CANDIDATE – PLEASE NOTE! PRINT your name on the line below and return TEST CODEЕ this booklet with your answer sheet. Failure to FORM ТР 2020055 do so may result in disqualification. CARIВВЕАN EXAMINATIONS 01212010 MAY/JUNE 2020 COUNCIL CARIBBEAN SECONDARY EDUCATION CERTIFICATE® EXAMINATION CHEMISTRY Paper 01 - General Proficiency 1 hour 15 minutes 75 05 JUNE 2020 (p.m.) READ THE FOLLOWING INSTRUCTIONS CAREFULLY. 1. This test consists of 60 items. You will have 1 hour and 15 minutes to answer them. 2. In addition to this test booklet, you should have an answer sheet. 3. answers lettered (A), Each item in this test has four are about to answer and decide which choice is best. 4. On your answer sheet, find the number which corresponds to your item and shade the space having the same letter as the answer you have chosen. Look at the sample item below. suggested (B), (C), (D). Read each item you Sample Item A005 The SI unit of length is the (A) metre (B) (C) (D) kilogram Sample Answer B (C) D second newton The best answer to this item is "metre", so (A) has been shaded. 5. 6. If you want to change your answer, erase it completely before you fill in your new choice. When you are told to begin, turn the page and work as quickly and as carefully as you can. If you cannot answer an item, go on to the next one. You may return to that item later. 7. You may do any rough work in this booklet. 8. Figures are not necessarily drawn to scale. 9. You may use a silent, non-programmable calculator to answer items. DO NOT TURN THIS PAGE UNTIL YOU ARE TOLD TO DO SO. Copyright © 2018 Caribbean Examinations Council All rights reserved. 01212010/MJ/CSEC 2020 -2- 1. Which of the following processes provide evidence of the particulate nature of Items 4-6 refer to the information in the following table. matter? I. Diffusion II. Filtration III. Osmosis (A) (B) (C) (D) Number Number Number of of of Protons Electrons Neutrons Q 8 8 8 R 16 16 16 S 8 8 9 T 16 18 16 Element I and II only I and III only II and III only I, II and III 4. Which of the following elements is an anion? 2. 'Mass number' is the number of (A) (B) (C) (D) (A) (B) (C) (D) neutrons plus protons neutrons minus protons electrons plus neutrons The arrangement of electrons in atoms of S T (A) (B) (C) (D) Y? X Y Non-metal Non-metal (B) Non-metal Metal (C) Metal Non-metal (D) Metal Metal Which of the following pairs of elements are X and Y are 2, 8, 5 and 2, 8, 6 respectively. Which of the following represents X and (A) R electrons plus protons 5. 3. Q 6. (A) (D) Q and S S and T oxygen chlorine nitrogen sulfur Which of the following acids will NOT form an acid salt? (A) (B) (C) (D) 01212010/MJ/CSEC 2020 Q and R R and T Element Q is (B) (C) 7. isotopes? HPO H₂CO HSO CH CO₂H GO ON TO THE NEXT PAGE -3- 8. An ion with a single negative charge may Item 12 refers to the information in the be converted into a neutral atom by (A) (B) (C) losing a neutron gaining a proton losing an electron gaining an electron (D) 9. Atomic Number I 3 II 6 III 17 IV 18 12. Which TWO elements above, when combined with each other, form an ionic (A) (B) 2 dm³ of 0.5 mol dm 3 HCI compound? 2 dm³ of 0.5 mol dm³ H SO (C) (D) 1 dm³ of 1.0 mol dm ³ H,SO 1 dm³ of 1.0 mol dm³ CH,COOH (A) I and II (B) I and III (C) (D) III and IV II and IV A separating funnel can be used to separate a mixture of (A) (B) water and ethanol (C) water and solid sodium chloride Item 13 refers to Compound X, which melts at 18 °C and boils at 55 °С. water and kerosene (D) 11. Element Which of the following aqueous solutions contains 1 mole of hydrogen ions? 10. following table. 13. kerosene and solid sodium chloride Compound X is MOST likely (A) (B) element, R, shows chemical properties similar to the element sodium. What is the correct formula of a compound A new liquid metal a giant molecule a (C) a (D) an ionic compound simple molecule formed with R and sulfur? 14. (A) (B) (C) (D) RS, Which of the following statements BEST describes the formation of a metallic bond? R,S (A) Anions are held together by electrons. (B) Metal atoms are held together by anions. (C) Metal ions are held together by a (D) Cations are held together by a sea RS R₂S sea of anions. of mobile electrons. GO ON TO THE NEXT PAGE 01212010/MJ/CSEC 2020 -4- 15. Covalent between compounds can be formed 19. In which of the following compounds does hydrogen have a negative oxidation number? (A) a (B) (C) two identical non-metal atoms, (D) metal and a non-metal a positive ion and a negative ion (A) (B) excluding the noble gases (C) (D) two identical non-metal atoms. including the noble gases 16. Graphite can be used as a lubricant because 20. of the (A) 17. loose electrons which can move NaH Which of the following when added to sulfuric acid would be the LEAST suitable (A) throughout the lattice weak attraction among the hexago- (C) strong attraction among the hexagonal layers of carbon atoms (B) (C) (D) nal layers of carbon atoms strong attraction within the hexagonal layers of carbon atoms 21. Which set of elements forms molecules Period 2 (D) Group 2 Copper(II) oxide Copper(II) chloride Copper(II) carbonate Copper(II) hydroxide The pH of fresh sugar cane juice, which is usually 5.0-5.5, can be changed to 7.5-8.0 for more efficient processing by adding (A) (B) (C) which contain two atoms? (A) (B) (C) (D) H,02 NH method for preparing copper(II) sulfate? (B) (D) CH acetic (ethanoic) acid, CH,CO,H sodium chloride, NaCl slaked lime, Ca(OH)2 limestone, CaCO Group 7 Period 3 22. Which of the substances, represented by the options, A, B, C and D in the following 18. Which ofthe following halogens is a liquid table, is MOST likely sodium chloride? at room temperature? (A) (B) Bromine (C) (D) Chlorine Substance 01212010/MJ/CSEC 2020 Point (°C) Fluorine Iodine Boiling Electrical Conductivity Solid Aqueous State State (A) 1465 No Yes (B) 444 No No (C) 2600 Yes No (D) -35 No Yes GO ON TO THE NEXT PAGE -5- Items 27-28 refer to the following table Items 23-24 refer to the following equation. showing various tests for gases. NO,(g) + SO2(g) → NO(g) + SO3(g) 23. Test Which of the following compounds is reduced? (A) NO (B) (C) NO SO, SO (D) (A) litmus turns red (B) Glowing splint Splint relights (C) Damp red oxidizing agent? (D) 25. (D) Splint extinguishes with a pop NO2 SO2 In answering Items 27-28, each option may be used once, more than once or not at all. 27. Nitric acid Ethanoic acid Which testcan be used to identify ammonia gas? 28. Which test can be used to identify an acidic gas? Sulfuric acid Hydrochloric acid 29. 26. Lit splint NO Which of the following acids is weakly ionized in aqueous solutions? (A) (B) (C) (D) OS (C) Damp red litmus turns blue Which of the following compounds is the (A) (B) Damp blue Damp blue litmus paper litmus paper 24. Observation Which of the statements below is true for the following equation? Which of the following occurs in a metal atom when it becomes an ion? (A) Gains electrons and is oxidized. Mg(s) +HSO (aq) → MgSO (aq) +H, (g) (B) Gains electrons and is reduced. (C) Loses electrons and is oxidized. (A) Mg is oxidized from oxidation state (D) (B) Mg is reduced from oxidation state Loses electrons and is reduced. 0 to +2. +2 to 0. (C) Hydrogen is reduced from oxidation state +2 to 0. (D) Hydrogen is oxidized from oxidation state 0 to +1. 30. On adding aqueous hydrochloric acid to a solution in a test tube, a gas is given off which extinguishes a burning splint. This shows the presence of (A) (B) (C) nitrate ions (D) carbonate ions sodium ions ammonium ions GO ON TO THE NEXT PAGE 01212010/MJ/CSEC 2020 -6- 31. Which of the following will NOT conduct 36. electricity? (A) (B) (C) (D) Which of the following gases will give a positive test with dry cobalt chloride paper? (A) (B) (C) (D) Solid calcium Solid calcium chloride Molten calcium chloride A solution of calcium chloride in 0, H CO, HO water Items 37-38 refer to the 32. An atom with atomic structureX contains (A) (B) (C) (D) following chart showing the conversion of ethene to different products. 13 protons, 14 neutrons 13 protons, 27 neutrons POLYETHENE I 14 protons, 13 neutrons HO conc. 27 protons, 13 neutrons H SO ETHENE 33. Which of the following is a list of ALL the raw materials used in the extraction of iron? (A) (B) (C) (D) 34. Br, Air, iron ore and limestone Air, coke, cryolite and limestone Air, coke, iron ore and limestone Coke, iron ore, bauxite and limestone Π 37. Which of the following metals will NOT displace hydrogen from dilute hydrochloric acid? (A) Zinc (B) (C) Iron (D) 35. Copper Aluminium How many coulombs (C) of electricity 38. The product, polyethene, is a (A) (B) (C) liquid (D) solution gas solid Product I is (A) ethane (B) (C) ethanol (D) ethanoic acid ethyl ethanoate passes through an electrolyte when a current of 100 A flows for 10 minutes? (A) (B) (C) (D) 100 600 10 000 60 000 GO ON TO THE NEXT PAGE -7- 39. Which of the following diagrams BEST illustrates bonding in hydrogen Items 41-42 refer to the bromide? W, X, Y and Z, with water or steam. The table also shows the products formed when XX the nitrates of each metal are heated. X (A) following table which shows the reaction of four metals, Metals Reaction with Water/Steam Products Formed When Nitrate is Heated XX XXX (B) W No reaction Metal, NO₂ and O₂ X Reacts with Oxide, NO, and O₂ steam but not with cold water Y Reacts rapidly Nitrite and oxygen Reacts slowly Oxide, NO, and O with cold water X Z (C) with cold water 41. soluble hydroxide? XX (A) (B) (C) (D) X (D) 42. 40. A solution, when treated with the gas sulfur dioxide, becomes green. contains potassium (A) (B) (C) (D) nitrate sulfate manganate(VII) dichromate(VI) Which of the metals is LIKELY to form a The solution W X Y Z In which of the following pairs of metals is the first metal MOST likely to displace the second metal from solution? (A) (B) (C) (D) X, Y Z, X W, X Z, Y GO ON TO THE NEXT PAGE 01212010/MJ/CSEC 2020 -8- 43. Which ofthe following molecules could be obtained by cracking the alkane, C¿H18? 1. CH II. CH14 II. I only (C) II and III only (D) 44. H-C-C gas = I and II only 45. H C-C -H+ Br, → X H What is the correct structural formula of X? I, II and III (A) which is different from the other H H C C Br Br H H H H H H C C C C H Br H Br H H H H H- C C C - C - H H- processes? (A) (B) (C) (D) H H Which of the following processes produces a H H C16H34 (A) (B) Item 45 refers to the following equation. Respiration in animals Photosynthesis in plants Heating calcium carbonate (B) Oxidation of carbon monoxide (C) H H - - - C H _ C -H _ H 1 (D) 46. Br H H Br H H H H H- C C C C H Br Br H - H Which ofthe following compounds contains a saturated hydrocarbon? (A) (B) (C) (D) Natural gas Propene Ethanol Vinegar GO ON TO THE NEXT PAGE 01212010/MJ/CSEC 202 -9- 47. How many isomers of butane, there? (A) (B) (C) (D) C,H1, are 52. 1 (A) 2 (B) 3 (C) (D) 4 Item 48 refer to the following equation. 53. (C) (D) Copper Calcium Magnesium A suitable drying agent for the laboratory (A) (B) The forward reaction is known as (A) (B) Iron preparation of ammonia gas is Organic Acid + AlcoholEster + Water. 48. Which of the following substances is an important constituent of chlorophyll? (C) synthesis (D) hydrolysis calcium oxide calcium chloride anhydrous copper sulfate concentrated sulfuric acid esterification polymerization Item 54 refers to the following compound. CH Items 49-50 refer to the following metals. (A) (B) (C) Al (D) Na HC Fe 54. not at all. 50. 51. СНОН strongly alkaline solution? Which metal has an alloy which is used in the manufacture of aircraft? Which of the following substances is soluble in water? CH,OH Which of the following phrases correctly describes the compound shown? (A) An alkane (B) An alcohol (D) Non-reactive with sodium (C) Which metal reacts vigorously with water (A) (B) (C) (D) - CH may be selected more than once, once or to produce a C CH, Cu In answering Items 49-50, a particularmetal 49. - 55. A branch alkane Which of the following observations is expected when aqueous silver nitrate is added to aqueous potassium chloride? (A) (B) (C) (D) Apungent gas is evolved. A blue precipitate appears. A white precipitate appears. A brown precipitate appears. C,H CH CH,COOC H GO ON TO THE NEXT PAGE 01212010/MJ/CSEC 2020 -10- 56. A polyamide is formed by a condensation reaction between a molecule containing (A) at least one -COOH group with another containing at least one -NH, group (B) at least one -OH group with another containing at least one -COOH group (C) (D) 57. at least one -OH group with another containing at least one -NH, group two -OH groups with another containing two -COOH groups Which of the following features is NOT true of all homologous series of compounds? The members of the series have (A) (B) (C) (D) 58. similar chemical properties the same empirical formula Which of the following substances can be produced DIRECTLY from ethanol? I. Ethene II. Ethane I. Ethyl ethanoate (A) I and II only (B) (C) (D) 59. the same functional group the same general formula I and III only II and III only I. II and III Which of the following statements is TRUE? (A) (B) (C) (D) a gas are larger when heated. in a The particles in The particles in a gas are further apart when heated. The particles in a gas are very closely packed together. The particles in a gas have strong forces between them. GO ON TO THE NEXT PAGE 01212010/MJ/CSEC 2020 -11- Item 60 refers to the following graph which shows the boiling points of some straight-chain alcohols. Boiling points (°С) 250 200 150 100 50 1 2 3 4 5 6 7 8 9 Number of carbon atoms in chain 60. Which of the following molecular formulae represents the alcohol whose boiling point is 160 °C? (A) (B) (C) (D) CH(CH)OH CH(CH OH CH,(CH)OH CH(CHOH END OF TEST IF YOU FINISH BEFORE TIME IS CALLED, CHECK YOUR WORK ON THIS TEST. 01212010/MJ/CSEC 2020
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