FS_G2 Test Date: 20/08/2023 Code-A Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456 Time : 3 Hrs TERM EXAM for First Step JEE (Advanced)-2023-25 MM : 180 Test – 1A (Paper - 1)_Actual Pattern-2021 ANSWERS PHYSICS CHEMISTRY MATHEMATICS 1. (B) 20. (B) 39. (D) 2. (A) 21. (D) 40. (B) 3. (B) 22. (B) 41. (C) 4. (D) 23. (A) 42. (D) 5. (46.00) 24. (03.00) 43. (00.00) 6. (15.00) 25. (01.00) 44. (04.00) 7. (08.00) 26. (03.00) 45. (06.00) 8. (59.00) 27. (01.00) 46. (01.00) 9. (05.00) 28. (85.00) 47. (23.00) 10. (01.00) 29. (02.00) 48. (15.00) 11. (A) 30. (A, B, D) 49. (A, B) 12. (B, C, D) 31. (B, C, D) 50. (B, D) 13. (C, D) 32. (A, B, C, D) 51. (B, C) 14. (A, C) 33. (A, D) 52. (A, C) 15. (B, C, D) 34. (A, B, D) 53. (A, D) 16. (A, B, D) 35. (A, C) 54. (B, D) 17. (04) 36. (02) 55. (71) 18. (02) 37. (17) 56. (36) 19. (01) 38. (04) 57. (04) Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456 [1] Test-1A_Paper-1 (Code-A)_G2_Answers & Solutions Term Exam for First Step JEE (Advanced)-2023-25 Test Date: 20/08/2023 FS_G2 Code-A Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456 Time : 3 Hrs TERM EXAM for First Step JEE (Advanced)-2023-25 MM : 180 Test – 1A (Paper - 1)_Actual Pattern-2021 ANSWERS & SOLUTIONS PART –I : PHYSICS 1. Answer (B) 5. Answer (46.00) 6. Answer (15.00) Solution for Q. Nos. 5 & 6 : ∆x ∆a 2 ∆b 3∆c = + + x a b c 2. Answer (A) Number of significant figures in sum is 2. 3. Answer (B) 1 = S U AB t + aAB t 2 2 1 1 v 0 t − gt 2 − gt 2 = 0 2 2 t= = t v0 g dt = 0 ⇒ x = 60 m dx v 02 1 v 02 H − = g 2 g 2 = t ∴ v 0 = gH 4. Answer (D) 302 + (100 − x )2 802 + x 2 + 3 4 100 50 + 46 s 3 4 ∴ dtotal = 802 + 602 + 302 + 402 = 150 m 7. Answer (08.00) ui = 10 m/s, ai = 6 m/s2 u1 = ( 10 – 6) = 4 m/s, a1 = 6 = 3 m/s2 2 u2 = ( 4 – 3) = 1 m/s, a2 = 1.5 m/s2 T = u2 1 2 ∆t3 = = = s a2 1.5 3 2v 0 g cos θ 1 = Y v 0 cos θ.T − gT 2 2 2v 2 2v 02 2v 02 =0 − = tan2 θ 2 g g g cos θ ∴t=1+1+ 8. 2 8 = s 3 3 Answer (59.00) = S1 102 − 42 100 − 16 = = 7m 2× 6 12 Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456 [2] Term Exam for First Step JEE (Advanced)-2023-25 S2 = 42 − 12 15 = = 2.5 m 2×3 2×3 S3 = 12 − 02 = 2 × 1.5 1 1 = m 3 3 2× 2 1 59 m ∴ Stotal = 7 + 2.5 + = 3 6 9. Answer (05.00) Test-1A_Paper-1 (Code-A)_G2_Answers & Solutions 13. Answer (C, D) While both are in air areal = 0, vreal = constant When, one is on ground areal = g, vreal will be increasing 14. Answer (A, C) [η] =ML−1T −1 Block will loose the contact when normal reaction vanishes. [η] =[m]x [D]y [v]z ⇒ x = 1, y = – 2, z = 1 10. Answer (01.00) Draw F.B.D. at t = 3 s ∴ η =k mv D2 15. Answer (B, C, D) 11. Answer (A) S = t3 + 5 am = µg = (0.1)10 = 1 m/s2 dS = 3t 2 dt a2m = v = 3t2 1 m/s2 2 1 3 arel = 1 + = m/s2 2 2 dv = 6t dt At t = 2 s (1) = (2)t – v = 12 m/s (12)2 144 ⇒ = ac = = 7.2 m/s 20 20 dv = 12 m/s2 dt a= ac2 + at2 = ≈ 14 m/s2 12. Answer (B, C, D) dv = 4 m/s2 at = dt aR = v2 = 16 m/s2 R t= 1 3 2 t 22 2 s 3 16. Answer (A, B, D) max ( 0.5 ) × 30 = 15 N f= s 122 + (7.2)2 3m amax = 0.5 × 10 = 5 m/s2 a= 10 5 = m/s2 6 3 17. Answer (04) 4F2 = 4F2 + F2 + 4F2cosθ cosθ = − 1 4 Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456 [3] Test-1A_Paper-1 (Code-A)_G2_Answers & Solutions 18. Answer (02) Term Exam for First Step JEE (Advanced)-2023-25 25. Answer (01.00) Retarding force F = ma = µR = µmg rmix 4/5 = = 2= rx 4 / 10 ∴ a = µg Now from equation of motion v2 = u2 – 2as ⇒ 0 = u 2 – 2as ⇒ s = 2 2 2 = 1 v 02 u u = = 2a 2µg 2µg 36 4 36 = = M(avg) 1 M(avg) M(avg) = 9 19. Answer (01) Suppose mole of H2 and CH4 are X and Y mg 3 g = ⇒ a= m (g – a) 2 3 respectively. 9= PART –II : CHEMISTRY 20. Answer (B) 2 × X + 16 × Y (X + Y) 9X + 9Y = 2X + 16Y Initially electrons are present in 6th state. ∴ Transition belonging to infrared region : 6 → 5, 6 → 4 6 → 3, 5 → 4, 5 → 3 4→3 X 1 = Y 1 26. Answer (03.00) N + e− → N− (Endothermic process) 21. Answer (D) Number of radial nodes for given orbital 27. Answer (01.00) =n––1=1 E.A. of Be is zero or negative. 28. Answer (85.00) 22. Answer (B) Na+ Mg+ Al+ Si+ s0 s1 s2 s 3 p1 + For the first excited state n = 2 Energy = −13.6 × + Na has noble gas configuration while Al has fully filled s-orbital. 23. Answer (A) = −13.6 × + 24. Answer (03.00) Mavg 4 = = 2 1 Mavg 16 M(avg) = = 2 1 2 Suppose mole of C2H4 and CO2 is x and y 32 = 28 × x + 44 × y x+y n2 25 22 = −85 eV rH = 0.529 n2 1 = 0.529 × 1 Å M(avg) = 32 respectively Z2 29. Answer (02.00) O= N= O has bond angle equal to 180°. rH2 = rmix Mx M(mix) = 0.529 Å rBe3 + 0.529 × = 22 = 0.529 Å 4 30. Answer (A, B, D) 3dxy > 4dxy (penetration power) 31. Answer (B, C, D) There are three possible values of spin quantum 4x = 12y number it means an orbital can accommodate 3 x 12 3 = = y 4 1 electrons. So 1s1 – 1s3, first period would have 3 vertical columns. Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456 [4] Term Exam for First Step JEE (Advanced)-2023-25 Test-1A_Paper-1 (Code-A)_G2_Answers & Solutions 37. Answer (17) 32. Answer (A, B, C, D) For mth line n2 = (m + 1) Let the volume of each vessel be V L 1 1 1 = Rz2 2 − 2 λm 1 (m + 1) V ×1 300 R moles of Cl2 = for nth line n2 = (n +1) moles of Cl2O = 1 1 1 = Rz2 2 − 2 λn 1 (n + 1) Cl2O → Cl2 + λm (m + 1)2 (n + 1)2 − 1 = λn (n + 1)2 (m + 1)2 − 1 V × 1.5 300 R 1 O2 2 After reaction total moles of Cl2 33. Answer (A, D) = V 1.5 V 2.5 V 5V + = = 300 R 300 R 300 R 600 R moles of O2 = 1.5 V 1.5 V = 2 × 300 R 600 R Total moles of gases in two vessel after the 34. Answer (A, B, D) The dipole moment of CH2Cl2 is greater than reaction = 5V 1.5 V 6.5 V + = 600 R 600 R 600 R CHCl3. When the two vessel are kept in water bath at 35. Answer (A, C) different temperatures diffusion will take place till En = –13.6 × Z2 n 2 the pressure of the gases in two vessel becomes eV ∴ 3.4 eV = –13.6 × equal. Let the moles of gases left in one of vessel 22 2 n ⇒n=4 n = 4, l = 2, m = 0 belongs to 4d orbital Number of angular nodes in an orbital = value of l Number of radial node in 4d = 1 Since it is a unielectronic species, there will be no shielding and the nuclear charge felt will maintained at 27°C be x. Thus moles of gases in another vessel maintained at 52°C would be 6.5 V − x . 600 R R × 325 x × R × 300 6.5 V = − x V 600 R V x = 5.65 × 10−3 V R P = 5.65 × 10 −3 V R × 300 × = 1.695 ~ 1.7 atm . R V be 2e. 36. Answer (02) 1 1 1 = RH z2 2 − 2 λ n1 n2 38. Answer (04) Energy of incident photon should be higher than for n1 = 1, n2 = ? work function to slow photoelectric effect 1 1 = 1.097 × 107 × 4 2 − 2 30.4 × 10 1 n2 Energy of photon 1 −9 n2 = 2 = 6.62 × 10−34 × 3 × 108 300 × 10−9 × 1.6 × 10−19 Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456 = 4.14 eV [5] Test-1A_Paper-1 (Code-A)_G2_Answers & Solutions Term Exam for First Step JEE (Advanced)-2023-25 PART –III : MATHEMATICS 39. Answer (D) | 2x − 5 | < 1 −1 < 2 x − 5 < 1 4 < 2x < 6 2<x<3 x ∈ (2, 3) 40. Answer (B) D≥0 −2 2 , ⇒ 3a2 – 4 ≤ 0 ⇒ a ∈ 3 3 If p > q, the two curves intersect at 8 points; 2 in Also f(2) > 0 each quadrant ⇒ a2 – 2a + 3 > 0 ⇒ a ∈ R x.y < 0 represents second and fourth −b <2 2a quadrant. So, required number of ordered pairs ⇒ −( −a ) <2 2 ×1 ⇒ a<4 41. Answer (C) If p < q, the two curves do not intersect. will be 4. 45. Answer (06.00) 46. Answer (01.00) Solution of Q. Nos. 45 & 46 : ( A ∪ (B ∪ C )) = {1, 2, 3, 4, 5, 6} ∴ n ( A ∪ (B ∪ C )) = 6 A × B = {(1, 3), (1, 4), (2, 3), (2, 4), (3, 3), (3, 4)} B × C = {(3, 4), (3, 5), (3, 6), (4, 4), (4, 5), (4, 6)} ( A × B ) ∩ (B × C ) = {(3, 4)} 42. Answer (D) n (( A × B ) ∩ (B × C )) = 1 A = {2, 3, 5, 7}, B = {1, 2, 3, 4, 5} 47. Answer (23.00) ∴ A ∩ B = {2, 3, 5} 48. Answer (15.00) ∴ n[(A × B) ∩ (B × A)] = [n(A ∩ B)]2 = 32 = 9 ordered pairs 43. Answer (00.00) 44. Answer (04.00) Solution for Q. Nos. 43 & 44 : Solution for Q. Nos. 47 & 48 : sin x cos y = 1 4 3 tan x = 4 tan y 3 sin x 4 sin y = cos x cos y 3 sin x cos y = 4 sin y cos x 3× 1 3 = 4 sin y cos x ⇒ sin y cos x = 4 16 ∴ sin(= x + y ) sin x cos y + cos x sin y = 4+3 1 3 7 + = = 16 4 16 16 ∴ a + b = 7 + 16 = 23 Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456 [6] Term Exam for First Step JEE (Advanced)-2023-25 Test-1A_Paper-1 (Code-A)_G2_Answers & Solutions 53. Answer (A, D) sin(= x − y ) sin x cos y − cos x sin y = α + β = –k and αβ = 9 1 3 1 − = 4 16 16 α + 2β = 2αβ2 ∴ a – b = 16 – 1 = 15 ⇒ –k + β = 18β ⇒ β = − 49. Answer (A, B) x + 2y = 5 2 k k So, − + k − + 9 = 0 17 17 For x = 1, y = 2 For x = 3, y = 1 If x ≥ 5 , then y is negative which does not belong to natural number. If x = 2, 4, then y become rational number. 51 ⇒ k= ± 4 54. Answer (B, D) Coffee is greater than choco. ∴ Domain = {1, 3} ∴ x>y Range = {2, 1} Each pack is at least 10 g 50. Answer (B, D) where x ≠ Let z = x + iy (x + iy)2 – (x – iy) – (x2 + y2) + 55. Answer (71) 64 ( 64 | x |5 x + y ≥ 10 ∴ 1 2 ) Z = (6 + 5i)2 =0 5 = 36 +25i2 + 60i x2 + y 2 2 = 11 + 60i ⇒ 2xy – y = 0 ⇒ y = 0 Also, − x + ∴ = 0 ⇒ x= 2 Z= 11 − 60i Re(Z ) − Im(Z ) = 11 – (–60) = 71 56. Answer (36) So, z = 2 If x and y are integers then sinx = siny 51. Answer (B, C) ⇒ x=y 1 ∉ A ∪ (B ∩ {1, 2, 3}) n(A × A) = 81 ⇒ 1 ∉ A and 1 ∉ B ∩ {1, 2, 3} Out of these 81 ordered pairs (1, 1), (2, 2) ..., (9, 9) ⇒ 1 ∉ A and 1 ∉ B ⇒ 1∉A∪B Cannot satisfy the given inequality. ⇒ 1 ∈ (A ∪ B)′ Required number of ordered pairs 4 ∉ B ∩ {1, 2, 3} and 5 ∉ B ∩ {1, 2, 3} = So, the smallest possible set A = {4, 5} Also, smallest possible set B = φ (when A = {2, 3, 4, 5}) 81 − 9 = 36 2 57. Answer (04) 52. Answer (A, C) tan2 θ sec 2 θ − 1 (sec θ + 1)(sec θ − 1) = = (1 + sec θ)2 (1 + sec θ)2 (1 + sec θ)2 1 −1 sec θ − 1 cos θ = = 1 sec θ + 1 +1 cos θ = k 17 tan10º tan80º + tan20º tan70º + tan30º tan60º + tan40º tan50º = tan10º cot10º + tan20º cot20º + tan30º cot30º + tan40º cot40º tan θ cot(90º − θ) = 1 θ = tan cot θ =1+1+1+1 1 − cos θ 1 + cos θ =4 Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456 [7]