1 “REUSE OF RDF DERIVED FROM MUNICIPAL SOLID WASTE IN A CEMENT MANUFACTURING INDUSTRY AND POTENTIAL REDUCTION OF CARBON FOOTPRINT” Authors:Nagalaxmi Kulkarni,Dr Nagabhushan Biliangandi Abstract The global cement industry plays a key role in releasing greenhouse gases (GHG) like Carbon dioxide,methane and nitrogen oxide respectively .From these gases the carbon dioxide provides almost 7% in greenhouse gases emission.Therefore,there is a need of sustainable alternatives which reduces the emission in clinkers.According to the various studies we found out that the municipal solid waste (MSW) management by exploring its conversion into refuse-derived fuel fuel(RDF) for cement co-processing ,reducing landfill dependency and environmental.This paper is also based on field visits like HubballiDharwad Municipal Cooperation (HDMC), City Municipal Cooperation Gokak (CMCG) and JK Super Cement ,Muddapur were we collected the data relevant to RDF and integrate into the clinker manufacturing process.In these process we consider the characters of Municipal solid waste like calorific value, combustion of RDF materials like plastic, paper,textiles and wood which is 70% suitable to replace the coal in terms of heating value in terms of manufacturing of cement in clinker At present the cement manufacturing industry is replacing petcoke with 25% of RDF which is significant but our objective is to quantify the potential reduction in GHG emission by replacing it with RDF(ranging from 25% to 50%) and also analyze the economic benefits of RDF utilization in cement production, including cost savings on fossil fuel. 2 1.Introduction 1.1 What is Carbon Emission? As we all know that Carbon dioxide is naturally present in the atmosphere as part of the Earth's carbon cycle (the natural circulation of carbon among the atmosphere, oceans, soil, plants, and animals) (Carbon Dioxide Emissions | US EPA, 2025)and these carbon compounds trap heat in the atmosphere resulting in global warming and releases gases like carbon dioxide ,methane,nitrous oxide,hydro fluro carbon,perfluro carbons and sulphur hexa fluoride and this process of emitting of gas is know as carbon emission. 1.2 Sources of Carbon Emission (Devi, 2024) Fossil Fuels: The burning of coal, oil, and natural gas for electricity, heat, and transportation is the largest source of carbon emissions. Power plants, vehicles, and industrial facilities are primary contributers. Industrial Processes: Certain industries, such as cement, steel, and chemical production, emit significant amounts of CO2 during manufacturing processes. Deforestation: Trees absorb CO2 from the atmosphere, so cutting down forests for agriculture, logging, or urban development reduces this carbon sink, increasing atmospheric CO2 levels. Agriculture: Agricultural practices, including livestock production and rice paddies, release other potent greenhouse gases like methane (CH4) and nitrous oxide (N2O), contributing indirectly to the overall carbon footprint. Waste Management: Landfills and waste treatment plants emit methane, a potent greenhouse gas, as organic waste decomposes anaerobically. Improper waste management exacerbates this issue. Residential and Commercial: Heating, cooling, and energy use in buildings contribute significantly to carbon emissions, especially in urban areas with high energy demands. 3 1.3 Overall Impact of Carbon Emission in Nature (Devi, 2024) Climate Change: Increased carbon emissions enhance the greenhouse effect, leading to global warming. This results in rising global temperatures, melting polar ice caps, and more frequent and severe weather events like hurricanes, droughts, and floods. Ocean Acidification: CO2 is absorbed by oceans, forming carbonic acid and lowering pH levels. This process affects marine life, particularly organisms with calcium carbonate shells or skeletons, such as coral reefs and shellfish. Public Health: Higher temperatures and altered weather patterns can lead to health issues, including heat-related illnesses, respiratory problems from increased air pollution, and the spread of diseases. Ecosystems and Biodiversity: Climate change disrupts habitats and ecosystems, leading to shifts in species distribution, altered migration patterns, and increased risk of extinction for many species. Economic Impacts: Climate change affects agriculture, infrastructure, and overall economic stability. Extreme weather events can damage crops, homes, and businesses, leading to financial losses and increased costs for recovery and adaptation. Water Resources: Changes in precipitation patterns and the melting of glaciers affect freshwater availability, impacting agriculture, drinking water supplies, and hydroelectric power generation. 1.4 Impact of Carbon Emission From Cement industry The cement industry is one of the most energy-intensive industrial sectors and is responsible for approximately 7–8% of global CO₂ emissions (Ali et al., 2011). These emissions predominantly result from the calcination of limestone and the combustion of fossil fuels needed to reach the high temperatures required during clinker production. (Azam et al., 2019). At the same time, the increasing generation of municipal solid waste (MSW) presents a significant environmental challenge. Current MSW disposal practices includes landfilling, which contribute to pollution and the release of methane—a potent greenhouse gas. In this context, the co-processing of MSW in the form of Refuse-Derived Fuel (RDF) in cement kilns represents a dual-benefit strategy. It addresses the dual challenges of reducing greenhouse gas (GHG) emissions from the cement industry and improving waste management systems by diverting waste from landfills(Bahor et al., 2009). This study investigates the feasibility, efficiency, and sustainability of utilizing RDF derived from MSW as an alternative fuel in cement manufacturing. It aims to assess RDF’s potential to reduce CO₂ emissions, enhance energy efficiency, and support circular economy principles through sustainable waste reuse. 4 1.5 Impact of Carbon Emission Due to Landfill Environmental Impact of Waste Management due to Solid waste treatment and disposal contribute significantly to carbon emissions, raising concerns about their environmental sustainability in Malaysia. Need for Sustainable Waste Solutions – Assessing the carbon footprint of different waste treatment methods is crucial for identifying eco-friendly and efficient disposal techniques to minimize environmental impact. High Carbon Emissions from Landfills – The study found that landfill disposal is the largest contributor to carbon footprint emissions among waste treatment methods in Malaysia.so one must dispose waste in proper such that landfill does not cause emissions 2. Problem Statement The cement industry is a major contributor to global greenhouse gas (GHG) emissions, responsible for CO₂ emissions. These emissions primarily arise from the calcination of limestone and the combustion of fossil fuels to achieve the high temperatures required in clinker production (Ali et al., 2011). Simultaneously, the management of municipal solid waste (MSW) presents a growing environmental challenge, with landfilling and incineration contributing to pollution and methane emissions (Sharma & Jain, 2018). The successful reuse of MSW as an alternative fuel in cement kilns presents a dual opportunity: reducing GHG emissions from both the cement sector and waste management systems (Tihin et al., 2023). However, significant challenges exist in ensuring the feasibility, efficiency, and sustainability of MSW co-processing, including concerns over emission control, material composition, and regulatory compliance. This study seeks to explore the potential of MSW-derived fuels in cement production, assessing their impact on emissions reduction, energy efficiency, and overall environmental benefits. 3 Objectives To assess the usage of municipal solid waste (MSW) as an alternative fuel in cement Industries. To quantify the potential reduction in GHG emission through substitution of petcoke with combustible RDF. To analyze the economic benefits of MSW utilization in cement production. 5 4.Methodology Adopted 1. Data Collection Primary data were collected through field visits to both municipal waste management authority and cement manufacturing plant. From the municipal entity ( Hubballi-Dharwad Municipal Corporation) list of data collected were: Number of wards Total dry waste generated Total dry waste processed Wet waste generated Wet waste processed Waste composition Daily waste generated Quantity of waste produced Significant data were collected from field visit to J.K Super Cement, Muddapur. The data Collected were: Quantity of petcoke used Quantity of Alternate fuel consumption Calorific values Daily Cement production 2. Waste Analysis A comprehensive analysis data of municipal solid waste (MSW) was provided by the Municipal corporation from both Hubballi-Dharwad Municipal Corporation to identify components suitable for RDF production. This involved categorizing the MSW into key types such as plastics, wood, rubber, and leather. Furthermore, the physical characteristics and chemical characteristics (calorific value) of these specific waste streams were provided to assess their suitability as an alternative fuel source. 3. Emission Analysis Emission analysis was performed to quantify the energy contribution of petcoke currently used in the cement clinker production process. This assessment established a baseline for energy consumption, allowing for a comparative evaluation of the potential energy contribution of RDF. The goal was to determine the equivalent amount of RDF required to substitute a given quantity of petcoke while maintaining the necessary thermal energy for clinkerization. 6 4. Cost Analysis The economic viability of the proposed RDF integration was evaluated through a detailed cost analysis. This included assessing the price of RDF, petcoke and identifying potential cost savings. Furthermore, the analysis explored how the adoption of RDF could contribute to achieving circular economy principles thereby minimizing overall environmental and economic. 5.Calculations COST ANALYSIS(25%) price of RDF=2500 Rs price of petcoke/ton =13800 Rs. Cost of 100% Petcoke = 44850000 Rs. Cost of Fuel (RDF + Petcoke) = 35668750 Rs. Reduction rate in Cost of fuel is (in %) = 20.471 Table 1. Carbon emission analysis (25%) Type of RDF Total Quantity of Petcoke used (Traditional Fuel) Total quantity of Petcoke Replaced with RDF(Purely Plastic) Total quantity of Petcoke Replaced with RDF(Paper and Cardboard) Total quantity of Petcoke Replaced with RDF(Purely Textile waste) Total quantity of Petcoke Replaced with RDF(Purely Rubber and Leather) Quantity Unit Emission Factor Unit Total Emission Unit 2437.5 Tonnes 3.3 CO2e/Kg 8254768.47 CO2e 888.333 Tonnes 3 CO2e/Kg 2664999 CO2e 1666.562 Tonnes 1.6 CO2e/Kg 2665500 CO2e 1480.56 Tonnes 2.15 CO2e/Kg 3183194.44 CO2e 1110.42 Tonnes 2.65 CO2e/Kg 2942604.17 CO2e 7 COST ANALYSIS(30%) Price of RDF = 2500 Rs Price of Petcoke/ton = 13800 Rs. Cost of 100% Petcoke = 44850000 Rs. Cost of Fuel (RDF + Petcoke) = 33832500 Rs Reduction rate in Cost of fuel is (in %) = 24.565 Table 2. Carbon emission analysis (30%) Type of RDF Total Quantity of Petcoke used (Traditional Fuel) Total quantity of Petcoke Replaced with RDF(Purely Plastic) Total quantity of Petcoke Replaced with RDF(Paper and Cardboard) Total quantity of Petcoke Replaced with RDF(Purely Textile waste) Total quantity of Petcoke Replaced with RDF(Purely Rubber and Leather) Quantity Unit Emission Factor Unit Total Emission Unit 2275 Tonnes 3.3 CO2e/kg 7704.451 TCO2e 1066 Tonnes 3 CO2e/Kg 3198 TCO2e 1998.75 Tonnes 1.6 CO2e/Kg 3198 TCO2e 1776.67 Tonnes 2.15 CO2e/Kg 3819.833 TCO2e 1332.5 2.65 CO2e/Kg 3531.125 TCO2e Tonnes 8 COST ANALYSIS price of RDF = 2500 Rs price of petcoke/ton = 13800 Rs. Cost of Petcoke = 44850000 Rs. Cost of Fuel (RDF + Petcoke) = 31996250 Rs Reduction rate in Cost of fuel is (in %)=28.659 Table 3. Carbon emission analysis (35%) Type of RDF Quantity Unit Emission Factor Unit Total Emission Unit Total Quantity of Petcoke used (Traditional Fuel) 2112.5 Tonnes 3.3 CO2e/Kg 7154.132 TCO2e Total quantity of Petcoke Replaced with RDF(Purely Plastic) 1243.67 Tonnes 3 CO2e/Kg 3731 TCO2e Total quantity of Petcoke Replaced with RDF(Paper and Cardboard) 2331.88 Tonnes 1.6 CO2e/Kg 3731 TCO2e Total quantity of Petcoke Replaced with RDF(Purely Textile waste) 2072.78 Tonnes 2.15 CO2e/Kg 4456.472 TCO2e Total quantity of Petcoke Replaced with RDF(Purely Rubber and Leather) 1554.58 Tonnes 2.65 CO2e/Kg 4119.645 TCO2e 9 COST ANALYSIS price of RDF = 2500 Rs (1000 waste1000transportation500 handling cost) price of petcoke/ton = 13800 Rs. Cost of Petcoke = 44850000 Rs. Cost of Fuel (RDF + Petcoke) = 30160000 Rs Reduction rate in Cost of fuel is (in %) = 32.753 Table 4. Carbon emission analysis (40%) Quantity Unit Emission Factor Unit Total Emission Unit 1950 Tonnes 3.3 CO2e/Kg 6603.814 TCO2e 1421.33 Tonnes 3 CO2e/Kg 4264 TCO2e Total quantity of Petcoke Replaced with RDF(Paper and Cardboard) 2665 Tonnes 1.6 CO2e/Kg 4264 TCO2e Total quantity of Petcoke Replaced with RDF(Purely Textile waste) 2368.89 Tonnes 2.15 CO2e/Kg 6093.111 TCO2e Total quantity of Petcoke Replaced with RDF(Purely Rubber and Leather) 1776.67 Tonnes 2.65 CO2e/Kg 4708.166 TCO2e Type of RDF Total Quantity of Petcoke used (Traditional Fuel) Total quantity of Petcoke Replaced with RDF(Purely Plastic) 10 COST ANALYSIS price of RDF = 2500 Rs price of petcoke/ton = 13800 Rs. Cost of Petcoke = 44850000 Rs. Cost of Fuel (RDF + Petcoke) = 28323750 Rs Reduction rate in Cost of fuel is (in %) = 36.847 Type of RDF Quantity Unit Total Quantity of Petcoke used 1950 Tonnes (Traditional Fuel) Total quantity of Petcoke Replaced with RDF(Purely 1598.999 Tonnes Plastic) Emission Factor Unit Total Emission Unit 3.3 CO2e/Kg 6435 TCO2e 3 CO2e/Kg 4796.997 TCO2e Total quantity of Petcoke Replaced with RDF(Paper and Cardboard) 2998.125 Tonnes 1.6 CO2e/Kg 4797 TCO2e Total quantity of Petcoke Replaced with RDF(Purely Textile waste) 2664.967 Tonnes 2.15 CO2e/Kg 5729.680 TCO2e Total quantity of Petcoke Replaced with RDF(Purely Rubber and Leather) 1998.74 2.65 CO2e/Kg 5296.661 TCO2e Tonnes 11 COST ANALYSIS price of RDF = 2500 Rs price of petcoke/ton = 13800 Rs. Cost of Petcoke = 44850000 Rs. Cost of Fuel (RDF + Petcoke) = 26487500 Rs Reduction rate in Cost of fuel is (in %) = 40.94 Table 5. Carbon emission analysis (50%) TYPE OF RDF Quantity Unit Emission Factor Unit Total Emission Unit Total Quantity of Petcoke used (Traditional Fuel) 1625 Tonnes 3.3 CO2e/Kg 5503.178 TCO2e Total quantity of Petcoke Replaced with RDF(Purely Plastic) 1776.67 Tonnes 3 CO2e/Kg 5330 TCO2e 3331.25 Tonnes 1.6 CO2e/Kg 5330 TCO2e 2961.11 Tonnes 2.15 CO2e/Kg 6366.388 TCO2e 2220.83 Tonnes 2.65 CO2e/Kg 5885.208 TCO2e Total quantity of Petcoke Replaced with RDF(Paper and Cardboard) Total quantity of Petcoke Replaced with RDF(Purely Textile waste) Total quantity of Petcoke Replaced with RDF(Purely Rubber and Leather) 12 6.Results and Discussion Case 1: Comparasion Of RDF (Traditional fuel) and their carbon emission Emission(tonnesCo2e) Carbon Emissions 9000 8254,768 7704,451 8000 7154,133 6603,815 7000 6053,497 5503,179 6000 5000 4000 3000 2000 1000 0 25 30 35 40 45 50 Type of rdf (traditional fuel) used in % Figure 1. Carbon emission for traditional fuel for different percentage RDF use Discussion: From figure 1 we come to know that as we increase the percentage of RDF the amount of carbon emission decreases,thereby by decreasing the usage of petcoke or traditional fuel in cement industr 13 Case 2: Comparasion Of RDF (Plastic) and their carbon emission Carbon Emission Emission (TonnesCo2e) 6000 5330 4797 5000 4264 3731 4000 3000 3198 2665 2000 1000 0 25 30 35 40 45 Type of RDF (plastic) used in % 50 Figure 2. Carbon emission for Plastic for different percentage RDF use Discussion: From figure 2 we come to know that as we increase the percentage of RDF the amount of carbon emission increases ,thereby by increasing the usage of plastic in place of petcoke as an alternative in cement industry. Case 3: Comparasion Of RDF (Paper and Cardboard) and their carbon emission 14 Carbon Emission Emission (TonnesCo2e) 6000 5330 4797 5000 4264 3731 4000 3000 3198 2665 2000 1000 0 25 30 35 40 45 50 Type of RDF (Paper and Cardboard) used in % Figure 3. Carbon emission for Paper and Cardboard for different percentage RDF use Discussion: From figure 3 we come to know that as we increase the percentage of RDF the amount of carbon emission increases ,thereby by increasing the usage of paper and cardboard in place of petcoke as an alternative in cement industry. Case 4: Comparasion Of RDF (Textile) and their carbon emission 15 Carbon Emission Emissions (Tonnes Co2e) 7000 6366,389 5729,75 6000 5093,111 5000 4000 4456,472 3819,833 3183,194 3000 2000 1000 0 25 30 35 40 45 Type of Rdf (textile) used in % 50 Figure 4. Carbon emission for textile for different percentage RDF use Discussion: From figure 4 we come to know that as we increase the percentage of RDF the amount of carbon emission increases ,thereby by increasing the usage of textile waste in place of petcoke as an alternative in cement industry. Case 5: Comparasion Of RDF (Rubber and Leather) and their carbon emission 16 Carbon Emission Emission(Tonnes Co2e) 7000 5885,203 6000 5296,688 4708,167 5000 4119,646 3531,125 4000 3000 2942,604 2000 1000 0 25 30 35 40 45 Type of RDF(rubber and leather) used in % 50 Figure 5. Carbon emission for Rubber and leather for different percentage RDF use Discussion: From figure 5 we come to know that as we increase the percentage of RDF the amount of carbon emission increases ,thereby by increasing the usage of leather and cardboard waste in place of petcoke as an alternative in cement industry. 17 Case 6: Cost Analysis Cost Analysis Reduction rate in Cost of fuel (in %) 45 40,94 40 36,848 32,754 35 28,659 30 25 24,565 20,471 20 15 10 5 0 25 30 35 40 45 Percentage(%) of RDF used 50 Figure 6. Cost Analysis for increase in percentage of RDF Discussion: From figure 6 we come to know that as we increase the percentage of RDF the amount of fuel cost reduces for each 5 % increase in percentage,thereby reducing suggesting that higher is the percentage of RDF used lower is the cost of fuel. 18 7.Conclusion Replacing pet coke with RDF in the cement industry can be beneficial due to its potential for cost savings and environmental advantages. RDF can also reduce reliance on fossil fuels and help in waste management. From the results we can conclude that replacing pet coke with 50% of RDF results in higher rate in reduction of fuel cost. It is observed that for every 5% increase in the RDF there is 4% increase in the reduction of fuel cost. From the results we can conclude that Traditional pet coke has the highest emission and plastic has the least emission amongst all and also plastic has higher calorific value than Rest of the RDF therefore we can use plastic for replacing Petcoke. Replacing 25% Petcoke with RDF Gives the least amount of emission. The project overall aims to meet the sustainable aspect, efficient consumption of resources and also stresses on the effects of GHG’s on the environment thereby satisfying the 5 USTDG sustainable development goals that are UNSTG no 7(Affordable and Clean Energy), UNSTG no 9(Industry, Innovation and Infrastructure), UNSTG no 11(Sustainable cities and comminites), UNSTG no 12(Responible Consumption and Production) and UNSTG no 13(Climate Action). 19 References Azam, M., Jahromy, S. S., Raza, W., Jordan, C., Harasek, M., & Winter, F. (2019). Comparison of the combustion characteristics and kinetic study of coal, municipal solid waste, and refuse‐ derived fuel: Model‐fitting methods. Energy Science & Engineering, 7(6), 2646–2657. https://doi.org/10.1002/ese3.450 Bahor, B., Van Brunt, M., Weitz, K., & Szurgot, A. (2009). Life-Cycle Assessment of Waste management greenhouse gas emissions using municipal waste Combustor data. 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