YMCA of Hong Kong Christian College Summer Assignments F.3 CHEMISTRY 75 Marks Total no. of pages: 19 Question-Answer Book Name: ______________________ Class: ________ Class No.: _____ Set: 3.1 / 3.2 / 3.3 GENERAL INSTRUCTIONS 1. There are TWO sections, A and B, in this assignment. 2. Section A consists of multiple-choice questions, while Section B contains short questions. 3. Answers to Section A should be marked on the Multiple-choice Answer Sheet while answers to Section B should be written in the spaces provided in Question-Answer Book. 4. A Periodic Table is printed on the last page. You may use it if necessary. Explanation F.3 Chemistry Summer Assignments – 1 – SECTION A: MULTIPLE CHOICE QUESTIONS (25 marks, 1 mark @) Choose the best answer for each question. Candidates may refer to the Periodic Table printed on the last page. 1. A B C D The above figure shows an experiment to compare the rate of diffusion between ammonia gas and hydrogen chloride gas. At which point will the white fumes of ammonium chloride first formed? 2. Solid carbon dioxide changes directly into a gas under suitable conditions of temperature and pressure. Carbon dioxide gas moves from a high concentration to a low concentration. Which row names these two processes? 3. Changing from solid to gas Moving from a high concentration to a low concentration A Evaporation Brownian motion B Evaporation Diffusion C Sublimation Brownian motion D Sublimation Diffusion A mixture of ice and water is left to stand and the ice melts. Which row describes what happens as the ice is melting? Temperature of mixture Energy changes A Increases Average kinetic energy of particles increases B Increases Energy is used to overcome attractive forces C Stays the same Average kinetic energy of particles increases D Stays the same Energy is used to overcome attractive forces F.3 Chemistry Summer Assignments – 2 – 4. Which particle diagrams shows the correct arrangement of particles when argon gas is cooled to below its boiling point, but above its melting point? A. B. C. 5. D. Which row about a change of state is correct? Change of state Energy change Process A Solid à Liquid Heat given out Melting B Gas à Liquid Heat taken in Evaporation C Solid à Gas Heat taken in Sublimation D Liquid à Solid Heat given out Condensing 6. Which of the following statement best describes a solute? A. The mixture of different solvents. B. The only substance that is inside a saturated solution. C. The compound of a solution and a solvent. D. The substance that dissolves in a solvent. 7. Which of the following procedures is most suitable for getting sodium chloride from a muddy sea water? A. Filtration à Evaporation à Saturated solution à Crystallisation B. Evaporation à Dilute solution à Concentrated solution à Fractional Distillation C. Filtration à Evaporation à Saturated solution à Simple distillation D. Evaporation à Concentrated solution à Saturated solution à Evaporation until dryness F.3 Chemistry Summer Assignments – 3 – 8. Which process is used to separate oxygen from liquid air? A. Chromatography B. Distillation C. Filtration D. Fractional Distillation 9. Different methods of separation rely on substances having different properties. Which property does distillation make use of? A. Boiling point B. Colour C. Particle size D. Solubility in different solvents 10. F.3 Chemistry Summer Assignments – 4 – 11. 12. F.3 Chemistry Summer Assignments – 5 – 13. Which of the following comparisons between iron(II) sulphide and a mixture of iron and sulphur is correct? Iron(II) sulphide A mixture of iron and sulphur A elements in it does not have a fixed ratio elements in it have a fixed ratio B attracted to magnet only iron is attracted to magnet C does not have a sharp melting point has a sharp melting point D constituents can be separated by chemical constituents can be separated by methods physical methods 14. 15. F.3 Chemistry Summer Assignments – 6 – 16. The following diagram shows the structure of an atom: Which of the following combinations is correct? Number of protons Period in periodic table Number of neutrons A 9 2 10 B 9 7 10 C 10 2 9 D 10 7 9 17. 18. Which of the following statements concerning an 131I atom and a 131Xe atom is / are correct? (1) They have the same number of protons. (2) They have different numbers of neutrons. (3) They have different numbers of outermost shell electrons. A. B. C. D. (1) only (2) only (1) and (3) only (2) and (3) only F.3 Chemistry Summer Assignments – 7 – 19. Which of the following statements concerning “atom” is correct? A. B. C. D. 20. All atoms do not carry net charges Mass is evenly distributed within an atom. All atoms consist of protons, neutrons and electrons. For all elements, atoms of the same element have the same mass number. Which statement about the trends shown by the elements of Period 3 in the periodic table is not correct? A. The elements become less metallic across the period. B. The group number increases across the period. C. The number of electron shells increases across the period. D. The number of outer electrons increases across the period. 21. 22. Metal X reacts with non-metal Y to form an ionic compound with the formula X2Y. Which statements are correct? (1) X is in Group I of the periodic table. (2) X is in Group II of the periodic table. (3) Y is in Group VI of the periodic table. (4) Y is in Group VII of the periodic table. A. B. C. D. (1) and (3) only (1) and (4) only (2) and (3) only (2) and (4) only F.3 Chemistry Summer Assignments – 8 – 23. The chemical formula of sodium borate is Na3BO3. The chemical formula of calcium borate is A. CaBO3 B. Ca2BO3 C. Ca3(BO3)2 D. Ca2(BO3)3 24. 25. Elements X and Y form an ionic compound with chemical formula X2Y. If the ion of X and the ion of Y have the same electronic arrangement, which of the following may this compound be? A. Lithium oxide B. Aluminium oxide C. Potassium sulphide D. Magnesium chloride END OF SECTION A F.3 Chemistry Summer Assignments – 9 – SECTION B: SHORT QUESTIONS (50 marks) Answer ALL questions. Write your answers in the spaces provided. 1. (a) Carbon disulfide is a liquid at room temperature and pressure. (5 marks) Describe the separation and motion of the particles in carbon disulfide liquid. Separation ________________________________________________________________ [1] Motion ___________________________________________________________________ [1] (b) ____________________________________________________________________________ ____________________________________________________________________________ _________________________________________________________________________ [3] F.3 Chemistry Summer Assignments – 10 – 2. X is a solid at room temperature and pressure, the heating curve of X is shown below: (3 marks) (a) Suggest a temperature range that X will exist as a liquid state. _____________________________________________________________________ [1] (b) Suggest the process occurred at 90oC for substance X. _____________________________________________________________________ [1] (c) Explain whether solid X is pure. _____________________________________________________________________ [1] F.3 Chemistry Summer Assignments – 11 – 3. Fractional distillation is always used in the industry for the separation of crude oil. (4 marks) The simplified table below shows the properties of the components inside crude oil. Physical Property Components of crude oil Boiling Point (°C) Carbon chain length Colour Physical state Petrol 40 5-8 Clear / Pale yellow Liquid Kerosene 180 10-16 Pale yellow Liquid Natural gas -161 1-4 Colourless Gas Bitumen 340 > 50 Black Solid A fractionating column is shown below: x y z Bitumen (a) Which physical property is used to separate substances in fractional distillation? _________________________________________________________________________ [1] (b) Using the table provided above, match the components of crude oil obtained in the fractionating column located as x, y, z. Petrol: _________________ [1] Kerosene: ________________ [1] Natural gas: _________________ [1] F.3 Chemistry Summer Assignments – 12 – 4. Water is an important chemical. It can be obtained in the laboratory from sea water. A student performs a sequence of steps to extract water from sea water. (7 marks) Step (a) (i) Procedure I Remove any insoluble substances from sea water. II Pour the resulting solution from step I to a round-bottomed flask. III Perform suitable process on the solution from step II and collect the resulting liquid from the condenser named ‘S’. IV Check whether ‘S’ is water. V Check whether ‘S’ is pure. Name the process involved in Step I. _________________________________________________________________ [1] (ii) Draw a labelled set-up for the process involved in Step I. [3] (b) Name the process involved in step III. _____________________________________________________________________ [1] (c) How can the student check that ‘S’ is water? _____________________________________________________________________ [1] (d) What can the student observe in the round-bottomed flask finally if the solution inside is heated for a very long time? _____________________________________________________________________ [1] F.3 Chemistry Summer Assignments – 13 – 5. Chromatography can be used to identify amino acids from a sample of protein. (7 marks) The diagram shows the chromatogram obtained when four samples of amino acids were analysed. The paper was sprayed with ninhydrin. 2cm 40cm 4cm (a) Why is the origin line drawn in pencil? _____________________________________________________________________ [1] (b) Which amino acids could possibly be the same? _____________________________________________________________________ [1] (c) Which amino acid sample contains more than one amino acid? Explain your answer. Sample _________________________________________________________________ Explanation______________________________________________________________ ____________________________________________________________________ [2] (d) Suggest why it is necessary to spray the chromatogram with ninhydrin. _____________________________________________________________________ [1] (e) The Rf value of Amino acid 1 is 0.75. What is the distance travelled by amino acid 1 from the origin? ________________________________________________________________________ ____________________________________________________________________ [2] F.3 Chemistry Summer Assignments – 14 – 6. (a) Define the term ‘Isotopes’. ________________________________________________________________________ _____________________________________________________________________ [2] (b) Rubidium (Atomic number = 37) has 2 stable isotopes 85Rb and 87Rb. (Given that the relative atomic mass of Rb = 85.5) Calculate the relative abundance of 87Rb. ________________________________________________________________________ ________________________________________________________________________ ________________________________________________________________________ _____________________________________________________________________ [2] 7. The diagram shows the positions of some elements in the Periodic Table. (5 marks) Group Period I II III IV V VI VII 0 2 Li Be B C N O F Ne 3 Na Mg Al Si P S Cl Ar 4 K Ca Br (a) Complete the following sentence: The elements in the Periodic Table are arranged in order of _________________________ _________________________________________________________________________ [1] (b) Suggest why group 0 elements seldom form compounds. _________________________________________________________________________ [1] (c) What is the similarity of the atoms in the period 4? _________________________________________________________________________ [1] (d) What is the similarity of the atoms in the group IV? _________________________________________________________________________ [1] (e) What is the electronic configuration of a bromine atom? 2, 8, ______, ______ [1] F.3 Chemistry Summer Assignments – 15 – 8. Draw the electron diagram for the compounds formed by the following elements. Show only the outermost electrons. (a) Carbon + Sulphur (4 marks) (b) Rubidium + Iodine 9. Complete the following table. (5 marks, 1 mark each) Name Ammonium Phosphate (ii) Chemical formula (i) Al2(CO3)3 Ni(OH)2 Potassium Dichromate (iii) (iv) Cu(NO3)2 F.3 Chemistry Summer Assignments Colour of ions – 16 – (v) 10. A brand of fertiliser contains only ammonium nitrate (NH4NO3) and potassium chloride (KCl). This experiment was performed to find out the percentage by mass of NH4NO3 in this fertiliser. The set-up used is shown below: (a) The potassium hydroxide, KOH(aq), was slowly added to the fertiliser and the mixture was heated gently. The NH4NO3(s) in the fertiliser will react with the KOH(aq) under heat to form ammonia gas, NH3(g), water, H2O(l) and potassium nitrate (KNO3). Write the balanced equation for the chemical reaction involved. (1 mark) (b) The ammonia gas, NH3(g), liberated from the reaction between NH4NO3 and KOH was first cooled when passing through the water condenser, and then passed through an inverted funnel to a solution containing 0.0485 mol of excess HCl. All of the ammonia gas reacts with HCl to form ammonium chloride (NH4Cl), write the chemical equation involved. (1 mark) F.3 Chemistry Summer Assignments – 17 – (c) The remaining HCl in (b) will react with 41cm3 of 0.400 moldm-3 NaOH for complete reaction according to the following equation: HCl + NaOH à NaCl + H2O Remaining Calculate the number of moles of the remaining HCl. (1 mark) (d) Calculate the number of moles of HCl used to react with NH3(g) in part (b). (1 mark) (e) Calculate the mass of NH4NO3(s) reacted in part (a). (1 mark) (f) Calculate the percentage by mass of NH4NO3(s) in this fertiliser. (1 mark) END OF SECTION B – THE END – F.3 Chemistry Summer Assignments – 18 – F.3 Chemistry Summer Assignments – 19 –