HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING DESIGN PRACTICES Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 1 of 79 Date December, 1999 Changes shown by ➧ CONTENTS Section Page SCOPE ............................................................................................................................................................ 2 REFERENCES ................................................................................................................................................ 2 GENERAL ....................................................................................................................................................... 2 THEORY AND DESIGN CONSIDERATIONS................................................................................................. 2 ZONES.................................................................................................................................................... 2 THE BASIC STEPS ................................................................................................................................ 3 SPECIAL DESIGN CONSIDERATIONS FOR DRUMLESS CONDENSERS ......................................... 8 DETAILED DESIGN PROCEDURE........................................................................................................ 8 VACUUM PIPESTILL OVERHEAD CONDENSER DESIGN PROCEDURE ........................................ 14 NOMENCLATURE ........................................................................................................................................ 15 TABLES Table 1 Table 2 Table 3 Table 4 FIGURES Figure 1 Figure 2A Figure 3B Figure 4 Figure 5 Figure 6A Figure 6B Figure 7A Figure 7B Figure 8 T-Q Curve Calculation Procedure....................................................................................... 19 Calculation Procedure For Condenser Design.................................................................... 21 Wide-Cut Condenser Design Sample Calculation .............................................................. 51 A Sample Condenser Design ............................................................................................. 55 Typical Heat Release (“T-Q") Curve (for Wide-Cut Hydrocarbons in the Presence of Steam) .................................................................................................. 70 Sample Flash Curve and Tds Plot ...................................................................................... 71 Vapor Pressure of Hydrocarbons (METRIC)....................................................................... 74 Average Vapor Quantity in Condensers (or Reboilers)....................................................... 75 Shell-Side Heat Transfer for Partial Condensation of Wide Cuts (Not Recommended for Definitive Designs)........................................................................ 76 Flash Curve Corrections ..................................................................................................... 77 Flash Curve Corrections ..................................................................................................... 77 Enthalpy of Water Above 32°F ........................................................................................... 78 Enthalpy of Water Above 0°C ............................................................................................. 78 Heat Transfer Coefficient for Fluids in Tubes ..................................................................... 79 Revision Memo 12/99 Minor revisions and updated information throughout the section. EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES Section CALCULATION PROCEDURE, CONDENSATION Page IX-F HEAT EXCHANGE EQUIPMENT 2 of 79 Date December, 1999 PROPRIETARY INFORMATION - For Authorized Company Use Only EXXON ENGINEERING SCOPE This section presents design considerations and the recommended manual design procedure for shell and tube condensers. REFERENCES 4. 5. Gloyer, W., Industrial and Engr. Chemistry, 42, 7, 1361, July, 1950. Devore, A., Petroleum Refiner, 38, 6, 205, June, 1959. Akers, Deans, Crosser, Condensing Heat Transfer Within Horizontal Tubes, Presented at the Second National Heat Transfer Conference, AIChE-ASME, Chicago, Illinois, August 18 - 21, 1958. Diehl, J. E. and Uhruh, C. H., Petroleum Refiner, 36, 10, 124, October 1959. Chenoweth, J. M. and Martin, M. W., Petroleum Refiner, 34, 151, October 1955. 6. 7. Heat Exchange Institute (HEI) Standards for Steam Surface Condensers. Perry's Chemical Engineers' Handbook, 6th Ed. 1. 2. 3. GENERAL ➧ ➧ The same basic approach that is used to design liquid-liquid exchangers is also used to design condensers. This approach uses a trial-and-error calculation to balance an assumed exchanger size against a calculated size, while staying within the prescribed limits of pressure drop. The basic difference lies in the so-called “zoning" of the condenser. Zoning is necessary because the concept of LMTD (based on the entire heat exchanger) is invalid whenever the heat transfer mechanisms vary from one region to another within the exchanger. The LMTD concept assumes that the heat transfer coefficients and the specific heats remain constant for both fluids. This is not the case for condensers. However, we may break down the exchanger into a number of zones and the LMTD concept can be applied separately in each of these zones. These zones are selected in a manner that the heat transfer coefficients and the specific heats (represented by the slope of heat release (T-Q) curve may be assumed to be constant. Therefore, all phase-change points, such as dew points (both hydrocarbon and steam) and bubble point define a start of a new zone. Additional zones may be required if the slope of the T-Q curve varies appreciably. It should be noted here that this discussion is primarily concerned with the more difficult case of condensing a wide-cut hydrocarbon in the presence of steam. For narrow cuts [15 to 20°F (8 to 11°C)], zoning is usually unnecessary and the following method simplifies considerably. HTRI has developed updated empirical correlations and procedures for computer analysis, which are explained in their design manual and reports. For design and rating of condensers, the CST-3 Computer Program is recommended. This program may be used stand-alone, or through the heat exchanger network analysis program HEXTRAN. THEORY AND DESIGN CONSIDERATIONS ZONES In setting up the zones, one assumes that the heat transfer coefficient is constant within the zone and that heat release is directly proportional to temperature change within the zone. One can see from this that the larger the number of condenser zones, the more accurate would be the condenser design. Unfortunately, the calculation of each zone is so time consuming that, for hand calculation, it is impractical to set up more than two or three zones. As shown in Figure 1, the usual zones are: 1. Vapor cooling. 2. Vapor cooling + hydrocarbon condensation and subcooling. 3. Vapor cooling + water condensation and subcooling + hydrocarbon condensation and subcooling. Figure 1 is somewhat simplified, in that the coolant is shown for a one-tube-pass unit. In this typical sequence, the hydrocarbon dew point is above the steam dew point. If the steam dew point should occur first, Zone 2 is essentially eliminated. When better accuracy is desirable, Zone 3 is sometimes divided into two “sub-zones" of roughly equal heat duty. In the absence of desuperheating, steam condensation or any other sharp break in the heat release curve, one condenser zone is adequate. EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING DESIGN PRACTICES Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 3 of 79 Date December, 1999 THEORY AND DESIGN CONSIDERATIONS (Cont) THE BASIC STEPS The following steps are basic to the design of a unit for condensing wide-cut hydrocarbons in the presence of steam. 1. Determine the hydrocarbon dew point. 2. Determine the steam dew point. 3. Determine the heat released in each zone. 4. Determine the simple LMTD for each zone, then ∆tew (weighted effective log mean temperature deference, °F or °C). 5. Estimate an overall coefficient (i.e., total area) for the condenser; determine mechanical features. 6. Calculate area required for each zone; sum the area. 7. Adjust mechanical features of the unit until the assumed total area is equal to the sum of the areas calculated for each zone. These basic steps will next be discussed generally. Dew Points; The Flash Curve - For wide-cut condensation, the hydrocarbon dew point is easily found by trial-and-error reductions in temperature to find the point where hydrocarbon vapor pressure equals its known partial pressure. (For the usual case of a fractionator overhead, the hydrocarbon is already at its dew point.) The steam dew point is more difficult, since the total number of moles of vapor changes between the hydrocarbon dew point and the steam dew point. This change in composition must be determined before the steam dew point can be calculated. It is usual practice to assume that as condensation proceeds, the vapor and liquid maintain an equilibrium composition. Hence, the composition and thermal properties of the system are obtained from equilibrium flash calculations. These calculations predict a “flash curve," which is a plot of temperature vs. “percent off" (percent not condensed). The design manual method for estimating the flash curve is a simplification of the Exxon Blue Book method. The entire flash curve is not constructed. Instead, several points along the volumetric flash curve are calculated. These are plotted and connected with straight lines. The molal flash curve lies slightly below the volumetric curve, and the weight flash curve lies above the volumetric curve. For the sake of simplification, this separation of the curves is assumed proportional to the width of certain boiling ranges in the cut. The three curves are plotted on the same graph and used to predict composition and temperature of the vapor and liquid phases as condensation proceeds. An example is shown in Figure 2. Since these curves represent conditions at one atmosphere partial pressure, an alignment chart is included to convert to the pressure of the condensing system (Figure 3). The steam dew point is then found by a trial-and-error reduction in the system temperature to find the temperature, where water vapor pressure equals its calculated partial pressure. The method is described in detail in Table 1. Heat Release in Each Zone - The following individual heat duties are calculated in each zone in which they occur. All duties occur simultaneously in the third zone only. 1. Cool entering liquid. 2. Cool vapor and gas that do not condense. 3. Cool condensing HC vapor. 4. Cool hydrocarbon condensate. 5. Cool condensing steam. 6. Cool steam condensate. 7. Remove latent heat of hydrocarbon. 8. Remove latent heat of steam. To calculate Duties 3, 4, 5, and 6, one assumes that 50% (or the average quantity) of the material is cooled through 100% of the temperature change in the zone. Although enthalpy charts can be used for these calculations, the use of average specific heats and average latent heats is adequate for most cases. Note that when enthalpy charts are used, Items 7 and 8 must be calculated at the average temperature (rather than inlet to outlet conditions) to avoid duplicating the sensible-heat portion of the duty. Temperature Driving Force - After the zone heat duties have been calculated, the weighted average LMTD (∆tew) can be calculated. This is done by calculating the LMTD for each zone and then “weighting" the LMTD according to the amount of heat transferred in the zone. The conventional equation is as follows: ∆t ew = Q q dh q ds q + + sc ∆t dh ∆t ds ∆t sc EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. Eq. (1) DESIGN PRACTICES Section CALCULATION PROCEDURE, CONDENSATION Page IX-F HEAT EXCHANGE EQUIPMENT 4 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING THEORY AND DESIGN CONSIDERATIONS (Cont) For explanation of symbols, see NOMENCLATURE. Each zone ∆t is corrected for noncountercurrent flow by multiplying by Fn from Figure 2 of Section IX-D. Fn is calculated from the zone terminal temperatures.1 This use of Fn is not theoretically sound but is justified, as a matter of convention, to make sure that enough shell passes are specified for the design temperature cross. The use of this equation for weighting ∆t's is strictly a matter of industrial convention. It gives the true value of ∆tew only when the coefficient is constant over the entire condenser; and this condition, of course, almost never prevails. But since the equation has been widely adopted, the use of other methods for weighting ∆t's might be misleading to exchanger suppliers. In reality, ∆tew does not enter into the condenser design and its value is of no real importance. The design is based on a summation of zone areas which are calculated from the individual zone ∆t's. The overall ∆tew is estimated only so that an overall average Uo can be reported. Heat Transfer Coefficients, Shell-Side Condensation - From an analytical viewpoint, a condenser is an extremely complex piece of equipment. The approach used in this manual is sometimes called the “Gloyer" (Reference 1) analysis, named after the first person to describe it in the literature. This method is not a theoretical analysis, but an empirical attempt to consider the various phenomena which occur simultaneously in a condenser. This approach considers the following mechanisms: 1. Vapor cooled by forced convection. 2. Liquid cooled by “dripping" from tube to tube. 3. Liquid cooled by forced convection along the bottom of the shell. 4. Condensation. In each zone of the condenser, a heat transfer coefficient “h" is calculated for each of the above mechanisms. The heat transfer coefficient for the zone is then evaluated by weighting and averaging the individual coefficients: Q zone q1 q + ... + 4 h1 h4 h zone = Eq. (2) (Subscripts refer to above mechanisms.) The overall zone coefficient is then calculated from the usual resistance equation: 1 U zone = 1 + ro + rw + rio + R io h zone Eq. (3) Q zone Uzone ∆t zone Eq. (4) and the area from A zone = The total area of the condenser is simply the sum of the zone areas. To calculate the coefficients for vapor cooling and “bottom flow" liquid cooling, one uses the average vapor and liquid quantities in the zone. These quantities are determined with the aid of Figure 4. This chart corrects for the variations in ∆T (between tubeside and shell side) with tube length. The usual relations for single-phase heat transfer are then used to calculate coefficients. The coefficient for “drip cooling" is taken as 1.5 times the condensing coefficient. It is arbitrarily assumed that half of the liquid cooling duty is by “drip cooling" and half by “bottom flow" (for zones with all vapor entering). To calculate the condensing coefficient, the following modifications of the Nusselt equation recommended by Devore should be used (Reference 2). 1 For hydrofiner effluent-hydrofiner feed exchangers and other similar services where there is a “pinch” in the T-Q curves of the two streams, each shell of the final arrangement should be checked graphically for a temperature cross (i.e., plot shell-side and tube-side temperatures vs. duty curves on a single graph and compare inlet vs. outlet temperatures for each shell). If a temperature cross occurs, either the shell areas or the number of shells should be adjusted to remove the cross. EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING DESIGN PRACTICES Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 5 of 79 Date December, 1999 THEORY AND DESIGN CONSIDERATIONS (Cont) For Vertical Tubes 1/ 3 1.04 x 10 4 2 k f sf hλ = 1 / 3 Γ µf (Customary) Eq. (5) (Metric) Eq. (5)M or 1/ 3 s2 254 hλ = 1 / 3 k f f µf Γ where: Γ = 12 Wc π Nt do (Customary) Eq. (6) Γ = 1000 Wc π Nt do (Metric) Eq. (6)M or This term is usually called “tube loading." The equation is restricted to: Γ ≤ 1090 µf (Customary) Γ ≤ 450 µf (Metric) or For Horizontal Tubes s2 8.33 x 10 3 kf f h′λ = µf Γ 1/ 3 1/ 3 (Customary) Eq. (7) (Metric) Eq. (7)M or s2 204 k f f h′λ = µf Γ 1/ 3 1/ 3 where: Γ = Wc L c ns Eq. (8) The term ns is the number of “condensate streams" in the bundle. ns = 1.29 Nt0.480 for square tube layout, 90°. ns = 2.08 Nt0.495 for rotated triangular layout, 60°. ns = 1.02 Nt0.519 for triangular layout, 30°. ns = 1.37 Nt0.518 for rotated square layout, 45°. EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F 6 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING THEORY AND DESIGN CONSIDERATIONS (Cont) The term Lc is the length of tube on which condensation occurs. If a condenser consists of one zone, Lc equals the tube length. Otherwise Lc is the fraction of the total tube length included in the zone in question. (If there are two shells in series, note that one zone might include 0.5L, the next zone 1.5L.) The paper by Devore suggests that the value of h′λ be increased by a multiplier which depends essentially on the number of tubes in the bundle. For a typical bundle, the value of this so-called “turbulence factor" is 1.5 to 2.5. This has not been included in this procedure. Instead, a modification is recommended which will relate the condenser design to vapor mass velocity. (An effect of mass velocity has been recognized for some time.) A great deal of Exxon data on wide-cut condensation show that the overall outside coefficient varies linearly with Gx, where x is between 0.7 and 0.9. A similar effect probably holds for narrow cuts as well. Based on this, the condensing coefficient for horizontal bundles should be adjusted as follows: G h λ = h′λ v 5 0.70 (Customary) Eq. (9) (Metric) Eq. (9)M or G h λ = h ′λ v 24.4 0.70 and h λ max = 2.0 h′λ Eq. (10) Where Gv is the average vapor mass velocity in the zone. Note that this mass velocity correction is not recommended for purecomponent condensation. In zones where both steam and hydrocarbon are condensing, the hydrocarbon wets the tubes preferentially. This forces the steam to condense on the hydrocarbon condensate film and the condensing coefficient for steam equals the condensing coefficient for the hydrocarbon. Empirical Equation for Shell-Side Condensation - Not Recommended for Definitive Designs - Exxon has analyzed a considerable amount of data on wide-cut condensation. These analyses have resulted in an equation which fits the original data with an average accuracy of 10%. So far, however, the equation has not been tested on enough additional data to substantiate its use for definitive designs. The equation can be used for estimating coefficients and for checking condenser performance under various operating conditions. Because of its simplicity, it is hoped that an equation of this type will eventually be backed up by enough data to warrant use in design work. The equation for the shell-side condensing coefficient, which includes the shell-side fouling factor, is as follows: ln (h oc ) = 0.82 ln (g)G + f (α) − 0.002 Pi (Customary) Eq. (11) (Metric) Eq. (11)M or ln (h oc ) = 0.82 ln(G) + f (α) − 0.00029 Pi + 0.436 The function f(α) is shown in Figure 5. This curve shows that the shell-side coefficient first decreases sharply with increasing nocondensables, then slowly increases. “G" is inlet mass velocity and “Pi" is inlet pressure (absolute). The data analyzed include condensers in the following services: 1. Fluid coking - scrubber overhead. 2. Cat cracking - fractionator overhead. 3. Fluid hydroforming - scrubber overhead. 4. Pipestill overhead. 5. Prefractionator overhead. The total range of the variables is as follows: 1.47 < G < 20.9 lb/sec-ft2 0.008 < α < 0.896 19.2 < Pi < 205 psia (Customary) or 7.18 < G < 102 kg/s-m2 (Metric) (Customary) or 132 < Pi < 1410 kPa abs (Metric) The equation includes no data on narrow-cut condensation and will give answers much too low for such cases. EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING DESIGN PRACTICES Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 7 of 79 Date December, 1999 THEORY AND DESIGN CONSIDERATIONS (Cont) Heat Transfer Coefficient: Condensation on the Tube Side - Condensation inside the tubes is seldom used in industry. Hence, little is known about the heat transfer coefficients in such service. In general, the coefficients are lower than for shell-side condensation. If the condenser is vertical, Nusselt's analysis is undoubtedly as valid inside the tubes as on the outside. But in the usual case, such as an air-fin condenser, the unit would be horizontal. This tends to fill part of the tube cross-section with condensate, blanking some of the condensing area. This mechanism is completely outside of Nusselt's work. The following empirical method has been proposed by Akers, Deans and Crosser (Reference 3). The method is based on data for condensing propane and Freon-12 in horizontal tubes. The authors correlated their data within about 20% by using an “equivalent" liquid mass velocity and the usual single-phase heat transfer relationships. Neither the Nusselt equation nor the Carpenter-Colburn equation would correlate the data. The basic equations are as follows: htλ = 5.03 Re1/3 Pr1/3 (12 kf / di) Re < 50,000 (Customary) Eq. (12) or htλ = 5.03 Re1/3 Pr1/3 (1000 kf / di) htλ = 0.0265 Re0.8 Pr1/3 (12 kf / di) (Metric) Re > 50,000 (Customary) Eq. (12)M Eq. (13) or htλ = 0.0265 Re0.8 Pr1/3 (1000 kf / di) (Metric) Eq. (13)M Re = Ge di 29 µ (Customary) Eq. (14) Re = Ge di 1000 µ (Metric) Eq. (14)M or ρ G e = G′l + G′v l ρv 1/ 2 Eq. (15) G′l and G′v are superficial average mass velocities of the liquid and vapor, respectively, based on the total flow area. The Nusselt, Prandtl and Reynolds numbers are in dimensionless forms. Physical properties used are those of the condensate film at average film temperature. It was found that these equations correlated the data for vertical, inclined, and horizontal tubes. Eqs. (12) through (15) are for the condensing coefficient only, and they would be applicable by themselves to narrow-cut condensation. When condensing a wide cut, the designer should follow the principles used on the shell side for wide cuts and calculate coefficients for gas and liquid cooling. For gas cooling, use the average vapor velocity in the zone to calculate a singlephase vapor heat transfer coefficient. The liquid cooling coefficient may be assumed to be equal to the condensing coefficient. There is, of course, no drip cooling and hence no required breakdown of the liquid cooling duty. Pressure Drop - Pressure drop in condensers is a complex variation of two-phase flow that has not been successfully analyzed theoretically. The data are amenable to correlation, however, and such correlations are frequently reported in the literature. The recommended procedure treats the two-phase system as a single phase, using the viscosity of the liquid and a density corresponding to the average density for both phases. The weighted average density is evaluated for each zone based on the inlet and outlet volume flow rates, or Average density = 2 x Mass rate ( Vol. rate in) + ( Vol. rate out ) This calculation method is applicable for both tube-side and shell-side pressure drops using weighted average values of density and velocity. Both tube-side and shell-side pressure drops are evaluated by the “no change of phase" procedure as outlined in Section IX-D. EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES Section CALCULATION PROCEDURE, CONDENSATION Page IX-F HEAT EXCHANGE EQUIPMENT 8 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING THEORY AND DESIGN CONSIDERATIONS (Cont) ➧ The two-phase pressure drop calculated for each zone is multiplied by the ratio (Zone Area/Total Area) to estimate the zone pressure drop. The overall pressure drop is obtained by summing the zone pressure drops. This procedure is believed to be conservative, i.e., actual pressure drops should be equal to or less than the calculated values. In cases where pressure drop is expensive or where a much lower than expected pressure drop would cause process difficulties, an independent check can be made by use of the Lockhart & Martinelli correlation (see Perry's Chemical Engineers' Handbook, 6th Ed., pages 5-40 to 5-42). This method is considered to be the best available generalized correlation for two-phase pressure drop in a system with heat (mass) transfer taking place. However, the accuracy of this correlation is only ± 50%. Thus, the actual pressure drop could be anywhere between 50% and 150% of the calculated value. Also, the HTRI CST-3 computer program is incorporated into HEXTRAN program and is available for problems requiring detailed analysis. SPECIAL DESIGN CONSIDERATIONS FOR DRUMLESS CONDENSERS ➧ When drumless condensers are designed, the following design criteria should be followed: 1. The condenser surface should be 110% of the surface required for condensing in order to account for surface normally covered by liquid. 2. The condenser should be equipped with a 2 in. (50 mm) vent located as close to the liquid outlet end as practicable. 3. A pot for liquid-vapor separation should be located on the condenser outlet. Pots up to 14 in. (356 mm) diameter should be sized for a liquid velocity of 1 ft (0.3 m) per second. The velocity in pots 16 in. (406 mm) and larger should be limited to 1.5 ft (0.5 m) per second. The pot should be 3 to 5 ft (0.9 to 1.5 m) long. 4. The condenser shell should be equipped with a gauge glass covering the entire shell diameter and pot. 5. The condenser should be elevated sufficiently to satisfy pump NPSH requirements with the condenser pot empty. In any event, the bottom of the condenser shell should be a minimum of 20 ft (6 m) above grade. 6. An anti-vortex baffle should be installed in the condenser pot. 7. The condenser should be located with its liquid outlet end on the pump side of the structure. All pump suction piping should be continuously sloped downwards towards the pump. Horizontal runs on the pump suction piping should be sloped at least 2 in. per 100 ft (50 mm per 30 m). 8. Pump suction lines up to and including 3 in. (76 mm) diameter should not have a liquid velocity in excess of 1.5 ft/sec (0.5 m/s). Four to 8 in. lines should be limited to 2.25 ft/sec (0.7 m/s). For 10 in. (254 mm) diameter and larger sizes, the liquid velocity should not exceed 3.5 ft/sec (1.1 m/s). 9. Pumps should be heavy-duty refinery type. 10. Pumps should be equipped with a recirculation line returning upstream of the condenser. The recirculation line should be equipped with a block valve and a restriction orifice sized for 25% of the normal pump capacity. DETAILED DESIGN PROCEDURE Table 2 lists the step-by-step procedure in the form of a calculation sheet. Each step is discussed below. The condensation calculation procedure presented in this section is based on hydrocarbon (with or without small amounts of steam, less than 15% by weight) condensation. The procedure should not be used for the design of vacuum pipestill overhead condensers or steam surface condensers. A sizing procedure for vacuum pipestill overhead condensers is presented later in this section. Steam surface condensers should be sized using the procedures presented in the Heat Exchange Institute (HEI) Standards for Steam Surface Condensers. 1. Determine the inlet and outlet temperatures, t1, t2, T1 and T2. 2. Determine the minimum number of shells in series; Fn (Figure 2, Section IX-D) based on exchanger inlet and outlet temperatures equal to or greater than 0.8. 3. Determine the overall duty Q and the weighted overall LMTD, ∆tew. a. If a T-Q curve (temperature vs. heat release) has already been prepared, determine ∆tew as follows: (1) From the curve, determine Q, Tdh and qdh, Tds and qds and qsc. (2) Calculate tdh and tds. t dh = t 2 − ( t 2 − t1) qdh Q Eq. (16) t ds = t 2 − ( t 2 − t1) qdh + qds Q Eq. (17) EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 9 of 79 Date December, 1999 THEORY AND DESIGN CONSIDERATIONS (Cont) (3) Calculate ∆tdh, ∆tds and ∆tsc. These are the LMTDs in each of the three zones. Apply individual Fn's (Figure 2, Section IX-D) to each zone, as calculated from zone terminal conditions. (4) Calculate ∆tew ∆t ew = 4. Q qdh qds q + + sc ∆t dh ∆t ds ∆t sc b. If a T-Q curve is not available, the method outlined in Table 1 may be used. Estimate the total area required for the condenser. See Table 1, Section IX-C for typical values of Uo. A = Q / Uo ∆tew 5. 6. 7. Eq. (19) For the condensing side, estimate the pressure drop so that the baffle pitch (or number of tube passes) can be established. a. Calculate average mixture density ρ based on inlet and outlet flow volumes. b. Assume a value of Pb (or Np) and calculate ∆P. Use liquid viscosity at average condensing temperature with equations for no change of phase. Adjust Pb or Np to obtain desired approximate pressure drop. Note that this is an approximate pressure drop, used only in setting up Pb or Np. A definitive ∆P will be calculated later. c. 9. Eq. (18) Calculate area per shell, number of shells and number of tubes according to the usual method. Use the appropriate section of the manual to calculate the transfer coefficient and pressure drop for the noncondensing side. Calculate Uox, the overall coefficient neglecting the resistance on the condensing side. 1 = ro + rw + rio + (R o or R io ) U ox 8. From Eq. (1) Calculate Adh, the area required for the desuperheating zone of the condenser. a. Calculate the gas cooling coefficient (hgc) using the usual method of no change of phase. b. Calculate Udh and Adh. Udh = hgc Uox hgc + Uox Adh = qdh / Udh ∆tdh Eq. (20) Eq. (21) 10. Calculate Ads, the area required for the hydrocarbon condensation and steam desuperheating zone. a. Estimate the condensate film temperature in the zone, assuming no temperature drop across the vapor film. For Shell-Side Condensation U t f = t s − (1 / 2) ( t s − t1) 1 − zone U ox Eq. (22) For Tube-Side Condensation U t f = t t − (1 / 2) ( t t − t s ) 1 − zone U ox All temperatures refer to the zone only, note the overall condenser. EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. Eq. (23) DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F 10 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING THEORY AND DESIGN CONSIDERATIONS (Cont) b. Calculate W v, the average vapor flow rate in the zone. Use Figure 4. c. Calculate Wl , average liquid flow rate. Wl = W – W v Eq. (24) d. Determine µf for the vapor; and µf, and sf for the liquid. e. Calculate h′ λ the condensing coefficient. (1) If on the tube side, calculate Ge and Re, obtain f, and calculate htλ. G′v = Np Wv 19.6 N t di2 (Customary) Eq. (25) (Metric) Eq. (25)M (Customary) Eq. (26) (Metric) Eq. (26)M or G′v = 1.273 x 106 G′l = Np Wv N t di2 Np Wv 19.6 N t di2 or G′l = Np Wv N t di2 Ge = G′l + G′v ( ρl / ρv) 1/2 From Eq. (15) Re = Ge di 29 µ (Customary) From Eq. (14) Re = Ge di 1000 µ (Metric) From Eq. (14)M or Calculate htλ from Eq. (12) or (13). (2) If on the shell side, A. Vertical bundle Γ = 12 Wc π Nt do (Customary) From Eq. (6) Γ = 1000 Wc π Nt do (Metric) From Eq. (6)M or EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING DESIGN PRACTICES Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 11 of 79 Date December, 1999 THEORY AND DESIGN CONSIDERATIONS (Cont) 1/ 3 1.04 x 10 4 2 k f sf hλ = 1 / 3 Γ µf (Customary) From Eq. (5) (Metric) From Eq. (5)M or 1/ 3 hλ s2 254 = 1/ 3 k f f µf Γ If Γ / µ f is larger than 1,100 (or 450), the value of hλ is quite conservative. B. Horizontal bundle Calculate ns, the number of condensate streams in the bundle. ns = 1.29 Nt0.480 for square tube layout, 90° ns = 2.08 Nt0.495 for rotated triangular layout, 60° ns = 1.02 Nt0.519 for triangular layout, 30° ns = 1.37 Nt0.518 for rotated square layout, 45° Calculate Γ, the tube loading. For this step Ads must be assumed. The final calculated value of Ads should be checked back for agreement (10 to 15%) with the assumed value. Γ = Wc L c ns Lc = A ds (L − 0.5) Ns A (Customary) Eq. (27) Lc = A ds (L − 0.152) Ns A (Metric) Eq. (27)M From Eq. (8) or Calculate h′λ , the condensing coefficient uncorrected for vapor velocity. s2 8.33 x 10 3 kf f h′λ = µf Γ 1/ 3 1/ 3 (Customary) From Eq. (7) (Metric) From Eq. (7)M or s2 204 k f f h′λ = µf Γ 1/ 3 1/ 3 Calculate xv, the fraction of shell free–flow area occupied by the vapor. xv = 1 − xl W µ 1 = 1 + v v xl Wl µl Eq. (28) 0.111 ρl ρ v 0.555 EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. Eq. (29) DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F 12 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING THEORY AND DESIGN CONSIDERATIONS (Cont) Calculate average mass velocity of the vapor in the zone Gv = Wv 25 A x x v (Customary) Eq. (30) Gv = 106 Wv A x xv (Metric) Eq. (30)M or Calculate hλ G h λ = h′λ v 5 0.70 (Customary) From Eq. (9) (Metric) From Eq. (9)M or G h λ = h′λ v 24.4 0.70 h λ max = 2.0 h′λ f. From Eq. (10) Calculate hgc, the vapor cooling coefficient. (1) If on the shell side: Use Gv, the average vapor mass velocity, to calculate the uncorrected vapor cooling coefficient hgc. Use correlations for no change of phase. Use the same film temperature as calculated for the condensing coefficient. Correct for the fact that heat flowing through the gas film must also overcome resistance of the condensate film. C 1 1 = + 1 h gc hλ h′gc Eq. (31) where: T1 + T2 − tf 2 Wc C1 = 1 − Wv1 T1 − T2 Eq. (32) The factor “C1" helps account for the additional gas cooling surface available from liquid droplets, ripples, etc. The temperatures T1 and T2 refer to the zone inlet and outlet temperatures. The value of C1 should fall in the range of 0.5 to 1.0. If the calculated value of C1 is less than 0.5, set C1 equal to 0.5; if the calculated value of C1 is greater than 1.0, set C1 equal to 1.0. (2) If on the tube side: Calculate Gv. A. Calculate xv [see Eq. (28)] B. Gv = G′v / xv Eq. (33) Use Gv with the procedure for no change of phase and calculate h′ gc . Calculate hgc. C1 1 1 = + h gc hλ h ′gc EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. Eq. (34) HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING DESIGN PRACTICES Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 13 of 79 Date December, 1999 THEORY AND DESIGN CONSIDERATIONS (Cont) g. Calculate hlc , the liquid cooling coefficient. For vertical bundles, assume hlc = hλ. For horizontal bundles: (1) If on the shell side Calculate Gl Gl = Wl 25 A x x l (Customary) Eq. (35) Gl = 106 Wl A x xl (Metric) Eq. (35)M or Using Gl , with the procedure for no change of phase, calculate h'lc , liquid cooling obtained by “bottom flow." Calculate the liquid cooling obtained by “drip cooling." hdc = 1.5 hλ Eq. (36) Calculate hlc For all vapor entering; h lc = 2 h dc h′lc h dc + h′lc Eq. (37) For liquid + vapor to the zone; hlc = ( Wl + Wc ) hdc h′lc Wc Wc h′lc + Wl + hdc 2 2 Eq. (38) (2) If on the tube side hlc h. = hλ Calculate hds, the weighted zone coefficient on the condensing side. hds = i. qλ q + + lc hλ hgc hl c Eq. (40) hds Uox hds + Uox Eq. (41) qds Uds ∆t e( ds ) Eq. (42) Calculate Ads A ds = k. qds qgc Calculate Uds, the zone coefficient. Uds = j. Eq. (39) Compare Ads calculated here with Ads assumed to calculate Γ. If necessary, repeat calculation to obtain agreement. EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F 14 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING THEORY AND DESIGN CONSIDERATIONS (Cont) 11. Calculate Ads, the area required for the steam condensing zone. Calculations for this zone are performed in the same way as for the previous zone. Note the following: a. The condensing coefficient for steam equals the hydrocarbon condensing coefficient. b. The cooling coefficient for condensed steam equals the hydrocarbon liquid cooling coefficient.. 12. Calculate the total condenser area. A = Adh + Ads + Asc Eq. (43) 13. If the area calculated in the previous step equals the area estimated in Step (4), proceed to the next step. If the calculated area is not equal to the estimated area, repeat the calculation with a better estimated area until agreement is reached. 14. Calculate the overall coefficient, Uo. Uo = Q A ∆t ew Eq. (44) 15. Calculate the clean coefficient, Uc 1 1 = − rio − ro + 0.001 Uc Uo (Customary) Eq. (45) 1 1 = − rio − ro + 0.00018 Uc Uo (Metric) Eq. (45)M or 16. Calculate pressure drop on the condensing side. a. Refer to Step 8 and calculate two-phase pressure drops for the overall condenser at the average conditions of each zone. b. Calculate zone pressure drops c. A ∆Pzone = ∆Pat zone conditions zone A total Eq. (46) ∆P = ∆Pdh + ∆Pds + ∆Psc Eq. (47) Calculate ∆P VACUUM PIPESTILL OVERHEAD CONDENSER DESIGN PROCEDURE ➧ Since a vacuum pipestill overhead condenser heat duty primarily results from condensing steam, the detailed condenser calculation procedure presented in this section is not applicable for design of these units. However, the HEXTRAN Program with HTRI CST-3 program may be used. For preliminary hand calculations, when sizing a vacuum pipestill overhead condenser, the following calculation procedure is recommended. 1. 2. 3. ➧ 4. Use an overall heat transfer coefficient of 130 Btu/hr-ft2-°F or 738 W/m2-K. (Values between 110 to 130 Btu/hr-ft2-°F (625 and 738 W/m2-K) have been used for past designs.) Use the steam dew point temperature, rather than the hydrocarbon dew point temperature, as the condensing zone inlet temperature for calculating the effective temperature difference. Design for 3 to 12 mm Hg (0.4 to 1.6 kPa) pressure drop. The pressure drop should be estimated based on 1/2 the calculated pressure drop using inlet vapor conditions. (Past designs frequently employed divided flow, TEMA Type J, shells with double segmental, modified disk and donut, baffles at or near maximum baffle spacing to obtain low pressure drop values.) Estimate nozzle pressure drop based on three velocity heads for inlet and outlet nozzles. EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 15 of 79 Date December, 1999 NOMENCLATURE A Adh Ads Asc As Ax B1 B2 = = = = = = = = Total exchanger area, ft2 (m2) c = Specific heat at caloric temperature, Btu/lb-°F (kJ/kg-K) cf D Dt di do f Fbt Fn FF FJ Fs Ft Fv G Ge = = = = = = = = = = = = = = = Specific heat of the shell-side fluid at average film temperature, Btu/lb-°F (kJ/kg-K) Shell I.D., in. (mm) Diameter of tube bundle (“outer tube limit"), in. (mm) Tube I.D., in. (mm) Tube O.D., in. (mm) Fanning friction factor, dimensionless Correction factor to account for baffle type, dimensionless Correction factor for log mean temperature difference (due to partially concurrent flow), dimensionless F shell correction factor, dimensionless J shell correction factor, dimensionless Shell-side pressure drop correction factor, dimensionless Tube-side pressure drop correction factor, dimensionless Correlation factor used to determine average vapor flow, dimensionless Mass velocity, lb/sec-ft2 (kg/s-m2) Equivalent mass velocity of liquid and vapor in 2-phase flow (see Figure 4), lb/sec-ft2 (kg/s-m2) Gl = Average mass velocity of liquid, lb/sec-ft2 (kg/s-m2) G′l = Superficial mass velocity of liquid, lb/sec-ft2 (kg/s-m2) Gv = Average mass velocity of vapor, lb/sec-ft2 (kg/s-m2) G′v = Superficial mass velocity of vapor, lb/sec-ft2 (kg/s-m2) hdc = Liquid cooling coefficient resulting from “dripping" in the condenser, Btu/hr-ft2-°F (W/m2-K) hdh = Film coefficient for condensing side of desuperheating zone, Btu/hr-ft2-°F (W/m2-K) hds = Film coefficient for condensing side of hydrocarbon condensing zone, Btu/hr-ft2-°F (W/m2-K) hsc = Film coefficient for condensing side of steam condensing zone, Btu/hr-ft2-°F (W/m2-K) h′gc = Gas cooling coefficient uncorrected for condensate film resistance, Btu/hr-ft2-°F (W/m2-K) hgc = Gas cooling coefficient, Btu/hr-ft2-°F (W/m2-K) hio = Inside film coefficient corrected to outside area, Btu/hr-ft2-°F (W/m2-K) h′l c = Liquid cooling coefficient resulting from “bottom flow" in the condenser, Btu/hr-ft2-°F (W/m2-K) hl c = Weighted liquid cooling coefficient, Btu/hr-ft2-°F (W/m2-K), assuming half of liquid cooling is “drip" cooling and half is ho = Shell-side film coefficient no change of phase, Btu/hr-ft2-°F (W/m2-K) hoc = Shell-side condensing coefficient including fouling factor, Btu/hr-ft2-°F (W/m2-K) h′λ = Shell-side condensing film coefficient uncorrected for effect of vapor mass velocity, Btu/hr-ft2-°F (W/m2-K) hλ = Shell-side condensing film coefficient, Btu/hr-ft2-°F (W/m2-K) htλ = Tube-side condensing film coefficient, Btu/hr-ft2-°F (W/m2-K) Area of desuperheating zone, ft2 (m2) Area of hydrocarbon condensation and steam desuperheating zone, ft2 (m2) Area of steam condensation zone, ft2 (m2) Area/shell, ft2 (m2) Free flow area between shell baffles, in.2 (mm2) Bundle factor for shell-side heat transfer, dimensionless Bundle factor for shell-side pressure drop, dimensionless “bottom flow" cooling EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES Section CALCULATION PROCEDURE, CONDENSATION Page IX-F HEAT EXCHANGE EQUIPMENT 16 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 NOMENCLATURE (Cont) k = Thermal conductivity at caloric temperature, Btu/hr-ft-°F (W/m-K) kf = Thermal conductivity of fluid at average film temperature, Btu/hr-ft-°F (W/m-K) kw = Thermal conductivity of the tube metal at average tube temperature, Btu/hr-ft-°F (W/m-K) l = Tube thickness, ft (m) L Lc = = Tube length, ft (m) Length of tube exposed to condensation, ft (m) LMTD MW Nb Np Ns Nt Ntc Nu ns Pb Pi = = = = = = = = = = = Log mean temperature difference, °F (K) Molecular weight, lb/mol (kg/kmol) Number of shell baffles Number of tube passes per shell Number of shells in series Number of tubes in the bundle Number of tubes across the center line of the bundle Nusselt number, hd/k, dimensionless Number of condensate streams in the shell Baffle pitch, in. (mm) Inlet pressure, psia Pr Pt = = Prandtl number, cµ/k, dimensionless Tube pitch, in. (mm) ∆Pdh = Pressure drop in desuperheating zone, psi (kPa) ∆Pds = Pressure drop in hydrocarbon condensing zone, psi (kPa) ∆Psc = Pressure drop in steam condensing zone, psi (kPa) ∆Pt = Total tube-side pressure drop, psi (kPa) ∆Ptf = Tube pressure drop due to friction, psi/tube pass (kPa/tube pass) ∆Ptr = Tube pressure drop due to turns, psi/tube pass (kPa/tube pass) ∆Psf = Shell-side pressure drop due to friction, psi/shell (kPa/shell) ∆Psr = Shell-side pressure drop due to turns, psi/shell (kPa/shell) ∆Ps = Total shell-side pressure drop, psi (kPa) Q qdh qds qsc qgc = = = = = Total heat duty, Btu/hr (W) Heat duty in desuperheating zone, Btu/hr (W) Heat duty in hydrocarbon condensing zone, Btu/hr (W) Heat duty in steam condensing zone, Btu/hr (W) Heat duty from gas cooling in a zone, Btu/hr (W) qlc = Heat duty from liquid cooling in a zone, Btu/hr (W) qλ = Heat duty from condensation in a zone, Btu/hr (W) Rc = Total resistance (clean) to heat transfer, hr-ft2-°F/Btu (m2-K/W) Rio = Inside film resistance to heat transfer corrected to outside area, hr-ft2-°F/Btu (m2-K/W) Ro = Outside film resistance to heat transfer, hr-ft2-°F/Btu (m2-K/W) Rt = Total resistance (duty) to heat transfer, hr-ft2-°F/Btu (m2-K/W) ri = Tube-side fouling factor referred to tube inside surface area, hr-ft2-°F/Btu (m2-K/W) rio = Tube-side fouling factor referred to tube outside surface area, hr-ft2-°F/Btu (m2-K/W) ro = Outside fouling factor, hr-ft2-°F/Btu (m2-K/W) rw Re S = = = Resistance of tube wall metal at average wall temperature, hr-ft2-°F/Btu (m2-K/W) Reynolds number Free width between baffles, in. (m) EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. EXXON ENGINEERING HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING DESIGN PRACTICES Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 17 of 79 Date December, 1999 NOMENCLATURE (Cont) sf = Specific gravity of the condensate film Tdh = Hydrocarbon dewpoint, °F (°C) Tds tdh = = tds = Steam dewpoint, °F (°C) Temperature of the fluid being heated, after it gains enough heat to have cooled the condensing stream from Tdh to T2, °F (°C) Temperature of the fluid being heated, after it gains enough heat to have cooled the condensing stream from Tds to T2,°F (°C) Tm = Tube sheet design temperature, ° F (°C) T1 = Inlet temperature of fluid being cooled, °F (°C) T2 = Outlet temperature of fluid being cooled, °F (°C) t1 = Inlet temperature of fluid being heated, °F (°C) t2 = Outlet temperature of fluid being heated, °F (°C) tf = Average shell-side film temperature, °F (°C) ts = Caloric temperature of the shell fluid, °F (°C) tt = Caloric temperature of the tube fluid, °F (°C) tw = Average tube wall temperature, °F (°C) ∆tdh = Log mean temperature difference in desuperheating zone, °F (°C) ∆tds = Log mean temperature difference in hydrocarbon condensing zone, °F (°C) ∆tsc = Log mean temperature difference in steam condensing zone, °F (°C) ∆te = Log mean temperature difference corrected for nonideal countercurrent flow (Effective temperature difference), °F (°C) ∆tew = Weighted effective log mean difference, °F (°C) ∆tm = Log mean temperature difference for true countercurrent flow, °F (°C) Uc = Overall clean coefficient of heat transfer, Btu/hr-ft2-°F (W/m2-K) Udh = Overall heat transfer coefficient in desuperheating zone, Btu/hr-ft2-°F (W/m2-K) Uds = Overall heat transfer coefficient in hydrocarbon condensing zone, Btu/hr-ft2-°F (W/m2-K) Usc = Overall heat transfer coefficient in steam condensing zone, Btu/hr-ft2-°F (W/m2-K) Uo = Overall duty coefficient of heat transfer, Btu/hr-ft2-°F (W/m2-K) Uox = Overall condenser heat transfer coefficient, neglecting the resistance of condensate film, Btu/hr-ft2-°F (W/m2-K) u V = = Compressibility factor of the vapor Velocity, ft/sec (m/s) Vl1 = Volume liquid entering a zone, ft3/hr (m3/s) Vl 2 = Outlet liquid volume, ft3/hr (m3/s) Vv Vv1 Vv2 W Wc = = = = = Volume vapor entering a zone, ft3/hr (m3/s) Inlet vapor volume, ft3/hr (m3/s) Outlet vapor volume, ft3/hr (m3/s) Mass flow rate, lb/hr (kg/s) Quantity condensed in a zone (or overall), lb/hr (kg/s) Wl1 = Inlet liquid rate, lb/hr (kg/s) Wl 2 = Outlet liquid rate, lb/hr (kg/s) Wl = Average liquid flow rate, lb/hr (kg/s) Wv Wv1 Wv2 = = = Average vapor flow rate, lb/hr (kg/s) Inlet vapor flow rate, lb/hr (kg/s) Outlet vapor flow rate, lb/hr (kg/s) EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES Section CALCULATION PROCEDURE, CONDENSATION Page IX-F HEAT EXCHANGE EQUIPMENT 18 of 79 Date December, 1999 PROPRIETARY INFORMATION - For Authorized Company Use Only NOMENCLATURE (Cont) xv = Fraction of cross-sectional flow area occupied by vapor xl = Fraction of cross-sectional flow area occupied by liquid Yth = Tube-side heat transfer correlation factor µ = Viscosity at caloric temperature, cP (Pa•s) µf = Viscosity of fluid at average film temperature, cP (Pa•s) µl = Average liquid viscosity, cP (Pa•s) µv = Average vapor viscosity, cP (Pa•s) µw = Viscosity of the tube-side fluid at tube wall temperature, cP (Pa•s) α = Ratio vapor rate to inlet vapor rate, shell-side condensation β = In a condenser: Weight fraction condensed Γ = Tube loading, lb/hr-ft (kg/s-m) ∆3 = Correlation factors used in calculating equilibrium flash curve λ = Average latent heat of vaporization, Btu/lb (kJ/kg) ρ = Fluid density (No change of phase), lb/ft3(kg/m3) ρl = Average liquid density, lb/ft3 (kg/m3) ρl1 = Inlet density of liquid, lb/ft3 (kg/m3) ρl 2 = Outlet density of liquid, lb/ft3 (kg/m3) ρv = Average vapor density, lb/ft3 (kg/m3) ρv1 = Inlet density of vapor, lb/ft3 (kg/m3) ρv2 = Outlet density of vapor, lb/ft3 (kg/m3) ∆1, ∆2, EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. EXXON ENGINEERING HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING DESIGN PRACTICES Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 19 of 79 Date December, 1999 TABLE 1 T-Q CURVE CALCULATION PROCEDURE I. CALCULATION PROCEDURE 1. From the predicted ASTM distillation of the condensing hydrocarbon, determine t10, t30, t50, t70, and t90. Then calculate ∆1 from: ∆1 = 2 ( t70 − t10 ) 3 2. From Figure 6, determine ∆2 and ∆3. 3. Calculate the 10, 30, 50, 70, and 90 Vol. % points on the atmospheric flash curve. 4. 5. a. t10f = t10 + (∆1 – ∆3) – ∆2 b. t30 f = t10 + c. t50f = t10 + 0.48 (t50 – t10 – ∆1) + (∆1 – ∆3) d. t70 f = t10 f + e. t90f = t10 + 0.23 (t90 – t10 – 2∆1) + (∆1 – ∆3) + ∆2 ∆2 2 ∆1 + ( t 30 − t10 ) + ( ∆1 − ∆3 ) − 3 3 2 3 ∆2 2 Estimate the temperatures at 10, 30, 50, 70, and 90 wt% flashed and at the same mol% flashed. t10w = t10f + 0.05 (t50f – t10f) t30w = t30f + 0.10 (t50f – t10f) t50w = t50f + 0.10 (t70f – t30f) t90w = t90f + 0.05 (t90f – t50f) t70w = t70f + 0.10 (t90f – t50f) t30m = t30f – 0.04 (t50f – t10f) t10m = t10f – 0.02 (t50f – t10f) t50m = t50f – 0.04 (t70f – t30f) t90m = t90f – 0.02 (t90f – t50f) t70m = t70f – 0.04 (t90f – t50f) Prepare a graph (see Figure 2) with percent off on the X-axis and temperature on the Y-axis. a. 6. Plot the five points calculated for the volume flash curve. Connect the points as follows: (1) A straight line from t30f through t10f, intersecting the 0% axis. (2) A straight line from t70f through t90f, intersecting the 100% axis. (3) A straight line between t50f and t30f. (4) A straight line between t50f and t70f. b. Plot the five weight percent flashed points and connect each adjacent point with a straight line. Connect t10w with the 0 vol. % intercept, and t90w with the 100 vol. % intercept. Repeat this process with the five mol percent flashed points. Estimate Tdh, the dew point of the hydrocarbon. (For the overhead of the fractionation tower, T1 = Tdh.) a. On the flash curve prepared above, the atmospheric-pressure dew point is the point at 100% NOT condensed. b. Calculate the partial pressure of the condensable hydrocarbon and adjust the atmospheric–pressure dew point to this partial pressure, using the alignment chart, Figure 3. HC Partial Pr ess. = 7. mol of Condensable HC x P1 Total mol of vapor Estimate Tds, the dew point of steam in the system. This is the temperature at which the vapor pressure of water is equal to the partial pressure of the water in the system. a. This calculation is done in tabular form, as shown below. b. The calculations for the table should be carried out at increasing values of weight percent condensed until the first point is found where the vapor pressure of water @ system temperature is less than the calculated partial pressure of water in the system. EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES Section CALCULATION PROCEDURE, CONDENSATION Page IX-F HEAT EXCHANGE EQUIPMENT 20 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING TABLE 1 (Cont) T-Q CURVE CALCULATION PROCEDURE c. Prepare a graph with temperature on Y-axis and pressure of the X-axis. From the table just completed, plot the last 3 or 4 steam partial pressure vs. system temperature points. On the same graph, plot the last 3 or 4 water-vapor-pressure vs. system temperature points. The intersection of the two curves gives the approximate steam dew point of the system (see Figure 2). Wt. % Hydrocarbon Condensed(1) Vapor Temp. @ Atm. Press.(2) Mol % HC not Condensed(2) Mol of HC not Condensed Mol of Non-Condensables (“NC") Mol of Steam Total Mol of Vapor Total Pressure, psia or kPa(3) Partial Pressure of Steam, psia or kPa Partial Press. of Condensables, psia or kPa System Temperature, °F or °C(4) Vapor Press. of H2O at Sys. Temp.(5), psia or kPa Notes: 8. (1) Arbitrary values. (2) Read from flash curves. (3) Assume percent pressure drop = mol percent condensed. (4) Vapor temperature at 1 atm. adjusted to the partial pressure of condensables by means of the alignment chart, Figure 3. (5) From steam tables or from alignment chart Figure 3. (Use the point marked H2O as the “normal boiling point".) Determine the amount and type of heat duty in each zone. Evaluate specific heat (c) and latent heat of vaporization (λ) at the arithmetic average zone temperature. a. Sensible heat transferred from material which passes through the zone without changing phase. q = W c (Temp Change) b. c. d. Sensible heat transferred from vapor or steam which condenses in the zone. Sensible heat transferred from hydrocarbon or water which has condensed in the zone. q = Wc c (Temp Change ) 2 (c of vapor) q = Wc c (Temp Change) 2 (c of liquid) Latent heat transferred from condensing hydrocarbon or steam. Q = λ Wc Note that Item (8a) may include as many as 4 calculations: steam; non-condensables; vapor which does not condense; and any entering liquid. Item (8b) may include two calculations: vapor and steam. Items (8c) and (8d) may each include two calculations: hydrocarbon and water. The above calculations, performed for each zone, will give qdh, qds, and qsc. These values permit the calculation of the LMTD's and overall temperature difference (∆tm) – also referred to as the Mean Temperature Difference (MTD). EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 21 of 79 Date December, 1999 TABLE 2 CALCULATION PROCEDURE FOR CONDENSER DESIGN I. Exchanger Number E - Refinery Service Calc By/Date ZONE DUTIES AND TEMPERATURES* A. Vapor Desuperheating Zone (If Present); 1st Zone CUSTOMARY UNITS METRIC UNITS qdh Fluid Being Condensed (Shell/Tube) = Btu/hr W T1 = °F °C Tdh Fluid Being Heated (Shell/Tube) = °F °C t2 = °F °C tdh = °F °C T −T R = 1 dh = t 2 − t dh = t 2 − t dh = T1 − t dh = = °F °C = °F °C ts = 0.4 (T1 – Tdh) + Tdh = °F °C tt = 0.4 (t2 – tdh) + tdh = °F °C tt = 0.4 (T1 – Tdh) + Tdh = °F °C ts = 0.4 (t2 – tdh) + tdh = °F °C = Btu/hr-°F W/K j= ∆t m = (T1 − t 2 ) − (Tdh − t dh ) = T − t2 ln 1 T dh − t dh From charts given in Section IX-D Fn = for this zone** ∆te(dh) = ∆tmFn For shell-side condensation: For tube-side condensation: qdh ∆t e * ** Use LMTD correction factor for each zone, based on zone temperatures. Use LMTD corrections factor, based on terminal temperatures to evaluate minimum number of shells in series. Fn must be equal to or greater than 0.8. EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F 22 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN B. Hydrocarbon Condensing Steam Desuperheating Zone (2nd Zone) CUSTOMARY UNITS METRIC UNITS qds Fluid Being Condensed (Shell/Tube) = Btu/hr W Tdh = °F °C Tds = °F °C tdh = °F °C tds = °F °C = °F °C ∆te(ds) = ∆tm Fn For shell-side condensation: = °F °C ts = 0.4 (Tdh – Tds) + Tds = °F °C tt = 0.4 (tdh – tds) + tds For tube-side condensation: = °F °C tt = 0.4 (Tdh – Tds) + Tds = °F °C ts = 0.4 (tdh – tds) + tds = °F °C = Btu/hr-°F W/K qsc Fluid Being Condensed (Shell/Tube) = Btu/hr W Tds = °F °C T2 = °F °C tds = °F °C t1 = °F °C T − T2 = R = ds t ds − t1 = t ds − t1 = Tds − t1 = R= Tdh − Tds = t dh − t ds = j= t dh − t ds = Tdh − t ds = ∆tm = (Tdh − t dh ) − ( Tds − t ds ) T −t ln dh dh Tds − t ds From charts given in Section IX-D, Fn = for shells qds ∆Te C. Steam Condensing Zone (3rd Zone) j= EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 23 of 79 Date December, 1999 TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS (Tds − t ds ) − (T2 − t1 ) METRIC UNITS = °F °C ∆te(sc) = ∆tmFn For shell-side condensation: = °F °C ts = 0.4 (Tds – T2) + T2 = °F °C tt = 0.4 (tds – t1) + t1 For tube-side condensation: = °F °C tt = 0.4 (Tds – T2) + T2 = °F °C ts = 0.4 (tds – t1) + t1 = °F °C = Btu/hr-°F WK = °F °C = Btu/hr-ft2-°F W/m2-K m2 ∆t m = T −t ln ds ds T 2 − t1 From charts given in Section IX-D, Fn = for shells qsc ∆t e D. Weighted Temperature Difference ∆t ew = Q qdh qds qsc + + ∆t e( dh ) ∆t e( ds ) ∆t e( sc ) where: Q = qdh + qds + qsc II. * = SHELL-SIDE CONDENSATION A. Overall Tube-Side Calculation (No Change of Phase) 1. Assumed value of Uo 2. 3. A = Q / Uo ∆tew Tube metal: ___________________ = ft2 Thermal conductivity, kw Tube outer diameter, do = = Btu/hr-ft-°F in. W/m-K mm Wall thickness, l = ft m Tube insider diameter, di Tube length, L = = in. ft mm m 4. Tube pitch (Pt) and layout (Note 1)* = in. mm 5. As = A / Ns (Note 2)* = ft2 m2 6. Nt = 3.82 As / (L – 0.5) do Nt = 318 As / (L – 0.152) do (Metric) = General notes contained on last page of calculation form. EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F 24 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS METRIC UNITS 7. Assumed Np = 8. ts overall = 0.4 (T1 – T2) + T2 = °F °C 9. tt overall = 0.5 (t1 + t2) 10. Tube-side properties at tt = °F °C a. Density, ρ = lb/ft3 kg/m3 b. Viscosity, µ = cP Pa•s c. Specific Heat, c = Btu/lb-°F kJ/kg-K d. Thermal Conductivity, k = Btu/hr-ft-°F W/m-K 11. Tube-side flow rate, W = Q / c (t2 – t1) = lb/hr kg/s = ft/sec 12. V = Np W (19.6) ρ N t di2 (1.273 x 10 6 ) Np W V = (Metric) ρ Nt di2 m/s 13. If tube-side fluid is water hio = hio = t 368 ( Vdi ) 0.7 t do 100 0.26 1.27 x 104 1.8 t t + 32 ( Vdi )0.7 do 100 = Btu/hr-ft-°F 0.26 ( V )1.73 ∆P = 0.020 Ft N s Np V 2 + 0.158 L (di )1.27 ( V )1.73 ∆P = 1.48 Ft Ns Np V 2 + 22.9 L (di )1.27 W/m2-K (Metric) = psi (Metric) kPa 14. For fluids other than water, evaluate overall tube-side heat transfer coefficient and pressure drop by the procedure outlined in Section IX-D, tube-side iteration. Btu/hr-ft-°F W/m2-K = psi kPa = hr-ft2-°F/Btu m2-K/W 16. Tube-side fouling factor, ri = hr-ft2-°F/Btu m2-K/W 17. rio = (do / di) ri = hr-ft2-°F/Btu m2-K/W = hr-ft2-°F/Btu m2-K/W hio = ∆Pt 15. Rio = 1 / hio 18. Shell-side fouling factor, ro EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 25 of 79 Date December, 1999 TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS = hr-ft2-°F/Btu m2-K/W 20. 1 / Uox = Rio + rio + rw + ro = hr-ft2-°F/Btu m2-K/W 21. Uox = Btu/hr-ft2-°F W/m2-K = °F °C 19. rw = l / kw B. METRIC UNITS Overall Shell-Side Calculation 1 U ( t s − t1) 1 − o 2 U ox 1. t f = ts − 2. For fluids other than hydrocarbons, determine vapor film properties. For hydrocarbons, determine only liquid viscosity µf Viscosity, µf = cP Pa•s Specific Heat, cf = Btu/lb-°F kJ/kg-K Thermal Conductivity, kf = Btu/hr-ft-°F W/m-K = = in. in. mm mm = in. mm Assumed Pb = NB = FF (10 L / Pb) (Note 4) = NB = FF (833 L / Pb) (Note 4) (Metric) 9. Ax = S (Pb – 0.375) (Segmental Baffles) = Ax = S (Pb – 9.53) (Metric) Ax = 0.85S (Pb – 0.375) (Double Segmental Baffles) = Ax = 0.85S (Pb – 9.53) (Metric) 10. Total shell-side flow rate, W = in. mm 3. NTC = 1.19 = 1.10 Nt square layout Nt triangular layout 4. 5. Dt = (NTC – 1) Pt + do D = Dt / 0.9 (Note 3) 6. S= 7. 8. D − (do NTC ) (Note 4) FF = in.2 mm2 in.2 lb/hr EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. mm2 kg/s DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F 26 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS METRIC UNITS 11. Inlet vapor density and volume ρ v1 = Inlet MW Pi (psia) 1 10.7 T1 + 460 u = lb/ft3 or ρ v1 = Inlet MW Pi (kPa abs) 1 8.29 T1 + 273 u (Metric) Inlet vapor rate, W v1 Vv1 = W v1 / ρv1 12. Outlet vapor density and volume ρv 2 = Outlet MW Pi (psia) 1 10.7 T2 + 460 u kg/m3 = = lb/hr kg/s = ft3/hr m3/s = lb/ft3 or ρv 2 = Outlet MW Pi (kPa abs ) 1 8.29 T2 + 273 u Outlet vapor rate, W v2 (Metric) kg/m3 = = lb/hr kg/s = ft3/hr m3/s ρl1 = lb/ft3 kg/m3 Inlet liquid rate, Wl1 = lb/hr kg/s Vl1 = Wl1 / ρl1 = ft3/hr m3/s ρl 2 = lb/ft3 kg/m3 Inlet liquid rate, Wl 2 = lb/hr kg/s Vl 2 = Wl 2 / ρl 2 = ft3/hr m3/s = lb/ft3 kg/m3 psi kPa Vv2 = W v2 / ρv2 13. Inlet liquid density and volume 14. Inlet liquid density and volume 15. Average mixture density ρ = 2W Vv1 + Vl1 + Vv 2 + Vl 2 16. Calculate shell-side pressure drop (∆Ps) using = procedures outlined in Section IX-D, Shell-Side Iteration The above-assumed geometry will now be checked using the following detailed procedures. EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 27 of 79 Date December, 1999 TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS C. METRIC UNITS Vapor Desuperheating Zone (Shell-Side Condensation) 1. 2. t +t U t f = s t + o (Rio + rio + rw + ro ) ( t s − t t ) 2 2 = °F = lb/ft3 °C (ts and tt for this zone were calculated in Step I.A.) Inlet vapor density and volume ρ v1 = Inlet MW Pi (psia) 1 10.7 T1 + 460 u or ρ v1 = 3. Inlet MW Pi (kPa abs) 1 8.31 T1 + 273 u (Metric) kg/m3 = For fluids other than hydrocarbons, determine film properties. For hydrocarbons, determine only µf Viscosity, µf = cP Pa•s Specific Heat, cf = Btu/lb-°F kJ/kg-K Thermal Conductivity, kf = Btu/hr-ft-°F W/m-K 4. Calculate shell-side coefficient (hgc) using Section IX-D, Shell-Side iteration = Btu/hr-ft2-°F W/m2-K 5. Udh = = Btu/hr-ft2-°F W/m2-K = ft2 m2 hgc Uox hgc + Uox (Uox was evaluated in Step II.A.21.) 6. A dh = qdh ∆t e Udh (qdh and ∆te were evaluated in Step I.A.) D. Hydrocarbon Condensing - Steam Desuperheating Zone (Shell-Side Condensation) 1. Assume a zone area, Ads = ft2 m2 2. Uds assumed = qds A ds ∆t e = Btu/hr-ft2-°F W/m2-K (qds and ∆te for this zone were evaluated in Step I.B.) EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F 28 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS 3. tf = ts − U 1 ( t s − t t ) 1 − ds 2 Uox METRIC UNITS °F = °C (ts and tt for this zone were evaluated in Step I.B.) 4. ∆Tzone inlet = ∆Tzone outlet Tdh − t dh Tds − t ds = 5. Fv (Figure 4) = 6. Average zone vapor rate, W v (Fv) (Vapor condensed in zone, W c) + (Vapor not condensed in zone, W v2) = Wv = = = Average Mol. weight of vapor = lb / hr mol / hr = lb/ft3 7. lb/hr mol/hr kg/s kmol/s kg / s kmol / hr Average vapor properties at film temperature a. Density, ρ v = Avg MW 10.7 P (psia) 1 t f + 460 u or ρv = b. Avg MW P (kPa abs) 1 8.31 t f + 273 u (Metric) Viscosity, µf (Used for hgc calc.) kg/m3 = = cP Pa•s lb/hr kg/s 8. Wl = W − Wv = 9. Average condensate properties at film temp. a. Specific gravity, sf = b. = Btu/hr-ft-°F W/m-K = cP Pa•s Thermal Conductivity, kf c. Viscosity, µf 10. Condensing Coefficient (Horizontal Bundle) a. ns = 1.29 Nt 0.48 (90° Square Tube Layout) = ns = 1.02 Nt 0.519 (30° Triangular Layout) = (For other layouts, see text) b. Lc = A ds (L − 0.5 ) Ns A = ft or A ds = (L − 0.152) Ns (Metric) A (Note that if a zone occupies more than one shell, Lc will be a multiple of the tube length.) Lc = EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. m DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 29 of 79 Date December, 1999 TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS Wc L c ns c. Γ= d. s2 8.33 x 10 3 kf f h′λ = µf Γ 1/ 3 condensate METRIC UNITS = lb/hr-ft = Btu/hr-ft2-°F kg/s-m 1/ 3 or 1/ 3 s2 204 k f f h ′λ = (Metric) µ Γ 1/ 3 f condensate 0.111 0.555 e. Wv µ f (v ) 1 =1+ xl W l µ f (l) f. xv = 1− x l g. Gv = FJ Wv , (Note 4), or 25 A x x v FBT = Gv = 10 6 Wv FJ A x x v FBT = h. ρl ρ v W/m2-K = = = G h λ = h′λ v 5 (Metric) lb/sec-ft2 kg/sm2 0.70 = Btu/hr-ft2-°F or G h λ = h′λ v 24.4 0.70 (Metric) W/m2-K = If hλ > 2 h′λ , use 2.0 h′λ (For pure components, h λ = h′λ ) 11. Condensing Coefficient (Vertical Bundles) a. Γ= 12 Wc π N t do = lb/hr-ft or Γ= 1000 Wc π N t do (Metric) = kg/s-m 1/ 3 b. 1.04 x 10 4 2 k f sf hλ = 1 / 3 Γ µf condensate = Btu/hr-ft2-°F or 1/ 3 s2 254 hλ = 1 / 3 k f f (Metric) µf Γ condensate = EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. W/m2-K DESIGN PRACTICES Section CALCULATION PROCEDURE, CONDENSATION Page IX-F HEAT EXCHANGE EQUIPMENT 30 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS METRIC UNITS 12. Vapor cooling coefficient Calculate h′gc using procedures outlined in Section IX-D, shell-side iteration (use W v as the flowrate) h′gc = Btu/hr-ft2-°F W/m2-K = Btu/hr-ft2-°F W/m2-K = Btu/hr-ft2-°F W/m2-K = = Btu/hr-ft2-°F lb/hr W/m2-K kg/s = Btu/hr-ft2-°F W/m2-K = Btu/hr-ft2-°F W/m2-K = Btu/hr-ft2-°F W/m2-K = = Btu/hr Btu/hr W W = Btu/hr W = Btu/hr-ft2-°F W/m2-K = Btu/hr-ft2-°F W/m2-K Tdh + Tds − tf Wc 2 C1 = 1 − Wv1 (Tdh − Tds ) 1 h gc = C 1 + 1 = h λ h ′gc hgc 13. Liquid cooling coefficient (Horizontal Bundles) a. Bottom Cooling Coefficient Calculate h′lc using procedures outlined in Section IX-D, shell-side iteration (use Wl as condensate flow rate) h′lc b. Drip Cooling Coefficient c. hdc = 1.5hλ Total liquid cooling coefficient (Horizontal) Bundles), Liquid entering zone, Wl h lc = 2 h dc h′lc (total vapor entering zone) h dc + h′lc or h lc = ( Wl + Wc ) h dc h′lc Wc W h′lc + Wl + c h dc 2 2 (For liquid + vapor entering zone) 14. Liquid cooling coefficient (Vertical Bundles) hlc = hλ 15. Weighted hydrocarbon condensing zone coefficient a. Zone condensing duty, qλ b. Zone vapor cooling duty, qgc c. Zone liquid cooling duty, qlc hds = Uds = qds qλ qgc qlc + + hλ hgc hlc hds Uox hds + Uox (Uox was evaluated in Step II.A.21.) EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 31 of 79 Date December, 1999 TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS METRIC UNITS 16. Zone Area A ds = qds Uds ∆t e( ds ) = ft2 m2 = Btu/hr-ft2-°F W/m2-K = °F °C (qds and ∆te for this zone were evaluated in Step I.B.) E. Steam Condensing Zone (Shell-Side Condensation) qsc ( A − A ds ) ∆t e( sc ) 1. Usc = 2. t f = ts − U 1 ( t s − t t ) 1 − sc 2 Uox (ts and tt for this zone were evaluated in Step I.C.) 3. ∆Tzone inlet ∆Tzone outlet = Tds − t ds = _____________ T2 − t 1 = 4. Fv (Figure 4) = 5. Average zone vapor rate, W v (Fv) (Vapor condensed in zone, W c) + Non Condensable = Wv = = = Average Mol. weight of vapor = lb / hr mol / hr = lb/ft3 6. lb/hr mol/hr kg/s kmol/s kg / s kmol / hr Average vapor properties at film temperature a. Density, ρ v = Avg MW 10.7 P (psia) 1 t + 460 u f or ρv = b. 7. 8. Avg MW 8.31 P (kPa abs) 1 t + 273 u f kg/m3 (Metric) = Viscosity, µf (Used for hgc calc.) = cP Pa•s Wl = W – W v = lb/hr kg/s Average condensate properties at film temperature a. Specific gravity, sf = b. = Btu/hr-ft-°F W/m-K cP Pa•s Average zone liquid rate, Wl Thermal conductivity, kf c. Viscosity, µf = (Note that hydrocarbon film properties should be used) EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F 32 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS 9. METRIC UNITS Condensing Coefficient (Horizontal Bundle) ns = 1.29 Nt 0.48 (90° Square Tube Layout) = ns = 1.02 Nt 0.519 (30° Triangular Layout) = b. (For other layouts, see text) Asc = A – Adh – Ads = ft2 c. Lc = = ft a. A sc (L − 0.5 ) N s A m2 or Lc = A sc (L − 0.152) N s A (Metric) = m (Note that if a zone occupies more than one shell, Lc will be a multiple of the tube length.) Wc L c ns d. Γ= e. s2 8.33 x 10 3 kf f h′λ = µf Γ 1/ 3 condensate = lb/hr-ft = Btu/hr-ft2-°F kg/s-m 1/ 3 or 1/ 3 s2 204 k f f (Metric) h′λ = 1/ 3 µf Γ condensate f. Wv µ f (v ) 1 =1+ xl W l µ f (l) g. xv = 1− x l h. Gv = 0.111 ρl ρ v W/m2-K = 0.555 = = FJ Wv , (Note 4), 25 A x x v FBT = lb/sec-ft2 or Gv = i. 10 6 Wv FJ , (Note 4) A x x v FBT G h λ = h′λ v 5 (Metric) kg/sm2 = 0.7 = Btu/hr-ft2-°F or G h λ = h′λ v 24.4 0.7 (Metric) = If hλ > 2 h′λ , use 2 h′λ (For pure components, h λ = h′λ ) EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. W/m2-K DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 33 of 79 Date December, 1999 TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS METRIC UNITS 10. Condensing Coefficient (Vertical Bundles) a. Γ= 12 Wc π Nt do = lb/hr-ft or Γ= 1000 Wc π Nt do (Metric) = kg/s-m 1/ 3 b. 1.04 x 10 4 2 k f sf hλ = Γ1/ 3 µf condensate = Btu/hr-ft2-°F or 1/ 3 s2 254 hλ = 1 / 3 k f f (Metric) µf Γ condensate W/m2-K = 11. Vapor cooling coefficient Calculate h′gc using procedures outlined in Section IX-D, shell-side iteration (use W v as the flowrate) h′gc = Btu/hr-ft2-°F W/m2-K = Btu/hr-ft2-°F W/m2-K = Btu/hr-ft2-°F W/m2-K = = Btu/hr-ft2-°F lb/hr W/m2-K kg/s = Btu/hr-ft2-°F W/m2-K = Btu/hr-ft2-°F W/m2-K Tdh + Tds − tf Wc 2 = 12. C1 = 1 − Wv1 (Tdh − Tds ) C 1 1 = + 1 = h gc hλ h′gc hgc 13. Liquid cooling coefficient (Horizontal Bundles) a. Bottom Cooling Coefficient Calculate h′lc using procedures outlined in Section IX-D, shell-side iteration (use Wl as condensate flow rate) h′lc b. Drip Cooling Coefficient c. hdc = 1.5hλ Total liquid cooling coefficient (Horizontal) Bundles), Liquid entering zone, Wl h lc = ( Wl + Wc ) h dc h ′lc Wc W h′lc + Wl + c h dc 2 2 14. Liquid cooling coefficient (Vertical Bundles) hlc = hλ EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F 34 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS METRIC UNITS 15. Weighted steam condensing coefficient a. Zone condensing duty, qλ = Btu/hr-ft2-°F W/m2-K W/m2-K b. Zone vapor cooling duty, qgc = Btu/hr-ft2-°F c. Zone liquid cooling duty, qlc = Btu/hr-ft2-°F W/m2-K q sc q gc = Btu/hr-ft2-°F W/m2-K hsc Uox hsc + Uox = Btu/hr-ft2-°F W/m2-K = ft2 m2 = A = Adh + Ads + Asc If total area calculated is not reasonably close to total area assumed, reiterate the various zone calculations. G. Condensing Pressure Drop (Shell-Side Condensation) ft2 m2 h sc = Usc = qλ q + + lc hλ h gc h lc 16. Zone Area A sc = F. qsc Usc ∆t e( sc ) (qsc and ∆te for this zone were evaluated in Step I.C.) Total Area 1. 1. Hydrocarbon condensing zone inlet volumes a. Vapor (1) ρ v1( dh ) = Vapor MW 10.7 P (psia) 1 T + 460 u dh lb/ft3 = or ρ v1( dh ) = Vapor MW 8.31 P (kPa abs) 1 T + 273 u (Metric) dh (2) Vapor rate, W v1(dh) = lb/hr kg/s = ft3/hr m3/s (1) ρl1( dh ) = lb/ft3 kg/m3 (2) Liquid rate, Wl1( dh ) = lb/hr kg/s (3) = ft3/hr m3/s (3) Vv1(dh) = W v1(dh) / ρv1(dh) b. kg/m3 = Liquid (if present) Vl1( dh ) EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 35 of 79 Date December, 1999 TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS 2. METRIC UNITS Steam condensing zone inlet volumes a. Vapor (1) ρ v1( dh ) = Vapor MW 10.7 P (psia) 1 T + 460 u ds lb/ft3 = or ρ v1( dh ) = Vapor MW P (kPa abs ) 1 T + 273 u (Metric) 8.31 ds (2) Vapor rate, W v1(ds) = lb/hr kg/s = ft3/hr m3/s (1) ρl1( ds ) = lb/ft3 kg/m3 (2) Liquid rate, Wl1( ds ) = lb/hr kg/s Vl1( ds ) = Wl1( ds ) / ρl1( ds ) = ft3/hr m3/s Steam condensing zone outlet volumes a. Vapor (if present) Vv2 (evaluated in Step II.B.12.) = ft3/hr m3/s Vl 2 (evaluated in Step II.B.14.) = ft3/hr m3/s = psi kPa = lb/ft3 kg/m3 = psi kPa = lb/ft3 kg/m3 = psi kPa = psi kPa (3) Vv1(ds) = W v1(ds) / ρv1(ds) b. Liquid (3) 3. 4. Vapor desuperheating zone ∆Pdh Calculate ∆Pdh using procedures outlined in Section IX-D, shell-side iteration, ∆Pdh 5. 6. 7. kg/m3 = Hydrocarbon condensing zone, ∆Pds 2W Vv1( dh ) + Vl1( dh ) + Vv1( ds ) + Vl1( ds ) a. ρds = b. Calculate ∆Pds using procedures outlined in Section IX-D, shell-side iteration Steam condensing zone ∆Psc 2W Vv1( ds ) + Vl1( ds ) + Vv 2 + Vl 2 a. ρsc = b. Calculate ∆Psc using procedures outlined in Section IX-D, shell-side iteration Total condensing-side pressure drop ∆P = ∆Pdh + ∆Pds + ∆Psc EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F 36 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS METRIC UNITS III. TUBE-SIDE CONDENSATION A. Overall Shell-Side Calculation (No Change of Phase) 1. Assumed value of Uo = Btu/hr-ft2-°F W/m2-K 2. Assumed value of Rio = hr-ft2-°F/Btu m2-K/W 3. 4. A = Q / Uo ∆tew Tube metal: = ft2 m2 Thermal conductivity, kw Tube outer diameter, do = = Btu/hr-ft-°F in. W/m-K mm Wall thickness, l = ft m Tube inside diameter, di Tube length, L Tube pitch (Pt) and layout (Note 1) As = A / Ns (Note 2) Nt = 3.82 As / (L – 0.5) do or Nt = 318 As / (L – 0.152) do (Metric) = = = = = in. ft in. ft2 mm mm mm m2 tt overall = 0.4 (T1 – T2) + T2 = °F °C = °F °C = hr-ft2-°F/Btu m2-K/W = hr-ft2-°F/Btu m2-K/W = hr-ft2-°F/Btu m2-K/W U t +t 12. t f = s t + o (Rio + rio + rw + ro ) ( t s − t t ) 2 2 = °F °C 13. Shell-side density, ρ = lb/ft3 kg/m3 Viscosity, µf = cP Pa •s Specific heat, cf = Btu/lb-°F kJ/kg-K Thermal conductivity, kf = Btu/hr-ft-°F W/m-K 5. 6. 7. 8. 9. ts overall = 0.4 (t2 – t1) +t1 10. Fouling factors a. rio = do (ri ) = di b. ro 11. Tube wall resistance rw = l / k w = 14. For fluids other than hydrocarbons, determine film properties. For hydrocarbons, determine only µ EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 37 of 79 Date December, 1999 TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS 15. Shell-side flow rate, W = Q / c (t2 – t1) 16. NTC = 1.19 lb/hr kg/s = = in. in. mm mm = in. mm = = in. mm Nt square layout = 1.10 N t triangular layout 17. Dt = (NTC – 1) Pt + do 18. D = Dt / 0.9 (Note 3) 19. S = = METRIC UNITS D − (do NTC ) (Note 4) FF 20. Assumed Pb 21. NB = FF (10L / Pb) (Note 4), or NB = FF (833 L / Pb) (Note 4) (Metric) 22. Ax = S (Pb – 0.375) (Segmental Baffles) or Ax = S (Pb – 9.53) (Metric) Ax = 0.85S (Pb – 0.375) (Double Segmental Baffles) or Ax = 0.85S (Pb – 9.53) (Metric) = = = = = in.2 mm2 in.2 mm2 = 23. Calculate ∆Ps using procedures outlines in = Section IX-D, shell-side iteration (if pressure drop is unreasonable, adjust Pb and reiterate.) 24. Calculate shell-side coefficient using procedures outlines in Section IX-D, shell-side iteration psi kPa = Btu/hr-ft2-°F W/m2-K = hr-ft2-°F/Btu m2-K/W 26. 1 / Uox = Rio + rio + rw + ro = hr-ft2-°F/Btu m2-K/W 27. Uox = Btu/hr-ft2-°F W/m2-K ho 25. Ro = 1 / ho EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F 38 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS B. METRIC UNITS Overall Tube-Side Calculation 1. 2. Total shell-side flow rate, W Inlet vapor density and volume ρ v1 = Inlet MW 10.7 Pi (psia) 1 T + 460 u 1 Inlet MW 8.31 Pi (kPa abs) 1 T + 273 u 1 = lb/hr = lb/ft3 kg/s or ρ v1 = 3. (Metric) kg/m3 = Inlet vapor rate, W v1 = lb/hr kg/s Vv1 = W v1 / ρv1 Outlet vapor density and volume = ft3/hr m3/s = lb/ft3 ρ v2 = Outlet MW 10.7 Pi (psia) 1 T + 460 u 2 Outet MW 8.31 Pi (kPa abs) 1 T + 273 u 2 or ρ v2 = 4. 5. 6. kg/m3 = Outlet vapor rate, W v2 = lb/hr kg/s Vv2 = W v2 / ρv2 Inlet liquid density and volume = ft3/hr m3/s ρl1 = lb/ft3 kg/m3 Inlet liquid rate, Wl1 = lb/hr kg/s Vl1 = Wl1 / ρl1 = ft3/hr m3/s ρl 2 = lb/ft3 kg/m3 Outlet liquid rate, Wl 2 = lb/hr kg/s Vl 2 = Wl 2 / ρl 2 = ft3/hr m3/s = lb/ft3 kg/m3 Outlet liquid density and volume Average density ρ= 7. (Metric) 2W Vv1 + Vl1 + Vv 2 + Vl 2 Assumed Np = EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 39 of 79 Date December, 1999 TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS 8. V= Np W = 19.6 ρ N t di2 METRIC UNITS ft/sec or 1.273 x 10 6 Np W V = 9. (Metric) ρ N t di2 = G = ρV 10. Re = lb/sec-ft2 kg/s-m2 = psi kPa = psi = di G di G or 29 µ 1000 µ (Metric) m/s = 11. Calculate Fanning friction factor f f = 16 / Re = 10–4 Re 0.575 (Re ≤ 2000) (2000 < Re < 3800) = = (Re ≥ 3800) = = 0.0035 + 0.264 / Re0.42 12. ρV2 / 9270 13. ∆Ptf = 48 f ρV2 / 2000 or 2 L ρV µ w di 9270 µ (Metric) 0.14 or 0.25 or = 4000 f L ρV 2 µ w di 2000 µ 0.14 or 0.25 (Metric) = kPa (use 0.25 for laminar flow) 14. ∆Ptr = 3 (ρV2 / 9270) ∆Ptr = 3 (ρV2 / 2000) = (Metric) psi = 15. ∆Pt = Ft Ns Np (∆Ptf + ∆Ptr) = kPa psi kPa (See Table 3, Section IX-D) (If ∆Pt is unreasonable change Np and reiterate tube-side calculation.) The above assumed geometry will now be checked using the following detailed procedure. C. Vapor Desuperheating Zone (Shell-Side Condensation) 1. ρ v1 = Inlet MW 10.7 Pi (psia) 1 t + 460 u t Inlet MW 8.31 Pi (kPa abs) 1 t + 273 u t = lb/ft3 or ρ v1 = (Metric) = (tt was calculated in Step I.A.) EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. kg/m3 DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F 40 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS 2. 3. 4. Total tube-side inlet vapor, W At tt, determine for fluids other than hydrocarbons: = METRIC UNITS lb/hr kg/s Viscosity, µf = cP Pa•s Specific Heat, c = Btu/lb-°F kJ/kg-K Thermal Conductivity, k = Btu/hr-ft-°F W/m-K = ft/sec V= Np W 19.6 ρ v N t di2 1.273 x 10 6 Np W V = (Metric) ρ N t di2 5. G = Vρv 6. Re = 7. From Figure 8, determine Yth a. di G 29 µ or di G (Metric) 1000 µ k (cµ / k)1/3 * = Yth k cµ hio do k * = 1 / Rio m/s lb/sec-ft2 kg/s-m2 = Btu/hr-ft-°F W/m-K = Btu/hr-ft2-°F W/m2-K °F °C = 1/ 3 b. = = = * Uncorrected for viscosity. c. * + r ) (t – t ) tw = tt + Uo ( Rio io s t = d. (µ / µw)0.14 = 8. * (µ / µ )0.14 hgc = hio w = Btu/hr-ft2-°F W/m2-K 9. Udh = = Btu/hr-ft2-°F W/m2-K = ft2 m2 hgc Uox hgc + Uox (Uox was evaluated in Step II.A.27.) 10. A dh = qdh ∆t e( dh ) Udh (qdh and ∆te were evaluated in Step I.A.) D. Hydrocarbon Condensing - Steam Desuperheating Zone (Shell-Side Condensation) 1. Assume a zone area, Ads = ft2 m2 2. Uds = qds A ds ∆t e( ds ) = Btu/hr-ft2-°F W/m2-K (qds and ∆te for this zone were evaluated in Step I.B.) EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 41 of 79 Date December, 1999 TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS 3. tf = tt − U 1 ( t t − t s ) 1 − ds 2 Uox METRIC UNITS °F = °C (ts and tt for this zone were evaluated in Step I.B.) 4. ∆Tzone inlet ∆Tzone outlet = Tdh − t dh Tds − t ds = 5. Fv (Figure 4) = 6. Average zone vapor rate, W v (Fv) (Vapor condensed in zone) + (Vapor not condensed in zone) = Wv = = = Average Mol. weight of vapor = lb / hr mol / hr = lb/ft3 7. lb/hr mol/hr kg/s kmol/s kg / s kmol / hr Average vapor properties at film temperature a. Density, ρ v = Avg MW 10.7 P (psia) 1 t + 460 u f or ρv = b. Avg MW P (kPa abs) 1 8.31 t f + 273 u (Metric) Viscosity, µf (Used for hgc calc.) kg/m3 = = cP Pa•s lb/hr kg/s 8. Wl = W − Wv = 9. Average condensate properties at film temperature a. Specific gravity, sf = b. = Btu/hr-ft-°F W/m-K = cP Pa•s = lb/sec-ft2 Thermal Conductivity, kf c. Viscosity, µf 10. Condensing Coefficient a. G′v = Np W v 19.6 N t di2 or G′v = 1.273 x 10 6 Np W v N t di2 (Metric) = EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. kg/s-m2 DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F 42 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS b. G′l = G′l = Np W l or 19.6 N t di2 1.273 x 10 6 Np Wl N t di2 (Metric) c. G e = G′l + G′v (ρ l / ρ v )1/ 2 d. Re = e. f. kf Prf1/3 If Re < 50,000 or htλ = 5.03 Re1/3 kf Prf1/3 [12 / di] htλ = 5.03 Re1/3 kf Prf1/3 [1000 / di] (Metric) If Re > 50,000 di Ge di Ge or 29 µ f ( l ) 103 µ f ( l ) (Metric) or htλ = 0.0265 Re0.8 kf Prf1/3 [1000 / di ] (Metric) 11. Vapor Cooling Coefficient ρl ρ v kg/s-m2 lb/sec-ft2 kg/s-m2 = Btu/hr-ft-°F W/m-K = = Btu/hr-ft-°F = Btu/hr-ft-°F = W/m-K = W/m-K 0.555 a. W v µ f (v ) 1 =1+ xl W l µ f (l ) b. xv = 1− x l = c. Gv = G ′v xv = d. Re = Gv di lb/sec-ft2 = = htλ = 0.0265 Re0.8 kf Prf1/3 [12 / di] 0.111 = METRIC UNITS = lb/sec-ft2 kg/sm2 = Btu/hr-ft2-°F W/m2-K = Btu/hr-ft2-°F W/m2-K = 29 µ f ( l ) or Re = 10 −3 Gv di (Metric) µ f (l ) e. From Figure 8, determine Yth f. k (cµ / k)1/3 g. * = Yth k cµ hio do k 1/ 3 * = 1 / Rio = * Uncorrected for viscosity. h. * + r ) (t – t ) tw = tt + Uo ( Rio io s t i. (µ / µw)0.14 = j. * (µ / µ )0.14 h′gc = hio w = Btu/hr-ft2-°F W/m2-K 1 1 1 = + h gc h tλ h′gc = Btu/hr-ft2-°F W/m2-K EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 43 of 79 Date December, 1999 TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS METRIC UNITS 12. Liquid cooling coefficient hlc = htλ 13. Weighted zone coefficient a. Zone condensing duty, qλ b. Zone vapor cooling duty, qgc c. Zone liquid cooling duty, qlc qds qgc qλ q + + lc hλ hgc h lc hds = Usc = hds Uox h ds + Uox = Btu/hr-ft2-°F W/m2-K = = Btu/hr Btu/hr W W = Btu/hr W = Btu/hr-ft2-°F W/m2-K = Btu/hr-ft2-°F W/m2-K = ft2 m2 = ft2 m2 = Btu/hr-ft2-°F W/m2-K °F °C (Uox was evaluated in Step III.A.27.) 14. Zone Area A ds = qds Uds ∆t e( ds ) (qds and ∆te for this zone were evaluated in Step I.B.) E. Steam Condensing Zone (Tube-Side Condensation) 1. Asc = A – Adh – Ads 2. Usc = qsc A sc ∆t e( sc ) (qsc and ∆te(sc) for this zone were evaluated in Step I.C.) 3. tf = tt + U 1 ( t t − t s ) 1 − sc 2 Uox = (ts and tt for this zone were evaluated in Step I.C.) 4. ∆Tzone inlet ∆Tzone outlet = Tds − t ds T2 − t1 = 5. Fv (Figure 4) = 6. Average zone vapor rate, W v (Fv) (Vapor condensed in zone, W) + Vapor not condensed in zone = Wv = = = Average Mol. weight of vapor = lb/hr mol/hr kg/s lb / hr mol / hr EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. kmol/s kg / s kmol / hr DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F 44 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS 7. Average zone liquid rate, Wl Wl = W – W v 8. = lb/hr kg/s = Btu/hr-ft2-°F W/m-K = cP Pa•s = lb/sec-ft2 Average H.C. condensate properties at film temperature a. Specific gravity, sf = b. 9. METRIC UNITS Thermal conductivity, kf c. Viscosity, µf Condensing Coefficient a. G′v = Np Wv 19.6 N t di2 or G′v = b. Gl = 1.273 x 10 6 Np W v N t di2 (Metric) Np Wl = 19.6 Nt di2 kg/s-m2 = lb/sec-ft2 or Gl = 1.273 x 10 6 Np Wl Nt di2 c. G e = G′l + G ′v (ρ l / ρ v )1/ 2 d. Re = (Metric) di Ge , 29 µ f ( l ) kg/s-m2 = = lb/sec-ft2 kg/s-m2 W/m-K = or Re = e. f. or or di Ge 1000 µ f ( l ) (Metric) = kf Prf1/3 If Re < 50,000 htλ = 5.03 Re1/3 kf Prf1/3 [12 / di] htλ = 5.03 Re1/3 kf Prf1/3 [1000 / di ] (Metric) If Re > 50,000 = Btu/hr-ft-°F htλ = 0.0265 Re0.8 kf Prf1/3 [12 / di] htλ = 0.0265 Re0.8 kf Prf1/3 [ 1000 / di ] (Metric) = Btu/hr-ft-°F 1/ 3 W/m-K g. * = Yth k cµ hio do k h. * + r ) (t – t ) tw = tt + Uo ( Rio io s t i. (µ / µw)0.14 = j. * (µ / µ )0.14 h′gc = hio w 1 1 1 = + h gc h tλ h′gc * = 1 / Rio Btu/hr-ft2-°F W/m2-K = Btu/hr-ft2-°F W/m2-K = Btu/hr-ft2-°F W/m2-K = EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 45 of 79 Date December, 1999 TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS METRIC UNITS 10. Vapor Cooling Coefficient 0.111 1 W µ (v) = 1+ v f xl Wl µ f ( l ) b. xv = 1− x l = c. Gv = G ′v xv = d. Re = Gv di 29 µ f ( l ) Re = 10 − 3 ρl ρ v 0.555 a. , or G v di lb/sec-ft2 kg/sm2 = Btu/hr-ft2-°F W/m2-K = Btu/hr-ft2-°F W/m2-K = (Metric) µ f (l ) = e. From Figure 8, read Yth f. k (cµ / k)1/3 g. * = Yth k cµ * = 1 / Rio hio do k vap. = 1/ 3 * Uncorrected for viscosity. h. * + r ) (t – t ) tw = tt + Uo ( Rio io s t i. (µ / µw)0.14 = j. * (µ / µ )0.14 h′gc = hio w = Btu/hr-ft2-°F W/m2-K 1 1 1 = + h gc h tλ h′gc = hr-ft2-°F/Btu W/m2-K = Btu/hr-ft2-°F W/m2-K = = Btu/hr Btu/hr W W = Btu/hr W = Btu/hr-ft2-°F W/m2-K = Btu/hr-ft2-°F W/m2-K 11. Liquid cooling coefficient hlc = htλ 12. Weighted zone coefficient a. Zone condensing duty, qλ b. Zone vapor cooling duty, qgc c. Zone liquid cooling duty, qlc hsc = Usc = qsc qλ qgc qlc + + hλ hgc hlc hsc Uox hsc + Uox EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F 46 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS METRIC UNITS 13. Zone Area A sc = qsc Usc ∆t e( sc ) = ft2 m2 = A = Adh + Ads + Asc If total area calculated is not reasonably close to total area assumed, reiterate the various zone calculations. G. Condensing Pressure Drop (Tube-Side Condensation) ft2 m2 F. (qsc and ∆te for this zone were evaluated in Step I.C.) Total Area 1. 1. All vapor flow mass velocity Gv = Gv = 2. Np Wv 19.6 Nt di2 , or 1.273 x 10 6 Np Wv Nt di2 lb/sec-ft2 = (Metric) kg/s-m2 = (W v = Total vapor rate to condenser.) This mass velocity will be used to calculate the ∆P for each zone of the condenser. Hydrocarbon condensing zone inlet volumes a. Vapor (1) ρ v1 = Inlet MW Pi (psia) 1 10.7 T1 + 460 u lb/ft3 = or ρ v1 = b. Inlet MW Pi (kPa abs) 1 8.31 T1 + 273 u (Metric) kg/m3 = (2) Vapor rate, W v1(dh) = lb/hr kg/s (3) Vv1(dh) = W v1(dh) / ρv1(dh) = ft3/hr m3/s (1) ρl1( dh ) = lb/ft3 kg/m3 (2) Liquid rate, Wl1( dh ) = lb/hr kg/s (3) = ft3/hr m3/s Liquid (if present) Vl1( dh ) EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 47 of 79 Date December, 1999 TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS 3. METRIC UNITS Steam condensing zone inlet volumes a. Vapor Vapor MW Pi (psia) 1 T + 460 u 10.7 ds = Vapor MW Pi (kPa abs) 1 T + 273 u 8.32 ds (Metric) (1) ρ v1( ds ) = lb/ft3 or ρ v1( ds ) = b. (2) Vapor rate, W v1(ds) = lb/hr kg/s (3) Vv1(dh) = W v1(ds) / ρv1(ds) Liquid (if present) = ft3/hr m3/s (1) ρl1( ds ) = lb/ft3 kg/m3 (2) Liquid rate, Wl1( ds ) = lb/hr kg/s = ft3/hr m3/s = ft3/hr m3/s = ft3/hr m3/s = = ft/sec m/s = psi Vl1( ds ) = Wl1( ds ) / ρl1( ds ) (3) 4. Steam condensing zone outlet volumes a. Vapor (if present) Vv2 (evaluated in Step III.B.3.) b. Liquid Vl 2 (evaluated in Step III.B.5.) 5. kg/m3 = Vapor desuperheating zone ∆P di G di G or 29 µ 1000 µ a. Re = b. Calculate Fanning friction factor f f = = (Metric) (Re ≤ 2000) = (2000 < Re < 3800) = 16 / Re 10-4 Re 0.575 = 0.0035 + 0.264 / Re0.42 From Step III.C.4., V c. ∆Ptf = 48 f = L ρV 2 µ w di 9270 µ (Re ≥ 3800) 0.14 or 0.25 or = 4000 f L ρV 2 µ w di 2000 µ 0.14 or 0.25 (Metric) = (Use 0.25 for laminar flow) EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. kPa DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F 48 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS d. ∆Ptr = 3 (ρV2 / 9270) = METRIC UNITS psi or ∆Ptr = 3 (ρV2 / 2000) e. (Metric) = A ∆Pdh = Ft Ns Np (∆Ptf + ∆Ptr) dh A = kPa psi kPa = lb/ft3 kg/m3 = ft/sec m/s = psi kPa (For Ft, see Table 3, Section IX-D) 6. Hydrocarbon condensing zone ∆P a. Re = di Ge di Ge or 29 µ f ( l ) 1000 µ f ( l ) (Metric) = ( uf ( l ) was evaluated in Step III.E.8.c.) b. Calculate the average density, ρds ρ ds = 2W Vv1( dh ) + Vl1( dh ) + Vv1( ds ) + Vl1( ds ) c. V = G / ρds d. ρds V2 / 9270 e. f = 16 / Re = 10–4 Re 0.575 or ρds V2 / 2000 (Metric) (Re ≤ 2000) = (2000 < Re < 3800) = = 0.0035 + 0.264 / Re0.42 f. ∆Ptf = 48 f L ρds V 2 µ w di 9270 µ (Re ≥ 3800) = 0.14 or 0.25 = psi or = 4000 f L ρds V 2 µ w di 2000 µ 0.14 or 0.25 (Metric) = kPa (Use 0.25 for laminar flow) g. ∆Ptr = 3 (ρds V2 / 9270) or ∆Ptr = 3 (ρds V2 / 2000) h. = (Metric) = A ∆Pds = Ft Ns Np (∆Ptf + ∆Ptr) ds A = psi kPa psi (For Ft, see Table 3, Section IX-D) EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. kPa DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 49 of 79 Date December, 1999 TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN CUSTOMARY UNITS 7. METRIC UNITS Steam condensing zone ∆P a. Re = di G 29 µ f ( l ) = or di G (Metric) 1000 µ f ( l ) ( uf ( l ) was evaluated in Step III.D.9.c.) b. Calculate the average density, ρds ρds = 2W Vv1( dh ) + Vl1( dh ) + Vv1( ds ) + Vl1( ds ) = lb/ft3 kg/m3 m/s c. V = G / ρds = ft/sec d. ρds V2 / 9270 = psi or ρds V2 / 2000 e. f (Metric) kPa (Re ≤ 2000) = (2000 < Re < 3800) = (Re ≥ 3800) = = 16 / Re = 10-4 Re 0.575 = 0.0035 + 0.264 / Re0.42 f. ∆Ptf = 48 f 2 L ρsc V di 9270 µw µ 0.14 or 0.25 = psi or = 4000 f L ρsc V 2 µ w di 2000 µ 0.14 or 0.25 (Metric) = kPa (Use 0.25 for laminar flow) g. ∆Ptr = 3 (ρsc V2 / 9270) = psi or ∆Ptr = 3 (ρds V2 / 2000) h. (Metric) = A ds A = psi kPa = psi kPa ∆Psc = Ft Ns Np (∆Ptf + ∆Ptr) kPa (For Ft, see Table 3, Section IX-D) 8. Total condensing-side pressure drop ∆P = ∆Pdh + ∆Pds + ∆Psc EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F 50 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 TABLE 2 (Cont) CALCULATION PROCEDURE FOR CONDENSER DESIGN Notes: Note 1 Pt Note 2 Max. Area Per Shell (Square Pitch)* 16 ft Tubes 20 ft Tubes 3/4 in. tubes — 1.000 in. 4780 ft2 5950 ft2 1 in. tubes — 1.250 in. 4140 ft2 5150 ft2 1 1/2 in. tubes — 1.875 in. 2660 ft2 3300 ft2 Note 1 Pt Note 2 Max. Area Per Shell (Square Pitch)* 4.88 m Tubes 6.1 m Tubes 19.05 mm tubes — 25.4 mm 444 m2 553 m2 25.4 mm tubes — 31.75 mm 385 m2 478 m2 38.1 mm tubes — 47.63 mm 247 m2 307 m2 * For triangular pitch, use the area of same size of tubes divided by 0.866 and (Pt of triangle / Pt of square)2 if a different tube pitch is used. Note 3 Do not make “D" smaller than (Dt + 1 in.) or (Dt + 25.4 mm) nor larger than (Dt + 3 in.) or (Dt + 76.2 mm). 1 for E & J shells FBT = 1 for Segmental Baffles Note 4 FF = FJ = 2 for F shells = 0.5 for J shells = 1 for E & F shells = 2 for Double Segmental Baffles EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. EXXON ENGINEERING DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 51 of 79 Date December, 1999 TABLE 3 WIDE-CUT CONDENSER DESIGN SAMPLE CALCULATION CUSTOMARY A. METRIC Design Data Inlet vapor is pipestill overhead 1. Condensable HC 2. 3. 4. 5. = 20,000 lb/hr 2.52 kg/s Mean ABP = 231°F 110.6°C M.W. = 100 100 ρ = 49.9 lb/ft3 799 kg/m3 Noncondensables (Hydrocarbon M.W. = 58) Steam ASTM Distillation of Condensable Hydrocarbon: = 580 lb/hr 0.073 kg/s = 720 lb/hr 0.0907 kg/s IBP - 165°F IBP - 73.9°C 60 - 127.8°C 10 - 183 70 - 269 20 - 211 80 - 274 30 - 231 90 - 283 40 - 245 FBP - 300 50 - 255 Tower overhead pressure - 5.3 psig 10 - 83.9 20 - 99.4 30 - 110.6 40 - 118.3 50 - 123.9 = 20.0 psia 70 - 131.7 80 - 134.4 90 - 139.4 FBP - 148.9 Tower overhead temperature = 263°F 128.3°C 60 - 262°F 36.5 kPa gage = 137.8 kPa abs 6. Assume condensate cooled to 95°F (35°C); water rise is 80 to 95°F (27 to 35°C) B. Calculations 1. Flash Curves From ASTM Distillation t10 = 183°F t70 = 269°F t10 = 83.9°C t70 = 131.7°C t30 = 231°F t90 = 283°F t30 = 110.6°C t90 = 139.4°C t50 = 255°F ∆1 = t50 = 123.9°C 2 (269 − 183) = 57 3 ∆1 = 2 (131.7 − 83.9 ) = 31.9 3 From Figure 6, ∆2 = 31, ∆3 = 16, ∆1 – ∆3 = 41 ∆2 = 18, ∆3 = 9.5, ∆1 – ∆3 = 22.4 t10f = t10 + (∆1 – ∆3) – ∆2 = 183 + 41 – 31 = 193°F t10f = t10 + (∆1 – ∆3) – ∆2 = 83.9 + 22.4 – 18 = 88.3°C t30 f = t10 + 2 ∆1 ∆2 + ( t30 − t10 ) + ( ∆1 − ∆3 ) − = 220o F 3 2 3 t30 f = t10 + t50f = 231°F = 110.2°C t70f = 240°F = 115.3°C 2 ∆1 ∆2 + ( t30 − t10 ) + ( ∆1 − ∆3 ) − = 104.5o C 3 2 3 = 122.6°C t90f = 252°F The above are points on the volumetric flash curve. To estimate the molal and weight flash curves, use the equations given in Section IX-F and obtain: t10w = 195°F t10m = 192°F t10w = 89.4°C t10m = 87.9°C t30w = 226°F t30m = 220°F t30w = 106.7°C t30m = 103.6°C t50w = 233°F t50m = 230°F t50w = 111.3°C t50m = 109.8°C t70w = 242°F t70m = 239°F t70w = 116.5°C t70m = 114.8°C t90m = 252°F t90w = 123.2°C t90w = 253°F The three sets of points are plotted and connected as shown in Figure 2. t90m = 122.4°C EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F 52 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING TABLE 3 (Cont) WIDE-CUT CONDENSER DESIGN SAMPLE CALCULATION 2. Calculate Tds (Since this is overhead from a fractionator, Tdh = t1) Molar composition of inlet vapor: Condensables: 20,000 lb / hr = 200 mol/hr 100 lb / hr NC: 580/58 = 10 (NC: Noncondensables) Steam 720/18 = 40 250 mol / hr total 2.520 kg / s = 0.0252 kmol/s 100 kg / kmol 0.0731/58 = 0.0013 0.0907/18 = 0.0050 kmol/s 0.0315 Partial pressure, condensables + NC = 210 x 20.0 = 16.8 psia 250 = 0.0265 x 137.8 = 115.9 kPa abs 0.0315 Partial pressure, condensables 200 x 20.0 = 16.0 psia 250 = 0.0252 x 137.8 = 110.2 kPa abs 0.0315 = Partial pressure of steam = 20.0 – 16.8 = 3.2 psia = 137.8 – 115.9 = 21.9 kPa abs Determine conditions at 20 wt% HC condensed (see Table on following page). From the flash curves, the atmospheric-pressure temperature would be 248°F (119.9°C) at 20 wt% condensed. Move horizontally at 248°F (119.9°C) to the molal flash curve, and note that 16.8 mol% has been condensed. Calculate the remaining condensate moles: 200 – (0.168 x 200) = 166 mol Total remaining mols of vapor = 166 +10 + 40 = 216 Pressure drop is assumed negligible, so that P = 20.0 psia 0.0252 – (0.166 – 0.0252) = 0.021 kmol = 0.0210 + 0.0013 + 0.005 = 0.0273 = 137.8 kPa abs Partial pressure steam = 40 x 20.0 = 3.7 psia 216 = 0.005 x 137.8 = 25.2 kPa abs 0.0273 Partial pressure, condensables 166 x 20.0 = 15.4 psia 216 = 0.021 x 137.8 = 106 kPa abs 0.0273 = WIDE-CUT CONDENSER DESIGN SAMPLE CALCULATION From the alignment chart, Figure 3, the temperature of the hydrocarbon [which normally boils at 248°F (119.9°C)] is 250°F (121.1°C) at 15.4 psia (105.9 kPa abs). From the same chart, the vapor pressure of water at 250°F (121.1°C) is 29.0 psia (177 kPa abs). Since the partial pressure of the water is less than its vapor pressure (3.7 < 29.0 psia) (25.2 < 177 kPa), steam is not yet condensing. Therefore, it is necessary to make another trial at a higher percentage HC condensed. Each successive trial is tabulated. At 85% HC condensed, the partial pressure of water was found to be 913 psia (64.2 kPa abs), while its vapor pressure should have been 6.3 psia (45.5 kPa abs). Hence, steam is condensing, and Tds has been passed. The exact value of Tds is found by plotting the vapor pressure and partial pressure of water on the same graph, as shown in Figure 2. The composition at Tds is then determined and entered in the last column of the table. For this case, Tds = 184°F (82.8°C). Vapor Pressure of Water @ 184°F (82.8°C) = Partial Pressure = 8.3 psia (57.7 kPa abs) Partial Pressure of condensables + NC = 20.0 – 8.3 = 11.7 psia = 137.8 – 57.7 = 80.1 kPa abs EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F 53 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 TABLE 3 (Cont) PARAMETER CUSTOMARY UNITS Wt.% Hydrocarbon Condensed(1) Vapor Temp. @ Atm. Pressure(2) Mol % HC not Condensed(2) Mol of HC not Condensed Mol of noncondensables (“NC") Mol of Steam Total Mols of Vapor Total Pressure, psia(3) Partial Pressure of Steam Partial Pressure of Condensables System Temperature(4) Vapor Pressure of H20 at System Temp.(5) 0 258 100 200 10 40 250 20.0 3.2 16.0 263 35.5 20 248 83.2 166 10 40 216 20.0 3.7 15.4 250 29.0 70 226 42.5 85 10 40 135 20.0 5.9 12.6 215 15.2 PARAMETER 80 210 23.5 47.0 10 40 97 20.0 8.2 9.7 186 8.6 85 203 18.1 36.2 10 40 86.2 20.0 9.3 8.4 173 6.3 81 — 23 46 10 40 96 20.0 8.3 — 184 8.3 85 93.8 17.6 0.00444 0.0013 0.0050 0.01074 137.8 64.2 57.0 75.6 45.5 80.5 — 22.4 0.00564 0.0013 0.0050 0.01194 137.8 57.7 — 82.8 57.7 METRIC UNITS Wt.% Hydrocarbon Condensed(1) Vapor Temp. @ Atm. Pressure(2) Mol % HC not Condensed(2) Mol of HC not Condensed Kmol of noncondensables (“NC") Kmol of Steam Total Kmol of Vapor Total Pressure, kPw abs(3) Partial Pressure of Steam Partial Pressure of Condensables System Temperature(4) Vapor Pressure of H20 at System Temp.(5) 0 126.2 100 0.0252 0.0013 0.0050 0.0315 137.8 21.9 110.2 128.3 210 20 119.9 83.4 0.0210 0.0013 0.0050 0.0273 137.8 25.2 106.0 121.1 177 70 106.7 39.9 0.0101 0.0013 0.0050 0.0164 137.8 42.0 84.9 101.1 103 80 98.0 22.9 0.00577 0.0013 0.0050 0.01207 137.8 57.1 65.9 83.9 59.3 Notes: (1) Arbitrary values. (2) Read from flash curves, Figure 2. (3) (4) Assume percent pressure drop = condensed (neglected in this example). Vapor temp. @ 1 atm. adjusted to the partial pressure of condensables by means of the alignment chart, Figure 3. (5) From steam tables or from alignment chart, Figure 3 (use the point marked H20 as the “normal boiling point"). Remaining Condensable moles = x; moles of condensables + NC = x + 10 (= x + 0.0013). Total moles = x + 10 + 40 (= x + 0.0013 + 0.0050). x + 10 x + 50 x + 0.0013 x 20.0 = 11.7 x + 0.0063 Solving for x, remaining condensable moles = 46 Mol% NOT condensed = ( 46) (100 ) 200 = 23% x 137.8 = 80.1 = 0.0056 = (0.0056 ) (100 ) 0.0252 = 22% From the flash curves, 23 mol% (22 mol%) not condensed corresponds to 19 wt% not condensed. First zone condensate = 20,000 (1 – 0.19) = 16,400 lb/hr = 2.52 (1 – 0.19) = 2.04 kg/s EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F 54 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING TABLE 3 (Cont) WIDE-CUT CONDENSER DESIGN SAMPLE CALCULATION CUSTOMARY 3. METRIC Heat Release a. From T1 to Tds (Zone 1) Temp change = 263 – 184 = 79°F Average % From Blue Book, = 224°F c (vapor + N.C.) c (condensate) c (steam) λ (condensate) = 128.3 – 82.8 = 45.5°C = 105.6°C = 2.05 = 1.88 = 1.90 = 333 = 0.49 = 0.45 = 0.453 = 143 Vapor Cooling Steam Vapor + N.C. (720) (4,180) (79) (79) (0.453) = 0.026 x 106 (0.49) = 0.162 Condens. Vapor (16,400 ) 2 (79) (0.49) = (16,400 ) 2 (79) (0.45) = 0.292 x 106 Btu/hr 0.318 0.506 x 10 6 (103) (0.0907) (103) (0.5531) (45.5) (45.5) (1.90) (2.05) = 7.8 x 103 = 51.6 (103) (2.040/2) (45.5) (2.05) = (2.040) 2 (1.88) = 87.3 x 103 W 95.1 154.5 x 103 Liquid Cooling Condens. Liquid (103) (45.5) LATENT HEAT Hydrocarbon (16,400) (143) qds = Zone Total b. From Tds to T2 (Zone 2) Temp Change Average T From Blue Book: c (vapor + N.C.) c (Steam) c (Condensate) λ (Condensate) λ (Water) Vapor Cooling N.C. (580) Condens. Steam (720/2) (89) (89) Condens. Vapor (3,600/2) (89) = 2.34 x 106 Btu/hr = 3.14 x 106 Btu/hr = (103) (2.04000) (333) = 679.3 x 103 W = 921.1 x 103 W = 184 – 95 = 89°F = 82.8 – 35 = 47.8°C = 140°F = 58.9°C = 0.44 Btu/lb°F = 0.448 Btu/lb°F = 0.405 Btu/lb°F = 143 Btu/lb = 1,020 Btu/lb = 1.84 kJ/kg-K = 1.88 kJ/kg-K = 1.70 kJ/kg-K = 333 kJ/kg = 2,370 kJ/kg (0.44) = 0.0023 x 106 (0.448) = 0.014 (103) (0.0731) (47.8) (103) (0.0907/2) (47.8) (1.84) (1.88) = 6.4 x 103 = 4.1 (103) (0.4536/2) (47.8) (1.84) = (103) (2.0400) (47.8) (103) (0.4536/2) (47.8) (1.70) (1.70) = 165.8 x 103 = 18.4 (103) (0.0907/2) (47.8) (4.19) = (0.44) = 0.071 0.108 x 106 19.9 30.4 x 103 Liquid Cooling Entering Liquid (16,400) (89) Condens. Liquid (3,600/2) (89) (0.405) = 0.591 x 106 (0.405) = 0.064 Condens. Steam (720/2) (1.0) (89) = 0.032 0.687 x 10 6 9 .1 193.3 x 103 Latent Heat Hydrocarbon (3,600) (143) Steam (720) qsc = Zone Total Total Condenser Duty = 0.515 x 106 (1,020) = 0.735 1.250 x 106 Btu / hr (103) (0.4536) (333) = 151 x 103 (103) (0.0907) (2370) = 215 x 103 366 x 103 W = 2.05 Btu/hr = 589.7 x 103 W = 3.14 + 2.05 = 5.19 MMBtu/hr = 921.1 x 103 + 589.7 x 103 = 1.511 x 106 W EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 55 of 79 Date December, 1999 TABLE 4 A SAMPLE CONDENSER DESIGN I. Exchanger Number E - 100 Refinery Service Calc By/Date Pipestill Overhead Condenser ZONE DUTIES AND TEMPERATURES* A. Vapor Desuperheating Zone (If Present); 1st Zone CUSTOMARY UNITS METRIC UNITS qdh Fluid Being Condensed (Shell/Tube) = Btu/hr W T1 = °F °C Tdh Fluid Being Heated (Shell/Tube) = °F °C t2 = °F °C tdh = °F °C T −T R = 1 dh = t 2 − t dh = t 2 − t dh = T1 − t dh = = °F °C = °F °C ts = 0.4 (T1 – Tdh) + Tdh = °F °C tt = 0.4 (t2 – tdh) + tdh = °F °C tt = 0.4 (T1 – Tdh) + Tdh = °F °C ts = 0.4 (t2 – tdh) + tdh = °F °C = Btu/hr-°F W/K j= ∆tm = (T1 − t 2 ) − (Tdh − t dh ) T −t ln 1 2 Tdh − t dh From charts given in Section IX-D Fn = for this zone** ∆te(dh) = ∆tmFn For shell-side condensation: For tube-side condensation: qdh ∆t e * ** Use LMTD correction factor for each zone, based on zone temperatures Use LMTD corrections factor, based on terminal temperatures to evaluate minimum number of shells in series. Fn must be equal to or greater than 0.8. EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F EXXON ENGINEERING 56 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 TABLE 4 (Cont) A SAMPLE CONDENSER DESIGN B. Hydrocarbon Condensing Steam Desuperheating Zone (2nd Zone) CUSTOMARY UNITS qds Fluid Being Condensed (Shell/Tube) = 3.14 x 106 Tdh = 263 Tds = 184 tdh = tds = METRIC UNITS 921.1 x 103 W °F 128.3 °C °F 84.4 °C 95 °F 35.0 °C 86 °F 30.0 °C Btu/hr R= Tdh − Tds = t dh − t ds = 8.78 8.78 j= t dh − t ds = Tdh − t ds = 0.051 0.051 = 130 °F 72.2 °C ∆te(ds) = ∆tm Fn For shell-side condensation: = 130 °F 72.2 °C ts = 0.4 (Tdh – Tds) + Tds = 216 °F 102 °C tt = 0.4 (tdh – tds) + tds For tube-side condensation: = 90 °F 32 °C tt = 0.4 (Tdh – Tds) + Tds = °F °C ts = 0.4 (tdh – tds) + tds = °F °C ∆tm = (Tdh − t dh ) − ( Tds − t ds ) T −t ln dh dh Tds − t ds From charts given in Section IX-D, Fn = 1.0 for 1 shells qds ∆Te C. = 24,200 Btu/hr-°F 12,800 W/K qsc Fluid Being Condensed (Shell/Tube) = 2.05 x 106 Btu/hr 589.7 x 103 W Tds = 184 °F 84.4 °C T2 = 95 °F 35.0 °C tds = 86 °F 30.0 °C t1 = 80 °F 26.7 °C T − T2 = R = ds t ds − t1 = 14.8 14.8 t ds − t1 = Tds − t1 = 0.058 0.058 Steam Condensing Zone (3rd Zone) j= EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 57 of 79 Date December, 1999 TABLE 4 (Cont) A SAMPLE CONDENSER DESIGN ∆tm = (Tds − t ds ) − (T2 − t1) T −t ln ds ds T 2 − t1 CUSTOMARY UNITS METRIC UNITS = ______________ = 44.2 °F 24.6 °C ∆te(sc) = ∆tmFn For shell-side condensation: = 42.4 °F 23.6 °C ts = 0.4 (Tds – T2) + T2 = 131 °F 55.0 °C tt = 0.4 (tds – t1) + t1 For tube-side condensation: = 82 °F 28.0 °C tt = 0.4 (Tds – T2) + T2 = °F °C ts= 0.4 (tds – t1) + t1 = °F °C From charts given in Section IX-D, Fn = 0.96 for 1 shells qsc ∆t e D. = Q qdh qds qsc + + ∆t e( dh ) ∆t e( ds ) ∆t e( sc ) where: Q = qdh + qds + qsc * Btu/hr-°F 25,000 WK Weighted Temperature Difference ∆t ew = II. 48,500 = 5.19 3.14 / 130 + 2.05 / 42.4 15.11 9.21 / 72.2 + 5.9 / 23.6 = 71.3 °F 40 °C = 48.5 Btu/hr-ft2-°F 272 W/m2-K 139 m2 SHELL-SIDE CONDENSATION A. Overall Tube-Side Calculation (No Change of Phase) 1. Assumed value of Uo 2. 3. A = Q / Uo ∆tew Tube metal: ___________________ = 1500 ft2 Thermal conductivity, kw Tube outer diameter, do = = 64 0.75 Btu/hr-ft-°F in. 110.8 19.05 W/m-K mm Wall thickness, l = 0.0054 ft 0.00165 m Tube insider diameter, di Tube length, L = = 0.62 20 in. ft 15.75 6.1 mm m 4. Tube pitch (Pt) and layout (Note 1)* = 1.0 in. 25.4 mm 5. As = A / Ns (Note 2)* = 1500 ft2 139 m2 6. Nt = 3.82 As / (L – 0.5) do, or Nt = 318 As / (L – 0.152) do (Metric) = = 392 General notes contained on last page of calculation form. EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. 390 DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F EXXON ENGINEERING 58 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 TABLE 4 (Cont) A SAMPLE CONDENSER DESIGN CUSTOMARY UNITS METRIC UNITS 7. Assumed Np = 2 8. ts overall = 0.4 (T1 – T2) + T2 = 162 °F 723 °C 9. tt overall = 0.5 (t1 + t2) 10. Tube-side properties at tt = 87.5 °F 30.8 °C a. Density, ρ = 62.4 lb/ft3 999.5 kg/m3 b. Viscosity, µ = 0.8 cP 0.0008 Pa•s c. Specific Heat, c = 1.006 Btu/lb-°F d. Thermal Conductivity, k = 11. Tube-side flow rate, W = Q / c (t2 – t1) = 346,000 lb/hr = 3.8 ft/sec 12. V = V = Np W (19.6) ρ N t di2 or (1.273 x 10 6 ) Np W ρ N t di2 2 4.2 Btu/hr-ft-°F (Metric) kJ/kg-K W/m-K 43.3 kg/s 1.14 m/s 4860 W/m2-K 22.8 kPa 13. If tube-side fluid is water hio = 368 t ( Vdi )0.7 t do 100 0.26 = 863 Btu/hr-ft2-°F or h io = 1.8 t t + 32 1.27 x 10 4 ( Vd i ) 0.7 do 100 0.26 (Metric) = ( V )1.73 ∆P = 0.020 Ft N s Np V 2 + 0.158 L (d i )1.27 = 3.4 psi or ( V )1.73 ∆P = 1.48 Ft N s Np V 2 + 22.9 L (d i )1.27 (Metric) = 14. For fluids other than water, evaluate overall tube-side heat transfer coefficient and pressure drop by the procedure outlined in Section IX-D, tube-side iteration. hio = Btu/hr-ft2-°F W/m2-K ∆Pt = psi kPa 15. Rio = 1 / hio = 0.00116 hr-ft2-°F/Btu 0.000206 m2-K/W 16. Tube-side fouling factor, ri = 0.00150 hr-ft2-°F/Btu 0.000264 m2-K/W 0.000320 m2-K/W 0.000176 m2-K/W 17. rio = (do / di) ri = 0.00181 hr-ft2-°F/Btu 18. Shell-side fouling factor, ro = 0.001 hr-ft2-°F/Btu EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 59 of 79 Date December, 1999 TABLE 4 (Cont) A SAMPLE CONDENSER DESIGN CUSTOMARY UNITS 19. rw = l / kw B. = METRIC UNITS 0.00008 hr-ft2-°F/Btu 0.000015 m2-K/W 0.000717 m2-K/W 20. 1 / Uox = Rio + rio + rw + ro = 0.00405 hr-ft2-°F/Btu 21. Uox = 247 Btu/hr-ft2-°F 1395 W/m2-K = 132 °F 55.6 °C Overall Shell-Side Calculation 1 U ( t s − t1) 1 − o 2 U ox 1. t f = ts − 2. For fluids other than hydrocarbons, determine vapor film properties. For hydrocarbons, determine only liquid viscosity µf 3. Viscosity, µf = Specific Heat, cf = Btu/lb-°F kJ/kg-K Thermal Conductivity, kf = Btu/hr-ft-°F W/m-K NTC = 1.19 = 1.10 cP 0.00035 Pa•s Nt square layout Nt triangular layout 4. 5. Dt = (NTC – 1) Pt + do D = Dt / 0.9 (Note 3) 6. S= 7. 8. 0.35 D − (do NTC ) (Note 4) FF Assumed Pb NB = FF (10L / Pb) (Note 4), or NB = FF (833 L / Pb) (Note 4) (Metric) 9. Ax = S (Pb – 0.375) (Segmental Baffles) or Ax = S (Pb – 9.53) (Metric) Ax = 0.85S (Pb – 0.375) (Double Segmental Baffles) or Ax = 0.85S (Pb – 9.53) (Metric) 10. Total shell-side flow rate, W = 23.6 = = 23.3 26.0 in. in. 590.6 656.2 mm mm = 8.3 in. 208.5 mm = = 13.375 in. 340 mm 107.9 in.2 68903 mm2 2.684 mm2 kg/s = = = = = = 23.5 in.2 21,300 lb/hr EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F EXXON ENGINEERING 60 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 TABLE 4 (Cont) A SAMPLE CONDENSER DESIGN CUSTOMARY UNITS METRIC UNITS 11. Inlet vapor density and volume ρ v1 = Inlet MW 10.7 Pi (psia) 1 T1 + 460 u = 0.256 lb/ft3 or ρ v1 = Inlet MW Pi (kPa abs) 1 T + 273 u 8.29 1 (Metric) Inlet vapor rate, W v1 = Vv1 = W v1 / ρv1 12. Outlet vapor density and volume ρv2 = = Outlet MW Pi (psia) 1 T + 460 u 10.7 2 4.1 kg/m3 21,300 lb/hr 2.684 kg/s = 83,200 ft3/hr 0.655 m3/s = 0.204 lb/ft3 3.26 kg/m3 or ρv2 = Outet MW Pi (kPa abs) 1 T + 273 u 8.29 2 Outlet vapor rate, W v2 Vv2 = W v2 / ρv2 13. Inlet liquid density and volume (Metric) = = = 580 lb/hr 0.0731 kg/s 2840 ft3/hr 0.0224 m3/s ρl1 = lb/ft3 kg/m3 Inlet liquid rate, Wl1 = lb/hr kg/s Vl1 = Wl1 / ρl1 = ft3/hr m3/s 14. Inlet liquid density and volume ρl 2 = 38.7 lb/ft3 619 kg/m3 Inlet liquid rate, Wl 2 = 20,720 lb/hr 2.61 kg/s Vl 2 = Wl 2 / ρl 2 = 535 ft3/hr 0.0042 m3/s = 0.491 lb/ft3 7.88 kg/m3 1.25 psi 15. Average mixture density ρ= 2W Vv1 + Vl1 + Vv 2 + Vl 2 16. Calculate shell-side pressure drop (∆Ps) using = procedures outlined in Section IX-D, Shell-Side Iteration The above-assumed geometry will now be checked using the following detailed procedures. EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. 8.53 kPa DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 61 of 79 Date December, 1999 TABLE 4 (Cont) A SAMPLE CONDENSER DESIGN CUSTOMARY UNITS C. METRIC UNITS Vapor Desuperheating Zone (Shell-Side Condensation) 1. 2. t +t U t f = s t + o (Rio + rio + rw + ro ) ( t s − t t ) 2 2 = °F = lb/ft3 °C (ts and tt for this zone were calculated in Step I.A.) Inlet vapor density and volume ρ v1 = Inlet MW 10.7 Pi (psia) 1 T1 + 460 u or ρv1 = 3. Inlet MW Pi (kPa abs) 1 8.31 T1 + 273 u (Metric) kg/m3 = For fluids other than hydrocarbons, determine film properties. For hydrocarbons, determine only µf Viscosity, µf = cP Pa•s Specific Heat, cf = Btu/lb-°F kJ/kg-K Thermal Conductivity, kf = Btu/hr-ft-°F W/m-K 4. Calculate shell-side coefficient (hgc) using Section IX-D, Shell-Side iteration = Btu/hr-ft2-°F W/m2-K 5. Udh = = Btu/hr-ft2-°F W/m2-K = ft2 m2 hgc Uox hgc + Uox (Uox was evaluated in Step II.A.21.) 6. A dh = qdh ∆t e Udh (qdh and ∆te were evaluated in Step I.A.) D. Hydrocarbon Condensing - Steam Desuperheating Zone (Shell-Side Condensation) 1. Assume a zone area, Ads = 400 ft2 37.2 m2 2. Uds assumed = qds A ds ∆t e = 60.4 Btu/hr-ft2-°F 342.9 W/m2-K (qds and ∆te for this zone were evaluated in Step I.B.) EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F EXXON ENGINEERING 62 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 TABLE 4 (Cont) A SAMPLE CONDENSER DESIGN CUSTOMARY UNITS 3. t f = ts − U 1 ( t s − t t ) 1 − ds 2 Uox = 168.4 = 1.71 0.46 METRIC UNITS °F °C 75.8 (ts and tt for this zone were evaluated in Step I.B.) 4. ∆Tzone inlet = ∆Tzone outlet Tdh − t dh Tds − t ds 1.71 5. Fv (Figure 4) = 6. Average zone vapor rate, W v (Fv) (Vapor condensed in zone, W c) + (Vapor not condensed in zone, W v2) = Wv lb/hr = 7550 = 4900 =12450 Average Mol. weight of vapor = 74.6 lb / hr mol / hr = 0.25 lb/ft3 7. 0.46 mol/hr 71 96 167 kg/s 0.938 0.643 1.587 kmol/s 0.009 0.0119 0.0209 75.6 kg / s kmol / hr Average vapor properties at film temperature a. Density, ρ v = Avg MW P (psia) 1 t + 460 u 10.7 f or Density, ρ v = b. Avg MW 8.31 P (kPa abs) 1 (Metric) t f + 273 u Viscosity, µf (Used for hgc calc.) = 4.0 kg/m3 = 0.0088 cP 0.88 x 10-5 Pa•s 8850 lb/hr 1.1 kg/s 8. Wl = W − Wv = 9. Average condensate properties at film temp. a. Specific gravity, sf = 0.65 b. = 0.077 Btu/hr-ft-°F 0.133 W/m-K = 0.3 cP 0.0003 Pa•s = 22.7 Thermal Conductivity, kf c. Viscosity, µf 10. Condensing Coefficient (Horizontal Bundle) a. ns = 1.29 Nt 0.48 (90° Square Tube Layout) ns = 1.02 Nt 0.519 (30° Triangular Layout) (For other layouts, see text) b. Lc = A ds (L − 0.5 ) Ns A 0.65 22.6 = = 5.2 ft or Lc = A ds (L − 0.152) Ns A (Metric) = (Note that if zone occupies more than one shell, Lc will be a multiple of the tube length.) EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. 1.59 m DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 63 of 79 Date December, 1999 TABLE 4 (Cont) A SAMPLE CONDENSER DESIGN CUSTOMARY UNITS Wc L c ns c. Γ= d. s2 8.33 x 10 3 kf f h′λ = µf Γ 1/ 3 condensate METRIC UNITS = 139 lb/hr-ft = 139 Btu/hr-ft2-°F 0.0568 kg/s-m 766.4 W/m2-K 1/ 3 or 1/ 3 s2 204 h′λ = k f f µf Γ1 / 3 condensate e. 1 W µ (v) = 1+ v f xl Wl µ f ( l ) f. xv = 1− x l g. Gv = 0.111 ρl ρ v (Metric) = 0.555 = 17 17 = 0.941 0.941 FJ Wv , (Note 4), 25 A x x v FBT = 4.9 10 6 Wv FJ A x x v FBT = lb/sec-ft2 or Gv = h. G h λ = h′λ v 5 (Metric) 24.5 kg/sm2 768.1 W/m2-K 0.70 = 137 Btu/hr-ft2-°F or G h λ = h′λ v 24.4 0.70 (Metric) = If hλ > 2 h′λ , use 2.0 h′λ (For pure components, h λ = h′λ ) 11. Condensing Coefficient (Vertical Bundles) a. Γ= 12 Wc π Nt do = lb/hr-ft or Γ= 1000 Wc π Nt do (Metric) = kg/s-m 1/ 3 b. 2 1.04 x 10 4 k f sf hλ = 1 / 3 µf Γ condensate = Btu/hr-ft2-°F or 1/ 3 s2 254 hλ = 1 / 3 k f f µf Γ condensate (Metric) = EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. W/m2-K DESIGN PRACTICES Section CALCULATION PROCEDURE, CONDENSATION Page IX-F HEAT EXCHANGE EQUIPMENT EXXON ENGINEERING 64 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 TABLE 4 (Cont) A SAMPLE CONDENSER DESIGN CUSTOMARY UNITS METRIC UNITS 12. Vapor cooling coefficient Calculate h′gc using procedures outlined in Section IX-D, shell-side iteration (use W v as the flowrate) h′gc = 16.0 Btu/hr-ft2-°F 89.3 W/m2-K = 22.6 Btu/hr-ft2-°F 126.4 W/m2-K Tdh + Tds − tf Wc 2 = 0.59 C1 = 1 − Wv1 (Tdh − Tds ) C 1 1 = + 1 h gc h λ h ′gc hgc 13. Liquid cooling coefficient (Horizontal Bundles) a. Bottom Cooling Coefficient Calculate h′lc using procedures outlined in Section IX-D, shell-side iteration (use Wl as condensate flow rate) h′lc b. Drip Cooling Coefficient c. hdc = 1.5hλ Total liquid cooling coefficient (Horizontal) Bundles), Liquid entering zone, Wl h lc = 2 h dc h ′lc h dc + h′lc = 17.6 Btu/hr-ft2-°F 99.5 W/m2-K = = 205.5 Btu/hr-ft2-°F lb/hr 1152.2 W/m2-K kg/s = 32.4 Btu/hr-ft2-°F 183.2 W/m2-K or h lc = ( Wl + Wc ) h dc h ′lc Wc W h′lc + Wl + c h dc 2 2 = Btu/hr-ft2-°F W/m2-K = Btu/hr-ft2-°F W/m2-K = 2.34 x 106 = 0.506 x 106 Btu/hr Btu/hr 679.3 x 103 154.5 x 103 W W = 0.292 x 106 Btu/hr 87.3 x 103 W = 64.8 Btu/hr-ft2-°F 356.6 W/m2-K = 51.3 Btu/hr-ft2-°F 284 W/m2-K (For liquid + vapor entering zone) 14. Liquid cooling coefficient (Vertical Bundles) hlc = hλ 15. Weighted hydrocarbon condensing zone coefficient a. Zone condensing duty, qλ b. Zone vapor cooling duty, qgc c. Zone liquid cooling duty, qlc hds = Uds = qds qλ qgc qlc + + hλ hgc hlc hds Uox hds + Uox (Uox was evaluated in Step II.A.21.) EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 65 of 79 Date December, 1999 TABLE 4 (Cont) A SAMPLE CONDENSER DESIGN CUSTOMARY UNITS METRIC UNITS 16. Zone Area A ds = qds Uds ∆t e( ds ) = 471 ft2 44.9 m2 = 47.1 Btu/hr-ft2-°F 265.5 W/m2-K = 111 °F 44.1 °C = 6.53 0.36 (qds and ∆te for this zone were evaluated in Step I.B.) E. Steam Condensing Zone (Shell-Side Condensation) qsc ( A − A ds ) ∆t e( sc ) 1. Usc = 2. t f = ts − U 1 ( t s − t t ) 1 − sc 2 Uox (ts and tt for this zone were evaluated in Step I.C.) 3. ∆Tzone inlet ∆Tzone outlet = Tds − t ds = _____________ T2 − t1 6.53 4. Fv (Figure 4) = 5. Average zone vapor rate, W v (Fv) (Vapor condensed in zone, W c) + Non Condensable = Wv lb/hr = 1550 = 580 = 2135 Average Mol. weight of vapor = 52.0 lb / hr mol / hr = 0.183 lb/ft3 6. 0.36 mol/hr 31 10 41 kg/s 0.196 0.073 0.269 kmol/s 0.0036 0.0013 0.0049 54.2 kg / s kmol / hr 2.93 kg/m3 Average vapor properties at film temperature a. Density, ρ v = Avg MW P (psia) 1 10.7 t f + 460 u or ρv = b. 7. 8. Avg MW P (kPa abs) 1 8.31 t f + 273 u (Metric) = Viscosity, µf (Used for hgc calc.) = 0.0068 cP 0.0000068 Pa•s Wl = W – W v = 19165 lb/hr 2.415 kg/s Average condensate properties at film temperature a. Specific gravity, sf = 0.62 b. = 0.078 Btu/hr-ft-°F 0.135 W/m-K = 0.38 cP 0.00038 Pa•s Average zone liquid rate, Wl Thermal conductivity, kf c. Viscosity, µf (Note that hydrocarbon film properties should be used) 0.62 EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F EXXON ENGINEERING 66 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 TABLE 4 (Cont) A SAMPLE CONDENSER DESIGN CUSTOMARY UNITS 9. METRIC UNITS Condensing Coefficient (Horizontal Bundle) ns = 1.29 Nt 0.48 (90° Square Tube Layout) = ns = 1.02 Nt 0.519 (30° Triangular Layout) = b. (For other layouts, see text) Asc = A – Adh – Ads = 1083 ft2 c. Lc = = 14.08 ft a. A sc (L − 0.5) Ns A 22.7 22.6 94.1 m2 4.03 m 0.006 kg/s-m 1522.5 W/m2-K or Lc = A sc (L − 0.152) Ns A (Metric) = (Note that if zone occupies more than one shell, Lc will be a multiple of the tube length.) Wc L c ns d. Γ= e. s2 8.33 x 10 3 kf f h′λ = µf Γ 1/ 3 condensate = 13.6 lb/hr-ft = 273.4 Btu/hr-ft2-°F 1/ 3 or s2 204 h′λ = kf f µf Γ1 / 3 f. 1 W µ (v) = 1+ v f xl Wl µ f ( l ) g. xv = 1− x l h. Gv = 1/ 3 (Metric) = condensate 0.111 ρl ρ v 0.555 FJ Wv , (Note 4), 25 A x x v FBT = 2.39 2.39 = 0.581 0.581 = 1.36 lb/sec-ft2 or Gv = i. 10 6 Wv FJ , (Note 4) A x x v FBT G h λ = h′λ v 5 (Metric) = 0.72 kg/sm2 617.4 W/m2-K 0.7 = 110.3 Btu/hr-ft2-°F or G h λ = h ′λ v 24.4 0.7 (Metric) = If hλ > 2 h′λ , use 2 h′λ (For pure components, h λ = h′λ ) EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 67 of 79 Date December, 1999 TABLE 4 (Cont) A SAMPLE CONDENSER DESIGN CUSTOMARY UNITS METRIC UNITS 10. Condensing Coefficient (Vertical Bundles) a. Γ= 12 Wc π Nt do = 1000 Wc π Nt do = lb/hr-ft or Γ= kg/s-m 1/ 3 b. 2 1.04 x 10 4 k f sf hλ = µf Γ1/ 3 condensate Btu/hr-ft2-°F = or 1/ 3 s2 254 hλ = 1 / 3 k f f µf Γ condensate (Metric) W/m2-K = 11. Vapor cooling coefficient Calculate h′gc using procedures outlined in Section IX-D, shell-side iteration (use W v as the flowrate) h′gc = 5.4 Btu/hr-ft2-°F 30.9 W/m2-K = 6.7 Btu/hr-ft2-°F 38.1 W/m2-K Tdh + Tds − tf Wc 2 = 0.76 12. C1 = 1 − Wv1 (Tdh − Tds ) C 1 1 = + 1 = h gc hλ h′gc hgc 13. Liquid cooling coefficient (Horizontal Bundles) a. Bottom Cooling Coefficient Calculate h′lc using procedures outlined in Section IX-D, shell-side iteration (use Wl as condensate flow rate) h′lc b. Drip Cooling Coefficient c. hdc = 1.5hλ Total liquid cooling coefficient (Horizontal) Bundles), Liquid entering zone, Wl h lc = ( Wl + Wc ) h dc h′lc Wc W h′lc + Wl + c h dc 2 2 = 28.0 Btu/hr-ft2-°F 160.2 W/m2-K = = 165.5 Btu/hr-ft2-°F lb/hr 955 W/m2-K kg/s = 30.8 Btu/hr-ft2-°F 175.6 W/m2-K 14. Liquid cooling coefficient (Vertical Bundles) hlc = hλ = Btu/hr-ft2-°F EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. W/m2-K DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F EXXON ENGINEERING 68 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 TABLE 4 (Cont) A SAMPLE CONDENSER DESIGN CUSTOMARY UNITS METRIC UNITS 15. Weighted steam condensing coefficient a. Zone condensing duty, qλ = 1.25 x 106 Btu/hr-ft2-°F 366 x 103 W/m2-K 0.108 x 106 Btu/hr-ft2-°F 30.4 x 103 W/m2-K b. Zone vapor cooling duty, qgc = c. Zone liquid cooling duty, qlc = 0.687 x 106 Btu/hr-ft2-°F 193.3 x 103 W/m2-K = 41.2 Btu/hr-ft2-°F 236.9 W/m2-K = 35.3 Btu/hr-ft2-°F 202.5 W/m2-K = 1373 ft2 123.4 m2 hsc = Usc = qsc qλ qgc qlc + + hλ hgc hlc hsc Uox hsc + Uox 16. Zone Area A sc = F. qsc Usc ∆t e( sc ) (qsc and ∆te for this zone were evaluated in Step I.C.) Total Area ft2 = A = Adh + Ads + Asc If total area calculated is not reasonably close to total area assumed, reiterate the various zone calculations. G. Condensing Pressure Drop (Shell-Side Condensation) 1. 1. m2 Hydrocarbon condensing zone inlet volumes a. Vapor Vapor MW P (psia) 1 T + 460 u 10.7 dh = 0.256 Vapor MW P (kPa abs) 1 T + 273 u 8.31 dh (Metric) = (1) ρ v1( dh ) = lb/ft3 or ρ v1( dh ) = b. 4.1 kg/m3 (2) Vapor rate, W v1(dh) = 21,300 lb/hr 2.684 kg/s (3) Vv1(dh) = W v1(dh) / ρv1(dh) = 83,200 ft3/hr 0.655 m3/s Liquid (if present) (1) ρl1( dh ) = (2) Liquid rate, Wl1( dh ) = (3) = Vl1( dh ) lb/ft3 0 lb/hr ft3/hr EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. kg/m3 0 kg/s m3/s DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 69 of 79 Date December, 1999 TABLE 4 (Cont) A SAMPLE CONDENSER DESIGN CUSTOMARY UNITS 2. METRIC UNITS Steam condensing zone inlet volumes a. Vapor Vapor MW P (psia) 1 T + 460 u 10.7 ds = 0.171 Vapor MW P (kPa abs) 1 T + 273 u 8.31 ds (Metric) = (1) ρ v1( dh ) = lb/ft3 or ρ v1( dh ) = = 4900 lb/hr 0.644 kg/s (3) Vv1(ds) = W v1(ds) / ρv1(ds) Liquid = 28,700 ft3/hr 0.235 m3/s (1) ρl1( ds ) = 40.5 lb/ft3 648 kg/m3 (2) Liquid rate, Wl1( ds ) = 16,400 lb/hr 2.04 kg/s Vl1( ds ) = Wl1( ds ) / ρl1( ds ) = 405 ft3/hr 0.00315 m3/s Steam condensing zone outlet volumes a. Vapor (if present) Vv2 (evaluated in Step II.B.12.) = 2840 ft3/hr 0.0224 m3/s Vl 2 (evaluated in Step II.B.14.) = 535 ft3/hr 0.0042 m3/s (3) 4. Vapor desuperheating zone ∆Pdh Calculate ∆Pdh using procedures outlined in Section IX-D, shell-side iteration, ∆Pdh 5. 6. 7. kg/m3 (2) Vapor rate, W v1(ds) b. 3. 2.74 = psi kPa Hydrocarbon condensing zone, ∆Pds 2W Vv1( dh ) + Vl1( dh ) + Vv1( ds ) + Vl1( ds ) a. ρds = b. Calculate ∆Pds using procedures outlined in Section IX-D, shell-side iteration = 0.38 lb/ft3 6.01 kg/m3 = 0.41 psi 2.9 kPa = 1.31 lb/ft3 20.3 kg/m3 = 0.35 psi 2.5 kPa = 0.76 psi 5.4 kPa Steam condensing zone ∆Psc 2W Vv1( ds ) + Vl1( ds ) + Vv 2 + Vl 2 a. ρsc = b. Calculate ∆Psc using procedures outlined in Section IX-D, shell-side iteration Total condensing-side pressure drop ∆P = ∆Pdh + ∆Pds + ∆Psc The area calculated in this sample (Item F) is not close enough to the assumed. Making the following modifications and repeating the calculation gives an acceptable area: Nt = 496, NTC = 26.5, Dt = 26.3 in. (668 mm), D = 29.0 in. (737 mm), S = 9.1 in. (231 mm), Ax = 102.1 in.2 (65871 mm2), Pb = 11.6 in. (294.6 mm), and NB = 17. EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F 70 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING FIGURE 1 TYPICAL HEAT RELEASE (“T-Q") CURVE (FOR WIDE-CUT HYDROCARBONS IN THE PRESENCE OF STEAM) Q, MW 0.2 420 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 200 380 T1 180 340 160 140 Vapor Cooling + HC Tdh = HC Dewpoint Condensation + Liquid Cooling 260 120 + Steam Condensation + Water Cooling 220 100 Vapor Tds = Steam Cooling 180 Dewpoint Vapor Cooling + HC 80 Condensation + Liquid Cooling 140 100 60 t2 60 t1 tdh T2 40 tds 0 1 qdh DP9FF01 2 3 4 20 5 qds 6 qsc Q, MM Btu/hr EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. 6.3 Temperature, °C Temperature, °F 300 DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F 71 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 FIGURE 2A SAMPLE FLASH CURVE AND Tds PLOT 260 255 250 245 240 235 230 % ht eig W % e um l Vo M ol e 220 215 220 210 Partial Pressure of Steam 210 205 200 200 Vapor Pressure of H2O 195 190 180 Tds = 184 F 190 170 186 4 6 8 10 12 14 80 90 Pressure, psia 180 0 DP9FFO2A 10 20 30 40 50 60 70 Percent Not Condensed EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. 100 Temperature, F Temperature, F % 225 DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F 72 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING FIGURE 2B SAMPLE FLASH CURVE AND Tds PLOT 125 120 115 % ht eig W 110 % M ol e 105 120 Partial Pressure of Steam 110 100 100 95 90 Vapor Pressure of H2O 90 80 Tds = 82.8 °C 85 70 20 40 60 80 100 120 Pressure, kPa abs 0 DP9FF02B 10 20 30 40 50 60 70 80 90 Percent Not Condensed EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. 100 Temperature, C Temperature, C % e m lu Vo HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING DESIGN PRACTICES Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 73 of 79 Date December, 1999 FIGURE 3A VAPOR PRESSURE OF HYDROCARBONS 1.0 1200 1100 2.0 1000 0 120 0 110 900 3.0 0 100 800 4.0 900 700 5.0 600 500 500 400 400 20 40 300 50 H2O 60 200 70 80 90 100 150 250 100 50 200 200 300 150 400 500 600 100 700 800 900 1000 1500 50 DP9FF03A EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. Vapor Pressure, psia 30 Temperature, °F 300 t, °F oin P iling l Bo ma r o N 700 600 350 6.0 7.0 8.0 9.0 10 800 DESIGN PRACTICES Section HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION Page IX-F 74 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING FIGURE 3B VAPOR PRESSURE OF HYDROCARBONS (METRIC) 650 10 600 650 600 500 20 500 30 400 400 40 300 200 150 Temperature, °C 200 60 70 80 90 100 150 200 150 300 100 400 500 600 50 100 10 1000 1500 2000 50 3000 4000 5000 6000 10,000 10 DP9FF03B EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. Vapor Pressure, kPa 300 °C nt, Poi g ilin l Bo ma r o N 50 DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F PROPRIETARY INFORMATION - For Authorized Company Use Only 75 of 79 Date December, 1999 FIGURE 4 AVERAGE VAPOR QUANTITY IN CONDENSERS (OR REBOILERS) 0.7 0.6 Wv = (Vapor not condensed) + Fv (Vapor condensed) Wv = Fv (Liquid vaporized) + (Initial vapor if any) (Condensing) (Vaporizing) 0.5 Fv 0.4 0.3 0.2 0.1 DP9FF04 0.2 0.3 0.5 0.8 1 2 Ratio of 3 5 Inlet ∆ T T1 − t 2 * = Outlet ∆ T T2 − t1 8 10 20 30 50 80 * Or Corresponding Zone Temperature EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. DESIGN PRACTICES Section CALCULATION PROCEDURE, CONDENSATION Page IX-F HEAT EXCHANGE EQUIPMENT 76 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING FIGURE 5 SHELL-SIDE HEAT TRANSFER FOR PARTIAL CONDENSATION OF WIDE CUTS (NOT RECOMMENDED FOR DEFINITIVE DESIGNS) In(hoc) = 0.82 In(G) + f(α ) - 0.002 Pi, or In(hoc) = 0.82 In(G) + f(α ) - 0.0029 Pi + 0.436 (Metric) 4.0 3.5 f(α ) 3.0 2.5 2.0 0.0 DP9FF05 0.1 0.2 0.3 0.4 α = 0.5 0.6 0.7 lb/hr (or kg/s) vapor out lb/hr (or kg/s) vapor in EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. 0.8 0.9 1.0 DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F 77 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 FIGURE 6A FLASH CURVE CORRECTIONS 60 0 20 40 40 0 200 30 20 D3, °F D2, °F 300 0 60 150 100 °F 50 50 0 250 10 0 -10 t 10 00 =7 1 +D -20 50 -30 -40 0 50 100 150 200 0 250 300 50 100 150 200 250 300 D1, °F D1, °F DP9FF06A FIGURE 6B FLASH CURVE CORRECTIONS 140 30 120 1 +D 20 = 150 °C 95 0 20 t 10 0 26 100 10 0 32 D3, °C D2, °C 80 0 0 37 60 -10 40 -20 20 0 DP9FF06B 20 40 60 80 100 120 140 160 180 D1, °C 0 20 40 60 80 D1, °C EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. 100 120 140 DESIGN PRACTICES Section CALCULATION PROCEDURE, CONDENSATION Page IX-F HEAT EXCHANGE EQUIPMENT 78 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 EXXON ENGINEERING FIGURE 7A ENTHALPY OF WATER ABOVE 32°F 1600 0-1 Atm. 1400 Enthalpy (Btu/lb) Sat. Vapor 1200 1000 Critical Point 800 600 Sat. Liquid 400 200 0 100 200 300 400 500 600 700 800 900 1000 Temperature, F DP9FF07A FIGURE 7B ENTHALPY OF WATER ABOVE 0°C 0-1 Atm. Sat. Vapor Enthalpy (kJ/kg) 3000 Critical Point 2000 Sat. Liquid 1000 0 DP9FF07B 100 200 300 400 500 Temperature, C EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. 600 DESIGN PRACTICES HEAT EXCHANGE EQUIPMENT CALCULATION PROCEDURE, CONDENSATION EXXON ENGINEERING Section Page IX-F 79 of 79 Date PROPRIETARY INFORMATION - For Authorized Company Use Only December, 1999 FIGURE 8 HEAT TRANSFER COEFFICIENT FOR FLUIDS IN TUBES 107 5 106 5 yth hio = 0 .012 5 10 12 L/di or 1000 L/di = 5 25 35 60 120 180 350 600 µ y th k Pr 1 / 3 di µw or µ y hio = th k Pr 1 / 3 di µw 0 .14 0.14 (Metric) 104 102 DP9FF08 5 103 5 104 Reynolds Number, Re = 5 105 d iG 29 µ or 5 d iG 10 3 µ 106 (Metric) EXXON RESEARCH AND ENGINEERING COMPANY - FLORHAM PARK, N.J. 5 107
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