Q. Matching Match each item with the correct statement below. a. product d. balanced equation b. reactant e. skeleton equation c. chemical equation ____ 1. a chemical equation that does not indicate relative amounts of reactants and products ____ 2. a new substance formed in a chemical reaction ____ 3. a starting substance in a chemical reaction ____ 4. a concise representation of a chemical reaction ____ 5. an equation in which each side has the same number of atoms of each element Match each item with the correct statement below. a. activity series of metals c. combustion reaction b. single-replacement reaction d. decomposition reaction ____ 6. a reaction in which a single compound is broken down into simpler substances ____ 7. a reaction in which oxygen reacts with another substance, often producing heat or light ____ 8. a reaction in which the atoms of one element replace the atoms of a second element in a compound ____ 9. a list of metals in order of decreasing reactivity Match each item with the correct statement below. a. Henry's law d. supersaturated solution b. immiscible e. concentration c. saturated solution ____ 10. describes liquids that are insoluble in one another ____ 11. solution containing maximum amount of solute ____ 12. solution containing more solute than can theoretically dissolve at a given temperature ____ 13. At a given temperature, the solubility of a gas in a liquid is directly proportional to the pressure of the gas above the liquid. ____ 14. measure of the amount of solute dissolved in a specified quantity of solvent Match each item with the correct statement below. a. boiling point elevation d. molarity b. molality e. freezing point depression c. mole fraction ____ 15. number of moles of solute dissolved in 1 L of solution ____ 16. a colligative property related to the fact that ice will form at higher temperatures in the Great Lakes than in the ocean ____ 17. a colligative property related to a decrease in the vapor pressure of a solution ____ 18. number of moles of solute dissolved in 1 kg of solvent ____ 19. ratio of moles of solute in solution to total number of moles of both solvent and solute Multiple Choice Identify the choice that best completes the statement or answers the question. ____ 20. Chemical reactions a. occur only in living organisms. b. create and destroy atoms. c. only occur outside living organisms. d. produce new substances. ____ 21. A net ionic equation a. shows the spectator ions. b. shows only those particles involved in the reaction. c. is not necessarily balanced with respect to mass or charge. d. shows dissolved ionic compounds as dissociated free ions. ____ 22. What does the symbol above the arrow in a chemical equation mean? a. Heat is supplied to the reaction. b. A catalyst is needed in the reaction. c. Electricity is need in the reaction. d. A precipitate will form during the reaction. ____ 23. Chemical equations a. describe chemical reactions. b. show how to write chemical formulas. c. give directions for naming chemical compounds. d. describe only biological changes. ____ 24. A skeleton equation shows just the reactants and products whereas a balanced equation shows the a. approximate amounts of the reactants only. b. approximate amounts of the products only. c. products on the left, the reactants on the right. d. relative amounts of reactants and products. ____ 25. Which of the following combinations of symbol and explanation of symbol is correct when used in a chemical equation? a. (g), grams b. (l), liters c. (aq), dissolved in water d. s, solid product ____ 26. In the chemical equation H O (aq) H O(l) a. catalyst b. solid O (g), the is a ____. c. product d. reactant ____ 27. This symbol ( ) indicates that ____. a. heat must be applied b. an incomplete combustion reaction has occurred c. a gas is formed by the reaction d. the reaction is reversible ____ 28. A catalyst is a. the product of a combustion reaction. b. not used up in a reaction. c. one of the reactants in single-replacement reactions. d. a solid product of a reaction. ____ 29. Which of the following is the correct skeleton equation for the reaction that takes place when solid phosphorus combines with oxygen gas to form diphosphorus pentoxide? a. P(s) O (g) PO (g) b. P(s) O(g) P O (g) c. P(s) O2(g) P O (s) d. P O (s) P (s) O (g) ____ 30. Rewrite the following word equation as a balanced chemical equation. What is the coefficient and symbol for fluorine? nitrogen trifluoride nitrogen fluorine a. 6F b. F c. 6F d. 3F ____ 31. What are the coefficients that will balance the skeleton equation below? AlCl + NaOH Al(OH) NaCl a. 1, 3, 1, 3 b. 3, 1, 3, 1 c. 1, 1, 1, 3 d. 1, 3, 3, 1 ____ 32. What are the coefficients that will balance the skeleton equation below? N +H NH a. 1, 1, 2 b. 1, 3, 3 c. 3, 1, 2 d. 1, 3, 2 ____ 33. When the equation Fe a. 1 b. 2 c. 3 d. 4 Cl FeCl is balanced, what is the coefficient for Cl ? ____ 34. When the following equation is balanced, what is the coefficient for HCl? Mg(s) a. 6 b. 3 c. 1 d. 2 HCl(aq) MgCl (aq) H (g) ____ 35. Which of the following statements is true about what happens in all chemical reactions? a. The ways in which atoms are joined together is not changed. b. New atoms are formed as products. c. The final substances are called reactants. d. Bonds between atoms are broken and new bonds are formed. ____ 36. Chemical equations must be balanced to satisfy a. the law of definite proportions. b. the law of multiple proportions. c. the law of conservation of mass. d. Avogadro’s principle. ____ 37. When the equation KClO (s) a. 1. b. 2. c. 3. d. 4. KCl(s) + O (g) is balanced, the coefficient of KClO3 is ____ 38. In every balanced chemical equation, each side of the equation has the same number of ____. a. atoms of each element b. molecules c. moles d. coefficients ____ 39. What are the missing coefficients for the skeleton equation below? Cr(s) Fe(NO ) (aq) Fe(s) Cr(NO ) (aq) a. 4, 6, 6, 2 b. 2, 3, 2, 3 c. 2, 3, 3, 2 d. 1, 3, 3, 1 ____ 40. What are the missing coefficients for the skeleton equation below? Al (SO ) (aq) KOH(aq) Al(OH) (aq) K SO (aq) a. 1, 3, 2, 3 b. 2, 12, 4, 6 c. 4, 6, 2, 3 d. 1, 6, 2, 3 ____ 41. When potassium hydroxide and barium chloride react, potassium chloride and barium hydroxide are formed. The balanced equation for this reaction is ____. a. KH BaCl KCl BaH b. KOH BaCl KCl BaOH c. 2KOH BaCl 2KCl Ba(OH) d. KOH BaCl KCl BaOH ____ 42. The product of a combination reaction is Ba(OH) . If one of the reactants is H O, what is the other reactant? a. Ba O b. BaO c. BaH d. BaO ____ 43. In order to predict whether or not a single-replacement reaction takes place, you need to consult a chart that shows the a. periodic table. b. activity series of metals. c. common polyatomic ions. d. ionic charges of representative elements. ____ 44. In order for the reaction 2Al 6HCl 2AlCl a. Al must be above Cl on the activity series. b. Al must be above H on the activity series. c. Heat must be supplied for the reaction. d. A precipitate must be formed. 3H to occur, which of the following must be true? ____ 45. In a combustion reaction, one of the reactants is a. hydrogen. b. nitrogen. c. oxygen. d. a metal. ____ 46. The products of a combustion reaction include a. water, carbon dioxide, and carbon monoxide. b. hydrogen, water, and carbon dioxide. c. hydrogen and carbon monoxide. d. hydrogen and water. ____ 47. The type of reaction that takes place when one element reacts with a compound to form a new compound and a different element is a ____. a. combination reaction b. decomposition reaction c. single-replacement reaction d. double-replacement reaction ____ 48. In a double-replacement reaction, the a. products are always molecular. b. reactants are two ionic compounds. c. reactants are two elements. d. products are a new element and a new compound. ____ 49. Which of the following statements is correct? a. All combustion reactions are also combination reactions. b. All chemical reactions can be classified as one of five general types. c. Incomplete combustion of a hydrocarbon may produce carbon monoxide and water. d. A single reactant is the identifying characteristic of a single replacement reaction. ____ 50. Which of the following is a balanced equation representing the decomposition of lead(IV) oxide? a. PbO Pb 2O b. PbO Pb O c. Pb O 2Pb O d. PbO Pb O ____ 51. What are the correct formulas and coefficients for the products of the following double-replacement reaction? RbOH H PO a. Rb(PO ) H O b. RbPO 2H O c. Rb PO 3H O d. H Rb PO OH ____ 52. When the equation for the complete combustion of one mole of C H OH is balanced, the coefficient for oxygen is ____. a. 13 2 b. 11 2 c. 7 2 d. 9 2 ____ 53. Which of the following statements is true about the decomposition of a simple binary compound? a. The products are unpredictable. b. The reactants are the constituent elements. c. The reactant is a single substance. d. The product could be an ionic or a molecular compound. ____ 54. Which of the following statements is true about single-replacement reactions? a. They are restricted to metals. b. They involve a single product. c. Two reactants produce two products. d. Any metal replaces any other metal. ____ 55. In the activity series of metals, which metal(s) will displace hydrogen from an acid? a. only metals above hydrogen b. only metals below hydrogen c. any metal d. only metals from Li to Na ____ 56. Use the activity series of metals to complete a balanced chemical equation for the following single replacement reaction. Ag(s) KNO (aq) a. AgNO K b. AgK NO c. AgKNO d. No reaction takes place because silver is less reactive than potassium. ____ 57. In a double-replacement reaction, one of the products a. b. c. d. may precipitate from solution. will never be a gas. may be a solid nonmetal. may be a solid metal. ____ 58. In a double-replacement reaction, a. the reactants are usually a metal and a nonmetal. b. one of the reactants is often water. c. the reactants are generally two ionic compounds in aqueous solution. d. energy in the form of heat or light is often produced. ____ 59. One of the products when aqueous Na CO reacts with aqueous Sn(NO ) is a. NaNO . b. NaSn. c. Sn(CO ) . d. CNO . ____ 60. The complete combustion of which of the following substances produces carbon dioxide and water? a. C H b. K CO c. CaHCO d. NO ____ 61. Which of the following is the correctly balanced equation for the incomplete combustion of heptene, C H ? a. C H 14O 7CO 7H O b. C H 7O 7CO 7H O c. 2C H 21O 14CO 14H O d. C H O C O 7H ____ 62. The reaction 2Fe 3Cl 2FeCl is an example of which type of reaction? a. combustion reaction b. single-replacement reaction c. combination reaction d. decomposition reaction ____ 63. The equation Mg(s) 2HCl(aq) a. combination reaction b. single-replacement reaction c. decomposition reaction d. double-replacement reaction MgCl (aq) H g is an example of which type of reaction? ____ 64. The equation H PO 3KOH K PO a. double-replacement reaction b. combination reaction c. decomposition reaction d. single-replacement reaction 3H O is an example of which type of reaction? ____ 65. The equation 2C H OH 9O a. combustion reaction b. single-replacement reaction 8H O is an example of which type of reaction? 6CO c. double-replacement reaction d. decomposition reaction ____ 66. A double-replacement reaction takes place when aqueous cobalt(III) chloride reacts with aqueous lithium hydroxide. One of the products of this reaction is a. Co(OH) . b. Co(OH) . c. LiCo . d. LiCl . ____ 67. If a combination reaction takes place between rubidium and bromine, the chemical formula for the product is ____. a. RuBr b. Rb Br c. RbBr d. RbBr ____ 68. What is the balanced chemical equation for the reaction that takes place between bromine and sodium iodide? a. Br NaI NaBr I b. Br 2NaI 2NaBr I c. Br NaI NaBrI d. Br NaI NaBr I ____ 69. What is the driving force in the following reaction? Ni(NO ) (aq) K S(aq) a. A gas is formed. b. A precipitate is formed. c. Ionic compounds are reactants. d. Ionic compounds are products. ____ 70. Which of the following usually makes a substance dissolve faster in a solvent? a. agitating the solution b. increasing the particle size of the solute c. lowering the temperature d. decreasing the number of particles ____ 71. The solubility of potassium chloride is at 20 C. What is the maximum amount of KCl that can dissolve in 200 g of water at 20 C? a. 17 g b. 34 g c. 68 g d. 6800 g ____ 72. What is the solubility of silver nitrate if 11.1 g can dissolve in 5.0 g of water at 20 C? a. at 20 C b. at 20 C c. d. at 20 C at 20 C ____ 73. How does shaking or stirring a mixture of solute and solvent affect a solution? a. It increases the rate of dissolving. b. It decreases the rate of dissolving. c. It increases the solubility of the solute. d. It decreases the solubility of the solute. ____ 74. Which of the following factors affect solubility? a. temperature and the nature of the solvent b. temperature and degree of mixing c. particle size and degree of mixing d. particle size and temperature ____ 75. If adding of a crystal of the solute to an aqueous solution causes many particles to come out of the solution, the original solution was ____. a. unsaturated b. saturated c. an emulsion d. supersaturated ____ 76. Which of the following substances is less soluble in hot water than in cold water? a. CO b. NaCl c. NaNO d. KBr ____ 77. Which of the following generally occurs as temperature increases? a. Solubility of a solid solute decreases. b. Solubility of a solid solute increases. c. Solubility of a solid solute remains the same. d. Molarity of a solid solute doubles. ____ 78. Which phrase correctly describes the effect of pressure on the solubility of a gas in a liquid? a. proportional to the square root of the pressure of the gas above the liquid b. directly proportional to the pressure of the gas above the liquid c. inversely proportional to the pressure of the gas above the liquid d. unrelated to the pressure of the gas above the liquid ____ 79. If the solubility of a particular solute is represent a supersaturated solution of that solute? a. at 25 C b. at 15 C at 20 C, which of the following concentrations would c. d. at 20 C at 20 C ____ 80. What happens to the solubility of a gas in a liquid if the partial pressure of the gas above the liquid decreases? a. The solubility decreases. b. The solubility increases. c. The solubility remains the same. d. The solubility cannot be determined. ____ 81. To increase the solubility of a gas at constant temperature from 1.20 g/L, at 1.4 atm, to 2.3 g/L, the pressure would have to be increased to ____. a. 0.37 atm b. 0.7 atm c. 1.37 atm d. 2.7 atm ____ 82. If the solubility of a gas in water is 4.0 g/L when the pressure of the gas above the water is 3.0 atm, what is the pressure of the gas above the water when the solubility of the gas is 1.0 g/L? a. 0.75 atm b. 1.3 atm c. 4.0 atm d. 12 atm ____ 83. What is the concentration of a solution? a. a measure of the number of moles of solute dissolved b. a measure of the amount of solute in a specified quantity of solvent c. a measure of the volume of solvent used to make the solution d. a measure of the amount of solute that can be dissolved ____ 84. What is the concentration of a solution that contains 6 moles of solute in 2 liters of solution? a. 6M b. 12M c. 7M d. 3M ____ 85. In which of the following is the solution concentration expressed in terms of molarity? a. b. c. d. ____ 86. Which of the following operations yields the number of moles of solute? a. molarity moles of solution b. molarity liters of solution c. molarity mass of solution d. moles of solution volume of solution ____ 87. What is the molarity of a solution containing 7.0 moles of solute in 569 mL of solution? a. 81M b. 0.081M c. 12M d. 4.0M ____ 88. What is the molarity of 200 mL of solution in which 2.0 moles of sodium bromide is dissolved? a. 2.0M b. 10M c. 0.40M d. 4.0M ____ 89. What is the number of moles of solute in 250 mL of a 0.4M solution? a. 0.1 mol b. 0.16 mol c. 0.62 mol d. 1.6 mol ____ 90. What is the molarity of a solution containing 56 grams of solute in 959 mL of solution? (molar mass of solute = 26 g/mol) a. 1.5M b. 2.2M c. 2.1M d. 0.0022M ____ 91. What mass of sucrose, C H O , is needed to make 500.0 mL of a 0.200M solution? a. 34.2 g b. 100 g c. 17.1 g d. 68.4 g ____ 92. What mass of Na SO is needed to make 2.5 L of 2.0M solution? (Na = 23 g; S = 32 g; O = 16 g) a. 178 g b. 284 g c. 356 g d. 710 g ____ 93. Which of the following is unchanged when a solution is diluted by the addition of solvent? a. volume of solvent b. mass of solvent c. number of moles of solute d. molarity of solution ____ 94. How many mL of a 2.0M NaBr solution are needed to make 200.0 mL of 0.50M NaBr? a. 25 mL b. 50 mL c. 100 mL d. 150 mL ____ 95. The volume of 6.00M HCl needed to make 319 mL of 6.80M HCl is ____. a. 0.128 mL b. 7.8 mL c. 281 mL d. 362 mL ____ 96. If 2.0 mL of 6.0M HCl is used to make a 500.0-mL aqueous solution, what is the molarity of the dilute solution? a. 0.024M b. 0.24M c. 0.30M d. 0.83M ____ 97. To 225 mL of a 0.80M solution of KI, a student adds enough water to make 1.0 L of a more dilute KI solution. What is the molarity of the new solution? a. 180M b. 2.8M c. 0.35M d. 0.18M ____ 98. If the percent by volume is 2.0% and the volume of solution is 250 mL, what is the volume of solute in solution? a. 0.5 mL b. 1.25 mL c. 5.0 mL d. 12.5 mL ____ 99. What measures are used to calculate the percent by volume of a solution? a. mass of solute and volume of solvent b. mass of solute and volume of solution c. volume of solute and volume of solvent d. volume of solute and volume of solution ____ 100. If the percent (mass/mass) for a solute is 4% and the mass of the solution is 200 g, what is the mass of solute in solution? a. 8.0 g b. 50 g c. 80 g d. 800 g ____ 101. The volume of alcohol present in 620 mL of a 40.0% (v/v) solution of alcohol is ____. a. 372 mL b. 40.0 mL c. 248 mL d. 580 mL ____ 102. How many milliliters of alcohol are in 167 mL of an 85.0% (v/v) alcohol solution? a. 252 mL b. 228 mL c. 145 mL d. 142 mL ____ 103. In which of the following is concentration expressed in percent by volume? a. 100% b. c. d. 100% 100% 100% ____ 104. Which of the following is a colligative property of a solution? a. boiling point elevation b. melting point elevation c. vapor pressure increase d. freezing point increase ____ 105. Colligative properties depend upon the ____ a. nature of the solute. b. nature of the solvent. c. number of solute particles in a solution. d. freezing point of a solute. ____ 106. A solute depresses the freezing point because the solute ____ a. is colder than the solvent. b. disrupts crystal formation of the solvent. c. tends to sink to the bottom of the solution. d. has bigger molecules than the solvent. ____ 107. The molality of a solution containing 8.1 moles of solute in 4847 g of solvent is ____. a. 39m b. 1.7m c. 0.17m d. 598m ____ 108. Which of the following is an expression of molality? a. b. c. d. ____ 109. What is the mole fraction of ethanol in a solution of 3.00 moles of ethanol and 5.00 moles of water? a. 0.375 b. 0.6 c. 1.67 d. 15 ____ 110. What is the molality of a solution containing 8.0 grams of solute in 0.50 kg of solvent? (molar mass of solute = 24 g) a. 0.67m b. 4m c. 1.67m d. 0.17m ____ 111. What is the number of kilograms of solvent in a 0.70 molal solution containing 5.0 grams of solute? (molar mass of solute = 30 g) a. 0.24 kg b. 2.4 kg c. 0.11 kg d. 1.1 kg ____ 112. To which of the following variables is change in boiling point directly proportional? a. molarity of solution b. molality of solution c. percent by volume of solution d. percent (mass/mass) of solution ____ 113. What is the freezing point of a solution of 0.5 mol of LiBr in 500 mL of water? (K = 1.86 C/m) a. –1.86 C b. –3.72 C c. –5.58 C d. –7.44 C ____ 114. The freezing point of a solution that contains 0.550 moles of NaI in 615 g of water is ____. (K = 1.86 C/m; molar mass of water = 18 g) a. 1.66 C b. –1.66 C c. 3.33 C d. –3.33 C ____ 115. What is the boiling point of a solution that contains 3 moles of KBr in 2000 g of water? (K = 0.512 C/m; molar mass of water = 18 g) a. 97 C b. 99.7 C c. 101.4 C d. 103 C ____ 116. What is the molality of a solution of water and KCl if the freezing point of the solution is –3 C? (K = 1.86 C/m; molar mass of water = 18 g) a. 0.6m b. 1.2m c. 0.8m d. 6m ____ 117. What is the boiling point of a solution of 0.1 mole of glucose in 200 mL of water? (K = 0.512 C/m) a. 100.06 C b. 100.13 C c. 100.26 C d. 100.5 C ____ 118. What is the approximate molar mass of a molecular solute if 300 g of the solute in 1000 g of water causes the solution to have a boiling point of 101 C? (K = 0.512 C/m; K = 1.86 C/m; molar mass of water = 18 g) a. 15 amu b. 30 amu c. 150 amu d. 300 amu Short Answer 119. Balance the following everyday equation described in the following sentence. "A tricycle is made of a handle, a body, three wheels, and two axles.” H B W A HBW A 120. Write the net ionic equation for the following reaction and indicate the state of the products. Ca(NO ) (aq) (NH )2SO4(aq) 121. Balance the following equation. NaClO NaCl O 122. Balance the following equation. Mg H PO Mg (PO ) H 123. Balance the following equation. (NH ) CO NaOH Na CO NH H O 124. Balance the following equation. C H O CO H O 125. Balance the following equation. Ba H O Ba(OH) H 126. Balance the following equation. Au O Au O 127. Balance the following equation. Indicate the states of the products. Na PO (aq) ZnSO (aq) Na SO Zn (PO ) 128. Complete and balance the following equation. Al Cl 129. Complete and balance the following equation. CH O CO 130. Complete and balance the following equation. Fe (SO ) Ba(OH) 131. Balance the following equation. Indicate whether combustion is complete or incomplete. C H O CO H O 132. Balance the following equation. Indicate whether combustion is complete or incomplete. 2C H OH O CO H O 133. Write a balanced net ionic equation for the following reaction. H PO (aq) NaOH(aq) Na PO (aq) H O(l) 134. Complete and balance the following equation and indicate the precipitate, if any: K PO (aq) BaCl (aq) 135. What mass of KCl (solubility = at 20 C) can dissolve in 3.30 10 g of water? 136. If the solubility of a gas is 7.5 g/L at 404 kPa pressure, what is the solubility of the gas when the pressure is 202 kPa? 137. How many liters of a 0.30M solution are needed to give 2.7 moles of solute? 138. What is the molarity of a solution containing 9.0 moles of solute in 2500 mL of solution? 139. What is the molarity of a solution containing 1.2 grams of solute in 450 mL of solution? (molar mass of solute = 24 g) 140. What is the number of moles of solute in 650 mL of a 0.40M solution? 141. How many liters of a 1.5M solution are required to yield 5.0 grams of solute? (molar mass of solute = 30.0 g) 142. If 1.0 mL of 6.0M HCl is added to 499 mL of water to give exactly a 500-mL solution, what is the molarity of the dilute solution? 143. If the volume of solute is 6.0 mL and the volume of solution is 300.0 mL, what is the solute's percent by volume? 144. What is the molality of a solution containing 5.0 moles of solute in 3.2 kg of solvent? 145. What is the molality of a solution containing 15 grams of solute in 0.50 kilograms of solvent? (molar mass of solute = 24 g) 146. Calculate the molality of a solution prepared by dissolving 175 g of KNO in 750 g of water. 147. What is the number of moles of solute in a 0.3 molal solution containing 0.10 kg of solvent? 148. How many kilograms of solvent are in a sample of 0.30 molal solution if the sample contains 13 moles of solute? 149. What is the mole fraction of KCl in a 0.20 molal solution of KCl? (molar mass of KCl = 75 g; molar mass of water = 18 g) 150. What is the freezing point of a solution that has 5.0 moles of NaI in 1250 g of water? (K = 1.86 C/m; molar mass of water = 18.0 g) Essay 151. In general, how are word equations written to describe chemical reactions? 152. Describe how to write the skeleton equation for the following reaction: iron + oxygen iron(III) oxide 153. Consider the description: copper(II) oxide reacts with sulfuric acid to produce copper(II) sulfate and water. List the steps required to write its balanced chemical equation. State how to determine which of the five general types of reaction this represents. 154. What determines whether one metal will replace another metal from a compound in a single-replacement reaction? 155. Predict the precipitate that forms when aqueous solutions of silver nitrate and potassium chloride react to form products in a double-replacement reaction. Include a discussion of how to write the complete chemical equation describing this reaction. 156. Explain what a saturated solution is. Give a specific example. 157. Discuss the phenomenon of supersaturation. Indicate how crystallization can be initiated in a supersaturated solution. 158. Discuss the different factors that can affect the solubility of a substance. Include specific examples in your discussion. 159. Explain on a particle basis how the addition of a solute affects the boiling point, the freezing point, and the vapor pressure of the solvent. 160. Compare and contrast molarity and molality. Q. Answer Section MATCHING 1. ANS: E PTS: 1 DIF: L1 REF: p. 348 OBJ: 11.1.1 Describe how to write a skeleton equation. BLM: knowledge 2. ANS: A PTS: 1 DIF: L1 REF: p. 346 | p. 347 OBJ: 11.1.1 Describe how to write a skeleton equation. BLM: knowledge 3. ANS: B PTS: 1 DIF: L1 REF: p. 346 | p. 347 OBJ: 11.1.1 Describe how to write a skeleton equation. BLM: knowledge 4. ANS: C PTS: 1 DIF: L1 REF: p. 348 OBJ: 11.1.1 Describe how to write a skeleton equation. BLM: knowledge 5. ANS: D PTS: 1 DIF: L1 REF: p. 350 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. BLM: knowledge 6. ANS: D PTS: 1 DIF: L1 OBJ: 11.2.1 Describe the five general types of reactions. 7. ANS: C PTS: 1 DIF: L1 OBJ: 11.2.1 Describe the five general types of reactions. 8. ANS: B PTS: 1 DIF: L1 OBJ: 11.2.1 Describe the five general types of reactions. 9. ANS: A PTS: 1 DIF: L1 OBJ: 11.2.1 Describe the five general types of reactions. REF: p. 358 BLM: knowledge REF: p. 363 BLM: knowledge REF: p. 360 BLM: knowledge REF: p. 361 BLM: knowledge 10. ANS: B PTS: 1 DIF: L1 REF: p. 521 OBJ: 16.1.2 Describe the equilibrium in a saturated solution. BLM: knowledge 11. ANS: C PTS: 1 DIF: L1 REF: p. 521 OBJ: 16.1.2 Describe the equilibrium in a saturated solution. BLM: knowledge 12. ANS: D PTS: 1 DIF: L1 REF: p. 522 OBJ: 16.1.3 Describe the factors that affect the solubility of a substance. BLM: knowledge 13. ANS: A PTS: 1 DIF: L1 REF: p. 523 OBJ: 16.1.3 Describe the factors that affect the solubility of a substance. BLM: knowledge 14. ANS: E PTS: 1 DIF: L1 REF: p. 525 OBJ: 16.2.1 Calculate the molarity of a solution. BLM: knowledge 15. ANS: D PTS: 1 DIF: L1 REF: p. 525 OBJ: 16.2.1 Calculate the molarity of a solution. BLM: knowledge 16. ANS: E PTS: 1 DIF: L1 REF: p. 534 | p. 536 OBJ: 16.3.1 Explain how colligative properties can be explained on a particle basis. BLM: knowledge 17. ANS: A PTS: 1 DIF: L1 REF: p. 534 | p. 537 OBJ: 16.3.1 Explain how colligative properties can be explained on a particle basis. BLM: knowledge 18. ANS: B PTS: 1 DIF: L1 REF: p. 538 OBJ: 16.4.1 Identify the two ways of expressing the ratio of solute to solvent in a solution. BLM: knowledge 19. ANS: C PTS: 1 DIF: L1 REF: p. 540 OBJ: 16.4.1 Identify the two ways of expressing the ratio of solute to solvent in a solution. BLM: knowledge MULTIPLE CHOICE 20. ANS: D PTS: 1 DIF: L2 REF: p. 346 OBJ: 11.1.1 Describe how to write a skeleton equation. BLM: comprehension 21. ANS: B PTS: 1 DIF: L1 REF: p. 370 OBJ: 11.3.1 Describe the information found in a net ionic equation. BLM: knowledge 22. ANS: A PTS: 1 DIF: L2 REF: p. 348 OBJ: 11.1.1 Describe how to write a skeleton equation. BLM: comprehension 23. ANS: A PTS: 1 DIF: L2 REF: p. 348 OBJ: 11.1.1 Describe how to write a skeleton equation. BLM: comprehension 24. ANS: D PTS: 1 DIF: L2 REF: p. 350 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. BLM: comprehension 25. ANS: C PTS: 1 DIF: L2 REF: p. 348 OBJ: 11.1.1 Describe how to write a skeleton equation. BLM: comprehension 26. ANS: C PTS: 1 DIF: L2 REF: p. 347 OBJ: 11.1.1 Describe how to write a skeleton equation. BLM: comprehension 27. ANS: D PTS: 1 DIF: L1 REF: p. 348 OBJ: 11.1.1 Describe how to write a skeleton equation. BLM: knowledge 28. ANS: B PTS: 1 DIF: L1 REF: p. 348 OBJ: 11.1.1 Describe how to write a skeleton equation. BLM: knowledge 29. ANS: C PTS: 1 DIF: L2 REF: p. 349 OBJ: 11.1.1 Describe how to write a skeleton equation. BLM: application 30. ANS: D PTS: 1 DIF: L2 REF: p. 351 | p. 352 | p. 353 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. BLM: analysis 31. ANS: A PTS: 1 DIF: L2 REF: p. 351 | p. 352 | p. 353 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. BLM: application 32. ANS: D PTS: 1 DIF: L2 REF: p. 351 | p. 352 | p. 353 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. BLM: application 33. ANS: C PTS: 1 DIF: L2 REF: p. 351 | p. 352 | p. 353 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. BLM: application 34. ANS: D PTS: 1 DIF: L2 REF: p. 351 | p. 352 | p. 353 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. BLM: analysis 35. ANS: D PTS: 1 DIF: L2 REF: p. 350 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. BLM: comprehension 36. ANS: C PTS: 1 DIF: L2 REF: p. 350 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. BLM: comprehension 37. ANS: B PTS: 1 DIF: L2 REF: p. 351 | p. 352 | p. 353 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. BLM: analysis 38. ANS: A PTS: 1 DIF: L2 REF: p. 350 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. BLM: comprehension 39. ANS: C PTS: 1 DIF: L2 REF: p. 351 | p. 352 | p. 353 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. BLM: analysis 40. ANS: D PTS: 1 DIF: L2 REF: p. 351 | p. 352 | p. 353 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. BLM: analysis 41. ANS: C PTS: 1 DIF: L2 REF: p. 351 | p. 352 | p. 353 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. BLM: application 42. ANS: B PTS: 1 DIF: L2 REF: p. 356 | p. 366 OBJ: 11.2.1 Describe the five general types of reactions. BLM: analysis 43. ANS: B PTS: 1 DIF: L2 REF: p. 361 OBJ: 11.2.1 Describe the five general types of reactions. BLM: comprehension 44. ANS: B PTS: 1 DIF: L2 REF: p. 361 OBJ: 11.2.1 Describe the five general types of reactions. BLM: comprehension 45. ANS: C PTS: 1 DIF: L1 REF: p. 363 | p. 367 OBJ: 11.2.1 Describe the five general types of reactions. BLM: knowledge 46. ANS: A PTS: 1 DIF: L2 REF: p. 363 | p. 367 OBJ: 11.2.1 Describe the five general types of reactions. BLM: comprehension 47. ANS: C PTS: 1 DIF: L2 REF: p. 360 | p. 366 OBJ: 11.2.1 Describe the five general types of reactions. BLM: comprehension 48. ANS: B PTS: 1 DIF: L2 REF: p. 362 | p. 367 OBJ: 11.2.1 Describe the five general types of reactions. BLM: comprehension 49. ANS: C PTS: 1 DIF: L2 REF: p. 363 | p. 364 OBJ: 11.2.1 Describe the five general types of reactions. BLM: comprehension 50. ANS: B PTS: 1 DIF: L2 REF: p. 358 | p. 366 OBJ: 11.2.1 Describe the five general types of reactions. BLM: analysis 51. ANS: C PTS: 1 DIF: L2 REF: p. 362 | p. 363 OBJ: 11.2.1 Describe the five general types of reactions. BLM: analysis 52. ANS: D PTS: 1 DIF: L2 REF: p. 363 | p. 364 | p. 365 OBJ: 11.2.1 Describe the five general types of reactions. BLM: analysis 53. ANS: C PTS: 1 DIF: L2 REF: p. 358 OBJ: 11.2.1 Describe the five general types of reactions. BLM: comprehension 54. ANS: C PTS: 1 DIF: L2 REF: p. 360 | p. 366 OBJ: 11.2.1 Describe the five general types of reactions. BLM: comprehension 55. ANS: A PTS: 1 DIF: L2 REF: p. 361 OBJ: 11.2.1 Describe the five general types of reactions. BLM: comprehension 56. ANS: D PTS: 1 DIF: L2 REF: p. 361 | p. 366 OBJ: 11.2.1 Describe the five general types of reactions. BLM: application 57. ANS: A PTS: 1 DIF: L2 REF: p. 362 OBJ: 11.2.1 Describe the five general types of reactions. BLM: comprehension 58. ANS: C PTS: 1 DIF: L2 REF: p. 362 OBJ: 11.2.1 Describe the five general types of reactions. BLM: comprehension 59. ANS: A PTS: 1 DIF: L2 REF: p. 362 | p. 367 OBJ: 11.2.1 Describe the five general types of reactions. BLM: analysis 60. ANS: A PTS: 1 DIF: L2 REF: p. 363 OBJ: 11.2.1 Describe the five general types of reactions. BLM: application 61. ANS: B PTS: 1 DIF: L2 REF: p. 363 | p. 367 OBJ: 11.2.1 Describe the five general types of reactions. BLM: analysis 62. ANS: C PTS: 1 DIF: L2 REF: p. 356 | p. 366 OBJ: 11.2.1 Describe the five general types of reactions. BLM: comprehension 63. ANS: B PTS: 1 DIF: L2 REF: p. 360 | p. 366 OBJ: 11.2.1 Describe the five general types of reactions. BLM: comprehension 64. ANS: A PTS: 1 DIF: L2 REF: p. 362 | p. 367 OBJ: 11.2.1 Describe the five general types of reactions. BLM: comprehension 65. ANS: A PTS: 1 DIF: L2 REF: p. 363 | p. 367 OBJ: 11.2.1 Describe the five general types of reactions. BLM: application 66. ANS: A PTS: 1 DIF: L2 REF: p. 362 | p. 367 OBJ: 11.2.1 Describe the five general types of reactions. BLM: analysis 67. ANS: D PTS: 1 DIF: L2 REF: p. 356 | p. 366 OBJ: 11.2.1 Describe the five general types of reactions. BLM: analysis 68. ANS: B PTS: 1 DIF: L2 REF: p. 360 | p. 366 OBJ: 11.2.1 Describe the five general types of reactions. BLM: analysis 69. ANS: B PTS: 1 DIF: L3 REF: p. 367 | p. 372 OBJ: 11.2.1 Describe the five general types of reactions. | 11.3.2 Predict the formation of a precipitate in a double-replacement reaction. BLM: analysis 70. ANS: A PTS: 1 DIF: L1 REF: p. 519 OBJ: 16.1.1 Identify the factors that affect how fast a substance dissolves. BLM: knowledge 71. ANS: C PTS: 1 DIF: L2 REF: p. 521 OBJ: 16.1.3 Describe the factors that affect the solubility of a substance. BLM: analysis 72. ANS: D PTS: 1 DIF: L2 REF: p. 521 OBJ: 16.1.3 Describe the factors that affect the solubility of a substance. BLM: analysis 73. ANS: A PTS: 1 DIF: L1 REF: p. 519 OBJ: 16.1.1 Identify the factors that affect how fast a substance dissolves. BLM: knowledge 74. ANS: A PTS: 1 DIF: L1 REF: p. 521 | p. 522 OBJ: 16.1.3 Describe the factors that affect the solubility of a substance. BLM: knowledge 75. ANS: D PTS: 1 DIF: L2 REF: p. 522 OBJ: 16.1.3 Describe the factors that affect the solubility of a substance. BLM: comprehension 76. ANS: A PTS: 1 DIF: L2 REF: p. 522 OBJ: 16.1.3 Describe the factors that affect the solubility of a substance. BLM: application 77. ANS: B PTS: 1 DIF: L2 REF: p. 521 OBJ: 16.1.3 Describe the factors that affect the solubility of a substance. BLM: comprehension 78. ANS: B PTS: 1 DIF: L2 REF: p. 523 OBJ: 16.1.3 Describe the factors that affect the solubility of a substance. BLM: comprehension 79. ANS: D PTS: 1 DIF: L2 REF: p. 522 OBJ: 16.1.3 Describe the factors that affect the solubility of a substance. BLM: analysis 80. ANS: A PTS: 1 DIF: L1 REF: p. 523 | p. 524 OBJ: 16.1.3 Describe the factors that affect the solubility of a substance. BLM: knowledge 81. ANS: D PTS: 1 DIF: L2 REF: p. 523 | p. 524 OBJ: 16.1.3 Describe the factors that affect the solubility of a substance. BLM: analysis 82. ANS: A PTS: 1 DIF: L2 REF: p. 523 | p. 524 OBJ: 16.1.3 Describe the factors that affect the solubility of a substance. BLM: analysis 83. ANS: B PTS: 1 DIF: L1 REF: p. 525 OBJ: 16.2.1 Calculate the molarity of a solution. BLM: knowledge 84. ANS: D PTS: 1 DIF: L1 REF: p. 526 OBJ: 16.2.1 Calculate the molarity of a solution. BLM: analysis 85. ANS: D PTS: 1 DIF: L2 REF: p. 538 OBJ: 16.4.1 Identify the two ways of expressing the ratio of solute to solvent in a solution. BLM: application 86. ANS: B PTS: 1 DIF: L2 REF: p. 538 OBJ: 16.4.1 Identify the two ways of expressing the ratio of solute to solvent in a solution. BLM: comprehension 87. ANS: C PTS: 1 DIF: L2 REF: p. 526 OBJ: 16.2.1 Calculate the molarity of a solution. BLM: analysis 88. ANS: B PTS: 1 DIF: L2 REF: p. 526 OBJ: 16.2.1 Calculate the molarity of a solution. BLM: analysis 89. ANS: A PTS: 1 DIF: L2 REF: p. 527 OBJ: 16.2.1 Calculate the molarity of a solution. BLM: analysis 90. ANS: B PTS: 1 DIF: L3 REF: p. 526 OBJ: 16.2.1 Calculate the molarity of a solution. BLM: analysis 91. ANS: A PTS: 1 DIF: L3 REF: p. 526 OBJ: 16.2.1 Calculate the molarity of a solution. BLM: analysis 92. ANS: D PTS: 1 DIF: L3 REF: p. 526 OBJ: 16.2.1 Calculate the molarity of a solution. BLM: analysis 93. ANS: C PTS: 1 DIF: L1 REF: p. 528 OBJ: 16.2.2 Describe the effect of dilution on the total moles of solute in solution. BLM: knowledge 94. ANS: B PTS: 1 DIF: L2 REF: p. 528 | p. 529 OBJ: 16.2.2 Describe the effect of dilution on the total moles of solute in solution. BLM: analysis 95. ANS: D PTS: 1 DIF: L2 REF: p. 528 | p. 529 OBJ: 16.2.2 Describe the effect of dilution on the total moles of solute in solution. BLM: analysis 96. ANS: A PTS: 1 DIF: L2 REF: p. 528 | p. 529 OBJ: 16.2.2 Describe the effect of dilution on the total moles of solute in solution. BLM: analysis 97. ANS: D PTS: 1 DIF: L2 REF: p. 528 | p. 529 OBJ: 16.2.2 Describe the effect of dilution on the total moles of solute in solution. BLM: analysis 98. ANS: C PTS: 1 DIF: L2 REF: p. 529 OBJ: 16.2.3 Express solution concentration as a percent by volume or percent by mass. BLM: analysis 99. ANS: D PTS: 1 DIF: L1 REF: p. 529 OBJ: 16.2.3 Express solution concentration as a percent by volume or percent by mass. BLM: knowledge 100. ANS: A PTS: 1 DIF: L2 REF: p. 531 OBJ: 16.2.3 Express solution concentration as a percent by volume or percent by mass. BLM: analysis 101. ANS: C PTS: 1 DIF: L2 REF: p. 530 OBJ: 16.2.3 Express solution concentration as a percent by volume or percent by mass. BLM: analysis 102. ANS: D PTS: 1 DIF: L2 REF: p. 530 OBJ: 16.2.3 Express solution concentration as a percent by volume or percent by mass. BLM: analysis 103. ANS: B PTS: 1 DIF: L2 REF: p. 530 OBJ: 16.2.3 Express solution concentration as a percent by volume or percent by mass. BLM: comprehension 104. ANS: A PTS: 1 DIF: L1 REF: p. 534 OBJ: 16.3.1 Explain how colligative properties can be explained on a particle basis. BLM: knowledge 105. ANS: C PTS: 1 DIF: L1 REF: p. 534 OBJ: 16.3.1 Explain how colligative properties can be explained on a particle basis. BLM: knowledge 106. ANS: B PTS: 1 DIF: L2 REF: p. 534 OBJ: 16.3.1 Explain how colligative properties can be explained on a particle basis. BLM: comprehension 107. ANS: B PTS: 1 DIF: L2 REF: p. 538 OBJ: 16.4.1 Identify the two ways of expressing the ratio of solute to solvent in a solution. BLM: analysis 108. ANS: A PTS: 1 DIF: L2 REF: p. 538 OBJ: 16.4.1 Identify the two ways of expressing the ratio of solute to solvent in a solution. BLM: application 109. ANS: A PTS: 1 DIF: L2 REF: p. 540 OBJ: 16.4.1 Identify the two ways of expressing the ratio of solute to solvent in a solution. BLM: analysis 110. ANS: A PTS: 1 DIF: L2 REF: p. 539 OBJ: 16.4.1 Identify the two ways of expressing the ratio of solute to solvent in a solution. BLM: analysis 111. ANS: A PTS: 1 DIF: L2 REF: p. 539 OBJ: 16.4.1 Identify the two ways of expressing the ratio of solute to solvent in a solution. BLM: analysis 112. ANS: B PTS: 1 DIF: L1 REF: p. 540 OBJ: 16.4.2 Describe how the freezing-point depression and boiling-point elevation are related to molality. BLM: knowledge 113. ANS: B PTS: 1 DIF: L2 REF: p. 542 | p. 543 OBJ: 16.4.2 Describe how the freezing-point depression and boiling-point elevation are related to molality. BLM: analysis 114. ANS: D PTS: 1 DIF: L2 REF: p. 542 | p. 543 OBJ: 16.4.2 Describe how the freezing-point depression and boiling-point elevation are related to molality. BLM: analysis 115. ANS: C PTS: 1 DIF: L2 REF: p. 542 | p. 544 OBJ: 16.4.2 Describe how the freezing-point depression and boiling-point elevation are related to molality. BLM: analysis 116. ANS: C PTS: 1 DIF: L3 REF: p. 542 | p. 544 OBJ: 16.4.2 Describe how the freezing-point depression and boiling-point elevation are related to molality. BLM: analysis 117. ANS: C PTS: 1 DIF: L2 REF: p. 543 | p. 544 OBJ: 16.4.2 Describe how the freezing-point depression and boiling-point elevation are related to molality. BLM: analysis 118. ANS: C PTS: 1 DIF: L3 REF: p. 542 | p. 544 OBJ: 16.4.2 Describe how the freezing-point depression and boiling-point elevation are related to molality. BLM: analysis SHORT ANSWER 119. ANS: H + B + 3W + 2A HBW A PTS: 1 DIF: L2 REF: p. 350 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. BLM: application 120. ANS: Ca2+(aq) SO42-(aq) CaSO4(s) PTS: 1 DIF: L3 REF: p. 371 | p. 372 OBJ: 11.3.1 Describe the information found in a net ionic equation. | 11.3.2 Predict the formation of a precipitate in a double-replacement reaction. BLM: analysis 121. ANS: 2NaClO 2NaCl 3O PTS: 1 DIF: L2 REF: p. 352 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. BLM: application 122. ANS: 3Mg 2H PO Mg (PO ) 3H PTS: 1 DIF: L2 REF: p. 352 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. BLM: application 123. ANS: (NH ) CO 2NaOH Na CO 2NH 2H O PTS: 1 DIF: L2 REF: p. 352 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. BLM: analysis 124. ANS: C H 3O 3CO 3H O PTS: 1 DIF: L2 REF: p. 352 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. BLM: analysis 125. ANS: Ba 2H O Ba(OH) H PTS: 1 DIF: L2 REF: p. 352 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. BLM: analysis 126. ANS: 2Au O 4Au 3O PTS: 1 DIF: L2 REF: p. 352 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. BLM: analysis 127. ANS: 2Na PO 3ZnSO 3Na SO (aq) Zn (PO ) (s) PTS: 1 DIF: L3 REF: p. 352 | p. 372 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. | 11.3.2 Predict the formation of a precipitate in a double-replacement reaction. BLM: analysis 128. ANS: 2Al 3Cl 2AlCl PTS: 1 DIF: L3 REF: p. 352 | p. 367 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. | 11.2.1 Describe the five general types of reactions. BLM: analysis 129. ANS: CH 2O CO 2H O PTS: 1 DIF: L2 REF: p. 352 | p. 367 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. | 11.2.1 Describe the five general types of reactions. BLM: analysis 130. ANS: Fe (SO ) 3Ba(OH) 2Fe(OH) 3BaSO PTS: 1 DIF: L3 REF: p. 352 | p. 367 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. | 11.2.1 Describe the five general types of reactions. BLM: analysis 131. ANS: 2C H 7O 6CO 8H O (incomplete) PTS: 1 DIF: L3 REF: p. 352 | p. 367 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. | 11.2.1 Describe the five general types of reactions. BLM: analysis 132. ANS: C H OH 3O 2CO 3H O (complete) PTS: 1 DIF: L3 REF: p. 352 | p. 367 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. | 11.2.1 Describe the five general types of reactions. BLM: analysis 133. ANS: H (aq) OH (aq) H O(l) PTS: 1 DIF: L3 REF: p. 370 | p. 371 OBJ: 11.3.1 Describe the information found in a net ionic equation. BLM: analysis 134. ANS: 2K PO (aq) 3BaCl (aq) Ba (PO ) s 6KCl(aq) PTS: 1 DIF: L3 REF: p. 367 | p. 372 OBJ: 11.2.1 Describe the five general types of reactions. | 11.3.2 Predict the formation of a precipitate in a double-replacement reaction. BLM: analysis 135. ANS: PTS: 1 DIF: L2 REF: p. 521 OBJ: 16.1.2 Describe the equilibrium in a saturated solution. 136. ANS: S = = BLM: analysis = 3.8 g/L PTS: 1 DIF: L2 REF: p. 523 OBJ: 16.1.3 Describe the factors that affect the solubility of a substance. BLM: analysis 137. ANS: 2.7 mol = 9.0 L PTS: 1 DIF: L2 REF: p. 527 OBJ: 16.2.1 Calculate the molarity of a solution. 138. ANS: BLM: analysis PTS: 1 DIF: L2 REF: p. 526 OBJ: 16.2.1 Calculate the molarity of a solution. 139. ANS: BLM: analysis PTS: 1 DIF: L2 REF: p. 526 OBJ: 16.2.1 Calculate the molarity of a solution. 140. ANS: BLM: analysis PTS: 1 DIF: L2 REF: p. 527 OBJ: 16.2.1 Calculate the molarity of a solution. 141. ANS: BLM: analysis PTS: 1 DIF: L2 REF: p. 527 OBJ: 16.2.1 Calculate the molarity of a solution. 142. ANS: BLM: analysis PTS: 1 DIF: L2 REF: p. 528 | p. 529 OBJ: 16.2.2 Describe the effect of dilution on the total moles of solute in solution. BLM: analysis 143. ANS: % = 2.0% PTS: 1 DIF: L2 REF: p. 529 OBJ: 16.2.3 Express solution concentration as a percent by volume or percent by mass. BLM: analysis 144. ANS: PTS: 1 DIF: L1 REF: p. 538 OBJ: 16.4.1 Identify the two ways of expressing the ratio of solute to solvent in a solution. BLM: analysis 145. ANS: PTS: 1 DIF: L2 REF: p. 538 OBJ: 16.4.1 Identify the two ways of expressing the ratio of solute to solvent in a solution. BLM: analysis 146. ANS: molar mass KNO : K: 1 39.1 g = 39.1 g N: 1 14.0 g = 14.0 g O: 3 16.0 g = 48.0 g molar mass = 101.1 g PTS: 1 DIF: L2 REF: p. 538 | p. 539 OBJ: 16.4.1 Identify the two ways of expressing the ratio of solute to solvent in a solution. BLM: analysis 147. ANS: Number of moles = mass of solvent molality PTS: 1 DIF: L2 REF: p. 538 | p. 539 OBJ: 16.4.1 Identify the two ways of expressing the ratio of solute to solvent in a solution. BLM: analysis 148. ANS: PTS: 1 DIF: L2 REF: p. 539 OBJ: 16.4.1 Identify the two ways of expressing the ratio of solute to solvent in a solution. BLM: analysis 149. ANS: PTS: 1 DIF: L2 REF: p. 540 | p. 541 OBJ: 16.4.1 Identify the two ways of expressing the ratio of solute to solvent in a solution. BLM: analysis 150. ANS: = 15 PTS: 1 DIF: L2 REF: p. 543 OBJ: 16.4.2 Describe how the freezing-point depression and boiling-point elevation are related to molality. BLM: analysis ESSAY 151. ANS: Reactants and products are written as words. An arrow is drawn between the reactants and the products with its arrowhead pointing toward the right. Reactants are listed to the left of the arrow, and products are listed to the right of the arrow. If more than one reactant or product is involved in the reaction, they are separated by plus signs. The words describe substances that are part of the reaction. The arrow symbolizes that substances react to produce products, or that reactants yield products. PTS: 1 DIF: L2 REF: p. 348 OBJ: 11.1.1 Describe how to write a skeleton equation. BLM: comprehension 152. ANS: A skeleton equation includes substances involved in a chemical reaction, but does not necessarily show the relative quantities of each substance in the reaction. Chemical symbols and formulas are used to indicate the substances that are part of the reaction. The state of each substance in the skeleton equation may be indicated in parentheses, with s representing solid, g representing gas, l representing liquid, and aq representing an aqueous solution. The skeleton equation for the reaction of iron with oxygen to produce iron(III) oxide is not balanced. It is written as: Fe(s) + O (g) Fe O (s) PTS: 1 DIF: L3 REF: p. 348 | p. 349 OBJ: 11.1.1 Describe how to write a skeleton equation. BLM: analysis 153. ANS: A first approach is to indicate the reactants and products in a word equation: copper(II) oxide + sulfuric acid copper(II) sulfate + water Next, convert the word equation to a skeleton equation using chemical formulas: CuO(s) + H SO (aq) CuSO (aq) + H O(l) Because the Cu is exchanged in this reaction involving an aqueous solution, and the molecular compound H O is formed, the reaction type is double-replacement. In this case, the skeleton equation already is balanced. Inspection of substances on the left and right of the equation shows that the same relative amounts (number of atoms) of each element are present in the reactants and the products. PTS: 1 DIF: L3 REF: p. 352 | p. 367 OBJ: 11.1.2 Describe the steps for writing and balancing a chemical equation. | 11.2.1 Describe the five general types of reactions. BLM: analysis 154. ANS: Whether one metal will replace another is determined by the relative reactivity of the two metals. The activity series of metals lists metals in order of decreasing reactivity. A reactive metal will replace any metal found below it in the activity series. PTS: 1 DIF: L2 REF: p. 361 OBJ: 11.2.1 Describe the five general types of reactions. 155. ANS: BLM: comprehension Because the reaction is a double-replacement type, cations are exchanged among compounds during the reaction. The first step is to write the equation in skeleton form: AgNO + KCl AgCl + KNO Inspection of this equation shows that the insoluble precipitate silver chloride forms in an aqueous solution of potassium nitrate. The relative amounts of elements are the same on either side of the equation, so the complete equation is: AgNO (aq) + KCl(aq) AgCl(s) + KNO (aq) (balanced) PTS: 1 DIF: L3 REF: p. 371 | p. 372 OBJ: 11.2.1 Describe the five general types of reactions. | 11.3.2 Predict the formation of a precipitate in a double-replacement reaction. BLM: synthesis 156. ANS: A saturated solution contains the maximum amount of solute for a given amount of solvent at a constant temperature. For example, no more than 36.2 g of sodium chloride will dissolve in 100 g of water. In a saturated solution, a dynamic equilibrium exists between the solid and its dissolved ions. In this equilibrium, as many ions are going out of the solution as are going in per unit time. PTS: 1 DIF: L2 REF: p. 520 OBJ: 16.1.2 Describe the equilibrium in a saturated solution. BLM: application 157. ANS: A solution that contains more solute than it can theoretically hold at a given temperature is a supersaturated solution. Crystallization can be initiated by adding a seed crystal to the solution or by exposing the solution to a rough surface. The latter can be done by scratching the inside of the container holding the solution. PTS: 1 DIF: L2 REF: p. 522 OBJ: 16.1.3 Describe the factors that affect the solubility of a substance. BLM: application 158. ANS: The factors are temperature, pressure, and the nature of the solute and solvent. Specific examples include the following. Potassium nitrate is more soluble in water at high temperature than at low temperature. Gases are less soluble at high temperatures than at low temperatures. The solubility of a particular gas increases as the partial pressure of that gas above the solution increases. Sodium nitrate is much more soluble in water than is barium sulfate, regardless of temperature, because the attractive forces between the ions in BaSO are stronger than the attractive force of the solvent molecules. PTS: 1 DIF: L2 REF: p. 521 | p. 523 OBJ: 16.1.3 Describe the factors that affect the solubility of a substance. BLM: application 159. ANS: Boiling point elevation, freezing point lowering, and vapor pressure lowering are colligative properties. They depend on the number of particles in solution and not on the chemical nature of the solute. Boiling point elevation: Additional attractive forces exist between solute and solvent; they must be overcome for the solution to boil. Kinetic energy must be added to overcome these forces. Freezing point lowering: More kinetic energy must be withdrawn from a solution because the solute particles are surrounded by shells of solvent molecules. These shells interfere with the formation of the orderly pattern that the particles assume as the solvent changes from liquid to solid. Vapor pressure lowering: The formation of solvent shells around the solute particles reduces the number of solvent particles that have sufficient kinetic energy to vaporize. PTS: 1 DIF: L3 REF: p. 534 | p. 535 | p. 536 OBJ: 16.3.1 Explain how colligative properties can be explained on a particle basis. BLM: synthesis 160. ANS: Molarity is a quantitative measure of the concentration of a solution. It is defined as the number of moles of solute present in 1 L of solution. Molality is also a quantitative measure of the concentration of a solution. It is defined as the number of moles of solute present in 1 kg of solvent. Molarity is a ratio of moles of solute to 1 L of solution. Molality is a ratio of moles of solute to 1kg of solvent. Molarity: ; Molality: PTS: 1 DIF: L2 REF: p. 525 | p. 538 OBJ: 16.2.1 Calculate the molarity of a solution. | 16.4.1 Identify the two ways of expressing the ratio of solute to solvent in a solution. BLM: analysis
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