using specialized equipment designed for biomass fuels can help prevent issues like bridging and reduced flowability [14][16][17]. PKS and woodchips typically have higher moisture content than coal, which can lead to operational issues like clogging and corrosion in feeding systems [18]. The irregular shapes and often large sizes of PKS and woodchips, as shown in Table 1, can pose challenges for conveying and feeding. They are prone to interlocking and jamming, particularly in conventional feeding systems designed for granular fuels [19]. Table 1. Bulk density and particle size comparison of coal, PKS, and woodchips. Units Coal PKS Woodchips kg/m³ 700 ∼ 1100 650 ∼ 740 200 ∼ 400 mm 1∼5 3 ∼ 15 5 ∼ 50 2.2 Boiler Efficiency with PKS and Woodchips Switching from coal to PKS or woodchips in a CFB boiler can significantly impact the overall boiler efficiency due to the fuel properties and combustion behavior differences between biomass fuels and conventional coal [20][21]. As shown in Table 2, PKS and woodchips typically have a lower heating value than coal, meaning they contain less 4 energy per unit mass [21][22]. Also, biomass fuels' higher moisture content can reduce their effective heating value. It can negatively impact combustion efficiency as more energy evaporates the moisture, leaving less for steam generation. Understanding these fuel property differences and their impact on combustion behavior is essential for optimizing the boiler operation and maximizing the energy output when transitioning to full biomass firing. Despite the high combustion efficiency of CFB boilers, variations in the physical characteristics of PKS and woodchips, such as particle size and distribution, can influence their burning behavior and effectiveness within the boiler [23]. Incomplete or inefficient combustion of these biomass fuels can result in energy losses and elevated emissions. CFB boilers can handle increased ash levels, and the composition of the ash can influence slagging and fouling propensities [24]; this could impair heat transfer efficiency and require frequent boiler cleaning and maintenance. The performance of the fuel delivery system, encompassing storage, handling, and transportation, can significantly impact the overall boiler efficiency. Energy losses may arise from friction, material deterioration, and operational inefficiencies. Table 2. Typical ultimate analysis for each fuel type & mixed fuel properties (AR basis) [21]. Item 3 Types of Fuel Units Coal PKS WC Mixed Fuel %-wt. 58.74 8.25 33.01 Total Moisture % 30.94 17.94 31.06 29.907 HHV MJ/kg 17.93 16.75 17.64 17.736 LHV MJ/kg 16.40 14.99 15.63 16.027 C % 48.30 42.40 32.40 42.565 H % 5.02 5.21 5.96 5.346 N % 0.98 0.33 1.33 1.042 O % 10.87 31.62 25.20 17.312 Total S % 0.0900 0.0300 0.040 0.069 Total Cl % 0.0040 0.0961 0.010 0.014 Ash % 3.80 2.37 4.00 3.75 Total Moisture % 30.94 17.94 31.06 29.91 (Total) % 100.0 100.0 100.0 100.00 Ultimate Analysis Co-firing ratio (wt. basis) 5 3 Environmental Impact 3.1 Emissions in PKS and Woodchip-Fired CFB Boilers Biomass is considered a carbon-neutral fuel source, but its combustion produces emissions that must be effectively controlled to meet environmental regulations and minimize air pollution. CFB boilers offer several advantages in this regard, as they inherently operate at lower combustion temperatures, typically below 850°C, which can suppress the formation of nitrogen oxides [25]. Burning palm kernel shells in an oxy-fuel environment reduced NOx emissions by 16.5% and significantly reduced unburnt carbon in fly ash. Due to biomass's lower nitrogen and sulfur content, PKS combustion produced lower NOx and SO2 emissions than coal combustion. This study highlighted the benefits of small-scale oxy-combustion of PKS. However, further research is needed to investigate the impact of flue gas recycling, heat transfer, ash deposition, and scalability on larger systems [26]. Burning wood chips in a CFB combustor can create oxygen-depleted regions, leading to unburned gases like CO and hydrocarbons, even reaching the cyclone. These gases typically burn off due to high temperatures, but reducing excess air to decrease NOx emissions can significantly increase CO [27]. Compared to coal, PKS and woodchip combustion generally result in lower SO2 and Hg emissions [28]. However, they can produce higher particulate matter, NOx, and CO levels if combustion is not properly managed [29]. 4 Operational Impact 4.1 Common Operational Issues on Biomass Fuels Alkali metals, abundant in biomass fuels, contribute significantly to this problem by forming low-melting-point silicates that create a sticky surface, promoting further deposition. Complex chemical interactions involving chlorine, sulfur, silicon, and alkali metals can cause severe corrosion, especially in high-alkali biomass fuel systems [25]. Deposits like ash can accumulate on heat transfer surfaces (fouling) or surfaces exposed to radiant heat (slagging). These deposits, primarily composed of inorganic materials from the fuel, hinder heat transfer and can lead to corrosion, ultimately reducing the equipment's lifespan [30]. A study on the co-combustion of woodchips and with rapeseed cake pellets in a CFB boiler showed that the high phosphorus content in rapeseed cake significantly contributed to agglomeration and fouling ions [31]; this is important to consider as the industry explores new fuel combinations, even though the co-firing of PKS and woodchips still requires further investigation. In fluidized bed combustion, temperatures between 800 ~ 950°C allow for both the breakdown of Polycyclic aromatic hydrocarbons (PAHs) by oxidants and the formation of PAHs from the breakdown of larger molecules during pyrolysis [32]. Above 850°C, PAH formation increases due to endothermic reactions, especially in areas like the dense fluidized zone and freeboard region, with metals like iron and copper potentially 6 accelerating this process [25]. The buildup of PAHs and their by-products inside the boiler system can lead to fouling, which reduces the boiler's heat transfer efficiency and increases the risk of corrosion. This fouling and corrosion, in turn, requires more frequent cleaning and maintenance, leading to higher operational costs and more downtime for the CFB boiler [25]. Introducing limestone [31] to the boiler during co-combustion can prevent the formation of potassium silicates, which contribute to fouling. Limestone also enhances phosphorus retention in the bed by forming high-melting calcium phosphates, reducing slagging potential. Torrefaction of PKS before combustion can significantly reduce fouling [33]; this process involves heating the biomass to a specific temperature range of 200 ~ 300°C in a controlled environment, resulting in a more energy-dense and less problematic fuel. Implementing an optimized soot-blowing system [34] can help remove deposits from heat transfer surfaces; this system should be tailored to the specific boiler design and fuel characteristics to ensure efficient cleaning without compromising boiler performance. It is important to understand that the best approach typically includes a blend of these strategies customized to the particular boiler design, fuel properties, and operational objectives. 5 Potential Optimization Methods and Research Opportunities 5.1 Optimization Methods Fig. 1. Conceptual map of full biomass firing optimization methods. 7 The transition to full biomass-firing in large-scale CFB boilers presents several opportunities for optimization, as shown in Fig. 1; this flowchart outlines combustion control optimization through thermal and fuel-air ratio, fuel feed ratio, and fuel pre-treatment. It also includes heat recovery, ash management, and the possibility of co-firing PKS and woodchips (WC) for more efficient combustion. Fuel Pre-Treatment. Drying and size reduction can significantly improve combustion efficiency and reduce energy losses associated with moisture evaporation. Moisture content in biomass fuels directly impacts combustion efficiency. PKS and woodchips often contain significant moisture, which requires energy to evaporate during combustion, reducing the net energy output [13]. Drying removes excess moisture from the fuel, directly correlating to lower emissions and improved combustion efficiency; this is critical as high moisture content can lead to increased formation of sulfuric acid, a major contributor to fouling. Drier fuels require less energy to ignite and combust, leading to lower operating costs and improved overall boiler efficiency [35]. Dry fuels are easier to grind, allowing for better size reduction and more homogenous fuel particles. This homogeneity promotes more efficient combustion and reduces the likelihood of unburnt particles contributing to slagging and fouling [13]. The irregular shapes and frequently large sizes of PKS and woodchips can pose challenges for conveying and feeding [36]. As mentioned, they are prone to interlocking and jamming, particularly in conventional feeding systems designed for granular fuels. Size reduction through chipping, grinding, or milling can improve flowability, enhance mixing with combustion air, and promote complete combustion [19]; this leads to higher heat release rates and reduces the potential for unburnt particles to contribute to deposit formation. Consistent particle size distribution ensures uniform air-fuel mixing, leading to more efficient combustion and reduced formation of ash particles that can contribute to slagging. Smaller, uniformly sized particles are easier to transport pneumatically, improving fuel feeding consistency and reducing the risk of blockages or uneven distribution in the boiler. CFB Boiler Co-firing. Investigating the efficiency of CFB boilers co-firing biomass, particularly PKS, and woodchips, is critical. By simulating different co-firing scenarios, researchers can gain insights into the impact of biomass blend ratios on overall boiler efficiency, helping to optimize fuel blending strategies for both performance and emissions reduction [21]. Combustion Control Optimization. Precise control over combustion parameters like thermal, air-to-fuel ratio, bed temperature, and fuel distribution is vital for maximizing combustion efficiency and minimizing emissions [37]; this may involve using advanced combustion monitoring and control systems and careful tuning of the CFB boiler's operational parameters. Maintaining optimal conditions can minimize the release of alkali metals and phosphorus, reduce their interaction with other elements, and mitigate deposit formation, reducing the risk of potential operational issues. 8 Ash Management. Effective ash handling and disposal systems are essential for maintaining boiler efficiency and minimizing downtime for cleaning. Bed ash recirculation and efficient ash removal systems can help mitigate ash-related operational issues [21]. Optimizing bed pressure drop can significantly impact both combustion efficiency and ash characteristics. A study found an optimal bed pressure drop of around 5.7 kPa, which minimized carbon content in the fly ash while improving overall combustion efficiency. This finding underscores the interconnectedness of boiler operation parameters and the importance of a holistic approach to ash management [38]. Heat Recovery. Implementing effective heat recovery systems to capture waste heat from flue gases can significantly improve boiler efficiency [39]. Effective operation of soot-blowing in the superheaters and air-preheaters plays a vital role in heat recovery from flue gas. Important parameter indicators must be monitored, and the differential temperature and flue gas pressure between the upstream and downstream must be controlled. 5.2 Research Opportunities Despite the growing interest in biomass utilization for power generation, there needs to be more publicly available data on the efficiency of large-scale CFB boilers firing 100% PKS or woodchips. This gap in knowledge stems from several factors: Full conversion of large-scale CFB boilers from coal to 100% PKS or woodchips is still relatively uncommon. Many existing facilities operate in co-firing mode, blending biomass with coal, limiting the availability of real-world data on dedicated biomass-fired systems. Factors influencing boiler efficiency include fuel characteristics, design, operating conditions, and maintenance practices. This site-specific variability makes it difficult to generalize findings from one installation to another. Agglomeration also poses a significant challenge when operating CFB combustors and gasifiers. The fluidization process can influence agglomerates' formation, disrupting heat distribution within the system. In severe cases, agglomeration can lead to de-fluidization, forcing an unplanned boiler shutdown [40]. Addressing these knowledge gaps is vital; further research is needed for rigorous testing and monitoring of dedicated PKS/woodchip-fired CFB boilers, essential for quantifying their efficiency under various operating conditions. Advanced modeling tools, e.g., Computational Particle Fluid Dynamics (CPFD), can help simulate the 3phase flow involving bed material, solid fuels, and gas flow. Study the fluidization behavior in the furnace bed to identify the uneven heat distribution and predict efficiency under various scenarios. By simulating key parameters like particle size distribution, critical fluidization velocity, and pressure drop [41], CPFD can provide valuable insights into agglomeration processes, including the formation and distribution of pollutants during combustion. CPFD has proven valuable in optimizing CFB systems, but it is important to acknowledge the underlying limitations of CPFD modeling. Accurately representing complex flow regimes remains a challenge, which can impact the applicability of CPFD in certain scenarios. Despite these limitations, CPFD has 9 succeeded in areas like optimizing cyclone separator arrangement and analyzing the dynamic behavior of CFB boilers during thermal startup [42]. 6 Conclusion The flexibility of CFB technology makes the transition to 100% biomass fuels technically possible. However, widespread adoption will hinge on overcoming several key challenges. Specifically, advancements in fuel pre-treatment are crucial to optimize combustion efficiency, including drying and size reduction. They can also play a vital role in improving the flowability, air mixing, and overall combustion performance of PKS and woodchips in CFB boilers. Addressing the challenges posed by these biomass feedstocks' irregular shapes and large sizes will ensure reliable fuel handling and feeding to minimize fouling, slagging, and corrosion and ensure long-term operational reliability. Effective ash handling and disposal systems are essential for maintaining boiler efficiency and minimizing downtime for cleaning. Strategies like bed ash recirculation and efficient ash removal systems can help mitigate ash-related operational issues. Furthermore, optimizing bed pressure drop can significantly impact both combustion efficiency and ash characteristics, underscoring the interconnectedness of boiler operation parameters and the importance of a holistic approach to ash management. Further research in these areas is paramount, and we must develop innovative solutions tailored to the unique properties of PKS and wood chips. Advanced modeling tools, such as CPFD, offer promising avenues for predicting agglomeration, simulating, and optimizing the complex fluidization behavior and combustion dynamics within CFB boilers firing at 100% biomass fuels. References 1. Jose, R., Panigrahi, S.K., Patil, R.A., Fernando, Y., Ramakrishna, S.: Artificial IntelligenceDriven Circular Economy as a Key Enabler for Sustainable Energy Management. Materials Circular Economy. 2, (2020). 2. Sedjo, R.A.: Biomass Sequestration, Energy, and Global Change. International Review of Environmental and Resource Economics. 4, 355–386 (2011). 3. Hancharik, R.: Co-Firing Coal, Biomass and Waste Fuels in Circulating Fluidized Bed Boilers to Reduce CO2 Emissions. (2011). 4. Basu, P.: Combustion of coal in circulating fluidized-bed boilers: a review. Chemical Engineering Science. 54, 5547–5557 (1999). 5. Gao, M., Hong, F., Liu, J., Chen, F.: Investigation on the energy conversion and load control of supercritical circulating fluidized bed boiler units. Journal of Process Control. 68, 14–22 (2018). 6. Widell, H.: Industrial-scale biomass combustion plants: engineering issues and operation. In: Elsevier eBooks. pp. 225–277 (2013). 7. Loh, S.K.: The potential of the Malaysian oil palm biomass as a renewable energy source. Energy Conversion and Management. 141, 285–298 (2017). 8. Heyduk, A.: Bulk density estimation using a 3-dimensional image acquisition and analysis system. E3S Web of Conferences. 8, 01060 (2016). 10 9. Edmund, C.O., Christopher, M.S., Pascal, D.K.: Characterization of palm kernel shell for materials reinforcement and water treatment. Journal of Chemical Engineering and Materials Science. 5, 1–6 (2014). 10. Cakbentra: PKS For CFB Powerplant, https://biomassproject.blogspot.com/2018/03/pksfor-cfb-powerplant.html, last accessed 2024/01/27. 11. Bazargan, A., Rough, S.L., McKay, G.: Compaction of palm kernel shell biochars for application as solid fuel. Biomass and Bioenergy. 70, 489–497 (2014). 12. Tumuluru, N.J.S., Wright, N.C.T., Kenney, N.K.L., Hess, N.R.J.: A Technical Review on Biomass Processing: Densification, Preprocessing, Modeling and Optimization. 2010 Pittsburgh, Pennsylvania, June 20 - June 23, 2010. (2010). 13. Gebreegziabher, T., Oyedun, A.O., Luk, H.T., Lam, T.Y.G., Zhang, Y., Hui, C.W.: Design and optimization of biomass power plant. Process Safety and Environmental Protection. 92, 1412–1427 (2014). 14. Zabetta, E.C., Barisic, V., Peltola, K., Sarkki, J., Jantti, T.: Advanced technology to co-fire large shares of agricultural residues with biomass in utility CFBs. Fuel Processing Technology. 105, 2–10 (2013). 15. Huilin, L., Rushan, B., Wenti, L., Binxi, L., Lidan, Y.: Computations of a Circulating Fluidized-Bed Boiler with Wide Particle Size Distributions. Industrial & Engineering Chemistry Research. 39, 3212–3220 (2000). 16. Kuptz, D., Hartmann, H.: Evaluation of Fuel Quality, Throughput Rate and Energy Consumption During Non-Industrial Wood Chip Production with Three PTO Driven Chippers. Croatian Journal of Forest Engineering. 43, 109–122 (2021). 17. Nevalainen, H., Jegoroff, M., Saastamoinen, J., Tourunen, A., Jäntti, T., Kettunen, A., Johnsson, F., Niklasson, F.: Firing of coal and biomass and their mixtures in 50kW and 12MW circulating fluidized beds – Phenomenon study and comparison of scales. Fuel. 86, 2043–2051 (2007). 18. Dzurenda, L., Banski, A.: Influence of moisture content of combusted wood on the thermal efficiency of a boiler. Archives of Thermodynamics. 38, 63–74 (2017). 19. Craven, J.M., Swithenbank, J., Sharifi, V.N.: Investigation into the Flow Properties of Coarse Solid Fuels for Use in Industrial Feed Systems. Journal of Powder Technology. 2015, 1–12 (2015). 20. Nevalainen, H., Jegoroff, M., Saastamoinen, J., Tourunen, A., Jäntti, T., Kettunen, A., Johnsson, F., Niklasson, F.: Firing of coal and biomass and their mixtures in 50kW and 12MW circulating fluidized beds – Phenomenon study and comparison of scales. Fuel. 86, 2043–2051 (2007). 21. Urian, D.M., Tayactac, R.G., Honra, J.P., Ang, E.B.O., Umali, R.D.: Assessment of Fuel Feed Ratio and Emissions for Coal and Biomass Co-Firing in the Circulating Fluidized Bed Boiler. In: Green energy and technology. pp. 49–64 (2024). 22. Heat Values of Various Fuels - World Nuclear Association, https://world-nuclear.org/information-library/facts-and-figures/heat-values-of-various-fuels, last accessed 2024/02/05. 23. Niksa, S.: Predicting the macroscopic combustion characteristics of diverse forms of biomass in p. p. firing. Fuel. 283, 118911 (2021). 24. Zabetta, E.C., Barisic, V., Peltola, K., Sarkki, J., Jantti, T.: Advanced technology to co-fire large shares of agricultural residues with biomass in utility CFBs. Fuel Processing Technology. 105, 2–10 (2013). 25. Khan, A.A., De Jong, W., Jansens, P.J., Spliethoff, H.: Biomass combustion in fluidized bed boilers: Potential problems and remedies. Fuel Processing Technology. 90, 21–50 (2009). 11 26. Tumsa, T.Z., Chae, T.Y., Yang, W., Paneru, M., Maier, J.: Experimental study on combustion of torrefied palm kernel shell (PKS) in oxy‐fuel environment. International Journal of Energy Research. (2019). 27. Lyngfelt, A., Leckner, B.G.: Combustion of woodchips in circulating fluidized bed boilers — NO and CO emissions as functions of temperature and air-staging. Fuel. 78, 1065–1072 (1999). 28. Biomass for Power Generation and CHP – Analysis - IEA, https://www.iea.org/reports/biomass-for-power-generation-and-chp, last accessed 2024/02/05. 29. World Health Organization - The Potential Air Quality Impacts from Biomass Combustion, https://uk-air.defra.gov.uk/assets/documents/reports, last accessed 2024/02/05. 30. Bryers, R.W.: Fireside slagging, fouling, and high-temperature corrosion of heat-transfer surface due to impurities in steam-raising fuels. Progress in Energy and Combustion Science. 22, 29–120 (1996). 31. Piotrowska, P., Zevenhoven, M., Hupa, M., Davidsson, K., Åmand, L.-E., Zabetta, E.C., Barisic, V.: Fate of Phosphorus During Co-Combustion of Rapeseed Cake with Wood. In: Springer eBooks. pp. 979–986 (2009). 32. Liu, K., Han, W., Pan, W.P., Riley, J.T.: Polycyclic aromatic hydrocarbon (PAH) emissions from a coal-fired pilot FBC system. Journal of Hazardous Materials. 84, 175–188 (2001). 33. Pawlak-Kruczek, H., Arora, A., Mościcki, K., Krochmalny, K., Sharma, S., Niedzwiecki, L.: A transition of a domestic boiler from coal to biomass – Emissions from combustion of raw and torrefied Palm Kernel shells (PKS). Fuel. 263, 116718 (2020). 34. Pekar, J., Pachner, D., Beran, J., Havlena, V.: Soot blowing optimization system and application to oil-fired boiler. (2008). 35. Shastri, A.N.: Study of Efficiency Improvement and Optimization in CFB. Volume 14: Emerging Technologies; Materials: Genetics to Structures; Safety Engineering and Risk Analysis. (2016). 36. Craven, J.M., Swithenbank, J., Sharifi, V.N.: Investigation into the Flow Properties of Coarse Solid Fuels for Use in Industrial Feed Systems. Journal of Powder Technology. 2015, 1–12 (2015). 37. Urano, S., Nagai, M., Kako, J.: Study on the combustion control methodology for maximizing of engine thermal efficiency — The strategy for control of heat release pattern. (2017). 38. Yang, H., Zhang, H., Yang, S., Yue, G., Su, J., Fu, Z.: Effect of Bed Pressure Drop on Performance of a CFB Boiler. Energy & Fuels. 23, 2886–2890 (2009). 39. Lee, C.-E., Yu, B., Lee, S.: An analysis of the thermodynamic efficiency for exhaust gas recirculation-condensed water recirculation-waste heat recovery condensing boilers (EGRCWR-WHR CB). Energy. 86, 267–275 (2015). 40. Nijenhuis, J., Korbee, R., Lensselink, J., Kiel, J.H.A., Van Ommen, J.R.: A method for agglomeration detection and control in full-scale biomass fired fluidized beds. Chemical Engineering Science. 62, 644–654 (2007). 41. Li, D., Cai, R., Ahn, S., Lu, X., Jung, S., Jeon, C.-H., Zhu, X.: Hydrodynamics in the transport zone of a large-scale circulating fluidized bed boiler. Powder Technology. 414, 118099 (2023). 42. Jiang, Y., Qiu, G., Wang, H.: Modelling and experimental investigation of the full-loop gas– solid flow in a circulating fluidized bed with six cyclone separators. Chemical Engineering Science. 109, 85–97 (2014).
0
You can add this document to your study collection(s)
Sign in Available only to authorized usersYou can add this document to your saved list
Sign in Available only to authorized users(For complaints, use another form )