Organic Chemistry Summary

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ARGO CHEAT SHEET
3.2 (Oxidation of Alcohol )
IAtcohol-Alde.by#
→
viii.
IAkohol→Ket#
'
o
.
Hy
Hz
:
3. 3 ( Reduction of Aldehydes and ketone)
UsingNaBHyasareducingagen#
"
what can these two
reducing agents
"
→
→
reduce ?
to#
.
:÷÷÷÷÷÷ii:
Li Al Hy
Usingl.tt/Hyasareducingagent
3
.
.
is
÷
.
.
..
Na BH ,
( Oxidation of Aldehydes and ketones to Form Carboxylic Acids )
AIdehyde-icarboxylic.AT#
÷÷÷÷÷÷:÷
n
.
"
it
→
Nk
→
.
It
Was
µ
BBB
His
→
:
A
OH
it:
"
ketone-carboxylicAC.it
E
EXAMPLE
"
Htf
p.
1:
'
"
tito
.
2. mild acid
-
.
→
*
t
work up
x
x
"
'
ix.
'
→
mon .
.
T.io
'
→
→
ii.
.
o
.
-
.
.
E
"
-
⇐
2
H2O
.
o
a
MP
"
÷:
" no .
→
"
3. 5 ( Nucleophilic Addition
with
HCN )
carbonyl-containgcompounds-cyanohydrf.IE
"
'
-
:c
..
3. 6 ( Qualitative
ri
a
Tests for the Presence of carbonyl
+
-
on
Groups )
::::::÷÷÷:#i±
't
Fatten
tHEEEERMm
#E#FE#¥F
'
t
TEETHING
R
REACTION
p.cl/y+cuz+
→
cup +
p.cl#
RIFT
IP
"
t
Agt
Ag
+
p,
R
-
r
-
"
"
-
c Hz +
F Eltz
OH
F
-
"
-
th →
R
-
H
÷
Iz to H
-
→
R
R
-
ICHI
-
§ Etta
"
-
t t
→
t
H2O
et Es Eti I
-
R
-
c
at
:
→
R
in
brick red Cudd
-
positive Result
-
precipitate
metallic silver
mirror
pale yellow CHI ,
precipitate
R
-
-
at,
t
CHIS
3. 7- ( Esterification)
CarboxylicAcids→Est#
i÷÷÷÷÷÷:
""
a
U
'
÷
a
.
-
n
A
- "'
.
"
is
"
÷
.
.
ester
ester hydrate
3.8 (carbonyl
-
it.
+
compounds Reduction to Alcohol )
contain g
Aldehyde→Akoh#
fr
"
two .
Ketone→Akoh#
fr
"
"
"
two .
Ester→Akoh
ArOH
"
÷
e
2.
HD
:c
.
H
:
x
.-
-
-
.
H
CarboxylicAcid→Alcoh
H
H
-
tN-
H
H
H
H
-
ALA
H
:
:÷¥±
.
-
AH
C
O
"" →
:O :
-
H
it
-
Must
H
no:* .io .
?
-
OH
i
¥
H
.
-
n' Htiioit
3.9 ( Reduction Using Grignard
Reagent)
AIdehydeorketoneorianardreaaent-AK.ch#
it
t
.
a
→
.
pix
.
+
at
RIH
Esterorianardreaaent-Alc.ch#
PRE
H
-
H
3. 10 ( Ester
'
H
.
me
a
'
me
Hydrolysis Using
→
Hat
me
in
→ .
-
.
a
→
.
+
it .
R
Acids and Bases)
Acid-CatalyzedEsterHydrolys
( ft
*
(2 ]
(1)
g
[3]
m
A-
(
"
H
TI
-
ton ¥
HQ
AEA
n
+
A-
,
"
¥
'
+
.
¥
at H A
-
carboxylic
:
acid
Base-PromotedEsterHydrolys
"
"
¥
+
carboxylate
anion
it
tat
ADDITIONAL
and
Acetal
Hemi acetal
Formation
it
⇐
.
hemi acetal
⇐
acetal
Formation of
Hydrates from Aldehydes
or
ketones
'
"
"
.
iii.
i
gem diol
-
Baeyer
-
Villiger Oxidation
±
"
Ketone
ester
.
to .
.
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