Page Ho
Date:
Chaptu -88
tquli bia.
Ryeu si bl yeactioh: d tuachon in which DUbd
can lae ehanged blk to
Buactani by
Conditg
ing the
Enanplesi
Cusoy 5H,0
FesOy dn,0
FesOy t 4t,0
Pall qieen salt
Fesoy
ddislw
pungent
mell
'ChaactultiA tquilibai ua
alynauic.
Th fowaud and Hevee veaciony occUL al e
p The.Onanaatiohu,
Aaln contant ar
at
uackana and ppdLu
eauli biun:
T
Page No.:
YOUVA
Date:
Jt vequa a dosed syskuu
Pxd sstem : a nutu in wolch matu is not
in
cesedy08.
eauttite
(onuntahe
A Coneentuahen
at equlilaium
peduct
B= Tim takut tet pwcteti
actong
to seach equibuum:
he ChatelieDs Prinipl
e (haelieaá
equil bilw
uputon
is Chanqd , the
equllibiune noves
to wininmix thi chehqe
noati
due
to onch
ekued
added
thid
aL
ethanst
inMOUes
and
and
added
ova aci
aid ahole'
ths c00C
Te
eth Mee
cHa
MOe
cHcoon
4)
C,H_
t
produy
cantaaHow
(oncenaahon
Duuasx
|nuuax
CHANGE
SHIFT
OF
ConDCaN
Snuuase
Conuntai
on
heatant
Conuntation
BRIUM EQUILI
Concentaation
tqutibiunu
aljecting
A
tfute
autors
-
Date:
No. Page
T
T
F
Page No.:
YOUVA
Date:
* Some Gte0H
OH is emovLd
Tue þesition
cQuilibi w
ele Chane
and
Aoue
ethaneic
t and
eHhyl ehanatiand wathu
3t
34
1Ihat habpens swhen-.
*0atu i added to the eqili nintue
wateu
CHANGE
SHIFT OF EQUILIBRIUM
jn the dçectio
that
uduces sna
walees
in taealuecti
Deae in pessue
that
Page No
Dato
the
inmax
NgOycq)
Y9UVA
chang
t a thuu au
Tu eQuili bius will sjt to
Inprúu
Cal,
thu au
The equlibxium wil shyt to
wellulu CacoÀThis
ausu a
duuan in prsusM
m presu
) Dcuua
pepiLditk the hang
Tu eqilibium ghitt to Riqht as theL Qe
an induan in pruu
CHANGE
Jnuuae jn
Tenpuatw
DeuLan n
Tumpuatu
SMIFT OF EQUIUBRIUM
MDveo n te enAothele
uecio
to evl
th
duecton to
Uhang
M
S
T
Page No.:
YOUVA
Date:
) PaLdict he eget o inuan n unpate
beaus the
tswcud ttationi endothnic
tenmbuahue, inuuasu Hhe anount e
Unstant yanese.
Co
at
endoHheic
Sine
shi tng towauds thu Piqht and the seaction 8
endoHheinic
Cataysr: 4 catost
s e Mustan L that inuea
Hht Aalt Aeactiou by suasing he
acHvaion eheLqy and Hemains nchanqed
A CATALST DOES-NOT tFFEET-t UtKtBRUMt
Page No.
Date:
K, e Kp tquilibuwn Constant
[Produch ]
CReactara]
HaT
K¢
Note!
Soluds and hiquids that abþeas in balan cd cQ Llir
NOT INCLUDED. 0n Hhe equi libtium upiLMAIA
[NH
[N,J[H,I*
2f
AqTcag) t+ ecaq)
wutfamnotain)
Ags
A
M
W
T
F
S
Page No.:
YOUVA
Date:
[so
Bo' [o]
UN ITS.
KlMoe Haction_ and PauHaL PresAL
Pauia
Reuedt
a
Ryotat
Hole hacion: d
the totol no
in thu winte.
Mot 4attion
M
Page No.:
Date:
9:44
o.53
Inital cnC: Hg)
|0-00 wtl lduu?
[o537CO:587
319:26
A 319: 3
Equil laiuku tuptnsion ea Pauhal Arusue
(kp)
Ppoduca
p
W
T
F
S
S
Page lo.:
YOUVA
Date:
2NH, c9)q
() Ncq + 3H,co
NTS
kp
Pex Pa
PxPxPax Pa
N
2N0,
PNOS
Pa xxPa
Poy
(a) 2s0,
kp
Pax Po
Pexxpax Pa
2
Pa
as olow
1:0 X10 "pa
4-0Xi0Pa
&0X10'6 Pa
Page No.:
YOUVA
Date:
Calulatt he vau
Kp and wnit.
o
-GNTS
P
Po
o
Pax Pa
Pa
Es-oxo
-6
q-14 X0 P a
and HD cq
Jhe tquili btiwe bctwn Hy c9
dt conatat tempualue t
equi lbai um
meles
aue
-> -65 xID
pLesu- 00 KPa
Tot al
-2
mot
x\0
-02112 nue
+65 X[0
M
T
W
F
Page No.:
YOUVA
Date:
H
-084
Pa
00gt KPa
002|2
|65X 10
HI
O 138
PoA
X L0U
0-+8
t
Pa
0- D2U2
PH
Pa, Xfi
Q:5454 KPa
NO unia
gcd - Base tquilibiuh
Aid
Proton
DoneL
Bas
> Prottn dccepte
2HCI
t
Cao
+Dissoiation Cdád)
NO,
24
H
X10
138 KpPa
84KPa
Page No
Data
CHa, co0
CH, c00 H
HT
Bax
Na
NabH
Ko
KOH
t otH
+ OH
NH, + H,0
NH;0H
NH;on
ANHy t OH
Bronathd Thty
Bronaud- howlly aid: d potbn CHt ion) dana
aceptor
dcid
Bas
H,0 + NH,
doid
Bax
NHybH
d
Phenolpthaliw
Cotoue
Violet Pink]
(q-3) (8-2-10-0)
Bue
Melow
Bronuohy
nsl
0)(4(6-o-4-6)
Bromophenot
4euDw
6) (2-8-
"'eanqe
Red
Acid
Bac
(3-2-4
4)
(3-+)
Dyc
Name
e
hangeA
oUeLa colou
is itwhich ohin
dlpenddnqon
solUti
he
dcidba
indicator
d :
has thatcomþound
two
andicators
Aid
HCLOyt
+ os CHco0H
CHyc00H
Date:
YOUVA
No. Page
S
F
did E tquilibrium positio
Saong aid
Page No
Dato
weak ccid
tquitibiun
Patiat t )
Dissoiahn
fH
tanuntatton
tigh
Bax e tquilibùwm bei tict.
Staong bau
weak ba
Grp- mutol
hydouidu
NH, Aminld
TraiHon mltal
Peition e
tquilibiunw
Dissouadhow
OH tontntiatiow
tnemye
hydonidu
Page hn
Y0UVA
Date:
Stong
acids witHh shong bax CNabH yk HU)
bUnomthyrnt
vettrcttttton
totememehtyol
bwe i yuiow
2'0
ilope
6-0
4-6 to 6-0
4:6
a nange
yelbw QUO
whe the
Atepeut
t Phendphhalieu hangu colotu in pH oau &2 to
Saong add with weak oek CHNO, ys NHy)
Sndiate -- Nethyl tangt
unqu colatu- pH 4d and
Phentlphthalein s not
sui table to usc as it ony
20
Vel o HNO, added to NG l vit
changain alkalintAqions
Page Ho
Date
Weak acçds wiHh stong bases LNAoH Vs CzHsa
Gehic
I2
20
WLaK acidh
wihh
eak bat
suitable
-No acid-bass Indicatsd
EndomuacHon
tneumic
Tenpuatu tnoo
Change 2H*g
EnohermIacion
tt cgt cg
Pesiton e tquiubi umPosiHon
Tumpuatue thi fu to produca
dnuuaw
mou H d otnud
2502 9)
Eqùù bicun
shifti o Heactana
tmed
lpoition e tyuilibrium Pesitton 4 toui tii briun
Tnpuauu
Deuas
hifta to
eactant
&hitti to pro dutt
mou so tomed
enangt
Preste
Mau moees
N, cg> t 3H, cqT
N,Oycq
2NHgcg
2NO, cq)
Hon
tauiibriun pesitontquili bium pesi tion
Presute
Jnuan
Pres
Fewu musees e
ifs towauds product
hfts to waiA
eatanË
tyuùbtian posi How eaurtíbtl um Ps)Hon
prout
Deuean tactant
|N, and H, toLs