5.3 and 5.4 – Salts (Grade 8) 1. Different uses of salts Preserve food, table salt – to add flavors Gymnasts use to keep their hands dry so that they do not slip on the apparatus Calcium sulfate Make blackboard chalk Aluminium sulfate Added to dyes to help them stick to fibers Copper sulfate Soya seeds are coated with it. It stops fungi growing on the seeds when they are planted Ammonium nitrate Used as fertilizer to help crops to grow well 2. All acids contain hydrogen 3. Name three COMMON acids that are found in the labs Ans – Hydrochloric acid (HCl), Sulfuric acid (H2SO4) and Nitric acid (HNO3) 4. Name the other WEAK acids found in the lab Ans – Carbonic acid (formed when carbon dioxide reacts with water) Citric acid (found in fruits such as oranges and lemons). 5. Name of acid Salts formed from the acid Example of salt Hydrochloric acid Chlorides Sodium chloride (NaCl) Sulfuric acid Sulfates Copper sulfate (CuSO4) Nitric acid Nitrates Potassium nitrate (KNO3) Carbonic acid Carbonates Sodium Bicarbonate (Baking Soda) Citric acid Citrates Sodium citrate 6. Reactions: Sodium Bicarbonate (Baking Soda): Carbonic acid + Sodium hydroxide → Sodium bicarbonate + Water H2CO3 + NaOH → NaHCO3 + H2O Calcium Carbonate: Carbonic acid + Calcium hydroxide → Calcium carbonate + Water H2CO3 + Ca(OH)2→CaCO3 + 2H2O Sodium chloride Magnesium carbonate Sodium Citrate: Citric acid + Sodium hydroxide → Sodium citrate + Water C6H8O7 + 3NaOH → Na3C6H5O7 + 3H2O Calcium Citrate: Citric acid + Calcium hydroxide → Calcium citrate + Water C6H8O7 +3Ca(OH)2 → Ca3(C6H5O7)2 + 6H2O 7. What are the properties of acids? Ans - Turning litmus red, turning universal indicator solution yellow or red, having a pH of less than 7, tasting sour and that strong acids are corrosive 8. Name some everyday products that contain acids Ans - vinegar, fruit juices, lemonade, fizzy drinks, citrus fruits, tomato and other savory sauces, pickled vegetables. 9. Which elements are present in nitric acid? Ans - hydrogen, nitrogen and oxygen 10. Which elements are present in the sulfuric acid? How many atoms of each element make up one particle of sulfuric acid? Ans - Hydrogen, sulfur and oxygen; two atoms of hydrogen, one atom of sulfur and four atoms of oxygen 1 11. What is similar about the formula for hydrochloric acid and the formula for sodium chloride? Ans - Both formulae contain chlorine, Cl. 12. What is different about the two formulas? Ans - The hydrochloric acid contains hydrogen, H, but the sodium chloride contains sodium, Na 13. Which ingredient is a salt? 2 Ans - sodium citrate 14. Do some researches to find out why this ingredient is added to some kinds of food? Ans - Adding sodium citrate to foods such as orange jam helps to maintain its tangy taste and reduces the risk of the product decaying. 15. Different techniques of making salts Reactants Using Metal + Acid Products Salt + Hydrogen Using Metal oxide + Acid Salt + Water Using Metal carbonates + Acids Salt + Water + Carbon dioxide By Neutralisation Acid + Base Salt + Water 16. Examples of the above Metal + Acid → Salt + Hydrogen Zinc + hydrochloric acid → zinc chloride + hydrogen Zn + 2HCl → ZnCl2 + H2 1. What is crystallization? Ans - Crystallization is defined as a process by which a chemical is converted from a liquid solution into a solid crystalline state. 2. Write the word equation for this reaction? zinc + sulfuric acid → zinc sulfate + hydrogen 3. What are the important practical points you need to consider when you evaporate this solution? Ans - The solution may spit when heated, which could cause burns. 4. Which do you think is the better way to produce larger crystals – heating the evaporating dish until there is very little liquid left or leaving it to evaporate slowly? Ans - Larger crystals will be produced when the liquid is left to evaporate slowly, so that is the better way. 5. How could you investigate which is the best way to produce large crystals? Ans – Using the same mass and volume of zinc and acid for two reactions; using two identical evaporating basins; heating one evaporating basin with a Bunsen burner as in the experiment in the Learner’s Book, leaving the other evaporating basin so that the water evaporates very slowly, and then comparing the size of the crystals. Metal oxide + Acid → Salt + Water Copper oxide + sulfuric acid → Copper sulfate + water CuO + H2SO4 → CuSO4 + H2O 1. Make a list of the equipment you will need. Ans - Safety glasses, 250 cm3 beaker, glass stirring rod, copper oxide powder, dilute sulfuric acid, measuring cylinder, filter funnel, filter paper, conical flask, evaporating basin, tripod, gauze, pipeclay triangle, heatproof mat, Bunsen burner, tongs 2. Write a risk assessment for each stage of the process. Ans - The risk assessment should feature each process, for example: Step 1: Measuring acid and adding copper oxide: risk of getting acid in your eye, so wear safety glasses. Step 2: Heating the copper oxide and sulfuric acid: general risks of heating and not touching hot items, wearing eye protection when using acids, not boiling the mixture as harmful fumes can be given off. Learners should mention both the risks and how they can attempt to overcome them. Step 3: Allowing the mixture to cool: general risks of heating and not touching hot items, wearing eye protection when using acids. Step 4: Filtering: risk of splashes of the solution getting into the eyes, so wear safety glasses. Step 5: Evaporating: risk of solution spitting and general risk of heating and not touching hot items, using tongs to move the evaporating basin, wearing safety glasses, taking care about how close you get to the apparatus. 3. Suggest why the mixture was filtered Ans - To remove any unreacted copper oxide powder 4. Suggest how you could use a similar method to make copper chloride. Ans - Use hydrochloric acid instead of sulfuric acid. 5. Write the word equation for the reaction to make copper chloride from copper oxide Ans - Copper oxide + hydrochloric acid → copper chloride + water 6. Write the word equation for the reaction between copper oxide and nitric acid Ans - Copper oxide + nitric acid → copper nitrate + water 3 Metal carbonates + Acids → Salt + Water + Carbon dioxide Calcium carbonate + sulfuric acid → Calcium sulfate + Water + Carbon dioxide CaCO3 + H2SO4 → CaSO4 + H2O + CO2 Calcium carbonate + hydrochloric acid → calcium chloride + water + carbon dioxide CaCO3 + HCl → CaCl2 + H2O + CO2 The rock LIMESTONE is made from calcium carbonate. It is damaged when it reacts with acid rain and erodes (wears away). The skeletons of coral are made from calcium carbonate and react with acids. This happens when the oceans become slightly more acidic as more carbon dioxide dissolves in water 1. Read through the method and make a list of all the equipment you will need Ans - This will vary depending on what equipment you have available but is likely to include safety glasses, copper carbonate, hydrochloric acid, measuring cylinder, beaker, spatula, filter funnel, filter paper, conical flask, evaporating basin, tripod, pipeclay triangle, Bunsen burner, heatproof mat, tongs. 2. Carry out a risk assessment for each step of the method Ans - The risk assessment should feature each process, for example: Step 1: Measuring acid: risk of getting acid in your eye, so protect yourself by wearing safety glasses. Step 2: Adding the copper carbonate to the hydrochloric acid: wear eye protection when using acids. The risk assessment should feature each process and learners should mention the risks and also how they can attempt to overcome them. Step 3: Adding excess copper carbonate: wear eye protection when using acids. Step 4: Filtering: risk of splashes getting into the eyes, protection by wearing safety glasses. Step 5: Evaporating: risk of solution spitting and general risk of heating and not touching hot items, using tongs to move the evaporating basin, wearing eye protection, taking care about how close you get to the apparatus. Steps 6 and 7: low risk 3. What did you observe when you added copper carbonate to the hydrochloric acid? Ans - The most obvious will be bubbling as a gas is given off. 4. Which gas is given off during this reaction? Ans - carbon dioxide 5. Write the word equation for your reaction 4 Copper carbonate + hydrochloric acid → copper chloride + water + carbon dioxide 6. Describe the appearance of the copper chloride you have made Ans - Any description should include colour (pale green) and the nature of copper chloride (crystals/powder). 7. Which substances in your word equation are salts Ans - copper carbonate and copper chloride 8. Using your observations from this experiment, what can you say about the solubility of copper carbonate and copper chloride in hydrochloric acid? Ans - Copper carbonate is not soluble as it is left behind in the filter paper. Copper chloride is soluble as it passes through the filter paper as a solution 9. Suggest how you could use copper carbonate to make copper sulfate Ans - To make copper sulfate from copper carbonate, the experiment could be repeated but this time using sulfuric acid instead of hydrochloric acid. Acid + Base → Salt + Water Sodium hydroxide + hydrochloric acid → sodium chloride + water NaOH + HCl → NaCl + H2O 1. Carry out a risk assessment for each step of the method Step 1: Filling burette with acid: risk of getting acid in your eye, so protect yourself by wearing safety glasses; risk of spilling acid, so use a small funnel and place burette at a level lower than the bench to fill it; general risk of breaking glassware. Step 2: Measuring sodium hydroxide: risk of splashing it in eyes, so wear safety glasses. Step 3: Low risk Step 4: Swirling acid around: risk of spilling acid so take care, wear safety glasses. Step 5 and 6: Low risk Step 7: Filtering: risk of splashes of the mixture getting into the eyes, protection by wearing safety glasses. Step 8: Evaporating: risk of solution spitting and general risk of heating and not touching hot items; using tongs to move the evaporating basin; wearing safety glasses, taking care about how close you get to the apparatus. Steps 9 and 10: low risk 5 6 2. What colour is the universal indicator solution in sodium hydroxide? Ans - blue 3. What colour is the universal indicator in a neutral solution? Ans - green 4. Why do you need to swirl the flask as you add the acid? Ans - So that they mix together and react before you add more acid. 5. Imagine that you accidently add too much acid from the burette. What could you do to form a neutral solution? Ans - You could add a little more alkali until the universal indicator solution turns green. 6. What salt is formed in this reaction? Ans – sodium chloride 7. Write the word equation for this reaction Ans – sodium hydroxide + hydrochloric acid → sodium chloride + water + carbon dioxide 8. Describe the salt crystals you obtained Ans - The description should include the colour (white) and the shape of the crystals obtained (cubic). 17. Which of the above compounds in Zn + 2HCl → ZnCl2 + H2 is a salt? Ans – Zinc chloride 18. Which acid would you add to the metal magnesium to make the salt magnesium sulfate? Ans – Sulfuric acid 19. Write the word equation for the reaction between iron and hydrochloric acid Iron + hydrochloric acid → iron chloride + hydrogen 20. Why would it be dangerous to prepare sodium chloride by reacting sodium with hydrochloric acid? Ans - Sodium is very reactive and the reaction would be explosive. 21. Write the word equation for the reaction between magnesium carbonate and nitric acid Ans – Magnesium carbonate + nitric acid → Magnesium nitrate + water + carbon dioxide 22. Write the symbol equation for the reaction between magnesium carbonate and sulfuric acid Ans – MgCO3 + H2SO4 → MgSO4 + H2O + CO2 23. How could you check that the gas given off in these reactions is carbon dioxide Ans - By bubbling the gas through limewater, which will go cloudy if the gas is carbon dioxide. 24. The blue green colours in these rocks in the Atacama Desert in Chile tell you that they contain copper salts This bright blue-green mineral in the tock is called malachite. It is made from copper carbonate 25. How can you test to see if a liquid is an acid or an alkali? Ans - You could add an indicator such as universal indicator solution. If the test solution is an acid, universal indicator solution will turn yellow or red. If the solution is an alkali, universal indicator solution will turn blue or purple 26. What word is used to describe a solution that is neither acid nor alkali? Ans - A neutral solution’ 27. What are the properties of alkalis? Ans - properties, such as soapy feel, turns litmus blue, turns universal indicator solution blue or purple, has a pH greater than 7. 28. What is the difference between a base and an alkali? Ans - A base is a metal oxide. Metal oxides are called BASES SOLUBLE METAL BASES form alkalis when they dissolve in water If a metal oxide dissolves in water, it makes and alkaline solution. Example – Sodium oxide + water → sodium hydroxide Sodium oxide is a BASE and sodium hydroxide is an ALKALI 29. Are all metal oxides soluble in water? Ans - Some metal oxides are not soluble in water. Eg. Iron and copper oxide are not soluble. They do not form alkalis. They react with acids to form salts. 30. Write the word equation for the reaction between magnesium oxide and sulfuric acid? Ans – magnesium oxide + sulfuric acid → magnesium sulfate + water 31. Write the symbol equation for the reaction between magnesium oxide and sulfuric acid Ans – MgO + H2SO4 → MgSO4 + H2O 32. Suggest how you could use iron oxide to make iron chloride? Ans - Iron oxide could be reacted with hydrochloric acid to form iron chloride. ROADMAPS How to Determine whether a salt is soluble or insoluble in water? 7 In order to make life easier, chemists have divided salts into three types Soluble Salts Insoluble Salts Potassium, Sodium and Ammonium salts 8 1. What is the name of the indicator that is used to measure the pH of an acid or an alkali? Ans – Universal indicator 2. How do metals react with acids? Ans – They produce hydrogen and the metal salt 3. What is a 'pure' substance? Ans – A substance which is made from the atoms of one element, or the molecules of just one compound. In other words, pure substances are substances that contain only on type of particle. 4. What is evaporation Ans – The process in which liquid turns into a gas water vapour( without boiling) 5. Calcium chloride is a salt that forms white crystals. It is used to absorb moisture from the air and is known as a drying agent. 6. What is a carbonate? The word 'carbonate' means that the chemical compound contains and oxygen linked together. 7. How to make crystals? Ans – Step 1 - One way of making crystals in the preparation of salts is to start with a concentrated solution of a substance. Step 2 - When the concentrated solution is gently heated in an evaporating dish, the solvent begins to evaporate. This causes the solution to become even more concentrated. Step 3 - If the heat is removed and the concentrated solution is left to cool, evaporation will continue even when it reaches the temperature in the laboratory. In time, all the solvent will evaporate and pure crystals of the substance will be left behind Step 4 - The pure salt crystals can then be dried by patting them gently and carefully with a paper towel. 8. What is a saturated solution? Ans - A highly concentrated solution is called a saturated solution. It is a solution that is so packed with a solute that no more will dissolve in it 9. Preparing a salt from a metal and an acid Preparation of zinc chloride Ans: 1. Small fragments of zinc are added to hydrochloric acid in a flask. 2. Bubbles of gas rise from the metal, pass through the liquid and escape into the air. 3. Eventually, the bubbles are no longer produced and some metal remains in the flask. 4. The contents of the flask are then poured onto filter paper in a filter funnel 5. The zinc metal remains behind and the liquid passes through and falls into a beaker. 6. The liquid is then poured into an evaporating dish and heated gently until some solid appears 7. The mixture is then left to cool, and more evaporation takes place until only the crystals are left behind 10. Why do you think that granulated zinc is used instead of a block? Ans – It has a larger surface area and therefore reacts more rapidly. 11. What passed through the filter paper when the flask was emptied? Ans – A solution on zinc chloride. 12. Why was the solution heated before it was left in an evaporating dish? Ans – To speed up the process of removing the water by evaporation. 13. Write the word equation for this reaction. Ans – Zinc + hydrochloric acid → zinc chloride + hydrogen 14. Here is the symbol equation for a reaction: Zn + 2HCl→ ZnCl2 + H₂ What does this equation tell you about the reaction? Ans – It tells us that when zinc reacts with hydrochloric acid, zinc chloride and hydrogen are produced. 15. Zinc sulfate can be prepared in a similar way. Write a word equation for the reaction. Ans – Zinc + sulfuric acid → zinc sulfate + hydrogen 16. Here is the symbol equation for a reaction: Zn + H₂SO₄ → ZnSO4 + H2 What does this equation tell you about the reaction? Ans – When zinc and sulfuric acid are brought together, zinc sulfate and hydrogen are produced. 17. Write the word equations for the reactions between the following metals a. magnesium and sulfuric acid Ans – magnesium + sulfuric acid → magnesium sulfate + hydrogen b. iron and nitric acid Ans – iron + nitric acid → iron nitrate + hydrogen c. calcium and hydrochloric acid Ans – calcium + hydrochloric acid → calcium chloride + hydrogen d. lead and sulfuric acid Ans – lead + sulfuric acid → lead sulfate + hydrogen e. aluminium and hydrochloric acid Ans – aluminium + hydrochloric acid → aluminium chloride + hydrogen f. tin and nitric acid Ans – tin + nitric acid → tin nitrate + hydrogen 18. Preparing a salt from a metal carbonate and an acid Preparation of calcium chloride Ans. 1. The carbonate used in this reaction is calcium carbonate in the form of marble chips. 2. Some marble chips are added to hydrochloric acid in a flask. 3. Bubbles are produced and the chips dissolve. 4. Some more chips are added, and more bubbles are produced and then the reaction stops and some of the chips are left in the solution. 5. Then the contents of the flask are poured onto a filter paper in a filter funnel and the solution and chips are separated 6. The liquid is poured into an evaporating dish and heated until some solid appears. 7. The mixture is then left to cool, and more evaporation takes place. 8. When the mixture has been left to cool, it is filtered again. 19. Why did all the chips added at first dissolve? Ans – There was an excess of acid to take part in the reaction with the calcium carbonate (marble) chips. 20. Why did some of the chips added later not dissolve? Ans – All the acid had been used up so there was none left to react with the excess of marble chips 21. Why were the contents of the flask filtered? Ans – To remove the solid from the liquid 22. Write the word equation for the reaction. Ans – Calcium carbonate + hydrochloric acid → calcium chloride + carbon dioxide + water 23. A. Write the word equations for the reactions between the following metal carbonates and acids: i. zinc carbonate and sulfuric acid Ans – zinc carbonate + sulfuric acid → zinc sulfate + carbon dioxide + water ii. aluminium carbonate and hydrochloric acid Ans – aluminium carbonate + hydrochloric acid → aluminium chloride + carbon dioxide + water iii. magnesium carbonate and nitric acid Ans – Magnesium carbonate + nitric acid → magnesium nitrate + carbon dioxide + water iv. copper carbonate and sulfuric acid Ans – Copper carbonate + sulfuric acid → copper sulfate + carbon dioxide + water v. calcium carbonate and nitric acid Ans – Calcium carbonate + nitric acid → calcium nitrate + carbon dioxide + water vi. lead carbonate and hydrochloric acid Ans – Lead carbonate + hydrochloric acid → lead chloride + carbon dioxide + water B. Here are three symbol equations for the reactions above. Match them with their word equations. i. Al2(CO3)3 + 6HCI → 2AICI3 + 3CO₂ + 3H2O Ans - ii ii. CaCO3 + 2HNO3 → Ca(NO3)2 + CO2 + H2O Ans - v iii. ZnCO3 + H₂SO₄ → ZnSO4 + CO2 + H2O Ans - i 24. What is produced when you set up a reaction between a metal and an acid? Ans – The metal salt and hydrogen 25. What is produced when you set up a reaction between a metal carbonate and an acid? Ans – The metal salt, carbon dioxide and water 26. How would you filter a mixture of a solid and a liquid? Ans - Fold a piece of filter paper to make a cone, and insert it into a filter funnel. Support the funnel above a collecting vessel, and pour the mixture of solid and liquid into the paper cone. 27. Name two uses of calcium chloride. Ans - It is used as a drying agent, in food processing and seasoning, in medicine and in speeding up the setting of concrete. 28. Name four uses of zinc sulfate. Ans - Cosmetics, some deodorants, making rayon fibres from cellulose, making glue, bleaching paper, in making herbicides and sewage treatment, in chemical investigations. 29. Describe a crystal in one sentence. Ans - A solid structure with flat sides. 30. You have a concentrated solution of copper sulfate. Describe the cystalisation process you would use to make copper sulfate crystals. Ans - The solution is placed in an evaporating dish and gently heated. The heat is then removed and the solution is left in the laboratory, where it continues to lose water through the process of evaporation and the crystals form. 31. Name all the equipment you would use to prepare a salt from an acid and a metal. Ans - A spatula, conical flask, support (clamp and stand), filter funnel with filter paper in it, beaker, evaporating dish, gauze, tripod, Bunsen burner, heat-proof mat used in the laboratory. 1 Link the name of the acid with its formula, and with the name of the salt it produces. Draw lines to link the boxes. Use a ruler. Acid Formula Salt hydrochloric acid HNO, sulfates sulfuric acid HCI nitrates nitric acid H,SO, chlorides 2 The following compounds are all salts of sodium. For each one, state which acid is used to make th¹ salt. Sodium chloride Hydroch lonic,aad Sodium nitrate Sodium sulfate 3 Cnitric.acid .... SulfurnC..accd Write the name of the salt next to its formula. NaCI Sodium.chlortde. Cuso,.Opper. sWtte. Cucl, ..eppex..chloride KNOJ..btassium.nitrate 4 Citric acid is found in fruit. What are salts of this acid called? CiMates. 7.2Preparing copper chloride This exercise relates to 7.3 Metal carbonates and acids from the Coursebook. In this exercise, you explain the steps in the formation of a salt. You also consider safety precautions needed when preparing a salt. Sam and Elsa are preparing the salt copper chloride. Sam pours some hydrochloric acid into a beake. Then Elsa adds some copper carbonate. copper carbonate hydrochloric acid 1 What happens when Elsaadds theitgnate copper to the acid? with Elsa adds more and more copper carbonate until there is no more reaction. There is some unreacted copper carbonate left in the beaker. Sam filters the mixture. filtrate 2 What is left in the filter paper? ..Cunreaed) coppec..canbonate 3 The filtrate passes through the filter paper into the flask. What is this liquid? A.souton..f..LaRpea..chlarde..a..miatuaa".of..ate..md..cepper chlornd) 4 Next, Sam and El_a want to produce crystals of the salt. What must they do? Elace.he.haiA..an.. cdesh. bad in...and.hed.it.to.exeporate Cfhe.Qtend.easz.theCncfals. 5 Why must they be very careful when they carry out this step? hihen.he.. 6 Can.. What should they do to reduce the hazard? Weam.sa4daea..preemamage.1ake..specua.cane ohennea. exoporahag.shm...off.tha.heathen.aptn..bein.to..spit. then.leare Uthe. .alatea..to.Naporate..inhe..... 7 Write the word equation for this reaction. cpper hydchloric Coppor Carbon dioxide wter Chlonde aud 7.3Preparing potassium chloride Carbonat This exercise relates to 7.4 Forming salts by neutralisation from the Coursebook. In this exercise, youdescribe the steps needed in some practical work to produce a salt from an acid and an alkali. Anna and Jon want to prepare the salt potassium chloride, using potassium hydroxide and hydrochloric acid. 1 hydrochloric universal potassium acid indicator hydroxide For the first step in this process, Jon and Anna put 20 cm of potassium hydroxide in a beaker. They use the acid to neutralise it. List the equipment that they need for this first step. ..Measwingcfldes,beakex,bunelte niresat tndicatOI ADA hydchloncacid SaltyAtaeI stand Describe the method for carrying out this step. Include safety precautions. Et..on..safy.glaasca.Eist..add.adop.of .lactte..md.. How olutien wlach t4.e:Sel.uphe 4.,urdh.acid. ..mix the potasium.hy.mxide....ancl..s.. 3 wniverSa indi Cator willJon and Anna know when the potassium hydroxide is neutrlised? .MniNexIC.inciCator.olutuûn..hu..om. blue to qreen When the potassium hydroxide is neutralised, Anna and Jon have a coloured solution. HÍw do they remove the colout, so that the, crystals of potassium chloride they prepare are pure? the coour. Ad..chaxcpaln..nesra.splutpnaka..M. 4 . L . ADkutiQn.dhpcld..be..teASA...e.mDS.h...pieceo. 5 Write the word equation for the neutralisation reaction. Potasium. hydrchloric potayium chlonce aud hydroide oater Rememnber The general equation for a neutralisation reaction is acid + alkali 6 ’ salt + water that "0uton, fametal pxlde in uoate LAntaun. hydroxialpaahdea.ia.he.oppota..of..an aud. is an alkali? Youmay need to look up the meaning in the Coursebook. 7 Potassium hydroxide is an alkali. Giye an example of another alkali. Sodiu.m...hydaxicd. What is abase? 9 ..Metal.oxide Potassium oxide is a base. Give an example of another base. Lopper..Dxide 8.1 Investigating the reaction of calcium carbonate with an acid This exercise relates to 8.1 Measuring the rate of reaction from the Coursebook. Inthis exercise, youplot a graph of the volume of product obtained against time and interpret this. Anna and Nor investigate the reaction of calcium carbonate with sulfuric acid. They use the apparatus shown here to measure the total volume of gas given off every 20 seconds. acid measuring cylinder gas water conical flask sulfuric acid 1 lumps of calcium carbonate What is the name of the gas given off, in the reaction? Carbom...iDXIde Here are the girls' results. Time / seconds Total volume of gas produced / cm² 20 200 40 350 60 450 80 520 100 560 120 580 140 580 160 580 2 Plot agraph of these results. Time goes on the x-axis. Volume goes on the yaxis. Remember Use most of the graph grid. Check your scales carefully. produced/c gos of400 volume 500 3004 Total (00 3 Nime fsecond lto As.e..greAel.Mo... uaents no.maregs aren af Describe what the graph shows. ihe..sIcepe,.tinae.faotta. Suggest why no gas is given off after 120 seconds. -Athe..calcium..catbontp. Can..be. pocuced has untll 20 seonde akea comment.about reacted o..no. moxCanbon 7.1 Investigating concentration This challenge task relates to 7.4 Forming salts by neutralisation from the Coursebook. In this challenge task, you will discuss variables in an investigation and make some conclusions from experimental results. Elsa was asked to investigate this question: Is therea link between the concentration of acidand the volume of it needed to neutralise 50 cm of alkali? She made up five samples of acid with different concentrations, 100 cm of each. The first sample was from the laboratory bottle of acid. The second sample was made by adding 50 cm of acid to 50 cm water. Each subsequent sample of acid was half the concentration of the previous one. burette acid For each sample, Elsa put the acid in a burette and gradually added it to the alkali, until a neutral solution was formed. alkali 1 How could Elsa determine the pH of the solution, and what would _he observe as it became neutral? lSa.GeA.CQuld.lAl..ùvaa..ndi,sato..sLAldion.hi.would..he.bue..calr un..caSalne. aAtiAm....amd.AQLAld.he.9xeem..cOlOrhenneutralsed 2 Which variables should Elsa have controlled to make this a fair test? State at least three. the Same.ype,..of..acid..Same.ype.aQnd.conceghatuon...o4UkaiL. alkali ..CAAMe...MLMe.0f 3 Samme...e.A...Jnix.Áal..I0dsato Here are the results of Elsa's investigation. Acid sample Volume of laboratory acid used to make up 100 cm|Volume of acid sample needed to neutralise alkali / cm3 diluted sample / cm 100 21 50 25 25 34 D 12.5 51 E 6.25 100 B auslcn Sample A is the most concentrated and sample E is the least concentrated. neutalhe to tuoed Sot aid40t of B0 20 Volume 30 40 S0 60 ?0 30 90 00 Velume of lab oúd wmd to mate gcmpt /cm 4 Describe the graph. Jhe cmalleot oume ...alA.. 5 What conclusion can you make from thes results? Iha...atc.ta..Dncenhaa.Of.qs AAds.ttae.Small..ot. JAume..e MceacaalieealgiAchcng.i.nanfraton, -a..LA.AnCAnAtien.ha..MAs... .Qn..h R..af.t..ncedcd. 6 Elsa's results were for 50 cm3 of alkali. Nor did the same investigation but made a mistake. She used 60 cm? of alkali. How would Nor's results be affected? Ih...eaulta..lel.be..csAxcat...a.ralen.yoME. ol a d wold be .ne.edea.0..neutYadiSCtiQn..a..e.4c...NGAntaan..buIha..patten. he..alutnG..faced..nGed.ed..4,lae..n.LcA.ntratuon..a.chamged...eud.. -be.naLtahed.graph.CAnMe.A.b...gh,ca,p.. oume 4nddescribe COnienhtcoM the safety State the dangers should be taken. aud needed to .LonceAtas.CAsaA...nAe. asive.a.g .... .shoa..he..ak.e.a.. k . e x . a . q . b A e t t D . . p s . .a.&pil..a.f....d..Ahald.d .cuted..a..cdahg..2AA....hetore. ........ -.Cattmp.Aag....acaa..t..up. neutalise it 7.2 Salts, alkalis and equations This challenge task relates to 7.1 What is a salt?, 7.2 Preparing a salt using metal and acid, 7.3 Metal carbonates and acids and 7.4 Forming salts by neutralisation from the Coursebook. In this challenge task, you will use your knowledge to name salts, a base and an alkali. You will also correct some formulae and write word equations. 1 Name a salt formed from the following: a b hydrochloric acidS.ca'Am..chlorde citric acid Sadium..cihate. zinc and nitric acidncoate. d 2 copper and sulfuric acid -.capp.eA.ale. These formulae are incorrect. HSO, HCI, HNO teso4 Write them correctly. lodium.oxicde. Sodium..hyduxide. 5 Explain how alklis and bases are related, Give an example of a base. 3 4 Give an example of an alkali. QXide...A.... -onIKLiomtMetal..ox\ceA..NA...Q2.LLE form .Dn.. 6 Write a wordequation for the reaction between sulfuric acid and the alkali that contains sodium. Sol um 7 hydrox ide t Sufwic aud sodium sufete t o t r Write aword equation for the reaction to prepare the salt copper chloride from copper carbonate. Cypor Carbonate t hydchlore Qcid (arbon copper t water +dioxide Chlonde b produced. were B, no bubbles B milky. became limewater, through passed was gas this When produced. were it of A, gas bubbles containing limewater becoming milky A test three of tubes. test different tests. tube. some of to in liquid each did each one and reactions differentsample a Forming task salt?, given some to identify of C is a 7.3 Metal acid, and metal using salt a an carbonates substances. powder. ground-up form the C, use from 7.2 the each the informationPreparing in Coursebook. and A, you B wil 7.1 by neutralisation What task, A substances, different In relates this salts challenge to three 7.4 and had placed acids This 7.3 substances Mystery Jon containing observedthe They They a Theyadded challenge and tubethe In Nor In tube the pop In the tube containing C, bubbles of gas were produced. When the students collected this gas and tested it with a lighted splint, there was asqueaky pop. After the substances had finished reacting, the students heated the three solutions (after filtering if necessary). They evaporated them to dryness to form three crystalline substances: substance A produced zinc sulfate substance B produced iron chloride substance C produced magnesium chloride. 1 Which gas did substance Aproduce?...COLbon..dioxle 2 Which gas did substarnce C produce? .... ydrogen. 3 What general name is given tothe crystalline substances produced in this way, after evaporation? 4 Suggest which liquid wasadded to tube A. 5 Suggest which liquid was added to tube B. Appea..Chlonale. 6 Suggest which liquid was added to tube C. ....... 7 Suggest what substance A could h¡ve been. dal...AraQnate. 8 Suggest what substance B could have been. 9 Suggest what substance C could have been. 10 Write a word equation for the reaction involving substance A. ane canbonate t Sulfumiccacid ’ zincsutfate + Carbon diordu + water belowion ’ ion chloide t teatea copper.y 12 Write aword equation for the reaction involving substance C. 11 Write a word equation for the reaction involving substance B. iron t Copper chloide magneium + hydrochonc 0cid-magnesm ch londe t hyd ngen Preparing commonsalts Salts 1 Identify two uses of calcium chloride. Tick () two boxes. herbicides setting concrete bleaching paper drying agents 2 Identify two uses of zinc sulfate. Tick (/) making coSmetics two boxes. sewage treatment food processing Acids and their salts 3 Name the salt produced by each acid. hydrochloric acid..Chlonde Sulfate sulfuric acid.. nitric acid.. nitnate 4 Write the word equations for the following reactions: a magnesium and nitric acid MMaAnesium.t.nibis..aamgneium nihau t t b lead and hydrochloric acid Lead + hydnchlonc acd ’ lead chlonda hyadrgcn hadnagn c aluminium and sulfuric acid .aumánium.t Sultunc a ud 46 lumindm sultate + ydgen 10Preparing common salts 5 a Howdothefibres in afilter paper help in the process of filtration? rom meh, ike a sieve he liquid can pass Hysoughte mal..halea. lyetiwen thu hbnu but Hht bru prevent the solide from peming paaing Tuat thiough filtrate? b What is the c What is the residue? 6 Describe what happens in the process known as evaporation. Alhe. ate.has..NapenCted. 7a What is a crystal? Aclid.autink.t..a..ide. b How would you make crystals of a substance? SSolve dheAbatance....to...mak...a. cencentated Altien.Placa..aA.. Naporating.casl.. -ppy.A..heat..sQAICA..A20M M....u.Cbut not boi) thn leave to cool and let all the behnd tale crys leare to water evaporate . 47 CHEMISTRY Preparing a salt from a metal and 8 a Label the diagram for the anc an acid preparation of zinc chloride below. nleson a spoon or spatula conicoal hydrochloric auid i the fask 4ns..grandes ià hydch one aed they are in the wrona b These are the stages involved in the preparation of zinc chloride, but they occur. order. Arrange them correctly by numbering them in the order in which 3 ina filter funnel. A The flask contents are poured through a filter paper B The reactants are mixed together in a conical flask. C Metal remains on the filter paper and liquid passes through into a beaker. D Bubbles are formed and pass through the acid. c By what process is the final product obtained? Evaparatien. Preparing asalt from a metalcarbonate and an acid 9 a These are the stages in the preparation of a salt from a metal carbonate, but they are in the wrong order. Arrange them correctly by numbering them inthe order inwhich they occur. 3 A Look for the end of bubbling in the mixture. B Add the solid to the acid. C Leave the heated solidto cool. D Heat the liquid in a heat-proof container until a solid appears. 6 E Pour the acid into a container. FTransfer the separated liquid to a heat-proof G Separate the solid from the liquid. 48 container. 5 10 Preparing common salts What processissperformed at the end toremove any remaining liquid? The.solid.de.) -patted.awith.a.papea..towel..to.rcmor...any nemaining water on the cystals:from copper carbonate and preparation of copper Writethe equation for the 40a hydrochloricacid. chloride Coppea.Anbenale.AAe.hydoch loris.. uid .SePer.chloride t .Carbon..dioxide. woter b Why do you need to add excess copper carbonate? To.make....Swe.. .tha..ad..has.Meated c Describe one safety precaution you would need 11 Hans is preparing copper sulfate using sulfuric sample of copper carbonate. with it to take if you carried out this reaction. acid. He has a sample of copper metal and a a Which sample should he use? He cam.us...eatae.Sample. b Explain your answer. Sultate 49 5Reactivity > 5.3 Salts Exercise 5.3A Which acid is used to make which saa Focus In this exercise, you willidentify which acid is used to produce a salt. Then you identify a salt from its formula. 1 Link the name of the acid with its formula, and with the name of the salt it produces. Draw lines to link the boxes. Use a ruler. 2 Acid Formula Salt hydrochloric acid HNO, sulfates sulfuric acid HCI nitrates nitric acid H,SO4 chlorides The following compounds are all salts of magnesium. For each one, state the acid that has been used to make the salt. magnesium chloride magnesium sulfate tydrochloie aid. Sufunis aud magnesium nitrate..mitric ad 3 Write the name of the salt next to its formula. NaCl...Sodium..chlonde. CuS0,..apPeA...Sulfate. CuCl,..opper..chlande. KNO,..Potassium..nitrate. 4 Citric acid is found in fruit. What are salts of this acid ..Citrates 94 called? 5.3 Salts Exercise 5.3B Making salts Practice salts are you will explain how some exercise, Inthis some wordequations. made and practise could makethe salt zinc nitrate using zinc metal. Explainhowyou nitic aud inocilute some...KinG..metal. Place 1 put yeur itt pten it has. atoppecd..Heacting. and heat an..evporang..asin. into.. uten. cryala prduu maiamd h.. to.ewaperut. ntly xinc nate 2 Write the word equation for this reaction. inGt.niie..aa..n...nitate.t hydrogen sulfate 3 Explain why you could not make silver by that method. KLvenu..mauch.des...Heactine.than xinc amd .Mill..net..Meaut..ith..dlue..uic acid 4 Explain why you could not make potassium sulfate by that method. fotaaiun..a..an..e... uactie.thane wold be.an..explogine,..eaution.tpotassium aid wene pldced metal n diute sutfwlc sulfuricacid J Copper sulfate is made by mixing copper oxide with and gently heating it. Why is it important that the acid mixture does not boil? b fum theaid ginn. bnl.be Write the word equation for the reaction. Coppe.axide t..sulfunic audcOPpes sutfali + water 95> 5Reactivity 6 Write the word equations for the following reactions: magnesium and nitric acid magneuium..mtia. b aud copper oxide and nitric acid magnciun.t..ydrogen. nitrate ic CApper.axide...t.nuhet.GORPea...t.water.. ad zinc and hydrochloric acid d nrate acid zinc and sulfuric acid zin.t.sukuni..nhydayn. Sulfate aud Exercise 5.3C Practical steps for making salts Challenge Inthis exercise, you willdescribe in detail the practical steps needed to produce a salt using an oxide and an acid. 1 Why is copper chloride not made by reacting copper with dilute sulfuric acid? Copper.chlend.cannat.be.made.oy. neazlin.sgper with dilute Suue arecl.becauueto.make...a.chlande,..yQu..uwQuld need to 2 Ue hydrochlonic aid and copper is unteactibe and does not Describe the three steps involved in producing crystals of the salt nent it copper chloride. For each step, describe the method and include the amy calut acd safety precautions needed. Use diagrams if they help your answer. aid...ExeAS.cappea. 0xide.iu. .added... syfunic aid L¢.a..beakea..Thia. ia..heated.gnty..and. stimed .Conutanty..hen..a calaua.chamge.Lto. blue) i Seen, you. shauld..shyp.heatag...Sajerypncaukanin :: wea boil the aud mixtwe, a ginen off 96 hamul ume Cve 5.4 Other ways of making salts The. stwnd step ia do. futer thu moxtwne. The he.kiltate. io.a. JAlditn.9.. ceppr...s ufote No addioral. Salcly. prrcautens...necd to be taten trom (t khun.small..cytala..em.....thu..usten tarke..to...pka. p.haatun...an.allew the Salety prLAlanA..Aear..dafaty.gass and take.caA.ae..hu.ht.luten..nay .pit..md..au..you. > 5.4 Other ways of making salts Exercise 5.4A Preparing copper chloride Focus In this exercise, you will explain the steps in the formation of a salt. You willalso consider some of the safety precautions needed. Zara and Sofia are preparing the salt copper chloride. Zara pours some hydrochloric acid into a beaker. Then Sofia adds some copper carbonate. 97> 5Reactivity copper carbonate hydrochloric acid 1 hydrochloric acid What happens when Sofia adds the copper carbonate to the acid? he.copper.Carbonate...McaLt..wath..the auid ad ..carbon.aioxid. gao.agitn.4f. Sofia adds more and more copper carbonate until there is no more reaction. There is some unreacted copper carbonate left in the beaker. Sofia filters the mixture. filtrate 2 3 What is left in the filter paper? (unreatd.cppe. .Carborate The filtrate passes through the filter paper into the flask. What is this liquid? A. 4 mixane.ef watex and ulion.f.cappe.chloxideC cOPper chlonde) Next, Zara and Sofia want to produce crystals of the sált. What must they do? Plheat.it.to..evapunate..f.th. au.khe.l ake.ia. an.cuaponatwater...and iy. leave basin and the cryfals 98 5.4 Other ways of making salts 5 Why must they be very careful when they 6 What should they do to reduce the carry out this step? whun th doluton.wdeing..heuladlt tenda to 4pit..and thio Can bwn hazard? They..shaud.. wear..sately glasa. to prerent .0amagc..D.hus..ya.,.dake..spal..ane when Npenating..cdah..din..eff the heat when .clou.D.u the douton beguns 7 Write the word equation for this reaction. copper + carbonate hloic Copper + + chlonide Carbon dioxice Exercise 5.4B Preparing potassium chloride Practice In this exercise, you will describe the steps needed in some practical work toproduce a salt from an acid and an alkali. Zara and Marcus want to prepare the salt potassium chloride, using potassium hydroxide. 1 Which acid should they use? yanchtenc...aud. 2 For the first step in this process, Zara and Marcus put 20 cm³ of potassium hydroxide in a conical flask. They use the acid to neutralise it. List the equipment they willneed for this first step in the process. .M eaauing..aid.keakeu.C.conical..klat), hyarelane...aud.bunette.. stand.. univeAal.ndicater..shitct..selutwn.. 99 5 Reactivity 3 Deseribe the method for carrving out this step. Include any safetyprecautions. ta.00. Put..on. sacly glaes. Fint..add adnp of lunewal. indicator..saluleoh n. the. potaan Aydvxide isthe beater, which tum blue. .Set. 4p.the..burete...and.dl..wth. acid Add..aud..alittle.. aa.tome....o.bhe. petasai um..hydroxide...and. switl.the. beaken..to..mix.the. content. 4 How will they know when the potassium hydroxide is neutralised? khen.they.kar. See the.uninenalindi caler ..sauton.aunn.o...lue.t. 5 When the potassium hydroxide is neutralised, Zara and Marcus have a coloured solution. How do they remove the colour, so that the crystals of potassium chloride are pure? Add.chaxcoal.to the.neutral.satin. .t.Kmore...tha.calous.Ihen..the. soluten. Shauld.be..ltered..t.remas...the. piescf charoal 6 Write the word equation for the neutralisation reaction. potasoium hydoida 7 hydrochlonc ’ aid potasium + waler Chloride Write the symbol equation for this reaction. KoH 100 > + Hcl KcI + Ha0. 5.4 Other ways of making salts Exercise 5.4C Mystery substances Challenge In thisexercise, you will use theinformation given to identify some substances. Arun and Marcus had three diflerent substances, A. B and C each in the form of powder. A B C They placed a sample of cach in one of three different test tubes. Thev added a different liquid to each test tube. They observed the reactions and did some tests. In the tube containing A, bubbles of gas were produced. When this gas was passed through limewater, it became milky. limewater becoming milky A In thetube containing B, no bubbles were produced. B 101 > 5 Reactivity pop In the tube containing C, bubbles of gas were produced. When the students collected this gas and tested it with the lighted splint, there was a squeaky pop. C After these substances had finished reacting, Arun and Marcus heated the three solutions (after filtering where necessary). They evaporated the substances to dryness to form three crystalline substances: substanceA produced zinc sulfate substance B produced iron chloride substance Cproduced magnesium chloride. Which gas did substance A produce? 1 carbon.doxide 2 Which gas did substance C produce? 3 hytrogen. Which general name is given to the crystalline substances produced in this way, after evaporation? Salts 4 Suggest which liquid was added to tube A. Sufuric acid 5 Suggest which liquid was added to tube B. chlonde ..a.selulan.f.cappea.chlomda.Camy. veachviy Seni) ametal below iron 102> on the 5.5 Rearranging atoms 6 Suggest which liquid was added to tube C 7 Suggest what substance A could have nyodvchlonc Qcid been Casbonate Suggest what substance B could have been. 9 Suggest what substance C could have been. 10 Write a word equation for the reaction involving substance A. .... 11 Write a word equation for the reaction involving substance B. nom.t..cOPPeo.chlonlde.iron.chloridt cOppe r 12 Write a word equation for the reaction involving substance C. chonce >5.5 Rearranging atoms Exercise 5.5A What happens to the atoms and the mass when chemicals react? Focus Inthis exercise, you will develop your understanding of how atoms rearrange in a chemical reaction and look at what happens to the mass of products in a reaction. When chemicals react together, none of the atoms is lost. Ihey rearrange to make other chemicals. 103> ur ce s. re so Smart Exam Resources xa m CAMBRIDGE LOWER SECONDARY CHECKPOINT PRACTISE QUESTIONS -MARKSCHEMS Subject: Chemistry- Stage - 9 ar te Topic: Preparing Common Salts Set-2 1 Dilute sulfuric acid is used to make salts known as sulfates. m A method consisting of three steps is used to make zinc sulfate from zinc carbonate. Add an excess of zinc carbonate to 20 cm3 of 0.4 mol / dm3 dilute sulfuric acid until the reaction is complete. step 2 Filter the mixture. step 3 Heat the filtrate until a saturated solution forms and then allow it to crystallise. w w w .s step 1 (i) Name a suitable piece of apparatus for measuring 20 cm3 of dilute sulfuric acid in step 1. ....................................................................................................................................... [1] (ii) State two observations which would show that the reaction is complete in step 1. 1 .......................................................................................................................................... 2 .......................................................................................................................................... [2] (iii) Why is it important to add an excess of zinc carbonate in step 1? ....................................................................................................................................... [1] (iv) What is meant by the term saturated solution in step 3? ............................................................................................................................................. ....................................................................................................................................... [2] Cambridge Lower Secondary Checkpoints Stage 9 Practice Questions Chemistry Smart Exam Resources 1 ur c re so w w w .s m ar te xa m MARKING SCHEME: Cambridge Lower Secondary Checkpoints Stage 9 Practice Questions Chemistry Smart Exam Resources 2 s. ce ur Soluble salts can be made using a base and an acid. m re so 2 (a) Complete this method of preparing dry crystals of the soluble salt cobalt(II) chloride-6-water from the insoluble base cobalt(II) carbonate. te xa Step 1 Add an excess of cobalt(II) carbonate to hot dilute hydrochloric acid. ar Step 2 w .s m ........................................................................................................................................... ........................................................................................................................................... w w Step 3 ........................................................................................................................................... ........................................................................................................................................... Step 4 ........................................................................................................................................... ..................................................................................................................................... [4] Cambridge Lower Secondary Checkpoints Stage 9 Practice Questions Chemistry Smart Exam Resources 3 s. ce ur w w w .s m ar te xa m re so MARK SCHEME: Cambridge Lower Secondary Checkpoints Stage 9 Practice Questions Chemistry Smart Exam Resources 4 s. ce ur The diagrams show the stages in the preparation of zinc nitrate crystals from lumps of zinc m re so carbonate. zinc carbonate zinc carbonate dilute nitric acid stage 1 stage 2 bubbles of gas stage 3 w w w .s m ar te xa 3 zinc nitrate solution unreacted zinc carbonate stage 4 heat stage 5 stage 6 (a) Complete the boxes to show the apparatus used. [2] (b) Use the diagrams to write a list of instructions for the stages of this preparation. (i) stages 1, 2, 3 and 4 ............................................................................................................................................. ............................................................................................................................................. ....................................................................................................................................... [3] (ii) stage 5 ....................................................................................................................................... [1] (iii) stage 6 ............................................................................................................................................. ....................................................................................................................................... [2] [Total: 8] Cambridge Lower Secondary Checkpoints Stage 9 Practice Questions Chemistry Smart Exam Resources 5 ur c re so 1 w w w .s m ar te xa m MARKING SCHEME Cambridge Lower Secondary Checkpoints Stage 9 Practice Questions Chemistry Smart Exam Resources 6 s. ce ur 4 te 1 xa m re so A student reacted excess iron powder with sulfuric acid to prepare a solution of iron(II) sulfate. The diagram shows the procedure followed in three stages. 2 iron powder was added until all the sulfuric acid had reacted w w w .s m ar 50 cm3 of dilute sulfuric acid was measured and added to a beaker heat 3 the mixture was allowed to cool solution of iron(II) sulfate (a) Complete the boxes to identify the pieces of apparatus labelled. [2] (b) How would the student know when all of the sulfuric acid had reacted? Give two reasons. 1 ........................................................................................................................................ 2 .................................................................................................................................. [2] (c) Describe the effect of boiling the solution of iron(II) sulfate for several minutes. ........................................................................................................................................... ........................................................................................................................................... ..................................................................................................................................... [3] [Total: 7] Cambridge Lower Secondary Checkpoints Stage 9 Practice Questions Chemistry Smart Exam Resources 7 ur c re so w w w .s m ar te xa m MARKING SCHEME Cambridge Lower Secondary Checkpoints Stage 9 Practice Questions Chemistry Smart Exam Resources 8 s. ce Smart Exam Resources m re so ur CAMBRIDGE LOWER SECONDARY CHECKPOINT PRACTISE QUESTIONS -MARKSCHEMS Subject: Chemistry- Stage - 9 xa Topic: Preparing Common Salts Set-1 18 °C sodium hydroxide solution at 18 °C 22 °C w w w .s m ar te student adds an aqueous solution of sodium hydroxide to an aqueous solution of ethanoic acid. 1 AShe measures the temperature before and after the addition of sodium hydroxide. ethanoic acid solution The product of the reaction is a salt called sodium ethanoate. Describe how you would prepare pure, dry crystals of sodium ethanoate from a solution of sodium ethanoate in water. ............................................................................................................................................. ............................................................................................................................................. ............................................................................................................................................. ....................................................................................................................................... [3] 0620/23/M/J/15 Cambridge Lower Secondary Checkpoints Stage 9 Practice Questions Chemistry Smart Exam Resources 1 s. ce ur m re so MARK SCHEME: w w w .s m ar te xa Any three of: • evaporation/ heat solution/leave the solution; • to crystallisation point/to form crystals; • filter off crystals / pick out crystals; • dry crystals between filter papers / heat gently / heat to just above 100°C; 3 Cambridge Lower Secondary Checkpoints Stage 9 Practice Questions Chemistry Smart Exam Resources 2 ur ce s. Leave the mixture until no more bubbles are seen. B Leave the mixture at room temperature to form more crystals. C Add an excess of magnesium to dilute hydrochloric acid. D Warm the filtrate to the point of crystallisation. xa m A ar te 2 re so The following statements are about the procedure for making crystals of hydrated magnesium chloride from magnesium and dilute hydrochloric acid. Filter off the crystals and dry between filter papers. F Filter off the excess magnesium. m E w w w .s Put the statements A, B, C, D, E and F in the correct order. The first one has been done for you. C [2] Cambridge Lower Secondary Checkpoints Stage 9 Practice Questions Chemistry Smart Exam Resources 3 ur ce s. re so MARK SCHEME: w w w .s m ar te xa m (C), A, F, D, B, E (2) if 2 marks not scored 1 mark for 1 consecutive pair reversed Cambridge Lower Secondary Checkpoints Stage 9 Practice Questions Chemistry Smart Exam Resources 4 ur ce s. re so 3 (a) Dilute hydrochloric acid reacts with zinc. + hydrochloric acid .............................. + .............................. .............................. [2] m ar te zinc xa m Complete the word equation for this reaction. w w w .s (b) The following statements are about the procedure for making crystals of hydrated zinc sulfate from zinc and dilute sulfuric acid. A Warm the mixture until no more bubbles are seen. B Add excess zinc to dilute sulfuric acid. C Warm the filtrate to the point of crystallisation. D Leave the mixture at room temperature to form more crystals. E Filter off the excess zinc. F Filter off the crystals and dry between filter papers. Put the statements A, B, C, D, E and F in the correct order. The first one has been done for you. B [2] Cambridge Lower Secondary Checkpoints Stage 9 Practice Questions Chemistry Smart Exam Resources 5 ur ce s. w w w .s m ar te xa m re so MARK SCHEME: (a) (hydrochloric acid + zinc) → zinc chloride (1) + hydrogen (1) 2 (b)(B), A, E, C, D, F (2) If 2 marks not scored: 1 mark for 1 consecutive pair reversed Cambridge Lower Secondary Checkpoints Stage 9 Practice Questions Chemistry Smart Exam Resources 6 ur ce s. 4 + magnesium .............................. + .............................. .............................. xa m sulfuric acid re so Complete the word equation for the reaction of dilute sulfuric acid with magnesium. w w w .s m ar te [2] Cambridge Lower Secondary Checkpoints Stage 9 Practice Questions Chemistry Smart Exam Resources 7 ur ce s. re so MARK SCHEME: w w w .s m ar te xa m magnesium sulfate (1) hydrogen (1) Cambridge Lower Secondary Checkpoints Stage 9 Practice Questions Chemistry Smart Exam Resources 8 ur ce s. 5 re so Magnesium sulfate and lead(II) sulfate are examples of salts. (a) A student prepared magnesium sulfate crystals starting from magnesium carbonate. The xa m student carried out the experiment in four steps. ar te step 1 The student added excess magnesium carbonate to a small volume of dilute sulfuric acid until no more magnesium carbonate would react. w w w .s m step 2 The student filtered the mixture. (i) step 3 The student heated the filtrate obtained from step 2 until it was saturated. step 4 T he student allowed the hot filtrate to cool to room temperature and then removed the crystals which formed. How did the student know when the reaction had finished in step 1? ........................................................................................................................................ [1] (ii) Name the residue in step 2. ........................................................................................................................................ [1] (iii) A saturated solution forms in step 3. What is a saturated solution? .............................................................................................................................................. ........................................................................................................................................ [2] (iv) Explain why magnesium sulfate crystals form during step 4. .............................................................................................................................................. ........................................................................................................................................ [1] Cambridge Lower Secondary Checkpoints Stage 9 Practice Questions Chemistry Smart Exam Resources 9 ur c re so w w w .s m ar te xa m MARK SCHEME: Cambridge Lower Secondary Checkpoints Stage 9 Practice Questions Chemistry Smart Exam Resources 10 ur ce s. Describe how you would prepare a pure dry sample of copper(II) nitrate crystals in the laboratory using dilute nitric acid and solid copper(II) carbonate. Include a series of key steps in your answer. You should include a chemical equation for the reaction. xa m re so 6 ..................................................................................................................................................... ar te ..................................................................................................................................................... ..................................................................................................................................................... w w w .s m ..................................................................................................................................................... ..................................................................................................................................................... ..................................................................................................................................................... ..................................................................................................................................................... ............................................................................................................................................... [6] Cambridge Lower Secondary Checkpoints Stage 9 Practice Questions Chemistry Smart Exam Resources 11 ur c re so w w w .s m ar te xa m MARK SCHEME: Note: • At the checkpoint stage, you may include a word equation Cambridge Lower Secondary Checkpoints Stage 9 Practice Questions Chemistry Smart Exam Resources 12