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Lecture 3

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Lecture 3
Structure of Metals
Unit Cells
• Solid materials may be classified according to the regularity with
which atoms or ions are arranged with respect to one another. A
crystalline material is one in which the
• Atoms are situated in a repeating or periodic array over large atomic
distances.
• Crystal structures are specified in terms of parallelepiped unit cells,
which are characterized by geometry and atom positions within
Unit Cell Definition
• The atomic order in crystalline solids indicates that small groups of
atoms form a repetitive pattern.
• Unit cells for most crystal structures are parallelepipeds or prisms
having three sets of parallel faces
Type of Unit Cells – Face centred Cubic
• The crystal structure found for many metals has a unit cell of cubic
geometry, with atoms located at each of the corners and the centers
of all the cube faces. It is called face-centered cubic (FCC) crystal
structure
Face centred cubic
Body Centred Cubic
Hexagonal Close Packed crystal structure
Different calculations associated with crystal
structures
1. The number of unit atoms per unit celss
Atomic Packing factor
Coordination number
• For metals, each atom has the same number
• of nearest neighbor or touching atoms, which is the coordination
number.
Example
Example 2
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