Asset Intelligence Report A PRIMER ON CORROSION UNDER INSULATION SEPTEMBER 2022 A Higher Level of Asset Integrity Intelligence Sponsored by Copyright © 2022 by Inspectioneering, LLC 24900 Pitkin Road, Suite 325 Spring, Texas 77386 USA www.inspectioneering.com All rights reserved. No part of this publication may be reproduced, distributed, or transmi ed in any form or by any means, including photocopying, recording, or other electronic or mechanical methods, without the prior wri en permission of the publisher, except in the case of brief quotations embodied in critical reviews and certain other noncommercial uses permi ed by copyright law. Inspectioneering would like to thank all of those that contributed to the development of this work. For more downloadable resources, visit inspectioneering.com/downloads. The methodologies, technologies, philosophies, references, case histories, advice and all other information included in this work are presented solely for educational purposes. All information found in this report is without any implied warranty of tness for any purpose or use whatsoever. None of the contributors, sponsors, administrators or anyone else connected with this report, in any way whatsoever, can be held responsible for the inclusion of inaccurate information or for your use of the information contained herein. DO NOT RELY UPON ANY INFORMATION FOUND IN THIS BOOK WITHOUT INDEPENDENT VERIFICATION. fi tt Inspectioneering.com | Page 2 tt tt A Primer on Corrosion Under Insulation CONTENTS Overview 4 History of CUI 4 Causes 5 Detection 6 Prevention and Mitigation 7 Codes, Standards, and Best Practices 7 References 8 A Primer on Corrosion Under Insulation Inspectioneering.com | Page 3 Corrosion under insulation (CUI) and corrosion under reproo ng (CUF) are some of the most well-known phenomena in the process industries, yet they continue to constitute a large percentage of global maintenance expenditures. CUI is a subject that is well researched and understood based on extensive studies to determine its causes, effects, prevention, and mitigation. In simple terms, CUI is any type of corrosion that occurs due to the presence of moisture on the external surface of insulated or reproofed equipment. It is the presence of improperly speci ed insulation (i.e., wicking characteristics, chloride content, etc.) that makes this class of corrosion so aggressive and hard to detect and locate. The buildup of moisture can be caused by Figure 1. Example of CUI after insulation was removed several factors detailed in the “Causes” section of this primer. The corrosion itself is most commonly galvanic, chloride, acidic, or alkaline corrosion. If undetected, the results of CUI can lead to the shutdown of a process unit or an entire facility. In some cases, it may even lead to a process safety incident. History of CUI Corrosion under insulation has been around since insulation started being used on pipes and vessels. The frequency and severity of damage and related failures increased markedly after the 1973 oil shock when re nery operators started insulating low-temperature hot service piping and equipment. Despite the prevalence, CUI was not generally understood until the release of ASTM STP 880, Corrosion of Metals Under Thermal Insulation, in 1985. This led to the funding of a study by the US Materials Technology Institute to determine the effectiveness of nondestructive evaluation (NDE) methods in dealing with CUI. Not one single NDE technique was identi ed as being the best, but complementary NDE methods used together were seen to increase con dence levels for detecting CUI. Fortunately, NDE technology and techniques have improved signi cantly since that preliminary study. In 1998, NACE published RP 0198-98, The Control of Corrosion Under Thermal Insulation and Fireproo ng Materials - A Systems Approach. When published, RP 0198-98 was the only standard speci cally directed at combating CUI that was available to the public. This recommended practice suggested using protective coatings in lieu of insulation where applicable. Figure 2. Example of CUI after insulation was removed Inspectioneering.com | Page 4 fi fi fi fi fi fi fi A Primer on Corrosion Under Insulation fi fi fi Overview Signi cant strides have been made since the release of the RP There are several different types of corrosion that can occur, the 0198-98, and there are now several standards, best practices, and most common of which are galvanic, acidic, or alkaline, and studies that have led to a deeper understanding of ways to chloride stress corrosion cracking of austenitic stainless steels prevent and detect CUI, such as API RP 583, Corrosion Under [2]. Insulation and Fireproo ng, Second Edition, March 2021. Galvanic corrosion generally results from wet insulation with Causes an electrolyte or salt present that allows a current ow between While CUI may be one of the most well-known phenomena in dissimilar metals, such as the insulated metal pipe surface and the process industries, it is also the most prevalent. It is dif cult the outer jacket or accessories. The extent and severity of the to prevent because, by and large, no matter what precautions are attack on the less noble metal depend not only on the difference taken, water eventually bypasses the weather barrier (jacketing), in potential of the two metals but also on their relative areas. The gets through the insulation, and comes in contact with process complete galvanic series and the voltage potential for each metal surfaces. In more severe cases, this may even go unnoticed until or alloy appear in handbooks and other standard references [2]. process leakage occurs [1]. Alkaline or acidic corrosion results when an alkali or acid and According to API 570, there are speci c susceptible temperature moisture are present in certain brous or granular insulations. ranges under which CUI may occur. For carbon steel piping For hot service above 250°F, most of the water is driven off. This systems, the range is between 25°F and 250°F, particularly where water vapor may condense at the edge of the insulation and operating temperatures cause frequent or continuous dissolve the alkaline or acidic chemicals, resulting in corrosion condensation and re-evaporation of atmospheric moisture. of the aluminum or steel jacketing [2]. Carbon-steel piping systems that normally operate in-service Chloride (halide) corrosion and stress corrosion cracking above 250°F, but that are in intermittent service, are also at risk. CUI has even occurred in process piping operating above 600°F when insulation becomes soaked during intermittent downtimes by events such as drift from cooling towers, water from deluge systems, water from cleaning equipment, and rain. can be caused by the combination of insulation containing leachable chlorides with the 300 series austenitic-stainless-steel surfaces when moisture is present and temperatures are above 140°F. The concentration of the chloride ion usually results from the evaporation of rainwater, or of water used to ght res, rain or condensation, or of process water. Stress-corrosion cracking of piping and vessels and insulating jackets often results from airborne salts in coastal regions [2]. Figure 3. CUI leak discovered on hot service vessel Figure 4. CUI damage found on sweating service small bore operating at 180°F, 25 years in service pipe, 5 years in service fi Inspectioneering.com | Page 5 fi fl fi fi fi fi fi A Primer on Corrosion Under Insulation Detection Conventional radiography involves a process where radioactive There are several methods for detecting CUI, including “brute rays are directed at the object to be inspected, passing through it, forcing,” which is the practice of physically removing insulation, and capturing the image on visually inspecting, mitigating, repairing, re-coating, and re- numerous advantages, including use with insulation of any insulating, where suitable. Other methods may be used with an thickness or type; through many types of internal product (some appropriate strategy without removing insulation such as cases might require very high radiation sources); on pipes of radiography, pulsed eddy current, guided-wave ultrasonics, and varying diameters; and on both thick and thin wall pipes. Check ultrasonic thickness measurements from the internal surface of with your NDE specialist to make sure conditions permit valid the equipment, where practicable. Some operating facilities usage [3]. apply risk and/or criticality analysis to prioritize pressure vessels Digital radiography: As opposed to conventional radiography, and piping for CUI inspection as opposed to “brute forcing.” Unfortunately, there is still no NDE “silver bullet” for CUI yet. lm to be examined [3]. It has digital radiography relies on exposing reusable storage phosphor screens as an alternative to traditional silver halide lm. This Prior to selecting one or more inspection methods, one should allows the information to be stored digitally, saving both time understand what is or is not likely to be found based on the and storage space. It also requires less radiation due to the limitations of the methods selected and the impact on decisions phosphor lm, and therefore has a reduced impact on the safety that will be made about the anticipated reliability and suitability compared to conventional radiography. Consult with your for service of the component(s) in question (i.e., what risk or radiation safety specialist to make sure you fully understand the probability of failure remains). As with any inspection strategy, safety impact prior to establishing the Safe Zone [3]. it is common to complement approaches. Low intensity x-ray: A low-intensity x-ray imaging scope is a A partial sampling of the most popularly used detection hand-held, totally portable uoroscopic device utilizing a low- techniques is described as follows. As with anything, they have energy, low-intensity gamma source. This can be a very quick caveats, bene ts, and limitations. Check with your NDE way of qualitatively screening pipe for CUI. Iridium-192 is a specialist to make sure you understand the availability, typical radiation source for this technique. limitations, and bene ts of the various options. Pulsed eddy current (PEC): This method has been used in Brute forcing: As the least complex way to detect CUI, brute corrosion detection for several years and is highly useful in forcing involves simply stripping the insulation off the situations where an object’s surface is rough or inaccessible. equipment and examining it for corrosion. This is a Moreover, this method does not require surface preparation or comparatively time-consuming, expensive work process, the removal of insulation; thus, it can be a quick and cost- especially if the insulation contains asbestos, so it may not be effective solution for corrosion detection. The method works by suitable for all situations [1]. Targeted inspections in areas with a sending out a pulsed magnetic high probability of CUI can lower the overall disruptiveness and penetrates through the non-magnetic insulation between the cost of this detection strategy. The utilization of insulating probe and the object being inspected. This will induce eddy materials which can be removed and reused is often preferred. currents that can be measured to determine whether corrosion Brute forcing may or may not be preceded by visual inspection eld via a probe coil which is present [4]. of the insulated vessels or piping looking for signs of moisture Guided-wave ultrasonics (GWUT): This method of testing ingress such as rust discoloration of the weather barrier, involves sending guided ultrasonic waves out along the axial insulation damage, etc. It should also consider areas where direction of a pipe and then measuring the re ections for echoes moisture could collect such as low points, supports, insulation which might be caused by corrosion. The main advantage of this support rings, etc. Consideration may also include insulation method is that it is possible to inspect supports that are not type and their propensity to absorb or hold moisture. directly accessible for visual inspection. The downside of the Conventional radiography: This is the most common NDE technique used for detecting CUI without insulation removal [1]. on the capabilities of the inspector and the testing procedures Inspectioneering.com | Page 6 fi fl fi fi fl fi fi fi A Primer on Corrosion Under Insulation method is that the accuracy of the results is strongly dependent used; thus, an inexperienced inspector can lead to inaccurate effective maintenance practices will help to prevent corrosion results [5]. While insulation removal between the transducer damage before it becomes a severe problem. However, rings is not needed, access to the pipe surface is required at each maintenance alone is not an effective solution without a well- end. Refer to the manufacturer for the maximum distance thought-out inspection strategy as none of these mitigation between transducer rings required to achieve the desired practices guarantee the complete prevention of CUI [2]. sensitivity. Insulation should be certi ed as chloride free to avoid related Ultrasonic thickness measurements: This process can be used to determine the external condition of vessels and Codes, Standards, and Best Practices remaining thickness of piping components. It works by sending API 510, Pressure Vessel Inspector Program, is an inspection ultrasonic waves into the surface of the object and measuring code that covers the in-service inspection, repair, alteration, and the time taken by the wave to return to the surface. It is a simple rerating activities for pressure vessels and the pressure relieving technique; however, it does require adequate contact with the devices protecting these vessels. It applies to most re ning and material, so it is not viable for every situation and requires chemical process vessels that have been placed into service. CUI insulation removal for access to the physical surface. inspection is covered in Section 5.5.6 of the standard (Tenth Other techniques (i.e., neutron backscatter, infrared thermography, Edition released April 2014). etc.) can help to nd moisture under insulation, which may then API 570, Piping Inspection Code - Inspection, Repair, Alteration help indicate where CUI is potentially occurring as well. These and Rerating of In-Service Piping Systems, provides guidance on methods infer that there is potential CUI activity, as opposed to how to determine which piping systems are most susceptible to directly detecting metal loss or cracking. CUI as well as some of the most common locations to nd CUI Dye penetrant testing (PT): PT is often used to sample areas on those systems (Section 5.8, Fourth Edition released February for chloride stress corrosion cracking of austenitic stainless 2016). steels. This does require insulation removal to access the API RP 574, Inspection Practices for Piping System Components, chloride exposed surface of the component. discusses inspection practices for piping, tubing, valves (other Prevention and Mitigation than control valves), and There are several ways to prevent CUI. In general, it is typically far more cost-effective to prevent CUI than to repair or even replace damaged equipment later. ttings used in petroleum re neries and chemical plants. To aid inspectors in ful lling their role in implementing API 570, this document describes common piping components, valve types, pipe joining methods, inspection planning processes, inspection intervals and techniques, and It is also important to understand the system approach for the types of records. CUI is covered in Section 6.3.3 (Fourth Edition prevention of CUI. First and foremost, the most effective method released November 2016). of preventing CUI is to keep water or electrolytes from contacting the unprotected metal surface. To design a system that has the best odds of mitigating CUI, a specifying engineer should use a three-pronged approach that utilizes (1) effective protective pipe coatings, (2) well-designed and installed weather barriers (jacketing), and (3) thermal insulation that is designed to mitigate CUI and is tight tting, durable, and water resistant. There are several useful test standards that can inform the speci er as to which thermal insulations are most appropriate for use in CUI temperature range services. It is important to note most standardized tests evaluate insulation materials “out API RP 583, Corrosion Under Insulation and Fireproofing, covers design, maintenance, inspection, and mitigation practices to address external CUI as it applies to pressure vessels, piping, storage tanks, and spheres. It examines the factors that affect the damage mechanisms, as well as provides guidelines to prevent external corrosion or cracking under insulation, maintenance practices to avoid damage, inspection practices to detect and assess damage, and the guidelines for risk assessment of equipment or structural steel subject to CUI (First Edition released May 2014). of the box,” so understanding how materials will perform “in NACE SP0198-2010, Control of Corrosion Under Thermal use” is key in selecting the proper insulation [9]. Furthermore, Insulation and Fireproo ng Materials – A Systems Approach, fi fi Inspectioneering.com | Page 7 fi fi fi fi fi fi fi A Primer on Corrosion Under Insulation fi damage. (Published July 2010). This standard is a replacement for NACE 6. Alleyne, D., 2012, "Guided Wave Testing for touch point RP 0198-08 (March 2004). corrosion," 18th WCNDT, Durban, South Africa. ASTM STP 880, Corrosion of Metals Under Thermal Insulation, 7. Wikipedia, 2022, “Ultrasonic thickness measurement,” provides information on corrosion problems that can occur on https://en.wikipedia.org/wiki/ thermally-insulated plant equipment and piping components if Ultrasonic_thickness_measurement. the insulation becomes wet (First Edition released in 1985). ASTM C795-08 (2018), Standard Speci cation for Thermal Insulation for Use in Contact with Austenitic Stainless Steel, is used to assess the tness for use of insulation on stressed austenitic stainless-steel pipe and equipment which is susceptible to corrosion cracking. 8. Corrosion Doctors, (n.d.) “Corrosion under Insulation (CUI),” http://corrosion-doctors.org/Forms-crevice/CUI.htm. 9. Williams, J., Evans, O., 2010, “The In uence of Insulation Material on Corrosion Under Insulation,” NACE Northern Area Western Conference, Calgary, Alberta. ASTM C871-18, Standard Test Methods for Chemical Analysis of Thermal Insulation Materials for Leachable Chloride, Fluoride, Silicate, and Sodium Ions, provides an analytical technique to measure the amount of halides and protective ions that can leach from thermal insulation. ASTM C1617-19, Standard Practice for Quantitative Accelerated Laboratory Evaluation of Extraction Solutions Containing Ions Leached from Thermal Insulation on Aqueous Corrosion of Metals, provides a test method for assessing the in uence of different thermal insulations (in their pristine condition) on corrosion rates of carbon steel and other metallic substrates. ASTM C1763-20, Standard Test Method for Water Absorption by Immersion of Thermal Insulation Materials, is used to assess the water absorption rate of thermal insulation materials. References 1. Reynolds, J., 2004, “99 Diseases of Pressure Equipment: Corrosion Under Insulation,” Inspectioneering Journal, 10(3), pp. 1-6. 2. Liss, V., 1988, “Preventing Corrosion Under Insulation,” National Board BULLETIN, The National Board of Boiler and Pressure Vessel Inspectors. 3. Patel, R., 2005, “Digital Applications of Radiography,” Proc. of 3rd MENDT, Manama, Barain, pp. 210-215. 4. Black, J.T., Kohser, R, 2011, Materials and Processes in Manufacturing, 11th Edition, John Wiley & Sons. 5. Robers, M., Scottini, R., 2002, "Pulsed Eddy Current in Corrosion Detection," NDT.net Issue 2002-10. Inspectioneering.com | Page 8 fl fi fl fi A Primer on Corrosion Under Insulation PERFORMANCE. PROVEN. For over two decades, Aspen Aerogels has produced high-quality insulation to help you deliver the job right. When your reputation matters, trust the experts. Trust Aspen Aerogels. A Primer on Corrosion Under Insulation Inspectioneering.com | Page 9 Visit aerogel.com or contact us at info@aerogel.com