No. 1. 2. Course Information Name and Code of Course: UGPA3143 Petrochemical Processes Synopsis: The course introduces the students to the various process involved in the technology of petrochemicals production, the raw materials used in the composition and processing. The chemical reactions and conversion process that produce the precursors and intermediates for further processing into petrochemicals are outlined. 3. Name(s) of Academic Staff: To be assigned 4. Trimester and Year Offered: 1/3 5. Credit Value: 3 6. Pre-requisite/Co-requisite (if any): None 7. Couse Classification: Core Note: Course Classification as per COPPA 2 standard: Compulsory Course, Core / Major / Specialisation – Course / Project, Optional / Elective Course, Minor Course (if applicable), Industrial Training, Others (Specify). Course Learning Outcomes (CLO): CLO 1 - Demonstrate on a process for chemical transformations to synthesize petrochemical precursor. CLO 2 - Relate the chemical structure of input and output materials for petrochemical processes. CLO3 – Explain the inter-relationship of various chemical processes in a petrochemical refinery. Mapping of the Course Learning Outcomes to the Programme Learning Outcomes, Teaching Methods and Assessment: 8. 9. Programme Learning Outcomes (PLO) Course Learning Outcomes (CLO) P L O 1 P L O 2 P L O 3 P L O 4 CLO 1 Demonstrate on a process for chemical transformations to synthesize petrochemical precursor. P L O 5 CLO 2 - Relate the chemical structure of input and output materials to the transformation petrochemical processes. CLO 3 - Explain the inter-relationship of various chemical processes in a petrochemical refinery. TOTAL 1 1 1 P L O 6 P L O 7 P L O 8 P L O 9 P L O 10 P L O 11 P L O 12 Teaching Methods Assessment Lecture, tutorial &practical Lab Practical / Lab Assignment Lecture & Tutorial Quiz / Test / Final exam Lecture & Tutorial Quiz / Test / Final exam Indicate the primary causal link between the CLO and PLO by ticking “√” the appropriate box. 10. Transferable Skills (if applicable): (Skills learned in the course of study which can be useful and utilized in other settings) Transferable Skills TS 1: Cognitive Skills TS 2: Interpersonal Skills TS 3: Communication Skills TS 4: Digital Skills TS 5: Numeracy Skills TS 6: Leadership, autonomy and responsibilities TS 7: Personal Skills (Life-long learning) TS 8: Entrepreneurial Skills TS 9: Ethics and Professionalism Yes √ No √ √ √ √ √ √ √ √ Note: Yes denotes that this course contributes to the development of the transferable skills. No indicates that this course does not contribute to the development of the transferable skills. 11. Distribution of Student Learning Time (SLT): Teaching and Learning Activities Course Content Outline CLO Guided Learning (F2F) Guided Learning (NF2F) eg: eLearning Independent Learning (NF2F) Total SLT L T P O 1,2,3 6 1 - - - 7 14 1,2,3 4 1 3 - - 8 16 1,2,3 9 1 - - - 10 20 Topic 1: Present status and future trend in Petrochemical industry and its feedstock • Product pattern of paraffins, olefins, dienes and acetylene. • Manufacturing of important paraffins, olefins, acetylene, butadiene, isoprene, oligomers and aromatics • Separation and purification and developments in these areas. • New technology trends in Petrochemicals manufacture. Topic 2: Industrial Catalysis • Catalyst choice • Homogeneous & heterogeneous catalysis • Catalyst design • Shape selective catalyst Topic 3: Production of synthesis gas • Various roots, reactions, mechanisms, conditions, thermodynamics, kinetics, coal gasification and hydrogenation. • Conversion of ethylene to ethylene oxide, ethylene glycol and ethanolamines. • Conversion of propylene to acrylic acid, methyl ethyl ketone and acrylonitrile. • Conversion of butenes to, iso and n-butanols, MIBK, MTBE. • Conversion of aromatics to maleic and phathalic anhydride, DMT, phenol and acetones. • Conversion of cyclohexane to caprolactum, adipic acid, succinic acid etc. Topic 4: Hydration and Esterification • Technologies for the production of alcohols such as ethanol, isobutyl alcohol and higher alcohols. 1,2,3 4 1 3 - - 8 16 1,2,3 9 1 - - - 10 20 1,2,3 4 1 - - - 5 10 • Process for production of few esters such as acrylates, terephalates, esters for flavoring industries, ester synthesis Topic 5: Chlorination, Nitration and Sulphonation • Chlorination of paraffin, olefins and aromatic hydrocarbons and Technologies involved in production of chloromethane, chloroethanes, ethylene chlorides, vinyl chlorides, chlorobenezenes. Benzoylchloride, • Precaution and safety for handling chlorine and fluorine compounds. • Nitrobenzene, Aniline, Nitrotoluenes, nitrochlorobenzenes. • Sulphonation of benzene and discussion in the context of detergent industries Topic 6: Polymerization • Principles and types, control and monitoring of polymerization processes • Technological method for production of:• Rubbers : SBR, isoprene/ neoprene • Resin: Phenol Formaldehyde, melamine formaldehyde. • Fibres: Nylons and polyesters. • Plastics: PE, Polypropylene, PVC Total Notional Hours 36 Continuous Assessment Percentage (%) 40 Lab reports/ Lab Assignment/ Quiz/ Psychomotor practical evaluation/ Test Final Assessment Final Examination 6 6 Percentage (%) 60 - - 48 96 F2F NF2F Total SLT 5 13 18 F2F NF2F 2.5 12.5 GRAND TOTAL SLT Total SLT 15 129 **Please tick (√) if this course is Industrial Training / Clinical Placement / Practicum / WBL using Effective Learning Time(ELT) of 50% L= Lecture; T= Tutorial; P=Practical; O=Others; F2F= Face to Face; NF2F= Non Face to Face 12. Special Requirement or Resources to Deliver the Course (e.g., software, nursery, computer lab, simulation room): None 13. • Main References: 1) S. Matar and L.F. Hatch. (2001). Chemistry of Petrochemical Processes, 2nd Ed., Gulf Publishing Company. 2) I.D. Mall. (2008). Petrochemical Process Technology. 1st Ed., Macmillan, Inc • Additional References: 3) Meyers, Robert A. (2019). Handbook of Petrochemical Production Process New York : McGraw-Hill Education. 14. Other Additional Information: Practical 1 Activity Topic: Preparation of heterogeneous catalyst for methyl ester synthesis Task: To study the physical properties of the prepared heterogeneous catalyst. Resource: Ferric chloride, Titanium dioxide, glycerol, sodium hydroxide, methanol, ethanol, filter paper, heater magnetic stirrer, graduated cylinder, biuret, pipet, filtering set. 2 Topic: Synthesis of Methyl Esters Task: To study the preparation of methyl ester in the presence of a catalyst. Resources: Methanoic acid, acetic acid, propanoic acid, butyric acid, salicylic acid, anthranilic acid, methanol, ethanol, n-propanol, isopropanol, butanol, isopentanol, octanol, concentrated sulfuric acid, baking soda, test tubes, beaker, erlenmeyer flask, condenser with cork fittings, thermometer, beaker, ring and wire gauze, test tube and cork stopper, capillary dropper, boiling stone, distilling flask, clamps, hot plate, beaker, separatory funnel. 15. 16. Date of Senate Approval:05/09/2019 Date of UADCC Approval: 12/05/2021