pubs.acs.org/estengg Article Assessing Flow Rate and Nominal Pore Diameter as Parameters for Predicting the Removal of Microorganisms by Ceramic Water Filters Hem Pokharel, Zachary Shepard, and Vinka Oyanedel-Craver* Cite This: https://dx.doi.org/10.1021/acsestengg.0c00216 Downloaded via UNIV DE MONTREAL on March 2, 2021 at 18:55:11 (UTC). See https://pubs.acs.org/sharingguidelines for options on how to legitimately share published articles. ACCESS Metrics & More Read Online Article Recommendations sı Supporting Information * ABSTRACT: Ceramic water filters (CWFs) are manufactured worldwide using local materials and infrastructure. In this study, we assessed flow rate (FR) and nominal pore diameter (NPD) values as parameters to predict the microbial removal of CWFs. Two empirical models (flow rate model, FRM, and nominal pore diameter model, NPDM) were developed based on the log removal values (LRVs) for total coliform obtained from the operation of CWFs manufactured under controlled conditions in the United States. The proposed empirical models were validated using CWFs manufactured in Nepal and India. The models and principal component analysis (PCA) were used to identify materials and processes in CWF manufacturing with the highest impact on LRV. Our results showed that both the FRM and NPDM have a good predictive capability with high coefficients of determination, R2, and statistical significance (p) values less than 0.05. PCA showed that the burnout material was the most important variable in the manufacturing process. Even though both models are appropriate to predict LRV from a CWF, the FRM and NPDM could have slightly different applications at CWF factories. The FRM could be used to predict LRVs of CWFs manufactured in an already operational factory as it fits with existing quality control procedures, such as measurement of flow rate. We propose that the NPDM could be applied in the research and performance enhancement of CWFs as additional filter characteristics can be tested for the potential to improve LRV. The use of either model could help factories improve the removal of bacteria by their CWFs. KEYWORDS: Ceramic water filter, nominal pore diameter, point of use water treatment, quality control 1. INTRODUCTION Point-of-use (POU) water treatment technologies are simple, socially acceptable, and low-cost technologies that reduce the prevalence of waterborne pathogens in underserved communities.1−4 These devices are typically made with locally available materials (clay and burnout material) and infrastructure (mills, hydraulic presses, kilns).5,6 Mechanical filtration is the primary mechanism in CWFs, which means that microorganisms are physically prevented from reaching the filter effluent by small, tortuous pores.7−10 The microbial removal efficiency of a CWF varies depending on the properties of the local materials used.11−13 Most factories utilize flow rate measurements as a fast and low-cost method of quality controls, but this has no definitive relationship to microbiological removal performance.14−16 CWFs are ceramic microfiltration devices (depth filter) with a highly heterogeneous pore size, porosity, discharge area, tortuosity, raw material composition, and thickness.17 Pore size is considered one of the most critical parameters for determining turbidity and pathogen removal in porous water filters.18 The pores in the CWFs are formed during the firing stage when sawdust (or other combustible material) is incinerated producing small and interconnected void spaces creating a tortuous path.8,19,20 The pore size distribution of a © XXXX American Chemical Society CWF is affected by a number of variables, including burnout material size, quantity, type, clay composition, and application of the heat and pressure during manufacturing process.21,22 Characterization of the pore size distribution can be obtained using techniques such as scanning electron microscopy or mercury intrusion porosimetry.17 These tests cannot be performed at the CWF factory level due to their high cost and required equipment. The nominal pore diameter (NPD) in microfiltration membranes is usually defined in terms of the largest particle able to penetrate the membrane; it is 5−10 times smaller than the apparent pore diameter measured using direct microscopic examination of the membrane.23 The technique for calculating NPD could be applied at CWF factories as it is low cost and can be calculated using variables that can be easily measured with the infrastructure of the CWF factory. Received: November 12, 2020 Revised: February 14, 2021 Accepted: February 17, 2021 A https://dx.doi.org/10.1021/acsestengg.0c00216 ACS EST Engg. XXXX, XXX, XXX−XXX ACS ES&T Engineering pubs.acs.org/estengg Article Table 1. Range of Values for Manufacturing Parameters for CWFs Manufactured in the USA Parameters Range Sawdust range Sawdust sieve opening size Clay range Water range Pressure range Heat range 160−440 g <0.42 to >1.77 mm 560−840 g 270−550 g 20 psi (1000 lbs/50 in2) to 300 psi (15,000 lbs/50 in2) 590−1180 °C (cone 022 to cone 4) which temperature was increased 50 °C per hour until 120 °C. Then, the temperature increased at a rate of 120 °C per hour until reaching the desired maximum firing temperature. After reaching the maximum firing temperature, the CWFs were cooled to room temperature. Six parameters of CWF manufacturing were analyzed for their effect on LRV during this study: amounts of sawdust, clay, and water; sawdust sieve size opening, molding pressure, and maximum firing temperature. Each parameter was studied using a fit developed from the LRVs of at least four CWFs. All fired CWFs were visually inspected (for cracking or warping). CWFs that did not pass the visual inspection were not included in the tests. For those CWFs that passed, diameter (cm) was measured at two locations on the disks, and thickness (cm) was measured at four locations on the disks. These measurements were averaged to generate the measured diameters and thicknesses of the disks used in subsequent calculations. The disks were soaked in water to determine porosity, which was calculated by dividing the volume of water (mL) absorbed in half an hour of soaking (volume of void) by the volume of the disk (mL). Density was calculated by dividing the fired disk weight (g) by the disk volume (mL). After the weight and shape measurements, CWFs were placed at the bottom of a filter holder using wax O rings. The discharge diameter (cm) was measured at two locations on the disks to determine the discharge area. The flow rate (liters per hour, LPH) was measured twice with a constant head at 19 cm (maintained with a hand pump). Constant head was maintained by hand; water was added manually to keep a constant head volume. Variations in head height were low (about 14%) and were considered negligible for this experiment. Velocity was measured by dividing the flow rate by the discharge area of the CWFs. These measurements will be used later for developing the empirical models. The clay used to manufacture CWFs in Nepal and India was locally sourced. Both CWF factories in Nepal and India sieved clay and sawdust using 0.595 mm screens. The CWFs manufactured in Nepal and India used sawdust collected from nearby sawmills. The wood source of these mills is unknown. The clay, sawdust, and water mixtures were prepared using the same method used for the USA CWFs. However, instead of a hydraulic press, a screw press without a pressure gauge was used to press CWFs in Nepal and India. In both locations, pressed CWFs were dried using a method like the one used for the USA CWFs. The factory in Nepal used kerosene and sawdust for firing, while pit firing was used in India. For the Nepal and India operations, molding pressure and maximum firing temperature data were unavailable. The same visual inspections and measurements were performed in the Nepal and India factories as those described for the USA CWFs. CWFs were then shipped to the USA for testing. Filter Testing. Sudbury River water (about 19 L) was collected on the same day the test was conducted. After In this study, we present two empirical models based on the flow rate (FR) through the CWF and nominal pore diameter (NPD) of the ceramic. The purpose of these models is to predict the microbial removal of CWFs as a function of manufacturing variables or filter properties. The flow rate model (FRM) and nominal pore diameter model (NPDM) and principal component analysis were used to determine the most important manufacturing variables in the production of a CWF. The FRM and NPDM were validated using CWFs produced at factories in India and Nepal. The models will be able to assist CWF factories with quality control and development of new filter designs. While the models developed here will only be able to accurately predict the LRV of the filters used in this study, we provide the necessary information for CWF manufacturers to develop models applicable to their filters. 2. MATERIALS AND METHODS A total of 92 CWFs were used to develop the flow rate and nominal pore diameter empirical models. Of the 92 filters used in the testing, 76 were from the USA, 10 were from India, and 6 were from Nepal (the CWFs manufactured in India and Nepal were used for validation). During the production of the filters, the composition and firing conditions were varied to understand the effect of each manufacturing variable. These variables were categorized as raw materials (clay, sawdust, water content, and sawdust diameter), manufacturing (pressure during molding and temperature during firing), and geography (Sudbury, USA; Varanasi, India; and Thimi, Nepal). CWF Manufacturing. CWFs were manufactured under the ranges of conditions listed in Table 1. Table S1 contains the specific manufacturing location, materials, molding pressure, and firing temperature for each disk used in the testing. Sawdust was obtained from a sawmill in Hopkinton, MA. The exact type of sawdust is unknown, but the facility handles mostly pine and oak lumber. Red art clay was purchased from Braintree Pottery Facilities (Braintree, MA), and all USA CWFs were manufactured at Village Forward (previously Solutions Benefiting Life), a nonprofit organization in the Town of Sudbury, MA. Both clay and sawdust were sieved using a sieve with openings listed in Table S1 and then manually mixed for 10 min. After clay and sawdust were mixed, water was slowly added and mixed manually for 30 min. The amounts of sawdust, clay, and water are listed in Table S1. One kilogram of the mixture was then pressed into a disk-shaped mold (20 cm diameter and 8 cm height) using a hydraulic press that applied the pressures listed in Table S1. The pressed CWFs were dried indoors for a week protected from sunlight to ensure uniform drying. After drying for 1 week, they were placed in the sun from mornings to evenings and kept inside the facility at night for a second week. Dried CWFs were fired in a kiln. The firing program consisted of a 2 h drying period in B https://dx.doi.org/10.1021/acsestengg.0c00216 ACS EST Engg. XXXX, XXX, XXX−XXX ACS ES&T Engineering pubs.acs.org/estengg Article Figure 1. Data sets for establishing FRM and NPDM from USA manufactured disks. (a) LRV as a function of flow rate. (b) LRV as a function of NPD. Samples were grouped in 5 LPH or 1 μm intervals and averaged to generate the data points in (a) and (b), respectively. Error bars represent the standard deviation of the samples within the 5 LPH or 1 μm intervals. The data points here are used to establish the FRM and NPDM displayed in eqs 3 and 4 The calculated NPD determines the size of the particle (in this case the microorganism) permitted through the tortuous path of the CWF. This makes it an important factor in the determination of the log removal value (LRV) of the filter. The flow rate (FR) and nominal pore diameter (NPD) empirical models were built using the LRV of total coliform for the CWFs manufactured in the USA using an industrial grade red art clay and modifying the ratios of raw materials and the manufacturing parameters. This stage was also used to assess the impact of the manufacturing variables on the microbial removal performance as LRV. The variables studied here included raw materials (sawdust diameter, sawdust:water ratio, sawdust:clay ratio, and clay:water ratio) and manufacturing parameters (pressure during molding and firing temperature). The LRV of each scenario was plotted as a function of either NPD or FR (calculated based on the above equations), and the fit of the appropriate empirical model to the data points was determined. Principal component analysis (PCA), a modeling technique that can be utilized to find patterns in complex data sets, was used to determine the most important variable in the filter manufacturing process.28 The derived empirical models were then applied to LRV data collected from CWFs produced in Nepal and India. Regression analysis was used to determine the robustness of the fit and has been used widely in the literature for making predictions about drinking water quality.29−32 Three aspects of the fit were assessed: selection criteria (outcome measures, such as flow rate and NPD, on LRV predictability), selecting the predictor (efficiency, R2, residual), and assessing the accuracy of the prediction (standard error of the mean, SEM, and standard error estimate, SEE).33 The selection was later confirmed using PCA in all variables (included in the Supporting Information). collection, it was left to settle and reach room temperature for three hours. The average total coliform count at the Sudbury River during the research period was 1525 total coliform CFU with a range from 480 to 3480 total coliform CFU (only 4 days during the experimental period) as shown in the Table S2 of the Supporting Information. CWF holders were filled with the Sudbury River water to a level of 19 cm. Two 100 mL samples for total coliform counts were collected in clean, sterilized beakers from each CWF after two hours of operation. MColiblue broth (Millipore, MA) was used to determine the colony forming units (CFU) using an established methodology.24 Samples were incubated for 24 h at 25 °C. Unlike most locally produced CWFs, the CWFs here were not impregnated with colloidal silver since many previous reports have addressed its importance.25−27 Additionally, it has been shown that properties of the ceramic matrix are the main contributors to microbial removal for CWFs.7−10 Determination of FR and NPD. Equations 1 and 2 show the FR and NPD equations (respectively) used in this study. These equations were derived based on the information in Derivations 1 and 2 and Scheme 1, which can be found in the Supporting Information. FR = Q = − NPD = kA(ρgh) μL vμ ρgτ (1) (2) In eqs 1 and 2, FR and Q are variables for flow rate (cm3/s), k is the intrinsic permeability of the clay disk (cm2), A is the disk area (cm2), ρ is the water density (g/cm3), g is acceleration due to gravity (cm/s2), h is the height of the water over the disk cm), μ is the water viscosity (g/cm s), L is the disk width (cm), NPD is the nominal pore diameter (cm), v is the hydraulic conductivity of the water through the CWF (cm/s), and τ is the tortuosity (unitless). 3. RESULTS AND DISCUSSION Modeling LRV Using Flow Rate and NPD. All of the models shown in this study are based on the data presented in C https://dx.doi.org/10.1021/acsestengg.0c00216 ACS EST Engg. XXXX, XXX, XXX−XXX ACS ES&T Engineering pubs.acs.org/estengg Article Table 2. Error in Validation of the NPDM and FRM Using CWFs from India and Nepal Statistic NPDM India NPDM Nepal FRM India FRM Nepal Average error (%) SEE 13.8 0.38 10.1 0.11 20.2 0.41 9.3 0.11 Table S3, which contains the porosity, tortuosity, flow rate, pore size, and LRV values for each disk. Figure 1 shows the relationships between the NPD (Figure 1a) or FR (Figure 1b) and LRV. This LRV data were collected from 76 filters on CWFs manufactured in the USA. The LRV values were averaged at 1 μm and 5 LPH intervals for the NPD and FR models, respectively. There were five samples per 1 μm or 5 LPH interval, on average. The standard deviation (σ) of the LRV value was calculated at each interval. The LRV values plotted in Figure 1 were used to fit an empirical relationship between NPD or flow rate and LRV (eqs 3 and 4) LRVFRM = − 0.588ln(flow rate) + 3.47 (3) LRVNPDM = − 1.08ln(NPD) + 3.4 (4) the prediction. The values are reported in Table 2. The average error and SEE of the NPDM (11.9% and 0.25) were slightly lower than the FRM (14.8% and 0.26), indicating that the predictive capability of the NPDM was slightly better than the FRM. The predictive capacities in both types of models were better for Nepal CWFs than the CWFs made in India. Differences in microbial removal between these groups could be due to the local clays used the construction or differences in manufacturing practices at the two factories.11−13,35 CWF performance varies widely depending on where they were constructed.11−13 Overall, both models showed strong predictive capabilities with the NPDM being slightly better based on the average error and average SEE. In order to develop the FRM, CWFs were manufactured under a range of conditions that produced filters with flow rates of 5−25 L/h. These conditions were helpful in producing the models that were used in the study but are not necessarily representative of the conditions in the field. The acceptable range for flow rates in most CWF factories is 1−5 L/h.25 Previous studies analyzing the microbial removal of ceramic disks have used much lower flow rates (0.03−0.036 L/h) because the area of those disks (11.3−33.2 cm2) is much smaller than the disks used in the current study (314.2 cm2).25,26,36 The size of the disk filters used here increases the volume of throughput, which allows a comparison to the range of flow rates for ceramic pot filters manufactured in CWF factories. High flow rate filters, such as those used to create the FRM, have a lower LRV initially compared to filters with a standard flow rate.37 While the flow rates measured here may not be ideal for use in the field, they were essential for the establishment of the FRM. The use of filters with flow rates that are higher than what would usually be utilized in the field allowed us to capture trends in LRV as they relate to higher flow rates. The NPD range in these samples conform to pore sizes measured in previous studies, which range between 2 and 5 μm.19,20 However, in previous studies, the pore sizes were measured using mercury intrusion porosimetry, while here they are calculated using eq 2. This represents a range of pore sizes that are microbiologically relevant and can physically prevent microorganisms from reaching the effluent of the filter. The presented empirical FRM and NPDM could offer CWF manufacturers a framework to improve their filters at a low cost. The FRM and NPDM could have slightly different applications for CWF manufacturers. The FRM could be applied for quality control because it fits with procedures that are already in place. This model could be used to estimate LRV during the daily quality control tests. The FRM would be able to provide simple, low-cost, and fast estimation of LRV for daily factory operations. The NPDM would be more applicable for CWF factories that are adjusting their manufacturing practices to make improvements in filter performance. The application of this model allows CWF factories to predict how changing their manufacturing parameters will affect performance. Tortuosity is the main parameter in the NPDM. In the NPD equation (eq 2), tortuosity is the only variable that is related to the CWF. Tortuosity (Derivation 2, line 8, Supporting Information) is a These equations represent the flow rate model (FRM, eq 3) and the nominal pore diameter model (NPDM, eq 4). Both models satisfactorily fit the experimental data, with high R2 values and p < 0.05. Logarithmic curves had a better fit for the data compared to other model types (linear, exponent, and power) as shown in the Figures S4a and b of the Supporting Information. The entire data set was used to determine the most appropriate model type (Figure S1). Bins based on flow rate and pore size were used for the model shown in Figure 1 because this provides a more accurate prediction of LRV. Figure S2A and B show that predicting LRV using the bin method provides a more linear regression (R2 = 0.93−0.94) compared to using the entire data set (R2 = 0.53−0.55). The cutoff values for the FRM and NPDM (25 LPH and 5 μm, respectively) were selected based on the operational parameters at CWF manufacturing sites. Most CWF factories want their filters to have a flow rate ranging from 1 to 5 LPH and a pore size around 2 μm, so including points higher than 25 LPH and 5 μm in our model would not be applicable to filter manufacturers. The accuracy of the models was based on the standard deviation, SEM for each interval, percentage error, and the residuals of the sample results. The standard deviation (σ) describes the variability between individuals in a sample. SEM describes the uncertainty of how the sample mean represents the population mean.34 The average LRV standard deviation, SEM of LRV, average percentage error of LRV, and average residual for the FRM were 0.7, 0.22, 31%, and 0.18, respectively. Similarly, average LRV standard deviation, SEM of LRV, average percentage error of LRV, and average residual for the NPDM were 0.57, 0.21, 29%, and 0.14, respectively. Since the NPDM has lower values in each statistic described above, it is a more statistically valid method of predicting the LRV of the CWFs compared to the FRM. The plots of the residuals for both empirical models are shown in the Supporting Information (Figure S3). The FR and NPD empirical models were validated using 16 CWFs made in Nepal (n = 6) and India (n = 10). The validation data is shown in Figure S4. The average percentage error and SEE between the measured and the predicted LRV were calculated for both sets of CWFs (Nepal and India) and both models (NPDM and FRM) to determine the accuracy of D https://dx.doi.org/10.1021/acsestengg.0c00216 ACS EST Engg. XXXX, XXX, XXX−XXX ACS ES&T Engineering pubs.acs.org/estengg Article Figure 2. Effect of manufacturing variables on LRV plotted as a function of flow rate. These results are based on LRV measured for filters made in the USA with manufacturing parameters varied within the ranges listed in Table 1. Here, each panel represents a set of CWFs made by varying different parameters (Table 1). The parameters varied here are (a) sawdust diameter, (b) sawdust:water ratio, (c) clay:sawdust ratio, (d) clay:water ratio, (e) firing temperature, and (f) pressure during molding. Markers represent the LRV of a filter with a known flow rate. These data points are used to generate the lines of best fit, which are plotted in each panel. The equations and R2 and p values are also listed in each panel. Figure 3. Effect of manufacturing variables on LRV plotted as a function of nominal pore diameter (NPD). The filters used to generate these graphs were manufactured in the USA with manufacturing parameters varied within the ranges listed in Table 1. As in Figure 2, each panel represents a set of filters with varied manufacturing parameters presented in Table S1. The variables in the panels are (a) sawdust diameter, (b) sawdust:water ratio, (c) clay:sawdust ratio, (d) clay:water ratio, (e) firing temperature, and (f) pressure during molding. NPD was calculated for each filter and plotted on the axis. The measured LRV for each filter is then plotted in the figure based on its NPD. These data points are used to generate the lines of best fit, which are plotted in each panel. The equations and R2 and p values are listed in each panel. Manufacturers could also change the thickness of the filter by changing the pressing procedure or adding more raw material to each filter. Changes in any of these manufacturing parameters would affect the tortuosity of the filters, which would influence the NPD and LRV. The model would allow factories to predict how altering the raw materials in their function of porosity, C2 (a dimensionless constant referring to the length of the tortuous flow path), and the thickness of the filter, L. These variables could change based on the manufacturing parameters. Alterations to the ratio of clay to sawdust or the grain size of the clay or sawdust could change the porosity and C2, which can have an effect on tortuosity (Derivation 2, line 8, Supporting Information). 25,38,39 E https://dx.doi.org/10.1021/acsestengg.0c00216 ACS EST Engg. XXXX, XXX, XXX−XXX ACS ES&T Engineering pubs.acs.org/estengg filters would affect the LRV. This would save time and money by preventing a “trial and error” approach to improving LRV. In order to apply any of the models discussed here in the field, CWF manufacturers would need to generate filters with a range of flow rate or NPD. The factories would then measure the microbial removal of the filters and develop their own versions of eqs 3 and 4. After adaptation with factory-specific data, the models would be accurate for the filters produced at the specific CWF factory. Once equations specific to the CWF factory were developed, they could be used to determine microbial removal from flow rate or NPD of new filters. Effects of Manufacturing Parameters. Figures 2 and 3 show the effect of manufacturing variables on LRV. The raw data for these figures can be found in Table S3. Samples generated in each set were divided into bins based on their flow rate (Figure 2) or NPD (Figure 3). The plots generated by the collected data were then compared to either the NPDM or FRM results. The best R2 values for both models were obtained in the variables that include sawdust (sawdust diameter, sawdust:water ratio, or clay:sawdust ratio). The sawdust diameter showed the highest fit with respect to LRV: R2 = 0.99 for the NPDM (Figure 2a) and R2 = 0.97 (Figure 3a) for the FRM. PCA (Figure S5a−f) shows that the sawdust percentage and diameter had more of an impact determining the LRV of the CWFs compared to the other manufacturing variables. Figure 3 shows that the NPDM is most strongly correlated to variables involving the burnout material: sawdust diameter, sawdust:water ratio, and sawdust:clay ratio. The link between pore size, burnout material, and LRV has been demonstrated in previous studies, but this is the first mathematical relationship demonstrated.25,38,39 PCA analysis (Figure S5) showed that the sawdust diameter and percentage was the most important variable for the LRV. Changing the size and quantity of the sawdust will have the largest impact on the LRV by altering the pore structure of the CWF. CWFs utilizing less sawdust or sawdust of a smaller grain size have a higher LRV because they have smaller pores.8,35−37 A smaller average pore size increases the likelihood of microorganisms adsorbing to or becoming trapped in the ceramic.7,14,25,36,40 Every CWF factory utilizes a unique set of raw materials and manufacturing procedures in the construction of their filter. Some factories use burnout materials that were not used in this study, such as rice husks, and every factory uses a different source of clay.7,25,40 The unique set of construction materials and procedures used at each factory limits the applicability of the models developed in our study. This study is limited to demonstrating the changes in LRV caused by sawdust and red art clay. The principal components in their filters may also be different if the raw materials are significantly different compared to those used in our study. For example, the use of rice husks instead of sawdust could change the results as rice husks have different properties compared to sawdust. Our results can be used to understand trends, such as the importance of the grain size and amount of sawdust over manufacturing procedures (such as firing temperature and molding pressure) for microbial removal, but cannot be related to specific changes in LRV at filter factories without prior optimization. Article NPD- and FR-based models. These models can be applied once they have been adapted with factory-specific microbial removal data. The validation of the models using filters produced in India and Nepal demonstrates that these models may be widely applicable. While the NPDM is more accurate, we would recommend the FRM for application for quality control at CWF factories because it works with the existing procedures. This model could be useful for CWF factories that need an easy method to estimate LRV for their filters using information they are already measuring (flow rate). The NPDM could be useful for CWF manufacturers who wish to redesign their filters to improve the LRV. In this application, the accuracy of the model will help guide improvements in the filter design. This model also highlights the importance of the pore diameter in the removal of microorganisms. Control over the NPD will help CWF factories control their LRV. PCA and model results show that the raw materials used in the construction of the filters are more likely to effect LRV compared to differences in the manufacturing practices. CWF manufacturers should focus on engineering the burnout materials to make targeted improvements in LRV. The results of this study have the potential to improve the quality of CWFs produced and therefore available water quality and related health impacts in underserved communities. ■ ASSOCIATED CONTENT sı Supporting Information * The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsestengg.0c00216. Raw data for manufacturing and bacterial removal, derivations for equations used here (with helpful schematics), and plots of residuals, principal component analysis information, and regressions for predicted vs actual LRV (PDF) ■ AUTHOR INFORMATION Corresponding Author Vinka Oyanedel-Craver − Civil and Environmental Engineering, University of Rhode Island, Kingston, Rhode Island 02881, United States; Email: craver@uri.edu Authors Hem Pokharel − Civil and Environmental Engineering, University of Rhode Island, Kingston, Rhode Island 02881, United States; Drinking Water, Bureau of Water Resources, Massachusetts Department of Environmental Protection, Springfield, Massachusetts 01103, United States; orcid.org/0000-0001-6641-0334 Zachary Shepard − Civil and Environmental Engineering, University of Rhode Island, Kingston, Rhode Island 02881, United States; orcid.org/0000-0003-0079-8537 Complete contact information is available at: https://pubs.acs.org/10.1021/acsestengg.0c00216 Notes The authors declare no competing financial interest. ■ ACKNOWLEDGMENTS This work was funded by NSF CBET Award No. 1350789. This work was partially funded by the Rhode Island Water Resources Center. Special thanks to Village Forward, formerly Solutions Benefiting Life, for their assistance and support 4. CONCLUSIONS In this study, we developed two empirical models that could be used to evaluate and predict the performance of CWFs: the F https://dx.doi.org/10.1021/acsestengg.0c00216 ACS EST Engg. XXXX, XXX, XXX−XXX ACS ES&T Engineering pubs.acs.org/estengg (17) Youmoue, M.; Fongang, R. T.; Sofack, J.; Kamseu, E.; Melo, U. C.; Tonle, I. K.; Leonelli, C.; Rossignol, S. Design of ceramic filters using Clay/Sawdust composites: Effect of pore network on the hydraulic permeability. Ceram. Int. 2017, 43 (5), 4496−4507. (18) Madaeni, S. The application of membrane technology for water disinfection. Water Res. 1999, 33 (2), 301−308. (19) Oyanedel-Craver, V. A.; Smith, J. A. Sustainable colloidal-silverimpregnated ceramic filter for point-of-use water treatment. Environ. Sci. Technol. 2008, 42 (3), 927−933. 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