SAFETY DATA SHEET Creation Date 20-Apr-2010 Revision Date 13-Oct-2023 Revision Number 7 1. Identification Product Name Carborundum Cat No. : C192; C192-500 CAS No Synonyms 409-21-2 Silicon Carbide. Recommended Use Uses advised against Laboratory chemicals. Food, drug, pesticide or biocidal product use. Details of the supplier of the safety data sheet Company Fisher Scientific Company One Reagent Lane Fair Lawn, NJ 07410 Tel: (201) 796-7100 Emergency Telephone Number CHEMTRECÒ, Inside the USA: 800-424-9300 CHEMTRECÒ, Outside the USA: 001-703-527-3887 2. Hazard(s) identification Classification Classification under 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label Elements None required Hazards not otherwise classified (HNOC) None identified 3. Composition/Information on Ingredients ______________________________________________________________________________________________ Page 1 / 7 Revision Date 13-Oct-2023 Carborundum ______________________________________________________________________________________________ Component Silicon carbide CAS No 409-21-2 Weight % <=100 4. First-aid measures Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Get medical attention immediately if symptoms occur. Inhalation Remove to fresh air. Get medical attention immediately if symptoms occur. Ingestion Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur. Most important symptoms and effects Notes to Physician None reasonably foreseeable. Treat symptomatically 5. Fire-fighting measures Unsuitable Extinguishing Media Flash Point Method - No information available Not applicable No information available No information available Autoignition Temperature Explosion Limits No data available Upper No data available Lower Sensitivity to Mechanical Impact No information available Sensitivity to Static Discharge No information available Specific Hazards Arising from the Chemical Keep product and empty container away from heat and sources of ignition. Hazardous Combustion Products Silicon dioxide. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health 1 Flammability 0 Instability 0 Physical hazards N/A 6. Accidental release measures Personal Precautions Environmental Precautions Ensure adequate ventilation. Use personal protective equipment as required. Avoid dust formation. Should not be released into the environment. Methods for Containment and Clean Sweep up and shovel into suitable containers for disposal. Avoid dust formation. Up 7. Handling and storage Handling Wear personal protective equipment/face protection. Ensure adequate ventilation. Avoid ______________________________________________________________________________________________ Page 2 / 7 Revision Date 13-Oct-2023 Carborundum ______________________________________________________________________________________________ ingestion and inhalation. Avoid contact with skin, eyes or clothing. Avoid dust formation. Keep containers tightly closed in a dry, cool and well-ventilated place. Incompatible Materials. Strong oxidizing agents. Storage. 8. Exposure controls / personal protection Exposure Guidelines Component Silicon carbide ACGIH TLV TWA: 10 mg/m3 TWA: 3 mg/m3 TWA: 0.1 fiber/cm3 OSHA PEL (Vacated) TWA: 10 mg/m3 (Vacated) TWA: 5 mg/m3 TWA: 15 mg/m3 TWA: 5 mg/m3 NIOSH TWA: 10 mg/m3 TWA: 5 mg/m3 Mexico OEL (TWA) TWA: 10 mg/m3 TWA: 0.1 fiber/cm3 TWA: 3 mg/m3 Legend ACGIH - American Conference of Governmental Industrial Hygienists OSHA - Occupational Safety and Health Administration NIOSH: NIOSH - National Institute for Occupational Safety and Health None under normal use conditions. Engineering Measures Personal Protective Equipment Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure. Respiratory Protection No protective equipment is needed under normal use conditions. Recommended Filter type: Particle filter. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. 9. Physical and chemical properties Physical State Appearance Odor Odor Threshold pH Melting Point/Range Boiling Point/Range Flash Point Evaporation Rate Flammability (solid,gas) Flammability or explosive limits Upper Lower Vapor Pressure Vapor Density Specific Gravity Solubility Partition coefficient; n-octanol/water Autoignition Temperature Decomposition Temperature Viscosity Molecular Formula Solid Black Odorless No information available Not applicable 2700 °C / 4892 °F Not applicable Not applicable Not applicable No information available No data available No data available No information available Not applicable 3.2 Insoluble in water No data available No information available No information available Not applicable SiC ______________________________________________________________________________________________ Page 3 / 7 Revision Date 13-Oct-2023 Carborundum ______________________________________________________________________________________________ 40.0855 Molecular Weight 10. Stability and reactivity Reactive Hazard None known, based on information available Stability Stable under normal conditions. Conditions to Avoid Incompatible products. Excess heat. Avoid dust formation. Incompatible Materials Strong oxidizing agents Hazardous Decomposition Products Silicon dioxide Hazardous Polymerization Hazardous polymerization does not occur. Hazardous Reactions None under normal processing. 11. Toxicological information Acute Toxicity Product does not present an acute toxicity hazard based on known information Product Information Component Information No information available Toxicologically Synergistic Products Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation May cause skin, eye, and respiratory tract irritation Sensitization No information available Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Some agencies list SiC microfibers/whiskers as potential carcinogens, based on limited experimental animal data that suggests a carcinogenic effect. Component CAS No IARC Silicon carbide 409-21-2 Group 2A IARC (International Agency for Research on Cancer) NTP: (National Toxicity Program) ACGIH: (American Conference of Governmental Industrial Hygienists) NTP ACGIH OSHA Mexico Not listed A2 X A2 IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 2A - Probably Carcinogenic to Humans Group 2B - Possibly Carcinogenic to Humans NTP: (National Toxicity Program) Known - Known Carcinogen Reasonably Anticipated - Reasonably Anticipated to be a Human Carcinogen A1 - Known Human Carcinogen A2 - Suspected Human Carcinogen A3 - Animal Carcinogen ACGIH: (American Conference of Governmental Industrial Hygienists) Mutagenic Effects No information available Reproductive Effects No information available. Developmental Effects No information available. Teratogenicity No information available. STOT - single exposure STOT - repeated exposure None known None known Aspiration hazard No information available ______________________________________________________________________________________________ Page 4 / 7 Revision Date 13-Oct-2023 Carborundum ______________________________________________________________________________________________ Symptoms / effects,both acute and No information available delayed Endocrine Disruptor Information No information available Other Adverse Effects The toxicological properties have not been fully investigated. 12. Ecological information Ecotoxicity Do not empty into drains. Do not flush into surface water or sanitary sewer system. Persistence and Degradability Insoluble in water Bioaccumulation/ Accumulation No information available. Mobility Is not likely mobile in the environment due its low water solubility. 13. Disposal considerations Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. DOT TDG IATA IMDG/IMO Not regulated Not regulated Not regulated Not regulated 14. Transport information 15. Regulatory information United States of America Inventory Component CAS No TSCA Silicon carbide 409-21-2 X TSCA Inventory notification Active-Inactive ACTIVE TSCA - EPA Regulatory Flags - Legend: TSCA US EPA (TSCA) - Toxic Substances Control Act, (40 CFR Part 710) X - Listed '-' - Not Listed TSCA - Per 40 CFR 751, Regulation of Certain Chemical Substances & Mixtures, Under TSCA Section 6(h) (PBT) Not applicable TSCA 12(b) - Notices of Export Not applicable International Inventories Canada (DSL/NDSL), Europe (EINECS/ELINCS/NLP), Philippines (PICCS), Japan (ENCS), Japan (ISHL), Australia (AICS), China (IECSC), Korea (KECL). Component Silicon carbide CAS No 409-21-2 DSL X NDSL - EINECS 206-991-8 PICCS X ENCS X ISHL X AICS X IECSC X KECL KE-31031 KECL - NIER number or KE number (http://ncis.nier.go.kr/en/main.do) U.S. Federal Regulations ______________________________________________________________________________________________ Page 5 / 7 Revision Date 13-Oct-2023 Carborundum ______________________________________________________________________________________________ SARA 313 Not applicable SARA 311/312 Hazard Categories See section 2 for more information CWA (Clean Water Act) Not applicable Clean Air Act Not applicable OSHA - Occupational Safety and Health Administration Not applicable CERCLA Not applicable California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Component Silicon carbide Massachusetts X U.S. Department of Transportation Reportable Quantity (RQ): DOT Marine Pollutant DOT Severe Marine Pollutant U.S. Department of Homeland Security New Jersey X Pennsylvania X Illinois X Rhode Island X N N N This product does not contain any DHS chemicals. Other International Regulations Mexico - Grade No information available Authorisation/Restrictions according to EU REACH Component CAS No Silicon carbide 409-21-2 REACH (1907/2006) REACH (1907/2006) REACH Regulation (EC Annex XIV - Substances Annex XVII - Restrictions 1907/2006) article 59 Subject to Authorization on Certain Dangerous Candidate List of Substances Substances of Very High Concern (SVHC) Use restricted. See item 28. (see link for restriction details) Use restricted. See item 75. (see link for restriction details) Safety, health and environmental regulations/legislation specific for the substance or mixture Component CAS No OECD HPV Persistent Organic Pollutant Ozone Depletion Potential Silicon carbide 409-21-2 Listed Not applicable Not applicable Restriction of Hazardous Substances (RoHS) Not applicable Contains component(s) that meet a 'definition' of per & poly fluoroalkyl substance (PFAS)? Not applicable ______________________________________________________________________________________________ Page 6 / 7 Revision Date 13-Oct-2023 Carborundum ______________________________________________________________________________________________ Other International Regulations Component CAS No Silicon carbide 409-21-2 Seveso III Directive Seveso III Directive (2012/18/EC) (2012/18/EC) Qualifying Quantities Qualifying Quantities for Major Accident for Safety Report Notification Requirements Not applicable Not applicable Rotterdam Convention (PIC) Basel Convention (Hazardous Waste) Not applicable Not applicable 16. Other information Prepared By Regulatory Affairs Thermo Fisher Scientific Email: EMSDS.RA@thermofisher.com Creation Date Revision Date Print Date Revision Summary 20-Apr-2010 13-Oct-2023 13-Oct-2023 This document has been updated to comply with the US OSHA HazCom 2012 Standard replacing the current legislation under 29 CFR 1910.1200 to align with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS). Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of SDS ______________________________________________________________________________________________ Page 7 / 7
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