b a gas to liquid. liquid to gas at a precise temperature liquid to solid . ethanol -182 -117 -164 b a What effect does the presence of an impurity have on t_he freezing point of a liquid? Which two substances are liquids at room temperature? Explain your answer.~) All three substances have negative values for their melting point. Which of them has the lowest melting point? 357 c What do you understand by the word volatile when used in chemistry? fJI...~ Jo~,. -U-W a Put these three liquids in order of volatility, with the most volatile first: water (b.p. 10~ °C), ethanoic acid (b.p. 128 °C) and ethanol (b.p. 78 °C). mercury -30 I Table 1.3: Melting and boiling points of ethanol, methane and mercury. methane iSubstancc; The melting and boiling points of three pure substances are given In Table 1.3. c State the names for the following physical changes: Questions 1 2 3 b 1.~~ ?)~ 3)~ou1 f 0 -1 5 5 10 5 15 7 20 25 13 28 30 45 35 40 62 76 45 79 so 55 82 60 82 1 A sample of a solid substance, which had been cooled to -5 °c, was put Into a test-tube. The test-tube was then heated In a water bath. The temperature of the substance was taken every -5 5 minutes for an hour. The results obtained are shown below. Time/min Temperature/°C • . ' •. I• t· l I • ' I 'T ' 1 I (). ' ; • r:; ++ ~- •• t t l l I •· l I .,, Ii I . I I I • l I I . I • I r I JI 1 r -• I . • L+ • - ~., ' 1 . , • ;-L... 1 --t- - I. I -f ·-r--- T :1 - - i.i-1 I l ! ,- ' tP ti T -l -, '. 1 ! 1 LL :i~ 'T 'J 1 :J ·r;f ' .• j ' 1 . - f i I t l' • ' I -1 ! ,. 1 ... ,f , ,, - ,....11 J'r· . __;_j • _;__ - .. l •, 'I .I : )· 1 ' . r, , II '-t • • f -- 7 L J I ·I• 1•, l 1 r-. · ,·- , .1 1I 1 ,f ,-t1 t , '• '1 '. ·,· -·--·. 1 1; l;l; Tf1 'tr~ ij' . I . . . . i . • -! ,;f. i •.; ·"~ J ti. '-0 1 -;- _1 {4} a Plot the results on the graph paper below, putting time on the horizontal axis and temperature on the vertical axis. -~ ,~.,,- ...,J 0 -,o 7 T5 60 ½5' 3o [5, ... 7> ~··· r ·r:f't-· 1)f •:: <r· rc: <-T )·f 1>, c:_,"•,r •(i:, -is= .j_, {1] ') ::5 .. [1} b What Is the melting point of the substance? ...... c What Is the boiling point of the substance? .....:!:.S'.~..... d Describe what Is happening to the particles of ~he substance after SO minutes.~ ~.