Unit 1.1 Solids, liquids and gases 1-4 DDBD 5. 6. 7. (a) (b) (ii) increasing the temperature increases the volume/volume proportional to temperature Unit 1.2 Using the kinetic particle theory 1-4 BDCA 5. 6. (C) 7. (a) (b) (c) Unit 1.3 Heating and cooling curves6 1-2 DD 3. (b) (d)tick D-E (e) 4. Unit 1.4 Solvents, solutes and solutions 1-3 CDB 4. anhydrous---a substance which does not contain water of crystallization hydrated---a substance which contains water of crystallization solute---a substance which dissolves in a solvent solvent---a substance which dissolves a solid, liquid or gas 5. (a) solute (b) (i) anhydrous copper(II) sulfate (ii) white, blue (iii) Unit 1.5 Diffusion 1-5 CCDDD 6-9 BCDC 10. 11. Unit 2.1 Apparatus for measuring 1-5 CCDDD 6-8 BDC 9. Unit 2.2 Paper Chromatography 1-5 CADDB 6. 7. (a) chromatography (b) Unit 2.3 Is that chemical pure? 1-6 BADCBB 7. (b) Unit 2.4 Separation and Purification 1-8 BDBBCCCD 9. 10. Unit 2.5 More about separation and purification 1-6 DCADBD 7. 8. 9. 10. A-3 B-5 C-6 D-1 E-4 F-2 3.1 Inside the atom 1-6 BCCDDC 7. 8 (IV) (V) 3.2 Isotopes 1-5 BABADD 7. 8. (a) 3.3 Electronic structure 1-5 DACAA 6-10 BBCAD 11. 12. 2,2 3.4 Elements, compounds and mixtures 1-4 ACCC 5. (a) (iii) (b) 6. (i) element (ii) compound (iii) mixture (iv) element 3.5 Metals and non-metals 1-5 ADCAC 6. 7. (a) iron (b) mercury (c) oxygen Unit 4.1 Ions (1) 1-9 DCDBA CDAB 10. 11. 12. a. charged b. protons and electrons- 13. = 14. Unit 4.1 Ionic bond (2) 1-7 CBACBCB 8. 9. Unit 4.2 covalent bond (1) simple molecules 1-8 DABC BCDC 10. GR,Y8V 11. Unit 4.3 covalent bond (2): more complex molecules 1-3 BCA Unit 4.4 Ionic or simple molecular? 1-9 AABCC AABC 10. 11. 12. 13. 14. Unit 4.5 giant covalent structure 1-5 CDDAB 6. 7. 8. 9. Unit 4.6 Bonding in metals 1-7 DDAA BCA 8. √√×√ 9. 10. Unit 5.1 Naming compounds 1. D 2. 3. (a) (i) calcium sulfate (ii) ammonium sulfate (iii) sodium nitrate (iv) potassium bromide (v) iodide (vi) ammonium chloride 4. Unit 5.2 Chemical formula 1-5 BDABA 6. 7. (a) GaCl3 Ga2(SO4)3 Cr2(SO4)3 Ba(OH)2 (b) NO2 + (c) NH4 PH4I (d) Ca3(PO4)2 (e) 5. ZnI2 BeCl2 ReCl3 Unit 5.3 Chemical Equations 1-8 ADCCD ABB 9. (a) 6 3 2 (e) (i) 2 2 (b) 2 (ii) 4 2 2 (c) 2 Br 2 (d) 6 (iii) 5 6 (iv) 2 2 (v) 2 3 (vi) 4 Unit 5.4 Ionic equations and state symbols - - 1. (a) Cl2(aq) + 2Br (aq) → Br2(aq) + 2Cl (aq) 2+ - (b) Fe (aq) + 2OH (aq) → Fe(OH)2(s) + 2+ (c) Mg(s) + 2H (aq) → Mg (aq) + H2(g) + - (d) Ag (aq) + Br (aq) → AgBr(s) 2. equation, ions, precipitate, reaction, spectator 3. (a) 2Na(s) + 2H2O(l) → 2NaOH(aq) + H2(g) (b) (i) AgNO3(aq) + NaCl(aq) → AgCl(s) + NaNO3(aq) + - (ii) Ag (aq) + Cl (aq) → AgCl(s) 2 Unit 6.1 Masses and molecules 1-3 CCD 4. (a) (b) (c) (d) (e) 5. (a) 331 (b) 23 (c) 3.01 × 10 Unit 6.2 Chemical calculations and the mole 1-9 DBCCC CDCB 10. v (c) Unit 6.3 More Chemical calculations 1-8 CBDBC CBD 9. mass of oxygen formed: 0.02 × 32 = 0.64 g (b) (c) 10. Unit 6.4 Limiting reagent 1. C 2. (a) (b) Unit 6.5 Gas volume calculations 1-8 ADBBC CCB 9. 10. Unit 6.6 Yield and purity 1-3 CCA 4. 5. Unit 6.7 Empirical and molecular formula 1-4 ADDB 5. 6. 7. Unit 6.8 Titrations 1-8 BBDCB AAA 9. 10. 11. Unit 7.1 Conductors and insulators 1-6 ACBABC 7. (b) Unit 7.2 The products of electrolysis 1-5 ACCCD 6. 7. (iii) platinum 8. 9. Unit 7.3 Electrolysis of aqueous solution 1-2 B D 4. (a) (b) 5. Unit 7.4 Explaining electrolysis 1-8 CBACCDBA 9. 10. 11. 12. Unit 7.5 Purifying copper 1-6 CADABD 7. (a) (b) 8. (a) (b) Unit 7.6 Electroplating 1-7 ADDAD CA 8. 9. Unit 7.7 Extracting aluminium 1-6 CDABDD 7. (i) (ii) (iii) 8. (e) (f) Unit 8.1 Energy transfer in chemical reactions 1-5 DCCCA 6-11 CACCCA 12. Absorb heat/thermal energy from the surroundings Release heat/thermal energy to the surroundings Unit 8.2 Reactions pathway diagrams 1-5 ABACC 6. (b) (c)(i) (ii) Unit 8.3 Reactions pathway diagrams 1-8 CADBA ADA 9. 10. Unit 8.4 Fuels and energy production 1-8 DDCBD CBC 9. 10. Unit 8.5 Fuels cells 1-7 BCBDDCD 8. Unit 9.1 Investigating rate of reaction 1-4 CDCB 7. 8. 9. 10. ttt Unit 9.3 Interpreting data 1. C 2. 336s 3. Unit 9.4 Surfaces and reaction rate 1-4 BDBA 5. 6. 7. Unit 9.5 Concentration and rate of reaction 1-3 DAD 4. 5. Unit 9.6 Concentration and rate of reaction 1-5 A D D B B 10. 11. 6-9 D A D A Unit 10.2 Shifting the equilibrium 1-10 DCACD BBBBD Unit 10.3 Redox reaction 1-5 DCBAC 6-9 CABC Structured Questions 1. (b) (b) (c) (d) 2. 3. Unit 10.4 More about redox reaction 1-6 BDAAAC 7. (i) (ii) (iii) (iv) (v) Potassium manganate change from purple to colourless 2+ 8. (a) (i) Fe → Fe because it lose electrons (ii) Fe Unit 11.1 How acidic? 1-5 BADBD 6. Unit 11.2 Properties of acids 1-5 BCBCD 6-11 DBDBBD 12. 13. (a) (b) (c) sodium sulfate (d) water (e) Unit 11.3 Bases 1-5 BAABA 6-9 CBAC 10. (c)(iii) calcium chloride, water, carbon dioxide Unit 11.4 More about acids and bases 1-5 CCDDD 6. (a)(i) proton donor (b)(i) (b)(ii) 7. 8. Unit 11.5 Acid-base titrations Unit 11.6 Oxides 1-5 CCCCB 6-10 BCBCA 11. (a) (b) (b) (c) 12. 13. Unit 12.1 Making salts from metals, bases or carbonates 1-6 DCBCC D 7. (a) (b) (c) (d) (e) (f) 8. 9. Unit 12.2 Making salts (2) titration 1. C 2. 3. (a) (i) burette (ii) neutralization (iii) indicator 4. Unit 12.3 Making salts (3) precipitation 1-5 ADDAA 6-7 CC 8. 9. 10. 11. Unit 12.4 What’s the gas? 1-5 AACCB 6-8 BBC 9. 10. Unit 12.5 Testing for cations 1-5 DBCCA 6. (a) (b) (c) (d) Unit 12.6 Testing for anions 1-7 DCBDCAD 8. 9. 10. Unit 13.1 The Periodic Table 1-5 BDBAC 6-10 BCACA 11. 12. Unit 13.2 The Group I metals Element Li Na K Rb Cs Name Density Trends down the group Melting point Hardness Reactivity lithium sodium potassium rubidium caesium Increase down the group decrease down the group softer down the group Increase down the group 2-8 CDACAAB 9. Unit 13.3 The Group VII elements 1. elements State at r.t.p. Colour Colour at r.t.p. of gases F2 gas yellow / / Cl2 gas green / / Br2 liquid brown orange I2 solid redbrown black purple brown 2-6 CDACB 7-10 CCDB 11. Colour of aqueous Trends down the group colour Density Melting Reactivi point ty darker increase increase decreas e (c)(ii) chlorine bromine iodine aqueous potassium chloride aqueous potassium bromide aqueous potassium iodide × √ √ × × √ × × × Unit 13.4 Group VII: the noble gases 1. 2-8 CDD DC 9. DD Unit 13.5 The transition metals 1. Physical properties 1. shiny 2. Malleable/ductile 3. conduct electricity 4. high melting point 5. high density 2-9 ACBBCDAD 10. (a) (c) (d) 9. Chemical properties 1. many transition elements and transition element oxides are good catalysts. 2. They are less reactive than metals from other groups. 3. they have more than one oxidation number in compounds. (g) Copper Unit 14.1 The metal reactivity series 1-5 AACDD 6-8 DCA 9. (b) (i) Ca + 2H2O → Ca(OH)2 + H2 10. (a) (b) 11. Unit 14.2 Metal oxides and their reduction 1-7 CCCDDDC 8. Unit 14.3 From metal compounds to metals 1-10 CBDCD DDAAA 11. 12. Unit 14.4 More about metal reactivity 1-6 ACDACB 7. 8. 9. Unit 15.1 Extracting iron 1-8 BBAD ADDA 9. 10. 11. Unit 15.2 The rusting of iron 1-9 BCCCA DCDB 10. (iii) (c) (ii) (d) (e) 11. Unit 15.3 Alloys 1-10 BACBD ABDCD 11. 12. (v) Unit 15.4 Use of metals 1-15 CDBCA 16. (a) (b) 17. ADBCA ABBBB (iii) (iv) (v) (vi) Unit 16.1 Making ammonia 1-4 ACAB 1. 2. Unit 16.2 Fertilisers 1-7 ACCCC BA 8. Unit 16.3 Sulfuric acid 1-4 CDDA 1. (iii) (vii) Unit 16.4 Acid rain 1-5 DACBB 6. 7. 8. Unit 18.1 Petroleum 1-9 ADCCC ABDC 10. 11. (vi) (vii) Unit 18.2 Cracking of hydrocarbons 1-7 CBDBC BB 8. (a) (i) (ii) (c) (e) Unit 18.3 Homologous series 1-13 BABBB CBBBC BCC 14. (b) 15. Unit 18.4 Alkanes 1-9 ACADB CACC 10. (iv) 11. (b) 12. (a) Unit 18.5 Alkenes 1-11 BDDCD BBBAD B 12. 13. (e) CH2 (f) C6H12 14. 15. (b) 16. Unit 18.6 Alcohols 1-16