CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK English Language Skills answers Chapter 1 Exercise 1.1 1 a b 2 Physical state Volume Density Shape Fluidity solid has a fixed volume high has a definite shape does not flow liquid has a fixed volume moderate to high does not have a definite shape – takes the shape of the container generally flows easily gas does not have a fixed volume – expands to fill the container and can be compressed low does not have a definite shape – takes the shape of the container flows easily i ii iii iv v higher lower fixed; expands fluid; more compressed; pressure a Evaporation and condensation take place over a range of temperatures; boiling takes place at a specific temperature known as the boiling point. freezing or solidification melting liquid Melting: a pure substance melts suddenly at a particular temperature. Freezing: the reverse takes place sharply at the same temperature known as the freezing point. increasing temperature condensation or liquefaction evaporation or vaporisation gas solid 1 Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 1 continued b 3 Possible titles include: Changes in physical state / The effect of temperature on the physical state (of a substance) / Changes in physical state with increasing (rising) temperature Verb Noun – name of process Noun – product of process to condense condensation condensate to evaporate evaporation vapour to crystallise crystallisation crystals to precipitate precipitation precipitate to solidify solidification solid Exercise 1.4 8 9 Diffusion • is the process occurring when the particles of a substance spread and mix • is a random process that can only take place in fluids (liquids and gases) • is much faster in gases • is faster at higher temperatures. a dilute/concentrated; dissolved/ undissolved; soluble/insoluble b i solution; solute; solvent ii solute; solution; saturated Exercise 1.2 4 5 a b c d e a b so so because because which suggests that 1–D; 2–A; 3–B; 4–C ii A word used to describe a liquid that has a low boiling point and evaporates easily. iii The process which is the reverse of melting and can also be called solidification. iv The process which turns a liquid into a gas below its boiling point. Exercise 1.3 6 7 a b a b 2 random; irregular; able; can irregular; able; collide i vibrate; strongly; melting point; energy; move; melts; liquid ii temperature; gain; faster; evaporation; boiling point; bubbles; boils lose energy; move around more slowly; forces between particles; freezing point; fixed positions; turns into a solid Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 2 Exercise 2.1 Exercise 2.2 1 2 a molecule; element; atom; compound b Term Definition mixture two or more chemical substances physically mixed together compound a chemical substance made from two or more elements chemically bonded together molecule c nucleus proton electron a particle made up of more than one atom chemically bonded together element a chemical ‘building block’ of all matter that cannot be broken down into simpler substances atom the smallest particle of an element that can take part in a chemical reaction a b c B = element; C = mixture; D = compound 3 4 protons and neutrons; 7 The electrical charge on the nucleus is positive because it contains protons which are positive and neutrons that have no charge. d It must lose at least one electron. The reason for this is that it will then have more protons than electrons and so will be positively charged. e first shell (energy level) = 2; second shell (energy level) = 8 x = 31 y = 15 1 2 3 4 5 6 F E B A C D Exercise 2.3 5 3 Order of sentence fragments: b, d, f, e, a, c, g. Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 2 continued Exercise 2.4 6 7 tri-oxygen a 4; 2 b 2 c i ii d 4 Prefix Meaning of the prefix Example Explanation of example mono- one of something carbon monoxide the molecule contains one oxygen atom di- or bi- two of something diatomic a molecule containing two atoms tri- three of something sulfur trioxide the molecule contains three oxygen atoms tetra- four of something tetrachloromethane the molecule contains four chlorine atoms penta- five of something phosphorus pentoxide the molecule contains five oxygen atoms nitrogen dioxide; vanadium pentoxide; phosphorus trioxide Prefix Meaning of the prefix Example Explanation of example non- not having a particular nature or property non-metal an element that is not a metal un- not having a particular nature or property unstable a substance that breaks down very easily in- not having a particular nature or property insoluble a substance that is not soluble (does not dissolve) ir- not having a particular nature or property irregular having an arrangement that is not organised sub- under or smaller than subatomic particles particles smaller than an atom iso- same isotope atoms of the same element with different nucleon numbers Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 3 Exercise 3.1 Exercise 3.4 1 8 transfer; from; to; metal; lose; positive; forces; between; opposite; sharing; between; in; non-metals; two 2 + 3 – H Na O When an ionic bond is made, electrons are transferred from one atom to another. A shared pair of electrons makes a covalent bond. a b c There are two covalent bonds between the atoms in an oxygen molecule. The bonds in oxygen and carbon dioxide molecules are covalent bonds. All the atoms in these two molecules have a share of eight electrons in their outer shell. Exercise 3.2 4 a b c 5 a b c d 9 a b c d e f g h i j a b c d e conduct transparent shiny appearance slippery tetrahedrally three-dimensional hexagonally two-dimensional layered Both; covalent bonds; giant but; colourless and transparent but; is soft and slippery but; does (conduct) Here is an example answer: Diamond is a very hard transparent solid that does not conduct electricity, but graphite is a dark grey, slippery and opaque solid that does (conduct electricity). 10 Order of statements 1 A 2 C 3 E 4 D 5 B 6 G 7 F are; contains; are; lost; negatively consists; is; electrons; positive are; consist; protons; 18; negative; is; moves electrostatic; hold form; regular attraction; are; require Six; surround Exercise 3.3 6 7 5 molecule; share; overlap; centre; single; eight; stable; noble a with; to b in c of; in d to e between f throughout g within/in; between Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 4 Exercise 4.1 1 2 3 6 Exercise 4.2 4 a nucleus; electrons; protons; nuclei; nucleus; proton electrons; power; combining; electrons; formula; formulae; valencies Elements present Name of compound Formula potassium and bromine potassium bromide KBr2 zinc and sulfur zinc sulfide ZnS Exercise 4.3 barium and chlorine barium chloride BaCl2 5 magnesium and nitrogen magnesium nitride sulfur and oxygen nitrogen and oxygen b Definition Term Mg3N2 a change in which new substances are produced chemical reaction sulfur trioxide SO3 the substances that react together in a chemical reaction reactants nitrogen dioxide NO2 the chemicals available in a laboratory reagents the substance formed in a chemical reaction product a change in which the substances remain the same – no new substances are formed physical change Elements present Name of compound Formula sodium, hydrogen, carbon and oxygen sodium hydrogen carbonate NaHCO3 zinc, sulfur and oxygen zinc sulfate ZnSO4 magnesium, carbon and oxygen magnesium carbonate MgCO3 copper, carbon and oxygen copper carbonate CuCO3 sodium, hydrogen phosphorus and oxygen sodium dihydrogen phosphate NaH2PO4 Elements present Name of compound Formula nitrogen and hydrogen ammonia NH3 potassium, hydrogen and oxygen potassium hydroxide KOH magnesium and oxygen magnesium oxide MgO hydrogen and oxygen water H2O nitrogen, hydrogen and chlorine ammonium chloride NH4Cl nitrogen, hydrogen and oxygen ammonium nitrate NH4NO3 copper, sulfur and oxygen copper sulfate CuSO4 6 7 a b c d e a b 8 a physical change chemical reaction chemical reaction chemical reaction physical change zinc + hydrochloric acid → zinc chloride + hydrogen carbon dioxide + water → glucose + oxygen i methane + oxygen → carbon dioxide + water ii reactants: C = 1 / H = 4 / O = 4 products: C = 1 / H = 4 / O = 4 The numbers of each type of atom are the same on both sides of the equation. iii CH4(g) + 2O2(g) → CO2(g) + 2H2O(l) Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 5 Exercise 5.1 1 a b i twice ii double iii less iv twice; double; twenty-four; third; relative v half four times Exercise 5.2 2 a b percentage of nitrogen (%) = (mass of nitrogen × 100) / relative formula mass percentage of nitrogen (%) = (28 × 100) / 80 = 35% every 100 g of ammonium nitrate contains 35 g Exercise 5.3 3 4 Chemical term Definition mass number a carbon-12 atom is given a mass of exactly 12 the standard for measuring relative atomic mass the number of protons and neutrons in the nucleus of an atom; also called the nucleon number relative atomic mass, Ar the sum of all the relative atomic masses for the atoms in a molecule; use only for covalent substances isotopes atoms of the same element with different nucleon numbers; they have different numbers of neutrons relative molecular (or formula) mass, Mr the average mass of an atom of an element, using a scale where an atom of carbon-12 has a mass of exactly 12 a b b isotopes; isotopes atoms; atoms; isotopes Exercise 5.4 5 a b c d 6 7 One mole of a substance has a mass equal to the molecular (or formula) mass of the substance in grams. Avogadro’s constant is the number of atoms, molecules or characteristic particles in one mole of a substance. One mole of a substance contains 6.02 × 1023 (Avogadro’s constant) atoms, molecules or other characteristic particles. Avogadro’s constant = 6.02 × 1023 atoms, molecules or other characteristic particles. one; two; two 2 × 24 = 48 g + 32 g → 80 g 0.80 g of magnesium oxide Carry out the exercise to familiarise yourself with the mathematical expressions. Exercise 5.5 8 7 a solute; solvent; soluble; insoluble; dilute; concentrated c Use a balance to measure out 1.0 g of sodium chloride and then add the solid to the water in the beaker. ✓ Measure 50 cm3 of distilled water in a measuring cylinder and pour it into a beaker. ✓ Carry on adding small portions of salt to the solution until no more dissolves. ✓ Stir the mixture with a glass rod until all the salt has dissolved. ✓ 1 Take a 100 cm3 measuring cylinder. Fill it approximately half full with distilled water. 2 Use a balance to carefully measure out 1.0 g of copper sulfate. 3 Use a small filter funnel to pour the solid into the measuring cylinder. 4 Wash out any remaining solid on the filter funnel with a little distilled water. 5 Shake the cylinder gently until all the solid has dissolved. 6 With gentle shaking, add more distilled water to the solution, until the level of the solution is exactly at the 100 cm3 mark on the neck of the cylinder. Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 6 Exercise 6.1 1 a b i to split ii to electrolyse iii to discharge iv to decompose to split and to decompose c d Exercise 6.2 2 a is carried out; are connected; becomes; reach; are discharged; splits; move; is switched on; move; occurs; lose; are oxidised i move; are discharged; gain electrons; are gained; is formed; 2e– ii move; are discharged; lose; are lost; is formed; Br2 battery electrons repelled into wire from negative – terminal + electrons attracted to positive terminal A ammeter solid b i ii iii iv v 8 light bulb Solid Appearance of solid Test result Conductor or insulator A shiny, light grey rod bulb lit up and current recorded conductor B hard brown rod bulb did not light up and no current recorded insulator C black rod bulb lit up and current recorded conductor D yellow block bulb did not light up and no current recorded insulator E red–brown strip bulb lit up and current recorded conductor C A and E B D Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 6 continued Exercise 6.3 3 a b 1–C; 2–A; 3–D; 4–B i As ii Therefore iii As iv Therefore v As Exercise 6.4 4 a i ii iii iv b 9 elements compound; produces oxygen; water 2H2 + O2 → 2H2O opposite Across 1 elements 3 negative 6 water 9 two 10 redox 12 graphite 15 electroplating 18 oxygen Down 2 electrolytic cell 4 battery 5 decompose 7 electrolyte 8 ions 11 hydrogen 13 oxidation 14 copper 16 lead 17 anode Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 7 5 Exercise 7.1 1 a b i different; to ii between iii different; from iv same; as The major feature of a chemical change, or reaction, is that new substances are made during the reaction. Many reactions, but not all, are difficult to reverse. During a chemical reaction, energy can be given out or taken in. Most reactions give out energy. 6 a i ii iii iv b enthalpy change of reaction = 2736 – 3462 = -726 kJ / mol break; covalent; releases; released; –; exothermic; formed; used; broken i Key points: • the products have higher energy than the reactants, so the reaction is endothermic • ∆H arrow is pointing upwards, so value is positive • activation energy (Ea) is needed for the reaction to take place ii The product’s energy level would be below that of the reactants and the ∆H arrow would point downwards. i Bond energy is the energy needed to break one mole of the bonds. ii The heat of combustion is the energy given out when one mole of the substance is completely burned. iii Activation energy is the minimum energy needed for the reaction to take place. a Exercise 7.2 2 3 a b c d e a b Given that; chemical reaction Since; physical change For this reason; chemical reaction Given that; physical change For this reason; chemical reaction exothermic endothermic b Exercise 7.3 a b vertical; products; progress; horizontal i exothermic reaction Energy / kJ reactants products heat given out progress of reaction products heat given out action Energy / kJ ii Energy / kJ 4 M = making (bonds) B = breaking (bonds) EXO = exothermic ENDO = endothermic products reactants heat taken in progress of reaction endothermic reaction products heat taken in reactants progress of reaction 10 Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 8 Exercise 8.1 Exercise 8.2 1 2 a b c d e 11 Hydrogen and oxygen take part in an explosive reaction that can be used to power rockets. Photosynthesis is a reaction that takes place in the leaves of green plants. Copper carbonate is green coloured and is stable at room temperature but decomposes quickly when heated with a Bunsen burner, producing a black powder. OR Copper carbonate is coloured green and is stable at room temperature but decomposes quickly when heated with a Bunsen burner, producing a black powder. The metal zinc reacts with copper sulfate solution and the blue colour of the solution fades. OR The metal zinc reacts with blue copper sulfate solution and the colour of the solution fades. The vigorous reaction between calcium carbonate and dilute hydrochloric acid produces a large volume of gas. a b K H T I M E I W Z K V S I R R C T N E X P L O S I V E E S R O E M J P L X R Y C H A U I E N M T N E J U H A V C R N D A C P J E W B P T A T F C K E C E E J E W C A R I A R N B C T N R J S M L I O N C E S P F R A T A B I Y A E A O R A U E N R T O S B R A S E O S Q E A T A U T L A R E S D T E W Y S Y T R E T E S L U H B I T Z E J I E E A I O C T T Y M F Y S S O F A S W T P R E S S U R E F N concentration; surface area; pressure; temperature; catalyst Exercise 8.3 3 4 a b c a b c d concentrated; more concentrated; least concentrated high; higher; highest largest; smallest; lowest; greater; greatest fastest; slowest greater; increases smaller; closer; more; increases faster; more; higher Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 8 continued Exercise 8.4 5 a b horizontal axis origin curve slope change points plateau gradient dependent variable tangent point flattens out trend best-fit line straight line outlier measure independent variable vertical axis Terms (word or combination of words Definition horizontal axis The x-axis of the graph; the axis along which the independent variable (the variable you change) is plotted vertical axis The y-axis of the graph; the axis along which the dependent variable (the variable you measure) is plotted outlier An anomalous point that does not fit close to the curve or straight line of the graph; the line of the graph should not include this point origin The point 0,0 of the graph The slope or gradient of the graph The rate of change shown by the graph; the steepness of the curve shows how quickly the reaction is taking place tangent A straight line drawn at a point on the curve of the graph, used to work out the rate of reaction at that time best-fit line The line drawn that passes through or as close to as many points as possible; this can show the overall trend in the results plateau The part of the graph where the curve flattens out, showing no further reaction i ii iii At B, the gradient has decreased. This shows that less product is formed in a given time. The reaction is slower here. At C, the gradient is very small. This shows that only a small amount of product is being formed. The reaction is slowing down. At D, the graph has flattened. This shows that no more product is being formed. The reaction has stopped. Exercise 8.5 6 a b effects affects c d effect affects; effect 7 a b 12 effect iv / iii / i / ii / v A catalyst is a substance that speeds up the rate of a chemical reaction without being used up during the reaction. The catalyst is chemically unchanged at the end of the reaction. biological; catalysts; affect; faster; milder; without Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 9 Exercise 9.1 1 a b c 3 anhydrous making something absorb water (n) aqueous dried (water has been lost or removed) (adj) dehydrated making something lose water (n) hydration containing no water (adj) dehydration made of or containing water (adj) decomposition; split up; simpler; decomposes; reverse; dehydration; dehydrated; anhydrous; dehydration dehydrated; crystallised; carried out; added; reversed; combined; used Exercise 9.2 2 a b i ii 13 Position on diagram Label reaction vessel H condenser F iron catalyst B liquid ammonia D recycled nitrogen and hydrogen gases C temperature of about 450 °C G mixture of nitrogen and hydrogen gases enters A pressure of 20 000 kPa E 1 2 3 4 5 6 7 A D F G E B C Exercise 9.3 4 5 a b c d e f a b might should will; will will will will In general, a decrease in pressure will move the equilibrium position to the side of the reaction that has the higher number of moles. This side will occupy a higher volume. In general, a decrease in temperature will move an equilibrium position in the direction of the exothermic reaction. There will be more ammonia in the equilibrium mixture. Snitrogen Tiron catalyst Ucompressed V The hydrogen and nitrogen are mixed in a ratio of 3:1. Wcondensed Xrecycled Yammonia Zhydrogen 1 2 3 4 5 6 7 8 S V U T Z W X Y Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 10 Exercise 10.1 Exercise 10.4 1 6 a b oxidised; reduced An oxidising agent is a substance that will give (add) oxygen to another element or compound. a 2 reduction iron oxide + carbon monoxide → iron + carbon dioxide b oxidation Exercise 10.2 3 a b c d In the blast furnace, iron(III) oxide (usually in the form of hematite) is reduced to iron metal by the reducing agent (carbon monoxide). However, in this process the carbon monoxide is oxidised to carbon dioxide. This is a redox reaction as one substance loses oxygen while another gains it. In the extraction of aluminium the aluminium ions (Al3+) present in the electrolyte gain electrons to form neutral aluminium atoms. This is a reduction reaction. Oxidation is the loss of electrons. Reduction is the gain of electrons. An oxidising agent is a substance which will remove electrons from an atom, molecule or ion. A reducing agent is a substance that will give electrons to an atom, molecule or ion. Exercise 10.3 4 a b This is a reduction as electrons are gained as chlorine atoms become chloride ions. This is a reduction as electrons are lost as iodide ions become iodine atoms. c reduction chlorine + potassium iodide → potassium chloride + iodine oxidation 5 14 Compound Oxidation number of metal present Formula of metal ion present copper(II) sulfate +2 Cu2+ iron(III) oxide +3 Fe3+ cobalt(II) chloride +2 Co2+ copper(I) oxide +1 Cu+ Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 11 Exercise 11.1 1 2 3 a An acid is a substance that gives a solution with a pH less than 7 when dissolved in water. b An acid is a solution that reacts with an alkali to give a salt and water only. c An acid dissolves in water to give a solution that contains an excess of hydrogen ions. • All bases neutralise acids. • Bases include metal oxides and hydroxides. • Alkalis are soluble bases. • Not all bases are alkalis. Acids: ions; lower; red; neutralised; only Bases: hydroxides; insoluble Alkalis: dissolve; excess; ions; higher; red Exercise 11.2 4 less acidic; the least acidic B<C<A the least more alkaline; the least X>Y=Z more concentrated Exercise 11.3 15 5 strong; covalent; completely; chloride; weak; some; less; lower; higher; more 6 Statement True / False A sulfuric acid solution is less corrosive than a solution of ethanoic acid. False A hydrochloric acid solution will conduct electricity better than an ethanoic acid solution. True An ethanoic acid solution will produce carbon dioxide gas at a faster rate than a hydrochloric acid solution when reacted with calcium carbonate. False Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 12 Exercise 12.1 Exercise 12.3 1 3 a b c i ii iii i ii iii iv v i ii iii on of on consist of results in depends on dependent on depends on The acidity of a solution depends on the concentration of hydrogen ions present. Adding an alkali to an acid results in the formation of a salt and water only. Salts are ionic compounds consisting of a positive metal ion and a negative non-metal ion. a b 4 a b c i 0.1 mol / dm3 = nought (or zero) point one moles per decimetre cubed (or cubic decimetre) ii 0.5 mol / dm3 = nought (or zero) point five moles per decimetre cubed (or cubic decimetre) iii 20 g / dm3 = twenty grams per decimetre cubed (or cubic decimetre) iv 0.2 mol per 200 cm3 = 1 mol / dm3 = one mole per decimetre cubed (or cubic decimetre) i the amount of substance ii the volume of the solution iii Student exercise burette; acid; volume; pipette indicator; colour; end point evaporated; filtered Exercise 12.2 2 a b 16 i A measuring cylinder was used to add 25 cm3 of dilute hydrochloric acid to a beaker. ii Then some solid magnesium carbonate was added to the acid in the beaker. iii The reaction mixture was stirred with a glass rod. iv More solid was carefully added to the acid in small amounts so that the mixture did not froth out of the beaker. v Further solid was added until there was no more fizzing and some solid was left in the bottom of the beaker. The mixture was stirred and filtered to remove the excess solid. The filtrate was then put in an evaporating basin and heated. It was heated until crystals formed at the edges of the solution. The Bunsen burner was removed and the solution left to cool slowly. After a time the crystals were filtered off and dried between pieces of filter paper. Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 13 Exercise 13.1 1 a b c d e f g h hydrogen halogen non-metal vertical; groups noble gases horizontal; period transition elements T O I O L A N N E E H E O I T L A T G R O U P I S N A R T A T N O Z I R O H G N S O C O I G H N O L S N E R H A B A O E A Z E D N N R R L E L L R O A O S O O H O L O O E K D I T T T I N H E L G O I A Y T E S N R M S N E E N I L H R H E S E E E R L N T L I L T O S N P T L O E E A I N E R R A O M A P I U R T L E N E O G E E L N P I S I R V E R T I C A L E D N L M E P R L N G S T N E M E L E Exercise 13.2 2 a Statement True The first attempts to make a table of the elements placed them in order of increasing atomic mass. ✓ The sequence of the elements is the same, whether it is based on their proton number or their atomic mass. The sequence of the elements is split into rows, based on the electron shells being filled in their atoms. ✓ ✓ The splitting of the sequence of elements gives us a table consisting of horizontal groups and vertical periods. b 17 ✓ Usually, as you move down a group in the Periodic Table, the number of electrons in the outer shell of the atoms is the same. ✓ The first row of the table only has two elements in it, because the first electron shell can only hold two electrons. ✓ All the elements in Group VII of the table have eight electrons in their outer shell. i ii iii iv v vi vii False ✓ continuous two-dimensional electronic configuration group period outer shell energy level Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 13 continued 3 a b 1 the melting A point 5 The chart 2 the melting C points 6 the melting B points 3 the elements C 7 The melting points 4 the proton number C 8 the highest C values A C the; a; the; the; the; a; the Exercise 13.3 4 a b c d e 5 18 Sodium is a highly reactive metal in Group I. It reacts vigorously with cold water. Transition elements form a block in the middle of the Periodic Table. They are especially useful, strong metals. Fluorine is the most reactive of the elements in Group VII. It can react explosively, and it will displace other halogens from compounds. Atoms of the elements get smaller as we move across a period in the table. As they get smaller the elements concerned become less metallic. The elements of Group I are very reactive, and their reactivity increases as we go down the group. Pronoun What the reference is number referring to 1 metals 2 metals 3 alkali metals 4 non-metals 5 transition from metals to non-metals 6 a metal or non-metal 7 copper Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 14 Exercise 14.1 1 a 4 A B C E L E R E A C T M A L L E A B L E C T R O D E S R U B I D C O N D L Y D E I U M U C T S I E L E C T R O G D U C T I L E M O N O X I D E S O N O R O U I c V F H b I 3 19 E b S S 1 Reduction is the removal of oxygen from a compound. 2 Reduction is the gain of electrons by an atom, ion or molecule. regular; lattice; lose; stronger; between; positive; conduct; heat; metallic; ductile This gave a colourless solution. The solution was acidified with dilute nitric acid and then barium nitrate solution added. A white precipitate was formed, showing that the salt was a sulfate. The white zinc salt was dissolved in distilled water to give a colourless solution. Dilute sodium hydroxide solution was added and a white precipitate was formed. This white precipitate redissolved on addition of an excess of sodium hydroxide solution. This is the positive test for zinc ions. Exercise 14.3 5 Exercise 14.2 2 a a Gap Gap 1 brass 8 lattice 1 2 3 4 5 2 copper 9 metallic C A E D B 3 carbon 10 electricity 4 transition 11 ductile 5 stainless 12 positive 6 chromium 13 delocalised 7 molten 14 slide Key word Meaning dilute hydrochloric acid a solution of a substance in a large amount of water (noun) fizzing bubbles of gas forming (noun / -ing form) dissolves the solid disappears forming a solution (verb) precipitate a solid suddenly formed by mixing two solutions or passing a gas into a solution (noun) clear transparent and can be seen through (adjective) colourless has no colour (adjective) milky cloudy white in colour (adjective) b i ii iii iv Mild steel is used for making car bodies because it is easy to shape without breaking. Solder is used for joining metals together because it has a low melting point. Stainless steel is used for making surgical instruments and cutlery because it is resistant to rusting. Brass is used for making decorative objects because it is hard and gold coloured. Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 15 Exercise 15.1 1 2 Property Alkali metals Transition metals hardness soft hard melting point low high density low density high density colour of solid salts white often coloured reactivity highly reactive moderately reactive a Element Reaction with water Reaction with air lithium reacts steadily tarnishes slowly to give a layer of oxide 2Li + 2H2O → 2LiOH + H2 sodium reacts strongly 2Na + 2H2O → 2NaOH + H2 potassium i ii iii iv brilliantly explosively slowly strongly 6 Exercise 15.2 3 a b i further; greater; lower; more/less reactive ii more reactive; greater; further; lower; less Correct answer: iii Exercise 15.3 4 5 20 a b c d a b c is placed is held is bubbled is passed a–ii, b–iv, c–i, d–iii more; will; less will should increasing reactivity tarnishes very quickly to give a layer of oxide reacts violently 2K + 2H2O → 2KOH + H2 b tarnishes quickly to give a layer of oxide One possible set of sentences: Hypothesis If one metal is more reactive than another, it will displace the less reactive one from solution. If we test different combinations of metals and salt solutions we should see which reactions take place. Predictions We/I think that magnesium should displace both zinc and copper from its salts. I/ We expect to see zinc displace copper from solution but that it will not displace magnesium. I/We think that copper will not displace either zinc or magnesium. Exercise 15.4 7 a i ii When magnesium is placed in copper(II) sulfate solution the blue colour of the solution fades, suggesting that magnesium is more reactive than copper. There is no observed reaction when copper is placed in magnesium sulfate solution, which means that copper is less reactive than magnesium. Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 15 continued iii b 21 i ii There is a reaction when magnesium is placed in iron(II) sulfate solution. This means that magnesium is more reactive than iron. copper < iron < magnesium Iron reacted with copper sulfate solution, but it did not displace magnesium from solution. This means that iron is more reactive than copper, but is less reactive than magnesium. Copper did not react with either iron sulfate or magnesium sulfate. This suggests that it is the least reactive of these three metals / it is less reactive than iron or magnesium. Magnesium reacts with both copper sulfate and iron sulfate solutions. This means that it is more reactive than iron or copper. Therefore, we can conclude that magnesium is the most reactive of these metals, and copper is the least reactive of the three. Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 16 c Exercise 16.1 1 a b Key word 1 2 3 4 5 6 7 8 Definition C F E G D A H B T E i ii iii limestone, iron ore, coke molten iron, slag, waste gas tapped off (a process, not a chemical substance) Stainless steel is an alloy of iron that is resistant to rusting. This metal contains iron that has been mixed with another transition metal that does not corrode easily in order to improve the resistance to rusting. Exercise 16.2 2 a A B C C B A U X I R Y O L I T E R E D D C T I O N O L T E N V E P H I T E E N E G A T I F O X Y G E N G R A G b U M Al2O3 Exercise 16.3 3 4 5 22 light; good; alloys; metals; low; corrosion; recycling; expensive; large a air (oxygen) and water b i paint, plastic or oil ii Iron objects are covered with plastic, or by painting, to produce a barrier so that air and water cannot get to the surface of the iron. a Blocks of a metal that is more reactive than iron are attached to the iron or steel object in order to prevent rusting. The blocks of metal react with the air and water in preference to the iron object. b Coating an object with a complete layer of zinc (galvanising) provides a total covering for the object that acts as a barrier preventing water and air from coming into contact with the iron. If the zinc layer is broken by scratching or wear, the zinc still protects by sacrificial protection as it is more reactive than iron. The zinc corrodes rather than the iron. Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 17 Exercise 17.1 1 a 4 pie chart a b nitrogen 78% oxygen 21% argon 0.90% carbon dioxide 0.04% b 2 a i ii iii iv v vi vii i ii iii iv v b c A B C i ii nitrogen oxygen xenon helium neon oxygen argon ✗ An indicator that turns yellow in alkaline solution is methyl orange. ✓ ✗ In clean dry air, carbon dioxide is the only greenhouse gas. ✓ ✗ The only gaseous compound in clean dry air is carbon dioxide. ‘The noble gases in the air’ = ii ‘Methyl orange as an indicator’ = i ‘Carbon dioxide’ = iii The discovery of the noble gases by William Ramsay was remarkable as these gases are very unreactive. Carbon dioxide and methane are the main greenhouse gases present in the air. Exercise 17.2 3 23 other noble gases 0.06% global warming ozone layer sulfur dioxide photochemical smog carbon dioxide climate change i photosynthesis ii combustion Possible answers include: i The process in the first picture is called photosynthesis. It is a reaction taking place in the green leaves of plants in which energy from the Sun is used to convert carbon dioxide and water into glucose. ii The process in the second picture is called combustion. It is a type of reaction in which wood and fossil fuels are burnt to produce energy. Exercise 17.3 5 a b c d 6 a b c 7 a b c 8 ozone and chlorine Harmful organisms such as bacteria are killed. Harmful organisms could spread disease. screens and sand filters Attach some chemicals to themselves, removing them from the water. break down pesticide absorb d e precipitator reservoir 2, 1, 4, 3 A–4; B–2; C–1; D–3 i Three-quarters of our world is covered in water. ii only 2.5% of water on Earth is fresh water iii competition for this water is growing iv The increase in human population means that competition for this water is growing and underground sources are being used up. d The importance of water ✓ because the key word at the end of the first sentence of the introduction is ‘water’ Possible answer: An important step in cleaning water for domestic use is filtration through sand/carbon. Using sand filters out some solid particles that would make the water unpleasant to drink while the carbon removes some harmful chemicals. Together this filtration is a key step in producing clean water for domestic use. Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 18 Exercise 18.1 1 a b c 2 i ethane ii propane iii hexane iv octane i CH4 ii C3H8 iii C4H10 iv C5H12 CnH2n+2 Hydrocarbons are ... ... is methane, CH4. The simplest hydrocarbon ... ... butane. The major source of hydrocarbons ... ... because they only contain carbon–carbon single bonds. Alkanes are saturated hydrocarbons ... ... compounds that contain carbon and hydrogen only. The fourth member of the alkanes is ... ... is the fossil fuel petroleum. Exercise 18.2 3 a b Compound Prefix hexane hex- 6 -ane alkanes butene but- 4 -ene alkenes ethanol eth- 2 -ol alcohols pentanol pent- 5 -ol alcohols ethanoic acid eth- 2 -oic acid carboxylic acids i ii iii methanol CH3OH ethene C2H4 ethanoic acid CH3COOH Exercise 18.3 4 a b 24 i ii iii i ii iii iv A–2 C–1 B–3 In addition; also as well as In addition; also Furthermore; and Number of carbon Suffix atoms in chain c i ii iii Homologous series Unlike alkanes containing carbon and hydrogen atoms, alcohol and carboxylic acid molecules also contain oxygen atoms. Pentene molecules contain a carbon– carbon double bond as well as carbon–carbon single bonds. Carbon can exist in the form of graphite. In addition, it can exist in other structural forms such as diamond. Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 19 Exercise 19.1 1 A 5 C A R B O N B S A T U R A T E D C D E C A N E D A L E B F G H 2 3 K A N E I S T U M E N C O V A L E N T E T H A N O L A L K E N E S a Because both the skeleton and a hydrocarbon molecule have a chain of repeating units to which other structures are attached. i Each ii Each iii Both iv Each v Both b i Both ii Each iii both iv whereas v Whereas c i Alkanes are saturated hydrocarbons whereas alkenes are unsaturated. ii Both ethane and propane are alkanes even though they contain different numbers of carbon atoms. d a functional group / e.g. –COOH ethene; water; colourless; unsaturated; reaction; orange Exercise 19.2 4 25 a b c d e butane three C4H10 / CH3CH(CH3)CH3 compounds; same; structures; isomerism but-2-ene A B C D E F G H O M O L O G O U S F R P R O E A V C T F I U S L F N E T H E N E N N T V A O G P H W E H G C R P K M L O I A J S L T U E J E A L K A N E E I C T O R H Y G P R E Z O T H I S O M E R I S M N U A H S D E R L X N D A R N R Y C R N O E O I L A O B S A T U R A T E D L L X V L C O V A L E N T homologous covalent methane alkane single saturated ethene H I J K L M ethanol functional structural isomerism polymer monomer Exercise 19.3 6 7 a b a b butanol; C4H9OH propanoic acid; C2H5COOH i Despite ii Although iii However iv Whereas i An addition reaction produces just one product, whereas a substitution reaction will produce two products. The reaction of steam and ethene gives just one product and so is an addition reaction. ii Non-renewable resources have a finite lifetime and will eventually be used up. However, renewable resources can be replaced by newly grown materials. Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 20 Exercise 20.1 Exercise 20.2 1 3 2 a b c a b c d e 26 A refinery gas B petrol (gasoline) C paraffin (kerosene) D diesel oil E lubricating oil A E decane → octane + ethene Monomer Polymer ethene CH2=CH2 poly(ethene) propene CH2=CHCH3 poly(propene) styrene CH2=CHC6H5 poly(styrene) chloroethene CH2=CHCl 4 poly(chloroethene) Addition; polymers; broken; Poly(ethene); Fatty acids; monomers; natural; artificial; biodegradable Decane (a liquid) Ethene (a gas) Exercise 20.3 Hydrocarbon series alkane alkene Saturated or unsaturated? saturated unsaturated Reacts with bromine water? Yes/No no yes Boiling point above/ below room temperature above below Possible answers: 5 a In conclusion, while valuable minerals are obtainable by mining the ocean floor, the potential ecological damage to the seabed must also be taken into serious consideration. b Therefore, in order to prevent the further loss of environmentally important rainforest habitats, we must impose greater control on the clearing of forest areas for townships and ranching. 6 In conclusion, there are issues to be resolved in developing hydrogen as a fuel. These include finding methods for safe storage and the development of an extensive infrastructure for distribution. However, with its high energy output, its use as an environmentally clean fuel needs to be exploited. 7 Here are some ideas for the different sections of your answer: Introduction Statements as to how significant plastics have become and the essential problems. Advantages – the usefulness of polymers (one or two main examples) Include ideas about how the introduction of plastics has positively affected our lives – lightweight materials / durability and freedom from corrosion / ease of shaping, moulding and shaping objects / mass production Disadvantages of the use of polymers (e.g. waste disposal, plastic in the oceans) Problems of waste disposal / non-biodegradable products that are consuming resources / impact of waste on land and in the oceans Conclusion Give your own summary and opinion. long-; shorter; alkane; short i Consequently ii Therefore iii Because iv so v because vi Consequently i The alkali metals all react with oxygen and water vapour in the air. Consequently, the alkali metals must be stored under oil. ii Because litmus changes colour in acid and alkaline solutions, it can be used as an acid–base indicator. iii Alkanes and alkenes react differently with bromine water, so bromine water can be used as a test to distinguish them. iv The electronic configurations of noble gas atoms are very stable. Therefore, the noble gases exist as single atoms and are very unreactive. Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 21 Exercise 21.1 1 a b c Verb -ing form Noun – name of process Noun – product of process to condense condensing condensation the condensate to separate separating separation to distil distilling distillation the distillate to filter filtering filtration the filtrate to precipitate precipitating precipitation the precipitate to neutralise neutralising neutralisation to calculate calculating calculation to titrate titrating titration to oxidise oxidising oxidation to reduce reducing reduction to purify purifying purification b precipitation; precipitate filtration; filtered; filtrate separating; purifying; Filtering; precipitating; titrating; distilling 3 27 i ii Exercise 21.2 2 the titre The following is one suggested description. You should check you have the same ideas even though your sentences will be different. The seawater is heated in the flask. The boiling point of water is much lower than that of salt. When the temperature reaches its boiling point, the water boils. The boiling point of salt is much higher so it remains in the flask. The water vapour passes from the flask into the condenser. Cold water flows through the outer jacket of the condenser. The water vapour cools down and condenses back to a liquid in the condenser. The pure water flows from the condenser into the flask. Pure water is the distillate. a i by ii in (by could also be used) iii to iv in v at vi with iii iv v vi Carl Bosch is the person with whom Fritz Haber worked on developing the industrial process for making ammonia. A volumetric pipette is the apparatus with which to measure out an accurate volume of solution. In an acid–alkali titration the end point is the point at which the indicator just changes colour. Group VII of the Periodic Table is the group in which we find the halogens such as chlorine. The boiling point of a liquid is the temperature at which it turns into a gas. Barium nitrate solution is the reagent with which we test for a sulfate. Exercise 21.3 4 5 a b time and solubility in the solvent No, none of the spots present in the samples are at the same distance up the paper. a B b A c B d A e B All these choices give correct advice. Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 21 continued 6 6 allowed solvent to rise up the paper 7followed how the solvent rose up the paper and how the spots separated 8removed the paper from the solvent before the front reached the top of the paper 9carefully hung the paper to dry 10analysed and measured the distances moved by the spot 7 Method to include the following points: • Choice of solvent – try dissolving the two samples of saffron to get a concentrated solution of the yellow colour. • Dissolve and concentrate the two samples of saffron. • Prepare chromatography paper – with pencil baseline. • Carefully spot the two samples in position on the baseline. • Assemble beaker and shallow layer of solvent. • Place chromatogram in the solvent chosen and allow solvent to rise up the paper. • Stop the separation before solvent overruns the top of the paper. • Remove paper and dry carefully / analyse spots to see if the two samples move the same distance or not. 28 Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 22 Exercise 22.1 1 a i ii iii iv The pH can be measured using universal indicator paper – this would give an approximate value. A more accurate value can be found using an electronic pH meter. by using a flame test / a nichrome wire is dipped in the water sample and then held on a strong Bunsen burner flame / a yellow colour to the flame indicates the presence of sodium ions. the flame test gives a quick and clear indication of the presence of certain metal ions / restricted to those metals that give a distinctive colour to the flame precipitation tests are available for various metals that have insoluble and coloured hydroxides / but also for zinc and aluminium that give white hydroxide precipitates / these tests are more involved than the flame test one litre of water must be carefully evaporated to dryness / use an evaporating basin that has first been weighed / evaporate the water in batches in this basin / be careful not to let any water spray out / when all the water has been evaporated, weigh the evaporating basin again to find the mass of the dry residue Exercise 22.2 2 a b C/D/B/A First of all, heat up the nichrome wire in a hot Bunsen flame. Then dip the wire into concentrated hydrochloric acid. Next, dip the wire into a pile of crystals of the sample being tested. Finally, hold the wire in the hot Bunsen flame and note the colour produced by the sample. Exercise 22.3 3 a i ii iii iv v vi 4 4 the solutions being used the halogen solution used the observation seen no change Test solution KCl solution chlorine water 29 bromine water No change iodine water No change KBr solution KI solution Solution turns brown Solution turns brown Solution turns brown No change Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022 CAMBRIDGE IGCSE™ CHEMISTRY: ENGLISH LANGUAGE SKILLS WORKBOOK Chapter 22 continued b c iodine → bromine → chlorine i Concluding paragraph 1: sentences D / F / B Concluding paragraph 2: sentences E / A / C ii In conclusion, study of the Periodic Table shows that the reactivity of the elements in a group in the table does vary as we go down the group. However, it is clear from looking at Groups I and VII that the direction of the trend varies depending on whether the elements are metals or non-metals. Therefore, it is important to keep the distinction between metals and nonmetals in mind when describing trends in the table. Exercise 22.4 4 a b c d 30 Step 1: First of all, dissolve a sample of magnalium in dilute hydrochloric acid to obtain a colourless solution. Step 2: Split the solution into portions and add sodium hydroxide solution dropwise to both samples. Observe the precipitate formed. Step 3: Finally, add further drops of sodium hydroxide to the samples and observe whether the precipitate redissolves or not. Al3+ and Mg2+ precipitate A: magnesium hydroxide precipitate B: aluminium hydroxide Take the solution and add a few drops of dilute nitric acid. Then add silver nitrate solution dropwise to the solution and observe whether a precipitate is formed. The formation of a white precipitate shows that chloride ions (Cl-) were present. Cambridge IGCSE™ Chemistry – Harwood & Chadwick © Cambridge University Press 2022