Cambridge IGCSE Combined and Co-ordinated Sciences Answers to questions Biology Chapter B1 Cells B1.01 about 1500 times B1.02 10 mm (1 cm) B1.03 all cells B1.04 cellulose B1.05 It will allow all substances to pass through. B1.06 It will allow some substances to pass through, but not others. B1.07 water B1.08 It is a space inside a cell, surrounded by a membrane, containing a liquid. B1.09 It is a liquid containing sugars and other substances dissolved in water, found inside a vacuole in a plant cell. B1.10 It absorbs energy from sunlight. 1 B1.11 DNA, in the form of chromosomes; this is the genetic information of the cell. B1.12 They are usually too long and thin, but become shorter and fatter just before the cell divides. Chapter B2 Movement in and out of cells B2.01 It is the net movement of molecules from a region of their higher concentration down a concentration gradient to a region of their lower concentration, as a result of their random movement. B2.02 For example: oxygen diffusing into an organism across a gas exchange surface, or into a cell across its cell surface membrane; carbon dioxide diffusing out of an organism across a gas exchange surface, or out of a cell across its cell surface membrane; diffusion of carbon dioxide into the air spaces of a leaf. B2.03 a It increases kinetic energy. b It will increase the rate of diffusion, because the molecules move faster. B2.04 a sugar molecule B2.05 a membrane that allows some particles to pass through, but not others B2.06 Visking tubing, a cell membrane B2.07 It is a dilute solution (or it has a high water potential). B2.08 It absorbs water by osmosis, swelling until it bursts. B2.09 The plant cell absorbs water by osmosis just like an animal cell, but the strong cellulose cell wall prevents it bursting. B2.10 a the cell wall b the cell membrane B2.11 a cell that has taken up water so that the cell contents are pressing outwards onto the cell wall B2.12 the condition of a plant cell when it has lost so much water that the cytoplasm and vacuole have shrunk, pulling the cell membrane away from the cell wall B2.13 by putting a plant cell into a solution that is more concentrated than the cytoplasm and cell sap B2.14 The same solution as is outside the cell – the cell wall is fully permeable, so both water and solute molecules can diffuse freely through it. B2.15 In Figure B2.04, the solution outside the cell has a higher water potential than the cytoplasm or cell sap. Water therefore diffuses down the water potential gradient, into the cell, through the partially permeable cell membrane. In Figure B2.05, the solution outside the cell has a lower water potential than the cytoplasm or cell sap. Water therefore diffuses down the water potential gradient, out of the cell, through the partially permeable cell membrane. Chapter B3 Biological molecules B3.01 the chemical reactions that take place inside the body B3.02 Cells will lose water. Reactions take place in solution in the cytoplasm. If there is not enough water, this cannot happen. Water is also required for transport (e.g. substances dissolve in the water in blood plasma), and cooling (sweating and transpiration). B3.03 carbon, hydrogen, oxygen B3.04 There are 6 carbon atoms, 12 hydrogen atoms and 6 oxygen atoms in one glucose molecule. Answers to questions B3.05 a simple sugar (monosaccharide) b polysaccharide c polysaccharide B3.06 a b c d e glucose glucose glycogen sucrose starch B4.06 small holes, mostly on the lower surface of a leaf, through which gases can diffuse B4.07 sausage-shaped cells surrounding a stoma, which can change their shape and open or close the stoma B3.07 carbon, hydrogen, oxygen B4.08 Palisade mesophyll cells, spongy mesophyll cells and guard cells contain chloroplasts. Epidermal cells (and xylem vessels and phloem sieve tubes) do not. B3.08 heat insulation, energy store B4.09 carbon dioxide and water B3.09 The oils are an energy store for the embryo plant to use when germination begins, before it can photosynthesise. B4.10 about 0.04% B3.10 nitrogen, sometimes sulfur B3.11 about 20 B3.12 They are made of long chains of smaller molecules linked together. B3.13 haemoglobin, any enzyme, antibodies, other suitable example B3.14 for example: transporting oxygen (haemoglobin); the formation of new cells (for growth or repair); forming hair (keratin); catalysing reactions (enzymes) B3.15 a substance that speeds up a chemical reaction without itself being changed B3.16 enzymes B3.17 all of them B3.18 For amylase, the substrate is starch and the product is maltose. B3.19 the temperature at which an enzyme works at its fastest B3.20 40 °C B3.21 The enzyme molecule loses its shape at high temperature, so the substrate will no longer fit into the active site. Chapter B4 Plant nutrition B4.01 any suitable organic substance – for example, sugar B4.02 carbon dioxide and water B4.03 the green pigment, found in chloroplasts, that absorbs energy from sunlight, used to drive photosynthesis B4.04 epidermal cells B4.05 to prevent water loss from leaf cells B4.11 by diffusion, through the stomata B4.12 Water is brought to the leaf in xylem vessels. B4.13 More sunlight can be absorbed; more carbon dioxide can diffuse into the leaf at the same time. B4.14 Sunlight can reach all the cells in the leaf. Carbon dioxide can diffuse quickly to all the cells in the leaf. B4.15 Glucose is soluble and fairly reactive. B4.16 nitrogen (in a reactive form, such as nitrates) B4.17 Nitrate ions are needed for making amino acids. These in turn are used to make proteins, and proteins are needed for growth. B4.18 Sucrose, produced by photosynthesis in the leaves, is supplied to them through phloem sieve tubes. Chapter B5 Animal nutrition B5.01 a Carbohydrates, fats, proteins and vitamins are organic. Minerals and water are inorganic. b carbohydrates, fats and proteins cto stimulate peristalsis and prevent constipation B5.02 heart disease, diabetes, stroke B5.03 a disease of the coronary arteries of the heart, which become partially blocked by deposits of cholesterol, preventing sufficient oxygen reaching the heart muscle B5.04 Starvation means not getting enough food. Malnutrition means having an unbalanced diet, perhaps a diet lacking in one nutrient or containing too much fat. B5.05 a disease caused by a lack of a particular nutrient in the diet B5.06 scurvy (lack of vitamin C); rickets (lack of vitamin D); brittle bones (lack of calcium); anaemia (lack of iron) 2 Cambridge IGCSE Combined and Co-ordinated Sciences B5.07 the breakdown of large, insoluble food molecules into small molecules using mechanical and chemical processes B5.08 vitamins and minerals (and water) B5.09 a simple sugars (glucose) b amino acids c fatty acids and glycerol B5.10 breaking down large molecules of food into small ones, using enzymes B5.11 the teeth at the front of the mouth, used for biting off pieces of food B5.12 a mix of food remnants and bacteria coating the teeth B5.13 Bacteria in plaque can breed and penetrate between the tooth and the gums, causing inflammation and eventually even loss of the tooth. Bacteria in plaque produce acids when they metabolise foods. The acid dissolves enamel, producing a hole through which bacteria can reach the living part of the tooth. B5.14 The mouth (in saliva); the small intestine (in pancreatic juice). It breaks down starch to maltose. 3 B5.15 The acid provides the optimum pH for pepsin to work, and destroys bacteria in the food. B5.16 pancreatic juice and bile B5.17 Bile salts emulsify fats, making it easier for lipase to come into contact with them and digest them. Chapter B6 Transport in plants B6.01 water and inorganic ions such as nitrate B6.02 sucrose and amino acids B6.03 a collection of xylem vessels and phloem tubes B6.08 a An increase in temperature increases the rate of transpiration. (This happens because, at higher temperatures, water molecules have more kinetic energy. They are more likely to turn from liquid to gas, and will diffuse more rapidly out of the leaf.) b An increase in humidity decreases the rate of transpiration. (This happens because the greater quantity of water vapour in the air outside the leaf means that the diffusion gradient for water vapour is less.) Chapter B7 Transport in animals B7.01 a system of blood vessels with a pump and valves to ensure one-way flow of blood B7.02 blood containing a lot of oxygen B7.03 the lungs B7.04 the left side B7.05 In a double circulatory system, blood flows from the heart to the lungs, and then back to the heart again before travelling to the rest of the body. In a single circulatory system, blood flows directly from the lungs or gills to the rest of the body. B7.06 In a double circulatory system, oxygenated blood is transported to body cells faster, at higher pressure. B7.07 a left atrium b right atrium B7.08 between the atria and the ventricles B7.09 a right ventricle b left ventricle B7.10 They contain more cardiac muscle, which can therefore provide a greater force when they contract. This is needed to pump the blood around the body. B6.04 Water moves into root hairs by osmosis, down its water potential gradient (or from a less concentrated solution to a more concentrated one), through the partially permeable cell membrane of the root hair cells. B7.11 It contains more cardiac muscle, needed to produce more force to pump blood all around the body rather than just to the lungs. B6.05 evaporation of water from the surfaces of mesophyll cells followed by loss of water vapour from plant leaves, through the stomata B7.12 The pulse is the regular expansion of arteries, caused by blood surging through at high pressure each time the ventricles contract. B6.06 small holes, mostly on the lower surface of a leaf, each surrounded by a pair of guard cells, through which gases can diffuse into and out of the leaf B7.13 to move oxygenated blood to the muscles more quickly, to supply the oxygen they need to release energy from glucose, by respiration B6.07 measuring the rate at which a shoot takes up water (and therefore the rate at which it loses water by transpiration) B7.14 a patch of muscle in the right atrium which sets the pace for the beating of the rest of the heart muscle Answers to questions B7.15 Extra CO2 (from respiring muscles) dissolves in blood plasma, reducing its pH. This is sensed by receptors in the brain, which increases the frequency of nerve impulses sent to the pacemaker. B7.16 The valves are pushed closed by the high pressure of the blood in the ventricles. This prevents blood flowing back into the atria. B8.07 the voice box B8.08 They sweep mucus, which contains trapped bacteria and dust particles, up to the top of the trachea and into the throat, where it can be swallowed. B8.09 across the walls of the alveoli B8.10 two B7.17 a arteries b veins Chapter B9 Coordination and homeostasis B7.18 The pressure of the blood in arteries is high and pulsing, so the strong walls are needed to withstand this pressure. B9.02 nerves and hormones (the nervous system and the endocrine system) B7.19 The elastic walls allow the arteries to expand with each pulse of pressure (produced by the heart) and then recoil in between pulses; if they could not do this, they might burst. B9.01 any muscles or glands B9.03 They have a nucleus, cell membrane and cytoplasm. B7.21 A large lumen provides less resistance to blood flow, needed because blood pressure in the veins is low. B9.04 They have a long axon (or dendron) to transmit impulses rapidly from one part of the body to another. They have nerve endings to pass the impulses onto another nerve cell or an effector. They (may) have a myelin sheath around the axon (or dendron) to speed up the impulses. They have dendrites to receive nerve impulses from other cells. B7.22 Skeletal muscles in the legs squeeze inwards on the veins when the muscles contract, pushing blood along inside them. B9.05 The CNS receives inputs from different receptors, which it integrates, and produces nerve impulses to send to appropriate effectors. B7.23 five from: water, glucose, vitamins, minerals (inorganic ions), hormones, antibodies (and others) B9.06 a in a small swelling just outside the spinal cord b in the central nervous system – either the brain or the spinal cord c in the central nervous system – either the brain or the spinal cord B7.20 Capillaries deliver blood, containing oxygen and nutrients, very close to every cell in the body. B7.24 They transport oxygen. B7.25 They have no nucleus, and contain haemoglobin. They have a biconcave shape. B7.26 a red pigment that absorbs and releases oxygen; a protein found inside red blood cells B9.07 They produce very quick, automatic responses with no time wasted in making decisions. This can enable escape from danger. B7.27 tiny fragments of cells that help with blood clotting B9.08 There are many possibilities. Answers should state the stimulus and the response. Chapter B8 Respiration and gas exchange B9.09 a change in the environment that is detected by a receptor B8.01 to release energy from glucose for cells to use B8.02 active transport; driving chemical reactions such as protein synthesis; movement; producing heat; transmitting nerve impulses; cell division B9.10 retina B9.11 conjunctiva, cornea, aqueous humour, pupil, lens, vitreous humour, retina B9.12 cornea and lens B8.03 the release of a relatively small amount of energy by the breakdown of food substances in the absence of oxygen B9.13 changing the shape of the lens to focus light rays from different distances onto the retina B8.04 yeast, humans (for short periods of time) B9.14 a contract B8.05 It produces lactic acid. It does not produce CO2. It releases less energy. b iThis reduces tension on the suspensory ligaments B8.06 It produces lactic acid, not ethanol. It does not produce CO2. iiwhich allows the lens to become its natural, rounded shape. 4 Cambridge IGCSE Combined and Co-ordinated Sciences B9.15 dissolved in blood plasma B9.16 any situation in which you are nervous, frightened or angry B9.17 It increases glucose concentration in the blood, so muscles can use more for respiration; it increases heart rate, increasing the supply of glucose and oxygen to muscles; it increases breathing rate – similar effect. B9.18 the tip B9.19 just behind the tip B9.20 Auxin made in the tip diffuses down into the part just below the tip. Auxin is like an animal hormone, a chemical that is made in one part of the body and moves to another where it has an effect. However, auxin is not made in an endocrine gland like animal hormones, and it is not transported in the blood. B9.21 It moves the leaves towards a light source, maximising the amount of light available for photosynthesis. B9.22 It grows towards it. 5 B9.23 It stores fat as an energy reserve, which can be used in respiration to release energy for cells to use. It acts as a heat insulator, preventing loss of heat from the body to the external environment. B9.24 The water in sweat evaporates. This requires energy, which is taken from the skin, thus cooling it. B9.25 hypothalamus B9.26 Vasodilation is the widening of the arterioles supplying the blood capillaries near the surface of the skin. It allows more blood to flow through these capillaries, losing heat by radiation through the skin surface. B9.27 When a parameter changes in a particular direction, this is sensed and measures are put into place to change it back towards the norm. Chapter B10 Reproduction in plants B10.01 In asexual reproduction, there is only one parent. Cells divide by a type of cell division that produces genetically identical cells, so the offspring are genetically identical to their parent and to each other. B10.02 a haploid cell that fuses with another haploid gamete to produce a zygote – for example, an egg or a sperm B10.03 a diploid cell formed by the fusion of the nuclei of two gametes B10.04 so that when their nuclei fuse at fertilisation, the new cell formed will have the normal two sets of chromosomes B10.05 a cell with two complete sets of chromosomes B10.06 any part of the body B10.07 a cell with one set of chromosomes B10.08 egg or sperm B10.09 sexual reproduction B10.10 anthers B10.11 ovules B10.12 the transfer of pollen grains from the male part of the flower (anther of stamen) to the female part of the flower (stigma) B10.13 Much of the pollen of wind-pollinated flowers will not land on the stigma of a flower of the same species and will be wasted. The pollen of insectpollinated flowers is more likely to be delivered to an appropriate flower. B10.14 down a tube that grows out of the pollen grain, through the style and into the ovule Chapter B11 Reproduction in humans B11.01 cervix B11.02 where the two sperm ducts join the urethra; it produces fluid for sperm to swim in B11.03 An egg bursts out of an ovary, and is caught in the funnel of the oviduct. B11.04 in the testes B11.05 Cilia in the wall of the oviduct waft it along. B11.06 in the oviducts B11.07 Sperm are much smaller than eggs. Sperm can swim but eggs cannot. Sperm have a head, a long tail, and enzymes in a vesicle in the head. Eggs have none of these, but they have a layer of jelly surrounding them. B11.08 when the embryo sinks into the lining of the uterus B11.09 a developing baby in the uterus from about the 11th week after fertilisation B11.10 by the umbilical cord, which contains two arteries and a vein B11.11 oxygen; glucose; any other soluble nutrients; water B11.12 so that it is prepared for the arrival of an embryo if an egg is fertilised B11.13 It is lost through the vagina. Answers to questions Chapter B12 Inheritance B12.09 She could breed the black-spotted dog with a liver-spotted dog. If the dog is heterozygous: B12.01 DNA B12.02 a pair of chromosomes that carry the same genes in the same positions B12.03 different forms of a gene black spots Bb B b B12.04 a B and b (or any other upper and lower case versions of the same letter) b brown eyes B B12.05 23 B12.06 a Nn b N or n b B12.07 normal wings NN N N N normal wings Nn n N n NN normal wings Nn normal wings All the offspring would have normal wings. B12.08 a brown hair Bb B b B b brown hair Bb B b B b BB brown hair Bb brown hair Bb brown hair bb red hair If both parents were heterozygous, then both can produce gametes containing the b alleles. If two such gametes fuse to form a zygote, the resulting child will have the genotype bb and have red hair. The chance of this happening is one in four each time they have a child. By chance, this has happened three times out of five. b Person 1 must be heterozygous, Bb, because at least two of his children have red hair and so must have inherited a b allele from both parents. Person 3 has red hair, and so must have the genotype bb. Person 2 must also be heterozygous, Bb, for the same reason. He has brown hair. liver spots bb b Bb black spots bb liver spots If the black-spotted dog is homozygous, all of its gametes will have the allele B, so all the offspring will have the genotype Bb and will have black spots. Therefore, if any of the offspring have liver spots, the breeder knows that the genotype of the black-spotted dog is Bb. Chapter B13 Variation and natural selection B13.01 a b c d discontinuous continuous continuous discontinuous B13.02 a and d genes only b and c genes and environment B13.03 The more that populations of bacteria are exposed to an antibiotic, the more likely that bacteria resistant to this antibiotic will gain an advantage over non-resistant bacteria. These will breed and pass on their resistance genes to the next generation. B13.04 Choose sperm from a bull whose female offspring and other female relatives have high milk yields. Choose a cow that has a high milk yield, and fertilise her eggs with sperm from the chosen bull. Continue for several generations. B13.05 a Grow wheat in conditions where it gets infected by rust. Collect seed from any plants that are not infected, or that are not harmed. Grow this seed and repeat for several generations, each time picking out seed from plants that are least affected by rust. b Some of the rust organisms may have a variation that allows them to infect the resistant wheat plants. These will have a selective advantage, and be more likely to 6 Cambridge IGCSE Combined and Co-ordinated Sciences survive and reproduce, passing on the genes for this characteristic to the next generation of rust fungi. Over time, most of the rust fungi may have this gene and be able to infect the previously resistant wheat plants. Chapter B14 Organisms and their environment B14.01 Almost all the energy in living organisms on Earth originates from sunlight. (There are deepsea ecosystems that are based on energy from geothermal vents on the ocean floor, but the vast majority of life on Earth is ultimately driven by solar energy.) B14.02 a One example might be: Sun → maize (grown for fodder) → cattle → human. b One example might be: Sun → phytoplankton → zooplankton → fish → seal → shark. c One example might be: Sun → grass → grasshopper → rat → snake → hawk. 7 B14.03 because, in photosynthesis, they use energy from sunlight to produce the food that then powers the rest of the food chain B14.04 The further up the food chain you go, the less energy is available from the original energy provided by the Sun. This is because, at each trophic level, the organisms use up a lot of energy as they live and grow, so there is less available to pass on to animals that eat them. Beyond about five links in a chain, the energy has effectively run out. B14.05 photosynthesis B14.06 protein or any named proteins, carbohydrates or a named carbohydrate (glucose, glycogen), fats B14.07 It will increase, because the combustion of fossil fuels produces carbon dioxide that is released into the air. B14.08 Growing trees take carbon dioxide from the air for photosynthesis. If trees are removed, then less carbon dioxide is removed. If the trees are burnt, this produces carbon dioxide that goes into the air. B14.09 Tree roots help to hold soil in place, especially on sloping land. Without trees, rain can easily wash the soil down the slope. Trees intercept raindrops as they fall, reducing the force with which they hit the soil. Without trees, rain hits the ground harder, so that soil is loosened and washed away. Trees absorb water from the soil. Without trees, less water is absorbed and more runs off the surface of the land, increasing soil erosion and flooding. B14.10 untreated sewage, fertilisers B14.11 oxygen B14.12 Plastic bags are not able to be decomposed by organisms. Instead, they remain in the environment, where they can cause problems such as being eaten by animals and staying, undigested, in their alimentary canals. Paper bags are easily broken down by decomposers. Chemistry Chapter C1 Planet Earth C1.01 sulfur dioxide and nitrogen dioxide C1.02 the burning of fossil fuels (mainly coal for sulfur dioxide) C1.03 damage to limestone buildings, death of trees, acidification of lakes leading to death of fish C1.04 a combination of nitrogen oxides and low-level ozone that causes breathing problems, especially for people with asthma C1.05 It combines with the haemoglobin in red blood cells, stopping them from carrying oxygen. C1.06 because it does not react with the filament, which would burn in air when it became hot C1.07 Heat which would normally escape into space is reflected back to the Earth’s surface by gases such as carbon dioxide and methane in the atmosphere. C1.08 It changes nitrogen oxides and carbon monoxide to nitrogen and carbon dioxide. C1.09 because solid matter is easiest to remove and would interfere with subsequent processes C1.10 to kill bacteria present in the water C1.11 because the energy needed to boil the water is costly C1.12 It contains a high concentration of a particular metal compound. C1.13 Lime is calcium oxide, which is reacted with water to make calcium hydroxide (slaked lime). C1.14 It reflects heat back to Earth when present in the atmosphere. Heat is kept in the atmospheric layer. Answers to questions Chapter C2 The nature of matter C2.01 a b c d liquid: particles close together but less regularly arranged; particles able to move about gas: particles far apart and irregularly arranged; particles moving independently freezing (solidification) boiling condensation sublimation C2.02 The impurity lowers the freezing point of the liquid. C2.03 Temperature / °C 80 liquid C2.14 Ammonia, because it has a lower molecular mass. Place cotton wool plugs soaked in ammonia solution and hydrochloric acid at opposite ends of a tube. Seal the tube at both ends. Allow the gases to diffuse towards each other. A white smoke disc of ammonium chloride will form where the two gases meet. This disc is closer to the hydrochloric acid end of the tube, as ammonia diffuses faster. C2.15 hydrogen 0 C2.16 15 protons, 16 neutrons, 15 electrons freezing solid C2.17 proton = 1, neutron = 1, electron = 0 (or X) C2.18 Chlorine-37 has two more neutrons in the nucleus. –20 Time C2.19 first shell, maximum 2; second shell, maximum 8 C2.04 A volatile liquid is one that evaporates easily; it has a low boiling point. C2.20 2,8,8,2 C2.05 ethanol > water > ethanoic acid. Ethanol is the most volatile, ethanoic acid the least. C2.22 6 in both cases C2.06 a distillation b fractional distillation c crystallisation (evaporation to concentrate the solution, cooling, crystallisation, filtration and drying) Chapter C3 Elements and compounds C2.07 Sublimation is when a solid changes to a gas without passing through the liquid phase (and the reverse). C2.08 coloured substances (e.g. dyes) C2.09 by the use of locating agents that react with colourless ‘spots’ to produce a colour that can be seen C2.10 Rf gives a standard measure of how far a sample moves in a chromatography system, as it relates the movement of the sample compound to how far the solvent front has moved. It is equal to the distance moved by the sample divided by the distance moved by the solvent front. C2.11 An element is a substance that cannot be broken down into anything simpler by chemical means. C2.21 8 in both cases C3.01 fluorine C3.02 2 C3.03 the bottom of Group I C3.04 Metal: can be beaten into sheets, gives a ringing sound when hit, conducts heat, conducts electricity Non-metal: is an insulator, has a dull surface C3.05 Helium has a full first shell. The others all have 8 electrons in the outer energy level (shell/orbit). C3.06 potassium hydroxide C3.07 lithium + water → lithium hydroxide + hydrogen C3.08 It is used in the treatment of drinking water; it will bleach moist litmus paper. C3.09 chlorine and fluorine C3.10 metal to non-metal C3.11 aluminium C3.12 sodium C2.12 A compound is a substance formed from two or more elements chemically bonded together. C3.13 Cl2 C2.13 solid: particles packed close together in a regular arrangement; each particle only vibrating about a fixed point C3.15 because copper is a transition metal C3.14 silicon C3.16 a covalent b covalent c ionic d metallic 8 Cambridge IGCSE Combined and Co-ordinated Sciences C3.17 because in hydrogen gas two atoms are covalently bonded together C3.18 an electrostatic force (attraction between two oppositely charged ions) C3.24 a C3.19 a H c H b H O H c N H H H d H C H 9 H H C3.20 a – [Na]+ Cl b – + [Li] F C3.21 The calcium ion is ionically bonded to the carbonate ion but the carbonate ion is held together by covalent bonds. C3.22 a 2– [Mg]2+ – Cl 2+ [Ca] calcium hydroxide nitrogen monoxide nitrogen dioxide sulfur trioxide SiCl4 b CS2 PCl3 (or PCl5) d SiO2 C3.25 a i Na = 1, O = 1, H = 1 ii C = 2, H = 6 iii H = 2, S = 1, O = 4 iv Cu = 1, N = 2, O = 6 v C = 12, H = 22, O = 11 b i potassium bromide ii aluminium hydroxide iii copper carbonate iv magnesium nitride v phosphorus trichloride vi nitric acid vii silicon tetrachloride viii iron(ii) sulfate ix methane x sulfuric acid c i K 2SO4 ii AlF3 iii Fe2O3 iv Ca(NO3)2 v ZnCl2 vi NH3 vii HCl viii CuSO4 ix SO3 C3.26 a b c d e f carbon, hydrogen and oxygen 8 carbon and oxygen 4 A liquid: it is a small covalent molecule. No, it is covalently bonded. C3.27 The ions are free to move and they carry the charge. O b – Cl C3.23 a b c d e f g h sodium iodide magnesium sulfide potassium oxide lithium nitride C3.28 because the ions are fixed in position and cannot move C3.29 a There are electrons between the flat planes of atoms which are free to move. b There are only weak forces between the layers in graphite and therefore they can slide over each other. C3.30 because, in diamond, each carbon atom is attached to four other carbon atoms, making a strong lattice Answers to questions C3.31 because there are no charged particles to move around b magnesium + steam → magnesium oxide + hydrogen Mg + H2O → MgO + H2 C3.32 because there are electrons which are free to move in solid metals c C3.33 Both substances have a three-dimensional structure in which the atoms are arranged tetrahedrally and all the atoms are joined by covalent bonds. 2Ca + O2 → 2CaO d bromine + potassium iodide → potassium bromide + iodine Br2 + 2KI → 2KBr + I2 e zinc + copper sulfate → zinc sulfate + copper Chapter C4 Chemical reactions C4.01 a physical physical d physical C4.02 a exothermic b exothermic c exothermic d endothermic C4.03 A new substance(s) has been formed. C4.04 a iron + oxygen → iron(iii) oxide b sodium hydroxide + sulfuric acid → sodium sulfate + water c sodium + water → sodium hydroxide + hydrogen C4.05 a 2Cu + O2 → 2CuO b N2 + 3H2 c 2NH3 4Na + O2 → 2Na2O d 2NaOH + H2SO4 → Na2SO4 + 2H2O e 2Al + 3Cl → 2AlCl3 f 3Fe + 4H2O → Fe3O4 + 4H2 C4.06 a chlorine + potassium bromide → potassium chloride + bromine b Iodine is less reactive than chlorine so it will not displace chlorine from its salts. C4.07 a combustion b decomposition c Zn + CuSO4 → ZnSO4 + Cu C4.09 a Solid sodium carbonate reacts with hydrochloric acid solution to give sodium chloride solution and carbon dioxide gas. Water, a liquid, is also produced. b chemical c calcium + oxygen → calcium oxide redox d neutralisation C4.08 a sodium + water → sodium hydroxide + hydrogen 2Na + 2H2O → 2NaOH + H2 b i ii iii iv Ag+ (aq) + Cl–(aq) → AgCl(s) Ba2+(aq) + SO42–(aq) → BaSO4(s) H+(aq) + OH–(aq) → H2O(l) 2H+(aq) + CO32–(s) → H2O(l) + CO2(g) C4.10 Reduction is the gain of electrons; oxidation is the loss of electrons. During a redox reaction the oxidising agent gains electrons; the oxidising agent is itself reduced during the reaction. C4.11 a The compound is split into its elements. b The ions are not free to move in the solid, so they cannot move to the electrodes to be discharged. c The vapour is brown. d because bromine vapour is toxic e the cathode C4.12 a the cathode b copper sulfate solution C4.13 a 2Br – → Br2 + 2e– b because electrons are gained by the lead ions C4.14 Solution Gas (electrolyte) given off at the anode Gas given Substance off or left in metal solution at deposited the end of at the electrolysis cathode silver sulfate oxygen silver sulfuric acid sodium nitrate oxygen hydrogen sodium nitrate C4.15 a i electrode Y ii a cathode b The solution would become acidic. c To make the electrode conduct electricity. 10 Cambridge IGCSE Combined and Co-ordinated Sciences Chapter C5 Acids, bases and salts C5.01 A corrosive substance ‘eats’ things away. C5.02 citric acid C5.03 a alkaline b neutral c alkaline d acidic C5.04 It changes its colour depending on whether it is in an acidic or alkaline solution. C5.05 pH 1 is more acidic. C5.06 green C5.07 ethanoic acid C5.08 hydrogen C5.09 hydroxide ion, OH– C5.10 a calcium ions and hydroxide ions b ammonium ions and hydroxide ions C5.11 a H2SO4 b HCl C5.12 They are equal. C5.13 blue 11 C5.14 white b potassium hydroxide + sulfuric acid → potassium sulfate + water 2KOH + H2SO4 → K 2SO4 + 2H2O C5.25 sodium hydroxide, potassium hydroxide, calcium hydroxide (limewater), ammonia solution C5.26 ammonia C5.27 sulfuric acid (H2SO4), hydrochloric acid (HCl) C5.28 a potassium hydroxide + hydrochloric acid → potassium chloride + water b copper oxide + hydrochloric acid → copper chloride + water c zinc + hydrochloric acid → zinc chloride + hydrogen d sodium carbonate + hydrochloric acid → sodium chloride + water + carbon dioxide C5.29 a b c d KOH + HCl → KCl + H2O CuO + 2HCl → CuCl2 + H2O Zn + 2HCl → ZnCl2 + H2 Na2CO3 + 2HCl → 2NaCl + H2O + CO2 C5.30 a carbonate + hydrochloric acid → salt + water + carbon dioxide C5.31 blue precipitate, copper(ii) hydroxide C5.17 magnesium + oxygen → magnesium oxide C5.32 Ammonia solution; you get a white precipitate in both cases but the zinc hydroxide precipitate re-dissolves in excess ammonia and the aluminium hydroxide precipitate does not. C5.18 carbon monoxide C5.33 pink (purple) C5.19 zinc hydroxide or aluminium hydroxide C5.34 to make sure all the acid is used up/reacted C5.15 sulfur + oxygen → sulfur dioxide C5.16 S + O2 → SO2 zinc hydroxide + sodium hydroxide → sodium zincate + water Zn(OH)2 + 2NaOH → Na2ZnO2 +2H2O or aluminium hydroxide + sodium hydroxide → sodium aluminate + water Al(OH)3 + NaOH → NaAlO2 + 2H2O C5.20 baking soda C5.21 hydrochloric acid, to help digest our food C5.22 calcium carbonate, magnesium hydroxide C5.23 insoluble bases: copper oxide, zinc oxide; alkalis: sodium hydroxide, potassium hydroxide C5.24 a sodium hydroxide + hydrochloric acid → sodium chloride + water NaOH + HCl → NaCl + H2O C5.35 filtration C5.36 pipette, burette C5.37 If heated too strongly, the salt could dehydrate (lose water of crystallisation) or even decompose. method B C5.38 a i ii sulfuric acid iiizinc oxide + sulfuric acid → zinc sulfate + water b i method A ii hydrochloric acid iii KOH + HCl → KCl + H2O Chapter C6 Quantitative chemistry C6.01 a covalent b ionic c CH4, NaI, C3H6, ICl3, BrF5, HBr Answers to questions C6.02 a 32 C7.04 d 114 64 e 98 f g 188 h 133.5 Energy c b 17 119 C6.03 a 0.20 g; 0.18 g; 0.08 g; 0.12 g ZnSO4 (aq) + Cu(s) Progress of reaction b C7.05 a rate increases b rate increases c rate increases 0.2 Mass of oxygen/g EA Zn(s) + CuSO4(aq) C7.06 The reactions which would spoil the food are slowed down at the lower temperature. 0.1 C7.07 at the beginning C7.08 because the reactants are being used up 0 0 0.1 0.2 0.3 Mass of magnesium /g c The graph is a straight line, showing a fixed ratio of oxygen to magnesium; this indicates a fixed formula. C6.04 a i near the neck of the test tube ii to flush out all of the air from the tube iiito make sure the reaction was complete b i C = 1.60 g, E = 1.28 g, F = 0.32 g ii 0.02 moles iii 0.02 moles iv 1 mole v CuO vicopper(ii) oxide + hydrogen → copper + water CuO + H2 → Cu + H2O C6.05 a 0.02 moles c 0.07 moles b 2 moles C6.06 a 36 000 cm3 c 12 000 cm3 b 1440 cm3 C6.07 a 2 mol/dm3 b 0.2 mol/dm3 c 1 mol/dm3 d 0.8 g of NaOH = 0.2 moles; 0.2 mol/dm3 Chapter C7 How far? How fast? C7.09 A catalyst is a substance that speeds up a chemical reaction but is not itself used up in the course of the reaction. C7.10 a biological catalyst C7.11 manganese(iv) oxide C7.12 a iron b vanadium(v) oxide C7.13 changes in temperature and pH C7.14 The presence of a catalyst decreases the activation energy of reaction. C7.15 a An increased temperature means that the particles are moving faster and will therefore collide more frequently; when they collide, more particles will have energy greater than the activation energy so there will be more collisions that result in a reaction. b There will be more surface area of the solid exposed to the reactant and therefore more frequent collisions. c Greater concentration means there are more reactant molecules present and so there will be a greater frequency of collision. C7.16 white to blue C7.17 the presence of water Chapter C8 Patterns and properties of metals C7.01 endothermic C8.01 They are soft and have a low density. C7.02 endothermic C8.02 Sodium gives a yellow flame, potassium a lilac flame. C7.03 Polystyrene is a good insulator (and absorbs very little heat itself). C8.03 hydrogen C8.04 potassium hydroxide C8.05 sodium + water → sodium hydroxide + hydrogen 12 Cambridge IGCSE Combined and Co-ordinated Sciences C8.06 2K + 2H2O → 2KOH + H2 C8.07 lithium C8.08 It is strong but light and it does not corrode. C9.12 by reacting methane gas with steam C8.09 It is more reactive than carbon (so its oxide cannot be reduced by carbon). C9.13 an iron catalyst, a moderately high temperature (450 °C) and a high pressure (200 atmospheres) C8.10 A thin layer of aluminium oxide forms on the surface of the metal and sticks to it, giving it a protective coating; with iron, the oxide forms but flakes off and so does not protect the metal. C9.14 so that they react the second time around (saves producing more raw materials) C8.11 They are strong and dense, have high melting points, their compounds are often coloured, they can show more than one valency, they or their compounds often act as catalysts (any three). C9.16 They are washed off fields by rain and end up in streams and rivers. C8.12 2 and 3 C8.13 blue C8.14 (hydrated) iron(iii) oxide, Fe2O3 C8.15 the Haber process C8.16 zinc + hydrochloric acid → zinc chloride + hydrogen C8.17 copper 13 C9.11 because it forms an oxide layer which prevents any further reaction with oxygen (corrosion) C8.18 magnesium + copper(ii) sulfate → magnesium sulfate + copper C8.19 A brown deposit is formed and the blue colour of the solution fades to colourless. C8.20 Mg + CuSO4 → MgSO4 + Cu Mg(s) + Cu2+(aq) → Mg2+(aq) + Cu(s) Chapter C9 Industrial inorganic chemistry C9.01 to combine with the silicon dioxide (sand) and remove it as slag C9.02 Fe2O3 + 3CO → 2Fe + 3CO2 C9.03 oxygen C9.04 to make an alloy which doesn’t corrode (stainless steel) C9.05 water and oxygen (air) C9.06 It can be used to coat iron (galvanisation) or can be attached to iron as blocks (cathodic protection). C9.15 because these are the three elements needed by plants which can become used up in soil C9.17 S + O2 → SO2 C9.18 a catalyst (vanadium(v) oxide) and a temperature of around 450 °C C9.19 because the reaction is too violent: a mist of sulfuric acid is formed which is very dangerous C9.20 a concentrated solution of sodium chloride in water C9.21 It converts a cheap raw material (common salt) into three important chemicals: chlorine, hydrogen and sodium hydroxide. There are no waste products. C9.22 to neutralise acidity in the water C9.23 to remove silicon dioxide (sand) from the iron ore C9.24 CaCO3 → CaO + CO2 C9.25 Ca(OH)2 C9.26 treating soil to remove excess acidity; removing impurities from iron during the basic oxygen steel making process C9.27 because it is quick to recycle, and ‘new’ aluminium is very expensive to produce C9.28 conserving non-renewable resources such as metal ores; avoiding dumping waste in landfill Chapter C10 Organic chemistry C10.01 covalent C10.02 4 C9.07 because of the high cost of electricity, which is needed in large quantities C10.03 diamond and graphite C9.08 because this makes the temperature needed to melt the aluminium oxide much lower C10.05 methane, ethane, propane, butane, pentane, hexane CH4, C2H6, C3H8, C4H10, C5H12, C6H14 C9.09 because the oxygen produced at the anode causes them to burn away C9.10 Al3+ + 3e– → Al C10.04 proteins, carbohydrates, nucleic acids (any two) Answers to questions C10.06 H H C C10.17 C2H4Br2 H H H H H H C C C C H H H H H methane butane H Br Br H Boiling point / °C C10.07 C C H H H 100 C10.18 ethene + hydrogen → ethane C2H4 + H2 → C2H6 50 C10.19 finely divided nickel C10.20 a propene + hydrogen → propane 0 b C4H8 + H2O → C4H9OH –50 C10.21 methanol, ethanol, propanol –100 C10.22 ethene + steam → ethanol C2H4 + H2O → C2H5OH –150 C10.23 yeast, carbohydrate source, water 1 2 4 3 5 6 Number of carbon atoms The graph shows a smooth curve with a steady, but decreasing, change in boiling point as the hydrocarbon chain gets longer. C10.08 ethane + oxygen → carbon dioxide + water C10.09 natural gas C10.10 C10.24 a carbon dioxide b It is an air-lock – allowing the carbon dioxide to escape but not allowing air/bacteria in. c yeast d at around 37 °C e This is the temperature favoured by the yeast, which are living organisms. C10.25 a H H H C O H H H H C H methanol C10.11 ethene, propene, butene C2H4, C3H6, C4H8 H H C C H H H H H C C H ethene H H H O H ethanol H C11.01 refinery gas, petrol (gasoline), naphtha, kerosene (paraffin), diesel, bitumen C10.14 bromine + ethene → 1,2-dibromoethane H C C Chapter C11 Petrochemicals and polymers propene H C 14 H C C10.13 The bromine water is decolorised from brown to colourless. C10.15 H b A homologous series of compounds is a family of organic compounds that have the same general formula, similar chemical properties and a gradual trend in their physical properties. H C10.12 H C H C10.16 a propane + oxygen → carbon dioxide + water b C3H8 + 5O2 → 3CO2 + 4H2O C11.02 coal, natural gas, petroleum (crude oil) C11.03 Cracking is the thermal decomposition of a longchain alkane to a shorter-chain alkane and an alkene (or hydrogen). decane → octane + ethene C10H22 → C8H18 + C2H4 C11.04 road surfacing, ships’ engines, car engines, aircraft fuel (domestic heating) C11.05 C2H4 H H C C H H H ethene H H C C H propene H C H Cambridge IGCSE Combined and Co-ordinated Sciences C11.06 Addition polymerisation takes place when many molecules of an unsaturated monomer join together to form a long-chain polymer. H H n C b heat, catalyst H H C11.07 a high pressure C H H C C H CH3 H H C C H Cl H H C C H H P1.02 1968 cm3 P1.03 a 0.71 mm b 158 mm3 n P1.04 18 cm3 P1.05 13.2 g/cm3 P1.06 7.6 g/cm3 P1.07 80 cm3; 7.75 g/cm3 P1.08 0.04 s P1.09 0.87 s; 0.864 s C11.09 a crates/plastic rope Chapter P2 Describing motion b insulation/pipes P2.01 inches per minute non-stick pans/gear wheels P2.02 s/m, ms C11.10 The monomers join together by a reaction in which a small molecule (usually water) is eliminated each time a link is made. P2.03 a fastest: C b slowest: B P2.04 250 m/s C11.11 a the amide link (or peptide link) b ... O O C C N N H H O O C C P2.05 75 km/h N N H H ... Chapter C12 Chemical analysis and investigation P2.06 1728 000 km P2.07 3.33 h (3 h 20 min) P2.08 Distance C12.01 because their hydroxides are insoluble and form as precipitates C12.02 aluminium and zinc hydroxides C12.03 because iron has two different oxidation states (iron(ii) and iron(iii)) C12.04 carbon dioxide Time P2.09 C12.05 silver nitrate C12.06 nitric acid C12.07 oxygen Speed 15 Chapter P1 Making measurements P1.01 3.23 mm C11.08 tetrafluoroethene c Physics C12.08 the ammonium ion C12.09 a D c A b E d C C12.10 Add bromine water: it turns from brown to colourless. C12.11 the amount of water, the amount of fuel used, or the time it was used for C12.12 substance, appearance before heating, appearance during heating, appearance after cooling Time P2.10 a A, C, G c E b d F B, D Answers to questions 10 P3.04 a 900 N 8 P3.05 1500 N Speed / m/s P2.11 a, b 6 P2.12 P3.07 25 m/s2 2 P3.08 800 kg 0 1 2 3 4 5 6 Time / s 7 8 9 Chapter P4 Turning effects of forces 45 m P4.01 force F3 at end; it is at 90° to trapdoor and furthest from the pivot 50 P4.02 The force of the wind has a greater turning effect on a tall tree. Distance / km 40 30 P4.03 X = 1000 N; Y = 1400 N 20 P4.04 Z = 90 N; 1.50 m 10 0 10 P4.05 a This is to lower their centre of mass. 10 0 20 30 40 50 Time / min 60 b The block on the arm is there to balance the load. The blocks at the base are to lower its centre of gravity, broaden its base and make it more stable. 70 32 km/h P2.13 km/s P4.06 a The forces are equal and along the same straight line, so there is no moment. P2.14 1.5 m/s2 P2.15 0.20 m/s2 b No, because there is an unbalanced force to the right. P2.16 a c Speed / m/s 20 15 10 0 The cyclist is unstable, because the forces are not balanced. Chapter P5 Forces and matter 5 P5.01 22.0 cm 0 5 10 Time / s 15 20 b 2.5 m/s2 c 280 m Chapter P3 Forces and motion P3.01 a accelerate to right b slow down / accelerate to left c change direction P3.02 a i unbalanced ii 20 N to right iii accelerate to right b i balanced ii no resultant force iii no acceleration c i unbalanced ii 50 N downwards iii accelerate downwards P3.03 a mass = 1 kg; weight is less than 10 N b mass = 1 kg; weight is greater than 10 N P5.02 Load / N 0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 Length / mm 50 54 58 62 66 70 73 75 76 Extension / mm 0 4 8 12 16 20 23 25 26 3 4 5 Load / N 8 30 Extension / mm c 333 N P3.06 2.0 N 4 0 b 25 20 15 10 5 0 0 1 2 6 7 16 Cambridge IGCSE Combined and Co-ordinated Sciences P5.03 7.5 N P6.12 60% P5.04 24 N P6.13 25% 120 100 80 60 40 20 0 P6.14 200 J limit of proportionality P6.15 a decreasing b constant c increasing Extension / mm P5.05 P6.16 1000 J 0 1 2 3 4 5 6 7 8 9 10 11 12 Load / N load at the limit of proportionality = 8.0 N F P5.06 p = A P5.07 pascal, Pa P5.08 100 N on 1 cm 2 P5.10 600 000 N 27 600 N c 9200 Pa Chapter P6 Energy transformations and energy transfers P6.01 kinetic energy 17 P6.02 thermal (heat) energy, light energy P6.03 elastic potential energy P6.04 gravitational potential energy; raise it upwards P6.05 loudspeaker, buzzer, and so on P6.06 light, sound, heat P6.07 P6.18 speed P6.19 0.5 J P6.20 2560 J P6.21 wasp Chapter P7 Energy resources P5.09 20 000 Pa P5.11 a 3.0 m3 b P6.17 100 m P7.01 Both are variable (more wind and waves some days than others). P7.02 light energy → electrical energy (+ heat) P7.03 k.e. and g.p.e. P7.04 a coal, oil, gas b wood, charcoal, peat (also straw and others) P7.05 chemical energy → heat (+ light) P7.06 Nuclear energy is converted to heat energy and electrical energy. P7.07 a non-renewable – because uranium is used up b renewable – because new waves appear every day P7.08 uranium (nuclear fuel), geothermal energy, tidal energy Energy stores Example kinetic energy moving car gravitational potential energy water in cloud chemical energy petrol nuclear energy uranium P8.02 gravity strain energy wound-up clockwork toy P8.03 joule (J) P8.04 0.50 MJ internal energy hot water bottle P8.05 a 1.0 J Chapter P8 Work and power P8.01 15 kg of feathers b P6.08 a chemical energy of fuel → internal energy of room and water b electrical energy → light and heat c electrical energy → heat, k.e. and sound P8.06 500 N through 10 m P6.09 a 100 J b 90 J P6.10 a heat b P8.09 a 1000 sound P6.11 harms the environment; wastes limited resources; costs money 10 J P8.07 none – it is not moving P8.08 lift more bricks at a time (greater force); lift them faster P8.10 40 J/s P8.11 100 W P8.12 increased b 1 000 000 Answers to questions Chapter P9 The kinetic model of matter Chapter P10 Thermal properties of matter P9.01 A liquid takes up the shape of a container without its volume changing. P10.01 P9.02 boiling point (or condensing point) P9.03 a solidification or freezing b freezing point or melting point P9.04 a Water is becoming hotter. b Water and steam are present. P9.05 Air is a mixture, so it does not have fixed melting and boiling points. P9.06 a because the particles are moving (they have kinetic energy) b gas P9.07 a solid b gas P9.08 Air is a gas and water is a liquid. In these states, the particles can move past each other, so we can push past them. In a solid, such as a wall, particles are in fixed positions, so that we cannot push them apart. P9.09 a Water molecules are too small to see. b It was constantly jostled by molecules of the water. P9.10 Forces between tungsten atoms are stronger than forces between iron atoms. P9.11 a It is melting. b Energy is required to break bonds between particles (it increases their potential energy). P9.12 The pressure will increase because the force of the molecules on the walls of the container will be greater (and collisions will be more frequent). P9.13 a halved b halved c remains the same P9.14 a The cold water gets hotter and expands. As its volume increases, it pushes further up the tube. b Set up two identical flasks, one with water, the other with paraffin. Add a thermometer to each. Place both in a hot water bath. Record the level of the liquid in the tube as the temperature increases. P10.02 a The 2 kg of water at 30 °C has twice as much internal energy as 1 kg. The internal energy of the water is made up of the energies of all the molecules. There are twice as many molecules in 2 kg. b The temperature is the same (because the average energy of a molecule is the same in each bucket). c The average energy per molecule is the same, as they are at the same temperature. P10.03 0 °C = melting point of pure ice 100 °C = boiling point of pure water P10.04 Place thermometer in pure melting ice and mark 0 °C. Place in pure boiling water and mark 100 °C. Divide the scale between these two into 100 equal units. P10.05 As the temperature rises, the air in the flask expands and pushes downwards, so that the water level drops. P10.06 a approximately 40 to 50 °C b At 20 °C, the resistance changes only a little for each degree change in temperature. It changes more rapidly around 50 °C. P10.07 The temperature-sensitive junction of the thermocouple is very small and can heat up or cool down more rapidly than the bulb of a mercury thermometer. Chapter P11 Thermal (heat) energy transfers P11.01 a copper, steel, other metals b air, wood, plastic, glass P11.02 a temperature difference P11.03 marble (it has a greater thermal conductivity) volume doubled The volume is doubled but the number of particles remains the same, so their collisions with the walls are half as frequent. P9.15 Decrease the temperature so that the particles move more slowly. Then they will collide with the walls with less force, and less frequently. P11.04 convection P11.05 a Particles of hot gas move faster. b Particles of hot gas are further apart. P11.06 When a fluid is heated, its expansion causes its density to decrease. It rises because it is less dense than the surrounding air. Cooler, denser air sinks as a result of the pull of gravity. 18 Cambridge IGCSE Combined and Co-ordinated Sciences P11.07 Warm air rises above the heater, and moves around the room. Cold air flows in to replace it and so is heated. P12.09 period T P11.08 No convection current would be established because the air heated by the heater cannot rise. P11.09 radiation P11.10 infrared, ultraviolet P11.11 The rate of infrared emission increases. P12.10 a A has the greater frequency. P11.12 a Matt black is a better absorber. b Matt black is a better emitter. c Shiny black is a better reflector. b A will sound more high-pitched. P11.13 Lids reduce heat loss by convection. Wooden or plastic surfaces reduce heat loss by conduction. P11.14 19 Feature Reduces Reduces Reduces conduction? convection? radiation? double glazing yes yes yes (if coated) cavity wall insulation yes yes yes carpet, underfloor insulation yes no no draught excluders no yes no curtains yes yes no loft insulation (with shiny foil) yes yes yes P12.11 Sound waves travel by the vibration of the particles of a material. There are no particles in a vacuum. P12.12 (for example) shout from outside a closed window P12.13 In a compression, the particles are closer together than before the wave is formed. In a rarefaction, the particles are further apart. See Figure P12.05 in the main text. Chapter P13 Light P13.01 a b This is so that it looks the right way round in a motorist’s rear-view mirror. P13.02 a normal mirror angle of incidence i P11.15 Heat is lost from head by convection, and a hat greatly reduces this. Chapter P12 Sound P12.01 all three P12.02 the air in the hollow tube P12.03 a 600 ms = 0.6 s b three-fifths P12.04 They must be in a straight line so that the distance travelled in the time interval measured is equal to the separation of the microphones. P12.05 Light travels faster than sound. For example, lightning is seen before thunder is heard. P12.08 a 20 Hz to 20 kHz b upper limit in particular decreases reflected ray incident ray b angle of incidence = angle of reflection P13.03 60° P13.04 No light reaches the place at which the image appears to be formed. P13.05 refracted ray angle of refraction glass air angle of incidence P12.06 pitch gets higher P12.07 loudness decreases angle of reflection r incident ray normal Answers to questions P13.06 towards the normal P13.21 P13.07 a TIR TIR TIR TIR P13.22 Light travelling along the glass will be absorbed by any impurities present. P13.23 b It is parallel to its initial direction. P13.08 a angle of incidence = 0° b angle of refraction = 0° P13.09 The angle of refraction is less than the angle of incidence. converging P13.24 parallel rays diverging focus P13.10 Rays of light are refracted as they pass through the raindrops. P13.11 2.4 P13.12 a Light travels more slowly in material B, because the ray bends more on entering B. b material B P13.13 a glass b away from the normal P13.26 It is the point at which rays travelling parallel to the axis of the lens are made to converge. P13.14 1.58 P13.15 2.17 × 108 m/s P13.16 25.4° P13.17 total: 100% of the light is reflected internal: reflection happens inside the transparent material P13.18 No, it will not be totally internally reflected because 45° is less than the critical angle. P13.19 a c = 48.8° b See Figure P13.05c in the main text. F P13.27 Light rays pass through the point at which a real image is formed, and it can be formed on a screen. For a virtual image, the rays only appear to emerge from that point, and the image cannot be formed on a screen. P13.28 The image arrow is below the axis. P13.29 The rays from the image are dashed. They only appear to be diverging from that point. P13.30 a See ray diagram below. b 7.5 cm P13.20 n = 1.56 I P13.25 Reverse the arrow on the rays so that they spread out from the focus. O F 20 Cambridge IGCSE Combined and Co-ordinated Sciences Chapter P14 Properties of waves P14.17 P14.01 The first has distance on its horizontal axis, and the second has time on its horizontal axis. Displacement P14.02 amplitude Distance or Time Chapter P15 Spectra P15.01 yellow, blue The diagram should show that amplitude is the height of a wave crest above the central (undisturbed) level. P15.02 spectrum P14.03 Measure across, say, 10 ripples and find the average separation by dividing by 10. P14.04 1.5 cm (or 15 mm) P14.05 a 100 Hz b 0.01 s P14.06 The molecules vibrate up and down. P14.07 longitudinal 21 red white light prism violet orange yellow green blue indigo P15.03 Some colours of light are more strongly refracted because their speed decreases more. P15.04 a red light b violet light P15.05 a infrared b red light P14.08 v = f l (speed v in m/s, frequency f in Hz, wavelength l in m) P15.06 a gamma rays P14.09 300 m/s P15.07 a Both violet light and red light travel equally fast in empty space. P14.10 wavelength 1 m has higher frequency P14.11 frequency 90 MHz has longer wavelength P14.12 a speed decreases b wavelength decreases c frequency is unchanged P14.13 reflected waves b radio waves b Red light travels faster in glass. P15.08 infrared radiation, microwaves P15.09 Microwaves may transfer signals to and from satellite; radio waves are broadcast, and received by an aerial; remote control uses infrared. Chapter P16 Magnetism P16.01 a incident waves barrier P14.14 Change the depth of the water – shallower water gives slower ripple speed. P14.15 Diffraction – ripples spread out into the space beyond the gap. P14.16 For greatest diffraction effect, the width of the gap should be equal to the wavelength of the waves. N S S N Adjacent N and S poles attract one another with equal forces. b N N S S The adjacent N poles and the adjacent S poles repel one another with equal forces. Answers to questions P16.02 a Soft magnetic materials are easier to magnetise and demagnetise. Hard magnetic materials are more difficult to magnetise and also more difficult to demagnetise. b A permanent magnet made of steel will retain its magnetism for a longer time. P17.04 rod positive charges attracted to rod paper P16.03 negative charges repelled by rod N S S P17.05 a negative b repel N P16.04 Copper and iron are mixed together. Pass the electromagnet over the mixture of metal. Because copper is not magnetic, the electromagnet will attract only the iron, pulling it out of the mixture. P16.05 a P17.06 The electric force causes the negative charges (electrons) to repel each other. As a result, some of them move through the wire to the other sphere, so that it gains a negative charge. (The charge on the first sphere decreases.) Chapter P18 Electrical quantities P18.01 a ammeter b connected in series c A P18.02 a, b N S current in 22 A A current out c Ammeter readings are the same. P18.03 a (for example) copper, gold, silver b (for example) glass, Perspex, polythene b When the current is reversed, the field is reversed, so the arrows on the field lines are reversed. Chapter P17 Electric charge P17.01 repel P17.02 a positive (and equal in size to the negative charge on the rod) b attract P17.03 Individual hairs all have the same charge, so they repel. Hair and comb have opposite charges, so they attract. P18.04 a ampere, amp (A) b coulomb (C) P18.05 a 1000 b 1 000 000 P18.06 1 A = 1 C/s P18.07 20 A P18.08 40 C P18.09 a potential difference b volt (V) c voltmeter d V Cambridge IGCSE Combined and Co-ordinated Sciences P18.10 a e.m.f. (electro-motive force) b volt (V) P18.11 a 6.0 Ω P19.08 4 b increase b 30 V P18.12 20 V P18.13 a 10 Ω P19.07 90 Ω P18.14 14.5 mA (0.0145 A) P18.15 a longer wire has greater resistance b P19.09 A long wire is like two or more short wires connected in series. Their resistances add up to give the combined resistance. P19.10 A thick wire is like two or more thin wires connected in parallel. Their effective resistance is less than that of an individual wire. P19.11 a 0.50 A A wire b The 20 Ω resistor has the greater p.d. across it. P19.12 20 Ω P19.13 20 Ω V P18.16 a 80 Ω b 160 Ω P18.17 The graph is a straight line through the origin. P18.18 The graph is curved; twice the p.d. gives less than twice the current. P18.19 watts = volts × amps 23 P18.20 50 W P18.21 2.5 A P19.14 5 A; slightly above normal current P19.15 a To protect the wiring of the circuits; if an excessive current flows, the fuse blows and breaks the circuit. b An electromagnetic trip switch could be used instead. P19.16 Heating of wires, leading to melting of insulation (poisonous fumes, possibility of fire) and possible short-circuit between wires. P18.22 2640 J Chapter P20 Electromagnetic circuits Chapter P19 Electric circuits P20.02 The field lines are further apart. P19.01 a P20.01 clockwise P20.03 It would rotate in the opposite direction because its poles would be attracted the opposite way round. b P19.02 1.4 V P19.03 a light-dependent resistor P20.04 a If the current was not reversed, the coil would turn until its poles were facing their opposites and then stop turning. b The commutator reverses the current. b P20.05 A greater current gives a greater turning effect. c Its resistance decreases when light shines on it. P20.06 reverse the current; reverse the magnetic field P20.07 force (motion) – thumb magnetic field – first finger P19.04 a current – second finger b used in temperature sensing circuit c Its resistance changes rapidly when temperature changes a little. P19.05 40 Ω P19.06 The same current (1.4 A) flows through resistors B and C. P20.08 increase the current; increase the magnetic field strength P20.09 zero force Answers to questions Chapter P21 Electromagnetic induction P21.01 a heat electrical energy b k.e. P22.07 a The number of protons is the same (and the number of electrons in a neutral atom). b number of neutrons P22.08 a heat k.e. electrical energy P21.02 The wire or magnet must move. P21.03 move the N pole out of the coil; move the S pole towards the coil P21.04 Move the magnet faster; use a stronger magnet. P21.05 bigger coil; more turns; stronger magnetic field; faster movement P21.06 so that less energy is lost during transmission P21.07 primary coil; secondary coil; core P21.08 step-up P21.09 step-down P21.10 2.5 P21.11 100 P21.12 a The core transfers the varying magnetic field from the primary coil to the secondary. b Its magnetism must change rapidly. P21.13 The magnetic field in the core does not change, so no e.m.f. will be induced in the secondary coil. P21.14 current is less P21.15 a 400 kV b 250 A c 1.5 MW P21.16 a 157 b 1.53 A c No power is lost in the transformer. Chapter P22 Atomic physics P22.01 a protons, neutrons b electrons P22.02 There is electrostatic attraction between opposite charges. P22.03 a nucleon number = 17 b proton number = 8 P22.04 210 82 Pb P22.05 47 protons, 60 neutrons, 47 electrons P22.06 1840 approximately Nuclide Proton number, Z Nu-1 6 Nu-2 7 Nu-3 7 Nu-4 6 Nu-5 5 Nu-6 6 Neutron number, N 6 6 7 8 6 7 Nucleon number, A 12 13 14 14 11 13 b Nu-1, Nu-4, Nu-6 c Nu-2, Nu-3 d boron (B), carbon (C), nitrogen (N) P22.09 radon and thoron gases in atmosphere P22.10 There is less atmosphere above them to absorb cosmic rays from space. P22.11 15% approximately P22.12 (for example) medical, weapons fallout, air travel, TV sets, working with radioactive materials, nuclear discharges P22.13 Geiger counter, photographic film P22.14 a a b b P22.15 electron P22.16 g P22.17 a g a b P22.18 a, b, g, X-rays P22.19 g-rays are uncharged. P22.20 a a b It is most easily absorbed. P22.21 a 210 206 4 Po → 82Pb + 2He + energy 84 b 84 = 82 + 2 c 210 = 206 + 4 P22.22 average (… the average time taken …) P22.23 25 P22.24 55 P22.25 6000 years P22.26 b-radiation is less easily absorbed than a-radiation. P22.27 The radiation must penetrate thick metal. a- and b-radiation would be completely absorbed. P22.28 The plastic is too thin to absorb the g-radiation used. P22.29 The radiation must penetrate the ground to reach the surface if it is to be detected. 24