Materials Today: Proceedings xxx (xxxx) xxx Contents lists available at ScienceDirect Materials Today: Proceedings journal homepage: www.elsevier.com/locate/matpr Battery thermal management system for the cooling of Li-Ion batteries, used in electric vehicles Saurav Sikarwar a, Rajesh Kumar a,⇑, Ashok Yadav a, Manoj Gwalwanshi b a b Dayalbagh Educational Institute, India Graphic Era University, India a r t i c l e i n f o Article history: Available online xxxx Keywords: Lithium-Ion battery Battery thermal management system Cooling methods a b s t r a c t Conventional technology has avital role in increased greenhouse gas emission, which is harmful for the environment. A major part of rising emission is emitted by traditional vehicle technologies. The use of carbon-based fuels plays a major roll in rising pollution levels. The amount of pollution can be reduced nearly sixty percent. Globally by avoiding fossil fuel. Vehicles are gaining popularity. Now day Electric vehicles (EVs) have nearly negligible tail emissions, which contributes significantly to reduce pollution levels. Lithium-ion (Li-Ion) batteries in EVs, performance well within a small temperature range. There for management of temperature of Li-Ion battery pack is important for battery pack & cell life BTMS is used for effective temperature management. The Battery Thermal Management System (BTMS) is the component in charge of controlling and dissipating the heat produced by the electrochemical reactions taking place in the cells, enabling the battery to function safely and effectively. Air-based, liquid-based, and phase change material (PCM)-based are the three most frequent mediums utilized in BTMSs. Future work will focus on liquid-cooled BTMSs, PCM based & hybrid type BTMSs. The lithium-ion battery pack gives better performance in the temperature limits of 15 °C to 35 °C. This review paper talks about how thermal management systems (BTMSs) can be used with different methods and materials to keep the temperature within the desirable range (15 °C to 35 °C). Ó 2023 Elsevier Ltd. All rights reserved. Selection and peer-review under responsibility of the scientific committee of the Recent Advances in Materials, Manufacturing and Thermal Engineering. 1. Introduction Greenhouse gas emission thrown out by conventional internal combustion engine-based vehicles is one of the primary cause of environment pollution. Many researchers are trying to figure out the causes of rise in greenhouse gases emissions. The fossil fuels used by power plants, industry and factories, household activities, and the automobile emits a lot of pollution, Therefore the conventional technology used in the automobile sector is the biggest reason for greenhouse emissions [1]. In this regard, it is a must to find another green alternative for transportation purposes [2,3]. Conventional technology uses a great deal of fossil fuel, which increases the greenhouse effects and also causes a drastic change in the climate [4]. At that time, a higher percentage of greenhouse ⇑ Corresponding author at: Mechanical Department, Faculty of Engineering, Dayalbagh Educational Institute, Agra, U.P. E-mail addresses: sauravsikarwar019@gmail.com (S. Sikarwar), kumarrajesh. iitr@gmail.com (R. Kumar). emissions were due to fossil fuels, which increased greenhouse emissions at a very alarming rate. Furthermore, all over the world, governments are switching to another alternative to conventional technology, which is electricity [1]. That is why the electric vehicle is more popular everywhere and decreases greenhouse pollution effects as well as the demand for fossil fuel. In this paper, the author focused only on replacing conventional technology with electric-driven vehicles. In this way, almost every country suggested the electric vehicle, but each one had different benefits and rules for both consumers and carmakers. As a result, pollution levels in the EV industries are decreasing and rapidly increasing [5,6]. Although there are a lot of advantages to using an electric vehicle, there are still a few problems with it, such as range anxiety because there are very few charging substations while a gasoline pump is more than enough, and another one is the battery. According to a literature review, almost all electric vehicles use lithiumion batteries because they are better for electric vehicles. [7] According to the literature review, it is therefore necessary to understand why lithium-ion batteries lose capacity and perfor- https://doi.org/10.1016/j.matpr.2023.02.293 2214-7853/Ó 2023 Elsevier Ltd. All rights reserved. Selection and peer-review under responsibility of the scientific committee of the Recent Advances in Materials, Manufacturing and Thermal Engineering. Please cite this article as: S. Sikarwar, R. Kumar, A. Yadav et al., Battery thermal management system for the cooling of Li-Ion batteries, used in electric vehicles, Materials Today: Proceedings, https://doi.org/10.1016/j.matpr.2023.02.293 S. Sikarwar, R. Kumar, A. Yadav et al. Materials Today: Proceedings xxx (xxxx) xxx above mentioned two cooling methods is how they are using aircooled BTMS, these are now classified by the type of coolant used, whereas air-based BTMS uses air as the coolant. The battery module of EVs uses direct air from the environment; that air moved over the battery pack after cooling; this air then released into the environment [20]. Maintenance of air based BTMS is easy also, there are two types of air-cooled BTMS. mance. In the case of a lithium-ion battery, the operating temperature and uniformity of temperature in the whole battery pack are most important; otherwise, the battery pack degrades and shortens the life of the battery [8,9]. Therefore, to achieve the controlled temperature and uniformity of temperature in the whole battery pack, thermal management is must otherwise, it would not perform well [10]. Variation in temperature directly affects the lithium-ion battery’s performance and its life time, if it is not managed within the limit. Hence the lithium-ion battery is very sensitive to temperature. The EV manufacturers are also more concern about the battery thermal management. The battery’s thermal management system controls the temperature within a limited range [11,12]. During the high rate of discharge and charge (C-rate), the lithium-ion battery generates more heat. According to the literature review, the optimum temperature is range is defined from 15 °C to 35 °C as shown in Fig. 1. If the temperature is lower than 15 °C, the electrolyte reaction slow, which can lowers the capacity and performance of the battery during charging and discharging. Similarly, when the temperature inside the battery exceeds 35 °C during charging and discharging, the capacity and performance of the battery start reducing which leads to increased possibilities of thermal runaway [1]. To achieve this narrow limit of temperature, numerous techniques have been investigated, for battery thermal management system (BTMS). The techniques used are air, phase change material (PCM), or liquid heat pipe based [10]. 2.1.1. Natural convection air based BTMS In natural convection, the dissipation of heat depends on the external airflow, the externally facing forward drive of the EV to the lithium-ion battery pack. As a result, heat generated by the battery pack is released into the environment via an external flow of air. Various studies define that good performance of cooling the battery pack depends on two factors: the first layout of batteries, and second is geometry of airflow through the battery pack [21]. As shown in Fig. 2, when the EV moves forward the air flows naturally in backward direction. The natural cooling of the battery pack is caused by the airflow over it naturally without any external force. The natural convection does not require electronic and electrical devices to force air to flow [22]. 2.1.2. Forced convection air based BTMS In forced convection, an additional fan is used for forced airflow to cool the battery pack because natural convection is not enough for the heavy battery pack of EVs. Forced airflow over the battery pack gives more efficient cooling in comparison to natural convection cooling [12]. Fig. 3 shows that pre-cooled air is supplies from the air conditioning system [23]. Wang et al. suggested that the ambient temperature of air below 20 °C is not necessary for forced convection cooling [25]. 2. Types of BTMS It is required to maintain the optimal temperature of the lithium-ion battery pack in the EVs, which can be achieved using battery thermal management system (BTMS). It serves the following purposes: removing the heat from the battery pack if the temperature is low, maintaining the temperature with the help of BTMS, also ventilation for gases [14]. BTMSs must be as small as possible, light, need less building, be more reliable, need less and easy maintenance, Several BTMS have been suggested in the literature for keeping the battery configuration and temperature within a narrow range [17]. Manly three types of BTMSs can be used. 2.2. Phase change material based BTMS The phase change material (PCM) is used in the phase change material-based BTMS for the storage of latent heat. It is one of the simplest methods of storing thermal energy and also has a high energy density for isothermal storage. PCMs have been widely used in the thermal management of systems for heat pumps, solar engineering, and electric vehicles. For higher temperature limits of Liion battery pack the PCM melts and solidifies as shown in figure number 4 [26]. When a material changes phases from solid to liquid or liquid to solid, it transfers fundamental thermal energy from one form to another, resulting in PCM behaviors similar to traditional storage materials. When the temperature rises, PCM absorbs heat, and vice versa when the temperature is nearly constant. It was found in previous studies that PCM can store about 5–14 times more heat per unit volume [27]. The idle PCM has a melting point between 30 °C and 60 °C, which is beneficial for the narrow temperature limit of the lithium-ion battery pack. The lithium-ion battery pack has a lot of modules, and those modules have many cells that are connected in series or parallel according to the energy demand of EVs. For example, a few lines of lithium-ion cells are connected in series, while a few are connected in parallel to each other, like 26S8P, which fulfils the capability and voltage requirement of the battery pack for EVs Application. Fig. 5 shows the lithium-ion battery pack with PCM [29]. 2.1. Air based BTMS The air-based BTMSs used in EVs, is most conventional method. The air is easily and freely available that is why the air-based BTMSs is adopted because due to simple construction and economic [18]. Air-based BTMS is a simple way to remove heat from inside the battery pack, and it is also advantageous due to the smaller space requirement for EVs [19]. Air-based BTMS, two categories: the first is the passive air cooling system, which is based on natural convection process, whereas the second is the active air cooling system, which uses forced convection with the help of a fan and different channels [17]. The main difference between the Fig. 1. Temperature influence the performance Of Lithium-Ion battery [13]. Fig. 2. Natural convection air based [24]. 2 Materials Today: Proceedings xxx (xxxx) xxx S. Sikarwar, R. Kumar, A. Yadav et al. Fig. 3. Forced convection air based [13]. Fig. 6. Direct liquid cooling based BTMS [32]. Fig. 4. Phase change during heating the substance (temperature vs. time) [28]. Fig. 7. Indirect liquid cooling based BTMS [32]. 2.3. Liquid based BTMS pack in liquid or oil has large surface area for heat dissipation [31]. As the air cooling BTMS has two ways to cooling natural and forced. Similarly, there are two ways of cooling with liquid based: direct cooling and indirect cooling based BTMS. [32]. In liquid-based BTMSs any liquid coolants and oils are used as cooling medium. This type of BTMS is more efficient as compared to other systems. It maintains the temperature of the battery pack with in the safe limit more effectively and quickly. Lithium-ion battery pack doesn’t come into direct contact with the coolant because it has blocks, pipes, and channels [30]. Many researchers concluded that a good air flow rate can remove heat from the battery pack in electric vehicles with air-cooled BTMS when fast generates more heat [33,35]. But air has a very low thermal conductivity than that for liquid fluids. It is very difficult to prevent the thermal runaway in the battery pack using air based BTMS. In that case, use of liquid coolants can be another alternative of air based BTMS. The liquid coolants are supplied through liquid jackets, tubes, and different pattern cold plates to construct a liquid based BTMS. Also various geometrical arrangements for batteries are being tested by researchers. The directly submerged battery 2.3.1. Direct liquid cooling based BTMS Fig. 6 shows that the whole battery pack is submerged in the liquid fluid or oil tank. A circulating pump moves the coolant through the heat exchanger to return the battery pack to its original state [32]. 2.3.2. Indirect liquid cooling based BTMS. In indirect liquid cooling-based BTMS, the coolant does not come in direct contact with the battery pack. As shown in Fig. 7, a tube, channels, and cold plates are used between the coolant fluid and the battery pack. This can be concluded that PCM and liquid based BTMSs are more effective for higher temperature range. Fig. 5. Lithium-Ion battery pack with PCM [29]. 3 S. Sikarwar, R. Kumar, A. Yadav et al. Materials Today: Proceedings xxx (xxxx) xxx Fig. 8. Materials used as coolant in BTMS. Table 1 Summary of BTMS. S. No. Ref. Variables Battery Type Coolant Type Cooling Type No. of batteries in pack Charging and/or Discharging Rate Method Findings 1 Hussam et al. [10] Power and energy density Prismatic, lithium-ion battery Air & liquid based Passive and active 3 1C–3C Chemical reactions increased at hotter batteries. The heat raised caused loss the battery capacity and increased self-discharge rate 2 Maosung wu et al. [33] Current, heat and state-of-discharge Cylindrical, lithium-ion battery Liquid based Active 1 2C 3C Temperature management with air, liquid and PCM Liquid cooling 3 Suman basu et al. [34] Paul Nelson et al. [35] Coolant flow-rate and current Cylindrical, lithium-ion battery Liquid based Active 30 0.6 C 0.9 C Area-specific impedances, the lumpedparameter, layer thicknesses Heat generation, different C rate and time Flat-wound cells, lithium-ion battery Air & liquid based Active 48 1C Air and liquid pouch cells, Lithium-ion battery Liquid based Active 1 1C – 5C Liquid cooling 4 5 L.H. Saw et al. [36] Liquid cooling (by simulation) Temperature decreased, when the heat pipe is used with fins, the difference between of maximum and minimum temperature is 20 °C, at the end of discharged, temperature is 65 °C while current does not exceed 10 A Conduction element is worked as a separator, taking the heat through thermal conduction; maximum temperature is within 7 K at high discharged & low coolant flow rate. High power required, air as the heat transfer medium, During the first few year at 10 °C, more battery life, Refrigeration system is more reliable, for not suffer the power loss Liquid cooling is more efficient to removes the heat from the battery pack, Performance of EVs directly affected to temperature 2. To maintain the cell temperature with in the safe limit various cooling techniques have been tested and compared. Battery thermal management system (BTMS) is one of such good technique. The air-based, PCM-based and liquid-based are three commonly types of BTMSs. 3. Air-based BTMSs are adopted due to their simple construction and economic operation as air is freely available. There are two types of air-cooled BTMS: natural convection air-based BMTS and forced convection air-based BMTS. 4. PCMs have been widely used in the thermal management of systems for heat pumps, solar engineering, and electric vehicles. The PCM melts and solidifies and stores heat during its phase change. PCM can store 5–14 times more heat per unit volume. Therefore PCM is also a good option for heat dissipation from battery packs. 5. Liquid-cooled BTMSs are capable of removing the heat from the battery pack using any liquid as coolant. Liquid based BTMS has many benefits such as high heat transfer capabilities. These are more compact for the same heat removal, and the liquid fluid has a better density. 6. Future this study suggests that liquid cooling type BTMSs and hybrid BTMSs (a combination of two types of BTMS) can give best results. Some of the recent studies are also available with the combination of PCM and any of the other cooling technique to form a hybrid system. This can be helpful in combining the advantages of both the systems (see Fig. 8). The comparative summary of some of the studies with various types of BTMSs and their findings in tabular form is given below (see Table 1): 3. Conclusion The above studies find BTMS an effective and essential component to improve the performance and life cycle of battery pack. Mainly three types of BTMSs viz. air based, liquid based and PCM based are used. This study concludes the comparative analysis of all three systems with different materials and combinations of parameters. The following conclusion are made: 1. The lithium-ion battery is most suitable for EVs due to its high energy density, longer cell life and less self-discharging. 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