Name of Candidate:……………………………………………. Class:…………………. D Quantitative analysis (salt analysis) 1. The pain experienced in a toothache can be reduced when traces of one of the salts in PESTALOZZI EDUCATION CENTRE the chemistry syllabus gets into contact with the affected area. SENIOR SECONDARY SCHOOL GRADE 11 END OF TERM III TESTS (2024) CHEMISTRY (5070/3) TIME: 20 HOURS Instructions to candidates. Write your name and class in the space provided at the top of the paper. There are two sections, A and B in this question paper. Section A Answer all questions from this section Write your answers in the spaces provided on the question paper Section B Chose any three questions Write the answers in the separate booklet provided. For examiner`s use Information for candidates Section A The number of marks is given in rackets [] at the end of each question A10 or part of the question. A11 The periodic table is printed on page 20 A12 A13 This question paper consists of 20 printed pages PEC/2024/G11/P3/TERM3 0 Section A: [50 marks] Answer all questions in the spaces provided. A1. (a). (i) Explain why most laboratories do not have smooth floors, but have rough floors. …………………………………………………..…………………………… …….……..………………………………………..………………………. [1] (ii) Give one laboratory safety rule you would need to observe when carrying out a titration experiment. …………………………………………………..………………………… …….……..……………………………………………..………………. [2] (b). Draw the arrangement of particles in a solid, liquid and gas in the spaces below [3] Liquid Solid Gas (c). Explain why (i). for the space occupied, solids have higher density than liquids and gases. ………………………………………..……………………………. [1] (ii). Gases are compressible. ……………………………………………..………………………. [1] [Total: 7 marks] 1 A2. The diagram below shows apparatus used in separating components of crude oil in a school laboratory. a. Name the process by which crude oil is separated into other products on a large scale. ………………………………………………………………………….. [1] b. What is the purpose of the cotton wool? ………………………………………………………………………….. [1] c. Why is the thermometer included in the diagram? ………………………………………………………………………….. [1] d. Why is the general term used to refer to substance X? ………………………………………………………………………….. [1] [Total: 4 marks] 2 A3. Crystals of Copper (ii) Sulphate (CuSO4.5H2O) are obtained from aqueous solution of Sulphate (CuSO4). State the four steps (processes) in their correct order, and for each step give the reason for carrying out such step, in obtaining the crystals. i. Step 1………………………………………………………………………. …………………………………………………………………………….. Reasons……………………………………………………………………. ………………………………………………………………………… [2] ii. Step 2………………………………………………………………………. …………………………………………………………………………….. Reasons……………………………………………………………………. ………………………………………………………………………… [2] iii. Step 3………………………………………………………………………. …………………………………………………………………………….. Reasons……………………………………………………………………. ………………………………………………………………………… [2] iv. Step 4………………………………………………………………………. …………………………………………………………………………….. Reasons……………………………………………………………………. ………………………………………………………………………… [2] [Total: 8 marks] ‘ 3 A4. (a). A coefficient and subscript on the symbols of Nitrogen atom (N) mean different notations in chemistry. i. What is the significant difference between the two notations 2N and N2? ………………………………………...…………..……………… ………………….……..……………………………………… [1] ii. Draw the dot and cross structures showing outer shells only for the two notations. (b). [2] N2 2N Both Carbon tetrachloride (CCl4) and potassium Chloride (KCl) are compounds of Chlorine. i. compare the electrical; conductivity of liquid Carbon tetrachloride (CCl4) and potassium Chloride (KCl) ………………………………………...…………..……………… ………………….……..…………………………………….... [1] iii. Which of the two compounds has a higher melting point. Explain your answer. ………………………………………...…………..……………… ………………….……..……………………………………….[2] [Total: 6 marks] 4 A5. A Grade 11 student at Pestalozzi Education center left a sample of iron filling in a dump condition for the period of 24 hours. It was discovered that it developed rust. He measured 3.5g of the sample and reacted it with aqueous Copper (ii) Sulphate and 3.2g of Copper was formed. Given that neither Copper Sulphate nor Iron fillings was in in excess during the reaction. a. Construct a balanced chemical equation for the reaction described above, including the state symbols. …………………………………………………………………………… [1] b. Calculate the mass of Iron that reacted with aqueous Copper (ii) Sulphate. [2] c. Determine the percentage by mass on rust in the sample of Iron fillings. [2] d. Give one differences between electroplating and galvanizing as the methods of preventing iron from rusting. ………………………………………………………………………………… ………………………………………………………………………………. [1] [Total: 6 marks] 5 A6. The diagram below shows how three compounds can be interconverted. a. Which of the three calcium compounds above: i. Occurs widely in nature? ……………………………………………………………..….. [1] ii. Is present in lime water? ……………………………………………………………..….. [1] b. Using the information in the diagram above, i. Suggest the substance that is added to calcium oxide to carry out step 1 ……………………………………………………………..….. [1] ii. Explain how step 3 can be carried out. ……………………………………………………………..….. [1] [Total: 4 marks] A7. Lithium, Sodium, Potassium and Rubidium are members of group I of the periodic Table. a. What is the common name given to Group I elements? ………………………………………………………………………………. [1] b. State two physical properties of Group I elements? ………………………………………………………………………………… ………………………………………………………………………………. [2] c. Lithium reacts with water to form Lithium Hydroxide and Hydrogen gas. Write a balanced chemical equation for this reaction. ………………………………………………………………………………. [2] d. How would the sped of reaction of Lithium with water compare with that of Rubidium with water? ………………………………………………………………………………… ………………………………………………………………………………. [1] [Total: 4 marks] 6 A8. Choose from the list of Oxides given to answer the questions that follow. An oxide may be chosen once, more than once or not at all. Name of the oxide Its chemical formula Aluminium Oxide Al2O3 Calcium Oxide CaO Carbon dioxide CO2 Iron (iii) Oxide Fe2O3 Water H2O Zinc Oxide ZnO Carbon Monoxide CO a. Which two Oxides are amphoteric? …………….………………………….…………………….…………..........[1] b. Which two Oxides are neutral? …………….………………………….…………………….…………..........[1] c. State the other types of oxides. Give an example of each oxide from the table above i. …………………………….………………………….………………… ii. ………………………….….………………………….……………. [2] d. Suggest two Oxides which can be extracted from their metal ores using the same method. …………….………………………….…………………….…………...……… .………….…………………….………………………….……………...…. [2] [Total: 6 marks] 7 A9. The diagram below was used to measure the rate of reaction. The initial mass of the beaker and the content was 50.0g The graph below show also shows how the reaction between limestone and hydrochloric acid proceeded with time. 8 a. What mass of carbon dioxide was lost when the reaction was completed? [1] b. Calculate the mass of calcium carbonate was used up in the first 2 minutes? [2] c. On the same graph sketch how, the curve would appear if powdered limestone was used. [2] [Total: 5 marks] 9 Section B (30 marks) Answer three questions from this section Write your answers in the Answer Booklet provided. A10. Zinc is extracted from its Sulphide Ore, Zinc blende, in a blast furnace shown below. a. What reducing agent is used in the extraction process shown above? [1] b. What is the chemical name for Zinc Sulphide. [1] c. Write a balanced chemical equation for the reaction which occurs when zinc blende is roasted in air. [2] d. Name a pollutant gas which is produced when zinc blende is roasted in air. [1] e. Describe how the named pollutant in (d) is converted to a useful product in industry. f. i. ii. [2] Zinc is often alloyed with other metals. Name an element which is alloyed with Zinc to form brass. [1] Give two use of Zinc. [1] [Total: 10 marks] 10 A11. A current of 0.5 amperes was passed for 2 400 seconds through colorimeters in series. One colorimeter contains dilute sodium hydroxide and the other molten potassium iodine. Graphite electrodes were used. a. What quantity of electricity was used? [2] b. Write ionic equations for reactions occurring at the two anodes. [2] c. How many moles of electrons were passed through each electrolyte? [2] d. What mass of product is liberated at the cathode in the potassium iodide voltmeter? [2] e. State any two applications of electrolysis. [2] [Total: 10 marks] 11 A12. The diagram below shows the energy-level diagram for a particular type of a chemical reaction. a. What does X shown in the diagram represent? [1] b. Is this reaction exothermic or endothermic? Give a reason for your answer. [2] c. Calculate the amount of heat change involved when 5.2g of glucose reacts completely with oxygen. [2] d. Hydrogen combines with chlorine to form hydrogen chloride gas. i. Write balanced chemical equation for the reaction. [1] ii. Calculate the enthalpy change for the reaction of hydrogen and chlorine using the bond energies below. bond Bond energy (KJ/mol H-H 436 Cl-Cl 242 H-Cl 431 [2] iii. Is the reaction between Hydrogen and Chlorine exothermic or endothermic? Justify your answer [2] [Total: 10 marks] 12 A13. The main ore of iron, Hematite, contains iron (III) oxide as its main constituent Iron is extracted from this ore by chemical reduction in the blast furnace. The temperature inside the furnace is about 2000°C. a. Describe, with the aid of chemical equations how the carbon monoxide is formed. [2] b. Write a balanced chemical equation for the reaction in which Iron Oxide is reduced to Iron metal. [2] c. During the extraction of iron, molten slag is formed. Explain how slag is produced during the extraction of Iron. [2] d. Most of the iron obtained in the blast furnace is converted into steel, which is an alloy. Explain, with particular reference to iron, why metals are often used as alloys rather than as pure metals. [2] e. A current of SOA is passed in the electrolyte for 1 hour. Calculate the mass of Aluminium that will be produced. (1F = 1 mole of electrons = 96 500C). [2] [Total: 10 marks] 13 Question number ANSWER BOOKLET Start each question on a new page …………………………………………………………….…………………………… ….……………………………………………………….………………………………. ……………………………………………………………………………………….… …………………………….……………………………………………………….…… ………………………….……………………………………………………….……… ……………………….……………………………………………………….………… …………………….……………………………………………………….…………… ………………….……………………………………………………….……………… ……………….……………………………………………………….………………… …………….………………………………………………………………………….… …………………………….……………………………………………………….…… ………………………….……………………………………………………….……… ……………………….……………………………………………………….………… …………………….……………………………………………………….…………… ………………….……………………………………………………….……………… ……………….……………………………………………………….………………… …………….…………………………………….……………………………………… ……………….……………………………….………………………………………… …………….……………………………….…………………………………………… ………….……………………………….……………………………………………… ……….……………………………….………………………………………………… …….……………………………….…………………………………………………… ….……………………………….………………………………………….…………… ………………….……………………………………………………….……………… 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