--`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Welding of Stainless Steels i Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Compiled/Edited by Richard D. Campbell, P.E. Welding Solutions, Inc., Broomfield, CO 550 N.W. LeJeune Road, Miami, Florida 33126 NOTE: Although care was taken in choosing and presenting the data in this guide, AWS cannot guarantee that it is error free. Further, this guide is not intended to be an exhaustive treatment of the topic and therefore may not include all available information, particularly with respect to safety and health issues. By publishing this guide, AWS does not insure anyone using the information it contains against any liability or injury to property or persons arising from that use. ii Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- © 1999 by American Welding Society. All rights reserved Printed in the United States of America Table of Contents --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Chapter 1—Definitions........................................................................................................1 Chapter 2—Introduction to Stainless Steels and Types of Stainless Steels .........................5 Chapter 3—Stainless Steel Filler Materials.......................................................................17 Chapter 4—Preweld Cleaning and Preparation of Stainless Steels ...................................41 Chapter 5—Welding and Cutting of Stainless Steels.........................................................43 Chapter 6—Postweld Cleaning of Stainless Steels............................................................65 Chapter 7—Heat Treatments of Stainless Steels ...............................................................67 Chapter 8—Weld Discontinuities and Defects in Stainless Steels ....................................71 Chapter 9—Stainless Steels in Welding Codes and Other Standards ................................83 Chapter 10—Safety and Health Considerations in Welding of Stainless Steels................91 References and Other Publications Available from AWS .................................................93 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS iii Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT List of Tables Table Page Table 3-7 Recommended Filler Metals for Welding Austenitic Stainless Steels ................................................................................................ 30 3-8 Recommended Filler Metals for Welding Precipitation-Hardening Stainless Steels ................................................................................. 31 3-9 Suggested Filler Metals for Welds Between Dissimilar Austenitic Stainless Steels ................................................................................. 32 3-10 Compositions of Silver Filler Metals for Brazing of Stainless Steels 33 3-11 Characteristics of Silver Filler Metals for Brazing of Stainless Steels ................................................................................................ 35 3-12 Compositions of Nickel and Cobalt Filler Metals for Brazing of Stainless Steels ................................................................................. 37 3-13 Characteristics of Nickel and Cobalt Filler Metals for Brazing of Stainless Steels ................................................................................. 38 3-14 Compositions of Gold Filler Metals for Brazing of Stainless Steels. 39 3-15 Characteristics of Gold Filler Metals for Brazing of Stainless Steels 39 Base Metal Compositions (Chapter 2) 2-2 2-3 2-4 2-5 2-6 2-7 2-8 --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- 2-1 Chemical Compositions of Typical Wrought Austenitic Stainless Steels .................................................................................................. 7 Chemical Compositions of Typical Cast Austenitic Stainless Steels . 8 Chemical Compositions of Typical Superaustenitic Stainless Steels.. 9 Chemical Compositions of Typical Ferritic Stainless Steels ........... 11 Chemical Compositions of Typical Superferritic Stainless Steels... 12 Chemical Compositions of Typical Martensitic Stainless Steels..... 13 Chemical Compositions of Typical Duplex Stainless Steels ........... 15 Chemical Compositions of Typical Precipitation-Hardening Stainless Steels................................................................................. 16 Filler Metal/Electrode Compositions (Chapter 3) 3-1 3-2 3-3 3-4 3-5 3-6 Page Chemical Composition Requirements for Stainless Steel Shielded Metal Arc Welding Electrodes......................................................... 18 Types of Welding Current and Positions of Welding....................... 20 Chemical Composition Requirements for Bare Stainless Steel Welding Electrodes and Rods .......................................................... 21 Chemical Composition Requirements for Stainless Steel Flux Cored Arc Welding and Flux Cored Gas Tungsten Arc Welding Filler Metals ..................................................................................... 24 External Shielding Medium, Polarity, and Welding Process ........... 27 Chemical Composition Requirements for Stainless Steel Consumable Inserts.......................................................................... 28 Welding Processes (Chapter 5) 5-1 Typical Groove Weld Joint Designs for Austenitic Stainless Steels 45 5-2 GMAW Globular-to-Spray Transition Currents for a Variety of Electrodes......................................................................................... 47 5-3 Typical Arc Voltages for GMAW of Various Metals ....................... 48 5-4 GMAW Shielding Gases for Spray Transfer.................................... 49 5-5 GMAW Shielding Gases for Short Circuiting Transfer ................... 50 iv Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table Page Table 5-6 Typical Conditions for GMAW of Austenitic Stainless Steel Using a Spray Arc in the Flat Position ............................................ 51 5-7 Typical Conditions for GMAW of Austenitic Stainless Steel Using a Short Circuiting Arc ........................................................... 51 5-8 Typical PAW Conditions for Butt Joints in Stainless Steel.............. 52 5-9 Typical PAW Conditions for Welding Stainless Steels—Low Amperage......................................................................................... 53 5-10 Typical Self-Shielded FCAW Procedures for Stainless Steels Using Stainless Steel Electrodes ...................................................... 55 5-11 Typical Conditions for SAW Double-V-Groove Joints in Stainless Steel Plate......................................................................................... 57 5-12 A—Suggested Practices for Spot Welding Stainless Steels (U.S. Customary Units) ................................................................... 58 B—Suggested Practices for Spot Welding Stainless Steels (Metric Units) .................................................................................. 59 5-13 Welding Schedules Suggested for Seam Welding Stainless Steels.. 60 5-14 Projection Welding Design Data...................................................... 61 5-15 Manufacturing Process Data for Projection Welding Stainless Steels ................................................................................................ 62 Heat Treatments of Stainless Steels (Chapter 7) 7-1 Typical Preheat and Postweld Heat Treatment Requirements for Martensitic Stainless Steels.............................................................. 67 7-2 Postweld Heat Treatments for Martensitic Stainless Steels ............. 68 7-3 Recommended Solution Annealing Temperatures for Austenitic Stainless Steels ................................................................................. 68 7-4 Typical Heat Treatments for Precipitation-Hardening Stainless Steels ................................................................................................ 69 --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Page Welding Codes and Standards (Chapter 9) 9-1 Typical Stainless Steel Base Metal P-Number, S-Number, and M-Number Categories...................................................................... 85 9-2 F-Number Groupings of Welding Electrodes and Rods for Qualifications ................................................................................... 86 9-3 A-Number Classifications of Stainless Steel Ferrous Weld Metal for Procedure Qualifications ............................................................ 87 9-4 Preheat Requirements in Various Codes .......................................... 88 9-5 Postweld Heat Treatment Requirements in Various Codes.............. 89 v Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT List of Figures Figure Page Figure Chapter 3 Page 5-4 FCAW Electrode Feed Rate Versus Welding Current for Self-Shielding E308T-3...................................................................... 54 3-1 Standard Consumable Insert Designs ................................................ 29 Chapter 8 Chapter 5 8-1 Sensitization—Formation of Chromium Carbides at Grain Boundaries ......................................................................................... 72 8-2 Weld Metal Area, Heat-Affected Zone, and Base Metal ................... 72 8-3 Multi-Pass Weld ................................................................................. 73 8-4 Weld Penetration in Stainless Steels .................................................. 76 8-5 Weld Penetration in Mismatched Base Metals................................... 76 8-6 DeLong Diagram................................................................................ 78 8-7 Schaeffler Diagram ............................................................................ 79 8-8 Weld Dilution ..................................................................................... 80 --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- 5-1 Schematic Illustration of Weld Bead Produced with Arc Welds Made with the Same Parameters (Current, Voltage, and Travel Speed) on Different Materials............................................................ 43 5-2 Schematic Illustration of Distortion Produced with Arc Welds Made with the Same Parameters (Current, Voltage and Travel Speed) on Different Materials............................................................ 43 5-3 Typical Welding Currents Versus Wire Feed Speeds for 300 Series Stainless Steel Electrodes................................................. 46 vi Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Basic Safety Precautions Burn Protection. Molten metal, sparks, slag, and hot work surfaces are cuit. A separate connection is required to ground the workpiece. The workpiece should not be mistaken for a ground connection. produced by welding, cutting, and allied processes. These can cause burns if precautionary measures are not used. Workers should wear protective clothing made of fire-resistant material. Pant cuffs, open pockets, or other places on clothing that can catch and retain molten metal or sparks should not be worn. High-top shoes or leather leggings and fire-resistant gloves should be worn. Pant legs should be worn over the outside of high-top shoes. Helmets or hand shields that provide protection for the face, neck, and ears, and a head covering to protect the head should be used. In addition, appropriate eye protection should be used. Fumes and Gases. Many welding, cutting, and allied processes produce fumes and gases which may be harmful to health. Avoid breathing the air in the fume plume directly above the arc. Do not weld in a confined area without a ventilation system. Use point-of-welding fume removal when welding galvanized steel, zinc, lead, cadmium, chromium, manganese, brass, or bronze. No container should be presumed to be clean or safe. Do not weld or cut on any container, including piping, until it has been examined by, cleaned under the supervision of, and rendered safe by qualified personnel. Electrical Hazards. Electric shock can kill. However, it can be avoided. Live electrical parts should not be touched. The manufacturer’s instructions and recommended safe practices should be read and understood. Faulty installation, improper grounding, and incorrect operation and maintenance of electrical equipment are all sources of danger. Compressed Gas Cylinders. Keep caps on cylinders when not in use. Make sure that gas cylinders are chained to a wall or other structural support. Do not weld on cylinders. Radiation. Arc welding may produce ultraviolet, infrared, or light radiation. Always wear protective clothing and eye protection to protect the skin and eyes from radiation. Shield others from light radiation from your welding operation. All electrical equipment and the workpiece should be grounded. The workpiece lead is not a ground lead. It is used only to complete the welding cir- AWS recommends a personal copy of Arc Welding Safely, Fire Safety in Welding and Cutting, Recommended Safe Practices for the Preparation for Welding and Cutting of Containers and Piping, and Safety in Welding, Cutting, and Allied Processes. --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS vii Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Abbreviation Quick Reference Ag Al Ar B Be C Cd Co CO2 Cr Cu Fe He La Li Mg Mn Mo N Nb Ni O P S Se Si Sn Ta Ti V W Zn Zr Silver Aluminum Argon Boron Beryllium Carbon Cadmium Cobalt Carbon Dioxide Chromium Copper Iron Helium Lanthanum Lithium Magnesium Manganese viii Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Molybdenum Nitrogen Niobium Nickel Oxygen Phosphorus Sulfur Selenium Silicon Tin Tantalum Titanium Vanadium Tungsten Zinc Zirconium --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Chapter 1—Definitions The terms in this chapter are common words used in dealing with welding of stainless steels. See the latest revision of AWS A3.0, Standard Welding Terms and Definitions, for the standard terms used in the welding industry. Some other terms and definitions are standard metallurgical and corrosion terms from ASM International and the National Association of Corrosion Engineers (NACE). Cold crack—A crack which develops after solidification is complete. Corrosion—The deterioration of a metal by chemical or electrochemical reaction with its environment. Consumable insert—Filler metal that is placed at the joint root before welding, and is intended to be completely fused into the joint root to become part of the weld. Air carbon arc cutting (CAC-A)—A carbon arc cutting process variation that removes molten metal with a jet of air. Crater crack—A crack formed in the crater or end of a weld bead, typically a form of a hot crack. Austenite—A nonmagnetic phase of steel with a face-centered cubic (FCC) structure. Crevice corrosion—Corrosion caused by the concentration of corrodent along crevices. Austenitic stainless steel—A stainless steel that contains chromium, nickel, and sometimes manganese, which produce austenite. Defect—A discontinuity or discontinuities that by nature or accumulated effect (for example total crack length) render a part or product unable to meet minimum applicable standards or specifications. The term designates rejectability. --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Autogenous weld—A fusion weld made without filler metal. Base metal—The metal or alloy that is welded. Buttering—A surfacing variation that deposits surfacing metal on one or more surfaces to provide metallurgically compatible weld metal for the subsequent completion of the weld. Delayed crack—A nonstandard term for cold crack caused by hydrogen embrittlement. Carbon arc cutting (CAC)—An arc cutting process that uses a carbon electrode. Dilution—The change in chemical composition of a welding filler metal caused by the admixture of the base metal or previous weld metal in the weld bead. Carburizing flame—A reducing oxyfuel gas flame in which there is an excess of fuel gas, resulting in a carbon-rich zone extending around and beyond the cone. Discontinuity—An interruption of the typical structure of a material, such as a lack of homogeneity in its mechanical, metallurgical, or physical characteristics. A discontinuity is not necessarily a defect. Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 1 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Duplex stainless steel—A stainless steel that contains chromium plus other alloying elements, designed to produce a duplex structure at room temperature of a mixture of austenite and ferrite, austenite and martensite, etc. Fusion zone—The area of base metal melted as determined on the cross section of a weld. Gas metal arc welding (GMAW)—An arc welding process that uses an arc between a continuous filler metal electrode and the weld pool. The process is used with shielding from an externally supplied gas. Electrode—A component of the electrical circuit that terminates at the arc, molten conductive slag, or base metal. Gas tungsten arc welding (GTAW)—An arc welding process that uses an arc between a tungsten electrode (nonconsumable) and the weld pool. The process is used with shielding gas. Electron beam welding (EBW)—A welding process that produces fusion (coalescence) with a concentrated beam, composed primarily of highvelocity electrons, impinging on the joint. Heat-affected zone (HAZ)—The portion of the base metal whose mechanical properties or microstructure have been altered by the heat of welding. Ferrite—A magnetic phase of steel with a body-centered cubic (BCC) structure. Heliarc welding—A nonstandard term for gas tungsten arc welding. Ferrite number (FN)—An arbitrary, standardized value designating the ferrite content of an austenitic stainless steel weld metal. Hot crack—A crack formed at temperatures near the completion of solidification. Ferritic stainless steel—A stainless steel that contains chromium (and often molybdenum), which produce ferrite. Hydrogen crack—Another term for cold crack. Inert gas—A gas that normally does not combine chemically with materials. Flux cored arc welding (FCAW)—An arc welding process that uses an arc between a continuous filler metal electrode and the weld pool. The process is used with shielding gas from a flux contained within the tubular electrode, with or without additional shielding from an externally supplied gas. Intergranular corrosion—Corrosion occurring along grain boundaries, with little attack on the surrounding grains. Fusion welding—Any welding process that uses fusion of the base metal to make the weld. Laser beam cutting (LBC)—A thermal cutting process that severs metal by locally melting or vaporizing with the heat from a laser beam. --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Filler metal—The metal or alloy to be added in making a welded joint. Interpass temperature—In a multipass weld, the temperature of the weld area between weld passes. 2 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Plasma arc welding (PAW)—An arc welding process that uses a constricted arc between a nonconsumable electrode and the weld pool (transferred arc) or between the electrode and the constricting nozzle (nontransferred arc). Shielding is obtained from the ionized gas issuing from the torch, which may be supplemented by an auxiliary source of shielding gas. Laser beam welding (LBW)—A welding process that produces fusion (coalescence) with the heat from a laser beam impinging on the joint. Martensite—A hard, brittle phase of steel with a body-centered tetragonal (BCT) structure. Martensitic stainless steel—A stainless steel that contains chromium and carbon, which produce martensite. Postheating (Postweld heat treatment)—The application of heat to an assembly after welding. MIG Welding—A nonstandard term for gas metal arc welding. Precipitation-hardening stainless steel—A stainless steel that contains chromium plus other alloying elements designed to produce a hardened structure by precipitation of constituents. The main structure can be austenite, ferrite, or martensite. Oxidizing flame—An oxyfuel gas flame in which there is an excess of oxygen, resulting in an oxygen-rich zone extending around and beyond the cone. Oxyfuel gas cutting (OFC)—A group of oxygen cutting processes that use heat from an oxyfuel gas flame. --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Preheat—The heat applied to the base metal to attain and maintain preheat temperature. Oxyfuel welding (OFW)—A group of welding processes that produces fusion (coalescence) of workpieces by heating them with an oxyfuel gas flame. Resistance welding (RW)—A group of welding processes that produces fusion (coalescence) of the faying surfaces with the heat obtained from resistance of the workpieces to the flow of the welding current in a circuit of which the workpieces are a part, and by the application of pressure. Passivation—The changing of a chemically active surface of stainless steel to a much less reactive state. Formation of a chromium-rich oxide layer, which is passive to corrosion or further oxidation. Sensitization—In austenitic stainless steels, precipitation of chromium carbides along grain boundaries in the temperature range of 800–1500°F (427–816°C), which leaves the grain boundaries depleted of chromium and susceptible to intergranular corrosion. Pitting corrosion—Localized corrosion occurring in the form of cavities or pits. Plasma arc cutting (PAC)—An arc cutting process that uses a constricted arc and removes the molten metal with a high-velocity jet of ionized gas issuing from the constricting orifice. Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Shielded metal arc welding (SMAW)—An arc welding process with an arc between a covered electrode and the weld pool. The process is used 3 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Submerged arc welding (SAW)—An arc welding process that uses an arc or arcs between a bare metal electrode or electrodes and the weld pool. The arc and molten metal are shielded by a blanket of granular flux on the workpieces. The process is used with filler metal from the electrode and sometimes from a supplemental source (such as the flux). with shielding from the decomposition of the electrode covering and with filler metal from the electrode. --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Stabilized stainless steels—Stainless steels that contain niobium, tantalum and/or titanium, which form carbides that are more stable than chromium carbides, thus avoiding sensitization. TIG welding—A nonstandard term for gas tungsten arc welding. Stainless steel—Steels that contain a minimum of 10.5–12% chromium, depending on classification. Stick electrode welding—A nonstandard term for shielded metal arc welding. Weld (arc)—A localized coalescence (fusion) of metals produced by heating the metals to the welding temperature, with or without the use of filler metals. Stress-corrosion cracking (SCC)—Failure of metals by cracking under combined action of corrosion and stress, residual or applied. Welding rod—A form of welding filler metal, normally packaged in straight lengths, that does not conduct the welding current. 4 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Chapter 2—Introduction to Stainless Steels and Types of Stainless Steels What are Stainless Steels? Classification AISI Series Stainless steels are steels (iron-based alloys) that contain a minimum of approximately 10.5 wt.% chromium (sometimes classified as containing no less than 12 wt.% chromium). With more than this amount of chromium, stainless steels are very resistant to corrosion and oxidation in specific environments. These steels are properly called corrosion-resistant steels, or “CRES,” as called for on some older drawings and material lists. Just as chromium plating provides protection for steel, the chromium in stainless steels provides corrosion resistance. The chromium causes a “passive” chromium-rich oxide layer to form on the surface of the steel. This is an invisible layer that adheres to the surface of the steel. Unlike plated or painted steel, if stainless steel is scratched, the passive chromium oxide reforms in air, thus protecting the steel from corrosion or oxidation. Austenitic Ferritic Martensitic Duplex Precipitation-Hardening 200 and 300 Series Some of the 400 Series Some of the 400 Series Each type is described by the metallurgical structure present at room temperature. Most stainless steel base metals are available in various forms, including: (1) Wrought • Plate, sheet • Pipe, tube • Bar, wire • Forgings (2) Cast Types of Stainless Steels The American Iron and Steel Institute (AISI) classifications for stainless steels are: AISI Classification Series Major Alloying Elements 200 Series 300 Series 400 Series Cr-Ni-Mn Cr-Ni Cr Note: The 500 series of steels are technically heat-resistant steels, not corrosion-resistant, because they contain less than 10.5% chromium. However, they are often classified with the corrosion-resistant base metals and filler metals. In the following tables, the stainless steels are listed by their AISI type (e.g., 304). The tables also list the Unified Numbering System (UNS) numbers for the various stainless steels. The UNS numbers include an “S” for wrought stainless steel. The number typically includes the common type The five major types or classifications of stainless steels are: --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 5 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT The most common stainless steels used are the wrought austenitics in Table 2-1. Type 302 is the basic austenitic 18Cr-8Ni alloy. Type 304 has a higher chromium and nickel content to improve corrosion resistance. Although Type 316 has lower chromium, a higher nickel content, plus the addition of molybdenum provides even better resistance to pitting corrosion, crevice corrosion, and stress-corrosion cracking (especially in chloride environments). number, such as UNS S30400 for Type 304; S30403 for Type 304L, etc. Some of the superaustenitic stainless steels are actually classified as nickel alloys and have UNS “N” designations (see Table 2-3). Cast stainless steels have a UNS “J” designation. Austenitic Stainless Steels The majority of stainless steels used are austenitic stainless steels, which contain approximately 16–25 wt.% chromium and 7–35 wt.% nickel. The 300 series austenitics are iron-chromium-nickel alloys, while the 200 series also contain manganese and nitrogen to replace some of the nickel. These steels are named for the face-centered cubic (FCC) structure that is present at room temperature, called austenite. Some properties of these stainless steels (with some exceptions) include: The “L” grades (e.g., 304L and 316L) contain a lower carbon content, thus, they are less likely to be sensitized or produce intergranular corrosion. The “H” grades (e.g., 304H and 316H) have a higher carbon content for greater strength at elevated temperatures. There are many cast austenitic stainless steels with compositions similar to the wrought stainless steels, as shown in Table 2-2. For example, alloy designation CF-8 is the cast equivalent of Type 304 and CF-3M is the cast equivalent of Type 316L. The “C” denotes corrosion resistant, the 8 indicates a maximum of 0.08% carbon, the 3 indicates 0.03% maximum carbon, and the M denotes molybdenum. (1) Nonmagnetic. (2) Best general corrosion resistance. (3) Not heat treatable (cannot be heat treated to increase strength or hardness). (4) Can be strengthened only by cold work. (5) Good ductility and toughness at low and high temperatures (nickel provides good cryogenic properties). (6) Poor resistance to: • Stress corrosion cracking • Pitting corrosion • Crevice corrosion The superaustenitic stainless steels in Table 2-3 contain higher levels of chromium, nickel, and molybdenum, with significantly lower carbon and nitrogen contents (such as Type 904L). These provide better corrosion resistance in specific environments, such as improved pitting and stresscorrosion cracking resistance in chlorides. Ferritic Stainless Steels Ferritic stainless steels are iron-chromium alloys that contain approximately 11–30 wt.% chromium and low levels of carbon. The name refers to Chemical compositions of typical austenitic stainless steels are provided in Tables 2-1–2-3. 6 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Type 201 202 301 302 302B 303 303Se 304 304H 304L 304LN 304N 305 308 309 309S 310 310S 314 316 316H 316L 317 317L 321 329 330 347 348 384 Table 2-1—Chemical Compositions of Typical Wrought Austenitic Stainless Steels Composition, wt.%a UNS Number S20100 S20200 S30100 S30200 S30215 S30300 S30323 S30400 S30409 S30403 S30453 S30451 S30500 S30800 S30900 S30908 S31000 S31008 S31400 S31600 S31609 S31603 S31700 S31703 S32100 S32900 N08330 S34700 S34800 S38400 C 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.08 0.04–0.10 0.03 0.03 0.08 0.12 0.08 0.20 0.08 0.25 0.08 0.25 0.08 0.04–0.10 0.03 0.08 0.03 0.08 0.08 0.08 0.08 0.08 0.08 Mn 5.5–7.50 7.5–10.0 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 1.00 2.00 2.00 2.00 2.00 Si 1.00 1.00 1.00 1.00 2.0–3.0 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.50 1.50 1.5–3.0 1.00 1.00 1.00 1.00 1.00 1.00 0.75 0.75–1.50 1.00 1.00 1.00 Cr 16.0–18.0 17.0–19.0 16.0–18.0 17.0–19.0 17.0–19.0 17.0–19.0 17.0–19.0 18.0–20.0 18.0–20.0 18.0–20.0 18.0–20.0 18.0–20.0 17.0–19.0 19.0–21.0 22.0–24.0 22.0–24.0 24.0–26.0 24.0–26.0 23.0–26.0 16.0–18.0 16.0–18.0 16.0–18.0 18.0–20.0 18.0–20.0 17.0–19.0 23.0–28.0 17.0–20.0 17.0–19.0 17.0–19.0 15.0–17.0 Nib 3.5–5.5 4.0–6.0 6.0–8.0 8.0–10.0 8.0–10.0 8.0–10.0 8.0–10.0 8.0–10.5 8.0–11.0 8.0–12.0 8.0–12.0 8.0–10.5 10.0–13.0 10.0–12.0 12.0–15.0 12.0–15.0 19.0–22.0 19.0–22.0 19.0–22.0 10.0–14.0 10.0–14.0 10.0–14.0 11.0–15.0 11.0–15.0 9.0–12.0 2.5–5.0 34.0–37.0 9.0–13.0 9.0–13.0 17.0–19.0 Notes: a. Single values are maximum percentages unless indicated otherwise. b. Higher percentages are required for certain tube manufacturing processes. c. 10 × %C (Nb +Ta) min. d. 0.10% TaWelding max. Society Copyright American 7 Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT P 0.060 0.060 0.045 0.045 0.045 0.200 0.200 0.045 0.045 0.045 0.045 0.045 0.045 0.045 0.045 0.045 0.045 0.045 0.045 0.045 0.040 0.045 0.045 0.045 0.045 0.045 0.040 0.045 0.045 0.045 S 0.03 0.03 0.03 0.03 0.03 0.15 min 0.06 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 Other 0.25 N 0.25 N — — — 0–0.6 Mo 0.15 Se min — — — 0.10–0.16 N 0.10–0.16 N — — — — — — — 2.0–3.0 Mo 2.0–3.0 Mo 2.0–3.0 Mo 3.0–4.0 Mo 3.0–4.0 Mo 5 × %C Ti min 1.0–2.0 Mo Note c 0.20 Coc,d Table 2-2—Chemical Compositions of Typical Cast Austenitic Stainless Steels Composition, wt.%a Alloy Designation CE-30 CF-3 CF-3M CF-8 CF-8C CF-8M CF-12M CF-16F CF-20 CG-8M CH-20 CK-20 CN-7M HE HF HH HI HK HL HN HP HT HU UNS Number Similar Wrought Typeb C Si Cr Ni Mo Other J93423 J92700 J92800 J92600 J92710 J92900 — J92701 J92602 — J93402 J94202 J95150 J93403 J92603 J93503 J94003 J94224 J94604 J94213 — J94605 — 312 L304L L316L 304 347 316 316 303 302 317 309 310 — — 304 309 — 310 — — — 330 — 0.30 0.03 0.03 0.08 0.08 0.08 0.12 0.16 0.20 0.08 0.20 0.20 0.07 0.2–0.5 0.2–0.4 0.20 0.2–0.5 0.2–0.6 0.2–0.6 0.2–0.5 0.35–0.75 0.35–0.75 0.35–0.75 2.0 2.0 1.5 2.0 2.0 1.5 1.5 2.0 2.0 1.5 2.0 2.0 1.5 2.0 2.0 — 2.0 2.0 2.0 2.0 2.0 2.5 2.5 26–30 17–21 17–21 18–21 18–21 18–21 18–21 18–21 18–21 18–21 22–26 23–27 18–22 26–30 19–23 — 26–30 24–28 28–32 19–23 24–28 15–19 17–21 8–11 8–12 9–13 8–11 9–12 9–12 9–12 9–12 8–11 9–13 12–15 19–22 27.5–30.5 8–11 9–12 — 14–18 18–22 18–22 23–27 33–37 33–37 37–41 — — 2.0–3.0 — — 2.0–3.0 2.0–3.0 1.5 — 3.0–4.0 — — 2.0–3.0 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 — — — — Note c — — 0.20–0.35 Se — — — — 3–4 Cu — — — — — — — — — — Notes: a. Single values are maximum percentages. 1.50% Mn max for CX-XX types. 2.0% Mn max for HX types. 0.04% P max (exception: CF-16F has 0.17% P max). 0.04% S max. b. Compositions are similar but not exactly the same as the cast types. c. 8 × %C Nb, 1.0% Nb max, or 9 × %C (Nb + Ta), 1.1% (Nb + Ta) max. 8 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 2-3—Chemical Compositions of Typical Superaustenitic Stainless Steels Nominal Composition, wt.%b Alloya UNS Number C Cr Ni Mo Cu Mn N Si P S Other Elements 20 Cb3™ 20 Mo6™ SANICRO™ 28 AL-6XN® JS™ 700 904L 1925hMo, 25-6MO™ 254SMO™ 317LM 17-14-4 LN N08020 N08026 N08028 N08367 N08700 N08904 N08925 S31254 S31725 S31726 0.07 0.03 0.03 0.03 0.04 0.02 0.02 0.02 0.03 0.03 19–21 22–26 26–28 20–22 19–23 19–23 19–21 19.5–20.5 18–20 17–20 32–38 33–37 29.5–32.5 23.5–25.5 24–26 23–28 24–26 17.5–18.5 13–17 13.5–17.5 2–3 5–6.7 3–4 6–7 4.3–5.0 4–5 6–7 6.0–6.5 4–5 4–5 3–4 2–4 0.6–1.4 0.75 0.5 1–2 0.8–1.5 0.5–1.0 — — 2.0 1.0 2.5 2.0 2.0 2.0 1.0 1.0 2.0 2.0 — — — 0.18–0.25 — — 0.18–0.20 0.18–0.22 — 0.10–0.20 1.00 0.50 1.00 1.00 1.00 1.00 0.50 0.80 0.75 0.75 0.045 0.030 0.030 0.040 0.040 0.045 0.045 0.030 0.045 0.030 0.035 0.030 0.030 0.030 0.030 0.035 0.030 0.010 0.030 0.030 8 × %C ≤ Nb ≤ 1.0 — — — 8 × %C ≤ Nb ≤ 0.5 — — — — — --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Notes: a. AL-6XN is a registered trademark of Allegheny Ludlum Corporation. 20 Cb3 and 20 Mo6 are trademarks of Carpenter Technology Corporation; SANICRO is a registered trademark of AB Sandvik Steel; 25-6MO is a trademark of INCO; JS is a trademark of Jessop Steel; and 254SMO is a trademark of Avesta Jernwerke AB. b. Single values are maximum percentages; balance is Fe. Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 9 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT that forms when these stainless steels are quenched (rapidly cooled), often when cooled in air. Some properties of these stainless steels include: the body-centered cubic (BCC) structure present at room temperature, called ferrite. Some properties of these stainless steels include: (1) Ferromagnetic. (2) Lowest corrosion resistance. (3) Heat treatable (can be strengthened by quenching). (4) High strength. (5) Lowest ductility and toughness. (6) Good high temperature oxidation resistance. (1) Ferromagnetic. (2) Intermediate general corrosion resistance. (3) Better stress-corrosion cracking resistance than austenitics. (4) Good pitting and crevice corrosion resistance. (5) Not heat treatable (by quenching and tempering). (6) Lower strength and toughness than austenitics. (7) Good ductility. When these steels are quenched from high temperatures, martensite is produced, which gives the steels high strength and hardness. Since the steels also become very brittle and subject to cold (or hydrogen) cracking, they are often tempered after quenching. This process improves ductility (reduces the brittleness), although strength and hardness are somewhat reduced. The chemical compositions of typical martensitic stainless steels are provided in Table 2-6. The chemical compositions of typical ferritic stainless steels are provided in Tables 2-4 and 2-5. The ferritic stainless steels shown in Table 2-4 include both wrought and cast alloys. These alloys essentially contain no nickel, but have chromium contents from the lowest allowable levels in stainless steels (Type 409) up to very high levels (29-4-2). Some of these alloys contain moderate levels of carbon (Type 430) and can form martensite, although most form only ferrite. The superferritic stainless steels shown in Table 2-5 have even higher levels of chromium, with some molybdenum and significantly lower carbon. These alloys provide much improved corrosion resistance, especially in chloride environments. Duplex Stainless Steels Duplex stainless steels are iron-chromium-nickel alloys that contain 23–30 wt.% chromium and 2–7 wt.% nickel, plus other elements. Since these stainless steels have two phases present at room temperature, ferrite and austenite, they are referred to as duplex. Some properties of these stainless steels include: Martensitic Stainless Steels (1) Partially magnetic. (2) Good general corrosion resistance. (3) Better stress-corrosion cracking resistance than austenitics. Martensitic stainless steels are iron-chromium alloys with 11–17 wt.% chromium and enough carbon (0.1–1.2 wt.%) to produce some martensite on cooling. This martensite is a body-centered tetragonal (BCT) structure --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 10 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 2-4—Chemical Compositions of Typical Ferritic Stainless Steels Composition, wt.%a Type UNS Number C Mn Si Cr Ni P S Others Wrought Alloys 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 11.5–14.5 10.5–11.75 14.0–16.0 16.0–18.0 16.0–19.5 16.0–18.0 16.0–18.0 17.0–19.0 — — — — 0.75 — — 0.50 0.040 0.045 0.040 0.040 0.040 0.040 0.040 0.040 0.030 0.045 0.030 0.030 0.030 0.030 0.030 0.030 S44200 S44400 0.200 0.025 1.00 1.00 1.00 1.00 18.0–23.0 17.5–19.5 — 1.00 0.040 0.040 0.030 0.030 S44600 S44626 S44700 S44800 0.200 0.006 0.010 0.010 1.50 0.75 0.20 0.20 1.00 0.75 0.30 0.30 23.0–27.0 25.0–27.0 28.0–30.0 28.0–30.0 — 0.50 0.15 2.0–2.5 0.040 0.040 0.025 0.025 0.030 0.020 0.020 0.020 0.10–0.30 Al Ti, 6 × %C min — — Ti, 5 × %C min, 0.75 max 0.75–1.25 Mo 0.75–1.25 Mo; (Nb+Ta), 5 × %C min 0.15 Al max; 0.04 N max; Ti, 0.20 + 4(%C + %N) min, 1.10 max Ti, 0.20 + 4(%C + %N) 1.75–2.5 Mo; 0.035 N max; (Nb+Ta), 0.2 + 4 (%C + %N) min 0.25 N 0.75–1.50 Mo; 0.20–1.0 Ti; 0.04 N; 0.2 Cu 3.5–4.2 Mo; 0.020 Ni; 0.15 Cu 3.5–4.2 Mo; 0.020 Ni, 0.15 Cu 0.04 0.04 0.04 0.04 — — S40500 S40900 S42900 S43000 S43036 S43400 S43600 S43035 442 444 446 26-1 29-4 29-4-2 0.080 b0.08b0 --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- 0.120 0.120 0.100 0.120 0.120 0.070 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 405 409 429 430 430Ti 434 436 439 Casting Alloys CB-30 CC-50 J91803 J92616 0.30 0.50 1.50 1.50 1.00 1.00 18.0–21.0 26.0–30.0 2.0 4.0 Notes: a. Single values are a maximum. b. Most producers can now make a low-carbon with 0.02% carbon. Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 11 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 2-5—Chemical Compositions of Typical Superferritic Stainless Steels Nominal Composition, wt.%b E-BRITE® MONIT™ SEA-CURE® AL 29-4® AL 29-4C® AL 29-4-2® SHOMAC® 30-2 UNS Number C Cr Mo Ni N Mn Other Elements S44726 S44635 S44660 S44700 S44735 S44800 — 0.010 0.025 0.025 0.010 0.030 0.010 c0.003c 25–27 24.5–26.0 25–27 28–30 28–30 28–30 c30c 0.75–1.50 3.5–4.5 2.5–3.5 3.5–4.2 3.6–4.2 3.5–4.2 c2.0c 0.30 3.5–4.5 1.5–3.5 0.15 1.0 2.0–2.5 c0.2c 0.015 0.035 0.035 0.020 0.045 0.020 c0.007c 0.40 1.00 1.00 0.30 1.00 0.30 c0.05c 0.05–0.20 Nb [0.20 + 4(C + N)] ≤ (Nb + Ti) ≤ 0.80 [0.20 + 4(C + N)] ≤ (Nb + Ti) ≤ 0.80 6(C + N) ≤ (Nb + Ti) ≤ 1.0 --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Alloya Notes: a. E-BRITE, AL 29-4, AL 29-4-2, and AL 29-4C are registered trademarks of Allegheny Ludlum Corporation; SEA-CURE is a registered trademark of Crucible Materials Corporation; SHOMAC is a registered trademark of Showa Denko KK. Monit is a trademark of Nyby Uddeholm AB. b. Single values are maximum percentages; balance is Fe. c. Typical value. 12 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT 403 410 414 416 420 422 431 440A 440B 440C --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Type Table 2-6—Chemical Compositions of Typical Martensitic Stainless Steels Composition, wt.%a UNS Number C Mn Si Cr Ni P S Other 0.040 0.040 0.040 0.040 0.040 0.025 0.040 0.040 0.040 0.040 0.030 0.030 0.030 0.15 min 0.030 0.025 0.030 0.030 0.030 0.030 — — — — — 0.75–1.25 Mo; 0.75–1.25 W; 0.15–0.3 V — 0.75 Mo 0.75 Mo 0.75 Mo 0.040 0.040 0.040 0.030 0.030 0.030 0.40–1.0 Mo 0.5 Mo 0.5 Mo Wrought Alloys S40300 S41000 S41400 S41600 S42000 S42200 S43100 S44002 S44003 S44004 0.15 0.15 0.15 0.15 0.15 min 0.20–0.25 0.20 0.60–0.75 0.75–0.95 0.95–1.20 1.00 1.00 1.00 1.25 1.00 1.00 1.00 1.00 1.00 1.00 0.50 1.00 1.00 1.00 1.00 0.75 1.00 1.00 1.00 1.00 — — 1.25–2.50 — — 0.5–1.0 1.25–2.50 — — — 11.5–13.0 11.5–13.0 11.5–13.5 12.0–14.0 12.0–14.0 11.0–13.0 15.0–17.0 16.0–18.0 16.0–18.0 16.0–18.0 Casting Alloys CA-6NM CA-15 CA-40 J91540 J91150 J91153 0.06 0.15 0.20–0.40 1.00 1.00 1.00 1.00 1.50 1.50 11.5–14.0 11.5–14.0 11.5–14.0 3.5–4.5 1.0 1.0 Note: a. Single values are maximum percentages. Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 13 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT (4) Better pitting corrosion resistance than austenitics. (5) Better intergranular corrosion resistance than austenitics. (6) Higher strength than austenitics. Depending on their compositions, these alloys can be one of three types as shown in Table 2-8: (1) Martensitic. (2) Semiaustenitic (structure is austenite with some ferrite and/or martensite). (3) Austenitic. The chemical compositions of typical duplex stainless steels are provided in Table 2-7. Precipitation-Hardening Stainless Steels Precipitation-hardening stainless steels require a two-step heat treatment to obtain the best properties. The first is a solution anneal at an elevated temperature of 1900–2200°F (1038–1204°C) followed by quenching. This produces the various structures listed above. Then the steel is aged to cause precipitates of copper, nickel, titanium or other elements to form, which dramatically increase the strength. The chemical compositions of typical precipitation-hardening stainless steels are provided in Table 2-8. --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Precipitation-hardening stainless steels are iron-chromium-nickel alloys that have other elements added to form precipitates. During a postweld heat treatment, these constituents precipitate and dramatically improve hardness, thus the name precipitation-hardening. Some properties of these stainless steels include: (1) Intermediate corrosion resistance. (2) Very high strength (when heat treated). 14 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 2-7—Chemical Compositions of Typical Duplex Stainless Steels Composition, wt.% a,b,c Alloy --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- 329 44LN DP3 2205 2304 255 2507 Z100d 3RE60 U50d 7MoPLUS DP3W UNS Number C Cr Ni Mo N Other Elements S32900 S31200 S31260 S31803 S32304 S32550 S32750 S32760 S31500 S32404 S32950 S39274 0.080 0.030 0.030 0.030 0.030 0.040 0.030 0.030 0.030 0.040 0.030 0.030 23.0–28.0 24.0–26.0 23.0–28.0 21.0–23.0 21.5–24.5 24.0–27.0 24.0–26.0 24.0–26.0 18.0–19.0 20.5–22.5 26.0–29.0 24.0–26.0 2.5–5.0 5.5–6.5 2.5–5.0 4.5–6.5 3.0–5.5 4.5–6.5 6.0–8.0 6.0–8.0 4.25–5.25 5.5–8.5 3.5–5.2 6.0–8.0 1.0–2.0 1.2–2.0 2.5–3.5 2.5–3.5 0.05–0.60 2.9–3.9 3.0–4.0 3.0–4.0 2.5–3.0 2.0–3.0 1.0–2.5 2.5–3.5 — 0.14–0.20 0.10–0.30 0.08–0.20 0.05–0.20 0.10–0.25 0.24–0.32 0.2–0.3 — 0.20 0.15–0.35 0.24–0.32 — — 0.20–0.80 Cu; 0.10–0.50 W — — 1.5–2.0 Cu — 0.5–1.0 Cu; 0.5–1.0 W — 1.0–2.0 Cu — 0.2–0.8 Cu; 1.5–2.5 W Notes: a. Single values are maximum percentages. b. 2.5 Mn max. c. 0.70–1.0 Si max. d. Z100—Zeron 100; U50—Uranus 50. Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 15 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 2-8—Chemical Compositions of Typical Precipitation-Hardening Stainless Steels Nominal Composition, wt.% Designationa UNS Number C Mn Si Cr Ni Mo Al Other Elements Moderate strength 17-4 PH 15-5 PH Custom 450 S17400 S15500 S45000 0.04 0.04 0.03 0.30 0.30 0.25 0.60 0.40 0.25 16.00 15.00 15.00 4.20 4.50 6.00 — — 0.80 — — — 3.4 Cu; 0.25 Nb 3.4 Cu; 0.25 Nb 1.5 Cu; 0.3 Nb High strength PH 13-8 Mo Custom 455 S13800 S45500 0.04 0.03 0.03 0.25 0.03 0.25 12.70 11.75 8.20 8.50 2.20 — 1.1 — — 2.5 Cu; 1.2 Ti; 0.3 Nb Semiaustenitic PH 15-7 Mo PH 14-8 Mo AM-350 AM-355 S15700 S14800 S35000 S35500 0.07 0.04 0.10 0.13 0.50 0.02 0.75 0.85 0.30 0.02 0.35 0.35 15.20 15.10 16.50 15.50 7.10 8.20 4.25 4.25 2.20 2.20 2.75 2.75 1.2 1.2 — — — — — — A-286 17-10 P HNM S66286 — — 0.05 0.10 0.30 0.50 0.60 3.50 0.50 0.50 0.50 14.75 17.00 18.50 25.000 11.000 9.50 1.30 — — 0.15 — — 0.30 V; 2.15 Ti; 0.005 B 0.30 P 0.25 P Type Martensitic Austenitic Note: a. Some of these designations are registered trademarks. 16 --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Chapter 3—Stainless Steel Filler Materials Welding Filler Metals Tables 3-1 through 3-6 list the chemical compositions of stainless steel filler metals described in these specifications. The compositions of bare wire or strip are based on chemical analysis of the bare filler metal. The compositions of coated or cored electrodes and rods are based on asdeposited, undiluted weld metal. The UNS numbers have a prefix of “W” to denote welding filler metal. Stainless steels can be welded with or without filler metals. Processes Requiring Filler Metal: • SMAW • GMAW • FCAW • SAW AWS A5.4 Stainless steel electrodes for shielded metal arc welding (SMAW) are listed in Table 3-1. Electrodes are available for all five major groups of stainless steels; however, there are only a few martensitic and ferritic stainless steel electrodes. There are electrodes available that closely match the base metal compositions; however, the actual chemical composition of any filler metal is typically higher than the base metal, because some elements are often lost in the transfer across the arc. The classifications indicated with “-XX” suffixes designate the various types of welding currents and positions of welding, as summarized in Table 3-2. The “XXX(X)” classification denotes the stainless steel composition, such as 308L. The “1” suffix indicates that the electrodes can be used in all welding positions, while the “2” indicates flat and horizontal positions only. The last digit designates whether the electrode can be used with direct current electrode positive (dcep–reverse polarity) only or with both dcep and alternating current (ac). --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Processes For Which Filler Metal is Optional: • GTAW • PAW • LBW • EBW AWS specifications for stainless steel welding electrodes and filler metals are described in the list of standards that are provided at the end of this Advisor. The welding processes covered for filler metals are as follows: (1) AWS A5.4 (2) AWS A5.9 (3) AWS A5.22 (4) AWS A5.30 SMAW electrodes GMAW electrodes GTAW welding rod SAW electrodes FCAW electrodes Cored wire for GTAW Consumable inserts Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 17 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 3-1—Chemical Composition Requirements for Stainless Steel Shielded Metal Arc Welding Electrodesa Composition, wt.%b AWS Classificationc UNS Numberd C Cr Ni Mo E209-XXe E219-XX E240-XX E307-XX E308-XX E308H-XX E308L-XX E308Mo-XX E308LMo-XX E309-XX E309H-XX E309L-XX E309Cb-XX E309Mo-XX E309LMo-XX E310-XX E310H-XX E310Cb-XX E310Mo-XX E312-XX E316-XX E316H-XX E316L-XX E317-XX E317L-XX E318-XX W32210 W32310 W32410 W30710 W30810 W30810 W30813 W30820 W30823 W30910 — W30913 W30917 W30920 W30923 W31010 W31015 W31017 W31020 W31310 W31610 W31610 W31613 W31710 W31713 W31910 0.06 0.06 0.06 0.04–0.14 0.08 0.04–0.08 0.04 0.08 0.04 0.15 0.04–0.15 0.04 0.12 0.12 0.04 0.08–0.20 0.35–0.45 0.12 0.12 0.15 0.08 0.04–0.08 0.04 0.08 0.04 0.08 20.5–24.0 19.0–21.5 17.0–19.0 18.0–21.5 18.0–21.0 18.0–21.0 18.0–21.0 18.0–21.0 18.0–21.0 22.0–25.0 22.0–25.0 22.0–25.0 22.0–25.0 22.0–25.0 22.0–25.0 25.0–28.0 25.0–28.0 25.0–28.0 25.0–28.0 28.0–32.0 17.0–20.0 17.0–20.0 17.0–20.0 18.0–21.0 18.0–21.0 17.0–20.0 9.5–12.0 5.5–7.0 4.0–6.0 9.0–10.7 9.0–11.0 9.0–11.0 9.0–11.0 9.0–12.0 9.0–12.0 12.0–14.0 12.0–14.0 12.0–14.0 12.0–14.0 12.0–14.0 12.0–14.0 20.0–22.5 20.0–22.5 20.0–22.0 20.0–22.0 8.0–10.5 11.0–14.0 11.0–14.0 11.0–14.0 12.0–14.0 12.0–14.0 11.0–14.0 1.5–3.0 0.75 0.75 0.5–1.5 0.75 0.75 0.75 2.0–3.0 2.0–3.0 0.75 0.75 0.75 0.75 2.0–3.0 2.0–3.0 0.75 0.75 0.75 2.0–3.0 0.75 2.0–3.0 2.0–3.0 2.0–3.0 3.0–4.0 3.0–4.0 2.0–3.0 E320-XX W88021 0.07 19.0–21.0 32.0–36.0 — — — — — — — — — — — — 0.70–1.00 — — — — 0.70–1.00 — — — — — — — 6 × %C min, 1.00 max 2.0–3.0 8 × %C min, 1.00 max (continued) --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Nb + Ta Mn Si P S N Cu 4.0–7.0 8.0–10.0 10.5–13.5 3.30–4.75 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 1.0–2.5 1.0–2.5 1.0–2.5 1.0–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.90 1.00 1.00 0.90 0.90 0.90 0.90 0.90 0.90 0.90 0.90 0.90 0.90 0.90 0.90 0.75 0.75 0.75 0.75 0.90 0.90 0.90 0.90 0.90 0.90 0.90 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.03 0.03 0.03 0.03 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.10–0.30 0.10–0.30 0.10–0.30 — — — — — — — — — — — — — — — — — — — — — — — 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.5–2.5 0.60 0.04 0.03 — 3.0–4.0 18 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 3-1—Chemical Composition Requirements for Stainless Steel Shielded Metal Arc Welding Electrodesa (Continued) Composition, wt.%b AWS Classificationc UNS Numberd C Cr Ni Mo Nb + Ta Mn Si P S N Cu E320LR-XX W88022 0.03 19.0–21.0 32.0–36.0 2.0–3.0 1.50–2.50 0.30 0.020 0.015 — 3.0–4.0 E330-XX E330H-XX E347-XX W88331 W88335 W34710 0.18–0.25 0.35–0.45 0.08 14.0–17.0 14.0–17.0 18.0–21.0 33.0–37.0 33.0–37.0 9.0–11.0 0.75 0.75 0.75 1.0–2.5 1.0–2.5 0.5–2.5 0.90 0.90 0.90 0.04 0.04 0.04 0.03 0.03 0.03 — — — 0.75 0.75 0.75 E349-XXe,f,g E383-XX E385-XX E410-XX E410NiMo-XX E430-XX E502-XXh E505-XXh E630-XX E16-8-2-XX E7Cr-XXh E2209-XX E2553-XX E2593-XX W34910 W88028 W88904 W41010 W41016 W43010 W50210 W50410 W37410 W36810 W50310 W39209 W39553 W39593 0.13 0.03 0.03 0.12 0.06 0.10 0.10 0.10 0.05 0.10 0.10 0.04 0.06 0.04 18.0–21.0 26.5–29.0 19.5–21.5 11.0–13.5 11.0–12.5 15.0–18.0 4.0–6.0 8.0–10.5 16.0–16.75 14.5–16.5 6.0–8.0 21.5–23.5 24.0–27.0 24.0–27.0 8.0–10.0 30.0–33.0 24.0–26.0 0.75 4.0–5.0 0.6 0.4 0.4 4.5–5.0 7.5–9.5 0.4 8.5–10.5 6.5–8.5 8.5–11.0 0.35–0.65 3.2–4.2 4.2–5.2 0.7 0.40–0.70 0.75 0.45–0.65 0.85–1.20 0.75 1.0–2.0 0.45–0.65 2.5–3.5 2.9–3.9 2.9–3.9 8 × %C min 0.40 max — — 8 × %C min, 1.00 max 0.75–1.2 — — — — — — — 0.15–0.30 — — — — — 0.5–2.5 0.5–2.5 1.0–2.5 1.0 1.0 1.0 1.0 1.0 0.25–0.75 0.5–2.5 1.0 0.5–2.0 0.5–1.5 0.5–1.5 0.90 0.90 0.75 0.90 0.90 0.90 0.90 0.90 0.75 0.60 0.90 0.90 1.0 1.0 0.04 0.02 0.03 0.04 0.04 0.04 0.04 0.04 0.04 0.03 0.04 0.04 0.04 0.04 0.03 0.02 0.02 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 — — — — — — — — — — — 0.08–0.20 0.10–0.25 0.08–0.25 0.75 0.6–1.5 1.2–2.0 0.75 0.75 0.75 0.75 0.75 3.25–4.00 0.75 0.75 0.75 1.5–2.5 1.5–3.0 Notes: a. Analysis shall be made for the elements for which specific values are shown in this table. If, however, the presence of other elements is indicated in the course of routine analysis, further analysis shall be made to determine that the total of these other elements, except iron, is not present in excess of 0.50%. b. Single values shown are maximum percentages. c. Classification suffix may be -15, -16, -17, -25, or -26. See Section A8 of the Appendix of AWS A5.4, Specification for Stainless Steel Electrodes for Shielded Metal Arc Welding, for an explanation. d. ASTM/SAE Unified Numbering System for Metals and Alloys. e. 0.10–0.30% V. f. 0.15% Ti max. g. 1.25–1.75% W. h. In the next revision of A5.4, classifications E502, E505, and E7Cr will be eliminated, but they will be added to the next revision of A5.5 and listed as follows: E502 as E901X-B6, E505 as E901X-B8, and E7Cr as E901X-B7. --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 19 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT EC—Composite metal cored or stranded wire (for GTAW or PAW) EQ—Bare strip electrodes (for SAW) Table 3-2—Types of Welding Current and Positions of Welding AWS Classification EXXX(X)-15 EXXX(X)-25 EXXX(X)-16 EXXX(X)-17 EXXX(X)-26 Welding Currentb Welding Positiona,c dcep dcep dcep or ac dcep or ac dcep or ac Alld H, F Alld Alld H, F There are electrodes and rods available for many of the stainless steels, and most stainless steel base metals are welded with filler metals of the same type. However, the actual compositions of the filler metals typically contain greater amounts of most elements, because there is some loss across the arc. Note that there is no Type 304 filler metal; Type 308 is the filler metal used for Type 304 base metal. Notes: a. See A5.4, Section A8, Classification as to Usability, for explanation of positions. b. dcep = Direct current electrode positive (reverse polarity). ac = Alternating current. c. The abbreviations H and F indicate welding positions as follows: F = Flat. H = Horizontal. d. Electrodes 3/16 in. (4.8 mm) and larger are not recommended for welding all positions. AWS A5.22 Table 3-4 lists the chemical compositions of stainless steel flux cored wires as described in AWS A5.22. The designation system includes: E—Cored electrode for flux cored arc welding (FCAW) R—Flux cored rod for GTAW (or PAW) T—Tubular wire As with all SMAW electrodes, it is important to keep these dry and stored properly, according to the code requirements or manufacturer’s instructions. Since some of the alloying in the weld comes from the coating, the solid core wire should never be used as a bare wire for welding. --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- The designations indicate the chemical compositions of the as-deposited, undiluted weld metal, positions of welding, external shielding medium, and type of current. There are flux cored filler metals for many stainless steel alloys. The “E” designation filler metals shown in Table 3-4 are used for FCAW processes—both gas-shielded and self-shielded; while the “R” designates filler metals for GTAW. These filler metals are typically used for root pass welding of stainless steel pipe, without the use of back shielding gas. The rods contain 5 wt.% or more of non-metallic content. Cored rods with less than this amount are not contained in AWS A5.22, but are classified as metal cored rods in AWS A5.9. AWS A5.9 Table 3-3 lists the chemical compositions of numerous types of stainless steel filler metals described in AWS A5.9. These filler metals are used for various welding processes. As listed in Note (c) in Table 3-3, the designations are: ER—Solid wires used as electrodes (for GMAW and SAW) and rods (for GTAW and PAW) 20 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 3-3—Chemical Composition Requirements for Bare Stainless Steel Welding Electrodes and Rodsa UNS Numbere C Cr Ni Mo ER209 ER218 ER219 ER240 ER307 ER308 ER308H ER308L ER308Mo ER308LMo ER308Si ER308LSi ER309 ER309L ER309Mo ER309LMo ER309Si ER309LSi ER310 ER312 ER316 ER316H ER316L ER316Si S20980 S21880 S21980 S24080 S30780 S30880 S30880 S30883 S30882 S30886 S30881 S30888 S30980 S30983 S30982 S30986 S30981 S30988 S31080 S31380 S31680 S31680 S31683 S31681 0.05 0.10 0.05 0.05 0.04–0.14 0.08 0.04–0.08 0.03 0.08 0.04 0.08 0.03 0.12 0.03 0.12 0.03 0.12 0.03 0.08–0.15 0.15 0.08 0.04–0.08 0.03 0.08 20.5–24.0 16.0–18.0 19.0–21.5 17.0–19.0 19.5–22.0 19.5–22.0 19.5–22.0 19.5–22.0 18.0–21.0 18.0–21.0 19.5–22.0 19.5–22.0 23.0–25.0 23.0–25.0 23.0–25.0 23.0–25.0 23.0–25.0 23.0–25.0 25.0–28.0 28.0–32.0 18.0–20.0 18.0–20.0 18.0–20.0 18.0–20.0 9.5–12.0 8.0–9.0 5.5–7.0 4.0–6.0 8.0–10.7 9.0–11.0 9.0–11.0 9.0–11.0 9.0–12.0 9.0–12.0 9.0–11.0 9.0–11.0 12.0–14.0 12.0–14.0 12.0–14.0 12.0–14.0 12.0–14.0 12.0–14.0 20.0–22.5 8.0–10.5 11.0–14.0 11.0–14.0 11.0–14.0 11.0–14.0 1.5–3.0 0.75 0.75 0.75 0.5–1.5 0.75 0.50 0.75 2.0–3.0 2.0–3.0 0.75 0.75 0.75 0.75 2.0–3.0 2.0–3.0 0.75 0.75 0.75 0.75 2.0–3.0 2.0–3.0 2.0–3.0 2.0–3.0 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Mn Si 4.0–7.0 0.90 7.0–9.0 3.5–4.5 8.0–10.0 1.00 10.5–13.5 1.00 3.3–4.75 0.30–0.65 1.0–2.5 0.30–0.65 1.0–2.5 0.30–0.65 1.0–2.5 0.30–0.65 1.0–2.5 0.30–0.65 1.0–2.5 0.30–0.65 1.0–2.5 0.65–1.00 1.0–2.5 0.65–1.00 1.0–2.5 0.30–0.65 1.0–2.5 0.30–0.65 1.0–2.5 0.30–0.65 1.0–2.5 0.30–0.65 1.0–2.5 0.65–1.00 1.0–2.5 0.65–1.00 1.0–2.5 0.30–0.65 1.0–2.5 0.30–0.65 1.0–2.5 0.30–0.65 1.0–2.5 0.30–0.65 1.0–2.5 0.30–0.65 1.0–2.5 0.65–1.00 (continued) P S N Cu Other Element 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.10–0.30 0.08–0.18 0.10–0.30 0.10–0.30 — — — — — — — — — — — — — — — — — — — — 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 V — — — — — — — — — — — — — — — — — — — — — — — 21 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Amount of Other Element 0.10–0.30 — — — — — — — — — — — — — — — — — — — — — — — --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Composition, wt.%b AWS Classificationc,d Table 3-3—Chemical Composition Requirements for Bare Stainless Steel Welding Electrodes and Rodsa (Continued) Composition, wt.%b AWS Classificationc,d UNS Numbere C Cr Ni Mo Mn Si P S N Cu Other Element ER316LSi ER317 ER317L ER318 S31688 S31780 S31783 S31980 0.03 0.08 0.03 0.08 18.0–20.0 18.5–20.5 18.5–20.5 18.0–20.0 11.0–14.0 13.0–15.0 13.0–15.0 11.0–14.0 2.0–3.0 3.0–4.0 3.0–4.0 2.0–3.0 1.0–2.5 1.0–2.5 1.0–2.5 1.0–2.5 0.65–1.00 0.30–0.65 0.30–0.65 0.30–0.65 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 — — — — 0.75 0.75 0.75 0.75 — — — Nbg ER320 NO8021 0.07 19.0–21.0 32.0–36.0 2.0–3.0 2.5 0.60 0.03 0.03 — 3.0–4.0 Nbg ER320LR NO8022 0.025 19.0–21.0 32.0–36.0 2.0–3.0 1.5–2.0 0.15 0.015 0.02 — 3.0–4.0 Nbg ER321 S32180 0.08 18.5–20.5 9.0–10.5 0.75 1.0–2.5 0.30–0.65 0.03 0.03 — 0.75 Ti ER330 ER347 NO8331 S34780 0.18–0.25 0.08 15.0–17.0 19.0–21.5 34.0–37.0 9.0–11.0 0.75 0.75 1.0–2.5 1.0–2.5 0.30–0.65 0.30–0.65 0.03 0.03 0.03 0.03 — — 0.75 0.75 — Nbg ER347Si S34788 0.08 19.0–21.5 9.0–11.0 0.75 1.0–2.5 0.65–1.00 0.03 0.03 — 0.75 Nbg ER383 ER385 ER409 NO8028 NO8904 S40900 0.025 0.025 0.08 26.5–28.5 19.5–21.5 10.5–13.5 30.0–33.0 24.0–26.0 0.6 3.2–4.2 4.2–5.2 0.50 1.0–2.5 1.0–2.5 0.8 0.50 0.50 0.8 0.02 0.02 0.03 0.03 0.03 0.03 — — — 0.70–1.5 1.2–2.0 0.75 — — Ti ER409Cb S40940 0.08 10.5–13.5 0.6 0.50 0.8 1.0 0.04 0.03 — 0.75 Nbg 0.12 0.06 0.25–0.40 11.5–13.5 11.0–12.5 12.0–14.0 0.6 4.0–5.0 0.6 0.75 0.4–0.7 0.75 0.6 0.6 0.6 0.5 0.5 0.5 0.03 0.03 0.03 0.03 0.03 0.03 — — — 0.75 0.75 0.75 — — — ER410 S41080 ER410NiMo S41086 ER420 S42080 (continued) 22 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Amount of Other Element — — — 8 × %C min, 1.0 max 8 × %C min, 1.0 max 8 × %C min, 0.40 max 9 × %C min, 1.0 max — 10 × %C min, 1.0 max 10 × %C min, 1.0 max — — 10 × %C min, 1.5 max 10 × %C min, 0.75 max — — — Composition, wt.%b AWS Classificationc,d UNS Numbere C Cr Ni Mo Mn Si P S N Cu ER430 ER446LMo ER502 ER505 ER630 ER19-10H S43080 S44687 S50280 S50480 S17480 S30480 0.10 0.015 0.10 0.10 0.05 0.04–0.08 15.5–17.0 25.0–27.5 4.6–6.0 8.0–10.5 16.0–16.75 18.5–20.0 0.6 Note f 0.6 0.5 4.5–5.0 9.0–11.0 0.75 0.75–1.50 0.45–0.65 0.8–1.2 0.75 0.25 0.6 0.4 0.6 0.6 0.25–0.75 1.0–2.0 0.5 0.4 0.5 0.5 0.75 0.30–0.65 0.03 0.02 0.03 0.03 0.03 0.03 0.03 0.02 0.03 0.03 0.03 0.03 — 0.015 — — — — 0.75 Note f 0.75 0.75 3.25–4.00 0.75 ER16-8-2 ER2209 ER2553 ER3556 S16880 S39209 S39553 R30556 0.10 0.03 0.04 0.05–0.15 14.5–16.5 21.5–23.5 24.0–27.0 21.0–23.0 7.5–9.5 7.5–9.5 4.5–6.5 19.0–22.5 1.0–2.0 2.5–3.5 2.9–3.9 2.5–4.0 1.0–2.0 0.50–2.00 1.5 0.50–2.00 0.30–0.65 0.90 1.0 0.20–0.80 0.03 0.03 0.04 0.04 0.03 0.03 0.03 0.015 — 0.08–0.20 0.10–0.25 0.10–0.30 0.75 0.75 1.5–2.5 — Other Element Amount of Other Element — — — — Nbg Nbg Ti — — — Co W Nb Ta Al Zr La B — — — — 0.15–0.30 0.05 0.05 — — — 16.0–21.0 2.0–3.5 0.30 0.30–1.25 0.10–0.50 0.001–0.10 0.005–0.10 0.02 --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Table 3-3—Chemical Composition Requirements for Bare Stainless Steel Welding Electrodes and Rodsa (Continued) Notes: a. Analysis shall be made for the elements for which specific values are shown in this table. If the presence of other elements is indicated in the course of this work, the amount of those elements shall be determined to ensure that their total, excluding iron, does not exceed 0.50%. b. Single values shown are maximum percentages. c. In the designator for composite, stranded, and strip electrodes, the “R” shall be deleted. A designator “C” shall be used for composite and stranded electrodes, and a designator “Q” shall be used for strip electrodes. For example, ERXXX designates a solid wire and EQXXX designates a strip electrode of the same general analysis and the same UNS number. However, ECXXX designates a composite metal cored or stranded electrode and may not have the same UNS number. Consult ASTM/SAE Uniform Numbering System for the proper UNS number. d. For special applications, electrodes and rods may be purchased with less than the specified silicon content. e. ASTM/SAE Unified Numbering System for Metals and Alloys. f. 0.5% (Ni + Cu) max. g. Nb may be reported as Nb + Ta. Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 23 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 3-4—Chemical Composition Requirements for Stainless Steel Flux Cored Arc Welding and Flux Cored Gas Tungsten Arc Welding Filler Metalsa Composition, wt.%b AWS Classificationc UNS Numberd C Cr Ni E307TX-X E308TX-X E308LTX-X E308HTX-X E308MoTX-X E308LMoTX-X E309TX-X E309LCbTX-X E309LTX-X E309MoTX-X E309LMoTX-X E309LNiMoTX-X E310TX-X E312TX-X E316TX-X E316LTX-X E317LTX-X E347TX-X E409TX-Xe E410TX-X E410NiMoTX-X E410NiTiTX-Xe E430TX-X W30731 W30831 W30835 W30831 W30832 W30838 W30931 W30932 W30935 W30939 W30938 W30936 W31031 W31331 W31631 W31635 W31735 W34731 W40931 W41031 W41036 W41038 W43031 0.13 0.08 0.04 0.04–0.08 0.08 0.04 0.10 0.04 0.04 0.12 0.04 0.04 0.20 0.15 0.08 0.04 0.04 0.08 0.10 0.12 0.06 0.04 0.10 18.0–20.5 18.0–21.0 18.0–21.0 18.0–21.0 18.0–21.0 18.0–21.0 22.0–25.0 22.0–25.0 22.0–25.0 21.0–25.0 21.0–25.0 20.5–23.5 25.0–28.0 28.0–32.0 17.0–20.0 17.0–20.0 18.0–21.0 18.0–21.0 10.5–13.5 11.0–13.5 11.0–12.5 11.0–12.0 15.0–18.0 9.0–10.5 9.0–11.0 9.0–11.0 9.0–11.0 9.0–11.0 9.0–12.0 12.0–14.0 12.0–14.0 12.0–14.0 12.0–16.0 12.0–16.0 15.0–17.0 20.0–22.5 8.0–10.5 11.0–14.0 11.0–14.0 12.0–14.0 9.0–11.0 0.60 0.60 4.0–5.0 3.6–4.5 0.60 Mo Nb + Ta Mn Si P S N Cu 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 0.50 1.0 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.03 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.03 0.04 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 — — — — — — — — — — — — — — — — — — — — — — — 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Gas Shielded Flux Cored Arc Welding 0.5–1.5 0.5 0.5 0.5 2.0–3.0 2.0–3.0 0.5 0.5 0.5 2.0–3.0 2.0–3.0 2.5–3.5 0.5 0.5 2.0–3.0 2.0–3.0 3.0–4.0 0.5 0.5 0.5 0.40–0.70 0.5 0.5 — — — — — — — 0.70–1.00 — — — — — — — — — Note h — — — — — 3.30–4.75 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 1.0–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.80 1.20 1.00 0.70 1.20 (continued) 24 --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Table 3-4—Chemical Composition Requirements for Stainless Steel Flux Cored Arc Welding and Flux Cored Gas Tungsten Arc Welding Filler Metalsa (Continued) Composition, wt.%b AWS Classificationc UNS Numberd C Cr E502TX-X E505TX-X W50231 W50431 0.10 0.10 4.0–6.0 8.0–10.5 E307T0-3 E308T0-3 E308LT0-3 E308HT0-3 E308MoT0-3 E308LMoT0-3 E308HMoT0-3 E309T0-3 E309LT0-3 E309LCbT0-3 E309MoT0-3 E309LMoT0-3 E310T0-3 E312T0-3 E316T0-3 E316LT0-3 E316LKT0-3f E317LT0-3 E347T0-3 Ni Mo Nb + Ta Mn Si P S N Cu 1.0 1.0 0.04 0.04 0.03 0.03 — — 0.5 0.5 1.0 1.0 1.0 1.0 1.0 1.0 0.25–0.80 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.03 0.04 0.04 0.04 0.04 0.04 0.04 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 — — — — — — — — — — — — — — — — — — — 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Gas Shielded Flux Cored Arc Welding (Continued) 0.40 0.40 0.45–0.65 0.85–1.20 — — 1.20 1.20 Self-Shielded Flux Cored Arc Welding W30733 W30833 W30837 W30833 W30839 W30838 W30830 W30933 W30937 W30934 W30939 W30938 W31031 W31231 W31633 W31637 W31630 W31737 W34733 0.13 0.08 0.03 0.04–0.08 0.08 0.03 0.07–0.12 0.10 0.03 0.03 0.12 0.04 0.20 0.15 0.08 0.03 0.04 0.03 0.08 19.5–22.0 19.5–22.0 19.5–22.0 19.5–22.0 18.0–21.0 18.0–21.0 19.0–21.5 23.0–25.5 23.0–25.5 23.0–25.5 21.0–25.0 21.0–25.0 25.0–28.0 28.0–32.0 18.0–20.5 18.0–20.5 17.0–20.0 18.5–21.0 19.0–21.5 9.0–10.5 9.0–11.0 9.0–11.0 9.0–11.0 9.0–11.0 9.0–12.0 9.0–10.7 12.0–14.0 12.0–14.0 12.0–14.0 12.0–16.0 12.0–16.0 20.0–22.5 8.0–10.5 11.0–14.0 11.0–14.0 11.0–14.0 13.0–15.0 9.0–11.0 0.5–1.5 0.5 0.5 0.5 2.0–3.0 2.0–3.0 1.8–2.4 0.5 0.5 0.5 2.0–3.0 2.0–3.0 0.5 0.5 2.0–3.0 2.0–3.0 2.0–3.0 3.0–4.0 0.5 — — — — — — — — — 0.70–1.00 — — — — — — — — Note h 3.30–4.75 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 1.25–2.25 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 1.0–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 (continued) Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 25 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 3-4—Chemical Composition Requirements for Stainless Steel Flux Cored Arc Welding and Flux Cored Gas Tungsten Arc Welding Filler Metalsa (Continued) Composition, wt.%b AWS Classificationc UNS Numberd C Cr E409T0-3e E410T0-3 E410NiMoT0-3 E410NiTiT0-3e E430T0-3 E2209T0-X E2553T0-X W40931 W41031 W41036 W41038 W43031 W39239 W39533 0.10 0.12 0.06 0.04 0.10 0.04 0.04 10.5–13.5 11.0–13.5 11.0–12.5 11.0–12.0 15.0–18.0 21.0–24.0 24.0–27.0 EXXXTX-Gg Unspecified — — Ni Mo Nb + Ta Mn Si P S N Cu 1.00 1.00 1.00 0.50 1.00 1.00 0.75 0.04 0.04 0.04 0.03 0.04 0.04 0.04 0.03 0.03 0.03 0.03 0.03 0.03 0.03 — — — — — 0.08–0.20 0.10–0.20 0.5 0.5 0.5 0.5 0.5 0.5 1.5–2.5 — — — — — 1.20 1.20 1.20 1.20 0.04 0.04 0.04 0.04 0.03 0.03 0.03 0.03 — — — — 0.5 0.5 0.5 0.5 0.60 0.60 4.0–5.0 3.6–4.5 0.60 7.5–10.0 8.5–10.5 0.5 0.5 0.40–0.70 0.5 0.5 2.5–4.0 2.9–3.9 — — — — — — — 0.80 1.00 1.00 0.70 1.00 0.5–2.0 0.5–1.5 Special Category Flux Cored Arc Welding — — — — Flux Cored Gas Tungsten Arc Welding R308LT1-5 R309LT1-5 R316LT1-5 R347T1-5 W30835 W30935 W31635 W34731 0.03 0.03 0.03 0.08 18.0–21.0 22.0–25.0 17.0–20.0 18.0–11.0 9.0–11.0 12.0–14.0 11.0–14.0 9.0–11.0 0.5 0.5 2.0–3.0 0.5 — — — Note h 0.5–2.5 0.5–2.5 0.5–2.5 0.5–2.5 --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Self-Shielded Flux Cored Arc Welding (Continued) Notes: a. The weld metal shall be analyzed for the specific elements in this table. If the presence of other elements is indicated in the course of this work, the amount of those elements shall be determined to ensure that their total (excluding iron) does not exceed 0.50%. b. Single values shown are maximum percentages. c. In this table, the “X” following the “T” refers to the position of welding (1 for all-position operation or 0 for flat or horizontal operation) and the “X” following the hyphen refers to the shielding medium (-1 for carbon dioxide, -3 for none (self-shielded), -4 for 75–80% argon/25–20% carbon dioxide, or -5 for 100% argon). Also see footnote g. d. ASTM/SAE Unified Number System for Metals and Alloys. e. 10 × %C Ti min, 1.5% Ti max. f. This alloy is designed for cryogenic applications. g. For information concerning the “G” following the hyphen, see AWS A5.22, Annex items A2.3.7 and A2.3.8. h. 8 × %C (Nb + Ta) min, 1.0% (Nb + Ta) max. 26 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT As shown in Table 3-5, electrodes with a -1, -4, or -5 suffix require external gas shielding, while a -3 suffix denotes self-shielding (refer to the categories of “Gas-Shielded” and “Self-Shielded” in Table 3-4). The “-G” suffix denotes general, or that the shielding medium is not specified. The “X” following the “T” designates the position of welding; a “0” indicates flat or horizontal only; a “1” indicates all positions. typically used for making root pass welds from one side with the GTAW or PAW process. The inserts produce consistent, high-quality weld shapes on both pipe and tube. Figure 3-1 shows cross sections of the five classes of consumable insert shapes available (some are shown as continuous rings, while others are shown as split rings). Recommended Filler Metals AWS A5.30 Table 3-5—External Shielding Medium, Polarity, and Welding Process AWS Designationa EXXXTX-1 EXXXTX-3 EXXXTX-4 RXXXT1-5 EXXXTX-Gc RXXXT1-Gc External Shieldingb Welding Polarity Welding Process 100% carbon dioxide (CO2) None (self-shielded) 75–80% Ar, remainder CO2 100% argon (Ar) Not specified Not specified dcep dcep dcep dcen Not specified Not specified FCAW FCAW FCAW GTAW FCAW GTAW Filler Metals for Use with Dissimilar Base Metals When welding dissimilar base metals together, it is typical to use a filler metal that is available for the higher composition base metal; however, this procedure does not always work. Table 3-9 provides the recommended filler metals for welding various stainless steels together. Types 308, 309, and 310 are used for many dissimilar base metal combinations. In addition, Types 309 and 310 are also good for welding many austenitic stainless steel base metals to carbon and alloy steels. Type 308 would not be used in this case, because there is not enough nickel in the diluted weld metal, and the Notes: a. The letters “XXX” stand for the designation of the chemical composition. The “X” after the “T” designates the position of operation. A “0” indicates flat or horizontal operation; a “1” indicates all-position operation. b. A restrictive requirement only for classification tests; suitability may be determined for other applications. c. For more information, see Annex items A2.3.7 and A2.3.8 in AWS A5.22. Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Recommended filler metals for welding various austenitic stainless steel base metals (both wrought and cast base metals) are shown in Table 3-7. Table 3-8 lists the recommended filler metals for welding precipitation-hardened stainless steel base metals. Of the few filler metals available for welding martensitic and ferritic stainless steels, Types 410 and 430 are most often used. For duplex stainless steels, filler metals such as Type 2209 are available. For superaustenitic and superferritic stainless steels, filler metals of the same (or nearly the same) composition are typically used. Most of these steels are welded with gas shielded processes (GMAW or GTAW) or beam processes (electron or laser beam). Table 3-6 lists the chemical compositions of austenitic stainless steel consumable inserts described in AWS A5.30. The “IN” classification denotes insert (several stainless steel consumable inserts are available). Consumable inserts are made up of filler metal that has been formed into various shapes. These inserts are preplaced into the weld joint and 27 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 3-6—Chemical Composition Requirements for Stainless Steel Consumable Inserts Composition, wt.%a,b UNS Numberc C Cr Ni Mo Nb + Ta Mn Si P S Cu C IN308d S30880 0.08 19.5–22.0 9.0–11.0 0.75 — 1.0–2.5 0.30–0.65 0.03 0.03 0.75 IN308Ld S30883 0.03 19.5–22.0 9.0–11.0 0.75 — 1.0–2.5 0.30–0.65 0.03 0.03 0.75 IN309d S30980 0.12 23.0–25.0 12.0–14.0 0.75 — 1.0–2.5 0.30–0.65 0.03 0.03 0.75 IN309Ld S30983 0.03 23.0–25.0 12.0–14.0 0.75 — 1.0–2.5 0.30–0.65 0.03 0.03 0.75 IN310 S31080 0.08–0.15 25.0–28.0 20.0–22.5 0.75 — 1.0–2.5 0.30–0.65 0.03 0.03 0.75 IN312d S31380 0.15 28.0–32.0 8.0–10.5 0.75 — 1.0–2.5 0.30–0.65 0.03 0.03 0.75 IN316d S31680 0.08 18.0–20.0 11.0–14.0 2.0–3.0 — 1.0–2.5 0.30–0.65 0.03 0.03 0.75 IN316Ld S31683 0.03 18.0–20.0 11.0–14.0 2.0–3.0 — 1.0–2.5 0.30–0.65 0.03 0.03 IN348d S34780 0.08 19.0–21.5 9.0–11.0 0.75 e10 × C mine 1.0–2.5 0.30–0.65 0.03 0.03 –1.0 max Notes: a. The consumable insert shall be analyzed for the specific elements for which values are shown in this table. b. Single values shown are maximum. c. ASTM/SAE Unified Numbering System for Metals and Alloys. d. Delta ferrite may be specified upon agreement between supplier and purchaser. e. Tantalum content shall not exceed 0.10 percent. (Nb is the same as Cb.) 28 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Group AWS Classification 0.75 0.75 Brazing Filler Metals Tables 3-10 through 3-15 list the brazing filler metals available for brazing of stainless steels (as described in AWS A5.8). Stainless steels are often brazed with silver, gold, cobalt, or nickel brazing filler metals. (The “B” classification designates brazing filler metal.) Figure 3-1—Standard Consumable Insert Designs Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- weld can produce enough martensite to be susceptible to cold cracking. Types 309 and 310 filler metals contain greater amounts of nickel; therefore, when diluted with the carbon or alloy steel, this higher level of nickel does not allow much martensite to form, which greatly reduces the chances of cold cracking. When dissimilar welds are made—for example, between carbon steel and Type 304—it is best to use a “buttering technique” of Type 309 or 310 filler metal on the carbon steel joint. After the weld joint is prepared, the buttered surface can then be welded to the Type 304 base metal. The highnickel content of Types 309 or 310 filler metal provides the carbon steel with improved ductility. When welded to the Type 304 base metal, the Type 309 or 310 filler metal dramatically reduces the chances of cold cracking. When hot cracking of austenitic stainless steels is a concern, Type 312 filler metal is the best choice, because it forms more ferrite than Types 308, 309, or 310. However, in some cases, the high ferrite content can decrease toughness (at cryogenic temperatures) or cause problems because of its magnetic properties (if the material was selected for nonmagnetic purposes). When it is necessary to weld martensitic stainless steels without postweld heat treatment, or in cases where ferritic stainless steels are welded but there is no matching filler metal, Types 309 or 310 filler metals are often used. Since the austenitic stainless steel provides much greater ductility in the weld metal than the martensitic or ferritic stainless steel base metal, there is less chance of cracking. 29 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 3-7—Recommended Filler Metals for Welding Austenitic Stainless Steels Type of Stainless Steel Wrought 201, 202 301, 302, 304, 305 304L 309 309S 310, 314 310S 316 316L 316H 317 317L 321 330 347, 348 Recommended Filler Metals Casta SMAWb GMAW, GTAW, PAW, SAWc FCAWd — CF-20, CF-8 CF-3 CH-20 — CK-20 — CF-8M CF-3M CF-12M — — — HT CF-8C eE209, E219, E308 e ER209, E219, E308 e ER308 e ER308L ER309 ER309L ER310 ER310 ER316 e ER316L ER16-8-2, ER316H ER317 ER317L ER321 ER330 ER347 E308TX-X e E308TX-X e E308LTX-X E309TX-X E309LTX-X, E309CbLTX-X E310TX-X E310TX-X E316TX-X e E316LTX-X E316TX-X E317LTX-X E317LTX-X E347TX-X — E347TX-X E308 e E308L E309 E309L, E309Cb E310 E310, E310Cb E316 e E316L E16-8-2, E316H E317 E317L E347 E330 E347 Notes: a. Castings higher in carbon but otherwise of generally corresponding compositions are available in heat-resisting grades. These castings carry the “H” designation (HF, HH, and HK, for instance). Electrodes best suited for welding these high-carbon versions are the standard electrodes recommended for the corresponding lower carbon corrosion-resistant castings shown above. b. Covered electrodes for shielded metal arc welding (SMAW). c. Bare welding rods and electrodes for gas metal arc (GMAW), gas tungsten arc (GTAW), plasma arc (PAW), and submerged arc (SAW) welding. Higher silicon versions (e.g., ER308LSi) are also classified and are often preferred for better wetting and fluidity in GMAW. d. Tubular electrodes for flux cored arc welding (FCAW). (See Table 3-4.) e. Low carbon versions of these filler metals may also be used. 30 --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 3-8—Recommended Filler Metals for Welding Precipitation-Hardening Stainless Steels Covered Electrodes Base Metal Designation UNS Number AMSa AWSb Bare Welding Wires AWSc Dissimilar PH Stainless Steels (AWS) ER630 ER630 E308, ER308, E309, ER309, E309Cb, ER309Cb E308, ER308, E309, ER309, E309Cb, ER309Cb ER630 ER630 ER630 ER630 E310, ER 310, ENiCrFe-2d, ERNiCr-3e E308, E309, ER309, E310, ER310 E308, ER308, E309, ER309 E308, ER308, E309, ER309 ERNiCrFe-6e, ERNiMo-3e E309, ER309, E310, ER310 AMS Martensitic Types 17-4 PH 15-5 PH S17400 S15500 5827B (17-4PH) 5827B (17-4PH) E630 E630 5826 (17-4 PH) 5826 (17-4 PH) 17-7 PH PH 15-7 Mo AM 350 AM 355 S17700 S15700 S35000 S35500 5827B (17-4 PH) 5775A (AM 350) 5781A (AM 355) E630 E630 E630 E630 5824A (17-7 PH) 5812C (PH 15-7 Mo) 5774B (AM 350) 5780A (AM 355) Austenitic Type A286 S66286 E309, E310 5805C (A286) Notes: a. AMS refers to Aerospace Materials Specification (published by SAE). b. See AWS A5.4, Specification for Stainless Steel Electrodes for Shielded Metal Arc Welding. c. See AWS A5.9, Specification for Bare Stainless Steel Welding Electrodes and Rods. d. See AWS A5.11, Specification for Nickel and Nickel Alloy Welding Electrodes for Shielded Metal Arc Welding. e. See AWS A5.14, Specification for Nickel and Nickel Alloy Bare Welding Electrodes and Rods. Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 31 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Semiaustenitic Types Table 3-9—Suggested Filler Metals for Welds Between Dissimilar Austenitic Stainless Steelsa 316H 316H 316L 317 308 309 310 308 316 308 316 b308 b 310 308 b 309 b 310 308 309 310 308 309 310 309 310 309 310 AISI Type 304L 308 309 309S 310 310S 304, 304H, 305 308 b 308 308 309 308 309 308 309 310 b308 b b308 b b308 b b308 b b308 b 308 309 309 304L 308 b309 b b309 b 309 b309 b b309 b 310 321H 321H 347, 347H 348, 348H 308 316 317 308 347 308 347 L308L L316L 308 316 317 L308L 347 L308L 347 308 316 b308 b b316 b 308 316 317 308 347 308 347 309 316 309 316 309 316 309 347 309 347 316 310 310Mo 316 Mo310Mo 310 317 Mo310Mo 310 308 310 308 310 b316 b 317 316 308 316 347 316 347 b317 b L316L 347 L316L 347 308 317 317 347 b316 b 316, 316H 316L 317 317, 321H 347 Notes: a. Electrodes and welding rods listed are not in any preferred order. b. Low carbon grades of these filler metals may also be used. 32 --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 3-10—Compositions of Silver Filler Metals for Brazing of Stainless Steels Composition, wt.% AWS Classificationa UNS Numberb Ag Cu Zn Cd Ni Sn Li Mn Total, Other Elementsc BAg-1 P07450 44.0–46.0 14.0–16.0 14.0–18.0 23.0–25.0 — — — — 0.15 BAg-1a P07500 49.0–51.0 14.5–16.5 14.5–18.5 17.0–19.0 — — — — 0.15 BAg-2 P07350 34.0–36.0 25.0–27.0 19.0–23.0 17.0–19.0 — — — — 0.15 — BAg-2a P07300 29.0–31.0 26.0–28.0 21.0–25.0 19.0–21.0 — — — BAg-3 P07501 49.0–51.0 14.5–16.5 13.5–17.5 15.0–17.0 2.5–3.5 — — 0.15 BAg-4 P07400 39.0–41.0 29.0–31.0 26.0–30.0 — 1.5–2.5 — — — 0.15 BAg-5 P07453 44.0–46.0 29.0–31.0 23.0–27.0 — — — — — 0.15 BAg-6 P07503 49.0–51.0 33.0–35.0 14.0–18.0 — — — — — 0.15 BAg-7 P07563 55.0–57.0 21.0–23.0 15.0–19.0 — — 4.5–5.5 — — 0.15 BAg-8 P07720 71.0–73.0 Bal. — — — — — — 0.15 BAg-8a P07723 71.0–73.0 Bal. — — — — — 0.25–0.50 0.15 BAg-9 P07650 64.0–66.0 19.0–21.0 13.0–17.0 — — — — — 0.15 0.15 0.15 BAg-10 P07700 69.0–71.0 19.0–21.0 8.0–12.0 — — — — — BAg-13 P07540 53.0–55.0 Bal. 4.0–6.0 — 0.5–1.5 — — — 0.15 BAg-13a P07560 55.0–57.0 Bal. — — 1.5–2.5 — — — 0.15 BAg-18 P07600 59.0–61.0 Bal. — — — 9.5–10.5 — — 0.15 BAg-19 P07925 92.0–93.0 19.0–21.0 26.0–30.0 — 1.5–2.5 — — 0.15–0.30 0.15 BAg-20 P07301 29.0–31.0 37.0–39.0 30.0–34.0 — — — — — 0.15 BAg-21 P07630 62.0–64.0 27.5–29.5 — — 2.0–3.0 5.0–7.0 — — 0.15 BAg-22 P07490 48.0–50.0 15.0–17.0 21.0–25.0 — 4.0–5.0 — 7.0–8.0 — 0.15 BAg-23 P07850 84.0–86.0 — — — — — Rem — 0.15 (continued) --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 33 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 3-10—Compositions of Silver Filler Metals for Brazing of Stainless Steels (Continued) Composition, wt.% Li Mn Total, Other Elementsc — — — 0.15 — 1.5–2.5 — 0.15 — — — — 0.15 — — 1.5–2.5 — — 0.15 26.5–28.5 — — — — — 0.15 26.0–30.0 — — 1.5–2.5 — — 0.15 31.0–33.0 31.0–35.0 — — — — — 0.15 26.0–28.0 23.0–27.0 — — 2.5–3.5 — — 0.15 39.0–41.0 31.0–35.0 — — 1.5–2.5 — — 0.15 AWS Classificationa UNS Numberb Ag Cu Zn Cd Ni Sn BAg-24 P07505 49.0–51.0 19.0–21.0 26.0–30.0 — 1.5–2.5 BAg-26 P07250 24.0–26.0 37.0–39.0 31.0–35.0 — 1.5–2.5 BAg-27 P07251 24.0–26.0 34.0–36.0 24.5–28.5 12.5–14.5 BAg-28 P07401 39.0–41.0 29.0–31.0 26.0–30.0 BAg-33 P07252 24.0–26.0 29.0–31.0 BAg-34 P07380 37.0–39.0 31.0–33.0 BAg-35 P07351 34.0–36.0 BAg-36 P07454 44.0–46.0 BAg-37 P07253 24.0–26.0 Notes: a. For more information on these and similar filler metals for vacuum service (e.g., BVAg-8b), see AWS A5.8, Specification for Filler Metals for Brazing and Braze Welding. b. ASTM/SAE Unified Numbering System for Metals and Alloys. c. The brazing filler metal shall be analyzed for those specific elements for which values are shown in this table. If the presence of other elements is indicated in the course of this work, the amount of those elements shall be determined to ensure that their total does not exceed the limit specified. 34 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT AWS Classification Solidus Temperaturea Liquidus Temperaturea Brazing Temperature Range °F °F °C °F °C Color Other Characteristics Free-flowing °C BAg-1 1125 607 1145 618 1145–1400 618–760 whitish yellow BAg-1a 1160 627 1175 635 1175–1400 635–760 whitish yellow Free-flowing BAg-2 1125 607 1295 702 1295–1550 702–843 light yellow Good for nonuniform clearance BAg-2a 1125 607 1310 710 1310–1550 710–843 — — BAg-3 1170 632 1270 688 1270–1500 688–816 whitish yellow Retards corrosion at joint BAg-4 1240 671 1435 779 1435–1650 779–899 light yellow Flows better than BAg3 BAg-5 1225 663 1370 743 1370–1550 743–843 light yellow Not free-flowing, cadmium-free, useful in food industry BAg-6 1270 688 1425 774 1425–1600 774–871 light yellow Similar to BAg5 BAg-7 1145 618 1205 652 1205–1400 652–760 white Good color match BAg-8 1435 779 1435 779 1435–1650 779–899 white Wetting is slow BAg-8a 1410 766 1410 766 1410–1600 766–871 white For furnace brazing PH SS --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Table 3-11—Characteristics of Silver Filler Metals for Brazing of Stainless Steels BAg-9 1240 671 1325 718 1325–1550 718–843 — — BAg-10 1275 691 1360 738 1360–1550 738–843 — — BAg-13 1325 718 1575 857 1575–1775 857–968 white Useful to 700°F (371°C) BAg-13a 1420 771 1640 893 1600–1800 871–982 — — BAg-18 1115 602 1325 718 1325–1550 718–843 white Wets well for brazing PH SS BAg-19 1400 760 1635 891 1610–1800 877–982 white Good for furnace brazing BAg-20 1250 677 1410 766 1410–1600 766–871 — — BAg-21 1275 691 1475 802 1475–1650 802–899 — Immune to crevice corrosion BAg-22 1260 682 1290 699 1290–1525 699–829 — Low temperature, good wettability on carbides (continued) Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 35 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 3-11—Characteristics of Silver Filler Metals for Brazing of Stainless Steels (Continued) Solidus Temperaturea Liquidus Temperaturea Brazing Temperature Range °F °C °F °C °F BAg-23 1760 960 1780 971 1780–1900 971–1038 — — BAg-24 1220 660 1305 707 1305–1550 707–843 — Low melting, cadmium free torch alloy BAg-26 1305 707 1475 800 1475–1600 802–871 — Moderately low temperature, low silver, good wettability on stainless BAg-27 1125 607 1375 746 1375–1575 746–857 — — BAg-28 1200 649 1310 710 1310–1550 710–843 — — BAg-33 1125 607 1260 682 1260–1400 682–760 — — BAg-34 1200 649 1330 721 1330–1550 721–843 — Free flowing, cadmium free torch alloy BAg-35 1265 685 1390 754 1390–1545 754–841 — — 1195 646 1251 677 1251–1495 677–813 — — 1270 688 1435 779 1435–1625 779–885 — — 1761 961 1761 961 1761–1900 961–1038 — — 1435 779 1602 872 1600–1800 871–982 — — 1435 779 1435 779 1435–1650 779–899 — — 1435 779 1463 795 1470–1650 799–899 — — 1115 602 1325 718 1325–1550 718–843 — — AWS Classification BAg-37 BVAg-0 BVAg-6 BVAg-8 BVAg-8b BVAg-18 BVAg-29 --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- BAg-36 °C Color Other Characteristics 1155 624 1305 707 1305–1450 707–788 — — BVAg-30 1485 807 1490 810 1490–1700 810–927 — — BVAg-31 1515 824 1565 852 1565–1625 852–885 — — BVAg-32 1650 899 1740 949 1740–1800 949–982 — — Note: a. Solidus and liquidus shown are for the nominal composition in each classification. 36 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 3-12—Compositions of Nickel and Cobalt Filler Metals for Brazing of Stainless Steels Composition, wt.%a Ni P S Al Ti Mn Cu Zr W Co BNi-1 N99600 Bal. 13.0–15.00 2.75–3.50 4.0–5.0 4.0–5.0 0.60–0.90 0.02 0.02 0.05 0.05 — — 0.05 — 0.10 0.005 0.50 BNi-1a N99610 Bal. 13.0–15.00 2.75–3.50 4.0–5.0 4.0–5.0 0.06 0.02 0.02 0.05 0.05 — — 0.05 — 0.10 0.005 0.50 BNi-2 N99620 Bal. 6.0–8.00 2.75–3.50 4.0–5.0 2.5–3.5 0.06 0.02 0.02 0.05 0.05 — — 0.05 — 0.10 0.005 0.50 BNi-3 N99630 Bal. — 2.75–3.50 4.0–5.0 0.5 0.06 0.02 0.02 0.05 0.05 — — 0.05 — 0.10 0.005 0.50 BNi-4 N99640 Bal. — 1.50–2.20 3.0–4.0 1.5 0.06 0.02 0.02 0.05 0.05 — — 0.05 — 0.10 0.005 0.50 BNi-5 N99650 Bal. 18.5–19.50 0.03 9.75–10.50 — 0.06 0.02 0.02 0.05 0.05 — — 0.05 — 0.10 0.005 0.50 BNi-5a N99651 Bal. 18.5–19.50 1.0–1.5 7.0–7.5 0.5 0.10 0.02 0.02 0.05 0.05 — — 0.05 — 0.10 0.005 0.50 BNi-6 N99700 Bal. — — — — 0.06 10.0–12.0 0.02 0.05 0.05 — — 0.05 — 0.10 0.005 0.50 BNi-7 N99710 Bal. 13.0–15.00 0.01 0.10 0.2 0.06 9.7–10.5 0.02 0.05 0.05 0.04 — 0.05 — 0.10 0.005 0.50 BNi-8 N99800 Bal. — — 6.0–8.0 — 0.06 0.02 0.02 0.05 0.05 12.5– 24.50 4.0– 5.00 0.05 — 0.10 0.005 0.50 BNi-9 N99612 Bal. 13.5–16.50 3.25–4.00 1.5 0.06 0.02 0.02 0.05 0.05 — — 0.05 — 0.10 0.005 0.50 BNi-10 N99622 Bal. 10.0–13.00 2.0–3.0 3.0–4.0 2.5–4.5 0.40–0.55 0.02 0.02 0.05 0.05 — — 0.05 15.0–17.0 0.10 0.005 0.50 BNi-11 N99624 Bal. 9.00–11.75 2.2–3.1 3.35–4.25 2.5–4.0 0.30–0.50 0.02 0.02 0.05 0.05 — — 0.05 11.5–12.75 0.10 0.005 0.50 BCo-1 R39001 16.0– 18.0–20.00 0.70–0.90 18.00 7.5–8.5 0.02 0.02 0.05 0.05 — — 0.05 0.50 --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- AWS ClassiUNS fication Numberb Cr B Si — Fe 1.0 C 0.35–0.45 3.5–4.5 Bal. Se 0.005 Total, Other Elementsc Notes: a. Single values are maximum percentages. 0.10% Co max and 0.005% Se max for the BN series. b. ASTM/SAE Unified Numbering System for Metals and Alloys. c. The filler metal shall be analyzed for those specific elements for which values are shown in this table. If the presence of other elements is indicated in the course of this work, the amount of those elements shall be determined to ensure that their total does not exceed the limit specified. Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 37 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 3-13—Characteristics of Nickel and Cobalt Filler Metals for Brazing of Stainless Steels AWS Classification Solidus Temperaturea Liquidus Temperaturea Brazing Temperature Range °F °F °C °F °C 1038 1077 999 1038 1066 1135 1155 877 888 1010 1054 1104 1095 1950–2200 1970–2200 1850–2150 1850–2150 1850–2150 2100–2200 2100–2200 1700–2000 1700–2000 1850–2000 1950–2200 2100–2200 2100–2200 1066-1204 1077-1204 1010–1177 1010–1177 1010–1177 1149–1204 1149–1204 927–1093 927–1093 1010–1093 1066–1204 1149–1204 1149–1204 1149 2100–2250 1149–1232 °C Nickel Filler Metals BCo-1 --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- BNi-1 BNi-1a BNi-2 BNi-3 BNi-4 BNi-5 BNi-5a BNi-6 BNi-7 BNi-8 BNi-9 BNi-10 BNi-11 1790 1790 1780 1800 1800 1975 1931 1610 1630 1800 1930 1780 1780 977 977 971 982 982 1079 1055 877 888 982 1054 971 971 1900 1970 1830 1900 1950 2075 2111 1610 1630 1850 1930 2020 2003 Cobalt Filler Metal 2050 1121 2100 Note: a. Solidus and liquidus shown are for the nominal composition in each classification. 38 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 3-14—Compositions of Gold Filler Metals for Brazing of Stainless Steels Composition, wt.% AWS Classificationa --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- BAu-1 BAu-2 BAu-3 BAu-4 BAu-5 BAu-6 UNS Numberb Au Cu Pd Ni Total, Other Elementsc P00375 P00800 P00350 P00820 P00300 P00700 37.0–38.0 79.5–80.5 34.5–35.5 81.5–82.5 29.5–30.5 69.5–70.5 Bal. Bal. Bal. — — — — — — — 33.5–34.5 7.5–8.5 — — 2.5–3.5 Bal. 35.5–36.5 21.5–22.5 0.15 0.15 0.15 0.15 0.15 0.15 Notes: a. For more information on these and similar filler metals for vacuum service (e.g., BVAg-8b), see AWS A5.8, Specification for Filler Metals for Brazing and Braze Welding. b. ASTM/SAE Unified Numbering System for Metals and Alloys. c. The brazing filler metal shall be analyzed for those specific elements for which values are shown in this table. If the presence of other elements is indicated in the course of this work, the amount of those elements shall be determined to ensure that their total does not exceed the limit specified. Table 3-15—Characteristics of Gold Filler Metals for Brazing of Stainless Steels Solidus Temperaturea Liquidus Temperaturea Brazing Temperature Range AWS Classification °F °C °F °C °F °C BAu-1 BAu-2 BAu-3 BAu-4 BAu-5 BAu-6 BVAu-2 BVAu-4 BVAu-7 BVAu-8 1815 1635 1785 1740 2075 1845 1635 1740 2015 2190 991 891 974 949 1135 1007 891 949 1102 1199 1860 1635 1885 1740 2130 1915 1635 1740 2050 2265 1016 891 1029 949 1166 1046 891 949 1121 1241 1860–2000 1635–1850 1885–1995 1740–1840 2130–2250 1915–2050 1635–1850 1740–1840 2050–2110 2265–2325 1016–1093 891–1010 1029–1091 949–1004 1166–1232 1046–1121 891–1010 949–1004 1121–1154 1241–1274 Note: a. Solidus and liquidus shown are for the nominal composition in each classification. Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 39 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Chapter 4—Preweld Cleaning and Preparation of Stainless Steels Cutting, Grinding, Prepping Preweld Cleaning All stainless steels need to be prepared without contamination. Any sources of free iron, rust, carbon, hydrogen, etc., can cause welding or corrosion problems. Therefore, the following guidelines should be followed: Regardless of the type of stainless steel to be used, it is imperative that the base metal be properly cleaned before welding. In most cases, this involves: (1) Thermal cutting should be done with the appropriate process (not oxyfuel). (2) If machining is performed, it should be done without overheating the base metal, which could cause oxidation. (3) Mechanical grinding should be done with grinding wheels that are segregated for use on stainless steels. (4) All hand tools should be segregated for use on stainless steels only (e.g., deburring knives, files). (5) All wire brushes should be made of stainless steel, and used only on stainless steels. Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Welding Preparation --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- (1) Wire brush or grind to remove any oxidation (which may be present on hot rolled parts). (2) Chemically clean all surfaces that were machine-cut with cutting fluids. (3) Remove all grease, oil, moisture, etc. (4) Wipe all surfaces to be welded with acetone or isopropyl alcohol. (1) Weld in an area segregated from the welding of other alloys, especially carbon and low-alloy steels. (2) Cover welding tables with stainless steel, aluminum, or other material to protect the stainless steel parts from contamination. (3) Use vises, hold-down fixtures and tools, clamps, etc., made of stainless steel or covered with protective material (stainless steel, tape, etc.). 41 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Chapter 5—Welding and Cutting of Stainless Steels Basic Fusion Welding Behavior welding parameters, as shown in Figure 5-2, significantly less heat will be conducted away from the weld. This produces a much larger weld bead on austenitic stainless steels than on low carbon steels. The martensitic and ferritic stainless steels have thermal conductivities approximately 1/2 that of carbon steels. The weld beads made with these same parameters will produce a larger weld than on carbon steel, but smaller than on the austenitic stainless steel. To produce a similar size weld bead on each material, a lower current (lower heat input) would be used on the martensitic and ferritic stainless steels than on the carbon steel. The austenitics would require an even lower current and heat input. Welding stainless steels is inherently different from welding carbon and low-alloy steels. There are two major physical properties of stainless steels that dramatically affect their weldability—thermal conductivity and thermal coefficient of expansion. Figures 5-1 and 5-2 illustrate the effects of these properties on fusion welding (arc or beam welding). Thermal Conductivity Austenitic stainless steels have approximately 1/3 the thermal conductivity of low carbon steels; therefore, if they are welded with the same arc Type of Steel Thermal Conductivity* Type of Steel Main Coefficient of Thermal Expansion* Low Carbon Steel 35 Low Carbon Steel 6.5 410 Martensitic Stainless 430 Ferritic Stainless 15–17 410 Martensitic Stainless 430 Ferritic Stainless 6.5 304 Austenitic Stainless 11–13 304 Austenitic Stainless 10 *Btu/hr-ft-F *From 32–1000°F (micro-in./in.-F) Figure 5-1—Schematic Illustration of Weld Bead Produced with Arc Welds Made with the Same Parameters (Current, Voltage, and Travel Speed) on Different Materials Figure 5-2—Schematic Illustration of Distortion Produced with Arc Welds Made with the Same Parameters (Current, Voltage and Travel Speed) on Different Materials --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 43 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Thermal Expansion However, it is important to note that tables of parameters for arc or resistance welding of “stainless steels” refer to the austenitic stainless steels. Parameters for the ferritic and martensitic stainless steels would be about midway between those for the carbon steels and for austenitic stainless steels. There are also differences in the coefficients of thermal expansion of austenitic stainless steels, as compared with carbon steels. This property determines how much a metal expands when heated and shrinks when cooled. During welding, thermal expansion produces distortion. The higher the coefficient, the more expansion and contraction, and the greater the amount of distortion. General Welding Information Figures 5-1 and 5-2 illustrate that fusion welding parameters for austenitic stainless steels are significantly different from those for carbon steels. Recommended arc welding parameters for the austenitic stainless steels are cooler (lower current, faster travel speed, etc.) than those for carbon steels. This is due to the lower heat input required (from the low thermal conductivity), as well as to reduce the distortion (because of the higher thermal expansion). Shielding Pipe, tube, and vessels are normally shielded on the inside with inert shielding gas (such as argon or helium). There are also fluxes developed for stainless steels. These are applied to the backside of the weld before welding. This flux helps protect the backside of the weld from oxidation and contamination. However, these fluxes do not shield the weld underbead as well as inert gases, and should not be used in critical or high-purity applications. For resistance welding, the austenitics also have lower electrical conductivity (higher electrical resistance). This means that lower levels of current are required to produce a similar weld nugget in austenitic stainless steels as in carbon steels, which is reflected in the recommended resistance welding parameters for austenitic stainless steels. 44 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Stainless steels can be welded using all five joint types (butt, T, corner, lap, and edge), in all positions, and with any type of weld (groove, fillet, seam, etc.). Table 5-1 provides typical groove weld joint designs for austenitic stainless steels. All forms of stainless steel can be welded; however, the wrought forms (plate, bar, pipe, tube, etc.) are more weldable than cast versions. Castings contain high levels of silicon and other elements, which also tend to cause hot cracking. Higher carbon contents (such as those found in high-carbon cast austenitics or martensitics) are more difficult to weld than other stainless steels, due to the greater chance of cold cracks. As shown in Figure 5-2, austenitic stainless steels have a coefficient of thermal expansion approximately 50% higher than carbon steels, while martensitic and ferritic stainless steels are similar to the carbon steels. If the welding parameters are changed for the austenitic stainless steels to provide the same weld shape as in the carbon steels and the martensitic and ferritic stainless steels, the distortion will be significantly greater with the austenitic stainless steels. Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 5-1—Typical Groove Weld Joint Designs for Austenitic Stainless Steels Thickness Joint Design Square-groove, one-pass Square-groove, two-pass --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Single-V-grooveb Welding Processa in. Root Opening mm in. Root Face mm in. mm Groove Angle, Degrees SMAW 0.08–0.16 2.0–4.1 .0–0.08 .00–2.0 — — — GTAW 0.04–0.13 1.0–3.3 .0–0.08 .00–2.0 — — — GMAW 0.08–0.16 2.0–4.1 .0–0.08 .00–2.0 — — — SMAW 0.12–0.25 3.1–6.4 .0–0.08 .00–2.0 — — — GTAW 0.12–0.25 3.1–6.4 .0–0.04 .00–1.0 — — — GMAW 0.12–0.32 3.1–8.1 .0–0.04 .00–1.0 — — — SAW 0.15–0.32 3.8–8.1 0 0 — — — SMAW 0.12–0.50 3.1–12.70 .0–0.08 .00–2.0 0.06–0.12 1.5–3.1 60 GTAW 0.15–0.25 3.8–6.4 .0–0.01 .00–0.3 0.06–0.08 1.5–2.0 90 GTAW 0.25–0.63 6.4–16.0 .0–0.02 .00–0.5 0.04–0.06 1.0–1.5 70 GMAW 0.15–0.50 3.8–12.70 .0–0.08 .00–2.0 0.06–0.12 1.5–3.1 60 SAW 0.31–0.50 7.9–12.70 .0–0.08 .00–2.0 0.06–0.16 1.5–4.1 60 Single-U-groove GMAW ≥ 0.50 ≥ 12.70 .0–0.08 .00–2.0 0.08–0.12 2.0–3.1 c15c Double-V-grooveb SMAW 0.50–1.25 12.70–31.80 0.04–0.13 1.0–3.3 0.06–0.16 1.5–4.1 60 GMAW 0.50–1.25 12.70–31.80 .0–0.08 .00–2.0 0.08–0.12 2.0–3.1 60 SMAW Over 1.25 Over 31.8 0.04–0.08 1.0–2.0 0.08–0.12 2.0–3.1 10–15c SAW Double-U-groove Notes: a. SMAW, shielded metal arc welding; GTAW, gas tungsten arc welding; GMAW, gas metal arc welding; SAW, submerged arc welding. b. For welding in the horizontal position, the lower member should be beveled only 10–15 degrees, and the top member 45–55 degrees. c. Groove radius, 0.25– 0.31 in. (6.3–7.93 mm). Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 45 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Arc Welding Processes For weld repair on used or in-service stainless steels, proper grinding and cleaning is necessary to remove contaminants, acids, etc. Use of SMAW or FCAW, with their flux, may additionally help ‘clean’ the metal. There are two major shielding methods for arc welding processes: (1) Gas shielding—uses an external shielding gas to protect the arc and weld pool. While providing excellent protection from contamination from the air, this process does not “clean” or remove contaminants from the weld pool. (2) Flux shielding—uses a flux that forms a vapor to protect the arc and weld pool. The flux also “cleans” the weld pool by combining with contaminants (oxygen, sulfur, etc.) to form a slag that floats on the top surface of the weld pool. Although flux shielding provides good cleaning of the weld, it does not protect the weld from atmospheric contamination as well as the gas shielding processes. Arc Welding Figures and Tables Figure 5-3 and Tables 5-2–5-7 provide data for GMAW of (austenitic) stainless steels. Some of these tables include comparison data with other base metals. New stainless steels are often welded with the following processes: • GMAW • GTAW • PAW • SMAW • FCAW • SAW The shielding gas is typically argon or helium, although gas mixtures containing hydrogen, nitrogen, carbon dioxide, and oxygen have been used. The superaustenitic and superferritic stainless steels are almost exclusively welded with these processes, because the use of flux processes introduces too much oxygen and nitrogen (and other contaminants). Repair welding is often performed with: • SMAW • FCAW • GTAW Figure 5-3—Typical Welding Currents Versus Wire Feed Speeds for 300 Series Stainless Steel Electrodes 46 --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 5-2—GMAW Globular-to-Spray Transition Currents for a Variety of Electrodes --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Wire Electrode Diameter Wire Electrode Type in. mm Shielding Gas Minimum Spray Arc Current, A Mild Steel 0.030 0.035 0.045 0.062 0.8 0.9 1.1 1.6 98% Argon + 2% Oxygen 150 165 220 275 Stainless Steel 0.035 0.045 0.062 0.9 1.1 1.6 98% Argon + 2% Oxygen 170 225 285 Aluminum 0.030 0.045 0.062 0.8 1.1 1.6 Argon 95 135 180 Deoxidized Copper 0.035 0.045 0.062 0.9 1.1 1.6 Argon 180 210 310 Silicon Bronze 0.035 0.045 0.062 0.9 1.1 1.6 Argon 165 205 270 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 47 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 5-3—Typical Arc Voltages for GMAW of Various Metalsa Sprayb Globular Transfer 1/16 in. (1.6 mm) Diameter Electrode Short Circuiting Transfer 0.035 in. (0.9 mm) Diameter Electrode Argon Helium 75% He + 25% Ar Ar–O2 (1–5% O2) CO2 Argon Ar–O2 (1–5% O2) 75%Ar + 25% CO2 CO2 Aluminum Magnesium 25 26 30 — 29 28 — — — — 19 16 — — — — — — Carbon Steel Low-Alloy Steel Stainless Steel — — 24 — — — — — — 28 28 26 30 30 — 17 17 18 18 18 19 19 19 21 20 20 — Nickel Nickel-Copper Alloy Nickel-Chromium-Iron Alloy 26 26 26 30 30 30 28 28 28 — — — — — — 22 22 22 — — — — — — — — — Copper Copper-Nickel Alloy 30 28 36 32 33 30 — — — — 24 23 22 — — — — — Silicon Bronze Aluminum Bronze Phosphor Bronze 28 28 28 32 32 32 30 30 30 28 — 23 — — — 23 23 23 — — — — — — — — — Metal Notes: a. Plus or minus approximately 10%. The lower voltages are normally used on light material and at low amperage; the higher voltages are used on heavy material at high amperage. b. For the pulsed variation of spray transfer, the arc voltage would be from 18–28 volts, depending on the amperage range used. 48 --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 5-4—GMAW Shielding Gases for Spray Transfer Metal Shielding Gas Thickness Aluminum 100% Argon 0 to 1 in. (0 to 25 mm)0 Best metal transfer and arc stability; least spatter 65% Helium + 35% Argon 1 to 3 in. (25 to 76 mm) Higher heat input than straight argon; improved fusion characteristics with 5XXX series Al-Mg alloys 75% Helium + 25% Argon Over 3 in. (76 mm) Magnesium 100% Argon — Excellent cleaning action Carbon Steel 95% Argon + 3.5% Oxygen — Improves arc stability; produces a more fluid and controllable weld puddle; good coalescence and bead contour; minimizes undercutting; permits higher speeds than pure argon 90% Argon + 8 to 10% Carbon Dioxide — High-speed mechanized welding; low-cost manual welding Low-Alloy Steel 98% Argon + 2% Oxygen — Minimizes undercutting; provides good toughness Stainless Steel 99% Argon + 1% Oxygen — Improves arc stability; produces a more fluid and controllable weld puddle, good coalescence and bead contour; minimizes undercutting on heavier stainless steels 98% Argon + 2% Oxygen — Provides better arc stability, coalescence, and welding speed than 1% oxygen mixture for thinner stainless steel materials 100% Argon Up to 1/8 in. (3.2 mm) Argon + Helium Mixtures — Higher heat inputs of 50 and 75% helium mixtures offset high heat dissipation of heavier gages 100% Argon — Good arc stability; minimum weld contamination; inert gas backing is required to prevent air contamination on back of weld area Titanium Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Highest heat input; minimizes porosity Provides good wetting; decreases fluidity of weld metal 49 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Nickel, Copper, and their Alloys Advantages Table 5-5—GMAW Shielding Gases for Short Circuiting Transfer Metal Shielding Gas Carbon Steel --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- 75% Argon + 25% CO2 Thickness Advantages Less than 1/8 in. (3.2 mm) High welding speeds without burn-through; minimum distortion and spatter More than 1/8 in. (3.2 mm) Minimum spatter; clean weld appearance; good puddle control in vertical and overhead positions 50% Argon + 50% CO2 — Deeper penetration; faster welding speeds Stainless Steel 90% Helium + 7.5% Argon + 2.5% CO2 — No effect on corrosion resistance; small heat-affected zone; no undercutting; minimum distortion Low-Alloy Steel 60–70% Helium + 25–35% Argon + 4.5% CO2 — Minimum reactivity; excellent toughness; excellent arc stability, wetting characteristics, and bead contour; little spatter 75% Argon + 25% CO2 — Fair toughness; excellent arc stability, wetting characteristics, and bead contour; little spatter Argon and Argon + Helium Mixtures Over 1/8 in. (3.2 mm) Argon satisfactory on sheet metal; argon-helium preferred on thicker base material Aluminum, Copper, Magnesium, Nickel, and their Alloys 50 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 5-6—Typical Conditions for GMAW of Austenitic Stainless Steel Using a Spray Arc in the Flat Position Material Thickness Wire Diameter Current Voltagea Wire Feed Speed Gas Flow in. mm Type of Weld in. mm amps volts IPM mm/s Shielding Gas CFH LPM 0.125(1 3.2 Butt Joint with Backing 0.062 1.6 225 24 130 55 98% Ar + 2% O2 30 14 0.250 b 6.4 V-Butt Joint 60° Inc. Angle 0.062 1.6 275 26 175 74 98% Ar + 2% O2 35 16 0.375 b 9.5 V-Butt Joint 60° Inc. Angle 0.062 1.6 300 28 240 102 98% Ar + 2% O2 35 16 ) Table 5-7—Typical Conditions for GMAW of Austenitic Stainless Steel Using a Short Circuiting Arc Material Thickness Wire Diameter Current Voltagea Wire Feed Speed Gas Flow in. mm Type of Weld in. mm amps volts IPM mm/s Shielding Gas CFH LPM 0.062 1.6 Butt Joint 0.030 0.8 85 21 185 78 98% He + 7.5% Ar + 2.5% CO2 30 14 0.093 2.4 Butt Joint 0.030 0.8 105 23 230 97 98% He + 7.5% Ar + 2.5% CO2 30 14 0.125 3.2 Butt Joint 0.030 0.8 125 24 280 118 98% He + 7.5% Ar + 2.5% CO2 30 14 Note: a. Direct current electrode positive (dcep). Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 51 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Notes: a. Direct current electrode positive (dcep). b. Two passes required. Submerged arc welding (SAW) does not presently have any fluxes that are classified. The various codes and standards (such as AWS D1.6) address the specific requirements for these fluxes. Table 5-11 provides typical conditions for SAW of double V-groove welds in stainless steel plate. GTAW is typically performed using thoriated, lanthanated, or ceriated tungsten electrodes. Direct current electrode negative (dcen–straight polarity) is used for all current levels. For thin stainless steels, alternating current (ac) or direct current electrode positive (dcep–reverse polarity) can be used, but care is needed to ensure that the tungsten electrode does not melt. Resistance Welding Processes PAW of stainless steels is typically performed using argon or mixtures of argon-hydrogen for keyhole welding, and argon or argon-helium mixtures for the melt-in welding technique. Tables 5-8 and 5-9 provide some typical PAW conditions for stainless steels. Tables 5-12–5-15 provide data for welding of stainless steels with: • Resistance spot welding • Resistance seam welding • Projection welding Typical data for FCAW is shown in Figure 5-4 and Table 5-10. Table 5-8—Typical PAW Conditions for Butt Joints in Stainless Steel Gas Flowb Travel Speed in. mm in./min mm/s Current (dcen) A 0.092 0.125 0.187 0.250 2.4 3.2 4.8 6.4 24 30 16 14 10 13 7 6 115 145 165 240 Orificec Shieldc Arc Voltage V Nozzle Typea ft3/h L/min ft3/h L/min Remarksd 30 32 36 38 111M 111M 136M 136M 6 10 13 18 3 5 6 8 35 35 45 50 17 17 21 24 Keyhole, square-groove weld Keyhole, square-groove weld Keyhole, square-groove weld Keyhole, square-groove weld Notes: a. Nozzle type: number designates orifice diameter in thousands of an inch; “M” designates design. b. Gas underbead shielding is required for all welds. c. Gas used: 95% Ar + 5% H. d. Torch standoff: 3/16 in. (4.8 mm). 52 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Thickness Table 5-9—Typical PAW Conditions for Welding Stainless Steels—Low Amperage Orifice Diameter Gas Flow Orificea,b,c Torch Standoff Electrode Diameter in. mm ft3/h L/min in. mm in. mm Remarks in. mm Type of Weld in./min mm/s Current (dcen) A 0.030 0.76 Square-groove weld, butt joint 5.0 2 11 0.030 0.76 0.6 0.3 1/4 6.4 0.040 1.0 Mechanized 0.060 1.50 Square-groove weld, butt joint 5.5 2 28 0.047 1.20 0.8 0.4 1/4 6.4 0.060 1.5 Mechanized Thickness Travel Speed 0.030 0.76 Fillet weld, tee joint — — 8 0.030 0.76 0.6 0.3 1/4 6.4 0.040 1.0 Manual, filler metald 0.060 1.50 Fillet weld, tee joint — — 22 0.047 1.20 0.8 0.4 1/4 6.4 0.060 1.5 Manual, filler metald 0.030 0.76 Fillet weld, lap joint — — 9 0.030 0.76 0.3 0.6 3/8 9.5 0.040 1.0 Manual, filler metald 0.060 1.50 Fillet weld, lap joint — — 22 0.047 1.20 0.8 0.4 3/8 9.5 0.060 1.5 Manual, filler metale Notes: a. Orifice gas: argon. b. Shielding gas: 95% Ar + 5% H at 20 ft3/h (10 L/min). c. Gas underbead shielding: argon at 10 ft3/h (5 L/min). d. Filler wire: 0.045 in. (1.1 mm) diameter 310 stainless steel. e. Filler wire: 0.055 in. (1.4 mm) diameter 310 stainless steel. --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 53 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Figure 5-4—FCAW Electrode Feed Rate Versus Welding Current for Self-Shielding E308T-3 54 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 5-10—Typical Self-Shielded FCAW Procedures for Stainless Steels Using Stainless Steel Electrodes Joint Design Weld Size, T Root Opening, R in. in. mm mm Electrode Diameter Total Passes in. mm Welding Power, dcep Wire Feed Speed Electrode Extension A V in./min mm/s in. mm Flat Position Groove Welds 1/4 3/8 6 10 1/8 1/8 3 3 1 2 3/32 3/32 2.4 2.4 300 300 27.5 27.5 190 170 70 70 1 1 25 25 1/2 3/4 13 19 3/16 3/16 5 5 2 4 3/32 3/32 2.4 2.4 300 300 27.5 27.5 170 170 70 70 1 1 25 25 7/8 1-1/4 22 32 3/8 3/8 10 10 6 8 3/32 3/32 2.4 2.4 300 300 27.5 27.5 170 170 70 70 1 1 to 1-1/4 25 25–32 1/2 3 13 76 1/8 1/8 3 3 2 250 3/32 3/32 2.4 2.4 300 300 27.5 27.5 170 170 70 70 1 1 to 1-1/4 25 25–32 (continued) --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 55 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 5-10—Typical Self-Shielded FCAW Procedures for Stainless Steels Using Stainless Steel Electrodes (Continued) Joint Design Weld Size, T Root Opening, R in. in. mm mm Electrode Diameter Total Passes in. mm Welding Power, dcep Wire Feed Speed Electrode Extension A V in./min mm/s in. mm 2.4 2.4 300 300 27.5 27.5 170 170 70 70 1 1 to 1-1/4 25 25–32 2.4 2.4 300 300 27.5 27.5 170 170 70 70 1 1 25 25 185 300 24 27 265 170 1100 70 1/2 1 13 25 Flat Position Groove Welds (Continued) 3/8 1-1/4 10 32 3/8 3/8 10 10 3 8 3/32 3/32 --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Flat Position Fillet Weld 3/8 3/4 10 19 0 0 0 0 1 3 3/32 3/32 Horizontal Position Fillet Weld 1/8 3/8 3 10 0 0 0 0 1 1 1/16 3/32 1.6 2.4 56 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 5-11—Typical Conditions for SAW Double-V-Groove Joints in Stainless Steel Plate First Welda Root Face Electrode Diameter mm in. mm in. 3/8 9.5 1/4 6.4 1/2 12.7 1/4 6.4 5/8 15.9 1/4 3/4 19.1 7/8 22.2 Plate Thickness in. Second Welda mm Welding Current, A Voltage, V in./min mm/s 3/16 4.8 525 30 20 8.5 3/16 4.8 700 35 18 7.6 6.4 3/16 4.8 700 33 16 6.8 1/4 6.4 1/4 6.4 700 33 15 5/16 7.9 1/4 6.4 715 33 15 Electrode Diameter mm Welding Current, A Voltage, V in./min mm/s 3/16 4.8 0575 32 24 10.2 3/16 4.8 0900 33 18 07.6 1/4 6.4 0900 35 12 05.1 6.4 1/4 6.4 0950 35 12 05.1 6.4 1/4 6.4 1025 35 12 05.1 Travel Speed in. Travel Speed --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Note: a. 90-degree groove angle. Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 57 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 5-12A—Suggested Practices for Spot Welding Stainless Steels (U.S. Customary Units) Thickness of Thinnest Outside Piece, in.a 0.006 0.008 0.010 0.012 0.014 0.016 0.018 0.021 0.025 0.031 0.034 0.040 0.044 0.050 0.056 0.062 0.070 0.078 0.094 0.109 0.125 Electrodeb Diameter, in. Face Diameter, in. Net Electrode Force, lb 3/16 3/16 3/16 1/4 1/4 1/4 1/4 1/4 3/8 3/8 3/8 3/8 3/8 1/2 1/2 1/2 5/8 5/8 5/8 3/4 3/4 3/32 3/32 1/8 1/8 1/8 1/8 1/8 5/32 5/32 3/16 3/16 3/16 3/16 1/4 1/4 1/4 1/4 5/16 5/16 3/8 3/8 180 200 230 260 300 330 380 400 520 650 750 900 1000 1200 1350 1500 1700 1900 2400 2800 3300 Weld Time Minimum Shear Strength, lb (Single Impulse), Base Metal Base Metal Base Metal Cycles UTS 70–90 UTS UTS (60 Hz) ksi 90–150 ksi ≥150 ksi 2 3 3 3 4 4 4 4 5 5 6 6 8 8 10 10 12 14 16 18 20 60 100 150 185 240 280 320 370 500 680 800 1000 1200 1450 1700 1950 2400 2700 3550 4200 5000 70 130 170 210 250 300 360 470 600 800 920 1270 1450 1700 2000 2400 2800 3400 4200 5000 6000 85 145 210 250 320 380 470 500 680 930 1100 1400 1700 2000 2450 2900 3550 4000 5300 6400 7600 Welding Current, A (approx.) Tensile Strength <150 ksi Tensile Strength ≥150 ksi Fused Zone Diameter, in. (approx.) 2 000 2 000 2 000 2 100 2 500 3 000 3 500 4 000 5 000 6 000 7 000 7 800 8 700 9 500 10 300 11 000 12 300 14 000 15 700 17 700 18 000 2 000 2 000 2 000 2 000 2 200 2 500 2 800 3 200 4 100 4 800 5 500 6 300 7 000 7 500 8 300 9 000 10 000 11 000 12 700 14 000 15 500 0.045 0.055 0.065 0.076 0.082 0.088 0.093 0.100 0.120 0.130 0.150 0.160 0.180 0.190 0.210 0.220 0.250 0.275 0.285 0.290 0.300 Minimum Minimum Weld Contacting Spacing, Overlap, in.c in. 3/16 3/16 3/16 1/4 1/4 3/16 3/16 3/16 7/16 1/2 9/16 5/8 11/16 3/4 7/8 1 1-1/8 1-1/4 1-1/8 1-1/2 2 3/16 3/16 3/16 1/4 1/4 1/4 1/4 5/16 3/8 3/8 7/16 7/16 7/16 1/2 9/16 5/8 5/8 11/16 3/4 13/16 7/8 Notes: a. Types of steel are 301, 302, 303, 304, 308, 309, 310, 316, 317, 321, 347, and 348. Material should be free from scale, oxides, paint, grease, and oil. Welding conditions are determined by thickness of the thinnest outside piece, T. Data for total thickness of pile-up not exceeding 4T. Maximum ratio between two thicknesses is 3 to 1. b. Truncated electrodes of RWMA Group A, Class 3 or Group B, Class 2 material. Electrodes with 3 in. spherical faces also are used. c. Minimum weld spacing is that spacing for two pieces for which no special precautions need be taken to compensate for shunted current effect of adjacent welds. For three pieces, increase spacing 30%. 58 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 5-12B—Suggested Practices for Spot Welding Stainless Steels (Metric Units) 0.15 0.20 0.25 0.31 0.36 0.41 0.46 0.53 0.64 0.79 0.86 1.02 1.12 1.27 1.42 1.58 1.78 1.98 2.39 2.77 3.18 --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Thickness of Thinnest Outside Piece, mma Electrodeb Diameter, mm Face Diameter, mm Net Electrode Force, N 4.76 4.76 4.76 6.35 6.35 6.35 6.35 6.35 9.53 9.53 9.53 9.53 9.53 12.70 12.70 12.70 15.88 15.88 15.88 19.05 19.05 2.38 2.38 3.18 3.18 3.18 3.18 3.18 3.97 3.97 4.76 4.76 4.76 4.76 6.35 6.35 6.35 6.35 7.94 7.94 9.53 9.53 801 890 1 023 1 157 1 334 1 468 1 690 1 779 2 313 2 891 3 336 4 003 4 448 5 338 6 005 6 672 7 562 8 452 10 676 12 455 14 679 Welding Current, A Weld Time Fused Minimum Shear Strength, N (approx.) (Single Zone Impulse), Base Metal Base Metal Base Metal Diameter, Tensile Tensile mm Cycles UTS 483– UTS 621– UTS Strength Strength (60 Hz) 621 MPa 1034 MPa ≥1034 MPa <1034 MPa ≥1034 MPa (approx.) 2 3 3 3 4 4 4 4 5 5 6 6 8 8 10 10 12 14 16 18 20 267 445 667 823 1 068 1 246 1 423 1 646 2 224 3 025 3 559 4 448 5 338 6 450 7 562 8 674 10 676 12 010 15 791 18 683 22 241 311 578 756 934 1 112 1 334 1 601 2 091 2 669 3 559 4 092 5 649 6 450 7 562 8 896 10 676 12 455 15 124 18 683 22 241 26 689 378 645 934 1 112 1 423 1 690 2 091 2 224 3 025 4 137 4 893 6 228 7 562 8 896 10 898 12 900 15 791 17 793 23 576 28 469 33 806 2 000 2 000 2 000 2 100 2 500 3 000 3 500 4 000 5 000 6 000 7 000 7 800 8 700 9 500 10 300 11 000 12 300 14 000 15 700 17 700 18 000 2 000 2 000 2 000 2 000 2 200 2 500 2 800 3 200 4 100 4 800 5 500 6 300 7 000 7 500 8 300 9 000 10 000 11 000 12 700 14 000 15 500 1.14 1.40 1.65 1.93 2.08 2.24 2.36 2.54 3.05 3.30 3.81 4.06 4.57 4.83 5.33 5.59 6.35 6.99 7.24 7.37 7.62 Minimum Minimum Weld Contacting Spacing, Overlap, mmc mm 4.76 4.76 4.76 6.35 6.35 4.76 4.76 4.76 11.11 12.70 14.29 15.88 17.46 19.05 22.23 25.40 28.58 31.75 28.58 38.10 50.80 4.76 4.76 4.76 6.35 6.35 6.35 6.35 7.94 9.53 9.53 11.11 11.11 11.11 12.70 14.29 15.88 15.88 17.46 19.05 20.64 22.23 Notes: a. Types of steel are 301, 302, 303, 304, 308, 309, 310, 316, 317, 321, 347, and 348. Material should be free from scale, oxides, paint, grease, and oil. Welding conditions are determined by thickness of the thinnest outside piece, T. Data for total thickness of pile-up not exceeding 4T. Maximum ratio between two thicknesses is 3 to 1. b. Truncated electrodes of RWMA Group A, Class 3 or Group B, Class 2 material. Electrodes with 76 mm spherical faces also are used. c. Minimum weld spacing is that spacing for two pieces for which no special precautions need be taken to compensate for shunted current effect of adjacent welds. For three pieces, increase spacing 30%. Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 59 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 5-13—Welding Schedules Suggested for Seam Welding Stainless Steels Minimum Electrode Widthb Net Electrode Force in. mm in. mm lb N 0.006 0.008 0.010 0.012 0.014 0.016 0.018 0.021 0.025 0.031 0.040 0.050 0.062 0.070 0.078 0.094 0.109 0.125 0.15 0.20 0.25 0.31 0.36 0.41 0.46 0.53 0.64 0.79 1.02 1.27 1.58 1.78 1.98 2.39 2.77 3.18 3/16 3/16 3/16 1/4 1/4 1/4 1/4 1/4 3/8 3/8 3/8 1/2 1/2 5/8 5/8 5/8 3/4 3/4 4.8 4.8 4.8 6.4 6.4 6.4 6.4 6.4 9.5 9.5 9.5 12.7 12.7 15.9 15.9 15.9 19.1 19.1 300 350 400 450 500 600 650 700 850 1000 1300 1600 1850 2150 2300 2550 2950 3300 1 334 1 557 1 779 2 002 2 224 2 669 2 891 3 114 3 781 4 448 5 783 7 117 8 229 9 564 10 231 11 343 13 122 14 679 Maximum Cool Time for Heat Time, Maximum Speed Welding Speed Cycles (Pressure-Tight), Cycles (60 Hz) (60 Hz) in./min mm/s in. 25.4 28.4 19.1 20.3 21.6 21.6 23.3 23.3 21.2 21.2 19.9 19.1 16.9 18.6 16.9 15.2 16.1 16.1 20 18 16 15 14 14 13 13 12 12 11 10 10 9 9 9 8 8 2 2 3 3 3 3 3 3 3 3 3 4 4 4 4 5 5 6 1 1 2 2 2 2 2 2 3 3 4 4 5 5 6 6 7 6 60 67 45 48 51 51 55 55 50 50 47 45 40 44 40 36 38 38 Minimum Joint Overlapc mm Welding Current, A (approx.) in. mm 508 457 406 381 356 356 330 330 305 305 279 254 254 229 229 229 203 203 4 000 4 600 5 000 5 600 6 200 6 700 7 300 7 900 9 200 10 600 13 000 14 200 15 100 15 900 16 500 16 600 16 800 17 000 1/4 1/4 1/4 5/16 5/16 5/16 5/16 3/8 7/16 7/16 1/2 5/8 5/8 11/16 11/16 3/4 13/16 7/8 6.4 6.4 6.4 7.9 7.9 7.9 7.9 9.5 11.1 11.1 12.7 15.9 15.9 17.5 17.5 19.1 20.6 22.2 Welds --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Thickness of Thinnest Outside Piecea Notes: a. Types of steel are 301, 302, 303, 304, 308, 309, 310, 316, 317, 321, and 347. Material should be free from scale, oxides, paint, grease, and oil. Welding conditions determined by thickness of thinnest outside piece. Data for total thickness of pile-up not exceeding 4 (thinnest outside piece thickness). Maximum ratio between thicknesses 3 to 1. b. Electrode material RWMA Group A, Class 3 copper alloy. Face radius, 3 in. (76 mm). c. For large assemblies, minimum joint overlap should be increased 30%. 60 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 5-14—Projection Welding Design Data Minimum Shear Strength (Single Projection Weld) --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Thickness of Thinnest Outside Piecea Diameter of Projectionb Height of Projectionc in. mm in. mm in. mm lb N lb N lb N in. mm in. mm 0.25 0.31 0.36 0.41 0.53 0.64 0.79 0.86 1.12 1.27 1.58 1.78 1.98 2.39 2.77 3.18 0.055 0.055 0.055 0.067 0.067 0.081 0.094 0.094 0.119 0.119 0.156 0.156 0.187 0.218 0.250 0.281 1.40 1.40 1.40 1.70 1.70 2.06 2.39 2.39 3.02 3.02 3.96 3.96 4.75 5.54 6.35 7.14 0.015 0.015 0.015 0.017 0.017 0.020 0.022 0.022 0.028 0.028 0.035 0.035 0.041 0.048 0.054 0.060 0.38 0.38 0.38 0.43 0.43 0.51 0.56 0.56 0.71 0.71 0.89 0.89 1.04 1.22 1.37 1.52 130 170 200 240 320 450 635 790 920 1350 1950 2300 2700 3450 4150 4800 578 756 890 1 068 1 423 2 002 2 825 3 514 4 092 6 005 8 674 10 231 12 010 15 346 18 460 21 351 180 220 280 330 440 600 850 1000 1300 1700 2250 2800 3200 4000 5000 5700 801 979 1 246 1 468 1 957 2 669 3 781 4 448 5 783 7 562 10 008 12 455 14 234 17 792 22 241 25 355 250 330 380 450 600 820 1100 1300 2000 2400 3400 4200 4800 6100 7000 8000 1 112 1 468 1 690 2 002 2 669 3 648 4 893 5 783 8 896 10 676 15 124 18 683 21 351 27 134 31 138 35 586 0.112 0.112 0.112 0.112 0.140 0.140 0.169 0.169 0.169 0.225 0.225 0.281 0.281 0.281 0.338 0.338 2.85 2.85 2.85 2.85 3.56 3.56 4.29 4.29 4.29 5.72 5.72 7.14 7.14 7.14 8.59 8.59 1/8 1/8 1/8 5/32 5/32 3/16 7/32 7/32 9/32 9/32 3/8 3/8 7/16 1/2 5/8 11/16 3.2 3.2 3.2 4.0 4.0 4.8 5.6 5.6 7.1 7.1 9.5 9.5 11.1 12.7 15.9 17.5 0.010 0.012 0.014 0.016 0.021 0.025 0.031 0.034 0.044 0.050 0.062 0.070 0.078 0.094 0.109 0.125 Tensile Strength < 70 ksi (483 MPa) Tensile Strength 70–150 ksi (483–1034 MPa) Tensile Strength ≥ 150 ksi (1034 MPa) Minimum Diameter of Fused Zone Minimum Joint Overlapd Notes: a. Types of steel are 309, 310, 316, 317, 321, and 347 (maximum carbon content 0.15%). Material should be free from scale, oxides, paint, grease, and oil. Size of projection normally determined by thickness of thinner piece, and projection should be on thicker piece, where possible. Data based on thickness of thinner sheet, and for two thicknesses only. b. Projection should be made on piece of higher conductivity when dissimilar metals are welded. For diameter of projection, a tolerance of ±0.003 in. (0.076 mm) in material up to and including 0.050 in. (1.27 mm) in thickness and ±0.007 in. (0.178 mm) in material over 0.050 in. (1.27 mm) in thickness may be allowed. c. For height of projection, a tolerance of ±0.002 in. (0.051 mm) in material up to and including 0.050 in. (1.27 mm) in thickness and ±0.005 in. (0.127 mm) in material over 0.050 in. in thickness may be allowed. d. Overlap does not include any radii from forming, etc. Weld should be located in center of overlap. Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 61 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 5-15—Manufacturing Process Data for Projection Welding Stainless Steels Thickness of Thinnest Outside Piecea Electrode Face Diameterb Net Electrode Force in. mm in. mm lb N Weld Time, Cycles (60 Hz) 0.014 0.021 0.031 0.044 0.062 0.078 0.094 0.109 0.125 0.36 0.53 0.79 1.12 1.59 1.98 2.39 2.78 3.18 1/8 3/32 3/16 1/4 5/16 3/8 7/16 1/2 9/16 3.2 2.4 4.8 6.4 7.9 9.5 11.10 12.70 14.30 300 500 700 700 1200 1900 1900 2800 2800 1 334 2 224 3 114 3 114 5 338 8 452 8 452 12 455 12 455 7 10 15 20 25 30 30 30 30 Hold Time, Cycles (60 Hz) Welding Current, A (approx.) 15 15 15 15 15 30 30 45 45 4 500 4 750 5 750 6 000 7 500 10 000 10 000 13 000 14 000 Notes: a. Types of steel are 309, 310, 316, 317, 321, and 347 (maximum carbon content, 0.15%). Material should be free from scale, oxides, paint, grease, and oil. Data based on thickness of thinner sheet, and for two thicknesses only. Maximum ratio between two thicknesses 3 to 1. b. Electrode material, RWMA Group A, Class 2, or Group B, Class 12 alloy. Truncated electrodes with flat faces. 62 --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Oxyfuel Welding Processes Cutting Processes Cutting processes not to use on stainless steels: Oxyfuel welding processes should not be used to weld stainless steels. These processes utilize a mixture of gases containing hydrocarbons and oxygen. If the flame is not adjusted properly it will result in either: (1) Oxyfuel—can carburize or oxidize the stainless steel. Cutting processes that can be used: (1) Plasma arc. (2) Laser. (3) Waterjet. (4) Air carbon arc—will carburize the cut surface, but if properly cleaned, is acceptable. Beam Welding Processes Brazing Electron beam and laser beam welding processes are readily suitable for stainless steels (no filler metal is required; however, it can be added). The faster travel speeds and solidification rates of these processes tend to produce more hot cracking problems. Stainless steels are readily brazed, using some of the brazing filler metals listed in Chapter 3. These are typically furnace brazed in a vacuum or inert atmosphere to avoid carburization or oxidation. Stainless steels are also torch brazed, provided a neutral flame is maintained. Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- (1) Carburizing flame—adds carbon to the stainless steel and leads to sensitization. (2) Oxidizing flame—adds oxygen that oxidizes the stainless steel, making it no longer corrosion resistant. 63 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Chapter 6—Postweld Cleaning of Stainless Steels Postweld Cleaning If the weldment is not properly cleaned, slag, entrapped foreign particles, and even discolored oxides (light blue or straw-colored or darker) may cause corrosion, depending on the environment. Following welding, the weld and surrounding heat-affected zone (HAZ) should be properly cleaned, to ensure that the entire weldment has full corrosion resistance. Depending upon the application, one or more of the following may be necessary: Further treatments could include: (1) Chemical cleaning. (1) Chip or grind to remove all slag, scale and heavy oxide. (2) Remove all spatter. (3) Grind any arc strikes. (4) Wire brush to remove all final traces of slag. (5) Wire brush to remove discoloration. (6) Grind and/or repair any crevices and pits. (7) Ensure all wire brushes are stainless steel, and are segregated for use only on stainless steels. (8) Segregate all tools for use on stainless steel, and do not allow them to become contaminated with carbon steel. (2) Pickling—use of an acid to attack and remove contamination, oxidized areas, etc. (3) Passivation—chemical treatment to form chromium-rich passive oxide layer on the surface. (4) Mechanical polishing—to remove crevices and produce a smooth surface. (5) Electropolishing (following mechanical polishing)—produces the smoothest surface finish to avoid crevices and pits. This also renders the surface less reactive than chemical passivation. --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 65 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Chapter 7—Heat Treatments of Stainless Steels Preweld Heat Treatment (Preheat) Table 7-1—Typical Preheat and Postweld Heat Treatment Requirements for Martensitic Stainless Steels Preweld heat treatment (preheating) is used only for some of the martensitic stainless steels and some of the ferritic stainless steels that produce martensite. There are two main reasons for preheating (both of which reduce the chances of forming cold cracks): Preheat (minimum)a (1) Slow down the cooling rate so that less martensite forms. (2) Drive off any hydrogen or moisture. °F °C Postweld Heat Treatment Requirementsb <0.05 0.05–0.15 >0.15 250 400 600 121 204 316 Optional Recommended Necessary Notes: a. The ASME Boiler & Pressure Vessel Code recommends a minimum preheat of 400°F (204°C) for those materials listed as P-6 in Section IX. b. The required heating and cooling rates are specified in the applicable construction code section of the ASME Boiler & Pressure Vessel Code. Table 7-1 lists the typical preheat and postweld heat treatment requirements for martensitic stainless steels. Note that the preheat temperature increases with greater carbon content (it also should increase with base metal thickness). As the carbon content increases, the martensite that forms is harder and more brittle; and therefore, more likely to crack. Preheat is not necessary for most other stainless steels. In fact, preheating of austenitic stainless steels and the majority of ferritic stainless steels (especially the superaustenitics and superferritics) is detrimental. These alloys, when heated, do not undergo a phase transformation; therefore, preheating these alloys makes the grains grow dramatically, which decreases the strength. Since no martensite forms, there is no beneficial effect in preheating, in fact, preheating of ferritic or austenitic stainless steels increases the undesirable possibility of sensitization. With austenitic stainless steels, the tremendous amount of distortion that occurs is another reason for not preheating these alloys. (Refer to Chapter 9 for preheat treatment information and code requirements.) Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Carbon, % Postweld Heat Treatment Postweld heat treatment is required for several types of stainless steels, but for different reasons. Table 7-2 presents postweld heat treatments for martensitic stainless steels as follows: (1) Subcritical heat treatment to temper the martensite and improve ductility and toughness, or (2) Full annealing heat treatment to transform the martensite and improve ductility and toughness. While both of these treatments will improve ductility and toughness, they will not remove cold cracks that may have already formed. Preheat is the best method to avoid cold cracks in martensitic stainless steels. 67 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 7-3—Recommended Solution Annealing Temperatures for Austenitic Stainless Steels Table 7-2—Postweld Heat Treatments for Martensitic Stainless Steels Subcritical Postweld Heat Treatment Temperature Rangea,b Type 403, 410, 416 414 420 431 440A, 440B, 440C CA-6NM CA-15, CA–40 Full Annealing Temperature Rangec °F °C °F °C 1200–1400 1200–1350 1250–1400 1150–1300 1250–1400 1100–1150 1150–1200 649–760 649–732 677–760 621–704 677–760 593–621 621–649 1525–1625 Note d 1525–1625 Note d 1550–1650 1450–1500 1550–1650 829–885 Note d 829–885 Note d 843–899 788–816 843–899 Temperature Type 201, 202, 301, 302, 303, 304, 304L, 305, 308 309, 309S, 316 316L, 317L 317 321 347, 348 °C 1850–2050 1900–2050 1900–2025 1950–2050 1750–1950 1800–1950 1010–1121 1038–1121 1038–1107 1066–1121 954–1066 982–1066 Precipitation-hardening stainless steels require a postweld heat treatment to provide for maximum strength. Table 7-4 shows typical heat treatments for precipitation-hardening stainless steels that involve (at least) a two-step process of: --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Notes: a. Air cool from temperature; lowest hardness is obtained by heating near the top of the range. b. Specific postweld heat treatment rules for ASME Boiler & Pressure Vessel Code applications are indicated in the applicable code sections. c. Furnace cool to 1100°F (593°C); weldment can then be air cooled. d. Not recommended. (1) Solution annealing—puts everything into solution, followed by fast cooling. (2) Precipitation-hardening—allows precipitates to form. (Refer to Chapter 9 for postweld heat treatment information and code requirements.) Most austenitic stainless steels do not require any postweld heat treatment—they are only annealed if it is necessary to reduce the chances of sensitization or stress. Table 7-3 lists the recommended solution annealing temperatures (followed by water quenching) for numerous 200 and 300 series austenitic stainless steels. Welded austenitic stainless steel tubing is an example of a material that is typically given a solution anneal followed by water quenching. Welding of precipitation-hardening stainless steels should be done prior to the heat treatment. If left untreated, the material will not achieve the high strength possible after heat treatment. Repair welding of these stainless steels typically causes problems. A postweld heat treatment on the repair weld will produce overaging of the surrounding metal, resulting in decreased strength. A full solution anneal and precipitation-hardening treatment should be performed, but may not be practical on an assembly or structure that is being repaired. 68 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS °F Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 7-4—Typical Heat Treatments for Precipitation-Hardening Stainless Steelsa Heat Treatment Steel Designationb UNS Number Grade or Type Solution Anneal °F °C Austenite Conditioning Quenchc Precipitation Hardening °F °C Quenchc °F °C Quenchc — — — — — — — — — — — — — — — 950–1000d 900–1150e 925–1150e 900–1150e 900–950d0 510–538d 482–621e 496–621e 482–621e 482–510d AC, 4 h AC, 4 h AC, 4 h AC, 4 h AC, 4 h 954 ± 80 954 ± 80 760 ± 14 760 ± 14 932 ± 14 954 ± 60 SZC SZC RC RC SZC SZC 950d 950d 1050d 1050d 850–1000e 850–1000f 510d 510d 566d 566d 454–538e 454–538f AC, 1 h AC, 1 h AC, 1-1/2 h AC, 1-1/2 h AC, 3 h AC, 3 h — — — — — — 1325 1300 1350 718 704 732 AC, 16 h AC, 24 h AC, 16 h Martensitic 17-7 PH PH 15-7 Mo 17-7 PH PH 15-7 Mo AM-350 AM-355 A-286 17-10 P HNM --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- PH 13-8 Mo 17-4 PH 15-5 PH Custom 450 Custom 455 S13800 S17400 S15500 S45000 S45500 XM-13 630 XM-12 XM-25 XM-16 1700 ± 25 1925 ± 50 1900 ± 25 1900 ± 25 1525 ± 25 927 ± 14 1052 ± 28 1038 ± 14 1038 ± 14 830 ± 14 AC AC AC RC WQ Semiaustenitic S17700 S15700 S17700 S15700 S35000 S35500 631 632 631 632 633 634 1950 ± 25 1950 ± 25 1950 ± 25 1950 ± 25 1950 ± 25 1900 ± 25 1066 ± 14 1066 ± 14 1066 ± 14 1066 ± 14 1066 ± 14 1038 ± 14 1750 ± 15 1750 ± 15 1400 ± 25 1400 ± 25 1710 ± 25 1750 ± 10 AC AC AC AC RC RC Austenitic S66286 — — 660 — — 1650–1800 2050 2050 899–982 1121 1121 RC WQ AC — — — Notes: a. For additional information, see ASTM A 693. b. Many of these are registered trade names. c. AC, air cool; WQ, water quench; RC, rapid cool (to 55 ± 5°F [13 ± 3°C] 1 h for S17700 or S15700); SZC, rapid cool to –100 ± 10°F (–73 ± 6°C) 8 h (S17700 or S15700) or –110 ± 10°F (–79 ± 6°C) 3 h (S35000 or S35500). d. The tolerance for values in this range is ±10°F (±6°C). e. The tolerance for values in this range is ±15°F (±8°C). f. The tolerance for values in this range is ±25°F (±14°C). Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 69 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Chapter 8—Weld Discontinuities and Defects in Stainless Steels General Weld Discontinuities and Defects Several references listed in the back of this Advisor provide guides to these discontinuities and their inspection, including: AWS B1.10, Guide for Nondestructive Inspection of Welds, AWS B1.11, Guide for Visual Inspection of Welds, and The Everyday Pocket Handbook for Visual Inspection and Weld Discontinuities. Welding of stainless steels can lead to various weld discontinuities or defects, including: --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- (1) Cracks. (2) Incomplete fusion. (3) Incomplete joint penetration. (4) Overlap. (5) Porosity. (6) Slag inclusions. (7) Tungsten inclusions. (8) Unacceptable weld profiles. (9) Undercut. (10) Underfill. Discontinuities and Defects in Stainless Steels Certain discontinuities and defects are unique to welds in stainless steels and higher alloys. For a comprehensive overview of those relating to corrosion of stainless steel welds, refer to The Practical Reference Guide for Corrosion of Welds: Causes and Cures. In addition, several weldingrelated discontinuities in stainless steels are reviewed below. Sensitization (Intergranular Corrosion) of Stainless Steels These can be caused by the: Sensitization is a problem that can occur mainly in austenitic and ferritic stainless steels, when chromium carbides (or nitrides) precipitate at grain boundaries (illustrated in Figure 8-1). In the austenitics, these chromium carbides form when the stainless steel is exposed to temperatures in the range of 800–1500°F (427–816°C). Because the chromium has diffused to the carbides, there is a chromium-depleted region around each carbide. When exposed to a corrosive environment, intergranular corrosion will likely occur at the grain boundaries, because the chromium content in the chromium-depleted region is less than the 10.5 wt.% needed for stainless steel. (1) Welding process. (2) Poor weld joint design. (3) Improper welding technique or application. (4) Base metal or filler metal. These discontinuities can occur in the: (1) Weld metal. (2) Heat-affected zone (HAZ). (3) Base metal. Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 71 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Figure 8-2—Weld Metal Area, Heat-Affected Zone, and Base Metal Figure 8-1—Sensitization—Formation of Chromium Carbides at Grain Boundaries show “wagon wheel tracks” or parallel lines of corrosion along the HAZs on either side of the weld (commonly termed “knife line attack”). Typically, the weld metal of a single-pass weld does not get sensitized, because the material exceeds the temperature for sensitization, and then cools through the sensitization temperature range too rapidly for chromium carbides to form. Sensitization rarely occurs in small single-pass welds or heat-affected zones on thin stainless steel, because these materials do not remain in the sensitization temperature range long enough. Multi-pass welds on stainless steel (Figure 8-3), especially on thicker material, can produce sensitization in the HAZ as well as in the first weld This is a defect only if the stainless steel is exposed to the proper corrosive environment, such as an acid; however, some sensitized stainless steels have “rusted” or oxidized when simply exposed to air. A weld on stainless steel will most often produce sensitization in the heat-affected zone (HAZ), because this region is in the sensitization temperature range during heating, welding, and cooling (see Figure 8-2). Welds that are sensitized and exposed to a corrosive environment will often 72 --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT by normal visual or other nondestructive examination (NDE) methods immediately after welding. Metallographic analysis on a sample is the only accurate method to detect sensitization; unfortunately, this is a destructive test. Methods to Avoid Sensitization (1) Solution Anneal and Water Quench—If the austenitic stainless steels have already been sensitized, annealing at 1900–2050°F (1038– 1121°C) causes the chromium carbides to dissolve and allows the chromium to return to the depleted regions. Water quenching (cooling rapidly) is important to avoid reformation of chromium carbides. Figure 8-3—Multi-Pass Weld Concerns: • Localized heat treatment will not work. While this treatment will remove sensitization in the heated region, it will also produce sensitization on both sides of the heated area. • Full annealing of a structure is often impractical. • Annealing of stainless steels, especially the austenitic stainless steels, produces significant distortion. --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- passes. The root pass is sensitized by the heat from the second and subsequent weld passes. In the same manner, the second weld pass is sensitized by the third pass, etc. Thus, sensitization can occur during: (1) Heat treatment (2) Multipass welding — In the heat-affected zone — In first weld passes (3) Service at elevated temperatures, i.e., 800–1500°F (427–816°C) Detection of Sensitization (2) Use Stabilized Stainless Steels—Types 321, 347, 348, and 444 contain “stabilizing” elements such as Ti, Nb, Ta, and Co, which cause the formation of carbides of these elements (e.g., TiC) that are more stable than chromium carbides. Since chromium carbides do not form, there is no depletion of chromium and no sensitization. Since sensitization becomes a defect only after the material has been exposed to corrosive or oxidizing environments, it cannot be detected It is important to note that the amount of the stabilizing elements is critical. For example, as shown in Table 2-1, the amount of titanium needed in Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 73 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT joint by exposure to carbon steel, tools that have contacted carbon steel, or other sources of carbon, such as grease, oil, paint, etc. Type 321 is at least 5 times the carbon content. If less than this amount of titanium were present, some chromium carbides could still form, thus producing sensitization. --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Avoid rubbing pencil “lead” on tungsten electrodes to help strike an arc—this “lead” is actually graphite, which is a form of carbon. Concerns: • Select stabilized grades of base metal. • Use stabilized grades of filler metal for stabilized base metals (i.e., use ER321 filler for Type 321 base metal). General Corrosion Stainless steels are resistant to general corrosion and oxidation mainly because of their chromium content. It is important that the stainless steel surfaces do not become contaminated or oxidized during weld preparation or welding. Avoid the following: (3) Use Low Carbon Stainless Steels—Several types of stainless steel contain lower levels of carbon. Types 304L and 316L contain a maximum of 0.03% carbon (see Table 2-1) compared with Types 304 and 316, which have a maximum of 0.08%. For Type 304 with 0.08% carbon, sensitization can occur in less than 1 min. For Type 304L with 0.03% carbon, it would take several hours at the appropriate temperature to produce sensitization, due to the extremely low carbon content of the steel. (1) Contamination of stainless steel with: — Free iron from carbon steels (tools, worktables, other steel, etc.) — Rust (2) Improper gas shielding of the weld face (top side) and weld root (underbead), which causes excessive discoloration. (3) Using improper welding process, such as oxyfuel welding. These low carbon stainless steels were specifically developed to avoid sensitization. The “L” denotes low carbon. Concerns: • Select low carbon grades of base metal. • Use low carbon grades of filler metal for low carbon base metals (use ER308L filler for Type 304L base metal). • Do not use low carbon filler metal on high or moderate carbon content base metal due to undermatching strength. Weld Contamination/Discoloration Stainless steel welds can become discolored if not properly shielded with inert gas or flux during welding. Discoloration is simply varying compositions and thicknesses of oxidation on the stainless steel surface. Depending upon the application, different levels of discoloration or oxidation may be acceptable. (4) Avoid Contact with Carbon—Proper cleaning and surface preparation are very important. Avoid contamination of the stainless steel weld 74 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT — Arc strikes — Rough weld ripples — Overlap — Incomplete fusion — Incomplete joint penetration — Porosity (2) Use of incorrect alloy filler metal. • In the semiconductor and pharmaceutical industries, no discoloration on the weld surface is allowed, and only a light blue or light straw color is allowed on the heat-affected zone (for surfaces that come in contact with the product). • In the food, dairy, and beverage industry, AWS D18.1 provides a color photograph of weld discoloration levels on stainless steel tubing, and suggests that acceptable discoloration on the weld be no darker than a straw or blue color. • In other industries, even darker discoloration levels may be acceptable. • Sugaring (a black oxidation with white “crystals” of oxide frequently present) is the extreme condition of weld oxidation/contamination, and is typically unacceptable for all stainless steel applications. Stress Corrosion Cracking Avoid the following: (1) Highly restrained welds. (2) Contamination with chlorides or sulfides (such as marking pens, penetrants, etc.). All forms of discoloration or contamination leave a chromium-depleted layer underneath. Since these areas do not have the passive chromiumoxide layer that provides corrosion resistance, these areas are no longer considered “stainless.” Proper mechanical or chemical cleaning, followed by a passivation treatment is necessary to restore corrosion resistance. Weld Penetration Problems Weld penetration variations, especially in arc welds, can be caused by many factors. Normal methods to overcome incomplete joint penetration problems include: Pitting and Crevice Corrosion --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- (1) Decreasing travel speed. (2) Increasing welding current. (3) Changing joint design (such as decreasing weld root face or land thickness). The pitting and crevice corrosion cracking resistance of stainless steels is improved by the addition of molybdenum and nickel. Any contamination that removes or oxidizes these elements will decrease the corrosion resistance. Avoid the following: In stainless steels, however, the weld penetration is often dramatically affected by the chemistry of the weld (from both the base metal and the filler metal). The main element that causes this variable penetration is sulfur, and to a lesser extent, oxygen and certain other elements. (1) Unacceptable weld profiles that create crevices, such as: — Weld spatter Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 75 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT is the reason that some stainless steel specifications presently require sulfur contents of 0.005–0.017 wt.% sulfur (e.g., ASTM A 269 and A 270). The minimum of 0.005 wt.% should prevent the shallow penetration problem. This penetration problem can be further aggravated when a low-sulfur metal is welded to a high-sulfur metal. The weld pool can be shifted offcenter towards the low sulfur side, causing a missed joint—as shown in Figure 8-5. Shifting the welding electrode off-center towards the high sulfur side may shift the weld pool back and allow the weld to consume the joint. Specification limits of 0.005–0.017 wt.% tend to prevent this problem from occurring. Figure 8-4—Weld Penetration in Stainless Steels Figure 8-5—Weld Penetration in Mismatched Base Metals --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Figure 8-4 illustrates weld pools in low and high sulfur 304 stainless steel. With low levels of sulfur present (<0.003 wt.%), the liquid weld pool flows outward, producing shallow weld penetration (Figure 8-4A). When the sulfur content is higher (>0.005 wt.%), the weld pool flows inward, producing deep, narrow weld penetration (Figure 8-4B). This problem can sometimes be overcome by the methods listed above. However, when the sulfur content is extremely low, changing the sulfur content of the base metal or filler metal may be the only acceptable option. This 76 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Hot Cracking (3) Use high ferrite base metal and/or filler metal. (4) Fill all craters. (5) Reduce tensile stresses (e.g., stress relieve, change joint design). (6) Avoid long arc lengths (which allow more air/nitrogen to enter the arc, since nitrogen increases the austenite content). Welding of stainless steels often results in cracking during welding—in the HAZ of the weld metal, or in the root pass of a multi-pass weld. If the weld is made with a fast travel speed, a centerline crack may form. If the crater of the weld is not filled properly, crater or star cracks may form. All of the above are hot cracks—cracks that occur while the weld is still hot, before it has cooled to room temperature. The types of hot cracking include: The grades most susceptible to hot-cracking are the austenitic stainless steels, because when compared with ferrite, austenite is the more susceptible structure. Since contaminants are more easily dissolved into ferrite than into austenite, a small amount of delta ferrite in an austenitic stainless steel weld helps reduce hot cracking. Several diagrams have been developed to predict the amount of ferrite present, depending on the base metal and filler metal compositions. The DeLong Diagram (Figure 8-6) shows the structures (austenite—A, ferrite—F, and martensite—M) that should be present in a GTA or GMA weld, based on the chemistry. This diagram uses two equations: the chromium equivalent and the nickel equivalent. Certain elements tend to act like chromium to produce ferrite, while other elements tend to act like nickel to produce austenite. Using the chemical analysis of the base metal, the chromium and nickel equivalents are calculated, and the point on the diagram where they intersect provides the predicted ferrite number (FN). Typically, a ferrite number exceeding 3 will produce a weld that should not be subject to hot cracking. Certain instruments are available that can measure the ferrite number (or the percent ferrite, another indicator). These instruments measure the magnetic field produced by the ferromagnetic ferrite in the nonmagnetic austenite. AWS A4.2 describes the calibration techniques for these instruments. The Schaeffler Diagram, shown in Figure 8-7, has also been developed to predict ferrite. The chromium and nickel equivalent equations are • Microfissuring. • Heat-affected zone cracking. • Reheat cracking (cracking in previous weld beads caused by subsequent weld passes). • Crater cracking. • Solidification cracking. Hot cracking is caused by: (1) Tensile stress. (2) Crack-susceptible microstructure (especially austenite). (3) Contaminants (especially sulfur, phosphorus, titanium, and niobium). --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- This hot cracking can occur in any of the stainless steels. The freemachining stainless steels that contain high levels of sulfur and phosphorus (such as Type 303) are especially susceptible. Some of the stabilized grades that contain titanium and niobium (Types 321, 347, 444) are also susceptible, in addition to the precipitation-hardening grades (17-4PH). Welding conditions can also affect hot cracking. Suggested methods to reduce hot cracking include: (1) Use stringer beads. (2) Reduce travel speed. Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 77 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Figure 8-6—DeLong Diagram 78 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Note: Calculate the nickel and chromium equivalents from the weld metal analysis. If nitrogen analysis of the weld metal is not available, assume 0.06% for GTA and covered electrode, or 0.08% for GMA weld metals. If the chemistry is accurate, the diagram predicts the WRC Ferrite Number within ±3 in approximately 90% of the tests for the 308, 309, 316, and 317 families. --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Figure 8-7—Schaeffler Diagram Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 79 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT slightly different from those shown on the DeLong Diagram, since they do not include the strong effects of nitrogen. The Schaeffler Diagram plots typical composition ranges for various stainless steel alloys. Type 310 has such a large nickel content that it produces no ferrite in the weld. Type 316 produces some ferrite, and Type 308 even more. This diagram also plots some of the ferritic and martensitic stainless steels. Both the DeLong and Schaeffler Diagrams can be used to predict the amount of ferrite present in austenitic stainless steel welds, even when a different filler metal composition is used. Figure 8-8 illustrates the dilution (amount of base metal in the weld) that occurs when a weld is made with filler metal (A) on a base metal with the amount of base metal melted (B). The dilution shown is 50%. If Type 310 base metal had been welded without filler metal, Figure 8-7 shows that the ferrite percent would be 0. If this Type 310 base metal had been welded with Type 308 filler metal, the actual compositions of these two alloys could be plotted on Figure 8-4. A straight line drawn between the two would show the range of compositions (and ferrite numbers) produced with different dilutions. Assuming the middle of the compositions for Types 310 and 308, the 50% dilution would still produce a ferrite content of 0%. However, if Type 312 filler metal had been used and a straight Figure 8-8—Weld Dilution 80 --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT line drawn between the center of the 310 box and the 312 box, the 50% dilution would produce a ferrite content of approximately 7%—an amount that should produce a crack-free weld. Type 312 filler metal is often selected to reduce hot-cracking problems. Ferrite in austenitic stainless steels can be detrimental if the weld is to be used in cryogenic applications, because the ferrite has significantly lower toughness than austenite. Ferrite can also be detrimental if its magnetic properties are the source of further problems. Cold cracking is caused by: (1) Tensile stress (2) Crack-susceptible microstructure (martensite) (3) Hydrogen Although martensite is a very strong and hard structure, it has very low ductility and toughness, and therefore, can easily cause cracking. The greater the carbon content, the harder and less ductile the martensite. If hydrogen is present, it can diffuse through the metal (even at room temperature), accumulate at the martensite, and increase pressure until more cracking occurs. Methods to avoid cold cracking include: Cold Cracking --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Another form of cracking that occurs hours or even days after the weld has cooled to room temperature and solidified is called: (1) Preheat—this is the best solution. Preheating slows down the cooling rate, so that less martensite forms; it also drives off moisture and hydrogen. (2) Postweld heat treat—A postweld heat treatment tempers the martensite and makes it more ductile (although this is not as effective as preheating in preventing the problem). (3) Reduce the stress. (1) Cold cracking (2) Hydrogen cracking (3) Delayed cracking This type of cracking occurs only in martensitic stainless steels, in some ferritics that form martensite, and in certain martensitic precipitationhardening stainless steels. Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 81 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Chapter 9—Stainless Steels in Welding Codes and Other Standards Welding Codes and Other Standards must be performed within ranges of these variables as defined in the standard. Several standards allow use of prequalified WPSs. AWS D1.6 code applies prequalified status to many austenitic stainless steels, when welded with specified joint designs, filler metals, and other variables. Many standards also allow the use of standard WPSs. AWS standards D1.6 and D18.1 allow the use of standard WPSs without performing procedure qualification tests. AWS has many standard WPSs available for welding of austenitic stainless steel plate, pipe, and sheet metal, which can be used in accordance with several welding codes and standards. (Refer to the AWS B2.1 series, listed on page 93.) Some variables are grouped to reduce the number of procedure and performance qualifications required—stainless steel base metals, filler metals, and heat treatments are variables that will be discussed. • • • • --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Most production welding of stainless steels is performed in accordance with various welding standards including codes. Examples of these publications include: ASME Boiler & Pressure Vessel Code, Section VIII ASME B31 Codes AWS D1.6, Structural Welding Code—Stainless Steel AWS D18.1, Specification for Welding of Austenitic Stainless Steel Tube and Pipe Systems in Sanitary (Hygienic) Applications • Military Standards Most standards (including codes) require: (1) Welding Procedure Qualifications—through Procedure Qualification Records (PQRs) and Welding Procedure Specifications (WPSs). (2) Performance Qualifications—through Welder or Welding Operator Performance Qualification Records (WPQs) or similar forms. Base Metals—Typical P/S/M-Numbers in Welding Codes and Standards Most codes categorize base metals into groups on the basis of comparable characteristics, such as chemical composition, mechanical properties, and metallurgical compatibility; however, these category groupings do not imply that the base metals may be indiscriminately substituted for others within the same category without consideration for weldability and other issues. In the ASME Boiler & Pressure Vessel Code, Section IX, these categories are designated as P-Numbers; in the ASME B31 codes for Pressure Procedure qualification typically requires tensile tests and guided bend tests. Performance qualification usually requires either guided bend tests or radiography. For stainless steels, corrosion and/or hardness tests may be required by some codes, or by the National Association of Corrosion Engineers (NACE) or ASTM standards. These standards define the essential or qualification variables that affect the properties of the weldment. Once qualified, production welding Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 83 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Piping and in many military standards, the categories are designated as P- or S-Numbers; in AWS B2.1, AWS D18.1, and other standards, the categories are designated by M-Numbers. Within the ferrous base metals (steels), there are also subcategories called Group Numbers. These groupings are based on specified impact test requirements (when low-temperature properties are required). Table 9-1 shows some of the P/S/M-Numbers of stainless steel base metals found in typical welding standards (refer to AWS B2.1 and ASME Boiler & Pressure Vessel Code, Section IX). The table lists typical grades and types of stainless steels (but not necessarily all grades), and the UNS (Unified Numbering System) numbers. The UNS “S” designations are stainless steel wrought base metals. Table 9-1 shows that the P/S/M-Number 6 category includes mainly martensitic stainless steels; Number 7 includes mainly ferritics; Number 8 includes the austenitics; and the Number 10 category includes some duplex and ferritics. This table also lists some base metals in P/S/M-Number 45. Although these are some of the superaustenitic stainless steels, they are grouped with the P/S/M-Number 45 nickel alloys (thus the UNS “N” designation), because of their higher nickel content. Cast stainless steels have a UNS “J” designation and are typically included in the same P/S/M-Numbers as the wrought equivalents. Depending upon the code, a welding procedure qualified with a base metal from one P/S/M-Number (and Group Number) might qualify all base metals in that P/S/M-Number (and Group Number). This is because all base metals in that category have similar mechanical and metallurgical properties (and heat treatments, when required). For welder performance qualifications (refer to AWS B2.1 and ASME Boiler & Pressure Vessel Code, Section IX), a welder who qualifies on any stainless steel base metal --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- is typically qualified for welding all stainless steels. These requirements vary with each standard: for example, military standards may limit the welder qualification to the S-Number tested. It is imperative that the appropriate standard be reviewed. There are numerous stainless steel base metals that are not included in P/S/M-Numbers. Most codes require these unlisted base metals to be qualified separately. AWS D1.6 covers structural welding of all five types of stainless steels, in addition to dissimilar welding between different types of stainless steels, and between stainless steels and carbon or low-alloy steels. This code provides prequalified status to some of the austenitic stainless steels only, classified in AWS D1.6 as Base Metal Groups A through E. Filler Metals—Typical F-Numbers and A-Numbers in Welding Codes and Other Standards Most welding codes and standards categorize filler metals into F-Number groupings (for filler metals) according to their usability characteristics. These groupings are used to reduce the number of welding procedure and welder performance qualifications required; however, they do not imply that filler metals within an F-Number group can be indiscriminately substituted for others. There are several F-Number groups for stainless steel filler metals, depending on the standard. Table 9-2 shows some F-Numbers from AWS B2.1 and ASME Boiler & Pressure Vessel Code, Section IX. The filler metal classifications with “XXX” indicate the stainless steel alloy designation. For example, E316-15 is an F-Number 5 SMAW electrode; ER308L 84 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 9-1—Typical Stainless Steel Base Metal P-Number, S-Number, and M-Number Categoriesa 6 7 8 Typical Stainless Steel Base Metals in P/S/M Numbers UNS (Unified Numbering System) Stainless Steel Numbers (UNS “S” Numbers are Stainless Steels) 1 403, 409, 410, 414A S40300, S40900, S41000 (Some), S41400 (Some) 2 405 (Some), 420, 429, 430 S40500 (Some), S42000, S42900, S43000 3 414, CA15 (13Cr) S41000 (Some), S41026, S41400 (Some) 4 415, CA6NM S41500 1 405 (Some), 409, 410S, 430Ti S40500 (Some), S40800, S40900, S41008, S43036 2 430, 439, 444, 18Cr-2Mo, XM-27 (Some) S43000, S43035, S44400, S44627 (Some) 1 302, 304, 304L, 305, 316, 316L, 317, 321, 347, 348, CF3, CF3M, CF8, CF8M S16800, S30200, S30215, S30300, S30323, S30400, S03403, S30409, S30451, S30452, S30453, S30500, S30600 (Some), S31254 (Some), S31600, S31603, S31609, S31635, S31640, S31651, S31653, S31700, S31703, S31753, S32100, S32109, S34700, S34709, S34800, S34809, S38100 (Some) 2 308, 309, 309S, 310, CH8, HK40 S30800, S30815, S30900, S30908, S30909, S30940, S30941, S31000, S31008, S31009, S31040, S31041, S31050, S31400, S33100 3 201, 202, XM-17, XM-18, XM-19, XM-29 S20100, S20200, S20400, S20910, S21600, S21603, S21800, S21900, S21903, S21904, S24000, S38100 (Some) --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Typical P/S/M Typical Group Number Number 4 F44, F46 S30600 (Some), S31254 (Some), S31725, S31726 10H 1 312, 329 S31200, S31260, S31500, S31803, S32304, S32550, S32750, S32760, S32900, S32950 10I 1 446-1, 446-2, XM-27 (Some), XM-33 S44600, S44626, S44627 (Some), S44635 10J 1 447, 29-4 S44700, S44735 10K 1 Types 26-3-3, 29-4-2 S44660, S44800 45 N/A Superaustenitics N08020, N08026, N08367, N08700, N08904, N08925 Note: a. From AWS B2.1 and ASME Boiler & Pressure Vessel Code, Section IX. Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 85 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT 1 4 5 6 6 6 --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- F-Number Table 9-2—F-Number Groupings of Welding Electrodes and Rods for Qualificationsa Welding Process(es) AWS Filler Metal Specification AWS Filler Metal Classification SMAW SMAW SMAW GMAW, GTAW, SAW FCAW GTAW AWS A5.40 AWS A5.40 AWS A5.40 AWS A5.90 AWS A5.22 AWS A5.30 EXXX(X)-25, EXXX(X)-26 EXXX(X)-15, EXXX(X)-16, EXXX(X)-17 EXXX(X)-15, EXXX(X)-16, EXXX(X)-17 ERXXX(X), ECXXX(X), EQXXX(X) EXXXTX-X, RXXXT1-5 INXXX Comments Other than Austenitic and Duplex Austenitic and Duplex Also includes flux rods for GTAW Consumable Inserts Note: a. From AWS B2.1 and ASME Boiler & Pressure Vessel Code, Section IX. Heat Treatment Requirements for Stainless Steels in Welding Codes and Other Standards is a GMAW or GTAW wire that is in F-Number 6; and E312TX-X is an FNumber 6 FCAW electrode. For welding procedure qualification of ferrous weld metals, most codes and other standards also further classify the weld metal by “A” designations (for analyses). Table 9-3 shows typical A-Number analyses (chemical compositions of the as-deposited weld metal). For most procedure and welder qualifications, the F-Number and ANumber are essential or qualification variables. Qualification with an electrode or filler metal of one F-Number and A-Number will typically qualify only all other filler metals within that same F-Number and A-Number. For welding procedure and welder performance qualifications, refer to the actual code or other standard for the specific essential or welding variables and requirements. Preheat For the martensitic stainless steels (P/S/M-Number 6), preheating is used for the same reasons as with high-carbon and low-alloy steels—to avoid cold cracking (also called hydrogen cracking, or delayed cracking). Preheating slows down the cooling rate, so that less hard, brittle martensite forms, which also drives off any moisture or hydrogen. Both of these reduce the chances of cracking. Table 9-4 provides recommended and/or required preheat temperatures from the ASME B31.3 and B31.1 codes. 86 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 9-3—A-Number Classifications of Stainless Steel Ferrous Weld Metal for Procedure Qualifications Weld Metal Analysis, wt.%a Types of Weld Deposit C Cr Mo Ni Mn Si 6 7 8 9 Chromium-Martensitic Chromium-Ferritic Chromium-Nickel Chromium-Nickel 0.15 0.15 0.15 0.30 11.00–15.00 11.00–30.00 14.50–30.00 19.00–30.00 0.70 1.00 4.00 6.00 — — 7.50–15.00 15.00–37.00 2.00 1.00 2.50 2.50 1.00 3.00 1.00 1.00 --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- A-Number b Weld Metal Analysis, wt.%a A-Number c Types of Weld Deposit C Cr Mo Ni Mn Si 6 7 8 9 Chromium-Martensitic Chromium-Ferritic Chromium-Nickel Chromium-Nickel 0.15 0.15 0.15 0.35 11.00–15.0 11.00–30.0 14.50–30.0 19.00–30.0 0.70 1.00 4.00 6.00 — — 7.50–15.0 15.0–37.5 2.00 1.00 2.50 2.50 1.00 3.00 1.00 1.00 Notes: a. Single values shown above are maximum. b. From ASME Boiler & Pressure Vessel Code, Section IX. c. From AWS B2.1. Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 87 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Table 9-4—Preheat Requirements in Various Codesa Refer to the applicable code or other standard for actual requirements and exceptions. Preheat temperatures are often higher with increased carbon content and greater thicknesses. Minimum Preheat Temperatures P or S-Numberc A-Number Required Recommended 6 7 8 6 7 8, 9 N/A N/A N/A b 300°F (149°C) b Postweld Heat Treatment 50°F (10°C) 50°F (10°C) P-Numberd Minimum Preheat Temperatures Required 6 7 8 400°F (200°C) 50°F (10°C) 50 F (10°C) Most codes and standards specify any postweld heat treatment that may be required. Table 9-5 shows the recommended postweld heat treatments from ASME B31.3 and B31.1 for some of the stainless steels. For example, to temper the alloy, P-Number 6, martensitic stainless steels are heat treated at between 1350–1450°F (732–788°C) for 1 hour per inch of thickness (minimum of 2 hours). For the ferritics (P-Number 7), no heat treatment is required in ASME B31.3, but treatment is required for some alloys in ASME B31.1. The austenitics (P-Number 8) require no postweld heat treatment. For the same reasons that no preheat is used, postweld heat treatment typically is not performed for metallurgical reasons. PWHT may be employed for dimensional stabilization and chemical stabilization reasons (e.g., carbide stabilization in 347-SS), even though codes may not require PWHT. Certain duplex and precipitation-hardening stainless steels require heat treatment; the codes typically provide the requirements. Again, refer to the code or other standard for actual requirements. For example, there are exceptions to postweld heat treatments for Types 410 and 430 in ASME B31.1, if no more than 0.08 wt.% carbon is present and the weld metal is no more than 3/8 in. thick. Notes: a. For all thicknesses. b. Maximum interpass temperature 600°F (316°C). c. From ASME B31.3. d. From ASME B31.1. For austenitic stainless steels and most of the ferritic, duplex, and precipitation-hardening stainless steels, no preheating is required. In the austenitics (and most other types), since no martensite forms, there is no reason to preheat. In fact, preheating is disadvantageous because it causes excessive grain growth, which reduces strength. It also causes excessive distortion of the weldment, especially for the austenitic stainless steels. --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 88 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Table 9-5—Postweld Heat Treatment Requirements in Various Codesa Holding Time P or S-Numberb A-Number Alloy Temperature Time (hr/in.) Minimum Time (hr) 6 6 High-Alloy Steels—Martensitic 1350–1450°F (732–788°C) 1 2 7 High-Alloy Steels—Ferritic None N/A N/A 8, 9 High-Alloy Steels—Austenitic None N/A N/A 7 8 Holding Time Up to 2 in. Thick Over 2 in. Thick P-Numberc Alloy Temperature Time Minimum Time 6 Group Nos. 1, 2, 3 1400–1475°F (760–800°C) 1 hr/in. 15 min. 2 hr plus 15 min. per in. over 2 in. 7 Group Nos. 1, 2, 0 1350–1425°F (730–775°C) 1 hr/in. 15 min. 2 hr plus 15 min. per in. over 2 in. 8 High-Alloy Steels—Austenitic None N/A N/A N/A Notes: a. For all thicknesses. b. From ASME B31.3. c. From ASME B31.1. Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS 89 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Chapter 10—Safety and Health Considerations in Welding of Stainless Steels Selection displace oxygen necessary for breathing. Therefore, the appropriate ventilation measures as described in ANSI Z49.1 must be addressed. All welding equipment (such as arc, resistance, electron beam, laser beam, etc.) shall be selected for safe applications to the work intended. ANSI Z49.1, Safety in Welding, Cutting, and Allied Processes, should be referenced for appropriate safety measures for all welding equipment. Ventilation—Chromium in Stainless Steels During welding, chromium oxides (such as chromium pentoxide) form and mix with the welding fumes. Breathing of these fumes should be avoided. ANSI Z49.1 addresses welding, brazing, or cutting of steels that contain hazardous materials. One of the materials listed is chromium, which is present in all stainless steels. ANSI Z49.1 addresses safety concerns when welding as follows: --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Ventilation—Inert and Other Purge Gases Adequate ventilation shall be provided for all welding, cutting, brazing and related operations. Adequate ventilation shall be enough ventilation such that personnel exposures to hazardous concentrations of airborne contaminants are maintained below the allowable limits specified by the authority having jurisdiction. Stainless steels are often welded using gas purging to protect the backside of the weld. These gases are typically inert, but all of these purge gases Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS (1) Confined spaces—When welding, brazing, or cutting operations are performed on stainless steels in confined spaces, local exhaust ventilation, and respiratory protection (when required) shall be used. (2) Adjacent persons—All persons in the immediate vicinity of the welding or cutting operations should be similarly protected. 91 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT References and Other Publications Available from AWS Title A3.0 Standard Welding Terms and Definitions A4.2 Standard Procedures for Calibrating Magnetic Instruments to Measure the Delta Ferrite Content of Austenitic and Duplex Austenitic-Ferritic Stainless Steel Weld Metal A5.4 Specification for Stainless Steel Electrodes for Shielded Metal Arc Welding A5.9 Specification for Bare Stainless Steel Welding Electrodes and Rods A5.22 Specification for Stainless Steel Electrodes for Flux Cored Arc Welding and Stainless Steel Flux Cored Rods for Gas Tungsten Arc Welding A5.30 Specification for Consumable Inserts B1.10 Guide for the Nondestructive Inspection of Welds B1.11 Guide for the Visual Inspection of Welds B2.1 Specification for Welding Procedure and Performance Qualification B2.1.005 Standard Welding Procedure Specification for Gas Metal Arc Welding of Austenitic Stainless Steel, (M-8 or P-8), 10 through 18 Gage, in the As-Welded Condition, With or Without Backing Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Order No. Title B2.1.006 Standard Welding Procedure Specification for Gas Metal Arc Welding of Carbon Steel to Austenitic Stainless Steel, (M-1 to M-8 or P-8), 10 through 18 Gage, in the As-Welded Condition, With or Without Backing B2.1.009 Standard Welding Procedure Specification for Gas Tungsten Arc Welding of Austenitic Stainless Steel (M-8/P-8), 10 through 18 Gage, in the As-Welded Condition, With or Without Backing B2.1.010 Standard Welding Procedure Specification for Gas Tungsten Arc Welding of Carbon Steel to Austenitic Stainless Steel, (M-1 to M-8 or P-8), 10 through 18 Gage, in the As-Welded Condition, With or Without Backing B2.1.013 Standard Welding Procedure Specification for Shielded Metal Arc Welding of Austenitic Stainless Steel (M-8 or P-8) 10 through 18 Gage, in the As-Welded Condition, With or Without Backing B2.1.014 Standard Welding Procedure Specification for Shielded Metal Arc Welding of Carbon Steel to Austenitic Stainless Steel, (M-1 to M-8 or P-8), 10 through 18 Gage, in the As-Welded Condition, With or Without Backing --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Order No. B2.1-8-023 Standard Welding Procedure Specification (WPS) Shielded Metal Arc Welding of Austenitic Stainless Steel (M-8/P-8/S-8, Group 1) 1/8 through 1-1/2 inch Thick, As-Welded Condition 93 Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT Order No. Title Order No. B2.1-8-024 Standard Welding Procedure Specification (WPS) Gas Tungsten Arc Welding of Austenitic Stainless Steel (M-8/P-8/S-8, Group 1) 1/8 through 1-1/2 inch Thick, As-Welded Condition Title B2.1-8-216 Standard Welding Procedure Specification (WPS) for Gas Tungsten Arc Welding with Consumable Insert Followed by Shielded Metal Arc Welding of Austenitic Stainless Steel (M-8/P-8/S-8, Group 1), 1/8 through 1-1/2 inch Thick, IN3XX, ER3XXX, and E3XX-XX, As-Welded Condition B2.1-8-025 Standard Welding Procedure Specification (WPS) Gas Tungsten Arc Welding followed by Shielded Metal Arc Welding of Austenitic Stainless Steel (M-8/P-8/S-8, Group 1) 1/8 through 1-1/2 inch Thick, As-Welded Condition B2.1-8-212 Standard Welding Procedure Specification (WPS) Gas Tungsten Arc Welding of Austenitic Stainless Steel (M-8/P-8/S-8, Group 1) 1/8 through 1-1/2 inch Thick, ER3XX As-Welded Condition, Primary Pipe Applications B2.1-8-213 Standard Welding Procedure Specification (WPS) Shielded Metal Arc Welding of Austenitic Stainless Steel (M-8/P-8/ S-8, Group 1) 1/8 through 1-1/2 inch Thick, E3XX-XX AsWelded Condition, Primary Pipe Applications B2.1-8-214 Standard Welding Procedure Specification (WPS) Gas Tungsten Arc Welding Followed by Shielded Metal Arc Welding of Austenitic Stainless Steel (M-8/P-8/S-8, Group 1) 1/8 through 1-1/2 inch Thick, ER3XX, E3XX-XX As-Welded Condition, Primary Pipe Applications D1.6 Structural Welding Code—Stainless Steel D10.4 Recommended Practices for Welding Austenitic ChromiumNickel Stainless Steel Piping and Tubing D18.1 Specification for Welding of Austenitic Stainless Steel Tube and Pipe Systems in Sanitary (Hygienic) Applications PHB-2 The Everyday Pocket Handbook for Visual Inspection and Weld Discontinuities—Causes and Remedies PRGC The Practical Reference Guide for Corrosion of Welds: Causes and Cures WHB-1.8 WHB-2.8 WHB-3.8 Welding Technology, Welding Handbook, 8th Ed., Vol. 1 Welding Processes, Welding Handbook, 8th Ed., Vol. 2 Materials and Applications—Part 1, Welding Handbook, 8th Ed., Vol. 3 Materials and Applications—Part 2, Welding Handbook, 8th Ed., Vol. 4 WHB-4.8 B2.1-8-215 Standard Welding Procedure Specification (WPS) for Gas Tungsten Arc Welding with Consumable Insert of Austenitic Stainless Steel (M-8/P-8/S-8, Group 1), 1/8 through 1-1/2 inch Thick, IN3XX and ER3XX, As-Welded Condition WI Welding Inspection ANSI Z49.1 Safety in Welding, Cutting, and Allied Processes To order these, or any AWS publication, call Customer Service at: (800) 334-9353 94 --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT --`,,,,,,``````,`,```,,`````,``-`-`,,`,,`,`,,`--- 550 N.W. LeJeune Road, Miami, Florida 33126 Copyright American Welding Society Provided by IHS under license with AWS No reproduction or networking permitted without license from IHS Licensee=Shell Services International B.V./5924979112 Not for Resale, 09/23/2005 16:24:35 MDT