ARGO CHEAT SHEET 3.2 (Oxidation of Alcohol ) IAtcohol-Alde.by# → viii. IAkohol→Ket# ' o . Hy Hz : 3. 3 ( Reduction of Aldehydes and ketone) UsingNaBHyasareducingagen# " what can these two reducing agents " → → reduce ? to# . :÷÷÷÷÷÷ii: Li Al Hy Usingl.tt/Hyasareducingagent 3 . . is ÷ . . .. Na BH , ( Oxidation of Aldehydes and ketones to Form Carboxylic Acids ) AIdehyde-icarboxylic.AT# ÷÷÷÷÷÷:÷ n . " it → Nk → . It Was µ BBB His → : A OH it: " ketone-carboxylicAC.it E EXAMPLE " Htf p. 1: ' " tito . 2. mild acid - . → * t work up x x " ' ix. ' → mon . . T.io ' → → ii. . o . - . . E " - ⇐ 2 H2O . o a MP " ÷: " no . → " 3. 5 ( Nucleophilic Addition with HCN ) carbonyl-containgcompounds-cyanohydrf.IE " ' - :c .. 3. 6 ( Qualitative ri a Tests for the Presence of carbonyl + - on Groups ) ::::::÷÷÷:#i± 't Fatten tHEEEERMm #E#FE#¥F ' t TEETHING R REACTION p.cl/y+cuz+ → cup + p.cl# RIFT IP " t Agt Ag + p, R - r - " " - c Hz + F Eltz OH F - " - th → R - H ÷ Iz to H - → R R - ICHI - § Etta " - t t → t H2O et Es Eti I - R - c at : → R in brick red Cudd - positive Result - precipitate metallic silver mirror pale yellow CHI , precipitate R - - at, t CHIS 3. 7- ( Esterification) CarboxylicAcids→Est# i÷÷÷÷÷÷: "" a U ' ÷ a . - n A - "' . " is " ÷ . . ester ester hydrate 3.8 (carbonyl - it. + compounds Reduction to Alcohol ) contain g Aldehyde→Akoh# fr " two . Ketone→Akoh# fr " " " two . Ester→Akoh ArOH " ÷ e 2. HD :c . H : x .- - - . H CarboxylicAcid→Alcoh H H - tN- H H H H - ALA H : :÷¥± . - AH C O "" → :O : - H it - Must H no:* .io . ? - OH i ¥ H . - n' Htiioit 3.9 ( Reduction Using Grignard Reagent) AIdehydeorketoneorianardreaaent-AK.ch# it t . a → . pix . + at RIH Esterorianardreaaent-Alc.ch# PRE H - H 3. 10 ( Ester ' H . me a ' me Hydrolysis Using → Hat me in → . - . a → . + it . R Acids and Bases) Acid-CatalyzedEsterHydrolys ( ft * (2 ] (1) g [3] m A- ( " H TI - ton ¥ HQ AEA n + A- , " ¥ ' + . ¥ at H A - carboxylic : acid Base-PromotedEsterHydrolys " " ¥ + carboxylate anion it tat ADDITIONAL and Acetal Hemi acetal Formation it ⇐ . hemi acetal ⇐ acetal Formation of Hydrates from Aldehydes or ketones ' " " . iii. i gem diol - Baeyer - Villiger Oxidation ± " Ketone ester . to . .