CORROSION RESISTANT MATERIALS HANDBOOK 4TH ED

CORROSION RESISTANT MATERIALS HANDBOOK Fourth Edition Edited by D.J. De Renzo NOYES DATA Park Ridge, CORPORATION New Jersey, U.S.A. Copyright G 1985 by Noyes Data Corporation No part of this book may be reproduced in any form without permission in writing from the Publisher. Library of Congress Catalog Card Number: 854872 ISBN o-8155-1023-3 Printed in the United States Published in the United States of America Noyes Data Corporation Mill Road, Park Ridge, New Jersey 07656 by 1098765432 Library of Congress Cataloging Main entry under title: Corrosion in Publication Data resistant materials handbook. Rev. ed. of: Corrosion resistant materials handbook I lbert Mellan. 3rd ed. 1976. Includes indexes. 1. Corrosion resistant materials--Handbooks, manuals, etc. I. De Renzo, D.J. II. Mellan, Ibert. Corrosion resistant materials handbook. TA418.75.C67 1985 620.1’1223 85-4872 ISBN o-8155-1023-3 NOTICE To the tained best in publisher for of this does our knowledge publication not is assume the any or product for of any information the use contemplated by any user, and the manner of that use, is the sole responsibility We recommend any recommendation publication and that standards. should of intending materials himself We strongly mentioned recommend manufacturer’s of the to rely on in this as to such suitability, he can meet all applicable safety adhere to the structions that anyone satisfy the whatsoever of such information. of the suitability user. con- however, liability the accuracy or completeness Final determination information accurate; that and health users seek and or supplier’s for handling each material they use. current in- Foreword The fourth edition and vastly ful reference the concerned cially to first engineer available corrosion designers having Corrosion specific published to cut resistant materials and others corrosion The more resistant materials. corrosive substances. Trade The Name various alloys; resins nonferrous mercial engineering from, of The vast amount of contents book cover rubbers and alloys; 13 tables directly or distributors of information and the exhaustive from guide which by choosing suitable It would in choosing revised and success- information application. screening work lies in the extensive tables in the book Index is organized to specific will enable commer- also be useful materials selected for equip- materials the categories corrosive chemicals in the tables. of corrosion cements, and other A separate resistant materials, mortars, and asphalt; and carbon-graphite. A separate anticorrosive essential manufacturers’ by of thousands by types of corrosion Listing are also included. and elastomers; compare cross-indexing are arranged recommendations and glass, ceramics, which and construction taken the makers reader useful a particular Name and Address and polymers; metals a group selections in the for Material the provide has been completely This well-established losses due to corrosion reference Corrosive will data. requirements. 160 detailed It refers sections presents sent The than Handbook technical as a valuable resistance Index and a Company as synthetic Materials in 1966, or manager The great value of this outstanding of substances. Resistant based on the latest available volume, equipment ment of the expanded, merits to industry. literature made of a cross section The tables at no cost section of com- in the book to, nor such ferrous repre- influence of these materials. contained in the book is evidenced at once in the extensive indexes. Advanced composition and production methods developed by Noyes Data Corporation are employed to bring this durably bound book to you in a minimum of time. Special techniques are used to close the gap between “manuscript” and “completed book.” In order to keep the price of the book to a reasonable level, it has been partially reproduced by photo-offset directly from the original material and the cost savings passed on to the reader. Due to this method of publishing, certain portions of the book may be less legible than desired. table Contents SYNTHETIC RESINS AND 1.1 ABS Jackets 1.2 ABS/PVC .1 ................................................ POLYMERS. .I ............................................. and Covers-CEEL-CO 1.4 ................................................ Acetal Copolymers-Celanese Plastics ............................................ Acrylic Resins-Rohm and Haas. ............................................... 1.5 Acrylic 1.6 Cellulose 1.3 Alloys-A. Resin-Sohio Acetates, .2 Schulman .6 .9 ................................................ Chemical. Butyrates, Propionates-Eastman .27 Chlorinated Epoxy Compounds-Devcon 1.9 Epoxy Pipe and Fittings-Ameron 1.10 Epoxy Resin-Duriron 1.11 Epoxy Resins-Shell 1.12 Fiberglass Reinforced Epoxy 1.13 Fiberglass Reinforced Furan 1.14 Fiberglass Reinforced lsophthalic 1.15 1.23 ...................... .................................... Fiberglass Reinforced Polyester Panels-Resolite Fluoropolymer-Allied Engineered Plastics. ........................................ ............................ Furan Resin-Koch Engineering, Maurice A. Knight Division .......................................... lsopolyester Resins-Amoco Chemicals Nylon 6/6 Resins-Celanese Plastics ............................................ .................................................... Nylon 11 Resin-Rilsan .......................... Nylon Reinforced Vinyl Hose-Sethco Division, Met Pro Corp. .............................. Oxirane Oligomer of Resorcinol-Plastonics International 1.24 Phenolic 1.25 1.29 .................................... ........................................ Polyallomer-Eastman Chemical Products .............................................. Polycarbonate-Mobay Chemical ...................................... Polyester Engineering Resin-Dart Industries Polyester Laminates-Haysite Reinforced Plastics ................................... 1.30 Polyether 1.31 Polyethylene-Eastman 1.32 Polyethylene-Himont 1.33 Polyethylene-Lined 1.34 Polyethylene 1.17 1.18 1.19 1.20 1.21 1.22 1.26 1.27 1.28 and Vinyl Polyester Polybutylene .32 .33 .34 .35 .37 Chemical and Vinyl .............. Smith-Inland .39 .......................... Ester-Morrison Molded Fiber Glass. Plastics. Resins-U.S.I. Chemicals. 1.35 Polyethylene Tank 1.36 Polyethylene Terephthalate-Based Material-Nalge. 1.37 Polymethylpentene-Westlake 1.38 Polyphenylene Sulfides-Phillips .65 .67 .68 107 108 110 111 Scientifics Inc .............. Chemical .......................................... Chemical ........................................ 113 114 116 ............................................ vii .63 106 .......................................... Plastics. 54 .60 .61 112 Tubing-Thermoplastic Copolyester-Eastman .52 .53 104 .............................................. ....................................... Products. Acetate .47 102 Electric. ..................................................... Ethylene-Vinyl ....... .95 .......................................... Resin-General Amides-Rilsan. Systems-A.O. Oats Chemicals. Terephthalate-Celanese Chemical. Oxide-Based Ester Piping Polymer-Quaker Resins-Occidental Block Goodrich ................................................. ............................................. ..................................................... Chemical ................................................ Reinforced Phenylene Pipe and Fittings-B.F. ......................... 1.7 Fiberglass Chloride 10 ........................... Chemical. 1.8 1.16 Polyvinyl .3 Products ................. 116 118 120 Contents VIII 1.39 1.40 1.41 1.42 1.43 1.44 1.45 1.46 1.47 .................................... ........................................ ......................... Polystyrene Resins-Huntsman Chemical ............. Polysulfone-Union Carbide ............................................... Polyvinyl Chloride Ducts-Dayco ............................................ Polyvinyl Chloride Jackets and Covers-CEEL-CO ................................. Polyvinyl Chloride Liners-Fabrico. .......................................... Polyvinyl Chloride Pipe and Fittings-Thermoplastic Processes. ........................ ................................ Polyvinyl Chloride Tank Liners-Peabody Tectank. Polypropylene-Eastman Polypropylene Chemical Resins-Shell 1.52 .................................... Tetrafluoroethylene Resins-Du Pont ......................................... Vinyl Ester Resins-Interplastic Corp. ......................................... Epoxy and Polyester Pipe and Fittings-Ameron .................................. 1.53 Phenol-Formaldehyde 1.54 Polyester 1.55 Polypropylene 1.56 Acetal, Nylon 1.57 Epoxy, Fluoropolymer 1.51 Fluoride-Rilsan. 1.58 Isopolyester, 1.59 Polystyrene, 1.60 Polyvinyl 1.61 Vinyl, Hose-Everflex Ester Alcohol-Formaldehyde and Polyester Lined and Bisphenol Polypropylene 1.62 Various Glass-Reinforced Various Polymers-Westlake 1.64 Various Resins-General Resins and Elastomers Resins and Metals-Phillips 1.67 Various Resins for Membrane 1.68 Various Resins for Plastic 1.69 Various Thermoplastic and Elastomeric 1.70 Various Thermoplastic Polymers A Polyesters, for Linings Lined Piping for Products-Dow Piping Silicone 2.7 Urethane-American 2.8 Urethane-Devcon. 2.9 Urethane 2.10 Various Elastomers-American 2.11 Various Elastomers and Rubbers-Du 2.12 Various Elastomers and Rubbers-Exxon Chemicals. 2.13 Various Elastomers and Rubbers-Minor Rubber 2.14 Various Rubber Rubber Sealant-Stonhard. Linings-Huron Chemicals ........ Ltd ........ .................... Cyanamid ............................ AND 3.2 Epoxy Flooring 3.3 Epoxy Mortar 3.4 Epoxy Surfacing 3.5 Furan Grout-Atlas 3.6 Furan Polymer 3.7 Polyester Pont. Tank ...... Co. ...... . 239 239 . 242 . 247 . .. . . . . . . . . . Concrete-Quaker . . . . ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... . . . . 290 . 293 294 . 296 . 297 . 297 .298 . 299 . 302 .355 . 367 .......... .......... . . . . . .. .. .. . . . . . . . . . . . . .. . . . . . . . . . . . 284 284 .285 . 287 .......... . . . . .. . . . . . . . . Oats Chemicals Technology. ....................... .. .. . . . . .. . Toppings-Pennwalt . . . . . . . . 250 . 251 . 263 . 272 ....................... Linings-Acme-Fisher. . . Cements-Sternson. Grout-Radiation ............ Systems-Stonhard Compounds-Atlas. and Floor ............. Cyanamid. ASPHALT Surfacing .............. Limited. and Elastomeric Floor ................. ....................... Rubber Cyanamid Membrane-Sternson MORTARS, Chemical Materials-Nibco. 2.6 Epoxy-Base . . 218 . 220 .221 . 223 . 225 . 236 . 238 . 240 Hose Stocks-Gates Polysulfide 3.1 Chemicals and Membranes-Atlas. 2.5 Elastomer Resins-Amoco Fabrications-Atlas. .......................... Elastomer-American Synthetic Ester Chemical 2.4 CEMENTS, and Vinyl .................................. .............. .................. Fluoroelastomer-Elkhart Rubber. ............... Fluorosilicone Rubbers-Dow Corning. ................ Polysulfide Rubber-Morton Thiokol 2.3 179 ............. Systems-Resistoflex. ...................... .................................... ................................ Linings-Watersaver. Various Various 2.2 174 ............................................ 1.65 Acrylic .... .............................. Resins-Celanese Plastics ................................ Plastics .......................................... 1.66 2.1 Haveg Division. Tubing-Barnant Electric RUBBERSANDELASTOMERS . 170 Resins-Ametek, Piping and Polyethylene and Fluoroelastomer 1.63 . 159 Pont .................................... ........................... Resins-Duriron. Resins-Du and ABS Plastics-Monsanto. Chloride, Silicone Fluoride and Polyethylene Halogenated . 156 . 157 ..................................... Resins-Ashland. and Polyvinylidene SAN 151 . 152 . 154 . 155 Products and Furfuryl and Vinyl 147 . 149 155 Polyvinylidene 1.49 1.50 122 . 142 ............................................ 1.48 Tetrafluoroethylene 120 Products. Chemical. 369 369 373 .......... 375 .......... 379 .......... 382 .......... 383 .......... 383 Contents 3.8 Sulfur 3.9 Urethane Asphalt 3.10 Polyester and Epoxy 3.11 Various 3.12 Various 3.13 Various 3.14 Various Concrete and Coating-Sulcon Flooring .......... .... Compounds-Atlas ..................... ............. Mortars-Koch Engineering Mortars-Pennwalt ................... Mortars-Sternson ................... Cements-Atlas Austenitic Alloy-Allegheny 4.2 Austenitic Stainless 4.3 Ferritic 4.4 Ferritic-Austenitic Stainless Steel-Cabot 4.5 Iron Alloy-Cabot Wrought Products. 4.6 Iron 4.7 iron- 4.8 Stainless 4.9 Various Duplex 4.10 Various Stainless Steels-American 4.11 Various Stainless Steels-Carpenter 4.12 Various Stainless Steels-Cyclops .................. ............................ 4.13 Various Stainless Steels and High Nickel Stainless Ludlum. Steels-Jessop Steels-Allegheny Alloys-Cabot Stellite and Nickel-Base Wrought ......................... .......................... Division Alloys-Stainless Steel-Armco Stainless and Austenitic Foundry Steel Products. Stainless .................. Steels-Climax Iron and Steel Technology. Alloys-Climax Aluminum 5.3 Aluminum Bronzes 5.4 Aluminum 5.5 Aluminum-Zinc ALLOYS. Alloy-Alcoa. and Nickel-Aluminum Bronzes-Ampco 5.7 ........................... Steel ................. Beryllium Copper Alloy-Brush Wellman .................. ...................... Cobalt-Base Alloys-Cabot Stellite 5.8 Cobalt-Base 5.9 Cobalt-Base Alloy-Cabot Wrought Alloys-Wall ............... Products. and Copper Colmonov 5.13 Copper 5.14 Lead and Lead Alloys-Lead 5.15 Magnesium-Dow 5.16 Nickel 5.17 Nickel-Base Alloys-Arco 5.18 Nickel-Base Alloys-Cabot Nickel-Base Alloys-Stainless 5.20 Nickel-Base Alloys-Wall 5.21 Nickel-Base and Other Nickel-Base Rods, 5.23 Tantalum-NRC 5.24 Tantalum 5.25 Titanium-Industrial Brass Association. Alloys-Huntington 5.19 ....... .......... American Wrought Pipe and Tubing-Colt and Wires-Cabot and Tantalum-Columbium Alloy-Cabot KBI Zinc 5.32 Stainless 5.33 Titanium, ............................... Alloys-Teledyne Wah Chang Albany. and Molybdenum-Schwarzkopf Nickel Steel, ........ Titanium. Coating-Alcoa. Cobalt, ........ .................................. 5.28 5.31 . . . . . . . . . . Industries Stellite. 5.27 Zirconium ......... & Engineering. ..................... Colmonoy and Stainless Nickel Zirconium Steel Alloys-Cabot and Copper ............ Development. Alloys-Carpenter and Tantalum-Astro . . . . . . . . . . . . . . . .. . . . . .. . . . . . . . . . . . .. . . . .. . . . . . . ............... Products Foundry High Alloy ........... Alloys ........................ ................... Titanium and Titanium Alloys-Timet. Zinc Alloy-New Jersey Zinc. ......................... Tungsten . . . ..................... Allvac Electrodes . . . . . . . . . . ........................... Alloy-Teledyne 5.22 Metals, Industries Chemical and High-Nickel 5.29 . Coating-Bethlehem 5.12 5.30 Metal Coating-Alcoa ..................... Columbium-Cabot KBI ............................. ................ Columbium-Teledyne Wah Chang Albany. Copper Alloys-Revere. ............................. 5.26 ... Molybdenum. 5.2 5.11 .......... Institute. ....................... ............................ ................ Alloys-Aluminum Association. AND .... Molybdenum Aluminum METALS ........ & Engineering 5.1 NONFERROUS .......... Products Stellite. ....... ....... Technology. Metallurgical. ....... . .. . . . . . . . . . . . . . . . . . . . . . . . . . ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ......................... Steel. ....................... Ludlum ..................... 4.1 5.10 . . . . . .. . . . . . . . . . . ........................................... FERROUSALLOYS 5.6 . . . . . . . . . . ...... ...... ...... ...... ...... ...... ...... ...... Systems. Membrane-Pennwalt. . . . . . . . . . . . . . . . . . . . . . . . . . ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... . ix 384 . 387 . .. . . . . .. . . 388 389 391 399 406 . . . . . . . . . . . . . . . . . . . . . . . . . . 412 412 413 414 420 424 425 426 428 429 431 . . . . . . . . . 433 . . . . . . . . 609 609 610 632 633 638 639 643 644 645 646 647 648 649 655 663 664 665 666 725 728 729 730 731 732 735 736 742 744 749 756 756 757 764 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. .. . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . . . .. .. . . . . . . . . 440 444 X Contents 5.34 Tungsten, 5.35 Various Metals and Alloys-Duriron 5.36 Various Metals and Alloys-General 5.37 Various Metals and Alloys-Walworth GLASS, Tantalum CERAMICS, AND Alloys-Kennametal ............. ............................... Metals Technologies. ................. .............................. and Titanium Carbide Carbon-Graphite-U.S. 6.2 6.3 6.4 6.5 6.6 COMPARATIVE Graphite. RESISTANCES OF MATERIALS . . .. . . . . . . . . . . . .781 . . . . . . . . . . . . . . . . . . . . . . . 786 . . 786 . . 790 . .791 . 792 . . . 792 . 793 .796 Aluminum Iron and Steel 7.2 Metal, Carbon, 7.3 Polymeric 7.4 Rubber, 7.5 iron, ................ 839 7.6 846 7.9 .................. ............................. Various Resin, Elastomer and Steel Tank Materials-Nalge. .............................. Metal, Elastomer and Plastic Pump Materials-Oberdorfer ...................... Glass, Metal and Plastic Piping Systems-0-I/Schott Process Systems. 7.10 Natura! 7.7 7.8 Nickel Filtration System 7.12 Plastic 7.13 Steel, Titanium, NAME Fibers, Titanium, AND MATERIAL 796 Lead, Glass, Concrete for Castings Porous Stone Ceramic, Pump or Porous Rubber, Carbon Natural Lining Materials-Gates Jabsco. 797 809 Rubber. Cylinder Filter Tube and Synthetic 854 882 ...... Materials-Sethco. Fiber Pump . . . . . . Heating . . 884 and 885 889 ............................... and Tantalum .. 821 848 ........................................... Columbium LISTING and Wood Materials-ITT and Forgings-Janney Materials-Thompson-Chemtrol. Zirconium, ............ Materials-Corning ................... Rubber. Construction and Brass Couplers-Gates Materials-Sethco ADDRESS and Wood Resin and Rubber Alloys and Steel Pump TRADENAMEINDEX CORROSIVE Aluminum, and Synthetic Alloy, Plastic Aluminum Synthetic and Copper 7.1 1 Resin, Steel, COMPANY Rubber, Hose and Steel, Steel, Materials-American ................................................... Institute. Ceramic, Resin, Steel, Construction . 771 . 773 ,777 Steel, Bronze, Plastic Tank . . . . .. . . ........................ OF CONSTRUCTION Reinforced . . . . . . . . . . . . . . . . . 7.1 Iron, and Glass Fiber . . . . . . . . . . . .. . . . . . . . CARBON-GRAPHITE. ..... ........ Ceramic Fiber Products-3M. ......... Ceramic Linings-Abresist. ...... Foamed Glass Block-Pennwalt .............. Glass Pipe-Corning ........... Glassed Steel-Pfaudler. 6.1 . . . . .. .. and Cooling . . . . . . . . ..... Coils-Vulcanium . . . . . 891 . . . . . . . . . . . .892 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ...897 INDEX. . . . . . . . . . . . . . . . . . . . . . . . . . . . .900 Synthetic TABLE 1.1: ABS JACKETS AND Resins and Polymers COVERS-CEEL-CO Typical Resistance Acetrc Acrd. I %, 30 days Acetic Acrd. 50%. 30 days ‘Acetrc Acrd. concentrate Acetone, 10% Alummum Sulfate, 25% Ammonra Gas Ammonrum Hydroxrde Beer (over 3 2% alcohol) lBenzaldehyde Concentrate *Benzene lBenzyl Ether ‘Bromrne lBromoethane Butane ‘Butyrrc Actd Calctum Chloride. 25% Calcrum Sulfa!e, 25% solutron Carbon Droxrde ‘Carbon Tetrachlonde lChlorobenzene ‘Chloropropane Chromrc Acrd, 30% Citrrc Acrd, 25% Cod Lrver 011 Collordal Sulfur, 30 days, 140°F Corn 011 Cyciohexanol lCyciohexanone Detergent Drethanolamtne. 30 davs. 140°F Dtethylene Glycol ‘Diethyl Ether “Drethyl Ketone ‘Ethyl Acetate Ethyl Alcohol. 50% Ethylene Gfycol. 30 days, 140°F Ferrol 1s Sulfate, 25% Form: Ildehyde, 30%. 30 days *Freon 11 Freon 12 Features of CEEL-TITE 100 Series ‘Gasorne Glucose, 30 days. 30% 146°F Gfycerrn, 30 days, 140°F Grapefrurt Jutce 30 days Heptane. 30 days lHexane Hydrochlonc Acrd, 30 days Hydrogen Peroxide. 3% Kerosene, 30 days Ltght Process Ori. 30 days : 40°F Liquid Wrench” *Methyl Ethyl Ketone Mrnerai Spirits. 18 months Motor 011. 6 months Naphtha (lighter fiurd) 3 months Paratftn, 30 days lPentane *Phenol Phosphonc Acid. 30 days ‘Phosphonc Acid, 30 days 140°F Potassium Chloride, 25% Potassrum Hydrox\de. Saturated sol&on 30 davs. 146°F Red Copper Oxrde. 30 days 140°F Sodrum Brcarbonate Solutton 30 days, 140°F Sodrum Chlonde Solutron, 30 days. 140°F Sulfunc Acid, 50% 30 davs Syrup. Srmple’Sugar Tomato JUICP Tnsodrum Phosphate Ucon M-l@ Hydraulic Flurd 7 days. 160°F Unc Acrd. 30 davs Vtnegar Frim Remover S S 2 U S S -Satisfactory U - Unsatfsfactory Test Method lSatisfactory atmospheric @- ASTM D - 543 - for use under conditions Regtstered Trademark 72 u z S ; : s S s U s’ S S il U S U S S S S S s” s” Z Z 2 Corrosion Resistant Materials Handbook TAB.LE 1.2: ABSIPVC ALLOYS-A. SCHULMAN A special outdoor rigid polymer alloy, POLYMAN 507 retains more impact strength after UV exposure than any competitive material according to UL recognition tests. It is rated UL Bulletin 94 V-O and carries 95°C continuous use temperature rating. In addition it offers the good electrical properties and tensile strength needed for wiring devices and small tool housings. A rigid polymer alloy, POLYMAN 509 exhibits low shrinkage (0.0045 in/in) and combines a 212°F heat distortion temperature with a superior 430,000 flexural modulus to mold and hold strict dimensional tolerances in critical fit applications such as printed circuit card holders. Its high arc track resistance and compressive strength, along with a good balance of other properties, qualifies for applications in severe electrical service such as junction boxes and connectors. POLYMAN 511 offers the highest impact strength (83.5 tensile impact; 320 in lb Gardner impact) of the POLYMAN UL V-O rated rigid polymer alloys. It also has excellent UV color stability along with the exceptional stiffness and flatness required for large business machine and consumer appliance housings. POLYMAN 507, 509, 511 Chemical Resistance Class S-Satisfactory (only minor absorption) Class A-Surface affected only slightly; still performs mechanically Class P-Poor resistance; not recommended exposure CLASS s Linseed Oil Mineral Oil Motor Oil Nitric Acid, 40% Olive Oil Potassium Hydroxide, 50% Sodium Carbonate Sodium Hydroxide, 50% Sulphuric Acid, 97% Ammonia, 30% Brine Solution Clorox Citric Acid 2N Gasoline Glacial Acetic Acid Hexane Hydrochloric Acid, 30% Hydrochloric Acid 2N lgepal Lactic Acid 20% CLASS A Chloroform Chromic Acid 30% Ethyl Alcohol Formaldehyde, 35% Formic Acid (Anhydrous) Glycol Isopropyl Alcohol Oxalic Acid 50% Phosphoric Acid, 85% Silicone Oil Turpentine CLASS P Acetone Benzene Carbon Bisulfide Carbon Tetrachloride Ethyl Acetate Methyl Ethyl Ketone Toluene Xylene NOTE: For solvent welding, use such solvents as: Perchlorethylene with Cyclohexanone Tetra Hydrofurane with M.E.K. For vapor degreasing, use such agent as: Freon TE with Alcohol Synthetic TABLE 1.3: ACETAL CELCON trioxane. COPOLYMERS-CELANESE PLASTICS is a registered trademark of the Celanese Corporation used for its crystalline CELCON acetal copolymer can be injection molded, blow molded, extruded, machined. CELCON acetal copolymer offers high mechanical strength through broad ranges of temperature and environment. Celcon Grade Formulation Melt Index UlO-11 1.0 M25-01 M2504 3 Resins and Polymers strength, stiffness, acetal copolymer based on rotationally cast and easily toughness, and practical impact Range Description Application Excellent processabillty in extrusion blow moldtng. injection blow molding and extrusion. High melt strength. Low odor grade for aerosols. Aerosols, containers, industrial articles, rod, tube, slab, profiles. 2.5 Excellent processability Not lubricated. Rod, tube, sheet, slab, wire coating 2.5 Good processability for injection molding in easy-to-fill molds. Possesses greater toughness and elongation than materials with 9.0 melt index. Same as M25-01 except that it is internally lubricated. Injection molded parts requiring timum toughness and elongation. General injection molding. in extrusion. M90-04 9.0 Excellent moldability due to high flow characteristics and stabtlity in processing High surface gloss and good dimensional stability. Internally lubricated. M90-08 9.0 Ultraviolet stabilized. Good maintenance of physical properties and resistance to chalking in outdoor exposures. Injection molded plications. M270-04 27.0 Highest flow. Superior moldability for hard to fill molds with somewhat less toughness than M90. Internally lubricated. H.igh speed injection cavity parts. seasonal outdoor molding op ap- for multi- M90-07 - Celcon color Concentrates are provided in a wide range of standard colors for letdown into natural Celcon via extruinjection molding sion or screw machines. To obtain body colored injection molded or extruded products at cost savings. GC-25A 2.5 M90 Resin reinforced with 25% by weight of glass fibers together with a unique coupling agent. Provides increased stiffness, tensile strength and creep resistance. Windshield wiper pivots, gears, pulleys and other parts requrring the maximum in stiffness and strength. (continued) 4 Corrosion Resistant Materials Handbook TABLE 1.3: ACETAL COPOLYMERS-CELANESE PLASTICS Chemical Resistance of Celcon Time Temp Yield (continued) M90, M25, M270 o:cChange’ Matenal Months Control (Air) INORGANIC F Strength 12 73 0 6 12 6 6 12 6 6 6 12 73 73 180 73 73 73 73 73 73 180 73 73 180 180 73 73 73 73 180 180 73 180 0 0.7 -0.3 Tensile Modulus 0 Length 0 Weight Vwble Effect3 0.22 N.C. CHEMICALS 10% Ammonium Hydroxide 3% Hydrogen Peroxide 10% Hydrochloric Acid 10% Nitric Acid 10% Sodium Chloride 2% Sodium Carbonate 20% Sodium Carbonate 1% Sodium Hydroxide 10% Sodium Hydroxide 60% Sodium Hydroxide 4-6% Sodrum Hypochlorite 26% Sodium Thiosulfate 3% Sulfuric Acid 30% Sulfuric Acid Buffer, pH 7.0 Buffer, pH 10.0 Buffer, pH 4.0 Water (Distilled) ORGANIC CHEMICALS 5% Acetic Acid Acetone Aniline Tint Benzene Carbon Tetrachloride 10% Citric Acid Diethyl Ether Dimethyl Formamide Ethyl Acetate : 12 6 6 6 12 6 12 6 6 6 6 6 12 6 6” 4 6 12 12 6 12 6 12 6 6 6 6 12 : 12 6 6 6 12 6 0 -16 -12 -15 -12 X X -12 -15 -10 -9 -9 -6 -7 -12 0.2 0.2 0.2 0.2 0.2 0.4 0.2 0.2 0.2 0.2 0.2 0.2 -0.1 0.1 0.2 0.88 1.03 0.74 0.97 0.88 X X 0.59 0.71 0.49 0.77 0.78 0.96 0.61 0.80 0.84 0.49 0.73 0.83 -0.18 -3.29 0.61 -8 -14 X -15 -12 X -12 -12 -18 0.4 0.2 X 0.3 0.3 X 0.2 0.2 -0.1 0.81 0.82 X 0.94 0.89 X 0.83 0.84 -3.32 73 73 120 180 -1 0.6 -4 -17 -19 -26 -15 -16 -20 -48 -48 -73 0.3 0.2 0.7 1.6 2.1 4.8 1.05 1.13 3.60 3.68 4.45 12.1 N.C. N.C. N.C. N.C. N.C. Reddish 120 73 73 120 73 73 73 180 73 73 120 -17 -1 2 -11 0 3 -15 -19 -5 -17 -22 -43 -4 -6 -32 -12 -10 -26 -63 -20 -46 -50 1.8 0.2 0.1 1.2 0.3 0.2 1.1 3.1 0.6 1.6 2.1 3.93 0.86 1.39 5.23 0.74 1.93 2.09 7.7 3.62 4.25 5.23 N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. : X X 2 3 4 0 6 3 3 1 2 1 -2 -3 -3 -6 3 73 73 73 180 180 180 73 73 180 3: 1; 2 2 -8 1; 0.3 0.3 0.4 0.3 0.3 Disc. DISC. Disc. N.C N.C. N.C. SI. Disc. SI. Disc. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. SI. Disc. St. Disc. Pitted N.C. N.C. N.C. SI. Disc. SI. Disc. N.C. N.C. Disc. (continued) Synthetic TABLE 1.3: ACETAL COPOLYMERS-CELANESE PLASTICS Materral Ethylene Dichloride 50% Ethylene Glycol 95% Ethanol 50% Ethanol Heptane Oleic Acid 5% Phenol Toluene OTHER Temp F 6 6 6 12 6 6 12 6 6 12 6 6 12 6 6 12 6 12 6 120 180 73 73 120 73 73 120 73 73 180 73 73 180 73 73 73 73 180 -17 -4 -5 -13 -2 3 -6 -1 3 0 -15 -10 -7 -7 -14 6 6 6 12 6 12 6 6 180 180 73 73 73 73 180 180 6 6 : 180 180 180 73 73 180 180 180 I; 6 6 6 6 6 6 6 12 6 6 12 6 120 120 120 180 180 180 73 73 180 73 73 180 -12 -6 0 8 4 -3 3 8 -1 5 5 Yreld Strength O0Change’ TenslIe Modulus Vwble Effect3 Length Wetght -45 -46 -17 -19 -43 3.2 0.4 0.6 0.7 1.3 0.6 0.7 1.0 0.2 -0.07 0.2 0.3 -0.04 0.5 2.1 1.4 0.4 0.7 16 10.05 1.33 1.43 2.19 2.54 1.62 1.98 2.27 0.04 0.09 0.35 1.05 -1.26 1.04 9.34 4.70 1.12 1.87 3.80 N.C. SI. Disc. N.C. N.C. N.C. N.C. N.C. N.C. N C. N.C. N.C. N.C. N.C. N.C. N.C. Disc. N.C. N.C. N.C 5 0 0 3 -3 -0.5 -11 -5 5 -23 -12 -1 -13 -9 -41 -33 -0.07 0.6 0.3 0.2 0.3 0.2 1.4 1.3 -0.15 1.53 0.34 0.53 0.70 1.05 3.60 3.18 N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. 2 3 3 18 3 0 -11 -15 -10 -14 -15 -18 -20 -15 0.2 0.3 0.3 0.4 0.4 0.7 0.4 0.5 0.85 1.00 1.04 0.75 0.84 1.62 1.04 1.32 0.7 0.7 0.7 0.3 0.2 0.2 0.2 -0.06 0.0 0.2 -0.06 -0.06 1.30 1.50 1.43 0.34 -0.13 -0.03 -0.03 0.05 -0.18 0.02 0.04 -0.14 -23 0 1; -68 -18 -19 -35 -31 -24 -32 -34 -13 4 -9 -15 -i’ MATERIALS Automatic Transmission Anti-Freeze (Telar) Brake Fluid, “Super 9” Fluid Brake Fluid, Lockheed “21” Brake Fluid, “Delco 222” Detergents “Acclaim” “Calgonite” “Electra-Sol” 50% lgepal Detergent Solution2 1% Soap Solution Gasolines Mobil Regular (9315 Octane) Mobil “Hi-Test” (99.0 Octane) Sunoco “280” (103 Octane) Kerosene Linseed Oil Lubricating Grease Mineral Oil (“Nujol”) Motor Oil (1 OW30) : 12 6 -11 -12 -12 -10 -7 11 3 -14 -1 7 -9 7 0 SI. Disc. SI. Disc. N.C. N.C. N.C. N.C. SI. Disc. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. 1. Type 1 TenslIe bars used nnthese tests measure 8!5 x % x ‘/ Inches. rutlal yleld strength IS 8800. tenslle modulus 410,000. weight 13 grams 2 Cowsts 5 (continued) __~ Time Months Resins and Polymers of 0 5 grams of an alkyl sulfonate + 0 20 grams of trisodlum phosphate per liter of water 3 X = Not recommended, N C. = No Change; DISC = Dlscoloratlon. SI DISC = Slight discoloration TABLE 1.4: ACRYLIC RESINS-ROHM AND HAAS 0, PLEXIGLAS is the registered trademark for acrylic plastic sheet produced by Rohm and Haas Company. In its natural tically clear, transparent, lightweight material having outstanding weatherability, high impact resistance, good chemical ity and machinability. form, PLEXIGLAS acrylic sheet is an opresistance, and excellent thermoformabil- 2 q o I. 2 Chemical Resistance of PLEXIGLAS Sheet* PROPERTY 1 Thickness CHEMICAL 1 inches RESISTANCE 0543 WEIGHT GAIN AFTER 7 DAYS IMMERSION AT 77°F. (WEIGHT GAIN OR LOSS OF 1% OR LESS IS CONSIDERED COMPOUND ACIDS CLASS % TYPE Glacial Chromic Acid Citric Acid Hydrochloric Hydrochloric Acid Acid Hydrofluoric Acid Concentrated Concentrated Nitric Acid Nitric Acid Nitric Acid CONCENTRATION. % R-S 05 100 5 R-S 04 R-S 40 10 0.2 03 0.2 0.3 0.2 30 10 0.2 0.3 40 70 40 10 Olelc Acid BASES .0250 NEGLIGIBLE) NAME Acetic Acid Acetic Acid 1 ’ 04 DL 0.5 0.4 -_ 0.3 4-D 0.4 02 03 A-D-S 0.4 0.3 A 04 8 SE 0 SE 13E - - A-D 20 0.3 A-D 2.8 03 D-R 5.3D 0.4 03 A 5-A 04 0.0 00 0.0 00 -0.1 04 Sulfuric Acid Sulfuric Acid Sulfuric Acid Concentrated 96 30 3 D-R-S 0.2 0.4 D-R-S 0.2 0.4 D-R-S 0.3 0.5 0.2 0.4 DL 03 0.5 Ammonrum Ammonium Concentrated 20 10 0.2 0.4 0.2 0.3 0.3 0.5 0.3 0.3 0.5 Sodrum Carbonate Sodwm Carbonate 20 2 0.2 0.4 0.2 0.4 0.3 0.5 0.3 0.3 0.5 Sodrum Hydroxrde Sodwm Hydroxrde Sodrum Hydroxrde 60 10 -0.2 0.3 0.4 -0.2 0.3 0.4 -0.2 0.4 0.5 0.3 0.4 -0.4 04 0.5 Hydroxrde Hydroxtde (continued) TABLE 1.4: ACRYLIC RESINS-ROHM AND HAAS (continued) TYPE I COMPOUND CLASS COMMERCIAL PRODUCTS Cottonseed 011 Detergent Solution Kerosene 0.25 I Plexrglas G II UVA. II-UVT. G-UVT Plexrglas K Plexiglas 55 Plexrglas IA UVA Plexiglas MC er0.1 -rO.l to.1 - 0.1 0.4 - 0.5 - 0.1 0.3 0.3 -:o. 1 -;O.l c:.o. 1 DL DL 0.3 DL DL USP c.o.1 to.1 co.1 - 0.1 Olive Oil Edible Grade ..O.l co. 1 <O.l - 0.1 Soap Whrte Flakes 0.5 Sotutton 011 Turpentrne Distilled 0.3 0.3 0.4 - 01040) to.1 co.1 <O.l - 0.1 Distilled Spirit (ASTM 013) <O.l <O.l 0.1 - 0.1-c 0.4 0.4 0.5 0.4 0.6 - (ASTM 1 Water Hydrogen Hydrogen COMPOUNDS Duty PLASTICS White, Oil Transformer ORGANIC Heavy Thinner Mrneral COMPOUNDS Edrble Grade NO. 2 Fuel Oil (ASTM 0396) Lacquer INORGANIC TYPE NAME CONCENTRATION. % OF ACRYLIC Peroxide Peroxide Sodium Chloride Sodium hypochlorite 26 3 0.4 0.4 0.4 0.4 ct.7 0.6 0.4 0.8 0.6 10 0.3 0.3 0.4 0.3 0.5 5 0.3 0.3 0.3 - 0.4 DL DL R-S DL DL - DL Acetone Aniline DL DL 12R-S Benzene DL DL 0.1 Carbon --0. 1 Tetrachloride” ‘ 0.1 DL 0.0 -3.0 -5-A-E -0.1 -0.1 0.0 0.0 0.1 cro. 1c I: O.lC -0.1 - R-S DL DL A-S - DL Ethyl Acelate DL DL R-S DL DL Ethyl Alcohol Ethyl Alcohol 1.4 0.8 1.4 1.1 1.7 7.5 2.2 4.0 2.0 Drbutyl Sebacale Dlethyl Drmethyl Ether Formamrde 95 50 0.6 (continued) TABLE 1.4: ACRYLIC RESINS-ROHM AND HAAS (continued) 0 3 TYPE OF ACRYLIC COMPOUND ORGANIC NAME CLASS COMPOUNDS Ethylene TYPE CONCENTRATION. % Dichlorrde P-Ethylhexyl Sebacate Plexrglas Plexrglas K 55 IA UVA Plexrglas MC 4 2 2 DL DL R-S DL DL s co.1 - 0.0 0.0 0.0 0.0 0.1 lsooctane -rO.l co.1 <O.l - 0.1 0.1 5.5s 0.1 5.8s -0.2 14s -0.1 C - A A-C A-C A-C A-C A DL DL 0.0 DL DL Alcohol Toluene 99 A C 0 DL E R S = = = = = = = 5 Attacked Crazed Discolored Dlssolved Edge Swellmg Rubbery Swollen *Weight change is affected by the thickness of the material. Values given are for the thickness noted in the column heading. *“Although carbon tetrachloride causes negligible weight change in contact with PLEXIGLAS sheet, it does cause optical distortion used with PLEXIGLAS. 0.1 s-o.1 Phenol (Aqueous) Code: Plextglas G-UVT q.o.1 Methyl Alcohol Resistance II-UVT. z. s Heptane Isopropyl Chemical Plextglas G II UVA. ? PLASTICS of the surface. Carbon tetrachloride should not be $ ? 5’ z x % 8 8 h TABLE 1.5: BAREX 210 ACRYLIC Resin RESIN-SOHIO CHEMICAL is an acrylonitrile-methyl acrylate-butadiene polymer. Chemical Resistance of Barex 210% Resin “F/T Observed Change ACIDS 1090 30% 73123 100138 73123 100138 73123 100/38 73123 lOdl38 73123 100138 Hydrochloric Sulfuric Acetic 100% 30% Phosphoric 10% Nitric None None None None None Frosted, Softened None None None Yellowed Ammonium Hydroxide Barium Hydroxide Calcium Hydroxide 10% Potassium Hydroxide 10% Sodium Hydroxide 73123 100138 73123 100/38 73123 100138 73123 100/38 73123 100138 None Softened None None None 73123 100138 73123 100138 73123 100/38 None None None None None None None Slight Frost Frost, Softened Slight Frost Frost, Softened HYDROCARBONS Benzene Toluene Xylene Trichloroethane 73123 100138 Trichloroethylene 73123 100138 73123 Methylene Chloride 100138 73123 1 ,l ,l, 100138 Observed Change None None None None None None Frosted, Rubbery Frosted, Rubbery KETONES Acetone 73123 100138 Methyl Ethyl Ketone BASES 10% “FiT Carbon Tetrachioride Methyl lsobutyl Ketone 73123 100138 73123 100138 Softened Softened Frosted, Softened Frosted, Softened None None ALCOHOLS Ethyl Alcohol 73123 100/38 Isopropyl Alcohol Glycol 73123 100138 73123 100138 None None None None None None ESTERS Butyl Acetate Cellosolve Acetate 73123 100/38 73123 100138 Ethyl Acetate Exposure time in all testing was one year. 73123 100138 None None None None None Frosted, Softened TABLE 1.6: CELLULOSE ACETATES, BUTYRATES, PROPIONATES-EASTMAN CHEMICAL TENITE esters are cellulose derivatives of acetate, butyrate, and propionate. Tenite plastics for molding and extrusion are supplied in the form of pellets. These resins have good processability and finished articles may be resoftened by heat and reshaped by the application of suitable forces. thermoplastic Effect of Various Material I Tested Percent Increase l- Chemicals and Reagents on TENITE@ Observed Condition of Plastic hicknes! Material CHEMICALS Alcoholr. Acids n-Am+ tert.Amyl n-Bury1 seeBury tert-Butyl ‘Acetic. 590 I year 5 53 3 19 ‘Acetic, 1 week 5 44 3 03 17.03 22 57 2 63 1.67 10% ‘Acetic. 30% *Chromic. 6% Citric, 10% 1 week 6 days (100°F 1 year ‘Citric. 10% ‘Citric, 30% ‘Fluosi!iclc, 10% ‘Fluosillclc. 28% Formic, 3% 2 months l14O’F) 1week (140°F) 2 monrhs 2 months 20 days Hvdrochlorlc. +Hydrochlorrc, lHydrochloric, ‘Hydrofluoric, ‘Hydrofluoric, 2 days 2 days 1 month 1 month 1month 6% 6% 10% lo?/, 48% ) -1.30 -1.67 1.26 0 06 2.06 2.03 0 00 0.05 -0 61 1 49 Shghtly softened, surface attacked Shghtly softened, surface attacked Softened Softened and swollen Unchanged Decomposed Decomposed Slightly warped Slrghtly warped Unchanged Unchanged Softened Softeled and swollen Softened and swollen Decomposed Tested 2 days 2 days “N~rrlc, 10% Ol0C ‘Phosphoric. 30% 1 week 1 year 2 months ‘Phosphoric, 50% *Phosphoric, 75% Pyrogallic. 4% sreanc ‘Sulfuric, 3% 2 months 1week 1 week 1 week 1 month ‘Sulfuric, 10% ‘Sulfuric. 20% ‘Tannic. 10% Tartaric ‘Trichloroacetlc 1 year 6 months 4 months (14O’F) 2 days 1 month 3 14 6 80 1 50 4 34 -3 33 2 03 -0 83 0.63 1 63 -0 42 7.60 3 55 304 2.19 7.62 2.93 1 63 1.60 Unchanged Shghtly softened, surface atracked Decomposed Unchalged Unchanged Brittle, surface attacked Decoliposed Stamed yellow Unchanged Softened Decomposed Decomposed Softened Unchanged Decomposed Tim0 Exposed l- Percent Wai#n Increase licknen -r Obsmad of Condition Plastic monohydric 2 days 2 days Z days 2 days Z days -0.36 -0.17 1.41 0.36 -2.00 0.26 0.19 1.40 0.76 0.26 *Drawtone ‘Ethyl *Ethyl, 50% 2.Ethylhexyl lroamyl 2 days 1week 1 week 2 days 12.70 14.46 27.90 lsobutyl *Isopropyl ‘Methyl *Methyl, 5% vvPropyl lTetrahydrofurfuryl 2 days 2 days 2 days I year 2 days 3 days -1.70 10.90 22.60 3.96 2.20 0.42 16.40 51.00 2.59 4.22 Unchanged Swollen Blushed. softened, and swollen Blushed and softened Blushed Softened and swollen Ethylene Glycol ‘Oiethylene Glycol 1 year 1 year 4 months -0.66 1.29 20.76 -0.15 1.39 15.94 ‘Triethylene 4 months 25.40 22.69 0.39 0.42 Unchanged Very slightI\ softened Warped and softened; surface attacked Warped and softened, surface attacked Unchanged Alcohols, -0.36 0.14 Jnchanged Jnchanged Jnchanged Surface bleached slightly Unchanged Dissolved Swollen and softened Swollen and softened Unchanged Unchanged di. and tri-hydric Glycerin Lacttc, 10% “Lactic. 50% Acetate Glycol Propylene Glycol Bases ‘Ammonium Hydroxide, 10% ‘Sodium Hydroxide, 1% ‘Sodium Hydroxide. 10% ‘Trimethylbenzyl Ammomum Hydroxide. 5% 2 days 1 month 1 month I week 17 days 12.41 -0.12 -4.07 5.85 Softened; surface attacked bftened and warped I&composed iwollen and checked EltW Acetate ‘sec.Bury1 Acetate ‘Ethyl Acetate ‘Ethyl Lactate ‘n-Rutyl ! days ! days 7.24 3.74 9.75 3.62 iurface attacked iurface attacked Irnolved Irssolved (continued) TABLE 1.6: CELLULOSE ACETATES, BUTVRATES, PROPIONATES-EASTMAN Effect of Various Time Expord Material Tested &err Pornon Weidtt l- WOOS? Otnervad Condition of Plastic hlckna Material Hydrocarbons Glycol Acetate Monoethyl Ether (EKTASOLVE’= Acetate, ‘Ethylene Cello~olve Glycol Acetate Methyl lNaphthalene EM Acetate 2 days 1.89 0.61 Surface attacked ‘Isobutyl Acetate 2 days 7.82 4.32 Surface attacked 2 days 1.32 a.44 Surface Acetate attacked 1 month silicate (122°F) -2.39 2 days Ether ‘Oi-Isopropyl 2 days Ether (Moth 094 46 hours flOO’F, balls) -0.83 1.38 -9.31 11.20 -0.15 ‘1.4.Oioxane 24 hours f14O’F. 2.02 Ether (EKTASOLVE 1.63 considerable gas 2 months 0.00 liqurd 1 month 0.00 Unchanged lToluene 1 year a.92 Swollen Xylene 1year 2.12 Unchanged plashcizer Unchanged and slightly softened Halogenatad Tetrachloride 2 months 14.92 4.12 Unchanged Unchanged ‘Chlorobromomethane Dissolved ‘Chloroform Dissolved Orssolved lo-Oichlorobenzene 3 days p_Orchlorobenzene 3 days 2.24 0.73 Unchanged 3 days (100°F. 6.57 4.03 Showed 9.80 4.44 Slightly swollen Blushed and swollen Unchanged ‘p-Oichlorobenzene *Ethylene 1.02 2 days Showed ‘Chlorobenzene Ethar Alcohols Monobutyl plasticizer exudation Surface attacked slrghtly 06; some plasticizer exudation 80% R.H.) Glycol considerable exudatron Dissolved Dissolved ‘Oiethylene Showed Propane, Hydrocarbons, EUWS ‘Oiethyl balls) Propane, *Carbon Acetate Observed Condition of Plastic hicknos 88% R.H.) Cellosolve Tetra(2ethylbutyl) (Moth Oraolved Ethel klsoamyl ‘Methyl Pann Wei& 60% R If.1 Acetate) *Isopropyl Trme Expoad (Cont.) ‘Naphthalena Acetate) Monomethyl Acetate Tested EE (EKTASOLVE Acetate; Surface attacked 2 days (continued) Chemicals and Reagents on TENITE@ fCont) *Ethylene CHEMICAL Orssolved Chlorrde lMethylene Chlorrde ‘Propylene Chlorrde Dissolved 2 days 25.30 2.06 Blushed and blistered 3 days 5.36 3.45 Shghtly Bury1 Carbitol) ‘Diethylene Glycol Monoethyl (EKTASOLVE lDiethylene Ether Glycol Methyl 2 days 11.20 12.30 Swollen, surface attacked YTetrabromoethane lTetrachloroethane Dissolved Monomethyl (EKTASOLVE ‘Ethylene Ether DE. Carbitol) Monobutyl (EKTASOLVE Ether 2 days 1.95 2.64 Surface attacked shghtly 32 20 Surface attacked Ketones EBButyl Glycol Dissolved ‘Cyclohexenone Monoethyl (EKTASOLVE Glycol Dissolved ‘Acetone Cellosolve) ‘Ethylene 16 hours ‘Trrchloroethylene Carbitol) Glvcol ‘Ethylene Unchanged 2 weeks Tetrachloroethylene OM; Ether 2 days 23.10 25 30 Swollen and slightly softened EE. Cellosolve) Dissolved Monomethyl Ether (EKTASOLVE Methyl Cellosolve Oi-Isopropyl Ketone ‘Methyl n_Butyl ‘Methyl Ethyl Ketone 2 days 0.04 0.31 2 davs 13.40 16.20 Swollen, surface attacked EM, ‘Methyl lsobutyl Ketone 2 days 40.40 ‘Methyl n-Propyl Ketone 2 days 51.30 7.39 78.50 Swollen, Swollen surface attacked and warped, surface attacked I week I year ‘Benzene ‘Butadiene-1.3. liqurd ‘Butadiene-1.3, gas that material 5.94 -9.42 I month Heptane rc,,. Unchanged Dissolved Ketone Hydrocarbons Vndtcotu swollen Orssolved ir generally 4.21 I year -5 unr0rirfacrar-y Jar YIC in conmcr 36 17.47 a.85 2.77 -1.20 with TENITE Softened tiarped and swollen Phorone 2 davs 0.64 0.24 Stained yellow and shrunken Showed exudation Unchanged Acetalc under thr condimnr of rhu (continued) TABLE 1.6: CELLULOSE ACETATES, BUTYRATES, PROPIONATES-EASTMAN CHEMICAL (continued) Effect of Various Chemicals and Reagents on TENITE@ Material Time Expo&?d Tested Percent Weight Increase Obsetwd Condition of Plastic Thickness salts Material Acetate Time EXpOnd Tened Percent Weight Increase salts (Cant) Aluminum Acetate, 3 97 2 months Basic, 2.07 Unchanged Aluminum Chloride, Aluminum Chloride, saturated Aluminum 19% Ammonrum Unchanged 2 months 0.34 0 00 Unchanged 3 months 2.95 2.00 Unchanged I month 3.56 1year 19% 2 months -5.84 -4.64 Discolored and softened *Potassium Cyanide. saturated 2 months -1.15 -2.66 Discolored Slightly I.34 and softened 3.29 Iodide, saturated 3 days bleached Potassium Permanganate. I month Unchanged 0.36 1.43 solution saturated 3.27 1.39 Stained Unchanged Sulfate, sohd 1 year 0.06 0.40 Potassium Sulfate, 10% I year 2.60 1 46 Unchanged 2 days 1.97 0.61 Slightly 2 days 2.96 1.60 Unchanged 1 week 4.03 2.37 Unchanged 1.56 Unchanged I week 0.14 008 Unchanged Srlver Nitrate, Ammonium Nitrate, 10% 1 week 2.91 156 Unchanged Sodium Bicarbonate, Ammonium Sulfate, solid 1 year 0.0 055 Unchanged Sodium Bisulfrte, Ammonium Sulfate, 16% 1 year 3.66 1.64 Unchanged i 3% solid 20% Sodium Borate, Calcium Chloride, solid 2 days 2.91 0.61 Unchanged Sodrum Carbonate, solid 4 days -0.10 -0 Calcium Chloride, 2.5% 1year 2.93 2.10 Unchanged Sodium Carbonate, 2.5% 1 year -0.74 -2.25 Calcium Chloride, 40% 2 months 0.61 0.16 Unchanged Sodrum Chlorrde. 1.96 Slightly Sodium Chloride,saturated solution 1.38 Brittle, Chloride,saturated solution Hypochlorite, Phosphate, 3 months 6% 2.94 -1.09 1 year Monobasic. softened Sodium Phosphate, Dibasic, Calcium Phosphate, Tribasic, Calcium Sulfate, solid soled solid Cupric Sulfate, 10% Cupric Sulfate, saturated solution 1 year -3.27 -0.6 1 year -3.74 -0.87 1 year -0.20 I Unchanged Cyanide. 10% ‘Sodrum Cyanide, saturated Unchanged Sodrum Ferrocyanrde, Unchanged Sodrum Fluoride, 3.50 1.76 Unchanged 2 months 3.07 1.66 Unchanged 2.26 *Sodium 2.75 Unchanged solution Ferric Chloride, 5% 2 months 2.93 2.12 Unchanged Ferric Chloride. 20% 2 months 2.50 1.91 Unchanged 2 months 2.61 046 Ferric Chloride, Chloride, 46% saturated Magnesium Chloride, Magnesium Sulfate, Mercuric Chloride, Potassium Aluminum Potasswm Chloride, solution solid sohd 1week Sulfate, sohd 21% Unchanged Surface Nitrate, 10% sarurated Sodrum Nrtrite, soltd 06 Unchanged Slightly softened 2.52 1.53 Unchanged 2 months 1.26 0.54 Unchanged Nitrite, saturated Srlicate, solid *Sodium Srlicate, saturated Trimethylbenzyl 2 days 3 12 1.94 Unchanged Chloride, 5.66 I.75 Unchanged 3.89 2.61 Surface 0.02 075 Unchanged attacked Zinc Chloride, slightly ‘Zmc Chlorrde, -0.52 Unchanged 2 months 2 months -4.20 -5.60 Drscolored, softened 2 months -0.64 -2.59 Discolored, softened (140°F) 1 03 0 Unchanged 1 week 0.37 1 month 3.60 2 days solutron solutron solution Ammonium 0 65 -0.26 Unchanged 0 35 -0.23 Softened. 1year 2.56 145 Unchanged 1.46 0 65 Unchanged -0 42 -0.36 2 months 0.76 0.27 Unchanged 0.57 0.19 Etched -0.34 -2.60 17 days 0.59 3 20 1 weak 0.96 0 00 attacked Unchanged 2 months 2 months wface Unchanged 2 months 2 months ‘Sodrum Unchanged I year 2.66 1 year 2 months Nrtrate. I .64 (lOOoF) 5% solrd Sodium 2.93 4 months solrd Sodium Sodium tacky solution 4% Hypochlorite, Nrtrate. 2 days 2 days 5% 10% 0.42 2 months 1 week saturated 2 days ‘Sodrum Sodium Chlorrde, 2.5% softened surface attacked solid Cuprous black 2 days Potassium sohd Calcium yellow solution Nitrate, Calcium Stained solution Ammonium ‘Calcium Unchanged solution solution Chloride, saturated 1.65 10% Cyanrde. Potassium 30% &fluoride, saturated 3.25 solution Sulfate, Ammonium 2 months Chloride. *Potassium Potassium 33% water slurry *Ferric Obwwd Condition of Planlc Thickness Softened Unchanged 5% hydrous saturated salt solution 1week Unchanged Drssolved (continued) TABLE 1.6: CELLULOSE ACETATES, BUTYRATES, PROPIONATES-EASTMAN CHEMICAL (continued) Effect of Various Chemicals and Reagents on TENITE@ Time EXpOpd Materiel Tested Miscellaneous rhicknm 5 Chemicals, Compounds. Ammoniated Observed Condition of Plastic ,creas.? Wei&1 Mercury 1 week (60°C) Unchanged Carbon Disulfide. 1 month 2 days saturated 0.59 5 85 Aviarlon. 1.86 Unchanged 2.39 Unchanged ‘Chlorine. dry 1 week 3.58 0.77 Crazed and brittle ‘Chlorme, moist 2.96 0 12 Crazed and brittle *Chlorine, saturated I week 1 week *Ethylene Oxide, 1 day 18.54 Softened 39 70 1 week 35% 0.94 11.82 Extra Shell High-Test Shell Regular Softened and swollen Texaco Fire Chief Texaco Sky Chief Hydraulic dry 1 month Sulfide, moist 2 months Sulfide. saturated 2 months Hydrogen Hydrogen Slightly -2 58 -2 33 -2 29 -1.90 Stamed yellow Stamed yellow Stamed yellow Stained yellow -2 49 -3.35 Stamed yellow Stained light statned Softened and swollen 0.75 2.29 2.22 Unchanged Unchanged Kerosene 5 58 2.48 3 11 0 82 Stained hght yellow 011s Stained hght brown 500 Jet Propulsion Unchanged -1.07 1.15 -6.00 Skydrol 1 05 3.95 1.58 yellow FluIds Skydrol Sulfide, -5 56 011 and conslderably Dissolved ‘Eugenol Octane Vacuum Esso Regular swollen gas Hydrogen Obreweci Condition of P1asttc Company) Eao solution 115145 (Soconv atmosphere ‘Formaldehyde. Time EXPOred Gasolines Dissolved ‘A”lllne Dwlflde l- Material Te~ed Aeronautical and Automotive Item! (Cont.) and Gases Carbon Acetate (Humble Fuel 3 -0 24 0.42 -1.64 Unchanged Surface dulled Unchanged Oil Company) -084 Unchanged Solution ‘Hydroquinone, ‘lodme, saturated 1 week 20 g/gal solution 2 days 3 days ‘Nitrobenzene Softened, swollen, Aeroshell and badly warped *Phenol, 5% ‘Sulfur Dioxide. dry ‘Sulfur Dioxide, moist ‘Sulfur Dioxide. saturated solution 1 week 2 months 2 months 2 months HO. SAE Shell Dlala Socony Decomposed 17.30 13 50 10.60 11.60 9.71 13.50 No Purol 12 10 011 AX Oil OTE Mrdlum -5.95 -0.31 4 weeks (122°F) -2 01 Unchanged Unchanged -1 72 -0 08 -0 82 -0 12 -1 92 -0.30 No change Unchanged Spew Swollen and warped Swollen and warped Low-Temperature Swollen and conslderably MIL-L-644B Texaco Hew 1 VfA3l 6 months 2 months 3 days A50, 1692 011, warped Nonautomotive ‘Titanium Tetrachloride ‘Triethanolamine ‘Triethanolamine, 10% 3 days I week I week Very brlrtle 11.72 -5.16 24.90 Badly softened 0.69 Softened. surface attacked Essential Greases and Oils Oils ‘Bitter 50% I” n-Buranol CItronella COMMERCIAL AND NATURAL PRODUCTS Aeronautical and Automotive Items Unchanged 0 56 033 0 33 21days 0.28 0.14 Unchanged 21days 21days 21days 21days 71jays 0.26 004 0 98 1.03 0 09 0 19 0 51 Unchanged 062 Unchanged 2 days 2 days 0 10 I year I year I year -2 80 -2 92 -4.41 -0.19 08 -1 12 -0 I Stained ltght yellow Unchanged Slighrly stained Eucalyptus Lemon Menthol, Palmarosa Pennyroyal Spea!mtnt Unchanged Dtaolved ‘ClOVes Gasolines, Amoco Regular Amoco Premium Aviation, 100 Octane (Standard Oil Company) O&solved Almonds Borneol. 50% I” n-Butanol Unchanged Unc’ianged Unchanged (continued) TABLE 1.6: CELLULOSE ACETATES, BUTYRATES, PROPIONATES-EASTMAN CHEMICAL (continued) Effect of Various Chemicals and Reagents on TENITE@ Material Time EXpored Tsned Nonautomotive Percent Wei&t IncreaLe Observed Condition of Plastic Thickness Greases and Oils Howhold (CotIt) Oils Hind’s Terpineol 2 days Thyme (White) 2 days Turpentine 1 year ‘Wintergreen 2 days Mmeral Oil Crude Sperm 011 011 Oil. G.E., Transformer 011, Pyranol No 10-C 0.09 0.37 0.05 Unchanged 0 16 Unchanged 1.58 Surface -0.85 2.74 Unchanged iced Coffee 1 week 1.87 0.86 Stained Iced Tea 1 week 1.98 1.04 Air-Wick Detergent, Kool-Aid Items Odor -0.72 2 months 3 weeks Bacon 5.65 ‘Burma Halt Soft Esther Dressing (in Shave Cream Lemon Unchanged Lemonade Juice 0.00 5% Catsup ‘Clorox Solution Coffee Grounds Colgate Dental “Cologne Sticks Cream 2 days Slightly 3 days Unchanged swollen Detergent. 5% Dwin Household Insect Dwin Stamless Glim Detergent Glim Detergent, Fly Killer Stained attacked 4.30 4.00 Unchanged 1 week 2.47 1.37 Unchanged 4 days (lOOoF) 0.97 1.24 Unchanged Earle Talcum -0.73 Unchanged 3 days Base Cream 3 days Unchanged Powder Mennen 2 days Unchanged 3 days Unchanged Mercurochrome 2 days 2 days Unchanged Milk 3 days Badly Softened Slightly 2 months 1 week 1 week stained Shave Cream softened warped and swollen brittle and slightly Maid Frozen 3 26 1.46 Stained light pink Unchanged Concentrates: Grapefruit 1 week 1.94 0.62 Unchanged Orange 1 week 2.01 0.92 Unchanged Tangerine I week 1week 1.87 0.72 Unchanged 1.77 0.86 Unchanged 2.78 1.44 Stained Lemonade Unchanged 1.92 0.93 -0.02 0.24 -0.99 1.04 Unchanged 1.99 Mustard 2 days Oleomargarine 3 days Unchanged Unchanged 1.31 Unchanged Orange Juice Concentrate 3 days 0.00 Unchanged Peanut 3 days 0.00 Unchanged Pebeco Tooth 1.80 Slightly 1.49 Unchanged warped, spots on drying 2 months slightly Badly softened 2.61 Powder Badly 1 week warped Unchanged 1 week Slightly 2 months 10% 3 days 1 week 28 days Killer Surface 1 year Marie stained Dreft 3 days 2 days 40 days Concentrate and slightly Unchanged Unchanged LIpstIck Pineapple 1.82 3 days ‘Coty Frozen -0.32 Mayonnaise Barb Salts Dole 2 months Unchanged Swollen Decomposed ‘Coty Pomade Paste ‘Lysol Minute Lipstlck 10.05 1 week I day I day Coty -3.27 Unchanged Max Factor Acid. MIX Lipstock Lever Tooth 3 days Butter Carbolic OrInk 2 months 3 days Unchanged refrigerator) Brilliantine 10% Lard Neutralizer and softened bleached shghtly Lady Household warped Unchanged Bleached Joy Unchanged Slightly Shghtly warped Unchanged Unchanged 4.30 1.73 Detergent 0.00 0.74 1.80 2.95 *Joy 0.56 167 I week 3.10 stained 58 1 week 4.46 Shghtly -3 Cream 1 year -1.25 -2.94 Observed Condition of Plastic LI 2 days -3.20 1 week (194°F) l- 5% I year 1 week (180°F) 1hickne! 3% Unchanged Slightly bxreaLe Peroxtde. -0.95 0.00 Percent Wei$t Peroxide, Hydrogen -2.18 -4.03 T 3 days *Hydrogen attacked (194’F) Syrup & Almond Horseradish 4 months 1 week Transformer 0.06 EXpoad (Cont) Chocolate Honey Time Tested Items Hershey’s Essenttal Sour Material Acetate Butter Powder Unchanged 3 days (100°F) 2.65 2.00 Unchanged 1 week 1.38 1.17 Stained light green showed surface Pine Bath Oil ‘Port-a-Fount Liquid Dentifrice 2 days Softened and slightly swollen (continued) TABLE 1.6: CELLULOSE ACETATES, BUTYRATES, PROPIONATES-EASTMAN Effect of Various Matwial liousahold Powder ‘Rad lime Tested ltamr EXpOpd Percent Wei& Increase CHEMICAL Chemicals and Reagents on TENITE@ Obsewed Condition of Planic hicknes (Cont.) Miscellaneous Caultmg 1 week Unchanged Spiro 1 week Unchanged Cherry &lest 1 week Unchanged Chlordane, Richard 1day Hudnut Cteme Waving (16O’Fi 1 day (lOOoF 3.57 4 90 Swollen 2.15 Unchanged Time EXpOred Observed Condition of Plastic hicknes (Coot) Compound Amolin Cleaner Acetate Material Tested Deodorants Household (continued) (average of I week ~l40’F) -2 68 -0 05 Unchanged Unchanged five brands) and showed exudation Smash Syrup Concentrare 20% CowCola Syrup Concentrate I year 2 58 1.36 3 days 1 83 3 20 Unchanged I year 0 32 132 Statned 59 0.73 Unchanged 2 months I 59 2 96 Swollen, 2 months 2 82 I 94 Very 8 months Creosote -2 sllghfly Lotion ‘2.4.0 ‘Ronronol Lighter ‘Servac 1year Fluid Detergent -5.85 -1.32 Softened and etched Decomposed 1 year Shoe Polish Kllafl 0.00 0.15 3 daYs Stained Soap, I dav 10% Type. DOT. solld DOT. 6% in Flit Type. Floor Stokely’r Cleaner Orange Tamp Cleaner Tide Detergent, Tomato Juice Weed Killer 5% Weed Killer, 0.07 Softened Wave Lotion 2.50 1.36 Unchanged Flit Insect Spray with &DOT Unchanged Inks 2 months 0.08 1.24 Shghtly I week 2.06 1.52 Unchanged 3 daYs 4.72 0 86 Unchanged Toni Wave Lotion Neutraluer 3.24 1.28 Unchanged 1.08 2 16 3 days ‘Vicks Oecongestant 2 days ‘Vitalis Hair Tonic 3days Watkins Welch’s Fly Spray Frozen (122°F ) 37.30 -1.34 2 months Grape Juice warped Badly Caner’s Cream stamed No 011 Unchanged ‘Parker ,111. Unchanged 039 Unchanged 2 months 2.80 2 months 1 48 1 week 0 38 VerY slightly softened 1.41 Very softened 0 39 Unchanged -045 slightly 4 days 069 0 00 Shghtly stamed 2 months 2 06 5 12 Stamed blue 2 weeks 204 0 62 Unchanged 2 months -4 49 Stamed black 3 52 StaIned amber 1week Black Ori.Line 1.02 Unchanged Sanford’s I week 2.25 1.03 Unchanged Sheaffar’s 1.30 Unchanged L’arkmg Black 2 days 1tOO”F) Swollen, 3 days Very 3 days Stained 1 week Lager Beer 5.28 lweek Balsam 3.93 0.00 3 weeks -0.01 26.60 22.50 2.76 0.81 Gas Antileak Compound. 2months(100°F) Gas Antileak Compound, 2 months Spmts Unchanged Mortemoth Swollen Naphfha. Swollen, softened, and stained Insecticide. Shghtly stamed stamed slightly sramed red is~encrolly unkvisfacrory for YIC tn conr~cr with TENITE Acrurc under rhr condtrlonr Yellow of rhrl StaIned 112 1 Year -6 00 -2.23 Unchanged IO days -6 5 -1.4 Unchanged 1 69 2 months 0.68 Unchanged 82 Unchanged I month -3 24 -0 1 week -1 52 -0.26 Pamts Kemtone rhor marenal liquid Industrial Ou Poor 000°F) 1month Skrip Em&Ion Mmeral vapor *Indarer Stencil Superchrome 1.74 liquid Carboreal (for Edge Sanford’s 1week 3 days Blood ‘Carboseal Bail Porn and Oenison E-Z Brite Latex Canada 10856 Oiagraph-Bradleys swollen Mioallaneour ‘Budweiser 0 00 0.38 Marking Grape Juice Wildroot 0 17 1 week felt tip pens) Considerably 0.04 addeN Cado Concentrate Welch’s I week 4 tablespoons!gal Cushman Toni (Ester 1.0 1 day (Campbell’s) Spray and warped softened 4 13 (19O’Fl 1 week I week Juice Insect softened, slightly 12.7% free acid) End-O-Weed *Stanlay 14% free acid) 4 tablespoons/gal ‘End-O.Weed Stamed Shinola (Amme 2.4-O. Oulux Outside Enamel Unchanged 1011 base) I day Unchanged (continued) TABLE 1.6: CELLULOSE ACETATES, BUTYRATES, PROPIONATES-EASTMAN CHEMICAL (continued) Effect of Various Chemicals and Reagents on TENITE@ Material Miscellaneous Time Enpored Tested Percmt Wei& increase Observed Condition of Plastic Thickness Material Miscellaneous (Cont.) Weed-B-Gon Pamts Luminall L402 One-Coat Interior. 1 week 331 1.61 Unchanged Peach (water ‘Weedone Semt-Gloss Products (All Brand) KODAK Acid White 1 week -1.20 -0.42 Unchanged- 1 week 4 46 2.56 Unchanged 1 week 3.43 2 53 Shghtly softened 1 week 4.58 2.89 Stained light amber Developer Polycarbonate Observed Condition of Plastic hicknw I month 3.32 160 Unchanged (Ester Tvpe. 2 months 2 88 1.66 very slightly swollen Weed Killer, 2 months 2.56 1.62 very slightly swollen 5 tablespoons/gal Oweloper OK.50 Increase Weight (Cont.) Weed Killer, Weed Killer Weedone Fixer *o-72 EXpored 9% free acid) (011 base) Photographic Percent Time Tested 2% tablespoons/gal emulsion1 Pittsburg Acetate Plastic (Laxan) Unchanged 3 days (lOOoF, (Polycarbonate softened, 80% R.H.) cracked when flexed) 2 days (120°F) Ouinine Refrigerants. Freon Unchanged 11 2 hours Freon 12. gas 1 month Freon 12. liquid 1 month 22, gas 1 month 2.68 0.74 1 month 0.38 0.12 Unchanged 1 month 0.55 0.56 Unchanged 01 Unchanged Showed 0.32 -3.37 0.16 -1.11 exudation Unchanged Unchanged Freon ‘Freon Freon Freon Solvex Stoddard Super 2 lb/l0 Scale Solvent Fly Spray Paint and Varnish ‘Taxite Remover U.S.P. 61% (12%solution) Solvex -1.30 3 days -0.05 1 week of Green Soap. Toxaphine, 1 month -1 gal Market ‘Tincture Ultra 114, gas 114. liquid Mamtenance Retarder. Unchanged Dissolved 22, liquid Oescaling Agent. 0.12 0 00 Unchanged 0 00 Unchanged Swollen, partially 7.98 Swollen, slightly 1.94 2 50 Unchanged 3 00 1.45 Unchanged 1 day 2 months 3 days 1 month (100°F) -3.59 3 lb/IO gal Varsol No. 2 Solvent 1 week water I year 3.09 1.96 Unchanged 1 month 1.90 1.74 Unchanged ‘Weed-B.Gon Type, Weed Killer 13 8% free acid) (Ester -1.60 -0.28 Unchanged dissolved softened i Tl ?NITE, Most tests were conducted by placing dry, injection-molded Most figures given are the result of a single test, and the measured gains in weight and thickness without tions rounding. were aqueous. Unless stated otherwise, tests were of TENITE Acetate specimens in contact with the other material for the period of time shown. conducted are reported exasrly, at 73’F (23’C) and solu- (continued) TABLE 1.6: CELLULOSE ACETATES, BUTYRATES, PROPIONATES-EASTMAN CHEMICAL (continued) Effect of Various Chemicals and Reagents on TENITE@ Time Exposed Material Tested Percent Werght Increase Observed Condrtion of Plastic Thickness Material CHEMICALS Alcohols, Acids 2.07 2.38 Slightly softened Slightly softened 13.60 0 58 Softened 2 days 1.25 0.00 Unchanged 8 days (100°F) 2.00 0.13 Slightly stained 1.64 0.78 Slightly softened 1.38 0.62 5% 1 year Acetic, 10% 2 months *Acetic, 30% 2 months Acetrc, Boric, 5% Chromic, 6% Citric, 10% 4 months Citric, 10% 1 year 69% 4 months *Citric, 3.59 5.22 fl4O”Fl (140°F) and wollen Monohydric 2 days 6 45 ‘sec_Butyl 2 days 7 20 ltert.Butyl 2 daqs 3.62 ‘Ethyl (denatured) 1.20 Unchanged 4 69 3.57 Unchanged ‘Ethyl. 50% 10% 1 year lHydrofluoric, 10% 1 month ‘Hydrofluoric, 48% Hydrochloric, Lactic, *Nitric, Unchanged Surface slightly attacked 10.30 5.47 Slightly swollen and softened 2 days 10% 1.60 0.50 8 months Oleic 1 year 2.31 1.53 5% Alcohols, Unchanged 11.60 Softened 2 12 23.40 25 10 Very slightly Softened, softened tacky 1 year 2.02 1.24 Shghtly softened 2 days 1500 4.40 Slrghtly softened Di. and Tri-hydric Hexanedrol.1.3 Ethylene Unchanged Glycerin Phosphoric, 30% 2 months 1.26 0.80 Unchanged Propylene 50% 2 months 1.58 0.75 Unchanged “Triethylene 75% 2 months 8 24 6.10 1 year 4.24 2.10 Unchanged 1 year 0.03 0.4 1 Unchanged 2 months Glycol 2-Ethyl Decomposed Partially Swollen 2 02 Orssoived ‘Drethylene Phosphoric, *Phosphoric, 13.40 lTetrahydrofurfuryl 0.53 Drssolved 50% 1 weak Drssolved ‘n_Propyl 0.86 softened Softened ‘Methyl Methyl. 20 days Shghtly 24.70 2 days 4.45 3.30 23.00 *Isopropyl 2 months Swollen SWollen 2 davs Surface 2 months 7.20 1070 Drssolved 2 days attacked Observed Condaion of Plastic Thickness ‘Oracetone ‘Isoamyl 10% Increase Weight (Cont.) Unchanged 28% Percent - ‘n-Butyl 1 week Fluosilicic, 3% Time Exposed Tested ‘t.Ethylhexyl Fluosilicic, Formic, Butyrate 2 days (lOOoF) Glycol Glycol Glycoi Softened Unchanged 2 days 0.44 0 00 Unchanged 2 months 8.61 6 70 Softened 2 months 21.87 decomposed Bases Pvrogallic, 1 week 4% 1.08 Stained yellow 0.97 Slightly 1 year 1.50 0.74 Slightly discolored 1 year 0.91 0.31 Slightly softened, 1 year Sulfuric, 10% *Sulfuric, 20% Hydroxide, Calcrum 1.60 3% ‘Ammonium Unchanged 1 wek Stearic Sulfuric, 2 56 drscolored saturated Sodrum surface *Sodium attacked *Sulfuric, 3D% 94% Tannic. 1 year ‘Trichloroacetrc, -0.29 Surface 4 months (lOOoF) Unchanged ‘n-Buy1 ‘sec.Butyl 1% 1month 3.28 0.50 Unchanged 5% 1 month 9.25 3.07 Softened Dioctyl ‘Ethyl ‘tert-Amy1 2 days 14.00 Vndicarcr ICII. rhot material isgencr4lly unsatir/ncrory for use in conr4cr wth 3 00 11.30 TENITE Unchanged Hydroxide, 1% 1 year 0.95 0.61 Unchanged 10% 8 months 3.19 2.20 Brittle 17 days 1.13 0.00 Unchanged Ammonium 5% Acetate Dissolved Acetate Dr-2.Ethylhexyl Alcohols, Monohydric 3.06 Softened EStWS 1.20 2 days 0.65 attacked 2 75 n-Amy1 1 72 Hydroxide. Trimethylbenzyl Disintegrated 10% Trichloroacetic, -0.42 12.93 1 week solutron Hydroxrde. ‘Sulfuric, 10% Hydroxide. Phthalate Acetate Dissolved Adipate 0.91 1 year 1 month (122°F) Small 0 32 Unchanged gain Dissolved Unchanged Softened, Burpore tacky under the condrrionr o/this (continued) TABLE 1.6: CELLULOSE ACETATES, BUTYRATES, PROPIONATES-EASTMAN CHEMICAL (continued) Effect of Various Chemicals and Reagents on TENITE@ Time EvJ=-t Mearia Tened Percent Wei&t Increase Thickness Observed Condition of Plastic Material Hydrocarbons Esters (Cont.) Butyrate Tnme Exposed Tested Percent Weight Increase Thickness (Cont.) ‘Ethyl Lactate Drssolved Propane, ga: 2 months 0 34 0.64 ‘Ethyl Propionate Drssolved Propane, liquid 2 months 1.42 4 55 ‘Ethylene Glvcol Monoethyl Acetate lEKTASOLVEQ Acetate; Cellosolve ‘Ethylene Glycol Ether EE (EKTASOLVE Acetate; Methyl Ether Dissolved lIsobutyl Acetate Dissolved 54.90 Softened ‘Xylene 1week 41.52 33.17 Softened 2 days 14 80 Halogenated Tetrachlorrde Acetate Acetate Acetate Oiethyl Ether shghtly softened Drssolved lChloroform Drssolved 3 days Dissolved lp-Dichlorobenzene 3 days Dissolved ‘Ethylene Dissolved ‘Methylene Chloride ‘Propylene Chlorrde Softened 11.14 11.70 Chloride end swollen Swollen Drssolved Drssolved Dissolved 3 days Softened, swollen, and tacky Dissolved Ether Di-Isopropyl Surface ‘Chlorobromomethane ‘s-Tetrabromoethane ‘Orchloro 6 80 Drssolved ‘o-Drchlorobervene Ethrfl ‘Diethyl 39.30 ‘Chlorobenzene Cellosolve Acetate ‘n-Propyl 2 days ‘Carbon Acetate) ‘Methyl Unchanged ‘Toluene Hydrocarbons, Drssolved EM l,lsoamyl ‘Isopropvl Unchanged Acetate) Monomethyl Acetate Dissolved Observed Condition of Plastic Ether 2 days 46 00 2 days 0.78 50.00 1.06 Considerably swollen Unchanged ‘Tetrachloroethane Dissolved ‘Tetrachloroethylene 12 days Badly swollen ‘Trichloroethylene 1day Badly swollen Etbn-Alcohols ‘Ethylene Glycol Monoethyl (EKTASOLVE ‘Ethylene Ether Ketones Dissolved *Acetone EE; Cellosolve) Glycol Monomethyl (EKTASOLVE Ether Hydrocarbons ‘Benzene 1year Showed in impact 5% aromatic content 23 days Heptane 1year Hexane 1 week Showed 1.60 2.40 *Methyl Ethyl ‘Methyl n-Butyl *Methyl lsobutyl Dissolved Ketone Dissolved Ketone Dissolved Ketone Dissolved Dissolved slight decrease in tensile strength Gas, Natural, Ketone ‘Phorone Orssolved aromatic-free Drssolved ‘Di-Isopropyl EM; Methyl Cello&e) Gas, Natural, Dissolved ‘Cyclohexanone Dissolved and increase strength slight decrease in Salts Aluminum 33% water Acetate, tensile strength and rncrease Aluminum Chloride, in impact Aluminum Chloride, Unchanged Unchanged strength saturated Alvninum Ammonium saturated Basic, 2 months 10% 2 months 2 months 3 months 1.68 1.07 1 month 2.34 1.83 0.56 Unchanged 1.48 0.71 Unchanged 0.10 0.00 Unchanged slurry snlutron Sulfate. solid Bifluorrde. Unchanged Slrghtly bleached solutron (continued) TABLE 1.6: CELLULOSE ACETATES, BUTYRATES, PROPIONATES-EASTMAN CHEMICAL (continued) Effect of Various Chemicals and Reagents on TENITE@ Material I Tested salts Clnt.) Increase Material Weight Time Tested Exposed 1rh,cknes Percent Weight Increase Obwved Chlarlde. 1 month 2.11 0 78 Unchanged Potaswm solwon Cyanide. saturated 2 months 046 0.04 Slightly discolored Nitrate, solid 1 week 0 16 0.23 Unchanged Potassium Ferrlcyanlde, Ammanurn NItrate. 10% 1week 1 65 0 75 Unchanged Potassium Sulfate. solid 1 year 0 12 0 57 Unchanged Ammomum Sulfate. solid 1 year 011 0 58 Unchanged. Potaswm Sulfate, 10% 1 year 1 36 0 37 Unchanged Ammonium Sulfate. 10% 1 year 1 30 0.52 Unchanged Sliver 2 days 1.46 0 00 Unchanged 3 days (lOOoF) 1 30 1 week 1 64 0.44 Unchanged 2 days 1 68 0 53 Unchanged Nitrate. Chloride, 2.5% 1 year 1 49 0 88 Unchanged Sadlum Acetare, Calcwm Chloride, 40% 2 months 0 44 0 00 Unchanged S&urn Aluminum Calcium Hypochlonte. 6% 1 year 6 00 Sodium Bicarbonate. Calcwm Hypochlorlte, 30% 13 days 0 77 0 00 Unchanged Sodturn Bwlfate. Calcwm Phosphate, 1 year 1.73 0 54 Unchanged Monobaw, 75 Softened and cracked Phosphate, Dlbaslc, Calcium Phosphate, lrlbaslc, Calcwm Sulfate solld solid (Gypsum). soled 58 0 58 Unchanged Sodium Blsulflte, 0 60 Unchanged Sodium Borate, I year -0 10 0.55 Unchanged Sodium Carbonate. 1 67 0 64 Unchanged Copper Sulfate. saturated solution 2 months 1 66 0 93 Unchanged 1 week Sulfate, solid 1 week 1 50 (lOOoF, 80% R H Ferric Chloride. 5% Few Chloride, Ferric Chloride. Fernc Chloride, saturated 1.25 Unchanged 20% 2 5% 1 week 2.14 0 80 Unchanged 2 days 1 53 0.52 solid Unchanged 1 week 025 Sodium Carbonate. 2 5% 1 year 1 28 Sodium Carbonate. 6% 3 days (lOOoF) 118 Unchanged Sodturn Carbonate. 10% 1 year Sodium Chlorlda, 2 54L 1 year Sodium Chloride, 10% I year 2 months 1 73 0 96 Unchanged Sodium Chloride. saturated solution 2 months 1 34 043 Unchanged Sodurn Chloride. saturated soiutlon 2 months 0 30 Unchanged Sodium Chromate, 04 Unchanged Bromide. 50% Carbonate, Aluminum 2 5% Sulfate -0 1 week -0 2 days 4 months 0 75 0 88 1 week l1OO”F 68 3 90 1100°F. Unchanged 0 93 Unchanged Unchanged Unchanged i 1 1 month H.) 80% R H.) 2 months Ltrhlum (alum). 3 days (lOOoF) 2G?h solution (100°F. Unchanged Unchanged 40% solid Unchanged 010 2 00 Bromide, Potasswm 1 week 2 months Llthwm Magnesum 2 5% 1% 63 2 months Ammomum Bulfate, -0 10% Ferric Sodium -0 (CuprIcI, solid solId 1 year Sulfate solld Sulfate, 1 year copper Chloride, 3% 4 days 80XR salld Calwm 10% 2 5% Calctum -3 -0 Unchanged saturated Unchanged Unchailged 1 33 (140°F) 1 week 0 54 Unchanged 0 79 0 31 Unchanged 0 89 0 89 Unchanged 0 57 0 20 Unchanged 0 28 Unchanged solution 04 0.00 Unchanged Sodium Cyanide, 10% 155 1 00 Unchanged Sodwm Cyantde. saturated 1.94 084 Unchanged Sodium Ferrocyanlde, Sodium Fluoride. 21% 1 02 2 months solution solId 4% 2 months -0 18 -0 44 Unchanged 1 week 0 84 Unchanged 1 month 245 Unchanged Potawm Brcmlde. 3% 3 days (100°F) 1.30 Unchanged Sodium Hypochlorlte, 13 days 111 09 Unchanged Potasswm Chloride, solId 1 year 0 09 0.47 Unchanged Sodium NItrate, solld 2 months 0 08 0 12 Unchanged Potassium Chloride, 10% 1 year 1 66 0 44 Unchanged Sodium Nltrate, 10% 1 year 1 23 0 42 Unchanged 3otassium Chrome 3 days (100°F) 1 33 Unchanged Sodiurr N~rrafe, saturated 2 months 0 92 0 39 Unchanged 3otasswm Cyanide. 2 months 1 40 Sodium S~hcate. solid 2 months 0 30 0 20 Unchanged Alum. 10% 10% (brown) solution Ammonwm Cuprous Condttion of Plastic Thickness salts nMlt.) Ammonium saturated Percent Tume Exposed Butyrate 0 32 Shghtly discolored (brown) 30% soiut1on -2 (continued) TABLE 1.6: CELLULOSE ACETATES, BUTYRATES, PROPIONATES-EASTMAN CHEMICAL (continued) Effect of Various Chemicals and Reagents on TENITE@ Butvate -r Time fasted Material Expnred Percent I “crease Weight thickne! 2 months 1.16 0.13 l- Observed Condition of Plastic Material selts (Cont.) Sodium Miscellaneous Silicate, saturated Sodium Sulfite, 10% 1week 2.08 Sodium Thiosulfate, 20% 13 daYs 1.10 Thiosulfate, 24% 3days Silicate 1month Ammonium I7daYs 1.13 0.06 Sodium Tetra (2Ethylbutyl) solution flOO”Fj f122OF) 0.88 0.00 1.22 -0.74 Unchanged Kant.) Unchanged Hydrogen *Methyl Unchanged Percent Weight Increase 2 months 5.87 2.34 Unchanged 1 week 2.39 0.99 Slightly solution 20 g per gallon Methacrylete Benzyl Chloride, Unchanged stained yellow Dissolved Monomer ‘Nitrobenzene Trimethyl Observed Condition of Plastic Thickness end Gases Sulfide. Hydroquinone. Unchanged -0 1 Chemicals saturated Unchanged Time Exposed Tested Dissolved Ozone. 0.05-0.15 Ozone, 0.7 ppm ppm 45 daYs (outdoors) Unchanged 45 daYs (120°F) Yellowed I week Decomposed 5% Zinc Chloride (hYdroussalt) I week 0.53 0.00 Unchanged Zinc Chloride, saturated 1 week 1.37 0.78 Slightly Zinc Oxide, solution 1week sohd *Phenol etched ‘StYrene Unchanged Sulfur, Chemicals and Gases Mii&neous Ammoniated Mercury I week (60°C) Oissolved ‘Benzeldehyde Dissolved I,3, Butedrene- liquid S months gas 1month 26.40 2.72 2.34 Unchanged Softened Oisulfide 1 week 25.62 1.56 *Carbon Oisulfrde, ? days 1740 11.75 Swollen end softened dry ‘Chlorine, moist *Chlorine, saturated solution I week I week I week Dioxrde, dry 2 months 19.40 8.60 ‘Sulfur Dioxide. moist 2 months 31.90 10.20 Swollen, slightly warped 8.60 2.22 7.77 0.14 *Sulfur Dioxide. saturated ‘Sulfur Dioxide in Hydrocarbons ‘Sulfur Dioxide and Hydrocarbon ‘Trtanium Warped swollen and solution 2 months 23.20 I6 10 Swollen and warped Drssolved 2 months 19.20 11.50 Swollen Tetrachloride Trinitrotoluene (TNT). water COMMERCIAL AN0 NATURAL slurry 3 days Very 4 weeks Stained brittle 3 weeks (122°F) Unchanged Crazed and brittle Crazed and brrttle Consrderably softened and PRODUCTS Aeronautical swollen and Automotive Dane Head Radiator l1,4-Oioxane Consrderably Vapor and swollen atmosphere ‘Chlorine, Unchanged *Sulfur warped 1925 *Carbon saturated I week solid Unchanged *Aniline ‘Butedrene-1.3, Dissolved Monomer Sealer Hems Drssolved Ethylene Oxide. gas IO minutes lEthYlene Oxide, gas I daY Formaldehyde, (105”FI 4% IO min per day 35% ! months Unchanged 20.85 25.60 0.24 Swollen and softened Unchanged *Amoco Regular ‘Amoco Premrum Aviation for 5 days ‘Formaldehyde, Gasolines, 12.96 6.74 Swollen and softened 100 Octane (Standard ‘Avtation ‘Furfural Dissolved Hydrogen Peroxide, 3% I year 1.72 1.07 Unchanged Hydrogen Peroxide, 5% 1.40 1.30 Unchanged Hydrogen Sulfide, dn/ 2.26 0.81 Unchanged Hydrogen Sulfide, moist ! days ! months ! months 3 04 1.65 Unchanged 1Year 1Year 5.5 Swollen 9.5 Swollen and stemed Yellow 1 Year 3.03 3.20 Slightly discolored 1 Year 5.21 6.06 Slightly stained 9.8 Swollen and stained pink Oil Company) 115145 (SoconY 7.7 18.4 Vacuum Octane Oil Company) ‘Exxon Extra 1 Year 13.9 Regular 1Year 5.77 Swollen and stained pink *Shell High.Test I Year 11.9 7.5 Swollen and stained pink *Shell Regular I Year 9.9 8 1 Swollen end stained Yellow ‘Exxon 5 19 (continued) TABLE 1.6: CELLULOSE ACETATES, BUTYRATES, PROPIONATES-EASTMAN CHEMICAL (continued) Effect of Various Chemicals and Reagents on TENITE@ Bun/rate Material Aeronautical Percent Time EXPOrag Tatted Weight Increase Thickness Observed Condition of Plastic Itams and Automotive Matenal Aeronautical and Automotive Weight Increase Thickness Observed Condition of Plastic Items (Cont.) (Cont.) ‘Texaco Fire Chief 1 year 9.7 ‘Texaco Sky Chief I year 15.0 7.0 Swollen and stained yellow Purol 12 1 Swollen and stained pink Shell DIala 011 AX HD, SAE IO STP Hydraulic Super 3 Brake FluId Pant No. 7 Heavy-Duty 1 week Screwdriver allowed Brake Fluid (VV&860) Swollen handle dipped in iluid and and softened requirement of Federal Head Brake Fluid lSkydrol Hydraulic ‘Skydrol 500 Hydraulic Wagner 21-6 Jet Propulsion Swollen Fluid Fuel IA 0.00 -0.16 0.09 4waeks (122’F) 30 minutes 011 0.00 Unchanged Unchanged 0.17 (15O’F) 5 weeks (140°F) Nonanomotive 1 week Fluid Low 10 Unchanged -1.09 -0.09 Unchanged Specificatmn Fluid Brake -0 -0.08 Oil, MIL-L.6448 Temperature Zerolene GGG-S-12ld. *Indian No. 50, 1692 Winsorlube Dissolved to stand 3 days passed torsional 6 months 2 months 2 weeks Texaco Fluids: lOelco ‘Do Percent Time ExP=d Tested 1 weak and stained Essential Greases and Oils 011s. Dissolved Dissolved ‘Bitter Dissolved ‘Citronella 2 days 6.10 4.20 Slightly softened ‘Eucalyptus 2 days 0.45 1.01 Slightly softened Lavender 2 days 0.69 0.51 Unchanged Lemon 2 days 041 0 00 Unchanged 2 days 5.40 4.50 Slightly Swollen and softened 8 months 3.42 3.01 Unchanged 6 months 3.87 3.22 Unchanged Almonds (Shell Oil Company) Jet Propulsion (Eao Fuel 3 Standard Jet Propulsion (Humble 1.41 1.32 Unchanged Fuel 4 Standard Jet Propulsion 6 months 3.39 3.22 Unchanged 8 months 0.29 0.32 Unchanged softened Dissolved ‘Spearmint Sweet Oil Company) Jet Propulsion (Eao 1 year Fuel 3 lPalmarosa *Pennyroyal Oil Company) Dissolved Orange Terpineol 2 days 0 26 0.88 Unchanged 2 days 0.56 0.00 Unchanged 1 year 99.20 62.62 Oil Company) Fuel 5 “Thyme Dissolved ‘Turpentine (Shell Oil Company) Softened, swollen, surface attacked Kerosene 1 week 0.41 1.32 Unchanged Oils: ‘Vanilla (Imitation) 2 days 11.80 9 70 ‘Wmtergreen Aeroshell No. 2 2 months 0.27 0.00 Unchanged Aeroshell No. 12 1 year 0.60 0.34 Unchanged Aeroshell Turbine 3 days (12O’F) 0 0 4 weeks 0.04 Bearing Oil No. 300 Guard Oil Unchanged Fuel 011 iL1 1 week Fuel 011 f2 1week Unchanged Oil 1 day Unchanged 011 Heavy Machine Light Machme DuoDrive Oil 4 waeks (122°F) Houghton Safe 1120 1 week Lubricating MIL-L-7808 Unchanged <1 <1 handle dipped in oil and Oil Oil Screwdriver allowed to stand 3 days passed torsmnal requirement GGG-S-121d. of Federal Specification Unchanged Dissolved Unchanged 1 day Unchanged Linseed 011 I month Unchanged Mmeral Oil 4 months Unchanged Neatsfoot NO.OX-IO 011 011. Dow-Corning -0.16 #200 Unchanged Unchanged Slightly 3 days (14O’F) Grease Pme Bath 011 Sihcone -0.40 6 weeks stamed 1 week 3.87 3 10 Unchanged 3 months 0 77 0.16 Unchanged (continued) TABLE 1.6: CELLULOSE BUTYRATES, ACETATES, PROPIONATES-EASTMAN CHEMICAL (continued) Effect of Various Chemicals and Reagents on TENITE@ Time Exposed Nonsutomotive l- Percent Weight Increase -r Observed Cnndltion of Plastic hicknes Tame Exposed Greases and Oils Hotwhold (Cont.) Sdicone IO days (16O’F) Grease No. 44 (Dow) StaIned yellow, properties unaffected Sour Crude 6 months Oil 6 40 2.24 1 week Soya 011 Sperm Oil 1 week Sperm Oil 1 week (194’F) Detergent. 5% Dwin Household Insect Dwin Stainless Unchanged Glim Detergent Unchanged Glim Detergent, -0.78 0 00 Unchanged -0.48 0 00 Unchanged Handy Andy Killer Fly Spray 10% Detergent Chocolate Syrup 131 0.50 Unchanged 018 00 Unchanged 1 week 0.51 0 38 Unchanged 2 monrhs 2 54 1.31 Slightly 2 months 147 0 60 Unchanged 1.97 1.50 Slightly 1week 1 30 048 Unchanged 1 week 1 20 1 50 Unchanged 1 46 0.80 StaIned 1 50 1.05 Unchanged 2 months 3 48 4.07 Slightly 2 months 1 67 0 82 Unchanged Unchanged Hind’s I week (77°F) -0.90 -0.92 0.22 Oil, Pyranol 0.00 Unchanged HorseradIsh 3 days Transformer Oil, Pyranol 1 week (194°F) -0.74 0 00 Unchanged Iced Coffee 1 week Oil Oil 1 week 0 19 3.56 Unchanged 2 days 0.12 0 00 Unchanged Honey ‘Air-Wick Items Odor Neutralizer 12.55 Soap Flakes 1240 Swollen and shghtly softened Joy Detergent Joy Detergent, “6-12” 10% Armour (694) Flotilla 4 days Unchanged Mioma Soap 4 days Unchanged Armour No. 99 Soap 4 days Unchanged Lard Armour Pumex 4 days Unchanged Lava Soap, saturated Atabrine Avon Cream Bon Ami. Cake saturated Borax, 2 5% ‘Breath O’Pine Brilliantine Bubble solution DIsinfectant Hair Bath Oressmg Carbohc Tomato Acid, Juice Catsup Clorox Solution Coffee Grounds Cologne Lipstlck Dart Furniture Dole Frozen Concentrate 3 days solution stained Unchanged 2 days 1 36 0 00 Unchanged Lemonade 1 week 1 63 1.01 Unchanged Lemon Juice 2 days 240 021 Unchanged Lighter FluIds 0 78 StaIned 2 days 1 42 049 Unchanged 2 days 1 53 0 52 Unchanged AMR 2 months 3 03 2 69 Unchanged Badly Energene 2 months 144 3 18 Unchanged Exxon 2 months 1 83 1.28 Unchanged Kwik-Lite 2 days 044 00 Unchanged 1 week 3 days 1.67 1 week 1 77 swollen 0 00 Unchanged 0 54 Unchanged Ronsonol 1 year 0 25 0 95 Unchanged Unchanged ZlPPO 2 months 2 17 2 05 Unchanged Unchanged 1.36 Unchanged Decomposed I week Slightly j weks 3davs Unchanged discolored Polish (Kress) I days Pineapple Juice week unror~sf~crory for USCin cmmct Very 0 54 wrrh TENITE slightly Disinfectant. “Malathion diluted Stamed 1.45 Cleanser Soap, saturated per gallon Unchanged 12 days Lighthouse Lighthouse ‘Lysol Dissolved lbtdrcarer rhm morerlol rsgrnrrally *cl,. Slightly 012 Sticks Cotv 3 days Lipstick warped 1 day (100°F) Unchanged I week 5% Unchanged 0.10 3 days Campbell’s Esther IlOO”F) 3 days (lOOoF) 1 week Oil Butter Lady Zdays yellowed Unchanged 1 week Repellent Armour Soap Cream Iced Tea insect Household and Almond warped 1 year Oil, 5in-1 Observed Candlt,on of Planic Thickness I week Transformer Wesson Increase 2 months Transformer 1 week (180°F) Percent Weight Items (Cont.1 Dreft Hershey’s G. E No. 10-C Butyrate Marie stalned Unchanged Buryrrrre under rhr condirmnr of thtr solution 5 tablespoonsful 2 days 1 38 0 00 2 days 1 28 0 00 Unchanged 2 months 6.97 4.37 Slightly I week 8.73 4 53 Softened, softened of water Insecticide. 50% spray pitted, to 0 5% Earle Talcum Powder 3 days 2 93 2 36 swollen, cloudy surface when wet Unchanged Mayonnaise 3 days Unchanged Milk 3 days Unchanged (continued) TABLE 1.6: CELLULOSE ACETATES, BUTYRATES, PROPIONATES-EASTMAN CHEMICAL (continued) Effect of Various Chemicals and Reagents on TENITE@ TlWX Exposed Material Tested Household Minute Items Maid -I- Observed Condition of Plastic hickne GrapefruIt ‘Tmcture Juice Lemonade Juice Detergent 146 0.64 Unchanged 1 week 1.34 0 62 Unchanged Toni Wave Lotlon 1 week 1.36 0.56 Unchanged Toni Wave Lollon 1week 1.41 0.46 Unchanged O’Cedar Furniture Old Dutch Polish Cleanser, saturated 3.42 2.74 Slightly Stamed (Potassium Observed Condition of Plastic ‘hickner LISP 9 82 6 56 Shghtly softened 3 days 173 0 62 Slightly stained 3 days 2 23 0 78 Unchanged 0 00 2 monrhs yellowad Bromate Swollen 2 days 1122°F) VapoRub 2 days 0 13 Va.Tro.Nol 2 days 0.14 2.30 0.50 0.12 0.45 Unchanged Vicks 2 days 1 30 0 00 Unchanged ‘Vitalis Salve Solution Hair Tome Watkin’s Frozen Grape Jwe 0.00 33 90 3 days Fly Spray Welch’s yellow Solut~anl Vicks 11 days Unchanged Neutralizer Decongestant 2 days 3 days Percent Increase Weight (30% alcohol) solution Oleomargarine -r (Cont.) 1 week 1 year Mustard Items of Green Soap, ‘Vicks Mr. Clean Tbme Exposed Materml Tested Household Concentrates Jwce Tangerine Percent InneaSe Wei*t (Cont.) Frozen Orange T Butyrate and stalned Unchanged Unchanged Swollen and softened 2 months 217 108 Unchanged 1 week 1 30 0.53 Unchanged 1 week 1 52 0 64 Unchanged 1 week 0.19 3 56 Unchanged 1.10 0.98 Concentrate Peanut Butter Pebeco Tooth Penicillin 3 days Powder 3 days (lOOOF) (powder) Unchanged 4.00 6.00 1 week (100°F. Welch’s - Unchanged Wesson 80% R H.) *Perfume Pme Bath Oil Grape Juice Unchanged Oil Wildroot 2 days 34 80 29 10 1 week 3 87 3 10 Swollen Wisk Cream Powder Liquid Denttfrlce ! days 16.70 Unchanged 3 days Detergent 1 year Swollen, shghtly crazed and Plastics 3 days (lOOoF. Polycarbonate Deodorants I week I week I week I week Amalin cluest Pride Wax Unchanged Polyurethane 3 days 1100°F. Foam Unchanged 3 01 2 25 1 days (120°F) Unchanged Vinyl Plastlsol (cured) 2 days (140°F) Softened Shghtly Vmyl Plastic. semwtgid 3 days (lOOoF. Unchanged softened Polish (Woolworth) Richard Hudnut Cream !vavlng 0.70 I 4 days 1 day (lOOoF) Unchanged Slightly 1.65 1 60 stained Unchanged Lotion Servac Cleanser, Floor Stokely’s 0.22 0.22 Unchanged solution Detergent Stanley ’ i days Cleaner Orange Temp Cleaner Tide Detergent, Julce Amway L.0.C ‘Bitumastic No Detergent 1 year 104 Unchanged ‘Carboseal 1 week 1.8 0.06 Unchanged liqwd 1 week 1.66 0.69 Unchanged ‘Carboseal Unchanged vapor 5% Unchanged Caulkmg -0.24 dw 2 months 1.58 0 20 Unchanged 30 days il22OFi Cone 50 32 6 3 days 24.9 Lager Beer Balsam (Average Softened, swollen Unchanged 1 week Budweiser Canada 1 i Miscellaneous Blood saturated and distorted Unchanged 1 day (16O’F) Cleaner Radiant Unchanged 80% R. H.) 80% R H I Ouinine Sane-Genio Unchanged 80% R H.) Spiro Rad Household DIscolored Unchanged Polymers ‘Pan-a-Fount Oil 1 week 2.71 0.77 3 weeks 0 85 0.34 Unchanged Gas Am-leak Compot rnd. :2 months (100°F) 26.90 23 20 Gas Anti-leak Compo; md, :! (1OO’Fl 9.56 8.80 Slightly 0 97 0 80 Unchanged months I week Compound Softened, swollen, and stalned statned of five brands) (continued) TABLE 1.6: CELLULOSE ACETATES, BUTYRATES, PROPIONATES-EASTMAN CHEMICAL (continued) Effect of Various Chemicals and Reagents on TENITE@ PfXCWl Exposed Miscellaneous 3 33 2 42 Unchanged 5.45 Softened 3.60 Slightly Miscellaneous 3 days 20% 1 year ‘Creosote (Amine Material of Plastic .hieknr (Cont.) Chlordane, ‘2.4-D Observed Condition Weight Type). 11.65 4 months Undiluted 5 02 four per gallon 4 months 1.53 7.61 Very ‘Carter’s swollerl and soitened sllght& Weed Killer (12.7% ‘Endowed per gallon Type). 4 months 19.50 8.19 as free acld) Weed Killer. spoons (Ester 4 table- Felt-TIP Dyna-Flo and dw 4 months Pen Ink Liquid 3.47 1.31 Slightly softened Cluick Drying Ink Ink (122°F) -0 Softened 159 Softened, 60.65 30 50 Softened. swollen I week Unchanged Slightly swned stained 1.56 Inc, 18 days 20 05 Black 3 days Stained Ink Sheaffer’sSkrip StaIned 1.44 (Formulab. Dri.Line Marking 07 3 days (lOOoF) 3 days Ink 1 month 4.09 2 40 1.11 0.31 Unchanged ye!low Latex Unchanged 1year Emulsion 250 Insecticide 48 hours (lOOoF. Unchanged Surface etched 80% R. H.) Cherry Smash Coca-Cola 32 00 21.8 2 days (100°F) Syrups. Cherry 38 40 IO days Blue No. 353) and swollen Malaphos Fountain Condnion of Plastic 1 week 3 days (100°F) Stencil Superchrome Sanford’s 1 month Phosphate, Observed Thickness Pens) Parker Dissolved (20% Disodium Fertilizer, swollen, of water Resin Fertilizer IncreaSe colored Hardener Epoxy Softened, Ink & Denison ‘Diagraph-Bradley Undiluted ‘Epoxy No 4,715 ‘Cushman swollen of water ‘Endoweed Percent Weight (Cont.) (For tablespoons Time Exposed Tested inks (14% tree acid) 2.4-D. Butyrate Concentrate Concentrate Grape Lemon 1 year 2.96 1.84 Unchanged Mineral 1 year 2.08 1.04 Unchanged ‘Mortemoth 1 year 1.69 1.15 Stamed I year I year 1.61 0 00 Unchanged 3.34 1.14 Unchanged shghtly yellow 1 year 1.31 0.14 Insecticide. Yarn Size 3 days (100°F) (CPC 400) Used as suggested Remover 340 1.40 Unchanged Do Pant 1 year 3.87 3.10 Unchanged yellow Pineapple 1 year 118 021 Unchanged Root 1 year 5.02 1.15 Dwzolored 2 04 0 66 Unchanged 1.70 0.28 Unchanged Dulux (outside enamel, 3 56 175 Unchanged 2 73 , 073 by’manufacturer Softened and swollen Unchanged Unchanged Distorted. surface attacked 1 week 2 88 2 45 1 week 3.11 1 .B9 Unchanged I week 0.75 0 62 Unchanged Unchanged 1 day Luminall, one coat intenor L-402 Pittsburgh Unchanged 011 base) Kemtone and blistered paint 1 year 1668 Dnhocryl 1 year 1year 21 26 45 1 month Orange Vanilla 2.0 1week Paints Unchanged Strawberry 10 days Industrial Pepsi-Cola Beer liquid Naphtha, Pamt Maple Spirits (water Semi-Gloss emulsion) White, 011 base Gas Odorizers, ‘Pentalarm 86 (Concentrate) 1 week Badly swollen Penetrox *Spotleak 1OOB (Concentrate) 1 week Badly swollen Photographic “Spotleak 1009 1week Badly swollen (Concentrate) (All A Lobwant Kodak’ Acid Inks: Cado *Carter’s 4 days 5 09 5.37 StaIned No. 10,856 Ball Point 10 days (140°F) 1038 6.10 Stamed No. 10.656 Ball Point 2 months 12.85 7 00 Stamed 4 weeks (122°F) -0.9 -0 I Unchanged Products Brand) Fixer 1 week 2 I6 0 85 Unchanged Developer O-72 1 week 2 20 0.91 Unchanged Developer DK-50 1 week 2 33 0 80 Unchanged Ink *Carter’s (continued) TABLE 1.6: CELLULOSE ACETATES, BUTYRATES, PROPIONATES-EASTMAN CHEMICAL (continued) Effect of Various Chemicals and Reagents on TENITE@ Material Time Exposed Tested Percent lncreare Obwved Condttton of Plasttc Thxkness Weight Material Mivxllaneour (Cont.) Miscellaneous Photographic Products- Ultra Ektachrome@ Processing l/3 K!t 1 week 3.05 0 55 Hardener 1 week 1.56 0.28 Unchanged Color 1 week 1.56 0 82 StaIned 1 week 1.56 0.28 Unchanged Developer Clearing and Fixmg Solution Stamed yellow dark amber Bleach 1 week 1 45 0.28 StaIned Stabliizer 1 week 2.30 0.28 Unchanged Dercallng lb per gallon Agent, No. 2 Solvent Water. dlstllled ‘Weedone 1 month 0 88 1 month 22. gas 0 20 1875 1 month 9 50 4 28 1 Slightly swollen Unchanged ‘Freon 22, liquid 3 days Weedone 1 (Ester Weed Killer, Type). 1.50 040 Unchanged 1 week 1.14 0 94 Unchanged Unchanged Type). 1.66 2 months 0 74 27.32 14.00 Unchanged Softened, swollen, dlscalored, and warped 5 tablespoons 2 months 1.98 0.55 Shghtly 6 58 Softened, swollen of water Weed Killer, Undlliited 1 month (Ester 1343 (13.8% as swollen. dlscafored. and warped free acid) Weed.B-Gon Wine S2 Flow 49.3 1 week (9% free acldl tablespoons OiSSOlbFd 113 0 54 hght amber Unchanged 1 20 1.70 1 year Weed Killer. Undiluted 1 month of water Varsof ‘Weed-B-Gon Refrtgerants’ Freon 12. gas *Freon 12. ltquid Fraon (Cont.) Solvex per gallon Freon Observed Condnion of Plastic Tested Urine No. E2 First Developer Butyrate Weed Killer, par gallon 112% Ethyl 1 month 2% 2 67 1.06 of water Alcohol) Softened, swollert, dtscolored. and warped 2 months 7 BB Unchanged 245 H3 Flow Freon 114. gas 114. I,qutd Freon Showersan Solvex Disinfectant Maintenance 115 lb per gallon Steel Picklmg 0.5 02 I month 0.84 0 00 Unchanged 1 month 7.76 2 37 Unchanged 12 days Scale Retarder, 1 month 1 58 1 year 1 60 Bath Steel Plckhng Bath (8% Sulfuric Acid 14% Ferrous Sulfate) Unchanged 062 ! Unchanged 1 year (140°F) 1 52 1 year 1.46 / 0 58 ! Unchanged ’ 1 .OB Slightly 0 38 Unchanged softened and specimens of TENITE Butyrate Most figures given are the result of a single test, and the measured gains in weight and thickness are reported exactly, rounding. Unless stated otherwise, tests were conducted tions were aqueous, i.e., “Acid, Acetic, 5%” indicates tested at 73OF. Unless other characteristics under “Observed Condition at 73’F (23°C) and solu- a 5% solution are specifically of acetic acid in water mentioned, of Plastic” refers only to the appearance the information given and feel of the plastic specimen. B months Solvent, liquid 3 days Stoddard Solvent, vapor 2 months Fly Spray ‘Taxi@ Pamt and Varnish Toxaphene Insecticide. by placing dry, injection-molded in contact with the other material for the period of time shown. without Stoddard Market 1.20 of water (3% Sulfurtc Acid and 8% Ferrous Sulfate) Super 1 BB Most tests were conducted 116O’F) (lOOoF -585 I -451 1 Softened 048 1 000 Unchanged 956 ! 880 Slightly stamed Slightly stalned 1 week 047 043 3 days 3 13 1 57 Dissolved Remover Unchanged 12% sOlUtlOn (continued) % TABLE 1.6: CELLULOSE ACETATES, The BUTYRATES, Effects PROPIONATES-EASTMAN of Various Chemicals and CHEMICAL (continued) Reagents on TENITE*@, Propionate :hange Thlckr Obretved Slightly Cond,tion Percent Time of Plss,,c Exposed Weight Premum 1 year Regular Change , Tfucknerr Observed Condition of Plasttc softened Dissolved Sligfwy swoiie” Dissolved ““changed ‘Carbon Softened, dlsul‘lde ‘Carbon Softened. Snftened, tetrachlorlde ‘Chioroform C,trtc Citric acid, IO’. acid (tablets1 swolien wolien Upchanged D’ssolved Softened. swolie” Softened. swoiie” Unchanged Dissolved *Ethylene acetate Dissolved 5.38 I year 1 year 4.81 2.44 5.33 5.08 ‘Shell 1 year 4.81 7.03 1 year i year 1 year 3.58 3.22 6 96 5.48 6.91 23.25 2.2 -5.6 High-Test Softened. swoIIe11 Dark yellow 35% Quick drymg Blue No. 353; Formulab. Inc. *Malath,on, 50% spray diluted ‘Nitric acid Oie~c acid Dzone. 5-l 5 pphm ozone. 70 pphm ‘Phenoi. 5% Propane (gas) Propane U,qu,di soap 501”tK’“. LISP Sodturn carbonate. 2.5% Sodium Sodzum S&urn *Sodium Sulfuric chlorade, 10% ferrocyantde Idry crystals1 hydroxide. 1% hydroxide, 10% aad. 3% ‘Sulfurs ac,d. 30% ‘TDl”elle Turpentine Water *Xylene 1 1 1 1 i year year year year year 1 week 011 HD SAE Texaco Co temperature Texaco Co temperature Sachet Wcks Dlslntegrated Unchanged Unchanged Unchanged Unchanged 080 0 9t Unchanged Unchanged Unchanged Drs,ntegrated Unchanged Shghtiy warped Softened. swollen Unchanged Unchanged Softened, saoiien Most 9.36 svrface Dark yellow P,nk and warped Yellow. slightly warped Yellow Swollen and pink 8.15 Softened, swollen. surface p,tted and cloudy when wet =50 =50 10 motor 011 2 months 6 months 1 week (122’F) 4 necks (122-F) 011 1692 low oil, MIL-L-644B 011 1692 low 01,. MIL-L-6440 powder tests an ontomate were -196 Unchanged -0 10 -030 -2.04 ““changed 0.03 -3.38 -0.64 1 month (122’F) 2 days (122°F) decongestant nc temperature -0.92 (122 Fl 4 weeks ,122 F) I year ““changed year year year year year 1 year 1 week 1 year 1 year 1 year 1 1 1 1 1 DISIntegrated ““changed Unchanged 1 week Crude oil Unchanged Unchanged Dlssoived D’ssoived Dlssnlved 1 year 1 year 45 days ,o”tdoars) 45 days (12O’F) 18 days 011 Bardah, Purol I year 1 year i year *avy Brownish yellow Pmk, wollen, and warped water to 0.5% Malathion 011: Bard& “n:ha”ged “nchanged Dlsmteglated 10% Hydrogen peroxide, 3% Methanol. 5% ‘Methanol, 100% ‘Methyl ethyl ketone *Methyl lsoamyl ketone swo,ien. Ink, wth glycol monomethyl ether (EKTASOLYE ERA Acetate1 ‘Gasolme, Regular Glycerin tieptane ‘Hydrochlor,c acid. 12.16 2 25 *Shell Regular ‘Texaco Regular ‘Texaco “Sky Ch,ef” F) ‘Ethyl acetate ‘Ethyl aicohol. 50% ‘Eulyi aicohoi. 95% Ethylene giycol ‘Ethylene g,yco, monoethyl ether (EKTASOLVE” EEI ‘Formaldehyde. 6.28 1 year ‘Esso Prenvum Esso Regular Amoco Vnchangrd month 1 I122 Gasoline, ‘Amoco swoilen conducted contact wth IS shown by placmg the were other dry, Badiy mjectmn-molded material conducted Unchanged losted at 73°F for the (23GCl. specimens perpod 01 tome ot TENITE shown stained. Proplonate Tests for whxh sottened TABLE 1.7: CHLORINATED POLYVINYL CHLORIDE PIPE AND FITTINGS-B.F. GOODRICH CPVC PIPE/FITTINGS CKEMICAL RESISTANCE The attached list is a compilation of chemical resistance data from three companies involved in the CPVC pipe, fittings and accessories market. Chemical company A company B Company C 739 Since each company has used a different scheme to report their findings, the following key will be needed to interpret the data. Company A - E - Excellent to operating limit of material G- Excellent to 80'F; material Good to maximum operating limit of S- Good to BO'F. L- Limited; may be used under certain conditions u- Unsatisfactory; not recommended Maximum operating limit is 18O'F 225'F Company B - 1 - Good for 200°F (93°C) 2 - Good for 185'F (85'0 3 - Good for 140'F (6O'C) 4 - Good for (21%) 70°F Q - Questionable NR - Not Recommended Company c - R - Recommended NR - Not Recommended R* - Reconrmended to 21O'F for pressure applications; for "on-pressure applications Acetaldehyde Acetate Solvents, Crude Acetate Solvents, Put-e Acetic Acid, 10% Acetic Acid, 20% Acetic Acid, 50% Acetic Acid, 80% Acetic Acid, Glacial Acetic Anhydride Acetone Acrylonitrile Adipic Acid Ally1 Alcohol Ally1 Chloride AlUUl Aluminum Chloride Aluminum Fluoride Aluminum Hydroxide Aluminum Oxychloride Aluminum Nitrate Aluminum Sulfate Punaonia, Aqueous Ammonia, Dry Gas Ammonia, Liquid Anrnonium Bifluoride Anaoonium Carbonate Ammonium Chloride Ammonium Fluoride, 25% Ammonium Hydroxide Arrmonim Hetaphosphete Anxnonium Nitrate Anrnonium Persulfate Anrnonium Phosphate Anreonium Sulfate Anmoniom Sulfide Atnaonium Thiocyanate Amy1 Acetate Amy1 Alcohol Amy1 Chloride Aniline Aniline Chlorohydrate Aniline Hydrochloride Anthraquinone Anthrequinone Sulfonic Acid Antimony Trichloride Aqua Regia Arsenic Acid Arylsulfonic Acid Asphalt Barium Carbonate Barium Chloride u u 1859 NR U R R S NR NR L L IJ u c S U E E R NR NR NR NR R NR R R R R R R R R R R R R NR R R R R R R R R R R NR R R R ti? NR NR R R NR R NR NR R E E E E E E E E E E E E E E E E E E E IJ S U II U u E E e L E L E E E 9 1 1 (continued) TABLE 1.7: CHLORINATED POLYVINYL canpany Chemical Barium Aydroxide Barium Sulfate Barirnn Sulfide Beer Beet Sugars Liquors Benzaldehyde Benzene Benzene Sulfonic Acid, 10% Benzene Sulfonic Acid Beotoic Acid Bismuth Carbonate Black Liquor Bleach, 12.5% Active CL2 Borax Boric Acid Boron Trifluoride Breeder pellets, fish Brine Brwic Acid Bromine, Liquid Bromine Water Butadiene Butane Butanol, Primary Butanol, Secondary Butyl Acetate Butyl Alcohol Butyl Amine Butyl Phenol Butyl Phthalate Butylene Butynedial (Erythrital) Butyric Acid Cadmium Cvanide Calcium Bisulfite Calcium Carbonate Calcium Chlorate CaIcium Chloride Calcium Aydroxide Calcium Hypochlorite Calcium Nitrate Calcium Phosphate Calcium Sulfate Cane Sugars Liquors Carbon Bisulfide Carbon Dioxide Carbon Monoxide Carbon Tetrachloride Carbonic Acid Casein Castor Oil Caustic Potash Caustic Soda A CHLORIDE E E E E u U E E E C R NR NR NR NR NR 1 E R E E E E E E E u L S L S S u S R R R R R R R 4 R R NR R NR R R NR NR i S tm S S L E E E E E E E E E u E E E E E E E E NR 1 R 1 R 1 1 1 1 1 R R R NB 4 1 R R R R R R canpany A company B 185Q R Q (continued) Chemical 1 1 1 1 GOODRICH Company Cwpany B 73Q E PIPE AND FITTINGS-B.F. R Cellosolve Chloracetic Acid Chloral Hydrate Cblaric Acid, 20% Chlorine Gas, Dry Chlorine Gas, Wet Chlorine, Liquid Chlorine Water Chlorobenzene Chloroform Chlorosulfonic Acid Chrome Alum Chromic Acid, 10% Chromic Acid, 30% Chromic Acid, 50% Citric Acid Coconut Oil Copper Chloride Copper Cyanide Copper Fluoride Copper Nitrate copper Sulfate Core Oils Cottonseed Oil creso1 Cresylic Acid, 50% Croton Aldehyde Crude Oil Cyclohexane Cyclohexanol Cyclohexanone Decalin Demineralized Water Detergents Dextrin Dextrose Diazo Salts Diesel Fuel Diglycolic Acid Dimethylemine Dimethyl Formamide Dioctylphthslste Disodium Phosphate Dowtherm Ethers Ethanolamine Ethyl Acetate Ethyl Acrylate Ethyl Alcohol Ethyl Chloride Ethyl Ether Ethylene Bromide Ethylene Cblorohydrin E S E E S II Q 4 E u U L E E 2 NR NR 4 E E E E E E e E E E S G U E canpany C 185Q 73Q NR R NR NR NR NR 4 2 R R R R R* R* R* R 1 1 R R R R 1 1 R R R R R R NR NR R R* R 3 Q 1 NR U U Q G 1 R E E E 1 E u 0 II E u U u E U U U U R NR NR R R R NR NR 1 I : 3 -. (continued) TABLE 1.7: CHLORINATED Chemical POLYVINYL Company A Ethylene Dichloride Ethylene Glycol Ethylene Oxide Fatty Acids Ferric Chloride Ferric Rydroxide Ferric Nitrate Ferric Sulfate Ferrous Chloride Ferrous Sulfate Fish Solubles Fluorine Gas Fluoroboric Acid Fluorosilicic Acid Formaldehyde, 35% Formaldehyde, 37% Formaldehyde, 50% Formic Acid Freon - 11 Freon - 12 Fructose Fruit Juices, Pulp Fuel Oils Fuel Oil with R2SOh Furfursl Gsllic Acid Gas - Coke Oven Gas - Manufactured Gas - Natural Gasoline - Refined Gasoline - Sour Gelatin GllXClse Glycerine (Glycerol) Glycol Glycolic Acid Green Liquor Aeptsne Rexsne Rexanol, Tertiary Rydrobrmic Acid, 20% Rydrochloric Acid, 0-25X Hydrochloric Acid, 25-372 Rydrocysnic Acid Aydrofluoric Acid, fOX Hydrofluoric Acid, 30% Rydrofluoric Acid, 50% Hydrofluoric Acid, 60% Rydrofluorosilicic Acid Rydrogen Hydrogen Cyanide Hydrogen Fluoride, Anhydrous Rydrogen Peroxide, 30% u E u E E CHLORIDE 1 1 1 1 1 1 E E E E E L E E 3 3 S 3 s 4 S E E 3 Chemical 739 1859 R R R R R R R R R R R R R R R R NR NR NR NR NR NR L L S E 6 NR R NR 4 2 R R R 2 2 R 2 2 2 R R R NR 4 4 4 R NR NR NR NR R* R* R NR 3 (continued) Cmpany C 4 E u E G E S S E E E E E E E S S S E G G E S S GOODRICH Cwpsny Company B NR 1 PIPE AND FITTINGS-B.F. NR Rydrogen Peroxide, 50% Hydrogen Peroxide, 90% Hydrogen Phosphide Rydrogen Sulfide, Aq. Sol Hydrogen Sulfide. Dry Rydroquinone AydroxyIsmine Sulfate Rypochloraus Acid Iodine fin Alcohol) Isopropyl Alcohol Jet Fuel, JP-4 Jet Fuel, JP-5 Kerosene Ketones Kraft Liquor Lacquer Thinners Lactic Acid, 25% Lard Oil Lsuric Acid Lauryl Chloride Lsuryl Sulfate Lead Acetate Lime Sulfur Lineolic Acid Linseed Oil Liquors, Liquers Lubricating Oils Magnesium Carbonate Magnesium Chloride Magnesium Hydroxide Magnesium Nitrate Magnesium Sulfate Naleic Acid Yalic Acid Mercuric Chloride Mercuric Cyanide Mercurous Nitrate Mercury Methyl Alcohol Methyl Chloride Methyl Ethyl Ketone Methyl Isobutyl Ketone Methyl Sulfate Methyl Sulfuric Acid Methylene Chloride Milk Mineral Oils n01ssses Motor Oil Naphtha Nsphthslene Nickel Acetate Nickel Chloride cwpa*y A B S 3 Canpsny C 185op 739 R R R R R R R R R R R R R R R R R R R R R R R R NR NR NR NR R R R u S S E E E S U G G G L G G G S E e E G S E G E E E E E E E E E E S U U S S U S E E S U E E 2 NR 9 1 1 1 1 1 1 3 NR NR NR R R R 3 2 R R (continued) TABLE 1.7: CHLORINATED Chemical POLYVINYL company A CHLORIDE c . 73oF Nickel Nitrate Nickel Sulfate Nicotine Nicotinic Acid Nitric Acid, 10% Nitric Acid, 20% Nitric Acid, 30% Nitric Acid, 40% Nitric Acid, 50% Nitric Acid, 60% Nitric Acid, 68% Nitric Acid, Anhydrous Nitrobenzene Nitropropane Nitrous Oxide OCWD3l Oils and Fats Oleic Acid Oleum Oxalic Acid Oxalic Acid, 50% oxygen ozone Falmitic Acid, 10% Palmitic Acid, 70% Paracetic Acid, 40% Perchloric Acid, 10% Perehloric Acid, 70% Perchloroethylene Phenol Phenylhydrazine Phenylhydrarine Hydrochloride Phosgene Gas Phosgene Liquid Phosphoric Acid, O-501 Phosphoric Acid, SO-752 Phosphoric Acid, 85% Phosphorous, Yellow Phosphorous, Red Phosphorous, Pentoxide Phosphorous, Trichloride Photographic Solutions Picric Acid Plating Solution, Brass Plating Solution, Cadium Plating Solution, Chromium Plating Solution, Copper Plating Solution, Gold Plating Solution, Lead Plating Solution, Nickel Plating Solution, Rhodium Plating Solution, Silver PIPE AND FITTINGS-B.F. 2 R 2 2 R G 2 G G U U S E E E U E S U E G u 6 6 S S L U E U E E E E E E E E R R R R 1 R* R* NR R NR 1 1 R R 1 R R R R R R R 1 3 2 2 Cwpany A Ccmpany B 185oF NR NR E E S S U E U (continued) Chemical E E E E G GOODRICH CCQKLXbV Company B R R R R R* R NR R R R R R R R R R R R R R R* R* R R* R* R* R Plating Solution, Tin Plating Solution, Zinc Potassium Acid Sulfate Potassium Antimonate Potassium Bicarbonate Potassium Bichromate Potassium Bisulfite Potassium Borate Potassium Bromate Potassium Bromide Potassium Carbonate Potassium Chlorate Potassium Chloride Potassium Chromate Potassium Cuprocyanide Potassium Cyanide Potassium Dichrmate Potassium Ferricyanide Potassium Fluoride Potassium Rydroxide, 0-20X Potassium Rydroxide, 35% Potassium Rypochlorite Potassium Nitrate Potassium Perborate Potassium Perchlorite Potassium Permanganate Potassium Persulfate Potassium Sulfate Potassium Sulfide Propane Propargyl Alcohol Propyl Alcohol Propylene Dichloride Rayon Coagulating Bath Selenic Acid Salicic Acid Silver Cyanide Silver Nitrate soaps Sodium Acetate Sodium Acid Sulfate Sodium Antimonate Sodium Arsenite Sodium Benzoace Sodium Bicarbonate Sodium Bisulfite Sodium Chlorate Sodium Chloride Sodium Chlorite Sodium Cyanide Sodium Dichromate Sodium Ferricyanide Sodium Ferrocyanide E E E E E E E E E E E E E E E E E E E E E L E E E E E E E S E S u G E E E E E E E E R E E E E E E E E company C 739 185oF R R R* R R NR 1 1 1 1 R R 1 1 R R R R 1 1 R R R R 1 1 1 R 2 1 1 1 1 1 1 1 R R R R R R R R R R R R R R R R R* R R R R (continued) TABLE 1.7: CHLORINATED POLYVINYL Ccmpany c=vny A Chemical CHLORIDE PIPE AND FITTINGS-B.F. GOODRICH (continued) Company Ccmpany C B Chemical A Cwpany 1859 Sodium Fluoride Sodirnn Rydroxide, Sodium Rydroxide, Sodium Rydroxide, Sodium Hydroxide, Sodium Aypochlorite Sodium Nitrate Sodium Nitrite Sodium Phosphate NR White NR Wines NR Xylem NR Zinc Chloride E Zinc Chromate E Zinc Cyanide E Zinc Nitrate E Zinc Sulfate E R R Acid Sodium Silicate Sodium Sulfate Sodium Sulfide Sodium Sulfite Stannic Chloride Stannoua Chloride Stearic Acid Stoddards Solvent Sulfur Sulfur Dioxide, Dry Sulfur Dioxide, Wet Sulfuric Acid, O-10% Sulfuric Acid, 10-50X Sulfuric Acid, SO-752 Sulfuric Acid, 80% Sulfuric Acid, 75-902 Sulfuric Acid, 90% Sulfuric Acid, 93% kulfuric Acid, 94% Sulfuric Acid, 95% Sulfuric Acid, 96% Sulfuric Acid, 98% Sulfuric Acid, 100% Sulfurous Acid Sulfur Dioxide, Liquid Sulfur Trioxide Tamic Acid R* R* R* R* NR NR R E NR 70% R c 739 Tanning Liquors Tartsric Acid Tetraethyl Lead Tetrahydrofurane Tetrahydrofuran Thicmyl Chloride Titanic Tetrachloride Toluol, Toluene Tributyl Phosphate Trichloroethylene Tricresylphosphate Triethanolamine Triethylamine Trimethylpropane Trisodimn Phosphate Turpentine urea and Urine Vinegar Vinyl Acetate Water Water, Acid Mine Water, Demineralized Water, Distilled Fresh Water, Potable water, Salt water, Sea water, Sewage WI iskey R R* R* 15% 30% 50% Company B Liquor or Xylol E 1859 R R NR NR NR NR NR NR NR NR R R 4 R 1 S U NR U S U U U U L S G E S E 1 R R E 1 R NR R R* U G G 2 2 2 G 2 G 2 G R R R R* R R* R* R R R* R R R* R E R R E R R R R U NR 1 NR NR R R 1 R R 32 Corrosion TABLE 1.8: Resistant Materials Handbook EPOXY COMPOUNDS-DEVCON Chemical Resistance of Devcon Epoxy Compounds Somple Size: l/2 ” x % ” x I“ Cure: 7 days at room temperature. Immersion: 30 days Product Name Plastfc Steel Putty Plastic Steel Lfqurd Piastrc Steel 5-Mtn Putty VG / Alumtnum Puttv VG / Alumfnum Lrqutd VG p VG / VG VG VG F VG VG VG VG VG VG U VG VG VG F VG VG VG VG U / VG F Tile Adhesrve VG F F Pump Repour Compound VG VG VG Hfqh Temp Wear ResIstant Putty VG VG / / VG VG Hugh Temp Mold Maker VG VG Tonkfte II VG VG Lrqurd VG VG Putty VG VG / F / I VG VG VG / 1 1 1 F , U I F 1 / F U F F U F VG F VG VG / / VG 1 VG VG I VG j / / VG VG j i ] 1 1 VG VG 1 VG VG VG VG VG VG VG VG VG / VG 1 VG VG VG VG ’ VG VG VG F U VG VG u U / / I u VG U U U VG VG VG VG F U U VG VG VG F F II VG VG VG leOOf VG VG / Wet Surface Reparr Puttv VG / F / Hfah lmpoct Bockma son SOIuftOn. F ‘VG’F U VG F i t VG F F F F 1 1 1 VG U F _ are Vti In Water, SOtUrOted VG VG VG VG 1 All products VG VG F F Epoxy Sealer 100 1 / ’ 1 1 ~ / ’ VG F 1 Bocktnq Compound F VG VG VG Backfng Compound U VG VG Ceromfc Puttv VG / / i / Wear Resstant HrahTemp VG / 1 Wear Reststant Puttv Ceramfc Wear Compound VG 1 1 j ’ VG VG Lraurd U VG VG 1 Carbrde Putty VG / / F I U I F 1 VG VG VG / / VG VG U U VG VG VG F u VG VG F VG U F F VG F U VG VG gasolrne, mtneral spwts, ASTM ‘3 011and propylene glycol CAUTION: Epoxres ore generally not recommended for long term exposures to concentrated ocfds and orgonfc solvents Key. VG-Very Good; F-Fas U-Unsdsfoctory TABLE 1.9: EPOXY PIPE AND FITTINGS-AMERON BONDSTRAND Series 1200 and Series 1600 are unlined epoxy products produced by the filament-winding process. Series 1200 piping offers the user a locked Q-ring joint for quick, reliable joining of either suspended or buried pipe systems, even under adverse weather conditions. For those users who prefer the rugged strenqth and performance of the QUICK-LOCK@ adhesive bonded joint, Ameron offers Series 1600 piping with its heavier pipe walls, longer spans and greater ring stiffness.. C Chemtcal Solution Chemical Solution oncen- 1, -L .3t10lY ‘C “F “C “F C 150 66 Chloroform NR NR Formaldehyde 75 24 NR NR Chlorine Gas wet NR YR Formc Acid NR G 75 24 Chlorinated Bwe NR VR Fuel O,i 210 99 NR Acrylic Acid NR NR Chlowated Wale? I-50 ppn 150 66 Gasoi~ne 150 66 NR Air 210 99 Chlorinated Water >50 pprr NR VR Glycerin 210 99 rr 210 99 Chrome ACIC NR UR Green Liquor (paper) 100 38 Y klum~num Chloride 210 99 C~tw Acid 210 99 r/ Heptane 150 66 Aluminum Nitrate 200 93 Copper Chlwde 2w 93 w Hexane 100 36 Alumuum Sulfate 210 99 Copper N~tra:e 200 93 _ Hydraulic 011s 200 93 --“F Acetic Acid 1 ACelOne A,“rnl”“rn Potassium Sulfa te O-IO% ~ Ammonla Gas Dry 150 66 Copper Sulfa% 210 99 V Hydrobromlc Aced Ammonium Chloride 120 49 Crude Oil (sweet 8 sour) 210 99 NR Hydrochloric Acid Ammonium Hydroxide 100 36 Cyclohexano’ 100 38 NR Ammomum Phosphate 150 66 Detergents 120 49 I/ Hydrofluoric Ammontum Sulfate 210 99 D~ailylpnthalate 120 49 - Hydrofluosillc Ammonium Nitrate 210 99 0-Dichlorobe?zene 150 66 NR Hydrogen Chiortde Gas 75 24 Diesel Fuei 200 93 NR Hydrogen Peroxide Barium Chloride 200 93 Diethylene Tr,anine NR VR Benzene 120 49 D,prooylene G’yco! 150 66 1/ Al?lllX? 1 “F “C Magnewm NItrate 200 93 Magnesum Sullate 210 99 rr Male~c Actd 770 77 NR Maleic AnhydrIde 150 66 NR Mefhyl Alcohoi 1w 38 v Methyl Chlor,de NR \IR NR Methyl Ethyl Ketone 100 36 NR Methyl lsobutyl Ketone 100 38 NR Methylene Chloride NR \1R Mineral Oil 210 99 NR Monochlorobenzene 1W 36 NR w NR 4R %or IX 75 24 Z-1’ NR dR Naphtha 210 99 NR NR JR Natural Gas 210 99 NR Nickel Chloride 210 99 v Nlckei N~frale 160 62 w Nickel Suitate 210 99 w 1.10% 75 24 w 10.70% NR QR Acid v NR ilR 150 66 NR JR Hydrogen Sulllde 150 66 r* N,,ric Acid’?’ lodlne (Sal @ R T) 120 43 v NI!~ Aod Acid NR O-25 O-30 NR 150 66 Ethyl Acetate 120 49 V Isopropyl Alcohol 120 43 1/ Oil (crude) 210 99 NR BornAcid 200 93 Ethyl Acrylatf 120 49 V Jet Fuel 200 93 NR Ole~c Acid 2cc 33 NR Bromine Water 150 66 Ethyl Alcoho, 100 38 r/ Kerosene 210 99 NR Perchloric Acld”l 75 24 NR Calctum Chlonde 210 99 Ethyl Benzene 100 38 NR Lactic Acio 170 77 NR Perchlowthylene 100 36 NR Calcium Hypochlonte’ 150 66 Ethy: Chloride NR \iR Latex Solulions 210 99 _ <l% 75 24 NR Calaum Nitrate 200 93 Ethyl Ether 100 36 Lead Nitrale 170 77 lr >I% NR \lR Calcum Sulfate 200 93 Ethylene Dlch,ortde NR \iR Linseed 011 200 93 NR 38 Carbon Dlsulflde 75 24 Ethylene Glyco 210 99 V Lllhium Chloride 210 99 150 66 Fatty Acids 100 36 NR L,thum Hydroxide 150 66 Black Liquor (paper mfg Carbon Tetrachlorzde Chloroacetlc Acetic Chloroacellc Acid-Glac\a Chlorobenzene - NR Phenol Phosphoric Acid _ _ 0.70% 0.2% 1W 2.25% 75 24 !5-50% 75 24 75 24 Femc Chloride 170 77 rr Magnesium Carbonate 170 77 NR m NR YR Ferric Nitrate 150 66 V Magnewm Chloride 210 39 v Polyvinyl Alcohol Em&Ion 103 38 75 24 - Femc Sulfate 210 - 210 - 39 - rr Potaswm 210 99 - I on- lued) 39 - - Magnestufr HyOroxlde jO-65% Chlonde _ I/ TABLE 1.9: EPOXY PIPE AND FITTINGS-AMERON Chemical (continued) -B Solutton SL Chemical Soiut~on Chemvzal bll “F ‘C 210 99 Sodurn Cyanide S&urn Po:aswrr Cyanide Potaw~m Fluortde 0.30% 150 66 Potassium Hydroxide 0.50% 1cO 36 Potaswm Nitrate 210 99 Polaswm Sulfate 99 Propylene Glycol 210 T 210 ’ 99 Sodturn Bromide 210 99 SDd~um Blsulfate 200 93 Sodium Carbonate S&urn Chlorate”’ c-10% 210 99 0.50% 150 66 210 99 210 99 TABLE 1.10: DURCON 1 Toluene Tr,chlorcethylene Trlethanolam!ne v Vinegar rr Water (dlslllied or delorwed: i, water (salt)“’ Y Water (fresh)“’ v NR Xylene ,, Ztnc Chloilde EPOXY RESIN-DURIRON 6 js a solid, cast thermosetting Acetic Acid, 7O?, 200°F Acetic Acid, Glacial, 200-F Acetone, boiling Acetyl Chloride, boiling Alcohol, 175’F Alum, 2OO’F Aluminum Chloride, 2@IcF Ammonium Bisulfite, 150’F Ammonium Chloride, 200-F Ammonium Sulfate, 200’F Amy1 Acetate, 2OO’F Amy1 Alcohol, 175’F Amy1 Chloride, 200cF Aniline, 15O’F Anod zing Solutions, 200 F Antimony Trichloride, 150-F Benz;Idehyde, 200. F Benzene, boiling Benzene Hexachloride, I75* F Black Liquor, 200~F Brine, 200-F Tanmc Acld Tetrachlorwthylene I epoxy which Butvric Acid, 200F Calcium Chlorate. 150 F Calcium Chloride. 200 F Carbon Tetrachloride, boiling Chloracetic 14cid . 125‘F Chlorinated \Vater, IFiO’F Chlorine Dioxide. 150 F Chlorine, IYet, 150 F Chlorobenzene, 175-F Chromic Acid, 305, ambient Citric Acid, 2OO’F Copper Sulfate, 2OO’F Cupric Chloride, 200 F Dichlorobutane, 2OO’F Dimethyl Formamide, 200-F Diethyl Sulfate, 200°F Ethyl Alcohol, boiling Ethyl Ether, boiling Ethyl Nitrate, boiling Ethylene Dichloride, 150 F Fatty Acids, 2OO’F is silica filled. Concen- Temperature Gasket ;.,.;.~ .Tartaric Acid Hydroxide Solution The following is a list of typical Ferric Chloride, 150. F Ferric Nitrate, 2OO’F Ferric Sulfate, 200cF Formaldehvde, boiling Formic Acid, boiling Hydrobromic Acid, 40$. 200’F Hydrochloric Acid, IO’?, 200F Hydrochloric Acid, 205, 200 F Hydrochloric Acid, 305, 2OQ’F Hydrochloric Acid, cont.. boiling Hydrocyanic Acid, 125’F Hypochlorous Acid, 125-F Lactic Acid, 200-F .Ilagnesium Chloride, 2OO’F Magnesium Sulfate. 200’ F ?rlaleic Acid, 200 F Malic Acid. 200 F Mercuric Chloride, 200 F hletal Plating Solutions, 150-F hlethyl Alcohol. boiling Methyl Ethyl Ketone, boiling applications I I I I “‘Where no concentration is shown, recommendations apply to any concentration up to 100% or to saturatton. %enes 5000 pipe can be expected to provide a ionger service life in thts environment. ‘J’General fluid compatibility of standard polymer used in O-ring gasket for Bondstrand Series 1200 piping. Vor water contaminated with oil or fuel, standard polymer provides suitable performance at temperatures up to 180°F (82°C). ti Standard Gasket OK NR Not Recommended - Not Tested for DIJRCON Nickel Chloride, 200 F Nickel Sulfate, 2OO’F Nitric Acid, IO%. 175-F Nitiic Acid, 5O%, ambient Nitrobenzene, 150-F Oleic Acid, 2OO’F Oxalic Acid, 200’F Perchloroethylene, 200-F Phenol, 125-F Phosphoric Acid, 85%, 2OO’F Phosphorous Oxychloride, 150’F Phthallc Acid, 2OO’F Potassium Nitrate, 200’F Rayon Spin Bath, 200-F Sea RBter, 200-F Sodium Bicarbonate, l’i5’F Sodium Bisulfate. 200 F Sodium Chloride, 200 F Sodium Nitrate. 200 F Sodium Perchlolate, 100 F Sodium Sulfate. 200 F 6. Sodium Thiosulfate, 200~ F Stannic Chloride. 200 F Sulfite Liquors. I5O’F Sulfur Chloride. 15O.F Sulfuric Acid, 305, 200 F Sulfuric Acid, ‘X-r, 150-F Sulfuric Acid, PO%, 125 F Tannic Acid, 2&I F Tartaric Acid, 200-F Thiophenol, 200 F Toluene, 175’ F Trichloroacetic Acid. 125’F Trichloroethylene, boiling Urea, 200F L’inegar, 200” F Water, boiling Zinc Chloride, 200’F Zinc Sulfate, 200’F 4 8 9. 9 $ P 6’ w x 3 3 8 * Synthetic TABLE 1.11: EPOXY RESINS-SHELL 35 Resins and Polymers CHEMICAL These amine-cured EPON resin coatings are unique because they cure at room temperature. They are outstanding for their resistance to heat, solvents, salt water, and most other corrosive materials, and have notable resistance to mechanical shock and abrasion. EPON resin coatings exhibit excellent adhesion and flexibility over wood,.ferrous and nonferrous metals, and green or dry concrete. These coatings have outstanding weatherability and the high solids content which is possible at application viscosity. Applications for these coatings are as finishes for wood, metal, and environment, as chemical resistant finishes for installed equipment Coating formulations must be supplied as two-package systems, i.e., base component containing the EPON resin. The usable working life concrete in marine and other severely corrosive where high-temperature baking is impractical. the curing agent packaged separately from the is a 10 to 15 hour period after the curing agent is added. A high solvent portant coating degree of cure is obtained overnight, but about five to seven days are required for maximum chemical and resistance properties to develop. More rapid cures can be obtained by forcedrying or baking. The most imreaction involves the crosslinking of the EPON resin with the polyfunctional amine curing agent. The epoxy systems referred to below are as follows: System 1: A fourcoat Svstembased on two coats of a long oil linseed ester red lead primer Plus two Coats of a long oil soya ester topcoat for a total film thickness of 6 to 6 mils. SWem 2: A fourcoat swtem based on two coats of EPON resin lOOl/EPON curing agent C-l 11 red lead primer plus two coats of the EPON resin 1001/C-l 11 topcoat for a total film thickness of 6 to 6 mils. Swtem 3: A four-coat system based on two coats of EPON resin lOOl/EPON curing agent V-15 red lead primer plus two coats of the EPON resin 1001/V-15 topcoat for a total film thickness of 6 to 6 mils. System 4: A two-coat n/stem based on EPON resin 815/EPON curing agent H-2 applied to a total film thickness of 8 to 10 mils. Code: R = Recommended for immersion service R(S) = Recommended for spillage only NR = Not recommended Coating Systems 1” 2 3 4 Hydrogen peroxide, 30% Sodium hypochlorit’e, 5% Calcium hypochlorite, 5% NR NR R(S) NR R NR R R Chromic acid, 40% NR Chromic acid, 5% NR R R NR NR Sulfu dioxide solutions R(S) R Chlorine water Oxidizing Agents R(S) R NR NR NR NR R(S) R NR R R Carbon dioxide R R R R Sulfur didxide NR R R R Chlorine NR NR NR Hydrogen sulfide NR R R NR R R Gases (Moist) Acids Sulfuric, 10% R(S) R(S) NR R Sulfuric, concentrated NR NR NR NR Hydrochloric, 10% R(S) R R(S) R Hydrochloric, concentrated NR R(S) R(S) R(S) Nitric, 10% R(S) R(S) Nitric, concentrated NR R(S) NR R(S) NR R(S) NR R(S) NR Phosphoric, 10% Phosphoric, concentrated R(S) NR NR R NR (continued) 36 Corrosion TABLE 1.11: Resistant Materials Handbook EPOXY RESINS-SHELL CHEMICAL (continued) Coating Systems Hydrofluoric, 10% Hydrofluoric, 30% Lower fatty, e.g., acetic, 20% Lower fatty, e.g., acetic, concentrated Higher fatty, e.g., oleic Organic food, e.g., citric 1’ 2 3 4 NR NR NR NR NR R(S) NR NR NR R(S) NR NR R(S) NR NR NR R R(S) R R NR NR R R Alkalies Sodium hydroxide, dilute R(S) R R Sodium hydroxide, concentrated R 61 R R R R R R R R Ammonium salts R(S) P Sodium carbonate R R(S) R R R(S) R R R R NR R R Calcium hydroxide Ammonium hydroxide, dilute Ammonium hydroxide, concentrated Salt Solutions (5%-l 0% concentration) Alum R Ferrous sulfate R(S) Copper sulfate R(S) R Sodium chloride Calcium chloride R Sodium sulfate Sodium phosphate Sodium acetate R R R Water NR NR NR NR R NR R R R(S) R R R(S) R(S) R R R Alcohol (methyl, ethyl, and butyl) R(S) R R R Ethers R(S) NR R R R R(S) R(S) R Ketones Phenol Furfuryl alcohol NR R(S) R(S) R NR NR R(S) R(S) R(S) R(S) R(S) R(S) Furfural NR R(S) R(S) R(S) R(S) R(S) R R(S) R Animal R R(S) R Vegetable R(S) R R(S) R Chlorine NR NR NR NR NR NR Bromine NR NR NR NR NR NR Tap Distilled Sea Solvents Chlorinated hydrocarbons (except methylene chloride) Aromatic hydrocarbons Aliphatic hydrocarbons Esters R R R l Fats and Oils Mineral Halogens (Moist) lodi ne *Esters are not recommended for continuous immersion service, only limited service. “MIBK and above. * Synthetic TABLE 1.12: FIBERGLASS REINFORCED EPOXY AND VINYL ESTER PIPING Resins and Polymers SYSTEMS-A.O. 37 SMITH- INLAND RED THREAD II Pipe: An unlined fiber glass reinforced epoxy resin pipe with the ability to solve corrosion problems in light chemical service at temperatures up to 21O’F. GREEN THREAD Pipe: Fiber glass reinforced epoxy resin pipe with a glass mat reinforced epoxy resin liner. Provides superior corrosion resistance at temperatures up to 225°F. POLY THREAD Pipe: Fiber glass reinforced vinyl ester resin pipe with a glass mat reinforced vinyl ester re.sin liner intended for use in corrosive services at temperatures to 200°F. Final liner thickness not less than ‘20 mils. Vinyl esters have better chemical resistance than epoxies in high acid concentrations and to oxidizing agents. Chemical Resistance MAXIMUM RECOMMENDED TEMPERATURE “F FOR PRODUCTS LISTED Red Green Thread II Thread Thread N.R.-Not MAXIMUM Recommended RECOMMENDEDTEMPEFIATUAE pw CHEMICAL Acetic Acrd, 10% Acetic Acid, 25% Acetrc Acid. 50% Acetlc Acid, 75% Acetic Acid. Glacial Acetone Acryhc Acid, 95% A&r(Wet or Dry)“’ Alummum Chloride. 1% Alumtnum Potasstum Sulfate, 56% Aluminum Sulfate, 50% Ammonia Gas-Dry*** Ammonium Hydroxide. 10% Ammontum Hydroxide. 26% Ammontum Persulfate. 30% Ammontum Nrtrate, 25% Anolyte Beer Benzene Benzene Sulfonic Acid, 5096 Benzene Sulfonic Acid, 75% Benzene Sulfonic Acid, 100% Black Liquor (Pulp Mill) Boric Acrd. 4% Bone Acid, 20% Bromoform Bromme Water, 4% Butyl Acetate Bury1 Cellosolve Calcrum Chloride, 37.5% Calcrum Hypochlorite, Sat’d. Carbon Disulfrde Carbon Tetrachloride Chloroacetic Acid, 10% Chloroacetic Acid, 25% Chloroacetrc Acrd, 50% Chloroacetrc Acrd, Glacial Chlorobenzene Chloroform Chlorothene Chlorine Gas, Wet t l ** Chlorine Saturated Brine d Chlorinated Water-G100 ppm Cl, Chlonnated Water-1~2CQ+mCI Chlorinated Water - Saturated $ Chromic Acrd. 5% Chromic Acid, 10% Chromic Aod. 30% Citric Acrd. 32% Coca-Cola (Syrup) Copper Sulfate, 17% Cresol 5% Cresol 10% Dichlorobenzene (Ortho) Drethylene Triamine Drmethyl Formamide 150 N.R. N.R. N.A. N.R. N.R. N.R. 210 210 210 210 150 lo0 100 N.T. 210 N.R. 210 120’ N.T. N.T. N.T. 150 210 200 N.R. N.R. 75 150 210 N.R. 120 150 100 N.T. N.T. N.R. 100’ N.R. 100 N.R. N.R. 150 N.R. N.R. N.R. N.R. N.R. 210 100 210 75 N.T. 150 N.R. N.R. 200’ 120 120 120 75 120 100 225 225 225 225 225 150 100 75 225 150 225 150 N.T. N.T. N.R. 225 225 225 N.R. N.R. 150 150 225 N.R. 120 150 120 N.T. N.T. N.R. 150’ N.R. 120 N.R. N.R. 225 200 N.R. N.R. N.R. N.R. 225 150 205. 120 75 150 N.R. N.R. 200 200 150’ 150. 75 N.R. N.R. 200 200 N.T. 200 N.T. 120 150 200 2oD N.T. N.T. 75’ 150 150 N.R. N.T. 200 200 N.T. N.T. N.T. N.T. 200 150 N.T. 150’ N.T. 120 150 N.T. N.R. N.T. 75 150 150 200 200 156 150 150 N.R. N.T. N.T. 200 N.T. N.T. N.T. N.R. N.T. CHEMICAL Dioxane Distillery Stillage Distillery Syrup Divinyl Benzene Dowanol EE Dowanol EM Dovviax BNB-Surfactant (NonylPhenol-Ethylene Oxde Condensate) Dow Latex 560 Dow Latex 700 Dow Latex 2144 Ethyl Acetate Ethyl Acrylate Ethyl Alcohol Ethyl Benzene Ethyl Ether Ethylene Glycol. 100% Ethylene Glycol-50% in Water Femc Chloride, 10% Ferric Chlonde 40% Ferric Sulfate, 10% Ferric Sulfate, 40% Formaldehyde Formic Acid, 88% Freon 12 OT 22 (Gas or Liquid) Gasolrne, 100 Octane Glycerine Glyoxal Green Liquor (Pulp Mill) Hexane Hydrdwomic Acid, 10% Hydrcbrornic Acid, 20% Hydrobromic Acid, 51% Hydrochloric Acid, 1%” Hydrochloric Acid, 10% Hydrochlonc Acrd. 20% Hydrochloric Acid. 36.5% Hydrofluoric Acid, 1% Hydrofluoric Acid, 5% Hydrofluoric Acid, 10% Hydroflweilicic Acid, 25% Hydrogen Chloride-Gas, Dry*** Hydrogen Peroxide, 10% Hydrogen Pemxide, 27.5% Hydrogen SuHie Gae*‘* Iodine (Sat’d. at Room temp.) Isopropyl Alcohol Jet Fuel (Super Refined Kerosene) Kerosene Lactrc Acid, 50% Lithium Chloride (Sat’d at Room Temperature) Lithium Hydroxide (Said. at Room Temperature) Magnesium Chloride, 24% (Mp Cf,6H,D) N.T.-Not Tested ‘F FOR PRODUCTS LISTED Red Green POIV rhread II Thread Thread N.R. 150 150 100’ 75 N.R. 75 150 150 N.T. N.T. 100. N.T. N.T. N.R. 75 N.R. 100’ 210. 210’ 210. 75 120 75. 120 100’ 210 210 150 150 210 210 75 N.R. N.T. 210 210 N.T. 100 100 N.R. N.R. N.R. 75 N.R. N.R. N.R. N.T. N.T. N.R. N.R. 150 N.R. N.R. 150 120 100’ 150 210 120’ 100’ 225 225 225 120 120 120’ 150 100’ 225 225 205 205 225 225 120’ N.R. 75 225 225 120’ 205’ loo’ 15Ql) 15ql) loQ1, 15Ql) 15Ql) 1541) 75.11 N.T. N.T. 7541) loql, N.T. N.T. N.T. N.T. N.T. N.T. N.T. N.T. N.T. N.T. N.T. N.T. 200 2clo 200 200 N.T. 75 N.T. 75’ N.T. N.T. N.T. 75’ 2Dct 200 150 200 2cxl 200 150 150 150 75 150 N.R. N.R. 150. 200 N.T. 75’ 75’ N.T. 150 120’ 150’ 225 225 N.T. N.T. N.T. N.T. N.T. 210 225 200 150 205. N.T. 225 200 210 (continued) TABLE 1.13: FIBERGLASS REINFORCED FURAN POLYMER-QUAKER OATS CHEMICALS QUACORR QUACORR is the trademark for furfuryl alcohol based resin/catalyst systems developed by the Quaker Oats Company for the manufacture of fiberglass reinforced plastic (FRP) equipment. QUACORR laminates exhibit a broad range of solvent and chemical resistance combined with excellent physical, flame spread, and smoke development properties. ACETIC for the proper application GUIDE CONCENTRATION MEDIA ACID ACETIC The QUACORR@ Media Guide provides guidelines QUACORR FRP equipment in corrosive media. MEDIA 25% 25% ACID 25% 100% (GLACIAL) 100% ACETIC ACID, CHLORIDE, SODIUM CHLORIDE, XYLENE, ACETIC METHANOL, ACETIC ANHYDRIDE ACETIC ANHYDRIDE, POTASSIUM POTASSIUM DICHLOROPHENDL, DICHLOROPHENOL, HYDROXIDE, ANHYDRIDE, - Unsatisfactory R.T. - Rcnrr Temperature (70°F to Unknown CHLORIDE, XYLENE, X X METHANOL, I50 X 150 X DICHLDROPHENOL, TRICHLOROBENZENE ACID, SODIUM ACETONE 100% I 501. X ACETONITRILE 100% R.T. X 100% R.T. X 176 X I50 X 190 X ACRYLIC ACID ACRYLIC ACID, SULFURIC ACID, METHACRYLATES, 6:60:5:5:24 WATER2. 100% (HEAVY), SODIUM ALKYD RESIN CHLCRIDE ACID MALEIC HYDROXIDE, HEXANE ALKYL (pH ACID, FUMARIC SODIUM BISULFITE, Unknown I-12) 100% (TRACE), R.T. X R.T. X 100% R.T. X Sat. 150 X Unknown HYDROCHLORIC (AQUEOUS1 gOoF) ALLYL I Ing (240) 150 100% SODIUM HYDROXIDE, HEPTANE, U X X I50 B.P. X X SODIUM ACETIC ACID, Satisfactory R.T. TRICHLOROBENZENE CHLORIDE, ALCOHOLS - X I50 B.P.(214) Unknown ACRYLONITRILE s R.T. u BROMO- BRDMODICHLCROPHENOL, METHANOL, -KEY s 100% of The data in this bulletin have been compiled from laboratory testing of QUACORR 1001/2001 laminates prepared in accordance with U.S. Department of Commerce Product Standard 15-69. Laminates were evaluated using the ASTM C-581 test method which requires total immersion of the laminates in test media. Data were obtained from coupons exposed to media for a minimum of three months and, in most cases, one year and compared to unexposed control laminates. Recommendations are based on an evaluation of the following properties: weight change, thickness change, visual appearance, flexural strength, flexural modulus, and Barcol hardness. Based on the results of one year testing in the media specified in ASTM Test C-581, this corrosion guide can also be used for QUACORR 1500 FR. TESTofEMP. @.P. - Boi SAT. - Saturated CONC. - Concentrated CHLORiDE Point ALUMINUM FLUORIDE ALUMINUM POTASSIUM SULFATE 5% R.T. X 5% I50 X 5% AMINES (ORGANIC), HYDROCHLORIC :: NITRO COMPOUNDS, Unknown B.P. R.T. (212) X X ACID Tested under Recommendation pressure. based on successful case histories. (continued) TABLE 1.13: FIBERGLASS REINFORCED QUACORR MEDIA FURAN POLYMER-QUAKER QNCENTRAT ACETATE I oh Sat. AMMON I UM BROM I DE TEMP OF S R.T. X HYDRDSEN At+t0JIUM HYDROXIDE” SULFATE, SULFURIC ACID Sat. 150 X 01 lute 250 X 20% R.T. X 100% 150 X ANILINE TETRACHLORIDE, CELLOSOLVE ACETATE CELLOSOLVE SOLVENT CHLORAL AQUA REGIA 100% 150 X BENZENE 100% 150 X 100% 100% R.T. 150 X X 100% 100% R.T. X 150 CHLORIDE 0-BENZYL-p-CHLOROPHENOL BLACK PULP MILL LIQUOR2’ Icd* SOLUT AROMATIC MLCRINATED CHLDROETHANE, SOLVENTS (TRACE). TRIHYDROCHLORIC ACID (DILUTE) CHLORINE (FREE?. ACID (MONO) X CHLOROACETIC ACID (TRI) R.T. X CHLOROFORM 150 X 150 X Sat. SODIUM CHLORIDE, ACETIC HYDROXIDE, CARBON TETRACHLORIDE, (MIXED WATER ISOMERS) X BRCMODICHLOROPHENOL, PHENOL, SCDIUM SOLVENT CHLORDACETIC (FREE13’ POTASSIUM WATER CHLORINATED CHLOROPHENOL BROMINE CHLOROFORM, ALCOHOLATE CrlLOROFORM, BORAX GUIDE X BENZALDEHYDE BENZYL MEDIA U CARBCN AfwINILIM (continued) QuACCRR ‘EST MEDIA Af+!CNIUM OATS CHEMICALS GUIDE CHLORIDE, XYLENE, Unknown 150 ANHYDRIDE, TRICHLORO- X X 95% R.T. 150 X 100% R.T. X 100% R.T. X 100% 150 X CYCLMEXANE 100% 150 X CYCLCHEXANONE 100% 150 X (312) X 100s 150 X 100% R.T. X 100% 150 X DICHLDRC- ACID, ACETIC METHANOL, 150 95% p-c%lLOROPHENOL X 100% CHLOROSULFQNIC ACIDI. BENZENE CHLCROTHENE BUTYL ACETATE 100% I I3 CRESOL BUTYL ALCOHOL lOO% 100% BUTYRALDEHYDE CALCIUM CARBON 150 DISULFIDEA’ 100% QuaCorr service Consult Technlcal Servlce 3. Maxlmum allowable concentrations In thls concentrations Recoranendation (MIXED ISOMERS) X X 100% X 2. 4. (243) HYPQCHLORITE 1. loh 3.P. N.U. X media may based on be on should be temperatures have satisfactory. successful dlscussed higher not been Testing case historles. with than deftned. Is 3.P.fll5) X Technical Service. CYCLOHEXYLAMINE DEMINERALIZED WATER 15O’F. QuaCorr recommended. servlce 100% at DICHLDRETHANE 1. Maximum low IOOl (1.2) allowable concentrations concentrations may be satisfactory. have not B.P. B.P.f212) 150 been defined. QuaCorr Test 1 ng is reccminended. X X servlce at (continued) TABLE 1.13: FIBERGLASS REINFORCED @JACDRR MEDIA FURAN ACID, :EST TEMP OF S 100-120 X Z-ETHYL X ETHYLENE WATER CHLOf?OtiYDRIN, Unknown ETHYLENE DIAMINE Unknown ETHYLENE DIBROMIDE ETHYLENE DICHLORIDE UHYLENE GLYCOL DNCENTRAT 0-DICHLOROBENZENE, HYDROXIDE (pH IO 98% HYDROCHLORIC ACID bYDROXlDE, MALEIC ACID, ISOPROPYL 190 Unknown SODIUM SODIUM MALEIC HYDROXIDE, ACID, FUMARIC ACID (2.4) 100% DICHLOROPHENOL, SDCIUM ACID, CHLORIDE, POTASSIUM XYLENE, CHLORIDE, SODIUM ACETIC FLUDE0RlC Unknown ACETIC HYDROXIDE, 150 X FDRMALIN 100% B.P.(257) X FDRMIC X FUEL OIL 100% R.T. DIMETHYL FORMAMIDE*. 100% R.T. DIMETHYL PHTHALATE 100% 300 X DIMETHYL PROPANOLAMINE 100% I50 X 100% 100% 150 3.P.(212) X 100% 100% 100% R.T. I50 3.P.(l71) X DIETHYLAMINE WATER ETHYL ACETATE X ACIDl’ FUMARIC ACID, HYDROCHLORIC ACID (DILUTE), SODIUM HYDROXIDE, MALEIC ACID, ISOPROPYL ALCOHOL, o-DICHLOROBENZENE FUMARIC ACID, MALEIC ACID, HYDROXIDE, SODIUV BISULFITE, HEXANE, HEAVY ALCOHOLS (pH FUMARIC ACID, SOOIUM HYDROXIDE, MALEIC ACID, o-DICHLORDBENZENE, ISOPROPYL ALCWOL X X * FUNDAL’ sat. II3 X ETHYL ACRYLATE 100% R.T. X 951 95% 95% R.T. I50 3.P.(l73) X FUNDAL, METHYL PARATHION FURFURYL ALCOHOL 1. Tested 2. Maxlmum lower (ETHANOL) in combination allohable concentrations with otter concentraticns may be GAS OIL, MINERAL PENlACHLCi?Df+lENOL X 1. satisfactory. not been Testing defined. Is QuaCorr recommended. ALCOHOL RESIN X media. have SODIUM HEPTANE, l-12) X ETHYLACFTOACETATE ETHYL ACID FDRMALDEHYDE IO05 CARBONATE DISTILLED ACIDl’ FLUOSILICIC FUEL DIETHYL ACID, TRI- CHLOROBENZENE DIESEL HYDROCHLORIC METHANOL, BROMODICHLOROPHENOL, ANHYDRIDE, ACID IO) o-DICHLOROBENZENE, ISOPROPYL ALCOHOL, DICHLOROPHENDL BUTYRIC GUIDE ALCOHOL 513% 7 (continued) QJACORR MEDIA DICHLOROBENZENE1’ o-DICHLOROBENZENE, (DILUTE), SODIUM OATS CHEMICALS GUIDE MEDIA FUMARIC POLYMER-OUAKER servlce al f+!axlmum allowable lower 2. SPIRIT, I part concentrations COnCentratlOnS Fundal to KEROSENE, may 7 parts be have sailsfactory. not been Testlng defined. Is QuaCorr ser~lce a+ recomnended. water. (continued) TABLE 1.13: FIBERGLASS REINFORCED QUACORR MEDIA FURAN POLYMER-QUAKER GUIDE IC+ IC DNCENTRAT GLYOXAL GREEN 40% PULP MILL LIQUOR’. 100% n-HEPTANE SODIUM ACID, HYDROXIDE, HEXANE, HEAVY HEXANE, SODIUM MALEIC BISULFITE, ALCOHOLS SODIUM ALCOHOLS (pH HYDROBRmlC FUMARIC ACID, 150 X R.T. X 150 X R.T. X X (208 X Unknown 199 X Unknown 190 X 48% R.T. BISIJLFITE, (pH l-12) FUMARIC ACID, HEPTANE, HEAVY ACID ACID HYDROCHLORIC ACID CHLORIDE (TRACE) CAQUEOUS,, ALKYL 15% R.T. 15% 25%2. I50 30%2. I50 HYDROCHLORIC ACID, ETHYLENE CHLOROI’YDRIN, HYDROCHLORIC ACID, NITRO HYCJROCHLORIC WATER ACID, PHOSPHOROUS HYDROCHLORIC WATER ACID, PHOSPHOROUS HYDROCHLORIC ACID (DILUTE), Unkrow” VINYL Unknown HYDROFLUDRIC ACI D1’ HYDROGEN HYPOCHLOROUS HYDROXIDE, MALEIC o-DICHLDROBENZENE, ACID, FUMARIC ISOPROPYL HYDROCHLORIC MONCCHLORIDE ACID, SULFUR, (VAPORS) HYD’7OCHLORIC ACID ETHANE, CHLORINATED (DILUTE), SOLVENTS 160-180 X R.T. X 19 R.T. X 6:75: 19 150 X 190 X ACID, FUMARIC ACID, II3 X Unknown 190 X ALCOHOL, ISOPROPYL ALCOHOL, MALEIC ACID (DILUTE) Unknown 190 X SODIUM HYDROXIDE, MALEIC ACID, Unknown 190 X 100% II3 X 95:5 185 X 75 X FUMARIC L ETHER MYRISTATE. L I GANC SULFURIC SULFURIC ( SOLVENT ACID, ACID EXTRACT U” know” I O+J 1, KEROSENE KEROSENE, GAS PENTACHLORCPHENOL KEROSENE, Unknown 200 X Unknown R.T. X KELEX ACID, SPIRIT, KELEX (SOLVENT ACID; LIGAND EXTRACTION); ACID, Consult Technlcal 2. Recorrnendatlon Service based on OTT temperatures successful case higher hlstorles. than 150°F. x 150 X Unknown 75 X Unknown 75 X B.P. 34% PULP MILL FUMARIC SODIUM HEAVY (266) KEROSENE ACID HYDROXIDE, X 150 B.P. 32:31:32:5 CHLORIDE MAGNEFITE HEXANE, MINERAL SULFURIC SULFURIC t4ALElC OIL, X R.T. 100% 100% 100% LlpUOR3. ACID, BISULFITE, ALCOHOLS (pH SODIUM Unknown (280) X R.T. X I50 X 190 X HEPTANE, l-12) 1. X o-DICHLDROBENZENE ISOPROPYL LITHI,UH TRICHLORO(TRACE) R.T. X ACID” ALCOHOL, HYDROCHLORIC ACID SOOIUM HYDROXIDE, MALEIC ACID, ISOPROPYL ALCOHOL SULFUR I% 100% ISOPROPYL (DILUTE), I SDf’RDPY 6:75: Unknown SODIUM R.T. X I SOPHORONE LIGAND, (DILUTE), u X R.T. 15% PEROXIDE” (ORGANIC) ACID, s WATER KEROSENE COMPOUNDS, TEMP. OF ION ACID R.T. 20:5:75 ACID CHLORIDE, KELEX HYDROCHLORIC WATER CONCENTRAT MEDIA o-DICHLORDBENZENE, 150 Unknown h __ __ TEST s - I-12) HYDROCHLORIC AMINES ACID, TEMP OF B.P. 100% MALEIC __..__.“. __ I50 100% HEPTANE, (continued) rEST MEDIA OATS CHEMICALS 1 1. Consult Technical Servlce 2. Maximum allowable concentrations have my be satlsfactoy. low 3. COnCentratiOnS Consult TechnIcal Service on on hydrofltiorlc temperatures acid not been Testing higher appltcatlons. defined. QuaCorr is recommended. than 15DoF. service at (continued) TABLE 1.13: FIBERGLASS REINFORCED ~ACDRR MEDIA FURAN POLYMER-QUAKER (continued) QUACORR MEDIA CONCENTRAT I ON MEDIA OATS CHEMICALS GUIDE TESTo:EHP. s METHYL PAP.ATH I ON, X MALEIC ACID, HYDROCHLORIC ACID (DILUTE), SODIUM HYDROXIDE, FUMARIC ACID, o-DICHLOROBENZENE, ISOPROPYL ALCOHOL Unknown MALE~~ ACID U” know” 190 X Unknown 190 X (DILUTE), ISOPROPYL 190 MALEIC ACID, SODIUM HYDROXIDE, FUMARIC ACID, o-DICHLOROBENZENE, ISOPROPYL ALCOHOL 176 X Crude 185 X METHALLYL CHLORIDE, SODIUM CARBONATE, TRIETHYLAMINE SALTS, METHALLYL ETHER OF o-NITROPHEYOL, WATER Un know” 170 X METHALLYL ETHER OF o-NITROPHENOL (CRUDE), METHALLYL CHLORIDE, SODIUM CARBONATE, TRIETHYLAMINE SALTS, WATER Un know” METHALLYL ACID, ACRYLIC CHLORIDE 100x SPIRIT, 170 Un know” 9.P.f 150) 150 INWSTRIAL X 100% 100% R.T. 150 X X 100% 100 X 100% 100% 100% R.T. 150 B.P.fl76) X X X R.T. 200 X X CHLORIDE1’ KETONE 100s KETONE based 100% on successful X 70s 150 :32:5 150 X R.T. 150 I.P.(27D) X 150 X 100% 150 X 52 51 R.T. 150 X X NAPTHA 2. ACID case hlstories. PESTICIDE 2. 3. 4. 150 X R.T. X GAS OIL, KEROSENE, 5:3l :32:32 150 X R.T. 150 235-250 l.P.(250) X 150 X I50 150 X 100% R.T. X I51 15% 15% 90s R.T. I50 l.P.(214) 150 X loos 100s loos IO01 fFUNDALj3’ 52 SOS4 RESIN PHOSF+lORlC 1. 975 Unknown H2S04) P+lENOL PHENOLIC (ORGANIC), U X X loos PERCHLOROETHYLENE 176 METHYLENE Recomndatlon 150 MORPHOLINE OLEUM (CONC. X 1. I 005 X X II3 I SOBUTY L. X II3 X 5:60:6:5:24 S loos PENTACHLDROPHENOL, MINERAL SPIRIT ACID, - l.QNOETHANOLAMINE NITRC COMPCUNDS, AMINES HYDRCCHLORIC ACID 100% METHYL 32:3l X METHYL CELLOSOLVE METHYL ETHYL KEROSENE, NITRCBENZENE METHANOL, ACETIC ACID, SODIUM CHLORIDE, POTASSIUM CHLORIDE, XYLENE, ACETIC ANHYDRIDE, DICHLOROPHENOL, SODIUM HYDROXIDE, BRDMODICHLOROPHENOL, TRICHLOROBENZENE METHYLATED ACIDl’ EST TEMP. OF 120 50:50 SULFATE MINERAL SPIRIT, GAS OIL, PENTACHLOROPHENOL NITRIC METHANOL METHANOL, SULFURIC ACID,.ACRYLIC METHACRYLATES, WATERl. FUNDAL ION MONOCHLORCBENZENE 5:60:6:5:24 METHACRYLATES, SULFURIC ACID, METHANOL, WATERI* METHYL METHYLSULFONIC ALCOHOL CNCENTRAT MEDIA IJ GUIDE ACID * X X X X X Maxlmum allowable concentrations have not been defined. DuaCorr service at lower concentrations may be satisfactory. Testlng Is recommended. Not remmended for concentrations over 51. I part Fundal to 7 parts water. Not recmnded at hlgh concentrations or hlgh temperatures. Consult Technical Service for concentrations above 5% and temperatures In excess of 15OOF. (continued) TABLE 1.13: FIBERGLASS REINFORCED QUACORR MEDIA MEDIA POLYMER-QUAKER (pH HYDROCHLORIC t-3). ACID, WATE’ EST TEMF OF S Unknown 200 X 75:6: 75:6: R.T. 150 X 19 19 POTASSIUM (PHOSPHORYL CARBONATE POTASSIUM CHLORIDE, SOCiUM CHLORIDE, XYLENE, DICHLOROPHENOL, ACETIC ACID, BRCh’4ODIWLOROPHENOL. ACETIC ANHYDRIDE, SODIUM HYDROXIDE, METHANOL, TRICHLOROBENZENE WTASSIUM FERRICYANIDE POTASSIUM HYDROXIDE POTASSIUM PERMANGANATEI’ POTASSIUM PEROXIDEl* POTASSIUM PYROPHOSPHATE PULP MILL PULP MILL PULP MILL PYRIDINE 1. 2. 3. Ll’&OR Licx~o~ LiwoR (GREEN13’ (RED)~. (wHITE)~. QUATERNARY LIQUORl. SILICON TETRACHLORIDE SLIMETROL 150 X 100% 100% R.T. 150 X X Sat. 150 X SODIUM EISULFITE, MALEIC ACID, FUMARIC ACID, SODIUM HYDROXIDE, HEPTANE, HEXANE, HEAVY ALCOHOLS (pH l-12) Unknown 150 X $00 Sat. 150 X R.T. 150 SODIUM CARBONATE, METHALLYL CHLORIDE, METHALLYL ETHER OF o-NITROPHENOL, TRIETHYLAMINE SALTS, WATER X X Sat. SLIMICIDE I50 X X (TKPP)‘* At+4044 IUM SALTS Sat. 50% 50% 60% 60% R.T. 150 X X R.T. 150 X R.T. 150 I UM CARBONATE SODIUM (2.5%), CARBONATE, SULFUROUS SODIUY CHLORIDE SODIUM HYDROSULFIDE ACID SODIUM CHLORIDE, POTASSIUM CHLORIDE, XYLENE, DICHLOROPHENOL, ACETIC ACID, BROMODICHLOROPHENOL, ACETIC ANHYDRIDE, SODIUM HYDROXIDE, METHANOL, TRICHLOROBENZENE X X X SODIUM CHROMATE R.T. 150 X SODIUM HYDROXIDE R.T. 150 X 150 150 R.T. X QuaCorr Maximum allowable concentrations have not been define low concentrations may be satisfactory. Testing Is recommended. Tested in comblnatlon with other media. Consult Technical Service on tervperafures higher than 150’F. GUIDE X X PHOSPHOROUS CHLORIDE (continued) U RED PULP MILL PHOSPHOROUS BROMIDEl* PHOSPHORUS OXYCHLORIDE CHLORIDE) OATS CHEMICALS &JACORR MEDIA ONCENTRAT ION PHOSPHORIC ACID SCRAP LIQUOR SODIUM PHOSPHATE PHOSPHOROUS ACID, FURAN GUIDE X X X X service SODIUK HYDROXIDE (3-13%), BENZENE (pH 7 10) o-DICHLORO- at 1. Consult Technical Service on temperatures higher than 15D’F. (:.ontinued) TABLE 1.13: FIBERGLASS REINFORCED FURAN POLYMER-QUAKER OATS CHEMICALS (continued) @lACORR MEDIA MEDIA CCNCENTRAT I ON SODIUM HYDROXIDE, o-DICHLOROBENZENE, ISOPROPYL ALCOHOL, MALEIC ACID, FUMARIC ACID Unknown SODIUM HYDROXIDE, HYDROCHLORIC ACID (DILUTE, MALEIC ACID, FUMARIC ACID, o-DICHLDROBENZENE, ISOPROPYL ALCOHOL Unknown SODIUM HYDROXIDE, MALEIC ACID, FUMARIC ACID, SODIUM BLSULFITE, HEPTANE, HEXANE, HEAVY ALCOHOLS, (pH I-12) Unknown SODIUM HYDROXIDE, SODIUM CHLORIDE, ACETIC ACID, POTASSIUM CHLORIDE, XYLENE, DICHLOROPHENOL, BROMODICHLOROFHENOL, ACETIC ANHYDRIDE, METHANOL, TRICHLOROBENZENE Unknown SODIUM HYPOCHLORITE” SODIUM LIQUOR PHOSPHATE, (pH l-3) SODIUM SULFIDE PHOSPHORIC SCRAP (HYDRO) SODIUM SULFIDE-HYDRO CARBONATE, SULFUROUS STANNIC ACID SODIUM CHLORIDE STYRENE SULFONIC ACID (CONCENTRATED), ACID, SULFUR DIOXIDE SULFUR, SULFURlC SULFUR CHLORIDE (MONO) SULFUR DIOXIDE, SULFURIC ACID SULFONIC SULFUR MONOCHLORIDE HYDROCHLORIC ACID ACID, (VAPCRS), SULFUR, 190 190 150 Not recomnended Maximum allowable low concentrations at higher concentrations. concentrations have may be satisfactory. not SULFURIC X :DNCENTRAT lo1 ACfD 25% 25% 25% 5@%1. 5Obl. 60%** X X X SULFURIC ACID, MEMACRYLATES, ACRYLIC WATERI* ACID, SULFURIC ACID, ISOPROPYL SULFURIC ACID, KEROSENE, SULFURIC DIOXIDE ACID, SULFONIC METHANOL, MYRISTATE 200 X TETRAHYDROFURAN 176 X Unknown 176 X I oog I50 X 100% R.T. X 160-180 TETRAHYDROFURFURYL Unknown (2.5% ALCOHOL TETRAPOTASS I UM PYROPHOSPHATE THICNYL CHLORIDE TOLUENE X TOLUENE DIISOCYANATE TOLUENE SULFONIC ACID (IN WATER) METHANOL) 300 X 200 X TOLUENE SULFONIC ACID (IN 100% 150 X TOLUENE SULFONIC ACID (PARA) TRIMLOROACETIC Unknown 160-180 X Unknown 200 X service ACID X TFI I CHLOROBENZENE , ACET I C AC ID. SOD I UM CHLORIDE, POTASSIUM CHLORIDE, YYLENE, DICHLOROPHENOL, BROMODICHLWOPHENOL, ACETIC ANHYDRIDE, SODIUM HYDROXIDE, METHANOL at 2. 1. _ Reconmwndatlon _ . . acla SdlterIc based on successful case recomnenaea to maxlmum of ~EST4EHF S R.T. I50 3.P.f216: 150 250 150 X X X X X I76 X 185 X 75 X 160-180 X 176 X 100% R.T. X 100% R.T. X 60% 60% R.T. 150 X 100% R.T. X 100% X 100% R.T. 150 1.P. (230) 100% R.T. X 70% 85% R.T. R.T. X X 70% R.T. X 180 X 50% R.T. X Unknown 150 X 100% hlstorles. 50% concentration U X Unknown 100% Unknown been defined. QuaCorr Testing is reccnmended. Unknown SULFUR Unknown 60:6:5:5:24 5:95 KELEX LIGAND ACID, SULFUROUS ACID, SODIUM HYDROSULFIDE SODIUM CARBONATE SULFUR TR10XlDE2’ 1. 2. MEDIA X Unknown SULFUR 190 u R.T. MOLTEN SULFUR, HYDROCHLORIC ACID, MONOCHLORIDE (VAPORS) s .lS 2% (2.5). ACID TESTO:EHP* GUIDE X X X and 250°F. (continued) TABLE 1.13: FIBERGLASS REINFORCED FURAN WACORR POLYMER-QUAKER MEDIA TRICHLOROETHANE (l,l,l) (MIXED GUIDE TEST MEDIA TRICHLOROETHANE CONCENTRAT I ON ISOMERS) TRICHLOROETHANE, CHLORINATED SOLVENTS (TRACE), HYDROCHLORIC ACID (DILUTE1 X 100s R.T. X R.T. X 150 B.P.(lB9) X X Unknown TRIETHANOLAMINE 100% PHOSPHATE VINYL CHLORIDE, HYDROCHLORIC (DILUTE), WATER ACID 5 R.T. 100s 100s TRIETHYLAMINE SALTS, METHYL ETHER OF o-NITROPHENOL, METHALLYL CHLORIDE, SODIUN CARBONATE, WATER TEMP. OF 100% TRICHLOROETHYLENE TRISODIUM OATS CHEMICALS II3 X Unknown 170 X sat. 150 X Unknown R.T. X WATER (DEMINERALIZED) loos loos IO01 R.T. 150 B.P.(ZlZ) X X x WATER (DISTILLED) 100% 100% 150 B.P.(212) X x R.T. 150 X X WdlTE XYLENE PULP MILL (MIXED LIQUOR’. ISOMERS) XYLENE, SODIUM CHLORIDE, POTASSIUM CHLORIDE, DICHLORORIENOL, ACETIC ACID, BROMODICHLORO~ENOL, ACETIC ANHYDRIDE. SODIUM HYDROXIDE, METHANOL, TRIMLOROBENZENE ZIRCONIUM RAFFINATE (ZIRCONIUM DXYCHLORIDE, HCI, MIBK, THIOCYANIC ACID) ZIRCONIUM RAFFINATE (ZIRCONIUM 3XYCHLORIDE. HCI, MIBK, THIOCYANIC ACID) 100% B.P.(284) X Unknown 150 X 100% R.T. X 100% 150 X u (continued) Synthetic TABLE 1.14: FIBERGLASS MOLDED REINFORCED ISOPHTHALIC POLYESTER Resins and Polymers AND VINYL 47 ESTER-MORRISON FIBER GLASS EXTREN is a proprietary combination of fiberglass reinforcements and thermosetting polyester or vinyl ester resin systems produced in standard structural shapes and sheets by Morrison Molded Fiber Glass Company. EXTREN is widely used in industrial construction and maintenance, commercial construction, and as components of industrial equipment and commercial products. The information below is based on data collected from several years of actual industrial applications. In addition it is based on conservative evaluation of the changes which occur in certain properties of replicate laminates after exposures of one year or longer, both in the laboratory and the field, according to the American Society for Testing Materials (ASTM C-581). These properties include hardness, flexural strength, and flexural modulus. Surface stability is also a major characteristic and must be evaluated. CHEMICAL polyester Series 500 and 525-lsophthalic Series 625-Vinyl ester SERIES500525 RT 160’F EXTREN RESISTANCE - NR = Not resistant R = Resistant SERIESso&525 SERIES 625 RT 160°F RT SERIES 625 RT 16c)‘F CHEMICAL CHEMICAL NR NR NR NR Ammonium Phosphate Acetlc Acid O-25% R R R R Ammonium Sulfate Acetic Acid 25-50% R NR R R Arsenious Acid Acetic AnhydrIde NR NR NR NR 0-Benzoyl Bentoic Acetone NR NR NR NR Acrylonltrile NR NR NR NR Barium Acetate Barrum Carbonate Alcoho!, Butyl NR NR R NR Barium Chloride Alcohol, Ethyl 10% NR NR R 150” Barium Hydroxide Alcohol, Ethyl 100% NR NR R NR Bawm Alcohol, Isopropyl 10% NR NR R 150” Alcohol, 100% Acetaldehyde Isopropyl Acid NR NR R R R R R R R NR R R NR NR R R NR NR NR NR NR NR R R NR NR NR NR Butyric Acid 040% R NR R R Butylene Glycol R R R R R NR R R NR NR R 120” Calcium Bisulfite R R R R Calcium Carbonate R NR R R Calcium Chlorate R R R R Calcium Chloride R R Methyl lsobutyl NR NR R 150” NR NR R 150” R R R R Benzyl Alcohol R R R R 120” Benzyl Chloride Brass Plating Solutton. R R R Aluminum Potassium Sulfate R Ammonia, Aqueous Ammonia, Gas O-10% NR NR R 100” NR NR R 100” R NR R 120” Ammonium Bicarbonate Ammonium Bisulfite NR NR R 120” Ammonium Carbonate NR NR R 120” Ammonium Citrate Ammonium Flouride R NR R 120” NR NR R 100” Ammonium Hydroxide 5% R NR R 120” Ammonium Hydroxide 10% R NR R 120” Ammonium Hydroxide 20% NR NR R 120” Ammonium Nitrate R R R R NR NR R 120” Persulfate 120” R Alcohol, fl R 120” NR Nitrate NR R NR Aluminum R NR NR NR R R NR NR R NR NR Methyl 100% R R R Alcohol, NR R R NR Beer R R R R R Benzene R R NR NR R NR 5% NR R 150” Hydroxide NP R R R R Aluminum NR R R R R Chloride NR 120” NR NR Aluminum R R R NR Alum R NR NR Butyl NR R Sulfate NR Alcohol, Secondary NR Barium Sulfide Alcohol, Methyl 10% Ammonium 160’F 5% Benzene in Kerosene Benzene Sulfonic Acid Benzoic Acid (3% 6% 1% 3% Copper Cyanide Sodum Cyamde Zinc Cyangde Sodum Carbonate) Bury1 Acerate Cadmium Chloride Cadmium Cyanide (3% Cadmwn Oxide 10% Wum Cyantde Plaling Solution: 1% Causticsoda) R R (continued) 48 Corrosion TABLE 1.14: Resistant Materials FIBERGLASS MOLDED Handbook REINFORCED FIBER GLASS SERIES 500-525 RT 160°F ISOPHTHALIC POLYESTER RT R NR R 120” Copper RT 16O'F Pickling Bath. NR NR R R R R 011 Crude Oil, Sour (10% Ferric Sulfate 10% Sulfuric Acid) Calcium Hypochlorite R NR R 120” Calcium Nitrate R R R R Copper Calcium Sulfate R R R R Corn Oil Calcium Sulfite R R R R Corn Starch - Caprylic R NR R R Corn Sugar R R R R Acid Carbon Dioxide Carbon Disulfide Carbon Monoxide NR NR NR NR R R R R Sulfate Cottonseed R R 120 R R Chlorine Dloxlde, NR NR NR NR R R R R Dichloroethylene R Diesel Fuel R Acid 040% Chlorobenzene NR NR R R NR NR NR NR R NR 100” NR R R R R NR NR NR NR NR R NR R NR NR R R R NR NR Carbon Methyl Cellulose Chlorinated Wax Chlorine Dloxlde;Alr NR NR R R NR R NR R R R NR R R R NR R R R NR R R R Chlorine, Llquld Chlortne. Water R R NR loo” Chlorine, Wet Gas R NR R Dry Gas R R R R R Wet Gas R NR NR R NR Castor 011 R Crude Oil, Sweet NR Acid Slurry R Cyclohexane NR R Carbon Tetrachloride Chloroacetlc SERIES 625 160ct- CHEMICAL Calcium Hydroxide Chlorine. ESTER-MORRISON SERIES MO-525 SERIES 625 RT 160°F CHEMICAL Carborw AND VINYL (continued) Detergents, Sulfonated Di-Ammonium Phosphate Dibromophenol Dibutyl Ether Dlchloro Benzene Diethylene Dimethyl NR NR NR NR NR R NR NR NR NR NR NR NR R NR R R R NR R R NR NR R R NR NR R R Glycol Phthalate Dioctyl Phthalate Dipropylene Dodecyl NR R NR Glycol Alcohol R NR R R NR NR R R R R R R NR NR NR NR Esters, Fatty Acids Acid NR NR NR NR Ethyl Acetate NR NR NR NR Chromic Acid 20% NR NR R R Ethyl Benzene NR NR NR NR Chromic Acid 30% NR NR NR NR Ethyl Ether NR NR NR NR R R R R Ethylene Glycol Cltrvz Acid d R R R Ethylene Dichloride Coconut 011 R NR R R R NR NR R NR NR R R R R R R R R R R NR NR R R Chloroform Chlorosulfonlc Chromium Sulfate Copper Chloride Copper Cyanide Copper Fluoride Copper Nltrate Copper Plattng Solution (Copper Cyanide 10 5% Copper 14% Copper Cyantde 6% Rochelle Salts) Copper NR Brite Platmg NR R 120” (Causttc Cyanide) NR NR R R Copper Matte Dipping (30% Few Chloride 19% Hydrochloric) NR NR R R R NR R R R R R R R R Ferric Nitrate R R R R Ferric Sulfate R R R R Ferrous Chloride R R R R Ferrous Nitrate R’ R R R Ferrous Sulfate R R R R 8-8-8 Fertilizer R NR R R NR NR R 120” Fertilizer NItrate) Flue Gas Fluosilicic Bath R NR Fatty Acids Fluoboric ‘19% Copper Sulfate 8% Sullur~c Acid) R NR Ferric Chloride (Urea Ammonium Copper Plating Solution. (45%Copper Fluoroborate R NR Acid Acid O-20% NR NR R R NR NR R NR NR R 120” R Formaldehyde R NR R R Formic Acid R NR R R (continued) Resins and Polymers Synthetic TABLE 1.14: FIBERGLASS MOLDED REINFORCED FIBER GLASS SERIES 500-525 16o’F RT ISOPHTHALIC POLYESTER AND VINYL 49 ESTER-MORRISON (continued) SERIES SERIES 625 RT 160°F CHEMICAL RT 500525 160’F SERIES 625 AT 160-F CHEMICAL R Fuel Ott R NR R Kerosene NR R R R R NR R NR NR R R Laurlc Acid R NR R R Gas. Natural R NR R R Lactic Acid Gasoline, R NR R R Laura1 Chloride R Auto R Gasoline, Aviation R NR R Gasoline, Ethyl R NR R R Lead Acetate R NR R R Gasoline. Sour R NR R R Lead Nitrate R NR R R Lead Plating Solution. NR NR R R R NR R R R R R R R NR R R Glucose R R R R Glycerine R R R R Levulinlc Glycol. Ethylene R R R R Linseed 011 Glycol. Propylene R R R R Lrthium Bromide R R R R Glycolic R NR R R Lithium Sulfate R R R R NR NR R R Magnesium Blsulflte R NR R R Magnesium Carbonate R NR R R R R R R NR NR R 140 R R R R Gluconic Acid Acrd Gold Plating Solution: (63% Potasswm Ferrocyanlde .2% Potassum Gold Cyanide .0% Sodurn Cyanide) Heptane Hexane Hexylene Glycol Hvdraulic Fluid .4% Actd Acid) BOW Acid Magnesium Chloride R R Magnesium Hydroxide NR R R Magnesium Sulfate R R R R NR R R - Hot Stack Gasses (II% Fluoborlc NR 340” - R NR R R Maleic Acid R R R R Mercuric R NR R R Chloride Mercurous Chloride R NR R R Methylene Chloride NR NR NR NR Hydrobromic Acid O-25% R NR R R Hydrochloric Acid O-37% R NR R Methyl Ethyl Ketone NR NR NR NR Hydrocyanic Acid R NR R R R Methyl lsobutyl NR NR NR NR Hydrofluoric Acid 10% NR NR R 120” R NR R R Acid NR NR R R NR NR NR NR NR NR NR NR R R R R R NR R R NR NR NR NR NR NR NR NR R R R Hydrofluosilicic Methanol Carbitol (see alcohol) Methyl lsobutyl Ketone Hydrogen Bromide, Wet Gas NR NR R R Methyl Styrene Hydrogen Chloride, Dry Gas NR NR R R Mineral Hydrogen Chloride, Wet Gas NR NR R R Molybdenum Disulfide Hydrogen Peroxide NR NR R 120” Monochloro Acetic Acid Hydrogen Sulfide Dry NR R A Hydrogen Sulfide, Aqueous R NR R R Motor 011 Hydrogen Fluoride, NR NR R R MyFIstic Acid NR NR R 120” NR NR R R Hydrosulfite ‘R Vapor Bleach Hypochlorous Acid O-10% Iron Plating Solutlon: (45% FeCIz. 15% CaCI, 20% FeSOa 11% (NH.) zSO,) Iron and Steel Cleaning (9% Hydrochloric 23% Sulfuw) Isopropyl Amtne Isopropyl PaImItate Jet Fuel Bath NR NR R NR NR R NR NR R R R R R NR R Oils Monoethanolamtne - - R R R Naphtha R R R R Naphlhalene R NR R R Nickel Chloride R R R R R R R R NR NR R R R NR R R R Nckel Nltrate Nickel Plattng. (6% Lead R 9% Fluobortc Acld 4% BOK Acld) NR R Nckel Plating. (11% Nckel Sullate 2% Nlckei Chlortde R 1% BOW Acid) (continued) 50 Corrosion Resistant Materials Handbook TABLE 1.14: FIBERGLASS MOLDED REINFORCED FIBER GLASS SERIES 500525 RT 160’F ISOPHTHALIC AND VINYL ESTER-MORRISON SERIES M&525 RT 160-F SERIES 625 FIT 16o’F CHEMICAL SERIES 625 RT 16o’F CHEMICAL Nickel Plating: (44% Nfckei Sulfate 4% Ammonium Chlorfde 4% Bone Actd) Nckel POLYESTER (continued) R NR R R Potassium Permanganate R NR R Potassium R NR R R R R R R 150% NR NR R 120” 50-100% NR NR NR NR R R R R Persulfate Potassium Sulfate Sulfate R R R R Nrtrrc Acrd 05% R R R R Nrtric Acid 20% NR NR R 120 Propylene Nrtric Acid Fumes NR NR NR NR R NR R NR Pulp Paper Mill Effluent Octanorc Acrd R NR R R 011. Sour Crude R R R R Oil. Sweet Crude Oleic Acid R R R R R R R R Nrtrobenzene Propionic Acid Glycol R NR R R NR NR NR NR Salicylic Acid NR NR R R Sebacic NR NR R R NR NR R R R R R R NR NR R R Pyridine Selenous Acid Acid Silver Nitrate Oleum (Fumrng Sulfuric) NR NR NR NR Olrve Oil R R R R Oxalic Acid R R R R R R R R Peroxrde Bleach (2% Sodium Peroxlde 96% .025% Epsom Salts 5% SodturnSlllcate. 4TBE 1.4% Sulfurtc Acid. 66-BE) Phenol NR NR NR NR Phenol Sulfonic Acid NR NR j\lR NR 140” Srlver Plating Solution: (4% Sher Cyanide 7% Potawum Cyanide 5% Sodium Cyanide 2% Potasswm Carbonate) Soaps R NR R R Sodium Acetate R NR R R Sodium Benzoate R NR R R Sodium Bicarbonate R NR R R R R Sodium Bifluoride R R Phosphoric Acid R R R R Sodium Bisulfate R R R R Phosphoric Acid Fumes R R R R Sodium Bwlflte R R R R Pentoxide R R R R Sodium Bromate R R R R Phosphorous Trichloride Phthalrc Acid NR NR NR NR Sodium Bromide R R R R .R R R R R NR R R R R R Phosphorous Pickling Acids R (Sulfuric and Hydrochloric) Picrrc Acid, Alcoholtc Polyvinyl Acetate R Latex Polyvinyl Alcohol Polyvinyl Chloride (Parts DOP) R R R NR NR R R R R R R Latex w/35 Potassium Aluminum NR Sulfate NR R 120” R R R R Potassium Brcarbonate R NR R 140” Potassium R Bromide NR R R Potassrum Carbonate R NR R 140” Potassium Chloride R R R R Drchromate R NR R ‘Potassium Ferricyanide Potassium R R R Potassium Potassium Ferrocyanide Hydroxide R NR R NR Potassium Nitrate R R R R R 140” R R 120” Sodium Carbonate O-25% Sodium Chlorate R NR R R Sodium Chloride R R R R Sodrum Chlorite R NR R R Sodium Chromate R R R R Sodium Cyanide R NR R R Sodium Dichromate R R R R Sodium Di-Phosphate R R R R Sodium Ferricyanide R R R R Sodium Ferrocyanide R R R R Sodium Fluoride NR NR R 120” Sodium Fluoro Silicate NR NR R 120” NR R 120” Sodium HexametaphosphatesNR Sodium Hydroxide O-5% NR NR R 120” Sodium Hydroxide 5-25% NR NR R Sodium Hydroxide 50% NR NR R 120” NR R (continued) Synthetic TABLE 1.14: FIBERGLASS MOLDED REINFORCED FIBER GLASS SERIES 500-525 RT 160°F ISOPHTHALIC SERIES 625 RT NR R R Sodium Hypochlorite R NR R 120” Sodium Lauryl Sulfate R NR R Sodium Mono-Phosphate R R R R R Sodium Nitrate R R R R NR ESTER-MORRISON SERIES 5Ob525 RT 160’F 160°F R R AND VINYL R R Sodium Sulfate R R R R Sodium Sulfide R NR R R SERIES RT (16% 7% 9% 2% Stannous Fluoroborate Tin Fluorobonc Ac!d Bow Acrd) Toluene Toluene Sulfonic Acid Transformer NR NR R R NR NR NR NR NR NR R R N: N; Oils: (Mneral 011 Types Chloro-Phenyl Types) Sodium Sulfite R NR R R Sodium Terra Borate R R R R Trichlorethylene NR N: NR R R NR NR NR NR NR R R Trichlorophenol NR NR NR R NR R R Tricresyl NR NR R Sodium Tripolyphosphate R NR R R R Sorbitol Solutions Sour Crude Oil Soya Oil R R R NR R NR R R R R R R R R Stannic Chloride R R R R Stannous Chloride R R R R R Stearic Acid Sugar, Beet and Cane Liquor Sugar, Sucrose R R R R NR NR NR NR R NR R R R R. R R Suifamic Acid R NR R R Sulfanilic Acrd R NR R R Sulfated Detergents R R R R NR NR NR NR NR R R Sulfuric Acid O-30% R R R R Sulfuric Acid 3040% NR NR R R Dry or Wet Sulfur Trioxide/Arr Sulfuric Acid 50-70% Sulfurous Acid NR NR R R 120” NR NR R 100’ R NR R R Tall Oil R NR R 140” Tannic Acid R NR R 120” Tartaric Acrd R R R R NR NR NR NR Superphosphoric Acid (76% PaOs) Thronyl Chloride Tridecylbenzene Trisodium Sulfonate Phosphate Turpentine Urea Vegetable 011s Vinegar Styrene Sulfur Dioxide, Phosphate NE R Sodrum Thiosulfate Sodium Xylene Sulfonate 625 160°F CHEMICAL Ttn Plating Trichlor Acetic Acid Sodium Thiocyanate 51 (continued) CHEMICAL Sodium Hydrosulfide Sodium Silicate POLYESTER Resins and Polymers NR 100” R NR R R NR R R NR NR R 100” R NR R 140 R R R R R R R R R NR NR NR NR Deronized R R R R Demineralized R R R R Distilled R R R R Vinvl Acetate Water Fresh R R R R Salt R R R R Sea R R R R R NR R R NR NR NR NR Zinc Chlorate R R R R Zinc Nitrate R R R R NR NR R 120” R NR R R R R R R White Liquor (Pulp Mill) Xylene Zrnc Plating Solution. (9%21ncCyamde 4% Sodwn Cyantde 9% Sodtum Hydrowde) Zrnc Platrng Solution: (49% Zvnc Fluoroborate 5% Ammontum Chlonde 6% Ammonium Fluoroborate) Zinc Sulfate 52 Corrosion Resistant Materials Handbook TABLE 1.15: FIBERGLASS REINFORCED POLYBUTYLENE TEREPHTHALATE-CELANESE PLASTICS A series of thermoplastic polyesters, polvbutylene terephthalate, was developed by Celanese and introduced under the trademark CELANEX. CELANEX@ resins are highly crystalline, and exhibit a unique combination of properties including high strength, rigidity and toughness, low creep even at elevated temperatures, minimal moisture absorption and exceptional dimensional stability, resistance to the effects of a wide range of chemicals, oils, greases and solvents, excellent electrical properties and outstanding processing characteristics. Chemical Resistance of CELANEX Material ‘YoChange Time Temp. Tensile % Change % Change (Days) “F Strength Weight Diameter* InorganIc Chemicals 10% Ammomum 90 Hydroxide 180 360 9 24 73 73 73 180 180 -13 -58 -73.5 -92 -99 +0.6 +03 +09 +2.1 -4 2 +0.3 0.0 +06 +0.3 +01 Glass-Reinforced Resins Material Carbon Telrachlorlde x Change Time Temp. Tensile % Change % Change “F Strength Weight Diameter’ (Days) 90 73 0 +o 1 00 180 73 +o 1 00 360 73 +o 1 +0.1 Dlefhyl Ether 90 180 360 73 73 73 50% Ethylene GlycollWater 90 180 360 24 90 180 360 73 73 73 180 73 73 73 Perchloroethylene 60 180 -6 -: +0.3 +03 +0.5 +o 1 +o 1 +o 1 -3 -3 -3 -50 -3 -6 -5 +0.3 +0.4 +03 +2.4 +0.2 +0.3 +04 +o 1 +o 1 co 1 +0.4 +0.1 +0.3 +o 1 180 180 -30 -32 +65 +67 +0.6 +06 -2 -1 -3 -0 +0.11 -0.1 :: 00 1% Sodium Hydroxide 90 180 360 24 73 73 73 180 -47 -72 -84 -96 +oe +0.5 +03 -1.9 +0.6 +o.,i +0.7 0.0 10% Sodtum Chloride 90 180 360 73 73 73 1; -4 +03 +0.2 +0.4 +0.2 +0.1 +02 10% Hydrochloric 90 Acid 180 360 24 64 73 73 73 180 180 -4 -12 -20 -24 -68 -0 1 +o 1 +02 -06 -24 +0.2 +0.1 +01 0.0 -10 Freon 113 3% Sulfunc Acid 90 180 360 24 64 73 73 73 180 180 -7 -10 -8 -25 -65 +02 +0.2 +0.2 +0.2 +02 +0.2 -0.1 +o 1 +0.1 +o 1 180 51 360 73 73 Gasoline (Amoco. Unleaded) 180 360 135 240 73 73 140 140 -1.6 -2.2 -74 -164 +0.2 +0.2 +1.4 +19 0.0 +o 1 +03 +03 40% Suifunc Acid 90 180 360 73 73 73 -2 -4 -4 +0.4 +o.o +o 1 0.0 +o 1 +o.r Aulomatlc Transmlsslon Flwd. (Type 6) 90 180 360 60 73 73 73 100 -5 -3 -5 -3 -0.3 +03 +0.3 - +o 1 +o 1 +0.1 - 73 73 200 200 1; Water (Tap) 180 360 30 48 -31 -51 +o 1 +03 +04 +o 1 + 1 00 + 1 Delco 222 Brake Fluid 90 180 360 :: -6 +1 -1 -43 -60 00 +20 -22 00 + 1 co3 + 4 1; +0.1 +0.2 +02 73 73 200 200 73 +03 0.0 +07 180 360 30 48 Motor 011 (10-20-40) 90 180 360 73 73’ 73 -4 -7 -8 +0.3 +0.3 +0.4 +0.1 +0.1 +0.1 180 360 60 100 73 73 200 200 -3 -3 -43 -61 +o 1 +02 +0.2 +01 +o 1 00 -0 1 Lubncatcng Grease 180 360 60 100 73 73 200 200 -6 -4 -34 -64 +01 +o 1 +03 +02 +01 -0 1 -0 1 Hydraukc FluId (Skydrol 500s) 180 360 60 240 73 73 180 180 0 -1 -2 -55 0.0 +03 +05 00 +o 1 +0.1 co 1 Turbine Lubncattng Oil (Texaco Sate 15) 18G 360 73 -17.3 -05 -0 1 - +0.1 +0.1 Houron - Cosmo Lubnc 2425 180 360 73 73 Cl -167 00 - 180 360 73 -5 -24 - +0.1 z +0.1 Buffer, pHl0 Buffer, pH 4 95% Ethanol/Water Organic Chemicals 5% Acetlc Actd 90 180 360 :z 73 73 73 180 0 -5 -55 -77 -41 +03 +0.3 +0.2 +11 +0.7 +02 +0.1 +0.2 +0.2 90 180 360 :; -4 -4 +0.5 +0.4 +08 +0.1 +0.1 +02 2:: 120 -40 -Z +5.9 +4.4 +0.9 +0.5 90 180 360 73 73 73 -15 -20 -27 +1.0 +2.0 +2.4 +0.2 +02 +0.6 1% Soap Solwon 2:: 120 -32 -35 +3.6 +3.4 +0.7 Presoak (AxIon) Sol. 180 360 :; 1: 90 180 360 60 240 73 73 73 180 180 -8 -7 -8 -36 -39 +0.4 +4.2 +4.3 +0.1 +0.1 +0.1 +0.8 +0.8 Calgon Water Softener Sol. 180 360 73 73 1; Bufler. pH7 BTX 90 180 3M) 73 73 73 I; +0.1 +0.1 +0.1 Calgomte Dishwasher Sol. :z 73 73 -10 +0.4 +0.5 - 180 360 180 360 Heptane 90 180 360 :il -4 180 360 73 73 1; -14 -17 +oo 0.0 00 +o 1 +02 Laundry Detergent 73 180 180 +0.2 +0.1 +05 +06 Benzene Acetone Toluene 73 l , . l/B” x 2” diameter discs. - . 00 00 r - 1 +o 1; -3 -23 +03 +03 +1.3 +0.1 +o 1 +0.2 -4 -24 z 0, Synthetic TABLE 1.16: RESOLITE tions. The application. FIBERGLASS REINFORCED POLYESTER CR panels are fiberglass-reinforced, polyester resin used in RESOLITE polyester CR panels 53 Resins and Polymers PANELS-RESOLITE sheets in flat and various corrugated and ribbed configurawas developed to withstand chemical abuse in heavy-duty Acids AC&C 5 o-75 o-50 50-75 100 Aqua Reglo Benzene S”llonlc Benzolc Bone Butyric Chloroocetlcs. Mono. di ond +r, Chromic Hydrobromac Hydrochlorx Hydrocyonlc Hypochlorous Hydrofluow Loctlc MOlelC N,trnc* Nl,,O”S OklC OXOllC Perchlorlc Phorphotuc steonc S”lf”,l< TOrtON IO”“IC Wet Gases Carbon Dioxide Carbon Monor,de Chlonne Ammomo Bromine Flwwne Hydrogen Hydrogen Chlonde Hydrogen Fluoride* Hydrogen Bromde Hydrogen Sulfide Owdamg Gores Redvcmg Gores SteOlIl Sulfur D,ox,de Svlfut T&oxide Chlorine Dioxide Svlfur o-100 o-50 50 100 o-30 30.50 oil 011 o-30 o-25 O-50 oil 011 011 o-10 O-20 011 011 0 35 35-60 over 60 O-10 oil 011 ol! 011 011 0-80 over 80. 011 011 S S S S S S T : 5 5 5 S S S 5 S S T T S : S z S 5 5 T S S S S T U S T 5 S S 5 T S S S S T s s S T T S 5 5 T : S T S S : S T S S : 5 : S S S S S and Fumes 011 OII 011 011 011 011 011 011 011 all oli 011 011 011 011 011 011 011 011 011 011 OII all oil all Arrenoter Bicorbonoter B,tluorvder B,rulfoter B,rulf,tes Borotes Bromldel Corbonotes Chlorates Chlorlder Chromate! D8chromotei Fluorlder Hydrorulf,des lodfder Ntt,oter Perchlototer Perrvlfoter Phosphates Phorphfter SillColel Slhco-fluor,der wtoter Sulflder Sulf,ter Solvents z S S S : S S S 5 : S S S 5 S S S S T S S S : S S S z S : T T ; S S S : S 5 T S - and Orgomcs Acerone Alcohols (all] Benzene Benzoldehyde Benzoyl Chlor,de Carbon Tetrochlorlde Chlorobenzerer Chloroform l Ethers Acetone, Ethylene Chlonde Formaldehyde Gorol,ne Glyc& “ep,one S S S 5 s S Herone Kerosene Methyl Ethyl Ketone Naphtha Nophtholene Phenol l Perchlorethylene Tvchlorethylene Thnonyl Chloride StyretIe Sulfuryl Chlonde Toluene Xylene OllS Ethylened,chlot,de Ethylocetote 100 100 100 100 100 S S S : T S S T T 100 100 100 100 100 100 37 100 100 100 100 100 S S S S S 5 S S S S S S S T S T T T S S 5 S S S 100 n rn v,v S S S S T S T S 100 100 011 100 100 100 100 100 100 100 100 100 100 z : S S S 5 S : T : T S T : S T T Amll?o”l”m Hydroxide. Borlum Hydrwde Coiclum Hydronde POtorrl”m Hydronde Sodium Hydrcwde l 10 o-30 S S S T 10 5 T o-50 5 T O-50 O-10 o-50 S S 5 T S T 20 SAT 011 3 011 S S 5 S 5 S S S 5 T 15 S T S S S S Mlscelioneous COlCl”lV Hypochlonte* Chlorine Water Chlorine Dmxlde Hydrogen Peroxade Sodturn Hypothl?r,te’ Underaround Wafer-D,rtilled M,ne Wo1err Se0 Water Coohng Tower Water Metal Plotmg Sol”t~oni P,cklmg Sol”tlonr Metal Plotlng Solutlonr Phorphow Oxychlonde Phosphorur Trichlcrgde Plrkling Solvt,ons Strlpplng SOl”tlO”r Petroleum Ether Moune Atmosphere Hum,d,ty, 100% Chlonter Cyclohexone Coprylic Acid Polrmtic Ethyl Acetate Cool Dust. moist lodrne Vopar Nut 0~1s Olw? Ollr Weed Killers, organic Fung,c,dei organic Insect,c,del, orgon,c Anthrocene 011 Sulfur, wenoble DDT l S S S 5 S (acid) S S (ocvd) S S S T 011 S T 011 S T (olkollne) S T : : S S S S _ _ (olkollnei : S z : : T S S S S T S T LEGEND S = Sof,sloctory w,th expected long and econom,c 1116 T = Tests suggested. Under some conditions materials moy not be sultoble. U: Unrotirfoctory for continuous service. TABLE 1.17: FLUOROPOLYMER-ALLIED ENGINEERED PLASTICS 2 HALAR ECTFE is a melt processable fluoropolymer from Allied Corporation. It possesses a unique combination of properties as a result of its chemical structure-a 1: 1 alternating copolymer of ethylene and chlorotrifluoroethylene. HALAR fluoropolymer offers excellent chemical resistance, good electrical properties, broad use temperature range-from cryogenic to 34O”F, and meets the requirements of the UL-94 V-O vertical flame test in thicknesses as low as 7 mils. It is a tough material with excellent impact strength over its broad use temperature range. HALAR ECTFE also maintains useful properties on exposure to cobalt 60 radiation at dosages of 200 megarads. It is one of the best fluoropolymers for abrasion resistance. HALAR fluoropolymer is a thermoplastic which can be processed by virtually any technique applicable with polyethylene. It can be extruded, injection molded, blow molded, rotomolded, and applied by ordinary fluidized bed or electrostatic coating techniques. It is available in a range of viscosity grades for extrusion and molding applications. HALAR ECTFE powders are available in three different particle sizes optimized for specific coating processes. HXARB ECTFE R - Recommended NR - Not Reco,'m,ended -- _ NO Avalla~la Data CHEMICAL RESiSTANCE Chemical Acetic Acid, 10% Acetic Acid, 20% Acetic Acid, 50% Acetic Acid, 80% Acetic Acid, Glacial ~ Acetic Anhydride Acetone Acetyl Chloride Acetylene Acetyl Nitrile Acrylonltrile Adipic 105 Acid Alcohol, Amy1 Alcohol, Benzyl Alcohol, Butyl, Primary Alcohol, Butyl, secondary Alcohol, Diacetone Alcohol, Ethyl Alcohol, Hexyl Alcohol, Isopropyl Alcohol, Methyl Alcohol, Propyl Ally1 Chloride Alum Alum, Ammonium Alum, Chrome Alum, Potassium Aluminum Chloride Aluminum Fluoride Alurcu~um Hydroxide Aluminum Nitrate Aluminum Oxychloride Aluminum Sulfate Ammonia, Gas Ammonia, Aqua, 10% AmmonilnnAcetate Ammonium Bifluoside Ammonium Bisulfide 73OF R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R Temperature 15O'F 250'f --R R R R R -_ R R R R __ R R R R R R R _R R R R R R R R R R R R R R R R R R R R R R --__ NR -_ __ _-_R R R R NR R -R R R R R R -R R R R R __ R R R __ R R Chen;cal 3OO'F __ ___ -_ -__ NR ___ _-_R R R R NR R _R R R R R R -R R R R R __ R R -__ R R 73°F --- Ammonium Carbonate Armnonium Chloride Ammonium Dichromate Ammonium Fluoride, 10% Ammonium Fluoride, 25% Ammonium Hydroxide Ammonium Metaphosphate ArmnoniumNitrate Ammonium Persulphate Ammonium Phosphate Anlmonlum Sulfate Ammonium Sulfide Pmyl Acetate Amy1 Chloride Aniline Anthraquinone Anthraqulnone Sulfonic Acid Antimony Trichloride Aqua Regia Arsenic Acid R R R R R R R R R R R R R R R R R R R R Barium Barium Barium Barium Barium R R R R R R R R R R R R R R Barium Carbcnate Chloride Hydroxide Nitrate Sulfate Sulfide Bt?WZ Beet Sugar Liquors Benzaldehyde, 10% Benzaldehyde, Above 10% Benzene, Benz01 Benzene Sulfonic Acid, 10% Benzoic Acid Bismuth Carbonate Black Liquor Bleach, 12.5% Active Cl2 Bleach, 5.5% Active Cl2 R R R Temperature 150°F 250°F XF R R R R R __ R -_ R R R R R __ R R R NR R NR _--R R R R R R R -R R R NR R NR ___ -_ -_ R R R R -_ R R _-NR NR NR NR R __ R R R R R R _- R R R R R R R R R R R NR R R __ R R R R R -R R R R R NR R R R -R R R R R ___ NR NR NR NR --_ R R R (continued) s 7 g 5’ ’ $ v)’ 5 $ q h. fi x $ c 8 * TABLE 1.17: FLUOROPOLYMER-ALLIED Chemical ENGINEERED 73OF __--- Temperature 150°F 250'F BOrZlX Boric Acid Brine, Acid Bromic Acid Bromine, Liqud Bromine, Vapor 25% Bromine, Water Bromobenzene Bromotoluene Butadiene BUtme Butyl Acetate Butyl Alcohol Butyl Cellosolve Butylene Butyl Phenol Butyl Stearate Butyrx Acid R R R R R R R R R R R R R R R R R R R R R R R R R NR R R R R R -_ R R __ R R R R R _NR R NR NR R R' NR R _R R _R Cadmium Cyanide Calcium Bisulfide Calcium BisulfitC Calcium Carbonate Calcium Chlorate Calcium Chloride Calcium Hydroxide Calcium Hypochlorite Calcium NItrate Calcium Oxide ca1c1um Sulfate cane Sugar Liquors Caprylic Acid Carbon Dioxide, Wet Carbon Dioxide, Dry Carbon Disulfide Carbon Monoxide Carbon Tetrachloride Carbonic Acid Castor Oil Caustic Potash Cellosolve Cellosolve Acetate Chloracetic Acid Chloral Hydrate Chloramine Chlorine Gas, Dry Chlorne Gas, Wet Chlorine, Liquid Chlorine Water, Saturated Chloracetic Acid Chlorobenzene R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R -R R R R R R -R R -_ R R R R R R -_ R R R R R R R R R R -_R R -__ R R R R R -R __ -_ NR R R R R NR PLASTICS 300°F R R R NR NR NR NR R R __ R R R R R R R R R R R R -NR NR (continued) 73'F Temperature 150°F 25O'F -- Chlorobenzyl Chloride Chloroform Chlorosulfonic Acid Chromic Acid, 10% Chromic Acid, 30% Chromic Acid, 40% Chromic Acid, 50% Citric Acid coconut 011 Coke Cven Gas Copper Carbonate Copper Chloride Copper Cyanide Copper Fluoride Copper Nitrate Copper Sulfate Corn syrup Cottonseed Oil creso1 Cresylic Acid, 50% Croton Aldehyde Crude Oil Cupric Fluoride Cupric sulfate Cuprous Chloride Cyclohexane Cyclohexanol Cyclohexanone R R R R R R R R R R R R R R R R R R R R R R R R R R R R NR R _R R R R R R R R R R R R R R R R R NR R R R R R R NR NR R _R R R R R R R _R R R R R R R NR NR NR R R R R R NR NR Detergents Detergent Solution (Heavy Duty) Dextrln Dextrose Dichlorobenzene Dlchoroethylene Diesel Fuels Diethylamine Diethyl Cellosolve Diethyl Ether Diglycolic Acid Dimethylamine Dimethyl Hydrazine Dioctyl Phthalate Dioxane Dioxane,1.4 Disodium Phosphate Divinylbenzene R R R R R R R R R R R R R R R R R R R R R R NR NR R NR R --NR NR NR R R R NR R R R R NR NR R NR R --NR NR Epsom Salt Ethyl Acetate Ethyl Acetoacetate R R R R R _- Chemical NR NR NR R -- XF NR _-_____ R R __ _R R R R R R R NR NR NR R R R R NR NR R R NR NR R NR R -_NR NR NR NR NR R -- 3 "s 9 w. 4 2 5 D "s Q R ? _-_ 3 (continued) 3 R --_ TABLE 1.17: FLUOROPOLYMER-ALLIED ENGINEERED PLASTICS (continued) lkmperarure Chemical 73'F -- 150°F 250°F TWperatUIe 3OO’F R R __ R R R NR NR NR R R NR R __ __ R R NR NR R R NR R __ __ R R NR NR NR R R R R R R R R R R R R R R R R R R R R __ -R R R -R R R R R R R R R R R R R R R R _-_ R ___R R __ -_ __ __ _--- R R R R R 11 R -_R -_ __ _-_ --_--__ _-_ R R R R R R R R R R R R R R R R R R R R __ R R R R R R R R -- _R R R R -_ R R R -- Ethyl Acrylate Ethyl Chloride Ethyl Chloroacetate Ethyl Ether Ethylene Bromide Ethylene Chloride Ethylene Chlorohydrin Ethylene Diamine Ethylene Dichloride Ethylene Glycol Ethylene Oxide R Fatty Acids Ferric Chloride Ferric Nitrate Ferric Sulfate Ferrous Chloride Ferrous Nitrate Ferrous Sulfate Fluorine Gas, Wet Fluoboric Acid Fluoslliclc And Formaldehyde, 35% Formaldehyde, 37% Formaldehyde, 50% Formic Acid Fornnc Acid (Anhydrous) Freon F-11 Freon F-12 Freon F-21 Freon F-22 Freon F-113 Freon F-114 Fruit Juices, Pulp R Gallic Acid Gas, Natural Gasoline, Leaded Gasoline, Unleaded Gasoline, Sour Gelatin Gin GlUCOSZ Glycerine, Glycerol Glycolic Acid R R R R R R R R R R R R R R R R R R R R NR Chenlcal 73'F 150°F -- 25OOF 3oo’F Glycols R R R R Fkptane Hexale Hydrobromic Acid, 20% Hydrobromlc Acid, 50% Hydrochloric Acid, Cone 37% Hydrocyanlc Acid Hydrocyanuz Acid, 10% Hydrofluoric Acid Dilute Hydrofluoric Acid, 30% Hydrofluoric Acid, 40% Hydrofluoric Acid, 50% Hydrofluosiliclc Acid Hydrogen Hydrogen Cyanide Hydrogen Peroxide Hydrogen Peroxide, 50% Hydrogen Peroxide, 90% Hydrogen Phosphlde Hydrogen Sulfide, Dry Hydrogen Sulfide, Aqueous Sol. Hydroquinone Hypochlorous Acid R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R -_ R R R R R R R R R R R R R R R R R R R R R --_-R _R R R R R R R R R R ---R R R ---_ -R -_ -_ R Iodine Iodine Solution, 10% Isopropyl Ether 1sooctane R R R R R R -_ __ R R ___ ---_ -- Jet Fuel, Jl'-4 Jet Fuel, JP-5 R R R R R R R R R R R R R R R R R R R R R R __ R R R R R R R --R R R R R R R __ __ R Lactic Acid, 25% Lactic Acid, 80% Lard Oil Laurie Acid Lauryl Chloride Lead Acetate Lead Chloride Lead Nitrate Lead Sulfate -_ R R R R (continued) TABLE 1.17: FLUOROPOLYMER-ALLIED ENGINEERED PLASTICS !continued) Ten-eratce Chemical Lemon Oil Lime Sulfur Linoleic Acid Llnoleic Oil Linseed Oil Linseed Oil, Blue Lithium Bromide Lubrlcatinq 011, ASTM #1 Lutxicatinq 011, ASTM #2 Lubrlcatlnq 011, ASTM #3 73'F -- 15O'F 2SOOF _)‘L’“-* R R R -- R R _- __- R R R R R R R R R R R R R R R R R R R R -_ R R R R R R R R R R R R R R R R R _NR R R R NR NR NR _R -NR NR NR R R __ R R R R R R _--_ _--_ R __ -NR R R R NR NR NR -_ R _NR NR NR -R -_ R R R Maqneslum Carbonate Maqneslun Chloride Maqneslum Hydroxide Magnesium Nitrate Maqneslum Sulfate Malelc Acid Mallc Acid Mercuric Chloride Mercuric Cyanide Mercuric Sulfate Mercurous Nitrate Mercury Methane Methoxyethyl Oleate Methylamine Methyl Bromide Methyl Cellosolve Methyl Chloride Methyl Chloroform Methyl Ethyl Ketone Methyl Isobutyl Ketone Methyl Methacrylate Methyl Sulfate Methyl Sulfuric Acid Methylene Bromide Methylene Chloride Methylene Iodine Milk Mineral Oil Molasses Motor Oil R R R R R R R R R R R R R R R R R R R R R -NR R R R R R R _R R NR NR NR R R R R Naphtha R R R R R R R R R R R R R R R R R R R R R R R R _-__- R R R Chemical Naphthalene Natural Gas Nickel Acetate Nickel Chloride Nickel Nztrate Nickel Sulfate Nicotine Nlcotinic Acid Nitric Aad, 10% Nitric Acid, 30% Nitrx And, 40% Nitric Acid, 50% Nitric Acid, 70% Nltrlc Acid, 100% Nitrobenzene Nitrous Aad, 10% Nitrous Oxide 73OF __--- 15O'F 25O'F 31)0OF __ __-_ R R R R __ R R R R R R R R R R R R R -- R R R -R R R R NR NR NR NR R -- R R R __R -_ -NR NR NR NR -_ R R R R R R R R R R R R R R R __ -- Oils, Vegetable Oleic Acid 0lelL-J Oxalic Acid Oxalic Aad, 50% Oxygen, Gas OZOIUZ R R R R R R R R NR R R R R R R NR NR NR R R R __ NR NR NR R R Palmit-c Acid Palmitlc Acid, 10% Parhfflrl Perchlorlc Acid, 10% Perchlorlc Acid, 70% Pa-phosphate Petroleum Oils, Sour Petroleum 011s. Refined Phenol Phenyl hydrazine Phosphoric Acid, 10% Phosphoric Acid, 50% Phosphoric Acid, 85% Phosphorus Yellow Phosphorus Pentoxlde Phosphorus Trlchloride Photographic Solutions R R R R R R R R R R R R R R R R R R R R R R -R R R -R R R _R R R R R _- ___ _- R _- -- NR __ R R R _R R -_ NR _R ---_ -_ -_ -_ (continued) 2 TABLE 1.17: FLUOROPOLYMER-ALLIED Chemical Plcric Acld Plating Solutions, Brass Plating Solutions, Cadmium Plating Solutions, ChrCJUE Plating Solutions, copper Plating Solutions, Gold Platrng Solutions, Lead Plating Solutions, Nickel Plating Solutions. Rhodium Plating Solutions, Silver Plating Solutions, Tin Plating Solutions, zulc Potash Potassium Alum Potassium Alur;inun Sulfate Potassium Bichromate Potassium Blsulfate Potassium Berate Potassium Bromide Potassium Carbonate Potassium Chlorate Aqueous Potassium Chloride Potassium Chromate Potassium Chlorate Potassium Cyanide Potassium Dichr9mate Potassium Ferricyanlde Potasslun Ferrocyanide Potassium Hydronde Potassium Iodide Potassium Nitrate Potassium Pa-chlorate Potassium Permanganate, 10% Potassium Pennanganate, 25% Potassium Persulfate Potassium Sulfate Propane Propylene Oxide Pyrldine Pyrogallic. Acld Salicylic Acid Salicylaldehyde Silxlc Acid ENGINEERED 72°F‘ I? __ R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R NR NR R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R -R R R R R NR NR R R R R R NR -- II R PLASTICS Temperature ,=,oc 250°F -- 330'F __ -___ ___ __ _--i_ -- -_ -- R R R R R -R R R R R R R R R R -R R _R R -_ R R NR NR -- R R R -_ _NR -_ (continued) -_ Chemical Silicone Oil Silver Cyanide Silver Nitrate Silver Sulfate SOSPS -_ __ R R R R R R R R R R __ -_ R -_ R R -R R NR NR NR Sodian Acetate Sodium Alum Sodium Benzoate Sodium Bicarbonate Sodium Bichromate Sodium Bisulfate Sodium Sisulfite Sodium Bromide Sodium Carbonate Sodium Chlorate Sodium Chloride Sodium Cyanide Sodium Dichromatc Sodlun Fluoride Sodiu Hydrande, 15% Sodium Hydroxide, 30% Sodium Hydroxide, 50% Sodium Hydroxide, 70% Sodium Hypochlorite Sodium Iodide Sodium Metaphosphate Sodium Nitrate Sodium Nitrite Sodium Perchlorate Sodium Peroxide Sodium Phosphate, Alkaline Sodium Phosphate, Acid Sodium Phosphate, Neutral Sodium Silicate Sodium Sulfate Sodium Sulfide Sodium Sulfite Sodium Thiosulfate Sour Crude 011 Stannlc Chloride Stanncus Chloride Starch Stearic Acid Stoddard's Solvent m 73°F R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R __ __ -- R R R R R R R R R R R R R R R R R R R R R R R R R R R __ R R R R R R R R R R R R R R R R R R _R R R R -R R R R R R R __ R R R R -R -R R R -R R R R R R R R R R R R -_R R R __ _R R R R _R R R R R R R -R R -_ -_ -R -R R R -_ R R R R R R R R R R R R _-_ R (continued) TABLE 1.17: FLUOROPOLYMER-ALLIED ENGINEERED PLASTICS (continued) Terneratme Chemical 73'F ---- 15O'F 250'F 303'F R R R R R R R R R R R R R R R R R R R R ___ R -_ R R R R R R R R R R R R R R -_ R R __ _R __ R -R R R' R R R --_ __ -_ -_ -__ R __ -_ ___ --_-_ ___ __ __ -_ __-__ --_ -_ __ R R R R R R NR KR R R R R R R R R R R NR NR R R R R R R R R R R NR NR -R NR R R -_ -R __ R NR NR _R NR __ Succinic Acid sulfate Liquors Sulfite Liquor Sulfur Sulfur Chloride Sulfur Dioxide, Dry Sulfur Dioxide, Wet Sulfuric Acid, 10% Sulfuric Acld, 30% Sulfuric Acid, 50% Sulfuric Acid, 60% Sulfuric Acid, 70% Sulfuric Acid, 80% Sulfuric Aad, 90% Sulfuric Acid, 93% Sulfuric Acid, 94% Sulfuric Acid, 95% Sulfuric Acid, 96% Sulfuric Acid, 98% Sulfuric Acld, 100% Sulfurous Acid R Tall Oil Tannic Acid Tanning LiqUOrS TX Tartaric Acid Tetraethyl Lead Tetrahydrodurane Tetrahydrofuran Thlonyl Chloride Thread Cutting Oils Toluene, Toluol Tomato Juice R Chemical 73°F _~____ Transformer 011 Transformer Oil DTE/30 Tributyl Phosphate Trlchloroacetic Acid Trichloroethylene Triethanolamlne Trlethylamine Triosodlum Phosphate Turpentine Temperature 250°F 150°F 300°F --- R R NR R R NR R R R R _NR NR R NR NR R R NR R R NR NR R NR Urine R R R R R -- __ __ vase11ne VUlegar Vinegar, White Vinyl Acetate R R R R R R R R -_ R R R -__ _-- water water, Acid Mine water, Demineralized water, Distilled or Fresh water, Salt water, sea water, sewage Whiskey White Liquor WlilES R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R xy1ene (xylol~ R R -- -- Zinc Chloride Zinc Nitrate Zinc Sulfate R R R R R R R R R R R R “X-E!.3 Corrosion 60 TABLE 1.18: Resistant FURAN Materials RESIN-KOCH Handbook ENGINEERING, CHEMICAL RESISTANCE Meaning E-Excellent r&stance; all concentrations Ga uitable for general an d temperatures. MAURICE service - resistance; suitable for most servicesconcentrations and temperatures to 2 12 “F. most A. KNIGHT DIVISION OF PERMANITE of Symbols F-Fair resistance; suitable for some services-dilute concentrations and temperatures to 90°F. NR-Not recommended for this service under most conditions. Resistance Chemicd Resistance Chemical Chemical Rerirtrnce ...... E Coconut Oil Acetic Acid (to 85%) ....... ... E Nitric Acid ,.. ,,.... NR G Copper Cyanide Acetic Acid, Glacial ............... ........ E Oleic Acid E .......... G Copper Sulfate .............. Acetic Anhydride E Oxalic Acid ‘. ...E I..................................... . Acetaldehyde ................. ...... E Paraffin .._ ..,.,. E Corn Oil E Cottonseed Oil Acetone ............................................................... ................ E Petroleum Erher .,.,,....... E .E Cresylic Acid ........... Aluminum Chloride ...................................... ...... .... NR Phenol ,.,.,........... E E Cupric Chloride Aluminum Sulfate ... ...... ....... E Phosphoric Acid (to 7% cone.) E Ammonium Bromide ........ .._......_........ E Dibutyl Phthalate ...... ........ .. .:.... E Phosphoric Acid (70 to E Ethyl Acetate .............. ................. E 85% cont.) _ G Ammonium Carbonate ........ Bisulfate E ................. .I.........E Ethyl Alcohol Ammonium Chloride E Potassium ............ ...................... E E Eth;l Ether Amnionium Fluoride ................... E Potassium Carbonate ______...._._____~ ._.........E Potassium Chloride E .................... E Ethylene Dichl&i& Ammonium Hydroxide Ammonium Nitrate .... .._...................... E Ferric Acid Salts (to 45% cont. ) E Potassium Hydroxide EE ................... ... E Ferric Salts ....... ................................. Ammonium Phosphate E Potassium Iodide E Ammonium Sulfate ........................ E Ferrous Salts .................... .E Potassium .Sulfate . . . .._________...__._........................ F Pyridine E Formaldehyde Amy1 Acetate ........................................................ ................. ... ..... ..... E Pyridine Sulfate __._.._._____.._.___........... G ................................ F Formic Acid .......... Aniline ___......_....._..._ E Sodium Bicarbonate E E Sodium Bisulfate ......................... G Fuel Oil ................. Aniline Hydrochloride E Furfural _._..._ .....___________ ::....‘:I................... . Sodium Carbonate NR Aqua Regia ....................................................... .E E Furfuryl Alcohol .................................... E Sodium Chloride Barium Chloride .............................................. E .......................................... .E Gasoline ................... Barium Hydroxide ...........E Sodium Chlorite, Acid Soln. I _...E Glycerine Beer .......................................................................... .................E Sodium Hydroxide .......... E Hydrobromic Benzene ........................................................................ E Sodium Hypochlorite Acid ................................. E E Hydrochloric Benzene, Monochlor ...................................... .E Sodium Iodide Acid ................................. Sodium Sulfate E ...................................... .E Ben-e, o-Dichlor Hydrofluoric Acid (to 50% cont.) E Sodium Sulfide ,...,.. E .................... .E Hydrofluoric Acid (50 to Benxene, 1, 2, &Trichlor Sodium Sulfite ,. E G Sodium Thiosulfate 70% cont.) .................................................... E Benxoyl Chloride .................. ................... E E Stearic Acid Acid .................................... G Hydrofluosilicic Benzyl Alcohol ................................................... E E Hydrogen Peroxide (to 3% cont.) ... F Sulfur Monochloride E Borax ............................................................................ Sulfuric Acid (to 5096 cont.) E . Boric Acid ............................................................... Hydrogen Peroxide (over G ....................................... NR Sulfuric Acid ( 50 to 60% cont.) 3% cont.) .NR Bromine ............................................................... F E Sulfuric Acid (over 60% cont.) Sulfide .......................................... G Hydrogen Bromine Water ................................................. ,, E NR Sulfurous Acid ...E Iodine ... .................................................................. Butyl Alcohol ................................... .,,.... E E Tannic Acid Isoamyl Alcohol .............................................. . Calcium Bisulfite ............................................... E E Tartaric Acid Alcohol .......................................... ..........E Isopropyl Calcium Chloride .................................. Tin Chloride ..,................ E E Trichlorethylene .................................................................. _............................. E Kerosene Calcium Hydroxide .............. __........_..._.._.................E E Trisodium Phosphate ................. ..................................... P lactic Acid ............................................. Calcium Hypochlorite E E Toluene E Lead Acetate ........................................................ Carbon Bisulfide ................................................. .,, E E .. _. ..... Magnesium Chloride ....................... E ....... ......... ............E Carbon Tetrachloride Turpentine E Vegetable Oils ..,.. ,._.... .._.... E ......................... E Magnesium Sulfate ...................................... Castor Oil .................................. E ., .E Vinegar ................................................. G Maleic Acid ............................................................ Chlorine (dry) E E Water. Distilled G Manganese Sulfate ............................................. Chlorine (wet) ................................................ . .._............... E E Water, Salt .............................................. Chlorine Water .........................................G Methyl Alcohol ,_......... . . _E S ,Wine ......................................... E Methyl Ethyl Ketone ..................................... Chloroform ‘Whiskey ................................... ...................... E E Xylene Mineral Oils ........................................................... ................................ P Chromic Acid (dilute) ...... .................................. ...................... E z.mc Chloride Nickel Chloride ...................................... .............. ........NR Chromic Acid (concentrated) ..”................. E .............................. ......E 2’rnc Sulfate ............................................ E E Nickel Sulfate ................................................. Citric Acid ....._........................................................... Synthetic TABLE 1.19: ISOPOLYESTER RESINS-AMOCO Resins and Polymers 61 CHEMICALS Corrosion resistant isopolyesters are characterized among resin suppliers and users by the molar ratio of the aromatic to the unsaturated acid and by the glycol used in synthesis. In this nomenclature, Amoco’s recommendation for a cost-effective resin with outstanding corrosion resistance to a broad range of liquids over a wide temperature range is a 1 : 1 propylene glycol isopolyester. That is, the resin is made with equal molar amounts of maleic anhydride and isophthalic acid and reacted with a sufficient excess of propylene glycol to ensure esterification to a high molecular weight. While the basic basic formulation three laboratory The resin stability. than the desirable corrosion suitable variations resistant resin offers the most versatile range of resistance properties, variations of the for specific applications are available from many resin suppliers. The second table shows of the recommended formulation. with higher levels of maleic anhydride has greater crosslink density and thus offers very good temperature It should maintain mechanical properties up to 100°C. It also shows better resistance to aromatic solvents basic formulation, although its resistance to mineral acids is not quite as good. Its brittleness may be unin some applications. Adipic acid improves flexibility formulations is not as consistent lowers resistance properties. and neopentyl glycol improves caustic resistance, The gasoline resistance of these as that of the other formulations shown in the second table. Adipic acid generally Chemical resistance Temperature, Medium 93 71 NaCl Saturated Distilled H,O of laboratory “C synthesized Composite resin* Rating Applications Marine, Acceptable bnne Excellent 71 Excellent 49 Acceptable Pipe, water handling 10% Na,CO, 49 Excellent 25% 93 Acceptable Chemical 5% HCI 71 71 Good Excellent Chemical 15% HCI 71 Excellent Descaler handltng 15% H,PO, 49 71 Good Good Fertilrzer, food handling 71 Good Chemical Chemical handlrng handling 71 Acceptable Food storage, 71 Acceptable Food processing, pH, Soil Slurry 38 Excellent Burial conditions pHlo Soil Slurry 38 Good 1N NH,OH 2% NaOH 38 23 Acceptable* Good’ 5% NaOH 23 Complete 38% Urea 100% Household 49 Acceptable 49 Excellent Excellent H,SO, 85% H,PO, 5% HNO, 25% Acetic Vinegar Acrd (5% Acetic Saturated Acid) Bleach Alum 100% Corn Syrup 50% Citric Acid 50% EtOH 50% 34-5-5 Fertilizer Lead Free Regular 50% 75% Toluene/50% Toluenel25% In Water l l Propylene Blistering glycol rsopolyester Failure Fertrlizers Excellent Food handling 71 49 Good Acceptable Food, beverage Fertilizer 23 Excellent Gasoline 23 Good Petroleum 23 Good 23 Good lsooctane cooked handling Chemical Excellent lsooctane handling Fertilizers l l 71 Gas was apparent. handling 49 71 Benzene “1:l storage to less than 15 acid number Food handling storage storage Chemical ASTM C581, one year rmmersron. (continued) 62 Corrosion TABLE Resistant Materials ISOPOLYESTER 1.19: Handbook RESINS-AMOCO Resin formulations Isophthalic/Maleic Adipic Acid, Ratio, for corrosion resistant Properties % Elongation Heat Distortion Temp., ASTM Strength, IO’psi (MPa) Flexural Modulus, 106psi (MPa) 1 .3 2.4 132 105 2.7 103 14.8 19.5 (134) 1.074 (7400) 0.887 56 Hardness Corrosion Distilled 45 C581 Flexural Water 5% HNO,at neopentyl 45 1 .6 Properties, 0.3 neopentyl 45 116 “C 0.7:1 1 :l - propylene 45 % Styrene Clear Casting performance 1 :2 - propylene Laminate (continued) 1 :l - Moles Moles Glycol Barcol CHEMICALS at 71 “C 71 “C 17.6 (121) (102) (6110) 0.843 53 Resistance, Composite ratings 18.6 (128) (5810) 0.795 from (5480) 53 50 one year data excellent excellent excel lent unacceptable good good excel lent good 5% HCI at 71 “C excellent excellent good unacceptable 25% H,SO, at 71 “C excellent acceptable complete failure excel lent good 5% NaOH at 71 “C complete unacceptable unacceptable #2 Fuel Oil at 23°C excellent excellent excel lent excellent Ethyl Gasoline excellent excellent excel lent unacceptable excellent excellent unacceptable excellent good excellent unacceptable unacceptable Unleaded at 23°C Regular Benzene at 23°C at 23°C A partial list of materials handled failure and stored in corrosion resistant isopolyesters Acetic Acid Gasoline Premium Acidic Fumes GI\,cols Salt Solution Grain Sa It Spray Grapes Seawater HCI Solutions Sewage Hs (NH.) H NO, Soap Curd Ammonia Beer Hydrogen Brine H,SO, Solutions Soybean H, PO. Sugar Solution Acrylic Emulsions Agricultural Chemicals Alcohols Alum Cheese Chlorine Dioxide Chlorinated Coconut Crude Oil Oil Fatty Acids Ferric Chloride Solutions Oil Oil Dioxide Vegetable Oils Vinegar Milk Monomeric H,O Sour Crude Sulphur Solution Meat Oil Distilled Soil Sulfide Lye Manganese Lye Cod-Liver PO, Gasoline Vinyl Plasticizers Water Acetate Treatment (NH.)z SO, Wet Gases from (NH,) Pasta Whey Fertilizers Peanut Fruit Juices Pickles Fuel Oil Potable NO, Oil Copper Smelting Wine Zinc Chloride H,O Chemicals Synthetic TABLE 1.20: NYLON 6/6 RESINS-CELANESE Resins and Polymers PLASTICS 1000 series nylons are of the 6/6 type polyamides. They are used in the replacement weight, corrosion resistance, self-extinguishing properties, self-lubricating qualities and lower cost. CELANESE reduced stantially Chemical Resistance Of Cklanese Acetaldehyde. Acetamrde. Acetrc acid, A/B Acetone, offering at sub- & 1003 Dimethyl formamide, Dioctyl phthalate. Droxane. D A [h;;o;ats Ally1 chlorrde. Alummum chloride, Aluminum sulfate, gaseous, Ammonrum~carbonate. Ammonrum chloride, Amvl acetate. Aniirne. Antrmony trichloride, Asprrin. Barium chloride, Barium sulfide, Benzaldehyde. Benzene, Benzene sulfonic acid, Benzoic acid, Bdumen. Bleaching lye, Boric acid, Boron trifluoride. Bromine, Bromine water, Butanol. Butvl acetate. Butilene glycol. acid, Calcium chloride, Calcium chloride in alcohol, Calcium hypochlorite. Camphor, Carbon disulfide, Carbon tetrachloride, Carbontc acid Chloracetic acid, Chloral hydrate, Chlorine, Chlorine water, Chlorobenzene, Chloroform, Chlorosulfonic acid, Chromic acid, Citric acid, Creosote, Cresols. Cresylic acids, Cupric chloride, Cupric sulfate, Cyclohexane, Cyclohexanol, Cyclohexanone. Decalin, Detergents, Dibutyl ohthalate. Drchlordrfluoromethane, Dresel 011. Drethylene glycol, Dimethvl carbinol. 10% 10% Ferric chloride, Ferrous chloride, Ferrous sulfate, Fluorrne. Fluorosilrcic acid, ‘Fluothane’, Formaldehyde, Formic acrd. 1009; 100% 10% 10% 10% 100% 100% 10% lo&& Heptane, Hexane. Hydrobromic Hydrochloric 30% 100% 100% 100% 20% 20% Iodine Iodine 100% 10% 10% 1OFh 100% lo-100% 1% 10% 10% 9Gh - Mixture :: B/C D B/C A 100% - : A 1OFh 100% - A:B A/B AIB A/B BBC ; 80:2Gj - : AD A A ; A/B ; acid, acid, 10% 2% 10% 4% 0.5% 3% Saturated - CD : Bl? A/B A in alcohol, in KI solution. Iso.octane, 10% A;B A0 Hydrogen sulftde, Hydroquinone, 100% 960/, 100% 400/, 3% 10% - Hydrofluoric acid, Hydrogen peroxide, 10% ; A 10% 10% 10% 10Yo Fruit juices, Gasoline Gasolrne/Benzene Glycerine, E/;:;ol. Saturated lOC% - and oils, Ether, ’ Ethyl acetate, Ethyl butyrate. Ethylene chlorhydrin, Ethylene chlorrde. Ethylene dramine. Ethylene dichloride. Ethylene glycol, Alcohol, benzyl, Alcohol, phenyl ethyl, Butyric 1000 t aliphatic. Ammonia, Ammonra. Nylons of metals, colorability EFFECT CHEMICAL Alcohols, 63 GJ - i! A Lactic acid, Lead acetate. Lead stearate. Linseed oil, 10% 10% - BgC - ; Magnesium chloride, Magnesium hydroxide, Magnesrum sulfate, Manganese sulfate, Mercuric chloride, Mercury, Methanol, Methyl acetate, Methyl ethyl ketone, Methylene chloride, Mrlk, Mrneral oils. 10% - 1osj 100% 100% 100% - : : AC A/B : AC A - Naphthalene. Nickel sulfate, Nitrrc acid, Nitro-alcohols. Nitrobenzene. 011s of vegetables Olerc acid, 10% 8% ; 10% and spices, lo@) : C 100% A A (continued) 64 Corrosion Resistant Materials Handbook TABLE 1.20: NYLON 616 RESINS-CELANESE EFFECT CHEMICAL - Oleum. Oxahc acid. Paraffin, Perchlorethylene. Perchloric acid. Petroleum ether, Phenol, Phosphoric acid, Phthahc acid. Potasswm bicarbonate. Potassium bromide. Potassium carbonate, Potassium chloride. Potassium dlchromate, Potassium ferrlcyanlde. Potassium ferrocyanlde. Potaswm hydroxide. Potassium Potassfum Potassium Potassium Pyrldlne. nltrate, permanganate. sulfate, sulftde. 10% 100% 10% 10% Saturated 60% 10% 60% 90% 5% 30% 30% 10% 50% 10% 1% 100% 90% - Resorcinol. 100% Sallcyhc acid. SIllcone flulds, Sliver nttrate. Soap solution. Sodium acetate, Sodlum benzoate. Sodturn bicarbonate. Sodium blsulfate. Sodlum blsulflte. 100% - Sodium bromtde. Sodium Sodbum Sodium Sodbum Sodturn Sodium Soolum PLASTICS carbonate. chlorate, chloride. cyanide. hydroxide. hypochlorite. nitrate. 6&$ 50% 10% 10% 10.50% 10.9oq/, 10% 50% 15% Cl 10.50% (continued) CHEMICAL EFFECT Sodbum perborate. Sodwm phosphate, Sodium skate. Sodturn sulfate, Sodium sulhde. Sodium thlosuifate. Stanmc chloride. Stannlc sulfate, Stearic acid, Styrene. Sulfur, Sulfur dioxide. Sulfuric acid. A/B 5% Sulfurous 90.10&+, 10.9oqo 2590% 10% 100% 2% and alb&e acid. Tallow, Tar, Tartaric acid. Tetrachlorethylene, Tetrahydrofuran. Tetralm. Thlonyl chloride, Toluene. Transformer oil. Trlchlorethylene. Triethanolamine. 0 ; 2 ; : A : C ii : 10% 1oGj - Urea. - VaselIne. Vegetable oils. Vinegar, Vinyl chloride. - AB A 1 A A?* A A ; B/C 1oG$o A Water, cold, Water, hot, Wax. molten, White spirit. Wmes and splrlts, - ; A A$ Xylene. Xylenol. - ; Zinc chloride. Zmc oxide, Zinc sulfate, - AC A 4. No attack, little or no absorption, little or no effect on mechanical properties. 3. Liile or no attack, some absorption causing slight swelling and slight reduction in mechanical properties at 73°F (23°C) C. Some attack or considerable absorption at 73°F (23°C) material not suitable for contact unless limited product life is acceptable. D. Material decomposes at 73°F (23°C) in a short time. TABLE 1.21: NYLON 11 RESIN-RILSAN RILSAN NYLON 11 CHEMICAL RESISTANCE RATING RATING CONCENTRATION CHFMICAL 6aoF 20-c a AWIafd&l”de 104OF 4o=c 6 14ooF 60°C x BESN BLACK T 194pF 9O’C CONCENTRATiON CHEMICAL Dwlhyl WF lOJ’=F 140~1 & 20‘3 - (,O’i 5% A A A D,octylphosphate A A Acetoc Ac,d 10% A A B D,ocrylphd,alare A A Acetoc Aud 50% B X Ethanol A+ E P”W El X X Ethyl AceWe A A A At B Ethylene Chlorhydrtn X X A A A Ethylene Glycol A+ At A A A- Ethylene Oxade A A A A A Fatty Aad A A Hydrorade A A A Fl”Orll-le X X Ammonium Nllrate A A A Formaldehyde A B Ammo”,“m Sulfate A A B Formic Actd X X Amy1 Acetate A A A A Anethola A Pure ACetOW ACZ?t”le”e Aluminum SuItate AllllIW”l~ Amonwm Pure Aniline Barun sat. sol. Chloride Esrers Freon 12 A Freon 22 A A A A B+ X X X Freon 502 A A A A Fru,t Jutices A A Furfuryl A A+ Gas (Coal) A A Gasolme (High Octane) A A Glucore A A A A Beer A Benzaldahyda A B X BeWe”* A A+ B Benzyl Alcohol n X X Bromine X X B”lxx A A A Gl”COl A A But”, Alcohol At B X Gr.?aSl?s A A Heplane A A Hydrogen A A Concenlrated A A A Calcium Chloride sat A A A X Ca,cum Hydrogen Carbon D,rult,de A+ a+ Carbon Tetrachk,r,de D X Chlorane X X X Chloroform B X X X X X Chromtc Actid 10% Coder A Citrtc Actd A B Copper Sulfate A A CWSOl X X Cyclohexane A 0 C”ClOhe~.3~Ol A X Cyclohexanone A X D D. T. Preparat~onr A D,ammonum Phosphate D,cnloroerhylene Dnrthanolammc A A NIlrate 20% A A I3 X A P”W Glycerine Calcwm Arsenate sol. X Alcohol A+ Peroxde Hydrochlortc Ac,d Hydrochlor,c Ac,d Hydroxy 2% 20% Oumolme A B B x B X X A B Isopropyl A Alcohol Kerosene A Lacttc Acid A A a Lmseed Cake A A A A A A A A A A Magnesrum Chloride 50% Mercury Methane Methanol PlJre B A AI B Methyl-Cellosolve A A Methyl Acetate A A Mrthyl Bromtde A X B A+ B A IY)cyanaleS T 194OF 9O’C A Ether Acettc Acid Ace,,c AnhydrIde BESN BLACK (continued) TABLE 1.21: NYLON 11 RESIN-RILSAN (continued) RATING CHEMlt34 CONCErJTCATlQW WF lWF 14OOF - 20°C GO’C RATING BESN BLACK T 194OF 9O*C CONCENTRATION WF --7G’C 104OF 40°C 14WF 6Ll”C Methyl Chloride A 4oc X Methyl Sullale A a A A A A Milk A A A B X X Monochiorobanlene B X X A A A Mustard A Naphtha A A A+ Ndphthalene A A A 6 A A7 X X X X 0 X Otis Crude A A At 011‘ Refw2d A A A Ole,c Actd A A Oxalx Melhy tthvl Ketcne Methyl Isobutvl Krrone All Concenrration Ntrrbc Ac\d A B B A A A x A A A X A Ai A A A B X A A A A A B A A A A A B X A A A Oxygen A A B X A A n Perchloroerhylrne B X A A Ai Phenol X X X A A 8 A B X A A A t3 X X A A A A A B A A A A 6 X A A A At Fit X A A A X X A A+ 6 A A B Acud Phosphoric Acid 401 P,cr,c Ac,d PJ,ars,“m Cdrbcnate Potauwm Hydroxade Potai,um N,rrats Potrwum Parmmp~rl*lu Pa,arsi”m S”ll~l. lro?? b’l. X X X A A A A Propane A A A Pydraui F9 A A A 0 X X X Pure Pyr,d,ne A A Soap Solution Sodum Carbonate Concenxaied A A B X Sodum Chlortde Saturated A A A A Sodurn Hydroxide SC% A 0 X X Sodurn Hvpochlwtte Concentrrred B X X A 5 X Sodwm Hypochlorlte Dduw Commrrcnl Grade Synthetic TABLE 1.22: NYLON REINFORCED VINYL HOSE-SETHCO DIVISION, Resins and Polymers 67 MET PRO CORP. Sethco’s NRV (Nylon Reinforced Vinyl) grade hose may be used at working pressures ranging from 100 to 250 psi (depending upon size). Its flex life exceeds that of rubber and its characteristic inertness satisfies requirements for a wide range of industrial and laboratory applications. The reinforcing nylon mesh is encapsulated in the walls of the clear vinyl, providing a high strength, smooth surface hose. The imbedded mesh is never in contact with fluid or atmosphere. Working temperatures range from 20” to 175°F as discharge hose and 20” to 140°F as suction hose. The vinyl is fire resistant and self-extinguishing. Sethco Nylon Reinforced Vinyl Hose Chemical Resistance Guide Excellent Chemical Resistance Acetic Acid Air Alcohols Aluminum Chloride Aluminum Sulfate Alums Ammonia Gas Ammontum Chloride Ammomum NItrate Amnlonlum Phosphate Ammomum Sulphate Amy1 Alcohol Animal 011s Ant:mony Salts Arsemc Salts Barium Salts Basic Copper Arsenate Beer Benzolc Acid Benzyl Alcohol Boric Acid Basic Copper Sulphate Bordeaux Mixture Butanol Butter Calcium Hydroxide Calcium Hvnochlorlte Calcium .&its Carbolic Acid Carbon Monoxtde Caster Oil Corn 011 Cottonseed 011 Caustic Potash (-20%) Caustic Soda (-20%) Chloroform Chromic Acid Chlortne IDrvt Chlortne (Water) Chromium Salts Copper Chloride Copper Sulphate Cltrlc Acid Cresvllc Actd Cupric Sulphate Also Recommended Essential Oils Ethgl Alcohol Ethyl Chloride Ethylene Glycol Fatty Acid Ferrtc Chloride Ferric Sulphate Fluoborlc Actd Flue SI~ICIC Acid Formic Actd Formaldehyde Freon Galhc Actd Gas (Natural) tS;sa;;;e (NonA:omattc) El;S;i?pendtng Oxahc Acid Oxygen Palmmc Actd Picrtc Acid Phosphoric Acid Potassium Chloride Potassium Sulphate Propane Pyrethrum Sodium Btsulflte Sodturn Bicarbonate Sodturn Borate Sodium Carbonate Sodium Chloride Sodium Cyanide Sodwm Hydroxtde Sodium Hypochlorlte Sodium Nitrate Sodium Phosphate Sodtum Slltcate Sodium Sulohlde Sodhum Sulphate Sodturn Thlosuiphate Steanc Acid Stannous Chloride Sulphur Dtoxtde Sulphurlc Actd (DII Sulphurous Acid Tanmc Acid Tartartc Acid Tar 011 Turpentine Urea Uric Actd Vinegar Water Whiskey Wine WOOI 011 Zinc Chloride Zinc Hydrate Zinc Sulphate ) for manufacturer Acetlc Anhydrtde Acetone Acetyl Bromide Acetyl Chlortde Ammonium Hydroxtde Amy1 Acetate Aromabc Hydrocarbons Butyl Acetaie Carbon Bisulfide on type) Glycerine Hydrochloric Acid Hydrocyantc Acid Hydrofluonc Acid Hydraulic 011 Hydrogen Gas Hydrogen Peroxide (DII.) Hydrogen Sulphlde Lacttc Acid Lard Lead Arsenate Lead Sulphate Lime Linseed 011 Magnesium Chlonde Magnestum Hydroxide Magnesium Sulphate Malelc Acid Milk MIneral 011 Molasses Ntckel Chloride Ntcottne Nttnc Acid 20% Nitrogen Oxtde Nitrous Actd 011 Aniltne Benzlne Benzol Borax Butane Bromine Calcium Btsulphlde Calctum Chlonde Carbon Tetrachlonde Caustic Potash (+ 20%) Check with for: Causttc Soda (+ 20%) Chlordane :t7zot e Gasoltne (AromatIc) Hvdroaen Peroxlde Icon.) K&o&e Mercunc Chloride Methyl Chlonde Olelc Actd Pentane Perchlortc .Actd Perchlorethylene Phw?olates Ph Jnols Stoddard Solvent Sulphurtc Acid (Cont.) Trtchlorethylene Trichloracetlc Acid or test in your plant Chloracetlc Acid Cresols Cyclohexanone Ethyl Acetate Ethylene Dlchlorlde Fuel 011 (AromatIc Gas) 100 octane Fuel 011 Isopropyl Acetate Ketones Laquer Solvent Naphtha Nltrobenzene Paint Solvents Pyridlne Toluene Toluol xylol Xyiene 68 Corrosion TABLE 1.23: Resistant Materials OXIRANE Handbook OLIGOMER OF RESORCINOL-PLASTONICS INTERNATIONAL KEY PROPERTIESOF PYROITE ll 1) Corrosron resistance to most solvents (See compatibMy chart.) chemrcals Erosion 2) resistance 3) High dielectric 4) Stability and corrosive 5) Excellent bondrng characterrstrcs. Bonds to metals, glass. concrete, glass. plastics, etc. and toughness. strength to temperatures from -80°F to over 500°F. 6) High resistance 7) Non-galling to thermal fiber cycling. capability. DATA INTERPRETATION M ETALS / DEPTH OF CORROSION PER SURFACE * 002 In. per year 4 4 020 In per year (4 050 In per year (4 ) 050 In per year or exploswe (4 RESULT mm. yr.) 05 A B 5 mm. yr ) 1.27 mm. yr.) C NR - Not recommended No data cl Questronable rate to mrlllgrams per To convert decimeter per year mdd (mdd) = I” yr X ,695 specific X gravity of metal PLASTICS SWELLING OR DIMENSIONAL CHANGE. (ANY DIRECTION.) WHICHEVER IS GREATER. LOSS OF TENSILE STRENGTH DESCRIPTION CHEMICAL ATTACK RESULT LIttIe or none A 4 1000 4 1500 4 1500 430°0 42000 45000 Ltmlted ,2000 ,5000 Attacked or dissolved wlthln minutes or years (Not recommended) NR No data - Good resistance resistance No data No data B (Manor attack) (Moderate C attack) Q Ouestlonable Note When botllng IS tndlcated. boiling temperature varies with concentrahon - of corrodent EXAMPLES OF TYPICAL CALL-OUT METALS w 002 I” yr I” any 1 002 I” yr al concentration 20°0 I 002 an yr saturated 4 010 I” yr I” any * 050 I” yr saturated ) 050 I” yr 0 to w 050 CentratIon) can yr 70°F lo 212’F A to 20°0 to 212’F A at 20°0 at 212°F at 70°F A between 20’0 and between 70°F 50’. and 140°F B 20.50°0 at 70°F eftect 70.140°F NR concentration saturated greatly from a1 212°F concentration I” any in 0.20% concentratnn at 70°F at 70 ‘F corrosion Just NR any a few degrees Comblnattons of temperature marked dtfterence A NR are crltlcal (or percentage points as to concentration concentration of con. A NR or temperature PLASTICS Llttle to no chemical 200°F Ltttle 200 Good from (temperature to no chemical ‘F (temperature resistance 70°F Attacked lo 4 lo00 swelling or 415O D loss of tensile strength at lOOn concentration at 70°F or A at top of column) attack 4 10O0 swelling or 4 15’ o loss ot tenslie strength from 0 to 20°0 concentration at 70°F or A to 20°0 at top of column) (minor chemical attack) 4 15’0 Swelltng or *30° o loss 01 tenstle strength lrom 20 to 50°0 concentration B 20.50°e 140°F or dissolved ~twnm=rati~re attack W20°0 at too 01 column swelling 1 01 b50° I) loss of tensle strength I” concentrated at 70°F 70.140°F or 200-F NR (continued) ‘ABLE 1.23: OXIRANE CHEMICAL OLIGOMER OF RESORCINOL-PLASTONICS PYROITE II 200°F KVNAR 200°F STAINLESSSTEEL 316 70°F INTERNATIONAL TEFLON FEP 70°F EPOXV 70°F (continued) HASTELLOV 6 70°F VINVL ESTER THERMOSET 70°F TEFLON PFA 200°F PYtlgrE 1 Acetamide Acetate Solvents Crude Acetic AcidVapors100% (hot) Ace& Anhydride 100% (boilng) Acetic AcidGlacial 70°F Acetone100% Acetonilrik Akohol, 2 Aminoethanol (continued] TABLE 1.23: OXIRANE OLIGOMER OF RESORCINOL-PLASTONICS PYIl#$E II CHEMICAL I KYNAR 200°F I INTERNATIONAL TEFLON FEP 7O'F STAINLESSSTEEL 316 7O'F I I (continued) EPOXY 70°F I VINYL ESTER THERMOSET 70°F tlASTEl.LOY C 7O'F I I PYROITE I TEFLON PFA ZOO'F I 70°F I Aluminum Sutphata 10% Aluminum Sutphata 410% hating Aluminum Sulphate ~10% boiling Aluminum Chbrohydroxtde (wet) A Ia 1 1 I. 201'F h "I as L I, 70°F Lb 7D'F 1E fn11w 6qIl?q I B AC Ia50% ,a210°F I h A A* to50% I#200°F Amines Ammonium Chloride 10% Ammonium ChMde 410% baiting Ammonium Chhnide blO% hoiting 1 I (continuec (continued) TABLE 1.23: OXIRANE OLIGOMER CHEMICAL Bromine Butane Moist OF RESORCINOL-PLASTONICS PYROITEII 200°F 1Bromine watt, A BI,llli(le WIIC 50% II 212-F Gas STAlNLESS STEEL 316 70°F KVNAR 200°F WI 25% to 212°F A to 212'F "Rh* wit" INTERNATIONAL TEFLON FEP 70°F A ,a 200-F (continued) NASTELLOV 70°F EPOXY 70°F C A A BR.im WIk WA II VJ'F 0c Broannrwater VINVL ESTEA TNEAMOSET 70 “F TEFLON PFA 200°F AC ID 100% to 80°F IdAliquid A A 25% 8w"m.e Wll" la 200°F PYFly\TE 0 1 "R to 70°F Bc Bmnlm wt.3 100% Buttermilk Butykne I Bulyl Phthalate I Cakium Carbonate Cakium Chloride (saturated) Cakium Chbride (dilute) Cakium llypochbrile I 100% A I A II 15'F I A,. 125'F A AC D WJ'F I I I A I I 74 Corrosion N -0 a N Y t I < v s c Ye -0 < P * Resistant :a a; - Pr :r E; a ” < f N s < Materials < N Y :: D Y c - Handbook 0 N Y 0 :: < - Y I f < < - I I TABLE 1.23: OXIRANE OLIGOMER OF RESORCINOL-PLASTONICS INTERNATIONAL (continued) Copper Flumtdc Copper Nitrate (hot, concentrated) Copper Sulfate (hot, concentrated) Coltonreed oil (continued) TABLE 1.23: OXIRANE OLIGOMER CHEMICAL I I Oebqcnts(general) I D*IAybther OF RESORCINOL-PLASTONICS KVNAR ZOO'F PY?tI$E II I AI * 70°F BDlrz"F I 7@"F Kd,L*'F INTERNATIONAL STAINLESSSTEEL 316 70°F A.” I I K (continued) EPOXY 7O'F TEFLON FEP 70°F I VINVL ESTER NASTELLOV C 70°F I TEFLON PFA 200°F THERMOSET 70°F I I PYROITE I 70°F I Ah300"F Olbobutybne DinethylAnillee Mmelbyl Fomumlde IAmelbyl Pbthalate Mnw?tbyl SuSexlk (continued) ‘ABLE 1.23: CHEMICAL P-Dioxanc OXIRANE OLIGOMER OF RESORCINOL-PLASTONICS PYROITE II 200°F 1 KYNAR 200°F Ch lZ2"F WI II 151°F ws ls0l.r 1.1 STAINLESSSTEEL 316 70°F o INTERNATIONAL TEFLON FEP 70°F Ill WD’F (continued) EPOXY 70°F “(I HASTELLOY C 70°F VINYLESTER TNERWOSET 7O'F TEFLONFTA PYll)bFTE I “R I 1 ,a 70°F 200°F Dow Therm Ethyl Benzene Ethyl Ether Ethyione Diamine (continued) TABLE 1.23: OXIRANE OLIGOMER PYIN$E CHEMICAL OF RESORCINOL-PLASTONICS II KVNAR 200°F STAINLESS STEEL 316 70°F INTERNATIONAL TEFLON FEP 70°F EPOXY 70 “F (continued) NASTELLOV 70°F C VINYL ESTER TNERMOSET 70 “F TEFLON PFA 200°F PYI$ITE I Hexamine Hydraulic Fluid (Petroleum) Hydraulic Fluid (Synthetic) Helium Hydrochloric Acid l-20% Hydrochloric Acid 41% Hydrochloric Acid 1% Nydrochlodc Acid ‘h-2% 175°F Hydrochloric Acid ,2% 175°F 175 “F (continued) TABLE 1.23: OXIRANE OLIGOMER PYROITE CHEMICAL 200°F I OF RESORCINOL-PLASTONICS II KYNAR 200°F I INTERNATIONAL TEFLON FEP 70°F STAINLESSSTEEL 316 70°F I I (continued) EPOXY 70°F I NASTELLOY C 70°F I VINYLESTER TNERMOSET 70°F I PYROITE TEFLON PFA 200°F I 70°F I (continued I TABLE 1.23: OXIRANE OLIGOMER OF RESORCINOL-PLASTONICS KVNAR 200°F PYIl$-f$E II CHEMICAL I I Lime-Sulpher (Cakium Sullide) Linokk Acid Linseed Oil Lithium Chloride 30% al 200°F I Lithium Hydroxide 10% al 200 “F 1 INTERNATIONAL STAINLESS STEEL 316 70°F I I (continued) NASTELLOY 70aF EPOXY 70°F TEFLON FEP 70 “F I I C TEFLON PFA 200 “F VINYL ESTER TNERMOSET 70 “F I I PYROITE I 7O’F I ‘ABLE 1.23: OXIRANE OLIGOMER OF RESORCINOL-PLASTONICS STAINLESS STEEL 316 70°F INTERNATIONAL TEFLON FEP 70°F EPOXY 70°F (continued) HASTELLOV 70 “F C VINYL ESTEA TNERMOSET 70 “F TEFLON PFA 200°F PYROITE I 70°F Mineral Oil Morpholhw Nickel Chloride Nickel Nitrate (continued) TABLE 1.23: OXIRANE OLIGOMER OF RESORCINOL-PLASTONICS PYllIfTE0 CHEMICAL II I With Acid Fuming HiIrk ACM (70% cont.) (Suflng) I 1 C soxm2~F KYNAA 200°F *s*,t2~F CnM rh@nur 70°F “II IS% I INTERNATIONAL STAINLESSSTEEL 316 70°F TEFLON FEP 70°F Ab125"F "(Id 212'F 170% ,#L,)"F 1111U,.,I,‘F I A OS% B SO% “II me. A 2540K Alw” CUT. A ,470-r sC w*-t,*'F A 100% ,040D"F A,. 300°F A A 1 II600°F A,# 300-F A I,1,2*F I b 122'F A A,#IOO'F Ati Z,t"F I I.212"F s 1sX II212'F Is 10% ,I150°F AI 10.100xbIO"F A,# too-F A YII., 70-F s 100% A ,,7DDF N-octane A Al4 176°F MIS Animal A OilsCrude A Mb A -en Nitmmethanc NAnus Acid Nllmus Oxtdc Mineral "II “0 I NASTELLOY C 70°F Atl,ZS"F C,@ 122'F nn * Z,?OF PYI$j~E TEFLON PFA 200°F I ml funllnp C/M SO'%a IO'F MD 50% a,l.l'F A * 248'1 1.90% c 73'F I) 10% 20% Cnl” sx AC 2x “s-ox A 70% WA m 1 s 100% b 211°F CnM I0100% Is100°F A M 10IO'F C 10122-F WR I,212'F A to600°F AilII-3ZO'F A A A A ID100°F A A ,a,OODF A I A 4 AC I#10% ID150°F s 100% A I A I.IO'F L 1s* 140°F A A Ah 28s'F IIO"Ftr M UlrPx )IhZDO"F A xs,# 100% ,a210°F ,ma*HUr) A A k,, Z75"F A 7)'FU b, A IO2ss"F A A AB,a ,sOX 1sl,O"F I A A A,4 7O'F A 1 Ash ,OOK b 210°F 1 )1 Ash ,OOK h 210°F A A Mb ,00x h 21O'F A A As 1, ,OOK m 210°F A A IO212°F A OlisVegetable A A,,17I"F A 70170°F A,. 70°F A A Okk A AD 248°F LB IO"F,#500°F 080% ti120°F A ,a200°F A A ,005 IO160-F B,OOW ,ss"Fh 212-F Oxalk Ac!d 4 Ah 12O'F CW 200°F UI ti211-F s te4ox WR cute. IM ,040# * 212°F A W+s# 11100°F A ,,2OO'F 1 I#112-F s,O~‘OOX 70-F IO21*-F Oxygen A A 11FzlS'F Ozone I AD t7s'F palmltk ACM A A ,It,.'F PWMII A A Is'F,.Wn A ,a70°F 1 Pentane 1 C C r.Fwa*,,S*F AIUO'F A A * 1W"F Asb75DF 1 & Antardq A I.,*s'F AII,%?ll'F A 1 1 I.70°F AClrWO"F A ,eIDO'F As,~,sox I#12O'F A A It)Cmm,Nld v.1 I.(50°F A L A A A I I M k 70-F "II,! 212'F MkMve Acid (redo/l) VINYLESTER TNEAMOSET 70°F 1 SC 10 70°F AsI0 212°F Wobmuene I (continued) EPOXY 70°F (continuec rABLE 1.23: OXIRANE OLIGOMER OF RESORCINOL-PLASTONICS PYIH$E D II CHEMICAL INTERNATIONAL KYNAR 200°F 3TAlNLESS STEEL 316 70°F TEFLON FEP 70 ‘F A !0 70°F (continued) VINYL ESTER THERMOSET 70 “F TEFLON PFA 200°F PYROITE I A 10 170°F A 10 1‘O”F Slqif ~ktf,Dk*I biB 10 180°F A L IO 180°F A 10 70°F A 10 lW”F A 110 210°F & A 10 *se “F A A EPOXY 70°F HASTELLOV 70°F C 70 “F Plating Solutions Nickel A A A to Ill’F AC IO 14O’F wa ckt,rnk** Plating Solutions Silver 1 A I0 120°F A 10 IZD’F 1 ID 70°F 1 I0 12D”F A ,a 120°F As IO 1.30”F Plating Solutions Tin L Aa c 11 10s “F A ID 70°F A 10 100°F 110 100°F 1s II *IO-F Plating Solution Zinc A 1s 1 Syllidt II 7s “F aa Chhlrld~L ““obofltr A 10 10°F L l0 150°F A 10 150°F rlclpl 1cld Chbnidl A _ AB 10 Ieo’F A 10 70 “F 1 A 10 275°F A8 10 15O’F I ,a 200°F A AE 10 30s “F ?.e 10 100% 10 220°F A A A 1s IO ZIS’F a 10% I0 21Z’F e WOY. 10 IO’F A I# 7O”F A a 10% ,D ZlZ”F a 100% 10 70°F Aa I0 50% I# 150’F 1s 10 100% 10 l,O’F L. A 1 10% c 100% a 100% a 70°F e lll.wh IO 212°F a 1OfJ% II 1501°F Ia 10 lee* 10 212°F A A A A 1* 30% 11 IO’F a 100% IO 212°F Ia lo 100% 11 110°F AC 10 IelI% 10 110°F L A As 10 sex IO 150°F 1 L Potassium Acetate Potassium Aluminum Potassium Bicarbonate Potassium Potassium Bichromate Bromide Sulphate (alum) 1 1 A ID 27S’F A *a.sox I0 212°F a CMC. I0 1W’F A 1v 275°F s I0 70% 1D 212°F (pit,) A l1lY tt I(15”F A II 200°F 1 A lee% 11 1500°F A lo-es% ID 21zv a 100% d 70°F A 10 2eev A I# 200 ‘F YR rylnldr 11 180 “F As 10 160°F Potassium Carbonate A A to 275°F A I, 17% 10 240°F a 2o.las’h II 70°F *20-70x II 211°F Potassium Chlorate A A to 27S’F A 104llK I@ 212’F s Io.1ee’h ID 7O’F 1 e 200°F A s 30% I0 21Z’F c se.7e% I, 212°F AB I0 lluJ% (0 110°F A A Potassium Chloride A Ah 275°F As lwh to 70 “F A 10~30K 10 212°F A 10 250°F A A loll% It 350°F a 100% IO 7O”F A8 10.sclx (0 212°F Aa 10 100% 10 21O’F A A Polassium Chromate A AI II 275°F I IO-40% I# ?1?“F e 10~100% II 70°F A 10 7O’F c A 1040% I0 212°F Aa lo 10% 10 IlO’F A ID 70°F A Potassium Cyanide A A I@ 275’F II II lOOK l0 2,2”F a le.,oo% 10 70°F a 10.30% ,D 212°F A lo 200°F A a ID-JO% 1. Z12”F e 100% II 70°F AI 10 loll% I0 14ev 1 A e 100% II 7O’F a 1e.eex IO 212°F II 100% aI 1500°F Ae 10 100% I# 2W’F A II a wwh 10 Z12’F As 10 100% 10 210’F A JO’,. 10 70’F A a 10-w,. IO 212°F Aa to 1Oil% 10 210°F A L Potassium Dichromalc ii A lo 275°F A 10-60’~ I# 212°F a OOIU. 10 150°F A 10 2OO’F A ID% c 100% Potassium Ferricyanide A AD 275°F a IO-WY. IO 212°F a 10.100% I0 7O’F A 30% I@ 70°F A Potassium Fetrocyanide A AC 275°F s IO-100% ,a 212°F A 5% 170°F A 10 2OO’F Potassium Hydrate A loax 11 70°F a lll~ssx t. 211°F we IODK #I 5DO’F I so.*w. I, 212°F A *ox l0 250°F A 1alw I0 125OF c 10% II 70°F II 100% n 7ev “II 30% d 70°F A IO 70°F A II 212’F Aa 10 130°F Potassium Hydroxide A Ah ,s7v I IO 212°F c e 230°F Potassium Hypochlorlte A A* Potassium iodide-iodine A Potassium Nitrate 1 A A a 10-6ax 10 3DO”F a 100% II 7ll’F a 10~1wh 7O’F I# ssev I\ so 200°F eme ID wh I( IIID’F A a lw/. II ID’F e IO-soy* 70°F ,a 212°F I,0 1aa”F A A 1 IO 70°F I 1a I0 lo**/, 10 ZOO’F A II 70°F A 18 10 100% ID 210°F A A a 10.1!wh 7DOF I# 212°F A 11027S’F A b 70°F (continuec (continued) TABLE 1.23: OXIRANE OLIGOMER OF RESORCINOL-PLASTONICS PYIi$JE CHEMICAL ssll Arhle (Sodium Chbrkb A Silver 1 Bromide I Sodium 1 H 122°F s 8, 15s”F E ., 211°F (continued) EPOXY 70°F TEFLON FEP 70°F VINYL ESTER TNERMOSET 70°F NASTELLOV C 70°F TEFLON PFA 200°F 1 In ,ls°F PYl$$TE 1 ). I Solution) Sinconc Oil Wlvcr Chbrlde INTERNATIONAL STAINLESS STEEL 316 70°F KVNAR 200 ‘F I SIlCyklddlVlb I II 1 Aluminum Sulfate I 1 A x a=*h 1 - I 1 @MIs-100% 70°F x c )1 1 h 70’F 1 1 x Ah A 1 lk125’F A,CWX a,211°F 1 h rO”F xs ,, ,W”F 1 U 2sV”F 1 - 1 B s t. (0% I0 r,Z”F 1 - 1s 10 ,usx 1 10 120°F A I 1 I A I Sodium Bcnzoate Sodium Rkrrbonate Sad&mBichmmale Sodium Aisulfate Sodium flisulSte Sodium Borate (Borax) x b 27s’F 1 1 xs 10 ,DO# I, 1,D’F 1 I (continued) 1 I YABLE 1.23: OXIRANE PYlgl_F CHEMICAL Salbm sodium OLIGOMER II Bfomtda CSf&onale(Sodx ash) sodbnl chbrate II STMLEI WEE1 316 70°F KVNAR 2OO’F B 1CSSU 1 U 275-F A A II 27S'F A A,4 27s"F I (brbe) OF RESORCINOL-PLASTONICS x” "175°F AuPr*I 11,155X b212'F S IWX 8,500"F MS.15.WX S1CIWX Y 212'F U7O"F "SISK II 12S'F S 2030% b 212°F A IWX ta 71.212-F bMSt%.7S°F INTERNATIONAL 7ERON FEP 70’F At, 20.-F AD 200-F A 10X N 2W"F A t,c11.t,20O~F CtMdr Sodbm Chmmate x I,lCWK 71.ZIZ'F .lSOX"IS'F So&m CNfab A S 15%,.212*F Sl,lSS%at7S'F Ata7O'F ChsdatlZSZ°F A IS% @212-F AlCIW(X,!7SDF Yt3SX al IllOF At4 71'F Sodium Cyantde 1 Sodium Dkhmmab 1 Sedbm Fafttcyantds A Sodium Fluodde Sodium Hydroxide ,I*dLi, A (cruxliC Sodldp) Sodium Hydroxide (mette11)WKt4 :F 1,. 275-F Aa xab A5X*lAny SICIWK 4l771'F CM .X al l.0.F AS%#bNh*c Ata27S*F A lCZOX Ia 212°F I "MD%~~2~F A WY. I, 212-F &".r-M25S.F SC,OS%.45S*F as YI lit, xc 275-F w x ” k%2;170 ‘F Sadbm Hypochbrtte I (sobtbn) Lt. 275'F A.,%,. ul-Y5x I,, AOXl.ZW"F 12°F ASlWX r2sx5aa2 A 20% t. 122-F C ~1.b 7S"F YIIul. aI 122-F SlOTOK SIOX A IaZlZ'F At, tWX C A 71-F ta212"F II 212'F aI 7O'F t. 212-F Al0IWX 7C212'F A AUZ12'F AS!4 IDS% t# 1SO"F A A II 212'F A ASb SSK t. 215-F 50% Ia 215-F l012O'F ASI8 50% blW"F AU71'F AS,. ,00X t. IIS-F A A A AS,, ISSOX b 21,-F * AIt4 210-F AS,, lWX II 21,-F ASt.2lO'F Aw7O'F A.U A m xa IIs xn lln 12OXt.2W'F A IS% ,a 2SO'F C 20% SS- Sodium Nitrate Sodium Nttttte So&urn Perborate A Sodium Pemxtde A AU 275°F A 70.212'F Ab2W'F 1,.50X AIcCW&. Sodium Phosphates A At. 275°F AS 10.100X 70212°F ADIW'F A A 1‘X AIlSOX AS5X.tl2S'F SC S.lSX .tlSO"F AS" A Ia 70°F 1 * lOOF A A II 2SO'F A "I1 AS S 30~1OOX 1,.20X : z;::: Ai:w9: “I ASU 20% I, ,.0-F AZSXtr2W'F A LSD 20X at210'F 1 A A A SS xn I AS!, IWX 1.2tS'F 111 ASI0 100% I. 210-F AII2WO"F At,7.'F 20% U 210-F 2lS"F (mkwvb A YX )I 241°F A ".&,a 7.-F A A ,00X at 70°F 510% U 212-F AS WX to *IS-F AS 100% t.22)'F AA-." 7S'F 2X 45-W% al 210-F Uils-25% til25'F AS5X121SDF A l&SO% U 212'F S 1204L d 70-F S 15~00% at 251°F AStl2OX AC-. A 5SX ,, 122OF D55H .I ISO'F 0 1,70X11 212-F A 100% "IS-F Nitrate I A AbIO'F A SK UIZZ'F 14OU b 122'F C4,X ., 212°F Sodium A k 275-F 10 1W 'F A A 1&1OOX 70212°F A AS10~2SX Al.lOOX Ia 12S'F ASSXt.2W~F Metasltbate I AS t, 1SO'F l--w Sodium KS A A.taISSX"lSS'F 1 (motten)~5S6°F PYilfjFFTEI to ZIO'F ASb2SX Ab2OSQF Metaphospbate Ata 2759 7EFLON FFA ZOO’F ASUIOOI AIH A tS5X lO.llS*F I ISX At, 7,'F Sodium A YtNYL ESTER l’NEttMO3E7 70°F SlSaOX A 1OSX M A C A 101WX1121Z°F S 1WY.U 15W'F At.212'F Sodium HyposulAta 24,-F NMI’ELLOY 70°F SIC5.K AO2SO'F Sodtum 275-F (continued) EPOXY 7O’F A A I AS S 10% I. 212'F AS* A 1&100X 70.212°F SO-F AS,4 IWX 10 210-F ru#pl rlJdilJ8 *I.mMa**tM* A AS A A Ia SD% h 150-F A ~~ A (continued) TABLE 1.23: OXIRANE OLIGOMER OF RESORCINOL-PLASTONICS INTERNATIONAL (continued) SlrnnkChbrkb Stannous Chloride liti SSO'F Steam I Sutphate Bbck Liquor I A Sulphate 6mn liquor 1 Sumnol A SUlphll l.kplu (100% soktion wtth10% SO,) A I PdSSS'F )rb,IOO'F At.2SO"F Ah27S'F It, 212'F Ek,SS'F A‘.Z"'F A Al, 70°F A )I,212°F A A Al978~F AI)II 212°F At.,O'F At. SSO'F I ABt,tZO'F At,212-F AOh It, 175°F AStelOOX 100% U 20.-F te2OO'F A A A At,,SO'F I A A A ABM 212°F AIt. 100% WZOO'F Ata7ST ASleIOOK II 220°F (continued) I TABLE 1.23: OXIRANE OLIGOMER CHEMICAL Thioey( Tb I I Triethykne Ttiethyl Trtphenyl As * M’F ,449”F Tnchbromoneiberoatham Glycol Phosphate (Freon STAINLESS STEEL 316 70°F KYNAR 200 “F ZOO’F Chloride Mottrn OF RESORCINOL-PLASTONICS PYROITE II INTERNATIONAL TEFLON FEP 70°F m It 70DF “1 A ,I 125-F ne C ee (continued) EPOXY 70 “F NASTELLOY 70°F C WY1 ESTER TNERMOSET 70 “F TEFLON PFA 200°F PYROITE I we A C MR IIR I “R *uil * “war WR AC tnnw* “I 70 “F 17) I I A A* 125’F I A A I. 200°F YII I ! AS ID 100% IO 2OP”F A 1 IO 2OO’F Phosphite (continued) I ‘ABLE 1.23: OXIRANE OLIGOMER PYIttI;E CHEMICAL OF RESORCINOL-PLASTONICS II KYNAR 200°F STAINLESS STEEL 316 70°F INTERNATIONAL 1 TEFLON 7O’F FEF EPOXY 70°F (continued) I I HASTELLOY 70 “F C VINYL ESTER THERMOSET 70°F TEFLON PFA 200°F I I PYl$ltE D I I Trisodium Phosphate Tung MI (china wood oil) Turponline Vinylkline Chbride (Resb) Water. Acid Mine Water. Boibr Feed Water. Uirtllbd Water. Fresh Water. Ueknlzed Water. lb-mineraLed Water. Brackish Water. (salt) See ah0 Sea Water Wax Whiskey (continued) TABLE 1.23: OXIRANE CHEMICAL WhHc Liquor(PulpMill) OLIGOMER OF RESORCINOL-PLASTONICS INTERNATIONAL (continued) PYROITE II 200°F KVNAR 200°F STAINLESSSTEEL 316 70°F TEFLON FEP 70°F EWXV 70°F HASTELLOY C 70°F A A Ia70°F A Al4 7D~F A 1 VINYL ESTEA THERMOSET 70°F mm 1ml"F TEFLON PFA 200°F A PYliy\TE D 1 I TABLE 1.24: PHENOLIC RESINS-OCCIDENTAL CHEMICAL Durez The following chemical resistance data was obtained by exposing several DUREZ materials to common known chemical contaminants for variable periods of time and then calculating the percent change in specimen dimensions and weight. The specimens were either 2” diameter discs by l/6’.” thick; or X” by I$” bars, 5” long. The appearance of the afterexposed specimen was graded according to the following codes: A - Smooth, glossy G -Wrinkled B - Slightly dull H - Swollen C - Dull I - Cracked D - Fiber shows J - Warped E - Pimpled K - Blistered F - Mottled or unsigned values indicate specimen growth or weight values indicate specimen shrinkage or weight loss. Positive negative 13856 % Change Chemical Acetic Acid (Glacial) Acetic Acid (5%) 791 CHEXICAL Black % Change Chemical in 118 x 2” Diameter Aretic Acid (5%) Hydroxide (10%) Aniline Tetrachloride Cztric Acid Hydroxide (cont. Ammoxuum Hydroxide (10%) Solution Dimethyl (0.25%) Formamide DistIlled Acid Acid Detergent Acetate Ethyl Alcohol Ethyl Alcohol Ethylene Hydrogen Nitric Acid Oleic Phenol 9.00 G Hydrochloric Acid (cont. 1.20 Hydrochloric Acid Hydrofluoric Acid Acid (cont. (50%) 1.20 5.00 G Nitric Acid 0.06 c Nitric Acid 1.80 A Oleic I Phenol G Soap Sodium Hydroxide (10%) Sodium Hydroxide (1%) Sodium Hypochlorite Sulfuric Acid (30%) Sulfuric Acid (3%) Toluene Oil A 9.21 11.11 E (10%) 2.70 6.40 8.20 E (40%) 3.00 8.00 14.00 H fuel oil) White USP ) 38 I 1.10 I 1.70 I I 5. a0 B 0.01 -0.39 0.21 A 0.04 -0.66 0.30 A 0.05 ) 0.13 A 0.39 I I I I (40%) I I I I (10%) I I I I Acid Solution Solution (5%) (1%) 0.20 0.04 1.30 0.99 0.60 5.40 A 1.10 0.49 5.30 A A I Sodium Carbonate (20%) 0. a2 0. a1 4.50 B 0.45 0.90 C Sodium Carbonate (2%) 1.10 1.40 5.90 A 2.70 5.40 11.00 Chloride 4.50 9.20 Sodium Hydroxide (60%) I I I I 1.90 3.80 a. 50 F G G So&urn 2.30 Sodium Hydroxide (10%) I I I I 1.60 3.00 7.10 A Sodium Hydroxide (1%) I Sodium Hypochlorite I I 7.00 3.20 (4-b%) I I I 0.15 (10%) (#Z -0.29 2.71 (3%) Nltrtc Chloride E A (28%) G Sodium A 0.66 0. 36 Peroxide Oil, -0.31 2.10 Peroxlde 0.49 (2%) G 4.70 0.21 Hydragen -0.11 (5%) -0.61 1.10 0.02 Hydrogen 0.09 (1%) A 0. (95%) Carbonate Turpentine Dichloride Mmeral Sodium Transformer Ethylene Heptane Kerosine Solution 1.17 -0.99 -0.44 C 3.20 (10%) Solution A G G Acid 5.29 4.40 c 9.80 0.68 1.20 lsooctane 4.60 F 1.00 0.98 E 2.10 5.05 (50%) G (3%) F 0.68 Alcohol 0.54 Peroxide -2.29 1.00 Ethyl G I A 0.87 -1.10 I B 0.14 0.26 0.63 I -0.55 0.29 0.20 0.21 (10%) A 0.98 32 -0.37 0.09 a. 10 Acid 1.50 -1. (95%) 0.18 0.25 B 30 Alcohol a. 70 0. 36 8. 0.95 -0.18 Heptane 2.50 Ethyl 9.70 -0.25 H 1.80 Acetate 3.90 0.03 12.00 Ethyl 4.60 2.30 E -0.39 5. 60 -0.16 Water 2.40 1.80 Dichloride Hydrochloric DIstilled B 0. 56 18 I G 13.00 I I I I I I I I 17.00 G 0.14 -0.05 0.51 C 0.02 -0.75 0.05 A -1.20 0.10 A 2.70 0.01 9.90 (10%) 1.00 (4-a%) 1.40 1.90 0.06 ) A 5.50 2.70 F 10.30 -7.90 13.00 F Sulfuric Acid (cont. Sulfuric Acid (30%) 3. 30 5.50 13.00 E Sulluric Acid (3%) 0.94 1.50 4.90 F TClhleIle Trauaformer Turpentme I 0. Oil 16 0.04 0.00 I -0.02 1.00 -1.00 I I 0. 61 A 0.02 A -0.05 23-C. B 5.50 3.90 0.12 FormamIde 12.00 -0.03 -0.22 (0.25%) at D 543-60T Appearance Weight -0.03 1.60 0.65 Ether 2.10 32 (40%) Solution Dlethyl Appearance -0.72 -0.02 (10%) 0.09 Water Ethyl W+ight -0.21 0.06 Tetrachloride Exposure ASTM Thickness 0. Citric D 543-601 ) One-Year bsk Diameter Benzene Chromic at 23-C. x 2” Anll~ne A C G G 0.00 (10%) Detergent Thickness -1. -0.29 Carbon iS.TM 5.00 2.40 Exposure Disk -0.35 -0.23 Ammonium One-Year 6.00 2.90 Acetone Soap RESISTANCE l/8 -0.04 Ammomum Dimethyl IIurez RESISTANCE in 1.10 Acetone Carbon gain; CHEMICAL Black A (continued) TABLE 1.24: PHENOLIC Exposure Material Condition and RESINS-OCCIDENTAL Chemical Resistance Various Chemicals to X Change X Change Length Thickness for (continued) CHEMICAL 1 Week Exposure X Change Width 2 Change Uaterial Weight and Condition 23570 l .12 +1.34 + .78 + .8b Boiling 10% E2SO4 + .04 l1.20 + .60 + 10% H2SO4 10% NaOH + .I3 +3.5a +I.85 +2.24 10% NaOH 10% WOH + .02 + .I5 + .13 + 10% N-&+OH 0 l .16 + .lO 0 Leaded 0 + .12 + .lO 0 lo-30 0 + -14 + .I1 - .Ol Transmission 0 -1.23 - .43 - .03 Brake Water Leaded Gasoline Motor Transmission Brake Resistance Various Chemicals to for 1 Month X Change Length X Change Thickness X Change Width X Change + +2.73 +1.42 +2.64 Weight 23570 BoillnR lo-30 Chemical Oil Fluid Fluid .88 .lO 50% Glycol + .Ol - .a7 - .40 + .09 50% 5% NaCL + .o: - .91 - .46 + .11 50% Alcohol + .Ol - .93 - .45 + .09 Water .12 * + .03 Oil Fluid + Fluid Glycol * + .28 + .18 0 + .13 + .I0 0 + .07 + .09 - .Ol + .14 + .ll + .09 l .98 + .47 + .07 Gasoline Motor * l .Ol 0 + .23 0 + -02 - .90 - .41 + .20 5% NaCl + .03 - .94 - .44 + .24 50% + .07 - .63 - .42 + .20 Alcohol - Not * Deteriorated Available (continued) TABLE PHENOLIC 1.24: RESINS-OCCIDENTAL Chemical Exposure to Various CHEMICAL (continued) Resistance Chemicals for I and Change % Change Length Condition -Thickness X Change - Width Various Chemicals Material and to X Change X Change Length Thickness + .08 10% H2S04 + l 10% NaOH + X Change Weight Condition for 1 Week X Change %Change Width Weight +1.09 + + .25 +6.95 +3.06 +4.56 .16 +2.54 +1.27 +2.48 + 29502 23570 Bolllng Boiling Water 10% B2S04 l + 10% NH40H Leaded -34 Transmission +7.11 * Water + .24 + .5fJ 10% NH40H 0 - .90 - .46 0 + .11 - .08 - .02 Leaded 0 - .77 - .46 0 + .06 + .04 - .04 lo-30 0 - .BO - .43 + .06 0 + .14 + .11 + .Ol Transmission 0 - .64 - .44 + .02 0 - .79 - .39 + .Ol - .92 - .41 + .lO - .80 - .46 + .06 - .92 - .40 + .05 Fluid Gasoline Motor .02 - .98 - .50 - .17 Brake 50% Glycol + .06 - .83 - .33 + .47 50% Glycol 5% NaCl l .08 - .83 - .36 + .61 5% NaCl 50% Alcohol + .06 - .82 - .22 + .47 50% Alcohol Fluid - Not l Deteriorated .55 .28 - Brake .64 + .09 Oil +2.56 * Gasoline Motor +5.66 l 10% NaOH lo-30 Resistance 6 Months Exposure Material Chemical Oil Fluid Fluid + .01 0 + -01 .Ol 0 Available (continued) 98 Corrosion Resistant Materials Handbook :: 0; + x Y; + 8 A + 4 2 + 2 + z + 0 0 2 0 l 8 1 + 0 + 0 D a :: + k s z + 2 + + w 1 1. z + TABLE 1.24: PHENOLIC RESINS-OCCIDENTAL CHEMICAL (continued) Chemical Chemical 10 Days in 25O’F Vapor at I X Change Weight Material Resistance 96 16 psls Change Pressure X Change -Diameter -Thickness Appearance Code 156 1.72 .76 .50 B 165 2.17 1.19 .73 B, E. K 13856 2.64 1.24 .05 .92 .66 22829 1.98 30169 3.27 2.55 1.22 30698 1.74 .a7 .57 Chemical 10 Days in 25O’F X Change H.3teria1 Weight 156 2.67 Water Resistance ilt 16 2 Change Diemeter - Code 1.03 B 1.55 3.00 13856 3.56 1.11 30169 3.75 Appearance 2 Change 165 2.20 Pressure -Thickness 1.74 22829 psis .77 1.. 09 -95 .59 B, E, K 30698 1.97 .80 In Boiling Water f X Change X Change Material Weight Thickness 111 7.24 5.72 1.71 8. F 118 7.68 4.45 1.23 B. R 123 5.14 6.03 1.26 B. R 145 2.36 1.13 .63 B. E 152 4.13 2.33 1 .oo A 4.05 Change Diameter Appearance Code 153 5.00 1.19 C. 156 2.09 .92 -48 B, E 161 3.39 1.46 .76 B, f 165 1.62 .60 .33 B 791 6.24 3.61 1.64 B, 3948 6.42 4.49 1.67 A E E 3856 3.80 1.70 .91 A 14900 2.82 1.21 .60 B, E 16378~ 3.39 1.65 .64 B. E 18420 6.17 3.13 1.60 A 18441 6.79 3.47 1.76 B 21028 6.44 3.35 1.88 B, A D 21210 7.52 5.11 1.00 22257 7.08 4.02 1.63 B 23570 1 .oo .22 .I5 B 29237 6.20 5.03 1.19 B. D, 30270 2.77 1.30 .69 B. K 30614 .a9 .32 .21 B 2.14 .59 .34 B 30698 3.00 1.20 30806 3.20 30645 2.59 Rours Resistance F 1.28 .52 .9O .80 A. .80 A B. (continued) D TABLE 1.24: PHENOLIC RESINS-OCCIDENTAL Chemical 96 Rours in X Change Naterial We IRh t BoilinR CHEMICAL (continued) Chemical Resistance Sulphuric X Change Thickness Acid 96 (H2S04) X Change Appearance Diameter Code Hours X Change In Boiling Resistance Caustic X Change Thickness (.5% NAOH) X Change Diameter Flaterial Weight 9.41 7.88 .90 Appearance Code 111 18.49 15.58 2.72 C. F. C 111 118 24.53 14.15 2.59 C. D. H 118 12.88 4.32 1.26 B, D 123 16.46 15.29 2.80 B. H, J 123 7.36 6.54 1.44 R, R 145 7.92 12.76 1.25 C.F 145 4.89 1.17 .77 R. E 152 15.14 12.39 2.25 C. F 152 4.64 2.57 1.19 B. E 153 11.58 11.14 2.19 C. F 153 6.38 5.54 1.47 C, E 1.51 1.18 .63 B. E R, F C. E 156 11.17 10.36 1.27 C. E. F 156 161 4.71 3.74 1.02 C. F 161 3.96 1.79 1.00 165 1.63 1.25 .61 C. F 165 2.14 .81 .49 B 791 17.66 13.93 7.20 C, D. H 791 7.16 4.39 1.87 B, 3948 10.20 7.31 2.43 B,F.R.J 3948 7.29 4.75 2.10 B 7.10 4.55 1.56 B 13856 3.91 1.80 .94 R, C C. E 14900 2.87 1.38 .62 B, E 3.69 1.90 .79 B, E 13856 E 8.76 8.01 1.13 16.75 11.37 .60 D, F 16378A 18420 6.05 3.55 1.78 B, J 18420 6.64 3.89 1.71 B 18441 8.84 4.98 2.27 R, D, J 18441 7.27 3.84 1.84 B. D 21028 26.67 16.66 4.89 C, D. H 21028 2.10 C. D 14900 16378A 21210 12.03 10.57 B J F 23570 1.05 .31 .22 B 3.30 C. D, F 29237 5.76 .57 1.22 C, 3.73 1.33 B. E. J 30270 3.65 8.08 .94 B, E. I 30614 29237 22.03 15.80 30270 5.21 30614 4.91 3.91 B 1.88 E. 8.84 7.10 2.27 5.84 H. 12.92 7.41 30698 9.36 8.16 C. 16.76 30806 B.C.H,J 6.31 C. 22257 25.75 4.21 22257 23570 30645 2.39 7.68 21210 2?.56 2.73 3.53 2.53 .86 3.59 .93 1.66 .99 2.05 .90 C .55 .24 R. -33 B C.R.C.R.1 30645 2.23 C. 30698 3.12 1.32 .82 R. 30806 3.70 1.12 .91 B B K .59 D, E K (continued) E TABLE 1.24: PHENOLIC RESINS-OCCIDENTAL CHEMICAL (continued) Chemical 96 Material Change Weight 111 8.05 2 chemical 168 Hours (7 Days) in Sodium Aypochlorite (52 NeOCl X Change 2 Change Thickness Diameter ‘at Appearance Code 118 6.08 1.80 .84 C 123 4.22 1.99 .83 C 165 1.6C .55 .47 C. D. 791 3.18 1.65 C, D 1.01 3940 4.05 2.02 1.21 C. D 13856 2.90 1 .Ol .71 C. D 14900 1.18 .41 .27 C. D 18420 4.26 1.93 .14 C, D 18441 4.89 2.39 1.28 C. D 21028 1.46 .93 C. D 22251 4.58 2.92 .67 2.70 1.95 1.47 .93 C, C, 2, Change Thickness (5% Ivory) X Change Diameter Appearance Code 6.16 1.79 C, C E 118 11.46 5.48 1.49 123 2.96 6.72 1.51 C. K 145 2.26 1.24 .52 C. S 152 4.45 2.65 .99 C 153 5.77 4.58 1.37 C f 156 2.11 1.09 .37 C. 161 3.51 1.73 .88 C 165 1.92 .64 .43 C, F 791 7.43 4.45 1.93 S. D 3948 8.13 5.76 1.99 C. D 13856 3.70 1.70 .80 B, D E 14900 2.94 1.37 .62 8, E 16378~ 3.47 1.78 .73 B. E 18420 7.40 4.11 1.93 C. J 18441 7.59 4.07 2.01 B, D 21028 7.44 3.90 2.12 C, D 21210 9.34 6.66 2.36 B. D 22257 8.58 6.30 1.95 C. D 23570 1.01 .26 .19 D 2.65 1.32 .76 C 30614 1.28 .03 -07 C, D 30645 1.41 .31 .33 C. D 30698 .83 .02 .50 C, D .50 .43 C. D, 1.61 Soap D 30270 30806 Boiling 50-c )lateria1 21210 In Resistance Change Weight 2 Hours Resistance B F 29237 7.39 8.02 30270 3.34 1.61 .88 C 30614 1.00 .39 .24 C 30645 2.34 .49 .33 B 30698 3.21 1.10 .a3 S. K 30806 3.50 1.10 .80 B. D 1.55 C, D. F TABLE 1.25: PHENYLENE OXIDE-BASED RESIN-GENERAL ELECTRIC COMPATIBILITY NORYL resins are especially noted for their outstanding hydrolytic stability. The water absorption rate of all NORYL resins, both at room temperature and at elevated temperatures, are among the lowest of any engineering thermoplastic, which contributes to the retention of properties and dimensional stability in the presence of water, high humidity and even steam environments. In addition,‘NORYL resins are also virtually unaffected by most aqueous solutions, detergents, acids, and bases. TESTING PROCEDURE Introduction This test is used as a method for predicting the longterm effects of contact materials or environments on the physical properties of Noryl. The test uses specimens which are exposed under strained conditions at various temperatures duplicating as closely as possible the effect of residual and induced stresses in a fabricated part. By measuring the loss of certain physical properties we can estimate the effects of exposure to the environment on a Noryl application. Test Procedure NOSYI QFN3Rssti NORYL 731,831 Resin Nom-l. QFNZ Ream APPUd%WS.Pl 0 8.ooO 0 WC0 0 3aOO 0 38ooApplied~,pSi 0 8Dw HJdEdl0mACid(lcrrs) N N N Ii N N N IiJdmao~Acid(mnc.) N N N N N N -Aud(lc%) N N N N N N -And(m) N NN N N N NA -Aua(m) N N N N N A BA IU?MCAdd(lulb) N N x N N N N NoiricM(lm) N N NN N NX -emc@Jm> N N x N N KTdmfmo*Add(m) N N -UtUEi N NNNNNNN W(lW) x x x N N aEcade(lB) NNNNNNNN N N OlelcAcld N NNANNNA N N MamiacQmo11 N NNANANA Unssedoli N N Unenrloil NNNNNNNA vammle NNNNNNNA x x x xliaptane N x bm,haml NNNANNNN x N N Impropanoi EthylcmeQlycai NNNANNNA Ammonia NNXXXXXX Qulf_~Ofi NNNNNNNN -w(lm) NNNNNNNN Ryhon NNNNNNNN -ImF=Jdee(mno.) dmmonflno phosphate(~) NNNNNNNA NNNNNNN N GE.6lllmneC)-e87 N NNNNNNN Hcw&tm6&6SO N NNNNNNN --(sat) N LlcmeaQmao NNNNNNNX --(eat) NNNNNNNN lnm6cm/m NNNNNNNN -O-illoIlds(Bat) NNNNNNNN BesterNo. 13.5 NNNNXXNN QOKIX NNNNNNNN NesterNo 164 NNNNXXNN Lesml(28) NNNAXXXX NNNNNNN 2. Test 3. Apply the contact material to the tensile bars making sure the material is in direct contact with the bars. If the material is a piece of tubing or gasket material, it may be secured by using a copper wire to tie it to If the material is a liquid, the tensile the tensile bar. If the bars and strain jigs should be totally immersed. material is a grease or paste, coat the tensile bars. x 0 3800 0 3800 x 4. xxx AAANALXX N 2EP Place the tensile bars in the strain jigs which dupliFor a standard cate the stress levels to be checked. test use 0%. l/2% and 1% for unfilled grades and O%, l/4% and l/2% for glass-filled grades. a minimum of 3 tensile bars for each stress level. TwsEl 0 6,CM N N NORYL Resin 1. N Place the specimens in suitable containers and place one set in an oven for 3 days at 185'F and the other leave out at room temperature for 7 days. Example: N N N If testing a material with NORYL number of specimens would be: 731 the N 0% l/2% 1% 3 days @ 185O~ 3 3 3 =9 7 days @ RT 3 3 3 =9 Total 18 5. At the duration of test, remove the specimens from the oven and leave at room temperature for a minimum of 30 minutes. Then use the Instron to determine tensile strength and % of elongation. Reporting Results The contact material is considered compatible if there is no cracking, embrittlement or less than 10% loss in tensile properties. The material is considered marginal if there is no cracking, crazing or less than 20% loss in tensile properties. An incompatible material is one which cracks, crazes or loses more than 20% of its tensile properties. (The above are compared against a control). (continued) TABLE 1.25: PHENYLENE OXIDE-BASED RESIN-GENERAL ELECTRIC COMPATIBILITY Effect en 731 Aggres - (continued) TESTING RESULTS Effect Norvl N-190 siveness* 731 Aggres- Aggres - en Nor!1 N-190 A5grcs- siveness* siveness' siveness' n-PtntAne Qlase S Craze S n-IItxk7e Craze S craze S Ethy~ne No CctAne Cr*se S Qaze S Ethyltncdiamine No Effect Dodccane Cr*ze S Craze S Diethylamine SW811 V Swell v n-Amylarome Qack V swell M hiethylamine Crack V Crack V Aromatic Effect NC Effect No Effect Toluene Solvent n Solvent n Ketones Xylem swell V Swell V Acetone Craze V Craze Methyl ethyl ketone Well V swell V V Hethyl propyl Ketone SW11 V swell V mtiyl Crack V Crack Methyl phenyl ketone Craze V Iscphorone Crack V aazt= QaZe Cyclohexmone Solvent M Swell V Swell M SVISll !4 Crack V Swell Qack V Swell n-Propyl acctAt-e SW11 v Swell isopropyl acetate Crack v we11 Acetic anhydrlde No Effect _ No Propionic anhydride Crack V Craze Alcohols No Effect Qare Et!!nol NO Effec? craze Isopropanol No Effect n-Butin No Effect Pentan Craze Isohexanol No L=fcct OCtanOl NO Effect Methan 2-Ethyl B-01 Trimethyl-3.5, 5-3-huancl U-are Craze Craze Craze S Craze Qaze S Qate Acetates Ethyl Solvent V Solvent Solvent V Solvent Trxhloroathylene Solvent V Solvent l,l,l-hichloroethme Craze V Craze 1.1,2-hichloroethane Solvent t4 Solvent Chlorobentcne Solvent n Solvent Chloroform V craze Chlorinated Chloride V V Q*2.S S Methyl Methylem iscbatyl ketone acetate acetate Anhydrides . AggressivencsS: S-Slight, M - Moderate. V - Veri Effect S 104 Corrosion TABLE 1.26: Resistant Materials Handbook POLYALLOMER-EASTMAN CHEMICAL PRODUCTS The effects of various chemicals on TENITE Polyallomer Formula 5020 were determined by and measured injection-molded samples of the plastic in the chemicals and maintaining them 73°F (23°C) for one year. After one year, each sample of plastic was removed from the jar in wiped dry, and quickly weighed and measured. The appearance of the sample after exposure was also recorded. immersing weighed at a temperature of which it was tested, to the test medium The shelf-life tests were conducted using 50 ml capacity, 0.010 inch (0.25 mm) wall thickness blow-molded bottles of TENITE Polyallomer 5020 filled with selected household items. The filled bottles were stored at temperatures of 73°F (23°C) and 140°F (60°C) for one year. Changes in bottle weight and appearance were determined at the end of the test period. Polyallomer is highly resistant to chemical attack and to stress-cracking. and attack the surface slightly. These chemicals are mainly chlorinated the higher aliphatic hydrocarbons, such as gasoline. Resistance of TENITEE Polyallomer [Exposure: One 5020 Year WeIghI. 0i0 Thickness. 4, 5L< Cl 04 c 28 Nc C’iange lsooctane cone ? ?8 i^ 33 NC’ Change Kerosene 1 94 0 01 c 74 NC, Change lysol Ace;one ChaII#E Raagenl Acellc Chemicals (23’(Z)] WeIghI, % Thicknass. 6 30 15 90 Appearance Ace:~c Acid Acid to Various at 73°F Change in Reagent However, a few chemicals produce swelling compounds, aromatic hydrocarbons, and 1750 ifl % Appearance B.lt.stered. Discolored. Swollen 5 50 BlIstered, Swollen DIscolored, DIsInfectant 0 11 0 12 No Change 0 04 Nc Change Methyl Alcohol 0 12 0 08 No Change Ammonium Hydroxide cone 0 37 c 04 Sli;htly D~scolore:! Mmeral 011 0 59 0 12 No Change Ammomum Hydroxide 10% 0 13 0 20 Slqhtly D~scolorec Molasses 0 03 0 28 No Change 15 10 5 70 Swollen Mouthwash 0 35 0 16 No Change c 38 0 12 NC Change Mustard 6 04 0 12 No Change 6; 50 11 20 Swollen Nltrlc Acid, cone 4 70 0 45 Badly DIscolored -0 08 c 04 Sl~;h!ly Nltrlc Acid. 40% 0 79 0 16 Slightly DIscolored (1 08 0 08 No Change Nltnc Acid, 10% 0 02 0 08 Slightly DIscolored 0 03 0 12 No Change Olelc Actd, 03% 0 51 0 12 No Change Aicorrox De’crgent (0 25°,L! Benzene Brake Fluid Carbon Tetrachlorlde Chromic Citric Acid. 40%. Acid. 10% Coffee DIscolored 011 c 05 0 08 No Change Ohve 011 0 04 0 08 No Ghange Dibatyi Sebacafe 1 51 0 29 No Change Orange Drink cl 05 0 04 No Change Dlerhyl Ether 14 10 0 20 5 so Sfiollen Phenol, 5% 0 04 0 08 No Change 0 08 No Change Soap Solution, 0 01 0 04 No Change 0 37 0 20 No Change Sodium Chloride, -0 01 0 00 No Change 0 01 0 04 No Change >odlum Cabonate. 2090 0 04 0 04 No Change 0 ia 0 24 No Change No Qlange Cottonseed DI 2-Ethyl Dlme:hyl Hexyl Pn!halate Folmarmoe Delomzed Water 1% 10% Ethanol 100% 0 26 0 12 No Change Sodium Carbonate, 2% Ethanol, 50% 0 07 G 21 No Change Sodtum Hydroxide, 10% -0 03 0 00 5 20 1 60 No Change Sodium Hydroxide. 1% -0 01 0 04 No Change Sodium Hypochlorite, 0 08 -0 03 0 12 Discolored Ethyl Acetate 3 5% Ethylene Dichlortde 10 60 1 90 Si4ollen Gasolme. Regular 19 40 7 60 BlIstered, Sulfuric Acid, cone 0 04 DIscolored Gasolme. High Test 17 60 6 80 Swollen Sulfuric Acid. 30% -0 005 0 12 No Change 16 90 6 70 Swollen Sulfunc Acid, 3% -0 008 0 08 No Change 19 50 6 20 BlIstered. 0 07 0 08 No Change 3 50 1 50 No Change 23 70 7 50 Blrstered. Hexane Swollen Hydrochlonc Aud, cone 0 11 0 24 No Change Toluene Hydrochloric Acid. 10% 0 01 0 08 No Change Tomato Hydrogen PeroxIde. 28% Hydrogen Peroxide, 3% lodme Juice 0 01 0 08 No Change Transformer -0 01 0 16 No Change Turpentme 011 0 08 Stalned 011 Swollen Swollen (continued) Synthetic TABLE 1.26: POLYALLOMER-EASTMAN Shelf-Life CHEMICAL PRODUCTS Resins and Polymers (continued) Data on Blow-Molded Bottles of TENITE@ Polyallomer [Exposure: One Year at 73” F (23” C)] 5020 Change In Weight. % Appii~llC8 Mustard -0 33 No Change Molasses -0.13 No Change Orange Ormk -1.66 No Change Mouthwash -1 14 No Change Tomato Jurce -1.06 No Change Coffee -0 61 No Change Lysol Drsinfectant -0 14 No Change lodme -1.69 No Change -0 12 No Change Shoe Polrsh -0.29 No Change Margarme -0 07 No Change Grape Jurce -1.00 No Change Cheese Spread -0.32 No Change Grape Jelly -0.42 No Change +o 14 No Change ivory Detergent, 1% Peanut Butter Shelf-Life Data on Blow-Molded Bottles of TENlTE@ Polyallomer [Exposure: One Year at 140” F (60” C)] Changs In fleapent Walght. % Appanncs Mustard -4.2 No Change Molasses -3.9 No Change Orange Drink -10.8 No Change Mouthwash -24.0 No Change Tomato Juice -5.0 No Change Coffee -9.1 No Change Lysol Disinfectant -6.0 Bottle Stained -31 .l Bottle Stained iodine ivory Detergent, 1% -4.0 No Change Shoe Polish -4.1 No Change Margarine Bottle cracked at seams in Grape Juice -5.0 No Change Cheese Spread -6 7 No Change Grape Jelly -6.5 No Change Peanut Butter 1 day Bottle cracked at seams in four weeks 5020 Corrosion 706 TABLE 1.27: Resistant Materials Handbook POLYCARBONATE-MOBAY CHEMICAL The combination of mechanical and optical properties offered of the characteristics of a transparent metal. It is a thermoplastic toughness, and a temperature capability up to 250°F. Because of a combination bonate sheets are finding MERLON is resistant of optical application characteristics, impact strength, and dimensional stability, MERLON as glazing, especially in those areas where glass breakage is high. at room temperature Industrial Acetic acid (20%) Aluminum chloride Aluminum sulphate Ammonium ctiloride Ammonium nitrate Ammonium sulphate Antimony trichloride Arsenic acid (20%) Butyl alcohol Calcium chloride Calcium nitrate Chlorinated lime paste Chlorinated lime solution Chrome alum Chromic acid (20%) Citric acid (40%) Copper chloride Copper sulphate Cuprous chloride Cyclohexane Decahydronaphthalene Ethyl alcohol (96%) Formic acid (10%) Formalin (30%) Glycerine Glycol Hydrochloric acid (10%) Hydrochloric acid (20%) Hydrogen peroxide (30%) Hydrofluoric acid (20%) Iron chloride Iron sulphate Isoamyl‘alcohol Lactic acid (20%) Magnesium chloride Magnesium sulphate Manganese sulphate Mercuric chloride Nickel sulphate Household Nitric acid Nitric acid Dleic acid ~,xxa$$id (2%) Chocolate Cinnamon Cod tiver (10%) (20%) Petroleum ether Phosphoric acid, cont. Propyl alcohol Potassium aluminum alum Potassium bichromate Potassium bromate Potassium bromide Potassium chloride Potassium nitrate Potassium perchlorate Potassium permanganate Potassium persulphate Potassium sulphate Propargyl alcohol Propionic acid (20%) Silicone oil Silver nitrate Sodium bicarbonate Sodium bisulphate Sodium bisulphite Sodium carbonate Sodium chlorate Sodium chloride Sodium hypochlorite Sodium sulphate Stannous chloride Mineral heating zvtse$water Detergents (nonionic Fish 011 Floor polish Fruit syrup Glaziers putty Grapefruit iuice gc”p”s;f~tt peel Ink Insulating tape Linseed oil Linseed oil standard and anionic) MERLON has limited Petrol Refined oil Spindle oil Transformer oil Vacuum pump oil resistance Orange jurce Orange peel Paraffin oil pepper Rapeseed 011 Rum Salad oil Salt solution (10%) Soap (soft and hard) Table vinegar Tincture of iodine (5%) Tomato concentrate Tomato juice Turpentine Vodka ;;&ng soap varnish Wine to: Cycloheranol Gasoline (high aromatic) Hydrochloric acid (cont.) M~RLOW is not Acetaldehyde Acetic acid Acetone Acrylonitrile Ammonium ;;nyz;$rn resistant Milk of lime Nitric acid :conc.) Sulfuric acid (cont.) to: Ethane tetrachloride Ethylamine Ethyl ether Ethylene chlorohydrin Formic acid (cont.) Freon* (refrigerant & propellant) Nitrobenzene ;;t;o;fllulose lacquer (cont.) fluoride sulfide Benzoic acid Benzyl alcohol Bromobenzene Butyric acid Carbon tetrachloride Carbon drsulfide Carbolic acid Caustic potash solution (5%) Caustic soda solution (5%) Chlorobenzene Cycle hexanone Cyclohexene Dimethyl formamrde lDupont unstressed MEaLon trademark, MERLON is dissolved except at room Phosphorous hydroxy chloride Phosphorous trichloride Propionic acid 5$cJr~n~ sulfide Sulfuryl chloride Tetrahydronaphthalene ;f$.x$~ne Xylene Freon 113, temperature. which may be used by: Ethylene Methylene Pyridine dichloride chloride oil $$ar~il %z! Products Chloroform Cresol Dioxane Materials oil Petroleum Axle oil Brake fluid (room temp.) Compressor oil Diesel oil Gasoline (low aromatic) ~~!$~:ic acid (10%) Sulphuric acid (50%) Tartaric acid (30%) Trichloroacetic acid (20%) Zinc chlorrde Zinc sulphate Beer Borax Cocoa ~~Z;;;il polycar- to: Chemicals Common by MERLON gives the designer a material with many which provides good optical properties, exceptional Dimensional Change Water A$sorption vs. Per Cent Water Absorption DimenGo,~nChartge Conditions n I I MERLON Samples Original 0.0003 50% 0.0013 Room Boiling 0.0008 Aged in Hot Water for 6 Months Dimension (Inches) 1.3373 1.3374 0.8735 0.0 R.H. Temp Water (212’F) Dimension after 6 months immersion (Inches) 1.3382 1.3390 0.8740 on Synthetic TABLE 1.28: POLYESTER ENGINEERING RESIN-DART Resins and Polymers INDUSTRIES XYDARM RESINS CHEMICAL TENSILE STRENGTH AND ELONGATION Original Value 60% RH (5 wks. @ Rm. Temp.) Water (200 Hrs. @ llO°C) Water (30 days @ 82'C) Acetic Acid (1 week @ reflux) Ethyl Acetate (1 week @ reflUX) Bleach (1 month @ 5O'C) Brake Fluid (1 month @ 50°C) 10% NaOH (1 month @ 5O'C) Transmission Fluid (1 month @ 50°Cl Motor Oil (1 month @ 5O'C) Skydrol (2 weeks @ 71'C) Antifreeze (1 month @ 5O'Cl 20% ~~S04 (1 month @ 50°C) 37% ~~S04 (1 week @ 50°C) 100% H2S04 (1 week @ 5O'C) 20% HCl (1 month at 50°C) 70% HNO~ (11 days @ Rm. Temp.) Gasoline (Leaded) (1 month @ 50°C) MEK (1 week @ reflux) Isopropyl Alcohol (1 week @ reflux) JP-4 (1 month @ 5O“C) Detergent (1 month 4 5O'Cl Trichloroethylene (1 week @ 5O'C) (*l % Decrease in tensile 30%; D = >30%. strength RESISTANCE BEFORE AND AFTER XYDAR- SRT-300 Tensile Elong Rating (%l_ (psi) 16810 4.9 16900 A 3.0 13770 B 4.9 15900 A 3.3 17290 A 3.9 16290 A 3.1 16640 A 3.9 16390 A 3.8 16010 A 3.4 17320 A 3.6 17090 A 4.7 17940 A 3.9 17990 A 4.2 17230 A 3.9 15600 A 3.2 ----Disintegrated---16520 A 3.6 16400 A 2.8 16840 A 4.3 16200 A 3.2 17680 A 4.4 16860 A 5.1 17800 A 5.1 19000 A 4.0 after exposure EXPOSURE(*) . Tensile (psi) 17730 17000 13380 17100 15420 18160 16920 17540 16490 17220 17580 17280 17700 17600 11080 XYDAR- SRT-500 Elong. Racing (%C B A A A A A A A A A D 4.8 3.1 4.2 3.4 3.2 4.0 3.1 3.8 3.3 4.0 4.6 3.7 2.8 3.8 3.6 17410 A 3.5 16840 18150 19420 17030 16840 19900 A A A A A A 4.9 5.4 6.0 4.8 4.9 4.1 A C A - A = 0 to 10%; B = 11 to 20%; C = 21 to 107 108 Corrosion TABLE 1.29: Resistant Materials POLYESTER Handbook LAMINATES-HAYSITE REINFORCED PLASTICS HCR-191 is a chemical resistant polyester laminate produced by the match metal molding of fiberglass mat, inert fillers and HETRON@ 197 resin. HCR-191 laminate when compared to other corrosive resistant materials offers excellent weight to strength ratio (specific gravity of HCR-191-1.9 . . stainless steel-8.0) and ease of handling and fabrication. HCR-196 is a chemical resistant polyester laminate produced by the match metal fillers and DERAKANEB470 resin. The DERAKANEB470 is a vinyl ester resin. HCR-197 is a chemical resistant polyester laminate produced by the match fillers and ATLAC 382 resin. The ATLAC 382 system is bisphenol A fumarate CHEMICAL RESISTANCE Concentration Temp. Materials % Acetlc Acid Acetic Acid Acetlc Acid. Glaclai Acetlc Acid. Vapor 8 C:ondensate Acetophenone Aluminum Tnchlonde Aiumlnum Fluonde 2.Ammoethanol Ammoma Aqulous Ammomum Chlonde Ammomum Fluonde Ammomum Hydroxide Ammomum Nltrate Ammowm Persulfate Ammomum Phosphate, Monobasic Ammorwm Salt of Pnmary Alcohol Glycol Ether Sulfate Ammomum Sulfate Ammomum Thiosulfate Amy1 Acetate Amy1 Alcohol AnlIme Antimony Pentachlonde Antimony. Tnchlonde Antimony. Tnchlonde Banum Carbonate Banum Chlonde Benzene Benzene Disulfonic Acid Benzene, Sulfontc Acid Benzolc Acid Bromme, Dry Gas Butyl Acetate Butyl Carixtol Butyl Phthalate Butyric Acid Calwm Chlorate Calcium Chloride Calccum Sulfate Caprylic Acid Carbon Dioxide Carbon Tetrachlonde Chlorine Gas, Dry Chlonne Gas,Wet Chlorofluocarbon ‘Note: S - F. 25 10 100 25 100 40 100 100 28 45 40 20 45 25-100 65 210 65-95 100 180 75 210 75 05 80 200 150 150 200 150 225 S S S S S S S S S S S S S S S 100 60 60 100 100 100 100 50 100 100 100 100 100 25 100 100 100 100 100 20 All All 100 100 100 100 100 100 100 100 250 100 75 200 125 75 200 75 250 250 75 194 200 250 75 75 85 100 200 250 250 250 140 250 120-122 ‘40 220 158 S S S S S S S S S S S S S S S S S S S S S S S S s S S S S of fiberglass mat, inert metal molding resin. of fiberglass mat, inert DATA OF HEIRONe Test ReSUI1S’ molding Materials 197 Concentration % 32 Chromic Acid Sat Chromous Sulfate All Copper Chloride All Copper Cyamde Sat Copper Nltrate 100 Dtbuty Phthalate 100 Diesel Fuel 1iW DIethanoI Amme 100 Dlethyl Sulfate 100 Dlethylene Gycol Dlethylene Gycol N-butyl Ether 100 100 Dilsobutyl Phthalate 100 Dodecene. trace WI Sat Ethyl Acetoacetate Ethyl Alcohol o-95 Ethyl Chlonde 100 Ethylene Chlorohydnn 100 Femc Chlonde 100 Fernc Nttrate 100 Ferrous Sulfate 100 37-44 Formaldehyde Gasoltne 100 Glycenne o-75 100 Heptane. Vapor 8 Condensate Hydrochlonc Acid O-20 Hydrogen Chlonde Gas 100 Lead Acetate All Magnestum Carbonate TM) Mercury 100 35% So Vapor Nitric Acid Perchlonc Acid O-72 Stanmc Chlonde 100 Steanc Acid 100 Sulfunc Actid O-50 Tetrapotassium Pyropl losphate 60 1.l .l-Tnchloroethane 100 100 Trimethyl Carbinol 100 Tnphenyl Phosphite 100 Trisodium Phosphate O-50 Urotroptne 28 Xylene 100 21nc Chlonde 70 Zinc Hydrosulfite Sat. Zinc Sulfate All Temp. F. 140 150 250 250 140 100 75 75 100 100 85 80 120 80 150 75 200 250 250 250 150 194 250 120 230 392 250 250 250 200 85 75 250 200 125 80 80 100 122 75 00 100 300-310 160 250 Test Results’ S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S 3 S S S S S S S S S S S Satisfactory (continued) Synthetic TABLE 1.29: POLYESTER LAMINATES-HAYSITE REINFORCED PLASTICS Chemical Resistance of Dow DERAKANE MAXIMUM SERVICE CONCENTRATION % CHEMICAL ENVIRONMENT Acebc Acld Acebc Acld Acetlc AnhydrIde Acetone Ac,d Cleaner hydrochloric acld Acrykc Acid Ally1 Chloride Alkyl Benzene Sulfow Acld Alummum Chlonde Alummum Chlorohydroxld.? Aiummum Nitrate Alum~nw” Sulfate Ammo”,um Chlortde Ammonun Phosphate. dlbaslc Ammomum Thlocyanate Ammonium Thwxulfate Barlum Sulfate Benzaldehyde Benzene Benzene, Ethyl Benzene Basulflte I” Scrubber Black Liquor recovery 25 50 100 10 31”. _ 25 A,, 92 All 50 10 All All 65 50 60 A,, 100 100 I/32/3 Gases _ Bow Acld’ Brine Butrylc Acid Capryl~c Acid Carbon Tetrachlortde Chlonne dry gas Chlorine. wet gas Chloroacetlc Aod Chromic Acid Copper Matte Dtpping Bath 3O”o FeCI3. 19% Hydrochloric TEMPERATURE VS CHEMICAL MAXIMUM F/“C CHEMICAL ENVIRONMENT 210199 180/82 loo/38 180/82 190188 100138 80127 120149 2501121 210199 180182 2501121 210/99 210199 100138 100/38 250,121 70/21 100138 100/38 350,177 100 All A,, 100 A,, 100 100 100 50 20 3501177 200193 210/99 210/99 120149 210/99 180182 250/121 2501121 150165 150165 _ 200/93 CHEMICAL (continued) 470 Resin ENVIRONMENT CONCENTRATION % Dethano, Amine Dlethylene Glycol Dwobuty Phthalate Ethanol Ethyl Alcohol Ethyl Benzene Benzene Ethylene Chlorohydrln Erhy, Sulfate Femc Chloride Hydrochloric Acld Formic Acid GaSOllne HeptZl”e Hydrobromlc Acld Hydrochlonc Acld ,sopropy, Myrlstate Jet Fuel (JP-4) Lead Acetate M&c Acld Morphollne Naphtha N,tr,c Acid Oxakc Acld Phenol S”,fo”,c Acid Pla,l”“m Piatlng Solution Propvavc Acld Sodium Chromate Sodlum Hydronde Sod,“m Lauryl Sulfate Stvrene 80 F Bath 120149 210199 150/65 100138 W/38 120149 100/38 100138 29 185 All 100 100 62 37 _ 180182 100/38 180/82 210199 100138 180/82 2301110 180/82 230/110 2501121 80127 210199 80127 210199 80127 180182 100138 210199 180182 160171 120149 3001149 100138 100138 3001149 3101154 2501121 A,, 100 100 40 Ali 65 100 50 10 Ail 100 _ 75 Ail _ _, Transformer 011s Z,nc Chloride Zinc Sulfate OF ATLAC MAXIMUM ‘FI”C 30 100 100 95 All 213 l/3 100 100 /1) RESISTANCE Resins and Polymers 70 Al, 1 382 The data below represknt the current knowledge of corrosive envlronmental conditions which Atlac 382 blsphenol A fumarate resin will withstand when properly used In relnforced olastlc laminates: CHEMICAL Acetic Aad Acetic Acid Acetic Acld Ammonium Hydroxide Ammomum Chloride Ammonum Sulfate Amvl Alcohol B&l Alcohol C&urn Chloride Calaum Sulfate Chlonne Dlox,de Chlorme Dry Chlorme Wet Chloroacetlc Acld Chloroacetu Acld Chromic Acad Ethyl Alcohol Ethylene Glycol Ferric Sulfate Ferrous Nltrate Fluos~luc Aod Gylcerm Hydrochlonc Acld Hydrochloric Aad Hydrochlonc Acld Hydrogen Peroxtde Hypochlorous Acld Lactic Acid CONCENTRATION % 10 25 50 20 All 20 All All A,, All 5 _ _ 25 50 5 All A,, All All 10 too 10 20 37 30 20 All MAXIMUM OF 220 220 140 140 220 220 220 180 220 220 220 220 220 220 140 200 180 220 220 220 80 220 220 160 160 160 220 220 CHEMICAL Magnesum Sulfate Metal Plating Solubon Methyl Alcohol Napthalene N,tr,c Acld N,tr,c Ac,d Perchlorlc Acld Phosphoric Acld Potassum Carbonate Potassum Carbonate Potassium Hydroxide Scdlum Blcdrbonate Sodurn Carbonate S&urn Carbonate Sodium Chlonde ?&&urn Hydroxade Sodium Hydroxide Sodurn Hvdroxlde Sodurn H&chlor& Sullonated Detergents Sulfur Dloxlde Drv Sulfur Dloxlde, Wet Sulfunc Acld Sulfwc Acid Sulfunc Ac,d Trtchloroacetlc Acld Zinc Chloride CONCENTRATION % All loo All 100 5 20 10 50 10 25 10 10 10 25 A,, 5 10 25 15 100 _ _ 25 50 70 50 A,, MAXIMUM OF 220 180 140 220 200 80 160 220 140 100 160 180 140 80 220 220 180 80 180 160 220 220 220 220 160 220 220 109 110 Corrosion Resistant Materials Handbook TABLE 1.30: POLYETHER BLOCK AMIDES-RILSAN PEBAX is ATOCHEM’s registered trade name for a family of polymers known as polyether block amides (PEBA). The structure of all PEBAX products comprises linear and regular chains of rigid polyamide segments and flexible polyether segments. In addition to their copolymeric structure, the various grades of PEBAX show other original characteristics: very wide range of flexibility; absence of any plasticizer; excellent impact resistance, even at low temperatures; little variation in flexibility between -40°C and +8O”C; low density; very high elastic memory; excellent mechanical properties; and good chemical resistance. Chemical Resistance in stress Change ,n elongation Chonge I” volume I Temperatures 0 0 7 days/23 “C I. ,. - 15 - II - - 20 - 20 - -;2 -32 ,. 7 days/100 oc T I I 3 days/IQ3 oc 7 days1121 “C 1.2 1.2 1.5 1 1,2 + - - 7 5 - 24 0 I 0 + + 4.7 1.8 - 14 - 3 days/ 100 “C 7 days1121 oc ASTM No 3 011 T 0 0 + + + + + 3533 SN 00 4033SNOO - 64 DiSSoiVeS I SKIP Detergent 30 g/l Potasswm 34O Boume I ot break in % m % 7 days/l21 Lockheed H 55 Skydrol ASTM No I 011 I ot break m % 5533 SN 00 Time SulphuracAcid. 100/O Sc&m Hydroxade. 10% Z,nc Chloride. 509’0 Water Bo,lmg Writer Polymers Change Test Chemicals of PEBAX 47 7 days/95 OC 7 days/79 OC 0 0 12.5 0 + 2.4 + 1.5 - 12.5 20 Lrxkheed H 55 Skydrol ASTM No 1 01 3 dqs/lcn 7 dqS/l21 ASTM No 3 011 SKIP Detergent 30 g/l Potosrlum 34’ Baume - oc oc - 55 -50 3 doys/lLm oc 7 days/l21 DC - 92 - 49 + 17.7 + 40 - + 135 + 51 7 days/95 =‘C 7 days/79 “C 5533 SN 00 Tests Time Chemicals 4033 SN 00 3533 SN 00 2533 SNOO 6312 MN00 5512 MN00 ~+27~+45~+60~+22~+33~ + 30 + 54 + 54 + 51 + 128 + 405 + 20 + 25 + 32 + 37 Temperatures I _ Ethanol Propnol Butanol lsooctane loo OCtonepetrol M 15 luel Kerosene Poraffm I 7 do&23 OC 7 days/23 OC 2 days/50 OC 7 days/23 OC 1 + 7 + 21 + 31 +fJ.5 + I8 + 32 + 9 + 44 + 64 + 21 + 110 _ + 28 + 110 _ 0 + 3.5 _ f + + + 27 + 15 + 48 + 26 +A8 + 26 +5 + j.5 +74 + 2:6 16 5 _ 0 14 (continued) Synthetic TABLE 1.30: POLYETHER BLOCK AMIDES-RILSAN Tests Chemicals 111 (continued) 5533 SN 00 Time Resins and Polymers 4033 SN 00 3533 SN 00 2533 SNOO 6312 MN00 5512 MN00 0 0. Temperature 0 0 ASTM Fuel B 7 days/23 2 days/50 OC OC +a + 21 tt3 + 41 ASTM Fuel C 2 days/50 “C t t Benzene ACHOW 27 + 33 + 4.2 Me?h leth TABLE 1.31: 0 POLYETHYLENE-EASTMAN CHEMICAL 41 t 60 t 42 + 4.5 I ketone 0 t 182 + 45 t 4,5 t t t 210 a n,5 t 12 +a +4,5 t 22 + 45 +a PRODUCTS Two-inch diameter by ‘/s-inch thick disks injection molded from a 0.918 density TENITE Polyethylene formulation were immersed in the chemicals listed in the tabulation and stored under a constant temperature of 73OF for one year. The disks were weighed and measured at the beginning of the test period and again at the end. The percent change in weight and thickness was calculated for each chemical at the end of the test. The change in appearance was also noted. Chemical resistance of polyethylene is density related-improving with increasing density. Therefore, the lowest density formulation of the TENITE Polyethylene family was tested to represent the greatest change that would be expected from contact with the various chemicals. The Effect of Various Chemicals on TENITE@ Polyethylene (Exposure: %Change Chemical ‘Acetone Acellc Acid Ammomum 5% Hydroxide “Butyl Acetate Calcium Chloride “Carbon ‘Carbon 2-“_0% Dlsulflde Tetrachlonde ‘Chloroform ‘C,trlc Acld “Ethanol 10% ‘Ethylene Dlchlorlde ‘Ethylene Glycol Glycoi “Formaldehyde “Gasolme “Gasolme Monoethyl 35% (Regular) (Awatlon) ‘Glycerme ‘Green ‘Heptane 0.2 No change Hydrochloric 08 00 No change No change Hydrogen Methanol 0.0 41 00 08 01 7.7 No change 4.3 Swolien Swollen 0.1 00 ‘Ethanol 95% “Ethyl Acetate “Ethylene 1.2 00 5040 Soap Solution 2.6 6.9 Ether Appearance 00 0.0 0.3 2.6 0.0 01 00 0.6 09 0.0 No change Swollen No change No change No change No change Swollen No change No change PeroxIde 59~ 00 0.0 30% Acid Acid (COW ) 24 05 No change 0.3 02 00 No change 00 No change 00 00 00 No change No change 0.0 No change 0.0 NO change 00 01 Sodwm Sodium tiydrowde Hypochlorlte 1% 00 13.5 3.2 15 1 0.0 3.0 0.0 Swollen No change Water 00 03 No change 10.0 2.5 Swollen “Wesson “Xyiene -01 No change Yellowed 2% lOoa -01 30% 0.0 00 3% 00 -01 Oil agent, but not tested for this characteristic. Solution 5% NO change No change No change 48 Carbonate Hydroxide Sulfuric Actd “Toluene ‘Turpentme 00 Appearance No change Sodium Sodium Acid 0.2 01 Chloride Sulfwc 10% In Thickness 0.6 14 00 05 Sooturn 0.1 ‘Listed as a stress-cracking agent. “Believed likely to be a stress-cracking -02 10% vmOlli,e 011 -‘Phenol 5% 0.0 0.0 No change Swollen, Pink Acid ‘Methanol 100% “Motor 011 Nltrtc ‘*Oleic and warped Welghc Chemical Thickness 25 1 10% K Change In Weigh! 36.6 37.9 One Year) 00 No change No change No change 15 1 14.5 2.9 3.3 Swollen Swollen 00 0.0 No change 0.2 15.4 00 No change 31 Swollen 112 Corrosion TABLE 1.32: Resistant Materials Handbook P~LYET~~YI_ENM~IMoNT 1900 UHMW Polymer is an ultrahigh molecular weight, high density polyethylene resin having a molecular weight range between 3 and 6 million. The extraordinary wear properties of parts manufactured from 1900 UHMW Polymer result in superior replacement parts or long-performance components on original equipment. Used either way, they offer outstanding resistance to impact, abrasion, and chemicals, plus high energy absorption and self-lubricating properties. Test pieces, Appearance 0.040 x 1 x 2 and weight inches, change immersed reported in reagent on removal from under reagent conditions and wiping given: dry. Synthetic TABLE 1.33: POLYETHYLENE-LINED SCIENTIFICS BEV-A-LINE, translucent, tate shell and a polyethylene ACETATE 713 TUBING-THERMOPLASTIC INC. flexible liner. The shell excels in durability A-LINEIV retains flexibility from -60” to 200°F. ETHYLENE-VINYL Resins and Polymers tubing for purity systems, combines two tubings Liner and shell are merged by a patented extrusion with superior at temperatures in one: an ethylene process. aging characteristics. Tubing burst strength surpasses that from -60” to 160°F and BEV-A-LINE V HT withstands vinyl ace- of PVC. BEVtemperatures The liner is ideal for use where purity must be maintained and good resistance to alcohols, acids, caustics and solvents is required. This tubing will resist stress-cracking. Its inert and neutral contact surface provides a stable environment in which the pH of the content is essentially maintained. The interior is exceptionally resistant to stains and it resists absorption of liquids, stays translucent and cleans easily. Chemical and Environmental Properties of BEV-A-LINE Chemical or Solvent Concentration Ace:aloa”+de A-E’ c Acid (Glacial) ACelOW Alumnurr Chloride Al~mi”um Hya’oxlde Al!,rr,rurr~ Sul’a!e lo?& COK 103% Dilute CO”C CO”C CO”C 521 d Sa’ d Sa’ ‘2 Sa’ d Sa’ d 100% 1 00% 1 00% Ammo”;un~ Carbowale Ammonwm Chlor,ae Ammon~u~,Ntlrafe Ammonium Persulla?a Ammowm Suliare Ammonlurr TWxyanate Amyl Ace:ate Amyl Chloride A”lll”e Antimony Chloride Arsenic Acid Bawm Carbonate Bawm Chior!de BarNurn Hydroxide Barturn Sulfa!e Benzene Benzo~c Acid Borax Botlc Acid Bow Acid Butanediol Bu:a”edlol Butanedzol Calcwm Calcium Calcium Calcium Carbonate Chlwde Hydroxide Hypochlorw Calcium Calwm NItrate Sulfate Copper Copper S S s S S s U S S S S Sa! d Sa’ d CO”C Dlill:E 100% 60% 10% 0 S S U s S S S S s S S S S S S S S S S S S S S 35% 100% 100% Sa! d Sal d Sal d Sal d 40% S S S S S S S S S S S S II U U U U S S S S S S S S S 0 S 0 0 U S S U S S 0 U 0 U S S 0 S S S S S S = sflghf &tack U = unsatisfactory S S S s s s s S S s S s s S S S S S I s s / s s S i S S s S s S 5 i ! s s S i g i ss ! s I s I s / : / s I 7O’F = 21°C ConccntratiooBEV-A-LINE Outer Shell’ L:uCtoSf Sa!lrc Acid 52 d Sa’ 0 s G’yCeWe Glycol~c AC<? Hepiane Hydrobronlc Acid ‘OO’C 30% 1004. S Laclic Acid La:ex Lead AceWe Magnesium Carbonate S S S 5 u S U U S or Solvent hidroger s : s : Chemical s s 1 IV and V HT Liner and Shell at Room Temperature (73“F) S S Sa’ d Sal d Sa’ d Sa’ d 100% 100% 100% 100% 0 S S I 100% (no attack) S S S s IS = satlafacfory s S S S S S Sat d Few Sulfate Ferrous Chloride Formaldehyde II S Sa, d 100% Sat d Sa’ d Ethyl Buryrate Ethyl Ether Fer”c Chloride Femc Nl!ra!e s S Sa! d Sal d Dilute 100% 100% 100% 100% Ethyl Ace!& Ethyl Alcohol Ethyl Alconol 0 0 s : s 50% Sa’ 0 DeXtKJse D6odlu-m Phosphate Dlethylene Glycol D~octyl Phthalale i, S Cl 5 S S s s S S S B-V Liner U S Sal d Sa! d 100% CoDpe’ Sulfaw Cottonseed 011 CresOl Cyclohexane Cyclohexanol Dexwl B-IV _iner U 0 S S Sa! d Bleach sot n Chloride N~!r.ale --__ u Sa! d Sat d Castor Oil Chromic Acid C~lric Ac!d EV-A-LINE IV Outer __-- Shell’ Pcroxde Magnewm Magnesium Magnesluv Chlortde Hydroxide Nitra:e Magnewm SLllfa!e Male~c Acid Me’curIc Chloi~oe Melhylene Chloride MIneral 011 Naphtha Nickel Chloride Nickel Nttrate Nickel Sulfate Po!assium Poiassium Pcxass~um Blcarbow!e Boraie Broma!e PoiassiuV Po!aswm Po!asswm Potassun Po:asswr Bromide Carbonate Chloride Dlchromale Ferrtcyaplde Polaswm Polasswm Po’asslum Polassu~ Puassium Hydroxide N!tra!e Perchloiale Permangdnale Sulfate Potaswm Propylene Sul!tte Glycol SI~ICIC Acid Sodium Blcarbonale Sodium Borate Sodium Carbora!e Sodwm Sodurn Sodwm Sulfuw Chloride Hydw.!de Sulfaw Acid Sul:ur!c Acid chemvzal contact Sa* d Sa: d Sat d Sa! d Sat d Sa’ d Sa: d 100% 100% 100% 0 0 S S 0 S S 0 S S 10% Sat d CO”C Sal d 40% S Sat d 20% S S Sat d Sal d 20% CO”C CO”C 100% S S U S S S S S Cone Sal d 50% I 100% S&d Thermoplastic i charactenstlcs Sclentiflcs. S U U u u U 100% u U S of Bev-A-Ltne Inc. 0 S S S s S S S S S S S 3 S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S CO”C 70% 5 S S S S S S S S S S S S S S S V HT c S c S 0 S S S S S S S S S S S S S S Sa! d Sal d COIX I / 0 S ” Sa! d 1% t S s 5 S S S S S 100% B-V LItlet __ S S S .I 0 s 30.50% C0”C Sal d 85?0 1% 7- S S S S S S S S 100% reststance 5 c S S 5 S S S u 100% Kylene 7.1-c Sulfate L 0 S S S S S S 98% 100% Tetrahydroturan roluene le!rachloroethyle”e rnchloroethylene ‘For s ” 50% CO”C 31 1% 309” 90% 100% Sal d S-IV Liner 5 5 S c s Sat 0 CO”C Sal d N,cotlnlc Acid NI!W Acid 01.x Acid Oxalic Acid Pnosphorlc Acid PICK Acid IV S S S S S S S 0 i: U S S S U U U S 0 0 S S outer shell 114 Corrosion Resistant Materials Handbook TABLE 1.34: POLYETHYLENE PETROTHENE density appear marked. There density may be RESINS-U.S.I. CHEMICALS resins are available across the entire range of polyethylene densities 0.91 to 0.96. The variations in very small, but the effect of even a very small change in density on certain essential properties is very are many applications for which resins of higher density and many others for which those of lower preferable. The three density ranges of polyethylene are: Low density Medium density High density (linear) Chemical Reagent Acetaldehyde Acetic Acid’ Acetic Acid’ Acetic Acid’ Acetic Anhydride Acetone Acrylic Emulsions’ Ally1 Alcohol Ally1 Chloride Aluminum Chloride Alummum Chloride Alummum Fluoride Aluminum Sulfate Alums tall typesl Ammonia, 100% Ammonium Carbonate Ammonium Chloride Ammonium Fluoride Ammonium Hydroxide Ammonium Metaphosphate Ammonium Nitrate Ammonium Persulfate Ammonium Sulfate Ammonium Sulfide Ammonium Thiocyanatc Amy1Acetate Amyl Alcohol’ Amy1Chloride Aniline* Aniline Hydrochloride Antimony Chloride Aqua Regia Arsenic Acid Barium Carbonate Sariurn Chloride barium Hydroxide Barium Sulfate Barium Sulfide Beer 6enzenc Benzene Sulfonic Acid’ Benzoic Acid Bismuth Carbonate Slack Liquor @leach lye Soras Soric Acid Boric Acid Bromic Acid Bromine Liquid Bromine Water Butanediol’ Butanediol* Sutanediol’ Butyl Alcohol Butyric Acid Calcium Bisulfide Resistance gjTz= Concen tration 100% 1.10% IO-SO% 80.IDO’X Dilute Cone. Cont. Cont. Cont. Dry Gas 1 1 i I I I , I I : Sat’d. 20% 0,880 s.g Sat’d. Sat’d. Sat’d. Sat’d. Sat’d. Sat’d. 100% 100% 100% 100% Sat’d. ( 4 ! a , ! I s I 1 S 1 100% Sat’d. Sat’d. : : Sat’d. Sat’d. All Cont. Sat’d. 10% Cold Sat’d. Dilute 10% 100% 10% 60% 100% 100% Cont. of Low and Medium : : S S S S : : S U U S S : U S Calcium Carbonate Calcium Chlorate Calcium Chloride Calcium Hydroxide Calcium Hypochlorite Calcium Nitrate Calcium Sulfate Camphor Oil Carbon Dioxide Carbon Dioxide Carbon Dioxide Carbon Oisulfide Carbon Monoxide Carbon Tetrachloride Carbonic Acid Castor Oil’ Chloracetic Acid Chlorine Dry Gas Chlorine Moist Gas Chlorine Liquid Chlorine Water Chlorobenzent Chloroform Chlorosulfonic Acid Chrome Alum Chromic Acid Chromic Acid Chromic Acid & Sulfuric Acid’ Cider’ Citric Acid’ Coconut Oil Alcohols’ Cola Concentrates’ Copper Chloride Copper Cyanide Copper Fluoride Copper Nitrate Copper Sulfate Copper Sulfate Cottonseed Oil’ Cresol Cresylic Acid Cuprous Chloride Cyclohexanol’ Cyclohexanone Detergents, Synthetic* Developers, Photographic Oertrin Dextrose Dibutylphthalate Disodium Phosphate Oiazo Salts Oiethylene Glycol’ Diglycolic Acid’ Dimethylamine Dioctyl Phthalate Emulsions, Photographic’ 0.910-0.925 0.926-0.940 0.941-0.965 Density Polyethylene Conccn. tram ‘1 Sat’d. Sat-d. Sat’d. 7 t , 100% dry 100% wet Cold Sat’d. _..I S S S S S S SU S S S U s U :S S Iu Cont. 100% 100% I% Sat’d. So 100% Sat’d. 20% up to SO% Sat’d. Sat’d. Sat’d. 2% SaYd. Dilute Sat’d. 100% 50% Sat’d. Sat’d. Sat’d. $ ! ! U I s uI S U S S U 0 0 U S U U U S S S s S s s : f E 5 i i I i i , I i to Various Reagents ry L Concen- ‘ Bleach Sot? SO% g/cc g/cc g/cc I I! Iu 3 IJ IJ IJ <i Si !i Cb d1 S1 5, 51 s S : S S S UI s” S U S s” S s” S S S : S II tration Ethyl Acetate Ethyl Alcohol’ Ethyl Alcohol* Ethyl Butyrate Ethyl Chloride Ethyl Ether Ethylene Chloride Ethylene Chlorohydrin Ethylene Dichloride Ethylene Glycol’ Ferric Chloride Ferric Nitrate Ferrous Chloride Ferrous Sulfate fish Solubles’ fluoboric Acid Fluorine fluosilicic Acid fluosilicic Acid Formaldehyde’ Formic Acid’ Formic Acid’ Formic Acid’ Fructose Fruit Pulp Fuel Oil Furfural Furfuryl Alcohol Gallic Acid’ Gasoline Gin Glucose Glycerine’ Glycol” Glycolic Acid’ Grape Sugar Heptane Hexanol. Tert: Hydrobromic Acid Hydrocyanic Acid Hydrochloric Acid Hydrochloric Acid Hydrochloric Acid Hydrochloric Acid Hydroftuoric Acid Hydrofluoric Acid Hydrofluoric Acid Hydrogen Hydrogen Bromide Hydrogen Chloride Gas Hydrogen Peroxide Hydrogen Peroxide Hydrogen Phosphide Hydrogen Sulfide Hydroquinone Hypochlorous &id Inhs’ Iodine tin KI Sol’n.) 100% 100% 35% p’ ’ .tC’ f I 7 I 5 ,j (1 1I II 1I 1I 1I !, s1 s, Sat’d. Sat’d. Sat’d. 32% Cont. 40% O-20% 20.50% 100% Sat-d. 100% Sat’d. 30% Sard. Aq. 50% Sat’d. 10% 30% 35% Cont. 40% 60% 75% 100% 10% 3Z 93% lW% : S S S S S S S S S S S 0 U U S U U S S S S S U S S : s” S s” S : S ! S S Corn. : Cont. s IS s U U U u U U S S s S S S S U s ,0 s s s 5 S j IJ tJ IJ ci J I1 ‘> <, <b 5 s 1I S s s s S S S S S D S S S 0 U S S S S S U (continued) Synthetic TABLE 1.34: POLYETHYLENE RESINS-U.S.I. CHEMICALS ‘- 400 Reagent F II Lactic Acid’ Lactic Acid’ Latex* Lead Acetate Lead T&a-Ethyl Linseed Oil Lube Oil Magnesium Carbonate Magnesium Chloride Magnesium Hydroxide Magnesium Nitrate Magnesium Sulfate Maleic Acid Mercuric Chloride Mercuric Cyanide Mercurous Nitrate Mercury Methyl Alcohol’ Methyl Bromide Methyl Chloride Methyl Ethyl Ketone Methylene Chloride Methylsulfuric Acid’ Milk Mineral Oils Molasses Naphtha Naphthalene Nickel Chloride Nickel Nitrate Nickel Sulfate Nicotine* Nicotinie Acid’ Nitric Acid Nitric Acid Nitric Acid Nitric Acid Nrtrobenzena Ocfyl Cresol Oils and Fats Oleic Acid Oleum Orange htract Oxalic Acid’ Oxalic Acid’ Oxygen Ozone Perchioric Acid Petroleum Ether Phenol Phosphoric kid Phosphoric Acid Phosphoric Acid Phosphorus (Yellow1 Phosphorus Pentoxide Phosphorus Trichlorida Photographic Solutions 7OCf = wc, 14w = 60OC S&d. 100% Sat’d. Sat’d. Sat’d. Sat’d. Sat’d. Sat’d. Sat’d. Sat’d. S&d. 100% 100% lDG% Comm. wd. Cont. Satd. Dilute 0.30% 30.50% 70% 9198% 100% Cont. Cont. Dilute Sat’d. 100% 100% 10% 90% up to 30% 309D% 90% lW% 100% 100% Reagent I Pickling Baths Hydrochloric kid’ Sulfuric Acid’ Sulfuric-Nitric* Picric kid’ Plating Solutions Brass” Cadmium’ Chromium* Copper’ Gold* Indium’ Lead’ Nickel’ Rhodium* Silver’ Tin* Zinc’ Potassium Bicarbonate Potassium Borate Potassium Bromata Potassium Bromide. Potassium Carbonate Potassium Chlorate Potassium Chloride Potassium Chromate Potassium Cyanide Potassium Oichmmate Potassium Farril ferro Cyanide Potassium Fluoride Potassium Hydroxide Potassium Hydroxide Potassium Nitrate Potassium Parborate Potassium Parchlorate Potassium Permangamte Potassium Persulfate Potassium Sulfate Potassium Sulfide Potassium Sulfite Ropargyl Alcohol’ Propyl Alcohol’ Propylene Dichloride Propylene Glycol’ Rayon Coagulating Bath’ Sea Water Selenic Acid Shortening* Silicic Acid Silver Nitrate Sol’n. Soap Solution’ Sodium ketate Sodium Benzoate Sodium Bicarbonate Kay: S-satisfactory Resins and Polymers 115 (continued) Concen- Conccn- tration tration 1% s” U S S : S S S S s S s s S S S S s S S SaFd. 1% 10% S&d. Sagd. S&d. 40% SaYd. 40% Sat’d. E 5 20% corm. Sat’d. SaFd. 10% ; E E i 5 20% S&d. Cont. Cont. Cone. I i i i i i i 1 i 100% i i i , i i ; 1 , 1 Any Conc’n. Saw. 35% s&d. O-some attack Sodium Elsulfate Sodium Bisulfita Sodium Borate Sodium Bromide Sodium Carbonate Sodium Chlorate Sodium Chloride Sodium Cyanide Sodium Dichromata Sodium Farricyanida Sodium Farrocyanide Sodium Fluoride Sodium Hydroxide Sodium Hypochlorite Sodium Nitrate Sodium Sulfate Sodium Sulfide Sodium Sulfide Sodium Sulfite Stannic Chloride Stannous Chloride Starch Solution’ Stearic Acid’ Sulfur Sulfur Dioxide Sulfur Dioxide Sulfur Trioxidc Sulfuric Acid Sulfuric Acid Sulfuric Acid Sulfuric Acid Sulfuric Acid Sulfuric Acid, Fuming Sulfurous Acid Tallow lannic Acid’ Tanning Extracts’ Tartaric Acid Tartaric kid Tetrahydrofurane Titanium Tatrachloridc Toluena Transformer Oil Trichloroathylene Triethanolamine Trisodium Phosphate Turpentine Urea’ Urine Vinegar Vanilla Extract’ Wetting Agents* Whiskey* Wines Xylene Yeast Zinc Chloride Zinc Sulfate Safd S&d. Dil. S&n. Cont. Sat’d. S&d. 1t F 3 3 s s S i S Sat’d. Sat’d. Sat’d. Sat’d. Cent. i S : : 25% Sat’d. Sol’n. Sat’d Sat’d. Tat’d. Sof’n. Sat’d. 100% Colloidal Dry, 100% wet. 100% 0.50% 70% 80% 96% 18% LConcJ : S S S S S S S S S S S S S 0 3 : S 10% Comm. 10% Sat’d. Sat’d. 100% Sat’d. rp to 30% Comm. Sat’d. Sat’d. S S S J J J ; J i E S S S 5 i ; S I i i i S S 0 u u U U S 0 S S S U U U U U U u S U S S S S S U-unsatisfactory *The values are obtained from tests made under static conditions and using nonstressed specimens. Reagents marked with an asterisk (“1 may, under certain conditions, cause environmental stress cracking if the polyethylene products are improperly designed or not made of the best suitable resins. 116 Corrosion Resistant Materials Handbook TABLE 1.35: POLYETHYLENE TANK MATERIAL-NALGE The XL-200 D.O.T.-exempted mini-bulk tank is a reusable, lightweight 200 gal tank system for hazardous liquids. Rotationally molded of cross-linked high-density polyethylene (XLPE), the XL-200 has superior resistance to impact and stress-cracking and is compatible with a wide range of chemicals (see chemical resistance summary). It’s strong over a wide temperature range, from -20” to +16O”F (-29” to +71”C). Chemical Rcslstance Summary’ Class of Substances at 20°C Acids, dilute or weak Excellent Acids*‘, -Excellent strong and concentrated Alcohols, Aliohatic Excellent Aldehydes Good Bases Excellent Esters Good Hydrocarbons, Aliphatic Hydrocarbons, Aromatic- - Good _ Good Hydrocarbons, Halogen&d Fair Ketones Good Oxidizing Agents, strong Fair l This Chemical Resistance Summary IS mrended as a genera/ guide only. “Except for ox:dizmg acids; for oxidizing sods, see “Ox/d,z,ng Agents, strong. ” TABLE 1.36: POLYETHYLENE TEREPHTHALATE-BASED COPOLYESTER-EASTMAN CHEMICAL PRODUCTS KODAR PETG Copolyester 6763 is a clear, amorphous polymer based on poly(ethylene terephthalate) and has a number average molecular weight (Mn) of about 26,000. To obtain the data shown below, sections of unstressed injection-molded tensile bars l/s inch (3.2 mm) thick were weighed and measured and immersed in the chemical or reagent shown and stored at 73°F (23°C) for a period of one year. At the end of the test period, each sample of plastic was removed from the jar in which it was tested, wiped dry, and quickly weighed and measured again and the to the test medium changes in weight and thickness were calculated. The appearance of the samr !e after exposure was also recorded. Ordinarily, a plastic would not be suggested for continuous immersion in a reagent that causes an increase of 5% or more in weight or thickness. This does not imply that a change in weight or thickness of less than 5% necessarily indicates suitability for immersion. The results of these tests showed that KODAR PETG Copolyester 6763 is resistant to a variety of chemicals, highmolecular-weight esters, aliphatic hydrocarbons, and dilute solutions of acids and salts. PETG 6763 was significantly affected by concentrated acetic acid, acetone, benzene, toluene, carbon tetrachloride, dimethyl formamide, and phenol and was completely deteriorated by concentrated nitric and sulfuric acids and by ethylene dichloride. (continued) Synthetic TABLE 1.36: POLYETHYLENE PRODUCTS TEREPHTHALATE-BASED %Change’ Weight Acettc Acid. 5% Acetone Hvdroxlde. cont. A;r.:r:on~um HvdroxIde. 10% I ! ,n Thickness ! / 1 0.5 ’ ) A cct~c Acad. cone Ammonum COPOLYESTER-EASTMAN 117 CHEMICAL (continued) Reagent 1 Resins and Polymers 192 15.6 Appearance of Plasrlc After Exposure 0.2 Verv sllqht vellowmq 18.5 234 I ~ Dwolored and swollen Dwolored (brown). swollen, rubber-like I Turned white - outslde crumbling off ~--.___ DIscolored (pInkI - surface has blisters Cttrlc Acid, 10% Cottcnseed 011 Detergent, Alconox (0 25%) Demnlzed Water Dlbutvl Sebacate Dlmethvl Formamlde I I Ethanol, 100% _ Ethanol, 50% 21.9 06 Ethyl Acetate -___ Ethylene Dlchlortde : Gasolme. High Test / Gasoline, Regular / 202 Hvdrochlortc Acid, cont. Hvdrochlorlc Acid. 10% 1.3 0.9 I 0.3 / 04 I I I Nltrlc Actd. 40% ! 1 Oleic Acid, 83% I I I Olwe011 05 02 i 0.1 0.8 0.5 ! : I 0.1 / 0.2 02 I j I 0.2 _ 0.5 10% 1 Sodium Carbonate, 2% I 0.5 1 Sodium Hvdroxlde. I 8.0 i Sodwm Hydroxide, 0.4 10% 1% 3.5% Turpentine unkn rhe/igure h precede Very slight vellowng _~___ Very sltght vellowng Very slight vellowlng. crazing [ / ’/ 1 I ’ ’/ j Completelv detertorated Slight vellowng Verv shqht vellowinq I Verv sltaht vellow~nq I Turned black Slight vellowmg Slight vellowmg 0.2 Sllqht vellow~ng 0.4 i Sllaht vellowina I 6.4 Sliaht vellowinq I / Completely / Slight yellowing 0.2 I ’ 0.4 0.2 25.9 31.0 0.3 0.2 Sisn. after one week __- Turned%hlte 0.2 b.v (I nfFtti I I jvsllghtvellowlng Shght vellowng I ‘Toluene j j 0.5 I Oil _~._____ Sllqht yellowlnq 0.2 I increases 0.2 - blisters under surface Sltqht vellowmg / - Slight -veliowlng 0.6 - I Sulfuric Acid, 3% Badly dlrcolored 0.8 0.3 were 14.3 !n one week / / I 0.8 Sulfuric Acid, 30% lC!wtgesshown 0.3 deteriorated -__ -_____Sltght vellowmq .__L__ S!lght vellowlng 1 j Sulfurtic Acid, cont. Transformer _ 01 i I Sodium Hvpochlorite, 0.7 0.3 Sodturn Carbonate. 20% :’ 0.2 0.2 13.2 -__ 1% 04 0.3 ; ~ 14 Nltrlc Acid. 10% Cloudy I / i Methyl Alcohol Nltrlc Acid, cone Completely ! 0.2 ___- Badly dtscolored and swollen - rubber llke ; I 0.3 _~--~ Slight vellowng 0.9 0.8 0.3 Badly discolored and dtstorted ____Very slight vellowlng _ 02 0.6 Mineral 011 , 0.8 Kerosene Sodwm Chloride, I 05 / __-___ 24.5 01 lSOOctane Phenol, 5% 0.7 11 1 Hydrogen PeroxIde, 28% 1 Hvdrogen PeroxIde. 3% / ~ ’ 38.6 _ Hexane Soap Solution, ! 05 Slight vellowmg deteriorated in one week Slight vellowing Very sltght vellowng Turned white - rubber-llke Slight vellowng I 118 TABLE Corrosion Resistant Materials Handbook 1.37: POLYMETHYLPENTENE-WESTLAKE PLASTICS The high resistance of TPX (polymethylpentene) to chemical attack, combined with its excellent transparency and high temperature performance, makes it particularly suitable for a wide range of applications. TPX polymers are highly resistant to inorganic environments, are not attacked by aqueous solutions of inorganic salts nor by most mineral acids or alkalis even in a concentrated form. They are, however, affected by oxidizing reagents. TPX polymers show good resistance to many organic chemicals although, as with other polyolefins, absorption does occur in certain cases leading to a loss of rigidity and a decrease in yield stress. Tests on injection molded samples at 20°C (68OF) and 60°C (140°F) over a period of 3 months are listed and give an indication of the behavior in practice. Acetic acid (glacial) Acetic acid (dilute) Acetone Aluminum chloride Aluminum fluoride Aluminum sulfate Ammonia Ammonium carbonate Ammonium chloride Ammonium fluoride (20%) Ammonium hydroxide (10%) Ammonium nitrate Ammonium sulfate Ammonium sulfide Ammonium thiocyanate Amy1 acetate Amy1 alcohol Amy1 chloride Anisole Barium carbonate Barium chloride Barium hydroxide Barium sulfate Barium sulfide Beer Benzaldehyde Benzene Benzoic acid Benzyl alcohol Brake fluid Bromine liquid Bromine water Butylacetate Calcium carbonate Calcium chlorate Calcium chloride Calcium hydroxide Calcium hypochlorite Calcium nitrate Calcium phosphate Calcium sulfate Calcium sulfite Carbon dioxide Carbon tetrachloride Carbonic acid Chlorine water Chlorobenzene Chloroform Chromic acid 2o”c 60°C B A B A A A A A A A A A A A A B B C B A A A A A A A C A A A D D C A x A A A A A A A A c A D C C A B A B A A A A A A A A A A A : C C C A A A A A A B C A A ; D C A A A A A A A A A A C A D C D A Citric acid Copper chloride Copper cyanide Copper fluoride Copper nitrate Copper sulfate Corn oil Cuprous chloride Cyclohexanol Cyclohexanone Decalin Diesel Oil Dimethyl formamide Dioctyl phthalate Ether Ethyl acetate Ethyl alcohol Ethyl oleate Ethylene glycol Ferric chloride Ferric nitrate Ferric sulfate Ferrous chloride Ferrous sulfate Fluosilic acid Formaldehyde Formic acid (100%) Fruit juices Gear box oil Gin Glycol Hexane Hydrochloric acid (50%) Hydrochloric acid (30%) Hydrochloric acid (20%) Hydrochloric acid (10%) Hydrofluoric acid (60%) Hydrogen peroxide (70%) Hydrogen peroxide (35%) Hydrogen peroxide ( 10%) Isopropyl alcohol (100%) Iodine in ethanol solution Lead acetate ( 100%) Lemon oil (concentrated) Linseed oil Lubricating oil Magnesium carbonate 2o”c 6O’C A A A A A A A A A B C B A A C B A B A A A A A A A A A A A A A C A A A A A A A A A A A C A B A A A A A A A A 4 B ” 6 D A A C C B C A A A A A A A A A A B A A C B A A A A B B A B A A C A C A (continued) Synthetic Resins and Polymers TABLE 1.37: POLYMETHYLPENTENE-WESTLAKE Magnesium chloride Magnesium hydroxide Magnesium nitrate Magnesium sulfate Magnesium sulfite Mercuric chloride Mercuric cyanide Mercurous nitrate Mercury Methyl alcohol Methyl ethyl ketone Methylene chloride Milk Mineral oil Motor oil Nickel nitrate Nickel sulfate Nitric acid (fuming) Nitric acid (70%) Nitric acid (50%) Nitric acid (10%) Nitrobenzene Oleum Olive oil Oxalic acid (50%) Paraffin ozone Paraffin wax Paraldehyde Petrol Petroleum ether Phenol Phosphoric acid (50%) Photographic developer Potassium bicarbonate Potassium bromide Potassium carbonate Potassium chlorate Potassium chloride Potassium chromate Potassium cyanide Potassium dichromate Potassium ferricyanide Potassium ferricyanide Potassium fluoride Potassium hydroxide Potassium nitrate Potassium perborate Potassium perchlorate Potassium permanganate Potassium sulfate Potassium sulfide Potassium sulfite Pyridine Resorcinol (saturated) PLASTICS 2o”c 60°C A A A A A A A A A A A A A A A A A A B A A A A A A D A A A A D A A A A B B C A A A A A A A A A A A A A A A A A A A li A A B A B” B A B B A A D B A A B D A B A A C C C A A A A A A A A A A A A A A A A A A A A A A B A 119 (continued) Rum Silicone oil Soap solution (concentrated) Sodium acetate Sodium bicarbonate Sodium bisulfite Sodium borate Sodium carbonate Sodium chlorate Sodium chloride Sodium chlorite (20%) Sodium cyanide Sodium dichromate Sodium ferricyanide Sodium ferrocyanide Sodium fluoride Sodium hydroxide (50%) Sodium hypochlorite Sodium nitrate Sodium nitrite Sodium silicate Sodium sulfate Sodium sulfide (25%) Sodium sulfite Stannic chloride Stannic sulfate Stannous chloride Sulphamic acid Sulfuric acid (98%) Sulfuric acid (60%) sulfuric acid (30%) Sulfuric acid ( 10%) Tannic acid Tartaric acid Tetrahydrofuran Toluene Transformer oil Trichloroacetic acid (10%) Trichloroethylene Turpentine Vaseline Vinegar Vodka Water Whisky White paraffin White spirit Wines Xylene Zinc chloride Zinc oxide Zinc sulfate A = B= C= D = Negligible effect Limited absorption or attack Extensive absorption Extensive attack 20°c 60°C A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A C C A A C C A A A A A A C A C A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A B A A A A A C C C A C C A A A A A B C A C A A A 120 Corrosion Resistant Materials Handbook TABLE 1.38: POLYPHENYLENE SULFIDES-PHILLIPS CHEMICAL RYTON polyphenylene sulfide resins and compounds are engineering thermoplastics developed by Phillips Petroleum Company. Available in both molding and coating grades, these materials feature excellent dimensional stability, inherent flame retardancy, thermal stability, chemical resistance, desirable electrical properties and ease of processing. RYTON resin compounds are resistant to a very broad range of chemical materials and at elevated temperatures are considered second only to PTFE in overall resistance to corrosive and hostile chemical environments. Environments to which RYTON compounds do not have adequate resistance include oxidizing environments such as 50% nitric acid, 30% sulfuric acid, sodium hypochlorite, bromine water, etc., all at 200°F (93°C) or above. ENVIRONMENTS COMPATIBLE WITH RYTON COMPOUNDS 200°F (93°C) Room Temperature Hydrocarbons Hydrocarbons Esters Esters Ketones Ketones Alcohols Alcohols Chlorinated Hydrocarbons Chlorinated Hydrocarbons Bases Bases Amines Dilute Acids Acids TABLE 1.39: POLYPROPYLENE-EASTMAN Resistance of TENITE CHEMICAL Polypropylene b Chemical PRODUCTS Wwght 4231 to Various Chemicals* Change in Appearance Thickness Acetone 2.2 1 .o No change Acetic Acid 5% 0.1 0.1 Slightly bleached Slightly bleached Slightly bleached Slightly yellov. Ammonium Hydroxide Bury1 Acetate Calcium Chloride 10% 0.0 6.3 2’12% 0.1 -0.1 1.8 -0.4 (continued) Synthetic Resins and Polymers TABLE 1.39: POLYPROPYLENE-EASTMAN CHEMICAL PRODUCTS 121 (continued) *Injection-molded disks 2 inches in diameter and %-inch thick were immersed in the chemicals and stored under a constant temperature of 73°F for one year. Polypropylene is highly resistant to chemical attack and to stress-cracking. However, a few chemicals produce swelling and attack the surtace slightly. These chemicals are mainly chlorinated compounds, aromatic hydrocarbons, and the higher aliphatic hydrocarbons, such as gasoline. 122 Corrosion Resistant Materials Handbook TABLE 1.40: POLYPROPYLENE RESINS-SHELL CHEMICAL EXPOSURE Acetaldehyde Temp., OF Time, days 68 122 180 365 S 140 30 S 70 100 140 100 S M 73 72 30 176 68 30 S S M 180 S 1.06 180 100 30 S M 6.4 S M M 4.2 73 73 Acetic Acid (50%) Acetic Acid (Glacial) Acetone (100%) (DMK) M 122 140 68 68 122 100 180 140 100 M Acetophenone 73 S Acetylene Acriflavine 73 68 S S 176 S 68 S 140 S M (2% aq. sol’n) Acrylic emulsions Ally1 chloride Almond Oil Aluminum Aluminum Aluminum chloride fluoride Sulfate Alums Ammonia (15% sol.) Ammonia (25%) Ammonia (30%) Ammonia, concen. Ammonia (gas-liquid) Ammonium Acetate Ammonium Bicarbonate Ammonium Carbonate 39.6 M M Acetic Acid (5%) Acetic Acid (20%) PERMEABILITY (gm./24 hr./ 100 rq. inlmil) 180 Acetate solvents, pure Acetic Acid (10%) CHEMICAL EXPOSURE PERFORMANCE S = Satis. M= Marginal U= Unsatis. 68 140 73 68 U 117 S 0.0 S 140 S 212 S 68 S 140 S 73 S S S 73 72 30 73 180 S 9.5 140 180 365 S 17.4 100 S S 73 73 73 73 68 140 73 S S S S S (continued) Synthetic Resins and Polymers TABLE 1.40: POLYPROPYLENE RESINS-SHELL CHEMICAL Ammonium Chloride fluoride CHEMICAL EXPOSURE PERFORMANCE S = M= Temp., OF Ammonium (continued) EXPOSURE REAGENT ,Soldr onsaturated ~ol~tton unlessandncated orherwsel Time, days 73 (10% aqueous sol.) metaphosphate Ammonium Ammonium Ammonium Ammonium Ammonium s S 73 365 S 68 S 140 212 S S Nitrate persulphate 73 68 S S Phosphate Sulfate Thiocyanate 140 212 73 73 68 S S S S S 140 212 73 S S S 68 S Amy1 Acetate Amy1 Alcohol Amyl Chloride Aniline Anisole 140 S 212 S M 68 140 M 68 180 S 0.165 122 180 M 2.77 140 30 S 68 140 S M 212 Anti-freeze Chloride, sat’d U 68 180 S 0.0 122 180 S 0.45 68 S 140 S 212 Apple Juice Aqua regia Aromatic Asphalt Marginal U= Unsatir. Hydroxide Ammonium Antimony Saris. PERMEABILITY (gm.124 hr.1 100 sq. inlmil) S s 68 140 212 Ammonium 123 Hydrocarbons Barium Carbonate 73 68 140 212 M 43 S 73 73 S M U U U 68 140 S S 1.78 (continued) 124 Corrosion Resistant Materials Handbook TABLE 1.40: POLYPROPYLENE RESINS-SHELL CHEMICAL (continued) EXPOSURE REAGENT (Sohdr m saturated solution unlessmdicated otherwKl Temp., “F Barium Carbonate Barium Chloride Barium Hydroxide Time, days CHEMICAL EXPOSURE PERFORMANCE S = Satis. M= Marginal U= Unsatis. 212 S 68 140 s s 212 S s 68 140 S 212 S Barium Salts Barium Sulfate 73 68 140 212 Barium Sulfide 68 140 212 72 30 73 73 68 180 S S S S S S S S S M U Beer Beet Juice Benzaldehyde Benzene/Benz01 Benzene Sulfonic Acid PERMEABILITY (gm.124 hr.1 100 sq. inlmil) 100% loss M 68 140 M Benzoic Acid 73 S Benzoyl Chloride Benzyl Alcohol 73 68 180 S S 0.22 122 180 S 1.0 Bismuth Carbonate 68 140 S 212 73 S S Boric Acid, 73 73 S S Brandy Brine Solution 73 73 Bluing Borax Bromine Gas (weak) S 365 68 140 S M M Bromine water, sat’d Butane 73 73 U M M M M Butanol Butter Butyl Acetate 73 73 73 365 S S S 72 176 80 30 S S Bromine Liquid Butyl Phthalate 68 140 Synthetic Resins and Polymers TABLE 1.40: POLYPROPYLENE RESINS-SHELL CHEMICAL (continued) EXPOSURE 1 Temp., OF Time, days CHEMICAL EXPOSURE PERFORMANCE S = Satis. M= Marginal PERMEABILITY (gm.124 hr./ 100 sq. in/mill U = Unsatir. Calcium Bisulfite 73 S Calcium Carbonate 68 S 140 212 68 S S Calcium Chlorate 125 140 S S 212 S Calcium Chloride (2.5% aqueous solution) Calcium Chloride (50% Solution) Calcium Hydroxide 73 365 S 72 30 S 176 68 30 S S 140 212 S S 73 68 S 140 S 212 68 S Calcium Salts 73 S Calcium Sulfate 68 S 140 S Calcium Hypochlorite Calcium Nitrate (50% sol’n.) Calcium Phosphate Calcium Sulfite S S 212 S 68 S 140 S 212 73 73 86 Carbon Bisulfide 73 365 Carbon Dioxide, dry 73 S Carbon Dioxide, wet Carbon Dioxide Solution 73 68 140 S S S Carbon Disulfide 73 68 140 73 365 140 106 Camphor Oil Cane Sugar Liquors Carbon Monoxide Carbon Tetrachloride Carbonic Acid Carrot Oil Castor Oil 365 3.64 U S S S U U S 68 140 S S 73 73 S U S 143 S 0.0 (continued) 126 Corrosion TABLE 1.40: Resistant Materials POLYPROPYLENE Handbook RESINS-SHELL REAGENT CHEMICAL (continued) PERMEABILIT) EXPOSURE (Sol,dr ,n salurated $oI”lm” unless indtcated othenwe) Castor Oil Caustic Soda, cont. Caustic Soda, dil. Cellosolve@ Cetyl Alcohol Char-co-sol Chlorobenzene Chlorine Gas Chlorine Liquid Chlorine Water Chlorine (wet) Chlorine (dry) Chlorinated Hydrocarbons Chloroform Chlorosulfonic Acid Chlorox Chrome Alum Chocolate Syrup Chromic Acid (10%) Chromic Acid (30%) Chromic Acid (40%) Chromic Acid, 2 N Cider Citric Acid (10%) sitric Acid, 2 N Zitrondropar (Lemon) Zlove Oil 73 73 365 U 73 365 S U 68 S 140 212 73 S S S S S S 73 73 73 365 140 73 30 30 S S 68 S 140 68 180 S S 0.48 122 180 S 2.3 140 30 S 73 68 365 109 S S 6.43 122 109 S 22.77 0.0 73 302 M 140 159 M 5.35 Zoconut Oil 73 162 S 0.0 96 S 0.0 Zod Liver Oil 73 Coffee 73 S Zoke Oven Gas 73 S (continued) Synthetic TABLE 1.40: POLYPROPYLENE RESINS-SHELL CHEMICAL ISohds I” saturated solutmn unless,nd,cated otherwsel Temp., “F Time, days CHEMICAL EXPOSURE PERFORMANCE S = Satis. M= Marginal U = Unratis. Copper Salts 73 S Copper Sulfate Core Oils 73 73 S S Corn Oil Cottonseed Oil Creosote Cresal Cresol Cupric Chloride Cupric Cyanide Curpic Fluoride Cupric Nitrate Cupric Sulfate Cuprous Chloride Cyclohexane Cyclohexanol Cyclohexanone DDT Spray Decalin Detergent Solution (Heavy Duty) Developers (Photographic) Dextrine Dextrose Diacetone Alcohol Diazo Salts Dibutyl Phthalate 73 140 PERMEABILITY (gm.124 hr.1 100 sq. in/mil) 158 167 S S 0.0 0.0 73 191 S 0.0 140 73 73 113 S S U 0.0 68 S S 68 140 S 68 s 140 S S 68 140 S 68 S 140 S 68 S 140 S 68 S 140 68 122 180 180 S M M 194.0 100% loss 68 122 68 122 180 180 189 180 S S M M 0.13 1.63 0.22 13.4 68 73 S U 73 30 S 140 30 S 68 S 140 S 68 S 140 S 68 S 140 68 180 S S 0.21 122 189 S 3.94 68 140 73 127 (continued) EXPOSURE REAGENT Resins and Polymers s S M (continued) 128 Corrosion Resistant Materials Handbook TABLE 1.40: POLYPROPYLENE RESINS-SHELL CHEMICAL (ccIntinued) EXPOSURE REAGENT (Solids an rarursted solution unlessmdicated ocherwise~ Temp., o F Time, days 1 CHEMICAL EXPOSURE PERFORMANCE S = Satis. M= Marginal U= Unsatis. Dichloroethylene 73 S Diethanolamine 68 S Diethyl Carbonate Diethylene Glycol Di-iso-octyl Phthalate Dimethyl Ether Dimethyl Formamide Dimethylamine Dioctyl Phthalate (DOW 140 S 68 140 S M 68 140 S 68 140 S S 68 140 M PERMEABILITY (gm./24 hr./ 100 sq. in/mill S M 73 30 S 140 68 30 180 S S 1.1 122 180 M 10.6 70 100 M 140 73 M M 68 140 73 140 78 160 S S S 68 140 68 122 180 180 S S S 0.0 0.40 73 68 122 180 180 S S S 1.42 17.9 Solution) 73 365 S Ethanol (95%) Ethanolamine 73 68 365 S S Dioxane Disodium Phosphate Distilled Water Dobanic Acid Donax “8” Dye (Rit) Epichlorohydrin Ethanol S 0.55 5.03 S (50% Aqueous 140 73 Ethers Ethyl Acetate S S 73 365 M 7.0 122 180 M 100% loss 140 100 M M M Ethyl Acrylate 68 140 Ethyl Alcohol 73 140 365 100 S S 68 30 S Ethyl Alcohol (50%) (continued) Synthetic TABLE 1.40: POLYPROPYLENE RESINS-SHELL CHEMICAL Time, days CHEMICAL EXPOSURE PERFORMANCE S = Satis. M= Marginal U-i Unsatis. Ethyl Alcohol (50%) 140 30 s Ethyl Alcohol (95%) 73 100 S 140 68 30 Ethyl Chloride S M Ethylene 140 68 Chloride M 140 M 68 70 180 30 M M Ethylene Glycol Ethylene Oxide EthYl Oleate 73 50 68 365 S M S M 140 Ferric Chloride Ferric Nitrate Ferrous Chloride Ferrous Sulfate Fish “Flit” Insecticide Fluosilicic Acid PERMEABILITY bnJ24 hr./ 100 tq. in/mill M Ethyl Ether Ethylene Di-chloride Fatty Acids, Ce 212 68 140 73 68 M S S S S S 140 73 S 73 S 73 68 S S 68 S 140 S 73 72 73 90 S S 72 30 S S Formic Acid (Anhydrous) 73 365 S Freon@ 73 M Fructose 68 S 140 S 68 S 140 S 68 140 73 68 140 73 S S U M M S 0.31 S S 0.31 24.7 Fly Spray (Ortho) Formaldehyde, (35% Solution) Formaline, (40% Solution) Formic Acid (85%) Fruit Juice Fruit Pulp Fuming Nitric Acid Furfural Furfurol Gas Oil 68 122 129 (continued) EXPOSURE Temp., OF Resins and Polymers 180 180 (continued) 130 TABLE Corrosion Resistant Materials Handbook 1.40: POLYPROPYLENE RESINS-SHELL CHEMICAL (continued) EXPOSURE REAGENT LSolldr I” saturated solution unlesstndacatedofherwsel Temp., OF Gasoline Gasoline (Aviation) Gasoline (Sour) Gearbox Oil Time, days CHEMICAL EXPOSURE PERFORMANCE S = S8tis. M= Marginal U= Unutis. 73 100 M 73 365 M 100% loss 140 73 73 100 365 M M 100% loss 140 S M 73 73 73 S S s Glycolic Acid (30%) 68 140 68 Glycerol 140 68 S S S S S Grape Sugar 122 68 Glycerine 180 180 140 S S S 68 Green Soap Solution 73 365 Heavy Duty Detergent 73 30 S (OMO) 73 100 S 73 73 180 365 M M (5%) Heptane Hexane Household Detergent Household Ammonia Household Soap Hydrobromic Hydrochloric Solution Acid -0.14 -0.86 S Grease Solution 100% loss M 68 Gelatin Glucose Glue PERMEABILIT? I (gm.124 hr./ 100 sq. in/mill S 70 100 S 140 100 S 73 73 100% loss S S 68 S 140 S Acid (Cont.) (38%) -lydrochloric Acid (10% aqueous solution) 73 100 S 73 365 S 100 365 S S iydrochloric Acid (30%) 140 73 hydrochloric Acid (35%) 68 180 S 73 140 100 100 S M 72 176 73 73 90 10 S S S 365 S iydrochloric Acid (36%) iydrochloric Acid (50%) iydrochloric Acid, 2N .35 (continued) Synthetic Resins and Polymers TABLE 1.40: POLYPROPYLENE RESINS-SHELL CHEMICAL (continued) EXPOSURE REAGENT IWads m saturated solution unlerrmdxated otherw84 Temp., o F Hydrocyanic Acid Hydrolfluoric Acid, Dil. Time, deys ’ CHEMICAL EXPOSURE PERFORMANCE S = Setir. M= Marginel U= Unsetis. 73 S 73 s Hydrofluoric Acid (38%) 73 30 S Hydrofluoric Hydrofluoric Acid (40%) Acid (50%) 140 73 30 S Hydrofluoric Acid, Techn. 72 90 S S 68 S Hydrogen Chloride Gas, dry 140 68 S S Hydrogen fluoride 140 73 S S Hydrogen Hydrogen Peroxide 73 S (3% Solution) 73 73 100 365 S S 73 140 30 30 S U Hydrogen Bromide (10%) PERMEABILITY (9mJ24 hr./ 100 sq. inlmil) Hydrogen Peroxide (28% Solution) Hydrogen Sulfide, dry 73 S 73 S 68 S Hydrogen Sulfide (wet + aqudbus solut&n) Hydroquinone 140 lgepal Ink, Washable 73 73 Iodine Solution 73 Iodine (in alcohol) losan lpana Plus S 365 S S 365 S S 140 30 S 73 30 S 73 68 180 S 122 180 S 68 122 73 186 80 30 M M M 140 30 M 109 86 Kerosine 68 122 73 68 180 S S S S Kerosine (No. 2 fuel oil) 122 140 73 180 106 30 M M M Isopropyl Alcohol Isopropyl Ether lsooctane 5.10 0.25 3.74 48.0 100% loss Kardemommudropar (Cardamom Karo Syrup 0.110 2.89 4.27 59.0 131 132 TABLE Corrosion Resistant Materials Handbook 1.40: POLYPROPYLENE RESINS-SHELL (continued) CHEMICAL REAGENT CHEMICAL EXPOSURE PERFORMANCE S = Satis. EXPOSURE ISohdr I” saturated solutcm unless tndicated otherwise) Temp.. OF 180 S 180 S M 140 Kresol 73 73 Lacquer and Lacquer Solvents Lactic Acid 73 Lactic Acid (20%) 73 Lanolin 68 73 73 Ligroine 140 65 14 68 180 122 180 73 365 Linseed Oil (blue) 73 30 73 140 100 100 303 be Machine Oil Magenta Dye (2% Soln.) Magnesium Chloride Magnesium Carbonate Magnesium hydroxide 73 73 S S 68 140 73 68 140 212 73 140 S S M M M 258.0 100% loss S M M M S S S S S S S S S S S 140 212 S S 68 140 S S 212 73 S S Manganese Salts 73 S Mayonnaise 73 Meat Sauce 68 Malic Acid 23.5 M 73 Magnesium Sulfide 1.56 S 212 Magnesium Sulfate 4.62 5.38 0.85 4.53 0.23 S 73 Linseed Oil Oil S S S Lime Sulfur Lubricating U S S 365 140 Lead Acetate Lemon Oil U= Unsatis. 68 122 Kleenosan Windshield M= Marginal 140 140 140 Washer Solvent Time. days 30 30 30 69 68 Kerosine (No. 2 fuel oil) Kleenezy Kleer-View 1 PERMEABILITY kgn.124 hr.f 100 sq. inlmilb S 180 S 0.29 Synthetic TABLE 1.40: POLYPROPYLENE RESINS-SHELL CHEMICAL CHEMICAL EXPOSURE PERFORMANCE (Sol& I” saturated solution unlesstndlcated otherwtre) s * Meat Sauce Mennen’s “Skin Bracer” Mercuric Cyanide Mercurochrome Mercuric Chloride Mercurous Nitrate Mercury Methyl Alcohol (100%) Methyl Bromide Methyl Ethyl Ketone Methyl lsobutyl Carbinol Methyl lsobutyl Methylene Ketone PERMEABILITY (gmJ24 hr./ 100 sq. in/mill Satir. M= Marginal Temp., OF 122 73 140 68 Time. days 180 23 23 u - Unsatir. S S S 140 S S 73 73 68 S S S 140 73 S S 73 140 365 30 68 140 68 122 180 180 1.3 0.68 6.8 S S M U M M 3.5 84.0 68 180 S 0.21 122 180 S 2.7 70 100 S 140 100 U M Chloride 73 Milk Mineral Oil (White) 73 73 140 30 30 30 S M M Molasses Mondludropar 73 68 122 109 86 S S S 68 140 73 68 180 S S S S 0.031 122 180 S 0.26 140 100 S Monochloracetic (Almond) Acid Moth’Spray (Black Flag) Motor Oil (Shell X-100) Mustard Paste 73 n-Heptane Naphtha 140 68 Naphthalene 68 140 Natural Gas Neatsfoot Oil Nickel Chloride 0.16 1.29 S 100 M M 1 M M 212 M 73 73 140 S S S 73 133 (continued) EXPOSURE REAGENT Resins and Polymers 103 110 0.0 0.06 S (continued) 134 Corrosion Resistant Materials Handbook TABLE 1.40: PGLYPROPYLENE RESINS-SHELL T CHEMICAL EXPOSURE Temp.. OF Nickel Nitrate Nickel Salts Nickel Sulfate Nitric Acid, Cont. (continued) Time, days CHEMICAL EXPOSURE PERFORMANCI S = Sstir. M= Marginal U- Unratcs. 68 S 140 212 S S 73 73 S S 73 122 140 70 140 365 S S U S M tvl 73 180 30 100 100 100 Nitric Acid (40%) 73 365 M Nitric Acid, Cont. 140 70 30 100 U M Nitric Acid, Oil (10%) Nitric Acid, (30%) (50%) 140 100 U Nitric Acid (75%) 68 180 M Nitric Acid, Fuming 73 365 U Nitrobenzene Nitrogen Oxides 68 180 S 122 180 S 140 100 73 73 73 82 U 73 100 S 68 122 180 S S 180 S 140 68 30 U 3ils. Vegetables 3leic Acid Ileum 0.42 0.40 8.4 U Vutmeg Oil (21%) 0.42 S Vitrous Acids DPC 60 Solution PERMEABILITY (gm.124 hr.1 100 $9. idmil) S 73 1.25 0.076 0.27 U U 140 212 73 365 U S 140 152 S 0.0 68 180 S 0.28 122 180 S 2.3 Oxalic Acid (50%) 73 365 Oxygen Gas ‘almitic Acid 73 73 S S S 3live Oil 3xalic Acid ‘araffin Wax ‘araldehyde S S 68 140 68 M M 140 )eanut Oil 73 133 S 0.0 (continued) Synthetic TABLE 1.40: POLYPROPYLENE RESINS-SHELL CHEMICAL CHEMICAL EXPOSURE PERFORMANCE lSol,ds on saturated solution unlessmdlcated otherwsel Peanut Oil Peppermint Oil Perchloric Acid Petroleum Oils, Sour Petroleum Oils, Refined Phenol Phenol Solution (5%) Phosphoric Acid (25%) Phosphoric Acid (25-50%) Phosphoric Acid (85%) Phosphorous Oxychloride s = Satis. Temp., OF Time, days Marginal lJ= Unsatis. 140 73 120 73 196 95 S S M M= 73 73 73 100 sg. inlmil) 0.07 0.14 39.3 S 73 140 100 loo S S 73 140 365 30 S S 73 73 70 S S 109 S 140 108 S M 68 Picric Acid 73 M 68 S 140 S Chromium, PERMEABILITY (gm J24 hr./ S M Plating Solutions: Brass, Cadmium, 135 (continued) EXPOSURE REAGENT Resins and Polymers Copper, Lead, Gold, Indium, Nickle, Rhodium, Silver, Tin, Zinc. Potassium Bichromate/ Sulphuric Acid/Water (5/l 00/5) Potassium Bicarbonate 70 106 M 140 108 M 68 140 S S S Potassium Borate 68 140 Potassium Bromate 68 140 Potassium Bromide 68 140 S S S S S Potassium Carbonate 73 S Potassium Chlorate Potassium Chloride 73 73 S S Potassium Chromate 68 140 S S Potassium Cyar.ide 68 140 S 212 S S Potassium Ferricyanide Potassium FerrVFerrocyanide 68 140 68 S S S (continued) 136 Corrosion Resistant Materials Handbook TABLE 1.40: POLYPROPYLENE RESINS-SHELL CHEMICAL (continued) CHEMICAL EXPOSURE PERFORMANCE EXPOSURE REAGENT (Sohdr m saturated solution unlerr mdicated otherwsel Temp., OF Potassium FerrVFerrocyanide 140 Potassium Fluoride 212 68 Potassium Hydroxide 140 212 68 Potassium Hydroxide Potassium iodide Potassium Nitrate 122 73 73 68 (50%) Potassium Perborate Potassium Perchlorate (10%) Potassium Persulphate Time, days S = Satis. M= Marginal PERMEABILITY (gm./24 hr./ 100 sq. inlmil) u= Unsatir. S S 180 180 365 S S S S 140 S S S S S 212 68 S S 140 68 S S 140 68 S 140 S 0.0 0.48 S Potassium Permanganate Solution Potassium Sulfate 70 100 140 73 100 M M S Potassium Sulfide 68 S S S Potassium Sulfite 140 212 68 Propane Propionic Acid Propylene Dichloride Pyridine Rice Barn Oil Rosin (light) Safflower Oil Sauerkraut Shell X-100 Shellac 140 S S 212 73 68 140 S M S M 68 M 140 M 73 73 140 S S S 106 111 73 S 73 140 73 68 161 63 122 73 0.0 0.0 0.0 0.0 180 S S S S 180 S 0.26 0.031 S (continued) Synthetic TABLE 1.40: POLYPROPYLENE RESINS-SHELL CHEMICAL Shoe Polish (liquid) Sea Water 73 68 Silica Gel 140 212 68 Silicone Oil Silver Nitrate Soap Solution (1%) Soap Solution (5%) Soapless Detergent Sodium Acetate Sodium Benzoate (35%) Time, days CHEMICAL EXPOSURE PERFORMANCE S = Sotis. _ M= Marginal U= Unsatis. S 140 S 212 73 73 365 S S 73 30 S S 140 30 S 70 100 S 140 73 100 S S 68 S 140 S 212 68 S 140 S S 2t2 S 73 Sodium Bisulfate 73 S Sodium Bisulfite 73 73 S Sodium Bromide Oil Sol’n Sodium Carbonate Sodium Carbonate, S 68 S S 140 68 140 S S 73 72 S 365 30 S S 176 30 S 73 30 S 140 30 S 73 73 365 30 S S (20% Solution) Sodium Chlorate 140 30 S sodium Chloride, 72 90 S 176 30 S 73 365 S 140 30 S Satur. Solution Sodium Carbonate Sodium Carbonate aqueous solution) sodium Carbonate Solution (2% Sol’n) PERMEABILITY (gm.124 hr./ 100 sq. in/mil) S S S S Sodium Bicarbonate Sodium Borate Sodium Bromide 137 (continued) EXPOSURE Temp., OF Resins and Polymers (2.5 73 S Sodium Chloride (10% Solution) (continued) 138 Corrosion Resistant Materials Handbook TABLE 1.40: POLYPROPYLENE RESINS-SHELL REAGENT (continued) CHEMICAL EXPOSURE Gollds &n saturated solution unlessindicated otherwse) Temp., OF Sodium Chlorite (2%) Time, days 68 Sodium Chlorite (20%) 140 68 Sodium Chlorite (30%) 140 68 CHEMICAL EXPOSURE PERFORMANCE S = Satis. M= Marginal U= Unsatis. S S s M S M Sodium Chromate 140 68 Sodium Cyanide 140 73 S 68 S 140 212 68 S S Sodium Dichromate Sodium Ferricyanide Sodium Ferrocyanide PERMEABILITY (gm.124 hr./ 100 sq. in/mill S S 140 S S 212 68 S S 140 S 212 S Sodium Hydroxide 73 365 S (1% Solution) Sodium Hydroxide 140 72 30 90 S S (30% Solution) Sodium Hydroxide, 176 70 30 365 S S (50%) Sodium Hydroxide 140 73 100 30 S S (60% Solution) Sodium Hypochlorite 30 180 180 30 30 30 S S S S M M M M Sodium Hypochlorite (5%) Sodium Hypochlorite (10% Sol’n) 140 68 122 73 140 73 sodium Hypochlorite Sol’n Cont. 73 70 100 100 140 100 0.58 1.92 M S sodium Metaphosphate 73 sodium Nitrate 73 sodium Palmitate 73 30 S (5% Solution) sodium Perborate Godium Phosphate, Alkaline 73 73 73 100 S sodium Phosphate, Acid 73 S sodium Phosphate, Neutral 73 S Aodium Silicate 73 S S S S (continued) Synthetic TABLE 1.40: POLYPROPYLENE RESINS-SHELL CHEMICAL 139 (continued) PERMEABILITY EXPOSURE REAGENT Resins and Polymers (Solids in saturated solution unless indicated otherwise) Sodium Sulfate Sodium Sulfide Sodium Sulfite Sodium Thiosulfate (hype) Soybean Oil Spindle Oil Stannic Chloride Stannous Chloride Starch 140 Stearic Acid Succinic Acid Sugars and Syrups Sulfate Liquors Sulfur Sulfamic Acid S 212 S 73 73 68 140 212 S S S 73 73 68 176 S S Sulphur Dichloride 68 S S S S S Sulfur Chloride 73 S Sulfur Dioxide (dry) 73 S Sulfur Dioxide (wet) 73 73 140 70 365 30 100 140 100 S 73 30 S 140 30 S 72 176 72 90 10 90 S S S 176 10 S 73 68 365 180 S S Sulfuric Acid (3%) Sulfuric Acid, Dil. (10%) Sulfuric Acid (30%) Sulfuric Acid (50%) Sulfuric Acid (96%) Sulfuric Acid (97%) Sulfuric Acid, cont. (98%) S S S S -1.01 (continued) 140 Corrosion Resistant Materials Handbook TABLE 1.40: POLYPROPYLENE RESINS-SHELL CHEMICAL (continued) EXPOSURE REAGENT (Solids m saturated solution unlesslndlcsted othmwr~~ Sulfuric Acid, cont. (98%) Sulfurous Acid Temp., OF Time, days 122 140 180 100 S M 180 180 S M M 73 68 122 Super Shell 68 Tallow CHEMICAL EXPOSURE PERFORMANCE S = Satir. T M= Marginal U= Unsatis. S Tannic Acid 73 s Tar Tartaric Acid 73 73 S S Tea 73 514 Solution (27%) Tetrahydrofurane Tetralin 73 S S M 365 100 S M M Tomato 73 2T Oil 68 122 73 180 180 30 S S M 140 72 176 30 90 30 U M M Transformer Oil Transformer Oil, DTE/3D Trichloracetic Acid, 2N Trichloroethylene Triethanolamine Tri-sodium Phosphate Two-stroke Oil Varnish Vaseline Vaseline Oil Vinegar S U 68 140 73 S S S M 365 140 30 U 70 140 100 100 S M 73 Urea Vanillindropar S 73 73 73 Turpentine (Vanilla) 68 122 100% loss 100% loss S 100 73 73 73 73 140 Thiopen Toluene -1.44 S 140 “Teepol” PERMEABILITY (gm.124 hr.1 100 sq. in/mil) 0.0 4.1 S 109 86 S S 1.99 73 68 122 180 180 S S S 0.0 0.073 72 90 S 176 68 30 180 S S 0.64 122 180 S 2.81 (continued) Synthetic TABLE 1.40: POLYPROPYLENE RESINS-SHELL CHEMICAL (continued) EXPOSURE REAGENT (Sol,dr I” saturated solutmn unlesslndacated otherwml Temp., OF Time, days 365 14 Water (brine) 73 140 73 Water (fresh) 73 Water Water (potable) Wax Crayon 176 Wedac Wesson Oil Wheat Germ Oil Whiskey White Paraffin Resins and Polymers CHEMICAL EXPOSURE PERFORMANCE S = Satir. M= Marginal U = Unsatis. PERMEABILITY (gm.124 hr./ 100 sq. in/mill S S S S 30 S 140 72 30 30 S S 2.46 0.10 73 160 S 0.01 140 58 S 0.0 73 S 73 S 68 176 S S White Spirit (low aromatic content) 73 100 U White Spirit (high aromatic 73 100 U Wines 73 30 S Xylene 68 180 M 100% loss 73 122 140 365 180 100 M M M 100% loss 100% loss 100% loss content) Yeast Zinc Chloride Zinc Oxide Zinc Sulfate 68 140 73 68 140 73 S S S S S S 141 142 Corrosion TABLE 1.41: Resistant Materials POLYSTYRENE Handbook RESINS-HUNTSMAN CHEMICAL These thermoplastic resins are crystalline, rigid and of brilliant clarity. They are formulated applications. All the polystyrene resins are processed by extrusion, thermoforming, blow only the rubber-modified impact polystyrene or ABS can be thermoformed. REAGENT CHEMICAL EXPOSURE PERFORMANCE EXPOSURE (Solodr 4” saturated solutm~ unless indscated otherwtsee) s = Temp., OF Time. days Satis. M= Marginal U= Unsatis. Acetic Acid 5% 77 365 Acetic Acid 10% 77 365 S M Acetic Acid 100% 77 365 U Acetophenone U Adrenalin S M Hydrochloride Adrenalin in oil Ally1 Alcohol Chloride (Sat.) 122 365 S Aluminum Ammonia Sulphate (Sat.) 122 365 S S 122 365 S Ammonium Hydroxide Amyl Alcohol U Amyl Acetate-n U U Amy1 Phthalate Amseed Oil Aspirin (pwd) Atropine Sulphate Barium Carbonate Beef X U (pwd) 365 Z S 122 365 S U S U S 122 122 365 S 365 S U 122 Benzaldehyde Benzedrine Benzene Acid X U Acetate Borax (Sat.) Boric Acid Bromine a SolventI U Aluminum Benzyl SOLVENT (X lndtcater that the reagent acted as U Acetone Benzoic to suit a wide variety of molding or injection but Liquid U Butter Butyl Acetate iso U X Butyl Butyl Acetate Alcohol n iso U X Butyl Alcohol n Butyl Phthalate Caffeine (Sat.) Calcium Hypochloride Calcium Hypochlorite Camphor Carbon Tetrachloride Carbolic Acid Carbolic Acid Cassia Oil Castor Oil 50% 100% 77 365 S S 15% U S M U M U M X U U S (continued) 144 Corrosion Resistant Materials Handbook TABLE 1.41: POLYSTYRENE RESINS-HUNTSMAN CHEMICAL (continued) CHEMICAL EXPOSURE PERFORMANCE S = Satir. EXPOSURE REAGENT (Soltdr in saturated solution unless md~cated otherwant 30% jlycerine ieptyl Alcohol-n fexane iexyl Alcohol-n horseradish ioney hydrochloric Acid iydrochloric Acid iydrofluoric Acid iydrogen Peroxide iydroquinone odine Tincture so-propyl Alcohol (erosene .actic Acid 16% M=MargiMl Temp., OF Time. dayr 77 240 SOLVENT (X lndoutn that the r+gent acted *I a 5ob4ent) U- Unutir. ;lucose 10% 38% 10% 30% 77 365 77 365 77 365 “s S s” M S S M U S M M M U U _anolin _ard .auryl Alcohol S U S M .ead Arsenate _ead Nitrate 122 365 _emon Juice _ime Water _ipstick Aagnesium Carbonate Aaleic Acid 10% S U S M 122 77 365 S 365 365 S S dercuric Chloride 5% Jlesityl Oxide 122 U U M vlethyl Acetate wlethyl Alcohol X vlethyl Ethyl Ketone U U X Methyl U X U X wlethyl Chloride lsobutyl Ketone Methyl Propyl Ketone Methyl Salicylate (Oil of U Wintergreen) Methylene U Chloride 77 Milk Mineral Oil Mono-Chloro Benzene Motor Oil Mustard Nitric Acid 20% Nitroglycerine 14 S S U M X M U S (continued) 146 Corrosion Resistant Materials Handbook TABLE 1.41: POLYSTYRENE RESINS-HUNTSMAN CHEMICAL EXPOSURE Tannic Acid 2% Tartaric Acid Tea (Sol.) Tetrahydrofurfuryl Alcohol Tetralin Thionyl Chloride Titanium Tetrachloride Toluene Trichloroethylene Trisodium Phosphate (Sat.) Triethylene Glycol Triethylene Tetramine Turpentine Water Water Carbonated Witch Hazel Distilled Worcestershire Sauce Zinc Carbonate Zinc Chloride Zinc Stearate 50% (continued) Synthetic TABLE 1.42: POLYSULFONE-UNION Resins and Polymers 147 CARBIDE UDEL Polysulfone is a high performance thermoplastic known for its high temperature resistance [3OO”F (149°C) UL listing for continuous use], hydrolytic stability, and excellent close tolerance moldability. Polysulfone also possesses good resistance to a wide variety of aggressive environmental conditions. In the most general terms, POlYsulfone is highly resistant to aqueous mineral acids, alkali, and salt solutions. Resistance to detergents and hydrocarbon oils is good, even at elevated temperatures under moderate levels of stress. In polar organic solvents such as ketones, chlorinated hydrocarbons, and aromatic hydrocarbons, polysulfone will swell, dissolve, or stress-crack. Chemical Inorganic Chemicals (22°C.)600C.)(tt50C.)(990C.) ‘730F: i40°F: ittS°F.ilOOF. Acids Chromic Acid, Chromic Acid, 12% Resistance (121°C.)(1490C.) .25O”F. 300°F NR NR NR NR NR NR NR NR NR NR NR NK Hydrobromic Acid, 20% R R R R R R Hydrochloric Acid, 10% R R R * * * Hydrochloric Acid, 15% R R R + * * Hydrochlonc Acid, 20% R R R * * * Hydrochlorw Acid, 37% R R LR NR NK NR ‘Hydrofluoric Nltnc 60% Acid, 50% Acid, 10% R * R YR Acetlc Acid. .50% AC~IIC Acid. * N#tr!c Acid, 71% NR * ’ * . _ Phosphoric Acid, R R R R K R R R R K R K R R K R YK R * ’ ’ K K R R K * R Sulfuric Actd, 65% K R R R K R Acid. 75% R R K K K NH Sulfunc Acid. 85% K K R R \K NR UK 1K Anhvdrlde Arc=tnnl= R 40% Acetic Acod. 95% NR YK YK Bases Ammonia. 15% R ’ ’ ’ Ammonia. 29% K . * Potawum Hydroxide, 20% R R Potawum Hydroxide, 35% I? R . ’ ’ \K lo”% Benzene. ___- 100% Butanol, 100% Butvl Acetate. Butyl CELLOSOLVE 5% K k K K K Hydroxide, 10% K R K- K K Solvent Carbon CELLOSOLVE III~IC K UK Crude K UK C!clohexane. * * Tnchlorlde, Sat. Calcium Chloride, Calcium Hypochlorlte 100% Sat. Wet 100% Oxygen Ozone Narrate, Sar. R Ethanol, R R R R K R R R R K R . . NR * * * K R Ethanolamlne. Ethyl 2.Ethvl ’ * * K ’ * R R * ’ ’ * ’ R K R R K “Freon’: BF, “Freon” TMC I . . LR * ’ Furfural K K R K R R Gasoline, Sodwm Hypochlorite, 17% K K R R K R Glucose Sodium Stl~cate, 1.7% I r 1 LR ’ * Clvcerlne. n-Heptane, K R R K R \K YR NK NR ’ . * ’ . . . * f K *- R r NK‘ ’ NR * . . 1 f * f ’ * + . * f . R 1 R * ” UR YK UK NK NK UK ‘rK UK CK YK . . . . f . . r f * . . . . . . NK R NK ZiK UK UK \iK LK vuK \iK UK \K R \K \K ‘*K \K . I . .- 100% 100% 11 , lOOo/ 0 “Freon”22. 100% 5X% K ’ 100% Glycol. Hypochlortte. S.U. Acid. Ethylene Carbonate, Chloride, 100% D~am~ne, 92% Sodium Zinc NK ’ 100% Butvrtc Sodium 1.7% 100% Ethylene “Freon” ’ K YK . 100% Acetare, Formaldehyde, * UK LR 100% R K 100% Phrha!ate, K K 100% ether, R R UK R _ Dwopropyl Dtoctyl 100% 100% ether, NR NR R R Green Liquor -Hydrogen Peroxide, . * NK NR R 100% Cvclohexanone, Liquor \R UK R 40% 011. Texas. Dwthyl 100% 100% Oil. R ‘Chlorine, Solvent, 4cld. Cottonseed 100% 100% K K 100% Tetrachlorlde. K K YR UK 100% R 40% UK UK Toluene, R Persulfate, YR ‘JR Hydroxy R Ammonium hK Prop~onate \R ’ * UK Butylated R ’ ’ * * UK Calcium K . ’ I \K R 25% * * . . NK \K LR R 50% R NR * 100% Hydroxide. R R * lOO”6 Hydroxide. 24% R - Solvent. Sodium Persulfate. R i\n~sole. Sodium Other Ammonium R LK Hvdroxy Butvlated Chloroform, Hydroxide. Antimony 100% Chlotobenzene. Sodium Potawum 100% CARBITOL Sodium Black Glacial Aceton~trtle. Suifwc Sulfuric R R NR ’ Acid, R R UK ’ Sulfuric R R * . 100% 10% NR NR Acid, Ar,d * LR (149Y.J 300°F. Actd. 20% UK LR depending Acetic * R possible Acetic NR R appllcatmns (22°C.)(600C.~(850C.)(990C.~ 73°F. 140°F. lBS°F. 210°F. Chemicals * 20% (many No data * 40% Phosphoric NR * * Acid, Actd, 50% Recommendation on stress level) Not Recommended LR Acid, Acid. 85% LImIted LR * Nitric Phosphoric Recommended LR Nifric Phosphoric rarrngs IO Organic NR 20% Key R Chart n-Hexane, 100% , 1007 ” loo”& 100% 100% 100% LR LR LR ’ * ’ ’ ’ * ’ * . . * .- UK UK YK NK PUK NK NK NK NK NK LR * R * R ’ R R ’ . * * ’ ’ * ’ * * * ’ ’ * . *- 1 (continued) 148 Corrosion Resistant Materials Handbook TABLE 1.42: POLYSULFONE-UNION Organic CARBIDE Chemicals Iroocta”e, (22OC.)(6OOC.) (85~C.J(9s~C.)(149~C.) 73OF. 140°F. 185OF. 210°F. 300°F. (continued) 100% Iropropanol. 100% Kerosene, 100% Lactac Acid, Laurie (continued) 60% Acld Linseed Oil, Malomc MEK, 100% Acid, 100% 100% Methanol, 100% Methylene Chloride, 100% R * * * + LR * * ’ 1.R * * * * * R R R R R * f * . SR K R * 1 * * * . * . NK NK NK YR R * * r * NR NR NK UK zrK NR NR NR NR NR NR 100% R * ’ * * Oxahc Actd, 20% R * * * NR NR NR UR Morphoiine Oletc Aad, Pyrtdine * hR R * ’ * ,,,.2.2-Tetrachloroethane. 100% UK UK UK 4K Tetrachloroerhylene. NR UK UK ‘.R ‘iK NR NR NK ‘uK \R Sorbx Acid, Tnl,apn.- 100% 100% Inns. Trlchloroethylene, Tributyl 100% Phosphate Turpentine, VM&P 100% Naphtha, Xvlene. + hK ‘JR \K UK QK 4iK NK NR UR NR hiR IR ’ ’ ’ . 100% 100% Pipe 5eal Compounds “Lot-Tote” AV 100% NK UK CK LK \K “Lx-Tire” FJ, 100% NK *K UK VK \K NK NK NK ‘rK \K “Lx-Tire” E. 100% “Masters” Metallic, “Permatex” “Trtion 100% ’ ’ ’ LK ” * * * ’ ’ . ’ ’ K R Commercial miscellaneous . K n2. 100% TF-15. ’ ’ + K 100% Products “Clobber” Acldlc Drain “Copperbwe” “Duckreal Cleaner, 100% Copper Cleaner, Sealant.” LR 100% 100% R Odr: ASTM Oil K K R ASTM 011 82. loo”<. K K K K ASTM 011 #3, lOo’%a K IK IK IK A‘,TM 011 #lO R K K K K LR * * ’ * * * ’ * ’ W, 100% 100% . 1 Slllcones. “SlidstIr” RTV refers chlorine. speclfrcaiiy as “chlorine” to 100% expocure lOO’Y, RTV-106 (GE) R R R RTV-109 (GE) R R R K * * “Zephlran” Thrs 140. lOO’%I 88 (GE). chlorme (wet), In many Dwnfectant. 100% It IS recognlred of these environmentr, that WIdespread polysulfone mdustry practice can provide ’ * * * * IS to refer excellent corrwon to many envwonm?nts. protection other than 100% Synthetic TABLE 1.43: POLYVINYL CHLORIDE Resins and Polymers 149 DUCTS-DAYCO PLIADUCT is a continuous, all plastic extruded strip, so shaped that when coiled, the edges interlock to form a rigid duct. It is flexible. Hand bend it to any position. It will remain in that position until bent again. Lightweight and durable, PLIADUCT has no wire or metal reinforcement. It will not corrode or oxidize. PLIADUCT is self-extinguishing. Service temperature range is -10” to 150°F. Chemical Resistance Chart* CHEMICAL TEMlEFR^rTR; 0 0 Acetaldehyde Acetic Acid, to 80% Acetic Acid, over SO% Acetic Acid, glacial Acetic Anhydride Acetone Acetylene Adipic Acid Allyl Alcohol, 96% Allyl Chloride Alum Aluminum Saks .Ammonia (gasdry) Ammonia (liquid) Ammonium Fluoride, 25% Ammonium Hydroxide Ammonium Salts (other) Amy1 Acetate Amyl Alcohol Amy1 Chloride Anilineand Salts Anthraquinonesulfonic Acid Antimony Trichlonde Aqua Regia Aromatic Hydrocarbons Arsenic Acid, 80% Arylsulfonic Acid Barium Salts Beer Beet Sugar Liquors Benzaldehyde, 10% Berualdehyde, above 10% Benzene Benzoic Acid Bismuth Carbonate Black Liquor Bleach (12% Cl) Borax Boric Acid Breeder Pellets (fish derivative) Bromic Acid Bromine, Liquid Bromine. Vapor (25%) Bromine Water Butadiene Butane Butanol, Primary Butanof, Secondary Butyl Acetate Butyl Alcohol Butyi Phenol NR NR R R R NR R NR NR NR NR NR A R -R R R NR NR NR A R R A A R NR NR R NR R R R R NR NR R NR NR NR NR NR R R R R R R NR NR R R R R R R R R R R R R NR NR NR NR A R R R R R R R R R R R fl R NR R R R R R R R R R R R NR R R R R NR NR R NR CHEMICAL Butyne Diol Butyric Acid Cadmium Saks Calcium Salts Carbon Bisuffide Carbon Dioxide Carbon Monoxide Carbon Tetrachloride Carbonic Acid Castor Oil Caustic Potash Cellosolve Caustic Soda Chloracetic Acid Chloral Hydrate Chloric Acid, 200~ Chloride (water) Chlorine (dry) Chlorine, Gas (dry) Chlorine, Gas (wet) ChlorineMater Chlorobenzene Chloroform Chlorosulfonic Acid Chrome Alum Chromic Acid, 10% Chromic Acid, 5090 Citric Acid Copper Salts Corn Syrup Cottonseed Oil Cresol Cresylic Acid, 50% Crotonaldehyde Crude Oil Cyclohexanol Cyclohexanone Detergents Dextrin Dextrose Diazo Salts Digtycolic Acid Dimethylamine Dioctylphthalate Disodium Phosphate Distilled Water Esters Ethers Ethyl Acetate Ethyl Acrylate Ethyl Alcohol Ethyl Chloride Ethyl Ether TEMPERATURE 72’F 140°F R R R R NR R R R R R R R R R R R R NR NR NR R NR NR R R R NR R R R R R R NR R NR NR R R R R R R NR R R NR NR NR NR R NR NR NR NR A R NR R R NR R R R NR R R R R R NR NR NR R NR NR R NR NR R R R R NR R NR R NR NR R R R R R R NR R R NR NR NR NR R NR NR CHEMICAL T~~PERITuRE 72-F 140°F Ethylene Bromide Ethylene Chlorohydrin Ethylene Dichloride Ethylene Glycol Ethy!ene Oxide Fattv Acids Ferric Salts Fish Solubles Fluboric Acid Fluorine, Gas (wet) Fluorine, Gas (dry) Fluorcsilicic Acid, 25% formaldehyde Formic Acid Fructose Fruit Juices and Pulp Furfural Gallic Acid Gasoline Gasoline, High Octane Gasoline, Jet Fuel, JP4 Gasoline, Jet Fuel, JP-5 Glucose Glycerine Glycol Glycolic Acid Grapesugar Hsptane Hezane Hexanol, Tertiary Hydrobromic Acid, 20% Hydrochloric Acid, to 25% Hydrochloric Acid, over 35% i-iyfiocyanic Acid Hydrofluoric Acid, to 50% Hydrofluoric Acid, over 50% Hydrogen Hydrogen Peroxide, to 93% Hydrogen F’hosphide Hydrogen Sutfide Hydroquinone Hydroxylamine Sulfate Hypochlorene Acid iiypochlorous Acid Iron Salts Jodine Kerosene Ketones KraR Liquors &tic Acid, 25% Lard Oil Laurie Acid Lauryl Chloride NR NR NR NR NR NR R R NR NR R R R R R R R R R R R NR A R R R R NR R R R A NR NR R R R R R R R R R R A R R R R R R R R R R R R R R R R R R NR NR R R NR R NR NR R R R R R R R R R R fl NR R R R R R R R NR R NR R R R R R fl NR R R R R (continued) 150 Corrosion TABLE 1.43: Resistant POLYVINYL CHEMICAL Oxygen Ozone Palmitic Acid, to 70% Palmitic Acid, over 70% Paraffin Perchlotic Acid, to 10% Handbook CHLORIDE TEMPERATURE Lead Salts Linoleic Acid Linoleic Oil Linseed Oil Liquers Lithium Bromide Lubricating Oil, ASTM #1.#2. u3 Machine Oil Magnesium Salts Maleic Acid Malic Acid Manufactured Gas Mercury Salts Mercury Methyl Alcohol Methyl Chloride Methylene Chloride Methyl Ethyl Ketone Methyl Iso-butyl Ketone Methyl Sulfate Methyl Sulfuric Acid Milk Mineral Oils Mixed Acids Molasses Muriatic Acid Naphtha Naphthalene Natural Gas Ntckel Salts Nicotine Nicotine Acid Nitric Acid. Anhydrous Nitric Acid, to 66% Vitric Acid, over 68% Nitrobenzene Nitrous Oxide OCHlOl Oils and Fats Oil, Sour Crude Oleic Acid Oleum Oxalic Acid $ Materials 72’F 140°F R R R R R R R R R R fl R R R R R NR NR NR NR R R R R R R R R NR R R R R NR R NR NR R R R A R NR R R R R R R R R R R R R R R R R R R R R R NR NR NR NR NR R R R R R R NR R R R R NR R NR NR R R R R R NR R R R R NR R R DUCTS-DAYCO CHEMICAL Perchloric Acid, to 70% Perchloric Acid, over 70% Petroleum Liquefier Phenol Phenylhydrazine Phenylhydrazine Hydrochloride Phosgene. Liquid Phosgene. Gas Phosphoric Acid, to 85% Phosphorus (yellow) Phosphorus Pentoxide phosphorus Trichloride Photographic Solutions: DK#3 Dektal Developer Kodak Fixer Kodak Short Stop Picric Acid Potassium Alum Potassium Bicarbonate Potassium Bichromate Potassium Borate Potassium Bromate Potassium Bromide Potassium Salts Potassium Hydroxide Potassium Pemanganate, 10% ,Potassium Permanganate, 15% Propane Propane Gas Propargyl Alcohol Propyl Alcohol Propylene Dichloride Plating Solutions: %rass Cadmium copper Gold lndium Lead Nickel Rhodium Silver Tin Zinc KEY. R-fiecommsndod NR-NU Recommended BLANK SPACES lodie kslr ofmfic (continued) tacommwodatcms TEMPERATURE 72-F 140°F R NR A R NR NR NR R NR NR R NR R R R R NR NR NR NR R R R R NR R R R R R R R R R R R R NR R A R R R R R R R R R NR above 125.F A R R R R NR R R R R NR R R R R R R R R R R R R R R R R R R R R A R CHEMICU Rayon Coagulating Rochelle Salts Sea Water Selenic Acid Sewerage Silicic Acid Silver Safts mCFm2T Bath R’ R R R R R R R R R R Soaps Sodium Acetate Salts Sodium Hydrox!de Sour Crude Oil (west Texas) StannicSalts R Stannous Salts R Starch R Blearic Acid R Btoddards Solvent NR Sulfur R Sulfur Dioxide, dry R Sulfur Dioxide, wet R Sulfur Trioxide R Sulfuric Acid, to I%% R Sulfuric Acid, over 8096 NR Sulfurous Acid R fall Oil R Tannic Acid R Tartaric Acid A fetraethyl Lead R Tetrahydrofurane NR Thionyl Chloride NR Tirpineol R Titaniumfetrachloride NR Tanning Liquors R TOluol or Toluene NR Tri Butyl Phosphate NR Trichloroethyiene NR Triethandamine R Trimethyl Propane R Trisodium Phosphate R Turpentine Fi Urea ‘R Urine Fl Ymegar NR Vinyl Acetate R Water Acid Mine R Water Deionized R Water Demineralized R Water Distilled-water trash R Wprer Saft R Whiskey R White Liquor R Wines Xylene or Xylol NR Zinc Satts R R’ R R R R R R R A R R R A A NR R R NR R R NR R R R R NR NR NR R NR NR NR NR A R R R z NR R R A R R R R R NR R Synthetic Resins and Polymers TABLE 1.44: POLYVINYL CHLORIDE JACKETS AND COVERS-CEEL-CO Typical Resistance Features of CEEL-TITE Acetrc Acrd 20% ‘Acetone *Alcohol, Ethyl Alumfnum Chloride Alumnum Sulfate Ammonia Gas Ammomum Chlonde Ammomum f-tydroxde A-nmontwn Sulfate *Amy1 Chlonde ‘AntIme Barium liydroxrde Barium Sulfate Barium Sulfide Beet Sugar Lrquors *Benzene Benzorc Acrd Black Lrquor Bleach 12.5% acttve Cl, Bone Acid Bromrc Acid Calcrum Carbonate Calcrum Chlonde Calctum ttydroxrde *Carbon Btsuffide Carbon Morwxrde ‘Carbon Telrachlorrde Carbonrc Acid Caustrc Soda Caustrc Potash Chlorrne Waler ‘Chlonne lChlorobenzene Chrome Ac!d 10% ‘Chromrc Acid 30% Cttnc Acrd lCcke Dven Gas Copper Cyanrde Copper Sulfate lCreosol lCvclohexanol ‘Cjclohexanone ‘Drmethvlamrne ‘Droctylphthalate Drsodrum Phosphate ‘Ethers Ethylene Glycol Fatty Acrds Ferrtc Chlonde Ferrous Sulfate Fluonne (gat-wet) Fluoailicic Acid Fomaldehyae ‘Formrc Acrd Fruit Jutces + PUID *Furfural Qasokne (refined) Glycenne Hydrochloric Acrd t-tydrocyanrc Acrd lttydroiluorrc Acrd 50% Hydrogen Sulfide (dry) Hydroqurnone Hypochlorous Acid lodlne Trncture Kerosene Magneswm Chlorrde Malerc Acrd Metnyl Alcohol *Methyl Ethyl Ketcne *Methyl Chloride Mrxed Acrds Nickel Chlonde Nrckei Sulfate 300 Series PVC-UVR and 500 Series PVC lNrtnc Acrd Anhydrous Nttnc Acrd, 10% Nrtrtc Acrd. 63% Nitrous Oxrde 011sand Fats Olerc Acrd ‘Oleum Cxalrc Acrd Palmrtrc Acrd, 10% Perchlonc Acid, 10% ?eFe;;um 011s (sour) Phosgene Gas Phosphonc Acrd, 25% Phospnorrc Acid. 50% *Phosphorous Trichlonde Phthalrc Anhydrrde Plattng Soltirons Potassrum Chlonde Potassum Cyanide Potasscum Drchromate &w;ss; Hydroxide Permanganate. 10% Propy Alcohol *Propylene Drchlonde Sea Water Stlver Cyanrde Silver Platrng Solutron Srlver Nrtrate Sodrum Brsulffte Sodrum Chlonde Sodrum Cyantde Sodturn Ferrocyanrde Sodrum ttydroxrde Sodrum l-typcchlonte, 125% Sodrum Sulfate Sodrum Sulfite Sodium Throsulfate Sour Crude 011 Stannrc Chlonde Steanc Acrd Stannous Chlonde Sulfur Sulfur Dfoxide (dry) ‘Sulfur Droxfde (wet) Sulfunc Acid, Ib%’ Sulfuric Acrd. 70% Sulfurous Acid Tannrc Aced Tartanc Acrd ‘Tetrahydrofuran lToluene lTnchloroethylene Triethanolamine Trisodtum Phosphate Turpentine Urea Vinegar Vl$ter (acrd mane water) Whtskey and Whrte liquor Xylene Zfnc Chloride Zrnc Sulfate S-Satrsfactory U-Unsatisfactory Test Method ASTM - D - 1784 ‘Satrsfactory for use under atmcephenc condrtrons 751 Corrosion Resistant Materials Handbook 752 1.45: TABLE POLYVINYL CHLORIDE LINERS-FABRIC0 CHEMICAL RESISTANCE CHART “R-Recommended” “RT-Room ANIC IN0 Chemical Reagent INORGANIC ACIDS Id .t P. x;i he. 0 Aqua t 6or1c Acld 10 Carbonic Aad Chromac Acld Chromium, R-130 R-130 R-110 R-l 10 R-130 R-130 Trloxade R-130 Hydrobromlc R-l 10 R-130 Acjd Hydrochlonc Acid @ 30 R-RT R-RT Hydrochlortc Acad@ 20 R-100 R-130 Hvdwluonc Acad 20 Acid R-120 R-RT R-110 40 Nttrwz Ac,d R-100 30 Acld PhosPhOrlC R-100 75 R-l 10 R-110 Sulfuric Acld 10 R-150 R-100 Sulturlc Acld 40 R-RT R-RT R-RT R-RT Sulfurous Mw.ed Acid 20% HN03 INORGANIC ALKALIES Chemical Reagent :onc. 0 I R-130 R-150 R-RT R-130 R-150 R-AT Copper Sulfate R-130 R-150 R-RT R.130 R-150 R-RT R-130 R-150 R-RT Fcrr~c Chloride R-110 R-130 R-RT Fernc R.l10 R-130 R-RT Chloride Phosphate NItrate Ferrous Chlorade R.l10 R.130 R.RT Ferrous Sulfate R.l10 R-130 R-RT R-l 10 R-110 R-RT R-RT R-RT R-RT Hydrogen PeroxIde@ Hydrogen Peroxnde@ Hydrogen Sultade I -I- 3 10 R-l 10 R-130 R-RT Magnestum Carbonate R.120 R-140 R-RT Magnesum Chlorade R-120 R-140 R-RT Magneswm Nitrate R-120 R.140 R-RT Magnerwm Sulfate R-120 R.140 R-RT Chloride R-110 R.130 R-RT NItrate R-110 R-130 R-RT R-130 R.150 R-RT R-RT Phosphorus (Yellow1 R-100 R-110 Phosphorus PentoxIde R.lOO R-110 R.RT Potasr~um B+carbonate R.130 R.150 R-AT R-130 R-150 R-RI Chloride R-130 R-150 R-RT Potarswm Chromate R.130 R-150 R.RT Potasswn Cyamde R-110 R-130 R-RT R-RT Potaswm Nitrate R-130 R-150 R-RT R-100 Potaswm Perchlorate R.l10 R-130 R-RT Potasrlum Permanganate R-130 R-150 R-RT Potassium Sulfate :‘DMPOl JNI >s &tori al r ecommendad tenw. nwx I. E,,nrtmt BORN R-RT Carbonate 2699 4LT.S 2699 R-150 Potasswm at L INORGANI( 651 R-130 Potassium d ~ BORN Nitrate Mercurv R.140 7%HF at Chloride Mercurous Sta~nlesr Steel plcklmg (Cont’d.1 Material recommended max. Co”sta”t twnp. Copper Mercuric Aclds for DUNDS Copper Dlsodwm R-140 R.120 :onc. Alum Cuprous R.140 30 - co & 0 Chrome R-RT Fluor~l~c~c Acid Nnrlc Reagent 26990 Regaa Brom~c Acid Chemical SAL Temp.” at i 2699@ @ R-130 R-150 R-RT Salver Nitrate R.130 R.130 R-RT Sodun Bicarbonate R-130 R-150 R-RT Sodum Bwltlte R-120 R-140 R-RT Sodwm Borate R-130 R.150 R-AT Sodium Carbonate R-130 R-150 R-AT Sodium Chlorate R-130 R-150 R-RT Alunvnum Chloride R.130 R-150 R-RT Aluminum Fluoride R.120 R-140 R.RT Sodtum Chlorado R-130 R.150 R-RT Alummum Sulfate R-130 R-150 R-RT Sodium Dachromate R-130 R-150 R-RT Ammomum Carbonate R-130 R.150 R.RT Sodum Ferrocyanlda R-130 R-150 R-RT Ammomum Chloride R-130 R-150 R-RT Sodium Fluoride R-130 R.150 R.RT Ammonium Fluorldc R-130 R-130 R-RT Sodium Hypochlorite R.130 R-150 R-RT Ammonwm Nnratt R-130 R-150 R-RT Sodium Nwate R-130 R-150 R-RF Ammonwm Sulfide R-130 R-150 R-RT Sodium Sulfete R.130 R-150 R-RT Chlonde R-130 R-150 R-RT Sodium Sulfite 4.130 R-150 9.RT q-130 R-150 7.RT Antwnony 50 20 6srlum csrhvlate R-130 R-150 R-RT Trisodium Barurn Sulfate R-130 R-150 R-RT Zinc Chlonde q-130 R-150 =I-RT Zinc Sulfate q-130 R-150 9.RT Bismuth Carbonate R-130 R-150 R-RT Calcium Btsulfatc R-1JO R-15P R-RT Calcium Carbonate R-130 R-150 R.RT Calcwn Chloride R-130 R-150 R-RT Calcrum Hyoochlorlte R-130 R-150 R-RT Calcaum NItrate R-130 R-150 R-RT Calcwm Sulfate R-130 R-150 R-RT Phosphate (continued) @I ~ Synthetic TABLE 1.45: PoLYvlNYL PLATING CHLORHDE LINERS-FABRIC0 1 ORGANIC Material recqmm”ded 3/32” & l/8” PVCType 651 are the materials plating and rinse tanks. The combinatton sol~t~qn strength Electroless and mechamcal Solutions 8 mil PVC Type 29L9 (dIsposableI I ORGANIC Chemical I COMPOUNDS Reagent ICont’d.) Reagent Material recomm en ded at m;r: K. CO”,,P”, te mp. rJnc.?i @I BORN NR Gallx Acid NR NR GhXqse R.120 R-150 Glvcertne R-l 20 Hvdroqulnone NR Alcohol@ 00 Acid 100 NR NR NR NR NR NR NR R-100 R-100 Mallc R-100 R-100 NR rvR Acid Methyl Alcohol Methyl Ethvl 00 @ Ketone NR NR Naphthalene NR NR Nltrobenrene NR NR led at RP. Olefc Acid R-RT R-RT Oxalic Acid R.lOO R-110 BOEE Phenol Acid NR NR NR NR Polvv~nvl Acetate R-RT Acetic Acid 80 NR NR Acetic Acid 10 R-130 R.130 Acetlc AnhydrIde NR NR Acetone NR NR Tetrahvdrofuran NR NR Alkvl Alcohol NR NR Trlethanolamlne NR NR Alkvl Chloride NR NR Amvl Alcohol NR NR Amvl Acetate NR NR Amvl Chloride NR NR A”lll”e NR NR Benzene NR NR R-100 R-110 Eutvl Alcohol NR NR Butvl Phenol NR NR 8enro1c Acid Butvr~c Acid NR NR Carbon Dwlfrde NR NR Carbon Tetrachlor!de Chloracetlc Acid Chlorobenzene Chloroform Chlorosulfonw Cltrlc Acid Acid NR NR NR NR NR NR NR NR NR NR R-110 R-130 Cvclohexanol NR NR Cvclohexanone NR NR DeXtrl” R-130 R.150 Dlbutvlphthalate NR NR Dlethvl NR NR NR NR NR NR NR NR NR Ketone Dimethvlsmine Ethyl Acetate Ethyl Alcohol@ Ethyl Bromide NR Ethyl Chloride NR NR Ethyl Ether NR NR R-RT R-UT NR NR Formaldehvde Formtc Acid 100 40 R.130 I Sodwm Acetare R-100 R-110 Stearlc Acid R-100 R.l10 Tann~c Acid R-100 R.130 Urea R-100 Crude 011. fuel 011s and other allphatx h use wth PVC Type 3134. an 011 res~sta~ jrocarbonr MIS< Chemrcal Reagent LANf Dtrtllled Water Fert~llrer Grape Solutions IORN ed ,P. R.150 I-RT R-RT 2699 @ R.RT R-150 Sugar R-110 R.150 No. 31 Photographic R-100 Solut~or 011 Sea Water I-RT R-RT IR NR l-130 R-150 sugar Salutlo” R-150 R-140 Vl”BgH Water are s”#t ab le for 651 l-150 Mustard Peanut R-130 Matenal r max. c, Juicer Dakjre I IS COMPOUNI 0°C. 9 0 Fruit BOEE R-150 r Lead Acetate Phe”v)hvdrazl”e Acetaldehvde 661 NR Lactic I this. WNC Furfural lswropvl of choice for of temperature. abuse drctates COh at Chemiul Note: 153 (continued SOLUTIONS I Resins and Polymers R-150 (Potable) R-150 Wine (non-fortifIedI A-RT Yeast R-150 Wet strength Kvmene 557 Kvmene 709 Perez Rcs~ns resins: R-95 IR R.70 l-95 R-95 NR The above ratjngs are based on the consideration of chemical resistance only. Potable water will not attack flexible vinyls, but to store it safely from the standpoint of toxicity, a specially formulated vinyl must be used. This would also apply to any material that is intended for human consumption. In this latter category, the possibility of the migration of very small amounts of plasticizer having an effect on the taste of the stored liquid should be considered. @Hydrochloric Acid must not be contaminated with organic chlorides (500 ppm max. concentration) @Applies only to inhibited hydrogen peroxide. Unrnhibited 10% H202 will not deteriorate lining, but lining will contaminate Solution. 02699 material is specially formulated for pit 81 pond lining applicationsand is generally serviceable after installation between -20 deg. and +150 deg. F. It has a bacteriostat which resists attack by soil microorganisms. Some of the recommended uses for particular compounds are shown above, however specific applrcations should be checked with the factory, particularly those containing mixtures of the compounds mentioned above. @Concentrations of 10% or less are suitable with all vinyls listed at right for non-food use. @All concentrations left blank are 100% or Saturated solution. 154 Corrosion TABLE 1.46: Resistant Materials POLYVINYL Handbook CHLORIDE PIPE AND FITTINGS-THERMOPLASTIC Chemical Resistance of EXCELON RECOMMENDED (tested @72°F. 140°F) ACETIC ACID. 10% ACETIC ACID. 20% ACETYLENE ADIPIC ACID ALUM ALUMINUM ALUM ALUMINUM CHLORIDE ALUMINUM FLUORIDE ALUMINUM HYDROXIDE ALUMINUM OXYCHLORIDF ALUMINUM NITRATE ALUMINUM SULFATE AMMONIA (GAS-DRY) AMMONIUM ACETATE AMMONIUM ALUM AMMONIUM BIFLUORIDE AMMONIUM CARBONATE AMMONIUM CHLORIDE AMMONIUM HYDROXIDE AMMONIUM HYDROXIDE. 10% AMMONIUM HYDROXIDE, 28% AMMONIUM METAPHOSPHATE AMMONIUM NITRATE AMMONIUM PERSULFATE AMMONIUM PHOSPHATE AMMONIUM SULFATE AMMONIUM SULFIDE AMMONIUM THIOCYANATE AN~~H;AOUINONESULFONlC ._.. ._ ANTIMmd” TRICHLORIDE AkSENlC ACID, 80% BARIUM CARBONATE BARIUM CHLORIDE BARIUM HYDROXIDE BARIUM SULFATE i;,“b”M SULFIDE -_-. BEET SUGAR LIQUORS BENZOIC ACID BISMUTH CARBONATE BLACK LIOUOR BLEACH112%CLI BORAX BORIC ACID BREEDERS PELLETS ,d~;p,fc~~’ CADMIUM CYANIDE CALCIUM BISULFIDE CALCIUM BISULFITE CALCIUM CARBONATE CALCIUM CHLORIDE CALCIUM HYDROXIDE CALCIUM HYPOCHLORITE CALCIUM NITRATE CALCIUM SULPHATE CARBON DIOXIDE CARBON MONOXIDE CARBONIC ACID CASTOR OIL CAUSTIC POTASH CAUSTIC SODA CHLORAL HYDRATE CHLORIC ACID. 20% CHLORIDE (WATER) CHLORINE WATER CHROME ALUM CITRIC ACID COPPER CARBONATE COPPER CHLORIDE COPPERCYANIDE COPPER FLUORIDE Unless specified, COPPER NITRATE CORN SYRUP c&PER SULFATE COTTONSEED OIL CUPRIC FLUORIDE CUPRIC SULFATE CUPROUS CHLORIDE DETERGENTS DEXTRIN DEXTROSE DIAZO SALTS DIGLYCOLIC ACID DISODIUM PHOSPHATE DISTILLED WATER ETHYLENE GLYCOL FATTY ACIDS FERRICCHLORIDE FERRIC HYDROXIDE FERRIC NITRATE FERRIC SULFATE FERROUS CHLORIDE FERROUS SULFATE FISH SOLUBLES FLUOBORIC ACID FLUORINE GAS (WET) FLUOROSILICIC ACID, 25% FRUCTOSE FRUIT JUICES 8 PULP FREON 11 FREON 12 GALLIC ACID GASOLINE. JET FUEL IP.‘l k.i GLUCOSE GLYCERINE GLYCOL GLYCOLIC ACID GRAPESUGAR HYDROBROMIC ACID. H:gOCHLORIC ACID. 10”. 30’. 35% HYDROCYANIC ACID HYDROGEN HYDROGEN PEROXIDE, 30% 50% H::;OGEN SULFIDE HYDROQUINONE HYDROXYMMINE SULFATE HYPOCHLORENE ACID HYPOCHLOROUS ACID KEROSENE KRAFT LIOUORS LACTIC ACID. 25% LAURIC ACID LEAD ACETATE LEAD CHLORIDE LEAD SULFATE LINOLEIC ACID LINSEED OIL LITHIUM BROMIDE LU[c;;A;;NG OIL ASTM C2 MACHINE OIL MAGNESIUM CARBONATE MAGNESIUM CHLORIDE MAGNESIUM HYDROXIDE MAGNESIUM NITRATE MAGNESIUM SULFATE MALEIC ACID MALIC ACID MANUFACTUREDGAS MERCURIC CHLORIDE MERCURIC CYANIDE MERCUROUS NITRATE MERCURY deta 6 basedon 7OY mm h?mperature METHYL ALCOHOL METHYL SULFURIC MILK MOLASSES MURIATIC ACID NATURAL GAS NICKELCHLORIDE NICKEL NITRATE NICKEL SULPHATE NICOTINE NICOTINE ACID NITROUSOXIDE OILS 8 FATS OIL, SOUR CRUDE OLEIC ACID CI$$lC$CID ACID OZONE PALMITRIC ACID, 10% PERCHLORIC ACID. 10% PETROLEUM LIOUIFIER PHOSGENE. GAS PHOSPHORIC ACID. 10% PHOSPHORIC ACID. 25% PHOSPHORIC ACID. 75% PHOSPHORIC ACID, 85% PHOTO SOLUTIONS DK #3 DEKTAL DEVELOPER KODAK FIXER KODAK SHORT STOP POTASSIUM ALUM POTASSIUM BICARBONATE POTASSIUM BICHROMATE POTASSIUM BORATE POTASSIUM BROMATE POTASSIUM BROMIDE POTASSIUM CARBONATE POTASSIUM CHROMATE POTASSIUM CHLORATE POTASSIUM CHLORIDE POTASSIUM CYANIDE POTASSIUM DICHROMATE POTASSIUM FERRICYANIDE POTASSIUM FERROCYANIDE POTASSIUM FLUORIDE POTASSIUM HYDROXIDE POTASSIUM NITRATE POTASSIUM PERBORATE POTASSIUM PERCHLORATE POTASSIUM PERMANGANATE. 1046 POTASSIUM SULFATE PROPANE PROPANE GAS PLATING SOLUTIONS BRASS CADMIUM :zlER INDIUM LEAD NICKEL RHODIUM SILVER TIN ZINC RAYON COAGULATING BATH SEA WATER SEWERAGE SILICIC ACID SILVER ZYANIDE SILVER NITRATE SILVER PLATING SOLUTION :A:;: SULFATE . PROCESSES R-4000 Pipe and Fittings SODIUM ACETATE SODIUM ALUM SODIUM BENZOATE SODIUM BICARBONATE SODIUM BISULFATE SODIUM BISULFITE SODIUM BROMIDE SODIUM CARBONATE SODIUM CHLORATE SODIUM CHLORIDE SODIUM CYANIDE SODIUM DICHROMATE SODIUM FERRICYANIDE SODIUM FERROCYANIDE SODIUM FLOURIDE SODIUM HYDROXIDE. 10% 30% 50% SODIUM HYPOCHLORITE SODIUM NITRATE SODIUM SUl~rlTE SODIUM SilLI IDE SODIUM SULFITE SOUR CRUDE OIL (WEST TEXAS) STANNICCHLORIDE STANNOUS CHLORIDE STARCH STEARIC ACID SULFUR SULFUR DIOXIDE. (DRY) SULFUR TRIOXIDE SULFURIC ACID 3”. 10% 20% 33’. 50% SL?&ROUS ACID TAN OIL TANNIC ACID TARTARIC ACID TANNING LIOUORS TRISODIUM PHOSPHATE UREA URINE VINEGAR WATER. ACID MINE WATER. DEIONIZED WATER, DEMINERALIZED WATER, DISTILLED WATER, FRESH WATER, SALT WHISKEY WHITE LIOUOR WINES ZINC CHLORIDE ZINC SULFATE ZINC NITRATE RECOMMENDED (@72”F) ANTHRAOUINONE ARYLSUFONlC ACID BUTYL ALCOHOL BUTYL PHENOL CELLOSOLVE CHLOROACETIC ACID CRESYLICACID, 50% CRUDE OIL ETHYL ALCOHOL FORMALDEHYDE FORMIC ACID GASOLINE HEPTANE HEXANOL. TERTIARY HYDROFLUORIC ACID. 46% LINOLEIC OIL LUBRICATING OIL, ASTM X3 METHYL SULFATE hlAPTU& NITRIC ACID. 10% NITRIC ACID. 30% NITRIC ACID, 60% PHENYLDHYDRAZINE HYDROCHLORIDE PHOSPHORUS (YELLOW) PHOSPHORUS PENTRIOXIDE POTASSIUM PERMANGANATE. 25% @ 125°F PROPARGYL ALCOHOL PROPYL ALCOHOL TETRAETHYLLEAD TRIETHANOLAMINE TRIMETHYL PROPANE .I . . .I. ETHYLENE DICHLORIDE ETHYLENE OXIDE FLUORINE. GAS FURFURAL HEXANE HYDROFLUORIC ACID. _. 0 IOZE ::aTuooNAEss METHYL CHLORIDE METHYLENE CHLORIDE METHYL ETHYL KETONE METHYL ISO-BUlYL KETONE NAPHTHALENE NITRIC ACID, ANHYDROUS NITRIC ACID. 68% NITROBENZENE OLEUM PALMITRIC ACID, 7090 PERACETIC ACID. 40% PERCHLORIC ACID, 15”. RECOMMENDEDPERCHLORICACID. 700. PHENYLrlYDRAZINE ACETALDEHYDE PHOSGENE. LIOUID ACETIC ACID. PURE PHOSPHORUS ACETIC ACID. 80% TRICHLORIDE ACETIC ACID. GLACIAL PICRICACID ACETIC ANHYDRIDE PROPYLENE ACETONE DICHLORIDE ALLYL ALCOHOL, 96% STODDARDS SOLVENT ALLYL CHLORIDE SULFUR DIOXIDE. (WET) AMMONIA (LIQUID) SULFURIC ACID. AMMONIUM FLUORIDE, 60% 25% 85% AMYL ACETATE 940. AMYL ALCOHOL 95% AMYLCHLORIDE TETRAHYDROFURANE ANILINE THIONYL CHLORIDE ANILINE TITANIUM CHLOROHYDRATE TETRACHLORIDE ANILINE TOLUOL OR TOLUENE HYDROCHLORIDE TRI BUTYL PHOSPHATE AQUA REGIA TRICWLOROETHYLENE AROMATIC TUHPENTINE HYDROCARBONS VINYL ACETATE BENZALDEHYDE. 10% XYLENE OR XYLOL BENZALDEHYDE.ABOVE ._. NOT I”% BENZENE BROMINE, LIOUID BROMINE WATER BUTADIENE BUTANE BUTANOL. PRIMARY BUTANOL.SECONDARY BUTYL ACETATE BUTYNE DIOL BUTYRIC ACID CARBON BISULFIDE CA.RI-mN TETRACHLORIDE CHLORINE (DRY) CHLORINE. GAS CHLORINE GAS (WET) CHLOROBENZENE CHLOROFORM CHROMIC ACID, 10% &l;g;c ACID, 50% _. __.. CROTONALDEHYDE CYCLOHEXANOL CYCLOHEXANONE DIMETHYLAMINE DIOCTYLPHTHALATE ESTERS ETHERS ETHYL ACETATE ETHYL ACRYLATE ETHYL CHLORIDE ETHYL ETHER ETHYLENE BROMIDE ETHYLENE CHLOROHYDRIN Synthetic Resins and Polymers TABLE 1.47: POLYVINYL CHLORIDE TANK LINERS-PEABODY TECLINE TL990 liners are suitable for the storage of which TECLINE TL990 liner will safely store includes: Acetic Acid (10%) Ammonium Hydroxide (30%) Ammonium Phosphate’ Ammonium Sulfate Antifreeze (Ethylene Glycol)’ Animal Oil’ Boric Acid Bromic Acid Calcium Chloride Solutions* Calcium Hydroxide Chlorine Solution (20%) Chromic Acid (10%) Clorox Crude Oil’ Diesel Fuel Ethyl Alcohol Fertilizer Solutions* FORAFLON@ variety of chemicals. l l l However, solutions. TECTANK Gasoline* Glycerine’ Hydraulic Fluid Hydrochloric Acid (60%) Hydrofluosilicic Acid (30%) Hydrogen Peroxide (30%) Isopropyl Alcohol Jet Fuel (JP-4)’ Kerosene Magnesium Chloride Magnesium Hydroxide Methyl Alcohol Mineral Spirits Naptha Nitric Acid Phenol Formaldehyde Phosphoric Acid (75%) l TABLE 1.48: POLYVINYLIDENE a wide 155 A partial guide to chemicals Potassium Chloride* Potassium Sulphate’ Salt Water* Sea Water’ Sodium Acetate Solution Sodium Bisulfite Solution Sodium Hydroxide (60%)’ Sulphuric Acid (40%) Tannic Acid (50%) Turpentine Urea* Zinc Chloride* ‘May be stored in Peabody TecTank’s TherrnoThane 7000, factorycoated bolted tanks. FLUORIDE-RILSAN in general resists mineral acids, bases, saline solutions, oxidizing agents, and halogens. it is attacked by concentrated hot sulphuric acid or nitric acid and very concentrated alkaline FORAFLON” resists alcohols, It swells in certain dimethylacetamide, chlorinated solvents, aliphatic and aromatic hydrocarbons and crude oil. polar solvents like ketones and esters and dissolves in aprotic solvents like dimethylformamide and N methylpyrrolidone. It is also attacked by hot amines. As an indication, the following table shows the good resistance in some particularly aggressive reagents. of FORAFLONQD immersed under stress Test pieces are cut according to ASTM D 1708 from an extruded plate 0.7 mm thick, and either unbent or bent by the device recommended in standard ASTM D 1693: the.y are immersed in a reagent at the temperature indicated. The tensile properties are checked periodically. For the reagents indicated, the yield strength of both bent and unbent test pieces varied by at least 10% after one year, as compared with that of a control left in the air at the same temperature. Reagents Concentrated hydrochloric acid, 36% Sulphuric acid 80% Nitric acid 32% Chromatosulphuric mixture (CrO3, 50%, H2SOq. 15%, H20, 35%) Acetrc acrd 50% Caustic soda 45% Sodium carbonate 40% Ethylene glycol, pure Perchloroethylene Crude 011 Temperature 130 :: 90 130 :: 90 130 90 90 130 “C 156 Corrosion Resistant Materials Handbook TABLE 1.49: TETRAFLUOROETHYLENE PARTIAL LIST OF CHEMICALS HOSE-EVERFLEX AND MATERIALS PRODUCTS COMPATIBLE WITH TEFLON HOSE “Teflon”@ TFE fluorocarbon resin is so broadly chemically resistant that factors such as temperature, pressure and their fluctuations are usually the primary influence on the serviceability of this material in a specific application. Solvents and gases known to require special consideration due to these factors are indicated by asterisk(*). Also, selection of material for fittings is influenced by reagent, concentration, duration of exposure and other considerations. For guidance only, our preliminary recommendations for coupling material are indicated by letter following the reagent, thus: (B) brass; (Cl carbon steel; (S) stainless steel; (M) monel. Teflon is attacked bv only two classes of chemiulr: al Molten alkali metals rueh as sodium 11 potassun bi Fluorahemicals rush as chlorine tnflwride ICIF, ._- I andoxggnn Synthetic Resins and Polymers TABLE 1.50: TETRAFLUOROETHYLENE Table I-Tvoical Abietic acid Acetic acid Acetic anhydride Acetone Acetophenone Acrylic anhydride Ally1 acetate Ally1 methacrylate Aluminum chloride Ammonia, liquid Ammonium chloride Aniline Benzonitrile Benzoyl chloride Benzyl alcohol Borax Boric acid Bromine n-Butyl amine Butyl acetate Butyl methacrylate Calcium chloride Carbon disulfide with TEFLON 2. Some conducted RESINS-DUPONT Chemicals with Which TEFLON Resins Are Comoatiblel Cetane Chlorine Chloroform Chlorosulfonic acid Chromic acid Cyclohexane Cyclohexanone Dibutyl phthalate Dibutyl sebacate Diethyl carbonate Dimethyl ether Dimethyl formamide Di-isobutyl adipate Dimethylformamide Dimethyl hydrazine, unsymmetrical Dioxane Ethyl acetate Ethyl alcohol Ethyl ether Ethyl hexoate Ethylene bromide Ethylene glycol 1. Based on expenmenls 157 up lo the bolllng Ferric chloride Ferric phosphate Fluoronaphthalene Fluoronitrobenzene Formaldehyde Formic acid Furane Gasoline Hexachloroethane Hexane Hydrazine Hydrochloric acid Hydrofluoric acid Hydrogen peroxide Lead Magnesium chloride Mercury Methyl ethyl ketone Methactylic acid Methanol Methyl methactylate Naphthalene Naphthols Nitric acid points of the liquids Itsted. Nitrobenzene 2-Nitro-butanol Nitromethane Nitrogen tetroxide P-Nitro-2-methyl propanol n-Octadecyl alcohol Oils, animal and vegetable Ozone Perchlorethylene Pentachlorobenzamide Perfluoroxylene Phenol Phosphoric acid Phosphorus pentachloride Phthalic acid Pinene Piperidene Polyacrylonitrile Potassium acetate Potassium hydroxide Potassium permanganate Pyridine Soap and detergents Sodium hydroxide Sodium hypochlorite Sodium peroxide Solvents, aliphatic and aromatic2 Stannous chloride Sulfur Sulfuric acid Tetrabromoethane Tetrachloroethylene Trichloroacetic acid Trichlorethylene Tricresyl phosphate Triethanolamine Vinyl methacrylate Water Xylene Zinc chloride Absence of a speclflc chemical does not mean that 11is lncompatlble resns. halogenated solvents may cause moderate swelling. Note Values are averages only and not for speckatlon purposes. Table II-Exposure of TEFLON Resins to Acids and Bases. Exposure Exp”,s;re Weight Increp& Reagent Temp., “C (F) Hydrochloricacid 10% 25 (77) 12 mo. 0 50 (122) 70 (158) 100 (212) 200 (392) 12 mo. 8 hr. 8 hr. : 0 0 25 (77) 70 (158) 12 mo. 12 mo. E.1 20% Nitric acid Sulfuric 10% acid Sodium hydroxide 30% 25 70 (158) (77) 100 (212) 200 (392) 12 mo. 8 hr. 8 hr. : 0 0.1 10% 25 (77) 70 (158) 100 (212) 12 mo. 12 mo. 8 hr. 0 0.1 0 25 (77) 70 (158) 12 mo. 12 mo. 0 0.1 50% Ammonium hydroxide 10% (continued) 158 Corrosion Resistant Materials Handbook TABLE 1.50: TETRAFLUOROETHYLENE RESINS-DU PONT (continued) Table Ill-Exposure of TEFLON Resins to Solvents. Exposure $rng;; Exyzre InCZF, Solvent Acetone 25 (77) 50 (122) 70 (158) 12 mo. 12 mo. 2 wk. 0.30 0.4 0 Benzene 78 (172) loo (212) 200 (392) 96 hr. 8 hr. 8 hr. 0.5 0.6 1.0 Carbon tetrachloride 25 50 70 loo 200 (77) (122) (158) (212) (392) 12 mo. 12 mo. 2 wk. 8 hr. 8 hr. 0.6 1.6 25 50 70 loo (77) (122) (158) (212) 0 0 0 200(392) 12 mo. 12 mo. 2 wk. 8 hr. 8 hr. Ethyl acetate 25 (77) 50 (122) 70 (158) 12 mo. 12 mo. 2 wk. 0.5 0.70 0.7 Toluene 25 (77) 50 (122) 70 (158) 12 mo. 12 mo. 2 wk. 0.3 0.6 0.6 Ethyl alcohol (95%) Table IV-Absorption of Representative fluorocarbon resins(l) ::95 3.7 Table II and Table Ill Notes: Many of the laboratory evaluations were run at the boiling point of the chemicals listed. This should not be considered the upper use temperature for TEFLON resins in such environments, which can be considerably higher. l These are essentially equilibrium test values: additional exposure times would not increase the values significantly. l Weight changes less than 0.2% are not considered to be experimentally significant. l Values are test averages only and are not for specification purpfxes. l Tests at over the boiling point of the reagent were in an enclosed chamber, hence at its vapor pressure. l 0.1 0.3 Liquids In TEFLON@160 FEP and TEFLON@350 PFA 168 Hour Exposures to Solvents’at Their Boiling Pointsm Range of Temperature Weight Gains “C “F % __ 185 (365) 0.3-0.4 Aniline 201 (394) 0.6-0.8 Acetophenone 179 (354) 0.4-0.5 Benzaldehyde 204 (400) 0.3-0.4 Benzyl Alcohol 78 (172) 0.3-0.4 n-Butyl Amine 78 (172) 2.3-2.4 Carbon Tetrachloride 190 (372) 0.1-0.2 Dimethyl Sulfoxide 1.2(3) 47 (117) Freon@113 99 (210) 0.7-0.8 Iso-Octane 210 (410) 0.7-0.9 Nitrobenzene 121 (250) 2.0-2.3 Perchloroethylene 68 (154) 1.7-2.7 Sulfuryl Chloride 110 (230) 0.7-0.8 Toluene 200(‘)(392) 1.8-2.0 Tri-Butyl Phosphate 166 Hour Exposure to Acidic Reagent Temperature “C “F Bromine (anhyd.) Chlorine (anhyd.) Chlorsulfonic Acid Chromic Acid, 50% Ferric Chloride, 25% Hydrochloric Acid, 37% Phosphoric Acid (Cone) Zinc Chloride, 25% 22 120 150 120 100 120 100 100 (-5) (248) (302) (248) (212) (248) (212) (212) Range of Weight Gains % 0.5(3' 0.5-0.6 0.7-0.8 0.00-0.01 0.00-0.01 0.00-0.03 0.00-0.01 0.00-0.03 Table IV Notes: (1) No significant differences between FEP and PFA resins in these tests. (2) These are essentially equilibrium values; additional exposure times would not increase the values significantly. (3) PFA data only. (4) Not boiling. (5) Values are test averages only and are not for specification purposes. TABLE 1.51: VINYL ESTER RESINS-INTERPLASTIC CORP. Chemical Resistance Co-Rezyn’3 Vinyl Ester Resins* Maximum Concentratlor Chemical % by Weigh A 1 1 \IE 8100 t \IE 8300 Recommended Temperature Concentration VE 8440 Acataldehyde All NR NR Acetlc Acid O-25 210 210 VE 8710 VE 8520 NR 210 25-50 180 180 210 50-75 150 150 180 150 150 Acetlc Anhydrlde All NR NR NR ACetOm 100 NR NR NR Acrylic Acid AcfyIonltrlle Alcohd. Alcohol, Butyt 25 100 100 100 All NR NR NR All Ethyl 10 100 Alcohol, Alcohol, teopropyl Methyl Atcohol, Methyl lrobutyl Alcohol, Secondary Sutyl 100 156 SO Maximum OF 160 150 SO % by Weigh Chemical 100 10 156 150 150 100 100 100 120 t50 10 150 150 100 NR NR 10 150 150 150 150 10 150 150 150 150 150 NR Ally1 Chloride All NR NR NR NR Alum All 210 210 220 210 Aluminum Chloride All 210 210 210 210 Aluminum Fluorlde All 80 80 80 80 VE 8300 VE 8440 VE 8710 VE 8520 Slcarbonate O-50 150 150 150 150 Ammonium Slsultlte All 150 150 150 150 Ammonium Carbonate All 150 150 150 150 Ammonium Chlorlda All 210 210 210 210 Ammonium Citrate All 150 150 150 150 Ammonium Fluoride All 150 150 150 150 Ammonium Hydroxlda NR 150 Temperature Ammonium 120 150 Recommended VE 8100 5 180 180 180 150 IO 150 150 180 150 20 150 150 180 150 29 100 100 150 100 Ammonium Nitrate All 180 180 180 180 Ammonium Persulfate All 180 180 180 180 Ammonium Phosphate 65 210 210 210 210 Ammonium Sulfate All 210 210 210 210 Amyl Acetate 100 NR NR NR NR Anlllne All NR NR NR NR All 150 150 180 150 210 Anlllne Hydrochloride Anlllne Sulfate Arsenlous Acid All 210 210 210 All 180 180 180 0 0-Benroyl Benzolc Acid All 780 180 180 Acetate All Aluminum Hydroxtde All 180 180 200 150 Barium 210 210 210 210 Aluminum Nltrate All 160 160 180 150 Earlurn Carbonate All 210 210 210 210 Chloride All 210 210 210 210 O-IQ 150 150 180 15r All 210 210 220 210 O-20 140 140 140 140 Sarlum Hydroxlda 180 100 Barium Sulfate All 210 210 210 210 NR NR Earlum Sulfide All 180 180 180 180 Atumlnum Poteulum Ammonia. Aqueous Ammonia, Gas 100 100 Ammonia, Ltquld NR NR 80 60 60 Ammonium Acetate Sulfate Barlom 65 Seer 120 (continued) OF TABLE 1.51: VINYL ESTER RESINS-INTERPLASTIC CORP. (continued) Maximum Recommended Temperature OF Concentratio % by Weigh Chemical senrene 100 in Kerosene 5% Benzene Benzene Sullonic Acid All VE 0300 NR VE8440 VE 8710 210 210 210 210 210 210 210 NR All 210 210 Benzyl Alcohol 100 NR NR 1.90 Benzyl Chloride 100 NR 3% 6% 1% 3% 325 180 Solution: NR NR 32.5 180 350 180 Copper CyanMe Sodium Cyanide Zinc CyanIda Sod& Carbonate Sromlne, Llquld 5 Bronze Plating 4% 5% 3% 4.5% NR NR 210 Bcnzolc Acid Brass PIstIng VE 8520 NR 210 Black Liquor Recovery, (hrrnace gasses) Solution: NR NR NR 180 180 190 180 180 190 NR Copper Cyanlde Sodium Cyanide Sodlunl carbonate Rochelle Salta Bulyl Acetate 100 NR NR NR Sutyrlc O-50 210 210 210 Acid I Concentratio VE 8100 100 NR Chemical Csdmlum Cysnlde Plrtlng 3% Cadmium Oxide 10% Sodium Cyanide 1% Caustic Soda Phthslate Butyl Carbltol 100 100 Sutyl Cellosolve 100 Eutylene 100 Glycol 150 160 160 Chorlde All 180 180 8440 VE 8710 9 180 180 200 180 180 180 180 All Csiclum Carbonate All 180 180 180 180 Calcium Chlorate All 210 210 210 210 Calcium Chloride All 210 210 210 210 Calcium Hydroxtde All 180 180 210 180 Cslclum Hypochlorlte All 160 180 180 160 Calcium Nltrate All 210 210 210 210 Calcium Sulfate All 210 210 210 210 Calcium Sulfite All 180 180 180 180 Cane Sugar Llqwr All 180 180 180 180 Capylic Acid 100 Carbon Dloxlde Carbon Dlsulflda NR NR NR NR Carbon Monoxide 210 210 240 210 100 100 150 150 150 150 Carbon Tetrachlorlde Carbon Acid 100 180 180 210 180 210 210 240 210 Carbowsx 100 100 100 Castor 210 210 210 210 150 150 150 150 011 Methyl Cellulose 100 Chlorinated (caustic Brine Liquors chlorine cell) 10 100 Chlorinated Wax 180 Chlorine DIoxIdelAIr Chlorine Dloxlde, 180 180 Wet Gas s VE 8520 150 c Cadmium VE Blsulflte 100 150 Sotn.: IE 8300 Calcium Carboxy Sutyl Senzyl % by Weigh Maximum Recommended Temperature OF IE 8100 190 All 180 180 180 15 200 200 200 Satd. 160 180 180 180 180 Chlorlne, Dry Gas 100 210 210 210 210 Chlorine. Wet Gas 100 210 210 210 210 Chlorine, Llquld NR NR NR NR (continued) TABLE 1.51: VINYL ESTER RESINS-INTERPLASTIC CORP. (continued) Maximum Recommended Temperature “F Concentratio % by Weigh Chemical Chlorine Wsbr Chioroecetk Acid Maximum Concentratio fE 8100 fE 8300 VE 8440 VE 8710 All 160 180 190 25 120 120 120 VE 8520 Chemical % by Weigh Copper Pickling Bath: 10% Ferrk Sulfate 10% Sulturlc Acid Recommended Temperature IE 8100 IE 8300 VE 8440 VE 8710 200 200 200 210 210 210 210 210 210 210 210 VE 8520 50 100 100 100 Con. NR NR NR NR Corn Oil Chlorobenxene 100 NR NR 100 NR Corn Starch Slurry 210 210 210 210 Chloroform 100 NR NR NR NR Corn Sugar All 210 210 210 210 100 NR NR NR NR Chloraulfonk Acid copper sunate Chromic Acid Chromium Cltrlc SuMate Acid Coconut 20 150 150 Cottonseed Cresyllc 140 Chrome PIstIng 60th: 19% Chromic Acid Sodium Fluoroslllcats Sulfate Oil Acid 100 210 210 210 210 210 210 210 210 Cyclohexene 100 120 120 120 Cyclohexenone 100 100 100 120 All 210 210 210 150 NR NR NR 140 All 150 150 190 All 210 210 210 210 D 210 210 210 210 Detergents, Sultonated 210 210 210 210 Diallyl 210 210 210 210 Di-Ammonium Copper All 210 210 210 210 copper Plating Sokls. Copper Cyenlde 10.5% CopPer 14% Sodium Cyenlde 6% Rochelh Bells Copper Brlts Plellng Csustlc-cyenlde Copper Plating Boln. 45% Copper nuoroborate 19% copper Sulfate 8% Sulturk Acid Copper Matte Dlpplng Beth: 30% Ferric Chloride 19% Hydrochloric All 210 210 210 160 150 190 210 phthalate All 150 150 190 65 210 210 210 210 Dlbromophenol 100 NR NR NR NR Dibutyl 100 100 100 150 160 160 160 190 Benzene Dichloroethylene 160 100 NR NR 120 NR 100 NR NR NR NR Dichloromonomethsne 100 NR NR NR NR Dichloropropane 100 NR NR NR NR Dlchloropropene 100 NR NR NR NR Diesel 100 160 160 200 160 Fuel 200 DIethanoI 160 Phosphate Ether Dlchloro 160 NR 100 All Nitrate 210 NR 011, Sour All Copper 210 NR 011, Sweet Chloride Fluoride 210 NR Crude CopperCyanide Copper 210 100 Crude 30 011 All 200 Amine 100 60 60 120 100 NR NR NR 60 60 100 NR NR NR Dlethyl Amlne Diethyl Benzene 100 Dlethyl Carbonate 100 NR NR (continued) OF TABLE 1.51: VINYL ESTER RESINS-INTERPLASTIC Maximum 1 CORP. (continued) Recommended Temperature OF Maxlmum Concentration 1 \IE 8100 Chemical Oiethytane Glycol % by Weigh t 100 Concentratio \{E 8300 VE 8440 VE 8710 150 150 200 120 120 150 Diethylhexyl Phosphoric Acid (in Kerosene) 20 Diethyl Sulfate 100 NR NR Diisobutylene 100 100 100 150 Oiisobutyl Phthalata 100 100 100 150 Dllsopropanol Amlne 100 100 100 150 Dlmethyl FormamIde 100 NR NR NR Olmethyl Morpbollne 100 NR 100 150 150 180 100 150 150 150 Dlpropylene Glycol 100 150 150 150 DMA 4 Weed Killer 2,4D 100 120 DMA 6 Weed Killer 100 120 150 150 % by Wefgt VE 8300 VE 8440 VE 8710 VE 8520 100 EthyleneGlyeolMor&utyiEttw All Ethyl Sulfate 100 80 80 100 F NR NR NR Dioctyl Phthalate 100 120 Chemical Temperature NR Dimethyl Phthelate Dodecyl Alcohol VE 8520 Recommended WE 8100 180 Fatty Acids All 210 210 210 Ferric Chloride All 210 210 210 210 Ferric Nitrate All 210 210 210 210 Ferric Sullate All 210 210 210 210 210 Ferrous Chloride All 210 210 210 210 Ferrous Nltrate All 210 210 210 210 Ferrous Sulfate All 210 210 210 210 8-8-8 Fertllirer 120 120 120 FertillzerUrea Ammonium Nitrate 120 120 120 E 5 150 150 150 150 Flue Gas 340 340 340 Epichlorohydrin 100 NR NR NR NR Fluoborlc Acid All 180 180 210 180 Epoxidlzed Soybean 011 100 150 150 150 150 FluosillclcAcid 10 210 210 210 210 Esters, Fatty AcIda 100 180 180 180 20 180 180 180 180 Ethyl Acetate 100 NR NR NR NR Formaldehyde All 150 150 15c Ethyl Acrylate 100 NR NR NR NR Formic Acid 10 180 180 180 180 Ethyl Benzene 100 NR NR All 100 100 100 100 Ethyl Sromlde 100 NR NR NR NR Freon 11 100 100 100 Ethyl Chloride 100 NR NR NR NR Fuel Oil 180 180 180 NR NR NR Furfural Electrosol Ethyl Ether 100 Ethylene Chlorohydrln 100 Ethylene Glycol All NR NR 100 210 210 210 210 100 5 120 120 150 10 100 100 120 100 NR NR NR NR (continued) OF TABLE 1.51: VINYL ESTER RESINS-INTERPLASTIC Maximum Concentratio Chemical % by Weigh CORP. (continued) Recommended Temperature Maximum OF VE 8100 VE 8300 Concentration VE 8440 VE 8710 VE 8520; G Chemical 200 100 200 O-20 20-37 30 210 190 190 210 190 190 210 180 190 210 180 Hydrocysnlc Acid All 180 150 180 190 Hydtolluwlc Acid 10 150 150 150 150 20 100 100 100 100 10 180 190 190 190 190 190 Gasoline, Auto 190 180 190 Hydrochloric Acid Hydrochloric Acid saturated wlth Chlorine gse Gssollne, Sour 150 190 190 190 180 190 190 210 Gluconk ACM 50 150 190 190 150 Glucoee All 210 210 210 210 Gluteraldehydc SO 120 120 120 HydrotluoslllclcAcid Gluterk Acid 50 120 120 120 Glycertne All 210 210 210 Glycol. Ethylene Glycol, Propylene Glycollc Acid All All 210 210 210 210 210 210 10 190 150 200 70 80 90 100 Hydrogen Sromlde, Wet Gas 100 160 190 Hydrogen Chlortde, Dry Gas 100 210 210 210 210 210 210 210 210 210 Hydrogen Chlortde, Wet Gas 100 Hydrogen Peroxlde O-30 150 150 150 150 Hydrogen Sulflde, dry All 210 210 210 210 Hydrogen Sulfide, Aqueour All 210 210 210 210 190 190 190 190 210 210 Hydrogen Fluorlde, Vapor Glyoxal 40 90 80 80 190 190 180 190 190 150 180 10 190 150 100 150 20 150 150 150 150 PtathIg Solutton: 45%FeCl : 15%CeCl 20FeSO,:ll%(NH,),SO~ 190 180 180 Iron end Steel Clesnlng Seth: 9% Hydrochlork 23% Sulturk 190 180 190 Hydroeultlte Bleach Gold Plating Solution: 63% Potserlum Ferrocysnlde 2% Potarrlum Gold Cysnlde .8% Sodium Cyantda 190 Hypochlorous Acid H troll HOptllll~ 150 150 150 150 liexane i50 150 150 150 Hexylene Glycol 150 150 150 150 Hot Stack Gerres 340 340 340 Hydraulk Fluld 210 210 210 Hydrerlna NR NR NR “F VE 8520 180 210 190 VE 0710 100 210 150 VE 8440 180 210 180 1IE 8300 O-25 Gas.Natural Gssollne, Ethyl Temperature 25-50 Hydrobromlc Acid Gsrollne, Avletlon % by Weight Recommended IIE 8100 210 isopropyl Amlno All 100 100 120 NR lropropyl Palmltate 100 210 210 210 210 (continued) z TABLE 1.51: VINYL ESTER RESINS-INTERPLASTIC Maximum Concentration % by Weigh1 Chemical CORP. Recommended (continued) Temperature fE 8300 VE 8440 VE 8710 VE 8520 Chemical Mercuric 180 Jet Fuel 180 180 K 180 KeImene 180 180 180 L Lactic Acid All Lasso (50% Chlorobenzone) 100 NR NR NR NR lsobutyl Carbltol 100 NR NR NR NR Methyl Isobutyl Ketone 100 NR NR NR NR Styrene 100 NR NR NR NR 210 210 Monochloro Dlsulflde Acetlc 210 210 210 210 Motor 011 All 210 210 210 210 Myrlstlc 180 180 IS0 210 210 210 210 210 210 210 210 210 210 210 210 All All All 210 210 210 210 210 210 100 200 200 200 100 NR NR NR NR 100 NR NR NR NR Ollr Molybdenum Acid 210 210 210 210 100 210 210 210 210 Naphtha 100 180 180 180 120 Naphthelene 100 180 180 200 180 Nickel Chloride All 210 210 210 210 Nickel Nltrate All 210 210 210 210 Nickel Platlno 8% Lead .S% fluoborlc Acid .4% Sorlc Acid 180 180 180 180 Nickel Plating 11% Nickel Sulfate 2% Nickel Chloride 1% Sorlc Acid 180 180 180 180 Nickel PLetlng 44% Nickel Sulfate 4% Ammonium Chloride 4% Sorlc Acid Nickel Sulfate 180 180 180 180 210 210 210 Acid N 210 M Magnesium Slrulflte All 180 IS0 180 180 Magnesium Carbonate All 180 180 180 180 Magnesium Chloride All 210 210 210 210 Magneelum Hydroxide All 210 210 210 210 Magnesium Sultate All 210 210 210 210 All 210 210 210 210 Acid Ethyl Ketone Methyl All Linseed 011 Sulfate Methyl 210 Lead Pletlng Solution: 6% Lead .8% fluorborlc Acid .4% Boric Acid Lithium Bromide xI( 210 Lead NItrate LevullnlcAcid 210 210 Lead Acetate 210 NR 210 Ail 210 210 Monoethynolamlne Laurie Acid 210 NR Mineral 120 210 210 NR 210 All NR 120 210 VE 8520 210 NR 120 VE 8710 All Ntt 120 VE 8440 100 210 210 IE 8300 Chloride 210 All % by Weigh1 Chloride 210 100 Temperature Methylene 210 Laura1Chtorlde Chloride Recommended fE 8100 Marcurous Methyl titex Malelc Maximum Concentration J Llthlum OF ilE 8100 All 210 (continued) OF TABLE 1.51: VINYL ESTER RESINS-INTERPLASTIC Maximum Temperature % by Weigh1 I \i‘E 8300 VE 8440 VE 8710 150 150 150 150 Phthallc Pickling Acids, Sulfurlc and tiydrochlorlc Concentratior VE 8520 20 120 120 140 120 52 NR NR 120 NR Nitric Acid Fumes 160 NR 160 NR 160 NR % by Weighi All Acid 160 160 160 100 160 160 210 160 Oil, Sour Crude 100 210 210 210 210 Oil, Sweet Crude 100 210 210 210 210 Oleic Acid All 210 210 210 210 NR NR NR NR Oleum (Fuming Sulfuric) Olive 011 100 210 210 210 210 Oxalic Acid All 210 210 210 210 P Perchlorathylene Acid Phorphorlc Acid Acid 210 210 210 210 210 210 210 210 210 210 210 210 210 210 Polyvinyl Acetate All 210 210 Polyvinyl Alcohol 100 120 120 120 120 120 120 120 120 All 210 210 220 210 O-50 150 150 150 150 210 210 Latex Potassium Alum Sulfate Potassium Blcsrbonate Potssslum Bromide All 210 210 Potassium Carbonate All 150 150 150 150 Potassium Chlorlde All 210 210 210 210 Potassium Dlchromate All 210 210 210 210 Potassium Ferricyanlde All 210 210 210 210 Potassium Ferrocyanlde All 210 210 210 210 Polarslum Hydroxlda All 150 150 150 150 Potassium Nltrate All 210 210 210 210 100 100 100 Potassium Permanganate All 210 210 210 210 10 150 150 150 150 Potasrlum PersuIfa1e All 210 210 210 210 30 100 100 100 100 Potassium Sulfate All 210 210 210 210 210 210 PropIonIc 20 200 200 200 200 60 160 160 160 160 210 NR 210 NR NR NR Propylene Acid Gtycol 100 NR NR NR NR Pulp Paper Mill Effluent All 210 210 210 210 Pyrldlne 210 210 220 210 PentoxIde o-54 210 210 210 210 R Phosphorous Trlchlorlde 100 NR NR NR NR Rayon Spln Bath Acid VE 8520 10 Phosphorous Phosphoric VE 8710 100 100 Phenol Sulfonlc VE 8440 100 Peroxide Bleach 2% Sodium Peroxlde g6% .025% Epson? Salt& 5% Sodium Sillcrfe, 42’BE 1.4% Sulhirlc Acid, 86’Be Phenol VE 8300 NR 160 Acid Temperature Picrlc Acid, Alcoholic Polyvinyl Chloride Latex with 35 parts DOP Oaklte Rust Stripper Perchlorlc Chemical Recommended VE 8100 160 0 Oclanoic Maximum OF v‘E 8100 5 Nitric Acid 1 Recommended I Concentration Chemical CORP. (continued) Fumes 100 NR NR NR NR All 210 210 210 210 160 160 160 NR NR NR 150 150 150 100 NR (continued) QF TABLE 1.51: VINYL ESTER RESINS-INTERPLASTIC Maximum Concentration Chemical % by Weigh CORP. (continued) Recommended Temperature Acid All Maximum rlE 8300 Concentration VE 8440 VE 8710 VE 8520 S Selkylk “F WE8100 160 160 160 Chemical Recommended Temperature 1IE 8100 % by Weigh IIE 8300 VE 8440 VE 8710 VE 8520 Sodium U-Phosphate All 210 210 210 210 160 Sodium Ferrkyanlde All 210 210 210 210 Ferrocyanlde All 210 210 210 210 Seback Acid All 210 210 210 210 Sodium Selenlus Acid All 210 210 210 210 Sodium Fluoride All 180 180 180 180 210 Sodium Fluoro Silicate All 150 150 130 150 Sodium Hexametaphosphetes All 120 120 120 120 Sodium Hydroxide 5 180 180 200 160 150 Silver Nltrete All Sllvar Plating Solution 4% Silver Cvsnlda 7% Potas&m Cyanide 5% Sodlum Cyenlde 2% Potassium Cerbonete 210 210 210 200 200 200 10 150 150 200 25 130 130 200 120 180 200 180 50 All 210 Sodium Acetate All 210 210 210 210 Sodium Hypochlorlte o-5 Sodium Alumlnete All 120 120 120 120 Sodium liypochlorlte 5-15 Sodium Alkyl Afyl Sulkmates All 150 150 150 150 Sodium Lwryl All S&urn Benmate 100 160 180 210 180 Sodium Mono-Phosphate Sodium Skarbonste All 160 160 160 180 Sodium Nltrate Sodium Bllluorlde All 120 120 120 120 Sodium Sodium Elsulfata All 210 210 210 210 Sodium 210 Sodium Sodium -eP* 210 210 Sodium 180 210 210 210 180 180 180 160 130 150 150 130 180 180 180 180 All 210 210 210 210 All 210 210 210 210 Nltrlte All 210 210 210 210 Persulfate 20 130 130 130 130 Silkate All 210 210 210 210 Sulfate All 210 210 210 210 Hydrosulflde Sullste All 210 Sodium Slsulflta All 210 210 210 Sodium Bromste 10 210 210 210 Sodium Sromlde All 210 210 210 Sodium Sulfide All 210 210 210 210 So&urn Co&mete o-25 160 160 180 Sodium Sulllte All 210 210 210 ‘210 35 160 160 180 Sodium Tetra Borate All 200 200 200 200 210 210 180 180 160 180 180 180 Sodium Chlorate All 210 Sodium Chloride All 210 210 Sodium Chlorite All 150 150 Sodium Chromate 50 210 210 Sodium Cyenlde All 210 210 Sodium Dlchromete All 210 210 210 210 210 Sodium Thlocyenste 37 210 210 Sodium Thlosulfste All 180 180 210 150 Sodium Trlpolypho8phste All 210 210 210 210 210 210 Sodium Xylene Sullonate All 210 210 210 210 210 210 Sorbltol Solutlonr, All 150 150 150 130 210 Sour Crude 011 100 210 210 210 210 (continued) OF TABLE 1.51: VINYL ESTER RESINS-INTERPLASTIC Maximum soya Chloride Slsnnous Slasrk Chloride Acid Temperature OF Maximum VE 8440 VE 8710 VE 8520 All 210 210 210 210 Thioglycolic All 210 210 210 210 Thionyl All 210 210 210 210 All 210 210 210 210 Tin Plating 16% Stannous Fluoroborate 7% Till 9% Fluorborlc Acid 2% Boric Acid % by Weigl 1t Oil Stannk Recommended 1VE 8100 ’b’E 8300 Concentratia n Chemical CORP. (continued) t Chemical Acid Chloride StyWe 100 NR NR succlommltrlle Ail 100 100 Sugar, Bee1 and Cane Liquor All 160 160 160 160 Toluene Sugar, sucrose All 210 210 210 210 O-26 210 210 210 210 Transformer Oils: Mineral 011 Types Chloro-Phenyl Types All 210 210 210 210 Trichlor All 210 210 210 210 210 210 210 All 210 210 210 210 O-50 210 210 210 160 SO-70 160 160 160 160 75 120 120 120 Over 75 NR NR NR Sullamk SultanIlk Acid Acid S&sled Detergents Sulfur Dloxlde, Dry or Wet Sulfur Trloxlde/Alr Sulturlc ACM Sulfurous Acid SuperphosphorIc 76% Pz 0, Acid NR 100 All 100 100 100 105% H, PO, 210 210 210 Tolusne Solfonlc Acetlc Acid Acid % by Weigl WE 8300 Recommended VE 8440 VE 8710 100 100 100 NR NR NR 200 200 200 100 NR NR 100 NR All 210 210 210 210 210 NR 210 NR 210 NR 210 NR 210 210 210 210 NR NR NR 100 50 100 100 60 60 Trlchlorophenol 100 NR NR NR 100 100 120 All 210 210 210 100 120 120 120 Sullonate Trlethanolamlne NR 100 Trlchloromonofluoro-Methane Phosphate NR NR 210 100 NR NR NR NR All 210 210 210 210 Turpentine 100 100 100 150 Tween’ All 150 150 150 O-50 150 150 210 210 210 210 Trlsodlum Chlorobromlde Phosphate Surfactant OF VE 8520 10 100 Trkresyl Temperature 100 Trlchloroethylene Trimethylene 210 VE 8100 Trkhloroethane Tridecylbenzane NR Concentratia 150 T Tall Oil 160 150 150 Tsnnk Acid All 100 100 100 Tartsrk Acid All 210 210 210 Tetrschlorosthylene 100 60 60 100 Tetrasodlum EthylensDlemlns All 120 120 120 U 210 Urea V Vegetable Textone’- 50% Aqusous Sodium Chlorete 210 210 210 Vhwgar 011s 210 210 (continued) 5 TABLE 1.51: VINYL ESTER RESINS-INTERPLASTIC CORP. (continued) *Co-Rezyn” Maximum ‘ES100 % by Weight ‘EE300 VE 8440 NR NR Vinyl Acetate 100 Toluena 100 Temperature 60 60 VE8710 VE8520 NR NR 60 lor filament physlcal hand winding lay-up levels, and custom remforced Co-Rezyna fabricated plastic tanks, 210 210 210 210 and Demineralized 210 210 210 210 This resin properties Dlstlllcd 210 210 210 210 Fresh 210 210 210 210 210 210 210 210 210 210 210 210 160 160 dary Sea Used excess Liquor (Pulp HI) demonstrates which makes Catalyst chemical or crarlng This excellent adheswe for reliable secon- wmdlng lay-up SMC match Pullruslon Tank linmgs Coatmgs has a v~scoslty melal lay-up die molding of 500 cps and CO”- 100 NR NA 100 NR properties as VE 6300. Cenlrlfuaal resistance reswance, Used of VE 6710. as an Altalns example. chlorobenrene Although a tough sacrlflce I” this stablll(y. excephonal good IS un- at amblent rest” there IS property versus Vmyl Other Esters uses’ to add addItIonal toughness. Coatmgs Tank lmmgs for. Primers casting Adheswes Co-Rezyn@ MVR-Modified L Zinc Chlorate All 210 210 210 210 Zinc All 210 210 210 210 I60 160 160 Nitrate 21°C Plating Solutlo”: 9% Zinc Cyanide 4% Sodium 9% So&urn MVR 6000 - Good where the optimum MVR 6040 spread conoslon - Fire of IeSs than resistance vinyl ester retardant. resin and physical properties brominated 25 per ASTM Vinyl Ester Resins Modilied E 64 “Tunnel properties. Hydroxide A” ecOnomlc are nof required. Vinyl Test”. choice - No” fire retardant. Ester Resm with a flame used with 3% antmony when trioxlde. DOeS not slfsl” the optimum physical proprrttrs associsled with the Vmyl Ester Resm. VE 6440 Cyanfde and corrosion resistance MVR 6050 - Fire retardant. brominated Modlfled Vinyl Ester with a flame spread rate of less then 25. per ASTM E 64 “Tunnel Test”, when used wlth 3% antimony PMng 21°C solutto”: 49% Zinc fluoborat* 6% Ammonium Chloride 6% Ammonium Ftuoroborate !OO 200 trloxlde An economic propertles are required 200 the ASTM resfstance 21°C Sulfate choice where superior corrosion resistance and over fire relardanl lsophthallc polyester resins MVR 6060 - Ffre retardant require the use of SntlmOny All ‘IO 210 210 210 E 64 “Tunnel and physical Test” VE m~nlmlze crackmg or crazmg due to thermal or mechanlcal shock and physlcal abuse. Relalns very good chemical reslstance. Is 100% compatible wth the other Co-Rezyn@ t Xylane causllc the VE 6520 An extremely tough epoxy based vinyl ester havmg 20% elongation This IS a non-rubber resin, developed for SPI Lmer appltcallons to VE 6100 A lower cham length version of VE 6300 havmg lower lnlrmsic and ewdent ~1stc0s111e.5. llsco?.lty Contains 50% styrene wlh a nommal of 100 cps. HSS eSSentlSlly the Sam e cured X hydrolytic by 6300 lams 45% styrene. 160 and demonstrated solvent some and spray reslstance density rest” than VE 6300 dIstortion and exceprlonal resistance IS affected by temperatures OperStlOnS. Filament Hand VE 8300 Whfte VE 6710 A higher cross ilnk giving hlgher heat be fabricated cracking and corrosion materials. as values warping. bonding I”: wlthout properlles I” a Vinyl Ester resm Lower halogen content and cost than VE 6400 and same competitive pipe, Outstanding propertles VE 6300 can mlo thick sections All Resins VE 6440 The fire reslstanl brommated counterpart 01 Ve 6300. When used with 3% antlmonv InoxIde. has a flame spread rate of less than 25 per ASTM E 64 “Tunnel Test”. Excellent and process equipment. toughness and fatigue W satt Ester The most versatile of all Ihe vinyl esters with excellent corrowon resistance from acids lo alkalies and oxldlzmg chemicals The m0S.t wdely used rest” of the family of vinyl esters demonstrated by high cycle pressure on lhin wall filament wound pipe. By suitable control of promoter - water Defonlzed Vinyl OF VE 6300 Concentration Chemical Vinyl Recommended bromfnated Modlfled Vlnyl Ester trloxlde or other flame retardant rstlng propertles of less than 25 Only a small from the unmodified vlnyl physical not resin which does chemicals lo achieve sacrifice ester of chemical VE 6400. (continued) TABLE 1.51: VINYL ESTER RESINS-INTERPLASTIC CORP. (continued) Chemical Concentration % bv Weight Chemical Acetic Add O-25 MVR 8000 Resistance Co-Rezynr Maxlmum Temperature MVR 8040 MVR 8050 MVR 8060 170 150 !70 170 200 50 150 150 180 100 NR NR NR NR MVR Reslns Chemlcel Glycol, Ethylrne Alcohol, Alcohol, Ethyl Methyl 100 80 10 150 60 150 80 150 NR NR .NR NR 10 150 150 150 150 Ammonls, Aqueous Ammonla, Oar Ammonia, Llquld All 170 170 170 210 o-20 140 140 80 140 100 100 100 100 NR NR NR NR 200 200 200 150 150 150 180 150 180 210 150 150 120 180 10 20 150 100 150 150 150 100 100 100 All 200 200 200 200 Jot Fuel 180 180 180 180 KerrnOn* 180 180 180 180 Hydrolluorlc Add Suttlde 180 180 180 180 5 20 150 120 150 150 120 120 100 50 60 80 NR 120 NR Naphtha NR Nltrlc Ammonium Carbonate Ammonium Hydroxide Senzene SrllN Sromln., Calcium All 150 120 Acid 150 O-20 29 150 100 150 80 100 80 150 100 011, sour 200 200 200 210 100 NR NR NR NR 011, Sweet 200 200 200 210 200 200 170 210 All Ltquld Carbonate 150 All 200 200 200 210 Phorphorlc NR NR NR NR Plckllnp A&b, Sulfudc 6 Hydrochloric 170 170 170 180 Potsulum Cslclum SuItate Chlorine Qar, Wet or Dry Acid Hydroxide 200 170 210 150 150 150 120 120 120 100 200 200 210 100 180 180 180 210 Sodium Carbonate o-25 180 180 120 150 NR NR NR NR Sodium Hydroxldo O-10 140 140 NR 160 10-25 120 120 NR 140 50 180 180 NR 180 o-15 150 150 NR 150 Chlorine Dloxlde All 150 150 100 180 Chlortna Water Ail 180 180 180 180 Sodium Chromic Acid 20 150 150 NR 150 Sultur Dioxide, All 120 120 80 120 Ethylene Glycol Atl 180 180 180 210 Fluailicic Acid 10 200 200 80 200 180 180 180 Avletlon 180 180 180 180 180 Ethyl 180 180 180 180 Auto 200 10 25 200 Ltquld Gasoline, All All Chtorlna, Cycloh*xane 210 150 Acid Hydrogen Alum All MVR 8060 All Hydrochloric 80 150 100 MVR 8000 O-20 20-37 H9X4M ACetOll* Maximum Temperature MVR 8040 MVR 8050 Concentration % by Weight Hypochlorlte Dry or Wet Sultur Trloxlds/Alr Sulturlc Acid Toluene Water, Dlrtlllcd or Sea 150 All 200 200 170 210 Alt 200 200 170 210 O-50 50-70 200 200 160 150 210 100 80 180 75 120 120 80 120 NR NR NR NR 200 200 200 210 TABLE 1.52: EPOXY AND POLYESTER PIPE AND FITTINGS-AMERON BONDSTRAND TEMPERATURE CHEMICAL RESISTANCE CHART LIMIT CHEMICAL SOLUTION Acetic Anhydride ACNOIX Acetonitrile II !I -I/ 120 11 120 I 1 49 49 -120 120 N” loo 3004’ I I 1 --49 49 I I NH NR I I NR 1 --- 1 NR 1 NR 1 -NR NR 1 -NR 38 NR NR I -14Q4) 200” 93” / RP-34 93 100 38 / UP-34 93 100 38 I RP-34 Acrylic Acid Acrylonitrile NR 100 Air Alcohol, Amyl 3004’ 200 93 203 Alcohol, Butyl Alcohol. Ethyl 200 180 93 82 200 180 82 __ __ __ Alcohol. lsobutyl 180 82 180 82 loo 38 RP-34 Alcohol, Methyl Alcohol. Isopropyl 180 150 82 66 180 160 82 66 100 -- _38 RP-34 -- Alcohol, Polyvinyl _ ^ 150 66 150 66 loo 38 RP-34 .M NR 38 14Q4’ l I 1 - I II Amy1 Acetate 100 38 100 38 NR NR -- Amy1 Chloride 100 38 100 38 NR NR -- Aniline Antimony Pentachloride NR -- NR -- NR -- NR -- NR NR 100 38 RP.34 220 104 220 104 150 66 RP-34 -- Carbon Disulflde Carbon Monoxide Carbon Tetrachkwde Carbonic Acid Castor Oil NH I/ Eutadiene _ 150 / 66 , NM , I 150 / NH 66 -2OiI -93 -200 -93 150 180 220 66 82 104 150 180 220 66 82 104 1 N” I -- NR 180 200 N” , 1 -- -- 1 -- NR 93 -RP-34 NR 82 93 -RP-34 RP-34 (continued) J, ’ TABLE 1.52: EPOXY AND POLYESTER PIPE AND FITTINGS-AMERON (continued) CHEMICAL SOLUTION “V Formic Acid n 0.10 n NR I Dcalc~umPhosphate-_ (continued) TABLE 1.52: EPOXY AND POLYESTER PIPE AND FITTINGS-AMERON TEMPERATURE CHEMICAL SOLUTION tlvowhlorour COflCWl tration LIMIT SERIES 5000 (continued) TEMPERATURE LIMIT SERIES 5000 %” Acid wine Jet Fuel KWOWW Lactic Acid Latex Louric Acad Lead Acetate Lead NItrate Levulinic Acid Lime Linseed Oil Lithium Chloride Lube 011 Magnesium Carbonate Magnesium Chloride Magnesium Hydroxide Magnestum Nitrate hlagneswm Sulfate Maleic Acid Mercuric Chloride Mercurous Chloride Mercury Methacrylic Acid, Glacial Methyl Chloride Methyl Ethyl Ketone Methyl Isobutyl Alcohol Methyl lrobutyl Cdrbitol Methyl Isobutyl Ketone Methyl Methaaylate Methyl Sulfonic Acid Methylene Chloride Mineral Oil Naphtha Naphthalene Nickel Chloride Nic!xel Nitrate Nickel Sulfate Nitric Acid Nitnc Acid Nitrobenzan hlitrogen Solutions 31, Sour Crude (continued) TABLE 1.52: EPOXY AND POLYESTER PIPE AND FITTINGS-AMERON TEMPERATURE 2000 CHEMICAL SOLUTION ___ ._ ---1-- LIMIT TEMPERATURE LIMIT --II SERIES 5060 ,Pd”s,W, SERIES 4000 IEDcd’ OF (continued) OF OC Adhesivetm OC NR NOTES: Sugar Solutions I! II Sulfite Liquors 2204’ 150 ( I NR Sulfur Chloride u II NR I 1. Concentration Where no concentration is shown, recommendations apply to any concentration up to 100% or saturation. Where a concentration range is given, recommendations apply to any concentration within that range. Where a single concentration is given, only that specific concentration has been tested. 2. Use RP-34 adhesive for all applications food applications up to 200°F (93’C). 3. Use adhesive shown for field installation RP-GA adhesive for food applications. 4. Use Bondstrand filament-wound fittings and flanges. flanges may be used in Series 5000 systems. 104 66 NR NR 1 150 1 NR 1 NR 66 1 NR ] NR , 200 1 NR 1 NR j NR , 93 NR I , RP-34 -- -- ,, NR-Not Recommended except except use RP-GA for use RP-105 or Molded TABLE 1.53: PHENOL-FORMALDEHYDE AND FURFURYL ALCOHOL-FORMALDEHYDE RESINS- AMETEK, HAVEG DIVISION Mmmum Haveg 41 NA is a lhermosetting of phenol-formaldahyde fillers. salts It is generally and chlorinated Haveg 61NA of furfuryl silicate dilute resin plastic, end inert recommended aromatic alcohoLformaldehyde acids, for service with Chemical Service silicate mineral Acetaldehyde. acid, 90% based on a composition recommended reactions for service and chlorinated hydro carbons. ACelOl-te 201 Acetonltrile. Haveg 46 is a phenol-formaldehyde Its primary fluosilicic consideration acid, resin is for use with and related with a graphite hydrofluoric fluorinebearing filler acid, Acelyl chloride compounds. Acrylic acid. Bosh Haveg 66 is furfuryl filler. Haveg In addition alcohol-formaldehyde to its resistance 66 has the same resin with lo HF and related resistance to alkalies a graphite Acrylonltrile compounds, as Haveg 61 NA. Alurmnum chloride Aluminum KEY: Ammonium E = Excellent. Can be used generally, and is to all intents affected at all by chemicals at the test temperature. G = Good. Can be used quite generally. Satisfactory F = Fair. Can be used for some purposes. sample or discolor solution. and purposes sulfate hydroxide. 26% not n-Amy1 alcohol in most se&ices. May involve some tendency AflillfW to swell Anilmt hydrochloride NR = Not recommended. Aqua regm SODIUM For alkaline service, HYDROXIDE Ally1 chloride (NaOH) AND HAVEG Haveg 61 NA is the recommended 4i NA c, Mb y,..^ I NR UEI I ..I. 41 NP E E.120 61 NA E NR.120 .1 NA E E E-212 61 NA E Trot .__. G G.212 F dl NC Acel~c anhydrIde with aromatic sO*F Grade _ . resin and inert non.asbestos It Is generally alkaline on a composition hydrocarbons. is a thermosetting.plastic fillers. based non-asbestos TWllperatUre “F 160°F 51 NA 1 G 01 NA 1 NR R,NA I G 41 NA F.133 NR F 61 NA G NR 61 NA Tl?st 41 NA G 61 NA E NR.212 I F 11 NA 1 41 NA F NR 61 NA G F 41 NA E E E-300 61 NA E E E-300 41 NA E E E-2.W 61 NA E E 41 NA NR 61 NA E 41 NA E E NR-212 61 NA E E G-278 41 NA F NR 61 NA G NR 01 NA E E 61 NA Test 91 NA NR 61 NA NR 41 NA TeSt 61 NA G E G-100 grade. Haveg 61 NA can be used with varying concentrations of NaOH, even concentrations up to 60% at elevated temperatures; however, it is affected . There is a surface effect that can contribute to contamination of the solution. Haveg 61 NA should be considered only where NaOH is used to neutralize conditions or as a reactant in a particular process. Haveg 41 overnight. NA, when exposed to 0.5% NaOH in water, will be seriously 1% NaOH will begin its attack immediately. acidic attacked (continued) TABLE 1.53: PHENOL-FORMALDEHYDE AND FURFURYL ALCOHOL-FORMALDEHYDE RESINS-AMETEK, HAVEG DIVISION (continued) Maximum Maximum Temperature ‘F Temperature Chemical Serries Chemical Service Benzotrachlonde Chlorosulfornc *I h‘ ______ 61 hC 41 luc een2yl chloride Bow acid Bromine, 3% maximum _~ chloride, n-Bulyric Calcium acid chlorlde Calcium hypcchlorile Carbon disulfide Carbon letrachlonde Chloral ___ F F.9a-Y 41 h' E E 41 NL E E E-300 61 NC E E E.3W 41N‘ E.140 ,’ E E I 1 I F F I E E E G.266 61 NA E E G.266 41 N‘ E E E-300 61 NF dl ML . E NR ,.. E 61 NC 1 NR 41 NC Al&J‘ 1 E Chloral hydrate Chlordlne BCX!. 2% (with sulfuric Copper lullate Cupw chlorfde Cyano‘,en chlonde I Dibutyl ether Dabutyltin dichloride F F E E-212 61 NA E E G.212 41 NL kl NL & E c . E E E-257 F NR.203 E c. E.203 dl NL E R 61 NL ; G 41 NA E Test E 61 NA Chromic ac~dl 80°F ‘1 NA E 6’ NA 1es1 4: NA NR 61 NA NR 41 NA NR 61 NA NR 41 NA NR 61 NA NR l&F hR 41NA E E E-300 61 NA E E E.3W.l Al NA E E E.300 61 NA E E E-300 41 NA E E 61 NA Test 41 NA E E E 41 NA 1 E t E 1 E I E-212 61 NA 4, NA E E E.212 61 NA E E E-212 41 NA 61 NA E E E F 4, NA G 61 NA E E-212 E E 61 NC 10% Dibutyl phthalate 41 NA E F G-257 41 NA 40% and MCB, 59% E-212 E 41 N& Chloral. Chromic acid Test E 61 NL. 30% NR-212 E ..r acts Em0 __.. F.-&n -1”” 41 NL _ ac,d G 61 NP I. Chlorel. 32% and MCB, 64% Chromic “I IWL 41NF r. .I, sec.butyl chlor#de G hl hL 41 NC ~Butyl NR Test F 61 N‘ n_Bulyl alcohol E Grade Dlethyl ether Dlethylkelone Dtethylene ~lycol Dusobutyl ketone Dimethyl phfhalate Eplchlorohydrln Ethyl acetate Ethyl alcohol 41 NA E E G-212 61 NA G G G-212 41 NA TM E E-23C I=.,,, 61 NA dl +.I& _. . E _._ 61 NA G-212 41 NA E E 61 NA E E 41 NA 1 61 NA 1 NR E.212 E.212 I NR 41 NA Tell 61 NA G G 41 NA kl NA F F NR r: (continued) s TABLE 1.53: Chemiul PHENOL-FORMALDEHYDE Servia GWJ9 80°F 1’ NA Methyl isobulyl ketone. 100% chloride Monochloroacelic Uonoch1oroaceto”e. acld 10% Ho”ochlorobe”re”t Uonoethanolamme. Monoethmoiamlne. 20% 50% methyl arsenate Naphthylene G-212 6’ NA G 4: NA T& 6’ NA NR 4, NA Test 61 NA Ntlrilotriacetic aud Nitrobenzene Nitrophenol Phenol. 9% Phenol. 6% G 41 NA E E E-212 E E E.212 41 NA TCSl 6, NA G.l!U 41 NA 1 61 NA 1 Test I F-212 E E 61 NA E E E-223 41 NA E F E F E.300 l=.!aY E E 1 NR i 1 , G_ 11 _ NA I NF) . 61 NA 1 61 NA NR 41 NA E E.233 ____ W3ctyl chloride Oleic acid Oxsl~c wad. 20% PlWil” F’e”tachloroethS”e Pentan&ione Pwchloroethylene PhOSpe”e Phosphorous orychlorlde Phosphorous trlchloride bisullate E E HR.212 E E F-2t2 E E E-265 Potasswm E E E.212 41 NA E E E.212 61 NA E E E-212 41 NA E E E.265 61 NA E E G-265 41 NA E G G.xx) 61 NA E E E.200 41 NA E E E-212 61 NA E E E.212 41 NA E E E.212 61 NA E G G.212 41 NA 61 NA NR r. F Al NA 1 E E 61 NA 1 E E 1 1 dlchromsle. 5% PolPssslum permangana1e Proplonic l#d. lCQ*A Ropiorw aad, 30% Pyrldlne Resorcinol. 46% Sodwm bisulfate Sodaurn bwltile 8dF 4: kA NR 61 NA NR 41 NA G 61 NA NR (continued) Maximum Temperature “F 160-F F NW212 F.212 41 NA E G 61 NA G NR 41 NA E E G.212 61 NA _ F F NW212 41 NA NR 61 NA E E ‘7 NA F F 1 I 1 I Test 41 NA E E 61 NA E E E.212 .I G G G.212 61 NA E E G.212 41 NA E E E.300 61 NA E E E-300 41 NA E E E.300 61 NA E E NA 1 1 F E 61 NA I F 1 F 41 NA 1 NR _. I NR 11 NA F-212 61 NA Grade 41 NA 61 NA F-212 61 NA _. . 50% Potassium cyanide G HAVEG DIVISION 61 NA Phosphoric awj. Polasswn 41 NA 61 NA Phenyl ether I 11 NA n.Octyl alcohol FT,e”ol. 100% P”enol, 65% 61 NA 41 NA Chemwzat Service G 61 NA Nitric acid. 2% maximum (with sulturic acid not recommended) RESINS-AMETEK, Maximum Temperature “F l&F 6: NA 41 NA Uwosodwm ALCOHOL-FORMALDEHYDE NR P! NA Methylene AND FURFURYL 6, NA EP12 E-300 I E 1 I I E-212 I 41 NA E F 61 NA E F 41 NA E G 61 NA E E 41 NA NR 61 NA NR 41 NA G G 61 NA G G 41 NA E E 61 NA E E E-300 41 NA E E E.303 61 NA E E E-300 E-212 Eaco E-212 E-212 (continued) TABLE 1.53: Chemiul PHENOL-FORMALDEHYDE Service Grade AND FURFURYL BO’F 160-F Maximum Temperature -F ALCOHOL-F0 ALDEHYDE RESINS-AMETEK, HAVEG DIVISION Grads 4’ NA (continued) 80°F 1SO’F -rest ND Temperature “F 61 NA E E PI NA TfZ.1 Nfi 67 NA E E E.212 41 kA E E G.212 61 NA E F E-212 Synthetic Resins and Polymers TABLE 1.54: POLYESTER AND VINYL H-RON ESTER RESINS-ASHLAND CHARACTERISTICS RESIN SERIES 92 SUGGESTED APPLICATIONS Maximun fwe retardancy. Class I flame spread cm he achreved. Good corrosion resistance. F’rimmily for severe fume handling equipment to 25O’F. HETRON 197 Habganated polyester. Maxbtmn corrosbn and heat resistance. Class I or II flame spread can be achiiad. All eqwpment where maxrmum corrosron and heat resrstance are required - intemrittent service to about 600°F: contrnuously rn 350°F range. Excelbnt for hot wet chlorine and other hrghly oxidizing environments. HETRON 72 Similar to HETRON 197 series. General corrosbn resrstant equrpmant. linings, coatmgs. toppings, HITRON 700 9isphanol~A Fumarate resins. Excellent corm&on resistance. Non-fire retardant. All corrosbn resrstant equipmmt except fume handhng systems to about 250°F. Ideal for caustrc and hvwchbnte. HETRON 900 I AROPOL 7240 Series (Includes 7241 and 7242) AROPOL 7430 Series (Includes 7530 and 7532) HETRON 99P 179 Vinyl ester restns. Nonfire retardant. Excellent corrosron resistance. Isophthahc resins. Nonfire retardant. Moderate corrosbn resistance. All equipment except fume handling systems to about 190” F. AFtOf’ 7242 can be used for FDA applicatrons. Resilient isophthahc resms. Nonfire retardant. Moderate corrosbn resrstance. All equpment except fume handling systems to about 150°F. Excaflent for filament winding applicatrons. Fee retardantlisophthafic with grnrd mrrosbn resistance. Class I f&ins spread can be achiied. For ftane handling equipment to 250°F. 1 . The following definitions will aid readers using this Guide. Service Temperature - Temperature data is not Asterisks - Resins marked with an asterisk indicate that it is preferable to use this resin over another resin even though both are resistant at the temperatures listed in the Guide. necessarily the maximum service temperature. It is the upper temperature at which a specific resin has been satisfactorily tested or used. AMB - Refers to ambient temperature LS - Indicates that limited service life can be expected. This means that some chemical attack will occur but not enough to render the equipment useless. of 7!XO’F. Blank Space - Showing no service temperature recommendation indicates that insufficient resistance data was available. It does not mean that the resin is unsuitable for that environment. NR- I\ I Resin is not recommended. SERVICE TEMPERATURE. OF FOR RESIN TYPES CONCEN. TRATION % CHEMICAL ENVIRONMENT Acid: Salt ACID: SALT ENVIRONMENT. HETRON 92 SERIES LAMINATES. GOOD FOR 25o’F VAPORS FROM THE ACID: SALT SOLUTION. ‘HETRON 99P recommended for fume service only. THESE RESINS RECOMMENDED AT AMB. (AMBIENT 7540°F) TEMPERATURE OR TEMPERATURE IN ‘F SHOWN FOR ESTIMATED 10.15 YEAR LIFE. HETRON 197 SERIES RESIN PRE. FERRED’ AT 2UO’F OVER HETRON 72 SERIES RESIN AT 2OO’F. THESE RESINS MAY BE SUITABLE AT HIGHER TEMPERATURES BUT NO DATA IS AVAILABLE. HETRON 922 RESIN RECOMMENDED FOR LIMITED SERVICE. AT 100-F WITH ABOUT 5 YEAR SERVICE LIFE. (continued) 180 TABLE Corrosion 1.54: Resistant POLYESTER Materials Handbook AND VINYL ESTER RESINS-ASHLAND (continued) List of Trademarks and Product Names Adogall* ... Aemsol . Allpal .......... Abdlrm ........ Am&em . Amerex . . . . . . . . Amine Salt Solutbns. 73g73 M-A, m-0, M-C Sherex Chemical Co. American Cyanamid Co. Chemical Div., GAF Corp. Amchem Products Inc. Amchem Products Inc. Drew Chemical Corp. W. R. Grace Co., Dewey 8 Almy Div. American Mineral Spirits Co. International Dioxide Inc. Wyandotte Chemical Co., J. P. Ford Div. Armak Co. Armak Co. AmscoBKOH Solvent Anthlum Dbxtde Apache Amlaal . Arquad . Benteo Wyandotte Chemical Co., J. P. Ford Div. Velsicol Chemical Corp. Bet2 Laboratories, Inc. Drew Chemical Corp. Oxy Metal Industries Corp., Parker Div. Spartan Chemical Co., Inc. Colgate-Palmolive Co. Bmuoflu:Brominex Betxsulllte3.. BlocidaCWT.102. Bondarlte Bowlcloanm Build . . C-56 Calgun carbitd Celbeolve cell Putty Cham-Rex c2m5. C-2009, C-2075 Chbrothene Clhex clealler508..... CWTlM Cyaf cygon Hooker Chemicals & Plastics Corp. Calaon Coro. Union Carbide Corp. Union Carbide Corp. Rowe Products Co. . . Ashland Oil, Inc. Dow Chemical Co. Peabody Engineered Systems Quaker Chemical Co. Drew Chemical Corp. American Cyanamid Co. American Cyanamid Co. Darux ___.._..___..___,.. Dynd W. R. Grace Co., Dewey 8 Almy Div. W. R. Grace Co., Dewey 8 Almy Div. Arapahoe Chemicals Huntington Laboratories Diversey Chemical Co. Dow Chemical Co. Drew Chemical Corp. Hooker Chemicals & Plastics Corp. Staley Chemical Co. Union Carbide Corp. Electrasol Elvase EP 52.A55 Eptam Erbnal NW EVA Exalt _. Economics Laboratory, Union Carbide Corp. Ashland Oil, Inc. Stauffer Chemical Co. Ciba-Geigy Corporation Union Carbide Corp. Pennwalt Corp. FClW, 2w, 206A Fluomluhes 3M Co. Hooker Chemicals 8 Plastics Corp. Buffalo Color Corp. Daxad ..__....__..__... DFR.121 Dkrohe Diversey Dowclem DmwSpenN Durex DW-575 Furbn . 12.62 G.51 Glass Cleaner .. Gbhrlte 15, X-200 ......... GokbnGb .............. Halao Sg ................ Igepal .................. lrgasd DA ............... Isocure ................. Isoprep ................. JM-235, JM-271 ........... Chemical Div., GAF Corp. Ciba-Geigy Corporation Ashland Oil, Inc. The Richardson Co. Johns-Manville Hercules Powder Co. Lasso .................. Lix 54N ................. Monsanto Co. General Mills Chemicals, Magnllbc .............. Matar .................. Mulsollne .............. American Cyanamid Co. Huntington Laboratories Dye & Chemical Co. of Canada, Ltd. Neodol ................. Shell Chemical Co. Oaklte ................. Olin ................... i%lD.. ................. OPM-i,OPM-2 ........... Oakite Products, Inc. Olin Chemical BASF Wyandotte Corp. Olin Chemical Parco................... Oxy Metal Industries Corp., Parker Div. Oxy Metal Industries Corp., Parker Div. G. H. Packwood Mfg. Co. Spartan Chemical Co., Inc. Ashland Oil, Inc. Spartan Chemical Co., Inc. Borden Co. Uniroyal, Inc. Pax Hyspeed ........ PD34 .............. PepSet.. .......... Plus 6 .............. Polyco ............. Pdywet ............ Raylene ................. Sam-Fresh Stackfas Mastic Telona .................. Tergitol ................. Textone ................. Thermolln ............... 35D.. .................. Tlnoflx OF ............... Dow Chemical Co. Union Carbide Corp. Olin Chemical Olin Chemical BASF Wyandotte Corp. Ciba-Geigy Corporation u-3400, U7ooo. ........... Ultrawet ................ Staley Chemical Co. Atlantic Richfield ........ ........ ........ ........ ........ ........ Varlquat Varlsoft Vamx 155E Varsol . . vtdden VlvoZyne . Zlmmite .. .. Inc Wyandotte Chemical Co., J. P. Ford Div. The Richardson Co. The Richardson Co. Ashland Oil, Inc. Envair, Inc. Spartan Chemical Co., Inc. Monsanto Co. Sherex Chemical Co. Tretolite Div., Petrolite Co. H. B. Fuller Company SD-20......... Skydrol ....... Softener B ..... SP-101 ........ Rohm 8 Haas Spartan Chemical Co., Inc. Hooker Chemicals 8 Plastics Corp. Kymene ................. Rkhamlde ............... Rkhonate ............... RJ.4 .................... Inc. Ashland Oil, Inc. Spartan Chemical Co., Inc. Sherex Chemical Co. Sherex Chemical Co. Sherex Chemical Co. Exxon Company Dow Chemical Co. Gcoch Feed Mill Corp. W. E. Zimmite. Inc. (continued) Synthetic Resins and Polymers TABLE 1.54: POLYESTER AND VINYL ESTER RESINS-ASHLAND 181 (continued) HETRON’andAROPOL” ResinSelectionGuide ior CorrosionResistantRTPAPPliceti0n-s SERVICE CONCENTRATION % CHEMICAL ENVIRONMENT Acotaldehyda ................ Acotaldehyde, 1% In air ........ Acetaldehyde Fumes .......... Acetk Acid .................. Acetk Acid .................. Aoetlc Acid .................. Acetk Acid .................. Acetic Acid ............................ Aoetk Aotd. about 10% In Hydrocarbon, Liquor end vapor ..................... Acetic ACM. Glackl ..................... Acetk Acid. Gkckl ..................... Acetlc: Gkckl: 70% Nltrlc: 49% Hydrolluorlc AcetIc ACM: HCI ........................ Acetlc: HCI: H,O ........................ Aoetlc: H,O, ............................ Acetic Acid: Sodium Dkhromato ........... Acetlc Actd Vapor ............... Acetic Acid, Vapor 6 Condensate . . Acetic Anhydrtdo ............... Acetic Anhydrlde ......................... Acetone ................................. Acetone ................................. Acetone ................................. Acetona: Cyclohoxanc Hexane: Water ........ Acetorw Water ........................... Acetonltrtk .............................. Acetophenona ............................ Acetyl Chlorldo ........................... Awtyl Chkrlde ........................... Acid Rinse, PhotographIc .................... Acldlc Gaseous Atmosphem, Saturated, Weak Phoaphorlc, Hydrolluork. Sulfurous, Etc., at 3900 fpm’ .............. Aclda (Sullurk, Phosphork, Acetic), Soda Ash, Organk Salts, Dye Sulk, 2.5%Soll&,pH2-5.. .................... Acrykmlde .............................. Acrylk Actd .............................. Acrylk Acid .............................. Acrylic Acid .............................. Acrylic dlrperslon: Acryknltrlk ............... Acrylic dkpersion: Vlnylldene Chloride ........ Acrylic Emulrlon ........................... Acrylic, Glrclrl ............................ Acrylk Spray Liner, Water Reduolbk at 12O”F(PPG Indwtrks) .................. Acrylic Stynne Emulsknst DW-975, U-3400, U.7091 ................... Acrylk Wet Ink Vamk h. Water Reduclbk at 120°F(PPG Industrka) .................. Acrylonitrlk ............................... Actlvatad Carbon Bedr, Water Treatment ...... Adlpk Acid, Adipyl Chloride and Hydrochloric ACM ........................ Adlpyl Chlortde, Adlpk Aold and Hydrochkrk Ad0g.n~381: xylem ....................... .............................. AdottAdo9en449 .............................. Aemsolt, Wettlng Agent .................... Alr, Humid, Trace Sulfur Fumes ............... Air: Methyl Sulfide: Methanol; Smell Amounts H,O. H,S, Methyl Mercrptrn, Acetone, TurPentlne ............ Alcohol, Ethoxylatad, pH 8.5, C,,.C,, ........... 100 (40 Ibsm’ 10 15 NETRON’ 92/99P NRI490 90 150 125 25 125 50 75 AMBKJO TEMPERATURE, HETRON 920 sEmw9so NR - NR - NR - NR - 210 210 170/150 170/150 2101200 21omo 210 125 17ol150 1541125 21wW 150 16a150 21w22u 160 - 180220 NFUNR NR - 100 100 @ 120-F 3:5:1 @ 1W’F NR/- 100’11ocu1w LYLSJNR NR 50:2U 50:16.5:315 95:1.5 AMB/66 AM0 25 100 1W @ 12o.F 10 100 100 @ 133°F 10:10:1:79 NW1801NR NR NR 1090 100 1W - 100 100 @ 13O’F - NR/- - 50 100 @ 1W’F 25 10 96:2 9&2 loo AMB 66 AMB 160 160 loo LS/LS/NR NR NR NR _ - NR NR NR - NR NR - - - NR NR NR NR NR AMBlNR NR NR NR - 90 2101220 2101220 lXU- NWNR NR NR NR - NR - 150 AMB - NR - NR NR NR NR - AI.40 - NR _ _ 90 - _ - - 10 165/- lo 16Y- --/lSQ NR -/to 165’/--1w- Unknown TYPES HETRON 700170Oc - 70:30 @ 212-F RESIN MOP01 724017430 SERYS - la, OF FOR HETRON 72/197119711 NR NR loo 100 AMB AM0 - 100’ - 90 --I-/NR - AM0 --I-/NR - - loo NRI- 2al Unknown Unknown - - 25:75 - lMYlW/NR NR NR 120/- AM0 loo _ AMBllOO AMBilW _ NR” SAT SATI- - - - NR” NR - SAT NR - - NR NR - - SATINR _ - 12W120/AMBI- 120’ 120‘ AMB 200 120’/120 120’1120 - 120 120 - 120/12W- 652.56 100 165 120’ - _ _ - 120 - SAT under SERVICE TEMPERATURE = S.stisl.%tory With mlemnce to mcommendaNons under s ,gqyh;;;?l;gps. W_UT%Y= First two msrerials sat at 1 msisrance unknown 100’/100 = Both mareriels sefislactoty, tirsl pn?lwr&, efc. 125’ = Pmhrmd mahrial, a/thou h others sm suifabfe at 125 .R. 100150 = Temperalum varied w!I m hmlls shown tSee list of trademarks and product namt?s. (continued) 182 Corrosion Resistant Materials Handbook TABLE 1.54: POLYESTER AND VINYL ESTER RESINS-ASHLAND bxntinued) SERVICE CHEMICAL ENVIRONMENT Algaecide, phenate based ............... Alipal C0433t ........................ Alkaline Film Stripper, Butyl Cellosolve: Monoethanol-Amine @ 136’F ............ Alkaline Soak Cleaner ................. Atkanolamide, Fatty Acid ................... Alkanolamide Nonionic Surfactant ........... Alkyl Benzene Sulfonic Acid ............... Alkyl Dimethyl Benzyl Ammonium Chloride: Phosphoric Acid: Inerts .................. Alkyl Dimethyl Beruyl Ammonium Chloride: Tributyl Tin Chloride/Ethylene Oxide/Amine: Hydrochloric Acid: Inerts ................ Alkyl Ether Amine Oxide Surlactant .......... Alkylate, Substituted Benzene Type, Relinery Alkylate Sulfonates, Linear ................. Atkylrtion, Aromatk Hydrocarbon ........... Ally1 Chlortde ............................. AlmondOtt ............................... Alodine 461/45t, pti 2 ...................... Alpha Otefin Sulfonate ..................... Alum ................................... Alum ................................... Alum, Potassium .......................... Aluminum Chloride ........................ Aluminum Chloride: Fluosllkk AtId’ ......... Aluminum Chloride Spent Catalyst Solution, 1DWppmBenzene rB13tt.F .............. Alumlnum Chlorohydmte ................... Aluminum Chlorohydroxlde ................. Aluminum Citrate ......................... Aluminum Desmutter 6 Deoxidtzer’ .......... Aluminum Etchant. Phosphate Free’ ......... Aluminum Fluorlde’ ....................... Aluminum Hardening Fixing Bath, , .......................... Photographic Aluminum Hardening Raptd Fbtlng Bath, Photographic ...................... Alumlnum Hydroxide’ ..................... Aluminum Hydroxide’ ..................... Aluminum Nltrate ......................... Aluminum Oxide Drying .................... Aluminum Oxide Wet with HCI, Drying ........ Aluminum PIatlng,Sulfuric, Sodium Dlchromate ..................... Aluminum Potassium Sulhte ................ Aluminum Potassium Sulfate, Vepor & Condensate.. ........................... Aluminum Reduction Pot Plant Rooflng andSIdIng .............................. Aluminum Sulfate .......................... Aluminum Trkhloride ....................... Amchem 616t: Nitric ....................... Amemx 2Dlt .............................. Amerex 209t .............................. Amine Salt Solutions, 73673 MA, M.Band MCt ........................... 2.Aminoethanol ............................ Amlnoethoxy Ethanol rB 2TO.F ... , ........... Aminoethyl Piperezlne ...................... Ammonia, Dry ............................. Ammonla, Liquid ........................... Ammonia, Wet ............................ Ammonia: Ammonium Nitrate: Hydra fluosilkk: Nitric: Phosphoric 6 Sullurlc, Wet Vapor’ ...................... CONCEN. TRATION % HETRON’ 92’99P 100 - 28 57.30 10 ouga1 - NPJ- 55 amtde - TEMPERATURE HETRON 7211971197A 1251- 125 1w - NR - NR NR 120 - 1W 0 1:01:23.77 - 100 120 AMW-I- 120 AMBI- - - 120 120 2cu 160 loo/- 1201- NR NR - 125 -!120 210 210 - 165 - 2101220 1601150 2w/150 160' 2101220 2101220 2101150 2101220 - 160130 170/150 - - AMB - 2OOll50 17ol150 170/120 2001150 2w/150 - 165!AMB 1651150 AMB AMBiW 2201200 NR Sat'd NW30 - 1701150 - 5oz/gal All - 1001- 120 NIV- SlImy:2 50 50 NPJ160/- 100 100 10 Sat'd 5 All NR 160 - 100 - 100 100 TYPFS 125 100 120 COtlC. Jnknown Q 10512O'F RESIN HETRON 920 SEAIESI9.90 0.1125.75 - FOR HETRON 7001100c 100 100 - ‘F AROPOL 724017430 SERIES AM0 16O/165/AM&-- 60 60 Sat’d 20 Sal’d - 5 160 - 210 16OJ- 160 13Oi250 40 6:16 103 100 100 100 100 - -/lso All FUllas 220&?90/- - - All 220/2901- 150 16wl40 - 17w150 2101220 210/230 - 1601150 - 1701150 - 125 125 LS125 125 125 65 - NfU- 65 NR NR NR NR 90 100 NFU- Gas -I90 180/200 16W2W 160/160 - - - Gas to assure AM0 170/150 250 210 6595 90 NR - 125 6595 - - AMBINR AM&- 250 15:5:2.5:2.5:Trace ’ HETRON SSP for fums service only IGood fesf results a/far shon axoosum ‘Synthehc suriacing WI/ recommended lor “ax~mu” msistance ‘l3enzo / Peroxrde - D#methyl am/ins cum system recommended SaYISr sctory satwcc ‘Post-cure racommendbd ‘Solution may discolor ‘Nonrh!xotroprc resms preleradle ‘Unsetlslacro/y as /mmg 1701150 AMB LYNR NR 90 601NR NWNWlW1160 lW/lM NR ‘Acceptable ss to odor end tasfe Ior AROPOL 7242 type resm. SNamed 4 hours wirh atmospheric steam pnor to axposum ‘*Three 3 hour exposures to 30% nitric at 1CiYF to simulate cksnin “No dwxlorstion occurs af 5 lt’/ga/. sod wrfh AROPOL 7242 and A ETRON 7W ryps construcfmn il surfaces are acid or steam cbanad ‘*“C” veil on/ -AROPOL 7r 4OOnly ‘*Apoears to be erosion/corms!on “AROPOL 7240 SAT al 1ZO’F 1See M 01 trademarks and oroducl names (continued) .. . P :: :::::::: : ::: 1:: ::: ::: : ::::“’ . . “’ . . . . . . . . . . . . . . . . . . . a:. .p..,::::::::.::: . . . . 5:::..2..::::::: .,.;jc:; ::::::::::::: . . . . ::.::: ::. : : : :: : : G Corrosion 184 TABLE 1.54: Resistant POLYESTER Materials Handbook AND VINYL ESTER RESIIN! j-ASHLAND (continued) SERVICE CONCEN. TRATION % CHEMICAL ENVIRONMENT Ammonium Thiocyanate: Hydrochloric Acid Ammonium Thiocyanate: Thiosuliate: Sulfate: Water ........................ Ammonium Thiosuliate ................... Ammonium Thiosuliate: Thiocyanate: Sulfate: Water ......................... Ammonium Tungstate .................... Amsco BKOH Solventt .................... Amyl Acetate ............................ Amyl Acetate @ 120°F .................... Amyl Alcohol ............................ Amy1 Alcohol ............................ Amy1 Chloride @ 120-F ................... Anaerobic Sewage ....................... Aniline ................................. Aniline Hydrochloride ..................... Anlllne Hydrochloride, Substltuted: HB r. HCI: Br,: H,O ..................... Anlllne Sulfate ........................... Anionlc Polyelactrolytes, Blend ............. Anionic Suriactant ....................... Anodizing Solutions ...................... Anthium Dloxidet ........................ Anthracene Oil ......................... Anthraquinone Disulionic Acid Q 150°F ..... Antimony Pentachloride ................... Antimony Trlchloride ....... ....... .... Apachet ............................... Apple Acid .............................. Aqua Ragia (Cont. Hydrochloric: Cont. Nitric, 33) ....................... Aqua Regia ....................... Aqua Ragla Fumes ................. Armeen Ct ........................ Armeen DMCDt .................. Aromatlc Hydrocarbon Alkylatlon ..... Aromatic Solvent: Tributyl Phosphate ArquadUSOt ...................... Arsenic Acid ....................... ArsenouoAcid ..................... Asphalt .......................... Atmosphere, Chemical Plant ......... Atmosphere. Coal Dust ............. Atmosphere, 100% Relative Humidity Axelaic Acid ....................... “B” Crude 011 ..................... Bacterlclde Phenate Based .......... Barlum Acetate .................... Barium Carbonate’ ................. Barium Chloride ................... Barium Hydroxide’ ................. Barium Hydroxide’ ................. Barium Sulfate .................... Barium Sulfide’ .................... .......... Beer Beer, BrewIn;’ I&i; ‘&ei ......... Bwt Sugar Liquor .................. Bentact’ ......................... Berual Chloride .................... Benzaldehyde ..................... Benzene .......................... Benzene @ 120°F .................. Benzene @ 2W°F.. ................ Benzene, HCI (trace), Water ......... Benzene I Hydrogen Chloride Vapors Benzene, Vapor .................... Benzene, Wet Acid (HCI) ............. Benzene: Ethyl Benzene ............. Benzene Disulionlc Acid ............ Benzene Sulionic Acid .............. Benzene Sulionic Acid .............. Benzene Sulionic Acid ............. Benzene Sulionic Acid: Sulfuric: Water Benzoilex 9.SEt .................... Benzoic Acid ..................... tSee l!st of trademarks HETAON’ 92199P - 4:5.5:2.3:68 60 5.5:4:2.3&I Sat’d lco All 100 All Vapor loo _ IM) loo -/NR 100 NW100 1601120 1w/200 - NR 200 140 -/LS/NR IWNA 140 NR 65 65 65 65 125 - NR - NR l&3/- NW- 14011401Ls140 AMBIAMBf90 2CO/l&l AMBI- 160 - - 1oollOO/- Sat’d - AMB NR 200 140/NR - 10 Sat’d All 120/- -/NR 2ca160 200 NWNW--/150 -/NR NR 200 125 120’ AMB 100 AMB --ISAT/NR AMB 200 150 95 NR LS12YNR AMB SATIAMB 1601150 - 130’ - NR NR AMB NR NR 120 120 120 AMB 120 NPJSAT 65 NW150/160 140’/1601220 _ SATIWI2001220 - 130/NR NR NR - NR - NR - 100 100 100 100 100 100 100 120 _ 120 _ 120 - 100 120 AMB 125 160 200 200 _ 195/- AMB 125 NR LSl6OINR 1601150 LS.AMB/NR NR 160 - 170/15u NR 50 100 160 - 1W 100 100 100 NFUAMBISO NR/- NR AMB NR NRI- LS 176 AMW- AMB AMBI- AMB 100 194 200 NR 65 100 140’ 120’ 250 NR NR LS:AMB/NR NR NR - 160 60/16O/- AMBI- 150 - 250 - NRJ- 180 - - 1CO Sat’d NR AMB AMB - 120 - AMB Sat’d 68715 - 120 NR 160 NFUAM B/W - 140 225l220 125 120 _ 120 NR - 150 - 1/3:2!3 100 30 loO@ 16O’F 140 NR 120 - 15W- vapors lCO/- LS/NR NR NR 19’ Be Sat’d All All 130/110 - 130’/- NR lOO’/NR 100 . 130’/110 100/1w/- COW. All Sat’d - - AMBIW NR - 65% - 130’ - COllC COW. COX. - 130/110 - - Cont.@ 160°F COW 160 HETAON 920 SERIES1980 130’/110 - 2iW150 - 10 130/110/- TYPES HETAON 700/790c 130/110/- Sat’d 100 56 100 Sat’d 50 180 “F FOR RESIN AROPOL 724017430 SERIES - 15:4.5:1.5:1:76 6 TEMPERATURE, HETRON 72/197/197A - 125 160 200 200 200/l 50 150 160 150/b AMBlNR NR NR NR NR - - lW210/220 210/1501160 150/2101160/AMBINR 16O/NR/NR/NRilOO NR NR _ AMB - - - - - 15OlNR NR 200 - NR 140 120 170/150 200 140 120 2201200 2 101220 SAT 210/220 140/120/210/- and product names (continued) Synthetic Resins and Polpm TABLE 1.54: POLYESTER AND VINYL ESTER RESINS-ASHLAND (continued) SERVICE CONCEN. TRATION % CHEMICAL ENVIRONMENT Benroic Anhydride ...... ..... Benzotnchloride Benzoyl Benzoic Acid to)’ ..... : : : ::: Benzoyl Chloride .... Benzoyl Chloride Vapors with HCI, H,O, Benroic Acid .................. ........... Benzyl Alcohol ........... Benzyl Benzoate ........................ Benzyl Chloride .......................... BetzSullite3t,pH5.5.. ................... ................. Biocidet 207 Biocidet 205 @ 125OF : : ................... Biocide: Chlorophenate, Organic Sulfur Type Biocide; Chlorophenol, Methylone Thiocyanate Blend @ 125’F ............. Biodegradable, All Purpose Liquid Cleaner .......................... Biodegradable Detergent, Liquld ............. Biodegradable Detergent Ultrawrtt 5OK ....... Biodegradable Dotergent Ultrawott 4tiDS ..... Biodegradable Detergent Ultrawrtt BOL ....... BKOH, AmscoT. Solvent .................... Black Chrome Bath: Chromic, Acetic, Barium, Acetate ........................ Black Liquor, pti > 7 ...................... Black Liquor Recovery Fumaca Gases @ 210.325*F .......................... Black Liquor Room Flooring, Spills ........... Black Liquor, Spent Sulfite, Calcium Bass Mill pH 1.52 (Trace Formic & Acatate) ...... Blanch, Peanut, Hot Water, Detergent @ 16Q°F ...................... Bleach, Ferricyanide with K Bromide for Photography ......................... Bleach Reactor. 6% Sodlum Hypochlorlta’ .... Bleached Pulp ............................. Blow Gas Absorber ......................... Bonderitet 73’ ............................ Bonderitet 722X? .......................... Bondarttrt K.7lCl-g 701-P .................... Bonderitet K.761. pH 56 .................... Bonderitet 37,3?S, 39’ ...................... Bondoritet 721-S’ .......................... Bonderitet 1303 Makeup .................... Bonderitet 1303 Replenishing ................ Borax .................................... Bordeaux Mlxturo .......................... Bork Acid ................................ Boric Acid: Nickel Chlorlda Nkkrl Sulfate ...... Boric Acid: Sodium Sulfate with 0.25% Sulfuric Acid, 0.03% H,O,, 100 ppm Iron, 3OG3 ppm Chloride, Temperature Cycled” .... Bottle Washer Solution ..................... Bowl Cleanset ............................ BowlCleanse,MildT ........................ Brake Fluid ............................... Brass Plating Solutton 3% Coppen 1% Zinc and 5.6% Sodium Cyanides, 3% Sodium Carbonate’ ............................. Brew Kettle Fumes ......................... Brine,CI,Sat.,pH2 ......................... Brine, Dechlorinatsd: pH 2-3, Free Chlorine (Traces) @ 2W~22gDF ............. Brine, Salt ................................ Broke Chest Fumes ........................ Bromine, Dry Gas .......................... BromineFumes ............................ Bromine, Liquid ............................ Bromine Water ............................ Bromine: Water ............................ Bromine, Wet Gas ......................... Bronze Plating, 4% Copper, 5% Sodium Cyanides, 3% Sodium Carbonate, 4.5% Rochelle Salts .............. Brown Stock Washer Hoods, Ducts .... : : : : tSee list Of tradem.wks and product names ‘*HETROf, c‘,“d,,,dns rg, ,nd 700 IC,,CI w,,h Some crazmo loo loo All 100 WETROM’ 92199P ‘F FOR RESIN AROKIL 7240/7430 SERIES TYPES WETRON 7001700c HETRON Pm SIIIIFI~PI” NR - 210:- NR NR NR NRJ- - NR NR NR AM0 _ NW- NR Jnknown Gt 194-221’ 1W TEMPERATURE, HETTROll 7211971197A NFCNPJ- 185 -/NR NPJNW30 - AMBlNR 100 100 NRI- 200 125 ID0 100 100 NW0 - NR 200 - 125 125 SAT 125 SAT SAT - 100 loo 1tM loo loo loo/- IO0 loo 1w 150 130 100 loo 100 lWfloo/- LYNR loo/- - IW LS/LYNR 125 LSiLYNR - 125 SAT lW’/- 115 NR NRINR --ISAT/NR NR 1001- - - 2201180 21OQ20 NR NWSAT AMB @ ZlZ’F NR - NFU- 80 140 190 - NR NR - 12w- 185 1M 100 - 120 150 NR Sat’d &I253 agal 167mcVI67 -/180 - - 1525 5.10 la3 Sat’d @ 75-F ,es,ns rpprrr 10 DC unswtabk under but l e n?sisf&7f under SUIK CondmnS. 22CV140 - 210/- 2W 210122u , -I206 --12ow206 loo - 206’1I ?O/twiloOiNFVIX) - 180 - 150 220 IM NR 2121200 2101220 SAT 220 1801150 200 210/220 - NR NR AM0 NR NR - NR gpl la, 1BoIlXl loo’/loo’/- lXV- S&d Sat’d 1801140 100 loo 180 loo 1w - IW 300310 140 200 - NR a5 NR Sat’d - 180 SATi AMBFaO 14WNRI- 180’ NR’,- SAT AMB 140 NR 5% AMB’ IBOI- NR Boll00 AMBIIW NR SAT 180/2w 80 100 AM&W - 180’SATISAT SAT 'D,Ssolvcd solids. 1574.2183 ppm PO.. 0.25 ppm: rota/ PO.. 1.3 ~ppm: CU. 0 7 pm. In. 3.4 pppm. Fe. 7.8 ppm: C&o, 4x) ppm mar.. Chromafr. hexa. 18.22 ppm Cl2 rosrduel.02045 p@n:NeCl. 527.‘02 pprn CyCllC (continued) 186 Corrosion TABLE 1.54: Resistant Materials Handbook POLYESTER AND VINYL ESTER RESINS-ASHLAND (continued) SERVICETEMPERATURE.'FFOR CHEMICAL ENVIRONMENT Build? Detergent Solution. pli 9.10 Butadisne Latex ........... P.Butoxyethanol 2.2.Butoxvethoxvethanol : : : .. :. ....... B;tyl Acetate : ... Butyl Alcohol: Ethyl Hrxylacatate: Di4sobutyl Ketone ...................... Butyl Alcohol, Normal .................... Butyl Alcohol, Secondary ................... Butyl Alcohol, Tertiary ..................... Butyl Carbitolt ........................... Butyl Cellosolvet ................... Butyl Cellosolvet: Monoethanolamine Film Stripper Q 136°F ................. Butyl Ether .... Butyl Ether. Phosphorfc: ~Hydr&lo&’ : : : :,I : : Butyl Phthalate ........................... Butylamlne .............................. Butylena Glycol ........................... Butylrne Oxide ........................... Butyric Acid ................. ......... Butyric Acid ............................. Butyric Acid .......................... Butyric Acid ............................. C56T .................................. C.56t.Crudo ............................. C56t; High Purfty ......................... C56T; Beg. P High Purfty Wet With H,O ....... Cadmium Cyanide Plating Bath, (3% Cadmium Oxide; 10% Sodium Cyanide; 12% Sodium Hydroxide)’ ............................ Calcium Bisulfide ......................... Calcium Bisulfite ......................... Calcium CarbonateJ ....................... Calcium Carbonate, 90%; Magnesium Hydroxide, 10%; Nickel & Iron Hydroxides’ . Calcium Chlorate ......................... Calcium Chloride ......................... Calcium Chloride, pH 5.5 ................... Calcium Chloride, pH 8.5 ................... Calcium Chloride: Phosphoric Acid ........... Calcium Chloride: Sodium Chloride: Magnesium Chloride .................... Calcium Hydroxide’ ....................... Calcium Hydroxide’ ....................... Calcium Hydroxide ....................... Calcium Hypochlorttea ’ ................... Calcium: Magnesium: Sodium Chlorides ...... Calcium Nitrate ........................... Calcium Oxide ............................ Calcium Sulfate .......................... Camphene, Chlorinated 68%: Xylene ......... Camphor ............................... Can Cleaner, Acidic, pH 1.2, Sulfuric & Hydrofluoric, Aluminum 6 Oil Impurities’ ............................. Can Treatment, ChromeFree, pH 5-6 ......... Can Treatment, Chrome Phosphate, pH 2 ...... CaneSugar Liquor.. ...................... Canning Plant Waste ...................... Capric Acid .............................. Capric Acid .............................. Caprylic Acid ............................. Caprylic Acid ............................ Carbamide .............................. Carbon Beds, Water Treatment .............. CO,: SO,: N,: 0,: H,O Vapors ................ Carbon Dioxide, Wet. Acidic ................. Carbon Disulflde .......................... Carbon Dlsulfide Recovery Fumes ............ Carbon Disulfide Vapor ..................... Carbon Monoxide Gas ...................... Carbon Tetrachloride ....................... Carbon Tetrachloride, Vapor .............. Carbonic Acid .................... ....... CONCENTRATION % HETROW' 92199P - 1012'b sollos HETRON 721197;197A 120' - AROPOL 7240:7430 SERIES m- RESIN TYPES HETRON 700 7ooc '20 _ _ HETAON 920 SERIES,980 1:‘: - loo 100 100 AMBi90 5 10:85 - 80 - - 100 100 8OINR 60 120 80INR lCK!NR - 100 100 -I93 -90 -1190 - BOINR - - %3'120 NRIOO 100 -ma 851- 220150 21G,- 5730 NPJ- NR 801- 80 AMB - 100 - NR *0.:_ - NR 100 Unknown NR8C' - - NR 100 100 IOU @ 75-F 100 100 25 50 70 100 100 100 99+ -/160 NW12OI150 -/150 --I150 a5 85 AM0 100 100 85 85 120 NR 1601140 120 - 120 AMB AMBI- AM0 200 - 180 90 wix%- - LSAMB,luR NR 15oi130 1501- - 160!140 25 Sat'd - 25cf180 --ILSI20 1501120 10:12:2 15 25 Sat'd Sat'd 10:2:12 Sal'd Sat'd Sat'd 90.10 100 @75-F --/lM) --ilfxJ 150 - -/160 175'/175/- -I100 120 NR lEo/15c 180193 160190 150 120/- -llE!O 150 220~200 1.60 210 200 225/220 27&23&_ 180 160 160 120 180 210220 210>220 2101220 180,160,180 - 150 1801150 - 2201200 - 210'220 - 18OflM 122 - 2101220 - --INR NR 22012cO - - 120 120 - - - Sat'd 5 --I160 --116O Sat'd - AM0 160/120 - 1601120 140 140 160 - 200 12zO0.1:70:5:14 by vol 100 100 250 NR 120 250 NR 25 140 NRI- 160 125' 100 Sal'd 160 160 140 - 180 - 160 NRBO 180200 16OllW 160/100 160 16C 160 150190 - 160190 - !80:200 1601- - - 2W/lYl NR 250/200 NR - NR 160/200 125/14OlAMB - - 120 100 100 210~220 _ 250 250/200 - - Satd 5 NR- - - --12w100 210*16C - 180,- -I170 -/160 250 --127e*/- 120 200:150 - Sal'd Sat'd - 160'180 - 16011701110 2M - 2001120 NR - NR _ 35 2510 8G'?20 160,N9100 _ - Sat'd 55 - - AMB NR 90 250 80 - ‘.P NR - Sat'd - AMB - NR 2001150 LS.AMB.NR AM0 16Oi130 160 NR NR AMB NR80 21013ol NR 210,300 LSAMB150 AMB.150 AMB tseellsl Of trademarksand product "arnes (continued) 188 Corrosion Resistant Materials Handbook TABLE 1.54: POLYESTER AND VI ‘L ESTER RESINS-ASHLAND (continued) SERVICE CONCEN. TRATION % CHEMICAL ENVIRONMENT Chlorine Dioxide Process Generator Covers’ Chlorine Dioxide Retention Tower’ Chlorine Dioxide: Sodium Carbonate and Bicarbonate. pH 6 Chlorine Dioxrde: Sodium’Chloride’ .............. Chlorine Dioxide, Vapor Chlorine Dioxide-Washer Hoods, Ducts ... Chlorine Dioxide, We? .............. Chlorine Dioxide: Sulfuric (lO.Shl) .......... Chloroacatlc Acid ........................ ....... Chloroacetic Acid Chloroacetic Acid ......... : : : ::: Chloroacetic Acid Plant Water Scrubber :: Chlorobenzene .... .. Chlorobenzene Vapor 6 Condensate’ ... :: Chlorolluocarbon ........................ Chlorofon Alkaloids, HCI, Acetic, Sodium Chloride, Water Fume System ............ Chloroform, Llquid ....................... Chloroform: Methylsno Chlorida: Carbon Tetrachloride, Small Amount Methyl Chloride, ii,O, HCI @ lOOoF ............ Chloroform, Vapor .................. Chlorosulfonic Acid ...................... Chlorothene N.U.f ............... Chlorotoluene (0) .......... : : ........ : : Choline Chloride; Reactlon of Trtmethylamlne HCI and Ethylene Oxide ................. Chromate-Zinc Blend lnhlbltor Strbillzed ... Chrome Acid Plating Bath Vapor ............ Chrome Anodizing Solution .............. Chrome Barrel Plating Fumes ............. Chrome Bath, Black, Chromic, Acetic, Barium Acetate ....................... Chrome Bath, 19% Chromic Acid with Sodium Fluorosilicate and Sulfate’ ............... Chrome Frae Can Treatment, pH 6 .......... Chrome, Hard, Plating Baths ....... :. ...... Chrome Phosphate Can Traatmant, pfi 2 ..... Chrome Plating .......................... Chrome Plating Bath Vapors ............... Chrome Reduction Process ................. Chrome Raductlon Procass Liquor ......... Chromic Acid ........................... Chromic Acid ............................ Chromk Acid ............................ Chromic Acid ............................ Chromic Acid ............................ Chromk Acid ............................ Chromic Acid ............................ Chromic Acid ............................ Chromic Acid ............................ Chromic Acid ........................... Chromic Acid Evaporator, Vacuum, Recovery Units wlth 20% by Volume Concentrated Sulfuric @ 160-F ....................... Chromic Acid, Intermittent .................. Chromic: Nitric: Hydrofluork Acids’ .......... Chromic: Nitric Hydrofluork Acids’ .......... Chromic: Phosphoric: Hydrofluoric Acids’ ..... Chromic: Phosphoric: Hydrofluoric Acids’ ..... Chromic Acid: Sodium Fluoride. High Agitation’ ......................... Chromic: Sulfuric Acids .................... Chromic: Sulfuric Acids .................... Chromic: Sulfuric Acids .................... Chrornlc: Sulfurk Acids .................... Chromic: Sulfuric Acids .................... Chromic: Sulfuric Acids .................... Chromic: Sulfuric Acids .................... Chromic: Sulfuric Acids’ .................. Chromic: Sulfuric: Hydrofluosilicic Acids’ ..... Chromic: Sulfuric: Hydrofluosilicic (Chrome Plating)’ .. ... Chromic Oxide in 300°F end 160°F’Air,’ ... Quenched with 1OO’F Water, 5060 fps t&e hsl of trademarks and product names HETRON’ 92 99P _ - 180 - loo 120 5.3 7 35.23 Sat’d - TEMPERATURE. HETRON 721971197A ‘F FOR RESIN AROPOL 724017430 SERIES - 180 200 SAT Sal’d - - 140 120’ 1201Qa - 25 NR 90 50 NR AM6 NR 1301NR NR TYPES NETRO” 700’700c HETRON 920 SERIES!990 - _ _ - NR - NR 120 QO - 200 150 NR NR - lo(1 NWNRI- NR - NR - N F&SO - COX 3040 Q 110-F NR 100 100 0 12O’F NR Nh- NR - 100 15&- 156 - At.46 NR - - NR NR NR - - - 100 NW- 39:65:5 NR NR NR NR NFU- NR NR NR 100 100 0 6O’F NRNR- NR NR - NR NR - NPJNR - 100 @ 200-F NW- NR - - 100 NR 100 - 125 160 LS125iNR - - - - 12Ol- 200 150 - - 115 - - 200 NR - NR - 100 NR - - - 125 - NR- - 1M 130 - - 1M - Q 100-F - @ 12O’F 25 10 2Ockl&Y- 2w 1% 15 LS200’1LSXXllNR 150 20 30 140 NR 40 M 6.5 ltwgal 60 NR AMBI- NR lOQi120 NR NR 601100 NR NR NR - 180 NW60 NR NR NR - NR NR NR - 22@220/2301230/- 5 NR - 40 vapor/- 140 140*11404150 - 1% Sat d NR 120 56 oz/gal NR NR - NR NR NR NR - NR NR NR NR NR NR NR SAT/-/- NR xx) NR 60 NR 62:1.5 7:40.2 - 60 103 9.3:6.5:11 - 100 NR NR NR 136 - 153 NR 6353 oz/ga1 33:0.33 or/gal 140 140 NR NR 530.53 177 NR NR NR NR NR 36:ppm 150- odgal 3:16 16.5 x)s?g 12.5.16 - 180 225/225/- 2032 QO 35.2:O 2:0 4 450305 OUgal <2 - 115 - 115 NO chemical attack wth - NR 1520 5:2:3 40:0.4 ougal SAT - NR - NR NR NR NR 197. not swtabie NR due to abrawn (continued) Synthetic Resins and Polymers TABLE 1.54: CHEMICAL ENVIRONMENT POLYESTER AND VII Ni fL ESTER RESI (continued) SERVICE TEMPERATURE, OF FOR RESIN TYPES J- Chromic: Phosphoric: Hydrofluoric Acids’. .... Chromic: Phosphoric: Hydrofluoric Acids’. .... ...... ................. Chromic Sulfate Chromium Hardening Fixing Bath, ........ Photographic .. .. Chromium Hardening Stop Bath; Photographic . ........................ Chromium Potassium Sulfate ................ Chromous Sulfate .......................... Citrate Process for SO, Removei .............. Citrext Process for SO, Removal ............. Citric Acid ............................... Citric Acid ............................. .......................... Citric Acid ..... Citric: Lactic Acids ........................ Citric AcidlSuifate/Chlorlde in Mixed Solvents-Minerel Spirlt Type @ 7S-220°F .... Clay Slurry 20%, 20% Potash in . Sat.Brine@AMB.. Cleaner 508T .............................. Cleaner, Biodegradable, All Purpose Liquid .................................. Cleaner 8 Disinfectant, Pd 94t ............... Coal Dust Scrubber ........................ Coal. Med. Sulfur, Particulate Scrubber, pH 1.439, Ci560-1200 ppm, 300,ooO ACFM .... Coal/Water Slurry @ 8o°F ................... Coatlngs, Water Reducible @ 120°F Acrylic Wet Ink Varnish (PPG industries) ..... Polyester White Enamel (PPG industries) ..... Epoxy Spray Liner (PPG Industries) .......... Acrylic Spray Liner (PPG Industries) ......... Cobalt di (2 ethyl hexyl) phosphate: tri-m.butyl phosphate: Shell’s livestock spray base ...................... Cobalt Nitrate ............................. Cocamidopropyl Betaine .................... Cocamidopropyi Dimethyiamine .............. Coconut Fatty Acid Dlethanoi Amide .......... CoconutOil.. ............................. ............ Codliver Oil .................. Collee Roasting Fumes ................... Combustion Gases, Particulate, Cooling and Washing with Water .................. Condensable Liquor, pH 9, Pulp and Paper Mlii .............................. Cooling Tower Inhibitor, ChromateZinc Blend, stabilized ......................... Coollng Towers ............................ Cooling Water”, ph 5.57 .................... ....... Cooling Water, 20 ppm Chromate ........... Copper Acetate ............... Copper Chloride ........................... Copper Chloride: Silver Nitrate ............... Copper Cyanide’ ........................... Copper Cyenide Plating ..................... Copper Cyanide Plating Bath, (10.5% Copper and 14% Sodium Cyanides; 6% Rochelie Saitsp @ 19tIOF ............................... Copper Cyanide, Potassium Cyanide, Potassium Hvdroxide’ Copper Electrolytic Cells Copper Extractant, Ion Exchange Oxime Type Copper Fluoride] CopperLeachTanks........................ Copper Matte Dipping Bath, 30% FeCI,; 19% Hydrochloric . . Copper Nitrate Copper Oxide: PbSO,: S: FeO: ZnSO,: Bi,(SOJr Dust ..__.... Copper Oxychloride Copper Oxychloride Copper Pellet Smelter Copper Pickle Bath, Sulfuric/Water _ S-ASHLAND 189 CONCEN. TRATION % HETRON’ 92/99P HETAON 7211971197A 9.3:6.5:11 All - _ - 60 - 80 - 7:40 2 Sat’d Sat’d Sat’d @ 265-F - 150 140 140 160 BP’ - -1200 BP1200 _ 150 170/l 40 1601150 160/150 NR - - - loo - 100 - 150 Liquor Hetron 1O/90 - - 30:5:65 Sat’d 100 100 150 197-3 with abrasion NR” SAT NW’ NR NR” SAT NR - 176 -/140/- - 120 - 120 100 - - loOI- 100 - - 130’ - At.40 - - -/I20 125 AMB 160 360’ - 14017YAMB - 140175 _ - Fumes 1 gal19 gal “Dissolved so/Ids. 1574.2183 ppm: PO.. 0.25 ppm; tofal PO., 7.3 pprn; Cu. 0.7 ppm; Zn, 3.4 ppm; Fe, 7.8 ppm; CaCo, 450 ppm max.; Chromate, hexa. 18-22 ppm. C/, res,doal, 0.2-0.45 ppm: NaCI, 527.702 ppm. tSee 130’/- AMB - AMB 1601130 160/- 180 1601150 - 2201200 - 115 - AMBI_ _ LS125INR _ _ - 125 175 150 1401- - AMB 1501130 - 1401160 120/15Ol160 _ 130 NR --INR - 120/- NW- 1CHl - 120 - 200 160 - SATINRISAT!- 120 AMB - SATI- 120/- 200190 - 250 SAT at 7 fps 120/- Sat’d Fumes Sat’d BP’ NR - 140’/- 250 - l&25:25 10.6 3 20 2101220 140/- Sat’d 1533 6:3:2 angal - Filler Satefactory NR --I-/NR 150/- 100 - resistant -/-/NR -/--INA 1W 100 100 - Sat’d - 160 220 NR _ 160 100 - Sat’d Q 75°F 140 140 - - SAT @ 12 fps 100 Sat’d _ 150 - Unknown 40 Slurry HETAON 920 SERIES/980 too _ - - HETAON 700/700c 100 Sat’d 50 AROPOL 724017430 SEAIES WNR - 200. - 170 180 1601160 2101220 _ 2101220 - SAT 1201- 200 _ - - _ _ 150 NR - - _ 160 140 160/140 200 300/3001175 list 01 trademarks - - - zoo/- 220/200 210/220 - - _ NR - _ - _ NR - - and product names (continued) 190 Corrosion TABLE 1.54: Resistant POLYESTER Materials Handbook AND VINYL ESTER RESINS-ASHLAND (continued) SERVICE CONCEN. TRATION % CH.#lCAL ENVIRONMENT - Copper Pickling Bath (Fe,(SO.),, &SO.) Copper Plating Solution(45% Cu(BF.),; 19% Copper Sulfate; 8% Sulfuric’ ..... Copper Refining Cells ................. Copper Smelter Fumes ......... CopperSullate ................ ::::...I:. Copper Sulfate: Sulluric ................... Copper Sulfate: Sulh~ric ................... Copper Sullate: Sulfuric Acid ............... Corn Oil _ - Sat‘d 50.xX1 gpl ................................ 2@3O.@JO gal 220 _ 180 SAT - 150 1801120 - 120 - lM’/- 250 Slurry All - - - - - 100 - loo - 100 - 100 100 lWl- 100 -/NR 100 - 100 NR 100 100 @ 75-F -/NR -/NR AMB - NA NR 100 12:5 -/NR SO - NR 130 134X- - 10:1020 - _ 22o:zw - 2’0 - laa 2iOi250 - 150 - 120 1eOllW 120*:150’200 2’0>22C - 210 220 _ 180rloo - ‘50 200 - NR - NR IBOI_ 130 - - 210 180,150 1301110 2w - 2101220 - 210 18ollM 200 2101230 - 180 - 100 - - LS125iNR - - - AMBI125 - 125 90 650 LSSAT - - - 212’ 212/NR 217J2w LS to 2lOiNR NR 14W- 1W - 175 175 140 NR NR Q 100-F 100 - 100 3 75 - 103 NFU- 150 NR 14W- 2.5 17Y1601NR 150/NR - NR NR - NFL- 180 180 - - - - - 200 - loo - l&I 212 1SO/w AMB”INR” - NR’I- 80 - 2101220 - - 2!0~220 - 1801212 200 - AMB - - AMB’I- AMBI- NR NR NR 120 - 120 loo loo loo 100 - loo 100 16LX- 100 Sat’d 1w 160 I40 loo/- tSee NRI120/1&l 120’1lW/:001- - lW/- 1w lW/- 120’ - 100 - NR 180,- - list of trademarks - - I&l/- 3 NR- loo NFU- - 150 - Sat’d loo - Kv120 150 IS0 1w 160 - - Sat’d - - - 100 Cone - HETROH 920 SERIES980 - Vapor 100 10:10:1:79 lank 22Ol220 AMB 100 - 955 TYPES HETRON 700!700c - 15Ol- 1228 100 ‘F FOR RESIN AROPOL 7240:7430 SERIES I50 250 - 5-18 Starch .................. ........ Corn Sugar ........... ............. Corn Syrup, Acid, Decoloriring ............ Corn Syrup, Crude Acidic ..... CottonseedOil ............. 1: .:..:::: Cresol ................................. Cresol Fumes ........................... Cresylic Acid ............................ Cresylic Acid Fumes .. ................... Cresylic Acid: Sodium Hydroxide’ ........... Cresylics, Water, Neutral Oils, Mercaptans. H,S, Waste Liquor, pH 56 .... CrudeOil,B ............................. Crude Oil, Sour ......................... Crude Oil Storage Tank Bottoms ........... Crude Oil, Sweet ......................... Cupric Sulfate: Fe& Bulfair: Sulfurtc Acid .......................... Cutback Diluent, Refinery ................. cw-ft 102 .............................. CyafSlOlt.. ........................... Cyanoacetic: Methyl lsobutyl Ketone; 0.6 Sulfuric in Saturated Sodium Chlorfde @ lOOoF ...................... Cyanuric Acid Tank with 16% Sulfuric, Steam and Calcined Urea ................ Cyanuric Chloride Scrubbed with 6.26% NAOH’ Cyclohexanr ............................ Cyclohexane ............................ CyClohOxaM: Acetone: Hrxan: Watr ....... Cyciohexanono .......................... Cyclohexylamine: Hydrochloric Acid ........ Cycl~Octadlrne ......................... Cygont 400 ............................. Cygont 400 ............................. Darext46 ............................... Daxadt 30 ............................... DDT. Inrectlcide Bolutlon ................... Decanol ................................. Dechlorinated Brlnr pH 2.3, Fm Chlorine (fracre) ........................ Deionized Watep ......................... Deionized Water, High Purity, 1.5 )rmho/cm. .... Demineralized Water ...................... Depleted Na 6 K Brines .................... Deamuttor I Deoxidizer for Aluminum’ ..... , .. Desulfurtzer Feed/Rofiney ................. DosulfurIzing SO,, H,S wlth Monoethanolamlnr ..................... Detergent Alcohols ........................ Detergent Base-Tridecylbenrenr Gulfonatr Detergent, Biodegradable, Llquid ............ Detergent, Dimethyl Benzyl NmAlkylType with 23% HCI. 77% Inerts ................ Detergent, Dlmethyl Benzyl N-Alkyl Type with 25% Phorphorlc. 75% Inert r .......... Detergent, Dirhwrrhing. Llquld, Biodegradable .......................... Detergent, Organic pH l&11’ ................ Detergent, Pax Hyrpwdt ................... Detergent, pH 6 ........................... Detergent Solution, Buildt pH 9.10, 1012% Solids’ ......................... Detergents, Germicidal .................... Detergents, Organic ....................... Detergents, Sulfated ..................... as m f TEMPERATURE. HETRON 72/1971197A - _ - Corn “NO change m ware, at 0 1 tf z lammare/gal. “AROPOL 7530 satslactory HETROW’ 92!99P 120 - _ 1201100 - and product names (continued) Synthetic TABLE 1.54: POLYESTER AND VII CHEMICAL ENVIRONMENT ........................ Dichloroethene ........................... Dichloroethylene .......................... Dichloromethane ......................... Dichloropene: Dlchloropropane .............. Dichlorophenol ........................... Dlchlorophenoxyacetlc Acid ................ Dichloropropane .......................... Dichloropropane: Dichloropene .............. Dichloropropene .......................... Dichloropropionic ......................... Dichromate Bleach, Sulfuric, Photographic .......................... Dicoco Dlmethyl Ammonium Chloride ........ DiCrobe NNT, Germicidal Detergent .......... Dlcyclopantadiene ........................ DieselFuel............................... Diesel Fuel, Premium ...................... DiethanoiAmine .......................... Diethanol Amine .......................... Diethyl Benzene .......................... Diethyl Carbonate ......................... Diethyl Ether ............................. Diethyl Formamide ........................ Diethyl Ketone ........................... Diethyl Maleate ........................... Diethyl Maleaie: Water ..................... Diethyl Sulfate .......................... Diethylamine ............................ Diethylene Giycol ......................... Diethyiene Glycol Nebutyi Ether .............. Diethylene lmide Oxide .................... Diethylene Trlrmine’ ...................... Diethylene Triamine: Ethylene Diamine: Sodium Hydroxide: Water’ ................ Dlethylhexyl Phosphoric Acid (In Kerosene) .... Digester Blow Down Vapors @ up to 220°F .... Digester Room, Pulp Mill, Floors, Spills ....... DigiycolamineG 270°F .................... Diglycolamine. Sat’d. with CO, and H,S @ 27OOF.. ......................... Dihydrcgenated.Tallow Dlmethyl Ammonium Chloride: Aqueous isopropanoi ............ Diisobutyl Ketone: Ethyl Hexyiacetate: Butyi Alcohol ........................... Diisobutyl Phthalate ................ ...... Diisobutylene ............................ Diisocyanate, Diphenyl Methane ............. Diisopropanolamine ....................... Dimethyl Acetamide ....................... Dimethyl Acetamide ....................... Dimethyl Benzyl N-Aikyl Type Detergents with 23% HCI or 25% phosphoric and rest inerts .......................... tSee 11s of trademarks (continued) SERVICE TEMPERATURE. “F FOR RESIN TYPES CONCEN. TRATION % Detergents, Sulfonated .................... Developer, Photographic, Caustic’ .......... Developer, Photographic, Moderately Alkaline ............................ Developers, Color ......................... DFR.lZlT ...................... ^. ....... Dialiylphthalate ........................... Di-Ammonium Phosphate @ 225OF .......... DFAmmonium Phosphate: Ammonium Sulfate Di.Ammonlum Phosphate Vapor ............. Dlbromophenoi ........................... 2,3Dibromopropanol Q 120°F .............. Dibromopropanol; Small Amount Trim bromopropane & Brominated Organics ..... Dibutyl Ether ............................. Dibutyl Phthalate ......................... Dibutyl Sebacate ......................... Dlcalcium Phosphate “gas”: Llquid; ScrubbingpH54.. ....... . .............. 2. SDichioroJ-Aniline in 32% HCI @ 170°F .... Dichloroacetaldehyde ..................... Dichioroacetic Acid ....................... Dichlorobenrene .......................... 1.2.Dichloroethane ‘L ESTER RESINS-ASHLAND 191 Resins and Polymers All 65 10:10 100 6%12O’F 100 @ 100 IW 100 - IW’F 100 @ 265’F 100 100 @ 100 100 100 HETRON’ 92199P HETAON 721197/197A - AAOPOL 724017430 SERIES 100 LS/LS/NR LSlLSlNR 80 Ah40 HETAON 920 SERIES/980 16OllW 2W’ - 2101220 - - - _ 80’/80/60 80’/80180 80’180180 HETAON 700/700c lW’/IW 160/13a AM0 - 100 180 - lCOI1501180 I W/SAT - NR - NR NR - NR NR SO’/- 80 15O/AMB 80’1150 1M/200 Ah40 NR NR 210/150 300 -/LSINR NR NR NR NR - - LS/NR - LSlNR - NR NR - NR LSI_ NR NR NRIlW NR NR NPJNRI- NR NR NR NR NR NR NR - NR - NR NR NR IO0 2 NR NR - NR - NRI- 100 @ 100-F NR NR NR - NR - NR - 100 100 NR NR NR - NR - - 100 Q 1W’F - 80 - 120’ 100 loo loo 100 175 - 120’112u - 120 - 175040 AMBI- - 30 100 110 110 AMBI- IW 100 120’ - NR - NR - 100 @ 75’F NR - NR - NR 100 @ 75’F loo 100 @ 75’F 97~3 @ 212’F 100 loo 100 100 10 100 10:10:10:70 20 - NR 1w 100 85 100 NR -/SAT/- NR NR NR NR NR - NR NR - 1801150 - 2M) - - NR - NR - - LS AMB NR 120/1501200 804120 80 120 801120 NR NR NR NR NFVNFUIOO NR 1501200 so _ 1201150 - loo NR NR LSiNR NPJ- 100 NA - LS/NR NRI- 75:25 120’ 120’1120 120 120/- 80 - 100 AMB IM) - loo 70 100 @ 75’F 150 NR - loo @5:10:5 100 100 - 120 - - - - 100/l 50 AMBIlOO - NR _ - NR NR 801120 _ - - lOOI- and product names (continued) 192 Corrosion Resistant Materials Handbook TABLE 1.54: POLYESTER AND VINYL ESTER RESINS-ASHLAND (continued) SEnVICE TEMPERATURE, ‘F FOR RESIN T\ PES CHEMICAL ENVIRONMENT Dimethyl Distearyl Ammonium Chloride: Aqueous lsopropanol Dimethyl Formamide ........................ ::::::: Dimethyl Formamide ..................... Dimethyl Formamide @ 9O’F .............. Dimethyl Formamide: Terephthalic Acid: HCI: Water ........................ Dimethyl Morpholine Q 120°F .............. Dimethyl Phthalate ........................ Dimethyl Phthalate: Methyl Ethyl Ketone: MEK Peroxide .................. ...... Dimethyl Sulfoxide ........................ Dimethyl Tin Dichloride. .................. Dimethylamine .......................... Dimethylamine ........................... DMP: MEK: MEK Peroxide .................. Dinitrobutyl Phenol in 25% Sulfuric Acid Weste @ 150°F .................... Dloctyl Phthalate ......................... Dioxane ................................. Diphenyl Ether ........................... Diphenyl Methane Diisocyanate ............. Diphenyl Oxide ........................... Dipropylene Glycol ........................ Dipropylene Glycol Dibenzoate .............. Dishwashlng Detergent, Liquid, Biodegradable .......................... Dishwashing Liquid ....................... Disinfectant, Chlorinated Phenol Type ........ Disinfectant & Cleaner, Pd 84T .............. Dispersant, Anionic, Blend .................. Dispersant, Nonionic, Blend ................ Dispersing Agents ........................ Distilled Water’ ........................... Di-Syston ............................... Dlversey 514T’ ............................ Diversey808T’ ............................ Divinyl Benzene ........................... Dodecane ............................... Dodecene ............................... Dodecene, Trace HCI ...................... Dodecyl Alcohol .......................... Dodecyl Benzene Sullonic Acid: Sulfuric Acid: Water: Oil .................. Dodecylbenrene Sulfonic Acid Dolomite Kiln Gases, Wet .................. Dowclene ECt ............................ Drain Cleaner, Liquid (Spartan Chemical) Q 80°F ............................... Drewsparse 732t .......................... Drewsperse734f .......................... Drewsperse735T Q 12S°F .................. Drewsperse 738T @ 125OF .................. Drewsperse 74lT Q 125°F ................. Drewsperse780f .......................... DW-875T, Styrene, Acrylic Emulsion .......... DXE: Xylene; Trace H,SO,; Flake Caustic ...... Dye Plant Water Treatment, pH 2-3 ........... EDTA ................................... Electrasolt Detergent ...................... Electronics Plant Waste .................... Electrostatic Precipitator Fumes, ‘11% Carbonate, 3% Sulfate, 1110% Fluorides, 1110% Bicarbonates ..................... Electrostatic Precipitators, S; H,S; SO, ........ Elvaset ................................. Emulsifier, Oil and Grease, Alkanolamide Type ................ EP52.A85t ......................... Epichlorohydrin ................ Epoxidized Soybean Oil .......... Epoxy Spray Liner, Water Reducible 0 120°F (PPG Industries) ...... Eptamt, Herbicide’ .............. Erional NWf .................. Esters, Fatty Acid .............. +~eelist of trademarks and productnames CONCENTRATION % 72~25 HETAON’ 92/99P HETRON 72119711971 AROPOL 7240/7430 SERIES HETAON 700170’lc 7.2 120/- 120’ 100 120’1120 _ 30 100 - go NR NR 120 _ NR NR NR NR NW00 NR 150 120/150 - - _ NR - NR - _ - - 7:14:26:51 - 100 NPJ-/NR 100 36:63:1 100 @ 75°F 50 4 NR - 100 LSILSINR --lLS65/NR NR 65.60 130 --ILSBO/NR --lLSWNR 120/NRINR - - - - 60 36:63:1 NRI- up to 16 100 100 NRI-/NR - - NR - - NR 150 NR _ - 120 NR NR _ 16a120 160 120’ 120 120 1504160 120/- 100 100 - 100 - 100 - - - 100 @ 75’F 100 1GfJ 100 100 NR 160 - 1M) - - 120 100 100 - 100 125 100 - 125 125 -/NR NR 125 - - 125 100 100 1 to 10 Dilutmn lW/- 14 ozlgal - &I - - 140 AMB - - - - NR - NR _ - 5.3 ozlga1 1W 210 120 125 1601140 - 125 200 _ 120/150 NR 60/120 60/120 100 loO/_ 2101220 NW120 100 - 100 100 100 NR - AM0 120 100 NR NR - 15X- 150 - - - 150 - _ - 65:10:4:1 All 1W - 100 100 100 1CO 100 @ to 165-F 60 601150 _ 1501160 2101220 - NR/- NR - - 125 125 125 125 125 125 - - SAT LS/NR SAT SAT SAT LSlNR LS/NR _ 125 125 - SAT SAT 125 100 5050 HETAON 920 SERIES/980 NR/- 36 5 - - - - - 100 1M) - 100 100 - - 60 NR 180 AMB - 165’ 260/260/100 NR - NR - _ - - AMB - AMB - 165 _ 185/k - 100 loo/- AMBI- 100’1100 120 - AM8 - AM0 - 120 AMB - 125 - - 150 AM0 NR 1201150 - - NR COilC 1Cil - 120 AMB NR _ NR - NPJ- AMB’ AMB!- loo - 120 1801150 180 160 (continued) .......................... ... ,,,::: ::: ... ............. 194 Corrosion TABLE 1.54: Resistant POLYESTER Materials Handbook AND VINYL ESTER RESINS-ASHLAND (continued) SERVICE CONCEN. TRATION CHEMICAL ENVIRONMENT ........ Fertilizer Scrubbing Fertilizer Solullon ................... Fertilizer Solution .................. Fertilizer Solution, Nitrogen ........... Fire Retardant Liquld (Osmose Co:)’ ........ Fish 011 and Meal Exhaust Gas .............. Flsh Tanks’ .............................. Flxlng Baths. Phologrrphy ................. Floor Wax Polymers ....................... Flue Gas” @ 26&34O*F .................... Flue Gas” @ 190.280°F ................... Flue Gas, Bohr up to 45o’F ................ Flue Gas, Chemical Incinerator .............. ............. FlurGas,CorlFlredupto350°F Flue Gas, Garbage lnclnrrator ............... Flue Gas, llog Fuel, Some HCI, pli 3.7-7 ....... Flur Gas, Ruovery Bolla up to 400.F ........ Flur Gas Scrubbing, Ammonia Process ....... Flue Gas, Wet*’ ........................... Flue Gasn; Some Sulfuric Acid Fumos. Abraslvo Clay Partlcl~s .................. Fluoborlc Acid’ ........................... Fluoboric Acid’ ........................... Fluoride Salts + HCI’ ...................... Fluorinated. ChlorlnaI4 Acid Organlcs N@utralizad Wlth Limo. Effluon~ ........... Fluorlna’ ................................ Fluodnr Gas’ ............................ Fluorlnr: Phosphorus Pontoxkte ............ Fluorine Scrubber, Rocovr H,SIF,’ ........... Fluomlubos~, Ollr and Gnasoa ............. Fluoslllck Acid’ .......................... Fluosiliclc Acid’ .......................... Fluoslliclc Acld’ .......................... Fluoslllclc Acid’ .......................... Fluosillclc Acid Furnn, Wop ................ Fluowlfonk Acid ......................... Fly ASJl Sluny ............................ Formaldahydo ............................ Formaldohydo ............................ Formaldohydo ............................ FormaldrhydeO 150°F .................... Formaldehyde. Phenol, Sulfuric Fumos ....... Forrnsmlde .............................. Formk: Acetlc Acids ...................... Formic Acid’ ............................. Formic Acid* ............................. Formic Acid’ ............................. Formic Acid’ ............................. Formic Acid 60%, Sat’d with NACI: Unknown Organlcs ...................... Formic Acid Vapor’ ........................ Fourdrinier Drying Section Fumrs ........... Fourdrlnier Liquor .......................... Freon II ................................. Fruit Julus’ ............................. Fuel Oil, No. 1 and No. 2 .................... Fuel Oil, Naval, ML-F-669A ................. Fumigant, Sol1 ............................ Fumigants ............................... Fungicide, Phsnate Based .................. Fungus, 95% Relative Humidity MIL E4272C Aspergillus Flavus (lCl636) ................ Chaelomlum Globosum (6205) ............. Memenoniella Echinata (9597) ............. Ponicllllum Cltrinum (9649) ................ Furfural ................................. Furfural .................................. Furtural .................................. Furturyi Alcohol ........................... Furnace Oil ............................... nAROPOL 2’ vol. H,O. 7343 SStr~lSclOy. ’ : SO,, 0.25: SO,. 0.03; CO, 76. I/y ash. 5.0 9rrms 12.5: NI. 74.6. 0,. 4.9: w. nlocrry60 IPS “VoI. ‘I SO,. 0.25: SO, 0.003. CO,. 12.5. N1. 74 6. 0,. 4.9. H.O. 76 t/v ash. 1.2 WW7U I?: YCIOCI~Y 8 IDS % - HETROW‘ 92l99P 6.6.6 15w- 10340 26 - 5oL - 16 TEMPERATURE, HETRON 7U1971197A ‘F FOR RESIN AROPOL 7240 1430 SERIES - 80’1 - w- - - @Q” 175 175’/- 175 - AMB - 60 - 80 160 - 160 - 160 - - 180 180 - 10 Sal’d BPil6O -rw 3O:10 100 @ 75-F im 3m13m/SAT’ISAT’INR lea 155 SATISATINR 125 BP Nix- AMBI- NPJ- LSlSY- NR - - 1%X251- NW- to 25 2x37 xx) --190 5052 37M -l9O --190 lx) NR AMB 2m - - - AMB 150 1M NR - AMB - 100 NR 150 - i 50~2m - AMB 50 AMB 100 NR 15c1 SAT AMB NR - im*iLs - imks 200 15&W 150 140’ 1201NR NR 150 160 120 AMB - 120 - 100. im’ 1m - - 13OiW 130 - - - - 17W17YNWNWAMBJw86/- - 86/- 5 mlAMB 170 175 NR AMB 17w130 AMB - NW- NR NR 125 125 66 86 66 66 66 66 66 AMB 66 100 - 120 - 125 - - - - lx)/150 - - NR - NR AM&- rrO. 72% S0,‘5% O/12% C0,70% N,ll3 4% H,O; 5 pm7WlP 2.3&X7 burn HQ 1020 Pam HF. rus, 14h?1 t!See list of trademarks 75 - - 10 50100 im loOi- - 120 Gnlc. AMB - 194 - 300 im 801120 1m 194/- 100 COW. AMBJNR - 40 5350 loo 1x1 im200 AMB - 150~1rn AMB 1501120 AMB 10:10 25 2101220 16012rn - - NFU- im 160 120 - - twi- 700 S&d NPJ- - - 160 10 SATiNR - - 160 AMB NR 10 NR - NR - -IAMB @ 200-F - 65 35 Unknown - NR 25 1751- NWNRI- 105 - 160 180 - - AMB im 12on50 _ NR NR - 120140 10 im @ 80-F - HETAOW 920 SERIES/990 NR lx) 1.5:1.5 100 SATlSATlNR SATISATINR SAT/SAT/NR TYPES HETRON 7001700c and product lm/wO NR 01 1.2% H,SC-. names (continued) Synthetic Resins and Polymers TABLE 1.54: POLYESTER AND VINYL ESTER RESINS-ASHLAND CONCEN. TRATION % CHEMICAL ENVIRONMENT Fusion 12.62t Q 175OF .................... G.61T .................................. Gallic Acid ........................ Gallotannin ........... .... ............. Galvanizing Line Fumes ................. Garbage Incinerator Fumes ................. Garbage Incinerator Water Scrubber ......... Gas Oil. Dirty, Refinery ..................... Gasohol; 91.6% Unleaded: 6.2% Ethanol ...... Gasohol; 93.6% Unleaded: 6.4% Ethanol ...... Gasoline ................................ Gasoline, Aviation ........................ Gasoline: Benzene ........................ Gasoline Components ..................... Gasoline, Ethyl ........................... Gaaollne, Lead Free ....................... Gasoline, Martna ........................ Gaaollna. MS-08 ........................ GelstIne; ........................... Geothermal Water ................... Gamtlcidal Detergents ................ Geyser Water, Condensate ............ Glass Cleaner, Fortified with NH, (Spartan Chemical Co.) .............. Globrita 15T ......................... Globrite X2tMT ...................... Gluconic Acid ....................... Glucose ............................ Glycerin Still Talllnga with Small Amount Sulfuric to 330°F ................... Glycerine ........................... Glycerine in Salt Sat’d. Water .......... Glycerol Dibromohydrln; Small Amount Tribromopropane & Brominated Organic8 ......................... Glycol.............................. Glycollc Acid ........................ Glycollc Acid ........................ Glyoxal ............................ Glyoxylic Acid @ 215OF ............... Glyoxylic Acid: SO, @ 215OF ........... Gold Pickling, Sulhuic ................ Gold Plating, pH 4.4 .................. Gold Plating Solution (23% Potassium Farrocyanide with Potassium Gold ’ Cyanide and Sodlum Cyanide), ....... Gold Smelting Furnace Gas and Dust.Wetupto4CxYF ............... Golden.GloT .............................. Golf Ball ScouringCleaning Solution .......... Green Liquor ......................... Gypsum Slurry + 1% H,PO,, + Trace HF’ Gypsum Slurry Cooler (Fertilizer Plant) ..... HalsoSSt ............................. Hard Chrome Plating Baths .............. HAS (Hydroxylammonium Acid Sulfate): Sulfurlc: Water’ ...................... HAS (Hydroxylammonlum Acid Sulfate): Sulfuric: Water’ ...................... HCI: Methylimlno Ether. Methanol: Isobutyronitrile: Impurities ............. Heating Oil ........................... Helium, Liquid ......................... Heptana, Dissolved Heavy Organics. Traces H,O, ZNCI,, HCI .60% Methanol, H,O, HCI, ZNCI,, Organics .2 Phases ............. Heptane, normal ....................... Heptane, Traces Water, HCI; Other Heavy Organic8 ...................... Haptane, Vapor & Condensate ........... Herbiclda, Liquid* ...................... Herbicide Powder & Fumes .............. Hexachlorocyclopentadiene ............. Haxachlorocyclopentadiana, Crude ....... Hexachlorocyclopentadiana; High Purity ... tSee hst ottrademarks and 100 Sat'd (continued) SERVICETEMPERATURE.°FFOR I HETRON' 92/99P NR - HETRON 7211971197A NR 125 100 - - 60 200 - 200 160 - - - - 60 - 194/l% 1751- 194 100 100 SO:10 - 160 - 175 AM6 _ AROWL 7240/7430 SERIES RESINTYPES HETAON 7001700c NR - NR _ _ _ - - AMBI- - 1W'YNR - NR - 100 - 100 - 100 100 - - 100 160 16011CQ 1601150 100 100 100 125 160 125 1601150 1M) 100 -020 160 100 70 200 - 12Y125/- 200 7C-240 - 160/150 - 100 @ 60.12O'F - - All 35 250/- 250125012w 140 16Oll50 14011x) 70100 40 25 25:Sat'd 25 - 140 120 - NR 160 - NR 220/200 loo/160/lOOI100/125 210/220 NPJ2101220 NW200 16012cC 103 - 120 - NW- NR NFU- NR NR NR LS'INR LS"NR 80 Ls/LSi- 150 - lW/- 150 125i- 150 _ 200 - 200 180/- NR NR NR 100 - 100 - 100 - loO/- NR - SATI_ NR - - - NRIAMW- @2CO'F - - - - 140 100 - - - 103 - 1601100 60 100 50 100 - AMB AMBI- - - - - - - __ - 100 100 C0fh.Z. - _ - - - NR - 100 - loOI- &I AMBI-I- HETRON 920 SERIES/980 1301100 1751100 1OO'YNR 100 - 100 195 NRJ- SATlSATlNR - AMBJlDO SAT _ 100 NR 100 190 NR 130 NR - 20:60:20 - 100 - - 100 - - - - _ - - - 11:75:14 23:74:2:0.3:1 100 -/77/HETRON AMBI- 31 SAT, NO Ve!. to .452"F 140 - 1M) AMBi120 2001200/- - 206 100 120 - 120 120 100 - 100 - 60/- 100 w- 2M) 180 90 NR - 110 10 - NW- - ZOO/- 2ca150 - - - - 120 _ NR - 160 160 - 120 tlO/NR 160 product names. (continued) 196 Corrosion Resistant Materials Handbook TABLE 1.54: POLYESTER AND VII ‘L ESTER RESII ;-ASHLAND (continued) SERVICE TEMPERATURE, OF FOR RESIN TYPES CHEMICAL ENVIRONMENT CONCEN. TRATION % Hexachlorocyclopentadlene; Reg. & High Purity Wet With H,O ..................... HexachloroendomethyleneTetra. hydrophthalic Anhydride, Wet ............. Hexamethylenetetramine .................. Hexane ................................. Hexylene Glycol Ammonium Chloride ........ High Purity Water, 1.5 pmhdcm. ............. Hog Fuel Flue Gases, Some HCI, pH 3.707 ..... “Huff”, Misrourf, Okla. or Texas ............. Humid Air, Trace Sulfur Fumes ............ Humid Atmosphere ........................ Hydraulic Fluid, Skydrol SWT ............... Hydrazine ............................... Hydrazine ............... ............... Hydrfodlc Acid ........................... Hydrobromlc Acid ......................... Hydrobromlc Acid ......................... Hydrobromic Acid ......................... Hydrobromic Acid: Copper Oxide: Bromine ......................... Hydrobromlc Fumes Q 290°F ............... Hydrocarbon Alkylation .................... Hydrocarbon With About 10% Acetic Acid, Liquor and Vapor ................... Hydrocarbons: Ferric Chloride Mist .......... Hydrochlorfc Acid’ ........................ Hydrochloric AcIda ........................ Hydrochlorfc Acid’ ........................ Hydrochlortc Acid’ ........................ Hydrochloric Acid’ ........................ Hydrochloric Acida ........................ Hydrochloric Acid’ ........................ Hydrochloric Acid’ ........................ Hydrochloric: Amine Q 2oO“F’ .............. Hydrochloric: Ammonium Thlocyanate ....... Hydrcohlorlc Acid (12%) + Aqueous Ammonia to pH 0.3 ...................... Hydrochloric Acid, 2o” Be: Amine ............ Hydrochloric Acid @ B.P. ................... Hydrochloric: Brighteners’ .................. Hydrochloric: Chlorinated Hydrocarbons ...... Hydrochloric (BZ%):Chlorinatsd Organic Contaminates (phase separation 213 acid: 113 organic) ..................... Hydrochloric Acid (32%): Chlorfnated Organlcs .................... Hydrochloric (32%): Chlorinated Organics: Trlchloroethylene ....................... Hydrochloric: Cl,; Aromatic Sulfonic Acid; H,SO. ............................ Hydrochloric Acid, Cl,. Water, Chlorinated Organics .................... Hydrochloric Acid: 2, &Dlchloro-4 aniline @ 170°F ........................ Hydrochloric: Fluoride Salts’ ............. Hydrochlortc Acid + Free Cl, ............ Hydrochloric Acid, Fumea @ 22529oOF .... Hydrochloric: Hydrofluorlc: Nitrate’ ....... Hydrochloric Acid: Inerts: NoAlkyl Dimethyl Benzyl Ammonium Chloride: Tributyl Tin ChloridelEthylene Oxide/Amine ......... Hydrochloric: Methyl lsobutyl Ketone ...... Hydrochloric: Methyl lsobutyl Ketone; NH,CNS.. .......................... Hydrochloric: Nitric Acid” ............... Hydrochloric: Nitric: Sulluric @ up to 225’F Hydrochloric: Phenol: Aqua Regia ......... Hydrochloric: SW ppm Phenol; Ml ppm Octyl, Decyl, Butyl, Phosphorous Chlorides ........................... Hydrochloric Acid: Phenol: Water ........ Hydrochloric: Phosphoric Acids .......... Hydrochloric: Phosphoric: Butyl Ether ..... Hydrochloric Acid Pickling Tank Covers & Fumes’ ..................... Hydrochloric: Silicone Oils ............... “NO change m water at 0.1 It.’ laminate/gal. ‘*AROPOL 7530 satmlactory. HETRON' 92/99P HETRON HETAON AROPOL 727197119711724017430SERIES 700179ac !3+ 90/- 90 - - _ 100 28 86/80 - 86 - _ 80 WI56 _ - 120’ 80156!120’1120 80.156 120/- 100 1OU 100 100 RH - 155 9w--/- - 200 120 160 120 1M) 10 70 NW- 1058 18 -/160 -/WI - 25 46 50:5:Trace - 100 - w2w120 120 LSlSY- 100 NR NR NA NR _ 200 NR 160/100 2001160 ZOO/160 210/220 2M) 1W 150 - - - - - 160/100 16W_ AMB SATlSATlNR 230 16Otl50 180/150 LS200 230/200 230 150 85190 85l90 230 180’ 150 15OtlOO 125(90 125190 150 150 8Y- 100’ lCQ/NR 230 230 230 36 36.37 SAT/SAT/NR 160 Unknown 160 77 98.8:0.2w/w 20 10:30 - @ 60-F 88.3:11.7 @ 104’F - 99:1 @ 104’F 104-F Unknown 32 - 158-203/- 15 20:5 - Unknown Unknown NW- tSee 180’/- NR - - - NR - - - - NRI- _ - - _ 60’/60/NR - NPJ- -/LS/NR LS/NR LS/NR - LSI- - - 100 -/156-203JNR - _ - - loo/- 203 2lot210/- - - - NR - - NRI- 200 -/SAT/NR 100 NR NRt- 21 SATI- - 60 30 150 100 - NR 100 15:100 NR 160 - - 23:77:0.1:0.1 180 _ 2101220 2101220 210/220 2101220 - 120 2al/- 77:13:10 6 Mola~lWO:10 Conc:0.5:0.5 - SATiNR - 160.220/- - 80 10:30 All - - 120 - - 25 37 10:20:70 150 1501120 140/LSAMB/NR 37.5 1.1:z.g 68.1:0.9:14@ _ -iEa- 15 20 32 ‘20 1501180 _ - 10 100 120/- 120 - 120 Unknown 1.5 as !n 2~3O.LWO gat. tank AMB’VNR” - 80 130100 - 200 200 Unknown 32:<5 HETAON 920 SERIES/990 120 120 -00 215/195 list of trademarks - _ NR - NR - - - NRI- _ _ - - and product names (continued) Synthetic TABLE 1.54: POLYESTER ;-ASHLAND CONCEN. TRATION % Hydrochloric: Sulfuric ......... Hydrochloric: Sulfurk: Antimony Trioxide ...... Hydrochloric: Sulfuric: Nitric Hydrochloric: Teraphthalk Acid: DImethyl’ Formamida: Water Hydrochlork Acid, Trace Phanol; &yl, Decyl. Butyl Chlorldor 6 Phosphorous Trichlortde ............................. Hydrochlork (aqueous) + Organic Solvents .... ..... Hydrochloric wlth 2 6 Dlchlor4nltroanlllnr Hydrochloric, 10% by volume with Ferrk and Ferrous Chlorides, pH 1 .............. Hydrochloric, Sat’d. Ferrous Chloride’ ......... Hydrochloric. Small Amount Acetone .......... Hydrochloric, Traca Organks ................ Hydrochlork. Traca Phenol and Cresylic Acid @ 175*F .................... Hydrochlork, Trrca Toluena 6 Chlorotoluene ... Hydrcchlork Trfmathylamlno ................ Hydrochloric, 60% by Vol.: Hydrofluork, 20% by Wt.: Sulfuric, 29% by Wt.: Sodium Dlchromate, 3% by Wt.a ............ Hydrocyanlc Acid .......................... Hydrolluork Acid’ .......................... Hydrofluoric Acid’ .......................... tfydrofluork Acid’ .......................... Hydrofluoric Acid’ .......................... Hydrolluorlc Acid’ @ 195-F .................. Hydrofluork Acid’ Q 195.F .................. Hydrofluork Acid’ .......................... Hydrofluork Acid @ 1WoF ... .............. Hydrofluork: Chlorfne: Nitric Oxide Fumes’ ..... Hydrofluorlc: Chromic: Nitric Aclds’ ........... Hydrolluork. 49%: Glacial Acat!c: 70% Nltrk ... Hydrofluork, 49%: Glacial Awtic: 70% Nltrk ... Hydrolluork: Hydrochlorfe Nltrfc’ ............ Hydrofluork, 20% by Wt.: Hydrochloric, 80% by Vd.: Sulfurk, 29% by Wt: Sodium Dkhromato, 3% by Wt.’ ............ Hydrofluork Actd: Nltrk’ .................... Hydrolluorlc Acid: Nltrfc’ .................... Hydrofluorlc Acid: Nltrlc’ .................... Hydrofluork: Nltrlc Acids .................... Hydrofluoric: Nitric Acids .................... Hydrofluork: Nitric Acids .................... Hydrofluorlc: Nltrk Pkkllng’ ................. Hydrofluoric: Nltrk Pkkllng Solutfon’ ......... Hydrofluoric: Phosphork: Chromic’ ........... Hydrolluork: Phosphork: Chromic’ ........... Hydrofluork Acid: Stannous Fluorfde .......... Hydrofluosillcic Acid’ ....................... Hydrofluosilicic Acid] ... ................... Hydrogen ..... ........................... Hydrogen Bromide, Dry ..................... Hydrogen Bromide, Wet ..................... Hydrogen Chloride ......................... Hydrogen Chlorfdr, Absorber ................ Hydrogen Chlorfdo, Anhydrous ............... Hydrogen Chloride and Benzene Vapors ....... Hydrogen Chlorldo: Chlorfne Saturated with Trtrachlorocyclopentano, Ccl., Trace .................. Hexachlorocyclopentane Hydrogen Chloride, Cl,, CO,, CO, H,, N,, 0, .................................. Hydrogen Chloride Fumos @ 350°F ........... Hydrogen Chlorfde Gas: Chlorine @ 392-F ..... Hydrogen Chloride Gas, Dry ................. Hydrogen Chlorlda Gas, Wet ................. Hydrogen Chloride. Steam’ .................. Hydrogen Fluorfde, Cl .. Nltrk Oxide Fumes’ .... Hydrogen Fluoride, Vapor’ ................... Hydrogen Fluoride, Wet’ .................... Hydrogen Fluoride. Wet’ .................... Hydrogen Iodide: Iodine Vapor ............... Hydrogen Iodide: Sulfuric ................... ......................... Hydrogen: Ozone ....... Hydrogen Peroxide ........... fSee1st01trademarks HETRON’ 92199P - 1445 15355 302010 - 37 @ 194’F Unknown TEMPERATURE. HETRON 7tlPlI19lA OF FOR RESIN uomt 7240’7430 SERIES - - 1W - - - 80 - - - NR 170 15 NFL- 36 - 32 NW- 2s-30 37:1W 170 - LSJLSINR - 1201- NR NFU- 80 SO LYNR - - 120 BM @ BP 10 2w NFUNW- 2W NR NR 100 AMB 15 loo 20 NR 22 40 15 Unknown. Hot SAT 3-6:2 1:2:5 @ IlO’F 1:X8 @ 1W’F 90 SATlSATlNR SATlSATlNR AMB --I-/LS - NPJ- 80 NR NRI- NR 13.77:10 - 120 240/240/- 140 130 5M @ BP HETRON 920 SEAIES’PBO NR 32 Sat’d TYPES HETRON 7001700c _ 140 loo 90 28 14:7:51 197 (continued) SERVICE CHEMICAL ENVIRONMENT Resins and Polymers lWNR NR 200 NR NR 1OCh’NR 1w wNR NR NR NR - lM/NR NR 93 153 1w 100 LYNR NR LYNR --ILS NR - loo SAT - - loo 120 515 2.57.5 23:20 24:12 Q BO’F - 165 165 NRI- 135 NR - 4.15 @ 190-F 5:50 @ 120-F Unknown NFU- 3.520 24017 11%.59.3 X1:50 @ 220-F 10 35 1W 100 NR HOI @ 210212’F 36 100 NR NR NR NR NR lOY- NR NR lOY- 105 loo 1w - - loo NR 180 loo/- 15o/lW 150 1M) NR 250 90 250 - AMB - 100 - AMB 180 AMB NR l&I - - - NR 100 Cont. - 250 23yz?Y- NR 250 AMB NR - 85 65.35 125 - - Unknown - AMB SATlSATlNR Ul-lknOWn - SATISATINR 100 100 Unknown 120 95 12 90 100 90 150/- 5 lx) 120 120 120 - not 95 l&3 150 - - - IBOIAMB - 21w2u 21w22u - NR AMB - 95 - loo - - 210 18OiNR AMB 158 - - 2u)/24w- Uh-lOW~ 35 66 BP1 25 gPl - - 18012w AMB 150 and product names (continued) 798 Corrosion Resistant Materials Handbook TABLE 1.54: POLYESTER AND VII L ESTER RESI j-ASHLAND (continued) SERVICETEMPERATURE.'F CHEMICAL ENVIRONMENT CONCEN. TRATION % Hydrogen Peroxide ........... ....... Hydrogen Peroxide .................... Hydrogen Peroxide ..................... Hydrogen Peroxide: Sulfuric: ZnSO,:NA,S:O, ............. ........ Hydrogen Peroxlde, Vapor 6 Condensete ...... Hydnqen Peroxide Vapon ................. Hydrogen Sulfide ......................... Hydroxyrcetic Acid ....................... Hydroxyecetlc Acid ....................... Hydroxyrcetlc: Phosphoric: Sullurlc Acids’ .... Hydroxylrmlne Acid Sulfate (Hydroxyl. ammonium Acid Sulfate) ................ Hydroxylrmine Acid Sulfate: Sulfurtc ......... Hydroxylrmmonlum Acid Sullate (Hydroxylamlne Acid Sultrto) .............. Hydroxylrmmonium ACM Sulfato: Proplonic Acid: Weter ..................... Hydroxylrmmonlum Actd Sulfate: Sulhrrk ...... Hydroxylrmmonlum Acid Sullrte: Sulturic Watep .......................... Hydroxylrmmonium Acid Sulfete: Sulfuric Watep .......................... Hypochlorour Acid ......................... Hypochlorous Acid ......................... Hypochlorour ACM ......................... Hypophoephortc Acid ....................... Hypophorphorour Acid ..................... l9eprlCO-B39t .......................... Ilmenite On: Sulfurlh SteernAb Agitation Q 220°F ....................... Iminoethyl Alcohol ......................... Incinerator, Chemical ...................... Incmerrtor,Gerbege. Fumes ................. Incinerator Water Scrubber .................. lodlne: Hydrogen lodlde Vapor ............... IodlneKeroeoneBrtne ...................... lodlne Vapor .............................. lqjarol DAt ............................... Iron Porchlortdo ........................... Iron Perchloride ........................... Iron PlotIn Solution 45% FOCI,; 15% C&I,; 29% FeSO.; 11%; (NH.),SO. ............... Iron and Steel CleanIn Bath, 9% Hydrochloric; 23% Sulluric ............... lrobutyl Alcohol ........................... lrocunt 399 .............................. lsocuret 399 .............................. Irocuret 999 .............................. Ieocyanrte, Polymethykne Potyphoqt ........ IsoDecrnol ............................... Isoprep 33t .............................. Isoprep Ut ............................... Isopropyl Alcohol ....................... ._ Isopropyl Alcohol .......................... Isopropyl Alcohol: Sodium Xyhne Sultrte: OPhonytphmol: Potrulum Rlclnoteata Inertr .................................. lropropyl Amine ........................... Isopropyl PaImItate ........................ ltrconic Acid .............................. Itaconic Acid .............................. Jet Fuel A ................................ Jet Fuel (JP.4) ............................ Jet Fuel PFB .............................. JM.23E.t Adhe8lvo .......................... JM.27lt Adhoslvo .......................... JP.9 Fuel ................................. JP.10 Fuel ................................ Kaolin Slurry .............................. Kerosene ................................. Kerosene, 70%, 10% Irodecanol. 29% organicr: 39% Phosphoric ................. Kerosene: Vapor & Condenrate ............... Kerosene: Xylene: 85% Phosphoric ........... Knofler Fumes .......................... Kymenet,Resin tSee Solution 1151of Irademarks .................. and oroducl names 30 35 50 HETROII' 92199P HETRON 72/197:19lA FOR AROPOL 724017430 SERIES 105/120 loO'/- 1051105iNR loo':lm/- Nfi - RESINTYPES "ETRON 7001700c AMB NR - - - - 100 120 140 All 250 253 35 70 29:51:20 140 140 100 140 - 140 - 2.15.Trac.a 5 50 12W- - go 6%1:10 Gmc. 50 50 100 Flue ge.s 100 100 - - - - - 160 - - - 100 - - - - - - 100 104 AM0 104 AMB 104 AMBlNR AMB AMB AhlB/NR - AMB AMB - loo AMB - - - - - - - - 105 NR"/- 110 300X0160 160 - 150 150 120 - 1751180 - 175 - AMB AMB’ - - -i¶a lR10&6%7 10 AMB' AMB' AMB’ AMBI- AMB AMB - AMB AMB AMB AM&AM&- 120 160/- NR 1651150 NR 165 15&156l- 601NR lW156l- 13ol60 -/lBO 95 160 AMB AMB - 80 - 100 100 im 17Y120 175 100 120 120 103 150 160 90 6OiloO 80:100 imi16O/- 160/150 AM&- 100 100 - 150160 16511601- 100/120 100 100 - 3&w AMB 100 AMBI- 33:33:35 2001- AMB - - 100/120 150 - 10 25 - - 50z@l lOoz/gal im im AMBI- 14CV- All 100 AMB - 160 100 im 100 100 1M 120 115 160 All - 175 -I140 20 - - 100 3&401(>20 2 101220 - 212 x):60:20 10 20 210 - - Bwao:10 11:75:14 1x LS:6of- - 24Y24y212 125 S&d:70 go - HETRON 920 SERIES'980 100 100 80 eel00 16Oll50 22ol125 125 AMB - im 100 2101220 1201210 1201210 120 - loo/imi- 150 150 - - - - - - - - - - (continued) Synthetic Resins and Polymers TABLE 1.54: POLYESTER AND VIN L ESTER RESIP -ASHLAND 199 (continued) SERVICE TEMPERATURE, OF FOR RESIN TYPES CHEMICAL ENVIRONMENT Lactic Acid .............................. Lactic: Citric Acids ......................... Lasso ECT ............................... Lasso ECT ................................ Lassot Herbicide’ ........................ Latex, Acrylic ............................. Latex Dispersion in Water ................... Latex, Rubber ............................. Latex,Vlnyl ............................... Laurie Acid ............................... LauriclMyristic Monoethanolamide: Sodium Xylene Sulfonato Solution .......... CONCENTRATION % HETRON' 92/99P All 200 - Sat'd lOO@ 140-F 100 1 to 10 Dllutlon All - 62 All LaurylAlcohol ............................. Lauryl Chloride ............................ Lauryl Chloride, Crude, Acidic ................ Lauryl Mercaptan .......................... Lauryl Pyrldinium Chloride ................... Lead Acetate .............................. Lead Chloride ............................. Lead Nitrate .............................. Lead Plating, Acid: Fluobortc, Boric Acids* ..... Lead Plating, Alkaline, Pb (C&&O),, NaOH* ..... Lead: S: CuO: FeO: &SO,: Bi,(SO,), Dust ....... Lead Smelter Fumes, Duct ................... Leather Dyeing & Finishing .................. Leather Tanning, Drums ..................... Levullnic Acid ............................. Light Gas Cycle Storage ..................... Light Water, FC195T ........................ Light Water, FC203T ........................ Light Water, FCZOgAT ....................... Lignin: Crude Tall Oil: Spent Acid: Sulfuric, pH3 ............................ Lignosullonate, pH 1.5-2 .................... Ligno-Sulfonic Acid ........................ Lime Kiln Stack Gases ...................... Lime Neutralization Effluent; Chlorinated Fluortnated Organica. Chlorlder, Fluortdee, HCI, HF, H,O’ ........................... Lime Slurry ............................... Lime, Thiosorbic ........................... Limestone Injectlon, SO, Removal, Fossil Fuel, Mist After Scrubber, pH 2.12 ............... Linear Alkylate Sufonates ................... Linoleic Acid .............................. Linseed Oil ............................... Linseed 011, Chlorfnated ..................... Liquid Chlorine’ ........................... Lithium Bromide ........................... Lithium Carbonate3 ......................... Lithium Chloride .......................... Lithium Chloride ........................... Lithium Chloride ........................... Lithium Chloride ........................... Lithium Chloride: Methyl Alcohol ............. Llthium Hydroxld3 ......................... Lithium Sulfate ............................ Llvestock Spray Base (Shell’s)z cobalt di(2-ethyl hexyl) phosphate: tr-mbutyl phosphate .............................. Lix54Nt .................................. LPC ..................................... Machine Oil & Sulphur Fumes ................ Magnesite Mill Spent Liquor ................. Magnesite Recovery Boiler Blow-Down; Acetic: Sulfuric: Sulfurous: Formic Acids; Acetone .......................... Magnestum Bicarbonate .................... Magnesium Blsulfite ....................... Magnesium Btsulflte Acid Liquor, 5% SO,, Chlorides, pH 4.55” ................... Magnesium: CakYurn: Sodium Chloride Solution ........................ Magnesium Carbonate ...................... Magnesium Chloride ....................... Magnesium Chloride, Hexahydrate; Filter Aid; Activated Carbon ........................ _ 200 160 NR AROPOL 724017430 SERlES HETRON 7001700c 1601130 2201200 - 160/130 - HETRON 920 SERIES/980 2101220 - NR NPJ- 120 - - 60 _ 601100 - 100 - 100 60 All - - Sat'd - - 160/130 - 100 103 22Ol200 100 2101220 - - 120' - 120 120/- 100 - 120 212 120 - 1201_ 212 120/- 120 155 - - - - 160 100 100 100 10 All Sat'd 160 - Sat'd 25:25:16:10:6:3 - NW- 100 200 NR - 200 - SAT SATI- SAT SAT - 100 160/NRINR w:10:29:1 - 100 - 160/- - Sat'd - --@ HETRON 72l1971197A 212-F - - - - - 160 160/AMW- 120 120 120' 120' 200 AM6 300 _ - 160 220/2cil 22OuOo 200 160 - 120 120 2cxl NR - 160 150 - 140 108 - 100 - 100 - 150/- COW. 100 All Sat'd 045 2840 4555 Sat'd 25175 Sat'd All 65:5:30 100 10 - Sat'd All 2:10:12 NWZMI140/160 NW- - 203 90 LS55 180 160/- 155 - 212 - - 180 - 210/220 NWNR NW- 170 - _ - NR - -55 - .55/2101220 160 150 160 - 2101220 2101220 - 2101220 - 140/- HOT 150 21w220 16O/- 2101220 - 140 160 176 115 2101220 210/220 2001150 1601130 - - - --/150 170160 - 250/250/265l265i- 170 NR _ - 105 160 Sat'd Sat'd _ 160/- 160' - - - - - - NR 160/130 - 212/200 180 - Sat'd Sat'd 160 220 150 160 160/150 150 220 160/15a 2201200 66 _ 31013101- - - 2101220 150 210/220 _ _ - 160 160 _ _ 160 2101220 - +See lislollrademarks and Droduct names (continued) 200 Corrosion TABLE 1.54: Resistant POLYESTER Materials AND Vlh Handbook _ ESTER RESII -ASHLAND (continued) SERVICE CHEMICAL ENVIRONMENT CONCENTRATION % Magnesium Chloride, Occasional HCI Vapors ........................... Magnesium Chloride: Sodium Chloride: Calcium Chloride ........................ Magnesium Hydroxide’ .................... Magnesium Nitrate ......................... Magnesium Oxide .......................... Magnesium Oxide Acid Condensate ........... Magnesium Oxide - Fluoride Mist and Fumes’ ............................. Magnesium Sulfate ........................ Magnifloc 509.Ct .......................... Magnifloc 573Xt .......................... Magnifloc E343t ........................... Maleic Acid .............................. Maleic Acid ............................... Maleic Acid, Trace Phthalic, Fumaric, Benzoic, Quinone ................ Maleic Anhydride .......................... Malelc Residue ............................ Maleic Residue, > 0.5% Phenol ............... Malic Acid ................................ Manganese: Ammonium Sulfates, pH5 ......... Manganese: Ammonium Sulfates: Sulfuric pH5 Manganese Sulfate ........................ Manganese Sulfate: Sulfuric ................. Manganese Sulfate: Sulfuric Acid ............. Marine Fouling ............................ Marine Gasoline ........................... Matart, Germicidal Detergent ................ MEK: DMP: MEK Peroxide ................... MEK, 100%: Sulfuric Acid, 50% ............... MEK: Toluene: Steam: Maleic Acid; Chlorides present ........................ Melamine Resin .......................... Mercaptan, Aromatic ....................... Mercaptan, Organic, H,S, H,O, Butanol ........ Mercapto-Ethanol .......................... Mercapto-Ethanol Tall Oil ................... MercapkkEthanol Tallate .................... Mercaptopropionic Acid ..................... Mercaptopropionic, Crude Acid ............... Mercuric Chloride .......................... Mercurous Chloride ........................ Mercury .................................. Metal Phosphate Salts ...................... Metal Phosphates, Trace HF. Hydrofluosilicic’ ......................... Metal SulfatsSalts: Sulfuric Acid ............. Methacrylic Acid ........................... Methacrylic Acid ........................... Methacrylic, Glacial ........................ Methallyl Chloride Q 165OF .................. Methanamide @ lOOoF ..................... Methanol 60%, H,O Trace, HCI, ZnCI,, Organic& Heptane, Dissolved Heavy Organlcs, Traces H,O, HCI, ZnCI,, 2 Phases ........... Methanol/Nitrogen Oxide Fumes, @ 220°F ..... Methyl Acrylamlde ......................... Methyl Alcohol ............................ Methyl Alcohol: Lithium Chloride Methyl Alcohol: Methyl Chloride: Hydrochloric ............................ Methyl Alcohol: Turpentine .................. Methyl Alcohol: Water: Hydrochloric @ 150°F .................... Methyl Bromide: Ethylene Dlbromide .......... Methyl Chloride ......... .................. Methyl Chloroform ......................... Methyl Ethyl Ketone ........................ Methyl Ethyl Ketone Q 120°F ................ Methyl Ethyl Ketone: Dimethyl Phthalate: MEK Peroxide ........................... Methyl Ethyl Ketone, Vapor & Condensate ...... Methyl lsobutyl Ketone ..................... Methyl lsobutyl Ketone; 200 gpl Fluorides; 500 gpl Sulfuric Acid& 3 .................... f See llsl 01trademarks and pmduct names HETRON’ 92199P Cont. Q 275°F lo 500°F at limes - 2:12:10 - Sat’d -I160 Sat’d S&d lW/200 Sat’d - - 5 2iw- Sat’d - 16 - @ 165’F 10 13:156 gpl 13:135:40 Sat’d gpl 9ozlO 50~~6 (gp0 100 Ccnc. 63:36:1 1o:w 100 100 100 100 100 100 Sat’d Sat’d 100 Sat’d NFU125’/125’/lW/601- 150 160 - _ -/NR 1601130 - 200 2W 1x)/120/- 1601150 90 %I 90 16o/lW - TYPES HETRON 7001700c HETRON 920 SERIES.1980 NR _ 200 - - 200 200 2101220 _ 2101220 160 - - - 150 _ - NR - 125’ 125 125’ - _ loo - - 203 1w - - - - - - _ 60 loo -/LS-BYNR 60. 60 - 80 65.60 65.60 60 - 60 60’/- _ 2101220 - 80’1- - _ _ NR - - - - - - - 65-W NR - - NR NR NR NR NR 212 212 1601150 220/2w 2 101220 212 250 - 212 250 1601130 16O/- 22012w 22012w 2101220 - NRJNRI- - 1W - - - Unknown 48 - 100 75:25 AMB - 94:0.4:0.2 o 65: lo 46 @ 150°F - 93:5:2 Vapor NRI- 100 100 40/- 100 IW NRINR NR/- NWNRI- - 60 - - NR - _ NR _ SATiLS SATiLS LS - - - NR - - 170 901NR - 1501NR - NW120 - 135 - - - - --INR NFV- - --/NR - 80 100 IW 63:36:1 100 Q 120-F 95 125 12Y- NRI- @ 75-F 165 NR - 100 @ 145-F 10 loo 150 _ - 30 24:10 3070 - “F FOR RESIN AROPOL 724017430 SERIES 154u120 100 - TEMPERATURE, HETRON 721197/197A 135 NR loo 90 --ILS/NR SAT’ 140 90 125 -/LS/NR NR 40 60 NR NR --/LS-65/NR - - - - - NR NR NR NR NR NR _ -/NR - NR - 50 NR NR NR 60 _ - _ (continued) Synthetic Resins and Polymers TABLE 1.54: POLYESTER AND VI ‘L ESTER RESI ;-ASHLAND (continued) SERVICE CONCEN. TRATION % CHEMICAL ENVIRONMENT Methyl Isobutyl Ketone; 300 gpl Fluorides; 40 gpl Hydrofluoric Acida ............ Methyl lsobutyl Ketone: Hydrochloric Acid Methyl Methrcrylrte ....... ........ ...... Methyl Parathion Methyl Phenol Fume;. : : 1.......... : : 11: : : Methyl Styrene .......................... Msthylene Blsthiocyanrtr, Polychlorophenol Blend @ 125-F.. ...................... Methylene Chloride ....................... Methylene Chloride: Chlororcetic Acid ....... Methylone Chloride: Chlorotorm: Carbon Tetrachlorlde, Small Amount Methyl Chloride, H,O, HCI ..................... Methylene Chloride Distillate Bottoms; High Caustic, Water, to 212-F ............ Methylene Chiortde: Ethyl Acetate: Caustic, 50% .......................... Methylene Chloride: Toluene ............... Methylene Chloride: Toluene: Xylene: MEK 6 MIBK: Benrenes: TCE: Ccl, ........ Methylene Succinlc Acid .................. Methylimino Ether Methanol: Isobutyronitrile: HCI: Imputities .......... Methylisobutyl Ketone: Cyanc+acetic; 0.8 Sulfuric in Saturated Sodium Chlortde @ lOOoF ............................. Methylol Acrylamlde ...................... Milk & Milk Products ...................... Milk Wsgon Cleaner ...................... Milk Waste ............................. Mineral Oils .......................... Mineral Wool Slurry ...................... Moisture ............................... Molten Salt ............................. Mortal 6 Nickel Cleaning Baths; HCI, CuC4 ... Monel 6 Nkkel Cleaning Bathr; HCI, Fh(SOJ, .......................... Monochloroacetic Add ................... Monochloroaoetk ACM .................... Monochlororcetic Acid .................... Monochlorobenzeno ....................... Monoethrnolamine ....................... Monoethenolamine: Butyl Cellosolve Film Stripper @ 138OF ................... Monc+thrnolrmlne Dosulturtzlng SO .. H.S .... Monohydroxysuccinic Acid ................. Monosodlum Phosphate, pH l-3 ............. Morphollnr .............................. Morphollne @ 1zO’F ...................... Motor Oil ............................ MS.08 Gasoline .......................... Mulsollnr 6WOt .......................... Murirtic Acid ............................. Mustsrd (3% Sodium Chloride, 5% Acetic Add) ............................ Myrlstic Acid ............................ MyristlclLaurk Moncethrnolrmidez Sodium Xylene Sullonate Sotution ................ Naphtha ................................. Naphthrlene ............................. Naphthenic Acid .......................... Naphthoquinone. 1,4 ...................... Naphthoquinone (scrubbing with water) ....... Naphthylamine Sullonic Acid ............... Neodol253St ............................ Neopentyl Glycol ......................... Nickel Anolyte Llquor (Into Metsls) ........... Nickel, Bright . . . . . .. Nickel Chlortde: Nickel Sulfate: Boric Acid . . Nickel Chloride NickeCCobalt + Solvent Extraction Circuit; pti 1.8~4.5.0.31.5gpl fluorides Nickel Electrolyte. Purified (Into Metals) Nickel 6 Monel Cleaning Bath; HCI, CuCI, Nickel & Monel Cleaning Bath; HCI, Fe,(SO.), tSee 161of trademarks and voduct names 10015 1W HETRON’ 92199P 158203/- @Zt75’F TEMPERATURE, HETRON 72.1971197A 60 --115&203/NR - 100 100 NRI- 100 201 80 NR --ILSINR NR - *F FOR RESIN AROPOL 7240 7430 SERIES TYPES HETRON 700,700c - HETROH 920 SERBS’990 - _ - NR NR - NR - NR NR NR NR SATINR NR SAT NR - NR NR- NR NR NW- NR- - 100 NR 9x5 NR 65.39:s NR NR - NR NR NR NR NFU- 83:16:1 NR NR NR - NR NR- - - - - - rw - - - -l771- - - - LSSAT -Mi¶o - - - AMB’ 90 AM0 WM 33:39:9:2:36:, 25 74:2:0.3:23:1 603 46 - Acid ltW150 100 Unknown loo RH Splash h Spills 50 80 @ 1W’F 100 0 145-F 100 AMBll&l AMB Hetron@ 197.3 wth 120 7w- NWNWNR loo 120 lt3oll5c filler satisfactory - AM% 80 _ 220iAMB for a@tated tank - ao/1801200:2 10 Amblenl - 750 - 180 - l&l AMB NR - - NR NR NR NR NR NR NR NR NR75 AM8 NR AM0 NPJAMB NRINPJ- 30:57 NR NR NR NR NW- loo NR - NR NR NR NFU- NR - NR _ 10 510 10 1w loo - 95 203 100 NR - NR AM&-I- - 150 See Hydrochloric - 1W - 100 200 4MB1130 21 o/220 120’ 200 180/150 AMB 1501120 Sat’d 150 150 Sat’d Unknown Sat’d - 1w w 81 Nl etc. - - loBi- ;ia* 1801- 120 1% 180 - 120/18012w 1BOiZW - - 120 150 lW/- 180 180 12:53% ozlgal Sat’d NRI2101220 - Acid lWAll - 220 - 220 1801150 - - 22012w 2101220 185 - - 180 - 140/- 180 - - (continued) 202 Corrosion TABLE 1.54: Resistant POLYESTER Materials AND VIF Handbook L ESTER RESI ;-ASHLAND (continued) SERVICE CHEMICAL ENVIRONMENT Nickel Nitrate :: Nickal Plating; Electrorafining pH 1.5 Nickel Plating (Nickel Sulfamate: Magnesium Chloride: Boric Acid) pH 3.7 Nickel Plating Solution (11% Nickel Sulfate: 2% Nickel Chloride: 1% Eorlc Acid) ....... Nickel Plating Solution (44% Nickel Sulfate, 4% Ammonium Chloride: 4% Bortc Acid) Nickel Soap Catalyrt ....................... Nickel Sulfate ............................. Nickel Sullate: Nickel Chloride: Boric Acid ..... Nickel Sulfate: Nickel Chloride: Boric Acid: Brightener (Nickel Plating) ........... Nitrating Acid Spent ................... Nitrating Acid, Strong .................... Nitration, Spent Acid ....................... Nitric Acid ................................ NitricAcid ................................ Nitric Acid ................................ Nitric Acid ................................ Nitric Acid ....................... Nitric Acid ............................... Nitric Acid .............................. Nitric Acid ............................. Nitric: Amchem 616f ...................... Nltrlc Acid: Copper Salts .................... Nltrlc: Copper Salta ........................ Nitric, 70%: Glacial Acetic: 49% Hydrolluodc’ . Nitric. 70%: Glacial Acotlc: Is% Hydrofluoric’ Nitric: Hydrochlork ........................ Nitric: Hydrochloric Acids’ ................. Nitric: Hydrochloric: Hydrofiuorlc’ .......... Nitric: Hydrofluoric’ ........................ Nitric: Hydrofluorlc’ ........................ Nitric: Hydrofluorlc Acids’ ................... Nit&: Hydrofluorfc AcIda’ ................... Nltrfc: Hydrofluortc Acldr’ ................... Nltrlc: Hydrofluorlc Acids’ ................... Nitric: Hydrofluorlc: Chromic Aclds’ ........... Nltrfc: fiydrofluorlc Pickllng sdutton’ ......... Nitric: Hydrofluorlc Vapors’ .................. Nitrfc Acid: Phosphoric ..................... Nitric (34%): Phosphoric (65%) ............... Nitrtc: Phorphortc: Sulfuric: Nonionic Surfactant ..................... Nitric: Sodium Dlchromato ................... Nitric: Sodlum Dlchromate: Mqfybdlc Acid: ....................... Water @ 13DlW°F Nltrlc: Sulfuric @ 210°F ..................... Nitric: Sulfuric: Cbpfmr Saltr ................. Nitric: SulfurlcDlnitro-Toluene Fumes ......... Nitric: Sulfuric: HCI @ up to 226OF ............ _. Nitric: Sulfuric: Hydrochloric: Water ........ Nitric: Sulfuric: Hydrochloric ................. Nitric: Sulfuric: Na dichromate: Cr,(SOJ, ....... Nitric: Sulfuric 6&50 ........................ Nitric: Sulfuric: Water ....................... Nltrlc Acid Vapor ........................... Nitric Acid Vapor ........................... Nltrfc Acid Vapor ........................... Nitric Acid Vapor ........................... Nitric Acid Vapor ........................... Nitric Acid. Vapor 6 Condonsato .............. Nitric Acid: Wettlng Agent ................... NitricAmmonia Fumra ..................... Nltrtc, Gone.; Sulfurfc. Cont. ................. Nltrfc Oxldo, Cl,, HF Furnor’ ................. Nitric Oxldr. Chlortnr. Hydrofluorlc Fumes’ ..... Nltrfc, Rod Fuming ......................... Nltrlc. 70%: Sulfurk. 70% Pickling Acid ........ Nltrobenzene .............................. Nitrogen .................................. Nitrogen Fertilizer Solution ................. Nitrogen, Liquid .......................... Nitrogen OxideMethanol Fumes, @ 22O’F .... Nitrogen: Oxygen ........................ N,: CO,: SO,: 0,: H,O Vapors .............. “AROPOL 7343 samlacmly CONCEN. TRATION % HETRON’ 92199P sa: - 220 220 - ‘F FOR RESIN rYPES AROPOL 724017430 SERIES 100 150 - 150 - M-3 5 5 07.&a TEMPERATURE. HETRON 7U1971197A - 150 HETRON 7ooi7ooc “ETRON 920 SERIES980 220 200 - 210,2X _ 1451- 200 Sat’d 53126 220 - orlgat 40.6:6: Trace oz/gai - NW- @ 160-F NRI- 2 5 10 AMB 150 60/6O/NA - - NR NR 60160/NR NR NR NR 160 150 NR NR AM0 NR 1001150 - 140 NR NR NR 110 NR - NR NR - 15&JNWNW- 65.95 150 10160 NR NR - 200’ NR - NR - zoo/- - loo - - NRI- 165 165 NR - - NW- 135 NR NR NR NR 7.5.2.5 15:5 .Yl 20x5 35:5 105 - 3:60 4:7 by vol. - 203 125 - 60 NR NR - - al NR NR - - NRI- 90 - - - SAT/SAT/NR 9.5:17:112 gpl - IO160 1020:10z6 molar 10:20:30.40 12:x):30 NW- - - 40180 180 NR/- WNRJNR NR NR 17Y95 - 175 - 160 NR NR - 60 120 - NR NR - ml- NRIlM)il&l 1601180 2cm 46 @ 1W’F 5 2% ougal - 160/160 - Hot NR - NR NR - 26 Go/- W5C t! jee NR NR NR NR 160/- 60 NR - &l/NR - 60’ 100 100 0.12 0.1:5 14 by VOI 001NRI- 2So.w:<o.1:75 %m 100 Unknown - - x):11:59.1 unknom not 100 0 75-F 1o.S:51 105 - - 120 ?0?8oz/gal@80 ‘:S3 ty vol. @ 1OO.F UIllUlOW - NR 154 @ 1Bo.F 2013 60% 6595 - 1201140 NR 21w2101- 5:x) 10.77 13 24 @ 183-F 210,220 160 140 140 NW- 36% 10% _ NRINR,- m 140 52 4 3.0:7.0:25 gpl 30 !m39 210/220 - 1401175 NWNW- 0 12Q’F 2z3.8 22G200 - 160/120 AMWNR Qp 110-F 505 l&J/- - a 50 12:24 @ 60-F 2w - 210 6:3:1 0 1W’F lo.10 521 16celo lBO/- 21w2@l 20 J5 166 15:lal gpl 2crlW gpl 220 160 200 65 120 lisl of trademarks 60” - Hetron 31 SAT also, no veil NR and product names _ (continued) Synthetic TABLE 1.54: POLYESTER AND VII L ESTER FiESl i-ASHLAND Nitrogen: Oxygen: SO,, droplets 60% Sulfuric Nitromethane’ Nitromethane(tris, hydioxymethyl): Formaldehyde: Water, pH3 ........ Nitrophenol ..... : : : : .. pNitrololuene !&Ironic Acid .............. Nitrous Acid .......... : : .............. Nitrous Acid ............. Nonandioic Acid .......................... Non-Condenrrble P&P Mill GJe ............. Nonionic DispersJnt, Blend a 12SDF ......... Nonionic SurfJctrnt, Afkanolrmide ......... Nonionic SurfJctJnt, Alkyl Ether Amine ............ Oxide ............ NonylPhenol:::::::::::::::: .................. Nonyl Phenol, Ethoxylrted NonylphenoxytrfethoxyethJnol SulfJte, SodiumSJlt ............................ Nuclorr, RJd WJste ....................... NucloJr Swimming Pool ReJctor Liner ........ Nuclear Waste Ammonium Nitrate ..................... Fluoride Solution’ Nuclear Waste, Water, Low Level ........................ ionexchange.. ......................... NutOif,Ground Oakitet Cleaner, pH 11.12 @ 185’F .......... Oakitet Strfpper SAt ...................... Octanoic Acid ............................ ........................ Odichlorobenzene Oil. Crude, B ............................. Oil, Crude Storrge Tank Bottoms ............ Off,Fumace. ............................ Oil. Gas, Dirty, Relinery .................... Oil, Heating .............................. Oil, Low Sullur Crude ...................... 011, Medium Sulfur Crude ................... Oil, Mid-Continent Sweet ................... Oil, Oxidized Petroleum Heavy Bottoms, 7.6 fbr/gJf with JbOUt 10% Acetic Acid ...... 011. Refinery WJste Eflluent ................. Oil. Slop, Refinery ......................... Oil, Sour Crude .......................... Oil, Sour Crude, Wyoming .................. ......................... oil. SWJJt CNdJ Oil, Waste, Various Ketones, ArOmJtiCS ....... Oil, Water SepJration ...................... Oil, West Texas Sour ...................... Oil, West Texas Sweet ..................... Oilr:AnimJl.............................. MinerJl................................ Vegetable ............................. Olefin (JiphJ) Sulfonate .................... Oleic Acid ............................... OfeoparJthion ............................ Oleum (fuming sulfuric) .................... Oligomertc Dlspenunt ...................... Olint 58981 ............................... OliveOil.. ................................ 1gODt: VlnylidJne Chlorlde .................. OPM.lf .................................. opht.2t .................................. Ore Smelting Furnace Gas, Wet, with dust: 4O%NJ. 23% Cd, 6% Pb, 21%B, 6%Zn Jnd other Oxides to 400°F .............. ..................... Orgrnic DJlJgJntJ Organic Solvents + Aqueous HCI ......... OrgJnotin, Quetemary Ammonium S~ltr, Amlne Selts Blended ............. OStnOSJ COmpJny TEMPERATURE. ‘F FOR RESIN TYPES CONCEN. TRATION % HETROn’ 92!99P HETRON 72ll971197A 79 157 100 _ - AM0 - - _ - - 120’ - NR - 120’- 51 0649 1W 175 NW- 200 10 Sat’d AM0 AM0 AM0 100 - 24 100 HETRON 700~700c lx)/- 55 aInN% 100 100 - 100 165 LSNR - 120 110’ 12O llr!’ 110 - 100 - loo SAT - 12O’F NFU- la, - NR/- - - - Unknown AMBI- 120 110 120.1 IO,- loo - - 120 100 - AM0 - - - LSI- - AM0 - NR 16Oirw NR 160 NR 1601200 NR’lW - - AM0 lx, loo AMB/AM&- - 2001210 - - AM&- - - 140 -/LS12Q’NR - - - - _ 160.220/- 12aAM&AM&-- - AM0 - 210 liM~15O ZICUIM 210 - 16@15O AM0 - - _ 200 210 2101150 210 200 - AM0 AMBI- AM0 - AM&- - - 1W 100 - 1W - 120 100 3 - 2w 140/- xx) - 100 13W- loo 14tN- s&2 - 100 NR NR 130 122 14O leeJ130 NR lx)’ 1801130 AM0 180 180 SATISATINR pHl2 @ 75’F Unknown @ 194-F NR 100 125 - tSee hsl 01 lrademarks 220 loo AM0 21.1.5:o 9.0.2.5 5050 15 79:7 5.70:12:0 1.14 by vol 3 220 AM0 200 - 65 175 120 100 200 200 200 - 200 - 200!210 - NR 130 - NR 130’.- AM0 - 2wi210 - - _ - NR_ - NR NR 210 NR- - - LSl2YNR 125 180 140 - - 02- 100; 5O L 16 All - SAT AMBI- - - - - - Unknown - - loo - HETAOH 920 SERIES980 loo’ 14O/- Sat’d lzol- SAT 1M loo - 26 Cone. 0 AROPOL 7240:7430 SERIES PrJmix; Jnd Fir0 Retardant Liquid Formulationr .......... Oxalic Acid ....................... ... .... Oxidizing Gases Oxygen: CO,: SO,: SO,: H,O, Trace; cl;.‘N, : : Oxygen: Nitrogen ................... Oxygen: Nitrogen: SO,; Droplets 8!% Sulfuric 0,: N,: CO,: SO,: H,O Vapors ........... ................ Ozone .... 203 (continued) SERVICE CHEMICAL ENVIRONMENT Resins and Polymers 2201200 AM0 - 216 220 _ _ _ _ and product ndnws (continued) 204 Corrosion Resistant Materials Handbook TABLE 1.54: POLYESTER AND VINYL ESTER RESINS-ASHLAND (continued) SERVICE CHEMICAL ENVIRONMENT Ozone/Cyanide CONCEN. TRATION % Fumes Ozone:Hydrogen Ozone: Ozone Oxygen, .............. ........................ Wet ................. 20 Ibs/day 8 1% Unknown HETRON’ 92199P 0, 1.5-2.5.0, Sewage Treatment ..... 3 :. : ......... Ozone Treatment Condominium Waste ....... 4 lbslday @ 2% 0, Palmitic Acid ............................. Sat’d Paper Machine ........................... Fumes Paper Mill Liquor .......................... Unknown Parathion, Wet ........................... Parco 450/45t, pH 1, HF presenta ............. Parco Cleanert 556R ...................... 100 Pax Hyspeedt, Detergent ................... Sat’d Peanut Oil .............................. 100 Peel Oil .............................. 100 PepSet1505t.. .......................... 100 Pep Set2596 ............................. 1W Perchlorlc Acid ........................... 5 Perchloric Acid ........................... 10 Perchlortc Acid ........................... 30 Perchloric Acid ........................... to 70 Perchloroethylene ....................... 100 Perchloroethylene, Vapor & Condensate ...... 100 Petroleum Ether .......................... 100 Petroleum Oil 61Waxes, Water Emulsion ..... Phenate Based Algaeclde .................. 1M) Phenate Based Bactericide ................. 100 Phenate Based Fungicide .................. 100 Phenol .................................. 2 Phenol .................................. 5 Phenol .................................. 10 Phenol .................................. 65 Phenol .................................. 100 Phenol, Formalin, Sulfuric Fumes ............ Unknown Q 2Cil’F Phenol, Fumes ........................... Phenol: HCI : Water ....................... 20:10:70 Phenol Sulfonic Acid ...................... Sat’d Phenolic Resin. Urea Modllied (Durezt 24942) .......................... PH 78 Phenolic Spent Caustic, Refinery ............ Phenollc Spent Caustic, Refinery, Neutralized to pH 5-6 .................... Phenols, Some: Sulletes, H,S, Water, Waste Liquor, pH 5-6 .......................... 0.Phenylphenol: Sodium Xylene Sulfate: Isopropyl Alcohol: Potassium Rlcinoleate: 6:10:10:6:67 lnerts ................................. Phosphate MIX (NaOH + H,PO,)’ ............ PhosphatelPhosphoric Acid Waste 510 Liquor, pH 1-3 .......................... Phosphate Rock Dust Scrubbing ............. Unknown Phosphate Salts .......................... 25 Phosphonitrilic Chloride, Cl,, HCI, Benzene. H,OVapors .................... Phosphoric Acid .......................... 65 Phosphoric Acid: Calcium Chloride ........... lo:25 Phosphoric Acid, 26%, Some Fluorides, Fumes Ammonla; Reactor’ ...................... 40:7:2 Phosphoric: Chromic: Hydrofluorlc’ .......... Phosphoric: Chromic: Hydrofluorld .......... 8.5:9.3:11 Phosphortc: Fluorine: SIO, .................. 54:1.2:2 65 Phosphoric, Food Grade” .................. 15:9 Phosphoric: HCI, Sat. with Cl, ............... 15:9 Phosphoric: HCI, Sat. with Phosphorous ...... Unknown Phosphoric: Hydrochloric Acids ............. Unknown Phosphoric: Hydrochloric: Butyl Ether ........ Phosphoric: Hydrochloric: HP .............. 65:1:5X ppm 50:2:7 Phosphoric: Hydrofluoric: Cr,O,’ ............. 6:11:9 Phosphoric: Hydrofluorlc: Cr,O,’ ............. Phosphoric: Hydroxyacetlc: Sulfuric Acids’ .... 5129120 Phosphoric, 36%: 70% Kerosene, 10% lsodecanol, 20% Organics ................ 35:33:33 Phosphoric 65%: Kerosene: Xylene .......... Phosphoric Acid: N-Alkyl Dimethyl Benxyl 25:0.1:75 Ammonium Chloride: lnerts ............... tSee list of Irademarks and product TEMPERATURE, “F FOR RESIN TYPES AROPOL 7240/7430 SERIES HETRON 7001700c 100 AMB _ - _ _ AMB - 160 - 2201200 - 140/- - 1801120 - - - _ - - 1601- _ - HETRON 7211971197A AMB ‘1cO1100/140 140/160 76-120 AMBJ120 120 NRINFUNPJNFU- 110 140 - 175/- AMB’ 120 AMB’ AMB AMB 65165/B516Y- NR 65/6=5/65’1851100 120 - NR NR NR NR _ AMBI- AMB - AMBI- - 1801150/- - SO/- NR _ 100 _ - _ - 125 125 125 125 125 125 - 125 125 - 160 NR NR NR NR _ - AMB’ 140 125 100 NR NR - HETAON 920 SERIESi loOI-lOOINR NR _ 8ollW NW30 NR/NR - NR NR/- 80-110 NR - _ NR - NR - - AMB - - 130 130/- 130 - 130 130/- 130 - 130 130/- 130 - - - loo/1701- - - - AMB - - _ - 1801150 - 2201200 - 2101220 _ - _ - 100 200 SATIAMB 220 _ AMB 120 250/250/200 100 to 250 100 - NR NR - 100’ _ 1OO’INR _ - - - - 100 - 175 180 220 220 - SAT SAT NFVNR AMB _ - 100 100 - 243/243/- - - - - 150 - - 100 - _ - - 100 - - loo/- 230/230/- NR - _ namrs (continued) 206 Corrosion Resistant Materials Handbook TABLE 1.54: POLYESTER AND VI L ESTER RESI ;-ASHLAND (continued) SERVICE CHEMICAL ENVIRONMENT CONCEN. TRATION % Potassium Carbonate’ Potassium Carbonate’ ...... Potassium Chlorate ............ ...... Potassium Chloride Potassium Chloride: Cl,, Br, Sat’d;. pH 2.4 Potassium Chloride, Mercury Grade ......... Potassium Chloride: Potassium Hydroxide: Hypochlorite with Treces Chloropicrin @ 194OF ........................... Potassium Chloride, Wet Vaporr ............ Potassium Cyenide’ Potassrum Cyanide: K Hydroxide:’ Copper Cyanide’ ...................... Potassium Dichromate .................. Potassium Ferrlcyenide .................. Potassium Ferrocyanlde .................. Potassium Fluoride2 ...................... Potessium Hydroxide’ .................... Potassium Hydroxide’ .................... Potassium Hydroxide’ .................... Potassium Hydroxide’ ................. Potassium Hydroxide’ ................. : Potassium Hydroxide: Potassium Chloride: Hypochlorite with Traces of Chloropicrin @ 194OF ....... .. .......... Potassium Hydroxtde: Potassium’ Cyanide: Copper Cyanide’ ................ Potassium Nltrate ......................... Potassium Oxalate ........................ Pota*sium Permanganrte .................. Potassium Peroxide ...................... Potassium Persultate ..................... Potassium Pyrophosphate ................. Potassium Ricinoleate: 0-Phenylphenol: Sodium Xylene Sulfate: Isopropylalcohot Inorta .................. Potessium Sulfate ........................ Power Plant Scrubber, Med. Sulfur Coal, pH 1.936 ......................... Power Plant Scrubber, Med. Sulfur Coal, pH 1.936 ......................... Premix Liquid (Osmose Co.) ................. Propenoic Acid See acrylic acid Propionic Acid ............................ Propionic Acid ............................ Proplonic Acid ............................ Propionic Acid @ 12CtvF .................... Propionyl Acid @ i2tJ°F .................... Propionyl Chlortde ........................ Propylene Glycol .......................... Pulp, Bleached ......................... Pulp and Paper Mill Bleach ................. Pulp end Paper Mill Condensable Liquor, pH 9 ....................... Pulp and Paper Mill Digester ................ Pulp and Paper Mill Recovery Boiler .......... P 6 P Mill Waste, Acidic .................... PulpStock.. ............................. Pulp Stock, Chlorinated, pH 4.5 .............. PVC Latex with 35 partr DOP ................ Pyridine ............................. Quaternary Ammonium Compound, In Isopropanol, Cationic .................... Quaternary Ammonium, Dialkyl, Dimethyl Type: Aqueous lropropanol ............... Ouatemary Ammonium Salts, Organotln, Complex Amine Selt Solution Q 125OF ..... Ouatemay, Dlcoco Dimethyl ................ Ourternary, Dimethyl, Dlrtraryl In Isopropenol .......................... Ouatemary, Dimethyl, Dlstearyl in “Neutral” Organic Solvent ................ Quaternary, Hexylene Glycol ................ Quaternary, Methosultate Type ............ Quaternary Softener, Difatty Complex ....... R.2 Solutions .... Rad Waste, Nuclear : : : : : : : : : tSee 115101 trademarks 25 sac d HETRON’ 92’99P TEMPERATURE, HETRON 72i19lf197L OF FOR RESlh AAOPOL 7240 7430 SEPIES AMB 110 AM6 NW90 - AM6 - 110 _ - _ 2w - 250 190 :60’150 - 180 - - - - - Sal C Q 265’F All Sat d Sal d 15:15:1 AMB - Sal’d 200, -/zoo 175 200 - 180,150 Sat’d 200 200 150 1801150 - Sat’d 3.2 8 origai All Sot’d 10 25 45 50 2 oz/gat NFUNFUNFU- 15.15 1 - arlgal 2:3$ All NR - 180 _ 220,206 _ NR 210,220 - - NRI- - NRJ- - - _ 1843!- 200 21ci22c lM/NR - 22O~lt3C 2201180 150 210’220 210!220 150 150lAMB 150 15OIAMB AMB _ 150 150 150 150 1751- 175 - - - 175 - - NFL- 101220 200 220 - 1801150 22012w - 2 150 - 150 - 12YNR - 2w115l - 2101220 - AMB AMB Sat’d All Sal’d Q 80-F All - HURON 920 SERIES980 :5G - AMBI- TYPES “ETROH 700 7OQC 100 loo’ AMBI- 200 100 - 2101220 1001- 6:0.10:10.%7 - loo - - All 2W 220 180150 22012w Liquor - 150 - - - 150 - 02J- - - 806 80 Mist 8 Fumes 100 1 20 - 100 80 NRI- NR 80 NW- NR NR 100 0 1W’F All - Fumes - NR/lOOU70 AMBI- Fumes AMBI- Fumes AMBI- FUMS 184 190 - 80 NR LS’INA 1701150 _ 130’ - - 150 - AMB 120 - 80 NR LSNR 2001180 - lW/2101220 80 2008NRINRINPi- - 2101220 _ 130 - 130’1- - - AMB - AVB - - 190 - - - - NR NR NR - 100 NR 110 NR - 120 120’ 120’1120 120 12OI- 1201- 120’ 120’~120 120 1201- - SAT 120 LS SAT - 1X4- 120’1120 120 120/- 120/- 120’ 120’1120 120 120/- 1%X- 190 1w 1901- 120/- 120’ 120’ 190’150 120’ 120 120 120 120 120 - 120 - 120 _ 75.25 75 - 1201Sal’d - 1201- 120. 180 100 120’ 120 120’ 120 _ _ - - and product names (continued) Synthetic TABLE 1.54: POLYESTER AND VIP ‘L ESTER RESI ;-ASHLAND CONCEN. TRATION % Radiochemical Hoods, Glove Boxes 50 - .... Raylenet’ : “‘I.’ .... RayonSpinBalh ..... Rayon Spin Bath Evaporator/ Crystalizer to 16O0F Rayon Spin Bath Fumes C 195.2C13bF : ...... Rayon Spinning Fumes ............... Recovery Boiler Biow.Down; Acetic: Sulfuric Sulfurous: Formic Acids: Acetone ............................... Recovery Boiler Flue Gas to 400°F ...... Recovery Boiler (Kraft), no contact rvap.; 59100 ppm SO,, 12.14% CO,, 19% by vol. .......... moisture, 37 lps to 4U0°F Recovery Boiler Stack Gases 6 3&“F ... .... RedLiquor ............................... Reformer Charge ......................... Renderlng Fumes, Ozone, Chlorine ........... Rhodium Plating, phosphate ................ Richamide CDAT .......................... Richonate 165Ot ......................... RJ-Qt Fuel ............................. Rock Wool Slurry ....................... Salicyiic Acid ......................... .I: Salt, Molten ........................ Sand, Dry, 60-70 Mesh, 350 cfm ............... send, Slurry ............................. Sani-Fresht Soap Solution .................. Scrubber, Med. Suitur Coal, Particulate, pH 1.9 3.6, Cl560-1200 ppm. 309,ooO ACFM Gas ..... Scrubber, Med. Sultur Coal, Particulate. pH 1.9. 3.6, Cl560-1200 ppm. 300.9W ACFM Gas ..... Scrubber Sludge; 30% Solids (96% Ca SultetelO% Ca Sulfate), ..................... 15%FlyAsh,pHll Scrubber Sludge; 36% Solids (90% Ca Sulfate 10% Ca Sulfato). 15% Fly Ash, pH5. ......... swat SIa hsl01trademarks and product 140 212 SAT!SAT/NR NR NR - SAT/SAT/N,? - SAT!SATINR NR NA - -/MO/- Fumes - 100 Unknown 4 8 Spells kY%'Qai @8o.F 804Hetron - 80’ satlstactow - - 120 80 tank. Amblent for aaltaled Restslant Liner - - 120 - - - - - 120 100 180 --/LSINR - 180 All - 132 - loo loo IWi- 18WlM - 180 - 2101_ - - 2101- - AMB - AM0 AMB’ AM0 125 125 85 85 AMB 85 AMB’ 125 - AMB AMB’ AM0 AM0 AMB --IAMB - - - - - - - - - - - - 150 2.75 x Normal 100 - - - - NOrmal 175 x Normal 160,- 150 - 150 - - 120 120 - Sallsfactoly NW- e- - 750 31 NW- - All NR wtth Abrasnn Hetron - - - 7501- NPJNR’- 120 80’ 197.3 with llller - wmes AMBI- 21212W 120 120 120’ - Sal’0 Splash 1401- --,LSSI- NW- 100 100 HETRON 920 SERIESI9EO - - - - - 180 1671- TYPES HETRON 700’700c 150 NRI140011W - ‘F FOR RESIN AROPOL 724017430 SERIES - AMBI- - TEMPERATURE, HETRON 72’19711971 92199P ................................... Water ................................ See Water, Desalination, pti 7.5 @ 265.F ....... Sea Water, Desalination, pH 7.5 .............. Sea Water, Desalination, pH 7.5 .............. Selenious Acid ............................ Septic System ............................. Sequestering Agents ....................... Sewage, Anaerobic ......................... Sewage, Municipal, Treated 6 Untreated ....... Sewage Treatment ......................... Sewage Tmatment Fumes ................... Sewage Treatment, Ozone, 3% ............... Sewer Gas; H,S .......................... Shampoo, Carpet .......................... Shampoo, Liquid .......................... Silicone Oils: Hydrochloric Acid .............. Silver Cyanide ............................. Silver Nitrato .............................. Silver Nitrate: Coppw Chloride ............... Silver Plating Solution. 4% Silver; 7% Potassium and 5% Sodium Cyanides 2% Potasslum Carbonatti ................. Silver Refining Cells ........................ Single Vessel Chlorine Dioxide Process (Hooker)’ ........................ Skydroi 500t, Hydraulic Fluid Siimicide, Organotln Amine Blend r@125’F ..... Slimlcide, Polychlorophenate organosulfur blend ....................... Slimicide, thiocyanatepoly&lorophenol blend @ 125OF.. ........................ Slurry, 20% Clay: 20% Potash In Sat’d. Brine .... Slurry, Coal/Water @ 6O’F .................. Slurry, Lime ............................... Slurry. Mineral or Rock Wool ................. ............... Slurry, Sand/Water Q 60°F Smelting Furnace Gas and Dust, Wet to 4OO’F ........................ tSee HETRON' 207 (continued) SERVICE CHEMICAL ENVIRONMENT Resins and Polymers AMBI- AMB - AMB AMB AMB 100 AM0 AM0 AMB - AMB AMB - AMB’ AMB 100 LSlWINR 1w - AM0 lW/2101- 100 - 120 79’21 - 195 - - - PO 180/150 200 2101- NR - 200 2W/- Sat‘d All 200 x3:15 80 - NR 100 loo SAT etro” - 197 SAT throughout - 125 - 10190 Sat’d Unknown --ILS/NR Hetron 197 SAT @ 12 tps for absorption Ah48 LSiNR 125 SAT Hetron 180 197.3 wth t!ller satlsfaclory Hetron SAT.SATINR resistant 170180 NaOH 150/1&l - SAT 125 197-3 with abrasion lEOI- Of Cl, or ClO,m SAT - Hetron 4 lbsigai - except 160 SAT 100 100 40 Slurry @ 80-F - - Fuller Satisfactory for agitated at 7 ips 170 tank. Amblent 31 Satlsiactory - - - (continued) 208 Corrosion Resistant Materials Handbook TABLE 1.54: POLYESTER VINYL S-ASHLAND (continued) SERVICE CHEMICAL ENVIRONMENT CONCEN. TRATION % Smoke, Particulate, Cooling and Washing with Waler Soap Plant Fumes Soap Solution :::: :‘. Soap: Sulfuric .,.... Soap Tower Exhruat Fumer’ 1 : : : Soda Ash; Sodium Carbonate ....... .. Thickener Fumea .......... Sodium Acrtrte .......... Sodium Acid Sulfite ..... Sodium Alkyl Benzene Sulfonrte .......... Sodium Alkyl Xanthate Sodium Alkylaryl Sulfonate; pH 6 .......... .......... Sodium Aluminate’ Sodium Ammonium Phosphate Sodium Benzdate ........................ Sodium Bicarbonate’ ..................... Sodium Bicarbonrts’ ..................... Sodium Bichromate ...................... Sodium Bichromate: Sulfuric: Sugar .. Reaclion Product, pH 26 ............ Sodium Bisullaie ....................... Sodium Birullide’ ........................ Sodium Blsulfider ...................... Sodium Bisulfide’ ........................ Sodium Bisulflde: NaOH’ .................. Sodium Blsulflte ......................... Sodium Bisulflte: Sodium Sulfate: Sodium Sulfite ........................ Sodium Birulflte/Sulflte ................... Sodium Borate ......................... ... Sodium Bromide ..................... Sodium Carbonate ....................... Sodium Carbonate’ ...................... Sodium Carbonate’ Q 206OF. .............. Sodium Carbonale’ ....................... Sodium Carbonate’ ....................... Sodium Carbonatea ....................... SodiumCa~otWt~:SodaAah Thlckrner Fumoe ...................... Sodium Carbonate, Vapor & Condensate ..... Sodium Chlorate .. ...................... Sodium Chlorate ....................... Sodium Chlorate, Sodium Chloride .......... Sodium Chlorate: Sodium Chloride with .... 350ppmCr,10ppmCa,10,000Ampr.. Sodium Chbrato: Sulfuric: Chlorinr Dioxldr: Methyl Alcohol’ ................. Sodium Chloratr, Sulfuric. Methanol, Sodium Sulfate ......................... ......... Sodium Chloride ................ Sodium Chloride: Calcium Chloride: ................... Magnesium Chloride Sodium Chloride, Cl, Sat’d., pli 2 ............. Sodium Chloride, Cl, Sat’d .. pH 2.6 ........... Sodium Chloride: CIO,’ ..................... Sodium Chloride, Dechlorinated: pH 25 Free Chlorlno (Traces) ................... Sodium Chloride: HCI ...................... Sodium Chlorldo, Mercury Grad r ............ Sodium Chloride, pH 3 ..................... Sodium Chloride. pH 3, Cl, Sat’d ............. ....... Sodium Chloride. pH 3.5 ............ Sodium Chloride, pH 10.5, Cl, Sat’d ........... Sodium Chloride, pH 11, some Cl, ............ Sddlum Chloride. Sat’d. Chlorine ............. Sodium Chlorldo: Sodium Chlorate ........... Sodium ChMdo: Sodium Chlorate wlth 366 ppm CR. 10 ppm Ca. lO.WO Ampa ....... Sodium Chloride: Sodium Nltrate: Sulfuric ..... Sodium Chloride: Sulfuric Acid .............. Sodium Chloride: Sulluric. Chlorine + CIO, .... Sodium Chloride, Vapor & Condensate ........ Sodium Chloride, Wet NaOH. Chute .......... Sodium Chlorite ....................... .................. Sodium Chlorite ... tSee list of lrademarks Unknown - 100 HETRON’ 92199P TEMPERATURE. HETAON 721971197A lW/- lee - - AMB AM0 - AMB AMB AMB - AM6 215!- - 1M) - - 160 15Ol- 165 100 - 2001150 - 150'- - 120iAMB 1201lie- NR - Unknown 176 14Ol140 120’ NR NR - 2cHl 176 140 -I90 140 - 200 - 200 160 - 200 15:15:15 5CU53 Sal’d Sal’d All 2 10 10 25 32 6&d 170 220 120/12O/- 90 Sat’d 3.2M:3.4M 150 170 - 140 1401- NR 140 2oa 140/- 16W90 16oirro 22Of140 - 2101220 1&J:1601- AMB AMB/- 1801160 160 160/l&I- 160 1601- LS - 180 203’ 200 160116Q - 160 130 NR - - 2co 200 - 160 210’ Sat’d Sal’d - Sal’d NIU- Sat’d Sat’d 3.4M:32M 210 165 190 220 - NRI- - - NR - LS - ZlW2101- NR 150 120 tons/day 2 - - gpl 23:35 25 212/200 2101220 160 160 212 100150 - 200 165 6:620 6.12 Sal’d 210!220 - 160/150 ZM) Sat’d Sal’d 210:220 - 170 120 Sat’d Sst’dJ 2w:340 2M 1M 212 2335 - 150 145 12:10:2 2101220 16CllW 160 -310 QVI Sat’d - 1601NR - AM0 200 210/220 - - 125 Sal’d 2101220 l40'- 160/160/- IWAMB 20:450 gpl:Sal’d:Trrce 150/- 1601150 150,- AM6 gpl 2101220 1601- 250 160/160/- AMBI- -i90 - 210/220 - 200 140 _ 165 - lW160 10 200 160~160 16oi140 1e01150 160 160 45 15% 150 - 176l160/120 1601- 140 Sat’d _ 2ao 40 sat d 15 65 - - - - All AMB 14O/- - 10 Sat’d IiETROH 920 SEWS980 2001150 15 Sat’d TYPES HETRON 700'7ooc AMWlOO - 100 All 340%0 OF FOR RESIN AROPOL 7240 7430 SERIES 160 - 160 AM0 - 212 175 175 - - - - - 210:220 210~220 and product name8 (continued) Synthetic Resins and Polymers TABLE 1.54: POLYESTER AND VI ‘L ESTER RESII S-ASHLAND (continued) SERVICETEMPERATURE.OF CONCEN. TRATION % CHEMICAL ENVIRONMENT ...... .... Sodium Chlorltr .... ......... Sodium Chromate ... Sodium Cumene Sullonate .... Sodium Cyanide’ ...... : .... : .. SodiumCyanide’. .......... 1:::. ........ SodiumCyanides.. Sodium Dichromato ...................... Sodium Dkhromatr: Acetic Acid ............ Sodium Di-phoaphato ..................... Sodium Dodocylknzeno Sulfonata, pH 8 ..... .................... Sodium Ethoxyrullatr ..................... Sodium Forrkyanide Sodium FormcyanIde ..................... Sodium Fluoride’ ..................... ................... Sodium Fluororilkatr’ .............. Sodium Hoxamotaphasphate Sodium Hydmgon Phoaphato .............. Sodium IiydrcHulfldo ..................... Sodium Hydrosulfldoa ..................... Sodium Hydmsulflde: NaOH’ .............. Sodium Hydroxide’ ....................... Sodium Hydroxide’ ....................... Sodium Hydroxide’ ....................... Sodium HydroxIdea ...................... Sodium Hydroxide’ ...................... Sodium Hydmxido’ ....................... Sodium Hydroxldr’ ....................... Sodium Hydroxldo’ ....................... Sodium Hydmxldo: Ccl.: Alumlnum Chlorida . . Sodium Hydroxide Croaylk Acid ........... Sodium Hydroxldr: Ethylonr Dlamlne: Diethylena Triamlnr: Water’ ............. Sodium Hydroxldr: Gluconic Acid ........... Sodium Hydroxldr (10% lxpoauro time): H,SO, Paato (90% rxporun tlmo), sulf1da Roductkn Proco8aJ .............. ..... Sodlum Hydmxkk, Intomtlttont Smlo’ Sodium Hydroxldo: NaHS ................. Sodlum Hydroxide Noutmlizatlon of Acidk Organks ..................... Sudlum Hydroxide Nwtralizatkn of Acidic Totuono, Naphtha ................ Sodium Hydroxide Scrubbing Cl, Blow Gas ... Sodium Hydroxldo Scrubbing Cl,. CIO,’ ...... Sodium Hydroxldo: Sodium Thio4fate 6 Sulflde’ ............................. Sodium Hydroxldo Vapor & Condonsatti ..... .............. Sodium Hypochlortto34.47.. .............. Sodlum Hypochloftt&~47.. ............... Sodium Hypochlorlt&~*7.. Sodium Hypochloriter 4 5. 7 ................ Sodium Hypochloritr Reactor, 10% Excess Cl, ......................... Sodium Hypochlorlto Reactor, .................... 10% Excorr NaOH’ Sodlum Hypochlorlto Vapora ................ Sadlum Lauryl Sulfatr ..................... Sodium: Magn4um: Calcium ChlorIdr Solution ....................... Sodium mota~araonltr ..................... Sodium Mothacrylatr, pH 10.10.5 ........... ................... Sodium Monophoaphatr Sodium Nitrato ........................... SodiumNitritr.. .......................... Sodium Nlttitr: Sodium Chlorldr: Sulfuric ..... Sodlum Porsulfrtm ........................ Sodium Phoaphato. Mono, pH 1-3 ............ Sodium PhosphatePhorphotic Acid Scrap Liquor. pH l-3 ..................... Sodlum Polyactylatr. pH Oslo.5 ............. Sodium Silicate’ .......................... Sodium Silicate, pH 1223 ................... Sodium Sulfate ........................... Sodium Sulfate: Boric Acid with 0.25% Sulfuric. 0.03% H,O,, 100 ppm Iron, 3000 ppm Chlorldr, TomPoratun Cyckd" “+fETRO% COndrt~onS 197 and wtth 700 Some Serk?S r.?s!“s CtsZ!“g but dogear Sat d Sat‘d 43 Sat'd 50 10 Sal‘d under METROW 72119711971 FOR AROPOL 7240!7430 SERIES --ILSlSO~NR 103 - --ILSl2O/NR lx):- 180 - 1M 210!2co 9ot160 120' 120' - Sat'd 220 250 180150 Sat'd All --1220 180 - 180150 - All Sst'd Unknown 15.65 45 15:15 1 5 10 150' - 160 - 155 NW1401180 NRl1B.I NFU- 15 NIU- 25 50 NW- 120 220/200 220'200 - - 140 NR 140 - 14O/ldoi_ LS2cO~120 150 LSAMB NR NR 212'150 150 NR 2121150 NR NR - 212115a 2lZlM NR - 120 120 NR NR 520 - - 80 - NR - 150 - - NR 140 NR - @W'F 2Q 5 NW- - NR NR 120 120 100 NR NR NR - 180 125 120 110 120 LSJNR NR 125 120 120 125 125 - - 100 100 150 130 180~150 --1150 Sat'd B:8:20 220 18CN- 20 - 1401 - loo 120 150 150 1M 150 120 180 250 180 180 - l@OllM 1801150 - 2201180 22cul80 2101220 2101220 210/220 - - 120/- l&3- 150 200 25 6 - - All AhW180 cond,t,ons - 180 510 StaOc - 150 25 25:15 - - 1W Sat'd Sat'd 180 1801- 10 122:10 50 - - 15 15 5% - - 140 @lO'F NR 12Y- 2101220 180 1501150'/- - 15 2 210:220 1M - 10 - LS125:NR 120'NR NW- 1Bo 125z'NR 1WNR 2101- 140 LSAMS 30.1.6 5 5% 210,2101- lcoNR 10:10:10:70 302 2101- LS/LYNR Unknown @ 160-F 5:12 15 15:15 2101220 2101220 - 120 - 200 160 HETAON 920 SERIES!980 - 180'- Sat'd 40 100 0.5 %@14O'F-33%&3'F-I HETRON 700 7ooc '50 200~180 - 180 120 LSl60iLSl60iNR -/loo - RESINTYPES ha - 150 - 30.70 to be unsurrable under cyclic are res,stdnt HETROM' 92/99P 209 tsee lslol - 200 180 160 9CjNR 160' 2ao NR 200' 2101220 - 175150 220.200 2101220 AMB --12061206 trademarks - -206 2ffi'f- and product names (continued) Synthetic TABLE 1.54: POLYESTER AND Vlh L ESTER RESI’ ;-ASHLAND Sugar Solution’ Sulfamic CONCEN. TRATION % .... Acid :: Sullanilic Acid : Sulfate: Ferrous Sullate ... 1. : : 1. Sulfate Recovery Boiler Gases ... ............. Sulfate Salts. Sulfurk ..................... Sulfated Detergents Sulfide Anolyte(NiS0 . . NiCI,. H,BO, @ pfi 1.5) for ekctro ............. nfinlng process ........... Sulfide Reduction Process Sullurk Acid Paste (go% exposure time): NaOH (10% exposure time) ... ....... ........ Sulfldic Spent Caustk. Petrochemical Sulfidk Spent Caustic, Petrochemical, .................... Nwtrallzod to pH S-6 SMte Liquors ............................. Sulfltr, Spent Liquor, Calcium Base MIII. pH 1.52 (trace lormk 6 acatk) ......... SSull4sophthalk Acid, Na Salt .............. Sulknate, Alpha Olefln .................... Sulfonated Allphatks. HCI, H.S. Butanol ....... Sulfonated Detergents Nwtrslization Fumes ... Sulfonated Detergents: Sodium Hydroxide: Sodium Trfpolyphosphate: Hypochlortte: Blsulflto Fumos .......................... Sulfonk Acid, Alkyl Benzene ................. Sullonk Acid, pnitrotolueno ................. Sullonyl Chlorfdo ......................... Sulfonyl Chlorfde, Aromatic .................. ..................... CSulfophthalic Acid CSullcphthalic Acid: Sulhwk Acid ............ Sulfur .................................... Sulfur Burner Gas Coolor. Wet to 3SO°F ........ Sullur Burner Gas, Wet to 35O’F .............. Sulfur Chlorfde ............................ Sulfur Chlortdr ............................ Sulfur: Cue: PbSO,: FsOz 2&O,: Bt,(SOJ, Dust ........................... Sulfur Dlchkrldo ........................... Sulfur Dichloride ........................... Sulfur Dioxldo, Ammonia Scrubber Process ..... SO,: Ammonia, Vapor ....................... Sulfur Dioxide Burner Gas, Cooler, Wet to 350*F .................... Sulfur Dioxide Burner Gss, Wet to 35O.F ....... SO,: CO,: N,: 0,: H,O Vapors ................. Sulfur Dloxtde, Dry or Wet ................... Sulfur Dioxldr. HF, H,S, F,H,SO.’ ............. Sulfur Dloxido; Oxygen: Nitrogen, droplets 80% Sulfuric .................... ........ Sulfur Dioxide Pulp Mill .......... SO, Removal by Cltroxt m Citrate Process ...... SO, Removal; Fossil Fuel; Limestone Injection Mist after Scrubber, pH 2.12 ........ Sulfur Dloxldr Sat’d. H,O: tracs HF, H,SO,, H.S. P ....................... SO,: SO, Fumos ........................... SO,: SO, Fumes, Watrr Spray ................ SO,: So,: HCI: H,SO,: Caustk It,0 Fumes ...... Sulfur Dioxidr: SO,, Wet @ 14gooF............. Sulfur Dioxidr, Trace Sulfur Trtoxide ........... SO,Vaportzatlon ........................... Sulfur Dioxide, Wet; Wet: CO .. N,, 0 .. .Dust to 350-F ................. Sulfur Fungklde ........................... SulfwHumld Ah. Fumos .................... Sulfur snd Machlne 011 Fumes ............... Sullur. Molton @ 250.28o’F .................. Sulfur, Molten (H,S, SO,, H,O, SO, in ppm) @ 260~30Cr°F .................. Sullur. Molten, Vapors ................. Sulfur Trioxide, Dry ...................... Sulfur Trioxide: SO,, Wet 2 140-F ........... Sulfur Trioxide, Wet ...................... ,See I,$., or lradrmarks and product nem~~ TEMPERATURE. NETRON 721197!1971 - 50 Sal d ... : ...... HETTRIJN’ 92199P 164 All - 15 16 - 3003co/- 24.10 135 050 200 OF FOR RESIN AROPOL 724017430 SERBS - AM0 160~100 - 160~150 150 - 1601100 130 160 - 200 25 50’1.6 - 130 - 2101220 NR - 100 - - - Vlpor - a0 120 NR - NR - w LSW/NR - - - - NRNPJ- NR NR - NRI- - - NR NR - NR - SATlSATlNR NR SATlSATlNR NR NR 200 115 120 by VOI 100 Water Sar’d 7.15:79 Fumes 2101220 NR _ 0.06:0.02 by VOI ).1:1270:5:14 190 - Vaoor @ 60-F 100 - - 2101220 NR @ 80-F 25:1&z!k10:83 190 - NR 100 - NR 100 @ 75-F im - 130/1601120 193’ 24 - _ 1M 140 190’ 100 NR SAT/SAT/N R NR SAT/SATlNR NR - - 120 250 170 175 --/10400/- 160/150 - 22Ol- - - - - - 170 - 1W 6.10 - - - 190 - 120/- - 250 140 - - - - - NR - lEOI- NRI- - SATlSATlNR 200 HOT -/SAT/NR 100 -/SAT/NR 100 2101250 - 190’ -/LYNR 100 100 100 24 76 NR/NR/- 1501- 7614 2 NFV- - 140 Unknown NR - 140 - 2101220 130 100. 100 210 21012101_ 2001- 4p 212-F 25 100 - HETRON 920 SERIES’990 lx)/- 150 130 TYPES NETRON 7001700c 170 20:5 211 (continued) SERVICE CHEMICAL ENVIRONMENT Resins and Polymers 30013cO/- NR NR - SAT/NR NFU- - NPJ- AMB -/LSiNR NR - - AMB NR - 21OQ20 NRI- (continued) 212 TABLE Corrosion Resistant Materials Handbook 1.54: POLYESTER AND VINYL ESTER RESII ;-ASHLAND (continued) SERVICE CHEMICAL ENVIRONMENT CONCEN. TRATION % Sullur, Wettable. Fungicide .......... .... ........ Sulluric Acid Sulfuric Acid Sulfuric Acid ‘.’ : 1::: .” :’ Sulfuric Acid SulfuricAcid.. ... :.:.:::.:::.:..:::::::::. Sulfuric Acid .............................. Sulfuric Acid ............................. Sulfuric: Ammonium Blsulfste: Surfactrnt ...... Sulfuric Acid: Ammonium Sulfate: Manganese, pH 9 ................... ..... Sulfuric: Anodizing Solution Sulfuric: Benzene Sulfonic Acid: Water : ....... Sulfuric: Chlorate, Methanol, Sodium Sulfite .... Sulfuric: Chlorine Saturated .............. Sulfuric: Chromk .......................... Sulfuric: Chromk .......................... Sulfuric: Chromic Acid ...................... Sulluric: Chromk Acids ..................... Sulfuric: Chromic Acids’ .................... Sulfuric: 2% Chromic Oxide ............... Sulfuric (106N): CIO, ....................... Sulfuric, Cont.: Nitric, Cont. Sulfuric: Contaminated with Maganese Sulfate and Oxide ........................ Sulfurfc: copper Salts ...................... Sullurk: CopfJer Salts ....................... Sulfurtc: Copper Sullrte ..................... Sulfuric: Copper Sulfate ...................... Sulfuric: Copper Sulfate ..................... Sulfuric: Cu: Fe: Zn SlurryrThickener ........... Sulfuric: 1% Dodecyl Benxene Sulfonic Acid ............................ Sulfuric Evaporation ....................... Sulluric: FeO.TiOI Ore, Sterm.Air Agltrted @ 220-F ........................ Sulfuric: Ferric Sulfate: Cupric Sulfate ........................... Sulfuric Acid Fume Scrubber ................. Sulfuric Fumes In Steam .................... Sulfurk: HCI ............................. Sulfuric: Heavy Polymer, Trece Iron and Hydrocarbons .................... Sulfuric: Hydrochloric Acids ................. Sulfuric: Hydrochloric: Antimony Trioxide ...... Sulfuric. 26% by Wt.: Hydrofluortc, 20% by Wt.: Hydrocfrlorlc. 66% by Vol.: Sodium Dichromate, 3% by Wt.’ ............ Sulfurk: Hydrogen lodlde ................... Sulfuric: Hydroxylemine Acid Sulfate .......... Sulfuric: Hydroxylrmmonium Acid Sullrte ...... Sulluric: llmenite Ore, Steam.Air Agitation a 22O’F ....................... Sulfuric: Llgnin: CrudeTell Oil, pH3 ............ Sulfuric: Manganese: Ammonlum Sulfates. pH, Sulfuric: Manganese Sulfate ................. Sulfuric: Manganese Sulfate ................. Sulfurk: 60%: MEK, 160% ................... Sulfurlc: Metal Sulfate Baits ................. Sulfurtc: Na, Mg, Zn Sulfrter ................. Sulfuric: Na Sulfate ........................ Sulfuric: Na SulfrteSat’d. with Cl, ............ Sulfuric (10.6N), Na,SO,, 0.06 gpl NeCIO,, 0.2 gpl N&I ..................... Sulfuric: Nltrtc Acid 609 .................... Sulfuric: Nitric Acldr ........................ Sulfurtc Nltrk Acldr ........................ Sulfuric: Nitric Acids @ 160~200aF ........ , ... Sulfuric: Nltrtc Acids @ 210°F ................ Bulfuric: Nltrtc: Copper Baltr ................. Sulfuric: Nitric: DinitroToluene Fumes. ........ Sulfuric: Nitric: HCI @ up to 22S°F ........... Sulfuric: Nitric: Hydrochloric ............... Sulluric: Nitric: Na dichromrte: Cr,(SO.), ....... Sulfuric: Nitric: Phosphoric: Nonionic Surfactant ................... tree !istof trademarks andprod!Jcl names HEmON’ 92 99P 8 25 50 50 Q 250-F Iti230 70 150 loo’- 75 80 93 30:6:10 2x NR- LSLS:NR 190’ 175/175/NR 724017430 SERIES NR NR 1M NR 110 LSNR 190/16i AMB NR - NR _ --1100’1100 - - AM0 140 - - 125 60 ?OfJ- - - NR NR - NR NR NR 160 NR 225 NR 3220 80 NR- 90 165 NR- 120’ NR NR - 140 10 gpi - 33.31 gpl - 150 - 120 150 200:50 gpl 10%.60 10:5gp1 NR- NR 120 - - - 150 - - 165 NR - NR’Y- 2a10:10 160 33 - 194 300/140 0.05 45 15 - 60 - 80 - - 30.1 160 - - x15:5 - 100 - - 10.86-W 1KU.3040 3OsO.10 40:13.135 gpl 1090 NR” 125’ - gpl 90:10 lo:24 Kv- lo:24 - 35:23 35.23 30 56:26 8 16O’F - - 156 - - 125 160 - - - - 200 125 125’ - 203 - 60’ 135 molar 20 1030 7 013.6.25 gpl 5.20 11 0 1 200 - - 60’/- 60 ao’i- 135 160 130 - - - 130 160 - NR NW- - NFV- 60’ 8Ol- AMB SATISATINR ppl - 1W NW- 20:s 179.5:112 - NRIMB/- f&:26 38a.5 10:1020:6 -no lh7 25 gpw QPI 70:Sat’d 2650 - 1x1’/- 150 160 - NW- 120 - NR 212 NR60 - NR - 160 a12 l&5 1020:3&40 220:2co NR - - 70 to 70 210~220 210 226 NW160:120/NR 20:20 16.12.5 a:31 _ 22512oC NR - 1oO.F HETRON 920 SERIES,980 NR 5353 OzlQal 1613 a 155-F 53:47byvol@ TYPES HETRDM 7001700c 1601120 1501NR NR - 30 125.13 gpl - 60 ‘F FOR RESIN AnomL 140 25025a200 200 NR - 7.6x.5 Unknown TEMPERATURE, HETRON 7211971197A - NR 160 - NR NRI- NR 90 40160 - - (continued) Synthetic TABLE 1.54: POLYESTER AND VII L ESTER RESI ;-ASHLAND (continued) SERVICE TEMPERATURE. CHEMICAL ENVIRONMENT CONCEN. TRATION % Sulfuric, 70%: Nitric, 70% Pickling Acid Sulfuric: Nitric: Water :: Sulfuric: Organic (Alkyl Benzene) Sulfuric Acid Paste (90% exposure time): NaOH (10% exposure time), Sulfide ............. Reduction Process : Sulfuric, 93%: Phosphoric, 85% @ 160°F .... .. ...... : : : Sulturic: Phosphoric Acid Sulluric: Phosphoric: Hydroxyacetic Acids’ .... Sulfuric: Phorphortc Acid: Sodium Hydroxide: Trisodium Phosphate: Water .... Sulfuric: Phosphoric Acid: Sodium Hydroxide: Trisodium Phosphate: Waler .... Sulfuric Acid, pickle liq. tank covers .......... ........... SuIturic: Soap ............... Sullurfc: Sodium Chlorate: Chlorine Dioxide: Methyl Alcohol’ ................. Sulfuric: Sodium Chloride .................. Sulfurtc: Sodium Chloride, Chlorfne and CIO, SuIturic:Sodium Chlorfde: Sodium Chlorate: Cl,: CIO,: Steam ................ Sulfuric: Sodium Dichromatr ................ Sullurlc: Sodium Dichromatr ............... SuIturic: Sodium Dichromate ..... : : .... Sulfuric: Sodium Dichromate ..... Sulfuric: Sodium Dlchromate: Chromic Sulfate Sulfuric: Sodium Dichromate Over Storm Coils ...................... Sullurfc: So&urn Nflralr: Sodium Chloride ..... Sulfurfc: Sodium Sulfate, H,S and CS, ........ Sulfuric: Soya Oil to 3W’F .................. Sulfuric: Sullate Salts ...................... Sulfuric: CSulf~phthalic Acid ............... Sulfuric: Traca Dichlorides .................. Sulfuric: Trace Dichlorides @ 196OF .......... Sulfurk: Trace Nitrogen 6 Nltrobenzene ...... Sulluric: Trace Organiw .................... Sulfurtc: Trace Organic8 .................... Sulfuric: Traca Organics .................... Sulfuric: Trace Organic8 .................... Sulfuric: Trace Organics ................... Sulfuric: Trace Organics .................... Sulfuric Acid Vapor ........................ Sulfuric Acid Vapor ........................ Sulfuric Add Vapor ........................ Sulfuric Acid Vapor ........................ Sulfuric Acid Vapor with Trace Niltic ......... Sulfuric Acid, Waste, with up to 16% Dinitro Butyl Phenol @ lsO°F ............. Sulfuric Acid, Waste, Leaching, pH 2-5 ........ Sulfuric Acid Waste with Metal Salts ......... Sulfuric Acid, wasle pickle Ilq. ................ Sulfuric Acid: Water: HAS (Hydroxylammonium Acid Sulfate)’ ........................... Sulfuric Acid: Watrr: HAS(Hydroxylammonium Acid Sulfate)* ........................... Sulfuric: lg20%: Xylene Derivative: T-Amine: Alkaline Metal Sal1 ............... Sulfurk: Zinc Sulfatr: Sodlum Sulfate ......... Sulfurfc: Zfnc Sulfatr: Sodium Sulfate ......... Sulfuric 134% Zn Sulfate 1.3% Na Sulfate 38%. CS,. Amines. Sat’d. with H,S .......... Sulfuric 5.10%. Zn Sulfate I-8%, Na Sulfate S-25% Sat’d. with H,S. Trace Amines ........................... Sulfurous Acid ............................ Sulfurous Acid ............................ Sulfuryl Chloride ........................... Sulfuryl Chloride ........................... Sulphidr Anoiyte. Nickel Plating Tank pH 1.5 .... Super Phosphoric Acid .............. ... Super Pnosphoric Acid ..... ::: Surfactants, Alkanolrmide .............. Surfactants. Amide Type ................. Surfactant. Anionic ..................... Surfactants, Linear Primary Alcohol Type tSee lisl 01trademarks 51 10.5 5.399 75 2 20:5 5050 HETRON’ 92’99P - 80’ 80:&,/N R NIX’- L.YSATI160 - x)51:29 160 NR _ 150 - - Unknown 45X?ogpl.Sst’d:Trace 12:a 35:23 TYPES HETRON 7001700c 80 NR - NR - - 100 - - loo 200 - - HETRON 920 SERIES/980 ao’NR- 243/243l- 2 14.2:0.5:82 2.5.20.2.0.5.75 25 lF FOR RESlN HETROM AnomL 721197l1971 7240'7430 SERIES NR- lOso 213 Resins and Polymers 21512w 145 - 212 120 4N 1M lM.Sat’d 30.3 - 30.5 ozfga1 32.4 - 42 5 oz/gal - 180 - 150 NR NR NR - 180 160 1M) - 60 - 952 gpl:Sat’d - 22+?6:3.5-5 2cKa:a 10:20 10% lo:24 - 1.6:M - 30 76 30 @ 160-F 30 47 @ 166-F NR 180 125 SAT/SAT/NR 135 100 166 -lLS/NA - 76 60 0 166-F NR SAT - - LSlMllNR - - NR NR - 166 62 0 166-F 72 @ 166’F - NR - 60 140 140 - NR NR - 50 140 NFU- 140 NR 120 NR - - NR NR 220 1wJlsl 98 @ 1Bo.F 1520 65.70 25 166 - to xx) NW- - l&I NFU- -/NR AM6 177 gpl -/go - w:20:20 75:14:11 - - 200 NR 100 - 100 loo 1MYNR NR 1.55:3:5 10 Sat’d 99 @ 120-F 100 0 75-F l&7'/- 205/- 610:18:1wo w- - - 16Y- 165 M2wI- %2oo 150 NR 150 NR AM6 - NA NR NR NR loo/NR NR NR NR AM0 NPJNW- - - 1001- lscl 76% P,O, - 300/3001- AMWNR 22012oo 210/22fl 2201200 210:220 120 100 120 AMWNF - 100 58 120 - - 120’ loo - 120’ loo 160 120 120 120 and product n.snes (continued) 274 Corrosion Resistant Materials Handbook TABLE 1.54: POLYESTER AND VII CHEMICAL ENVIRONMENT Surtactants, Linear Primary Alcohol Type-Ethanol Surfactant, Nonionic. Alkyl Ether Amine Oxide Surlactant, Nonionic, Tergitol 15&9t’ : : : Surtactant, Nonyl Phenoxytriethoxy EthanolType ........................ Surlactant, Polyethylene, oxy Derivative ...... Sweet Crude Oil .......................... Sweet Oil ............................... ... .... Sweetwater 35Dt: Acrylonitrile : : : ........... Tall Oil Tall Oil, Crude, ;.iO/.‘&en; hcid: Lien& &I 4:3 Tall Oil, 2% Spent Acid, pH1, Lignin Tall 011: Sulfuric: Llgnin, pH3 ........ : .. : : : Tannic Acid .............................. Tanning Leather, Drums .................... Tar Camphor ............................. Tariaric Acid ............................. “Teller” Scrubber, Wet Process P,O, Plant’ .... Telonett. Fumigant’ .. ............ Terephthalic Acid: HCI: Dimeth;; Formamide: Water .................. .......... Tergitol 15&9t .............. Tetrachlorocyclopentane Saturated with Cl, and Trace HCI. Ccl., Dlcyclopentadleno and Hexachlorocyclopentane .............. Tetrachloroethylenr ........................ 1.1,2, P.Totrachlorethylene : ................ Tetrachlorophenol, Sodium Salt .............. Tetrachloropyridino ....................... Tetrakls (Hydroxymethyl) Phosphonium Chloride .......... ....... Tetrakis (Hydroxymethyl) Phosphonium ........ Chloride, HCI, Ii,0 Vapors ................. Tetrapotasslum Pyrophosphatr .............. Tetrasodium Ethylenediamine Totraatate’ ..... Tetrasodlum Pyrophosphatr ................. Tetrasodlum Pyrophosphate ................. Textonet Bleach Thermolin RF-23Ot ......................... Thermolin RFe230t ....................... Thioglycol, Mono .......................... Thioglycolic Acid .......................... Thionyl Chloride ........................... Thionyl Chloride, Vapor ..................... Thiosorbic Lime ........................... Tin Fluoborate Pletlng Bath, 18% Stannous Fluobrate; 7% Tin, 9% Fluoboric Acid; 2% Boric Acid’ ......................... Tin, Molten, 7W*F, Fumes .................. Tinoflx DFt ............................... Titanium Sulfate Ftsduction Process ........... Tobias Acid ............................... Toilet Tanks, Aircraft ....................... Toluene .................................. Toluene @ 120’F.. ........................ Toluene Dllsocyenete ....................... Toluene Sulfonic Acid ...................... Toluene Sulfonic Acid ...................... Toluene, Vapor ............................ Toluene, Vapor 6 Condensate ................ Toluene, Vapor & Reflux .................... Toluene: Xylene: Aromatic: Aliphatic .......... Tolyl Chloride (0) ........................... Toxaphene: Xyleno ......................... Transformer 011 ............................ Trensmlsslon Fluid, Automatic ............... Tributyl Phosphate Tributyl Phosphate: Aromatic Solvent ......... .................... Trichloroacetaldehyde Trichloroacetic Acid ........................ Trichloroacetic Acid ..... .... ......... .......................... ......................... tSee hst of wademarks ‘L ESTER RESI ;-ASHLAND (continued) SERVICE TEMPERATURE.‘F FOR RESIN TYPES CONCEN. TRATION % HETRON 9Zi99P HETROM 721197'197A 1W - 12C’ - 120 - - 120 loo 12C - 120 - 12011 - - loo - 1W 28 100 100 98.2 10:30:60 Sat’d 100 Sat’d Cone 14:28’7:51 100 100 100 loo 13 loo loo 105 210 loo - AMB - - - 200 - 200 _ 200 All loo loo Sat’d 65 loo loo loo loo 86.3:5:6 100 @ 200-F 90:10 loo loo loo 35.65 100 @ 1W’F o-50 50 2W 250 - - AMWNR NW- - _ loo loo - - - - - - 12016s - - loo --ILS12Ch’NR AM0 NR ea1w NR - NR NR 120 120/- - - 170’11701NR NRI- _ AMB 125 SO/NR 1ZY- 65-80 NR lYX1501NR 130 22wOO BOlNR - 210/220 - - _ NR NR AMB’ - 200 - AMBINR NR NR NR - AM0 loo - 200 - 120 - 230/230/901--iNR 122 AMB NR - - 150 loo lW/- NR 200 AMB’IAMBINR NR 150/150/- - - SAT AME’ 80 lW/- lW/- - - so/-- - zoo/210/LS.AMBllW NR/.30/210/210/- - - AMB AMB ZlOi- - - AM0lNR AMB‘ AMB NRI210/2101_ AM0 NRI2wi- 1501NRINRI- 200 22a2w - 150 NR/- 180 - - 95 95 12U/- 210;230 - 22012w - - AMB NIV-/NR - - 125 - SATI- SERIES!980 1801150 - 125 -/125 -/125 NWNW- "ETRON 920 250 95 NR 120’ - 2@J 2w - 80 200 - 160/1w SAT 6w220 - Sat’d 50 _ 140 - HETROW 700 7ooc 100 - 16nilM 14af- AMW- 80 All 5 Sat’d @ 75-F Pure Impure loo 10 loo AROWL 7240:7430SERIES NR - 200 AM0 LSlBOrNR AM&- NR - 180 NR 2101- 180 210/- and Droducl names (continued) Synthetic TABLE 1.54: POLYESTER AND VINYL ESTER RESI ;-ASHLAND Resins and Polymers 215 (continued) SERVICE TEMPERATURE. ‘F FOR RESIN TYPES CHEMICAL ENVIRONMENT CONCEN. TRATION % Trichloroacrtonitrile. Trace Acetonitrile and HCI ................ Trichlorobenzene Trlchlorobenxene Vapors Wet wrth HCI’ : : ... 1, 1. l.Trichloroethane 1. 1, Z~Trtchloroethane ....... .. 1: : 1: : ... Trichloroethylene’ ...................... I, 1.2.Trichloroethylrne .................. Trlchlomethylene, 50%. .................. Trtchloroethylenr: Chlorinated Orpanics: ........ Hydrochloric (32%) ... ... Trichloroethylrne Fumes; 22% MI; 10% Cl,; 9% 0,; 6% CO; 4% H, ........... Trichloroethylene, HCI, Ct,, H,O Vapors ...... ..... Trtchloromethane ........ Trichloromonofluommethane ... : : 111: ..... Trtchlorophenol .......................... Trtcmyl Phosphate ...................... Trldecyl Benzene BulfonateDetergent Base Triethanol Ammonium Lauryl Sulfate ........ Trtethanolamine Llnaar Alkylate Sulfoneto ... Trlothylamine ........................... Triethylamine Hydrochlortde ............... Trlethanolamlne ....................... Trtethylene Glycol ................ Trtfluorovlnyl Chloride, Oils and G&ares ..... Trthydroxybenxoic Acid .................. Trtmethyl Borate In Methyl Alcohol* ......... Trlmethyl Carblnol ....................... Trimethylamlne Hydrochlodde ............. Trimethylamina Hydrochloride, pH 54 ....... Trlmrthylamine: HCI ..................... Trimethylamine HCI: Ethylene Oxide Reactlon Trtphenyl Phorphlte .................... Trtr (Hydroxymethyl) Nltromethane: Formaldehydr: Water, pH3 .............. Trtsodlum Phosphate ..................... Trtsodlum Phorphatr ...................... TunaOil ................................. Turpentlnr: Chlortno ....................... Turpentine, crude sulfate @ loOoF ........... Turpentine: Methyl Alcohol ................. Turpentine, Pure Gum .................... U-34EQt and U7000t. Styrene Acrylic Emulsions ....................... Ultraformer Fead, Reflnory .................. Ultralormer Faa&Xylena ................... Ultraformer Heavy Faed. Rrflnery ............ Ultrawett BOK Blodagrrdable Detergent ....... Ultrawet 46DS Btodegradable Detergent ...... Ultrawrt WL Biodegradable Detergent ........ Underground, Clay Soil ..................... URAN Ferlllizer~Ammonium Nitrate Composition; 44.3% Ammonium Nitrrtr. 35.4% Urea, 20.3% Water ............... Uranium Bxtraction ........................ Uranium Fluoride, KOH, HF, KF, K.0, K,UO., Cb, KCI, KOCI, KCIO,, KCIO., CO,, K,CO,, KHCO*, H,CO,, UO,CO,, F,, CIF,, DF, ....... Uranium SX Units ......................... Urea .................................... Urea: Ammonium Chloride: Ammonium Nitrate ................................ Urea: Ammonium Nitrate: Water ............. Urea: Ammonium Nitrate: Water ............. Una: Ammonium Nitrate: Water ............. Urea~Fonnaldehyde Resin .................. Urea Modified Phenolic Rerln (Durazt 24942) ... Urotropine ............................... Vanasol @ 6Cl’F .......................... Variquatt K-300 ............... .......... Varisottt 222-90 ...................... Varoxl6SET.. .......................... Varsolt @ 2G1°F .................... Veneer Drying Fumes .................. tSeeltst01trademarks and Droducl names HE7RON’ 92199P loo - 100 - NW- 100 NPJ- 100 100 NPJ- 100 @ 120-F NFU-I175 14:0.9:85.1 @ 104’F NRJ- - 175l12ui- 100 @ 80-F 1W 100 @I 175-F 100 HETROI 72119711971 AsomL 724017430 SERIES - NR- NR - NR - 80 - NR NR NPJ- NR NR - NFU- NR - - - - ‘212J212180 BOINWNR AMB NR - - NFU- NR NR NR- NRJ- NR NR NR ml/NFV- NR 120 80 - 80 loo - - - - - 180 AMB 80 loo AMBI- &I’d - 15C:- - - - - - - 13W- 130 130 NR - 122 9O/NR Sat’d NR NW- NR lSo/120 NR LY- LS - SATlNR -f90 120 AMBI- 15O.F 100 en - - AM&--I- 1w loo - - - - 1w AMB Sat’d - SAT -Do 160 38:2.5:20 AMB - 210/- LS AMB NRIAMBilW - - - - - AM0 AMB loo - - loo loo’/- SAT 1SOIAMB SAT ll301- 150190 - - 80 100 @a- - 12iX- 120’ SATI120’1120 120/- 120’ 120’/120 NW- 120 SATISATI10 3w/3Wi- 120/- - AMB 80 -/SAT/NR 1201- - 120 - 160/NFVSAT’I- - AMB 2cK3o:50 354420 loo - 2101- AMB 120 - 28 1 - 180 - SAT pli 78 lWi- 150 130 AMBI- - 180 - AMBIAMBI- loo 130/- 1201- 150 AMB AMBJ- loo SC++*.3 @ 320-F 4oI10:50 130 - 120’ 2s - - - - 51a8:49 to48:loB5Q NR - - -190 BW120 210’/- 15OI- lx) loo 130 loo - - loo Sat’d a 75-F too 1W loo.37 - - 120 NR - loo SO 98 loo NETRON 920 SERIES’980 NR - 85 NR 120 loo loo HETROW 700’700c 120 SATINR - SAT SAR- 120 1201- 120 120 SATINA - 120/1201SAT,- (continued) 216 Corrosion Resistant Materials Handbook TABLE 1.54: POLYESTER AND VI NY L ESTER RESINS-ASHLAND (continued) SERVICETEMPERATURE.°FFORRESINTYPES CHEMICAL ENVIRONMENT CONCEN. TRATION % Vegetable Oils’ :. : ..... Viddbn Dt Fumigant’ Vinegar ....... : .... Vinyl Acetate ........ Vinyl Toluene : : : : : : : 1 : : : : : : 1. .. 11 : .. : Vlnyl Trkhlortde’ VlvoZynet ............................. Wash Solution. pli 13.6’ ................... Washer Hoods, Ducts, Chlorination, CIO,. and Brown Stock .. , ................... Waste Oils, Gear. Cutting, etc., Treated with ............... Lime and 93% H,SO. Waste, Organic, H,O, HCI, Cl, Vapors ...... Waste Water Treatment Water: Acid: Organic conta’mbtated : : : : : : . Water, City (t&69 pal) ..................... Water, Condonaate. pH 7.342 with NH,, NO,, SO., B, Cl, 0,, H,S ............. Water, Condensate, Buffered .............. Water, Condensate, Traa Amounts Mercaptan, H,S. Turpentine, Acetone .............. Water, Condensate, Zero Hardness, pH 8.595 @ 2W.210°F ................. Water. Contaminated with Aromatic Solvents, Salts, Hydrocarbon Rosins, Organics; . Slightly Acid to Basic ................... .. wltaf, Cooling”, ph 5.57 .................. Water, Cooling, 26 ppm Chromate ........... Water, Cooling lower ..................... Water, DelonLuP~ s ...................... Water, Doionized, High Purity 1.5 pmhdcm. ... Water, Deminerallzedd’ ................... Water, DistIllad’ ......................... Water, Drinking’ ........................ Water: Ethylene Glycol rg 212OF ............ Water,GoothomlJl........................ Water, Geyser, Condensate ................ Water, Ground, Organic(1.310 ppm) Contaminated”, Untreated, pH 5.7 ......... , .......... Water, lrrtgatlon ............... ......... Water, Light, FC195T ........... Water, Light, FC203t ...................... ...................... Water.09 Separation Water. Organic: acid contaminated @ 15rYF ... Watec pH3, pH7. or pH 10 .................. Water, pH 5 to 9 (1.13 at tlmos) with HCI: Cl,, Benzok Acld; Baruoyl, Bansal, Bonql Chlorldoa Praaent ................. Water, 13,ooO ppm latk acid ............... Water, 6.ooO ppm chlorobenzeno ............. Water, 166 ppm methylone chloride .......... Water, 3,DW ppm 15ooctyl alcohol ........... Water, 56 ppm Phenol ...................... Water, 566 ppm sodium chlorldo ............. Water Sat’d. with 1.525% Ozone in Oxygen ... Water, Sea ............................... Water, Sea. dorrllnatlon pH 7.5 .............. Water, Sea, deaalinatlon pH 7.5 .............. Water, Saa, dosalinatlon pti 7.5 @ 265.F ...... Water, Steam Condanutaa ................. Water, Storm Condonsate, Steam; Buried ...................... Pipe B upto2Ul.F Water. Sulfuric: Aoatlc: Methylanr Chloride: Octyl Alcohol: Sodium Chlorlde: ......................... Chlorobenzrm Water, Tap ............................... Watr Treatment, Dye Plant, pH 2-3 ........... Watn Treatment, SoHonIng end Coagulating ......................... W8tar, Vapor 5 Condarwato~ ................ "AROPOL _ _ COnC 100 100 Q 75-F AM&- 1OOGi BO'F - 100 - 100 NW- HETRON 72:1971197A NR AM0 80’ NR - NR AROPOL 7240.7430 SERIES HETROh 700~700c 1BOilM NR NR - 2101220 NW- NR - 8Ol- 100' - 100 150 - SAT - - NW- NR 175 NR - - - 150/150/NR 15OINR 100 l&X- 180 1801150 - - 100 loo/- AM&- 100 103 100 loo/160/- loo - NW- %x0 - SATISAT'I- 100 180 180' 120 180 212/212/180 210/210/180 NR - - NW- - LS/- AM&160/- 100 100 NWAM&- g&5:1.5.2 - - - 110 AMB 160 120 AMB SATlSATlNR - 180 120 1801120 1601140 2cK!l‘% AMB"/- - - 1.7xNormal 2.75xNormal 100 2owNR 413:0.3:1.3:0.01:0.3:0.5:0.8 - 2p30.WOga~ tank 180 AMB/18011’ 2101220 2101220 AM&- 700 NR as mola~ng cpd - - 125l- AMB’ 120' AMB SATiNR Ah48 - AMB - 120 NW- NR NW- 120 150 150' 150'/120 150' 140 1%3 212' NR 150 150 150 150 150 150 - 150 153 - 1Sc4u50 180 180 132 -/LSINR Normal 120 210/220 - AMBI- AMB . l&l 180114O - 18oiXl AMB"!NR" 125 150' 150' 150' - - 12Y- - - NW160/220 - 12Y- - - NR - 100 @15O'F - AME NR - -I103 HETRON 920 SERIES'900 - l.SOf- 96 5.2 1.5 "D~ssolvea SOCUS. 1574.21#~~m'f'O, 0.25Mm; fOra PD., 7.3pPm: Cu. 0 7ppm. zn.3.4ppm; Fe. l.Bpprn:CaCo, 450ppm mex.; Chromate. hexs. 1~22ppm. 0, resrdual. 0.20.45p~". NaQ 527.702wm '@NO change m waler a! 0 1 It' lammarelgal. as m WETROW' 92 VVP 210/- lSou50 - NR - 15011501NR 1501NR NR l&I 1801150 180 - 180 AMB - 180/- NW180 AM0 212 ‘Such es mefhylene chloride. 50 ~,wn: chlorolorm. 2; tnchloroethylene 8 tncnloroelhane. 14: alcohols. 7W. MEK 8 MIBK. 2X Benzenes. 105. Acetone. 50 Phenol. 2 etc AROPOL 7242 safrslaclory 7430 Set~SIac~ory. (continued) TABLE 1.54: POLYESTER AND VII CHEMICAL ENVIRONMENT ‘L ESTER RESI CONCENTRATION % Water, Waste with Pine Oil, Kerosene, Methoxychlor, Melathion, Xylene, Detergents, Chlorophyll, Surface Active Agents and Other Oils Water, Waste, With Solids. Oil, Grease Water, Waste, Trickling Filters ........... .......... Water, White .......... :: Wax, Chlorinated : : : : 1. ... :. Weed Killrrs ........................... Whey ................................... .............. Whiskry ................. White Liquor (Pulp Mill) .................. ............. White Water ........ White Water, Splash 6 Spills ................ ....................... Wine Fermentation’ Wine Storego’ ............................ Winery Waete ............................ Wire Pickling Fumes ....................... Xylone .................................. Xylone @ 120-F .......................... Xylene: Adogent 381 ..................... Xylene: Camphene. Chlorinated 68% ......... Xylene Derlvatlvr: T-Amine: Alkallne Metal Salt: 10.20% Sulturlc Acid ............. Xylene: DXE; Trace li,SO.; Flake Caustic Xylene: Koroaeno: 05% Phoaphortc .......... ........................ Xylene:Toxaphene Xylene/Ultraformor Fnd ................... .................... Zlmmltet, Mud Remover Zinc Casting Fumos ....................... Zinc Chloride @ 310°F ..................... Zinc Chloride ............................. Zinc Chloride Plrting Bath; Zinc Chloride: Sodium Chlortde: Ammonium Chloride, pH 4.862 ...................... Zinc Cyanlde Plating Bath, 9% Zinc rnd 4% Sodlum Cyanides 9% Sodium Hydroxide’ ... ............... Zinc Dimethyidlthlocarbanate Zinc Electrolytic Collr ...................... ........................ Zinc Fluoborate* ZincFluoborste Plrting Bsth, 49% Zinc Fluoborate; 5% Ammonium Chlortde; 8% Ammonium Fluoborate’ .............. Zinc Hydrosulfite ......................... Zinc. Nick.1 Hydrophosphstr, HF rnd Fluoslliclc’ ............................ Zinc Nltrste .............................. Zinc Phosphate ........................... Zinc Smelter Fumes ....................... Zinc Sulfate .............................. Zinc Sulfite .............................. tSe llsl 01lrsdcmarks Unknown - - (continued) SESVICE TEMPERATURE. OF FOR WETRON’ 9C99P HETRON 721197!197A AKBAMB’I- en AROWL 7240 7430 SERIES AM8 BT,PUB’ AM0 AMB’ AM0 100 @ BO’F - ll@- TYPES HETRON 7001700c 80 AM0 AMB - HETRON 920 SERIES’990 80 AM8 AM0 lBo12W - NR - - 17Y- - Bi:- 180 - 1501- - RESIN AM0 110 - - - - - AMB”/AMB”IAMB - 9YNR NR AMB NR NRllOO NW- - - - 140 100 -rw 100 NW- 75125 10:90 5050@185 NR- 333335 l-2 70 Sat’d l@Y2al 18.31:3 oLlga, 3.5 50 NW90 14W- Sat’d SATINWNR 100 122 100 NR cwYxwoJSAT/SAT/- - loO’/- - - - - 265 la5150 220/200 210/- AM0 - NR 180 160 -JlElO 80 180 210/- 200 lXU15O 200 250 - 160/- 140 - 2w 200 --‘153 NR - SAT All Sal’d lt<)iNR NR - - 100 160 S&d Sal’d Unknown lSo/lwI- 100 122 AbIB/--/- 10% NR l&w50 15C:100 2001- - 180 - 210/- 2201200 - 210/lBO/- and c)roducI names ‘HETRON 99P tar turns service on/y ‘Good hst nsutts 8tkr short exposure YJynmelic sudecing veil mxmmended for mrximum resistance ‘BenZoyl PeIVXid8 - Dimefhyl uniline cure system recommended t0 8Ssur8 satist8ctOty cervice *Postcure recommended ‘Solulion mry discolor ‘Nonthixotropic ns@ prefenbk _ .... =U/7SUtfSlUClO~ ;-ASHLAND 217 Resins and Polymers Synthetic US Ill7hlg ‘Acceptuble 8s to odor 8mi Iusfe tar AROPOL 7242 fype resin. Steumed 4 hours with rtmospherlc steam prior to exposurs “Three 3 hour exposures lo 30% nrtrlc 8t 100’F to simukte cleenin “NO discvlorution occurs et 5 rttfgul. ucid with AROPOL 7242 md A ETRON 700 type construction M SlJ1f8soSS810 8cid or Steum C/UUned ‘r’YY - veil . _ an/v _ .. ‘aA ROPOL 7$40 only uAppceIs to be eroslon/comXion “AROF’OL 724L’SATut 12Q.F “HETRON 197 and 700 series resins appear to be unsuitable under cychc conditions with some crazing but are resistant under static conditions. “Dissolved solids, 1574-2163 ppm: PO,, 0.25 ppm; total PO, 1.3 ppm; Cu, 0.7 ppm; Zn, 3.4 ppm; Fe, 1.8 ppm; CaCo, 450 ppm max.; Chromate, hexa, 18-22 ppm. Cl, residual, 0.20.45 ppm; NaCI, 527.702 ppm. “NO change in water at 0.7 ft.’ laminate/gal. gal. tank. “AROPOL 7530 SatiStUCtOrj’. MAROPOL 7343 SUtiSfUCtOrY as in 20-30.000 “Vol. % SO, 0.25; SO,, 0.03; CO, 12.5; N, 74.6; O,, 4.9; H,O, 7.6; f/y esh, 5.0 grams fr; velocity 60 fps. ” Vol. % SO,, 0.25; SO, 0.003; CO, 72.5; NI. 74.6; 0, 4.9; H,O, 7.8; t/y 8sh. 1.2 grams fr; velocity 8 fps. “0.12% Sop% O,ll2% CO,RO% NJ13.4% H,O; 5 grams/fr of 1.2% tf,.S@, 2-3ooo ppm HCI. 1020 ppm HF, rust water. z4Such as methylene chloride, 50 ppm; chloroform, 2; trichloroethylene 8 trichloroethane, 74; alcohols. 760: MEK 8 MIBK. 200; Benzenes. 105: Acetone,’ 50; Phenol, 2 etc. “AROPOL 7242 satistactory. TABLE 1.55: POLYPROPYLENE AND POLYVINYLIDENE Chemical Acetic Aad iGlacial Acehc Acld 150%) Acetic AnhydrIde Acetone (1 O%l Acetone 150%) I Acetylchlonde ACWlOnltrlle j Allyf Chfortde Aluminum Ammonium Albmlnum Chlortde’ Alummum Fluoride Alummum 1Alummum Hydrowde Nitrate Aluminum Potassum Sulfate (Alum1 I 75 1 NR Sulfate ! Ammonium Chloride 1 Ammonwm Fluorlde(25%1 Ammonium Hvdroxlde Ammomum Nltrate Ammonlum Phosphate Ammorxum Sulfate Amyl Acetate Amyl Alcohol Amyl Chloride 120 100 NR 225 225 Acid (31!?, w!? 0 3:, H&O.1 Chromyl Chlonde qromme~Dvl NR 170 I/ Bromine(Llqu!d) NR 170 Citric Acld ,’ ” Bromme j 120 ‘1 Butadlene ; NR 1 Bufyl Acetate Water (25%) NR - - 212t 75 NR / Butyl Acrylate / n-B&y Alcohol 1set-Butyl Alcohol ‘j F;f;;$A;rhol NItrate 70t 275 copper Sulfate 7ot 275 NR NR 275 NR Butyl Chloride NR 275 150 225 212t 275 Butylphenol ’ Butyrlc 225 275 n-Bury Mercaptan 1Calaum Blsulfate Calcum Blsulflde 70 212t Aud Calclbm Chloride Calcium Hydroxide 125 Calcium Hypochforlte(PO%l 275 Calcium Hypochlorltef94%1 Calcwm Nitrate Calcium Sulfate BarNurn Carbonate 70t 225 Barurn 225 Barwm f-lydroxlde Banurn Sulfide 225 225 Benzaldehyde 70t NR / / ; ’ I 275 275 120 70t 70t c 275 275 Carbon Dlsulllde 275 CarbonTetrachlorlde 275 275 castor 011 125 170 (Wet1 (Dry) 150 150t 275 Dlmethyianllme 15ot NR 275 DImethyl 70t 275 p-Dtoxane Dtstllled 212t 275 Chloroacettc Chlorobenzene Chloroform Chlorcsulfonlc 4 (15%i 212 NR 212t NR NR NR - NR - EthyleneOxIde Ferric NItrate 225 140 275 Ferric Sulfate 225 140 275 Ferrous Chlorloe 225 275 Ferrous -___. NItrate 225 120 140 275 Ferrous Sulfate 275 70 150 Formaldehyde Formx Acld 140 __ + 70 NR 150 Fuel Oil FUrane 275 Furfural 275 Gall~c Acjd 150 Gas- Manufactured 70 Gas- Natural 120t 70 Unleaded Sour 12vt 275 70 GasolmeGasoline- / EthyleneChlonde ! EthvleneChlorohydrln ---I-- GlUCOSe Glycol ~- p-e 120 Glycol~c Aad 701 2121 Heptane / 1 HeXarle 275 t NR 70 J ’ NR 275 NR 275 NR 275 225 225 275 150t 275 150t NR 70 275 75 275 140 275 275 Acid 12%) 225 275 Hydrochlonc Acid flO%l 185 275 70 NR Hydrochlonc Acid 120X,! 175 275 Hydrochlonc Acfd Cone l3E%I 150 275 ~ 275 Hydrocyamc Acid 140t 275 120t 100 212 Hydrlodrc NR Hydrobromlc Aced i50% 225 NR Hydrochlonc 70 225 _----t_ 120t i NR ACE 48$, / HydrofluorlcAc,d(35$1 Hydrofluorlc Acid (70%) Hydrofluorlc Aud I1 00%) Acid Yydrogen Chloride Hydrogen Cyanide Hydrogen Peroxtde NR 230 +iydrogen PerOxIde l90$1 230 iydrogen ,ydroge” Phosphlde Sulftde (Dry1 70 250 7. 140 212 140t 275 140 275 275 275 275 j 1 1 (Dry1 NR NR 1 130%) 70 / I 7o 140 ’ 1 275 150 275 70 I : Glyceme 120t j I , 275 Leaoed Alcohol I 250t 275 Gasoline- 1Ez;.srtate Bromide 275 120t 140t NR NR Yydrogen Chloride + 225 140 NR 2301 NR / : I 137%) 150t 70 225 :50:,; 120 70 __) 225 NR 275 + i I I NR .EDCI 140 Hydrofluoslllclc Ethylene NR Acid 2121 ~ i Ethyl ~Ethyl NR Acld !50%1 GlycO 140 NR Water Ethylene 275 Phthalate NR (5% I” Ccl.1 Dloxlde 275 : Dtabutylene DImethyl Amne I_ Dimethyl Formamtde Chlorine Gas [Wet or Drvi 225 275 Eplchlorohydrm Chlorine 225 275 Esters Ether Chlorine Borax Ketone 275 275 Boric Aad -- Dllsobutyl 275 230 275 275 275 70t NR 150t Black Liquor Acid DIchlor,oe Ferric Chloride Cellosolve CellOSOlVe Chlorine L,qwd 160t i Dtethylamine Dlamlne Ethylene Fatty Acids t / ’ I Ett’ylene 1201 275 275 / -T,, 170 275 Fuels Dlglycollc 225 I NR / -+ -120t Chlor,neWater(Saturated) 70t I , Dfesel 275 225 Capryl~c Acid Carbon Dloxlde Carbon Dloxlde i Dlethyl Ether cDlethyleneTrlamme 120 / Dlacetone Alcohol ---/-- Dethyl 4 120 70 ; 275 225 275 Acid 275 225 7 Cyclohexanone 225 Carbonate -___ 011 j Crude 011 ~i”ie( Cyclohexanol / Chlorate i I Cresy”c AC’d Crotonaldehyde 275 Calcium 140t Benzene 1 I 225 Calcum ’ Cottonseed CreSOl ~ Dextrln 212 i 1 NR ( Chloride I / corn 011 275 I 275 120 NR 1 230t 225 c 225 i 275 I 225 225 Fluortde Copper I Copper 275 225 Cyanide 75 225 140 225 1Copper 275 / , 1 275 I 275 4 (KYNAR) 140 011 Copper Chloride 70 I / I Cocoanut I : 160 ! / ; 140t Gas 70t NR 1 tert-Butylamlne Butylene T___ Butyl Bromide 225 Coal 250 275 275 Aqua Regla Arsenrc Acld Benzyl Chloride Chromic 230t 225 225 AnttmonyTr!chlonde Benzac Acid Benzyl Alcohol 275 I LAnlflne BenzeneSulfomc 225 NR ~sec.Butylamlne ~ / / 1 ( , I and FLUOROFLEX-K ,’ Er1ne 120 NR i 120t , 70 1 212 ;;: ’ (Polypropylene) ‘I BromtcAcld 275 Ammoma Aqua (30%) Ammonium Blfluorlde Carbonate 70 NR LINED PIPING SYSTEMS-RESISTOFLEX Ratings for RESISTOFLEX-PP 225 I ’ AmmontaiDryGasi Ammonium 70 212 120t / I Acetoohenone i 70 225 120t Acetonttrife Resistance FLUORIDE 212 757 120t 275 (continued) j I I / TABLE 1.55: POLYPROPYLENE AND POLYVINYLIDENE FLUORIDE LINED PIPING SYSTEMS-RESISTOFLEX T , “SE IRE (OF SulftdelWetl Hywchlorous Acid 150 NR Potaswm Chlorate 225 275 Potassium Chlorlae 225 70 275 Potassium Cyamde Naphthalene 225 212 Potaswm 1 Sot Nickel Chloride 225 275 212t Nickel Nitrate 225 212 Nickel Sulfate 225 275 Monochlorobenzene 275 Morpholme 150t 170 Naphtha NR lodlne(Dryi IodmeiLiqutd) lodme (Wet; 70t lodoform Jet Fuel - JP4and NR JP5 NR Kerosene 275 NR 70 Ketones Lactvz Acid Laur~c Ac!d Acetate Lemon 011 I- 1 ** Dloxlde 70t 170 230 120 Acid (30%) 200 230 Nltrlc Acid - Cone 120 Propylene 120 NR Sulfuric 250t 70 NR Sulfuric Acid (50%~ !60%1 175 225 275 Nltnc Acid - NR 250t NltrlcAc!d 250t Nltrobenzene 140 275 Nitrogen 70 275 N~tromethane (70%~ Fummg 250t 250t Perchlorethylene Perchlorlc Ac,d (lO%l Mercuric 150t 275 Perchlorvz Acld(72%) 275 Phenol,lO%l 250t + 225 70t (50%) ;i NItro”s / Actd i Oleum ‘Fuming Sulfuric Oxalic Acld Gas 275 Phenol llOO$, i12t Phenylhydrazme 275 Phosgene IGas 8 LIquIdI Methyl Bromjde NR 275 Phosphoric Acid 130%) Methyl Cellosolve 75t NR 275 Phosphoric Actd (52%) 150 Phosphoric And tzot NR Phosphorus c 120 NR 70 NR 70 225 212t 70 ._ I 275 NR at publication * Not recommended in anhydrousconditlon Not recommended I” processes where - jl 1 ! ; 165%) PentoxIde Phosphorus Trlchlorlde 1 Polyvnyl 225 275 Sulfurous SilverCyamde 225 275 Tall 011 275 Sliver NItrate 225 275 Tann~c Acld 230t Sodturn Acetate 225 275 Tartar~c Acjd Sodium Benzoate 225 275 Tetraethyl Bicarbonate 225 275 Telrahydrofuran 275 250t / NR ! Sodturn IOleum) NR NR t50t 212t 250t Lead 225 NR 275 Sodwm Blsulfate 225 Sodwm Blsulflte 225 275 275 Terramethyl 230 225 NR 275 Sodium Bromide 225 275 TOlUerla : 120 70 Acid 120 - 275 NR Ammonium Hydroxide 150X, 212t 170 NR 70 140 75t Sodwm Carbonate 225 275 Tnbutyl Sodium -- Chlorate 225 275 Trlchloroacetlc Acid i tOh1 70t Sodium Chloride 225 275 Trlchloroacetlc Acid Sodturn Cyamde 225 275 Tr~chloroethylene NR 275 NR 120 275 Sodturn S&urn Sodwm NR Fluoride HydroxtdellO%l 225 275 Trlethylamlne 225 Hydroxide 225 120 NR Turpentine 150 212 UDMH-Hydrazlne 275 (50’ x I*+ 225 275 Sodaurn Hypochlorlte 225 140 250 Sodium 230 212t 70t j 140 75 I i 212 70t 275 275 275 temperature? type I1 7%1”’ Hypochlorlte(ZO%Y’ Sodium NItrate 150 225 Sod!“m NItrIte 225 Sodwm Peroxlde 225 275 275 - 75 150t 275 NR 275 urea (50%) VarSOl 225 NR 250t Vmyl Acetate NR water 225 250t 275 White Acid (Ammonium Trtsodlum Phosphate (50-501 70 Sodium Phosphate 225 275 Sodium Sltlcate 225 275 Dtfluonde Sodwm Sulfate 225 275 Sodwm Sulfide 225 225 Sulfite Thlosulfate 225 275 275 xytene Zinc Chloride Zmc NItrate 225 150t 275 zmc Sulfate 225 Sodium Sodium -_ reactlow Phosphate NR 70t 225 amalgam 11 12 8 22 70 225 mercury Acid (96%) Acld - Fuming Sea wzter I alkylatlon Sulfunc Sulfunc 275 I at htgher 130 120 212t I “se 150 125 NR Bromide for 140 Acid 196%) NR Carbonate factory Acld (93%; Sulfuric 212 Potawum as m “Frledel-Crafts”and Sulfuric 120 potaswm consult 120t 212t Sahcyl~c Ac!d I Acetate 230 170 120t -I--- PICNICAcid - 140 212t Phthallc AcldiOrthol 150 Sallcyl-aidehyde 75t Phosphorus i76%1 170 140 140 Sulfuric Acid 70 150 Alcohol 120 _ NR Pyrogallol Refrlgewlts NR Acldi Pyndlne i 120 70 70 Olelc Acid Oxide NR 120 Octane i 4 NR NR 50 Octane Methyl 70 _NA_ Dloxlde 225 275 190%) Acid50 -Sulfuric Mercur~cCyan~de temperature Sulfur NltrlcAcld150%1 Paimltic Acid Maximum 250 230t 250t t Permanganate 150 140 __ Potaswm 70t 250 Ozone Monoethanolamme 250t 250t NR 225 Oxygen 011 Dxhlonde Acid (10%) 275 Mineral Sulfur Sulfuric 250t Milk Sulfur Chloride 250 275 NR Ketone 275 140 :20%1 Propane Propyl Alcohol n-Butyl Methyl-isobutyl Nttrate Permanganate 225 70 Potaswm Potaswm 130 275 Acid 275 250t 140 100 225 140 Chloride Sulfur Nltrlc Acid !30%1 Sulfate Sulfuric 212t 275 Magnesium Methylene 225 70 NItrate Methyl Hydroxide 225 Magnewm - Potaswm Acid (5%) 275 Ethyl Ketone 275 s Solvent Sulfur Trloxide 225 225 Methyl Stoddard Sulfuric Methyl Chloroform i- 275 275 Hydroxide Methyl Chlonde 225 275 Magnesium Methane MethaneSulphonlcAc!d Ferrocyanlde 225 275 Mercury 275 Potasswm 225 275 Nttrate 120t Sulfide 225 Chloride Stearlc Acid Sulfate 225 Mercunc 275 Potassium Chloride (40%1 225 Potaswm Carbonate Chloride 275 Dlchromate Chloride 170 Magnesium Mercuric 225 m Magnewm Maltc Acld Stannous 150 011 Mercaptan 275 N~trlcAcld(Z%) Lubncatmg Malelc Acid 275 225 NltrlcAcld(lO%) L~noletc Acid Linseed 011 225 125t Lauryl Chloride c Lead 275 275 NlCOtlne Nlcotlmc Acid It”“.‘, Sour Crude 011 Stanmc Chloride 125 140 120%) Lactx Acid ,60%1 Lard 011 Ch.mul D~0P”l-A Chembc,l - &y Hydrogen PVDF POW PVDF Ck.“ld (continued) 250t 8 HCI; 250t 212t 275 NR 275 - 275 ___~ *** 1s formed Polypropylene from NR Not the IS not formatnon recommended recommended of sodium - severely where hypochlorlte affected tree chlorine or from IS present deCOmDOSltlon as a residual reactant 220 Corrosion Resistant Materials Handbook TABLE 1.56: ACETAL, NYLON AND POLYESTER DELRIN RESINS-DU Acetal PONT Resins Resistance Resists weak acids (pH 4). Not recommended in strong Basic Resistance Resists weak bases (pH 9). Not for strong Solvent Excellent resistance to a wide variety of solvents, gasoline and other petroleum hydrocarbons. Acid Resistance ZYTEL Acid Resistance Base Resistance Solvent Resistance Resistance Base Resistance Solvent Resistance ethers, acids. alkalies. oil, greases, Resins Limited. Attacked by strong acids. General order of resistance 612>66> copolymers or 6. Excellent at room temperature. Attacked by strong bases at elevated temperatures. Generally excellent. Some absorption by such polar solvents as water, alcohols, and certain halogenated hydrocarbons causing plasticization and dimension changes. RYNITE Acid Nylon recommended Polyester Resin Good at room temperature. Attacked by strong and weak acids at elevated temperatures. Good at room temperature. Attacked by strong and weak bases at elevated temperatures. Excellent resistance to a wide variety of fluids such as gasoline, motor oil, transmission fluid, hydrocarbons and organic solvents. Some absorption by ketones and esters causes plasticization and small dimensional changes. Synthetic Resins and Polymers TABLE 1.57: EPOXY, FLUOROPOLYMER AND POLYETHYLENE DURCON DURCON Olrrrn --.__ TFF Durco Symbol - Silica filled epoxy Glass fiber reinforced PFA UMPE I __._..I_.__... 1 1 1 *Most Durco equipment totally lined with TFE eooxv polymer T~trnfltlnrnPthylene . TFF Durco PFA Durcothene Max. Service Temperature Description DU6 D700 6 700 RESINS-DURIRON NON-METALLICS DURCO Durco Designation 221 Perfluoroalkox y polymer Ultra high molt ecular weight polyethylene is limited to 300° I 215O 225O 400° 400° F (102O C) F (1070 C) F” (204O C) F (2040 C) 200° F (93O C) F (149OCI. __rr_. . ynn-r silver nitrate . . .._._ I , I IG&E Ic Is IE Ferrous sulfate Formaldehyde’ E S E E Formic acid Glvocrin. crude G G E HCL waste pickle liquor I Hvdrochloricacidc150°F&50CI Hvdrochloric •cid>15~F65°Ct _.. ___.___ jW /Lactic acid Lead acetate G s E E - E E E E E E G E E E E E r-1 I I IG IP Ii 1: 1G IG IE IE 1; 1; IE JE (continued) 222 Corrosion Resistant Materials Handbook TABLE 1.57: EPOXY, FLUOROPOLYMER AND POLYETHYLENE RESINS-DURIRON (continued) I Sodium _Mangawse chloride Mercur,c chloride Mercuric E E E E E/E E G E G EiE E nrtrate Mercuric sulfate I Mercuvcus sulfate 7-E IE7ElF S’E P P E G S - E P jG(GjEjG Oleum IP Oxalic acid IGIGIE Phenol iElPiE Phosphoric acid 1 +2%H,SOd.l%HF _ . c Phosphoric acid, all strengths I (P I E I E-1 , E-1 SI (E 1P G P I I tSlPlEtE1 G Picric acid GGE Phthalic acid GGEE S E E E Potassium bisulfate E E E E Potassium chloride E E E E Potassium S G E E hvdroxide / 1 G Oleic acid I E E E Nftric acid. all strengths Nitrobenzene I E Nitric acrd + 3%. 5% HF bisulfate I Tar and ammonia E = Excellent - Virtually unattacked under all conditions. G = Good - Generally S = Satisfactory - Suitable under Some conditions: not recommended for remainder. for details. P = Poor - Unsuitable under ah conditions. TSlSrEl El acceptable with a few limitations. Consult The Duriron Company,Inc, Synthetic Resins and Polymers TABLE 1.58: ISOPOLYESTER, RESINS-AMOCO Comparison HALOGENATED CHEMICALS of commercial AND BISPHENOL corrosion resistant A POLYESTERS, resins after AND VINYL one year 223 ESTER immersion The lengths of the bars reflect the tested performance of the resins after one year in the indicated environments. The Composite Ratings are the ten year performances projected from the 1, 3, 6 and 12 month evaluations. All laminates were made according to ASTM Method C581 with a glass fiber content of 25f2%. To assure high quality, the ATLAC-based laminates were supplied by ICI United States. The other laminates were fabricated in the laboratory. Flexural psi MPa 0 I I I 0 20 5.000 I Flexural Strength 1 cl.000 I I 40 60 I I 80 15.000 I I 100 I 120 20.000 I I 140 I 160 25.000 I 3 3 Modulus 200,000 400.000 I I I I I 1000 2000 3000 600.000 I I 4000 800.000 1 I 5000 I 6000 l.Ooo.oKJ I I 7000 I 8000 Corrosion Resistant Materials Handbook 224 TABLE 1.58: ISOPOLYESTER, RESINS-AMOCO HALOGENATED AND BISPHENOL CHEMICALS (continued) 10 I 1. ICI United States 20 I 30 I AND VINYL ESTER Composite Ratings Barcol Hardness 0 I A POLYESTERS, 40 I 2. Dow Chemical Company 50 I 60 I 3. Hooker Chemical Corporation H,O at 71°C 5% HNO,at 71°C 5% HCI at 71 “C 25% H,SO. at 71°C X2 Fuel Oil at 23°C Ethyl Gasoline at 23°C Unleaded Regular at 23°C Benzene at 23”C/time to failure excellent good good good excellent excellent excellent 1 year H,O at 71 “C 5% HNO, at 71 “C 5% HCI at 71°C 25% H,SO. at 71 “C X2 Fuel Oil at 23°C Ethyl Gasoline at 23°C Unleaded Regular at 23°C Benzeneat 23”C/time to failure good excellent good good excellent excellent excellent 3 months HI0 at 71°C 5% HNO,at 71°C 5% HCI at 71°C 25% H,SO, at 71 “C #2 Fuel Oil at 23°C Ethyl Gasoline at 23°C Unleaded Regular at 23°C Benzene at 23”C/time to failure good acceptable excellent excellent excellent excellent good 6 months H,O at 71 “C 5% HNO,at 71°C 5% HCI at 71 “C 25% H,SO, at 71 ‘C X2 Fuel Oil at 23°C Ethyl Gasoline at 23°C Unleaded Regular at 23°C Benzene at 23”C/time to failure good excellent good excellent excellent failure acceptable 1 month H,O at 71°C 5% HNO, at 71 “C 5% HCI at 71°C 25% H,SO, at 71 ‘C X2 Fuel Oil at 23°C Ethyl Gasoline at 23°C Unleaded Regular at 23°C Benzene at 23”C/time to failure acceptable good acceptable good excellent excellent good 6 months TABLE 1.59: POLYSTYRENE, SAN AND ABS PLASTICS-MONSANTO The data shows results under Test Procedure ASTM D.543, “h&tante of Plastics to Chemical Reagents.” This method requires molded two-inch diameter disc specimens to be placed in a separate container and totally immersed for 168 hours (seven days) at 73.2”F. Appearance, weight and dimensional changes are noted as evidence of chemical attack. To obtain information on chemical resistance at elevated temperatures, these immersion studies were repeated at 50°C (122°F) and the results are set forth under the column “Heat Reduces Resistance.” The rating of certain reagents is followed by the designation ( t ). This designation indicates that the reagent was applied to a bar specimen which was then placed in a bending jig and held under constant 29& outer fiber strain at 23°C (73°F) for 72 hours. TEST CLASSIFICATIONS ‘73” - Resistant. No visual change “MR” - ModeratelV “X” - Not ReSiStSnt. Resistant Some WRS observed visual in the plastic for 1”” duratoon of the test. change (discoloration. crazmg. The plastic was severely crazed. or was softened. checking) or was d6solved occurred. by the end of the test. Chemical Resistance of Lustrex and Lustran Plastics ~LUSTREX” POLVSVYRENE~ SAN LUSTRAN’ lLUSTRAN ABS LUSTRANa LlJSTREX*POLVSTVRENE 73-F H#st Reduces Resistance 73-F SAN LUSTRAN tImat Redwas Rnistanw ASS 73-F Acids Acetic l-5% R Yes R NO R Acetic 25% MR’ Yes R NO R Acetic 50% MR Yes R Yes R x - X R Acetic Glacial 100% x - Benroic R’ Yes R NO Boric R Yes R NO ButYric - - - - Carbolic 50% Carbolic 100% Chromic 20% A j X - Yes x - ! x - x - ! X A” Yes R No ( R MR’ Chromic Sulfwc Acid Mixture Alcohols Yes x - n-AmVl MR’ R’ YSS R Yes R Benzovl x - - - - Benzyl - - - - X Butoxyethanol - - R - R n-Butyl R’ Yes A Yes R SK-BUWI - - Yes - - - Ally1 Ten.-Butyl I Octanoic Oleic 1 DO% Oxalic 10% Palmitic MR R’ MR - - - R Yes R Yes R Yes R NO NO R NO - ’ Cetvl I- - MR R IR X - NO No 1 - Cyclohaxanol R Yes R Yes Oecyl - - - - R Diacetone - - x - - Yes - - X - I 2.Ethoxvethanol Ethyl (denatured) I- R” I- I R -iXI Ethyl Formula 30 MR Y%S R Yes Ethvl 95% MR” Yes - - - (continued) TABLE 1.59: POLYSTYRENE, SAN AND ABS PLASTICS-MONSANTO Methylamyl R Yes - - - Nonyl R NO R - - WOCtYl R NO R NO - (continued) Dlmethylformamade 1 x Dlphenylawne 1 nl~th”lrnrtrlmlne I MR x Ix - - - IX - - Yea I - - - NO Dlephenylemmine (Carbazole) Ethylenedaamme - - R MR - - lsopropylamlne - _ - - Pel-WlFlm,ne _ - - - Twhopropanolamme - - R No - - 1 MR” Trlethylenetetramme / - X X 1 - Cosmetics 1 - No - - Cyclohexane - - R - R Methylcyclohexane X - R No - Alcohol 5DA40 Yes / R _ Perfume R’ 1 MR” LallOlln ’ - - Cyclopsraffins Alkalies Ammonia (aqueous) Ammonia Hydroxide (cont.) R Yes R - R R YeS R NO R (continued) TABLE 1.59: POLYSTYRENE, SAN AND ABS PLASTICS-MONSANTO (continued) LUSTREX‘POLVSlYRENE Group 73.F nut Rsducaa Rssinsnsr LUSTRAN” 73-F SAN LUSTRAN nut Rsdacss Flaaistsnu ABS n-r Foods L Black Peooer (fresh) _r , X I Butter Carrot Juice Catsup C*la#., C*l* Glycol Dibutyl Mono&hyl Ether) 1 Phthalate x _ Ix - X jx - X Che...__ \~______I Graw fconc.l Chicken SVYr ,uv,vu., Cinnamon, 1 x - - - X x - X Ethyl Chloroacetate Ethyl Lactate X _ Ethyl Salicylate - - - - - - - - X x - - _ - Benzoate lsoamyl Acetate Isopropyl Acetate Methyl Acetate x - - - - Methyl Benzoate - - - - X Methyl Laurate - - - - X Foods Fountam Syrups Chew, Chocolate, Orsnee, Root Bear, StraWbarrY, Vanilla - - R - ii Oil - _ Fl NO - MR - - - - Yes R NO R Rt - R Grapefruit - R - R Grape Gravy Beer (Over m-0, I,*irm R” 3.2% alcohol) R - Oil Crirco (Bourbon) Beef NO - R Yes R Pt NO R NO - - - - Yes I - - Ix - - I -I R Yes R - R Yes R - R MR” NO - - - R - MR Yss R NO 1 MR Yes 1 R No 1 R /hIA - 1 I R No 1 I R Oil Liver Almond Fat R R” Extract Butter Alcohol Bacon Yes - - x _ Ethyl R R I- Coca-Cola Cod NO .__ 1 Coca-Cola Coconut R pwd. _ _.. _. Clove 011 Cocoa - NO _ Chicken - Rt R Garlic Salt Gin Ginger Ale Ginger Ale Juice Extract Juice I - R” Yes R - R” Yes R - R” YeS R - - I - - - Rt - - MR - - - - R NO R - R R NO - - - MA’ - R - R - - R - - (continued) TABLE 1.59: POLYSTYRENE, A Yes - - - R NO R MR - - NO - - X - - - R No (Curtis) Lard Lean Beef Lemon Emulsion Flavoring SAN AND ABS PLASTICS-MONSANTO 1 Lemon Juice, Fresh IMR - 1 Lemon Oil and Peel Ix - Ix - (continued) R - 1 I R - Leaves, Caraway Seed. Celery Seed. Cinnamon (Stick), Coriander (Whole). Cumin Seed, Dill Seed, Fennel Seed (Whole), Marjoram. [ Parsley Flakes - - IRt - - Mustard 0 4 s :: ZtL, t; 3 I I I 1 I ILrclElLLILl nflslll IIIlIIIIIIIII I UC= I I I I I I z”P I I == Synthetic Resins and Polymers I zol 229 TABLE 1.59: , SMP POLYSTYRENE, SAN AND ABS PLASTICS-MONSANTO LUSTRAN’ LllSYREX* WLYSYYRENE 73-F nm nducm Raistanu 73’F SAN Ihat Reduces tksistanu LUSTRAN 73-F - - - Chloroform - - x - X a-Chloronaphthalene - - - - X Ethanol X Chloropropane - - - - X o-Dichlorobenzene x x - X P-Dichlorobenrene - - x - X Dethylene - - x - X Chloride Ethyl Chlonde ASS Halogensted Hydrocarbons. Chlok (continued) (gas & Acetophenetldm R” NO Adrenalin R” Yes Adrenalin Aspwn, Hydrochlonde m 011 pwd. Trichlorobenzene - - x - - Trichloroethane x - - - - Ttichloroeth,ylene x x - X Gum Tragacanth Tnchloropropene - - - - X Iodine 83% Iodine (T~ncfure Katonas 8 Ethers Gum Acacia, pwd. U.S.P.) Acetone x - x - X Mentholatum I Acetophenone x - x - X Menthol /x Crystals - - R” NO NO R YES j R Yes 1 - - - A - - R - _ - - - IX i- - - - X _ - - _ (continued) TABLE 1.59: POLYSTYRENE, LUSTREX’ 13-F GWlp SAN AND ABS PLASTICS-MONSANTO LUSTRAN’ POLYSTYRENE Flea1 Reduces Resistance 73-F SAN LUSTRAN Hut Reduc@s Resistance T ASS Salts Mercurochrome MR Ammomated Merthiolate, Novocain Yes - Omtment. tincture (2% Ml?” NO - - - MR” Yes - - - - R NO Pectin, sat. R Yes Penicillm R NO - R Yes R Petroleum and 4%) G Jelly __ Jell” _ I, ,bolated car n..;uullline rrra-hnin. .,.‘,“.‘.....” S,df.dia.inP __ ___-. .^._ _..* a”,,“, n“1IIIIIITIII P*trolaum C..I‘..- R - R MR R R’ 1 MR” ..aq Yes - N” .._ I - Yes ..” - Nn -- - - - R R - POLYSTYRENE, 73’F Haat Raducos Resistance 1 / - Stearate Calcwm Elromlde Calcium Calc,,.- Chloride Y ..^^_ &.,^.,A^ me. Calcium nypocnlc ,rite pwd Calcium Oxide Calcwm Sulfate - Copper “xloe Copper Sulphate Cupric Chloride Cupnc Sulfate Cuprous 1 I ,1 R L”0 NO Vnr R n n Yes .1_ I”” - - n 8”” MR No iR _ - R X - X D. - 25% 25% Oxide Ethylene Oxide Ferric Amm__...- _ NO Oxide Dlphenyl 1 : 73’F R 25% Sol Ceslu LUSTRAN’ e..,‘... Ferrous Sulfate sag. 25% , Hydrogen Ammonium Salt. I I I I Sulfide Hydroqulnone. sat. Hydroqumone. 4%. sat __AA.____._ LrdU -r>er1015 Lead NItrate Resistance R - NO - I NO _ _ R - , No I.” R R - R n I.” I? ,R _ R - ‘R - No ‘R No .I i 1 I 0 &I^ - - ‘A R R 1 R - - _ ” I”0 R NO V..* , 1 R I R ; R - R NO - - - x - - - - R’ Ye5 R Y8S MH ..- n L.D.. lllll - /_ - I”0 j- - - ,_ - L,. R’ Yes I j R - 1 - - 1 - R NO - - Magneswm Carbonate R’ NO R No : - No I 1 I _ - 5% ov,d R’ MR’ Yes IR Yes j R No 1 - I Bromide Chloride 1 - Magneswm Mercury ABS 73-F n ,es n. Lead Acetate LUSTRAN Heat Reduces, R n MR Ferrous Sulfite R 1 Femc -’ Ferrous ~n,or,qe. SAN I I Cadmium - 1 I / !LUSTREX’ CKIUP 73-F Pharmaceuticals Mercury (continued) - (continued) / TABLE 1.59: POLYSTYRENE, SAN AND ABS PLASTICS-MONSANTO LUSTRAN* LUSTREX*POLYSlYRENE 73.F Group Haat Rldua Resist*nu 73-F SAN Ifeat Reducn Rasistanu LUSTRAN (continued) ASS 73’F Salts Potasswm Sulfate. Aluminum sat. Potaswm Bxarbonate Potasswm Bwlfate, sat. - R Yes R No - - - - R NO R NO - MR” - NO R NO - - - - R Chrome Alum. R” Yes - _ - Potawum Ferricyamde R’ Yes R NO - Potassium Iodide. sat R’ Yes R NO _ Potassium .zilt Permanganate. MR’ NO R Yl?S R Potassum Bromate Potassium Bromide 3% Potassium Chloride Potassium Sodwm NItrate R MR” - - j R - - (continued) TABLE 1.59: POLYSTYRENE, SAN AND ABS PLASTICS-MONSANTO LUSTREX’POLVSNRENE 73’f GKIUP Heat Rduca Resirtuw.9 LUSTRAN” 73’F SAN Heat RDducDs Rnistrncs LUSTRAN 73’F Miscellaneous Benzomtnle - - - - X Benzyl - - - - X Benzoate (continued) ABS Group 73-F - - - X x - R Yes - Decahydronaphthalene - - R NO - Detergents Rt _ Ri - Fit R NO Joy (5%) - 1MR” NO NO R Cresolic Compounds MR’ - - - X R I - - NN-Diethyl-M-Toluidine - - X - - - DimethVl Sulfate - - X N,N-D~methylaniline - - - - X n,nrilnn - - Y - Y Distalled Water R Yes R No R NO Flutd 4 X R - Dow Cornmg Fluid 200 R No - - - Dowtherm A x - - - - R - - - - NO - - - MnO. MR” 3%. sat. Ethylcellulose MR - - - N-Ethvlaniline - - - - X - - - - Yes 1 - - - Ix - Eugenol IX Flit, insecticide 1MR Freon II R - and N&Cl R I- - Elan (Photoa.) Yes - - Carbonate D~v Cell Solution - ABS 73-F - Dow Corning Ml7 LUSTBAN DDT Diethyl MR” 73-F SAN Heat Roducm Resistmu P-Cymene Der0r”n Cottonseed Oil HIat R#duces Rnistancs Miscellaneous Detergent - Colloidal Sulfur LUSTRAN‘ LUSTREXaPOLVSNRENE - I x R (continued) I TABLE 1.59: POLYSTYRENE, SAN AND ABS PLASTICS-MONSANTO (continued) USTRAN L I 73'F ’ TVdOl Motor Oil-Sunoco lsobutyronitrile - - - Ivory Soap - - R Lactose, sat. R” Yes Lestoil - - NO x - - - X - - - R _ R /x ~1 1 X - ‘X - - /- - - I- - - m-Nitrotoluene R - - Nitrous Oxide R” Yes Nqol R - Anise Seed X - Clove x x x x x x x - Lilac (Aflificlal) Nutmeg Peppermmt Roses Rose Geranium. Mesityl Oxide Metalltc Mercury Metalltc Sodium dl-Methionine (powder) MR” - - - - R” - - - - - - R - - Sandalwooc Sassafras. Spearmint. Sweet c Almond, Oil-Light Wrntergreen Machme E Olive 011 Ozone (abs of light) Moth Flakes 1 MR” Yes IX - - 1 - -X WR” R’ -- I1- -1 No _ - iR - R IR No - - - R NO - WR No Paraff I” WR” Yes R No R R NO - - Para 011 ‘4R” Pentasol R Phenol 5% - X Palm Oil Paraffl” 011 Morpholine - Ix I ‘Oil of X X - - - - - - - - - - R” - - - R” Nitromethene - R - Nitroglycerin - I - - X - I R IIFI - clean ..-.-_____ - MR” Nepnthslsne Base Gear O+Telachron Mr. AB! Phenylacetomtrlte Phosohorous. White HR” _ HR’ - - - Yes - - X Yes x - - - - X NO - - - R (continued) TABLE 1.59: POLYSTYRENE, LUSTREX’ 73’F Group SAN AND ABS PLASTICS-MONSANTO LUSTRAN’ POLVSTVRENE flea1 R&ms Resistmn 73-F SAN LUSTRAN Heat Reduces Rmsistanu (continued) AES 73-F Miscellaneous Pine Needle x Oil Ix x - IX - - 1 - ‘Impact materials less resistant. “Impact materials not tested. tTested under 2% constant strain. ttComposition (White Spirits) Sucrose 30% Sulfur Dioxide (Moist) Tenite x - R NO R R” Yes - - - - - R - - - - X Tetrehydrofuran x - x - - Tetralin x x - - - - R - - x - - - - x - - - - - - R No Texaco 3-In-One Thmyl Tobacco Motor Oil Oil Chloride Tars Triethanolamine IR ( R’ NO 1 - j ii I may vary, each formulation should be checked individually. corrosion Resistant Materials Handbook 236 TABLE 1.60: POLYVINYL CHLORIDE, c 80°F. H “p POLYPROPYLENE KEY to the temperature t~mta- ,,on 01 the material I” cases where chern~~al bolls belowth,s IimItatIon. resistance 15 Intended to beshownuptothebolltng pomt RIGID PLASTIC AND POLYETHYLENE R RECOMMENDED C CONDITIONAL may be suit_ able but ConsuIt Atlas before w3ng. N NOT RECOMMENDED FABRICATIONS-ATLAS FABRICATIONS CHCHCHCH CHCHCHCH Acetaldehyde N N;N N’C N,C N Chlorrne gas, wet N NlN Acettc acrd. up to 10% R R ,R CiR RR R Chlorrne water R R R Acehc acrd. glacral R N A N R C A R R,R R R:R R:R R Alum A R R Alumrnum Chlorfde R R.R Alummum Nrtrate R R R R’R Alumrnum Sulfate R R’R R H Ammonrum Chlonde R R’R Ammonrum Hydroxrde R R Ammonium Nitrate R Ammonrum Sulfate c . R i -. R R R;R R R R R R R RIR R R R R R:R R A R R.R R Amy1 Acetate N N:N N~tN Amy1 Alcohol R R R Anrline N N N Aqua Regra R RCNNNNN Barrum Chlorrde R R Barlum Hydroxrde R Barrum Nrtrate + R Chloroacetic acid NON N;N N R.N C C N1.N N/C N N N-:C N R Chlorobenzene N N N N R Chloroform N N N N.C R Chromic R A R R R R.R acrd. up to 5% ~- C Chromrc acrd. 10% R R R Chromic actd. 20% R R’R R Chromrc acrd, 50% and over R C N C N[C N R N’R C N’R N R R N;R N N N N +_f4 N R’R R R Crtrrc acid R R’R R’R R R Copper Chlonde R R,R R R R:R R N N N Copper Nnrate R R R R RjR R RI-R---- C A C Copper Sulfates R R’R R-R RiR N R,R.N C N./C N’N N R ‘ Drchloroacehc actd R R N Drch!orobenzene N N NNNNNN R:-R R,R R Drethyl N N N R.R R-R R’R R Ethyl Acetate R RIR R,R R R R Ethyl Alcohol Barrum Sulfide R C!R C’R R A R Ethyl Sulfate R C R C C N:C Benzene N N N Ethylene Chloride N N: N N’ N N. R R Glycol R R R R R R;R_R Benzene sulfonrc Benzorc acrd. 10% R I~ N N R R - -. N.C N N N N Ethylene R R R R Formaldehyde N N N N Formic N Gasoline acrd Fluosiltcic Bone acid Bromrne water R R C N N N NtN Alcohol N -A acrd R N,C Butyl Acetate Butyl Butync C ether i R;R N,Ni N R R!R C N R C;R C _ N.pmmt N:N Hexane Cadmrum Nrtrate Hydrobromic Cadmtum Sulfate N’C R.I__RJ I Rmc ~~_.. - ~_._.._._-R.- R acid R ~. .-R,R R R R:R __---_-i_~-_i_---_- Bwlfite R ~. _ Calcrum Chlorrde Hydrofluonc acid, 3040% Calcium Hydroxtde Hydrofluosrlicic Nrtrate Hydrogen Peroxide, Drsulfide Hydrogen Sulfide 50% _. gas, dry R ._ A - R;R .._--. R R Tetrachlorrde Hydrogen Sulfide gas, wet Carbon C _~ C R acrd. 10% Carbon N R -.._RsR RIR RIR __ .T .___~_.___ 7m-m CR ~_ _____~~~ R - C.?.. N-_*- NI R/_.__... R acid, 20% Hydrochlonc Calcrum N N R;R ~_~. CIR C;R _~__~_-____-_ R .j ~__ R R/R R/R + --it__.. Hydrocyanrc Calcrum N ~~ .~p-_~-_j ~~_.___.._. R Chlonde C N!N -N:ti N m-i _ .___..~__. R ~.. R R_ ~R __.i R R_ .R ~_ _.~. R..~ __. R R R R R C R C~~ ._~ R _N? R-- R, .R~ R N G acrd Cadmrum .- _. ~~~_ ~_~__~~R-.__R c-5 acrd Glycerine -~. --~ Gold Cyanide N N _._ acid RIR I-_- C R/R R/R -mIm__t__-__ R R RIR __c R~~ -_i_-__RIR ~__---t---~C;R R R;R R RiR C Iron Chlorides Chlorrne gas, dry Iron Nitrates (continued) Synthetic Resins and Polymers TABLE 1.60: POLYVINYL CHLORIDE, POLYPROPYLENE CHCHCHCH Iron Sulfates AND POLYETHYLENE Potassium R R,R R RiR ~~~~- 1. ~-R!R CCR Magnesium Chloride R R’R R’R Magnesium Hydroxide .~~ R R ~~._ Magnesrum Nrtrate R RiR Magnesium Sultate R R Lrnseed Oil __~~~~ ..- Maleic acid R R R: R,R ~.~~ -__ R R Silver Nitrate R C Sodium R R Chlonde R R R’R R R Rj_R__R Sodlum Hydroxide, Sodium Hypochlortte, up to 3% Sodium Hypochlorrte. 15% and over R Sodium Nitrate Sodium Sulfate Sodium Sulftde __.. R R !R .~~~_~ RIR Sodium ~~ ~_~_F~~!?! R !R ~ R;R R R?R -_R/R : R’R R R ,R R 1 RRI~R~_.RJ. “.._” RRRRRR Methyl Acetate Methvl Alcohol R Methyl Ethyl Ketone Acetate Carbonate R RIR ~~ R/R R R R’R CR ~_r ~~ _~. __+_-R 1J--F, R - .~_ RIR+._ R~~_-___ R R’R R N N/N NiN N;N N Mercurrc Acetate Sodrum Brcarbonate ~~.__~~Sodium RRRRRR ...~~~~~~.__ RRR R R _._ - -- Nitrate Isopropyl Ether ..__ __ NLC_._N~LC_~mNPotassium Sulfate N +’ N Kerosene _ R RR N:C N .._ ___.___ ~ ~_~~~_~~ mm_ ~~_ R’C i.- ----+--_. Lactrc acid, 25% R R; -R R/R R _~ ~~______--_c A-_iRIR ._._~~. Salrcylrc acrd Lead Acetate R R;R R,R R’R R R FABRICATIONS- CHCHCHCH _____- ~- ~~~~~-R N Lead Nrtrate 237 R/R R’R RIR R Sodium Sulfite Sodtum Thiosulfate 30% and over R RIR R’R N N/N N R/R R Soya Oil Nickel Nitrate R R/R _Nickel _._._. Sulfate Nirtic acid, up to 5% R R R Nitrtc acid, 20% R Nrtric actd. 40% N!ric acid, 50% and~~~ over ~ Nrtrobenzene R R R Steanc RIR R R R Sulfur Dioxide __ gas, ____.-. ~__dry Sulfur Droxide gas, wet I _~-------L--__--T~~~~~_ R R:R ~+ R&_RRCR ! Sulfur Trioxide gas, dry C Sulfuric acid Perchloric acid R N:RT _~_~_~ CCi ~,__R ..~ N C mm-++ N N ~~~.. NIC ~~ _ N : N N ~~~~~~~~~~~._ N N’N NIC NIC N Oleic actd Oxalic R R/R acid. 10% acid, over 93% _ Phenol Phosphonc acrd Phosphorous Phosohorous Phthalrc actd Trtchlonde Tin Sulfate actd Toluene Picrrc acrd Potasstum Brcarbonate Potasswm Carbonate Trrchloroethylene -..- R R;R R!R R/Rids ~~~ R ~__-_~,~~______~~~~~~_ ~~ R RIR RJR R IR A_ ___~_, _-._ , -...-._R Potassrum Chloride Potassium Potassrum Cyanide _~. ___.~ FerncyanIde Potasstum Ferrocyanide Potassium Hydroxide. UP to 30% Potassium Hydroxide, 30% and over R R R’R$_ ___ R -;‘R_ R_i .R-_ f? Trrsodtum Tung 011 Urea Phosphate C N N N 238 Corrosion Resistant tWaterials Handbook TABLE 1.61: VINYL, SILICONE AND FLUOROELASTOMER MASTERFLEX Legend: C X N = Not satisfactory = Satisfactory = Use only after testing I Fluld ArrI<~ldehyde /wetdIes IlOW mol WtI ?CCIIC acid [less Ihan 5%l N - Cresol :yClOhexane >clohexanone N 3acetone alcohol 3methyl lormamrde Essentral 011s Acellc ;1Cld (more than 5’bl AcetIc nrlhydrlae Acrl0 “ItrIle 1 pumped+ to be X TUBING-BARNANT Tubing Compatibility T = TYGON S = (vinyl) Silicone blng tubing v x x Aolybdenum N N X X .4onoerhanolarnme daphtha N N C N datural gas Jrckel salts dltrtc acrd (drluted) dtsulftde Ethers Ethyl acetate C N NC C .itrtone Aceryl bromide Ethyl alcohol (Ethanol) C c .Aceryl chlorrae Ethyl bromtde Ethyl chloride Ethylarnme N - x x N N N - X N chlorohydrln dlchlonde glycol N N X N N X X 31s. vegetable 3lerc actd x x 3XdllC acid oxrae - N N All UWVJIS Allphatlc hydrocnrbon\ ?~“rn~num Chl0rrae Ethylene Ethylene Ethylene Alum~nurn sulphdte Ethylene Alurlls .Ammonld (gas. IlquldJ ~\mmon~“m acetxe Ammorwm carbonxe ?mmonwm hyarOxlae 4n111rir h>arvchiorlae 4rlIlmon\’ I&S c c c c c N x x x Farry acids Femc chloride X Frrrrc sulrate Ferrous chloride Ferrous sulfate X X Fluoborate salts X Fluoborrc acrd Flue-SI~ICIC acta X X ---- Formaldehyde X C N FormlC wd C Frron X N N N C Gdsolrne (nondromr)clcJ N N X Gasoline (hrgh aromatlcrtyj GlUCOSf? N X N X x x - x x x x X X x x ?rorrlatlc hydrocarbons Hydr@bromlC actd X N N X X Hydrochlonc acid (rned concj X N X X X N X N X X N X X x x N x c X N N Berwldehyde Benzene ~erizenwlon~c Benzorc dcla aCla Benlyl dliohol Ble‘ichlng Ilquors Bow dcra BrOlnl”e Bul‘lne IBuwr 101) HUlVllC dCld Calcium oxode (alluteal Cdlwm salt5 C3rbon brsulfrae Cdrbon arowde Carbon tetrdchlorrae Chlordceuc dcld Chlorine (wctj Clllorlne (dry1 Chlorooenrene C1110(obrornonlethdrle Chlotolwm Chlorosull0”lc acrri Chromic acra Chrom8”nl \dlts Copper S&S X X X acid Hydrochlorrc (concJ acrd Hydrocyaw acid Hydrofluorlc acid Hyarogen peroxlde Iail Hydrogen (COIILI Hydrogen X peroxrde sulfide Hypochloroul acid I0rJlne so1ut10ns Krrosrne X X N Krrones Lacquer soIvents Ldctrc acrd N N Ledd acetate Lrnseed 011 Lrthrum hydroxrde X x - acid carbonate chlorate ‘otaswm hydroxide Iodide joap solutrons jodrum jordum btcarbonate blsullate jodwm brsulrite jodrum borate SOdrUm carbonate Sodrum iodlum Sodrum chlorate chlorrde ferrocyantde iodtum Sodrum hydrosulfite hydroxrde Id4 ,Merc”ry salts hlethdne 1Methyl - C N c f- X x xJ N Y C C x X N N C X I X X ;i X x X x - X X x X - x -X X - X X X X N c x x x X X X Uquehd food producu N - X x Ty9on “food” X X x x X X X x X X X x x -C _-X - X hypochlorlte srlrcate sulhde sulphrte Steam Iup to 40 pstl Stedrlc acid Styrene chlorrde dloxrde hexdlluorrde C X x X X -ii X - X T X X 1 x c x - 2 X ot maqnesra X X -X Sodrum hypochlorrte Ibelow 5%) Milk x X - Sulrur Sulfur Sullur N X X X -X Sodrum Xylene (Xyloll Zlrlc ihlorrde X - Sodrum hydroxide lconcj Sodrum Sodrum Sodrum X X - C X X - /above 5%) Sodlurn nrtrate salrs T X N X x x x x x x x C X Sodrum hydrcxlde (med concl x X X X ;i -N ~tlrcone flurds ;&one 011 jllver nttrate N x x x - X ‘;i x C N Fluldto be pumped hydroxide N N rhlorlde ‘Mlxed dud (40% s”lph”rlc. 15% rlllrlcJ ‘otasstum (CO”Cl ‘otasslum ‘pdlne X X X X X X - ‘otasslum ‘otaswum N N x X X N N - X C tubing sod X _ iManganese ‘hosphonc @rthol N chlorrde sulldte 15%) Magnewm Maynewum M&c dcld ‘erchloroethylene ‘henot ru x (fluoroelastomer) = No data available r- v -_- - 3xygen lgasl ‘erchlorlc acrd (med concl dcrd Hydrochlorrc 311s. mmeral ‘olyglycol hrsenlc Bnwm salts \rllts Jltrogen oxides Qtrous acid 311s. animal ‘lattng solutrons Glue Glycerme Hyarlourc rlrtric sod [med cone) \11trrcdcrd Iconc) Qtrobenzene ‘hthallc A4”d regra (75% hyarochlortc. 25% “llll‘ dCldJ V = VITON - - IFluldto be pumper 5 -- Tables tubing x hod Uquclltd producu Beer Butter Coca co13 syrup Coffee Lard hldzola 011 Orange peel 011 Orange syrup Scotch whiskey Spry shortenmg Tdb concerltrdte Tla Marla liqueur Vegetable Vl”egar 011 X X z, JWeAlOd >,,q&lu,ec(l 99 WAN ‘S’H B ‘d.9 W=‘W~bd Odd ‘P’W euelAlS w c-9 a a u_ a wwaw .- me w aueldaH < 0 0 0 0 _._ < C . < ‘ auazuag pawluasuog awwwaa LLLWWLW 1 / uo!lnlos ap!xoJpAq wntpos W 3lJnw-s (%OL) PI= 3’Jl’N (~~86) P9 3lJOlWOJp~~ waaw w wwwQwwww~www~ww~wwww~wwwcJwwQ-wQ-uwww~w a aw 0 0 ww ww LOW aww wuwaw Resins and Polymers waawwww wwaw Synthetic a 239 240 TABLE Corrosion 1.64: Resistant VARIOUS Materials Handbook RESINS-GENERAL Comparison ELECTRIC of Chemical Resistance of Six Plastics Resins % tensile retaineda NylonChemical 10% acetic Glacial acetic Acetic anhydride Lactic Benzene sulfonic 88% formic 10% WI 37% I-ICI 10% HNO, 30% H2S0, 85% H,PO, 10% chromic 30 0 74 22 0 0 0 0 0 0 0 67 15% NaOH 30% NaOH 28% NH,OH 69 89 85 HID 37 67 0 100 20 30 100 0 100 100 100 100 Phenolic - 100 70 55 100 100 99 100 100 100 100 100 100 100 98 100 100 100 75 100 100 96 100 100 100 98 7 0 100 100 100 100 100 100 100 100 loo CaWW 66 33 62 76 90 60 94 73 82 86 74 19 13 47 29 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 loo 100 loo 100 100 100 loo loo loo 100 loo NaHC03 Na2C0, Na2CriOj 76 80 57 100 100 100 100 100 100 100 100 100 100 100 100 - KMnO, NaOCl 100 100 48 100 100 92 loo 100 87 100 04 64 - Brl 2-Aminoethanol Amyl alcohol Butyl alcohol Cyclohexanol Ethylene glycol 39 44 8 93 07 87 84 96 0 48 94 74 100 100 100 100 95 100 100 62 84 27 100 100 100 100 100 100 n-Butylamine c Ethylenediamine Aniline Dimethylaniline Morpholine Pyridine 91 78 85 100 93 74 0 0 0 0 0 0 0 0 0 0 0 0 0 51 0 0 0 0 49 65 96 100 80 93 i ! Bases 1 / A12(S%)3 WW2S0, Na2S0, Na2SIO3 Na2S NaCl NH,CI CaCI, BaCI, lnorgallic aqueous solutlon WCl2 AICI, FeCI, NH,NO, L Alcohols I’ Amlnes Potycarbonate3 100 91 0 100 35 79 100 100 100 100 100 100 Acids 10% 616’ Noryl phenylene Poly- oxide based Polyphenylsulfone4 resin2 ene sulfide5 98 4 83 13 73 63 99 100 - 85 loo 100 96 loo 100 (continued) Synthetic TABLE 1.64: VARIOUS RESINS-GENERAL ELECTRIC Resins and Polymers 241 (continued) 76 tensile retaineda Chemical Aldehydes. ketones 1 Chlorinated organics Esters { Nylon6/6 I N&riles{ Nltro compounds { Phenolic6 - 0 100 0 0 0 0 0 100 0 100 99 100 84 100 100 0 0 0 0 0 0 42 0 0 0 0 17 0 0 0 0 0 0 0 0 0 0 53 0 57 0 0 100 100 100 100 100 07 100 74 72 88 95 90 89 46 0 46 0 0 32 63 0 0 0 19 0 100 100 100 100 100 81 96 87 61 78 0 0 100 0 0 0 0 47 0 0 100 89 88 76 90 84 07 80 86 90 88 100 89 76 91 75 100 100 99 100 100 100 99 0 0 0 99 100 100 100 100 100 100 100 0 0 0 0 36 36 0 0 100 100 100 0 0 0 100 91 100 100 100 100 100 100 100 96 100 100 ;f;z;.;$; 93 88 25 0 0 0 69 0 96 100 100 - Nitrobenzene Nitro methane 100 57 0 0 0 0 0 66 100 71 100 100 0 0 0 0 0 0 0 0 100 100 a4 07 95 66 a4 0 0 0 62 16 0 0 0 55 77 93 100 - 100 97 100 100 100 87 07 07 98 77 81 0 0 0 100 0 Acetyl chloride Benzyl chloride Carbon tetrachloride Chlorobenzene 2Chloroethanol Chloroform 5% aq. chlorophenol Epichlorohydrin Ethylene chloride 0 80 76 73 12 57 41 a4 65 Amyl Butyl Butyl Ethyl acetate acetate phthalate acetate Cyclohexane Heptane Diesel fuel Gasoline Stoddard solvent Mineral oil Motor oil Wesson oil Dowtherm Toluene Xylene m-cresol Phenol MibcdlalWOUS 0 0 0 Acetophenone Cyclohexanone Methyl ethyl ketone Benzaldehyde 37% Formaldehyde Furfural Butyl ether Cellosolve Hydrocarbons Poly- 1 carbonate3 Noryl phenylene Poly- oxide based Polyphenylsulfone* resin 2 ene sullies Dimethyl sulfoxide Sulfolane N.N-dimethylformamide Cresyldiphenyl phosphate Triphenylphosphite 24-hr. l~powre at ZOO’F. 1-Zytel 101, Du Ponc Co. 2-Noryl. General Electric Co. 3-Lexan 141. General Electric Co. CUdel. Union Carbide Corp. S-Ryton, Phitlips Pelroleum CO. G-Gcnal 4300. General Eleclric CO. 0 19 0 100 100 100 100 100 100 100 100 92 98 - 100 100 94 - a--Alter (Reprinted from Modern Plastics) 242 Corrosion Resistant Materials Handbook TABLE 1.65: VARIOUS KOROSEAL RESINS is an extruded, ATLASTAFLEX is a synthetic CHLOROBUTYL ELASTOMERS polyvinyl chloride rubber-based is a synthetic 3-PLY is a sheet lining rubber. Atlas PVDF plasticized is a polyvinyl NEOPRENE AND rubber consisting FOR chloride laminated LININGS AND MEMBRANES-ATLAS sheet lining material. sheet lining. sheet lining. lining material. of a layer of hard natural sheet lining is a polyvinylidene rubber sandwiched between two layers of soft natural fluoride. ATLASTIC 31 is a hot-melt asphaltic compound with a ball-and-ring softening point of 200° to 225°F (93” to 107°C). ATLASTIC 40 is a corrosion-resistant membrane system consisting of a layer of ATLASTIC 40 textile in the center of two layers of ATLASTIC 31. ATLASTIC 50 is a textile-reinforced, hot-melt asphaltic membrane with a ball-andring softening point of 250” to 275OF (121” to 135OC). CHEMPRUF linings are a series of heavy-duty monolithic systems based on epoxy, furan, polyester, and vinyl ester resins. The CHEMPRUF 1000 Series systems contain flake glass as filler and reinforcement. The CHEMPRUF 2000 Series systems contain fabric reinforcement which provides a lining with outstanding structural integrity and chemical resistance in broad thermal ranges. Flake Glass Systems CHEMPRUF CHEMPRUF CHEMPRUF CHEMPRUF CHEMPRUF Resin Binder 1100 1200 1300 1301 1400 Fabric Reinforced Furan CHEMPRUF CYEMPRUF CHEMPRUF CHEMPRUF CHEMPRUF Epow Polyester Polyester Vinyl Ester Chemical R: N: A: C: X: Resistance Systems Resin Binder 2100 2200 2300 2301 2400 Furan Epoxy Polyester Polyester Vinyl Ester Chart Recommended Not recommended Silica filler will be attacked. Sealing the surface may prolong Conditional; may be suitable but consult Atlas before using Does not apply life - 2 =0 5 = 4: - C H Ct. I - Acetaldehyde NN Hh I - t Acetic acad. up lo 10% CN RR I - P Acetlc acid. glaClal NN RN I P C Room Temn ti 150°F ‘A Alum Alumwwm Chlortde RR Alummum Nitrate RR Alummum Sulfate Ft _ i-i - ( I F 9R I F Ti - I P 3R F Ammomum Chloride ‘RR El - F Ammomum Hydroxide NRC 3A - b IRR (continued) Synthetic TABLE 1.65: VARIOUS RESINS AND ELASTOMERS 1t 1 - - FOR LININGS - 7- AND MEMBRANES-ATLAS =E a T I C Room Temp. , Ammomum ~Ammontum Amvl H 150°F CH - Nltrale RP SuItate RR - Acetale ~ Amy1 Alcohol , Aqua CH 3N 3C JN RR - 4N Rh - I Regba j Barwm r4N I F3R I F1R RR i-i - I F1R IR RR I F UN I P JN Chlortde RR Barwm Hydroxide Barurn NltraIe Barium Sulfide BeMerle -. / Benzene sulfon~c I Etromme acid. 4N RR __ cl FIC i-i FIR 10% z - wear ~ Bulyl Acetate 1 Butyl Alcohol Nh I - - NhI r4N I Amhne h1ri rJN RR - I rJN MNI P4N 1 F3R RR G UN UN UN - CH RR RR NN RC _ NN UN YN G - RR 3R RR G UN (:n -7i-c i-i - F rUN f UN - t UN rUN f i-i - RR FIR PIN 4N - I RR F I RR n IUN - RR in4N - IUN n1N IUN FIR - 2 % -6 -6 -6 [ ( I c:n - c F RI R F hIN h n i-i - 4C RC F hIN F NN nIN - JN NN h hIN h NN nIN - JN CN c hIN L I9R RR RIR - 4R RR F R R F FIR I9C RR RIR JN AC F A R h :C - cc Cz - tR RR C.i IaC RR RIR - 3N RC F R R RINI 1N - L1N RIA - IU Nj AC 4N NN h NIN n 4 h IN - F RR RIA - ;k RR R R R R I1C I3R IU N! RR RIR - IR RR R R R RIR RR RI- RR RIA - 1-i R R R R R RIA RR AR - NN NIN - IC NN h NIN R N IN - I RR h IN 1N CN C NIN h N IN I RR C:H - IC RN R C N R Ac I RR IN AC RIC RR N Ni A Rc I RC h IN RIC IR RR RIR I- RR C C R R 77 cc Cz - I’A R C C R RR A C R Y- RIR - JN UN UN - PIN - UN 1N nIN nIN I!IN hIN RIR JN JN - 9R F4A 3R -7 1R c RIR - 1R F RR RIC - IR RR A RIR - IR RR R R t-R R R RR R R R I- RR n R N II r, R .- hiIN h hlNiRR C.N R NIN - A NIN R RIR A -G -; R A RR F RR Calcium Chloride RR 9R FIR FIA RII4 -_ *R I RR IR IR RR RIR Gi - 3R - F,R 3R FE - RIA - 1R F RR IA - IN RC A:R 9fi FIR G h4N RIA t il. . ..- 4C F A” IH RR H NIN NIN NIN - IN - #A -IN - N IN N IN IN I- CN .N R C N R IN 6 - NN c - R C d R / !4 N IN - NIN - IN - Carbon Tetrachlorlde ‘NN IN - IN - ICC IR - N ‘N N N - IN - IN P hIN JN NIN 4N - ‘Chlorine gas. dry RC IN - N N - IN - 4N - NIN - ,Chlorme gas. wet RC IN - N N IN IN NIN - /Chlorme water AC IR c - Rc - c - CN N N - IN - IR IN R R N IN - IN - N N - IN - IN N N N N N N Chlorobenzene N N; Chloroform N ‘U I Chromic acid. up to 5% ,Chromlc acid. 10% /Otric j Copper acld Chloride /R Ri R R; IRRIRR -ii. -F T -i- - N IN - N N N N i NN N N N Rc 1 C N N N L 7 4 f NI AC JNI RR IN k :N - IC NN R N ; R/RR/ :N IN - 2 R z ; R C N R R R C N - R R N N N N C N N -A C;NN N N N C N R R NiNN N N R N NiNN N Ni R NN N N R RR R R ‘R CR RR - NN ;;7 NN iN NN RR - - K N t R h IN - N IN i c IN ;N A RR _-_I h JN:NN - R Y- N RR N N A N R NN .N f - N Ni NIN R R 1C 1R Dlsulllde R R - RE - RI ? -_ Carbon Rx R C --I FK - 10% Rc PIR - G - acid. 6 IR Fz F1N I ,Chloroacellc IN FIR - Gi - solution NIN - F1R - RR water NIN Rz - F B~sulftte Dloxlde. 1 RIR - F Calctum Chlorme :I4 RIR - F RI R RR RIR - L C ( I FtR(RR NN FIR - G - i Ii ii JN ( 72 - G L-i - l7 3R G - IR I z IN - r JN G - I ; I , F ( s 8 Ei -6 c:n Fii I I 3R - fE FIC PiN RR - I F,R 1 0 :li 3C Nh 4 z - 8 ;; i t 6 I ” -:nz i-z - 8 z z yr t-3 Is ;i; 2 -z 8 $ ? 2 (cont’d) - 54 s 243 Resins and Polymers ;~ - N N i #N N A CI,,RRr;;;;j C (continued) 244 Corrosion Resistant Materials Handbook TABLE 1.65: VARIOUS RESINS AND ELASTOMERS FOR LININGS AND MEMBRANES-ATLAS - - --r c 2 0: 5 z i C Room ; Copper H 150°F Ntlrale Dlethyl Ethyl Temp. Glycol Ethylene 5 -6 CM CH cc cc 5-i RR RR RR ( :n ( RR UN I __ FtR 1 tc UN / FIR f tR UN c1N r t JN:NN UN c4N r JN NN UN h1N r dN/NN I NN I-NN UN -~ hIN r :N C:N ( RR JN hIN r RR JN hIN P AC tC RIC tC RR RR ~HlCH z - i E al 6 :ti E6 - ! ’ ( RR I ii I NN r4N ,YNlRR , RR UN - NN I JN - IVNjRR r hIN - UN - RR UN - VN rJN IVN;RR rrlN h IN - 4N 3R ?R FIN I3C,RR F1R RIR - E - NN 3N FK - (,NIRR EJN RIN - :N - NN VN PJN rqN/RC rJN 1N - F ?R FG - F3R’RR F1R NIN A R - AIA F UN r.IN - rrl P4N RI’R - R’R h IN F ?R FIN FIC - FIAlAR FtR F r.,N Rc F FIC AR N;RR 63R!RR FIC R Tt - C r- RR RlRR - - - - N / R’R JN hIN F 3C RR 4N C:c P 3R FIN - Glycsrme RR RR tC hIN C 3R Gold RR RR tFt RIA F 7R FIC PIR - NN RR JN RIN h 2R RIN - F1R RR IC NIN F ?C RIR - RR IC NIN F 3R RR IC R C F 3R acld RC Hydrocyanlc rcad RR - Pwortdr Hydrogwt Sulhd, R R RR - N r- RR FIC/NN C:N R C - R:RC RIA - FtR RR RIC R R - RIR - FtR t RR RIC R A - C 4N h IN - c1 N NIN h JN NIN - F1N RR RR IN A N R 3C RIN - RR IN R R h IR JN RIA C 1” JN h IN F :c R1R 4N 4N C:’ c RI’C hIN R -c FIClNN C.C Rc RIC - FlR:RA R A AR RIC - FlR;RR RI” RR 1R RIR - FIRIRR nIC F IR FtR RIR F 3R NIN _~ Ir 4 Ni IQ RIA RIA IN __.. X - ININNIRCINN :c tR INj-&&lNIR~R I R --+ ‘N’R :c -4 R! R ARIAA tR ccb IR RRT- IN / Magnesium Chloride ’ Magnesvdm Hydroxide ~RRIRR RR RR : Magneswn Nitrate RR RR CN A kf p IR IR’RR I R’C t- R’C IFtR]RR HIC r.4NlRR I, , cIRIRR hIN .. T R F F R R R R N N :i R :N R IA R N t- RR IC R R IC R R RlRR IC __ + 3RtNN FfI R’C R R - a R‘R r !F 1C /R d c J ‘W /R R R IR - R C:c. CC A R N IC,RC FIC NIN IN R R FIR 1N Jr4 tR - RR :c RR F 3N - RR RR gas. dry FtR RR - Hydrogan 1 RR RC 4N - UN - NN Hydrochloric hIN - 3R - RR NN Gasolme - 3R - , RN RC FIR FIR FIN - I3NIRR CN acld -6 CH -_ t1, c:k - I i-i Formx IiydrObrOmlC E a8 RN JN nex*ne ri: UN - RR - i RR RR Cyrnlde 2 % x 6 - Ii-ii Formaldehyde .~ 8 tt 1 t RR aad 8 z :! FIUOSIIICIC acld RR - 8 z t CH CM I NN Acetate 2 i 2! ; CH / CM \RR Ether f 5 i _.- 6 2 8 t bnt’d) IR - R -E R R5 ‘Req”,,es Synthetic (continued) Fabric Synthetic TABLE 1.65: VARIOUS RESINS AND ELASTOMERS FOR LININGS Resins and Polymers AND MEMBRANES-ATLAS 8 8 I? It. 245 (cont’d) cy -,i i c [ C Room Mercuric Temp. 1”” cl.41 CHjCH Acetate Methyl Acetate Methyl Alcohol Methyl Ethyl Methyl Sulfate ___- H 150°F Ketone ’ NN--*- NN NN I---NN NN/NN NN NN -_-~ CN MIneral 011 MIneral Splrlts Murlatlc acid - CN NN -t cnicn -NN RR!RC i---NN “C NN CN RC+NG NNICN NN -NNIRC NN NNiRR.NN’CNICN; -i--7 NN “CCNNICN! RRIRRiRR “C CC NN NN I RRtCN RRJCN c c F r E h F c F h FE~CNIAR;NNJCN ii IN NN.NN RR NN NNF RR I- NN RR RC F FIR RR RR t RC F RIC RC R!R t RR KilRRIRRR [ F Rta Nickel Chloride F Nickel NItrate F R Nickel Sullate F~F~RRIRR;“C/RR R N,lrtcac,d.20%1Nltrlc acld. +--RRINNlNN ,RC +- NNICN F ” F ” NN h N h N h N N N/ C N R ” RC,RC R N NN t-NN 30% YN NN acid Oxalic acid Perchlorx RR G”R acid Phenol Phosphoric acfd Phosphorous acid Phosphorous Trlchlorlde Phthallc ?G~RR NN NN iRR ._i acld --I /RR RR RC NNlNN Potasswm Carbonate Potawum Chloride ‘R -4 H RR’“” -.I !RRIRR/“” NN t- NN N NI NN I- N N! NN/RR Olelc F NN I GJRR~NN I- RR NN t NN NN h N CN CN R ” R RRiRR RR,“C RR RC ;;;;;R” RR:“C RR c RC R R CN i- NN N;;;~NN~NN/GNI RR NN NN’R N I NN NN NN NN RC “C NNI ---I H RR RR _f--- H R RC,RR N R ” I- N N RR R ” RR R N R n A R t RR - Potasswm Fetrtcyanlde R I, Potasswm Ferrocyamde R II R ” R ” N R ” ” Potasswm L- Hydroxide. Potassum Norate Potaswm Sulfate up to 30% N N salt 9R RR RC AC cc ICC/cc r--- c_ RRjRC Bicarbonate t- RR NN R R’RR R C Sodium CN R RiRR Pyrldlne Rochelle CN -RR iA Ad 1. R R RR R R .R C 1~ RR RR (continued) Corrosion Resistant Materials Handbook 246 TABLE 1.65: VARIOUS I- RESINS AND ELASTOMERS I I FOR LININGS AND MEMBRANES-ATLAS kont’d) - I i 5 z 2 2 n A C Room Temp. H 150°F CniCnlcHlcnlcn t; c cn cn i-i - Sodium Carbonate I Sodium Chloride 1?R - Sodlum Cyamde Sodium Hydroxide. up to 30% I3R j Sodium Hydroxide. 30% and IG - Sodium cn cn CH I3R - Hypochlonle. over up to 3% IGN - r4N - Sodium RCIRCIRR/RRRAI F3R I 3R - Sulfate I 3R I *R i Sodlum Thwxulfafe i Stearlc fG 14N 9R/RRti-Nm acid I 1N - / Sulfur Dioxide gas. dry n4N 1 Sulfur Dloxlde gas. wet n1N 1 Sullur Trloxlde gas. dry n1N i Sulfur Trloxlde gas. wet ?R!RCjRCk CN - Sulfut~c , Sulfurx I - up to 50% FIR - acid. 80% hIN hIN hIN hIN h IN h IN NIN ~RRHCN~RRR ‘Tin- :N - Toluene IN - Trxhloroelhylene Trlsodwm Tung Phosphate 011 Urea xylene Ant C:N - IN R lk R N Chloride Zinc Nitrate Ztnc Sulfate NN NN hIN - acid. Tin Chlortde - NN CN NN NN NN Synthetic TABLE 1.66: VARIOUS RESINS AND METALS-PHILLIPS CORROSION 2fvf MEDIA RYTOf 2w”F 2wF KINAR 247 CHEMICAL RESISTANCE ‘ENTO, Resins and Polymers GUIDE 2wF MtBOI STEEL lEFLOh AIL”. M,N”M wm) I A A Acctaldehyde Acettc Acids Acetac Anhydride Ac,d Acetlc Acid, Glacial Acetone Acetonitrile Acetophenone NR - A Q A A NR A NR A/Q A A A NR Q A NR NR A A A NR Q A A/NR - A - A NR Alcohol, Amyl Alcohol, Alcohol, Butyl 2.Aminoethanol A A A A A A AI- Chlorohydroxlde (wet) Ammonia, anhydrous Ammonium Chlortde Ammonium Hydroxide Ammomum Nitrate Ammonium Sulfate Amyl Acetate Aniline Asphalt Emulsions Barium Hydrorlde Sulfate Benzene Benzaldehyde Benzene NR/C Sulfonic Acid Benzonitrile Benzyl Chloride Borax Bromine A A A A A A A A A A A Bar&urn Chloride Barium Al- A A A A WQ (wet) Butadiene A A A Butylene Butyl Acetate Butyl Amme A/Q’ Butyl Phthalate NR NR NR A Q A A A A A A NR A A NR - A A A A NR Q A A NR A A A A Q A Q A NR NR A NR A NR NR A A - A A A A A A NR NR A/Q AlQ A/Q A A NR A h 4 Q Q NR A A A A NR A : A A Q A - - NR A NR NR A A NR A NR NR A NR NR A NR NR - NR - NR - A NR - - - A A Q A NR NR NR A NR A A A A NR Q NR A A A A A NR - A A A A - A A - - A A A A NR NR A A A A A A P NR A - A - A A A A Q Q NR A A Q A A A A : Q NR - A AjNR A NR NR A A NR NR A A A NR A Q NR A A A A A A A NR A NR - NR NR A A A A A A A A NR A A - A A A A A A NR NR A A A A A NR A NR NR - A NR NR A NR NR A A A NR A A A NR A NR A A A Q NR NR NR Q NR NR Q - NR - A - A - A NR Q Q NR NR Q Q NR A A A Q A NR NR NR A A A A A A Q A NR NR NR NR A A A Q NR A Q - Q NR A A Q A NR A : A - A Q A A NR A A P I\ A A A A pi A A A NR A A A NR NR A NR NR A NR n Cycloherane A - NR NR NR - Copper Sulfate A NR t Q A A/Q ). Q Q A A A Q NR A A A A NR NR A A A A NR NR A - NR Crude Oil NR : NR m-Crew1 (crude) Cresyldiphenyl Phosphate NR A A NR A A A NR Q A A - Chromic Acid Cottonseed Oil A A A A Q A A A NR A A Chlorme(dry) A NR A A NR A NR A - A NR 5% Aqueous Acid A A A A Q Chlorophenol, Chlorosulfonic A NR A A A A Chloroform A A A - A A/Q (dry) A A Tetrschloride Chlorobenzene 2-Chloroethanol Q Q NR NR Cellosolves A A A (wet) A Q A A A A NR NR NR NR - A A AlA Sulfate Q Q A NR Calcium Carbon D&oxide NR NR - Dlsulftde Chloride NItrate NR A A A A A A A Calcium Calcium A Nfl Al- Q A A Butyl Ether NR A Al- Butane Q i NR A Acetylene Chloride (dry) Sulfate NR A A Acetyl Chloride (dry) Acid Mane Water Alummum Aluminum A Cyclohexanol 4 P 9 Cyclohexanone 4 NR Detergents 4 4 Dtesel Fuel 4 z A 4 A NR A (continued) 248 Corrosion Resistant Materials Handbook TABLE 1.66: VARIOUS RESINS AND METALS-PHILLIPS m WF ‘ENYD, Y - m - m MO’F MO’F 20s F KYNAR TEFLDf POLY “LFOf NYLON m m 1W’ F Diisobutylene Dimethyl Aniline A A A Dimethyl Formamide A A/Q Dimethyl Phthalate A Dlmethyl Sulfoxide A Diphenyl Ether A - A Phthalate A Q A p-Diorane A Dowtherm A NR - Dioctyl Eplchlorohydrin Ethanolamine (dry) NR NR A Q Q Ethylene (wet) Chloride A Ethylene Dlamine Ethylene Dichloride Q AIQ Ethylene Glycol A FC-77 (Cyclic Fluormated Ferric Chloride Ferrous Chloride Flo-Cool lSO(SilicateEster) Fluorosilicic Acid, 25% Formaldehyde. Formic Acid 37% Ethe A NR NR - NR - A Q A - A NR A - A NR Q” A NR NR NR NR NR A A A NR - NR NR A A A A A - Q A A A NR NR NR - A Q A NR NR NR Q Q Q Q Q A A A A NR NR NR A NR NR NR - A A A A A A A A A A A - A A A AiA - A Q NR A A - FlWlll Furfural A AIQ A/Q A A A A - A A A Freon (dry) Fuel Oil - A A Q A A : Q Q - A A A A/Q A NR A/NA AL”MlNUM (3cQI) - m - - NR Q STEEI - NR NR XROC NR NR A ZWF P&E:I NR NR A m NR A Lthyl Acetate Ethyl Chloride (continued) A - A Ethers CHEMICAL NR NR NR - NR A A A A A A - NR NR - A NR NR - Q A NR NR NR NR Q A NR A - A A A - - A A A :/NR NR A NR NR A NR A A CaSOllne A A A NR A : NR A A - A Glycohc Acid A - Heptane A A A Q Q A Hexane NR - A - A A NR A NR NR A A A Hydrochloric Acid, 20% NRIF A Hydrochloric Hydrufluoric Acid, 37% Acid, 5.75% NR/Q A’ A A A Hydrogen Gas Hydrogen Peroxide, HydroSen Sulfide (wet) 30% : A A A A A Q Q A A : A A NR NR A Lactic Acid A A Q NR A A NR A A - Oil A A A - Chloride A A A A Magnesium Hydroxide A : - A A NR NR NR A A NR NR Q - A A A A NR A &IQ k Morphofme C9tor Oil Naphtha Naphthalene Nitric Acid, 10% 35% (Cont.) Nitrobenzene Nitrogen Nitromethane A n h WQ VQ 1 VQ \ VQ A NR NR - NR NR NR A A NR A Q A NR A A A A A - A A NR A NR A A - Lubricating A A A A A A - Magnesium Ketone A A A Ethyl Ketone Q A A Methyl NR A JP Fuels Ketones MethylenaChloride A A : A A Methyl lsobutyl Mmeral Oil A A KWOSel-le LPC A A A A NR A A Q Q A A A A A A - NR - A A A A A NR A A NR A A A A A A Q A A A A NR A A iI A R A )I NR n A 9 NR VQ 9 A 4 4 /4 4 YR A NR A NR NR NR Q A A Q A YR (continued) Synthetic TABLE 1.66: VARIOUS RESINS AND METALS-PHILLIPS CHEMICAL m m MEDIA MO-r 2W” F RYTON PENTON m Perchloroethylene Phenol (dry) Acid Phosphorus Trnchloride (dry: A A AIQ A A A A A A A NR A - NR A NR A NR Q NR A A A A A P A A A/NR A NR A A A A A A - A Sodturn Chloride A Sodaurn Chromate A A Q A A’ A A Q Q Q NR NR Q NR A A A A A A A A A A A : Q A Q NR A A NR Q NR A NR Q A Q A Q NR A - A A A A A A A z A NR P A A A : A A A A A A A A A A A A A A Q A A A A A - Sulfuric And. 30% A Q A Sulfuric Acid, 50% A’ A Sulfuric Acid. 98% A/Q * NR A Q NR A A Al’2 A NR A NR : A _ A - NR A A NR - NR NR A A NR NR A A A A Q A A NR - A - : NR A A A A NR NR A NR NR NR A A - A A NR A A A A - vmegar A A A A Sea A A Tap A A A A Xykfle A A NR Zmc Chloride A A NR - than indicated. polyphenylene sulfide poly-3,3-bis(chloromethyl)oxacyclobutane polyvinylidene fluoride polytetrafluoroethylene phenylene oxide-based polymer NR NR A P NR Q NR A A A A NR A Deionized - - NR - A Turpentme(dry) RYTON PENTON KYNAR TEFLON NORYL A A A reslstant A NA A A A ‘Ryton grades c~nta~nlng glass fiber and/or mineral fillers will be less chemically NR Q NR NR - Water, NR NR A A A A AjNR NR NR A QINR A - A A A - A A A Q NR A A A A A A Phosphite Phosphate NR A Sulfur Trlphenyl Trlsodlum A A A Actd Q A A A NR P A A A S”lfolUle Phosphate A A A A Trlethyl A - A’ Stoddard Solvent Sulllnol Trxhlorrcetic A A A A Tomato JUG Tnchlorethylene A NR A A A Tetrahydrofuran Toluene - NR Sodturn Carbonate Dmxide NR Q AIQ A Sodium Thlosulfate Steam-&IV F - Q Chlorohydrin Sodium Sulfate Sodwm Sulttde A A Propylene Pyrldlne Soln. m - A NR A Sodturn Hypochlorlte ALU- STEELYINUY oca1) NR Permanpanate 15% 3D% :ARBON NR Polarslum 50% wF NYLON Nil Hydroxide, Sodium Hydroxide, Sodium Hydroxide. m A Chloride Sodium Hydroxide. m NORlL A Polarslum Sodium Bicarbonate m ZW’F 2wf POL”. ULFONI A Potassium So% IW”F TEFLON kontinued) A A Phosphoric 2M’ F KYNAR Resins and Polymers - NR - Q NR A Q 249 250 TABLE Corrosion Resistant Materials Handbook 1.67: VARIOUS RESINS FOR MEMBRANE LININGS-WATERSAVER WATERSAVER MEMBRANE LININGS HYPALON’ (Chlorosulfonated OR CPE R Polyethylene) (Reinforced . ..provides excellent resistance to weathering and chemical attack. Hypalon is available only as a rein. forced membrane and does not require a protective cover for most applicatrons. Hypalon is approved for potable water containment. PVC (Polyvihyl Chlorinated Polyethylene) . ..specifically formulated for resistance to oils. Offers all of the desirable characteristics of Watersaver CPE and in addition, provides greater strength and resistance to creep, sagging, and puncture where conditions of use are severe, such as steep slopes or other high stress applications. Chloride) EPDM . ..membrane offers good chemical resistance, sealability, and serviceability in unexposed applications. It has performed satisfactorily as a liner for recreational lakes, canals, evaporation ponds, sewage lagoons, brine ponds, etc. It is recommended that an earthen cover be provided for PVC to maximize its service life as a fluid barrier. OR CPE (Chlorinated (Ethylene EPDM OIL RESISTANT R (Reinforced POLWINYL ISOBUTYLENE EPDM) CllLORlDE ISDPRENE (ORPVC) (BUTYL) (IIR) 1 I POLYCHLOROPRENE I ETHYLENE PROPYLENE DIENE (NEOPRENE) MONOMER (EPDY) - CHLOROSULFONATED POLYETHYLENE CHLORINATED POLWINYL EXPOSED BURIED ACID (HYPALON) POLYETHYLENE CHLORIDE SIDE SLOPE LINER LINERS RESISTANCE ALKALINE PETROLEUM DH 2 to 7 RESISTANCE (PVC1 II DOMESTIC ROOFING RECOMMENDED RR III IYR UR NR RR RR ii R I RR II 9 II II RR i P i YR i i UR 1R I pH&VOW I PRODUCTS 1 NR WATER WASTE MEMBRANE “II. RECOMMENDED 1 (CSMI I POTABLE (CR) (CPE) NR LINER EXPOSED Monomer) . ..has the superior weathering characteristics of the non-reinforced EPDM with additional strength and tear resistance required by some applications. Many potable water reservoirs are rehabilitated with EPDM R or Hypalon. . ..specifically formulated for resistance to oils. Membrane features excellent weatherability, sealability, chemical resistance and long term durability. CPE does not require a cover material for most applications. I. Diene . ..he. ,sen used for roofing and lining applications for many years. Superior weathering and elongation characteristics have made EPDM the most widely used single ply roofing membrane in the U.S.A. Polyethylene) I Propylene . R 1 RR R R RR i NR R NR i - ONLY WITH REINFORCING 1 iii YR _ NOT RECDMYENDED TABLE 1.68: VARIOUS RESINS FOR PLASTIC LINED PIPING PRODUCTS-DOW DOW plastic lined pipe, fittings, and valves are designed and manufactured specifically for safety with long service life and process integrity in handling corrosive media, either liquids or gases, The variety of lining materials in the line of DOW piping engineer designing a piping system to select components particular service. The complete line includes: SL piping products lined with SARAN* polyvinylidene PPL piping products lined with polypropylene resin. KL piping products lined with KYNAR** polyvinylidene PTFE piping products lined with polytetrafluoroethylene ‘Trademark **Trademark products allows the best suited for that chloride of The Dow Chemical Company of Pennwalt Corporation Ratings of serviceability of DOW plastic lined pipe, in terms of resistance to corrosive attack by process media and maximum operating temperatures, are shown in the following table. Unless otherwise noted: Solutions of inorganic materials appearing in the listing are saturated solutions. Where concentration percentages are indicated, the percentages are by weight. fluoride resin. resin. resin. CHEMICAL Maximum Tsmperaturs-nF PC) 252 L : - : - - Corrosion Resistant Materials Handbook i :d - - #$ - - - 1 - - - - = d : - 9 2 g .’ t ._ - E - d - E - f i 1 - - d - - - - - - - - - - - - 64 - - - 6 - - Sd - - - Eh - - - - - - s - - - - - - - - - - - iA - - 2ci - - - k - - E - - d - d s z - zl - - = b = -E 3 -E -; -E 0 e i 1 5 ._ g i i i J2 3 f 5 ._ I f 5 h - - P d = !i E = - d - - d - - - - = 7 Y ;: 0 .- 11 1 - - 5 x I ; E g I i E E = d - h .t 3 ; -E = e I d 5 -ir . .i .I i TABLE 1.68: VARIOUS RESINS FOR PLASTIC LINED PIPING PRODUCTS-DOW CHEMICAL (continued) Maximum Cormsiw Strsrm 1 *ls 11361 = llnl 110 llm ml ?m Calciumchlwin Pm IL 19 El 1 11 I I Calcium chlorid*(rmunmdl Temperature--7(T) as 2 I PPt St IL PPt St 04 Not Recom mended E ti i; . d - i - - - Zd - - - ;ris : - e - - - $0 - - - - , : - 6d - - - id - - h - - - - - ih i - - - - - - - - - - $ - - - -- z 7, 0 1 f E i - - - - e -E ij ?s m 2 : z - u‘ - - E E y il: -i - 7 i; - - = - - - ii - - = - - - - - = - - - id - - -E = - - - i - i; - - i - : - - - - - - = -iz m 5 i 1 -E -E -E D e _O ; .r d x f 1 f 3 .Y I i f 0 6 i 0 0 B i; L : - D 6 1 - - = = = f 0 D = r; If 2 - D Y I 5 = -E -E a I 8 E d - = = -E 2 Corrosion Resistant Materials Handbook - - - - = - .Y ; ‘. s TABLE 1.68: VARIOUS RESINS FOR PLASTK LINED PIPING PRODUCTS-DOW CHEMICAL z KL SL PPL PPL ‘i IL SL KL PPL SL PR’ SL SL It KL PPL St PPL St IL -t KL PPL St KL (continued) L - 6 - iti - - - - - $c4 - - - - - $ - * - - Handbook - - - Materials - - - Resistant - ti = Corrosion - i: = ii - i; = - = I E f .Y ; F - $ f P 2 H 5 E - I 5 E E - - 2 - - - - - c c - i h - - - - - - - b t - - ii - f - - - - - - - f - - i; - - c ii - - - - i - - - iti - 2 ii - - - L - - - - - - ii - - - d = = 1 = Z K a 8 i :: $s i i = ij f d .Y Y .5 -1 -E 0 2 z Y .Y x -E -E -is -k - - - ii = = = -E -E -E 0 Y . I f: I: ; 2 f j B -r” ii = = -E j i G; E t: t E 2 a! E iit - - - - - ; - - - = : - 3 D f 3 : : ‘, d TABLE 1.68: VARIOUS RESINS FOR PLASTIC LINED PIPING PRODUCTS-DOW CHEMICAL (continued) Maximum I I Tempcrahln-*F I I PC) I IL I Y (continued) TABLE 1.68: VARIOUS RESINS FOR PLASTIC LINED PIPING PRODUCTS-DOW CHEMICAL (continued) (continued) TABLE 1.68: VARIOUS RESINS FOR PLASTIC LINED PIPING PRODUCTS-DOW Maximum Temperature--‘F CHEMICAL (continued) PCI Maximum (60 11311 sodium uh I =* II I I St PPL m 11351 lull 250 m Ilull Temper&m-*F El I’C) :n: El tzI ISI n WI NOt Recom mended TABLE 1.68: VARIOUS I Pnoriun chbrat llSWOPll I nff RESINS FOR PLASTIC LINED PIPING PRODUCTS-DOW II II’ Pm n nrf I(t nffll I I WL I PPL I I I I PPLi I KL i PPt I St-3I PrR KL Pauaium nrf Kt ?Pt nR IL PPL- nfi IL PPL St nfi lu PPt St Pmubm Pamssbm dide I whl Iwfll Pm Kt al n I I I I SL I St It’ PlFf I St I I nrf pwchbrn* Pmauium pwmangan.a I St Pmusium chbrida shmmtie ImIk~lin*~ I SL wt I I SL PPt m I I M’ I sl* I PPL SL I I I I P I CHEMICAL (continued) A - f L +I - - - s = Synthetic : - Resins and Polymers - % - - :L - - i - ti - a ~ - I - - - - - 2 1 - - I a i: - 5 - I - - itI - - E - - - - ti - 2 - - - - 22 - - :;: - - - : - ; - -E - I I ” 3 g ZZ - - lz - - s - n g i$ g ; x .u .g 2H .g - - - 2 - - - - - LYI i - - - - - = il = -. I ._ :: 5 % 2 ._ fi fs 3 ,x z ; B f P e ; - * = -E - E E - - - - - = - - - - i t L - z ;: = m 5 ,; i I - rcs :i - &l e % : - - - = - - Z? z - c - - ?I - - = c _E _ - - - - d = E -E _ c - zrE!!?E -E z - kg - z s - - - = Z . 2 e 1 i - E - - ti - = E _ E t 1 F . - - 3 - z 2 -t i - - - - - - - - - b = c. f 5 Y E E -E - . I L 5 1 z E I I i I s . = = F k I 5 I 5 s :: 0 -E s 3 s E -E - ; x = E 4 : c OL 2 I d 5 t 5 3 1. - 3 - - i , i; - ; I = E E - = k 6 z H i P .a ep 1 t P i I 3 3 261 TABLE 1.68: VARIOUS RESINS FOR PLASTIC LINED Msximum Comasire Stream Temperature--7 fTI PIPING PRODUCTS-DOW CHEMICAL (continued) I Maximum I Synthetic Resins and Polymers TABLE 1.69: VARIOUS THERMOPLASTIC AND ELASTOMERIC PIPING MATERIALS-NlBCO Chemical Resistanceof Industrial lhetmoplastics I 140°F NR NR R R R R R R R NR R NR NR NR ACetOne Acetophenone Acetyl Chloride Acetylene NR NR R R Acetyl Nltrlle Acrylac Acad. Ethyl Acrylonltrlle Adlplc 105 Acid NR NR NR R NR NR NR R A NR NR R NR NR NR R Acetaldehyde Acetamlde Acetic Acid, Acetic Acid. Acebc Acebc Acettc Acebc 10% 20% Acid. 50% Ackd. 80% Acid. Glacial AnhydrIde Ester 7 3°F i 185°F R R NR R NR NR NR NR NR NR NR R NR R R NR Ally! Amy1 Benzyl Butyl. Pnmary R NR Alcohol Alcohol. Alcohol. Alcohol Butyl. Secondary Dlacetone Ethyl Hexyl R NR R NR R R R R R R AICOhOl. Alconol Alc”nOl Al‘Otwl Isopropyl Methyl Propargyl Propyl R R R R R R R R NR R R R NR R R R Alum. Potassium Alurmnum Chloride Alumnum Fluoride Aluminum Hydroxide R R R R R A NR R Alum,num Alum,num Alum,num Ammoma Nitrate Oxychlonde Sulfate Gas R R R R R R R R Ammonia Ammonia. Ammonwm Ammon,“m Aqua 10% Llquld Acetate Blfluorlde R NR R R R NR R R Ammonum Ammon,um Ammonwm Ammomum Blsulflde Carbonate Chloride Olchromate A R R R R R R Ammon!um Ammomum Ammonium Ammonium Fluoride. 10% Fluoride. 25% Hydrwde Metaphosphate R A R R R NR R R Ammohlum Ammonwm Ammonwm Ammonum Nitrate Persulphate Phosphate Sulfate R A R R R R R R Ammonum Sulfide Ammonwm Thmcyanate Amyl Acetate Amyl Chlorlde R NR NR R NR NR An,l,ne An,lme Chlorohyarate An,l,ne Hydrochloride Anthraqumone NR NR NR R NR NR NR R 12O’F R R R R R 15O’F VITON PVDF 18O’F 3-F 15O’F 23O’F 2BO’F to 210°F NR NR NR NR UR UR UR UR NR NR NR NR UR UR R R 14O’F 210°F R A R R R R R R R NR NR NR NR NR NR R R R UR R R R NR NR NR NR NR NR NR R R NR NR R R R R R UR R NR R NR R UR NR NR UR NR NR UR NR iR UR NR NR R UR R R R NR R R R NR R R R R R R NR R R R NR R R R R R d NR NR R R R NR NR NR NR NR NR R R NR NR R NR NR R NR NR NR NR R R NR R NR R R R R R R R R R R R R R NR R R NR R R NR R R UR UR R R NR NR R R NR NR R R R R UR R R R NR R R R NR R R NR R NR R R UR R NR R NR R R R R R R R R R R R R R R A R R NR R R R R R R NR R R R NR R R R R R R R R R R R A R R R R R R R R R R R R R R R R R R R UR R UR R NR R NR R NR R NR R R A R R NR UR UR R NR NR NR NR NR NR R R R R R ‘R R. R A R R R R R R NR R R R R R R R R R R R R R R NR R R R A R R R R R R R R R R R R R R R R R A R NR R R R R R R R R R R R R R R R R R R R R R R A R R R R R R R R R R R R R R R R R R R R R R R RS R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R ‘R R R R R NR R R R R R R R R R R R R R R R R R R R R R - NR NR NR NR R R NR UR UR UR UR 7:3’F R R R NR 185°F R R R R 14O’F .R R R R F EPDM 3°F .R R R R Polyvmyl Chlorrde. Type 1. Grade : $hlonnated Polyvmyl Chloride R’ Recommended 3’F R Alcohol Alcohol Alcohol, Alcohol. Ally, Chloride Alum Alum Ammon,“m Alum Chrome R = Recommended NR = Not Recommended = No Data Available POLYPROPYLENE CPVC’ PVC’ ‘3°F 263 R R R R R R A A R NR R’ NR R UR NR NR R UR R NR R NR NR R NR R NR R NR A R UR R NR R N” UR NR Nk NR R R R R NR R NR R UR R UR R R R R R R NR NR NR UR NR NR R R NH R R R R R R R R R 1 Data tp 210°F for other chemxals presently not awlable Corrosion Resistant Materials Handbook 264 TABLE 1.69: VARIOUS THERMOPLASTIC CHEMICAL PVC’ S”lfonlc Ant,mony Trlchloride Aqua Aegla Arsenic Acid Aryl Sullon~c Acld Anfhraq”4”one ACld AND ELASTOMERIC POLYPROPYLENE CPVC’ ‘3°F 140°F R R NR R R R R NR R R R R R R R R R R R R R R A 3°F 185°F’ 3°F R R R R 120°F 150°F R A A R R NR NR NR R A R NR R R R VR NR R R R R R R R R R R R R R R R NR R R R A NR R R R R NR NR R R NR NR R R NR R R R NR A NR R R A A R R R R NR R NR R NR R R R R R R NR NR NR NR NR NR NR NR R NR R NR R NR R NR R R R R R R NR NR 3°F 150°F 230°F R NR R R R NR NR R R R R R R NR R R R R R R A R R R R Carbon Carbon Carbon Carbon Oloxlde Dry Otsulllde Monoxide Tetrachlorlde R NR NR NR R R R R R R R R R 140°F 210°F R NR R NR R NR R NR NR NR NR NR NR NR NR NR R R R R R R R R R R R R R R R R R R R R R R R R R NR NR NA NR NR NR R R R R NR R NR NR R NR NR R R R R R R R R R R R R NR R R R NR R R R NR NR NR R R R R R R R R R R R R R R NR R R R NR R R NR NR R R R R R NR NR NR NR NR NR NR NR NR R R R R R R NR R R R NR R f R R R R R R f R NR R R R NR NR R R NR NR R R NR NR NR NR R R NR NR R R NR NR NR R NR NR R NR NR R R R NR R NR R R NR NR NR R R R NR NR NR R NR NR R R NR NR R NR R NR R R NR R R R R R R A R R R R R R R R R R R R R R R R R R R R R R R NR R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R NR R NR R R R R R R R R R R NR R R R NR R NR R R NR R NR R NR R R R NR R R NR NR NR NR R R R R R R R NR R NR R R R R R NR NR R R R R R R R NR R R R NR R R R R NR R NR R NR R NR R NR R NR 1 Polyvmyl Chloride Type 1. Grade Chlorinated Polyvmyl Chloride + For dratnage apphcat~on only R’ Recommended lo 210°F - Data to 210DF z R R R R R 7 3°F R R R R R R EPDM 185°F R R R R R R R 140°F R R R R R R R R R cane sugar Liquors Carbltol Capryllc Acid Carbon Oloxlde Wet 7 3°F 280°F R R R (continued) VITON PVDF 18O’F NR R R R NR R R R PIPING MATERIALS-NIBCO for other chemocals presently not avatlable (continued) Synthetic TABLE 1.69: VARIOUS THERMOPLASTIC CHEMICAL PVC’ F CPVC ‘3°F 140°F R R R R R R R NR 155°F R R R R A R R R R R NR NR R NR NR NR Water Saturated Chioracetlc Acld Chloroacetyl Chiorlde Chlorobenzene R R R NR R R NR Chlorobenzyl Chloroform Chlorop,cr,” Chlorosulfonlc Acid NR NR NR A NR NR NR NR 10% 30% 40% 50% R R R NR R A R NR C~tr,c Acid Cocon”r 011 Coke Oven Gas Copper Carbonate R R R R A R R R Cooper Copper Copper Copper R R R R R R R R A R R R R R R NR R R R NR R R R NR R R R NR R R R A NR NR NR R R NR NR NR UR NR R R R R R R R A R R R R NR R R R NR NR R NR NR NR NR NR NR R NR R NR Chlmne Chrome Chromic CHromfc Chromfc Chloride Ac,d Acld Acld Acid Chloride Cyantde Fluoride Nitrate copper Sulfate Corn syrup 011 Cottonseed CISOl Cresylx Croton Aad 50% Aldehyde e II 3°F 120°F NR NR UR NR A NR R UR NR NR NR NR PVDF 180”Ft 3°F 150°F R R R R R NR NR NR NR NR NR R R R R A I VITON EPDM 7 3-F 14O’F 185’F 3°F 140°F R R NR NR R R NR NR R R NR NR R R R NR R NR R R NR NR NR NR NR NR NR R R R NR NR NR 210°F R R NR NR NR R R A R R A R R R R R R A R R NR NR NR NR NR NR NR NR NR R R R R R NR R NR R NR R R NR NR R NR NR R R A NR NR NR R R R R R R NR NR NR R R NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR R’ R’ R’ R’ R R R R R R R R R R R R NR R R R R R NR NR NR NR NR NR NR NR R R R R R R R R R R A A R R R R R R R R R A R R R R R R R R R R R R R R R R R R R R R NR NR R R NR NR R R NR NR R R R R R R R R A R R A R R R R R R R R R R R R R R R R R R R A R R R R R R R R R R R R R R R R R R R R NR R R R NR R R R R R R R R R R R R NR NR NR NR NR NR R R R R R NR R R NR NR R R NR NR R R R R R NR NR NR R R R NR R NR R NR R R R R R R R NR NR R NR NR R R R A NR R R R NR R R R R NR R R R R R R A R NR NR NR R NR NR NR NR PUR NR R R R R R R R R R R R R NR NR NR R R R NR NR NR R R R R R R NR NR NR NR NR NR NR NR NR NR R NR R NR NR R NR NR NR NR NR NR NR NR NR NR NR NR NR R R R R R R R R R R R R R NR R R R NR R NR NR NR NR R R R R NR NR R R R R R R NR Poiyv~nyl Chloride Type 1 Grade 1 2 Chlonnated Polywnyl Chlotlde + For dramage appl~caf~o” only R’ Recommended 10 2:O”F - Data lo 21O’F R R R R 280°F (continued) NR R UR 230°F 265 NR A NR NR R R NR NR 150°F R R R R NR NR PIPING MATERIALS-NIBCO POLYPROPYLENE 7 3°F R R R R Chloracerlc Acid Chloral Hydrate AND ELASTOMERIC Resins and Polymers NR lor other NR NR NR R NR NR R R chemicals R R presently R R R R R NR R NR R NR R NR R NR R NR NR NR NR R UR UR UR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR not available (continued) 266 Corrosion Resistant Materials Handbook TABLE 1.69: VARIOUS THERMOPLASTIC PVC’ CHEMICAL AND ELASTOMERIC CPVC’ POLYPROPYLENE ‘3°F 140°F r3OF 185°F’ 3°F 120°F D~octyl Phthalate Dloxane D~oxane. 1. 4 Dlsodlum Phosphate Dwmylbenzene NR NR NR R NR NR NR R NR NR NR R NR NR Epsom Salt Ethvl Acetate Eth;l Acetoacetate R NR NR NR NR Ethyl Ethyl Ethyl Ethyl NR NR NR NR NR NR NR NR NR NR NR NR NR NR Ethylene Bromide Chloride Chlorohydrln Dlamme Ethylene Ethylene Ethylene Dxhlorlde Glycol Oxide NR R NR NR R NR Fatty Acids Ferrac Acetate Fernc Chloride Ferrac Hydroxxde Ferric NItrate R R R R R R NR R R R Ferrac Sulfate Ferrous Chloride Ferrous Hydroxkde Ferrous NItrate R R R R R R Ferrous Sulfate Fish Solubles Fluorine Gas Wet Fluoborlc Acld A R R R Formaldehyde. Formaldehyde. Formaldehyde. Acrylate Chloride Chloroacetate Ether Ethylene Ethvlene Eth;lene Formrc Ac,d Formic Acld Freon F-11 Freon F-12 Freon Freon Freon Freon 35% 37% 50% R R R R R NR NR NR R NR NR NR R NR NR NR R R NR NR NR NR NR NR NR NR R UR R R NR NR R NR NR R NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR R R R UR R R NR NR R R NR NR R R NR NR R R NR R R NR ‘R R NR NR NR R R NR NR NR R NR NR NR R R R R NR R R NR R R NR R R NR NR R R NR R R NR R R R R R R R NR NR NR R R R. R. ‘R R R R R. R R R R R R A R R R R R R R R R NR Nk Nk YR R NR R NR NR NR R R NR NR YR R R NR NR R R R R YR R R NR R R R R R R R R R R R R R R d R R R R R R R R’ R R R R R R R R R R R R. R R R.. R R R Nk NR NR R NR NR NR NR NR NR NR NR NR NR NR R R R R R NR NR NR :: :: R R R R NR NR R R NR NR NR R NR NR NR R NR R NR R NR R NR R NR R NR R R R NR R R NR R R NR NR NR NR NR NR UR NR NR NR R R NR NR NR NR NR NR NR NR NR NR R R R R R R R R R R R R R R R R R R R NR ik NR R R R R NR NR NR R R R R R idi R R R R R NR NR NR NR NR NR NR NR NR R R R R R R R R R R R R R R R R A R R R R’ R R R R R R R A R R R ri R R :: R R R : R R R NR NR R R NR NR NR NR NR NR UR R NR R R A R NR NR R NR R R R R NR NR NR R R R NR R R NR NR NR NR R NR NR NR R’ R R R NR R R R R NR R NR NR NR NR R R R R NR R NR R R R NR NR NR R R R R R R R 210°F NR NR NR R R R R 140°F R R NR R R R R R A f I R R R R. R tik i&l NR R UR UR UR UR R R R R 1 Polyvmyl Chloride. Type 1. Grade 1 2 Chlorinated Polyvinyl Chlonde t For dramage application only R’ Recommended to 21O’F - Data to 210°F. ’ UR UR UR R EPDM 7 3°F NR R R A R R 185°F NR R R R 37% 140°F NR R : 7‘3°F ‘R R R Acld. 20% Acud. 5wb Acld. Cont. ZIJO’F NR R R NR R R Hydrobromoc Hydrobromx Hydrochloric 230°F NR R GeMIn Glfl GlUCOSe Glycerme. neptane 150°F R R R R R R R Glycohc Acld Glycols Grape Sugar NR NR VITON PVDF 7 3’F (continued) ‘R R R Gall~c Acld Gas. Natural Gasoline. Leaded Gasolme, Unleaded Gasolme. Sour Glycerol NR NR tI R (Anhydrous) F-21 F-22 F-l 13 F-114 150°F lEOoF’ PIPING MATERIALS-NIBCO NR NR R NR NR NR NR kI R for other chemicals .R R R R R R R R R R NR R NR R NR R : R R R presently E R R R NR NR R R R not avaalable (continued) Synthetic Resins and Polymers TABLE 1.69: VARIOUS THERMOPLASTIC CHEMICAL PVC’ Hvdrocvanc H;droc;an,c Hvdrofluorlc Hydroflurac Acld Aad. 10% Acid. Dalute Acod. 30% Hydrofluorlc Aad. 40% Hydrofluonc Acid. 50% Hydrofluos~l~ac Acid Hydrogen Hydrogen Hydrogen Hydrogen Hydrogen Cyamde Fluor!de. PeroxIde PeroxIde. Hydrogen Hydrogen Hydrogen Hydrogen PeroxIde. 90% Phosphrde Sulfide. Dry Sulfide. Aqueous Hydroqumone Hydroxylamme Hypochlorous Hydrazme Anhydrous 50% Sulfate Ac!d lodIne Iodine Solutton. Isopropyl Ether 1sooctane 10% So CPVC WF 14O’F R R R R R R NR N9 R A R R NR NR R R R NR R NR ‘3°F NR NR R R R R R ‘R. A R NR NR R. R R R R R R : F 1‘3’F 230°F R R R R R R R NR NR R R A R R R R R R R R R R R R R NR R R R NR R R R R R R NR NR NR NR R A R R R R R’ R R R A R R R R R R R Lauryl Chlonde Lead Acetate Lead Chloride Lead Nitrate R R R R R A R R Lead Sulfate Lemon 011 Llgrolne Lime Sulfur R A R R L~noletc Llnolelc Linseed Linseed R R R R R R R R R R R R R R R R MachIne 011 Magnesium Carbonate Magnesium Chloride A R R R R R Magnesium Magnesium Magnesium Magneswm R R R R R R R A Manganese Sulfate Male% Acid Mal~c Acid Mercurtc Chloride R R R R R A R R Cyamde Mercuric Sulfate Mercurous Nitrate Mercury R R R R R R R R .A NR R iR R NR NR R R R R R R R R R R UR R R NR R NR .R R R R R NR NR R R 25O’F R R R A R R R R R R NR NR NR R R NR NR R R NR NR R R Uk R R NR R R NR R R UR UR NR NR NR NR R R R NR NR UR UR NR NR NR NR UR R R R R R R R R R NR R R UR R R NR R R A NR R R R NR R R R NR R R R NR NR NR A NR NR NR NR R R R R R R NR NR NR NR NR NR R NR R R NA NR NR R R R R NR NR R A NR NR R R NR NR R R R R R R R R R R R R NR NR NR NR NR NR NR R R R R R R R NR NR NR R R R R R R R R R NR R NR R NR R R R R A R NR R R NR NR R R NR NR NR NR NR NR R R R R R R R R R R R R R R R R R R R R R .R R R R R A A R R R R R R NR NR NR NR NR NR NR NR NR R R R NR R R NR R R NR R R R R R R A R R R R R R R R R 9 R R R R R R R R R R R R NR NR A NR NR R NR NR R R R R R R R R R R R R R R R R R R R R R R R R R R A R R R R R R R R R R R A R R R R R R R R R R R R R R A R R R R A NR R R R R R R R R R R R R R R R R R R R R R R Presently NR NR A R R 210°F R NR ChemlCalS R R NR NR R R R for other NR NR : 14O’F R NR ’ Polyvmyl Chloride. Type 1. Grade 1 2 Chlonnated Polyvmyl Chloride + For dramage applfcatlon Only R’ Recommended to 210°F - Data to 210°F R R NR NR R R R. R R NR NR 3-F R R R 155°F R R R R EPDM 140°F R R R R 7 3°F R R R R (continued) VlTON PVDF 1SO’F R R R R R R R dt UP 113 15O”Fj R Kerosene Kraff L,quor Acld 011 011 011 Blue ISO’F R. R 25% 80% IZO’F PIPING MATERIALS-NIBCO R R R MB,CU,IC NR NR R R R R NR R R Catrate Hydroxide NItrate Sulfate 3’F R R R Llq”e”rs LIthum Bromide Lubr,cat,ng 011. ASTM Lubr!cat,nq 011. ASTM Lubncatm~ 011. ASTM POLYPROPYLENE 155OF’ NR NR Jet Fuel JP-4 Jet Fuel. JP-5 Lactic Acid Lactic Aad. Lard 011 Launc Acid AND ELASTOMERIC 267 R not avaIlable (continued) 268 Corrosion TABLE 1.69: Resistant VARIOUS Materials Handbook THERMOPLASTIC PVC’ CHEMICAL F AND ELASTOMERIC 140°F ~efhylene ik R NR Methylamlne R NR NR Methyl Methyl Methyl Methyl NR NR NR NR NR NR NR NR NR NR A R NR NR R NR NR NR R R R NR R R R R NR R R R R R R R NR R R R A R NA R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R NR R R R R R’ R’ NR NR R R R NR R NR NR NR NR NR NR NR NR NR A NR NR NR NR NR R NR NR NR NR Nitrous Ox,de Nltroglycol R NR NR NR R 0,lsVegetable Ole,cAcld R R A R R R R R NR R R R R NR R R R R R R R NR R R R R R R NR R R R R R R R NR NR NR R R R R R NR R R NR R NR NR NR R NR NR NR NR Methane Cplcrobromlde Methoxyethyl Oleate Bromide Cellosolve Chloride Chloroform Oleum Oxalic Actd Oxalic Acid 50% Oxygen Gas OZOfl.5 Pai”,f,c Palmittc Palm,,,‘ Paraflln Peracervz Perchlorlc Perchlo,,‘ Ac,d Acid Ac,d 10% 70% Acid 40% Acid 10% Acid 70% Perphosphate Petroleum 011s Sow Phenylhydrazme Phenylhydranne Hydrochloride Phosgene Ltquld Phosgene Gas 7 3°F I POLYPROPYLENE CPVC’ B”F 185’F’ ’ 1‘3°F 120°F 150°F PIPING MATERIALS-NIBCO PVDF 18O’Fi I 7 3°F 150°F IR VITON 230°F R R R R R R R R R R R R R NR NR NR NR NR R R NR NR NR R NR NR NR NR NR 280°F 1‘3-F 140°F R R NR NR NR NR R R R R R 140°F NR NR 21O’F NR R R R R R R NR R R NR R R NR R NR R NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR R NR NR NR NR NR NR NR NR R R R NR NR NR NR NR NR NR NR NR R NR NR NR NR NR NR NR NR R R R R R R R R R R R R A R R R R NR R R NR R R NR R NR NR NR NR R R R R R R R NR NR NR NR NR R R R R R NR R NR R R R R R R R R R R R R NR R R R R R NR R R A R R NR R R NR NR NR R R R NR NR NR R R R NR NR NR R R R R R R R R R NR R R R NR R NR R NR R R A R R R NR R R R NR NR NR NR NR R R R R R R R NR NR NR NR NR NR NR NR NR R R R R R R R R R NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR R NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR R R R R R R NR R NR NR NR NR NR NR NR R R R R R R R R R R R R R R R NR R R NR R NR R R NR R NR R R NR R R R R R R R R R R R R NR NR NR NR R R R A R R R R R R R R R R R R R R R R NR NR NR NR NR NR NR NR NR R R NR NR NR NR NR NR NR R R R NR NR NR NR NR NR R NR NR NR NR NR R R R NR NR NR R R R R R R R R R R R R R R NR NR NR R R R NR R R R R NR NR NR R R NR NR NR R R A R R R R R R R R R R NR NR NR NR A R NR R NR NR for other 7‘3°F R R Polyvmyl Chloride. Type 1 Grade 1 2 Chlor,nated Polyvinyl Chlortde + For dratnage appkatmn only R’ Recommended to 210°F - Data to 210°F F EPDM 185°F f NR NR bntinued chemxals presently not wallable (continued) Synthetic TABLE 1.69: VARIOUS THERMOPLASTIC PVC’ 1‘3°F CPVC’ 140°F R R R R R NA R 7 3°F R POLYPROPYLENE 185’F’ ‘3°F (20°F 150°F PVDF 18O”Fi 3°F 150°F R R R 230°F R R R R R R R R R R R R NR R R R R R R NR R R NR R R R R 280°F R NR I 1‘3°F (continued) VITON 140°F 269 EPDM 185°F ‘3°F 140°F R R R R R R R R R R R R R R R R R R R R R R R R R 210°F NR R R R R R R R R R R R R R R R R R R R A R R R NR A R NR R R R R R R R R R R R R R R R R R’ R R R R R R R R R R R R’ A R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R’ R’ R R R R R R R R R R R R R R R R R R R R R R R R R R R R’ R R R R A R R R R R A R R R R R R R A R R R R R R R R R R R R NR R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R NR R R R R A R R R R R R A R R R R R R R R R R R R R R R R A A R R R R R R R R R R R R R R R R A R R R R R R R R R R R R R R A R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R NR R R R A R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R Polyvinyl : Chlonnated PIPING MATERIALS-NIBCO R’ R’ R f 1 AND ELASTOMERIC Resins and Polymers R R R R R 4 R R R R NR NR NR R R R R R R R R R R R R R R R NR R R R R R R R R R R R R R R R R NR NR NR NR NR NR NR R NR NR NR R R R R R R NR NR NR R R R R R R R R R R R R H R NR NR NR NR NR NR NR NR NR NR R NR NR NR NR NR NR NR NR NR R R R R R R NR NR R NR R R R R NR R R R R R R R R R R R R Chloride Type 1 Grade Polywnyl Chlortde R R R R R R R R R R A R R R R R R R R R R R R R R R 1 (continued) 270 Corrosion Resistant Materials Handbook TABLE 1.69: VARIOUS THERMOPLASTIC CHEMICAL PVC’ 73°F soaps Sodaurn Sodwm Sodlum AND ELASTOMERIC CPVC’ 140°F ‘3°F POLYPROPYLENE 185’F R Acetate Alum Benzoate R R * 7 3°F : R R R R R R R R R R R R R R R R R R R R R R R NR R R R R R R R R R R R R R R R R NR NR R R R R R R R NR NR NR R NR NR NR R R R R R R R R R R R NR R NR R R R R R R R R R R R R R R R R NR R R R R R R R’ R R R R R Sodium Sodturn Sodium Sod,““, Ferrlcyanlde Ferrocyanide Fluoride Hydrox!de R R R R R R R R Sodium Sodium Sodium Sodwm Hydroxide Hydroxide Hydroxide Hypochlorw R R R R R R R Sodturn Sodium Sodium Sod,um lodlde Metaphosphate Nitrate Nitrite R R R R Sodlum Sodium Sodium Sodium Palmttate Perborate Perchlorate PeroxIde R R R R R R Sodium Sodium Sodium Sodium Phosphate Phosphate Phosphate Silicate Sodium Sodium Sodium Sodium Sulfate Suillde Suif~te Thlosullate R R R R R R R R Sour Crude 011 Stannlc Chloride Stannous Chloride Starch R R R R R R R R Stearlc Acid Stoddard s Solvent SUCCI”IC Acid Sul+amtc Acid. 20% R NR R R R NR R R Sulfated Detergents sui1ate Liquors Sulfite Liquor Sulfur R R R R R R R R R R R R R R NR R R R NR R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R 1 R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R A R R R R R R R R R R R A R R R R R R R R R R R R R R R R R R R R R VR R R R NR R R R NR R R A UR R R R NR R R R NR R R R R R R R R R R R R R UR UR NR NR NR NR R R R UR R NR R NR R UR UR A R NR NR R A NR NR R R R A R R R R R R R R R R R \1R NR NR NR R rlR R R NR NR NR R R R NR R A NR NR NR NR R R R NR R A R NR R R R NR NR R R R R R R R R R R R R R NR NR NR NR NR NR NR R R R R R R R NR NR R R R R NR R Sulfur Trloxlde Gas Suilur~c Acid 10% Sulfuric Acld. 30% Sullurlc Ac,d. 50% R H R R R R R R R’ R’ R’ R R R R R R ‘R R R R R NR Sulfuric Sulfuric Sulfuric Sulfuric R R R R R R R NR R’ R’ R’ NR R R R rlR R R NR NR R NR NR NR NR NR NR 1 Polyvmyl Chloride. Type 1. Grade 1 2 Chlonnated Polyvinyl Chloride t For dra,“age appllcatlo” Only R’ Recommended to 21O’F - Data to 21O’F ’ R R R R R R R NR R R 60% 70% 80% 90% 210°F R Chiorlde Chior~te Cyanide Dlchromate Acid, Acid. Acld. Aad. R R R R Nk i 140°F R R Sodium Sod,““Sodlum Sodium R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R 7 3°F R R R R R R 185°F R R R Alkaline Acld Neutral EPDM 140°F R R R 5% VITON 7 3°F R R R Dry Wet 280°F : R R R Chlotlde Dloxlde. Dloxlde Tr,ox,de 230°F R R R R NR Sullur Sulfur Sulfur Sulfur 150°F ik R R R U’F (continued) ik R R R R Solur~an 18O’F R R I PVDF 150°F R Borate Bromide Carbonate Chlorate 30% 50% 70% 120°F R Sodium Sodium Sodium Sodium 154. PIPING MATERIALS-NIBCO for 3fher chemicals presently R R R R UR R R NR R R NR R A A R R R R R R R R R R R R R R R R UR UR R R NR NR NR NR not wallable (continued) Synthetic TABLE 1.69: VARIOUS F PVC’ CHEMICAL Sulfuric Sulfuric Suifur~c Sulfuric THERMOPLASTIC Actd Acid Acid Acid 93% 94% 95% 96% I ‘3-F 140°F R NR NR NR NR NR NR NR NR NR NR NR R R R R R R NR NR Sulfuric Ac,d 98% Sulfuric Acid 100% Sulfurous Ac,d Tall Oil Tann~c Acid Tanning Liquors TX Tartarlc Acid R R Tetraethyl iead Tetrahydrodurane Tetrahydrofuran Tetra Sodium Pyrophosphafe R NR NR A NR NR NR R Thwnyl Chloride Thread Ctittlng 011s Tlrpl”Kl T,tan,“m Te,rachlor,de NR R NR NR NR Toluene Toluol Tomato Juice Transformer 011 Transformer 011 CITE/30 NR NR R R Trlbutyl Phosphate Tributyl Citrate Trvzhloroacetec Ac,d Trichloroethylene NR R R NR NR Tr~efhanoiam~ne Trtefhyiamlne Trimethyipiopane Trlsodlum Phosphate Turpentine I POLYPROPYLENE CPVC’ 7 3°F 185-F’ R R R R NR R UR NR NR R R 1 NR NR NR R R 7 3°F 120°F 150°F UR UR UR UR NR NR NR NR NR NR NR NR UR UR R NR NR R NR NR R NR R R R R R UR ELASTOMERIC NR UR R. NR lBO”F1 PIPING 1 7 3°F 230°F 28O’F 7: 3°F R R R NR NR NR NR NR NR NR NR NR R R R R NR NR NR R R R R R R R R R R R R R NR R NR NR R NR NR R NR NR NR R NR UR UR NR NR UR R R R UR NR R R NR A NR R NR R NR R R R R NR R R R R R R R R R R R’ R R’ R. R’ R R R R R R R R R R R R R’ R’ R R R R R R R R R R A R R R R R R NR R NR R NR NR NR R NR NR R UR R NR R NR NR R R R R R R R R R R R A R R R R R NR R R R R R A R R R R R 210°F NR NR NR NR NR NR NR NR R R R NR NR NR NR NR NR NR NR NR R R R R R NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR R A NR NR R R NR NR NR 4R NR NR R NR NR NR R NR R 4R R NR R NR R R NR NR NR NR NR R R NR NR NR NR NR NR 4R R NR R NR fi R NR NR R R R R R R R R R R R R R R NR NR NR R R R R R R R R R R R H R R H R R R R R R R R R R R R R R R NR R R R NR R R NR R a R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R NR NR NR R R R R R R R R R R R R R R R R R R UR NR VR NR NR NR R R R R R R R R R R R R R R R R R R R R chemicals presently fluoride-hexafluoropropylene R R R NR R R R for other NR NR R NR I Polywnyl Chlorlde Type 1 Grade 1 7 Chlonnated Polywnyl Chloride t For dramage applatlon oniy R’ Recommended lo 210°F - Data to 210°F NR NR R R R name for vinylidene 140°F NR NR NR NR : R R NR trade 7 3°F R ,xylol, VITON: EPDM 185°F R R R R R f 140°F 271 (continued) VITON PVDF 150°F ZI”C Chiorlde Zinc N~trale zinc Sulfate xyiene MATERIALS-NIBCO NR NR NR R NR R R water Salt water Sea water sewage Whiskey White Liquor w,nes AND Resins and Polymers not available copolymer. R R R R R R 272 Corrosion Resistant Materials Handbook TABLE 1.70: VARIOUS THERMOPLASTIO POLYMERS Stock Type Composition G Plasticized Polyamide Resins (Nylon 610) Y Polyester Elastomer E Ethylene Vinyl Acetate U Polyurethane cl Special Material “1” Excellent Rcstrtance - This fluid is expected minor or no effect on the polymer. to have polymer should give reasonably “2” Good Rerirtrnce -This satisfactory service. Due to the nature of this chemical and under prolonged continuous exposure, the stock may exhibit minor to moderate deterioration and/or solution discoloration. Environmental changes such as concentration, etc., temperature, may promote increased degradation. “x” Not Recommended - The stock is unsatisfactory this chemical and should not be used. “-” (Darh) - Insufficient or no data is available material. Testing is advised. RUBBER Polyvinyl Chloride i! GATES CHEMICAL Note FOR HOSE STOCKS-GATES (Hytrel) (EVA) (Gates Tufflex Hose) RATING SYSTEM The amount of discoloration that can be tolerated is usually established by the user on the basis of application. Obviously, products such as paint must be conveyed through a hose having very good nondiscoloring characteristics. If the product is not visually affected, then the hose is satisfactory. For some products, the discoloration may not be objectionable from a visual standpoint. However, the amount and makeup of the particles causing discoloration may be objectionable if they affect the final use of the product. for Some of the more discoloration are: common methods of checking for this 1: The above ratings as applied to the Chemical Resistance Tables are intended as guides only. They are compiled from the best data available to us. Ratings shown in the tables are based on a temperature of 70” F. and 100% concentrated or saturated solutions unless otherwise noted. Note 2: If unusual conditions exist, a stock test in the fluid is suggested. Allowing the fluid to remain in a sample piece of hose for a given period, and then inspecting visually for discoloration. Testing fluid as in No. 1 above and then passtng it through filter paper to check foreign content. A more refined test can be made with a soectroohotometer. This instrument measures light transmission ihrough the fluid before and after immersron tests with the stocks. This ives a relative rating expressed in percent, the original uid being rated as 100%. 1 Note 3: Where a chemical listed in the Resistance Tables is soluble in a solvent other than water, the solvent should also be checked for its suitability with the stock. Note 4: Discoloration of fluids conveyed in hose-There are no generally accepted standard tests for measuring or rating discoloration of fluids passing through a hose. (continued) Synthetic TABLE 1.70: VARIOUS THERMOPLASTIC POLYMERS CHEMICAL Resins and Polymers FOR HOSE STOCKS-GATES RESISTANCE 273 RUBBER (continued) TABLE HOSE POLYMER TYPES G CHEMICAL A Acetaldehyde .................................. Acelamrde .................................... Acellc Acrds ................................... Acetone ....................................... Acetophenone ................................. 2 I X Y I - 2(;[2 - X 1 - - Use Chemrcal Hoses 1 2 I I 1 1 1 Use Weldmg Hoses 1 X 1 1 Atr, 150°F ..................................... Air,1600F ..................................... Air. 200°F. .................................... Awcratt Hyd 011 AA ........................... Alcohol, Amy1 ................................. 2 X X - 1 2 X - 1 - Alcohol, Sutyl ................................. Alcohol, Furlural ............................... Alcohol.Ethyl ................................. Alcohol, Isopropyl ............................. Alcohol. Methyl (6%). .......................... 1 - 1 - : - 1 - Acetylene ..................................... Acrylonttrlle ................................... Aero-Safe 2?iOO................................ Aeroshell. 1A. 1AC. 4 .......................... Air, Ambrenl.. ................................. Alcohol, Methyl (166%) ........................ ,Alkazene ...................................... Chlonde............................ 1alummum 1Alummum Fluortde ............................ .......................... 1Mummum Hydroxrde 2 1 1 1 Nitrate .............................. I kluminum Sulfate ............................. hIurn ........................................ 1 1kmmonia. Anhydrous .......................... 14mmonia. Aqueous ............................ 1 1 1 1 1 1 1 Acetate ............................ 14mmonium Bicarbonate ....................... I4mmonwm Carbonate.. ....................... I4mmonium Chlonde ........................... ......................... 14mmoniumkydroxlde 1 1 1 1 Metaphosphate ...................... Nrtrate ............................ (Fertrlirer) c\mmonium Nrtrite ............................. I Immonium Persulfate ......................... 2 1 - b4mmonwm Phosphate.. ....................... Abmmonium Sulfate ............................ Pbmmonium Bulfrde ............................ P\mmonwm Thiocyanate ....................... Armyl Acetate .................................. 1 1 1 X Akmyl Borate ................................... Armyl Chloride ................................. Aimyl Chloronaphthalene ....................... ............................. A,myl Naphthalene Armyl Phenol .................................. - 4 1Muminum 14mmonwm 14mmoma 14mmonium Anathole ...................................... Aaniline ......................................... A&line Oils .................................... A,rrimal Fats ................................... A,nti-Fraaze (Glycol) ........................... A ntimony Chlorrde (50%) ...................... A ntimony Baits ................................ A qua Regra .................................... A rcq A T.F. Dexron ............................ Type2 ............................ A rco ATF ................................. A rcqc-2.100 A roclqr, Monsanlo ............................. A rqmatx Hydrocarbons ........................ A raemic Baits.................................. A’akarel (Transformer 011) ...................... - - - - - - - - - 2 - 2 2 1 - - - - 1 1 - - 1 1 1 1 - 1 1 - - 1 1 2 1 1 2 2 1 - 1 2 1 1 - - 1 1 1 1 - 2 2 2 2 X - 2 X 2 - - - - - X - - - 2 2 2 1 1 X 1 2 1 1 1 1 X 1 2 2 1 1 2 - 1 X 1 Use Chemical 1 1 x - X 1 - - 1 X X 1 2 2 Hoses - - 1 - - 2 1 - 2 1 1 - - 1 - 1 X ; ) - - 2 1 , - - - 1 ) 1 - 1 1 - - 2 - 2 - X - - 1 1 1 X - - 1 1 1 1 Use Chemical Hoses - X X CI I 1 : 2 2 1 No Hose Available 1 1 - 2 2 2 - 1 - - - 1 2 X U 1 1 1 1 1 1 - - E 1 1 - X X (continued) 274 Corrosion TABLE 1.70: Resistant VARIOUS Materials Handbook THERMOPLASTIC POLYMERS FOR HOSE STOCKS-GATES RUBBER bontinued) HOSE POLVMER TYPES G CHEMICAL 2 I v I E I U I A-Continued Asphalt, 18O’F ................................ ASTM O,l No 1.. .............................. ASTM 011 No 2 ................................ ASTM 011 NO 3 ................................ ASTM Ref Fuel A ............................. 2 X X 2 ASTM Ref Fuel B ............................. ASTM Ref Fuel C ............................. B BalticTypes 100 150. 200 300. 500 ............ Banvel. Concentrated .......................... Barium Carbonate ............................. 3arwm Chlonde ............................... 1 1 1 3arlum Hydroxide ............................. 3arfumSulfate ................................ 3arlum Sulfide ................................ 3aslc Copper Arsenate ........................ 3aygon ....................................... 3eer .......................................... 3eel Sugar Lquors ............................ 3ellows.SO-20 Hydraulic Oil ................... 3enzaldehyde ................................. 3enzene ...................................... : Use Chenvcal Hoses I 2 I -- 1 1 - Use FDA Hoses : X X 3enzoic Actid .................................. 3enzyl Alcohol ................................ $lack Sulfur LlquOr ............................ )orax (Sodium Borate) ........................ {ordeaur Mxture ............................. 1 2 Use Chemical Hoses 2 2 - 1 1 1 1 2 - Acld .................................... iorlc Copper Sulfate .......................... hake Flwd (Petroleum) ........................ lrake Flwd (Synthetic) ........................ lrme (Salt) .................................... X 1 1 2 1 1 1 1 1 1 2 - Elunker 011 .................................... Elutane. Gas or Liquid .......................... B#utter .......................................... t ebutyl Acetate ................................... 0 ,utyl Alcohol (ButanOl) ........................ 2 I 2 I Use 20BHB Only Use FDA Hoses 2 1 - 2 X 1 1 low I C alcium Arsenate alcium al&m alcium alctum slcium 1 1 ............................... Bisulfate ............................... Bisutflde ............................... ..- .................... Bisulftte ........ Carbonate ............................. Chlorite... ............................. Chloride. 1.. ........................... Hydroxide (Cont.) ..................... Clklcium Hypochlorite (5%) .. .................... Calcium HypochloftlO (15%). .._ . . . . ..__. .__._.. . Calcium Nitrate _.. . . . . . . ..... .... .... . .. ccslcium ccllcium 1 Calcium Silicate . . . . . . . . _. . . . . . . . . . . _. . . . . Calcium Sutflde . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Cane Sugar Lquon . . . ._.. . . . . . . . . . . . . . . . . . . Carbohc Acid (Phenol) . . . . . . . . . . . . . . . . . . . . . . . . , Carbon Disufhdc . . . . . . . . . . . . . . . . . . . . . . . . . . Carbon Dioxide (Dry) . . ......... ........... Carbon Dloxicb (Wet) . . . . . . . . . _. . . . . . . . . _. _. . . : Carbon Totnchloride . . . . . . .._. . . . . . . . . . . . . _... Carbonic AIM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Carter MotorDt1................................ 2 - 1 1 2 1 1 1 1 X 1 Use Chemical Hoses 1 2 1 1 1 1 1 1 - 2 1 - 1 2 1 1 Use Chemical X 7 1 X 2 Hoses 2 1 1 1 1 1 Use Chemical H05en 1 1 1 X 1 X 2 I 0 Synthetic TABLE 1.70: VARIOUS THERMOPLASTIC POLYMERS Resins and Polymers FOR HOSE STOCKS-GATES 275 RUBBER (continued) HOSE POLYMER TYPES CHEMICAL 0 z I Y I L I C-Continued Caseln ........................................ 1 CastorCM..................................... 1 Caustic Potash (30%) .......................... Caustic Soda (20%) ............................ Cellosolve Ace!are............................. U - I 1 1 I Usd Chemical Ho;es Use Chemical Hoses 1 c2 3 I I > Cellosolve. Union Carbode ..................... Cellugard. Cellugard 200 ....................... Cellulube, 80. 150. 220. 300 .................... 550. 1000 22OA. ST220 A60 ................. Chlorine Water (25%) .......................... Chlorme Gas .................................. Chlorine Trrtluorlde ............................ Chlorobenzene ................................ ChlorobrOmO Methane ......................... Chlorodane ................................... X Chloroform .................................... Chlorosulfonic Acfd ............................ ChlOrO!Ol~ne Chlorox.. ChOcOlale ................................. ..................................... Syrup ............................... Chrome Alum ................................. Chromic Acid ................................. Chromium Salts ............................... Cider ......................................... Citpo A.T.F. Type F. Dexron .................... Crroo Citgo Citgo Citgo Cttgo - X X X 2 2 1 1 - ., ~tlonaead Oils ................................ Creosote ....................................... Creoaol (Cresylic Acid) ......................... Crude Petroleum Oil ............................ Cyclohexane . . . . . . . . . . . . . . . . . . . _. . . . . . 2 2 2 2 2 1 1 1 1 1 1 1 X - 2 - - X 1 1 1 2 2 1 1 X 2 X 1 X 2 2 1 X :hemicel l-l 1 1 2 - -- 1 1 1 1 1 1 1 1 2 US .................................. Cycloheunone................................. Cymene ........................................ - Daaco. FR160: FR200. FRZOOB. FR310 ........................................ Daaco IFR ...................................... DC 200. 510. 550. 560.. ......................... DDT Weed Killer (DIL.) ......................... 2 2 2 2 2 I Developing Solutions ........................... Dexron ......................................... Dextrin ......................................... Dtacetone Alcohol .............................. Diammonium Phosphate ........................ -c HlOs( 1 1 Cyclohexanol Docalm . . . . . . . . . . . . . . . .._.................._... Deionized Water ................................ Decrol R 6 0 Oils .............................. Denatured Alcohol .............................. Datergant Solutions ............................. Zhemxal 1 1 1 : 2 Copper Chloride ............................... Copper Cyanide ............................... Copper Nitrate ................................. Copper Sulfate ................................. CornOils ...................................... I FJOIHose Available UI ;e IZhernlcal l-lost 2 1 UI FR Fluids. . . _.. . . . . . . . . . . ._. . . . . . Glycol FFMOXD ......................... Pacemaker .............................. Sentry ................................... Tractor Hyd Fluids ...................... Citric Acid .................................... CoalGas ...................................... CoalTar ...................................... CokeOven Gas ................................ Condor Oils. 1WO. 1002. 1004 ................. 1006.1008.1010, 1012, 1014. 1016 1 1 No Hose Available : - 2 t 2 1 1 2 ltact Gate: 1 2 1 X X !s - X X - 2 2 - - 1 2 1 1 1 1 2 2 :ontlnued) 276 Corrosion TABLE 1.70: Resistant VARIOUS Materials Handbook THERMOPLASTIC POLYMERS FOR HOSE STOCKS-GATES RUBBER (continued) HOSE POLYMER TYPES c CHEMICAL z I Y I I E U t I D-Continued Drazmon. Drlute ................................ Dlbutyl Phrhalate ............................... ............................... Dtchlorobenzene Drchloroethylene ............................... ..................................... DreselOrl 2 X X - 2 2 2 1 2 1 X 2 1 2 X X X 2 X 1 D@thanolamlne (20%) ....................... Dlelhylamtne ................................... Drethyl Ether.. ................................. Drelhyl Glycol .................................. Droctyl Phosphate .............................. 2 1 2 1 X 2 - - 2 - 1 - 2 2 2 1 2 2 1 2 1 X 1 X X - - - 1 - - Dtoxane ........................................ Dow General Weed Killer (~~0) Dowtherm A ................................... Duro FR-HD., ................................. Duro OrIs ..................................... DP 47. 200 FluId (Dow) ................. ; X X 2 ......................... - - 2 1 2 1 - - E Enamels....................................... 2 Energol HL66 .................................. Energol HLPC66 ................................ EP Hydraulrc Orb.. Chevron ...................... Essential Oils ................................... Ethanolamrne .................................. - - 1 2 2 2 1 1 - 1 1 1 - 1 - Ethers ......................................... ....................... Ethyl Acetate ........... Ethyl Alcohol (Ethanol) ......................... ithyl Chlorrde.. ................................ EthylEther .................................... 2 X 2 X X X 1 1 - 2 2 1 X 2 1 1 - 2 2 2 X - ................................ Ilhyl MerCaptan .............. Ethylene Chlorrde ............... Ethylene Chlorohydrin .......................... ilhylene Glycol ................................ X X X 1 1 - 1 1 1 - - 1 - - I - X X 1 I ) X X 1 1 1 F errous Sulfate ................................. 1 - 1 1 1 1 - 1 1 2 1 - ............... we Resistant ktyd Fluid (TeXaco) king Solutron (Photo) ......................... ................................. luorborickid luorine Liquid ................................. ._. ......... tuoailicic Acid .................... - ormaldehydc (37%). ........................... ormic Acid .................................... R Fluid D ..................................... R Hydraulic Fluid .............................. FtM ........................................... 1 won (all tym) ................................ _. . _. ............... wit Juices ............... nloil........................................ . ............................ rmaric Acid ...... rran (Furturan). .............................. rrtural (Ant Oil) ............................... ._........ rrguard 150, 200. 226 ................. nquel go. 16Q22Q 300. sx). tooo. ............... 16RA0.22oA40.55oR&0.. - - .................................... .................................... ‘arrrc Chlorrde ................................. _.............. ‘erric Sultate .................... errous Chloride ............................... errous Nitrate ................................. :actovis 52 :atty Acids 1 1 2 1 1 - 1 - - - 1 ) - 1 1 1 1 - - - 1 2 > i 2 2 2 - Use Chemical Hoses No HoseAvailable UseChemical tioaes - _ 1 3 - X - 2 2 I lha Chemical Hoses 1 1 1 Special Hose Raqurrad 1 1 I I Use Chemical Hosas X - X - - 2 2 1 - 2 1 - 2 1 1 X 2 - X (continued) Synthetic TABLE 1.70: VARIOUS THERMOPLASTIC POLYMERS Resins and Polymers FOR HOSE STOCKS-GATES RUBBER (continued) HOSE POLYMER TYPES CHEMICAL G Galllc Ac8d .................................. .......... Gas, Natural .................. Gasoline. Regular Unlealed............... Gasolme, Regular. Leadec ..................... Use X X L I II I U I t ChemicalHoses Contacl Gasoline. Premium .......................... Gasohol ....................................... Gelatin. ...................................... Gates X - 1 1 X X 1 1 2 1 1 1 1 1 1 1 1 1 1 1 1 1 - 1 - 1 1 1 1 X X X X - 2 - - 2 1 1 X - 1 K 1 2 - K 2 - X X X 1 1 1 Glucose ...................................... ......................................... Glycerine (Glycerol) ........................ Glycol FR Flulds ............................... Grease....................... v I G I Glue z I 277 .................. FR FluId G-ZOO .......................... t Gult FR Flutd P37. P40. P43. P45. P47 .......... Gulf 1 1 1 - 1 1 1 1 H Heptachlor (m Petroleum) ...................... Heptane ....................................... Hexane .................................... Houghto-Safe 271.416 ......................... 520 526. 616. 620 625 640 2 2 2 - Houghto-Safe 5046. 5046W ................... Hy-Chock 011 ................................ Hydra Fluld. AZR (L 0. A. 0. AA. C ............. Hydra FluId 760 ............................... HydraSol A .................................... - Hydraultc Hydraulic Hydraulic Hydraulic Hydraulic Flwd FluId Flwd FluId Flutd HF-31 ......................... HF-16. HF-20 ................... (Std Petroleum). ............... (Phosphate Ester) .............. (Waler Glycol) ................. Hydra&c FluId (Texaco Safely 200. 300). Hydraulic 011s (Shell) .......................... Hydrazme ..................................... Hydrobromlc Acid ............................. Hydrochloric Acld ............................. ....... Chloride ............................ Fluoride ............................. Peroxide (lo”). ...................... Peroxide (Over 10%). ............ Sulhde .............................. Hydrolubric 011(Houghton) ............ Hydrolube (Water Glycol) ....................... Hypochlorous Acid ..... _. _. .................... 1 - 1 - 2 1 - 2 1 - 2 1 - 2 1 1 1 : 2 2 - - 1 1 - : 1 - 1 1 2 2 2 1 1 2 - - 2 2 2 1 : - - - Use Chemical Hoses Use Chermcal Hoses Hydrocyamc Acld ............................. Hydro-drme 011.. ............................. Hydrofluoric Acid ........ __.................... Hydrofluosllicx Acld ........................... Hydrogen .................................... Hydrogen Hydrogen Hydrogen Hydrogen Hydrogen 1 -- Use Chemical Hoses 2 2 1 I 1 - 2 Use Chemical Hoses Use Chemical Hoses Contact Gates - - 1 2 Use Chemical Hoses 1 I Use Chemical Hoses Contact Gates _. .. 2 2 1 1 - x 1 - - - ._... _.. I Imd. Imd 5150. 5220.5300. 5500 ................ lnduatron ..................................... .._ ................... Ink. Printers.. ............ lnrulating Oil, Transformer ...................... 1 1 1 1 1 1 1 1 Use LPG Hoaea Only IklIne .......................................... Iodine. in Alcohol ............................... lrut Fluid 902 .................................. , .. ., ........ lrusFluid BOS ...................... lrobutane.. ................................... aobutyl Alcohol ................................ ..__....._ ................... soOctane.. ...... __. .................. a0 Ropyl Acetate ......... so Ropyl Alcohol (Iroproprnol) ................ moPropylEthw ............ ., .................. 2 1 2 2 (continued) 278 Corrosion TABLE 1.70: Resistant VARIOUS Materials Handbook THERMOPLASTIC POLYMERS FOR HOSE STOCKS-GATES RUBBER (continued) HOSE POLYMER TYPES 0 CMEYICAL z I Y I E I U I C I I-Continued _. _. _. I.50Cyanate - _. J X ,e,FuelJP-3................................... let Fuel JP-4 _. X let Fuel JP-5................................... let Fuel JP-6 _. . let Fuel JP-X _.. 2 2 2 X _. _. _. _, .__ .._. ._. . . _. . . _. ( X ._._. 1 X ttar0 Syrup ..................................... t(erosene ....................................... t(etones ........................................ - I (Toluene Of-lsocyanate) I X X t X -- X i X 2 2 - 1 - L L.acquers L acquer X ....................................... L ead. Acetate ................................... Arsenate .................................. Sullate .................................... Telraethyl ................................ Tetramethyl .............................. L me ........................................... L ead L ead L ead L ead. ’ Llubrtcattng 011s 2 1 2 2 - (Orester) M achrne 011 .................................... M agnestum Carbonate .......................... Chlorrde ............................ U agnesturn U agnesrum Hydroxide .......................... 2 1 1 M agneswm NItrate . . . . . . . . . . . . . . .._._. a&3eswm Sulfate ............................. U agnus-Light ................................. ............................... U agnus-Medw'n hl alarhron (Ag. Spray C on C) ................... U ( 1 1 1 : 1 1 1 1 : 1 ,yonn.rsc .................................... *Iamine Varnish .............................. Mcwuric Chloride .............................. Mcwcuric Cyanide ............................... MCwcurous Nitrate .............................. 2 2 - Mercury ........................................ Marcury Slttr .................................. Metallic Soaps .................................. Meaityt Oxide .................................. Mathcne ....................................... 1 1 1 X Methoxychlor &elate UethylAcrylrt. Why1 WhyI (Inaectici6a) . .. . . .. . . . . . . . . . . . . . . . 1 ................................. ................................. Alcohol (h40thW~M) ...................... ............. I X 1 - 1 1 : X - - : - 2 X 1 1 1 Use Chemical Hoses X 1 1 1 - - 1 1 1 1 2 1 1 1 1 2 MImlathion (Ag Spray Dilute). .................... Ml8licAcid ..................................... Ul sngancae Satts ............................... Mlsnganeae Sulfnte ............................. Mcsximut (Hyd. Fluid) ........................... 1 - - 1 M - 1 2 1 2 1 1 2 X ....................... 1 1 1 1 2 1 1 : - : 2 2 - ............................ ; 1 2 1 1 1 2 1 - - L iqutd Soap .................................... 011s ................................ Llubrlcatmg I I 1 1 1 2 Bleach .................................... L rme Sulfur ..................................... L mdane (Ag Spray). ........................... L tnseed Cake 011 (Bolled) Use Chemical Hoses - L rme L maeed X X X Solvents ............................... _,.............. L actrc Acld ................... L asso (Ag Spray) ............................... 1 - 1 Use Chemical Hoaea 1 1 1 - 2 2 2 - X 2 1 2 2 2 2 2 - 1 1 1 I 1 1 1 1 1 1 I 2 I 2 _I 2 X 2 (continued) Synthetic TABLE 1.70: VARIOUS THERMOPLASTIC POLYMERS Resins and Polymers FOR HOSE STOCKS-GATES 279 RUBBER (continued) HOSE POLYMER TYPES G CHEMICAL I z I Y E I u I I 0 M-Continued Me!hyl - Methyl Melhyl Methyl Methyl AmIne (60%) ........................... ........................... Amlne (9%) Amy1 Carbmol.. ........................ Bromide ............................... Butyl Ketone (MBK) .................... Methyl Methyl Methyl Methyl Methyl Cellosolve .............................. Chlonde ............................... Ethyl Ketone (MEK) ..................... Formate ................................ lsobutyl Ketone (MIBK)................. X - X 2 X 2 1 - X X Methyl isopropyl Ketone ....................... Methyl Methacrylate ........................... Methyl Salrcylate .............................. Methyl Sulfate. ................................ Methvlene Chlonde............................ X - 2 X - - 1 X Methylene Dlchlonde . . Milk ........................................... MIneral 011 .................................... MIneral Spirits ................................. Mobile Hydrauhc Oils .......................... X 1 1 - - X I I Mobilmet S 122.. . .. .. . . .. . . . Molasses ...................................... Monochlorobenzene ........................... Motor 011s .................................... ................... Munatx Acid (Hydrochlonc) . 2 1 1 1 2 2 X 2 1 1 X 1 X - - X X X - X X X X - X - X - X X 1 1 - X 1 1 - 2 2 1 X 2 1 X 2 2 2 X 2 1 - - 2 - - - - 1 1 2 - 1 - 1 1 X 1 Chemical Hoses U! X - - X 1 1 - - (Mustard....................................... - - 1 X X - - 1 X - X X - I - 2 - - N I Naphtha (Low Aromatic Content) . .. ........ . X / Contact Gates Naphthalene ................................... Natural Gas ................................... Nickel Acetate ................................. Nickel Chloride ................................ Nickel Nitrate ................................. 1 Nickel Salts ................................... Nickel Platmg Solution ......................... ..:. .................... Nxkel Sulfate ......... Nwzotine ....................................... Niter Cake (Sodium Bisulfatel ................... Nitric Acid . . . . . . . 1 1 1 X __. 1 1 ...... ~~ - 2 2 Nyvac20 (WG) 30 (WG) ........................ n-Octane ....................................... Ctctyl Alcohol .................................. Oil (SAE) ...................................... Oil of TurPwttine ............................... Oila. Animal.. .......... ... .... ....... ....... I 1 2 . . . . . . . . . . . . . . . . . . . . . . . .._. Nitrogen Oxide up to 50% . . . . .._. _.._.. - : t 2 2 1 Use Chemical 1 I 1 1 x Use Chemical t X I -4 1 1 ies 1 1 1 X X - 1 - 1 - X X - - ms 1 1 2 2 Use Chemical F les 1 1 - 2 1 1 1 U 2 -f 1 2 2 X - :~ 2 2’ 1 2 x 2 X 2 1 1 1 Chemiul 2 1 1 1 _I X H X 1 2 2 2 2 (continued) 280 Corrosion Resistant Materials Handbook TABLE 1.70: VARIOUS THERMOPLASTIC POLYMERS FOR HOSE STOCKS-GATES RUBBER (contimed) HOSE POLYMER TYPES G CHEMICAL I 2 I Y E I O-Continued OS 45 Hydrauhc Flu&d ......................... (Sd0cate Ester Base) Oxakc Acid .................................... Oxygen ....................................... Ozone ........................................ 1 UseChemcalI - I 0 es 1 - - P Pacemaker Types 15OT. 300T SC0T (Citgo) ................................ Pamt .......................................... Pam1 Solvents (Oil Base). ...................... Pamts (011 Base) .............................. - - Palm 011 ...................................... Palmmc Acid .................................. Paraffm (Petroleum) ........................... Paralormaldehyde ............................. Peanut 011 .................................... X - 1 - Pennant Motor OfIS ............................ Pentachlorophenol m 011. ...................... Pentane ....................................... Perchlortc Acid ................................ Perchloroethylene _. . I Use 20BHB C Use Chemrcal t . es - 2 - - - - Pentasol ...................................... Petroleum 011s ................................. Petroleum 011s (Sour). ................. ._. ...... Pelroleum 011s (Refmed) ........................ Phenol (Carbohc Acid). ......................... 2 2 Use Chemical t Phenolates ..................................... Phorone ....................................... Phosphate Esters (to 150°F) ..................... Phosphate Esters (above 15o’F). ................ Phosphorrc Acid. ............................... 2 Use Chemmal Hoses Photographrc. Developers ....................... Photographrc. Emulsions ....................... Photographic. Fuung Solutrons.................. Phthahc Acrd ................................... PICNICAcid (Water Solution). .................... RneOil........................................ Pmene ......................................... Prperarme Hydrochlonde Solution I - 2 I U I - Use Chemical Hoses - 1 ............... 0-w X Prtch ........................................... Platmg Solution (Chrome) ...................... Polyester Resin ................................. Polyurethane (to 125’F) ......................... Potassium Acetate .............................. Potassium Bromrde............................. Potassium Bmarbonate . . . . . . . . . . . . . . . . . Potassium Potassium Potassium Potassium Potassium Brsulphrte ........................... &ornate ............................. Carbonate ........................... Chlorate ............................ Chromate.. ......................... Potassium Potasrium Potassium Potarsium Potassium Chloride ............................. Cuprocyantde ........................ I I Dichromate.......................... Ferrocyanlde ......................... Fluoride ............................. Potarrium Hydroxide Potassium Hydroxide Potassium Hydroxide 1 1 1 .... ... .I 1 1 2 1 1 - - 1 1 1 1 1 1 2 2 1 1 2 2 1 1 1 1 - 1 (low) ..................... @Mb) ..................... (50%) ..................... Uae Chamial Hoses Use Chamical Hoses .............................. ............................... 1 1 Permanganate ....................... Permanganate (5%) ................. Panuttate. .......................... Phosphate ........................... Sulfate .............................. X X 1 1 Potasswm Iodide Potassium Nttrate Potassium Potassium Potassium Potassium Potassium Use Chemical Hoses 2 (continued) Synthetic TABLE 1.70: VARIOUS THERMOPLASTIC POLYMERS Resins and Polymers FOR HOSE STOCKS-GATES 281 RUBBER (continued) HOSE POLYMER TYPES 0 CHEMICAL 2 I p-continued potassium Sulhde .............................. p0ta~sw-n Sulfite ............................... : potassr~rh Throsullate .......................... ....... Powerlube (Carter) ..................... :Prrmatol A. S. P (Agrrc Spray). .................. : - Purrna Insectrcrcte .................... Puropale RX 011s ............................... Pydraul F-9 ..................................... Pydraul SCIE .................................... Pydraul150 .................................... 1 2 2 - ......... - t I Use 2OBHB Only u! se Chemical Hoses 1 2 u I 1; / z i ‘propaneGas ................................... P,op,onrc Acrd ................................. Propyl Acetate ................................. Propyl Alcohol (PrOpanOl) ...................... Propylene Glycol ............................... I I - 0 I - , , , , 2 - 2 - , 2 2 2 2 , ( ( 2 1 2 1 2 2 2 X X X X X X X X 2 1 X 2 X 2 1 X 2 X 2 2 ; ( X X 1 X - 1 1 ( 2 - X 2 X X 2 - 1 - 2 1 - - Ramrod (Ag Spray) ............................ RandoOrls .................................... Rape Seed 011. ................................. Red 011 (Comm Olerc Acrd). .................... - 1 1 2 1 2 1 1 - Retrned Wax (Petroleum). ...................... Regal 011s (R 6 0). ............................. Rrtchlreld “A” Weed Keller....................... Rosm (Lrghl) ................................... Rubrlene 011s.. ................................. 2 2 2 2 1 1 1 1 1 1 2 1 1 jalrcylrc Acrd ................................... jail Water (Sea Water). ......................... jantosafe W-Gl5. W-G20. W-G30 ............... 1 2 1 1 X X 1 1 jauerkraut ..................................... ;CC 7204 (Strutter) ............................ ievin .......................................... *wage.. ...................................... ;FR Flurd B (Shell) ............................. 2 - Pvdraul Pydraul Pydraul Pydraul Pydraul A-200 _. 260 _, _. _. 312 _.. 540 __. _. 625 _. _. _. _._. _. _. _._. _. _. _. _. _. . _, _. _._. _._. ._. _. .._. Pydraul 10E 23E LT. 30E. 65E ll-SE.. Pydraul. 135.. ._. __. ..__.___. Pyrene (Carbon Telrachlorrde) Pyrethrum...................................... Pyrrdrne (50%). _. _. _. _._. _. _._._. _. _. _. _. Pvrooard 51. 53 55.. .._.___. _. F+ogard 160 230 630 .......................... PyrogardC.0 .................................. Pyronal (Transtormer 011) ....................... R jafetytex 215 ........... S ........................ : 1 2 : - : 2 1 1 1 2 1 1 1 2 1 1 1 - 1 2 - 1 1 1 1 1 : 1 1 1 ................................ odwm Benzoate. .............................. 1 1 1 1 1 1 1 - 2 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 i j ( 2 2 X 1 1 1 1 1 1 1 1 ( > 2 2 - iilwr Nitrate ................................... ikydrol 500 A.1 7OW.. ......................... hap Solutrons ................................. ada Ash (Sodium Carbonate) ................. 0da Water ..................................... odrum Btcarbonate ............................ odrum Brsultate (Nrter Cdke)................... odwmBrsulfrte ................................ ( 2 - - odrum Acetate ( 2 - ;FR Fluid C (Shell) ............................ ihellac ......................................... iiticone Grease ................................. iilicone OrIs ................................... iilw! Cyanide .................................. 2 2 1 ( ( - 2 I 2 2 2 - 2 X 1 1 1 1 1 1 _A : 1 1 2 1 1 1 , continued) 282 Corrosion Resistant Materials Handbook TABLE 1.70: VARIOUS THERMOPLASTIC POLYMERS FOR HOSE STOCKS-GATES RUBBER (continued) HOSE POLYMER TYPES CHEMICAL G S-Continued Sodrum Sodium Sodrum Sodjum ............................ D,ch,o;ate Ferr8cyanrde ......................... Ferrocyanide .......................... Fluorrde (70%). ......................... Hydrosulfrde ........................... Sod!um HydroSUlflle............................ Sodrum Sodiwn Sodrum Sodrum Hydroxrde Hydroxide Hydroxrde Hydroxrde Sodmum I z - (10%). ...................... (40%). ...................... (50% 115°F). ................ (50% 160°F). ................ jodjum HypochlOrlte (20%) ..................... Sodwm HypoSuffate ............................ ..... ._.................. SodlurnMetaphosphate ................................. Sodaurn Ndrate ................................ ................................ Sod#“m!&lflle ................................. Sochum Throsulfate (HPO) ..................... jodrum Trrpolyphosphate (STPP) ............... Soln”s011s ..................................... Solvac1535 G .................................. jodrum Sulfate So&urn !julfde ES Use Chemrcaf 1 2 1 ES 1 1 1 1 - 1 1 1 1 - SlannousChlorrde.............................. 1 1 1 2 1 No 15. 16. 25, 31. 35. 51 ................ ......................................... FR ..................................... Acrd ............................ ........................................ 1 1 1 1 1 joybean DIG.................................... jtannrc Chlorrde. .............................. jtanorl Starch jtaysol jtearrc jtearin jtoddard Solvent ............................... jtrarght Synlheuc OrIs ....................... (phosphate ester. phosphate ester base ) jtyrene (Monomer) ............................ ....... 2 1 __ ................................. T allOil ......................................... IIIOW ......................................... uvrrc Acid (10%) .............................. u (Bituminous) ............................... vOrl......................................... rrlaric Acid.. ................................. dlus Oils ..................................... rnol Oil8 ...................................... *pinwl ...................................... ES es es 1 - X X - 1 1 1 X 1 Use Chemrcal HOSeS 1 1 2 1 julfur Droxrde (Lrqurd). ......................... jullur Dfoxrde (Moist) .......................... _. ., julfur Hexaflounde (Gas) ................ julfur Trroxfde (Dry). .............................. julfurlc Acid ................................... untac WR Oils U Use Chemrcaf k ................. julfamrc Acrd ............... julfate Liquors ................................. jurfur (2OO%F) ................................. julfur Chlorrde ................................. julfur Droxrde (Dry) ............................ ..................... unvisOils (700.6@3.900) uper Hydraulic Oils ........................... 33 Fluid (ConooO) ............................. ynthetic oil (Citgo). ........................... I 1 + + k 1 1 1 1 - t I CheTrcal Chemical Chemrcal Chemrcal 1 1 1 1 Perborate .............................. Peroxrde ............................... Phosphates. ........................... .jrlrcate ................................. Y 2 2 2 Use Use Use Use Sodun Hydrorrde (60%) ....................... Sodtun Hypochlonte (5%) ..................... jodrum jodrum Sodrum jodrum ! - X X 2 1 Use Chemical Hoses 2 2 2 2 . 2 x 2 2 1 2 1 2’ 2 Chemtcal 1 1 1 I 1 1 1 1 sses I a Synthetic TABLE 1.70: VARIOUS THERMOPLASTIC POLYMERS Resins and Polymers FOR HOSE STOCKS-GATES 283 RUBBER (continued) HOSE POLYMER TYPES 0 T-Continued Terresstlc .............................. Telraethyllead (TEL). ................... TefrahydrOfurNl (THF). ................. Tetralm ................................ Th,open................................ Toluene (Toluol).. Toluene Dllsocyanate.. Transformer 011 (Petroleum Type) Transformer 011 (Askarel Types). Transmission FluId (Type A) Trlbutoxyethyl Phosphate.. Trlbutyl Phosphate Trtchloroethylene.. _. . Trlcresyl Phosphate (Skydrol) ‘Tne:banolamine ITEA) . . ._ . . . _.. _. _. . _, _, . . . _. _._. . . . . . . ._ _. _._. ._. Ucon MI ....................................... Ucon Hydrolube Types 15OCP. 2DOCP. 275CP. 3OOCP. 550CP. 900CP. 150DB. 275DB. 150LT. POOLT. 275LT. 300LT. 2OONM. 300NM 2 - : - - 1 2 1 2 - Water Water Water White Wood 1 1 1 c : 1 X .. .. .. .. . .. . ... ... . . . ... . ... ... . . C 1 1 1 X z zenc ........................................... ZmcAcetsle................................... 2 Zinc Chloride Solutions ........................ Zmc Hvdrate ................................... : 1 Zmc Oxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Zinc Sulfate Solutions . . . . . . . . . . . . . . . . . . . . . . . . . : 2 - - X - I - -i- - I I r 2 2 1 - ntact Gate (Distilled) ................................ Glycols ................................. in Oil Emulsions .......................... 6 Bagley No. 2190 Cutting Oil ............. Oil ....................................... I - g X 2 1 1 1 ‘FDA Hoses Rwuired I 2 I Hoses A?(:hemlcal Hcse Water .......................................... Water (Potable) ................................ Water(Brine) ................................... Water (Demineralized) ......................... I I 1 2 2 Vmyl Acetate. .................................. Vmyl Chloride (Monomer). ...................... Vltrea Oils ...................................... (XyW) I Use Chemical 2 - 2 2 1 xykme 2 I Use Chemical Hoses t 2 2 U I X 1 : 2 ... E X - Umon Hydrauhc Tractor Flwd ................... Urea Solubon ................................. I I Use Chemical Hoses 2 2 2 2 2 I v 2 C-2 Flwd ................................ C-P 011 .................................. ATF Dexron ............................. ATF Type F .............................. Hydraulic Oil AW ......................... I I 1 2 2 - Tnpolyphosphate (STPP) ....................... Tung 011 ....................................... Turpentme..................................... Tycol Avalon 50. 51. 60 ......................... Tycol A Turblo 37. 50. 58. 60 .................... Umon Union Unton Union Union 2 I 2 - i I c i Y / : Rubbers and Elastomers TABLE 2.1: ACRYLIC ELASTOMER-AMERICAN CYANAMID CYANACRYL is especially noted for its ability to withstand most lubricating oils at 350°F (176°C). including those sulfur modified lubricants, essential in the performance of hot running modern cars. Other petroleum based oils, such as high and low aniline point lubricating aliphatic hydrocarbons offer opportunities for outstanding performance by CYANACRYL. Resistance to chlorinated hydrocarbons, degreasers, LP gases, fuel oils, animal and vegetable oils and silicate esters is very good. Aromatic hydrocarbons, such as toluol, have some moderate to severe effects but ketones, some alcohols and oxgenated solvents can cause severe swelling. Nonpetroleum based brake fluid, phosphate ester, and diester synthetic lubricants can have a severe effect so CYANACRYL should be tested in these environments before using. CYANACRYL shows “fair” resistance to dilute and concentrated acids and bases. Therefore, caution or a “test first” method is suggested when considering it for this type of application. Fluid Resistance Data for CYANACRYL Room Temo. Fluid Ethyl Acetate Amyl Acetate MEK Varsol Toluene Kerosene Naphtha Acetone Trichlorethylene Perchlorethylene Reference Fuel A Reference Fuel B Reference Fuel C Leaded gasoline Lead free gasoline Water Freon # 12 # 2 Diesel Fuel Silicone Fluids Ethylene glycol Elco # 28 Oil (SAE 140) Texaco TL 3450 (ATF) Wheel Bearing Grease Regular SAE # 20 Oil Premium SAE # 20 Oil Premium 1OW - 30 Oil Premium Outboard Motor ATF - Type A ATF - Type C Hydraulic Fluid Mil O-6081 Hytran Tractor Fluid ATF Chrysler MS4228 Anti-Freeze Lubrizol G L-5 (SAE 140) Jet II Hydrocarbon Fluid NOTE: 118 ; 193 i 110 1.8 !12 0.85; 5.9 I I 1 Ii I 167 3.3 I 45 80 28 332 I Elastomer 7 hrs 1 wk I- (Volume Change, %) 250°F(1210C) 212°F(1000C) 1wk 24 hrs Acrylic 2wks 70 -- lwk I 1 I I I I f I 1 I I I 1 f ;7 to 14 27 I I I 8.0 ’ 21.9 )o to -5.1 I I 1 I I 26 10 12 1 I 1.2 1.2 I I 1.5 1.7 I Oi I I 2.3 2.0 0.5 1 ; 2:; 1 3.0 I I I All values in this tab le i Ire (+) unless ot -1.5 I 13.0 8.6 6.7 ! 28 I 75 1 I 3.0 2.0 Rubbers TABLE 2.2: FLUOROELASTOMER-ELKHART and Elastomers 285 RUBBER In many applications, AFLAS outperforms other elastomers because of the following characteristics: (1) High temperature resistance (400°F long term; 55O+‘F shorter term); (2) Resistance to a wide range of chemicals (including acids, bases, steam, sour (H2S) oil and gas with amine corrosion inhibitors, oils and lubricants, hydraulic fluids of all types, brake fluids, bleaches, oxidizing agents, alcohol, etc.); (3) Durable physical properties; (4) Excellent electrical resistance-Dielectric constant at 60 Hz of 2.5. There are three grades of AFLAS. All provide essentially the same heat and chemical resistance but they differ in molecular weight (which can affect processing and physical properties). AFLAS 150E is the lowest molecularweight, AFLAS 150P is intermediate weight, and AFLAS IOOH is the highest molecular weight. AFLAS 100H is generally recommended for optimal extrusion, gas blistering, and compression set resistance. The following chart provides an indication of the chemical resistance of AFLAS. Since temperature, concentrations, mixtures, and elastomer compound selection can affect performance, this chart provides guidelines only. Unless otherwise noted, the tests were run on a 75 Shore A carbon black filled AFLAS 150P formulation with the following properties: Orlglnal Pro~wtl*r of le.1 Formulation Shon A Hardness Tensile Strength (pal) Elongation @ Break 2500 120% 75 Where available, the chart shows the change in hardness (in Shore A points) and volume as well as the percentage of original tensile strength and elongation retained after immersion in the test fluid under the time and temperature conditions denoted. In other instances, volume change only is shown. MEDIA RESISTANCE OUIDELINES Amlnes ................................................. G to E 011s and Lubricants (Incl. synthetics. SF CD, etc.) .................................. G to E OXidlZlnQAQenlS ................................. G to E Sour (H2S) 011 and Gas with Conoslon lnhlbltors .................... G to E Benzene, Xylene, etc. .......................... F to G Fuels ..................................................... F to G Ketones ........................................................ F Chloroform ................................................... P E Animal and VeQetable Oils ......................... E Bases ............................................................ E Brake Fluids ................................................. E Hydraulic Flulds (lncl. phosphate esters, Mil-H-5806, water/Qlycol, etc.) ........ E BteamrWaterlBrine ...................................... E Radiation ...................................................... E WeatherlnQ/Ozone ....................................... E Alcohol ................................................. G to E Adds ............................................................. E. Excellent T Property Retention After Test Test Condition CHEMICAL G. Good F - Falr P - Poor CHEMICAL Property Retention After Test Test Condition rime lays AcetIc Acid Acetrc acrd/lO% Sodium chlonte Acetone Acetyl acetone Aeroshell Grease 67’ Amrne Corroston lnhrbrtors (see Oilfield Media) Ammonia (28%) Ammonium (28%) Aniline ASTM Oil I1 73 7 ‘1.0 ASTM Oil 13 212 73 73 176 1 !4.0 7 3 2 io.0 Benzene Benzene/Methanol i4.0 8.0 Bl~;;~n’q, 30/X 501% powder 10% Bromine 158 73 3.2 1 .o hydroxide ;: 158 73 212 350 7 180 3 7 Z 1.0 2.5 3.2 .7 1.8 4.1 Bromine 32%/ Hydrochlonc acid 1B%/Sulfunc acrd 25 % Calcium hypochlorite 10 % Caproic acid Carbon tetrachloride Castro1 325’ 7.9 i3.0 212 350 73 3 3 7 3: 3 212 73 7 7 212 1 6.0 212 73 73 176 7 7 7 2 0 6.8 16.0 6.0 Il.0 12.0 !l.O 89 36 0.0 6.2 (continued) 286 Corrosion TABLE 2.2: Resistant Materials Handbook FLUOROELASTOMER-ELKHART RUBBER (continued) -- 1 Test Condition CHEMICAL Chlorine solution (saturated) Chlorine solution (Sat.), 35% Sodium chlonde 10% Sodium hypochlonte Chloroform Chromrc acid (62%) Chromic acid (46%)/ Sulfurtc acid (25%) Cyclohexane Cyclohexanone Diesel Fuel #2 95 Shore A Compcurw Diethyl ether D~octyl Cebacate Dloxane Dowtherm 209’ Ethyl acetate Ethyl benzene Ethyl benzoate Ethylene Chlorohydrrn Ethylene glycolMlater/ Nalcool 2000’ 50/5C 4 oz. per gallon Exxon Caloria HT43’ Freon TF Fuel B Gasoline Hydrochloric acid (37% Hydrochloric Hydrofluoric acid (20% acid (50% Hydrogen peroxide (30% lsoamyl alcohol Iso-Octane Kerosene KFlHF (111.8) Lacquer thinner Light oil Lithium Bromrde (58%) Lithium chromate Methyl alcohol Methyl cellosolve Methyl chloroform Methyl ether ketone Mil-H-5606 Mil-L-7808 Mobil 1 5W-30’ Mobil Super lOW-40’ n .hexane Naphtha Nitiic acid fuming Nitric acrd (98%) Nitric acid (60%) Property Retentron After Test Test Condition CHEMICAL Property Retention After Test Nitric acid (20%) 212 73 73 2.5 7 7 69 78 -9 90 98 -2 73 73 73 212 302 73 212 350 73 212 73 73 73 73 7 7 7 15 117 -1 ; 1 3 3 3 3 7 7 7 7 75 70 103 121 -18 -5 5.9 12.0 1.7 2.6 13.0 22.0 9.0 29.2 42.0 8.8 20.0 57 0 6.3 88.0 22.0 26.7 0.0 Nitrobenzene OILFIELD MEDIA Amine corrosion inhibitors (mtnerallblack filled compound) 1 % KW44’ in water 10% KW44’ in water 1% NACE A In water Sour gas, wet (35% H2S. 50% CH,, 15% COz. 10 ml Hd)) Sour oil. wet with 5% NICE B corrosion Inhibitor (47.5% ASTM %l oil. 47.5% HzQ, 5% NACE 6: Mixed gas 35% HzS 15% COz. 50% CHI under pressure) Skydrol 500’ Skydrol 5008’ Skydrol 500 84’ 73 I 7I I I I 5fi NOTE Afhs rerrared etastcmenc and dzl not -1 2 150 144 194 -4 -4 ;.i 4 66 86 -3 3.0 350 6 40 111 -15 8.6 176 212 176 2 3 2 9c 212 212 324 14 400 i 77 14.6 14.0 17.2 100 HI 15OP blend comoound 324 500 73 73 73 73 158 158 3: 212 73 73 73 185 73 73 320 392 73 73 73 73 212 212 400 400 73 73 73 73 73 5: 158 14 4 106 50 I 7 7 7 SOIVC 180 3 3 7 180 7 7 7 7 3 7 7 11 11 7 7 7 7 3 3 3 3 7 7 7 I80 30 7 I80 3 100 106 +; 164 -E \flas 15OP 107 -1 57 58 63 112 85 117 -2 -6 +1 105 99 c 94 106 99 111 106 1lC 82 84 111 107 42 126 94 95 44 107 03 +1 +1 -6 -6 1.1 11.0 58.0 25.0 .2 4.5 7.0 7.4 1.5 4.1 -1.1 0.0 19.0 2.0 .4 53.3 5.0 -0.3 -0.3 0.2 1.4 25.0 58.0 12.0 6.0 8.4 10.1 24.0 4.0 19.0 15.0 21.0 0.0 5.1 IO.0 Sodium chloride (35%)/ Sodium hypochlorite (10%) Saturated chlonne solution Sodium chlorite (10%) Sodium hydroxrde 50% 212 212 2:; Sodium hydroxide 20% 2:: Sodium hypochlorite (10 % ) Sour (HzS) gas and oil (See Oilfield Media) Stauffer 7700’ Steam (93 Shore A cmpd) Sulfur dioxide (5%) Sulfuric acid fuming Sulfunc acrd (96%) Sulfunc acid (60%) Sulfunc acrd (20%) l rho -9 -12 +2 -1 1; 5.9 22.0 1.2 1.1 -0.3 2.0 7 too 95 -1 1.0 350 320 392 392 550 104 73 73 73 3 7 80 91 -10 -3 ;z 65 69 76 120 84 97 100 145 84 98 98 99 -3 99 -3 -1 :; 02 99 101 98 104 105 98 87 89 120 117 18.0 4.6 16 1.3 1.6 78 4.2 7.4 0.4 2.3 4.4 0.1 0.4 0.5 04 41.0 95.0 49.0 9.0 1 1 30 0 ;: 4 2 7 180 7 I80 3 2:; : 2:: 73 73 73 300 212 73 ; 7 7 7 3 3 7 /nfot?muo/l was technical literature. above publlshbd 78 93 116 116 104 117 212 2:; Toluene Tnchloroethylene Tnchlorotrlfluoroethane Wagner 218’ brake fluid Water Xylene 69 80 108 101 85 95 obtained from :: -1 .4 -2 fl 1; -8 0 TABLE 2.3: FL”,D FLUOROSILICONE RESISTANCE OF SILASTIC RUBBERS-DOW LS-S3U FLUOROSILICONE lmmersron Condrtrons Nu,ds ASTM Reference Fuel B ASTM Reference Fuel C 10% Methanol/SO% 10% Ethanol,90% _. No-Lead No-Lead 1 1 4 1 1 4 1 1 1 1 1 Gas Gas.. _. ._.... .................... ...................... ASTM NO 1 Oil ASTM No 3 Oil Jet Fuel. JP-l Jet Fuel, JP-6 _. _. day/23 C (73 F) we&f23 C (73 F, weeks/23 C (73 F, day123 C (73 F, week/23 C (73 F) weeks123 C (73 F, day/&flux day123 C (73 F, week/23 C (73 F, day123 C (73 F, week/23 C (73 F, 70 hrdl50 C (302 F) 70 hrs/lSO C (302 F) 70 hrs123 C (73 FI 1 day123 C (;3 F; 1 week123 C (73 F, 70 hrs1135 C (275 F, 70 hrs/150 C (302 F) _. MIL-H-5606 (PO4226). MIL-L-7806F (Brayco 660 G, DI-P-ethylhexyl sebacate with 0.5% phenothwlne Skydrolt 5OOA.. _, _. _. 46 hrs/l50 C (302 F) 70 hrs1121 C (250 F) CORNING FLUID RESISTANCE RUBBER’ Durometer. Pants Change -9 -9 -6 -10 -11 -6 -11 -12 -13 -11 -11 4 -6 -5 -7 -7 -7 -14 TenSlIe srrengm Percent Change 0 -30 -35 -9 -7 -13 -33 -70 -26 -90 -3 -5 - +22 l22 +22 +25 +25 l25 +29 +26 +25 +23 +22 0 +4 +12 +6 +7 +tO +13 - +6 -36 -36 -36 -36 36 -36 -44 -49 -36 -31 -33 - 42 -37 -39 -43 -36 36 -42 57 -57 -IQ 46 -7 tWlJ”Ie s we//, PerCe”f Change Elongation, PWCe”t Change OF SILASTIC LS-70 FLUOROSILICONE RUBBER’ Volume Te”Sh? ImmerS!on Cond!trons Flwds ASTM Reference Fuel B ASTM Reference Fuel C 10% Methanol/SO% 1wb Ethanol/SO% No-Lead No-Lead Jet Fuel. JP-6 Gas Gas.. _. _. Duromefer. POl”lS Change Strength. Percent Change Elongarion. PerCent Change SbVe11. Parren, _ __ Change 1 1 4 1 1 day1123 C 173 F, week/23 C (73 F) weeks/23 C (73 F) day/23 C (73 F, week123 C 173 F) -12 -12 -10 -10 -13 -12 -13 -16 -16 -16 -10 -10 -14 -14 -14 +17 +17 lla 117 -30 4 1 1 1 1 1 1 1 weeks123 C’(73 i) day/Reflux day/23 C (73 F, week/23 C (73 FJ day123 C (73 F, week/23 C (73 F, day123 C (73 F, week123 C (73 F, -15 -10 -19 -17 -16 -15 -5 -4 -20 -29 -42 -41 -37 -35 -4 -2 -19 -33 -33 -19 -19 -14 -0 110 +20 +27 +22 +21 +16 +17 +3 +5 I= ‘Obtained by add,“9 1 0 phr “arox to SILASTIC LS-70 ‘l~~r~~~l~c~ne rubber Slabs 0 075 mch truck were press cured 10 m,~‘?,, (340 F, and post cured 4 hrsQc0 C ,392 F) prmr to testmg C +2a 1.O *Obtam& by addIn phr Varox to SfLASTlC LS-53” fluorosillcone rubber Slabs 0 075 inch tluck were press cured 10 mm,,71 C (340 F) and post cured 4 hrs/2@3 C (392 FJ war to testw +Skydro, IS B rqstered trademark 01 Monsanto lndustrlal Chemu.1 Company FLUlD FLUID RESISTANCE OF SILASTIC LS-SSU FLUORDSILICONE lmmersron Conddrons Fluids ASTM Reference Fuel B ASTM Fuel C Reference 10% Methanol/90% 10% Ethanol/90% No-Lead ND-Lead ASTM NO. 1 Oil ASTM NO 3 Oil .,_., Jet Fuel, JP4 Jet Fuel. JP-6 _. _. 1 1 4 1 1 4 1 1 1 Gas Gas.. _._. ,_. _. _, _. _. _. _. MIL-H-5606 (PO4226). MIL-L-7606G (Stauffer Skydrolt 500A.. Jet 1,. _. _. _. _. day/23 C (73 F, week123 C (73 F, weeks123 C (73 F, day/23 C (73 F, week/23 C (73 F, weeks123 C (73 F, day/Reflux day/23 C (73 F) week/23 C 173 F, 1 day/23 C (73 F) 1 week/23 C (73 F) 70 hrs/150 C (302 F) 70 hrs/l50 C (302 F) 70 h&23 C (73 F, 1 day123 C (73 F) 1 week/23 C (73 F, 70 h&135 C (275 F, 70 hrsIl50 C (302 F, 70 hrs/70 C (1% F, RESISTANCE OF SILASTIC LS-2249U FLUOROSILICONE RUBBER’ RUBBER’ Duromefer, PO!“tS Change -14 -13 -14 -16 -16 -13 -14 -19 -19 -16 -16 +1 -4 -6 -9 -9 -7 -10 -15 TenslIe Sfrengfh. PerCe”f Change -17 -21 -17 -23 -27 -20 -23 -47 49 -37 -37 -3 -27 -25 -6 -13 +5 -25 -22 *Dbta,ned by .,,.,in~ , 0 p,,, “,,ror (0 SILASTIC LS-SW ,,“orosll,co”e rubber Slabs 0 075 I”& (340 F) ,nd port cured 4 hn/2OO C (392 F) prior to test!“9 +Skydrol II a rq,s,ered trademark 01 Monsanto l”d”strlal Chem,cals Compr~ Elo”geflon, PWCL?“f Change -10 -13 -13 -16 -19 -16 -33 -35 -26 -19 -16 -10 -13 -20 a d -10 -25 -7 thick IOre press curti VOlU”l.9 SW/l, Percent Change +16 +20 +20 +22 +22 +22 +27 +2.3 +26 +22 +21 l1 +4 +10 +4 +5 +7 +10 +16 10 ml”/171 C ,“lmerS,O” Condrfrons Flurds ASTM ASTM Reference Reference 10% Methanol/W% 10% Ethanol/SO% ASTM NO 1 Oil ASTM No 3 011 Jet Fuel, JP-4 Jet Fuel. JP-6 Fuel B Fuel C No-Lead No-Lead Gas Gas.. _. _. MIL-H-5= (Unwist J-43) MIL-L-7606 (Turbo 011 NO 15) DI-?-ethylhexyl sebacate wth 0.5% phenoth,az,“e _. Duromefer. POl”lS Change TenSlIe Strength. Percent Change Elongarron. Percent Change Volume SbWll. Percent Change 4-Z .e 1 day123 C (73 F1 1 v&k/23 d (73 k) 4 weeks123 C (73 F, 1 day/23 C (73 F) 1 week/23 C (73 F, 4 weeks123 C (73 F, 1 day/Reflux 1 day/23 C (73 F, 1 week/23 C (73 F, 1 day123 C (73 F) 1 week123 C (73 F, 70 h&l50 C (302 F) 70 hrs/lbO C (302 F, 70 hrs/23 C (73 F, 1 day123 C (73 F, 1 week/23 C (73 F, 70 ha1135 C (275 F) 70 hrz.1177 C (350 F) -17 -15 -16 -16 -16 -15 -16 -23 -20 -16 -17 -1 -62 -10 -6 -9 -6 -19 -29 -29 -29 -33 -40 -37 -53 -63 -54 -54 -45 -0 -26 -9 -6 -6 -11 -60 -19 -19 -19 -20 -20 -20 -41 -37 -24 -30 -20 -2 -22 -0 -0 -7 -11 -22 +t4 +15 +17 +16 +15 ‘20 +26 ‘20 +19 +14 +0 +3 +6 +3 +4 ‘9 +12 46 hrs/l50 -12 -14 -16 ‘6 b w a m $ h s 8 3 3 C (302 F) ‘Ob,a,ned by add,“9 1 0 phr “arox to SILASTIC LS-2249” ‘luoros~lwzonerubber Slabs0075 &“ch thuck were presscured 10 ma”/171 C (340 F, and post cured 4 hrsQc0 c (392 F) pnor to test!“9 +Unws IS B reg,stered trademark of Humble 011and R&m”9 Company (continued) h> 2 TABLE 2.3: FLUOROSILICONE FLUID RESISTANCE OF SILASTIC LS-2311U RUBBERS-DOW FLUOROSILICONE Duromerer, FluIds ASTM Reference Fuel B ASTM Reference Fuel C 10% Methanol/W% _. No-Lead Gas 10% Ethanol/SO% No-Lead Gas.. _. _._. ...................... ASTM NO. 1 011 ASTM NO 3 011 Jet Fuel. JP4 Jet Fuel. JP-6 ...................... _. MIL-H-5606 (Un,v,s+ J43) MIL-H-7606 (Turbo Oil No. 15) DI-P-ethylhexyl SebaCBte wth 0.5% phenothoazlne Skydrol” SOOA _. CORNING (continued) FLUID RESISTANCE RUBBER’ TenslIe svengm Percent Change Elongation. PBICB”f Change Volume SWII, Percent Change Immersmn Co”dr,ro”S POl”lS Change 1 day123 C (73 Fl 1 we&23 d (73 F) 4 weeku’23 C (73 F) 1 day123 C (73 F) 1 week/23 C (73 F) 4 weekJ/23 C (73 F) 1 day/Reflux 1 d&23 C (73 F) 1 weeW23 C (73 F) 1 day123 C (73 F) 1 we&V23 C (73 F) 70 h&l50 C (302 F) 70 hrdl50 C (302 F) 70 h&23 C (73 F) 1 dav123 C 173 F) 1 we&/23 d (73 F) 70 hn/l37 C (275 F) 70 hrs/l77 C (350 F) -12 -11 -9 -12 -13 -10 -15 -15 -17 -12 -13 -2 -2 -10 -4 -7 -5 -6 -14 -14 -16 -15 -17 -15 -15 -40 -45 -31 -29 +2 +5 -10 -10 -13 +10 -9 -7 -14 -21 -7 -0 -14 -7 -29 -29 -0 -0 -6 -17 -17 +7 +7 -17 -17 +14 l14 114 +17 +17 +17 +20 ‘20 +20 +16 +17 +1 +3 +7 +2 +3 +7 +7 46 hrs’l50 70 hrsIl21 -5 -39 +4 -74 -6 -17 +6 17 C (302 F) C (250 F) ‘Obtmmd by add,“9 1 0 ph, “arox 10 SILASTIC LS-2311” ,,“~r~s~l~c~“e rubber Slabs 0 075 mch thick were press cured 10 rnI”l171 C (340 F) and post CURCI4 hW?w c (392 F) pnclr to teStIn +Unw~r I) a repwwd trademark ot Humble 011and Refmmg Company “Skydrol 1sa rsp~rteredtrademark 01 Monsanto lndusinal Chemicals Company FLUID RESISTANCE OF SILASTIC LS-2323 FLUOROSILICONE lmmersron Cond!tions Fluids _. ASTM Reference Fuel B ASTM Reference Fuel C 10% Methanol/SO% No-Lead Gas 10% Ethanol/QO% No-Lead Gas.. _. _,_. _. _. _. ASTM NO 1 011 ASTM NO 3 011 Jet Fuel, JP-4 _........_...._.._.... Jet Fuel. JP-6 _. MIL-H-5606 (Univist J-43) _MIL-H-7606 (Turbo 011 No. 15) Dt-P-ethylhexyl sebacate wth 0.5% phenothlazme Skydrol” 5WA.. ._ .. _. 1day123 C (73 F) 1 week123 C (73 F) 4 weeks123 C (73 F) 1 day/23 C (73 F) 1 week/23 C (73 F) 4 weeks/23 C (73 F) 1 daylReflux 1 day/23 C (73 F) 1 week/23 C (73 F) 1 day/23 C (73 F) 1 week/23 C (73 F) 70 h&l50 C (302 F) 70 hrsllS0 C (302 F) 70 hrs123 C (73 F) 1 day/23 C (73 F) 1 week/23 C (73 F) 70 hrs/135 C (275 F) 70 hrs1177 C (350 F) Te”Slle Strength. Percenl Chanoe -14 -14 -16 -15 -17 -15 -15 -40 -45 -31 -29 +2 +5 -10 -10 -13 +10 -9 ElO”Wfl0”. percent Chanoe -7 -14 -21 -7 Volume Swell. Percent Change +14 +14 +14 117 +17 +17 +20 +20 ‘20 +I6 +17 +I +3 +7 +2 +3 +7 +7 Fluds ASTM Reference Fuel B ASTM Reletence Fuel C 10% Methanol/QO% No-Lead Gas 10% Ethanol/W% No-Lead Gas ASTMNo 1011 ASTM No 3 011 Jet Fuel. JP-t Jet Fuel. JP-6 _. ._ _._. _. _. MIL-H-5606 (Unwist J-43) MIL-L-7606 (Turbo 011 NO 15) CV-2-ethylhexyl sebacate wth 0.5% phenothiazme C (302 F) C (250 F) +6 +7 FLUOROSILICONE _. RUBBER’ Duromerer. Pomts Change Te”S,le Svenglh PerCe”f Change Elongarro”. percent Change Volume SbVe,, P.YCe”t Change 1 day’23 C (73 F) 1 week123 C (73 F) 4 weeks/23 C (73 F) 1 day123 C (73 F) 1 week’23 C (73 F) 4 weeks/23 C (73 F) 1 day:Reflux 1 day/23 C (73 F) 1 weeW23 C (73 F) 1 day/23 C (73 F) 1 week/23 C (73 F) 70hrs/l50C(302F) 70 h&l50 C 1302 F1 70 h&23 C (73 F) 1 day/23 C (73 F) 1 week/23 C (73 F) 70 h&57 C (135 F) 70 hrsI150 C (302 F) -19 -19 -16 -21 -20 -20 -22 -23 -26 -21 -21 -0 a -6 -6 -11 4 -12 -3 -2 -1 -3 4 -4 -33 -27 -29 -10 -10 _ -2 -2 -6 -2 d -2 -22 -11 -3 -2 -5 _ - -0 -2 - l5 +3 _ 110 ‘3 l4 +a +6 46 h&150 -1 - - +Q C (302 F) +17 +17 +17 +19 +16 ‘16 +25 +21 +20 +17 +16 +0 +4 ‘Obtafned by addq t 0 phr “a,“.. to SILASTIC LS-2332” ‘l”~r~~~i~c~nerubber Slabs 0 075 mch thxk were press cured IO mm/l71 C ,340 F) and post cured 4 hrsr200 C (392 F) prior to tesl,nQ +“nws IS a regfrtered traclemark01 Humble 011and R&“l”Q Company OF SILASTIC Flurds ASTM Reference Fuel B ASTM Reference Fuel C 10% Melha”ol/QO% 10% Ethanol/O% No-Lead Gas No-Lead Gas.. ASTM NO 1 011 ASTM NO 3 011 Jet Fuel, JP4 Jet Fuel, JP-9 _. _. _. _. _. _. MIL-“-5606 (P04226) MIL-L-7606G (Stauffer Jet 1). MIL-L-23699 (Mobil Jet II) ATF-Dextron (AMOCO). Crude Oil API 315 * Otame* LS-23SOU FLUOROSILICONE ,mr”erSiO” Condlbons _. 46 hrsfl50 70 h&l21 LS-2332U lmmersmn Co”d,ho”s FLUID RESISTANCE BASE Duromeler. Points Chanoe OF SILASTIC RUBBER’ Duometer. POi”fS Chanoe 1 day123 C (73 F) 1 week123 C (73 F) 4 weeks123 C (73 F) 1 day123 C (73 F) 1 week/23 C (73 F) 4 weeks/23 C (73 F) 1 day/Reflux 1 day/23 C (73 F) 1 week123 C (73 F) 1 day123 C (73 F) 1 week/23 C (73 F) 70 hrs/l50 C (302 F) 70 hrs/l50 C (302 F) 70 hrs/23 C (73 F) 1 day/23 C (73 F) 1 week/23 C (73 F) 70 h&150 C (302 F) 70 hrs/l50 C (302 F) 70 hrs/150 C (302 F) 70 h&150 C (302 F) 70 hrsi135 C (275 F) -11 -10 -9 -11 -11 -10 -12 -14 -15 -11 -10 +1 -1 -7 -6 -6 -7 -6 -9 +1 4 Te”S!le SWenglh. percent Chanoe -16 -16 -14 -23 -22 -16 -26 46 -59 -37 -37 -1 -16 -14 +2 +1 -16 -29 -39 4 -26 Elongation, percent Chanoe -16 -16 -24 -24 -16 -24 -29 -41 41 -16 -16 +I6 -13 -9 -6 -0 -17 -25 -29 -21 -29 Volume .%e/i. Percent C.k3noe +15 +15 +14 +17 rlR +17 +21 +21 +19 +12 +15 +I +4 l7 +3 I? +I3 +a ‘9 +I +6 _. 10phr“arortoSlLASTlC LS-2380” fl”OrO*lllCO”e rubber Slabs 0075-4”ch-thlck wsre press Cured by a&j,np F) and post cured 4 hrs 200 C (392 F) prior to test,“9 10m,nilllC(2~0 (continued) 3 a 3 2 _. x s 5 s G’ > x 3 g 8 h TABLE 2.3: FLUOROSlLiCONE FL”,DRESISTANCE OF SILASTIC RUBBERS-DOW Ls-2640 FLUOROSILICONE CORNING (continued) RESISTANCE RUBBER’ OF SILASTIC *125lJ SILICONE RUBBER TO IMMERSION IN SOLVENTS Tensde Change Ekmgabon, P6XY?nf Change -13 -13 -13 -13 -19 -14 -14 -13 -12 +1 0 -6 -5 -13 -19 -40 -40 -43 -42 -57 -53 -50 -42 -36 -7 -27 -20 -16 -64 -55 -27 -23 -26 -27 -39 -29 -27 -21 -17 - 13 -22 -6 -11 -62 -23 POlfll -Floids ASTM Reference Fuel B ASTM Relerence Fuel C 10% MethanolM% 10% E!hanol90% No-Lead Gas No-Lead Gas .................... .................. ................... ............. ...... .................... ASTM No. 1 oil ASTM NO. 3 011 Fuel. JP-4 MIL-H-5606 (PO-4226). ML-L-76M)G (Slaulfer Jet 1). Skydrol*’ 500A. Jet 1 day’23 C 173 F) , weeW23 C (73 FI 1 day/23 C (73 F) 1 weeW23 C (73 F) 1 day:Reflux 1 day/23 C (73 F) 1 week/23 C (73 F) 1 day/23 C (73 F) 1 week/23 C (73 F) 70 hrs/l50 C (302 F) 70 hrs’l50 C (302 F) 70 hrsi23 C (73 F) 70 hrsil50 C (302 F) 70 hrsIl5C C (302 F) 70 h&i70 C (156 F) FOODS’ Prop&lest Strength, Percent Change Durometer, AND LIQUID SWdl, PWX?lll m +16 + 16 +20 +21 +26 +19 +22 +16 +17 +1 +3 +11 +9 +6 +23 Immersmn Llqwd Test Condrtions Water Detergent. 3% m water. Steari ___....._....,..__.,_.... coffee ................. ......................... ....................... ..................... Vegetable 011.. Lard. Whiskey Cola Syrup Vinegar ........................ Durorneter Hardness, Shore A-2, pornts change TBnSlle Strength. percent change Elongation, percent change Volume. percent change 14 days/l00 C (212 F) 14 days/62 C (160 F) 3 days/20psi 7 dew/62 C il60 FI +3 t2 +5 +3 +a +2 -4 I-III +7 -9 -9 -2 l1 -1 nil +2 7 da&l50 7 days/150 14 days/23 14 days/23 7 days123 +2 +2 -2 -1 -1 -24 -29 +6 -10 -3 -35 -41 +10 -6 -2 +1 +1 +1 nil nil C’(302 ;) C (302 F) C (73 F) C (73 F) C (73 F) 10w.Rs Cadox TSSO per1Wharts rubber b”wm,h,. wess ‘~cm-rens ““lcanued wth molded onto0.075-m’-,h,ck ASTM slabs (1 Slmm) tar 5 mmuter/llS C (240 F), and oven cured for 4 houroi200 k (392 F) torlgmal !&WI duromster hardness - 54 pomts. twslle rtrsngti- - 1200 p.¶c,slongatlo” - 580 percant 290 Corrosion Resistant Materials Handbook TABLE 2.4: POLYSULFIDE RUBBER-MORTON THIOKOL ST polysulfide rubber is a millable gum elastomer prepared from bis (2chloroethyl) formal and sodium polysulfide. Vulcanizates exhibit outstanding resistance to a broac’ spectrum of oils and solvents, to gas permeability, low temperature, ozone and weathering. Typical uses include gas meter diaphragms, rollers, printing blankets, o-rings, and many specialty molded items. All of the solvent Immersion tests were run with the following Ingredients ST polysulfide Stearic acid recipe: Parts by weight rubber 100 1 Sterling S Zinc peroxide Calcium hydroxide 60 5 1 167 Cure 30 minutes at 310°F SOLVENT RESISTANCE AT ELEVATED Volume 1 week Solvent Xylene Iso-octane Butyl acetate Methyl isobutyl ketone Water RESISTANCE Tensile, psi Elongation, 96 TO WATER 45 6 46 37 21 140°F Swell, % 1 month 58 6 46 67 41 (DISTILLED AND SALT) Original Properties Distilled Water 4% NaCl Water Distilled Water 4% NaCl Water 1090 1065 1100 665 1050 215 215 215 150 215 73 71 72 67 70 2 1 12 2 Hardness, Shore A Volume Swell, % TEMPERATURE, - Immersed 14 days at 80°F Immersed 14 days at 158°F (continued) Rubbers TABLE 2.4: POLYSULFIDE RUBBER-MORTON THIOKOL and Elastomers 291 (continued) SOLVENT RESISTANCE (30-Day Immersion at 80°F - ASTM-D471-66, Method B) SOLVENT VOLUME INCREASE, CONDITION Aliphatic and Aromatic Hydrocarbons Mineral oil Benzene Toluene Xylene -2 110 70 41 OK Tender Swollen but OK OK Halogenated Hydrocarbons Carbon tetrachloride Ethylene dichloride Trichloroethylene Perchlorethylene Dowtherm A Monochlorobenzene 46 230 159 28 127 161 OK Very tender Tender OK Tender Tender Aliphatic and Aromatic Fuels, Oils and Solvents SR-6 (60% diisobutylene, 40% aromatics) SR-10 (diisobutylene) ASTM Reference Fuel Afa) ASTM Reference Fuel Bfb’ 73 octane gasoline 100 octane gasoline ASTM oil No. 1 ASTM oil No. 3 Turpentine Motor oil (Esso) Circa light process oil Diesel oil Circosol 2XH Paint thinner (Duco) Drip oil Gulf motor oil Pydraul F-9 Skydrol Sovaloid C Sovaloid N Sundex 53 Tetrahydrofuran JP-3 JP-4 Houghto-Safe No. 271 14 1 2 10 3 2 -4 -2 4 0 -2 3 -2 23 62 -3 37 24 30 2 -1 175 -2 1 2 OK OK OK OK OK OK OK OK OK OK OK OK OK OK Slightly tender OK OK OK OK OK OK Very tender OK OK OK Organic Acids 10% acetic acid 50% acetic acid Glacial acetic acid Cresylic acid 9 26 18 123 OK OK OK Tender 37 35 24 OK OK OK Ketones Acetone Methyl ethyl ketone Methyl isobutyl ketone la7 Reference Fuel A has the same composition fbl Reference Fuel 8 has the same composibon SOLVENT % VOLUME INCREASE, CONDITION % Esters Ethyl.acetate Butyl acetate Tributoxy ethyl phosphate Dibutyl phthalate Plasticizer SC TP-SOB” Plasticizer TP-95@ Plasticizer Dibutyl sebacate Dioctyl phthalate Flexol 3 G 0 Tricresyl phosphate Adipol BCA 35 30 4 10 6 12 28 2 -2 1 7 20 OK OK OK OK OK OK OK OK OK OK OK OK Ethers “Cellosolve” Solvent Bun/l “Cellosolve” Dibenzyl ether Butyl “Carbitol” 14 11 30 13 OK OK Very tender OK Vegetable and Wood Oils Linseed oil Cottonseed oil Castor oil Corn oil White pine oil Crude soya bean oil -2 -2 -3 -4 14 4 OK OK OK OK OK OK Hydroxy Compounds Ethyl alcohol (denatured) Butyl alcohol Isopropyl alcohol Diacetone alcohol Prestone Methyl alcohol Ethylene glycol Gasohol Glycerine P-ethyl hexanol 2 2 0 18 3 6 0 5 1 1 OK OK OK OK OK OK OK OK OK OK Inorganic Compounds 10% Sulfuric acid 20% Sulfuric acid 50% Sulfuric acid 100% Sulfuric acid 10% Nitric acid 50% Nitric acid 10% Hydrochloric acid 50% Hydrochloric acid 100% Hydrochloric acid 10% Sodium hydroxide 20% Sodium hydroxide 3% Sodium chluide sdution 10% Sodium chloride 10% Copper sulfate 10% Zinc chloride Water 2 -2 3 3 _ 2 2 3 3 5 2 5 OK Slightly soft Deteriorated 2 wks Deteriorated 1 day Deteriorated 2 wks Deteriorated 1 day OK Tender Deteriorated 1 day OK OK OK OK OK OK OK - as Type I te?sffluid in Mil-H-3136 119501, i.e., fuel is 100% iso-octane. as Type III msf fluid in MY-H-3136 11950). i.e.. fuel is 70% iso-octane, 30% toluene (by volume/. (continued) 292 Corrosion Resistant Materials Handbook TABLE 2.4: POLYSULFIDE RUBBER-MORTON THIOKOL (continued) EFFECTOFHALOGENATEDHYDROCARBONS VS OriginalPhysical Properties Dichloromethane 1 week 1 month T M E H - 1100 950 240 70 285 260 1180 930 240 72 1200 910 290 71 328 1110 1100 820 620 270 320 84 63 VS 307 1.1.2.2.Tetrachloroethane 1 week 1 month 950 240 70 153 156 1210 1290 920 960 270 290 69 70 1 week 34 1180 920 250 68 1 month 32 1085 850 250 68 25 26 990 1040 820 1000 230 230 67 68 306 - 800 840 570 360 300 400 53 54 1 week 1 month Decomposed 1.2.3.Trichloropropane 318 1160 1200 810 850 280 280 68 65 1020 1000 950 740 220 250 64 64 240 1100 1140 800 810 250 260 67 65 285 410 - 120 67 1 week 135 300 295 730 - 200 69 1 month 146 600 340 N.A. 1030 1010 800 750 260 280 64 61 32 32 1050 1110 900 1000 320 1 week 1 month Chlorobenzene 54 54 1 week 159 1200 1000 250 70 1 month 164 1150 950 280 67 1 week 159 1100 880 250 67 1 month 166 950 750 250 58 - 160 48 - 180 50 250 235 70 70 1.2.Dichlorobenzene 235 1,1,2-Trichloroethane 1 week 1 month 1100 2-Chloropropane Decomposed 1.2.Dichloroethane 1 week 1 month - Proparties 1 week 1 month Tetrachloromethane 1 week 1 month H Tetrachloroethylene 1 month 1 month E Trichloroethylene Diiodomethane 1 week Trichloromethane 1 week M OriginalPhysical Dibromomethane 1 week 1 month T 1.2.4.Trichlorobenzene 1-Chlorobutane Pentachloroethane 1 week 1 month 1 week 1 month Decomposed Decomposed VS- volume swell T- tensile strength, psi E- Elongation, % H- Hardness, Shore A M- 200% modulus, PSI N.A.- not available RESISTANCE TO KEROSENE AND BUNKER C FUEL OIL Original Properties Immersed 1 weak at 80°F Kerosene Bunker C Immersed 1 weak at 158°F Kerosene Bunker C 100% Modulus, psi 420 420 420 260 410 200% Modulus, psi 890 860 880 590 870 1200 1140 1180 790 1120 280 270 270 260 260 72 71 69 67 69 Tensile, psi Elongation, % Hardness, Shore A Volume Swell, % - 1.2 4.0 4.0 4.8 Rubbers TABLE 2.5: STDNLAST POLYSULFIDE SYNTHETIC is a heavy-duty, ing materials currently flexibility allows those properties the RUBBER and Elastomers 293 SEALANT-STONHARD two-component synthetic rubber sealant. It adheres tenaciously to just about all buildby exposure to water or most corrosive gases. STONLAST’s great and contract to compensate for movement, vibration, etc., and it retains in use, and is unaffected material to expand over a wide range of temperatures (-65O to +215’F). The purpose of this “guide” is to aid in determining the potential to the damaging effects of erosive chemical spillages. value of Stonlast sealant when exposed The test procedure used was to totally immerse cured samples of Stonlast in the chemrcals listed for a period of 30 days at normal room temperature per ASTM 0471.62T. Method B. (This is an exceptionally severe test, since n-lost areas subject to chemical spillages such as these are “flushed down” periodically with water as part of the normal maintenance operation ) The resultant resistance of Stonlast to the various chemicals (It is assumed that normal “good housekeeping procedures” with clean water.) RATING is related are used, CODE E - Excellent F - Fatr G - Good NR - Not Recommended The (number) which appears next to each rattng IS the percent ALKALIES ACIDS E (1 %) E (6%) NR NR NR Hydrochloric - 10%. Hydrochloric - 30%. Hydrochloric - 37%. Nitric - 10% Nitric - 50% Sulfuric - 10% Sulfuric - 20%. Sulfuric - 50%. Sulfuric - 100%. Hydrocarbons) Benzene. Toluene. Xylene. NR (314%) NR (138%) G ( 61%) (Halogenated Hydrocarbons) Carbon Tetrachloride. Ethylene Dichloride. Monochlorobenzene. Perchloroethylene. Trichloroethylene. (Hydroxy F ( 78%) NR (605%) NR (474%) E ( 43%) NR (401%) Copper Copper Sodium Sodium Sodium Sodium Sodium Sodrum E (1%) .E (1%) NR NR SOLVENTS (Aromatic AND OTHER (Aliphatic and Aromatic Oils and Solvent) ASTM Oil No. 1 ASTM Oil No. 2 ASTM Reference ASTM Reference JP-5.. Motor Oil. Skydroltv. SR-6. SR-10. Turpentine. AND (Esters E E E E E E (-2%) (10%) E E E E E E : : : : : ::G E E E ( ( ( ( ( ( 2%) 1%) 4%) 1%) 2%) 3%) (Ketones ( 1%) (12%) (-1%) (12%) ( 2%) (-1%) (59%) (21%) (11%) (11%) and Ethers) Acetone. Butyl “Carbitol”‘M. Butyl “Cellosolve”‘~. Dibutyl Ether Ethyl “Cellosolve’? Methyl Ethyl Ketone. Methyl lsobutyl Ketone SALTS E (3%) E (5%) E E E E E (1%) (1%) (1%) (0%) (1%) E (1%) and Plasticizers) Butyl Acetate Butyl “Cellosolve”‘” Adipate Dibutyl Phthalate Dibutyl Sebacate Dioctyl Adipate Dioctyl Phthalate Ethyl Acetate Propylene Glycol Ricinoleate TP-SOB’” Plasticizer TP-95’% Plasticizer Tributoxy Ethyl Phosphate (Vegetable E E swell. CHEMICALS Fuels, : Fuel A Fuel B volume Sulfate - 10% Sulfate - 14% Chloride 3% Chloride - 10% Chloride - 36% Hydroxrde - 10% Hydroxtde - 20% Hydroxide - 50% Compounds) Butyl Alcohol. Diacetone Alcohol Ethyl Alcohol (denatured). 2-Ethyl Hexanol Ethylene Glycol Glycerol Isopropyl Alcohol Methyl Alcohol. using the symbols listed below. includtng a daily flushing down Castor G .E ( 50%) ( 19%) ( 8%) E NR (605%) E ( 28%) F ( 87%) E ( 36%) and Wood ( 48%) ( 36%) G E ( 55%) ( 8%) E ( 0%) ( 33%) : :E G E ( 64%) ( 5%) ( 26%) G E ( 51%) ( 17%) E ( -2%) :E Oils) Oil Corn Oil. Cottonseed Gil: Linseed Oil Soya Bean Oil.. White Pine Oil. G E : ::: ::::: E E E E E (4%) ( -3%) ( 0%) ( 0%) ( 17%) 294 Corrosion TABLE 2.6: Resistant SILICONE CORROSION Materials ELASTOMER Handbook LININGS-HURON RESISTANCE DATA FOR SlLlGL4S~ Concentration CHEMICALS LTD LININGS* Temperature Conditions [“Cl Test Duration Pwl Corrosive Effect Noted Acids Hydrochloric (HCl] Acid 200 68 30 % 200 28 40 Nitric Acid (HN031 7% 25% 50% Reagent Grade 200 200 200 28 68 40 40 40 Sulphuric (H2504I 10% 50% 50% 50% 200 200 600 85O 5% Acid Phosphoric Acid 1.2% 1.2% 90-1000 .4 mils/yr loss .04% weight gain 24 mils/yr loss .2 1.3 10 4.4 mils/yr mils/yr mils/yr mils/yr loss loss loss loss 68 30 45 24 1 mil/yr 2 mils/yr 18 mils/yr 15 mils/yr loss loss loss loss 85O 48 Smils/yr loss 10% Reagent Grade 85O 60~ 48 45 4% weight gain 1.18% weight gain 50% 85O 48 (H2PO3) Bases Ammonium Hydroxide (NH4W Potassium (KOH] Hydroxide Sodium Hydroxide ( NaOH) 10% 10% 20% 30% 50% 200 90-1000 6oQ RT” RT” 42 28 45 40 42 33 mils/yr 1.4 11.6 15 5 mils/yr mils/yr mils/yr mils/yr 17 mils/yr loss loss loss loss loss loss (continued) Rubbers and Elastomers TABLE 2.6: SILICONE ELASTOMER LININGS-HURON Concentration 295 CHEMICALS LTD (continued) Temperature Conditions [“Cl [Days1 Corrosive Effect Noted 30 10 mils/yr loss Test Duration Salt Solutions Potassium Chloride (KC11 Sodium Chloride ( NaCL) 100 gpl 65O 30 gpl 68 1 mil/yr loss .I% weight gain 9Czo 200 90-1000 z 40 900 700+ 85O 48 Hypotower Simulation (No over-chlorination) pH- 14+ 10 20-500 147 Hypotower Simulation (50 over-chlorinations) pH- 14+ 5 2@800 70 200 600 42 45 30 gpl 300 gpl 300 gpl .5 mil/yr loss .I&% weight gain Oxidizing Environments Electrolytic Sodium Chlorate Production Cell NaCI, 50-250 gpl NaC103, lOO-600 gpl NaOCI, 1.5-2.Ogpl pH=7 4 mils/yr loss Hydrogen Peroxide 5% (H202) Sodium Hypochlorite (NaOCI-6%) pH 13 NOTE: lmil= .OOl inches. * SiIigIas lining material is a silicone elastomer on a glass fiber backing. .2% weight gain 2 mils/yr 7 mi Is/yr 2 mi Is/yr 7 mi Is/yr 296 TABLE Corrosion 2.7: Resistant Materials Handbook URETHANE-AMERICAN CYANAMID CYANAPRENE A-8 CYANASET M 90% Shore A % V.C.’ . . . . . Acids . . . . . . . Acetic acid 5% Hydrochloric 10% Nitric acid 10% Sulfuric acid 3% Sulfuric acid 30% -3 0 - 6.25 4.9 - -5 -3 3.7 3.3 - -1 0 6.9 0.3 -2 -2 5.7 0.8 . . . . . Alkalies Ammonium hydroxide 10% Detergent heavy duty Sodium carbonate 2% Sodium carbonate 20% Sodium hydroxide 1% Sodium hydroxide 10% Soap solution 1% . . . . . . . . . . . . . . . . . . . 0.75 0 4.2 3.6 0 -1.2 3.4 . . . . . . . . . . . Solvents -4 0 2.5 -0.25 -3 -5 -4 -2 -3 A.: 0:3 -0.4 1.5 . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . -29 -13 -7 - 105.2 76.4 27.5 -15 -3 0 -7 -2 0 . . . . . . . . . . . . . . . . . . . ASTM #I ASTM #3 Heptane lsooctane Kerosine Mineral oil Toluene Transformer . . . .. .. . . . .. . . . . . . . . . . . . . . . . . . -3 -1 +9 +7 -8 -4 -2 Acetone Benzene Carbon tetrachloride Dimethyl formamide Ethyl acetate Ethyl alcohol Methyl alcohol Toluene Turpentine Water CYANAPRENE D-5 CYANASET M 90% Shore A % v.c.* . . . . . . . . . . . . . . . . . . . . . . . . 40.4 17.8 11.4 37.8 3.2 1.4 -20 -11 0 -9 -5 0 -5 -2 -1 67.4 45.25 -0.25 31.4 13.9 14.6 21.3 0.3 1.3 . . . . . . . . . . Oils, Fuels. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0 0 +3 0 -7 +2 oil - - - 1.7 1.7 0.9 0.5 37.8 -0.3 -2 -3 -1 0 -5 0 0.3 1.3 1.0 0.5 21.3 -1.0 . . . . . . . . . . . . . . . . . . . . . . . . . . . . Other Media . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Aniline Ethylene dichloride Hydrogen peroxide 28% Sodium chloride 10% *% volume change. ASTM -38 -30 0 -3 Test Method: ASTM 367.9 109 5.9 -0.04 D-543-60T -35 -14 -3 0 239.5 53.9 3.8 1.3 297 Rubbers and Elastomers TABLE 2.8: URETHANE-DEVCON Devcon FLEXANE is a two-component room-temperature curing urethane for forming abrasion resistant linings, repairing rubber parts or equipment, and forming flexible molds and parts. FLEXANE is available in putty and liquid form in two durometers. A FLEXANE flexibilizer can be used to produce urethane of any desired durometer. Chemical Resistance of Aexane-ImllWSiOn SampleSize:Yz~x% “xl’ Cure:7 Days@ Roomlemperoture Immersion:30 m $g -D Flexone 80 (Llquld &Puny) VG Rezone 94 (Llquld & RQ) VG Aerone High Petiormonce Pully Flexone Brushable Urelhone 1Rexone BIW TABLE 2.9: _a?2 ,Ps ProductNome I l3Y F U U U U U U F u u u u u u V: F F U U U U U U U F U U u u u u 1 VG 1 VG VG VG VG VG U VG 1 ’ VG VG VG VG U U U / VG VG VG U VG VG VG ’ VG VG VG VG / VG U u URETHANE VG I u , VG , VG , MEMBRANE-STERNSON F 1 F 1 F 1 U 1 U 1 U 1 U 1 U 1 LIMITED LIQUATHANE is a high performance elastomeric urethane rubber membrane. Applied as a liquid, LIQUATHANE is designed to protect concrete and steel from corrosive attack as well as exhibiting excellent resistance when used as a waterproofing/liquidproofing or between slab membrane. CHEMICAL RESISTANCE Exposure Acids GUIDELINES Resistance Good resistance to common industrial strength acids (0% to 15%), such as sulphuric. hydrochloric, phoric, lactic, dilute oxidizing agents. Alkalis Good resistance to common industrial phosstrength caustics (0% to 15%), such as sodium hydroxide, many chloride, sulfate and nitrate salts, saturated salt solutions. Fresh Water/ Sea Water Excellent resistance 298 Corrosion Resistant Materials Handbook TABLE 2.10: VARIOUS ELASTOMERS-AMERICAN CYANAMID Test Formulas CYANACRYLO J-c -R CYANACRYL R Polyacrylate CYANACRYL L Polyacrylate c Polyacrylate cuwRn Chgn&um HR 665 vamac B-124 General Elecnic SE-3724 N-550 (FEF) Carbon Black N-990 (MT) Carbon Black Hi-Sil 215 Precipitated Silica Maglite D Hercoflex 600 Dioctyl Sebacate ~araplex G-25 silane A-189 zinc Oxide stearic Acid TE-80 Petrolatrrm Armeen 18-D NPS Red Oil Soap curative c-50 Spider Sulfur CYUFAM@DS Horfax Disk No. 1 DPG Total Parts Imersion 100 124 100 60 55 40 60 15 40 10 5 10 5 2 2 3.5 3.5 0.3 0.3 0.4 3 1 2 2 2 0.5 -160.8 8 0.3 0.3 2 1.2 ‘ 165.8 170.3 179.7 186.7 100.0 in Synthetic Fluids for 168 Hours at 3OO'F CYANACRYL@ -!L L NBR - -EA8 -SI -5 -8 +7 +10 -67 -49 +1 -2 -21 -33 +12 -16 -20 -12 +28 -6 -35 -41 +11 -2 -12 -11 +10 +16 -78 -86 +1 -5 -27 -36 +18 -13 -15 -4 +25 -14 -52 +7 -4 -21 -52 +10 -3 -12 -12 +10 +12 -71 -53 +2 -7 -14 -20 +15 -15 -24 -12 +28 -7 -6 -25 +13 -13 -30 -35 +20 -12 -22 -2 +19 +8 -77 -62 +6 -20 -39 -41 +42 -16 -25 -18 +28 -9 -8 -12 +18 -17 -24 -15 +28 -16 -34 -3 f26 +13 -80 -100 +8 -19 -50 -49 +69 -16 -29 -13 +24 +1 -28 -45 +5 -2 -36 -47 +7 Mobil 1 (LAOO) Hardness Channe. points Tensile Chang;,~%Elongation Change, % Volume Change. X -3 -31 40 +9 Polar Start DN-600 (LAB) Hardness Change, points Tensile Change. X ElongationChange, X Volume Change, X Chenlube (DAE) Eardness Change, points Tensile Chang;. X Elongation Change. X X Ultra E-11 (DAE) Hardness Change, points Tensile Change. X Elongation Change. X Volume Change. x L z 100 Valvoline ESP (Blend) Hardness Change. points Tensile Change, X Elongation Change. X Volme Change. x CYANACRY NBR EAE SI g 100 -R Volume Change. -NBR acrylic elastomer nitrile polymer ethylene acrylic silicone 0 LAO0 LAB DAE 0 I inear alpha olefin oligomer linear alkylated benzene dibasic acid ester Rubbers TABLE 2.11: VARIOUS ELASTOMERS AND RUBBERS-DU Chemical GATlNG KEY A-Flurd B-Flurd C-Flurd and Elastomers PONT Resistance * T-No X-No has kttle or no effect has mmor to moderate effect has severe effect data-kkely to be compatible data-not likely to be compahble VlTW@ chemical Acetaldehyde Acetic acid. 20% Acetic acid. 30% Acetic acrd. glacial Acebc acid. glacial Acetic anhydride Acetone Acetylene Alummum chloride solubons Alummum sulfate solutions Ammoma. anhydrous Ammonium chlonde soluhons Ammomum hydroxrde solutrons Ammonium sulfate solubons Amy1 acetate Amyl alcohol AmIme Anrlme Annme ASTM 011 xl ASTM 011x3 ASTM reference fuel A ASTM reference fuel B ASTM reference fuel C ASTM reference fuel C Asphalt Banum hydroxide solutrons Beer Benzaldehyde Benzene Benzoyl chlonde Borax solutions Borrc acrd solutions Bromme, anhydrous lrqurd Butane Butyl acetate Butyraldehyde Butync acrd Calcium brsulfite solubons Calcium chlonde solutions Calcrum hydroxide solubons Calcium hypochlonte, 5% Calcrum hypochlonte. 20% Carbon btsulfrde Carbon dioxrde Carbon monoxrde Carbon tetrachlonde Castor 011 Chlorme gas, dry Chlonne gas, wet Chloroacehc acid Chlorobenzene Chloroform Chlorosulfonrc acrd Chromtc acrd, lo-50% Citrrc acrd solutrons Copper chloride soluhons Copper sulfate soluhons Cottonseed 011 Creosote 011 Cyclohexane Drbutyl phthalate &ethyl sebacate Droctyl phthalate DOWTHERM A DOWTHERM A Eprchlorohydnn Ethyl acetate Ethyl acetate Ethyl alcohol Ethyl chlonde Ethyl ether 299 A ;: i C C t B (100°F) 1 t E B 0 (2:U’F) 5t A : 1 1 A A (ZO(PF) A (200°F) A (2;VF) c,toBw, - :: B A C ‘;; i A&F) : A (15B”F) A (1WF) A(t$F) - r A A A A L A A A AAB - A B (‘:PF’ Ii B (l&F, B A (ZL, A (200°F) A A : C : B ;:; A (2OODF) A (Z&F, A (2:B’F) x A A T A : ‘;; T A - : A A A : T C 6 X B” A X C : X C A (&F, A A A A ; A A A A-B C x B A (25°F) ! 7 C C f A (4pF) :: : X C X T A (l&F) C C B (&F) A B C A * ,1LF, B A A B (2l;PF) A C C T A A A r T B (t:bF) A (4&V, : x - A (t:B”F) x C - ; A (2:TF) : A A C A A A A (3:1pF) A (212°F) A B B - B c C A A A C A A A A 8-C C : A 8 : c A (2!2’F) A-B B(lWF) C (300°F) A (300°F) A (350°F) A A A B-C X r A(& r 7 (2t;F) r : C B A ; C : B X 7 A A A - A : C A (2:EPF) A (200°F) : A 1;:; :I:% A (15bF) A (15BF) 8 A (200°F) A c c X (15kF) : B A (2:,F) B (4OBF) C (12PF) C 7 A C (continued) 300 Corrosion TABLE 2.11: Resistant VARIOUS Materials Handbook ELASTOMERS AND RUBBERS-DU PONT Chemical Neoprene Ethylene dichlonde Ethylene glycol Ethylene oxide Exxon 2380 turbo oil (lubncant) Ferw chloride solutions Fluos~lw acid formaldehyde, 40% Formaldehyde. 40% Formic acrd FREON*-11 FREON-l 1 FREON-12 FREON-12 FREON-22 FREON-22 FREON-l 13 FREON-113 FREON-1 14 FREON-l 14 Furfural Fyrquel.220 (hydraulic fluld) Gasoline Glue Glycertn n-Hexane Hydrazme Hydrochlow acid, 20% Hydrochloric acid, 20% Hydrochlonc acid, 37% Hydrochloric acid. 37% Hydrochloric acid. 37% Hydrocyanic acid Hydrofluoric acid. 46% Hydrofluonc acid. 75% Hydrofluonc acid. anhydrous Hydrogen Hydrogen peroxtde. 90% Hydrogen peroxrde. 90% Hydrogen sulfide lsooctane Isopropyl alcohol Isopropyl ether JP-4 JP-5 JP-6 JP-6 Kerosene Kerosene Lacquer solvents Lactic acid Lmseed oil Lubrlcabng oils Magnesium chloride solutions Magnesium hydroxide solubons Mercunc chlonde solubons Mercury Methyl alcohol Methyl ethyl ketone Methylene chlonde Mineral oil Mobrl XRM 206A (aircraft eng. lube) Naphtha Naphthalene NWc acid. - 10% Nitnc actd. 30% Nitric acid. 30% Ndnc acid. 60% Ndnc acid. 70% NW acid. 70% NW acid. red fummg Nitric acid. red fummg Nitrobenzene Olelc acid Oleum. 20-25% PalnWc actd Perchloroethylene Phenol Phenol Phosphonc acid. 20% Phosphoric acid. 60% C(lZoT, A (1rFt (continued) 7 A(lyFI c Y’ A-0 I (13U'F) A&F, A A(l3VF) A(&F) r&q B B A(lWF) AWW A A VAMAC’ A(2:IF) X i 1 r 0 ks c a c E-c i 7 - VITOY' A-B(lZU'F) A(25O'F) C(l5c'F) A(39FF) A T i C,l;F) A-B T(lJ(PF) A.8 B(l3U'F) C X(lWF) T&F, B C&F) A(2lPF) A A A(2WF) z A A(23fTF) A(l5PF) B(2jg"F) A k&F, A A A C(27U'F) B(27BF) A A - a ;; A&F) A(4OU'F) A(lOVF) C(S5U'F) :::z; C A A,lAF) A A ;1 B S&F, A(3k-l A(158T) A(l76F) A A A x x x x x X r B ,lAF, C(&F, B e A A(2:Z'F) A(2lPF) B(3WF) A(2:FF) (continuec 301 Rubbers and Elastomers TABLE 2.11: VARIOUS ELASTOMERS HYPALOW@ Chemical Phosphonc actd. 70% Phosphoric acid. 65% Ptckkng solubon (20% nttnc actd. 4% HF) Pickling solution (17% nitric acid, 4% HF) Pickling solution (17% nitric acid, 4% HF) Picric acid Potassium dichromate solutions Potassium hydroxide. dilute solutions Pydraul312C Pyridine OFl-2023 (silicone brake fluid) SAE#lOoil Sea water Shell turbine oil 307 Silicone grease SKYDROL 500 SKYLUBE 450 Soap solubons Sodium chloride solutions Sodium dichromate. 20% Sodium hydroxide, 20% Sodium hydroxide, 46th% Sodium hydroxide, 46’h% Sodium hydroxide, 50% Sodium hydroxide, 73% Sodium hypochlorde. 5% Sodium hypochlorite. 20% Sodium peroxide solutions Soybean oil Stannic chlonde Stannous chloride. 15% Steam (see water) Steam Steanc acid Styrene Sulfur, molten Sulfur dioxide, gas Sulfur dioxide, liquid Sulfur tnoxtde Sulfuric acid, up to 5% Sulfuric actd. 5-10% Sulfuric actd. 1 O-50% Sulfuric acid, 50-60% Sulfurtc acid, 60% Sulfuric actd. 90% Sulfuric acid, 95% Sulfuric acid. 95% Sulfuric acid, fuming (20% oleum) Sulfurous acid Sunoco XS-620 (EP lubricant) Tanntc actd. 10% Tartaric acid Tetrahydrofuran Toluene Tributyl phosphate Trichloroethylene Trichloroethylene Tricresyl phosphate Triethanolamine Tnsodium phosphate solutions Tung oil Turpentine Water Water Xylene Xylene Zinc chloride solutions ‘Doless AND RUBBERS-DU otherwise noted, HYPALON HYTREL NEOPRENE (continued) NOADEV Wcoprcnc :: A A A C C X A(150”F) C C X _; A (26@v ;; A 7 A A c 8” c A F ;: : C A (2:lPF) A (20aF) A (21z”F) A (2& A (2OpF) A ; ; - :I:% A A c A(& A (2WF) A : A C i A (2$F) A B A (350°F) rT A(21tF) I) (1GFj B E A (2& A (1FF) A B (:;BpF) A ,& i t C A A A-0 X X : ; c ‘;; A&F) A (2;rTF) : polyethylene NORDEL VAMAC VITON All C A T A(2:pF’ ore saturated. BWV AW’=-l : A(15CF) A solutions A (2:QF) A (1yF-f : A (&F, A (2;F) ;7 A T A (2;F) A A C :: T i z C c A(l52’F) A (2&) T T T s : C A (250°F) A c z A A A (2mF) C of aqueous : : A A B A A : C A chlorosulfinated polyethylene polychloroprene VAMAC' A (269v A (200°F) A (2rF) concentration - PONT :: A(IWF) A ,& A (lSi?Ff c A (2:PF’ a (15IpFf A r ratings - are at room temperature synthetic rubber ethylene acrylic fluoroelastomer unless speciflod 302 TABLE Corrosion Resistant Materials Handbook 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS Exxon butyl rubber and its chlorinated analog, chlorobutyl rubber are isobutylene-isoprene basically inert, nonpolar, stable elastomers which exhibit outstanding resistance to attack ent chemicals. copolymers. They are by a great many differ- VISTALON elastomers are classified generically as either ethylene-propylene copolymers (EPM) or ethylene-propylene terpolymers (EPDM). All grades of VISTALON EPM have a completely saturated hydrocarbon chain which makes them highly resistant to attack by chemical agents such as oxygen, ozone, acids, and the like that seek to react at the site of a double bond. Exxon elastomers offer good resistance to water, inorganic glycol base antifreeze formulations, and to most inorganic elastomers show good resistance to attack by acids, amines, ethers, and ketones. Resistance to detergents and soaps is or in 1% solutions which approximate the concentrations cations. salt solutions, bases, synthetic hydraulic fluids, ethylene acids. When immersed in organic compounds, Exxon and oxygenated compounds-alcohols, aldehydes, esters, excellent whether in concentrated form (as purchased) of these materials commonly used in household appli- Exxon elastomers display good resistance to attack by animal or vegetable oils. However, they are like other petroleum derived synthetic polymers in that their resistance to the attack of hydrocarbons, oils, and other petroleum based chemicals is low. Only VISTALON 6505 blends with nitrile and polychloroprene rubbers maintain good physical properties after prolonged exposure to these materials. CHEMICAL RESISTANCE OF COMPOUND BASED ON INTERMEDIATE UNSATURATION BUl-YL RUBBER 72 Hours Immersion at 212OF VOlUnW change n WATER Distilled Water Sea Water--Atlantic Sea Water-Pacifu Tensik stmngth Retained % +0.78 +0.56 +1.04 95.8 98.8 95.8 INORGANIC ACIDS Boric Acid (10%) Chlorosulfanic Acid (10%) Chromic Acid (10%) Chromic Acid (Cont.) +0.93 Disintegrated +6.60 +19.6 103.0 Hydrochloric Acid (10%) Hydrochloric Acid (Cone.) Hydrofluoric Acid (Cont.) Nitric Acid (10%) +3.70 +15.9 -1.94 +9.09 fl0llgdfOll Retained % Hardness Change Pts. surface Condition 81.8 90.2 88.8 +1 +2 +2 Unchanged Unchanged Unchanged 94.1 +1 Unchanged 83.1 63.9 75.1 68.6 -2 -3 Unchanged V. Brittle 96.4 81.9 89.0 - 78.4 109.8 58.2 -2 -8 -3 - Sl. Tacky Unchanged Unchanged - Nitric Acid (Cow.) Disintegrated Phosphoric Acid (Cont.) Sulfuric Acid (10%) Sulfuric Acid (Cont.) -0.46 +0.24 Disintegrated 102.4 94.0 93.5 82.4 +1 +2 Unchanged Unchanged +1.89 +1.88 -0.45 +1.16 958 105.4 98.8 97.0 86.3 96.1 86.9 82.4 -1 -3 +2 0 Unchanged SI. Tacky Unchanged Unchanned +2.85 +1.92 98.2 101.8 88.2 91.2 -2 -2 0 Unchanged St. Tacky Unchanged -2 +1 +1 0 f2 Unchanged Unchanged Unchanged Unchanged Unchanged INORGANIC BASES Ammonium Hydroxide (10%) Ammonium Hydroxide (Gnu.) Barium Hydroxide (Cont.) Calcium Hvdmxide (10%) Potassium Hydroxide (10%) Sodium Hydroxide (10%) Sodium Hydroxide (Cont.) INDRGANIC SALTS (25% Sofutiona) Aluminum Chloride Aluminum Sulfate Ammonium Chloride Ammonium Nitrate Ammonium Phosphate +0.11 99.4 88.2 +0.50 +0.51 +0.13 +0.21 +0.57 89.2 97.0 94.0 95.2 96.4 78.4 83.7 83.7 85.0 82.4 (continued) Rubbers and Elastomers TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS 303 (continued) 72 Hours Immersion at 212“F VdumC Change K Tensik Strengtfr Retained SC Efongatifm Retained % Banum Chloride Barium Sulfide Calcium Chloride Calcium Hypochlorite +0.17 +0.39 -0.46 +0.69 95.8 94.0 89.8 98.8 82.4 82.9 77.1 80.4 +1 0 0 -2 Unchanged Unchanged Unchanged Unchanged Cupric Chloride Cupric Sulfate Ferric Chloride Ferric Nitrate +0.48 +0.94 +1.50 +3.65 98.2 91.6 95.2 97.6 Ferrous Sulfate +0.48 92.8 84.9 80.4 76.5 93.0 81.8 +1 +1 0 -4 +1 Unchanged Unchanged Unchanged V. Tacky SI. Tacky Magnesium Chloride Magnesium Sulfate Nickel Sulfate Potassium Chloride Potassium Permanganate +0.31 +0.82 +0.79 -0.07 +0.58 94.6 94.0 94.0 90.4 93.4 84.3 81.0 84.3 82.4 84.3 +2 +1 +1 +1 -6 SI. Tacky SI. Tacky SI. Tacky Unchanged SI. Brittle Potassium Bisulfite Potassium Dichromate Sodium Borate (Borax) +1.41 +0.61 +0.34 Sodium Bicarbonate Sodium Chloride Zinc Chloride Zinc Nitrate +0.52 0.00 io.73 +0.24 92.8 91.6 94.6 94.6 100.0 94.0 94.6 83.3 77.1 84.9 84.3 82.4 80.4 80.9 Citric Acid (10%) Formic Acid (10%) tactic Acid (10%) Oleic Acid (100%) +10.9 + 14.7 +9.w +0.69 +12.3 +6.12 +B22 88.0 79.5 86.7 97.0 86.0 90.4 28.3 73.9 67.2 72.0 85.7 68.6 74.5 50.4 -6 -3 -3 +2 -4 0 -38 Unchanged Unchanged Unchanged SI. Tacky Unchanged Unchanged Unchanged Oxalic Acid (10%) Phenol (10%) Phenol (100%) Picric Acid (10%) Stearic Acid (100%) Tannic Acid (10%) Tartaric Acid (10%) +2.36 +2.82 -7.54 + 14.6 +92.8 -0.76 +1.u 97.6 103.6 116.3 78.3 111.5 96.4 97.0 81.8 94.1 110.4 61.4 105.3 86.3 88.2 +1 -4 -7 -5 -4 0 +2 Unchanged SI. Tacky SI. Tacky Unchanged Unchanged SI. Tacky Unchanged +3.19 +2.04 +2.44 +0.63 +0.36 106.6 91.0 89.8 98.2 loo.0 98.0 82.9 91.6 91.6 84.9 -9 -3 -3 +2 +2 Unchanged Unchanged SI. Tacky SI. Tacky Unchanged Gfycerol 1 Hexand Resorcind -0.52 +17.B +0.50 98.8 95.8 103.6 86.3 104.6 91.6 +2 -23 +3 Unchanged Sf. Tacky Unchanged ALDEHYDES Benuldehyde Butyraldehyde Furfural +12.3 +24.9 +4.37 94.6 69.9 108.4 102.0 90.2 101.4 -19 -25 -8 Unchanged Sf. Tacky SI. Tacky AYINES Aniline Triethanolamine UDMH +7.97 -11.1 +13.7 98.2 100.6 54.2 109.2 88.8 79.8 -15 +2 -18 Unchanged Tacky Unchanged +67.2 +43.7 +22.5 +14.7 +1.80 31.3 51.2 88.0 60.2 112.1 46.5 78.4 83.7 67.3 103.3 -35 -33 -22 -17 -6 Unchanged Unchanged Unchanged Unchanged Unchanged ORGANfC ACIDS Acetic Acid (10%) Acetic Acid (Glacial) Chloracetic Acid (10%) ALcoHoLs Benzyl Alcohol Ethyl Alcohol Isopropyl Alcohol Methyl Alcohol Ethylene Glycol Hardness Change Pts. 0 0 -1 +1 -1 0 +2 Surface Condition Unchanged Unchanged Unchanged SI. Tacky Unchanged Unchanged Unchanged ESTERS Amy1 Acetate Dibutyl Sebacate Dioctyi Phthalate Ethyl Acetate Tricresyl Phosphate (continued) 304 Corrosion Resistant Materials Handbook TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS 72 Hours Im-ion TdkStNn#l RJtJinedw ETHERS Dibenryl Ether Diethylene Glycd Monobutyl Ether Ethyl Ether Ethylene Glycol Monoethyl Ether (continued) at 212*F Ehngation RJunedY HarlhleJJ ChJnrPts. suhce con&ion 99.4 110.8 28.9 W.0 111.8 104.9 30.0 89.6 -25 -12 -34 -12 Unchanged Sl. Tacky SI. Tacky Unchanged +125.6 +243.5 +190.2 19.9 18.1 15.7 24.1 17.7 26.1 -37 -37 -43 SI. Tacky Sf. Tacky Unchanged +144.1 +94.4 +108.8 +198.0 +206.8 15.7 22.3 83.1 10.2 16.3 22.2 22.2 75.9 26.1 25.5 -35 -32 +12 -51 -45 Unchanged Sl. Tacky Sl. Tacky Unchanged Unchanged 20.2 21.6 45.7 17.1 -38 -32 -24 -46 Unchanged St. Tacky SI. Tacky Tacky +20.6 +4.89 +54.8 +5.01 HYDRDCARBONS BelueM Cyclohexane Ethylbenzene Heptane HexJnJ Naphthalane Toluene Xylem HALDGENATED HYDROCARBONS 8enzyl Chloride Bromobenzene Carbon Tetrachloride Chloroform Ethylene Dichloride Perchlorathvlene OTHER SUBSTITUTED HYDROCARBONS Carbon Disulfide Nitrobanzene +225.8 +85.2 -I-37.9 +194.3 Disintegrated Disintegrated 18.1 21.1 39.8 12.7 + 144.9 +11.9 21.7 101.2 21.0 106.9 -30 -20 SI. Tacky Unchanged KETONES Acetone Methyl Ethyl Ketone Methyl lsobutyl Ketone +7.92 +15.7 +61.4 85.5 48.8 35.5 88.8 53.5 49.0 -11 -18 -32 SI. Tacky Unchanged SI. Tacky DETERGENTS&OTHER CLEANING PRODUCTS Calgonite (1%) Clorox (1%) Clorox (Cont.) Joy (1%) Joy (Cont.) +1.76 +1.13 +1.20 +2.08 -0.13 102.4 103.0 103.0 102.4 100.0 92.2 88.8 88.2 91.6 90.2 +1 +1 Cl1 +1 +1 Unchanged Unchanged Unchanged Unchanged Unchanged Lestoil (1%) Lux Flakes (1%) Rinse Dry (1%) Rinse Dry (Cow) Tide (1%) +2.94 +1.78 +1.18 +1.34 +1.38 100.6 105.4 101.8 95.2 100.0 96.1 96.7 88.8 86.3 93.1 -1 0 +2 +2 -1 Unchanged Unchanged Unchanged Unchanged Unchanged NATURAL FATS 6 OILS Butter Castor Oil Cottonseed Oil Lard Oleomargarine Olive Oil White Mineral Oil +23.1 -1.25 +19.2 t28.9 + 15.3 +24.8 t 100.6 66.9 89.8 71.1 75.9 81.9 71.1 28.9 97.7 86.9 94.1 104.5 102.6 99.4 31.4 -18 -22 -17 -21 -33 Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged OILS 6 FUELS A.S.T.M. No. 1 Oil A.S.T.M. No. 2 Oil A.S.T.M. No. 3 Oil A.S.T.M. Fuel A A.S.T.M. Fuel B A.S.T.M. Fuel C Heating Fuel Oil Jet Aircraft Engine Oil Kerosine +64.3 +88.2 + 173.4 + 159.0 +199.5 +232.7 +224.1 +92.3 t262.0 38.0 33.1 16.3 18.1 13.3 13.3 13.3 56.3 59.4 40.6 25.5 22.9 21.0 22.9 -34 -36 -46 -40 -45 -47 -45 SI. Tacky SI. Tacky Unchanged Unchanged SI. Tacky SI. Tacky Unchanged 13.3 22.2 -47 Unchanged -21 0 (continued) Rubbers TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS and Elastomers 305 (continued) 72 Hours Immersion at 212OF Volume Changa K Tensik Strength Retained K Elongation Retained K Hardness Change Pts. Sur(acC Condition AUTOMOTIVE PRODUCTS Chassis Grease Motor Oil (lOW.30) Gasohnc’ (RON 94) Gasohne’ (RON 99) Gasohne’ (RON 102) Gasolme: unleaded +44.8 +157.6 +200.8 +181.9 +202.5 + 162.0 40.0 17.5 15.7 15.7 14.5 12.7 45.7 30.8 21.6 20.2 20.2 18.2 -35 -56 -43 -39 -43 -43 SI. Tacky Unchanged Unchanged Unchanged Unchanged -15 -26 -18 -24 -22 Unchanged Unchanged Unchanged Unchanged Unchanged HYDRAULK FLUlDS Dronite Pydraul Pydraul Skydrol Skydrol 8200 F-9 60 500 MfSCELLANEDUS Gelatin (sat. sol’n.) Glucose (sat. sol’n.) Tincture of Iodine +13.4 +27.7 +9.79 +14.1 +12.3 69.9 74.7 98.2 92.2 88.6 79.9 102.0 103.9 107.3 103.3 +2.39 +0.12 +1.11 -0.23 -0.12 100.6 101.9 101.2 97.0 93.4 VOIU~ Chmge % TensUe Strength Retained % Elongation Retained% -0.11 +0.32 +0.25 100.0 102.4 97.6 97.5 100.6 94.1 +3 +3 +3 Unchanged SI. Tacky SI. Tackv lNORGANlC AClDS Boric Acid (10%) Chlorosulfonic Acid (10%) Chromic Acid (10%) Chromic Acid (Cont.) -0.11 Disintegrated +0.93 +43.7 103.0 98.6 -l-3 ‘3. Tacky 99.4 10.2 100.6 86.9 +3 -34 SI. Tacky Tacky Hydrochloric Acid (10%) Hydrochloric Acid (Cont.) Hydrofluoric &id (Cont.) Nitric Acid (10%) Nitric Acid (Cont.) -0.65 +2.67 +0.62 +0.63 +14.8 98.8 98.2 98.8 103.0 28.9 95.5 110.4 98.6 97.5 103.9 +4 0 +1 +1 -28 SI. Tacky SI. Tacky Tacky SI. Tacky V. Tacky -0.33 -1.22 Disinteerated 98.8 98.2 99.4 99.4 +3 +3 Sl. Tacky SI. Tacky 102.0 102.0 96.7 102.0 +2 -3 +3 +3 Unchanged Unchanged Unchanged Unchanged Prestonc antifreeze Dowgard antifreeze 85.7 86.9 88.8 88.2 82.4 +2 +2 +2 -1 +3 Unchanged Tacky Unchanged Unchanged Unchanged One Month Immersion at 7S” 2 5OF WATER Distilled Water Sea Water-Atlantic Sea Water-Pacific Phosphoric Acid (Cont.) Sulfuric Acid (10%) Sulfuric Acid (Cont.) Hardness Change Pts. Surface Condition INORGANICBASES Ammonium Hydroxide (10%) Ammonium Hydroxide (Cont.) 8arium Hydroxide (Cow) Calcium hydroxide (10%) +0.69 -l-o.75 +0.13 +0.35 103.6 103.6 99.4 101.2 Potassium Hydroxide (10%) Sodium Hydroxide (10%) Sodium Hydroxide (Cont.) +0.11 +0.23 +0.11 97.0 94.6 106.0 93.5 88.8 98.0 +3 +3 +2 SI. Tacky Unchanged Unchanged INDRGANIC SALTS (25% Sotutions) Aluminum Chloride Aluminum Sulfate Ammonium Chloride Ammonium Nitrate Ammonium Phosphate +0.34 +o.SD -0.48 +0.42 +0.26 100.0 99.4 97.0 96.4 101.8 91.6 95.5 94.7 96.1 99.4 +3 +3 +4 +3 +3 Unchanged Unchanged Unchanged Unchanged Unchanged Ranum Chloride Barium Sulfide Calcium Chloride Cakium Hypochlorite -0.83 -1.29 +1.43 +0.73 97.6 98.8 101.2 100.0 97.5 98.0 99.4 95.5 +3 +3 +3 +2 Unchanged Unchanged Unchanged Unchanged (continued) 306 Corrosion Resistant Materials Handbook TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS (continued) One Month Immersion at 75O 2 S°F Volume Change X Tensik strength Retained % Elongation Retained K Cupric Chloride Cupric Sulfate Ferric Chloride Ferric Nitrate Ferrous Sulfate -1.00 +0.48 -0.11 +0.68 +0.70 98.8 95.8 98.8 101.2 89.2 93.5 96.1 97.5 101.4 93.5 +3 +2 +3 +2 +2 Unchanged Unchanged Unchanged Unchanged Unchanged Magnesium Chloride Magnesium Sulfate Nickel Sulfate Potassium Chlorida Potassium Permanganate +1.66 -0.12 0.00 -0.56 +4.09 98.8 97.6 96.4 95.8 83.1 97.5 93.5 97.5 94.7 78.4 +2 +2 +2 +3 +2 Unchanged Unchanged Unchanged Unchanged Brittle Potassium Bisulfite Potassium Dichromate +0.23 +0.63 +0.37 +0.25 -0.37 -0.12 0.00 101.2 98.8 97.6 95.2 100.0 96.4 96.4 loo.0 97.5 98.0 93.5 100.0 93.5 96.7 +2 +3 +3 i-3 +3 +3 f4 Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged +1.88 +3.90 +1.24 -1.28 +0.38 0.00 +43.7 105.4 97.6 105.4 97.0 96.4 98.2 69.3 105.3 102.5 105.9 97.5 94.7 95.5 81.0 +3 -2 +3 +4 f3 +4 -16 Tacky St. Tacky St. Tacky St. Tacky SI. Tacky SI. Tacky Unchanged +0.23 +0.94 +0.59 +0.46 +6.14 -0.13 -0.36 98.8 109.7 105.4 105.4 106.6 96.4 98.8 98.0 108.4 108.4 102.6 109.8 92.8 96.1 +3 fl -2 +2 -1 +3 f5 SI. Tacky SI. Tacky Sl. Tacky St. Tacky Unchanged Unchanged St. Tacky Benryl Alcohol Ethyl Alcohol Isopropyl Alcohol Methyl Alcohol Ethylane Glycol +0.36 +0.39 G.00 +0.25 0.00 103.0 94.6 94.6 100.0 85.5 100.6 99.4 98.0 102.6 85.7 -1 -8 fl -1 +3 Tacky SI. Tacky SI. Tacky SI. Tacky SI. Tacky Glycerdl 1 .Hesarul ResorcinU -1.04 +3.39 +0.32 98.8 101.2 100.0 99.4 io3.3 98.0 +3 -3 +3 Tacky SJ. Tacky SI. Tacky ALMHYMS Renraldchyde Butyraldehyde Furfuraf +10.4 +21.6 +0.11 102.4 66.3 106.6 106.9 81.4 106.5 -15 -20 -5 SI. Tacky SI. Tacky Tacky AYINES Aniline Triethandamine UDMH +5.07 +0.13 +10.5 110.8 101.2 59.0 108.4 100.0 82.4 -6 +4 -13 SI. Tacky SI. Tacky Unchanged ESTERS Amy1 Acetate Dlbutyl Sebacate Oioctyl Phthalate Ethyl Acetate Tr~~resyl Phosphate +46.4 +22.8 +1.85 -l-24.2 -0.13 39.2 80.1 101.2 95.3 101.2 45.1 96.1 103.9 86.9 103.9 -23 -17 -1 -13 f2 Unchanged SI. Tacky St. Tacky Tacky Tacky +12.1 +1.32 -t-58.7 +1.29 loo.6 102.4 30.7 103.0 106.5 107.8 65.5 105.3 -16 -2 -24 -2 Unchanged Tacky Tacky Tacky Sodium Borate (8oru) Sodium Bicarbonate Sodium Chloride Zinc Chloride Zinc Nitrate ORGANIC ACIDS AcetIc Acid (10%) Acetic Acid (Glacial) Chloracetic Acid (10%) Citric Acid (10%) Fornw Acid (10%) Lactic Acid (10%) Oleic Acid (100%) Oxahc Acid (10%) Phenol (10%) Phenol (100%) Plcric Acid (10%) Steanc Acid (100%) Tanruc Acid (10%) Tartarlc Actd (10%) Hardness Change Pts. surface! Condition SI ALCOHOLS ETHERS O~benryl Ether Diethytene Glycd Monobutyt Ether Ethyl Ether Ethylene Glycol Monoethyl Ether (continued) Rubbers TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS and Elastomers 307 (continued) One Month Immersion at 75’ * 5-F Vdwnt ww Tensilt Strangth Rttaintd w Elongation Retained% Hardntss Change Pts. Surfact Condition HYDROCARBONS Btnztnt Cyclohtxant Ethylbenzene +71.4 +206.3 +167.4 26.5 22.9 24.7 27.5 18.2 23.5 -27 -28 -31 Unchanged Sl. Tacky SI. Tacky Htptant Hcxane Naphthaltnt +136.6 +160.8 +75.5 22.9 23.5 92.8 21.0 21.0 82.9 -27 -27 -13 SI Tacky SI. Tacky Sl. Tacky Tolutnt Xyltnt +123.6 +182.0 23.5 22.3 22.9 20.2 -29 -30 Tacky SI. Tacky HALOGENATEO HYDROCARBONS Btnryl Chloride Bromobenzene Carbon Tetrachloride Chloroform +12.8 +123.1 +192.0 +158.1 57.2 24.9 22.9 21.7 77.5 26.1 18.2 19.7 -20 -31 -29 -30 +25.6 50.0 62.8 -18 Per;hloroe!hylt”t +207.3 19.9 15.7 -32 Tacky SI. Tacky Unchanged SI. Tacky SI. Tacky SI. Tacky OTHER SUBSTITUTED HYDROCARBONS Carbon Dlsulflde Nltrobenzene +123.5 +7.64 23.5 105.4 21.0 105.3 -28 -13 SI. Tacky SI. Tacky +6.07 +10.2 +23.3 88.0 82.5 67.8 93.5 87.7 74.5 -10 -13 -18 SI. Tacky SI. Tacky SI. Tack; -0.38 +0.64 +2.09 +0.13 -11.1 101.1 104.2 102.4 98.8 101.8 102.5 103.9 101.0 98.6 99.4 +3 +3 +2 +3 +4 Unchanged Tacky Tacky Tacky Tacky +1.55 +0.35 +0.36 0.00 +0.26 131.8 137.2 100.0 95.8 100.0 104.5 106.5 97.5 93.5 101.4 +2 +3 +3 +3 +2 St. Unchanged Tacky +2.12 -0.39 -I-2.49 +3.77 +2.51 +2.38 +13.1 97.0 98.2 99.4 95.2 104.2 101.2 54.2 102.6 98.0 102.6 103.3 105.9 106.5 58.8 -3 -I-4 +1 -3 -3 -1 -13 Unchanged Tacky SI. Tacky Unchanged Unchanged SI. Tacky Unchanged Ethylene Oachlorlde KETONES Acetone . Mcthvl Methyl _ Ketone lsobutyl Ketone EIhvl DETERGENTS &OTHER CLUNING PRODUCTS Calgon1te (1%) C1orox (1%) Clorox (Cont.) Joy (1%) JOY (Cone ) LestoIl (1 a) Lux Flakes (1%) Rlnst Dry (1%) Rinse Dry (Cont.) Tide (1%) NATURAL FATS L OILS Buntr Castor 011 Cononsetd 011 Lard Oltomargarint Olwt 011 Whltt Mmtral 011 Tacky OILS FUELS A.S.T.M. 1 011 No. 2 A.S.T.M. No. 011 A T.M. Fuel A.S.T.M Fuel A.S.T.M. Fuel Heating Fuel Jet Aircraft Oil Ktrosmt +9.10 +9.88 +39.4 +84.2 + 143.8 +155.6 +59.6 + 17.2 +163.0 83.1 81.9 47.0 27.1 22.3 21.7 25.3 86.1 25.9 88.8 84.3 44.5 23.5 20.2 19.0 23.0 100.6 21.6 -5 -6 -19 -27 -31 -31 -31 -13 -32 SI. Tacky SI. Tacky Unchanged Unchanged Unchangtd Unchanged Unchangtd SI. Tacky Unchanged AUTOMOTIVE PRODUCTS Chassis Grease Motor 011 ( 1OW 30) Gasohne’ (RON 94) Gasoltnt’ (RON 99) Gasollnt’ (RON 102) Gasolvw.” unleaded +13.3 +21.8 +137.9 +145.7 +15B.4 +181.6 75.9 50.6 23.5 21.1 22.3 23.5 77.8 51.0 19.6 19.6 21.0 20.2 -7 -18 -31 -31 -31 -31 Sl. Tacky Unchanged Unchanged Unchanged Unchangtd Unchanged (continued) 308 Corrosion Resistant Materials Handbook TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS (continued) One Month lmmcrsion at 75O -C 5OF volume Chanrm % TensileStrength Elongation Retained K Ratained K Hardness Chanee Pts. Surface Condition HYDRAULIC FLUIDS Oron1tc 8200 Pydraul F.9 Pydraul 60 +2.81 +3.97 -3.04 101.8 103.0 105.4 loo.0 103.3 104.5 -1 -1 +2 Unchanged SI. Tacky SI. Tacky Skydrol +1.01 112.1 111.2 -2 St. Tacky Skydrol 500 +0.54 107.2 108.4 -2 Sf. Tacky +1.24 +0.23 +6.44 +o.!X +0.73 99.4 96.4 93.4 98.8 98.2 96.7 96.1 85.7 100.0 97.5 +3 +2 +1 +3 +4 SI. Tacky SI. Tacky SI. Tacky SI. Tacky Unchanged MISCELLANEOUS Gelatin (sat. sol’n.) Glucose (sat. sol’n.) Tincture of Iodine Prestonc antifreeze Dowgard antifreeze Three Months lmmcrsion at 7S” = 5OF WATER Distilled Water Saa Water--Atlantic Sea Water-Pacific volume Challm n Tensfle strength Retained % Elongatfm Retained % +0.11 .+0.32 i-o.37 103.0 102.4 98.8 loo.0 101.4 96.1 +3 +3 +2 SI. Tacky Unchanged SI. Tacky SI. Tacky Hardness Change Pts. Surface Condition INORGANIC ACIDS Boric Acid (10%) Chlorosulfonic Acid (10%) Chromic Acid (10%) Chromic Acid (Cow.) -0.11 Disintegrated +6.52 i-47.4 94.0. 93.5 +2 80.7 1.8 88.8 13.5 -2 -33 Hydrochloric Acid (10%) Hydrochloric Acid (Cont.) Hydrofluoric Acid (Cont.) Nitric Acid (10%) Nitric Acid (Cont.) -0.65 +11.8 +1.42 +0.88 Disintegrated 95.2 77.7 98.8 96.4 97.5 115.7 98.6 95.5 +3 -3 -2 0 SI. Tacky Sl. Tacky Unchanged Tacky 100.0 99.4 +3 SI. Tacky 98.2 96.1 +4 SI. Tacky -l-2.42 i-2.88 +1.21 +0.93 108.4 109.0 98.8 101.2 102.0 102.6 93.5 101.4 +3 -2 f4 +3 SI. Tacky SI. Tacky Unchanged Unchanned 0.00 +0.23 +0.55 102.4 98.8 104.2 99.4 95.5 98.6 +3 +2 -2 Unchanged Unchanged Unchanged Aluminum Chloride Aluminum Sulfate Ammonium Chloride Ammonium Nitrate Ammonium Phosphate -0.12 +0.13 -0.24 -0.13 -0.13 99.4 102.4 98.2 98.8 96.4 94.1 101.4 98.0 101.4 98.6 +3 +3 +4 +3 +5 Sf. Tacky Unchanged Unchanged Sf. Tacky St. Tacky Barium Chloride Barium Sulfide Calcium Chloride Calcium Hypochlorite -1.30 -0.91 +0.36 +1.09 97.0 99.4 98.8 98.8 96.1 96.1 96.1 98.0 +4 +3 +4 +3 Unchanged Unchanged Unchanged Unchanged Cupric Chloride Cupric Sulfate Ferric Chloride Ferric Nitrate Ferrous Sulfate -1.13 +0.24 0.00 +0.68 +0.93 104.8 loo.0 97.6 102.4 97.6 102.5 101.4 96.1 100.6 96.1 +4 i-4 +6 +4 +3 Sf. Tacky Unchanged Sf. Tacky Sl. Tacky Unchanged Magnesium Chloride Magnesium Sulfate Nickel Sulfate Potassium Chloride Potassium Permanganate -0.26 +0.46 +0.33 -0.32 +2.90 97.6 103.0 103.6 98.8 78.9 97.5 94.7 103.3 99.4 77.1 i-4 +3 +4 +5 -3 Unchanged Unchanged Unchanged Unchanged Brittfe Phosphoric Acid (Cont.) Sulfuric Acid (10%) Sulfuric Acid (Cont.) INORGANIC BASES Ammonium Hydroxide (10%) Ammonium Hydroxide (Cow) Barium Hydroxide (Cont.) Calcium Hydroxide (10%) Potassium Hydroxide (10%) Sodium Hydroxide (10%) Sodium Hydroxide (Cow.) +0.11 +0.74 Disintegrated Unchanged V. Tacky INORGANIC SALTS (25% Solutions) ’ (continued) Rubbers TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON Three Vdume Change Potassium Elsulflte Potassium Dlchromate +2.29 0.00 (Borax) Tensik x Strength Retained X CHEMICALS Months immersion (continued) at 75O - Elongation Retained and Elastomers 5°F Hardness % Change Surface Pts. Condition 106.6 107.8 +1 Unchanged 101.2 100.0 +4 Unchanged Sodium Borate 97.5 +4 Unchanged Sodium Bicarbonate -0.12 loo.0 98.0 +4 Unchanged Sodturn Chlwde -0.49 100.0 98.6 +5 Unchanged -0.12 97.0 98.0 +5 St. Tacky 97.6 96.7 +5 St. Tacky 0.00 21nc ChlorvJe 210~ NItrate 0.00 ORGANIC 96.4 ACIDS AcetIc Acid (10%) +2.58 99.4 102.6 AcetIc Acld (Glacial) +8.20 89.2 101.0 -9 SI. Tacky +3.34 107.8 99.4 +2 SI. Tacky SI. Tacky Chloracetlc Citric Acid (10%) Acid (10%) Formic 0.00 Acid (10%) Lactic Acld (10%) Ole~c Actid (100%) Oxalic 98.8 100.0 +3 103.0 loo.0 +3 SI +0.68 100.0 +3 SI. Tacky 98.0 48.8 59.4 101.2 98.0 +3 SI. Tacky SI +2.97 107.8 111.2 -3 Phenol (100%) +8.26 104.2 119.0 -17 Acid (10%) +0.81 Acid (100%) Tanmc Acid (10%) Tartax +13.9 0.00 Acld (10%) 97.6 94.7 Unchanged -26 (10%) Steanc Tacky +0.35 Phenol PWXIC SI. Tacky +I.76 +90.3 Acid (10%) 0 Tacky SI. Tacky +1 St. Tacky 106.6 107.8 -2 Unchanged 102.4 101.4 +2 St. Tacky -0.12 93.4 90.2 +3 SI. Tacky -0.96 100.0 98.6 -4 SI. Tacky 97.6 100.6 -1 SI. Tacky +0.36 97.6 100.0 -1 -0.36 92.7 90.8 -0.37 92.8 94.1 -0.25 +7.24 +0.76 100.0 86.8 loo.7 94.1 97.5 98.6 +9.66 91.6 100.9 -17 SI. Tacky 57.8 78.4 -18 SI. Tacky 105.4 103.9 -7 SI. Tackv 95.2 101.9 ALCOHOLS Benryl Alcohol Ethyl Alcohol Isopropyl Methyl 0.00 Alcohol Alcohol Ethylene Glycol Glycerol 1 -Hexanol ReSoWlnOl St. Tacky 0 +3 +5 -11 +3 Sl. Tacky St. Tacky Sl. Tacky Tacky Sl. Tacky ALDEHYDES Benzaldehyde Butyraldehyde +21.7 Furfural -l-2.57 AMINES Aniline +11.8 -13 Sl. Tacky Trlethanolamine +0.57 101.2 99.4 UDMH +7.90 57.2 74.5 -12 UnChanRed -l-47.2 +23.5 +5.36 +10.9 +0.75 40.4 89.8 106.0 78.9 102.4 103.3 +11.6 +2.56 +57.4 103.0 107.8 -13 107.8 113.1 -7 St. Tacky 30.1 32.8 -25 Unchanged 97.0 98.0 -5 s1. Tacky +3 Unchanged ESTERS Amy1 Acetate Dlbutyl Sebacate Dwtyl Phthalate Ethyl Acetate Tricresyl Phosphate 47.7 -22 Unchanged 103.3 -17 Unchanged 107.8 -3 SI. Tacky 88.2 -12 St. Tacky +3 Sl. Tacky ETHERS Dibenzyl Ether Ditthyltne Ethvl Glycd Monobutyl Ether Ether Ethilent Glycol Monoethyl Ether +2.05 Unchanged HYDROCARBONS Benztne +101.9 25.9 25.5 -28 Unchanged Cvclohtxant +230.2 21.7 17.7 -28 Unchanged Ethylbenzene +176.0 19.3 20.2 -31 g. Heptone +178.0 23.5 20.9 -28 Sl. Trky Htxtnt +169.0 Tacky 22.9 22.6 -27 +50.4 89.8 00.4 -7 SI. Tacky Toluenc +114.8 23.5 22.9 -29 SI. Tacky Xylenc +154.5 22.3 21.0 -30 St. Tacky Naphthaltne Y. Tacky (continued) 309 310 Corrosion Resistant Materials Handbook TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS (continued) Three Montlta Immersion at 75O 2 5OF 1-w R8tdlled% -w~InedW Hardness Chan8a Fts. surface Condition HALDGENATED HYDROCARBONS Benzyl Chloride Bromobcnrtnt Carbon Tttrachloridt Chloroform Ethylene Dwzhloridt Ptrchlorotthyltnt +25.1 +114.4 +199.5 +137.7 +25.2 +212.4 57.8 24.7 20.5 la7 48.8 la7 79.8 25.5 17.7 20.2 60.2 15.7 -20 -32 -31 -30 -18 -30 SI. Tacky SI. Tacky Unchanged SI: Tacky SI. Tacky SI. Tacky OTHER SUBSTITUTED HYDROCARBONS Carbon Dmlfedt Nmobtnztnt +183.4 -l-4.77 19.3 86.1 20.2 98.6 -30 -12 SI. Tacky SI. Tacky KETONES Acetone Methyl Ethyl Ketone Methyl lsobutyl Ketone +6.14 +19.7 +22.2 89.2 86.8 56.0 97.5 94.1 70.0 -9 -12 -17 SI. Tacky Unchanged SI. Tacky DETERGENTSaOTHER CLEANING PRODUCTS Calgonltt (1%) +0.50 98.8 +1.28 +1.48 +0.63 -11.32 101.2 106.0 96.7 98.8 103.3 103.9 103.9 98.0 102.6 +3 +2 -1 +3 fl Unchanged SI. Tacky Tacky SI. Tacky Tacky +2.74 +0.71 +0.72 -0.36 +0.65 102.4 98.8 95.2 93.4 101.2 105.9 97.5 96.6 96.6 103.3 -1 +2 +2 +3 -2 SI. Tacky Unchanged SI. Tacky SI. Tacky SI. Tacky +8.92 -0.65 +5.18 +7.OO +6.52 +7.87 +53.6 101.2 95.2 95.8 97.0 106.6 94.8 41.0 102.0 94.1 100.6 103.3 106.5 100.6 42.6 -7 -4 -6 -4 -3 -7 -26 Unchanged SI. Tacky SI. Tacky Unchanged SI. Tacky SI. Tacky Unchanged Clorox (1%) Cloror (COOC.) JOY (1%) Joy (Cone ) LestoIl (1%) Lux Flakes (1%) Ruvt Dry (1%) Rinse Dry (Cont.) Tide (1%) NATURAL FATS & OILS Butter Castor OrI Cononsetd011 Lard Oltomargarine Olwt 011 White Mmtral Ott OILS & FUELS A.S.T.M. No. 1 Oil A.S.T.M. No. 2 011 A.S.T.M. No. 3 011 A.S.T.M. Fuel A A S.T M. Fuel B A.S.T M. Futl C Htatmg Fuel 011 Jet Awcraft Engine Oil Ktrosint +20.0 +lB.9 + 103.2 +162.9 +185.5 + 197.8 +190.0 +27.0 + 197.2 74.1 74.1 34.9 25.9 22.3 22.3 22.9 66.9 22.3 82.9 78.4 33.9 24.2 21.6 21.6 22.2 88.2 21.6 -8 -9 -27 -28 -29 -30 -32 -19 -31 Unchanged Unchanged Unchanged Unchanged Unchanged Sl. Tacky Unchanged Unchanged Unchanged AUTOMOTIVE PRODUCTS Chassis Grease Motor 011 (low 30) Gasohnt’ (RON 94) Gasoline’ (RON 99) Gasolmt’ (RON 102) Gasoline.‘* unltsdtd +19.8 +93.0 +189.0 + 182.4 +189.6 + 196.9 54.4 37.8 21.7 21.1 19.9 20.5 59.4 39.2 20.2 22.2 21.0 20.2 -13 -37 -31 -31 -32 -32 SI. Tacky Unchanged Sl. Tacky SI. Tacky SI. Tacky Sl. Tacks -2 -4 -3 -3 -3 Unchanged SI. Tacky SI. Tacky SI. Tacky Si. Tackv HYDRAULIC FLUIDS Oronttt 8200 Pydraul F-9 Pydraul 60 Skydrol Skvdrol 500 +4.56 +6.08 +1.39 +4.32 +1.67 97.0 107.8 106.0 1102 112.0 99.4 112.3 105.9 105.3 109.8 (continued) Rubbers and Elastomers TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMlCALS 311 (continued) Three Months Immersion Jt X0 2 5i°F Vdwm CftJrrwx MISCELLANEOUS GJlJtln (SJt Sol’n.) Glucose (sat sol’n.) Tincture of Iodine Prestone antifreeze DOwgIrd JntifrJJZJ TJmitJSbmngth R~bined K DJngJtknl Retained% 101.2 100.0 78.9 101.2 97.6 104.9 95.5 66.1 loo.0 95.5 0.00 +0.23 +12.5 +1.44 +1.33 fbrdncss ChJnp PLs. +3 +3 -2 -1 +3 SUrfJcJ bnditkm Si. TJCky Sf. TJCb Unchanged St. TJcky UnChJngJd Six Months Immersion at 75O 2 IoF Vdume Charwe% fJ"SilJ Stmgth HJrdness Change Pts. SWfJcC Ccmdition Retained K ElcwlgJtion RJtainJd SC 101.2 105.4 105.4 102.6 104.5 100.6 +4 +4 +3 Unchsnged UnchJnged Unchanged 98.8 103.3 +2 SI. Tacky Chromic Acid (10%) Chromic Acld (Cont.) -0.23 Disintegrated +12.4 +4a.3 66.9 2.41 77.8 9.8 -6 -27 Tacky V. Tacky Hydrochloric Acid (10%) Hydrochloric Acid (Cont.) Hydrofluoric Acld (Cont.) Nitric Acid (10%) Nitric Acid (Cont.) -0.52 +8.52 +2.36 +1.13 Disintenrated 97.6 54.8 87.4 95.8 96.7 103.9 80.4 93.5 +2 -8 -2 +1 SI. Tacky SI. Tacky SI. Tacky V. Tacky Phosphoric Acid (Cont.) Sulfuric Acid (10%) Sulfuric Acld (Cont.) +0.11 +0.61 DisintJgrJted 102.4 99.4 100.6 101.4 +3 +4 TJcky Tacky WATER Distilled WJtJr !$ZJ Water-AttJntlC Sea Water-Pacific +0.90 +0.32 +0.25 INORGANIC ACIDS Boric Acid (10%) Chlorosulfonic Acid (10%) INORGANIC BASES Ammonium Hydroxide (10%) Ammomum Hydroxide (Cont.) Barium Hydroxide (Cont.) CJlcium Hydroxide (10%) +4.61 +5.14 +0.89 +0.82 111.5 108.4 101.2 101.2 103.9 96.7 97.5 95.5 +2 -3 +4 +4 Unchanged St. Tacky Unchanged Unchanged Potrsswm Hydroxide (10%) Sodium Hydroxide (10%) Sodium Hydroxide (Cont.) +0.68 +0.35 +1.33 101.2 109.6 106.6 96.7 97.5 100.6 +3 +3 -2 Unchanged Unchanged Unchanged Aluminum SulfJte Ammonium Chloride Ammonium NitrJtJ Ammonium Phosphate +0.81 +1.21 -0.61 0.00 0.00 96.4 95.8 94.0 96.4 98.2 90.2 83.7 92.8 95.5 98.0 +2 +2 +3 +2 +3 Sl. TJcky UnchJngJd SI. Tacky St. TJcky St. TJC~~ SJrium Chloride Barium Sulfide CJlcium Chloride CJlcium Hypochlorite +0.47 +0.26 +1.45 +1.58 88.6 97.6 95.8 110.8 86.9 95.5 96.7 103.9 +3 +2 +2 -2 Unchrnged UnChJngJd UnchJngJd St. TJC~~ Cupric Chlortdr Cupric S,,ffJtJ FJrric Chloride -f-o.37 +0.84 +0.22 96.4 94.6 100.6 96.1 92.8 101.4 +2 +3 -l-3 St. Trky UnChJngJd UtWhJngJd Ferric NitrJtJ Ferrous SulfJtJ +1.23 +1.16 100.0 98.8 99.4 96.1 +1 +2 T-=b UnchJnged MJgnJsium Chloride MJgnesium Sulfite Nickel SulfJte PotJssium Chloride PotJssium PermangJnJte +0.26 +1.0) +0.66 +oz? +-a47 96.4 101.8 100.0 94.6 85.5 96.1 94.7 101.4 94.7 88.2 +3 +2 +2 +1 -2 UnchJnged UrKhJngcd UnchJngJd Sl. Tacky Brittle PotJsswm Bisulflte PotJsslum Dichromrte Sodium Borate (8orrx) SJdlUm 8iCJrbonJtJ Sodwm Chlonde Zmc Chlorde 2IK NltrJtJ +5.51 +1.02 +0.85 i6.76 +D.25 +0.47 +0.36 111.5 96.4 94.0 96.4 94.6 94.6 101.8 108.4 95.5 96.1 93.5 95.5 92.2 103.3 -3 +3 +2 +2 +2 +3 +4 Unchrnged UnChJngJd UnchJngad UtKhJngJd St. Tacky Sf. Trky SI. Tuky INORGANIC SALTS (25% Solutions) Aluminum Chloride (continued) 312 Corrosion Resistant Materials Handbook TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS Six Months Immersion VdunW ww ORGANIC ACIDS Acetic Acid (10%) Acetic Acid (Glacial) Chloracetic Acid (10%) Citric Acid (10%) Formic Acid (10%) Lactic Acid (10%) Oleic Acid (100%) Oxalic Acid (10%) Phenol (10%) Phenol (100%) Robined% RetahdW 2 VF Hldll8SS ChangePts. surfra Condition 101.4 96.1 103.9 92.2 101.4 99.4 57.5 +1 -9 +2 +5 +3 +3 -26 Sl. Tacky Sl. Tacky Sl. Tacky SI. Tacky SL Tacky Sl. Tacky Unchanged 101.2 108.4 105.4 106.0 101.8 100.6 98.8 102.6 109.8 113.7 104.5 101.4 97.5 98.0 +3 -7 -15 +2 -2 +3 +3 SI. Tacky SI. Tacky Sl. Tacky Sl. Tacky Unchanged Sl. Tacky Sl. Tacky +1.19 -0.24 104.8 89.8 89.2 97.0 92.8 103.9 96.7 90.8 loo.0 90.2 -6 -2 -6 -1 +4 SI. Tacky St. Tacky SI. Tacky SI. Tacky Sl. Tacky 0.00 Unchanged +4.00 +0.38 +3.14 +0.68 +93.9 +1.15 +5.69 +6.16 +3.34 +17.9 Tannic Acid (10%) Tartaric Acid (10%) +0.65 +0.60 Glycerol at 7S” Elongation 104.2 07.4 114.5 98.2 103.0 101.8 43.4 +4.58 +a.44 Picric Acid (10%) Stearic Acid (100%) ALCOHOLS Bcnzyl Alcohol Ethyl Alcohol Isopropyl Alcohol Methyl Alcohol Ethylene Glycd TensileStrength (continued) +3.70 +0.51 +1.23 95.8 89.6 +3 +6.92 +2.46 91.6 97.0 102.0 93.5 -10 +2 Tacky St. Tacky Bsnzaldehyde Butyraldehyde Fur(ural +7.10 +21.6 +2.83 86.1 99.4 108.4 94.1 103.9 106.5 -13 -18 -8 SI. Tacky Unchanged TsClcy AMINES Aniline Triethanolamine UOMH +10.6 +2.38 +4.89 98.8 97.0 51.2 103.9 88.2 66.7 -14 +3 -9 Sl. Tacky St. Tacky Sl. Tacky ESTERS Amy1 Acetate Dibutyl Ssbacate Dioctyl Phthalate Ethyl Acetate +45.6 +21.6 +6.14 +11.8 42.2 93.4 109.6 81.3 51.6 lD4.5 117.6 90.8 -23 -18 -7 -12 Unchanged Unchanged Si. Tacky Unchanged +0.87 105.4 104.5 +2 +9.92 +3.71 +52.6 -l-3.33 108.4 102.4 29.5 101.2 101.1 105.3 33.9 101.4 -13 -9 -35 -7 Unchanged Unchanged Unchanged 9. Tacky 27.1 22.3 20.4 29.4 17.7 21.6 -30 -31 -31 Unchanged St. Tacky Unchanged l-Hexand Rcsorcinol ALOEHYDES Tricresyl Phosphatr EIHERS Olbenzyl Ether Diethylena Glycoi Monobutyl Ether Ethyl Ether Ethylene Glycol Monoethyl Ether HYDROCARBONS 8eruene Cyclohexane Ethylbenzene +112.2 +205.9 +140.0 Tacky Heptane +141.2 25.3 22.9 -28 Sl. TIJly Hexarm Naphthalene +129.3 +41.8 21.7 81.3 21.0 77.1 -28 +2 Tacky SI. Tacky Tduene XylWN +139.5 +1642 21.7 21.7 22.2 21.0 -32 -31 Tacky Sl. Tacky HALOGENATEO WYOROCAR8ONS Eenzyl Chloride Bromobeozene Carbon Tetrachloride Chloroform Ethylene Dxhloride Perchloroethylene +27.3 +115.6 +213.3 +170.1 +26.7 +220.0 57.3 24.7 21.7 19.9 56.0 19.9 78.4 26.1 19.0 21.0 70.6 18.2 -21 -32 -31 -32 -18 -33 Tacky SJ. Tacky Unchanged Sk Tacky SI. Tacky Unchanged (continued) Rubbers and Elastomers TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS 313 (continued) Six Months Immersion Jt 75” = 5’F lmsile Stnmgth RetJined SC Elongation Retained K +118.D +4.59 21.7 103.0 20.2 104.5 -30 -9 St. TJCky Tacky Methit lsobutyl Ketone +5.29 +9.22 +22.4 84.3 82.5 59.6 89.6 86.9 74.5 -8 -11 -16 Unchanged St. Tacky SI. Tacky DETERGENTS&OTHER CLUNING PRODUCTS Calgonlte (1%) Cloror (1%) Cloror (Cow) JO” 11%) Joy (Cone ) i-O.88 +2.43 +1.85 +1.79 -11.3 106.6 107.2 108.4 104.2 98.8 105.9 100.6 105.3 104.5 98.0 +5 +3 +2 +2.86 +1.30 +1.20 -0.50 +0.92 104.2 104.2 95.2 100.0 97.6 102.5 102.5 95.5 96.1 96.7 +2 +3 +3 +3 +3 SI. Tacky Unchanged SI. TJcky Si. Tacky SI. Tacky + 12.6 -D.92 +6.41 +11.8 +8.06 +12.0 +95.1 105.4 96.4 106.6 106.6 107.8 99.4 36.8 104.5 95.5 107.8 109.2 107.8 105.9 33.3 -12 +3 -4 -11 -7 -12 -26 Unchanged Tacky SI. Tacky Unchanged Unchanged SI Tacky SI. Tacky 56.0 54.2 30.1 23.5 20.5 19.9 20.5 60.8 22.3 67.3 63.3 28.8 23.5 21.6 21.6 21.0 84.3 21.6 -16 -17 -30 -28 -33 -32 -32 -21 -32 Unchanged Unchanged Unchanged Unchanged SI. Tacky SI. Tacky Unchanged Unchanged 50.0 31.9 19.9 18.7 16.9 21.1 52.0 32.8 21.6 21.6 20.2 21.0 -21 -31 -32 -33 -33 -32 SI. Tacky Unchanged SI. Tacky SI. Tacky SI. Tacky SI. Tacky VOlUmC ChJnmu OTHfR HJblJJJ Ch~nnJ Pts. SWfJCJ Condition SU8STITUTEo HYORDCARBONS Carbon Dlsulflde Nllrobenzcne KETONES Acctonc Methyl Ethyl Ketone LestoIl (1X) Lux Flakes (1%) Rlnre Dry (1%) Rlnre Dry (Cow ) Tide (1%) NATURAL FATS L OILS Butter CJStOr 011 CoItonsud 011 Lard Oleomargarine OIIVC 011 White MlnerJl 011 OILS L FUELS A.S.T.M No. 1 Oil A S T.M No. 2 011 A S T.M No. 3 011 ASTM FuelA A.5 T.M. Fuel 8 A.S T.M Fuel C Heating Fuel 011 Jet Atfcr~fi Engcne 011 Kcros~ne AUTOMDTIVC PRODUCTS Chassrs Grease Motor 011 (lOW.30) t30.8 +34.6 t 146.5 t-161.5 t189.7 t200.9 t 195.0 t41.7 t211.2 t38.0 t3 +3 SI. SI. Sl. SI. Sl. Tacky Tacky Tacky Tacky Tack; Unchanged (RON 102) GJsohne:* unleaded t118.4 +192.5 +1?6.9 +192.0 +201.9 HYDRAULIC FLUIDS Orontite 8200 edrJul F.9 Fydraul 60 Skydrol Skvdrol 500 +11.6 +7.89 t2.01 +4.98 +3.24 99.4 112.7 101.2 106.0 103.6 104.5 115.1 103.3 108.4 105.9 -7 -7 -3 -8 -6 Unchanged SI. Tacky SI. Tacky SI. Tacky SI. Tacky MISCELIANEOUS Gelatin (sat. sol’n.) Glucose (sat. sol’n.) Tincture of Iodine Prestone Jntitreeze Dowgard Jntifreeze +1.86 +0.23 +16.2 +I.67 to.39 98.8 98.8 53.6 99.4 94.8 96.1 94.1 40.6 100.0 92.8 +2 +3 -5 0 St. TJC@ Tacky Unchanged Unchanged Unchanged GJSOIWW (RON 94) GJSO~IIW’ (RON 99) GJSO~IW’ t3 (continued) 314 Corrosion Resistant Materials Handbook TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS (continued) 12 Months Immersion at 7S” = 5’F volume Chena K WATER Distilled Water Sea Wlter-Atlantic Sea Water-Pecifii -l-O.78 +0.43 -0.25 INORGANIC ACIDS Boric Acid (10%) Chlorosulfonic Acid (10%) Chromic Acid (10%) Chromic Acid (Cont.) -1.95 Disintegrated +20.2 f49.6 Hydrochloric Acid (10%) Hydrochloric Acid (Cont.) Hydrofluoric Acid (Cont.) Nitric Acld (10%) Nitric Acid (Co&) +0.37 +11.2 +2.18 +1.6f Disintegrated Phosphoric Acid (Cont.) Sulfuric Acid (10%) Sulfuric Acid (Cont.) +0.11 -0.12 Disintegrated Elongatii Retained% 95.2 100.6 98.8 96.1 102.5 96.1 +3 +4 +4 Unchanged Unchanged Unchanged 106.5 +3 Tacky 98.8 56.6 5.42 104.8 56.0 90.4 101.2 98.8 95.2 Hardness ChannePts. Surface Condition Tensik sbmgth Retained w -10 -21 Tacky V. Tacky 102.0 88.8 67.2 101.4 +2 -11 0 0 Tacky SI. Tacky SI. Tacky V. Tackv 101.4 95.5 +3 +4 Tacky Tacky 77.8 12.3 INORGANIC BASES Ammomum Hydroxbdc (10%) Ammomum Hydroxide (Cope.) Barwm Hydroxide (Cont.) Calcium Hydroxide (10%) -l-5.88 +7.39 +1.02 +1.05 106.0 101.2 100.6 96.4 96.1 89.6 99.4 98.6 -1 -3 i-3 f3 Unchanged SI. Tacky Unchanged Unchanned Potassium Hydroxide (10%) Sodium Hydroxide (10%) Sodium Hydroxide (Cont.) +0.23 +0.93 +1.77 100.0 104.8 104.8 96.1 99.4 101.4 +3 +1 -4 Unchanged Unchanged Unchanged Aluminum Sulfate Ammomum Chloride Ammonium N&rate Ammomum Phosphate +0.34 +1.34 +0.12 +0.13 +1.03 98.2 103.6 95.2 98.2 101.8 97.5 105.3 99.4 99.4 103.9 +2 +3 +3 +3 +3 St. Tacky Unchanged SI. Tacky SI. Tacky Sl. Tacky Barwm Chloride Barium Sulfide Calcium Chloride Calcwm Hypochlorite +0.47 +0.51 +1.55 +1.82 104.8 98.2 95.8 107.8 105.9 91.6 94.1 107.8 +4 +2 +1 -1 Unchanged Unchanged Unchanged Sl. Tacky Cupric Chloride Cupric Sulfate Ferric Chloride Ferric Nitrate Ferrous Sulfate +0.13 +1.80 +0.44 +1.25 +0.81 94.0 96.4 98.8 93.4 97.0 96.1 99.4 98.0 98.0 95.5 +4 +4 +3 +1 +3 St. Tacky Unchanged Unchanged Tacky Unchanged Magnesium Chloride Magnesium Sulfate Nickel Sulfate Potassium Chloride Potassium Permanganate +0.38 +0.69 +0.11 +0.56 +a.34 94.0 94.6 94.6 98.8 80.7 96.7 96.7 99.4 100.0 87.7 +3 +4 +3 +1 -3 Unchanged Unchanged Unchanged Unchanged Brittle Potassium Bisulfite Potassium Dichromrte Sodium Borate (Borax) Sodium Bicarbonate Sodwm Chloride Zinc Chlor& Zinc Nitrate +7.80 +0.63 +0.73 +0.12 -0.99 +0.23 +0.24 102.0 99.4 103.9 100.0 96.7 100.0 94.7 -4 +3 +3 +2 +3 +3 +4 Unchanged Unchanged Unchanged Unchanged Unchanged St. Tacky St. Tacky ORGANIC ACIDS Acetic Acid (10%) Acetlc Acid (Glacial) Chloracetlc Acid (10%) Citric Acid (10%) Fonmc Acid (10%) Lactic Acid (10%) Olelc Acid (100%) +5.63 +10.7 +5.45 +0.38 +4.15 +0.45 +95.7 103.9 92.2 99.0 101.4 105.9 100.0 59.4 -1 -9 -1 +3 +2 +2 -27 SI. Tacky SI Tacky Sl. Tacky SI. Tacky Sf. Tacky Sl. Tacky Unchanged INDRCANIC SALTS (25% Solutions) Alummum Chloride 113.3 98.8 100.6 98.8 93.4 98.2 93.4 103.0 88.6 133.1 98.8 107.2 98.8 45.8 (continued) Rubbers and Elastomers TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS 315 (continued) 12 Months immersion at 75O 2 5’F Hardness ChanPcPts. surface Condition VolUmC charwe x TenaifeSbangth Retained K Elongation Retained% +0.12 +7.35 +4.50 +2.07 +18.6 +1.05 +1.08 105.4 115.1 98.8 101.2 108.4 100.0 100.6 104.9 112.4 109.8 99.4 108.4 96.1 103.9 +4 -11 -14 +2 +2 -1 +3 Sl Tacky SI. Tacky Sl. Tacky SI. Tacky Unchanged Sl Tacky Tacky +2.79 +0.89 +1.53 +1.64 -0.36 104.8 94.0 92.2 97.6 94.6 103.9 96.1 96.1 96.1 92.2 -8 -2 -2 -2 f4 SJ. Tacky Si. Tacky SI. Tacky SI. Tacky SI. Taccky Rtsorclool +1.26 +6.60 +12.0 95.2 84.3 108.4 89.6 96.7 99.4 +2 -11 +1 Unchanged Sl. Tacky SI Tacky ALDLHYDES Benzaldthyde Butyraldchydt Furfural +7.28 +17.4 +5.34 92.2 91.6 103.6 98.6 102.6 103.3 -13 -18 -9 SI. Tacky Unchanged Tacky 98.8 94.0 58.4 103.9 90.2 77.8 -13 +3 -9 Unchanged SI. Tacky Unchanged Oxalc Acld (10%) Phenol (10%) Phenol (100%) PICNICAcid (10%) Stcarx Acid (100%) Tannx Acid (10%) Tartarlc Actd (10%) ALCOHOLS &nzyl Alcohol Ethyl Alcohol lsoprowl Alcohol Methyl Alcohol Ethylene Glycol Glyctrd 1 -Htranol AMINES Antlmt Trwthanolammt UDMH -l-7.33 -l-o.77 +7.00 ESTERS Amy1 Acetate Dlbutyl Sabacate 01octyl Phthalatt Ethyl Acetate Tricrtsyl Phosphate +45.7 +19.3 +9.13 +8.75 +0.49 39.8 85.5 104.8 78.3 101.8 48.4 103.3 109.2 88.2 102.6 -24 -17 -12 -12 +2 Unchanged Unchanged SI. Tacky Unchanged Tacky nlims D~btnryl Ether D+tthyltnt Glycol Monobutyl Ether Ethyl Ether Ethylene Glycol Monoethyl Ether +9.56 +3.85 +60.2 +4.35 106.6 96.4 31.3 101.2 103.9 106.5 35.3 103.9 -13 -10 -27 -7 Unchanged Unchanged Unchanged SI. Tacky +84.0 +218.5 -f-142.9 20.5 16.3 21.7 26.9 17.1 24.9 -30 -32 -32 Unchanged Sl Tacky Unchanced Xyltnt +142.0 +125.5 +41.9 +128.5 +142.5 19.3 21.1 89.2 18.7 19.9 21.0 23.5 79.0 26.1 21.6 -30 -28 +2 -31 -31 HALDGENATED HYDROCARBONS Btnryl Chlonde Bromobenrcne Carbon Tttrachloridt Chloroform Ethylene D&chloride Pcrchlorotthvltne +26.1 +118.0 +207.1 +169.5 +25.8 +200.5 56.0 22.9 19.9 19.3 52.4 16.3 79.8 26.1 19.6 22.2 62.7 18.2 -21 -32 -32 -33 -18 -33 T=ky St. Tacky Unchanged !X Tacky SI. Tacky Unchanged HYDRDCARBDNS 8tnzent Cyclohcxant Ethvlbtnztnt Htptant Htrant Naphthalane Tdutnt !X Sl. St. Sl. Sl. Tacky Tacky Tacky Tacky Tacky OTHER SUBSTITUTED HYDRDCAR8ONS Carbon Disulfidt Nltrobtnrene +87.0 +3.36 16.9 94.6 21.0 101.4 -31 -11 Sl. Tacky TabV KETONES Acetone Methyl Ethyl Ketone Methyl lsobutvl Ketone +6.07 +8.60 +22.0 86.7 83.1 56.6 90.8 88.8 75.1 -8 -11 -17 SI. Tacky Sl. Tacky SI. Tacky (continued) 316 Corrosion Resistant Materials Handbook TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS (continued) 12 Months Immersion at 75“ 2 S°F vohuna liardness ChangaPts. +0.63 +2.30 +1.85 +1.41 -10.6 102.4 106.0 109.6 98.2 97.0 103.9 103.9 107.8 105.3 98.0 +3 +2 +1 +2 +3 SI. Tacky Unchanged Unchanged Sl. Tacky SI. Tacky +3.34 +1.53 +0.96 -0.74 +1.77 101.2 101.8 98.8 97.6 100.7 105.3 100.6 105.3 98.0 99.0 -1 +3 +3 +4 +3 SI. Tacky Unchanged Unchanged St. Tack-y TaCkY +28.4 -1.31 +11.1 +17.8 +27.9 +18.3 +108.5 88.6 98.2 116.9 99.4 101.2 101.2 34.3 100.0 103.3 115.1 109.2 105.3 107.8 38.6 -16 +3 -13 -13 -16 -14 -33 SI. Tacky Tacky SI. Tacky Unchanged Unchanged Sl. Tacky Sl. Tacky Heatmg Fuel Oil Jet Awcraft Engine Oil Kerosmc +45.8 +5D.6 +151.8 +128.4 +156.1 + 140.0 +176.0 -l-44.7 +139.8 43.4 50.0 31.3 22.9 13.9 18.1 20.5 w.2 18.1 56.9 54.3 30.0 24.2 22.9 21.0 22.9 77.8 20.2 -23 -22 -32 -29 -32 -33 -33 -23 -32 Unchanged Si. Tacky Unchanged Unchanged St. Tacky SL Tacky Unchanged Unchanged Unchanged AUTOMOTIVE PRODUCTS Chassis Grease Motor 011 (lOW.30) Gasolmc (RON 94) Gasolmc’ (RON 99) Gasol~nc* (RON 102) Gasoline.” unleaded +53.6 + 149.8 +16D.9 +183.4 -l-203.7 +151.7 38.6 32.5 17.5 18.7 17.5 18.1 43.1 38.6 21.0 21.6 21.0 19.6 -26 -33 -34 -31 -36 -33 Unchanged Unchanged SI. Tacky Sl. Tacky SI. Tacky Sl. Taskv LestoIl (1%) Lur Flakes (1%) Rmre Dry (1%) Rmse Dry (Cont.) Tide (1%) NATURAL FATS 6 OILS Butter Castor 011 Cononsced011 Lard Oleomargarme Olwe 011 While Mineral 011 sbwtgth surfaa Retained% DETERGENTSLDTHER CLEANING PRODUCTS Calgonltc (1%) Clorox (1%) Clorox (COrlC.) Joy (1%) Joy (Cone ) Tamlk Elongation Ratainad n W% ConditM OILS 6 FUELS A.S.T.M. A S.T.M. A.S.T M. A S.T M. A.S.T.M. A.S T.M. No. 1 011 No. 2 011 No. 3 011 Fuel A Fuel 8 Fuel C HYDRAULIC FLUIDS Oronite 8200 Pydraul F.9 Pydraul 60 Skydrol Skydrol 500 +13.7 +11.2 +6.70 +7.30 +3.37 101.8 103.0 104.8 106.6 110.2 104.5 110.4 106.5 110.4 110.4 -9 -10 -6 -7 -10 Unchanged Tacky Tacky SI. Tacky SI. Tackv 0.00 95.8 96.1 +2 +1.99 +19.4 +1.47 -0.79 98.8 53.0 96.4 94.0 94.7 41.2 99.4 97.5 MISCELLANEOUS Gelatin (sat. sol’n.) Glucose (sat. sol’n.) Tincture of Iodine Preston8 antifreeze Dowgard antifreeze lConvcntmnel motor fuels contaming tetraethyl lead eddihve. Approximab **Motor fuel of “premium” grade containing no tatmethyl lead. 0 -5 -1 +3 Si. Tack-y T=ky Unchanged St. Tacky Unchanged Research Octane Numbers Ind,ceted. (continued) Rubbers and Elastomers TABLE 2.12: VARIOUS CHEMICAL ELASTOMERS RESISTANCE AND RUBBERS-EXXON OF COMPOUND CHEMICALS 317 (continued) BASED ON LOW UNSATURATION BU-I-YL RUBBER 72 Hours Immersion at 212OF Hardness Chanee Pts. vulume channc n Tensite Strength Retained K Elongation Retained K +6.62 +11.0 +20.9 +1.20 +1.46 97.0 103.8 97.8 96.8 90.3 99.4 94.6 98.6 88.1 88.7 -14 -21 -27 +2 -3 Unchanged Unchanged Unchanged Unchanged Unchanged Ethyl Ether Hexane Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone +56.7 +147.9 +4.57 +36.2 +134 28.0 16.7 102.2 87.1 82.8 46.3 24.1 80.6 100.0 87.3 -28 -36 -4 -32 -20 SI. Tacky SI. Tacky Tacky Unchanged Unchanged Perchloroethylene Potassium Permanganate (25%) Skydrol 500 Sudwm Chloride (25%) Sodium Hydroxide (10%) +339.1 +1.47 +13.8 +0.12 +2.67 64.5 94.1 86.6 101.1 102.7 17.7 79.9 96.2 87.0 94.1 -48 +2 -27 -1 -8 Tacky Unchanged Unchanged Unchanged Tacky Toluene Tide (1%) +3D9.3 +1.27 69.9 90.9 26.9 87.3 -53 Unchanged SI. Tacky Aniline Benraldchyde Dioctyl Phthalate Distilled Water Ethyl Alcohol Slll-faCe Condition 0 One Month Immersion at 75O -C 5OF vuhmn Change K Tensile Strength Retained K Elongation Retained K +10.0 +6.22 +3.09 -0.71 +0.36 112.9 110.2 104.8 95.2 90.3 103.3 110.8 103.7 94.3 96.2 -13 -17 -1 +4 +2 Ethyl Ether Hexane Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone +61.4 $166.9 -0.38 +4.02 +10.1 26.9 21.0 105.9 105.4 91.4 51.9 27.9 99.4 105.7 93.8 -29 -33 +3 -4 -16 Perchloroethylene Potassrum Permanganate (25%) Skydrol 500 Sodium Chlorrde (25%) Sodwm Hydroxrdc (10%) +251.5 +0.38 +1.89 -0.12 -0.12 14.5 88.7 104.3 98.4 184.3 18.4 84.9 99.4 95.2 96.6 -37 +5 -4 +2 +5 Tacky Brittle SI. Tacky Unchanged Unchanged Tduenc Trde (1%) +171.6 0.00 16.1 99.5 25.5 99.0 -36 +6 TKky T=ky Anilme Benxaldehyde Dioctyl Phthalate Distilled Water Ethyl Alcohol Hardness Change PCs. Surtace Cundiiiun Tacky Tacky Tacky Unchanged Tacky SI. SI. SI. Sl. SI. Tacky Tacky Tacky Tacky Tacky Three Months immersion at 75O f IoF VOtUme Ct=W% Aniline Benraldehyde Dioctyl Phthalatc Distilled Water Ethyl Alcohol +9.00 +6.74 +5.06 -0.83 +0.11 Tensile Stmngttt Retainad % Elongation Retained% 98.4 103.8 100.0 109.7 90.3 101.4 97.2 99.0 99.0 97.2 -12 -17 -7 +5 -1 SI. Tacky Tacky Tacky Unchanged Unchanged Hardness ChangePts. Swface Condition Ethyl Ether Hexane Hydr&hloric Acid (10%) Lard Methyl Ethyl Ketone +57.5 +X2.4 +0.38 +9.72 +7.55 31.2 18.3 98.4 111.3 93.6 50.5 25.9 97.6 103.3 94.3 -27 -32 +2 -8 -14 Unchanged Sl. Tacky Unchanged Unchanged St. Tacky Perchloroethylene Potasswm Permanganate (25%) Skydrd 500 Sodium Chloride (25%) Sodium Hydroxrde (10%) +264.2 +4.30 +4.40 -0.97 +1.16 14.0 95.7 lM.8 101.1 97.3 19.4 89.1 101.4 94.8 96.6 -38 +5 -12 +6 +4 St. Tacky Unchanged Unchanged Unchanged Unchanged Toluene Trde (1%) +187.4 0.00 17.2 102.2 27.3 98.6 -37 +2 T=ky SI. Tacky (continued) 318 Corrosion Resistant Materials Handbook TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS (continued) Six Months Immersion at 75O _C5OF vokune Change K Tensile Strength Retained K Elongation Retainad % +4.15 +1.87 +8.42 -0.71 -0.24 103.8 97.9 102.2 101.1 89.3 100.0 99.4 99.4 96.2 97.6 -12 -15 -9 +4 -2 SI. Tacky Tacky Tacky Unchanged SI. Tackv Aniline Benzaldehyde Dioctyl Phthalate Distilled Water Ethyl Alcohol Hardness Change PM. Surface Condition Ethyl Ether Hexane Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone +54.5 +162.5 +0.38 +12.0 +8.65 33.3 18.8 100.0 116.1 91.9 48.5 26.9 88.7 101.8 91.5 -28 -36 +3 -16 -13 Unchanged Tacky Unchanged SI. Tacky SI. Tacky Perchloroethylene Potassium Permanganate (25%) Skydrol 500 Sodium Chloride (25%) Sodwm Hydroxide (10%) +256.5 +7.06 +5.73 -!-0.24 +0.58 14.5 96.2 101.1 97.3 103.2 20.2 88.7 99.0 96.6 95.8 -39 -3 -13 +5 +4 Tacky SI. Enttle Unchanged Unchanged Unchanged Toluene Tide (1%) +166.3 +0.37 18.3 103.8 -37 +3 T=ky SI. Tacky 28.7 104.2 12 Months Immersion at 75” 2 5OF votume Change W Tensile Strength Retained K +6.00 +4.65 +11.6 +0.12 -I-o.97 96.2 97.9 102.7 102.2 93.6 100.4 98.6 112.7 99.7 100.0 -12 -15 -18 f3 -2 SI. Tacky SI. Tacky Tacky Unchanged St. Tacky Andme Benraldehyde Omctyl Phthalate Olstllled Water Ethyl Alcohol Elongation Retained % Hardness Chanee Pts. Surface Condition Ethyl Ether Hexane Hydrochloric Acld (10%) Lard Methyl Ethyl Ketone +48.8 +123.2 -0.13 +21.8 +7.93 29.0 15.1 104.3 111.3 100.5 46.3 28.7 97.6 103.3 92.9 -31 -37 +1 -23 -12 Unchanged SI. Tacky Unchanged SI. Tacky SI. Tackv Perchloroethylene Potaswum Permanganate (25%) +262.1 +7.95 +4.81 -l-O.48 +0.81 15.1 89.3 101.6 96.8 100.0 18.8 87.7 99.4 97.2 94.8 -41 +4 -12 +2 +5 Tacky SI. Brittle Unchanged Unchanged Unchanged i-131.9 +1.73 13.4 103.8 28.7 98.6 -38 +5 TafkV SI. Tacky Skydrol 500 Sodwm Chloride (25%) Sodturn Hydroxide (10%) --__ Toluene Tide (1%) CHEMICAL RESISTANCE OF CHLOROBUTYL 1066 COMPOUND 72 Hours Immersion at 212°F Vdume Change W Tensile Sbemzth Retained 4 qongation Ret&d K Hardness Change Pts. Surface Condition Aniline A.S.T.M. No. 1 Oil A.S.T.M. No. 3 Oil Benzaldehyde Oioctyl Phthalate -l-7.86 +78.8 +168.1 +50.8 +29.0 95.0 47.0 28.3 67.2 75.3 93.4 62.8 51.1 57.2 68.9 -3 -27 -34 -14 -16 Unchanged SI. Tacky Sl. Tacky SI. Tacky Unchanged Distilled Water Ethyl Alcohol Ethyl Ether Cesoline (RON 99) Hexane +6.96 +4.92 +62.6 +167.1 +129.0 98.0 92.4 38.9 21.7 29.8 74.6 72.9 40.7 28.9 28.9 0 -1 -20 -34 -25 SI. Tacky Unchanged SI. Tacky Unchanged Unchanged Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potassium Permanganatu (25%) +4.07 i-27.2 +19.9 +262.4 +2.59 102.0 78.3 61.6 18.7 97.0 84.0 67.5 61.2 21.9 72.9 fl -16 -14 -33 +1 SI. Tacky Unchanged Unchanged Unchanged Unchanged (continued) Rubbws TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS and Elastomers 319 (continued) 72 Hours Immersion at 212OF VOlUtVW Shydml500 Sodium Chloride (25%) Sodium Hydroxide (10%) Tolutnc Tide (1%) UDMH Elongation surface Hardness Change Fts. Qunp% Tonsik sb-tngm Ret&W K Retained W +19.4 +0.96 -Il.92 +238.2 +5.94 74.8 104.5 102.0 17.7 99.5 74.6 76.0 64.7 29.9 76.0 -15 +1 +1 -41 -2 Unchanged Unchanged SI. Tacky Unchanged SI. Twkv +18.6 84.9 45.7 -14 Unchanged Condiitm One Month Immersion at 75O t IoF VdUmC Change K Andme Tensile Strength Retained K Elongation Retained% Hardness Change-. Surface Condii A.S.T.M. No 1 011 ASTM No. 3 Oil Benzaldehyde Dioctyl Phlhalatt +4.89 +11.1 +39.5 +21.9 +2.71 91.9 84.3 53.5 71.7 95.5 87.1 75.3 49.4 62.8 85.4 +1 -4 -13 -9 +2 Tacky SI. Tacky Unchanged Tacky SI. Tacky Distilled Water Ethyl Alcohol Ethyl Ether Gasoltnt (RON 99) Hexane Lo.11 +1.78 +w.4 +158.2 + 138.4 102.0 99.0 34.9 25.8 28.3 91.8 91.1 35.3 23.5 25.2 +2 +3 -20 -23 -21 Unchanged Tacky SI. Tacky Unchanged SI Tackv Hydrochloric Acld (10%) Lard Methyl Ethyl Ketone Perchlorotthyltnt Potasswm Pennanganatt (25%) +0.68 +3.75 +16.7 + 170.0 +0.69 103.5 90.9 77.3 24.2 102.5 93.4 64.7 66.6 21.2 84.7 +3 -4 -10 -23 i-4 Unchanged 51. Tacky Sl. Tacky SI. Tackv Unchangid Skydrol500 Sodium Chloride (25%) Sodwn Hydroxide (10%) Tolutnt Tide (1%) +2.45 -0.12 0.00 +179.9 +1.01 101.5 104.5 102.5 29.3 101.5 91.1 91.8 92.5 28.2 92.5 +2 +2 +4 -22 d-4 SI Tacky Unchanged Unchanged SI. Tacky Unchanned 77.6 -11 Unchanged Three Months Immersion at 75O * 5OF Vdume Chanm K TmsikStren#h Retained X Ekmgation Retained% Hardness Chanfp Pts. Surface Conditb Amline A.S T.M. No. 1 Oil A.S.T.M. No. 3 011 Btnzaldehydt Dioctyl Phthalatc +6.64 +21.8 +114.s +31.7 +6.32 94.4 77.8 46.0 63.1 97.0 90.1 65.9 37.5 54.1 65.4 0 -9 -21 -10 -1 SI. Tacky Unchanged Unchanged Tacky SI. Tackv Distilled Water Ethyl Alcohol Ethyl Ether Gasoline (RON 99) Htxant +0.58 +1.46 +62.8 +193.2 +156.3 104.0 93.9 33.8 30.3 30.8 91.8 m.0 36.9 27.5 25.9 +4 -3 -20 -22 -21 Unchanged Sl. Tacky Unchanged Unchanged St. Tacky Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Ptrchloroethyltnt Potassium Ptrmanganatt +0.63 +8.20 +15.6 +220.0 98.0 96.0 74.2 22.2 +2.41 100.5 87.8 87.1 64.2 19.5 86.4 -l-3 -5 -9 -23 +4 Unchanged Unchanged Unchanged SI. Tacky Unchanged +2.80 0.00 99.5 103.0 99.0 29.3 100.0 65.4 88.7 64.0 27.5 87.8 +1 i-4 +2 -21 +1 SI. Tacky Unchanged Unchanged Unchanged Unchanged 72.7 68.9 -11 Unchanged Skydrol500 Sodium Chloride (25%) Sodium Hydroxide (10%) Tolutnt Tide (1%) UDMH (25%) -f-O.46 +182.5 +1.13 +17.0 (continued) 320 Corrosion TABLE 2.12: Resistant VARIOUS Materials Handbook ELASTOMERS AND RUBBERS-EXXON CHEMICALS (continued) Six Months Immersion at 75O 2 5OF Vdurm W% Tansik Strength Ret&ad % Elongation Hardness Retained SC ChangePts. Surtaca Condition Amline ASTM No. 1 oil A.S.T.M. No. 3 Dil Senraldehyde Dioctyl Phthalata +4.05 +43.7 +157.0 +36.5 +9.38 96.5 66.2 43.4 54.0 93.4 91.8 55.8 33.6 48.7 82.4 -15 -25 -11 -4 Distilled Water Ethyl Alcohol +1.97 +1.43 +59.8 +189.0 +131.6 loo.5 100.0 37.4 24.8 31.8 81.7 88.2 36.9 26.6 26.6 +2 +1 -21 -25 -21 Unchanged SI. Tacky Unchanged SI. Tacky Sl. Tacky Lard Methyl Ethyl Ketona Perchlomethyltna Potassium Pcrmanganate (25%) +0.89 +14.7 +14.7 +213.4 +4.59 100.0 90.9 77.8 24.2 106.1 87.1 76.0 64.2 20.5 86.4 +4 -9 -9 -23 +4 Unchanged St. Tacky Unchanged Unchanged SI. Brittle Skydrd 500 Sodium Chlorida (25%) Sodium Hydroxida (10%) Toluene Tide (1%) +4.79 +0.12 +0.23 +191.3 +2.27 98.5 97.0 112.5 31.3 100.0 87.1 84.0 87.8 26.6 83.1 0 +4 +4 -23 fl Sl. Tacky Unchanged Unchanged SI. Tacky Unchanged +14.5 73.7 71.3 -9 Sl. Tacky Ethyl Ether Gasoline (RON 99) Herant Hydrahloric Acid (10%) UDMH 0 Tacky Sl. Tacky Unchanged T=ky Sl. Tacky 12 Months Immersion at 75O 2 5°F VOlUnW Changa n Tensile Stigth Retaimd W Elongation Retained% Hardness ChangePtm Surfaa Condition Aniline A.S.T.M. No. 1 Oil A.S.T.M. No. 3 011 Btnzaldehyde Dioctyl Phthalate +7.58 +52.8 + 135.0 +44.5 +12.8 89.9 63.6 39.9 49.5 96.0 92.5 54.1 33.7 46.4 82.4 -3 -20 -21 -13 -6 Tacky St. Tacky Unchanged Tacky Sl. Tackv Distilled Water Ethyl Alcohol Ethyl Ether Gasoline (RON 99) Htxant f2.56 +2.82 +70.0 + 155.0 +110.4 101.5 99.0 34.3 25.8 25.8 88.7 82.4 37.6 25.2 29.9 +4 +2 -22 -26 -28 Unchanged Sl. Tacky Unchanged Sl. Tacky Sl. Tacky Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchlorotthyltnt Potassium Ptmanganatt (25%) +1.90 +19.9 +14.1 +220.0 +6.64 101.5 87.4 75.3 21.7 98.0 80.7 81.2 66.6 22.3 77.6 +5 -11 -8 -25 +4 Unchanged Sl. Tacky Skydrol500 Sodium Chloride (25%) Sodium Hydroxide (10%) i-5.27 +0.25 +0.80 +127.5 f4.03 97.0 98.0 100.5 25.8 102.0 88.7 86.4 84.0 27.5 87.4 -1 +4 +2 -22 +4 SI. Tack-y Unchanged Unchanged Sl. Tackv Sl. Ta& 72.2 72.2 -10 Unchanged Tolutnt Tide (1%) UOMH +13.5 CHEMICAL RESISTANCE OF VISTALON Sl. Tacky SL Brittle 404 COMPOUND 72 Hours Immersion at 212OF Volume Changa K Anlllnt A S.T.M. No. 1011 A.S.T.M. No. 3 011 Benraldehyde Dtoctyl Phthalate f560 * 129.2 +216.4 126.4 139.6 Tensile Strangth Retained K Elongation Retainad K 105.0 53 3 38.9 85.0 88.5 114 0 46 2 33.3 80.3 82.8 Hardness Change Pts. -3 -34 -35 -13 -18 Sutfaw Condition SI. Tacky Swollen Swollen SI. Tacky Unchanged (continued) Rubbers and Elastomers TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS 72 Hours volume Change W DIstIlled Ethyl Ethyl Water Alcohol Ether Gasolme (RON 99) Hexane Hydrochloric Hydrochloric Lard Acid Aud (10%) (Cow.) Methyl Ethyl Ketone Perchloroethylene Potassium Permanganate Skydrol 500 Sodturn Chloride Sodium Sulfuric Hydroxide (10%) Acid (Cont.) (25%) (25%) ltde (1%) Toluene UDMH 106.1 102.2 +2 Unchanged 105.0 36.5 -4 -28 Unchanged Unchanged + 187.8 38.4 35.2 -37 Swollen +177.6 36.9 30.2 -30 SI. Brittle +5.80 +37.7 +64.0 100.0 88.0 80.5 69.2 72.6 66.7 -10 -26 Unchanged Swollen + 16.3 +207.1 83.0 23.6 78 3 40.4 -12 -40 Unchanged Unchanged +0.84 +9.54 103.7 99.8 +0.93 111.5 +0.40 107.0 Dtstllled Ethyl Ethyl Water Gasoline Herane (RON 99) Hydrochloric Acid Hydrochlow Aced (Cone (10%) ) Lard Methyl Ethyl Ketone Perchloroethylene Potassium Permanganate Skydrol 500 Sodturn Chloride f25%) Sodpum Hydroxide Sulfuric Aced (Cone I (25%) (10%) ( I ?P, ) -4 Unchanged Unchanged 0 +3 Unchanged Unchanged 136 Cracked 102.7 22.6 100.0 30.2 +1 -35 Swollen Unchanged 86.4 97.5 -11 Unchanged Month Immersion Tensile Strength Retained SC at 75O 2 YF Elongation Hardness Retained SC Change Pts. 109.5 -2 57.2 46.8 47.2 34.0 -23 -29 79.8 103.6 76.8 94.0 -8 -4 Unchanged Unchanged ‘5 Unchanged -0.10 109.3 105 101.9 102.5 36.9 38.5 -27 +166.8 40.8 33.3 -30 + 190.9 36.4 28.9 -32 +0.94 114.4 110.1 +7.53 101.6 116 +23.9 +8.59 +93.3 93.2 92.7 45.8 +1.04 SUliWX Condiiion 103.8 +0.12 +99.9 94.5 1 Swollen SI Brlttle SI. Tacky 83 8 SI Unchanged Unchanged Unchanged -8 Unchanged Unchanged Unchanged +0.14 103.6 99.5 +3 74.4 107.1 +4 ‘3 .: 6 Unchanged Unchanged .‘6 28.9 99.3 Tacky -13 -8 -29 103.8 103.8 112.3 34.0 93.7 Sl. Tacky Si. Tacky -I 3 83.6 83.6 44.3 lacky Swollen Swollen 15 7 104.3 107.8 61.1 St .h 1 +1.08 +0.02 +0.43 +182.9 +7.68 I de Toluene UDMH +5 Brittle +10.1 ) 94.3 101.0 +0.91 +218.1 +15.9 +9.08 Alcohol Ether Unchanged +57.9 +70.1 +214.4 Benzaldehyde Dloctyl Phthalate +1 101.8 91.0 Brittle +2.14 1 011 3 011 Surface Condition 107.7 41.5 One M No M. No Hardness Change Pts. +0.65 volume Chanp SC Anlllne Elongation Retained W -1.31 +97.0 +16.5 A ST A ST (continued) at 212OF Immersion Tensile Strength Retained w 321 -31 -4 Sl Tacky Unchanged Unchanged Three Months Immersion at 75O f 5*F VOlUllW Change K +2.26 Andme A S.T.M Elongation Retained % Hardness Change Pts. Surface Condition 103.8 110.8 1011 + 108.4 51.7 44.8 -27 3 Oil +218.4 39.4 32.7 -31 +27.3 77.8 74.4 -8 Unchanged No. A S.T M. No. Benraldehyde Tensile Strength Retained W ‘2 Unchanged Swollen Swollen Dloctyl Phthalate +9.92 103.7 101.0 -3 Unchanged Dlst!lled Water +0.44 106.9 106.5 -’ 5 Unchanged +0.25 +94.4 97.2 40.8 104.5 42.8 -. 4 -28 Unchanged Unchanged 43.4 32.5 35.8 32.7 Ethyl Ethyl Alcohol Ether Gasoline Hexane LRON 99) +183.5 +175.8 Hydrochloric Actid (10%) Hydrochlonc Lard Acid Methyl Ethyl Ketone Perchioroethylene (Cow t1.02 ) 105 0 106 -33 -30 5 ‘6 +11.0 95.5 1130 +20.9 85.2 92.8 -14 +8.54 188 1 98.5 41.8 93.7 46 8 -5 -27 -2 Swollen Swollen SI Tacky Unchanged Unchanged Sl. Tacky Swollen (continued) 322 Corrosion Resistant Materials Handbook TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS (continued) Three Months Immersion at 75O f 5OF Volume Chane % POtaSslUm Permanganate 500 Skydrol Sodium Chiorlde Sodfum T!de (10%) ) aa 5 105 1 2 0.15 20 28 ;07 a 103.7 106 101 5 a -3 ~’ 7 39 9 48 2 -1 100 0 a7 a 102 -0.56 Toluene 7 Six Months immersion Tensile Vdumr Change % Anlllne A S T M. No. 1 011 A S T M. No. 3 011 -199 1130.0 1213.5 aewaldehyde +3a 2 Dmctyl J-10 1 Phthalate Ethyl Ethyl --0.66 Water Distilled Gasoline (RON 99) Hexane Hydrochlow Acid (1046) Hydrochlorfic Lard Methyl Ethvl Acfd (Cont.) Ketone 500 Chloride Sodturn Hydroxfde Sulfurtc Acjd Tide Unchanged Unchanged 5 107 2 -6 103 a 104 4 -6 Unchanged 101 a 410 -3 Unchanged 99 a 39 4 105 103 103 1018 1 011 f144 2 A ST 3 011 +211 8 M. No 103 +10 10 55 -0.06 +107.5 ‘Olstllled Water Ethyl Alcohol Ethyl Ether Gasoline (RON 99) Hexane Hydrochloric Hydrochlorx Lard Acid (10%) Aced (Cow ) Potassium Sodturn Hydroxide Sulfuric Acid Tide (1%) Toluene UDMH (Cow (25%) (10%) ) Unchanged Unchanged SI Tackv -26 swoiler!: -3 - -2 -4 Unchanged Unchanged -4 Unchanged -2 Unchanged 30.4 91.7 a -4 32.5 96 a -27 -3 103 SI Tacky Swollen Unchanged Months Immersion at 75O 2 5OF Tensile Strength Retained % 4 53.2 42.8 108 Elongation Retained % 108.3 -1 44.2 -29 75 0 107 9 107.4 38 5 Swollen SI -12 5 -6 108 9 108 2 40.3 -3 -2 -25 104 Surface Condition Unchanged Swollen -29 34.1 9 Hardness Change Pts. Tacky Unchanged Unchanged Unchanged Unchanged Swollen 42.8 34 6 -30 32.5 30 a -28 Swolfen 108 2 82 7 79 4 -2 -4 -16 SI. Tacky 98.6 424 96.9 49 4 -6 -30 98.8 1104 99 3 103 3 -1 Unchanged A3 -1 Unchanged Unchanged -3 Unchanged +2.50 +1.01 (25%) -18 -6 +193.5 +103 ‘1038 Permanganate 500 Chloride 7 SWOilen Swollen SI Tacky f179.4 fl54 123 3 132.1 Methyl Ethyl Ketone Perchloroethyiene Skydrol Sodium 5 2 2 Unchanged -30 -27 -4 -3 28 3 81.3 +31.3 Phthalate Dloctyl 7 23 4 105 ‘1.90 A S 1 M. No Benraldehyde 32.5 108 2 98 2 106 5 99 a 12 Anllloe -25 37 a -1.05 ‘007 Volume Change % Swollen 105 94 3 +I564 19 74 Toluene UDMH Surface Condition -27 -10 40.3 6 Hardness Change ph. 37 6 74 4 93.7 - 0 53 (1%) Retained % -2.65 - 0 33 Unchanged at 75O t 5OF Elongation a5 5 90 4 45 7 142 Unctiangod SWOlll?fl 414 77 4 a6 a a3 0 94 0 (10%) (Cow.) -7 -31 -3 Unchanged Swoller! +14 a +34 a +a.09 (25%) Unchanged l$hanged -1 -25 32 3 97 2 - Skydrol Sodaurn Unchanged Unchanged 103.2 44 a 1167 3 -1.63 a 0 98.5 51 2 42.8 (25s6) Permannanate Retained % 1-181.6 +a6 Perchloroeihylene Potassium 28 5 -0 187 Alcohol Ether Strength - ‘6 32 7 100 0 31.1 93.7 +169.9 ‘a.98 UDMH surface Condition Hardness Change Pk. 104.3 i 32.2 (I?,,) U0tlgG3tihl Retained K 2.67 11.15 A 125%) Hydroxide Acid (Cow Sulfurrc (25%) Tensile Strength Retained % +o 01 LO.19 ‘767 1O +178.6 i12.4 69 110.2 75 a 83.8 103.2 101 9 10.3 100 0 102 5 52 109.8 106 37 9 102 4 2 32 a 98 2 Unchanged Unchanged SI. Tacky SWOllell 0 -2 -30 -a SI Tacky Swollen Unchanged (continued) Rubbers and Elastomers TABLE 2.12: VARIOUS ELASTOMERS CHEMICAL AND RUBBE:RS-EXXON RESISTANCE CHEMICALS 72 HOWSimmersion chnp% +1.72 Anlllne (continued) BASED ON HIGH MOONEY EPDM OF COMPOUND VdUlIla Tamilc stnmgm Rabinad % at 212OF Elongation Ratainad W Hardnasa Changa Pts. Surface Condition 98.5 87.6 No. 1011 t83.1 51.7 49.5 -25 SWOllen A.S.T.M. No Senzaldehyde 3 Oil +119.9 +12.8 35.9 77.0 37.2 72.4 -28 -10 Swollen Unchanged 83.0 73.0 -11 A.S.T.M Dloctyl Phthalate Dlstllled +24.7 +1.10 Water Ethyl Alcohol Ethyl Ether Gasoline -3.47 (RON 99) Hexane 104.7 -1 85 0 SI. Tacky Unchanged 0 95.6 83.6 +62.6 36.0 36.3 -16 +121.8 35.5 38.0 -25 +93.4 28.1 25.8 -18 Unchanged +1 Unchanged Unchanged Swollen Unchanged Hydrochloric Acid (10%) +14.6 74.8 60.0 Hydrochloric Acid (Cont.) +32.3 70.7 60.9 -8 Unchanged +38.9 +5.15 65.0 72.1 63.7 73.5 -19 -7 Unchanged Unchanged -27 Lard Methyl Ethyl Ketone Perchloroethylene +109.7 Potasswm Permanganate Skydrol 500 Sodium Chloride Sodurn Hydroxide Sulfuric (Acid Tide (1%) (25%) (25%) (10%) (Cow.) Toluene Unchanged 20.7 31.4 99.5 104.4 78.0 89.5 +2.69 94.7 73.5 0 Unchanged +0.43 98.8 74.3 0 44.7 0 t29 Unchanged Cracked 88.6 77.2 t1 Unchanged 23.0 30.6 -25 Unchanged 70.1 66.5 -1 Unchanged t150.2 UDMH 0 +1.65 +2.08 t66.9 t1.63 +5.22 323 Unchanged Unchanged Unchanged +1 -1 Ona Month Immersion at 75O -C S°F VOIUIIN USC AnNlIne A S T.M No 1 011 A S.1 M No Senraldehyde 3 011 Dloclyl Elongation Ratainad% Hardnass ChangaPls. sulfaca Condition 93.4 90.7 -1 56.7 48.5 -13 Swollen 44.7 75.4 35.9 71.4 -16 -4 Swollen SI. Tacky SI. Tacky Phthalate +3.35 91.2 87.7 -2 Unchanged Water to.37 104.5 94.4 i2 Unchanged -0.65 +61.6 97.5 33.3 89.5 36.3 -~ 1 -12 SI. Tacky SI. Tacky t 106.9 42.8 363 +119.2 32.7 25.8 -17 -13 Dlstllled Ethyl Ethyl t 5.05 t53.1 t 128.6 +3.00 Tans& Srw#h Ratained n Alcohol Ether Gasoltne (RON 99) Herane Hydrochlonc Acld (10%) Hydrochloric Lard Acid (Cont.) Methyl Ketone Ethyl Perchloroethylene Sodium Sodium Chloride (25%) tivdroxlde (10%) Sulfuric (Acid Trde (1%) Tolue& UDMH +1.22 104.2 94.4 t4.37 t20.8 102.4 77.7 92.3 ‘1 +2 76.3 -8 Unchanged Unchanged +0.28 76.5 77.2 -1 Unchanged 37.4 36.3 -17 +0.59 -5.99 105.4 102.4 96.3 +0.04 +0.45 102.2 104.5 93.5 +73.5 Potassium Permanganate Skydrol 500 (25%) (Cont.) t7.81 t 1.61 +121.1 t1.65 . T_sbryth bt&md% c t4.97 Months Unchanged Unchanged Unchanged 12 t2 95.2 37.8 52.3 Unchanged -t2 97.2 100.8 28.5 75.2 lhroa AnlIme Swollen Unchanged Unchanged Unchanged Unchanged *2 ‘6 94.4 +3 26.6 60.8 -16 -c2 SI. Tacky Unchanged Unchanged Immanion at 7b0 2 So* w Hafdnesf Retainad % Surfaa? -- Change RI. Conditkw 90.8 89.5 -1 A.S T.M No. 1 011 +75.0 51.7 46.7 -17 A S.T.M No. 3 011 +128.4 36.5 30.6 -17 t7.30 +3.52 83.8 99.5 80.8 97.2 -4 -2 Unchanged Unchanged +0.69 106.0 97.2 -2 Unchangeg -0.67 95.8 91.5 ‘1 Unchanged 39.6 40.8 -13 Sl. Tacky +111.1 43.8 400 -18 Swollen +111.4 30.4 31.5 -15 Swollen Senzaldehyde Ouoctyl Phthalate Dbstllled Water Ethyl Alcohol Ethyl Ether Gasolmc Hexane (RON t63.7 99) - Unchanged Swollen Swollen (continued) 324 Corrosion Resistant Materials Handbook TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS Three Months Vdume chanm Hydrochlonc Hydrochloric Acld (10%) Acid (Cont.) Lard Methyl Ketone Ethvl Perchloroeihylene Potassium Permannanate - Skydrol 500 Sodwm Sodlum Chloride (25%) Hydroxide (10%) Sulfuric (Acid (25%) (Cont.) Tide (1%) Toluene UDMH Tensile Strength K Retained n ASTM No Benzaldehyde -1 +0.23 +0.26 103.8 99.5 97.8 93.5 i- 1 +3 Unchanged +32.1 35.5 22.8 -9 Unchanged +1.90 +117.3 102.2 26.1 97.2 29.4 -‘2 -16 89 5 71.8 Ketone Perchloroethylene Potasswm Permanganatc Skydrol Sodwm 500 Chloride Sodium Sulfuric Hvdroxidc (10%) (Aced (Con; ) Tide (25%) (25%) ’ (1%) Toluene UDMH Dloctyl Phthalate Dlstllled Water Ethyl Alcohol Ethyl Ether Gasolme (RON 99) Hexane Hydrochloric Acid (10%) Hydrochloric Lard Acid (Cont.) Methyl Ethyl Ketone Perchloroethylenc Potasswm Permanganatc Skydrol 500 Sodium Sodwm Chloride (25%) Hydroxldc (10%) Sulfuric (Acid Tide (1%) Toluene UDMH (Cont.) (25%) 5’F Hardness Chance Pts. Sur(aa Condition 48.5 -15 -1 Unchanaed SwolleG +129.7 +9.90 41.8 87.8 37.8 80.0 -15 -3 SWOlle” Unchanged -2 Unchanged 95 3 94 4 96.4 104 2 93.2 100 0 87.7 38.9 35.5 40.0 37.8 .1 Unchanged -1 Unchanged -11 -17 Sl. Tacky Swollen -14 Swollen 30.4 31.5 +2.00 97.5 89 +12.5 -l-27.0 +0.36 92.6 72.8 76.0 808 74.3 77.2 -2 -10 f73.2 37.3 39 2 -15 f1.88 95.0 89 5 -3 - -5.73 +0.20 91.7 98.8 91.5 95.2 -2 -2 Unchanged Unchanged +0.26 +45.2 100.9 93.5 23.8 11.4 -1 -8 Unchanged Unchanged +1.82 +115.3 +4.30 104.9 26.3 98.0 28.6 ‘1 SI. Tacky 70.0 56.3 -14 +2 Unchanged 12 Months Aniline Unchanged 50.7 Vdunw Change K A S T M No. 1011 A S.T M No 3 011 Eenraldehyde at 75O t Elongation Retained W Unchanged Swollen 93.9 + 103.0 Acld (Cont.) TenslIe strsllgth Retained % Unchanged 0 58.7 Immersion Unchanged +4.55 +59.4 f110.5 Hydrochlortc Lard Methyl Ethyl -2 96.3 -0.51 Acid (10%) Tackv swon;n 91.7 +0.93 Hexane SI 101.8 i-3.72 Hydrochloric Unchanged -0.91 Water 99) -9 -1 -5.95 Phthalate Ethyl Ether Gasolme (RON Condition -17 37.8 Dloctyl Alcohol Surface Pts. 41.4 61.7 85.7 -l-72.8 Dlstllled Ethyl Change 62.0 85.7 +25.5 +0.62 +85.0 3011 Hardness % SI Tacky Unchanged 83.6 91.5 Vdume C)unm n S T M. No. 1 011 75” + W -1 -1 90.8 97.5 +3.13 AntlIne at Elongation Retained +1.30 +9.43 Six Months A Immersion (continued) Tan80 Strom@ Retained % -2 5 SI 0 Tacky Unchanged Unchanged SI. Tacky Swollen Swollen at 75O 2 5OF Immersion Elongation Retained% Hardness ChangePb. Surtaw Cat&ion +6.53 95.0 95.2 -3 Unchanged +9D.9 +144.4 +7.63 47.8 42.8 87.9 43.7 36.3 80.0 -18 -22 -4 Swollen Swollen Unchanged +4.02 110.3 964 -3 +1.92 +0.33 +69.4 +1104 103.6 100.3 35.3 38.7 94.3 93.5 23.6 36.3 -10 -18 + 128.3 30.4 29.5 -13 +3.86 88.0 80.0 fl +18.3 +27.2 79.7 69 2 66.5 69.5 -9 +2.04 +75.9 74.6 32.7 73.5 31 5 +2.46 -5.47 101.8 100.8 93.4 92.3 -0.14 +0.29 +55.8 96.7 100.8 Broken 87.7 90.6 Broken +19 +2.83 +114.6 105.0 39.9 93.5 30.5 -1 -16 +21.9 61.3 43 Unchanged 0 0 Swollen SI. Tacky 0 -1 -14 +2 Al 6 +2 0 -3 Unchanged Unchanged SI. Tacky Swollen Unchangid Unchanged Sl. Tacky Swollen Unchanged Unchanged Unchanged Si. EMtIe SI. Tacky Swollen Unchanged (continued) Rubbers TABLE 2.12: VARIOUS CHEMICAL ELASTOMERS RESISTANCE AND RUBBERS-EXXON OF HIGHLY LOADED COMPOUND 72 Hours Vdume Change SC Anlllne A.S T.M A S T.M No No -10.7 f57.1 +103.3 1011 3 011 Tensile Strength Retained SC CHEMICALS and Elastomers (continued) BASED ON HIGH MOONEY EPDM Immersion at 212-F Elongation Retained K Hardness Change Pts. 116.0 108.0 65.2 81.9 89.3 68 0 +10 -31 -39 Sur(ace Condition Unchanged Swollen Swollen Benzaldchyde -5.26 102.3 68 0 +4 Dloctyl Phthalate +3.11 112.3 84.0 -2 Water +0.66 117.3 87.1 -16.4 +21.9 110.2 83.8 85.6 68.0 ,+12 -20 +85.6 69.5 68.0 -35 +59.8 58.7 48.2 -28 Unchanged +9.35 +25.2 121.0 109.5 87.1 90.9 -4 -13 Unchanged Unchanged +19.4 -8.71 +68.5 116.0 76.5 60.8 85.6 64.1 60.5 -15 -“348 Unchanged Unchanged Brittle +3.13 -9.89 -0.18 134.0 114.5 123.0 92.5 69.5 89.3 +2 +9 -3 Unchanged Sodium Hydroxide (10%) Sulfuric Acid (Cont.) Ttde (1%) +0.76 +74.2 126.0 65.0 89.3 - +2 Unchanged Broken 119.5 85.6 Toluene UDMH +96.9 -10.6 Distilled Ethyl Ethyl Alcohol Ether Gasoline (RON 99) Hexane Hydrochlow Hydrochloric Acid (10%) Acid (Cont.) Lard Methyl Ethyl Ketone Perchloroethylene Potassium Permanganate Skydrol 500 Sodwm Chloride (25%) (25%) +1.55 42.2 99.5 One votume Cm% Anilme -5.40 A S T.M No. 1011 AS T.M No 3 Oil Benraldehydc +29.3 +a1.1 48.2 69.5 Unchanged Unchanged 0 Unchanged Unchanged Unchanged Swollen Unchanged Unchanged +I6 +1 Unchanged -38 +7 SI. Brittle Unchanged * Month Immersion at 75’ 5 5OF Tensite Strength Retained K Elongation Retained K Hardness Change Pts. 105.7 94.7 116.2 ::t 90.8 -19 642 -26 -5.76 +5 Surface Condition Unchanged 85.5 14 Swollen Swollen Unchanged Dloctyl Phthalatc -5.18 97.7 89.5 -42 Unchanged Dlstllled Water +0.16 115.8 94.4 t2 Unchanged -6.77 +27.5 102.8 86.4 92.6 73.2 16 -16 Unchanged Unchanged 77.8 61.4 64.2 44.3 -28 -25 Swollen Unchanged +0.49 121.4 +4.31 +7.99 126.3 104.2 97.8 94.7 92.6 Ethyl Ethyl Alcohol Ether Gasolme Hexane (RON 99) Hydrochloric Acid (10%) Hydrochlow Lard Acid (Cow Methyl Ketone Ethyl +69.8 +70.8 ) -7.73 Perchhxoethylene Polasswm Permanganate Skydrol 500 Sodwm Chloride (25%) Sodwm Sulfuric (25%) Hydrorlde (10%) Actid (Cone ) Tide (1%) Tol”ene UDMh 325 SI.Tacky t2 +2 -8 Unchanged Unchanged +6 Unchanged 95.8 85.5 +39.3 100.0 85.5 +0.64 -11.8 +0.05 117.2 94.3 117.8 97.8 87.2 97.8 +2 +8 +0.08 +15.5 119.8 64.4 100.0 26.7 t2 -3 +0.21 i72.9 117.2 60.7 97.8 54.5 +1 -25 SI. Tacky SI. Brittle -8.76 110.7 58.5 +7 Unchanged Vdw Tanslle~ -24 Unchanged Unchanged Unchanged Unchanged Unchanged 0 Unchanged Three Months Immersion at 75* 2 5’F c-w% Anlllne A.S T.M. -5.43 No. 1011 +48.7 A.S.T.M. No. 3 Oil Benzaldehvde Dw~~tyl Phihalate Dlstllled +85.1 -6.19 -5.21 Water Gasolme Hcxane (RON -- Hardness Change Pts. Surface Condition 103.5 105.3 97.7 83.9 -24 Swollen 72.8 103.5 60.5 89.5 -29 +4 Swollen Unchaneed 16 Unchanged 97.8 -i4 Unchanged 123.0 105.3 -+2 Unchanaed 110.7 86.4 101.5 81.9 +71.6 80.0 69.5 -28 Swollen +62.i 63.5 53 8 -23 Swollen -6.98 +28.1 99) Elongation Retained% 100.0 +0.35 Ethyl Alcohol Ethyl Ether Retained K 13 -18 Unchanged Unchanged (continued) 326 Corrosion Resistant Materials Handbook TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON VOlUlllO Change K Hydrochlorx Actd (10%) Hydrbchlorlc Acid (Cow) -I 0.39 +6.24 Lard Methyl Ethyl Ketone Perchloroethylene (25%) Potassium Permanganate Skydrol 500 Sodwm Chlonde (25%) Sobum Sulrur~c Hydroxide A&d (Co&) (10%) Tensile strength Retained K UDMH 117.2 Anlllne No No 1 011 3 011 Benzaldehyde Dfoctyl Phthalate Dlsttlled Ethyl Water Alcohol Hexane Acfd (1046) Acid (Cone Unchanged -6 -24 Unchanged Swollen +1.08 -11.5 84.5 92.2 81.9 85.5 -4 Unchanged +0.10 +1.12 122.2 121.4 105.3 -2 Unchanged +0.31 +64.6 117.2 62.2 100.0 55 0 -7.84 113.5 62.6 VOIUIIW Change W Tensile Strength Retained % Potassium Permanganate 500 Chlortde (25%) Hydroxide (10%) Sulfurtc Acid (Cone (250,) ) Tide (1%) Toluene UDMH Months Immersion at 79 Elongation Retained W 89.5 -24 +85.9 -7.03 -5.15 74.4 103.7 102.3 65 8 85.6 5 92 -28 -5 Unchanged Unchanged 12 Unchanged -2 Unchanged Unchanged 96 3 94.7 81.5 75.0 74 8 -4 -13 Unchanged 74.8 57.3 -29 -28 Swollen 63.5 Swollen 1185 101.5 -2 Sl. Tacky 124 2 108.5 96.5 100.0 97.8 83.9 -3 -13 ‘5 Unchanged Unchanged 91 8 80.2 -21 +2.79 102.8 87.1 99.4 106.3 113.5 Broken 90 9 92.3 97.3 Broken +0.90 111.5 97.8 +68.1 -7.22 58.5 119.2 55.0 65.8 Tamik Strength RetBirmdn 109.2 Elongation Retained% 97 8 91.5 77.9 80.2 67.8 Unchanged Swollen Unchanged Unchanged 0 -3 -1 +6 Unchanged 2 S°F Hardness ChangePts. Surfaa Condii T3 Unchanged Swollen Swollen -28 -29 -7.94 106 73.2 -5.18 108.5 89 3 -4 +o 68 -5.64 107.0 116.3 92.3 96.3 Ethyl Ether Gasolme (RON Hexane Hydrochlor,c Hydrochlorx Lard Methvl Ethyl +31.1 +75.2 +70.9 99) Acid Acld (lo?&.) (Cone ) Ketone Perchloroethylene Potassium Permanganate Skydrol 500 Sodurn Sodturn Sulfuric Chloride (25%) Hydroxide ( IOn.) Acid (Cone ) Tide (1%) Toluene UDMH (25%) 82.2 75 7 64.3 Unchanged Unchanged SI.Tacky Swollen -27 Dloctyl 2 - 0 f8 -2 Eenzaldehyde Dtstllled Water Ethyl Alcohol Surface Condition Unchanged Swollen Swollen 15 Phthalate Swollen 108.0 103 5 -11.5 -0 01 -0.08 f410 +59.3 f88 0 1011 3 011 f7 -4 96.3 -4.31 AnlIme Unchanged Hardness Change pt* 93.7 Vdunw Change % t2 -26 k S°F 101.3 12 Months Immersion at 79 A ST M. No A S.T M No 0 -5.43 f55.6 6 Unchanged Unchanged ‘i2 3 9.4 +32.1 Skydrol Sodturn Sodium 105 0 42.2 +8.58 +12.0 -7.77 Methyl Ethyl Ketone Perchloroethylene SI. Tacky Unchanged -11 +0.26 ) -1 -1 85.5 A-61 Hydrochloric Hydrochlorx Lard 100 0 96 3 SUrfaCt Condition 89.5 81.9 +44.1 +73.0 99) Hardness Change Pts. 87.2 97.2 97.7 +0.32 -6.56 Ethyl Ether Gasoline (RON (continued) +10.0 -7.55 +34.5 Six A S T M A S T.M. Elongation Retained ?4 122.2 +33.9 ride (1%) Toluent CHEMICALS 69 5 71.2 53.5 Tacky Unchanged -1 ‘5 -20 -29 -22 SI Unchanged Unchanged Unchanged Swollen Swollen 10.39 +12 2 1165 122.0 92.5 90 8 ‘1 -4 SI Tacky Unchanged +I0 6 -7.48 100.0 93.5 89 3 74 8 -9 i3 Unchanged Unchanged +36.8 100 71 2 -19 +4.56 -11.2 -0.34 +o.os +44.1 0 104.5 99.3 87.1 +10 87.1 1115 96 3 110.7 92 Broken Swollen -2 0 5 Broken Unchanged Al 18 +0.51 -l-77.0 112.9 59.4 loo.0 53.5 -1 -28 +9.78 124.3 58.8 -5 Unchanged Unchanged SI Brittle SI. Tacky Swollen Unchanged (continued) Rubbers and Elastomers TABLE 2.12: VARIOUS ELASTOMERS CHEMICAL AND RUBBERS-EXXON RESISTANCE OF NATURAL CHEMICALS 327 (continued) RUBBER COMPOUND 72 Hwrs Immersion at 212OF VobM ~w.W Tensile Strength RaMled K Elongatii Ret8hd SC Aniline ASTM No. 1 Oil A.S.T.M. No. 3 Oil Benzsldehyde Dioctyl Phthalate +32.1 +77.6 +143.9 +244.8 +147.7 30.2 38.7 11.2 4.3 10.2 45.5 70.0 Distilled Water Ethyl Alcohol Ethyl Ether Heune Hydrochloric Acid (10%) +6.14 +2.35 +84.6 +io8.a +11.2 Lard Methyl Ethyl Ketone Perchloroethylene Potassium Permanganate (25%) Skydrol500 +BO.9 +47.2 -l-465.4 +3.15 +48.6 Sodium Chloride (25%) Sodium Hydroxide (10%) Toluene Tida (1%) -0.36 +2.96 Disinbgmted +5.89 SUlfXZ Hardness Change Pts. Condiiion 16.2 27.7 -19 -34 -35 -25 -30 Unchanged Unchanged Unchanged Unchanged Unchanged 89.2 78.4 34.a 26.2 61.0 78.5 58.4 34.6 28.4 49.2 -3 0 -15 -20 -4 Unchanged Unchanged Unchanged Unchanged SI. Tacky 36.7 44.6 3.6 54-4 22.6 42.3 51.5 17.8 49.2 65.4 -20 -21 -43 -1 -41 Unchanged Unchanged Unchanged Si. Brittle Unchanged 89.5 94.8 83.1 83.1 -3 -5 Unchanged SI. Tacky 86.9 75.5 -3 Unchanged 50.8 One Month Immersion at 75O i B°F Vuhnlle -m% Tmsile Sbwwth Reteined 2 Elonnation Hardness Retakd SC ChanpPts. Surface condition Amline A.S T.M. No. 1 011 A.S 7.M No. 3 Oil Benzaldehyde Dtoctvl Phthalate +a.90 +24.6 +107.3 +7a.3 +64.3 94.4 88.2 42.0 34.4 54.4 90.1 82.5 38.6 38. i 53.1 -5 -10 -20 -15 SI Tacky Unchanged Unchanged Unchanged Unchanned Drstilled Water Ethyl Alcohol Ethyl Ether Heune Hydrochloric Acid (10%) +1.32 +1.85 +95.5 +107.4 +2.17 102.6 88.9 28.2 31.5 96.1 100.9 73.2 32.3 31.6 91.7 0 -4 -17 -16 -1 Unchanged Unchanged Unchanged Unchanged Unchanged Lsrd Methyl Ethyl Ketone Perchloroethylene Potassium Permanganate(25%) Skvdrol 600 +51.3 +46.a +219.7 +4.19 +25.8 63.6 53.4 23.0 84.3 89.2 60.1 56.1 22.4 81.5 88.5 -15 -15 -20 -3 -11 Unchanged Unchanged Unchanged Brittle Unchanged Sodium Chloride (25%) Sodium Hydroxide (10%) Toluene Tide (1%) -0.83 +0.72 +206.1 +1.92 97.7 97.7 20.8 94.7 -1 -1 -20 0 Unchanged Unchanged Unchanged Unchanged 105.3 102.3 20.7 97.1 -18 Three Months immersion at 75“ 2 5OF VOIUITIO Channn Tmsile Stmngth Retained % Elongation Retained% Hardness ChanrgaPte. Suliace Condiiion Aniline A.S.T.M. No. 1 Oil A.S.T.M. No. 3 Oil Benzaldehyde Droctyl Phthalate +ii.a +41.8 +102.2 +87.0 +78.4 89.8 79.3 41.0 20.7 57.4 88.5 74.6 38.6 30.7 55.4 -7 -10 -15 -24 -19 SI Tacky Unchanged Unchenged SI. Tacky Unchanged Drstilled Water Ethyl Alcohol Ethyl Ether Hexane Hydrochloric Acid (10%) +2.98 +2.15 +119.3 +107.3 +3.61 103.0 79.7 24.3 28.9 84.0 98.6 78.5 31.6 30.7 79.2 0 -3 -21 -18 -2 UnchanIyd Unchanged Unchanged Unchanged Unchanged (continued) 328 Corrosion Resistant Materials Handbook TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON Thrn Vdume change K CHEMICALS (continued) Months Immersion at 75O t 5OF Tensile Strength Retained K Etongatbl Retained% Hardness Change ph Lard Methyl Ethyl Ketone Perchloroethylcne Potassium Permanganate(25W) Skydrol 500 +65.4 +4a.o +229.4 -1.29 +27.4 56.4 31.8 22.6 71.2 76.4 53.1 44.6 21.5 68.6 77.8 -17 -20 -23 Sodium Chloride (25%) +0.71 +2.41 +2122 +3.28 98.0 84.3 21.0 97.1 91.7 77.2 23.1 91.7 +2 Sodium Hydroxide (10%) Toluene Tide (1%) 0 -10 0 -23 -1 surface Condition Unchanged St. Tacky Unchanged Brittle Unchanged Unchanged Unchanged St. Tacky St. Tacky Six Months Immersion at 75O I?I5OF Surface Condition Tensile Strength Retained W AST M. No. 1 Oil A.S.T.M. No. 3 011 Benzaldehyde Dmctyl Phthalate +lO.B -I-47.9 +125.8 +91.6 +B2.9 89.5 71.8 35.4 11.5 44.9 87.1 67.7 34.0 23.1 45.5 -8 -15 -20 -29 -20 SI. Tacky Unchanged Unchanged SI. Tacky Unchanged Distilled Water Ethyl Alcohd Ethyl Ether Hexane Hydrochloric Acid (10%) +3.34 +1.81 +106.B +104.5 +4.22 97.7 76.7 21.6 30.2 79.3 91.7 73.9 27.0 30.0 69.3 0 -5 -23 -18 0 Unchanged Unchanged Unchanged Unchanged Unchanged Lard Methyl Ethyl Ketone Perchloroethylene Potassium Permanganate(25K) Skvdrol5OD +68.8 +50.8 +255.0 +0.65 +29.5 51.5 24.6 19.0 61.0 57.1 50.1 38.6 20.8 53.1 67.0 -16 -23 -25 -3 -18 Unchanged SI. Tacky Unchanged Brittle Unchanged Sodium Chloride (25%) Sodium Hydroxide (10%) Toluene Tide (1%) +1.31 +3.49 +246.8 +4.75 87.5 74.1 16.4 98.0 81.5 67.0 20.8 92.4 0 -1 -26 0 Unchanged Unchanged Tacky SI. Tacky Anlllne Ebngation Retained % Hardness Chanae Fts. Vdume chanee w 12 Months Immersion at 75k 2 5OF Vdume Change K Tensile Strength Ratained % Etongatien Retained W Hardness Change Pts. surface Cendition Aniline A.S.T M. No. 1 Oil A.S.T.M. No. 3 011 Benzaldchyde Dioctyl Phthalate f14.1 +48.1 + 128.8 + 106.8 +90.0 83.6 68.9 33.4 4.3 32.8 84.8 67.7 34.6 19.2 39.9 -7 -20 -23 -36 -24 SI. Tacky Unchanged Unchanged SI. Tacky Unchanged Distilled Water Ethyl Alcohol Ethyl Ether Hcune Hydrochloric Acid (10%) +4.54 +3.59 +111.5 +81.7 +5.06 92.1 74.8 16.7 25.3 67.2 84.8 68.6 27.7 30.0 60.1 +4 -2 -29 -20 +2 Unchanged Unchanged Unchanged SI. Tacky SI. Tacky Lard Methyl Ethyl Ketone Perchloruethylene Potassium Pennanganate(25%) Slwdrol 500 +74.8 +57.0 +211.4 +1.29 +32.4 40.0 13.4 13.1 71.2 37.4 44.6 32.3 19.2 67.0 53.8 -24 -3D -30 -3 -25 Unchanged SI. Tacky Unchanged Brittle Unchansed Sodium Chloride (25%) Sodium Hydruxide (10%) Tduene Tide (1%) -0.24 +7.34 + 187.6 +6.44 84.3 57.1 12.5 90.2 76.2 50.8 20.8 76.2 +3 0 -22 +2 Unchanged Unchanged St. Tacky St. Tacky (continued) Rubbers and Elastomers TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICAL RESISTANCE CHEMICALS 329 (continued) OF SBR COMPOUND 72 Hnurs Immersion at 212OF VOlUn CRawa% Aniline A.S.T.M. No. 1 Oil ASTM No. 3 Oil 8enzaldchydc Dioctvl Phthalatc Tmiksbwhgul R&abed% ElongM Retained% Wardness change Pls. Surface Condii +71.1 +24.9 + 103.9 +150.6 +%.2 25.8 84.4 37.7 22.5 41.8 34.0 66.0 55.8 25.5 40.5 -26 -13 -26 -27 -22 Unchanged Unchanged Unchanged Unchanged Unchanged +5.17 -0.12 +68.7 +61.6 +12.5 98.8 70.9 29.5 31.2 95.1 62.3 47.3 28.3 32.0 59.5 +2 +3 -17 -17 -2 Unchanged Unchanged Unchanged Unchanged SI. Tacky Lard Methyl Ethyl Ketone Perchloroethytene Potassium Permanganate (25%) Stwdrol 500 +45.8 +52.4 +208.3 +3.74 +97.2 64.3 29.9 13.9 78.7 20.1 51.8 33.1 16.2 51.0 38.8 -17 -17 -28 -37 Unchanged Unchanged Unchanged V. Brittle Unchanged Sodium Chloride (25%) Sodium Hydroxide (10%) Toluene Tide (1%) -0.11 +1.86 +255.7 +4.03 102.5 99.6 11.1 107.8 65.2 70.8 18.4 70.0 +3 0 -38 +2 Unchanged Unchanged Unchanged Unchanged Distilled Water Ethyl Alcohol Ethyl Ether Huane HydrochloricAcid (10%) 0 One Month Immersion at 75O * 5OF Volume CKawa% Aniline ASTM No. 1 oil ASTM No. 3 Dil Bcnzaldehyde Duxtyl Phthalate Distilled Water Ethyl Alcohol Ethyl Ether Huane Hydrochloric Acid (10%) TeMikSbulgth Retained% gKJr.rgattafr Retainad% Hardness ChangaPts. Surface Condition +x).3 +5.21 +58.0 +105.8 +53.3 67.2 lM.9 53.3 28.3 53.3 58.1 92.6 45.3 26.4 47.3 -11 -3 -18 -19 -16 SI. Tacky Unchanged Unchanged Unchanged Unchanged +1.35 +0.79 +74.8 +92.5 +2.04 111.9 99.2 29.5 32.0 109.8 96.3 85.8 29.2 30.3 92.6 0 -1 -17 -16 +1 Unchanged Unchanged SI. Tacky SI. Tacky Unchanged Lard Methyl Ethyl Ketone Perchloroethylcne Potasswm Permanganate (25%) Skydrol 500 +16.2 +47.5 +190.5 +7.42 +46.6 70.5 34.4 24.6 109.0 56.5 61.5 34.8 19.8 88.7 53.0 -14 -16 -20 -2 -17 Unchanged St. Tacky SI. Tacky V. Brittle Unchanged Sodwm Chloride (25%) wium Hydroxide (10%) Tduene Tide (1%) +0.21 +0.71 + 196.4 +2.16 109.0 108.2 25.0 107.8 90.7 90.7 19.8 96.3 +1 +3 -19 +1 Unchanged Unchanged SI. Tacky Unchanged mrs0 Months Im-ton f-8-m Rat&led% -WI* btaimd% at 75’ * S°F Hardness ChanlQPk SurtKc CondRhn Aniline A.S.T.M. No. 1 oil ASTM No. 3 Oil 8anzaldehyde Dioctyl Phthalate +22.1 +9.m +91.8 +104.8 +75.9 a.8 98.4 56.2 21.7 50.4 50.1 84.1 45.3 22.7 43.3 -9 +6 -17 -21 -16 St. Tacky Unchanged Unchanged St. Tacky Unchanged Distilled Water Ethyl Alcohol Ethyl Ether Huane Hvdrochlaric Acid llOX\ +2.93 +0.45 +110.0 +93.0 +3.95 117.6 94.3 29.9 31.9 109.4 93.5 77.3 28.3 32.0 87.8 +3 0 -17 -15 +3 Unchanged Unchanged Unchanged St. Tacky Unchanned (continued) 330 Corrosion Resistant Materials Handbook TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS (continued) Three Months Immersion at 750 ? 5oF Vdume change Y Tensile Strength Retained K Elongation Retained % Hardness Change Pts. Surface Condition Skydrol SD0 +54.7 +53.1 +189.6 +9.10 +45.3 68.0 32.4 22.9 101.2 53.7 60.3 31.1 17.9 79.3 50.1 -16 -15 -20 -1 -12 Unchanged Unchanged SI. Tacky Brittle Unchanged Sodium Chloride (25%) Sodium Hydroxide (10%) Toluene Tide (1%) +0.52 +1.74 +189.1 +3.67 113.9 107.0 23.8 109.8 94.3 85.0 17.1 89.8 +3 +1 -19 +2 Unchanged Unchanged Sf. Tacky Unchanged Lard Methyl Ethyl Ketone Perchloroethylcne Potasswm Pwmanganate (25%) Six Months Immersion at 75* 2 S°F Tansife sbength Retained% Elongation Retained W 57.4 101.6 52.5 24.6 54.9 47.3 85.0 41.6 23.6 44.5 -5 -6 -19 -22 -17 SI. Tacky Unchanged Unchanged SI. Tacky Unchanged +4.28 +1.26 +73.7 +58.4 +3.49 109.4 89.8 28.7 32.8 107.8 83.0 71.7 27.5 31.2 77.3 +3 0 -18 -15 0 Unchanged Unchanged Unchanged SI. Tacky Unchanged +46.3 +52.9 + 195.9 +9.31 +45.8 75.5 37.3 21.7 91.4 54.5 66.0 34.0 17.0 70.0 50.1 -16 -16 -17 -2 -18 Unchanged Unchanged SI. Tacky Brittle Unchanged +1.25 +2.84 108.6 92.6 18.4 107.8 85.0 70.0 16.2 82.2 +3 f3 -20 +3 Unchanged Unchanged Sl. Tacky Sf. Tacky c +19.6 +13.5 +88.2 +100.8 +a3.4 Aniline A.S.T.M. No. 1 Oil A.S.T.M. No. 3 011 Benzaldehyde Dioctyl Phthalate Distilled Water Ethyl Alcohol Ethyl Ether Huane Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potassium Pwmanganate Skydrol 500 (25%) Sodwm Chloride (25%) Sodwm Hydroxide (10%) Toluene lade (1%) +201.8 +4.75 Hardness ChangePts. Surface Conditii 12 Months Immersion at 75* 2 SF Vdume Change% Aniline A.S.T.M. No. 1 Oil A.S.T.M. No. 3 Oil Benraldehydc Dtoctyl Phthalate Distilled Water Ethyl Alcohd Ethyl Ether Hwane Hydrochloric Acid (10%) +26.5 +14.9 +87.8 +110.0 +78.3 +6.08 -l-O.42 +82.8 +52.7 +6.09 Lard Methyl Ethyl Ketone Perchloroethylene Potasswm Permanganate (25%) Skvdrol 500 +36.2 +57.3 +204.2 +11.2 +46.4 Sodaurn Chloride (25%) Sodwm Hydroxide (10%) Toluene Tide (1%) +0.11 +4.06 +166.6 +6.48 Tensile Sbength ReteimdK Elongatien Ret&ted% Hardness Change& Surface CendRfen 57.4 96.7 53.3 16.0 49.2 56.7 82.2 45.3 21.8 41.7 -6 -7 -19 -21 -17 Y. Tacky Unchanged Unchanged Y. Tacky Unchanged 111.9 94.7 26.2 29.5 106.6 76.5 72.8 27.5 33.1 72.8 +4 +2 -17 -16 +3 Unchanged Unchanged Unchanged Si. Tacky Unchanged 62.7 25.4 21.7 77.9 47.5 64.7 27.5 19.8 55.8 47.3 -17 -16 -22 -4 -17 Unchanged Unchanged Unchanged Brittle Unchanacd 109.0 85.7 13.9 110.7 83.0 61.5 17.9 78.5 +4 +1 -21 +4 Unchanged Unchanged Sl. Tacky St. Tacky (continued) Rubbers and Elastomers TABLE 2.12: VARIOUS ELASTOMERS CHEMICAL AND RUBBERS-EXXON RESISTANCE CHEMICALS 331 (continued) OF NITRILE RUBBER COMPOUND 72 Hours immersion at 212OF Surface Condition Hardness Change Pts. Tensite strength Retained K Elongation Ratainad K 17.8 118.6 104.4 20.6 60.1 21.7 79.4 83.0 19.9 55.2 -34 -1 -7 -28 -19 Unchanged Unchanged Unchanged Unchanged Unchanged +7.16 +22.3 -t-33.5 +29.1 +9.71 117.4 52.6 53.0 62.9 66.4 97.5 49.8 51.6 62.9 57.8 -5 -10 -14 -16 -9 Unchanged Unchanged SI. Tacky Unchanged Unchanged Hydrochloric Acid (10%) Lard Mathvl Ethvl Ketone Pe~rchloroe~hylenc Potassium Permanganate (25%) +11.8 +0.41 +108.8 +51.4 -5.87 92.1 108.3 25.7 43.5 83.0 75.8 85.6 24.2 48.0 57.8 -4 -2 -24 -22 +1 Unchanged Unchanged Unchanged Unchanged V. Brittle Skydrol 500 Sodium Chloride (25%) Sodium Hydroxide (10%) Tolwne Tide (1%) +154.2 +1.09 +1.22 +124.8 $7.54 24.5 109.9 101.2 10.7 106.3 33.6 84.8 86.6 17.0 86.6 -34 -3 -5 -31 -5 Unchanged Unchanged Unchanged Unchanged Unchanged Vdume Aniline A.S.T.M. No. 1 Oil A.S.T.M. No. 3 Oil Benzaldehyde Dioctyl Phthalate Distilled Water Ethyl Alcohol Ethyl Ether Gasoline (RON 99) Hexane chrne% +250.9 -1.17 +11.3 +229.5 +54.1 One Month Immersion at 75’ * S°F Surface Condition Ckarw% Tarstic Sbwgth Ratainad % Elongation Retaii W Amllne A S.T.M No. 1 Oil A.S.T.M. No. 3 Oil Eenzaldehyde Dioctyl Phthalate +204.2 +2.69 +4.30 +198.2 +15.7 24.5 104.0 105.1 26.1 79.8 20.6 93.9 97.5 22.7 74.7 -23 -4 -7 -23 -10 Unchanged Unchanged Unchanged Unchanged Unchanged Drstilled Water Ethyl Alcohol Ethyl Ether Gasoboe (RON 99) Hexane +2.51 +11.0 +21.8 +35.9 +11.0 109.5 86.2 53.8 80.2 85.4 103.6 82.0 55.2 78.3 83.0 -4 -11 -15 -13 -9 Unchanged Unchanged SI. Tacky Unchanged SI. Tacky Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potassium Permanganate (25%) +1.44 +5.52 +128.2 +43.2 +1.68 102.8 105.5 26.1 60.5 110.3 97.5 100.0 24.2 60.3 109.4 -3 -3 -23 -18 -7 Unchanged Unchanged Unchanged SI. Tacky V. Brittle Skydrol 500 Sodium Chloride (25%) Sodium Hydroxide (10%) Tolwne Tide (1%) +X34.2 +0.71 +1.11 +112.4 +2.54 37.9 111.5 111.1 29.3 101.2 35.0 101.1 100.0 28.9 93.9 -24 -2 -2 -23 -3 Unchanged Unchanged Unchanged St. Tacky St. Tacky Vduma mree Months G TdkStmr@h WnadW Anihne ASTM No. 1 Oil A.S.T.M. No. 3 Oil Benzaldehyde Dmctyl Phthalate +211.8 -1.24 +4.54 +202.8 +37.4 29.6 110.7 109.1 M.6 71.2 Distilled Water Ethyl Alcohol Ethyl Ether Gasolme (RON 99) Hexane +3.88 +10.6 +19.4 +18.6 +9.36 110.7 80.8 52.6 75.5 80.6 Hardness Change Fts. lmmarskrn at 75O 2 5*F RoRgatim lkwnad% Rardness Change Pts. Surface Condition 21.7 97.5 97.5 19.1 63.9 -22 -3 -3 -23 -18 Unchanged Unchanged Unchanged SI. Tacky St. Tacky 101.1 78.3 54.2 75.8 78.3 -3 -10 -16 -13 -8 Unchanged Unchanged Unchanged SI. Tacky Unchanged (continued) 332 Corrosion Resistant Materials Handbook TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS (continued) Three Months Immersion at 75O % 5OF Vdume -_-___~.-Hydrochloric Acld (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potassium Permanaanate (25%) Skydrol 500 Sodium Chloride (25%) Sodium Hydroxide (10%) Toluene Tide (1%) Ch=w% Tensile strength Retained w Elongation Hardness Retained SC ChangePts. SlllfaCe Condiion +1.92 +1.02 + 126.0 +55.8 +1.56 99.6 111.1 24.9 53.8 98.8 91.3 102.2 28.7 54.2 98.6 -4 +1 -22 -17 -4 Unchanged Unchanged Unchanged Unchanged Brittle +150.9 +0.48 +1.73 +119.5 +3.55 36.4 114.2 96.8 28.9 1028 32.5 108.3 86.6 30.7 96.4 -23 0 -4 A23 -4 Unchanged Unchanged Unchanged Unchanged 5l. Tacky Six Months immersion at 75* 2 5’F volume change % Tensile Strength Reteined W Elongation Retained % Hardness Change Pts. Surface Condition An,t,fle A S 1 M No 1 011 A S T M No 3 011 Benzaldehyde Dmctyl Phthalate +220.0 -0.21 -f-6.87 +191.0 +56.3 21.0 111.9 116.6 19.8 64.0 19.1 95.0 74.7 20.6 55.2 -25 -1 -4 -24 -18 Unchanged Unchanged Unchanged Sl. Tacky Unchanged Dlstllled Water Ethyl Alcohol Ethyl Ether Casolbne (RON 99) Hexane +5.44 +10.0 +34.5 +22.3 +9.20 105.9 84.2 49.8 77.1 79.1 93.9 77.6 49.5 75.8 72.2 -4 -10 -15 -Xi -6 Unchanged Unchanged Unchanged SI. Tacky Unchanged Hydrochloric Actd (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potassium Permanganate (25%) +2.88 -0.71 +154.6 +43.6 +2.63 104.0 115.9 24.9 46.3 98.0 93.9 101.1 25.3 49.5 98.6 -3 +1 -24 -18 -6 Unchanged Unchanged Unchanged Unchanged Brittle Skydrol 500 Sodium Chloride (25%) Sodwm Hydroxide (10%) Toluene Tide (1%) +142.6 +1.90 +1.60 +127.4 +5.79 35.6 107.9 94.9 27.7 104.7 35.0 90.3 79.4 27.8 93.9 -24 -3 -4 -23 -4 Unchanged Unchanged Unchanged Sl. Tacky Sl. Tacky 12 Months Immersion at 75O 2 5OF volume Change SC Afl,ltIW Tensile Strength Retained % Elongation Retained K Hardness Change Pts. 5urlace Condition +230.1 -0.70 +9.00 +216.3 +53.0 17.4 105.9 94.1 20.6 64.8 22.7 87.7 79.4 24.2 57.8 -28 ASTM No 1011 AS TM No 3011 Benraldehyde Dtoclyl Phthalate 0 -5 -23 -18 Unchanged Unchanged Unchanged SJ. Tacky Unchanged DMllled Water Ethyl Alcohol Ethyl Ether Gasoline (RON 99) Hexane +6.92 +14.2 +38.0 +27.6 +26.9 108.3 81.8 55.3 72.7 85.8 92.8 75.8 55.2 72.2 76.9 -3 -9 -16 -14 -7 Unchanged Unchanged Unchanged Y. Tacky Unchanned Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potassium Permanganate (25%) +3.25 +12.3 +151.6 +59.6 + 1.92 106.3 107.1 24.9 57.7 97.2 86.6 92.8 25.3 55.2 89.2 -3 -2 -24 -18 -6 Unchanged Unchanged Unchanged Unchanged Brittle Skydrol SO0 Sodium Chloride (25%) Sodium Hydroxide (10%) Toluene Tide (1%) + 147.7 +0.71 +7.04 +110.2 +8.02 33.6 111.1 89.7 24.5 102.0 35.0 97.5 73.3 28.9 89.2 -24 -1 -4 -24 -5 Unchanged Unchanged Unchanged Unchanged St. Tacky (continued) Rubbers TABLE 2.12: VARIOUS ELASTOMERS CHEMICAL AND RUBBERS-EXXON RESISTANCE CHEMICALS OF POLYCHLOROPRENE and Elastomers 333 (continued) COMPOUND 72 Hours Immersion at 212OF Vduma CharIRe K Tensile Strength Retained SC Elongation Retained X Hardness Change PM. Surface Condition A.S.T.M. No. I 011 AS T.M. No. 3 011 8enzaldehyde Diuctyl Phthalate + 143.3 +5.74 +61.7 +61.3 +116.6 22.9 100.0 46.1 25.0 39.1 58.3 88.3 67.3 40.4 61.4 -45 -4 -24 -35 -34 Unchanged Unchanged Unchanged Unchanged Unchanged Distilled Water Ethyl Alcohol Ethyl Ether Gasoline (RON 99) Hcxane +9.34 +2.92 +49.5 +69.6 +24.5 97.2 85.6 44.7 41.2 78.5 85.2 79.4 53.8 58.3 80.7 -4 -4 -20 -28 -15 Unchanged Unchanged Unchanged Unchanged Unchanged 93.3 95.4 32.4 22.9 89.1 76.2 89.7 52.5 42.6 71.8 -8 -15 -28 -38 +2 Unchanged Unchanged Unchanged Unchanged V. Brittle 57.0 76.2 89.7 37.2 74.9 -45 +5 +1 -44 -9 Unchanged Unchanged Unchanged Unchanged Unchanged Andme Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potassium Permanaanate (25%) +15.1 +20.0 +72.3 i242.9 +3.07 Skydrol 500 Sodium Chloride (25%) Sodaurn Hydroxide (10%) Toluene Tide (1%) +151.0 +1.20 iO.24 +2D9.1 +11.6 17.3 95.8 101.4 15.9 91.6 One Month Immersion at 75O 2 5“F Elongation Retained % +67.3 +0.57 +19.5 +132.0 +77.1 63.0 110.9 91.9 30.6 56.7 76.2 100.0 85.2 40.4 58.3 -13 -25 -24 Unchanged Unchanged Unchanged SI. Tacky Unchanned +3.67 +3.26 +49.8 +45.8 +19.4 112.7 97.5 41.2 57.8 86.3 106.3 91.0 52.5 62.8 80.7 0 -4 -20 -17 -13 Unchanged Unchanged Unchanged Unchanaed Unchanged Lard Methyl Elhyl Ketone Perchloroethylene Potassium Permanaanate (25%) +2.65 +7.08 +70.6 +132.6 +4.16 107.8 104.2 32.4 31.0 108.8 95.5 98.7 52.5 37.2 97.3 +1 -8 -30 -23 -1 Unchanged Unchanged Unchanged Unchanged V. Brittle Shydrol 500 Sodium Chlonde (25%) Sodium Hydrorlde (10%) Toluene Tide (1%) +115.6 +2.3G +1.41 +141.5 +3.78 30.7 112.7 104.6 29.9 109.2 -31 Unchanged Unchanged Unchanged Sf. Tacky Unchanged Amllne A.S.T M No. 1011 A S T M No. 3 011 Benzaldehyde Dmctyl Phthalate Dlstllled Water Ethyl Alcohol Ethyl Ether Gasolme (RON 99) Herane Hydrochlonc Acld (10%) Hardness Changa Pts. Surface Condition Tensile Strength Retainad W Vduma challm K 53.8 97.3 94.2 35.9 100.0 -28 0 0 0 -24 $1 Three Months Immersion at 75O 2 5OF Vdume m% Aniline A.S.T.M. No. 1 Oil A.S TM. No. 3 Oil Benzaldehyde Dtoctvl Phthalate +67.8 +o.S4 +37.5 +146.2 +108.7 Dlstdled Water Ethyl Alcohol Ethyl Ether Gasoline (RON 99) Hexane +6.35 +2.44 +54.8 +48.9 +21.1 Taleik stremglh Rat&ad 50.0 108.1 87.0 24.7 46.1 114.4 94.0 46.8 60.9 70.1 % Elmlgation Retained% Hardness Change PM. Surface Condition 70.4 98.7 80.7 35.9 49.3 -27 +1 -15 -29 -25 Sf. Tacky Unchanged Unchanged Sf. Tacky Unchanned 94.2 86.6 60.5 68.6 77.6 0 -4 -23 -19 -12 Unchanged Unchanged Unchanged Unchanaed “~ Unchanged (continued) 334 Corrosion Resistant Materials Handbook TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS (continued) Three Months Immersion at 75O 5 S°F Volume Change K Tensile strength Retained % Elongation Retained W Hardness Change Pts. Surface Condition Hydrochlortc Acid (10%) Lard Methyl Ethyl Ketone Perchloroethylcne Potasswm Permanaanate (25%) +4.09 +14.4 +85.5 +132.5 +7.22 108.8 110.9 29.5 32.8 112.0 95.5 103.1 51.6 37.2 95.5 +1 -10 -30 -24 0 Unchanged Unchanged Unchanged Unchanged SI. Brittle Skydrol 5DO Sodwm Chloride (25%) Sodium Hydroxtde (10%) Toluene Tide (1%) +X30.6 +2.53 +3.17 +166.5 +5.99 32.0 116.2 103.5 28.9 107.0 53.8 97.3 92.8 35.9 94.2 -35 +1 -5 -25 0 Unchanged Unchanged Unchanged Unchanged Unchanged Six Months Immersion at 75* 2 5OF VdUtlW Change K Tensile Sb-ength Retained W Elongation Retained % Hardness Change Pts. Surface Condition AnlIme A S.T.M No. 1 011 A.S.T M No 3 011 Etenzaldehyde D~octyl Phthalate +62.7 +1.20 +44.2 +156.4 +114.4 51.4 112.3 91.9 20.1 48.6 77.6 101.8 83.0 39.0 50.7 -29 +1 -20 -35 -26 SI. Tacky Unchanged Unchanged Unchanged Unchanged Dlstllled Water Ethyl Alcohol Ethyl Ether Gasolme (RON 99) Hexane +10.5 +2.48 +51.9 +50.7 +20.3 94.7 90.1 38.4 50.7 75.7 80.7 69.7 57.0 64.1 73.1 -4 -5 -25 -20 -12 Unchanged Unchanged Unchanged Unchanged Unchanged Hydrochlcr!c Actid(10%) Lard Methyl Ethyl Ketone Perchloroethylene Potasswm Permanganate (25%) +5.77 +15.5 +92.8 + 142.9 i9.72 102.1 107.4 23.2 26.8 106.7 85.2 94.2 49.3 31.4 83.9 -1 -14 -34 -29 -2 Unchanged Unchanged Unchanged Unchanged Sl. Brittle Skydrol 500 Sodwm Chlorlde (25%) Sodwm Hydrorlde (10%) Toluene Tide (1%) +142.3 +3.02 +3.87 +204.2 +9.42 25.0 112.3 95.8 23.2 91.2 53.8 94.2 86.6 31.4 77.6 -40 +2 0 -28 -3 Unchanged Unchanged Unchanged Unchanged Unchanged 12 Months Immersion at 75O 2 5OF Vduma Change K Tensile strength Retained % Elongation Rabined% HarW Chanp -38 Pts. sulfaa Condition Aniline A.S.T ht. No. 1 011 A.S T M. No. 3 011 Benzaldehyde D~octvl Phthalate +65.9 +1.10 +43.8 +190.0 +125.5 28.2 96.9 70.5 7.4 38.7 67.3 94.2 79.4 35.9 49.3 -19 -51 -29 SI Tacky Unchanged Unchanged SI. Tacky Unchanged Dtstllled Water Ethyl Alcohol Ethyl Ether Gasolme (RON 99) Hexane +ia7 +6.05 +56.8 +54.6 +20.8 79.6 89.8 34.5 47.9 65.1 70.4 86.6 59.6 67.3 70.4 -8 -4 -29 -23 -13 Unchanged Unchanged Unchanged Unchanged Unchanged Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potassium Permanganate (25%) +9.13 +17.5 +94.4 +147.5 + 13.0 95.8 94.0 21.5 25.0 90.5 73.1 95.5 55.2 37.2 70.4 0 -14 -38 -31 -4 Unchanged Unchanged Unchanged Unchanged SI. Brittle Skydrol 500 Sodium Chlonde (25%) Sodaurn Hydrorlde (10%) Toluene T#de (1%) +156.7 +1.81 +3.99 +171.5 +12.3 la7 104.6 816 20.4 84.2 57.0 83.9 73.1 35.9 64.1 -43 -7 +1 -34 0 Unchanged Unchanged Unchanged SI. Tacky Unchanged 0 (continued) Rubbers and Elastomers TABLE 2.12: VARIOUS ELASTOMERS CHEMICAL RESISTANCE AND RUBBERS-EXXON CHEMICALS (continued) OF CHLOROSULFONATED POLYETHYLENE COMPOUND 72 Hours Immersion VdUmC change K 335 at 212-F Tensile Strength Retainad K Elo”gatio” Retained K Hardness Change Pts. Surface Condition Aniline A.S.T.M. No. 1 011 A.S.T.M. No. 3 011 Benraldehyde Duxtyl Phthalate + 147.4 +6.59 +66.9 +40.4 + 125.3 86.4 73.3 49.6 20.1 28.4 73.9 35.3 114.5 29.0 49.8 -54 +4 -21 -30 -29 Unchanged Unchanged Unchanged Unchanged Unchanged Distilled Water Ethyl Alcohol Ethyl Ether Basoltne (RON 99) Hexane +9.43 +4.80 +44.9 +104.7 +24.7 97.2 81.1 34.5 25.4 49.3 80.7 82.1 48.3 53.1 62.8 -4 -6 -17 -30 -14 SI. Brittle Unchanged Unchanged Unchanged Unchanged Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Penhloroethylene Potassium Pennanganate (25%) +4.25 +20.3 +61.2 +150.2 +7.74 103.9 76.3 27.3 22.3 100.8 88.4 77.3 40.1 37.2 80.7 -1 -11 -24 -30 -5 Unchanged Unchanged Unchanged Unchanged SI. Brittle Skydrol5DO Sodium Chloride (25%) Sodium Hydroxide (10%) Toluene Tide (1%) +108.7 +1.14 +1.07 +171.1 +8.65 23.1 99.7 96.1 17.8 85.0 44.9 83.6 78.7 36.2 73.9 -32 -1 Unchanged Unchanged Unchanged Unchanged Unchanged 0 -37 -5 One kkmth Immersion at 75“ 5 5OF Vdume Ctwv% Tensile strength Retained 54 Elongation Retained % Hardness Change Pk. Surface Condition AmIme A S 1 M. No 1 011 A S T.M No 3 011 Benraldehyde D~octyl Phthalate +63.1 +0.59 +B.O2 +117.4 +40.3 47.6 104.7 82.5 28.4 56.6 67.6 101.5 82.1 33.8 61.4 -18 -3 -16 -21 Unchanged Unchanged Unchanged Unchanged Unchanged DMllled Water Ethyl Alcohol Ethyl Ether GasdIne (RON 99) Hexane +1.17 +2.51 +43.0 +48.4 +22.1 104.5 97.5 28.7 37.8 57.7 x30.0 98.1 46.9 51.7 67.6 +1 -4 -18 -20 -11 Unchanged St. Tacky SI. Tacky Tacky Unchanged Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potasswm Pennanganate (25%) +1.80 +5.04 +70.0 +112.7 +2.50 109.8 81.9 32.3 27.6 109.8 102.9 85.5 43.5 37.2 101.5 +3 -2 -16 -6 0 Unchanged Unchanged Unchanged Unchanged Unchanged Skydrol 500 Sodwm Chloride (25%) Sodium Hydroxide (10%) Tolucne Tide (1%) +88.0 -0.23 +0.58 +128.8 +1.98 40.4 109.2 109.5 25.6 108.1 44.9 98.1 114.5 33.8 100.0 -19 +1 +2 -18 +2 Unchanged Unchanged Unchanged Unchanged Unchanged Three Months Vdunm ChrnOls% T-=-m RM8MW knmerrion &nation Rabined% 0 at 75’ 2 !T°F Hardms Chanm Pk. Surface Condiin AmIme A.S.T.M. No. 1011 A.ST.M No 3011 Benzaldehyde Dmctvl Phthalate +64.1 +0.34 +1a.2 +115.2 +115.5 38.7 108.6 74.9 25.4 43.7 61.4 96.7 75.7 33.8 42.0 -20 +2 -9 -19 -16 sl. T8cky Unchanged Unchanged Unchanged Unchanned Olstllled Water Ethyl Alcohol Ethyl Ether Gasoirne (RON 99) +2.45 +5.50 +45.6 +51.7 +23.6 109.6 94.4 35.1 37.9 47.6 88.4 90.3 51.7 53.1 59.4 +2 -2 -16 -19 -11 Unchanged Unchanged V. Tacky Tackv Unchanged Herane (continued) 336 Corrosion Resistant Materials Handbook TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS (continued) Three Months Immersion at 75“ * 5OF volume Change W Tenrite Strength Retained < Elongation Retried % Hardness Change Pts. Surfs Condiiien Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Parchloroathvtene Potassium Pennanganatc (25%) +2.36 +7.56 +68.4 +125.5 +4.17 108.6 96.1 28.1 281 115.9 98.1 90.3 40.1 33.8 98.1 +2 -4 -16 -18 +4 Unchanged Unchanged Unchanged Unchanged Unchanged Skydrol 500 Sodium Chloride (25%) Sodium Hydroxide (10%) Toluenc Tide (1%) +87.8 l Fo.23 l Fo.93 i-135.4 +3.95 42.1 116.4 99.7 23.7 107.8 44.9 99.0 90.3 32.4 96.7 -17 +5 0 -18 +1 Unchanged Unchanged Unchanged Unchanged SJ. Tacky volume Chenge W Tensik Strengtft Retained W Elongation Retained K 35.1 109.8 77.7 28.4 41.0 62.8 93.2 82.1 37.2 42.0 -22 +2 -10 -20 -17 Unchanged Unchanged Unchanged Unchanged Unchanged 113.9 98.6 33.7 35.1 60.2 91.8 91.8 51.7 58.0 62.8 0 -3 -18 -20 -11 Unchanged SI. Tacky Tacky Tacky Unchanged Six Months Immersion at 75O 2 5OF Anlllnt A ST M No. I 011 A S 1 M No 3 011 Benraldehyde D~octyl Phthalatc Dtst~llcd Water Ethyl Alcohol Ethyl Ether Gasoline (RON 99) Hexanc +62.0 +0.44 +3G.3 +103.8 + 122.8 +5.13 +6.54 -t-46.0 +51.1 +23.6 Hardness Change Pts. surface Condition Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchloroathylene Potasswm Permanganate (25%) +3.27 +16.4 +68.4 +1G9.0 +6.80 108.1 86.6 29.5 25.1 111.4 95.2 84.5 42.0 30.4 90.3 +2 -7 -17 -19 +1 Unchanged Unchanged Unchanged Unchanged SI. Brittle Skydrol 500 Sodium Chloride (25%) So&urn Hydroxide (1.0%) Toluana Tide (1%) + 102.2 +0.46 +1.28 +143.6 +5.16 40.1 113.9 107.0 26.7 104.2 48.3 95.2 90.3 33.8 88.4 -19 +3 +2 -18 +2 Unchanged Unchanged Unchanged Unchanged SI. Tacky 12 Months Immersion at 75O -C 5OF Tensite Strength Retained K Elongation Rtiained K +71.8 +0.59 +40.3 +119.8 +110.5 26.2 108.6 72.4 24.5 39.8 64.3 95.2 75.9 37.2 43.5 -29 +2 -12 -21 -20 Unchanged Unchanged Unchanged Unchanged Unchanged +6.86 +5.53 116.2 101.7 87.0 91.8 0 -11 Unchanged Si. Tacky +47.8 +51.8 +25.0 33.9 32.3 54.6 58.0 51.7 66.2 -19 -19 -11 Tacky Tacky Unchanged Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Parchloroathylcne Potaswm Permanganata (25%) +16.1 +24.9 +86.0 +105.7 +8.83 114.2 75.2 28.1 24.5 114.2 90.3 78.7 42.0 37.2 87.0 +4 -10 -20 -20 +1 Unchanged Unchangad Unchanged Unchanged St. Brittle Skydrol 500 Sodwm Chloride (25%) Sodium Hydroxtde (10%) Tolucne Tide (1%) +88.6 +1.03 +X52 +188.0 +9.11 32.9 115.9 110.3 24.5 112.3 48.3 93.2 90.3 35.3 82.1 -19 +4 -l-4 -2G 0 Unchanged Unchanged Unchanged St. Tacky Unchanged Volume Change K AflhW A S 1 M No. 1 011 ASTM No 3011 Benraldehydc Dwtvl Phthalatc Dlstdled Water Ethyl Alcohol Ethyl Ether Gasolme (RON 99) Hexane Hardness Change Pts. Surface Condition (continued) Rubbers TABLE 2.12: VARIOUS ELASTOMERS CHEMICAL AND RUBBERS-EXXON RESISTANCE OF V&TALON CHEMICALS Tensile Strength Retained % (continued) 6505 COMPOUND 72 Hours Volume Change X and Elastomers Immersion at 2 12’F Elongation Retained % Hardness Change Pts. Surface Condition A.S.T.t.4 No. 1011 + 129.3 30.8 45.9 -37 SI. Tacky A.S.T.M. No. 3 011 + 222.4 20.9 29.5 -44 SI. Tacky A.S.T.M. Fuel B Unchanged + 171.9 14.1 21.3 -11 Dtistllled Water +0.5 93.2 77.0 +l Unchanged Ethyl Alcohol -4.6 87.5 82.0 +3 Unchanged Unchanged Hexane +69.0 18.6 24.6 +2 Hydrochloric Acid (10%) + 10.4 66.9 57.4 -2 Unchanged Methyl Ethyl Ketone + 10.7 62.7 70.5 -9 Unchanged Olive Oil +41.6 55.1 65.6 -27 SI. Tacky Skydrol 500 +5.5 98.1 88.5 -9 SI. Tacky Sodium Chloride (25%) +2.8 88.6 75.4 +l Sodium Hydroxide (lD%) -0.4 93.9 75.7 Trde (1%) +0.6 89.7 75.4 One Month Volume Change % Tensile Stmngth Retained % immersion 0 -1 Unchanged Unchanged Unchanged at 79” 2 5°F Elongation Retained % Hardness Change Pts. Surface Condition 1011 +42.8 40.3 49.2 -18 Unchanged A S 1 M No 3 Oti + 162.3 25.5 24.6 -29 Unchanged ASTM + 168.7 ASTM No Fuel B Drstllled Water + 1.25 Ethyl Alcohol +1.9 19.0 23.0 -27 Unchanged 111.0 96.7 -2 Unchanged 98.9 95.1 -5 Unchanged +159.9 20.2 23.0 -26 Unchanged +1.2 107.2 101.6 -2 Unchanged +3.1 82.9 90.2 -10 White Res. 14.6 81.0 85.3 -9 Unchanged -1.8 103.0 101.6 -4 V. Tacky Sodrum Chlonde (25%) +0.6 97.3 loo.0 -2 White Res. Sodwm Hydroxtde (10%) +O.l 95.8 95.1 -3 Unchanged Tide (1%) +0.7 92.0 95.1 Hexane Hydrochlonc Acid (10%) Methyl Ethyl Ketone Olive 011 Skydrol 5DO + 0 Unchanged 337 338 Corrosion Resistant Materials Handbook TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS (continued) Three Months Immersion at 75” 2 5°F Volume Change K ASTM No 1011 Tensile Strength Retained % Elosgation Retained % Hardness Change Pts. Surface Condition t83.7 36.1 42.6 -26 A S T M. No. 3 011 t 175.0 24.3 26.2 -27 Unchanged A S T M. Fuel El 7183.3 17.9 16.4 -30 Uuchange?d Drstrlled Water -0.9 98.1 96.7 Ethyl Alcohol +i.2 88.9 93.4 -4 Unchanged Unchanged Hexane + 152.6 Hydrochlonc Actd (10%) Methyl Ethyl Ketone Olrve 011 Skydrol 500 Sodrum Hydroxide (10”~) Tide ( 1%) 0 Unchanged 20.5 22.9 -29 t1.7 108.4 95.1 cl +2.7 77.6 83.6 - +25.4 76.8 85.2 -16 Unchanged 104.2 96.8 -2 Unchanged -2.2 Sodwm Chlonde (25”.) Unchanged Unchanged 7 Unchanged 0 91.2 88.5 -0 Unchanged -0.2 98.5 96.7 +l Unchanged +0.2 85.2 90.2 0 Unchanged Six Months Immersion at 75” + 5°F Volume Change % S TM No I AS TM No 3011 A Oil A S 1 M Fuel 8 Tensile Strength Retained K Elongation Retained % Hardness Change Pts. Surface Condition +115.3 36.1 42.0 -27 Unchanged t 198.9 27.8 27.9 -31 Unchanged Unchanged +211.0 18.6 18.0 -31 Dlstrlled Water -0.5 98.5 98.4 +I Unchanged Ethyl Alcohol +1.25 82.1 88.5 -2 Unchanged Hexane Hydrochlonc Acrd (100.) Methyl Ethyl Ketone Olive Oil +192.1 19.4 23.0 -28 +0.6 98.9 95.1 +l Unchanged t2.8 82.5 86.9 -5 Unchanged +29.0 Skydrol 500 (25%) Sodrum Hydroxrde I ~WC.) Trde (1%) CHEMICAL 73.8 83.6 -15 Unchanged 100.0 95.1 -2 Unchanged -0.2 94.3 91.8 +2 Unchanged 0 98.5 93.4 +l Unchanged +0.4 92.8 93.4 0 Unchanged -2.6 Sodium.Chlonde RESISTANCE Unchanged OF 30 VISTALON 6505170 BUTYL RUBBER BLEND COMPOUND 72 Hours Immersion at 212’f Volume Change X Tensile Strength Retained X Elongation Retained % Hardness Change Pts. Surface Condition A.S.T.M. No. 1 Oil + 68.2 57.6 57.1 -25 SI. Tacky A.S.T.M. No. 3 011 + 136.9 36.6 35.7 -28 SI. Tacky A.S.T.M. Fuel 8 + 133.7 -27 30.2 35.7 Dishtled Water +2.2 98.8 92.9 Etnyl Akohol -2.0 91.9 78.6 Unchanged 0 +l Unchanged Unchanged (continued) Rubbers TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON 72 Hours Volume Change % Hexane Tensile Strength Retained % CHEMICALS Elongation Retained % 35.5 35.7 +7.1 88.4 75.0 Methyl Ethyl Ketone +12.8 68.0 Olwe 011 +28.1 71.5 Skydrol 500 +a.5 Sodium Chlonde (25%) Sodwm Hydroxide (10%) Tide (1%) A S 1 h4 No 1 011 No 3011 A.S 1 M Fuel 8 Hardness Change Pts. -5 Surface Condition Unchanged Unchanged 71.4 - 12 Unchanged 78.6 -20 SI. Tacky 84.3 85.7 -12 SI. Tacky +0.8 100.6 85.7 +l Unchanged -0.1 95.9 85.7 -1 Unchanged +0.9 92.4 82.1 -2 Unchanged at 75” One Month Immersion AS TM (continued) 0 z S”F Surface Condition Tensile Strength Retained % Elongation Retained % +15.1 73.8 71.4 -8 Unchanged +67.9 49.4 50.0 -16 Unahanged Volume Change % Hardness Change Pts. +117.2 34.9 32.1 -19 Unchanged DIstilled Water +2.5 98.3 92.9 -1 Unchanged Etnyl Alcohol +2.5 94.2 92.9 -2 Unchanged + 104.6 33.1 32.1 -18 Unchanged +0.2 101.7 96.4 Methyl Ethyl Ketone +5.7 74.4 78.6 -8 White Res. Olwe 011 +5.3 93.6 92.9 -5 Unchanged Skydrol 500 +0.4 94.8 ?07.1 -2 V. Tacky Herane Hydrochloric Aild (10%) 0 Unchanged Sodurn Chloride (25:0) +O.l 95.3 96.4 -1 White Res. Sodium Hydrorlde +0.2 102.3 100.0 -2 Unchanged +0.2 100.5 100.0 Volume Change % Tensile Strength Retained % Elongation Retained % +29.0 Tide (1OQ I looI 339 Immersion at 212°F +51.9 Hydrochlonc Acid (10%) and Elastomers 0 Unchanged Three Months Immersion at 75” II s”F 1 011 A.S.7.M No. A.S.1.M No. 3 011 A S.T.M. fuel 8 Hardness Change Pts. Surface Condition 66.9 64.3 -12 + 108.6 45.4 42.9 -17 Unchanged + 132.3 34.3 32.1 -21 Unchanged Unchanged DistIlled Water -0.4 100.0 96.4 +l Unchanged Ethyl Alcohol -1.8 91.9 89.3 -2 Unchanged Unchanged Herane +117.3 37.8 35.7 -18 Hydrochlortc Acld (10%) +0.5 95.9 96.4 +l Unchanged Methyl Ethyl Ketone +6.5 75.0 82.1 -7 Unchanged Olwe 011 + 10.6 85.5 89.3 -8 Unchanged Skydrol 5DO io.4 97.7 96.4 -3 Unchanged Sodwm Chloride (25%) -0.11 97.1 78.6 0 92.4 89.3 +0.3 94.8 85.7 Sodurn Hydroxide (10%) Tide (lo.1 0 Unchanged +l Unchanged 0 Unchanged (continued) 340 Corrosion Resistant Materials Handbook TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS Sir Months Immersion Volume Change % Tensile Strength Retained % at 75” Elongation Retained % (continued) z S’F Hardness Change Pts. Surface Condition A.S T.M. No. 1011 +45.2 59.9 60.7 -17 Unchanged A S T.M. No. 3 011 + 118.0 45.3 39.3 -20 Unchanged A.S.1.M +151.1 33.7 28.6 -19 Unchanged -0.1 97.7 100.0 +1.7 89.0 85.7 Fuel 8 Dlstllled Water Etnyl Alcohol Hexane Hydrochlonc Methyl Acid CIOO~l Elhyl Ketone Olwe 011 Skydrol 500 Sodwm Chlonde (2!X.) Sodaurn Hydroxide Tide (I@41 (1%) CHEMICAL RESISTANCE +l 37.8 32.1 -18 Unchanged +0.5 98.9 92.9 -8 Unchanged +5.9 79.7 82.1 -7 Unchanged +15.8 87.2 92.9 -9 Unchanged +o. 1 94.2 92.9 -3 Unchanged -0.3 98.8 92.9 +3 Unchanged 0 93.0 89.3 +2 Unchanged +0.3 97.7 96.4 +l Unchanged OF 30 VISTALON 6505170 VISTALON 2504 BLEND COMPOUND 72 Hours Immersion No. 1011 Unchanged +159.0 Volume Change % A.S.T.M. Whrte Res. 0 at 2 12°F Tensile Strength Retained % Elongation Retained % HarrJness Change Pts. Surface Condition c94.7 59.6 63.0 -27 SI. Tacky A.S.T M. No. 3 011 + 141.0 37.3 40.7 -32 SI. Tacky A.S.T M Fuel 8 + 138.0 bstllled Water Ethyl Alcohol Hexane Hydrochloric Methyl Acid (10%) Ethyl Ketone Okve 011 Skydrol 500 Sodium Chlonde (25%) Sodium Hydroxide (10%) Tide (1%) 32.4 33.3 -12 Unchanged -13.0 105.9 92.6 -1 Unchanged -2.7 94.5 85.2 +49.8 40.5 37.0 -2 +12.2 89.3 74.1 -4 Unchanged +11.9 73.0 77.8 -10 Unchanged +34.9 68.6 74.1 -22 SI. Tacky +8.4 91.9 96.3 -10 SI. Tacky +1.7 106.5 88.9 +0.3 105.4 107.4 +l Unchanged co.2 98.8 88.9 -2 Unchanged One Month Volume Change % Tensile Strength Retained % immersion 0 0 Unchanged Unchanged Unchanged at 75” 2 5°F Elongation Retained % Hardness Change Pts. Surface Condition A S 1 M No I 011 +42.3 68.1 66.7 -15 Unchanged AS 3011 +114.0 47.0 40.7 -21 Unchanged +126.5 30.8 29.6 -21 Unchanged +l.l 105.9 107.4 -1 Unchanged +1.9 101.6 96.3 -4 Unchanged TM No A S T M Fuel I3 Dlstllled Water Ethyl Alcohol (continued) Rubbers TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON One Month Volume Change % Hexane +115.7 Hydrochior,c Methyl Acjd (IO”,) Ethyl Ketone Olive 011 Skydrol 500 Sodturn Chloride (250,) (10”.) Sodaurn Hydroxtde Tide Cl”,) CHEMICALS Elongation Retained % 37.8 +0.5 I 011 85.4 96.3 -9 Unchanged +0.6 101.6 103.7 -4 V. Tacky 104.3 107.4 -2 White Res. +0.2 104.3 100.0 -2 Unchanged +0.4 101.1 100.0 -1 Unchanged +69.5 +o. 1 +1.2 t 121.9 Herane Methyl Acid I lo”.) Ethyl Ketone Olive 011 Skydrol 500 Sodbum Chloride (25%) (lO”.l Sodium Hydroxide Tide (loo) White Res. +0.3 +135.6 Hydrochloric Unchanged + 14.9 A S 1 M Fuel B Ethyl Alcohol -3 -8 + 123.9 Waler Unchanged 111.1 100.0 A S I M No 3 011 Dlst!lled Surface Condition 89.1 Three Months No 2 5°F Hardness Change pts. -18 29.6 107.0 (continued) +5.6 Volume Change % A !, 1 M at 75’ Immersion Tensile Strength Retained % and Elastomers 0 Tensile Strength Retained % Immersion Elongation Retained % at 75” 2 5°F Hardness Channe Pts. Surface Condition 64.2 62.9 -19 Unchanged 47.0 40.7 - 19 Unchanged -22 White Res. 33.5 25.9 106.5 103.7 97.3 92.6 -2 33.3 -20 42.2 102.7 96.3 0 Unchanged Unchanged 0 White Res. Unchanged 88.7 85.2 -7 Unchanged t23.9 82.7 92.6 -13 Unchanged -0.6 101.6 100.0 -3 Unchanged +O.l 98.4 81.5 0 Unchanged +O.? 98.9 92.6 0 Unchanged +0.08 103.8 100.0 +7.0 Six Months Volume Change % Tensile Strength Retained % immersion -1 Unchanged at 75” + 5°F Elongation Retained % Hardness Change Pts. Surface Condition I 011 t 100.6 58.9 55.6 -20 Unchanged A S 1 M No 3 011 t 122.1 46.5 37.0 -23 Unchanged A S T M Fuel B +156.8 34.6 29.6 -22 White Res. +0.4 103.8 103.7 0 White Res. +2.4 101.6 100.0 0 Unchanged +157.3 42.2 37.0 +0.5 99.5 85.2 0 Unchanged A !z, T M No Dwllled Waler Ethyl Alcohol Hexane Hydrochlonc Methyl Acid (lo”,) Ethyl Ketone Olive DII Skydrol 500 Sodlum Chlonde (25% Sodwm Hydroxide Tide (1%) (:O%) -20 White Res. +5.6 88.1 85.2 -8 Unchanged t26.2 86.5 81.5 -13 Unchanged -0.2 102.2 100.0 -3 Unchanged +l White Res. -0.3 104.3 100.0 +0.3 105.4 100.0 0 Unchanged +0.9 103.2 96.3 0 Unchanged (continued) 341 342 Corrosion Resistant Materials Handbook TABLE 2.12: VARIOUS ELASTOMERS RESISTANCE AND RUBBERS-EXXON OF 30 VISTALON CHEMICALS NATURAL 6505170 RUBBER BLEND COMPOUND 72 Hours lmmersron Volume Change % A.S.1 M No 1011 Tensile Strength Retained % (continued) at 212’F Elongation Retained % Hardness Change Pts. Surface Condition + 121.5 42.3 54.0 -37 SI. Tacky A.S T M. No. 3 011 b232.4 12.6 25.8 -45 SI. Tacky A S.T.M. Fuel 8 + 155.9 18.1 22.6 -38 Unchanged +3.5 101.5 93.5 - 1.2 104.8 96.8 +l Unchanged Unchanged D,stllled Water Ethyl Alcohol Hexane 0 Unchanged +39.5 31.8 38.7 -4 + 16.4 74.1 67.7 -4 Unchanged +37.8 59.4 67.7 +3 Unchanged Olrve 011 + 76.6 48.8 61.3 -31 SI. Tacky Skydrol +35.7 55.4 90.3 -28 SI. Tacky Hydrochlonc Methyl Acid (lo”.) Ethyl Ketone 500 Sodium Chloride Sodwm Tide (25%) Hydroxide (10%) (1%) +0.2 107.6 93.5 +l Unchanged co.9 98.8 90.3 -1 Unchanged +3.1 109.2 97.8 -2 Unchanged One Month Immersion at 75” = 5°F Volume Change % Tensile Strength Retainrd % A.S T M No. 1011 +37.2 61.5 64.5 -7 Unchanged A.S.T M No. 3 011 + 141.8 41.2 41.9 -25 Unchanged A S.T.M. +178.9 18.1 16.1 -2 Unchanged +1.7 111.4 100.0 -1 Unchanged +3.1 105.9 103.2 -6 Unchanged Fuel B Dlstrlled Water Ethyl Alcohol Hexane Elongation Retained % Hardness Change Rts. Surface Condition + 131.4 32.4 38.7 -24 Unchanged +l.l 110.3 106.5 -1 Unchanged +34.0 47.2 58.1 -17 White Res. Olwe 011 +45.4 65.9 64.5 -14 Unchanged Skydrol 500 + 13.9 77.9 83.9 -4 Sodwm Chloride +O.l 105.9 106.5 +2 White Res. Sodlum Hydroxide 0 116.9 112.9 -2 Unchanged +0.9 107.0 103.2 Hydrochlorrc Methyl Acid (10%) Ethyl Ketone (25%) Trde (1%) (10%) Three Months Volume Charwe % Tensile Strength Retained % V. Tacky 0 Unchanged Immersion at 75” z 5°F Elongation Retained % Hardness Change Pts. Surface Condition A.S.T.M. No. 1011 +64.3 60.4 61.3 -20 A.S.T.M. No. 3 Ori +157.1 39.0 38.7 -25 Unchanged A.S.T.M. Fuel 6 + 193.5 23.1 29.0 -32 Unchanged Drstrlled Water +I.5 114.7 106.5 Ethyl Alcohol +2.4 84.5 96.8 Unchanged 0 -4 Unchanged Unchanged (continued) Rubbers TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS and Elastomers (continued Three Months Immersion at 75’ 2 5’F Volume Change % Hexane t141.3 Hydrochloric Acid (10%) Methyl Ethyl Ketone Tensile Strength Retained % Elongation Retained % Hardness Change Pts. Surface Condition 31.3 35.5 --20 +1.4 100.4 96.8 +l Unchanged Unchanged +35.1 52.7 74.2 -21 Unchanged Olive 011 +63.4 53.2 54.8 -23 Unchanged Shydrol 500 +16.5 65.9 77.4 -13 Unchanged +l Unchanged Sodwm Chlorrde (25~~~) -0.1 104.3 80.7 ( 10°o) +0.5 104.8 93.6 0 Unchanged +1.7 104.8 100.0 0 Unchanged Sodrum Hydroxide Tide 1loa) Six Months Immersion at 75” + 5°F Volume Change % Tensile Strength Retained X Elongation Retained % Hardness Change Pk. Surface Condition ASTM No 1011 +79.0 57.6 58.1 -25 Unchanged AS TM No 3011 + 161.8 41.2 41.9 -29 Unchanged AS TM Fuel 8 -258.2 19.2 29.0 -33 Unchanged Dtstllled Water +1.9 107.0 Ethyl Alcohol +2.4 Hexane + 189.9 Hydrochlonc Acrd (10%) Methyl Ethyl Ketone 100 0 Al Unchanged 58.7 74.2 -3 Unchanged 24.1 29.0 -29 Unchanged Unchanged +1.8 103.2 96.8 +l +41.1 24.7 54.8 -25 Unchanged Unchanged Unchanged Ohve 011 +72.7 65.9 61.3 -23 Skydrol 500 +21.8 39.5 64.5 -17 Sodrum Chlonde (25%) -0.3 101.0 90.3 +2 Sodrum Hydroxrde (10%) +0.7 98.2 87.1 42 Unchanged Trde (1%) +2.2 110.3 100.0 +l Unchanged CHEMICAL Unchanged RESISTANCE OF 30 VISTALON 6505170 SBR BLEND COMPOUND 72 Hours Immersion at 212’F Volume Channe % Tensile Strength Retained % Elongation Retained % Hardness Change Pts. Surface Condition A.S.T.M. No. 1 011 + 41.8 74.9 66.7 -17 SI. Tacky A.S.T.M. No. 3 011 + 107.0 50.7 42.9 -22 Sl. Tacky A.S.T.M. Fuel B +115.1 16.8 28.6 -23 Unchanged Drstilled Water +5.3 97.7 95.2 -1 Unchanged Ethyl Alcohol -2.1 87.5 81.0 -1 Unchanged Unchanged Hexane + 28.8 39.6 42.9 -2 Hydrochloric Acid (10%) + 12.8 94.9 76.2 -2 Unchanged +4 Unchanged Metnyl Ethyl Ketone +30.6 55.4 57.1 Olrve 011 +39.4 67.0 61.9 -18 SI. Tacky Skydrol 500 +37.7 64.7 66.7 -19 SI. Tacky Sodrum Chlonde (25%) +2.7 102.4 85.7 0 Unchanged Sodrum Hydroxtde (10%) +0.6 104.2 85.7 0 Unchanged Trde (1%) +5.3 101.9 85.7 -1 Unchanged (continued) 344 Corrosion Resistant Materials Handbook TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON One Month AS 1 M No 1011 A S 1 M No 3 011 ASTM Fuel 8 Dlstllled Ethyl Water Hydrochloric Methyl Acld (10%) Ethyl Ketone at 75” z 5°F Elongation Retained % Hardness Change Pts. surtrcc Condition Tensile Strength Retained K +13.1 91.2 90.5 +84.9 53.1 47.6 -17 Unchanged + 105.8 34.4 38.1 -17 Unchkged 105.6 95.2 -2 Unchanged 94.9 90.1 -3 Unchanged +2.8 Hexane Immersion (continued) Vdume Change X +2.86 Alcohol CHEMICALS -7 Unchanged +75.7 40.9 33.3 -16 Unchanged +1.8 106.6 109.5 -2 Unchanged +31.9 53.5 57.1 -12 Olwe 011 +22.5 81.9 76.2 -8 Unchanged Skydrol 500 +21.9 77.7 76.2 -8 V. Tacky Sodun Chloride +0.5 103.7 100.0 -2 White Res. Sodium Hydroxide +1.2 106.9 109.5 -2 Unchanged +1.3 93.0 95.2 (25%) L10%) Tide (1%) ihrea AS 1 M Month Volume Change X Tensile Strength Retained K White Res. 0 Immersion Elongation Retained X Unchanged at 75” : S”F Hardness Change Pts. Surface Condition No 1011 +23.4 77.7 71.4 -11 Unchanged A S 1 M No 3 011 +98.2 54.9 47.6 -16 Unchanged + 108.7 36.8 33.3 -18 +2.6 100.1 95.2 +3.1 94.5 100.0 -3 Unchanged +82.9 42.8 38.1 -16 Unchanged ~2.8 102.4 95.2 +l Unchanged +32.7 61.4 61.9 -13 Unchanged Olbve 011 i24.3 74.5 76.2 -13 Unchanged Skydrol + 19.9 76.8 71.4 -10 Unchanged +0.6 99.1 76.2 0 Unchanged +2.0 98.7 95.2 0 Unchanged +2.5 99.6 104.8 0 Unchanged A.S 1 M Fuel 8 Dlstllled Water Ethyl Alcohol Herane Hydrochloric Methyl Acld (10%) Ethyl Ketone 500 Sodbum Chlonde Sodwm (25%) Hydroxtde Tide (1%) (10%) Six Months Volume Change X Tensile Strength Retainrd X fmmersion Yellow Res. 0 Unchanged at 75” + 5°F Elongation Retained K Hardness ChanRr Pts. Surface Condition A S T M No 1 011 +31.0 82.8 76.2 -13 Unchanged A S 1 M 3 011 +99.0 64.4 47.6 -18 Unchanged AS No 1 M Fuel B Dlstllled Water Ethyl Alcohol +126.1 39.1 38.1 - 16 +3.7 102.8 90.5 +l Unchanged Yellow Res. +1.3 90.7 85.7 -1 Restdue (continued) Rubbers TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON Six Months Volume Change X neaane H,drochlor~c Acid Methyl Ketone (lo”,1 Tensile Strength Retained X CHEMICALS Immersion at 75’ Elongation Retained X +116.3 44.7 42.8 +3.7 85.6 61.9 and Elastomers (continued) + 5’F HIrdIleSS Change Pts. -16 Sllr(NLe Condition Yellow Res. +l Unchanged +31.7 57.7 52.4 -11 Yellow Res. Oilde 011 +39.3 72.1 61.9 -12 Unchanged Skydrol 500 + 19.6 79.1 71.4 - 10 Unchanged Ethyl Sodium Chloride (250-i +0.5 104.7 90.5 +l Unchanged Sodium Hydroxide ;lO%) +2.8 96.3 85.7 +l Unchanged Tide (10.) +3.3 105.6 90.5 +l Unchanged CHEMICAL RESISTANCE OF 30 VISTALON 6505170 NITRILE RUBBER BLEND COMPOUND 72 Hours Immersion Volume Change K Tensile Strength Retained X at 212°F Elongation Retained % Hardness Change Pts. Surface Condition A.S T M. No. 1011 +19.4 77.5 56.3 -7 A.S T.M +63.5 62.0 50.0 -22 SI. Tacky +84.4 37.1 40.6 -24 Unchanged Dlstllled Water +7.8 106.6 81.3 -1 Unchanged Ethyl Alcohol +9.3 83.6 71.9 -6 Unchanged -3 Unchanged No. 3 011 A.S T.M. Fuel B Hexane +27.8 53.5 50.0 Hydrochloric Acid (10%) + 10.7 98.6 65.6 Methyl Ethyl Ketone +60.5 31.9 37.5 SI. Tacky 0 -29 Unchanged Unchanged Olwe Oil + 10.6 80.3 65.6 -7 Sl. Tacky Skydrol 5OO +73.5 23.9 34.4 -37 SI. Tacky Sodium Chlonde (25%) +0.9 93.9 71.9 +l Unchanged Sodlum Hydroxtde (10%) -0.5 98.1 75.0 -1 Unchanged Tide (1%) +7.6 100.0 75.0 -2 Unchanged One Month Volume change x A S T M. No. 1 011 +6.0 A S T.M. No. 3 011 +28.2 A S.T.M. Fuel 8 Tonsila Strength Retainrd K Immersion at 75” d 5°F Elongation Retained % Hardness Change Pts. Surface Condition 95.3 87.5 -4 Unchanged 65.7 62.5 -17 Unchanged +79.9 42.7 40.6 -24 Unchanged Dlsttilled Water +2.1 97.6 87.5 -4 Unchanged Ethyl Alcohol +6.9 83.5 81.3 -10 Unchanged +45.4 49.3 46.9 -20 Unchanged 98.6 87.5 -2 Unchanged +99.9 40.9 37.5 -22 +1.6 103.3 93.8 -1 Unchanged +96.9 46.9 43.8 -17 V. Tacky Hexane Hydrochlonc Acid (lo”/,) Methyl Ethyl Ketone Olive 011 Skydrol 500 Sodium Chlonde (25O.I Sodium Hydrorlde Tide ( 1%) (lo”.) +1.83 +O.J 345 White Res. 99.5 93.5 -3 White Res. +0.8 101.9 96.9 -4 Unchanged +l.O 93.9 87.5 0 Unchanged (continued) 346 Corrosion Resistant Materials Handbook TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS Immersion Three Months volume Channe K Retained at 75” = 5°F Elongation Retained X Tensile Strength K kontinued) Hardness Change Pts. Surface Condition A.S.T.M. No. 1011 +8.9 86.9 78.1 -4 A.S.T.M. No. 3 011 +50.2 63.4 59.4 - 18 Unchanged A.S.T.M. Fuel B +87.3 41.3 40.6 -23 Unchanged +3.2 92.0 84.4 i5.5 82.6 78.2 -8 Unchanged +48.9 54.9 50.0 -18 Unchanged +2.3 96.7 87.5 +l Unchanged 42.2 43.8 -25 Unchanged DIstIlled Water Ethyl Alcohol Hexane Hydrochlonc Methyl Acid (10%) Ethyl Ketone + 110.8 Ohve 011 Skydrol 500 Sodturn Chlonde Sodium (25%) Hydroxtde (10%) Tide (1%) 0 Unchanged +3.5 93.0 84.4 -2 Unchanged + 100.7 41.3 40.6 -23 Unchanged +l +0.5 95.8 78.1 +0.9 94.4 81.3 0 Unchanged c2.2 98.6 87.5 0 Unchanged Six Months Volume Change % A S.T M. No. Unchanged immersion Tensile Strength Retained X Unchanged at 75” + 5°F Elongation Retained ‘% Hardness. Change Fts. Surface Condition 1 011 + 16.6 81.7 75.0 -5 A S T M. No. 3 011 +54.3 68.5 65.6 - 19 Unchanged + 103.5 43.2 34 4 -22 Unchanged A.S.T M. Fuel B Distilled Water Ethyl Alcohol Hexane Hydrochlonc Acid (10%) Methyl Ethyl Ketone Olive Oil Skydrol 500 Sodium Chlonde Sodturn Hydroxide Ttde (1%) CHEMICAL (25%) (10%) RESISTANCE OF +4.2 101.9 87.5 +2 Unchanged +4.6 b9.7 78.1 -6 Unchanged +90.4 53.1 46.9 - 18 Unchanged c2.0 99.1 84.4 +2 Unchanged + 124.3 35.2 34.4 -23 Unchanged +5.1 100.0 84.4 -2 Unchanged + 103.5 36.6 37.5 -24 Unchanged +0.4 96.2 84.4 73 Unchanged to.8 91.6 75.0 +2 Unchanged +3.1 96.2 81.3 +l Unchanged 50 VISTALON 6505150 NITRILE RUBBER 72 Hours Immersion Volume Change % A.S.T M. No. 1011 A.S.T.M. A.S.T.M. Dsttlled Unchanged Tensile Strength Retained K BLEND COMPOUND at 2 12°F Elongation Retained % Hardness Change Pts. Surface Condition +43.9 64.0 53.6 -15 SI. Tacky No. 3 011 + 100.3 45.7 39.3 -29 SI. Tacky Fuel El +263.3 Water Ethyl Alcohol + 13.2 t5.0 34.9 28.6 -33 Unchanged 100.5 71.4 tl Unchanged 96.8 78.6 -4 Unchanged (continued) Rubbers TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS and Elastomers 347 (continued9 72 Hours lmmerston at 212°F Hexane Hydrochlorrc Methyl Acrd (10%) Ethyl Ketone Elongation Retained % Hardness Change Pts. Surtace Condition Volume Change % Tensile Strength Retained % +33.3 48.9 42.9 -3 t11.1 91.9 60.7 -3 Unchanged +35.7 52.7 50.0 -23 Unchanged Unchanged Olrve 011 +18.7 83.3 64.3 -12 SI. Tacky Skydrol +76.5 42.5 50.0 -31 SI. Tacky + 1.3 101.6 71.4 +2 Unchanged -0.3 101.1 75.0 -1 Unchanged +4.4 98.5 75.0 -3 Unchanged 500 Sodrum Chloride (25%) Sodrum Hydroxrde (1046) Tide (1%) One Month Immersion at 75’ + 5°F Volume Change % AS 1 M No 1011 A 5 1 M No 3 011 Tensile Strength Retained $6 Elongation Retained % Hardness Change Pts. Surface Condition +16.3 87.6 71.4 -10 Unchanged +69.8 58.1 50.0 -23 Unchanged, Unchanged A S 1 M Fuel B +95.4 42.5 39.3 -26 Drstrlled Water + 4.8 103.2 92.7 -4 Unchanged E!hyl Alcohol + 4.3 96.2 89.3 -10 Unchanged Hexane Acrd (10”,) Hydrochlonc Methyl Ethyl Ketone Olrve Oil Skydrol 500 Sodrum Chlonde +64.9 47.9 46.4 -22 Unchanged +1.7 104.8 100.0 -2 Unchanged +61.7 53.7 50.0 -. 20 +5.3 98.4 89.3 -5 Unchanged +37.9 65.6 60.7 -15 V. Tacky White Res. (25?0) +0.2 104.8 92.6 -3 White Res. Sodrum Hydroxrde’(lO%) +0.2 106.5 92.6 -4 Unchanged +1.2 101.1 89.3 -1 Unchanged Trde (loo) Three Months Immersion Volume Change % Tensile Strength Retained % at 75” + 5°F Elongation Retained % Hardness Change Pts. Surface Condition ASTM No 1011 +29.0 79.0 71.4 -15 Unchanged AS TM No 3011 +81.1 61.3 50.0 -23 Unchanged ASTM FuelB +99.7 42.5 32.1 -27 Unchanged Drstrlled Water +0.3 104.8 85.7 -1 Unchanged E!hyl Alcohol +3.3 82.3 82.1 -8 Unchanged +74.5 48.4 42.9 -23 Unchanged +1.4 101.1 82.1 +62.9 61.8 53.6 -21 Unchanged +9.5 94.6 78.6 -6 Unchanged +54.6 61.8 53.6 -20 rlnchanged -1 Hexane Hydrochlonc Methyl Acrd tlO”.) Ethyl Ketone Olrve 011 Skydrol 500 Sodrum Chlorrde Sodrum Hydroxrde Trde (lTO) (25%) (lo”.) +0.3 96.8 75.0 +0.4 99.5 89.3 +4.3 102.2 89.3 0 0 -1 Unchanged Unchanged Unchanged Unchanged (continued9 348 Corrosion Resistant Materials Handbook TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS Six Months Immersion Volume Change ?4 A S T M No Tensile Strength Retained % (continued) at 75” = 5°F Elongation Retained % Hardness Change Pts. Surface Condition I 011 +41.2 67.7 60.7 -15 Unchanged A S 1 M No 3 011 +83.9 61.3 46.4 -24 Unchanged Unchanged ASTM +114.4 FuelB Dlstllled Water Ethyl Alcohol Herane 33.9 32.1 -24 +O.9 99.5 82.1 +l Unchanged +2.5 85.5 78.6 -6 Unchanged -21 Unchanged + 104.6 50.0 42.9 98.4 85.7 +63.0 53.8 46.4 -19 Olive 011 +12.6 89.8 71.4 -6 Unchanged Skydrol 500 +56.6 56.5 53.6 -21 Unchanged Sodium Chlonde +0.4 96.2 85.7 +2 Unchanged Sodium Hydroxide 0 93.0 75.0 +2 Unchanged +2.8 99.5 82.1 +l Unchanged Aod (10%) Hydrochlonc Methyl Tide Ethyl Ketone (25%) (10%) (1%) + 1.9 +2 Unchanged White Res. CHEMICAL RESISTANCE OF 70 VISTALON 6505130 NITRILE RUBBER BLEND COMPOUND 72 HoursImmersion at 212°F Volume Change K Tensile Strength Retained K Elongation Retained X Hardness Change Pts. Surface Condition A.S.T.M. No. 1 011’ +70.0 53.9 51.7 -25 A.S.T.M. No. 3 Oil + 130.9 43.9 37.9 -32 SI. Tacky A.S.T.M. Fuel 8 +224.0 33.9 27.6 -34 Unchanged +2.2 100.6 75.8 +l Unchanged - 12.7 97.8 86.2 -8 Unchanged Distilled Water Ethyl Alcohol Hexane Hydrochloric Methyl Acid (loo/.) Ethyl Ketone SI. Tacky +27.4 45.0 34.5 -2 Unchangqd + 12.6 94.4 65.5 -1 Unchanged +32.6 67.2 62.1 -1 Unchanged +26.3 71.1 65.5 -16 SI. Tacky +38.3 65.6 72.4 -25 Sl. Tacky +0.7 97.2 72.4 +2 Unchanged -0.3 98.9 79.3 -1 Unchanged +2.4 97.2 72.4 -1 Unchanged Volume Cheq. x Tensile Strength Retained K Elongation Retained K 011 +26.6 80.6 68.9 -13 Unchanged A S T M No 3 011 +98.1 62.7 44.8 -23 Unchanged Olive Oil Skydrol 500 Sodium Chlonde Sodwn (25%) Hydroxide (10%) Tide (1%) One Month Immersion at 75” + 5°F A S 1 M No I Hardness Change Pb. Surface Condition +114.9 42.8 34.5 -25 Destilled Water +1.9 98.9 93.1 -3 Unchanged Ethyl Alcohol +3.1 95.0 93.1 -7 Unchanged AS TM Fuel 8 Unchanged (continued) Rubbers and Elastomers TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS One Month Immersion Volume change HeXan.? Acid Hydtochlorlc f IO”,) Ethyl Ketone Methyl Olive Ott Skydrol 500 Sodturn Chloride (2Ya) Sodium Hydroxide (IO”.1 (loo) Ttde x Tensile Strength Retained c (continued) at 75” r 5°F Elongation Retained % Hardness Change Pts. Surface Condition +66.6 45.0 37.9 -22 Unchanged +1.2 104.4 100.0 -2 Unchanged +29.9 73.3 75.9 -17 +7.6 93.3 86.2 -7 Unchanged +2l.l 71.1 89.7 -12 V. Tacky White Res. 0 103.3 100.0 -3 White Res. +0.3 98.9 96.6 -3 Unchanged +0.6 96.7 93.0 -1 Unchanged Three Months Immersion Voluma Tensile Strength Change K Retained X Elongation Uetained K at 75” : 5°F Hardness Change Pts. 18 Surface Condition Unchanged AS 1 M No 1011 +49.1 67.8 55.2 AS 1 M 3011 + 106.3 51.1 41.4 -23 Unchanged +115.6 44.4 34.5 -26 Unchanged No AS 1 M Fuel B Dlstlllcd Water Alcohol Ethyl tiexatle Hydrochlorw Acid IlO”.) +0.3 98.9 89.7 -1 Unchanged +1.8 93.9 86.2 -6 Unchanged +98.6 47.8 34.5 -23 Unchanged +l Unchanged io.73 98.3 86.2 +31.1 77.2 72.4 -19 Gray Res. Olwe 011 +16.1 86.1 79.3 -10 Unchanged Skydrol 500 +22.2 86.1 75.9 -14 Unchanged +0.2 105.0 86.2 +l Unchanged +0.3 94.4 82.8 0 Unchanged +l.l 97.2 93.1 0 Unchanged Methyl Ethyl Ketone Chloride Sodaurn (25O.1 (lo”,) Sodium t-lydroxlde lldt’ 11-c) Six Months Immersion Volume Change K A.S T.M. No Tensile Strength Retained X at 75” ? S’F Elongation Retained X Hardness Channe Ptr. Surface Condition 1011 + 61.8 65.6 55.2 -19 Unchanged No 3 Oil + 109.8 51.7 44.8 -25 Unchanged +138.1 35.4 31.0 -24 Dlstdled Water +0.8 98.9 93.1 +1 Unchanged Ethyl Alcohol + 1.6 93.3 86.2 -4 Unchanged -22 A.S.T.M. A S T M. Fuel 8 Hexane + 137.6 Hydrochloric Methyl Acid (lo”.) Ethyl Ketone +l.l 52.2 44.8 100.0 86.2 +1 Unchanged Unchanged Unchanged +30.3 71.7 69.0 -16 White Res. Olwe 011 + 18.9 88.9 79.3 -10 Unchanged Skydrol SO0 +23.2 77.2 75.9 -14 Unchanged Sodwm Chlonde Sodwm Hydroalde Tide (1%) (25”J (1o”0) 349 +0.2 100.0 93.1 +2 Unchanged +0.2 96.1 82.8 +1 Unchanged +l.l 97.2 86.2 0 Unchanged (continued) 350 Corrosion TABLE 2.12: Resistant VARIOUS Materials Handbook ELASTOMERS CHEMICAL RESISTANCE OF AND RUBBERS-EXXON 30 VISTALON 65051’70 CHEMICALS POLYCHLOROPRENE BLEND 72 Hours Immersion Volume Change % Tensile Strength Retained % (continued) COMPOUND at 212°F Elongation Retained % Hardness Change Pts. Surface Condition A.S.T.M. No. 1 Oil +25.1 86.8 73.9 - 10 SI. Tacky A.S.T.M. No. 3 011 +99.8 46.2 65.3 -27 SI. Tacky A.S.T.M. Fuel B Distilled Water Etnyl Alcohol Hexane Hydrochloric Methyl Acid (lD?/J Ethyl Ketone Olive Oil Skydrol 500 Sodium Chloride Sodium Hydroxide (2596) (10%) Tide (1%) +92.3 33.8 47.8 -25 Unchanged +10.9 96.6 78.3 -1 Unchanged -0.1 91.9 87.0 +2 Unchanged +27.9 53.8 60.9 +3 Unchanged +7.1 88.4 75.0 0 +28.5 50.9 65.2 A S.T M No. 1011 AS TM Dlstllled +32.0 71.4 73.9 -17 SI. Tacky 40.6 65.2 -33 SI. Tacky to.2 100.4 73.9 +6 Unchanged +2.0 89.3 78.3 -3 Unchanged - 96.6 82.6 -1 Unchanged Tensile Strength Retained % Surtace Condition 91.3 -4 Unchanged ~55.8 60.8 -16 Unchanged Fuel 8 +a4.4 38.9 47.8 -19 Unchanged +3.5 103.0 95.7 -1 Unchanged +8.1 88.5 86.9 -6 Unchanged +51.9 Actd (10%) Ethyl Ketone Olive 011 500 Sodlum Chloride (25”,) Hydroxide 1lo01 I lo”.1 72.3 t40.0 51.3 60.9 -15 Unchanged 105.9 108.7 -1 Unchanged 52.6 73.9 -16 +9.4 92.3 83.3 -5 +50.3 56.8 69.6 -14 +I.2 101.3 100.0 +3.1 101.3 91.3 +0.3 105.6 100.0 Volume Change % Tensile Stmngth Retained % Three Months Immersion A S T M Hardness Change Pts. 59.0 Hydrochloric Sodium Elongation Retained % 95.7 Water Skydrol at 75” + 5°F +7.6 Hexane Tide Vdume Change % Immersion No. 3011 Ethyl Alcohol Methyl Unchanged Unchanged +73.3 One Month AST.M -18 No. 1 011 Elongation Retained % White Res. Unchanged V. Tacky 0 -2 0 White Res. Unchanged Unchanged at 75” z 5°F Hardness Change fb. Surface Condition + 13.8 85.9 78.3 -6 A S.T M No. 3 011 +72.8 55.9 56.5 -17 Unchanged A S.1.M +89.4 40.2 43.5 -22 Unchanged +6.2 104.7 95.7 -1 Unchanged + 10.6 79.1 82.6 -6 Unchanged Dlstllled Fuel 8 Water Ethyl Alcohol Unchanged (continued) Rubbers and Elastomers TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS 351 (continued) Three Months Immersion et 75’ = 5OF Volume Change % Hexane Tensile Strength Retained % Elongation Retained % Hardness Chanp Pts. Surface Condition +54.8 49.6 52.2 -15 Unchanged +4.3 100.4 87.0 +l Unchanged Methyl Ethyl Ketone +41.0 57.7 69.6 -17 Unchanged Olive Oil +19.5 84.6 82.6 -11 Unchanged Skydrol 500 +53.9 49.2 69.6 -21 Unchanged Sodturn Chloride (25%) +1.5 100.0 75.9 +l Sodium Hydroxldc (lC?o) +5.0 95.7 87.0 +5.8 97.9 87.0 Hydrochloric Acid (10%) Tide 1I”,) Unchanged 0 Unchanged -1 Unchanged Six Months Immersion at 75’ r 5’F Volume Change % 1 011 Tensile Strength Retained % Elongation Retained $6 Hardness Change Pts. Surface Condition +20.7 80.3 78.3 -8 Unchanged AS 1 M No 3011 +76.9 57.7 56.5 -21 Unchanged A S 1 M Fuel B +87.4 -20 Unchanged A S 1 M No 39.3 47.8 +8.5 99.6 87.0 -1 Unchanged +11.2 79.9 87.0 -4 Residue +54.2 46.6 52.2 -15 +5.7 93.6 82.6 +l Unchanged +41.6 48.7 65.2 -17 Unchanged +23.3 83.8 78.3 -12 Unchanged +57.8 44.4 52.2 -23 Unchanged Sodium Chlonde (25%) +1.9 102.1 87.0 +2 Unchanged Sodwm Hydroxide (10%) +6.3 86.8 78.3 +l Unchanged Tide (l”/.) +8.4 102.6 87.0 +l Unchanged Dtstllled Water Ethyl Alcohol Heaane Hydrochloric Acid (lo”.) Methyl Ethyl Ketone Olive 011 Skydrol 500 CHEMICAL RESISTANCE OF 50 V&TALON 6505150 POLYCHLOROPRENE 72 Hours Volume Change % Tensile Strength Retained X Immersion Unchanged BLEND COMPOUND at 2 12’F Elongation Retained % Hardness Change Pts. Surface Condition A.S.T.M. No. I Oil +46.4 70.8 68.0 -21 SI. Tacky A.S.T.M. No. 3 011 +114.0 42.7 48.0 -30 SI. Tacky A.S.T.M. Fuel B +118.4 37.1 48.0 -27 Unchanged Distilled Water +6.7 98.1 80.0 -1 Unchanged Ethyl Alcohol -2.3 88.3 80.0 +2 Unchanged Hexane +33.3 46.5 48.0 +2 Unchanged Hydrochloric Acid (10%) +15.0 84.0 64.0 -2 Unchanged Methyl Ethyl Ketone +21.2 59.3 72.0 -16 Unchanged Olwe Oil +33.4 72.5 72.0 -22 SI. Tacky Skydrol +43.4 53.5 80.0 -28 SI. Tacky 500 Sodturn Chloride (25%) Sodwm Hydroxide (10%) Tide (1%) 95.1 76.0 +3 Unchanged + 14.6 87.5 72.0 0 Unchanged +6.2 97.3 84.0 +O.Ol -2 Unchanged (continued) 352 Corrosion Resistant Materials Handbook TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS (continued) One Month Immersion at 75’ + 5°F Volume Change lb Tensile Strength Retained X Elongation Retained X Hardness Surfwe Change Pts. Condition A.S 1 M. No. 1011 +17.5 82.3 76.0 -9 Unchanged A.S.1 M. No. 3 011 +81.3 47.4 48.0 -21 Unchanged A.S.T.M. +99.0 39.7 44.0 -23 Unchanged Dlstllled Water +2.7 104.5 96.0 -2 Unchanged Ethyl Alcohol +5.2 88.7 84.0 -7 Unchanged Fuel I3 +73.6 40.5 48.0 -18 Unchanged +2.5 102.8 100.0 -2 Unchanged Methyl Ethyl Ketone +27.8 62.3 76.0 -16 Okve 011 +ll.O 88.7 84.0 -8 Skydrol 500 +29.6 77.2 84.0 -13 Hexane Hydrochlonc Actd (10%) White Res. Unchanged V. Tacky Sodium Chloride (250,~) +2.0 98.1 96.0 -3 White Res. Sodium Hydrorlde (10%) +2.2 101.1 96.0 -3 Unchanged +2.1 98.1 .%.O -1 Unchanged lode (1%) Three Months immersion at 75’ : 5’t Volume Change X A S T M No AS TM 1 011 No 3011 A S 1 M Fuel 8 Tensile Strength Retained X Elongation Retained K Hardness Change Fts. Surfacr Condlion +32.1 72.5 76.0 -14 93.3 50.3 52.0 -21 Unchanged 38.4 40.0 -25 Unchanged +110.5 Unchanged +4.0 101.5 96.0 -1 Unchanged +10.6 86.2 88.0 -6 Unchanged +81.6 44.8 48.0 -21 Unchanged +3.1 97.3 92.0 Methyl Ethyl Ketone +28.8 68.3 76.0 Olive 011 +20.8 84.5 Shydrol 500 +30.2 72.5 Dlstllled Water Etnyl Alcohol Hexane Hydrochlonc Aild t 10-o) Sodwm Chloride (2fP01 Sod~urn Hydroxide (IO”.) ltd.? II"ab 0 Unchanged -17 Unchanged 84.0 -14 Unchanged 80.0 -18 Unchanged +0.6 97.7 72.0 +2.7 97.7 92.0 -1 Unchanged +3.8 98.1 92.0 -1 Unchanged 0 Unchanged Six Months Immersion at 75” = 5°F VdlUllO Chrngo X Tonsil0 Strength Retained X Elongation Retainrd X HlrdMSS Change Pts. Surface Condition A.S.T.M. No. 1011 +41.6 67.8 72.0 -16 A.S.T.M. No. 3 011 +95.8 46.9 52.0 -25 Unchanged Unchanged A.S.T.M. Fuel B + 130.3 36.7 44.0 -24 Unchanged Dtstllled Water ~6.3 101.5 92.0 -1 Unchanged Ethyl Alcohol +6.1 85.8 88.0 -5 Unchanged (continued) Rubbers and Elastomers TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS 353 (continued) Six Months Immersion at 75’ r 5°F Volume Change K Hexane Tantile Strength Retainad K + 114.7 Hydrochlonc Acrd (10%) Elongation Retained X Hardnass Change Pts. 42.7 44.0 -20 +4.6 90.0 76.0 -1 Surtrce Condition Residue Unchanged Methyl Ethyl Ketone +28.5 60.6 72.0 -16 Unchanged Olbve 011 +23.6 80.2 76.0 -14 Unchanged Skydrol 500 +31.5 68.3 94.0 -19 Unchanged Sodrum Chlonde (25%) +1.2 99.8 88.0 +l Sodium Hydroxrde (10%) +4.3 93.0 84.0 Tide (1%) +5.8 99.8 88.0 CHEMICAL RESISTANCE OF 70 VISTALON 6505130 POLYCHLOROPRENE Unchanged 0 Unchanged -1 BLEND Unchanged COMPOUND 72 Hours Immersion at 212’F Volume Change X Tensile Strength Retained $6 Elongation Retained K Hardness Change Pts. Surface Condition A.S.T.M. No. 1 011 +66.4 61.0 62.5 -24 St. Tacky A.S.T.M No. 3 Oil + 130.9 39.5 45.8 -32 SI. Tacky A.S.T.M. Fuel 8 + 137.4 -27 29.5 37.5 Dlstrlled Water +4.0 101.5 87.5 0 Unchanged Unchanged Ethyl Alcohol -1.5 91.5 83.3 +3 Unchanged Unchanged Hexane +47.4 41.5 45.8 -1 Hydrochlonc Acrd (10%) + 12.3 91.0 75.0 -1 Unchanged Methyl Ethyl Ketone + 15.5 64.0 _ 79.2 -14 Unchanged Olive 011 + 37.0 72.5 75.0 -21 SI. Tacky Skydrol 500 +25.6 72.0 87.5 -21 SI. Tacky Sodium Chloride (25%) +0.8 108.C 83.3 +2 Unchanged Sodium Hydroxide (10%) +0.6 95.0 79.3 -1 Unchanged Tide (1%) +3.6 91.5 83.3 -1 Unchanged . One Month Immersion at 75” + 5’F Volume Change K Tensile Strength Retained K Elongation Retained % Hardness Change Pts. Surface Condition + 27.0 79.0 75.0 -11 Unchanged A S 1 M No 3 011 + 102.2 50.0 45.8 -21 Unchanged A S T M Fuel B +115.3 -23 Unchanged -2 Unchanged AS TM No 1011 29.5 33.3 Drstrlled Water + 2.5 108.0 100.0 Ethyl Alcohol +*3.8 98.0 95.8 - Hexane Hydrochlonc Actd (lo”.1 5 Unchanged +81.5 35.5 37.5 -21 Unchanged +2.3 109.5 108.3 -2 Unchanged Methyl Ethyl Ketone +15.5 61.5 75.0 -12 Olrve 011 + 14.4 90.5 91.7 -9 Skydrol 500 +15.3 89.5 91.8 -10 Sodrum Chlonde (.25”.) +O.? 101.5 100.0 -2 White Res. Sodrum Hydroxide (lO”.J + 1.2 95.5 87.5 -2 Unchanged 100.0 100.0 -1 Unchanged Trde (I”,) +1.4 White Res. Unchanged V. Tacky (continued) 354 Corrosion Resistant Materials Handbook TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS (continued) Three Months Immersion at 75” 2 5°F Volume Change X Tensile Strength Retained K Elongation Retained % Hardness Cnange pts. Surface Condition A.S 1 M No 1011 +47.6 67.5 70.8 -15 Unchanged AS TM 3011 +112.4 45.5 45.8 -21 Unchanged -23 Unchanged No A S.1 M. Fuel 8 Dlstllled Water Ethyl Alcohol + 128.5 37.0 37.5 +3.1 103.5 100.0 +4.5 93.5 91.7 -4 Unchanged -21 Unchanged 0 Unchanged + 105.4 43.0 41.7 +2.3 100.0 91.7 +17.1 79.0 87.5 -13 Unchanged Olwe 011 +25.3 80.5 79.2 -14 Unchanged Skydrbl 500 +14.3 83.5 95.8 -12 Unchanged Sodwm Chlonde -1 Sodium Hydroafde Hexane Hydrochlonc Methyl Acid (l(P,) Ethyl Ketone (25”.) (1P.l Tide (1%) +0.6 104.0 83.3 +1.8 100.0 95.8 ~2.4 107.5 95.8 0 0 -2 Unchanged Unchanged Unchanged Unchanged Six Months Immersion at 75” 2 5°F Volume Channe K Tensile Strength Retained K Elongation Retained K Hardness Change Pts. Surface Condition A.S.T.M. No. 1011 +60.9 66.0 70.8 -19 Unchanged A.S.T.M. No. 3 011 ~116.1 51.5 50.0 -23 Unchanged Fuel 8 + 155.6 36.0 37.5 -23 Unchanged +4.5 104.5 95.8 +3.2 95.0 87.5 -2 -20 A.S.T.M. Dlsttlled Water Ethyl Alcohol Hexane Methyl Acid (10%) Ethyl Ketone Unchanged Residue 39.5 41.7 c3.4 102.0 95.8 c17.7 67.5 75.0 -12 Unchanged + 147.3 Hydrochlonc 0 Unchanged 0 Unchanged Olwe 011 ~28.0 86.0 83.3 -14 Unchanged Skydrol 500 + 14.9 85.0 95.8 -13 Unchanged Sodwm Chlonde Sodturn Hydroxide Tide (1%) (25%) (lD%) +0.7 104.0 95.8 +l Unchanged +2.2 99.0 87.5 cl Unchanged +4.0 102.5 91.7 0 Unchanged Rubbers TABLE 2.13: VARIOUS ELASTOMERS AND RUBBERS-MINOR CHEMICAL COMPATIBILITY and Elastomers 355 RUBBER CO. CHARTS (continued) 356 Corrosion Resistant Materials Handbook TABLE 2.13: glcium C.lCl”rn Carbonat* ChlowJ. VARIOUS ELASTOMERS I I AND RUBBERS-MINOR AIAIAIAlAl RUBBER CO. kontinued) lAl*ICl’JI*I ~I~I~I~I~l~I~l~l~l~l~l (continued) Rubbers and Elastomers TABLE 2.13: VARIOUS ELASTOMERS AND RUBBERS-MINOR RUBBER CO. (continued) 357 358 Corrosion Resistant Materials Handbook TABLE 2.13: VARIOUS ELASTOMERS AND RUBBERS-MINOR RUBBER CO. (continued) LEGEND u ” A A A a u u ” u ” u B B ” ” ” u u B B ” u u u u c c ” u ” ” ” ” ” u n ” ‘J ” A l”l”l”lCl ” u 1 ” ” U U ” c A B “_ ” ” B ” IB ” ” B ” B B u c ” ” ” A ” A A A ” ” ” B ” B A A 1 ” A B B B ” B I u ” u u u u c I c ” u u ” ” B ” ” u ” u u u ” u ” B u u ” ” ” u ” ” ” u ” ” ” u ” ” u B ” u B ” ” ” B ” ” u u ” u ” ” B ” n u ” u ” lvlele ” ” ” u u u ” B B I B B ” ” B ” ” B B ” u n n B A n c u c ” it-. B u B ” ” C u ” u ” ” ” u u u ” u u A B u u u ” u c B ” A ” 8 A A fi A A A _ B A A A 8 ” B A A A !.-_ u u B u U B ” B u ” ” u ” ” B ” B ” C A A ” B ” A B ” B B ” 6 A ” ” A A B 8 c ” A c A -. c u ,” _~ ” u A A A R B A 4 n ” u . c B B B B A ” AL c B u 8 ” A C B C ” u B I”lcl”l”lsiclclcle B B U ” B A I A ._A A ” u d--4 (continued) Rubbers and Elastomers TABLE 2.13: VARIOUS ELASTOMERS AND RUBBERS-MINOR i ” ICI B ui~l~l~l iI B iI ” 359 RUBBER CO. (continued) I 6 I I I IAlA ; I 6 I I I IAl ” I i Lg I c I I- g; a__ ” I ] (continued) 360 Corrosion TABLE 2.13: Resistant VARIOUS LEGEND Materials Handbook ELASTOMERS / AND RUBBERS-MINOR / / / / RUBBER CO. (continued) / / / / / / / / / 362 Corrosion TABLE 2.13: Resistant VARIOUS Materials Handbook ELASTOMERS AND RUBBERS-MINOR RUBBER CO. (continued) ” ” -+ -+ B ” -+ --i” ” -5 A A ” ” -z--z- c --& -+- A c +_ ” c ” ” ” B ” _-!A” -& ” ” ” ---Ti--E- Rubbers TABLE 2.13: VARIOUS ELASTOMERS AND RUBBERS-MINOR and Elastomers 363 RUBBER CO. (continued) LEGEND (continued) 364 Corrosion TABLE 2.13: Resistant VARIOUS Materials Handbook ELASTOMERS AND RUBBERS-MINOR RUBBER CO. (continued) LEGEND ikelly. sol”ent ik”drol500 B. c. E :Lydrol7000 hap Sof”wm* $cow Mobtk Type A km”” Vacuum AM”AC781 ,Gmsw, bconv Vacuum PD959B ia& Ash UI ulul U u A u u A u u A _: VI Al u A A A 181 A B B A UI U B A l B A A U u l u U A B B 1 A A A _:: tinued) Rubbers TABLE 2.13: VARIOUS ELASTOMERS AND RUBBERS-MINOR and Elastomers RUBBER CO. (continued) _!I-_ u- I, II A ---_ I I I I I I I I a ” --t- T 365 n - u ” -4 ” 7 + ” -+ ” -2 j (continued) 366 Corrosion Resistant Materials Handbook TABLE 2.13: VARIOUS ELASTOMERS - AND RUBBERS-MINOR RUBBER CO. (continued) Rubbers TABLE 2.14: VARIOUS RUBBER AND ELASTOMERIC TANK 367 and Elastomers LININGS-ACME-FISHER Linings Recommended to Resist Various Chemicals LININGS. A - Abrasron Resistant B - Soft Natural C - Semi-Hard Natural CHEMICALS INORGANIC ACIDS Arsenic Battery Acid (Sulphuric) Carbonic Chlorine Water Cupric Acid (Copper Sulrate) Fluoboric Fluosilicic Hydrobromic Hydrochloric Hydrofluoric Hydrofluoric Max. Cont. Hydrogen Sulfide Water Nitric Nitric Perchloric Phosphoric Sulfonic Acid Sulphuric Sulfurous SALTS a ALKALIES Abrasive Solutions Aluminum Salts Alums Ammonium Hydroxide Ammonium Persulfate Other Ammonium Salts Barium Salts Barium Sulfide Calcium Bisulfite Bleach Lrquor Calcium Hydrochlorite Other Calcium Salts Copper Salts Iron Salts Lead Salts Mercuric Chloride Nickel Acetate Potassium Hydroxide Potassium Drchromate Other Potassium Salts Sodium Hydroxide Sodium Bisulfite Sodium Hydrochlorite Sodium Hypochlorite Other Sodium Salts Sulphur Chloride Silver Nitrate Tin Salts Zinc Salts D - Hard Natural E - Neoprene F - Polyvinyl Chloride Natural CONCENTRATION G - Chloro-Butyl H - Ethylene Propylene NR - Not Recommended (Koroseal) TEMPERATURE LINING OF 175 Any To Saturation To Saturation Any Any Any Any To 50% To Saturation 10% 25% To Saturation To 85% To 50% To Saturation To To To To To To Saturation Saturation Saturation Saturation Saturation Saturation To To To To To To To Saturation Saturation Saturation Saturation Saturation Saturation Saturatron To Saturation To Saturation To Saturation To Saturation To Saturation To Saturation To Saturation 16% To Saturation To Saturation Any To Saturahon High Bake Phenolic 175 125 140 175 175 175 186 175 225 160 90 70 120 180 180 160 160 OF 180 175 175 160 175 175 175 180 175 140 175 175 175 175 175 180 160 175 160 180 160 160 150 225 180 NR 175 175 175 DB DB D-H F DB DBE DB DB DB G DB DEF F DF EDB DB DB D A DB DB D DB DB DB DB DB D D DB DE DB DB D DE DB DF DBE DB DF D G-H DBE D-B DE DE (continued) 368 Corrosion Resistant Materials Handbook TABLE 2.14: VARIOUS CHEMICALS RUBBER AND ELASTOMERIC TANK CONCENTRATION Brass Cadmium Chromium Copper Gold Lead Nrckel Silver Tin Zinc Trace to Any Any To 25% Any Any To Saturation Any 40% Any To Saturation Any Any Any Any To Saturation Any To Saturation Any The temperatures given are somewhat conservative; however should be conducted to satisfy users particular problem. (continued) LINING TEMPERATURE PLATING SOLUTIONS ORGANIC MATERIALS Acetate Solvents Alrphatic Solvents Acetic Acid Acetic Anhydride Acetone Alcohols Castor Oil Citric Acrd Coconut Oil Cottonseed Oil Dye Stuffs Citric Acid Ethylene Glycol Formaldehyde Formic Acrd Fumaric Acid Furfural Gallic Acid Glucose Glue Glycerine Lactic Acid Malic Acid Minerals Oils Oxalic Acid Soaps Tannic Acid Triethanolmine Vinegar LININGS-ACME-FISHER If higher OF 140 F-B-D OF NR 160 160 150 150 175 150 160 150 150 150 160 160 100 100 180 100 160 175 175 175 160 150 160 160 175 175 175 150 E D D DB DB D DF D D D F DB D D BDF D DB DB DB DB D DB ED D DB DB DB DF operating temperatures are anticipated, tests Cements, Mortars, and Asphalt TABLE 3.1: EPOXY-BASE FLOOR SURFACING SYSTEMS-STONHARD STONCLAD is a three-component, epoxy-base floor surfacing system. It was specifically designed for surfacing and patching industrial floors exposed t o corrosive spillages and abrasive, wheeled traffic. STONCLAD-HT i s a threecomponent, epoxy-base floor surfacing system. It was specifically designed for surfacing and Fatching industrial but less floors exposed t o corrosive spillages and abrasives, wheeled traffic a t temperatures above 140 F (60°C), than 250°F (122°C). The test procedure used was to totally immerse cured samples of STONCLAD in the chemicals listed for a period of 90 days at normal room temperatures. (This is a n exceptionally severe test, since most floors subject t o chemical spillages such as these are "flushed down" periodically with water as part of the normal floor maintenance operation.) The resultant resistance of STONCLAD t o the various chemicals is rated using the symbols listed below. (It is assumed that normal "good housekeeping procedures" are used, including a daily flushing down with clean water.) RATING CODE E - Excellent G - Good F - Fair NR - Not Recommended OS - Suitable for use where "occasional spillages" occur, when followed by immediate water flushing. Chemical Resistance Guide for STONCLAD ACIDS CHEMICAL RATING Acetic - 5%. . . . . . . . Acetic - 10%. . . Acetic - 20%. . . Acetic - Glacial. . CH EM1CAL RATING Heptanoic.. . . . . . . . . . . . . . . . . . . . . OS Hydrochloric 15%. . . . . . . . . . . . . E Hydrochloric - 37%. . . . . . . . . . . . . G Hydrofluoric - 5%. . . . . . . . . . . . . . G Hydrofluoric - 10%. . . . . . . . . . . . . F Hydrofluoric - 15%. . . . . . . . . . . . . OS Hypochlorous - 5%. . . . . . . . . . . . . E - . . . . . . . . os Benzoic - Sat. 3%.. . . . . . . . . . . . . . E Boric - Sat. 30%. . . . . . . . . . . . . . . E Butyric - 10%. . . . . . . . . . . . . . . . . . F Lactic Lactic Chromic - 10%. . . . . . . . . . . . . . . . .G Chromic - 15%. .. Chromic - 20%. . . Citric - 50%. . . . . . . . . . . . . . . . . . .E Cresylic. . . . . . . . . . . . . . . . . . . . . . . OS - up t o 20%. . . . - over 25%. . . . Maleic - 30%. . . . . . . . . . . . . . . . . .G Maleic - 40%. . . . . . . . . . . . . . . . . .F Maleic - 60%. . . . . . . . . . . . . . . . . .OS Malic - 50%. . . . . . . . . . . . . . . . . . .E Monochloroacetic -5%. . . . . . . . . . . F Monochloroacetic 10%. . . . . . . . . OS . . . . . . . . . . . . . . . . . . .G - Fatty . . . . . . . . . . . . . . . . . . . . . . . . . . G Formic - up t o 10%. . . . . . . . . . . . .OS Formic - over 10%.. . . . . . . . . . . . . NR Fluoboric. ..................... G Nitric - 10%. . . . . . . . . . . . . . . . . . . E ................G . . . . . . . . . . . . . . . .F . . . . . . . . . . . .NR Nitric - over 40% 369 (continued) 370 Corrosion Resistant Materials Handbook T A B L E 3.1: EPOXY-BASE FLOOR SURFACING SYSTEMS-STONHARD (continued) ACIDS (continued) CHEMICAL Oleic. . . . . . . . . . Oxalic - Sat.. . . RATING CHEMICAL .............E . . . . . . . . . . . . .E Phthalic.. RATING ...................... F Succinic - Sat.. . . . . . . . . . . . . . . . .E Sulfuric - 20%. . . . . . . . . . . . . . . . . E Sulfuric - 50%. . . . . . . . . . . . . . . . . G Sulfuric - 70%. . . . . . . . . . . . . . . . . F Sulfuric - 98%. . . . . . . . . . . . . . . . . NR Pelargonic. . . . . . . . . . . . . . . . . . . . . OS Perchloric - 35%. . . . . . . . . . . . . . . F Phosphoric - u p t o 50%. . . . . . . . . i F Phosphoric - 70%. . . . . . . . . . . . . .os Phosphoric - Conc. 85%. . . . . . . . . NR Picric - Sat.. . . . . . . . . . . . . . . . . . . E Tannic - Sat.. . . . . . . . . . . . . . . . . . . E Tartaric - Sat.. . . . . . . . . . ....E ALKALIES AND SALTS CHEMICAL RATING Aluminum Chloride - 50%. . . . . . . . E Ammonium Chloride - 50%. . . . . . . E Ammonium Hydroxide - up t o 20%. E Ammonium Hydroxide - 409b.. . . . . G Ammonium Nitrate - Sat.. . . . . . . . . E Ammonium Persulfate . . . . . . . . . . . .E Ammonium Sulfate - Sat.. . . . . . . . . E Calcium Chloride - 50% Calcium Hydroxide - Sa Calcium Hypochlorite - up t o 15%. . G Copper Fluoroborate Ferric Chloride.. . . . . . . . . . . . . . . . . G Ferrous Sulfate.. . . . . . . . . . . . . . . . . G Potassium Hydroxide - up to 40%. . E CHEMICAL RATING Sodium Benzoate. . . . . . . . . . . . . . .. E Sodium Carbonate (Soda Ash)-Sat.. E Sodium Bicarbonate - Sat.. . . . . . . . E Sodium Bisulfate - Sat.. . . . . . . . . . E Sodium Bisulfite - Sat.. . . . . . . . . . . E Sodium Chloride (Salt) . . . . . . . . . . . .E Sodium Glutamate.. . . . . . . . . . . . . ..E Sodium Hydroxide - up t o 5 0 % . . . .E Sodium Hypochlorite - up t o 10%.. .G Sodium Propionate.. . . . . . . . . . . . . .E Sodium Sulfate - Sat.. . . . . . . . . . . . E Sodium Sulfide - Sat.. . . . . . . . . . . . E Trisodium Phosphate - Sat . . . . . . . E Zinc Nitrate.. . . . . . . . . . . . . . . . . . . .G SOLVENTS AND OTHER CHEMICALS SU B STAN CE RATING Acetone, . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . os Aniline, . . . . . . . . . . . . . . . . Alcohol (Methyl). . . . . . . . . . . . . . . . . 0 s Alcohol (Ethyl, Propyl. Isopropyl, Butyl). . . . . . . . . . G Amyl Acetate.. . . . . . . . . . . . . . . . . . E Beer . . . . . . . . . . . . . . . . . . . . . . . . . . Diacetone Alcohol. . . . . . . . . . . . . . . E Diethyl Phthalate. . . . . . . . . Dimethyl Phthalate. . . . . . . . Ethyl Acetate. . . . . . . . . . . . . . . . . . . OS Ethylene Glycol. . . . . . . . . . . . . . . . . E Ether. . . . . . . . . . . . . . . . . . . . . . . . . OS Ethylene Dichloride. . . . . . . . . . . . . . .NR E . . . . . . . . . . . . . . . . . . . os Butyl Acetate. . . . . . . . ........G RATING SUBSTANCE Formaldehyde. . . . . . . . . . . . . . . . . .E Butyl Lactate. . . . . . . . . . . . . . . . . . . G Bromine. . . . . . . . . . . . . . . . . . . . . . . NR Gasoline.. . . . . . . . . . . . . . . . . . . . . . Glycerine. . . . . . . . . . . . . . . . . . . . . . . Glyoxal ....................... Carbon Disulfide.. . . . . . . . . . . . . . . . Carbon Tetrachloride. . . . . . . . . . . . . Chlorobenzene. . . . . . . . Corn Oil. . . . . . . . . . . . . . . . . . . . . . . Cyclohexane. . . . . . . . . . . . . . . . . . . . Cyclohexanol. . . . . . . . . . . . . . . . . . . Cyclohexanone. . . . . . . . . . . . . . . . . . Chloroform. . . . . . . . . . . . . . . . . . . . . Hydrogen Peroxide NR E E E E OS NR E E E - 10%.. . . . . . . E JP5 Jet Fuel.. . . . . . . . . . . . . . . . . . . E Juices - Fruit. . . . . . . . . . . . . . . . . . E Juices - Vegetable. . . . . . . . . . . . . .E Kerosene ...................... OS (continued) 371 Cements, Mortars, and Asphalt TABLE 3.1: EPOXY-BASE FLOOR SURFACING SYSTEMS-STONHARD (continued) SOLVENTS AND OTHER CHEMICALS (Continued) SUBSTANCE RATING SUB STANCE Lanolin. . . . . . . . . . . Lard. . . . . . . . . . . . . . . . . . . . . Linseed Oil.. . . . . . . RATING .............E . . . . . . . . . . . . .F Phenol - 5%. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . NR Mayonnaise. . . . . . . . . . . . . . . . . . . . G Methyl Ethyl Ke . . . . . . NR Methyl Isobutyl . . . . . . . . . . . . NR Methyl Salicylate - 50% in Toluene. . . . . . . . . . . . . . . Methylene Chloride. . . . . . . . . . . Muriatic Acid (See Hydrochloric Acid) Mustard. . . . . . . . . . . . . . . . . . . . . . . E Naphtha. . . . . . . . . . . . . . . . . . . . . . . F Skydrol ....................... Sucrose - Sat. (Sugar). . . . E . . . . . . . . . . . . . . .E Trichloroethane. . . Trichloroethylene. . Triethanolamine. . . Triethylene Glyco I. Vinegar . . . . . . . . . . . . . . . .E (Household). . . . . . . . Water. . . . . . . . . . . . . . . . . . . Wine. . . . . . . . . . . . . . . . . . .E Oils - Mineral. . . . . Oils - Vegetable. . . Xylene. . . . . . . . . . . . . . . . . . . . . . . . G Chemical Resistance Guide for STONCLAD HT ACIDS CHEMICAL RATING Acetic - 5%. . . . . . Acetic - 10%.. . . . Acetic - 3 0 % . . , . , Acetic - Glacial.. . . . . RATING Lactic - u p to 20%. . . . . . . . . . . . . . F Lactic - over 25%. . . . . . . . . . . . . . OS Maleic Maleic Maleic Maleic Benzoic - Sat . . . . . . . . . Boric - Sat . . . . . . . . . . . . . . . Chromic - 10%.. . . Chromic - 150h.. . . . . . Chromic - 30%. . . . Citric - Sat . . . . . . . . . . . . . . . . . . .E Cresylic. . . . . . . . . . . . . . . . . . . . os Diglycolic. . . . . . . . . . . . . . . . . . . . . . CHEMICAL G Fatty.. . . . . . . . . . . . . . . . . . . . . . . . . E .F Formic - u p to 10%.. . . . . . . . Formic - over 10% . . . . . . . . . . . NR Fluoboric. . . . . . . . . . . . . . . . . . . . . . G . . . . . . . . . . . . . os . . . . . . . . . . . . .E Hydrochloric - 37%. . . . . . . . . . . . . G Hydrofluoric - 5%. . . . . . . . . . Hydrofluoric - 10%.. . . . . . . . . . . . G Hydrofluoric - 15%. . . Hypochlorous - 5%. . . . . . . . . . . . . E - 10%.. . . . . . . . . . . . .E - 30%. . . . . . . . . . . . . . . . . .G - 40%.. . . . . . . . . . . . . . . . . F - Sat . . . . . . . . Mr,nochloroacetic Mmochloroacetic -1 - 20%. . . . . . . . . 0s Nitric - 20%. . . . . . . . . . . . . . . . . . . E Nitric - 30% ......... G Nitric - over . . . . . . . . . . . . . . . NR Oleic.. . . . . . . . . . . . . . . . . . . . . . . E Oxalic - S a t . . . . . . . . . . ....E Pelargonic. . . . . . . . . . . . . . . . . .os Phosphoric - 70%. . . Picric - Sat.. . . Phthalic.. . . . . . . . . . . . . . . . . . . . . . . Succinic -Sat .... F ..E (continued) 372 Corrosion Resistant Materials Handbook T A B L E 3.1: EPOXY-BASE FLOOR SURFACING SYSTEMS-STONHARD (continued) ACIDS (continued) CHEMICAL Sulfuric RATING CHEMICAL . . . . . . . . . . . . . .E . . . . . . . . . . . . . .F - 98%. . . . . . . . . . . . . . . . .NR Tannic - Sat.. .............. RATING Tartaric - S a t . . . . . . . . . . . . . . . . . . E Trichloroacetic - 5?6 . . . . . . . . . . , G Trichloroacetic - 10% . . . . . . . . . . .F Trichloroacetic - 20% . . . . . . . . . .os .E ALKALIES A N D SALTS CHEMICAL RATING CHEMICAL Aluminum Chloride - 50%. . . . . . . . E Ammonium Chloride - Sat . . . . . . . E Ammonium Hydroxide - u p t o 20%. E Ammonium Hydroxide - u p t o 40%.G Ammonium Nitrate . . . . . . . . . . . . . . . E Ammonium Sulfate - Sat.. . . . . . . . . E RATING Potassium Hydroxide - up t o 40%. . E Sodium Carbonate (Soda Ash)-Sat.. E Sodium Bicarbonate - Sat.. . . . . . . . E Sodium Bisulfate - Sat.. . . . . . . . . . E Sodium Bisulfite - Sat.. . . . . . . . . . . E Sodium Chloride (Salt). . . . . . . . . . . .E Sodium Hydroxide - u p t o 50%. . . . E Sodium Hypochlorite - u p t o 10%.. . G Sodium Sulfate - Sat. Sodium Sulfide - S a t . . . . . . . . . . . . E Calcium Chloride - Sat . . . . . . . . . . E Calcium Hypochlorite - up t o 15%. . G Copper Fluoroborate. . . . . . . . . . . . . E Ferric Chloride - Sat.. . . . . Ferrous Sulfate. . . . . . . . . . . Trisodium Phosphate - Sat.. Zinc Nitrate.. ......E . . . . . . . . . . . . . . . . . . .G SOLVENTS AND OTHER CHEMICALS SUBSTANCE RATING Acetone. . . . . . . . . . . . . . .OS Acrylonitrile. . . . . . . . . . . .OS Aniline. . . . . . . . Isopropyl. Butyl). . G Amyl Acetate. . . . . . . . . . . E Beer.. . . . . . . . . . . . . . . . . E Butyl Lactate. . . . . . . . . . . G Bromine. . . . . . . . . . . . . . . NR Carbon Disulfide. Carbon Tetrachlo Chlorobenzene. . . . . . . . . . E Corn Oil. . . . . . . . . . . . . . . E Cyclohexane. . . . . . . . . . . . E Chloroform. . . . . . . . . . . . . NR Diacetone Alcohol. . . . . . . E Diethyl Phthalate., . . . . . . E Dimethyl Phthalate. . . . . . . E Ethyl Acetate. . . . . . . . . . . 0 s Ethylene Glycol. . . . . . . . . E Ether. . . . . . . . . . . . . . . . . 0s Ethylene Dichloride. . . . . . . NR SUBSTANCE Formaldehyde.. RAT ING . . . . . . . . . . . . . .E Gasoline.. . . . . . . . . . . . . . . . . . . . E Glycerine. . . . . . . . . . . . . . . . . . . . E Glyoxal. . . . . . . . . . . . . . . . . . . . . .E Hydrogen Peroxide - 10%.. . . . . E S U B STANC E RATING Naphtha.. . . . . . . . . . . . . . E Naphthalene . . . . . . . . . . . . G oils - Cutting.. . . . . . . . . E Oils - Mineral. . . . . . . . . . E Oils - Vegetable. . . . . . . . G JP5 Jet Fuel.. . . . . . . . . . . . . . . . . E E Juices - Fruit. . . . . . Juices - Vegetable.. ...... E Peanut Butter.. . . . . . . . . . E Perchloroethylene. . . . . . . E Phenol - 5%. . . . . . . . . . . NR Pyridine.. . . . . . . . . . . . . . NR Kerosene . . . . . . . . . . . . . . .G Sucrose Lard. . . . . . . . . . . . . . . . . .E .......... .........F ................ E Methanol . . . . . . . . . . . . . . . . . . .NR Mayonnaise. . . . . . . . . . . . . . . . . . G Methyl Ethyl Ketone.. . . . . . . . . . .OS Methyl Isobutyl Ketone.. . . . . . . . . OS Methyl Salicylate - 50% in Toluene. . . . . . . . . . . . . . . . NR Methylene Chloride. . . . . . . . . . . . NR Milk.. . . . . . . . . . . . . . . . . . . . . . .E Mineral Spirits. . . . . . . . . . . . . . . .E Muriatic Acid (See Hydrochloric Acid) . . . .E Mustard. . . . . . . . . - Sat. (Sugar). .. E Toluene . . . . . . . . . . . . . . . . G Triacetin.. . . . . . . ....E Trichloroethane. . . . ..G Trichtoroethylene. . . . . . . . G Triethanolamine. ....... E Triethylene Glycol. . . . . . . E Urea . . . . . . . . . . . . .E Vinegar (Household). ... E Cements, Mortars, and Asphalt 373 TABLE 3.2: EPOXY FLOORING COMPOUNDS-ATLAS REZKLAD C IS a monolithic overlay designed specifically for use in applications where hydrofluoric acid and high concentrations of sodium hydroxide are encountered. REZKLAD C has been formulated to incorporate toughness, ability t o tolerate temperature cycling and good physical strength.Thls material IS installed dlrectly on the concrete slab t o give a durable, corrosion-resistant topping. CHEMICAL RESISTANCE OF REZKLAD C FLOORING COMPOUND _____ RT 140'F ___ -~ - -_ _ Acetic A c i d b e l o w 5 % R 5% to 10% Acetic Actd - _______ C -__ ~ Acetic i d 10% t o 50% - A c~Acetone _ ~~ _ - N N Lux L i q u i d N N _ -~ _ C N R A l u m or A l u m i n_u _ m_ Sulfate _ A m r.r ~-i i u-n i-- C hl o r i d e Nitrate Sulfate 50% R __._ __ _ R R N ~ Benzene S u l f o n i c Acid 10% - ~ _ _ - Benzoic Acid - - - _ ___ Black Liquor - - - -_ _ _ _ Bicachinq Liquor below 2% R R R N ~ _ _-- R N E t h_y k_n-e Dichloride _-Ethylene -G l y_____ col F i~-~ t t i Acids.___Ferric C h l o- r i d__ e Nitrate- Sulfate _ _ _ Fluosilicic A c i d _ _R _ _ - N - -___ - -.- N R N R c c ___ Hydrofluoric Acid ~ _ 20% t o 70% H y d r o g e n Peroxide - - Phosphoric _ - _ _Acid _ _to 25% ___ __Phosphoric Acid 25% Io 50% _~ -~ c N N - _ - ~CR ~ R-~ C N __-N Phosphoric A c i d above 50% __________ __ Pycric Acid to 5% Potassium C h l o r i d e Nitrate Sulfate - -- __ __-___ Potassium H y d r o x i d e -____-_ _ N_ _ below 25% R-~ C R ____ R - R R ____ Potassium H y d r o x i d_ e 25% to 50% _ - ~._ R ____C Sodium Bicarbonate Carbondre ___ ______ _ _ Sodium Nitrate Phosphate _ _ ~ Chloride - Sodium_ Sulfate Sulfide _ -__ Sodium H y d r o x i d e t o 25% ________- R R R R R R R Sodium - H y d r o x i d e 25% t o 50% R R-____ C C N S o d i u m Hypochlorite below 6 % S o-______ d i u m Hypochlorite 16% N - -~ N__ C --_-R R N ____ - Stannic C h l o r i d e Stearic Acid Sugar Salt Solution c c Sulfuric c i d_ below _ _ _A_ _ 40% Sulfuric _ Acid _ _50% - R C ____- _R_ _ _C _ __ C -N --- R ~ _ _ _ _ _ -_R _ _ Tpmato Juice ____ R R ___ Trichloroethylene N N Trisodium _- R R C N ~~ -~ -R-CR C __ Phosphate ~ Turpentine _ _ _ R C R Vegetable O i l c c R ~C Vinegar -~ R R C R R - N R R C N N N Lactic A c i d 5% to 10% C N Urine ~- Water Distilled _ _ _ _ Water a n d Sewage _______ Xylene - ~~ Water Fresh ~- ~ - R R_ _ _____ Urea, t o 20% -____ R C - _ - - _ _ _c C __ ~ ~~ R t o 5% Jet Fuel Kerosene Lactic A c i d b e l o w 5% _ N Petroleum --__ _ ~ - _ Phenol below 5% ~ ~ N _H_y p o c h l o r o u s & i d _ R____ N Perchloroethylene - _ _ ___ c _____ t l y d r i x hl o r-i c ALid ---__20% to .36%~ C _ N_ _ -_ ___ _R_ _ C C H y d r o f l u o r i c A c i d t o 2Ooh R ~ c c - ___ _ Toluene Sulfonic A c i d - R - - - _ _ - _ R __ R c H y d r o b r o m i c A c i d 20% . -Hydrochli;ic A c i d t o 20% _ . S u l f u r o u s Acid below 10% -Toluene - ~ ___. R or washed off the surface __ R Grape Juice ~ _ _ _ - - --- - ______ Formic A_c i d _90% ____~ ~ _ N C N N __. i_ illu 50% _ r i_c ALid _ _ ~above ~ ~- _ _ _ _R_ ~ C Formaldehyde below 37% _____ ---- be s e r v i c e a b l e i f t h e c o n t a m i n a n t is i m m e d i a t e l y removed _-_~ N_ R N N ~~ R C _____ ~ ~ Oxalic Acid - __ __ R ~ - -_____ - C - C o n~ d i t i o n a l M a y~ . R -~ Mineral _ _Oil_ _ _ _ _ _ R_ R~ ~ _ ~ - _ __ ~~ E t h y l_ Acetate - - -__ E t h y l Alcohol_ _ R -Magnesium C h l o r i d e Nitrate Sulfate Maleic A c i d 25% _ _ _ _ N - Not Recommended C ~N Nitric A c i d b e l o w 5% _____ t o_ 10% C N N Nitric A c i d -5%._ . _- -- ~ _ - - ~ R Oils _Vegeldble c c __ _ _____ ----- ~~Oleic _Acid N ___ N R _ _ ~ _ _ _ _____ ~ Ether C _ c _ _c _ _ R R _ N i c k e l C h l o r i d e Nitrate Sulfate R R ~ ~- N N _ Milk ~ N N ___________ Boric Acid R __ _ _ _ ______ R Butyl Acetate N N ___ - _ t3ulyl AILotloI R __ C_ - _ _ _____ Uutyric Acid N _____ N I o ri d e N iI rat e Su IIat e C d I L i u in C h R _ _ -~ - _ -R ____ Cnlci u ni~H y d r o x i d e_ R _ _ _ - _ ~- R CdlClUm H y- p o-c h l_ o r i t_ e N _ _ _ _ _ C -___ Ctilorine Dry C N ______ Chlorine Wet - ~ c ~c Ctiloririe Wdlcr ___ - __- C - N___ ClllOlOdLellC Acid_ _10% _~ _____ ~ N~ N _ Chloroform _ _ R _ _~C_ N C h r o m-~ i c A c i d 5% _-____C C h r o i n i c A c i d 5% to 10% N N - -__ _ _ _ _ _ ___ R N__ Citric Acid 10% - - ~ _ _ _______ - N N Methyl Ethyl Ketone - Copper Nitrate Sulfate _ _ _Chloride _ - - _ R - Recommended -~ I? __ T 1400F - -. - ~ - ~-_ Methylene C h l o r i d e - N _ _ ~N f l d r i u_m~ Chloride Sulfate R ________ Beer ~ _ __ ~ ~R Benzene __ - - -_ _ _ _ - _ _ _N_ Aqua Regia - Methyl A_ lcohol ~ - ~ A m m o n i u m H y---__ d r o x i d e 10% R R ___________ Amrnonium R C _ _ H _y d_ r_o x i d e 30% Aniline -~ ~ Lactic A c i d above 10% Lard _ ~ . Z i n c C h l o r i d e Nitrate Sulfate R R C ______ ~ R _ R R - _ _ N ~ R (cont Inued ) 374 Corrosion Resistant Materials Handbook TABLE 3.2: EPOXY FLOORING COMPOUNDS-ATLAS (continued) REZKLAD 250 i s the trowelable counterpart to sprayable REZKLAD 125s. REZKLAD 250 utilizes a room temperature curing, aromatic amine hardening system, thus the reason for i t s outstanding chemical resistance. In addition, this material has been formulated t o incorporate outstanding physical properties. REZKLAD 250 upgrades t h e surface of existing concrete floors and provides positive protection a t a reasonable cost. Rezklad 250 complies with ASTM C722, Specification for Chemical-Resistant Monolithic Surfacings. CHEMICAL RESISTANCE OF REZKLAD 250 - .___ __..- H e i k i a d 250 R l 15O'F .- Rezklaa 250 --. ~_ _ ~ _ _ ..~_. R - Recommended R T~ ._.__ 150°F ~ . ~ Lactic Acid. 5% t o 10% R R Acelic A c i d~~-~ . below _ _5%~ ~ _ ~ ~ - ~ _ _ _ R~ _R_ ~ __ _ . _ _ _ _ _ ~ AceGc Acid. 5% t o 10% R -._ R Lactic Acid, above 10% R__.._ C - .-. .. ... -~ _-_. _______ Acetic A c i d , 10% t o 50°h R C Lard R R .-.. ..___ ~~-~ - ___________ ._____ Ace ton e .....~.. _ _ ...-. .___._C NR Lux L i q u i d R R ~-. __._ ..__________ ~ __ ~ ~ ~~ ~~~~ Magnesium Chloride. Nitrate. Sullate R R- ~ ___._ _ ________.___ ~ ~ ~ Methylene C h l o r i d e _. ~ ~ ____-___ . ..__ ~ ~ ~ - _ ~ ~ ~ Mineral C i I __ N~i c k el~ C h l o r_ i d e , Nitrate Sulfate ._~~ ~~__--______ 5"/.___ ~ black Liquor ~ ~ . ____..__~.____ i l e a c h i n g Liquor. below 2% . . _-._ - .~_____ ___-Bleaching L i q u o r . ~c _ on .. ._._._-___ _c_ _ _ _ _ _ _ _ _ R R NR NR Oleic A c i d ~~~~~ ~ ~ _ Oxalic A c i d _ _ _ _- -~ ._. -- ~ - Perchloroethylene .___._._ Boric Acid R-~ R Petroleum ~ .. . _ _ . ..__-- B u t y l Acetate - __.. .._ ... .Butyl Alcohol __ - ~_ Butyric Acid RR ~~~ c -- C NR CalL I u n i C h l o r i d e . Nit r dte, Sullat e R R Cdlcium Hydroxide R ~~ ___ ~~ __..__.--~__ ~ . .. -_ ._--_ ~ _ ~ _.____ _ _~ _ - ~ . ~~ C t i Iu f olor ni~ ~~ _ _ _ _ _ _ c_ R ._._. C t i Ior oac et i c Ac -........._._ i d , be l o w 1 0% _~ . . - R C_ R R Phenol, ~_~~ _ ~ below _ ~ _.__._. _5% _ .__-_ _ _ _ _ _c_.___ ~ -Phosphoric Acid, to 25% R B RB _~______ -. ~ _ _ _ Phosphoric A c i d , 25% to 50% CB N R ~~. -~_ _ _ _ _ .. __._ - _ ~ . . _ ~ . _ ~ ___._. _ Phosphoric Acid. above 50% NR --. __ - - ~ - - - ~ _.....__ R NR R R _ Potassium y d r.o x i d e_ , below 25% -_ _ ~ H . -.__._ _ _____ ~ Potassium ydro x i_ d_ e_ , 25% to ~50% _ _ _ _ _ ~H_ _ ~ --. __ R R -- -- c c- S o d i u m Bicarbona;e, Carbonate -~ _s o _d i u_m _Chloride. _ ~ - Nitrate. Phosphate R R R R R R R R c c _ _ _ _ R_ R_ . ~ _ _ _ _ R ~ --_ S o d i u m Sulfate.--__ Sulfide S o d. i u.___ m H y ___..~ d r o x i d e , t o 25% -.--. ~ ----_-___ ~ _ _ R_ c _ _ _ . .~~ Cllrornic Acid. 5% Io 10% c NR S o d i u m Hydroxide. 25% t o 50% . -.- _ _ ~ _ __ ~ - ~ _ _ _ _ ~ _ _ _ ~ Citric Acid, to 40% S__._ odium Hypochlorite. below 6% ______ ~.. . - - . ~ ~_ - ~ _~_ . _ _ _ _ __R R ~ _ _ _ _ _ C h r o m i c Acid. below 5% . ~ - __._ Picric Acid. t o 5% _._.__ _ _ _ _ _ _ _ _ _ _ _ ~ Potassium Chloride, Nitrate. Sulfate _- ~~ C h l o r i n e , Wet . .. . -C h l o r i n e Water . ~ .R . _ _ _ -.---..~- __.__ ~~ ~~~ _-....- . R. R- ~ ~_~ _ _ . . . _ _ __._..___ R R c Calci ~. um -. ~.. H y p _o c_ h l~ o r i_ t e_ _ _ _ _ _ _ _ _ _ _ _ Chlorine. D r y c -~. ~________ ~ surface filler will be a-t t a c k e d . Sealing t h e surface may prolong t h e life. - ~ - ....-.- ~~_ ~ . -. ~ removed or washed of1 the ~ ~ ~ mediately B - May c o n t a i n t r a c e s c c of hydrofluoric acid c or acid fluorides. --..---. c c c_ Silica filler may be _ __ . _ _ _ . R R attacked. See "A". _._.____- -- c ~ ..- ~ -- _ R~ R ~ R R - ~ . _ ~ _ _ __..____ _ _ ~ _ _ _ _ _ ~ __._ ~ NR R ~ . _.-~ __._ .~ __.___... - ~ ~ -- A ~~~ Benzene NR N't.'L%A2d~be!5"" ~ ~ _ .__.__ . - .___.__ ~- R Benzene ~ S ~ u_ l f o ~n i c~ A c~ i d~, 10% - - _ .- -_._____R R Nitric Acid, 5% t o 10% Benzoic A c i d R R Oils. Vegetable c May be s e r v i c e a b l e i t t h e c o i l l a m i n a n t is im- Conditional -'---: - ~ Silica _ _~_ . ._~ Ethyl Ketone _ _ _ - ~ ~ -_ - -_ ~ -_ _ _ . R_ R ~ _ ~ ~ Milk ~ ,e; ._.__._ ~. Methyl .~ ~ ~ ~ _ ~ ~ ~ _ - _ _ _~_______ _______ _Methyl~A l c o h o l ~ R R _ _ _ R~ R_ Maleic Acid ~ _ ~ _ -__._.__ _____ - ~~ B a r l u m Chloride. Sullate C- _______ ~ m Sullate R R -Alurn ...-. or A l u m i.n u_ ~ . _ _ ~_______ A m m o n i u m C h l o r i d e , nitrate sulfate. 50% R R - _ _ - . _._._ .-. __._._ -..R R~ A m m o n i u m H y d r o x i d e , 10% _ . . .~ _._ ~- .. _ __ -~_~______ A mm o_n i u m H y d r o x i d 30%. _ _~ . _R _ _ ~e. _ ~C_ Aniline C ..--NR _ ~ _..___._.._ _-. ______~. A q~~~_~ u a Regia __...._-._ ~ ~ _______ _ NR _NR ~ NR - Not Recommended ~ ~ R R C NR ~ ~ ~ _ _ ~____ __~ R Cuppal Chloride, Nitrate, Sullate .-. - ~ . R S o d i u m Hypochlorite. 16% ~___ _ -._-._.__ --_ ~ - _ _ ~ -Ethyl A l c o h o l ~ ~ ~ _ __-_ _ _~N R -Ethylene D i c h l o r i d e . __ _ _ _ _ _ ______ a Ether .. . _________ ~~ Sugar, Salt Solution Sulfuric Acid. t o 80% --Sulfuric Acid. above 80% ~ ~ _ _ __ R Ethylene ~ ~ G l y_c o l ~ Fatty Acids~ ~ . -.~ ~ ~~_ _.-~ R R R Fluosilicic Acid. 30%____-_______ A . ~. __.. ~ _ _ A ~ Formic _ _Acid. _ _ .90% . ~ R . - ~~~ ~ t i y d r o c h i o r i c Acid. t o 20% - -._~ ~_ _ ~ ~ ~ ~ . ~H y d-r o c h_l o r i_c Acid. 20% t o 36% H y d r o l l u~. o r i c. Acid. t o 20% ...___. _ __.._ ~ ~-~~ C R R c R C R - ~___ H y d r o l l u o r i c Acid. 20% to7OUh -~ ~ __ ~ ~~ Jet Fuel -.~ Kerosene _ ~ __--- Toluene ~- Sulfonic A ~c_i d _ _ _ ~ _ _ _ _ Tomato Juice __-.-___.._________.__ ~~ _ _ _ _ _ _ _ _ ~ . ._____ R -- R __ R R R R NR R R C R ~ ~ . ..____ -____ ~~ _ _ ~ ~ _ _ _ ~ _ _ R_ _-- _ _ __________________ R R Turpentine ~-~ .__-. ~ Urea, t o 20% -~~ ~ - NR _ ~ _ _ _A~____ _ R _ -- _ _ _ _ R C _-~_________ R --____ .~ Lactic Acid, below 5% _______ ~ Trichloroethylene C NR _____-__ _ _ _ _ _ _ __ Trisodium R R ~ _ Phosphate _ ~ ~ _ _ _______.-__~ _ _ _ _A_ _A- ___._._ H y d r o g e n Peroxide ____-~~_ H y p o c h l o r o u s Acid. t o 5% .__..___._. . ~ __.___ ~~ ~ R _ _R Grdpe Juice .~ - ~. . . __.__~ H y d r o b r o m i c A c i d . 20% __~ Acid. b e l o w 10% ~ Toluene R R ___ Forrndldehyde. b e l o w 37% . ~ -. ~ _ ~~ _ ~ _ ..-. Sullurous ___ . c~ __ c ._..__ Ferric~ Chloride. Nitrate. Sullate ~ ___.._..___ _ ~ . _ _ R NR ___ R R -~ R R R R C NR Stannic C h l o r i d e __ Acid _Stearic __ c c E t h_ y l Acetate _ ~ Urine Vegetable O i l ~ ~~~ __~___ ~ ~ ~ ~ Water. Distilled -.___ ___ ~ ~ R _ _ _ - ~ RR_ R _ _.__ ~~-~ R Water and Sewage .... C - - R R --~~ .___.__..._ Vinegar _ _ ~~ _ _ Water, Fresh ~~~ R - ~ _ ~R _ R_ _ R _ _ _ _ _ ~ . _ _ _._.___..._ xylene -~-___ - _._._. __. Zinc C h l o r i d-e , Nitrate. Sulfate . .-.. ~ ~ NR -R _~--.~ R R ._______~ ~ ~ ~ KEY: m Resistant to 160'F (71'C) = The highest temperature tested, may and/or could be revised basis of further test. Resistant to 90°F (32OC) C Not Resistant * * Resistant to 70'F (21'C) Carbon filled 1 376 Corrosion Resistant Materials Handbook TABLE 3.3: EPOXY MORTAR AND FLOOR TOPPINGS-PENNWALT Calcium hypochlorite. . . Calcium nitrate, saturated Calcium sulfate. ............ ............. .................. .................. Carbon disulfide . . . . . . . . . . . . . . . Carbon monoxide . . . . . . . . . . . Carbon tetrachloride . . . . . . . . . . . . . Carbon dioxide. Caustic (see Sodium hydroxide) . . . . Chlorinated lime. . . . . . . . . . . . . . . . ... . . . . . . . . . . . . . .. ........ Chlorine water . . . . . . . . . . . . . . . . . Chloroacetic acid 100% . . . . . . . . Chloracetic acid 10% . . . . . . . . . . Chloronaphthalene . . . . . . . . . . . . . . Chloronitrobenzene . . . . . . . . . Chromic acid 5 % . . . . . . . . . . . . . . Ferric chloride, below 50% Furfural. ........................... ...................... Furfuryl alcohol Chlorine (wet) 500 ppm Gallic acid Coolant brines . . . . . . Copper acetate, saturated .. Household ammonia (see ammonium hydroxide). Crude oil . . . . Cyclohexane. . ................. .................. Cyclohexanone . . . . . . . . . . . . . . . . . . Dichloroethylene. . . . . . . . . . . . . . . Diesel fuel . . . . . . . . . . . . . . . .. Dimethyla(1inoethanoI . Dimethyl formamide Diphenyl or diphenyl oxide Ether Ethyl alcohol .................. . . . . . . . . . . . . . . . . . . Ethylamine, 40% aq sol.. Ethyl chloride. ............. .................. ................. Ethylene glycol. . . . . . . . . . . . . . . . . . . . Fatty acids . . . . . . . . . . . . . . . . . . . . . . Ethylene dichloride Glycolic acid Hydrochloric acid, any. . . . . Hydrochloric acid, below 10% Hydrochloric acid ........... ........... 10-32%. . . . . . . . . . . . . . . . ................. ............... Hydrofluoric acid 20.70%. . . . . . . . . . . . . . Hydrogen peroxide 50% . . . . . . . . . . . . . . Hydrogen sulfide. . . . . . . . . . . . . . . . . . . Hydroquinone . . . . . . . . . . . . . . . . . . . . . . Hydrosilicofluoric acid. . . . . . . . . . . . . . . . . Hypochlorous acid. . . . . . . . . . . . . . . . . . . . . Hydrofluoboric acid Hydrofluoric acid 10.20% Iron sulfate, saturated . . . . . . . . . . . . . . . . Jetfuel . . . . . . . . . . . . . . . . . . . . . . . . . . . . Kerosene . . . . . . . . . . . . . . . . . . . . . . . . . . .. ..................... Lard . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Magnesium bisulfite. . . . . . . . . . . . . . . . . . . Lactic acid 85%. D in i tr o be n ze ne Ethyl acetate Glycerine. . . . . . . . . . . . . . . . . . . . . . . . . . Glycol. . . . . . . . . . . . . . . . . . . . . . . . . Glycol acetate. . . . . . . . . . . . . . . . . . . . . . . . . . . ............ . . . . . Gasoline .......................... ........................ ...................... Heptanoic acid, any. . . . . . . . . . . . . . . . . . . Hexachlorocyclopentadiene. . . . . . . . . . . . . . . . . . . . . . . . . Copper chloride, nitrate, sulfate . . . . . . Cottage cheese . . . . . . . . . . . . . . . . . Cottonseed oil . . . . . . . . . . . . . . . . . . . Cresols . . . . . . . . . . . . . . . . . . . . . . Diethylene glycol DiethylenetrLamine .............. ............... ............... Fluorine up t o approx. 50%. . . . . . . . . . . . . . . Fluosilicic acid 30%. . . . . . . . . . . . . . . . . . . Formaldehyde, below 37% . . . . . . . . . . . . . . . Formic acid 90%. . . . . . . . . . . . . . . . . . . . . . Fumaric acid . . . . . . . . . . . . . . . . . . . . . . . . Ferric chloride, anhydrous Ferric nitrate or sulfate. . . Chlorine (dry). . Chromicacid 5-10”o. . . . . . Citric acid 40’6 . . . . . . . . . . . (contlnuedl Magnesium chloride, saturated Magnesium sulfate, saturated ............ Maleic acid, below 40%. Maleic acid 40% Maleic anhydride ........... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . Mercuric chloride, saturated Mercury Methacrylic acid ... .... Cements, Mortars, and Asphalt TABLE 3.3: EPOXY MORTAR AND FLOOR TOPPINGS-PENNWALT Methyl a c e t a t e . . . . . . . . . . . . . . . . . . . . .................... Methyl amine 40%. . . . . . . . . . . . . . . . . . Methyl "Cellosolve". . . . . . . . . . . . . . . . . Methyl chloride. . . . . . . . . . . . . . . . . . . . Methy cyclohexanol. . . . . . . . . . . . . . . . . Methyl alcohol ................ ................ Methylene chloride . . . . . . . . . . . . . . . . . Milk . . . . . . . . . . . . . . . . . . . . . . . . . . . Mineral o i l . . . . . . . . . . . . . . . . . . . . . . . Miscible oil. . . . . . . . . . . . . . . . . . . . . . . Monochlorobenzene. . . . . . . . . . . . . . . . . Motor oil (see Crude o i l ) . . . . . . . . . . . . . . (continued) Po:assium chloride, nitrate or sulfate. . . . . . . . . Potassium cyanide, saturated . . . . . . . . . . . . . . Potassium ferricyanide, saturated . . . . . . . . . . . Potassium hydroxide 50%. . . . . . . . . . . . . . . . Potassium nitrate, saturated. . . . . . . . . . . . . . . Potassium permanganate, below 5% . . . . . . . . . Methyl ethyl ketone Potassium peroxide 5%. . . . . . . . . . . . . . . . . . Methyl naphthalene. Potassium persulfate, saturated . . . . . . . . . . . . Muriatic acid (see Hydrochloric acid) Naphthalene. ..... ..................... Nickel chlorate, nitrate or sulfate . . . . . . . . .................... Nitric acid 70%. . . . . . . . . . . . . . . . . . . . Nitric oxide gases . . . . . . . . . . . . . . . . . . N it r o be nze ne . . . . . . . . . . . . . . . . . . . . . Nitrosylsulfuric acid. . . . . . . . . . . . . . . . . Nitropropane . . . . . . . . . . . . . . . . . . . . . Oils (saponifiable) . . . . . . . . . . . . . . . . . . Oleic acid. . . . . . . . . . . . . . . . . . . . . . . . Oleum . . . . . . . . . . . . . . . . . . . . . . . . . . Nitric acid 5%. ...................... ......................... Oxalic acid. Oxygen ....... ........................ Perchloric acid . . . . . . . . . . . . . . . . . . . . Perchloroethylene . . . . . . . . . . . . . . . . . . Petargonic acid . . . . . . . . . . . . . . . . . . . . Petroleum . . . . . . . . . . . . . . . . . . . . . . . Phenol, below 5% . . . . . . . . . . . . . . . . . . Paradimethylaminobenzophenone Paraffin. Phosgene . . . . . . . . . . . . . . . . . . . . . . . . Phosphoric acid 85% ................ Phosphorous chlorides ............... ................. Picric acid 5%. . . . . . . . . . . . . . . . . . . . . Picric acid 50%. . . . . . . . . . . . . . . . . . . . Potassium bromide, saturated . . . . . . . . . . Potassium carbonate, saturated . . . . . . . . . Potassium chlorate, 50%. . . . . . . . . . . . . . Phthalic anhydride. Po?assiurnsulfate saruratsd . . . . . . . . . . . . . . . ..................... ......................... Potassium sulfide. Prussic acid Pyridine. . . . . . . . . . . . . . . . . . . . . . . . . . . . ..................... .................... Salicylic acid . . . . . . . . . . . . . . . . . . . . . . . . Salt, saturated. . . . . . . . . . . . . . . . . . . . . . . . Sodium acetate, saturated. . . . . . . . . . . . . . . . Sodium bichromate . . . . . . . . . . . . . . . . . . . . Quinoline sulfate. Saccharin solutions Sodium c h lor ide, carbonate, bicarbonate, phosphate, nitrate, sulfate or chlorate Sodium hydroxide 50% .... ................. ........ ............... Sodium peroxide 5% . . . . . . . . . . . . . . . . . . . Stannic chloride . . . . . . . . . . . . . . . . . . . . . . Steam . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Stearic acid, any . . . . . . . . . . . . . . . . . . . . . . Sugar, saturated . . . . . . . . . . . . . . . . . . . . . . Sulfur chloride . . . . . . . . . . . . . . . . . . . . . . . Sulfur dioxide. . . . . . . . . . . . . . . . . . . . . . . . Sodium hypochlorite, below 6% C12. Sodium hypochlorite 2 7%. Sulfuric acid 80% . . . . . . . . . . . . . . . . . . . . . Sulfuric acid 98% ..................... ............... Sulfurous acid, below 10% ................... ..................... ............................ Sulfur monochloride Sulfuryl chloride. Tannin Tar, tar oils . . . . . . . . . . . . . . . . . . . . . . . . . Tartaric acid, cold saturated . . . . . . . . . . . . . . ..................... Tetrachloromethane. . . . . . . . . . . . . . . . . . . . Tetrahydrofuran . . . . . . . . . . . . . . . . . . . . . . Toluene. . . . . . . . . . . . . . . . . . . . . . . . . . . . To Iuenesu If on ic acid . . . . . . . . . . . . . . . . . . . Tetrachloroethane 377 378 Corrosion Resistant Materials Handbook TABLE 3.3: EPOXY MORTAR AND FLOOR TOPPINGS-PENNWALT ........................ Trichloroacetic acid . . . . . . . . . . . . . . . . . Trichloroethylene . . . . . . . . . . . . . . . . . . Triethanolamine . . . . . . . . . . . . . . . . . . . Towngas ................ ...................... (continued) Urine . . . . . . . . . . . . . . . . . . . . . . . . . . . . Vegetable oil . . . . . . . . . . . . . . . . . . . . . . . Vinegar . . . . . . . . . . . . . . . . . . . . . . . . . . . Water, fresh . . . . . . . . . . . . . . . . . . . . . . . . Trisodium phosphate Water, dis;illed . . . . . . . . . . . . . . . . . . . . . Turpentine. Xylene . . . . . . . . . . . . . . . . . . . . . . . . . Urea 20%. . . . . . . . . . . . . . . . . . . . . . . . Zinc chlo: de 5096 . . . . . . . . . . . . . . . . . . Solutions Common to the Plating Industry Floor and Wall Service (Not for Immersion; Acidcopper . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . AcidZinc . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Aluminum bright dip +? 41 Phosphoric acid heat Bath alumabrite Concentrate # 41 ......................................... D.S.. . . . . . . . . . . . . . . . . . . . . . . . . Aluminum Pickle - Northwest AI, Alume Aluminum Pickling, Enthone Nitric acid with Enthone actane ii 70 ............................ Alkaline t i n . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Anodizing Electrolyte - 15 - 1806 sulfuric acid . . . . . . . . . . . . . . . . . . . . . . . . . Brass bright dip - 50% nitric, 50% sulfuric . . . . . . . . . . . . . . . . . . . . . . . . . . . . Cadmium bright d i p . with nitric acid with Kenvert conversion additive. ........ ......................................... ................................ Chrome plating bath - approx. 4502 CR t o gallon 4502 sulfuric . . . . . . . . . . . . . . Chromium . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Copper F luoroborate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Copper Lume, Copper cyanide. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Copper plating bath - cyanide with #625 Allied Research additive . . . . . . . . . . . . Copper plating bath -straight cyanide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Enthone stripper. SI8 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Iron Chloride . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Cadmium plating bath Calolume L. Cadmium cyanide bath Rochelle salt, Copper cyanide .................................... Udylite bright nickel # 425. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............................................... ....................................... Delchem946 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Enthone Stripper. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Watt's nickel. Zincalume, Cyanide zinc. ....................................... ............................................. Nuvite Take-off Stripper. A-29-S Stripper. Note: Top service temperature for continuous service is 14OoF (6OOC). Exposures to 16OoF (71OC) acceptable for not more than 20 minutes. r R - recommended t o 71OC. Contact Sternson Limited f o r h i g h e r t e m p e r a t u r e recommendations. C - u s e Talychem C 32 30% 50% - * NR D highest temperature t e s t e d . further tests. May be r e v i s e d w i t h s p e c i f i c chemical t e s t e d . may d i s c o l o u r s u r f a c e , w i l l n o t l o s e p r o p e r t i e s . c o n t a c t S t e r n s o n Limited f o r recommendation. n o t recommended. 380 Corrosion Resistant Materials Handbook TAB LE 3.4: EPOXY SUR FACl NG CEMENTS-STE R NSON Iconttnued) Calcium s u l p h a t e Carbon Dioxide Carbon d i s u l p h i d e Carbon monoxjde Carbon T e t r a c h l o r i d e C a u s t i c ( S e e Sodiun, Hydroxide) C h 1o r i n a t e d 1i m e Chlorine (Dry) C h l o r i n e (Wet) 5000 ppm C h l o r i n e Water C h l o r o a c e t i c a c i d , 100% ('hloroacetic. 10% Chloroform Chloronaphthalin C h l o r o n i t r o b e n z ene Chronic a c i d , below 5% Chrorric a c i d , 5% Chromic a c i d , 5 t o 10% C i t r i c Acid, below 5% C i t r i c Acid, 5-402 Coolant b r i n e s Copper a c e t a t e , s a t u r a t e d Copper c h l o r i d e , n i t r a t e o r sulphate C o t t a g e Cheese Cottonseed O i l Cresols Crude O i l Cyclohexane Cyclohexanone D i c h l o r o e t hylene Diegel Fuel D i e t h y l e n e Glycol Diethylenetriamine Dimet hylaminoethanol Dimethyl Formamide Dinitro-benzene Diphenyl o r d i p h e n y l o x i d e Ether Ethyl Acetate E t h y l Alcohol Ethylamine, 40% aqueous s o l . Ethyl chloride Ethylene d i c h l o r i d e Ethylene g l y c o l Fatty acids F e r r i c c h l o r i d e , below 50% F e r r i c c h l o r i d e , anhydrous Ferric n i t r a t e o r sulphate F l u o r i n e up t o approx. 50% RD R 32 R 32 R R R R NR 32 R 32 32 R R 32 R R 32 R R R R NR R * R m R R R R 32 R R R * R 32 NR NR RD 32 R R R NR F l u o s i l i c i c Acid, 30% Formaldehyde, below 37% Formic a c i d , 90% Fumaric a c i d , any Furfural Furfuryl alcohol Gallic acid Gasoline Glycerine Glycol Glycol a c e t a t e G l y c o l i c Acid Heptanoic Acid, any Hex ac h 1o r oc yc 1opent a d i ene Household ammonia ( S e e Ammonium hydroxide) Hydrobromic a c i d , any Hydrochloric a c i d , below 10% Hydrochloric a c i d , 1 0 t o 32% Hydrofluoboric a c i d H y d r o f l u o r i c a c i d , below 10% H y d r o f l u o r i c a c i d , 10 t o 20% H y d r o f l u o r i c a c i d , 20 t o 70% Hydrogen p e r o x i d e , 50% Hydrogen sulphid'e Hydroquinone H y d r o s i l i co f l u o r i c a c i d Hypochlorous a c i d Iron sulphate, saturated J e t Fuel Kerosene L a c t i c Acid, below 20% L a c t i c Acid, 20 t o 85% Lard Lead A c e t a t e , 25% Lead C h l o r i d e , s a t u r a t e d Magnesium b i s u l p h i t e Magnesium c h l o r i d e , s a t u r a t e d Magnesium s u l p h a t e , s a t u r a t e d Maleic a c i d , below 40% Maleic a c i d , 40% Maleic a n h y d r i d e Mercuric c h l o r i d e , s a t u r a t e d Mercury Methanol Methyl a c e t a t e Methyl a l c o h o l Methyl amine, 40% Methyl "Cellosolve" Methyl c h l o r i d e RC R NF 32 R 32 R * R 32 32 NR * NR RD R RD RC RC RC 32C RD R R 32C R R R R RD RD R RD RD R RD RD RD 32D R NR R 4 32 R R R NR (continued) Cements, Mortars, and Asphalt TABLE 3.4: EPOXY SURFACING CEMENTS-STERNSON Methylcyclohexanol Methyl e t h y l k e t o n e Methyl n a p h t h a l e n e Methylene c h l o r i d e Milk Milk o f l i m e Mineral O i l Miscible O i l Molybdic Acid, s a t u r a t e d Monochlorobenzene Motor O i l (see Crude O i l ) M u r i a t i c a c i d (see Hydrochloric Acid) Naphthalin Nickel C h l o r i d e , n i t r a t e o r sulphate N i t r i c a c i d , below 2 1/2% N i t r i c a c i d , 2 1/2 t o 5% N i t r i c a c i d , 70% ( c o n e . ) N i t r i c oxide gases Nitrobenzene Nitrosylsulphuric, acid N i t r opropzne O i l s ( saponifiable ) O l e i c a c i d , any Oleum Oxalic a c i d , any Oxygen Paradimethyl-amino-benzophenone Paraffin P e r c h l o r i c a c i d , any Perchloroethylene P e l a r g o n i c a c i d , any Petroleum Phenol, below 5% Phosgene Phosphoric a c i d , below 2% Phosphoric a c i d , 2 t o 5% Phosphoric a c i d , 5 t o 50% Phosphoric a c i d , 50 t o 85% Phosphorus c h l o r i d e s P h t h a l i c anhydride P i c r i c a c i d , 50% P i c r i c a c i d , 5% Potassium bromide, s a t u r a t e d Potassium c a r b o n a t e , s a t u r a t e d Potassium c h l o r a t e , 50% Potassium c h l o r i d e , n i t r a t e o r sulphate Potassium cyanide , s a t u r a t e d Potassium f e r r i c y a n i d e , s a t u r a t e d R * R NR R R R R RD 32 R RD R R NR m * NR 32 R R NR R K 32 R * R R R 21* 32 RD RC RC RC R R * 32 R R 32 R R R 381 (continued) Potassium hydroxide, below 25% R Potassium hydroxide, 25 t o 50% R Potassium n i t r a t e , s a t u r a t e d R Potassium permanganate, below 5% RD Potassium p e r o x i d e , 5% R Potassium p e r s u l p h a t e , s a t u r a t e d R Potassium s u l p h a t e , s a t u r a t e d R Pot as s i um s u l p h i de R R Prussic acid Pyridine 32 Quinoline s u l p h a t e R Red O i l * Rochelle S a l t , 25% R Saccharin s o l u t i o n s R Salicylic acid 32 Salt, saturated solution R Sodium a c e t a t e , s a t u r a t e d R Sodium bichromate *D Sodium c h l o r i d e , c a r b o n a t e , b i c a r b o n a t e , phosphate, n i t r a t e , s u l p h a t e , sulphide o r chlorate R Sodium hydroxide, below 25% R Sodium hydroxide, 25 t o 50%. R Sodium H y p o c h l o r i t e , 50 ppm C12 R Sodium H y p o c h l o r i t e , 5000 ppm C12 R Sodium H y p o c h l o r i t e , below 6% C12 R Sodium H y p o c h l o r i t e , 27% 32D Sodium H y p o c h l o r i t e , 16% 32D Sodium p e r o x i d e , 5% 32 Stannic chloride 32 Steam R S t e a r i c a c i d , any R Sugar, s a t u r a t e d s o l u t i o n R Sulphur c h l o r i d e NR Sulphur d i o x i d e R S u l p h u r i c a c i d , below 10% R S u l p h u r i c a c i d , 10 t o 20% R S u l p h u r i c a c i d , 20 t o 40% RD S u l p h u r i c a c i d , 40 t o 50% RD S u l p h u r i c a c i d , 50 t o 60% RD S u l p h u r i c a c i d , 60 t o 70% RD Sulphurous a c i d , below 1 0 % RD Sulphur monochloride 32 Sulfuryl chloride 32 Tannin R Tar, tar o i l s 32 Tartaric acid, cold saturated R Tetrachloroethane NR Tetrachloromethane NR Tet rahy d r o f u r an 32 * (continued) nuosllicic acid Acetic acid glacial Alum Alurmnum Sulfate Ammomum Hydroxide - Ammal ~ _ _olls _ _ _ _ Bakely Roducls .- _ ~ _ Beer Benzoic acid _ Bonc _ acid _ _ _ ~ Butter Butync acid _ ______ Calcium Chlonde ~ p ~~~ _ _ ~ Formaldehyde Formc acid Horse R a b h _ _ ~~ Jams % Jellies Calcium Hydronde p_ ______ - ____- Cheese all chloGGWatZp ~ ~ _ Chloroacetic acid 10% . -~ __.____Cider .~_ _ _ ____ acid Maleic acid _ _Cilnc_____ ___ Fmts . Citrus Coffee _______~ _ _ _ _ _ Corn Syrup Methyl Alcohol .~ _ _ _ _ ~ Yolk _ ~ ~ _ _ _ - Egg - _______Ethyl Alcohol . .__.__ __ Ethylene Glycol Mmeral 011 _ _ p _ _ c n s o l u m Hypochlonte up to 3% _ ~ _ - _ _ _ _ ___-_ _ _ _ _ _ _ S o l u m Nitrate ~ S o l u m Sulfite ~ ~S o l u m mosulfate ._________ Soft Dnnks _ _ _ _ __ Soft Dnnk Concentrates soups ~_Soya _ _ _ 011 __~~_ Steanc acid - _ ~ _ _ ~ _ _ _ Sugar ~ _ _ - - - Sulfunc acid up_lo 50% ~ - sulfunc acid 80% __-___ _ _ _ Sulfunc acid 93% ___ . _ _ _ ~ ~~ S~P----T a M i C acid ___ Tartanc acid _Tea _ -~ ___ ________ _____ Tnchloroethylene _ ____ -~~ ~ ~ __ ~ _ _ _ ~ _S_o_l u_m_Sulfate __ ~ _______ ~ ~ Mmeral Spints id - Munatic a c ~ _ _ Molasses Mustard _ ~ _ _ _ _ Nitnc acid Oleic acid 1 1 Olive 0 TxzCacid Pectin Phenol _ _________ -_ Phosphoric Acid ~ _ _ _ Plckels -~~ PIcnc acid ~ _ _ _ _ _ _ _ _ _ Potassium _ ~ _ Bicarbonate _ _ _ _ _ ~ Potassium Carbonate _ _ ~-_ _ Potassium Hydronde up lo 30% ~ _ ___ _ ______ Potavlum Hydronde 33% and over _ Salad Oils ~ Sahcylic acid Shortemng _______ ~Silver Nitrate ~ _ _ _ Smokehouse _ _ _ _ _ Resicues __.-- _~ Sodium Bicarbonate S o l u m Carbonate %&um Chlonde -___ __ ___ S o l u m Hydroxide up to 20% ~ _ Sodlum Hydronde 30%and over p~ ._______- -~ c n C H C H ~ ~ ~ Tnsolum Phosphate -~~_~~ ~_ Tung Oil_ ~~ urea _ _ p _ ~ UMe _______-Vinegar ~ _ _ Yeast - ~ ~ p _ ~ _ _ _ Solution 14 Days 90 Days 355 Days Appearance Change Concentrated Ammonium Hydroxide 10% Ammonium Hydroxide 10% Sulphuric Acid Concentrated Nitric Acid 10% Nitric Acid Concentrated Hydrochloric Acid 10% Hydrochloric Acid 2 5 % Aqueous Calcium Chloride Distilled Water Brake Fluid Gasoline Toluene Methyl Alcohol Motor Oil None None None None None None None None None 0.1% None <0.1% 0.5% 0.4% - 1.1% 0.5% 0.2% 1.8% 0.6% 0.7% 1.1% 0.4% 0.5% 0.6% 0.4% 1.1% 0.5% 0.7% Very Slightly Darker Very Slightly Darker Very Slightly Darker Slightly Yellow None Slightly Darker None Very Slightly Darker None None None Slightly Darker None Very Slightly Darker 3% None - 0.2% <0.1?6 0.4% 0.5% 0.5% <0.1% 0.396 0.2% 0.7% (A 5 k t; z 0 y I z " 5. + a 8 gcnv Y c tc ; a 'G 2 m 3 285 yo c z m'"Q -2'" L- ;c Q.c m a c n m 5 2 a z k5 L%I 2ab -Qgc 2.z.g c = E-'" 5 osp E E o w E S ' " . 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O - 9 ) . .*4.4 . y * .u v . . w y . y . d . . , + w . ' u . v . . . v . . . a . . . U . . .4. . V d sz; - 4 n w l . 4 u . P . . 2 2,u3 0 0 , 3 : 2 * 2 (0 z . . L I . . Y - I . - I " U Y m C o - ~ V Z I Z N U Z > ~ D . X ~ ( P M P U C P V C ~ U C J O ~ X + ~ O . A ~ U u * C o v v P u r ( d ~ c ~ f J c v 8 m e ao)o)or( ~ ~ w 4 m O m' D I ( L . V ~ ~ a c r ~ v n . ~ m e* am t * w ~p ~ ( d . C o d . + : : : 4 : 2 : : 7 .:U: :I . I 0 . I u v - 9 . . u a . a u a.2m:m.~mu-~ ; ~ m . c V . WI 0 m r ( w B X v ' u v 4 ' D ~ E w Y d C O & v a d u d m r ( r ( m i d =g2 zz:= m u o 4 4s 1 J D" i . m u . v m - m w z v c L "g"c E,.-? m o ' " s ,IIo%F m,:s g a m m LEG.!? FEE+ 8 u m a 2 ,CEO0 r( m 5 'D . . . . . . . . . . .. .. .. .. .. .. .. .. .. ..o4 v. .o . . . . . . . .... ,* ..(...... . . ... Y m m. 'ma_=a $E-2 s .= : 5a 0 gz K = 5 3E 2 a 0 . m o m n 3v-g 2 geon gYYs ~ Z$=,.C 2 E 3 5 - r0 G .-m .. 2 w 2 4 m W U F d V w I >. C W w F I " E o vE 0 U u a W U C Y X z o w F -u Y E U a W x %..,;I $E! z g ; @; 3 - z I C W J g w a 8 c t-x 8 q n z Q E x x x-x x x x x x x x x x x x x x x x x x x x e x x x x x x x x x x x x X x x x x x x x x x X x x x x x x X x x e x x x x x x B3 4- .-C C -8 ; 0 m 3 U V d 0 x W r( 4 W 01 u > w v . 4 vw c w V v c I " o E w u Y w x a : uo z V X w x W E U a W Ez 5 ;; p v) E (L W 0 Z rn c ( x 44 2 : u I-: 2 " 3 '? Q n z a W I- x X x X x x X x x x x x x x x X x x x x x x x x x x x x x x x x x x x x x x x x * Cements, Mortars, and Asphalt 387 TABLE 3.9: URETHANE ASPHALT MEMBRANE-PENNWALT PENNGUARD Adhesive/Membrane is a twocomponent urethane asphalt composition used in the installation of the PENNGUARD Block Lining System. As an adhesive, it serves t o bond the PENNGUARD Block to a prepared substrate, and as a membrane, it serves as a moisture and chemical-resistant barrier. TUFCHEM I 1 Membrane i s an improved, two component, urethane asphalt based membrane system, that can be used, within i t s limitations, to protect concrete and steel surfaces from chemical attack and abrasion. CHFlUlTCAL RESISTAWE OF URFTHANE ASPYALT MEXBFA!!S PENNCSWIB Adhesivefidrane TUFCE3B I1 Membrane Xey: R NR C - Resistant N o t Resistant - Conditional - A c e t i c Acid 25% chromic Acid 35% Citric Acid 35% Hydrochloric Acid 35% N i t r i c Acid 35% O l e i c Acid Phosphoric Acid 35% S u l f u r i c Acid 35% Acetone Benzene Carbon Tetrachloride Ethyl A c e t a t e Ethylene Glycol bkthyl Chloride Methanol Prapanol Toluene Xylene Water R NR R NR NR NR R NR NR NR NR Aluminum Hydroxide Calcium Hydroxide, sat. sodium Hydroxide 35% Aluminum Chloride 35% Calcium Chloride 35% Calcium Sulfate, sat. Magnesium Chloride 35% Potassium Chr-te 35% sodium CarbOMtE 35% Sodium Chloride, sat. Sodium Phosphate, sat. Sodium Sulfate, sat. B r ~ ~ ~ n i Nitrate urn m R m R R NR NR R Chemical r e s i s t a n c e was determined by imnersion in a solution of the listed chemicals for one year at 132% (55.5oC). m R R C R R R R R R R R R 388 Corrosion Resistant Materials Handbook TABLE 3.10: POLYESTER AND EPOXY FLOORING COMPOUNDS-ATLAS The REZKLAD epoxy-based system consists of a Concrete Primer and Flooring Compound, plus an Expansion Joint Compound and Surface Sealer available for use where necessary. The CLADKOTE Flooring Compound i s a modified polyester, resin-based monolithic overlay for concrete. The composite of resins and siliceous reinforcing material cures t o a tough, chemical resistant topping. CLADKOTE C utilizes a 100% carbon filler specifically designed for service in hydrofluoric acid and fluoride salts. CHEMICAL RESISTANCE OF Rezklad*"FLOORING MATERIALS .Clrdkob C Rcomnnnded KHV C 80°F. 0 RECOMMENDED n 0 Up to the temperature limilation of the material. In cafes where chemical boils below this limitation. resistance is intended to be shown up to the boiling point. CONDITIONAL. may b. suitable but conSult A t l a s b e f o r e using. I!&MMENDED Cements, Mortars, and Asphalt TABLE 3.11: VARIOUS CEMENTS-ATLAS Corrosion Resistance of Various Cements 389 390 Corrosion Resistant Materials Handbook TABLE 3.11: VARIOUS CEMENTS-ATLAS (continued) H = Recommended. fl= Conditional, may be suitable. 0= Not recommended. €3 = Carbon-filled variation must be used. = Possible failure through crystalline growth Sodium Hypochlorite, up to 3% Sodium Hypochlorite, 15% and over I H = Up to the temperature limitation of the cement. In cases where chemical boils below this limitation, resistance is intended t o be shown up to the boiling point. Cements, Mortars, and Asphalt 391 TABLE 3.12: VARIOUS MORTARS-KOCH ENGINEERING CORROSION-PROOF MORTARS PERMANITE" Resin Mortar: RESIBOND HF Mortar: An all-purpose furan resin mortar. Satisfactory for non-oxidizing acids, alkalies, and organic solvents. Available in quick setting or slow setting type to suit the installation. A selected polyester resin mortar with excellent adhesion to ceramics and metals. Satisfactory for dilute acids including those that contain fluorides, mild alkalies and many organic solvents. AClDSlL Mortar: CORESITE Mortar: An improved sodium silicate type mortar with greater water resistance and higher physical strength. Resistant to crystallization cracking, and vitrification to 1900°F. An especially compounded hydraulic type mortar. Resistant to chemical attack by acids, alkalies, salt solutions, and organic solvents. Not recommended for handling strong acids or concentrated alkalies. AClDSll K Mortar: EPllOC Mortar: An improved potassium silicate type mortar with greater water resistance and higher physical strength. Resistant to crystallization cracking and vitrification to 1900°F. A selected epoxy mortar with excellent adhesion to metal surfaces. Resistant to many nonoxidizing acids, alkalies, salts, and organic solvents. AClDSll HK Mortar: KNIGHTBOND C e m e n t : An alumina calcine mortar with great water resistance a n d bearing strength. Resistant to crystallization cracking, and vitrification to 2700°F. A plasticized sulfur cement. Satisfactory for all acids and many solvents. Set immediately upon cooling. Available with either silica or carbon filler. RESIBOND Mortar: KABO: A selected polyester resin mortar with excellent adhesion to ceramics and metals. Satisfactory for dilute acids, alkalies, and oxidizing agents. Recommended for chlorine, chrome chlorine, dioxide and peroxide. An improved phenolic resin mortar. Resistant to non-oxidizing acids, weak alkalies, and most organic solvents. Supplied with either silica or carbon filler. CH EMlCA L RESISTANCE ACID PH 0 1 2 NEUTRAL 3 4 5 6 1 ALKALI 8 9 1(1 11 12 13 14 CCRMANITE RESIN MORTAR ACIDSIL MORTAR ~ ~ KABO RESIN MORTAR (continued) Cements, Mortars, and Asphalt 393 TABLE 3.12: VARIOUS MORTARS-KOCH ENGINEERING (contlnud) Chemical Resistance of AClDSlL and AClDSlL HK Mortars (Meets ASTM specification 267 f o r chemical-resistant mortar) Acetaldehyde . . . . . . . . . . . . R R Acetic Acid . . . . . . . . . . . . . . . Acetic Anhydride . . . . . . . . . R .............. R Acetone R Alcohol, Amyl . . . . . . . . . . . . . . . . . R Alcohol, Butyl . . . . . . . . . . . . . . . . R . . . . . . . . Alcohol, Ethyl Alcohol. Iso-Propyl . . . . . R Alcohol. Methyl . . . . . . . . . . . . . . . R R Allyl Chloride . . . . . . . . . . . . . . . . . Aluminum Bromide .............. R R Aluminum Chloride ............... Aluminum Fluoride ............... NR R Alulnlnum Sulfate .................. Amnionla . . . . . . . . . . . . . . . . . . . . . . . NR Ammonium Bicarbonate ....... R R Ammonium Bromide ............. R Ammonium Carbonate ......... Ammonium Chloride ............. R Ammonium Fluoride .............. N R Ammonium N i t r a t e ................ R Ammonium Phosphate .......... R Ammonium Sulphate .............. R Amy1 Acetate ...................... R Amyl Chloride ........................ R Aniline ............................... ** Antimony Oxychloride . . . . . . . . R Antimony Trichloride ........... R Aqua Regia ............................ R Arsenic Acid ............................ R Barium Carbonate .................. R Barium Chloride ...................... R Barium Hydroxide .................. ** Benzaldehyde ............................ R Benzene ..................................... R ........................... Benzoic Acid R Bismuth Carbonate ................ R Boric Acid ................................ R Bromine .................................... R Butyl Acetate ........................ R Butyric Acid ............................ R Calcium Chlorate .................... R Calcium Chloride .................... R Calcium Hydroxide ................ N R Calcium H)-pochlorite ............ N R Calcium N i t r a t e ...................... R Calcium Sulfate ...._............ R Carbon Bisulphide ............. R Carbon Tetrachloride ............ R Carbonic Acid .......................... R Chloracetic Acid ........... R Chloral ............................. R Chlorine ........................... R ............. R Chlorine Dioxide ._.... Chlorobenzene .......................... R Chloroform ................................ R Chlorosulfonic Acid ................ R Chromic Acid .......................... R Chromic Chloride . .............. R Citric Acid ..._........._ ..__.............. R Copper Acetate ........................ R Copper Chloride ...................... R Copper Cyanide ...................... R Copper N i t r a t e _...___ ................. R Copper Sulfate ..............:_._ ...... R Creosote _.....__._ ....__._...... ..... ..... R R Cresylic Acid ............................ Dibutyl P h t h a l a t e .................. R E t h e r .......................................... R Ethyl Acetate ........................ R ~ __ R - Resistant. ~ Ethyl Bromide R Ethyl Chloride R Ethylene Chlorhgdrin . . . R Ethylene Dichloride . . . . . R Ethylene Glycol . . . . . . . . . R Ethylene Oxide . . . . . . . . . . . . . . . R F a t t y Acids . . . . . . . . . . . R Ferric Chloride . . . . . . . . . R Ferric Nitrate . . . . . . . . . . . . . . . R ......... R Ferric Sulfate Ferrous Chloride . . . . . . . . . . . R Ferrous Sulfate . . . . . . . . . . R Fluorine . . . . . . . . . . . . NR .* Fluosilicic Acid . . . . . . . . . . . . . . Formaldehyde . . . . . . . . . . . . . . . R Formic Acid . . . . . . . . . . . . . . . . . R Furfural . . . . . . . . . . . . . . . . . . . . . R Gasoline . . . . . . . . . . . . . . . . . . R Glycerine . . . . . . . . . . . . . . . . R Hydriodic Acid . . . . . . . . . . . . . R Hydrobromic . . . . . . . . . . . . . . . . . R Hydrochloric Acid . . . . . . . . . . . R Hydrocyanic Acid . . . . . . . . . R Hydrofluoric Acld . . . . . . . . . N R Hydrogen Peroxide . . . . . . . . R Hvdrogen Sulphide R . . . . Hypochlorous Acid . . . . . R Iodine .............................. R Lactic Acid ...................... R Lead Acetate . . . . . . . . . . . . . . . . . . R Lead Chloride .......................... R Lead Nitrate .......................... R Linseed 011 .............................. R Magnesium Carbonate ........... R Magnesium Chloride ............. R ........ Magnesium Hydroxide ** Magnesium Nitrate ................ R Magnesium Sulfate ............... R Maleic Acid ........................... R Manganese Chloride .............. R Manganese Sulfate ................ R Mercuric Chloride .................... R Mercuric Cyanide .................... R Mercurous Nitrate .................. R Mercury ................................... R Methyl Acetate ........................ R Methyl Chloride ...................... R Methyl Ethyl Ketone ............ R Methylene Chloride ................ R Mineral Oil .............................. R Mixed Acids ............................ R Naphtha ...................................... R Naphthalene ............................ R Naphthenic Acid .................... R Nickel Chloride ........................ R Nickel N i t r a t e ........................ R Nickel Sulfate ........................ R Nitric Acid ................................ R Nitrobenzene ...................... R Nitroglycerine .......................... R Nitrophenol .............................. R Nitrous Acid ............................ R Nitrosyl Chloride .......__........._. R Oleic Acid .................................. R Oxalic Acid ..............._..... ......... R P a r a m n ...................................... R Perchloric Acid ........................ R Phenol ............................... ............ R Phosgene .................................. ** Phosphoric Acid ( t o 70% ) .... R NR - Not Resistant Phosphoric Acid (above TO',: ) Phosphorous Bromide Phosphorous Chloride . . Phosphol,ous Oxlchloride Phthalic Anhydride .. Picric Acid Potassium Bicarbonate Potassium Bromide Potassium Carbonate Potassium Chloi.ate Potassium Chloride . . . . . potassium Cyanide poiassiuni Fei rocyanide Potassium Dichromate Potassium Fluoride Potassium Hydroxide . . . Potassium Nitrate . . . . potassiuni Oxalate ... Potassium Permanganate . . . . . . . Potassium Peroxide Potassiuni Sulfate . . . . . . . . Potassium Sulphide .. Propylene Dichloride Pyridine . . . . . . . Salicylic Acid . . . . . . . . . . Silver Nitrate . . . . . . . . . . Sodium Acetate . . . . . . . . . . Sodium Bicarbonate . . . . . . . Sodium Bisulfate . . . . . . . . . . Sodium Bisulphite . . . . . . . . . . . Sodium Bromide . . . . . . . . . . . Sodium Carbonate ............... Sodium Chlorate . . . . . . . . . . . . . . Sodium Chloride . . . . . . . . . . . . Sodium Chromate . . . . . . . . . . . . . . Sodium Cyanide . . . . . . . . . . . . . . Sodium Dichromate .............. Sodium Ferricyanide .............. Sodiuni Fluoride .................... Sodium Hydroxide ............... Sodium Hypochlorite ............ Sodium Nitrate ........................ Sodium Nitrite ...................... Sodium Oxalate ................... Sodium Peroxide .................. Sodium Sulfate ....................... Sodium Sulphide ................ Sodium Sulphite ................... Sodium Thiosulfate . . . . . . . . . . . Steam ................................... Sulphur .................................. Sulphur Chloride ................... Sulphur Dioxide .................... Sulphur Trioxide .................... Sulphuric Acid ...................... Oleum ........................................ Sulphurous Acid .................... Tannic Acid ............................ Tartaric Acid .......................... Tin Chloride ............................ Tin Sulfate ................................ Toluene ...................................... Trichloracetic Acid ................ Trichloroethylene .................... Trisodium Phosphate ............ Vegetable Oils ........................ W a t e r ........................................ Xylene ........................................ Zinc Chloride ............................ Zinc Sulfate ............................. "Consult M.A. Knight for specific recommendation. ** R R R R R R R NR R R NR R R NR NR R R R NR R NR R ** R R R R R R R NR R R R NR R R NR NR NR R R R NR R NR ** R * R R R R R R R R R R p R R R NR R R R R R (continued ) 394 Corrosion Resistant Materials Handbook TAB LE 3.12: V A R IO US MOR T A RS-KOCH ENGINEER I N G (continuedJ Chemical Resistance of RESIBOND Mortar (Meets ASTM specification 267 for chemical-resistant mortar) E - Excellenr resisrance, all concentrations and temperarures to 250°F G - Good resisrance. most concentrations and remperatures to 165°F F - Fdir resistance. ddute concentrations and temperatures to 9 0 ° F NR - Not recommended for this s e n ice under most conditions Aceric Acid ( t o 5 0 5 ) E Hydrofluoric Acid G Hydrogen Peroxide ( 3 0 5 ) Aceric Acid (Glacial) NR Magnesium Chloride Ace r on e E Magnesium Hydroxide Aluminum Chloride E Methyl Alcohol A 1um in u r n Su 1fare E Methyl Ethyl Ketone Ammon i um Car bonare E Naphtha ( V M 8( P ) Ammonium Chloride G Nickel Chloride Ammonium Hydroxide ( t o 755 ) r \ ; ~ Nickel Sulfate Ammonium Hydroxide (conc ) E Nitric Acid ( t o 207: ) Ammonium Nitrate E Nitric Acid ( t o 40% ) Ammonium Sulfate Aniline Barium Hydroxide Bcnzene Benzoic Acid Boric Acid Calcium Chloride Calcium Hydroxide Calcium Hypochlorite Carbon Disulfide Carbon Tetrachloride Chloroform Chlorine Dioxlde Bleach Chlorine Gas Chlorine Water Chrome Plating Solution Citric Acid Copper Sulfate Ethyl Acetate Erhyl Alcohol Erhyl Ether Ethylene Dichloride Ethylene Glycol Ferric Chloride Ferric Nitrate Ferric Sulfare Formaldehyde ( 37% ) Furfural Glycerine Hydrochloric Acid *Consult M.A. K n i g h t for specific recommendation. + L L E L NR G E I: E G F G F Nitric Acid (conc ) Oxalic Acid Perchloric Acid ( 20% ) NR E E E E NR E p. E E E F E Phenol Phosphoric Acid Potassium Chloride Potassium Cyanide Potassium Hydroxide (dilute) Potassium Hydroxide (conc ) Pyridine Sodium Bicarbonate Sodium Carbonate Sodium Chloride Sodium Hydroxide (dilute) Sodium Hydroxide (conc ) Sodium Hypochlorite (under 12 p H ) Sodium Hypochlorite (over 12 p H ) Sulfur Dioxide Sulfuric Acid ( t o 70% ) E NR E Sulfuric Acid (conc ) Sulfurous Acid Toluene NR E F E E E E Trichlorethylene Triethanolamine Trisodium Phosphate Water NR E G E NR E E Xylene Zinc Chloride Zinc Sulfate E E E F G G E G E G + NR F E E E # NR G NR E E F E E (continued) Cements, Mortars, and Asphalt 395 TABLE 3.12: VARIOUS MORTARS-KOCH ENGINEERING (continued) Chemical Resistance of RESIBOND HF Mortar (Meets ASTM specification 267 for chemical-resistant mortar) E - Excellenr resistance, all concentrations and temperatures to 250°F. G - Good resistance, most concentrations and temperatures to 165°F F - Fair resistance, dilute concentrations and temperatures to 9 0 ° F N R - Nor recommended for this Service under most conditions E Hydrofluoric Acid Acetic Acid ( to 50% ) G Hydrogen Peroxide ( 30% ) Acetic Acid (Glacial) N R Magnesium Chloride Acetone E Magnesium Hydroxide Alum in um Chloride E Methyl Alcohol Aluminum Sulfare Ammonium Carbonate E Methyl Ethyl Ketone E Naphtha ( V M & P ) Ammonium Chloride G Nickel Chloride Ammonium Hydroxide ( t o 7 % ) NR Nickel Sulfate Ammonium Hydroxide (conc ) E Nitric Acid (to 205%) Ammonium Nitrate E Nitric Acid (to 40% ) Ammonium Sulfate Aniline F Nitric Acid (conc ) G Oxalic Acid Barium Hydroxide F Perchloric Acid ( 20% ) Benzene E Phenol Benzoic Acid E Phosphoric Acid Boric Acid E Potassium Chloride Calcium Chloride E Potassium Cyanide Calcium Hydroxide E Potassium Hydroxide (dilute) Calcium Hypochlorite F Potassium Hydroxide (conc.) Carbon Disulfide G Pyridine Carbon Tetrachloride G Sodium Bicarbonate Chloroform E Sodium Carbonate Chlorine Dioxide Bleach G Sodium Chloride Chlorine Gas E Sodium Hydroxide (dilute) Chlorine Water G Sodium Hydroxide (conc.) Chrome Plating Solution E Sodium Hypochlorite (under 12 pH) Citric Acid E Sodium Hypochlorite (over 12 pH) Copper Sulfate F Sulfur Dioxide Ethyl Acetate E Sulfuric Acid (to 70% ) Ethyl Alcohol Ethyl Ether E Sulfuric Acid (conc.) NR Sulfurous Acid Ethylene Dichloride E Toluene Ethylene Glycol E Trichlorethylene Ferric Chloride E Triethanolamine Ferric Nitrate E Trisodium Phosphate Ferric Sulfate E Water Formaldehyde ( 37% ) NR Xylene Furfural E Zinc Chloride Glycerine E Zinc Sulfate Hydrochloric Acid 'Consult M.A. Knight for specific recommendation. E E E E E NR G E E E G NR E E NR E E E + NR F E E E # NR G NR E E NR E F NR E G E F E E (continued1 396 Corrosion Resistant Materials Handbook TABLE 3.12: VARIOUS MORTARS-KOCH ENGINEERING (continued) Chemical Resistance of CORESITE Mortar Acids: Acetic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .* Arsenic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . R ............................... R Boric Carbonic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . R Chloride Dioxide Water . . . . . . . . . . . . . . . . . R Chromic (Dilute) . . . . . . . . . . . . . . . . . . . . . . . . R R Citric . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . R Formic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . NR Hydrochloric.. . . . . . . . . . . . . . . . . . . . . . . . . Hydrofluoric . . . . . . . . . . . . . . . . . . . . . . . . . . NR ........... R Hydrogen Peroxide . . . . . . Hydrogen Sulfide Water. . Hypochlorous (C12 water). . . . . . . . . . . . . . . R R Lactic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . NR Nitric. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Oxalic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . * Phosphoric . . . . . . . . . . . . . . . . . . . . . . . . . . . NR NR Sulfuric.. ............................. Sulfurous (SO2 water) . . . . . . . . . . . . . . . . . . . * R Tannic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Tartaric . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . R Alkalies: Ammonium Hydroxide . . . . . . . . . . . . . . . . . . .* Calcium Hydroxide ..................... R Calcium Hypochlorite . . . . . . . . . . . . . . . . . . . R Magnesium Hydroxide . . . . . . . . . . . . . . . . . . R Potassium Hydroxide (15%). . . . . . . . . . . . . R Potassium Hydroxide (Conc.) . . . . . . . . . . . *R Sodium Hydroxide (15%) . . . . . . . . . . . . . . . . R Sodium Hydroxide (Conc.) . . . . . . . . . . . . . *R Sodium Hypochlorite. . . . . . . . . . . . . . . . . . . . R Sodium Peroxide ........................ R Salts: Aluminum Sulfate . . . . . . . . . . . . . . . . . . . . . . R Ammonium Chloride. . . . . . . . . . . . . . . . . . . . R R Ammonium Nitrate ..................... Ammonium Sulfate ..................... R Borax . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . R Calcium Bisulfite . . .................. R Calcium Chloride . . . . . . . . . . Calcium Hypochlorite.. . . . . Potassium Nitrate . . . . . . . . . . . Sodium Bicarbonate Sodium Carbonate . . . . . . . . . . . . . . . . . . . . . . Sodium Chloride . . . . . . . . . . . . . . Sodium Sulfate . . . . . . . . . . . . . . . Sodium Sulfide ...................... Sodium Sulfite . . . . . . . . . . . . . . . . . . . . . . . . . . Trisodium Phosphate . . . . . . . . . . . . . . . . . . . ............. Zinc Sulfate . . . . . . R R R R R Organic Materials: Alcohol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .......................... m ........................ Ethylene Glycol. . . . . . . . . . . . . . . . . . . . . . Formaldehyde . . . . . . . . . . . . . . . . . . . . . . . . . . Gasoline . . . . . . . . . . . . . . . . . Glucose . . . . . . . . . . . . . . . . . . ......................... ................. Milk . . . . . . . . . . . . . . . . . . . . . Mineral Oils . . . . . . . . . . . . . . . . . . . . . . . . . . . . Molasses . . . . . . . . . . . . . . . . . . . . Phenol. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Soaps . . . . . . . . . . .................... Starch . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Sugar Syrup . . . . . . . . . . . . . . . . . . . . . . . . . . . . Triethanolamine . . . . . . . . . . . . . . . . . . . . . . . . . Vegetable Oils . . . . . . . . . . . . . . . . . . . . . . . . . . R R R R R R R R R R * R 'Consult M.A. Knight for specific recommendation. R - Resistant NR - Not Resistant (continued) Cements, Mortars, and Asphalt 397 TABLE 3.12: VARIOUS MORTARS-KOCH ENGINEERING (continued) Chemical Resistance of KNIGHTBOND No. 6 Mortar (Meets ASTM specification 267 for chemical-resistant mortar) CHEMICAL MAX. CONC. MAX.TEMP. CHEMICAL MAX. CONC. MAX.TEMP. Yc by w t . o F. 7 a by wt. O F . 50 Acetaldehyde . . . . . 70 Hydrocyanic Acid ............... 10 70 Acetic Acid . . . . . . 100 70 **Hydrofluoric Acid ............. Any 200 Acetic Anhydride NR Any Hydrogen Peroxide ............ 30 70 Acetone . . . . . . . . . . . . . . . . . 50 70 Hypochlorous Acid . . . . . . . . . . . NR 70 NR Any Alcohol, Amyl . . . . . . Lactic Acid ........................ 25 200 50 70 Alcohol, Ethyl Lead Acetate .................. Any 200 50 70 Alcohol. Isopropyl . . . . . . Magnesium Chloride ......... Any 200 75 70 Magnesium N i t r a t e . . . . . . . Any Alcohol. Methyl . . . . . 200 Any 200 **Aluminuni Fluoride . . . Magnesium Sulphate . . . . . . . Any 200 Any 200 Mercurir Chloride . . . . . . . . . . . Any 200 Aluminum Sulphate . . . . . . NR 70 Mercuric Cyanide . . . . Any 200 Ammonia . . . . . . . . . . . Any 70 Mercurous Nitrate ... Any 200 Ammonium Cai.bonate . . . . 25 200 MEK . . . . . . . . . . . . . . . . . . . . . . . . . 15 160 Ammonium Chloride . . . . . . . 25 200 Mixed Acids . . . . . ..... 55 70 Ammonium Nitrate . . . 25 200 Naphtha . . . . . . . . . . . . NR 70 Ammonium Sulphate . . . . . Nickel Chloride .... Any 200 Aniline . . . . . . . . . . NR 70 200 Nickel Nitrate Any 200 Arsenic Acid . . . . . . . . . Any ............. 200 Nickel Sulphate Any 200 Barium Chloride Any Nitric Acid . . . . . . 50 70 Barium Hydroxide ............ NR 70 Barium Sulphide ............... NR 70 Nitric Acid .. 25 160 Benzene ............................. 7o Nitrous Acid NR 70 NR . . . . ................. NR 7o Oxalic Acid Any 200 Bi.omine 7o Perchloric Acid . . . . 25 70 Butyl Acetate ................... NR ........................ 2oo Phenol 50 70 Calcium Chlorate _ ............ Any 85 200 200 Phosphoric Acid Calcium Chloride .............. Any Calcium Hydroxide ............. NR 7o Phthalic Anhydride Any 200 7o Potassium Bicarbonate . . . 10 70 Calcium Hypochlorite ....... NR 2oo Potassium Bromide ...... Any 200 Any Calcium Sulphate .............. Potassium Chlorate . . . . . . . ~ n y 200 Carbonic Acid ...................... 5 Potassium Dichromate .... Any 200 Carbon Bisulfide . . . . . . . . . . NR 7o Potassium Ferrocyanlde .... 25 70 Carbon Tetrachloride .......... NR Potassium Permanganate Any 200 Chloracetic Acid .................. Any 70 Potassium Sulphate .......... Any 200 Chlorine ............................. NR 70 Silver N i t r a t e ............ 15 200 Chloroform ...................... NR 70 Sodium Acetate . . . . . . . . . . . . Any 200 Chromic Acid . . . . . . . . . . . . . . . . . 35 70 Sodium Bisulphate . . . . Any 200 Chromic Acid . . . . . . . . . . . . . . . . 10 160 Sodium Bisulphite . . . . . . . . . Any 200 Copper Chloride ............... Any ......... 2oo Sodium Carbonate 25 70 Copper Cyanide . . . . . . . . Any Zoo Sodium Chloride . . . . . . . . . Any 200 Copper N i t r a t e . . . . . . . . . . . . Any 2oo Sodium Cyanide . . . . . . . . . . . 25 70 i:2 Copper Sulphate . . . . . . . . . . . . Cresylic Acid . . . . . . . . . . . Ether . . . . . . . . . . . . . . . . . Ethyl Acetate . . . . . . . . . . . . . . . . Ethylene Dichloride .......... Ethylene Glycol . . . . . . . . . . . . . . . NR Sodium Ferricyanlde . . . . . 25 70 **Sodium Fluoride .................. Any 200 Sodium Hydroxide . . . . . . . . . . . NR 70 Sodium Hypochlorite ........ NR 70 Sodium N i t r a t e . . . . . . . . . . . . . . . . Any 200 Sodium Nitrite .................. 25 70 F a t t y Acids ....................... NR 70 Sodium Sulphite ............... 10 70 Ferric Chloride ................... Any 200 Sodium Sulphide .............. NR 70 Ferric N i t r a t e ..................... Any 200 Stannic Chloride ................. Any 130 Ferric Sulphate ................ Any 200 Stannous Chloride . . . . . . . . . . Any 200 Ferrous Chloride ............... Any 200 Sulphur Dioxide ................. Any 200 Ferrous Sulphate .............. Any 200 Sulphur Trioxide .................. NR 70 70 NR Fluorine ................................ Sulphuric Acid .................... 85 100 40 200 **Fluosilicic Acid ................... Sulphuric Acid .................. 60 200 35 150 Sulphurous Acid ................. Formaldehyde ..................... 10 70 Formic Acid .......................... 70 100 Trichloroethylene .............. NR 70 F u r f u r a l ......................... 50 70 Trisodium Phosphate . . . . . 10 70 40 200 Zinc Chloride ..................... Any 200 Hydrobromic Acid . . . . . . . . . . Zinc Sulphate ..... ......~ ....... Any 200 Hydrochloric Acid . . . . . . . . . . 30 200 **Use KNIGHTBOND # 7 Sulphur-Carbon Cement because hydrofluoric acid and fluorides a t t a c k fillers containing silica. Not Recommended for this service under most conditions. NR (continued) NR NR NR NR 50 - 70 70 70 70 140 398 Corrosion Resistant Materials Handbook TABLE 3.12: VARIOUS MORTARS-KOCH ENGINEERING (continued) Chemical Resistance of KABO Resin Mortar with Carbon Filler CHEMICAL RESISTANCE E Acetaldehyde . . . . . . . . E Acetic Acid . . . . Acetic Anhydride C E Acetone c Alcohol. Amyl E Alcohol. Ethyl . . Alcohol, Is0 PropyJ E E Alcohol. Methyl . . . . . E Aluminum Chloride' ... E Aluminum Hydroxide A I uni i num SUIpha t e E Ammonia _ _ . . NR Ammonium Bicarbonate F Ammonium Carbonate .. F Ammonium Chloride . . . E Ammonium Fluoride E E Ammonium N i t r a t e . . . Ammonium Sulphate . . . . E Amyl Acetate . . . . . . . . . . F Aniline . . . . F Antimony TrichloriPe E Arsenic Acid . . . . . . . . . . . . . E B a n u m Chrhonate . . . . . . E E Barium Chloride . . . . . . F Barium Hydroxide E Barium Sulphide . . . . . E Benzaldehyde . . . . . . . E Benzene . . . . . . . . . . Benzenesulfonic Acid E Benzoic Acid . . . . . . . . . . . . . E Bismuth Carbonate .... E Boric Acid ................ E Bromine ..................... NR Butyl Acetate . . . . . . . . . F Butyric Acid . . . . . . . . . . . . . G Calcium Chlorate . . . . . E Calcium Chloride _ _ . E Calcium Hydroxide ... NR Calcium Hypochlorite ...... F Calcium Sulphate . . . . . . . . . . . E .................... Camphor E E Carbonic Acid . . . . . . . . . . . . . . Carbon Bisulphide ........... E Carbon Tetrachloride ...... E G Chioracetic chi id .............. Chlorine ............................ G E Chlorobenzene ................... ..................... Chloroform E Chromic Acid . . . . . . . . . . . . . F E Citric Acid . . . . . . . . . . . . . . . . . Copper Chloride . . . . . . . . . . . . E Copper Cyanide .............. E CHEMICAL RESISTANCE Copper N i t r a t e . . . . . . . . . E Copper Sulphate ..... E E Creosote ......................... E t h e r .............................. E Ethyl Acetate . . . . . . . . . . . E Ethyl Chloride ........... E Ethylene Chlorhydrin G Ethylene Glycol ......... E F a t t y Acids ................. E Ferric Chloride .......... E E Ferric N i t r a t e ............... E F e m c Sulphate ........... Ferrous Chloride ......... E Ferrous Sulphate ........ E Fluorine ......................... NR Fluosilicic Acid ............ E Formaldehyde ............... E Formic Acid ................. E Furfural ........................ F Hydrochloric Acid ....... E Hydrofluoric Acid ......... E Hydrogen Peroxide .... F Wydrogen Strlphide E Hypochlorous Acid . . . . G Iodine ............................. NR Lactic Acid ................ E Lead Acetate . . . . . E Linseed Oil . . E Magnesium Carbonate E Magnesium Chloride ... E Magnesium Hydroxide F Ma@esium Nitrate . . E Magnesium Sulphate . . E Maleic Acid G Mercuric Chloride E Mercuric Cyanide . . E Mercurous N i t r a t e E Methyl Chloride E MEK . . . . . . . . . . . . . . . . . . . . . E Mixed Acids . . . . . . . . . . NR Naphtha . . . . . . . . . . . . . Naphthalene E Nickel Chloride E Nickel N i t r a t e . . Nicke] Sulohate . . . E F Nitric Acid ( D i l u t e ) Nitric Acid (Conc.) . NR . . E Nitrobenzene NR Nitrous Acid NR Nitrosyl Chloride Oleic Acid . . . . . . . . E Oxalic Acid .. E E CHEMICAL RESISTANCE Perchloric Acid . . . . . . . . F Phenol . . . . . . . . . . . . . G Phosphoric Acid E . . . . . . . . . . Phthalic Anhydride . . . E Picric Acid - Alcoholic . . . . . E Potassium Bromide . . . . . . . . . . E Potassium Carbonate (Dilute) . C Potassium Carbonate tconc.) . F Potassium Chlorate . . . . . . . . . . E Potassium Dichromate . . . E Potassium Ferrocyanide E Potassium Hydroxide .............. NR Potassium Permanganate .... c Silver N i t r a t e ............. E Sodium Acetate . . . . . . . . . E Sodium Bicarbonate . . . . . . . . . E Sodium Bisulphate . . . . . . . . . . . E Sodium Bisulphite . . . . . . . . . . . . . . . E Sodium Carbonate (Dilute) ...... G Sodium Carbonate (Conc.) . . . . . F Sodium Chloride . . . . . . . . . . . . . . . . E Sodium Cyanide . . . . . . . . . . . . E Sodium Ferricyanide . . . . . . . . E Sodium Fluoride . . . . . . . . . . . . . . . E Sodium Hydroxide . . . . . . . . . NR Sodium Hypochlorite . . . . . . . . . NR S o d i u m N i t r a t e ......................... E S o d i u m N i t r i t e ....................... E Sodium Sulphate .................. E Sodium Sulphite . . . . . . . . . . . . . . . . . . E Sodium Sulphide ....................... NR Sulphur .............................. F. Sulphur Chloride ....................... NR Sulphur Dioxide ........................... E Sulphur Trioxide ......................... NR Sulphuric Acid ( t o 6 0 % ) ........... E Sulphuric Acid ( 6 0 - 8 5 g ) ........_ G Sulphuric Acid (Conc.) ............... F Oleum ............................................ NR Sulphurous Acid ........................... E Tannic Acid ................................... E T a r t a r i c Acid .............................. E Tin Chloride .............................. E Toluene .......................................... E Trichloroethylene ......................... C Trisodium Phosphate (Dilute) C Trisodium Phosphate tConc.) ... F Zinc Chloride ............................. E Zinc Sulphate .............................. E - h t c e l l e n t resistance; ~ u i t a b l efor general serviceall concentrations and temperatures. F - Fair resistance; suitable for some senrIces-dilute concentrations and temperatures t o 90" F . G - Good resistance; suitable for most s e r v i c e k m o s t concentrations and temperatures to 212' F. NR-Not recommended conditions. for this service under most KEY a 0 a a 0 Resistant TYPE MORTAR x Not Recommended Limited Resistance Conairional Test Required Not Testeo RESIN" SILICA & SILICATE PENNWALT NAME FURAN -0 o I I rn 0 ? m I O 6 5 " p n m v) ~ MODIFIED PHENOLlC PHENOLIC e z ~ p n> z P v, ncnno v) T) -g u30T,ul=1, ?a:= D ID r ZD -06 (? ? ? ? ! r --1 r a' o < o z m= c_@ e3 - m m e -0 e= 2 a i 5 Cl SULFUR F =. c o 2 g 3 p 5 KEY TYPE MORTAR 0 Ressiant 0 Not Recommended a fl Conamonal a 5 Llmltea Reststance Requlred NOI Tesieo Test PENNWALT NAME - SILICA 8 SILICATE 4 r O 0 0 1 0 C F 6 ? 4 m RESIN” MoD’F’ED PHENOLIC FURAN I I (n-nc7T-n m m 5 v) gngz .2a>z - $5 n 6 ? 52 2 SULFUR PHENOLIC % D D W D O p g gEg; = c : =%w-3 6 2 5 0 0 B r ! < z s a 2 s a 0 e E; C Cements, Mortars, and Asphalt 40 1 TABLE 3.13: VARIOUS MORTARS- PENNWALT (continued) L!miled Reslsiance a Conaitional. Test Required a Not Tested (continued ) 402 Corrosion Resistant Materials Handbook TABLE 3.13: VARIOUS MORTARS- PENNWALT a Not Recommended a Llfnited Resisrance Conditional Test Required (contrnued) Cements, Mortars, and Asphalt 403 TABLE 3.13: VARIOUS MORTARS- PENNWALT (continued) 0 Not Recornmended Limited Resistance a Conditional. Test Required (continued) 404 Corrosion Resistant Materials Handbook TABLE 3.13: VARIOUS MORTARS- PENNWALT (continued) KEY g a TYPE RES'N" SILICA 8 SILICATE Llmited Resistance Conditional Test Required Zmc Chloride Nllrale Sulfate (continued) Cements, Mortars, and Asphalt 405 TABLE 3.13: VARIOUS MORTARS- PENNWALT (continued) Same cheqical resigtance with reduced physical strength above 750 F. (399 C) SeeTable 3.3 for epoxy mortars * * * Pennwalt K 1 4 8 Mortar has similar chemical resistances to CORLOK@ B Mortar and HB@ Mortar with some exceptions. Check with your Pennwalt representative for specific chemical resistances. t PENCHLOR@andCORLOK 6 Mortars should be tested for resistance in 1% range. All Mortars resistant in 10% and 25% range. @ Resistant up to 40% at 16OoF (71OC). Test higher concentrations and temperatures. S Up to 2% concentration. Q Limited resistance a t 48% concentration. Resistant t o 100°F (38OC). Test for higher temperatures. A Strong oxidizers must not be added because elemental bromine would be freed that would make the rating of all resin mortars Not Resistant. Polyester Mortar probably resistant to boiling point in all three concentrations. Epoxy toppings may be considered up t o 10% but verify by test. H.E.S.@and HB@ Mortars will resist some concentrations. See Addenda. # Attack is slow a t 1% or less. Resistant to 20% at 100cF. (38OC) c + + ++ & Resistant intermittent t o 1OO:F. (38zC) 0 Resistant ittermitt,nt t o 160 F. (71 C) ;= Up t o 302 F. ( 1 50-C) ADDENDA H.E.S. and HB Mortars differ from other siliceous, silicate, or silica mortars in resisting exposures between pH 0.0 and pH 8.0 with the exception of acid fluorides and HF acid. In addition, they can be used in glycol acetate, potassium sulfate or persulfate, sodium sulfide and trisodium phosphate, all of which will damage other siliceous mortars. "Use this reference information as a guide only. The information given in the resistance chart is believed t o be reliable, but no guarantee i s made nor can we assume liability in connection with their use. Please contact the Corrosion Engineering Department for specific recommendations." 406 Corrosion Resistant Materials Handbook TABLE 3.14: VARIOUS MORTARS-STERNSON IN 0 BOND C is a high-purity quartz colloidal silicate mortar for use with all sizes of acid brick and i s especially suited for stack or chimney linings as in sewage treatment operations and other, and as a mortar for process linings. IN 0 BOND P is a potassium silicate based inorganic brick mortar formulated for use with all sizes of acid brick and i s especially suited for chimney, stack or vessel linings where an easy t o use mortar will facilitate quick installation. IN 0 BOND S is a sodium silicate based mortar designed for use with all sizes of acid brick. FURABOND and FURASET are furan based cements that resist a wide range of strong corrosive solutions and severe mechanical abuse. They are formulated t o be used with all sizes of acid brick for protection of concrete and steel surfaces such as trenches, floors, piers, pump bases, supporting foundations, sumps, batching and pickling tanks, process vessels. They are especially suited for alternating alkali/acid conditions. STERNCHEM Polyester Mortar is formulated t o provide superior service for acid brick constructions in the chemical process, pulp and paper, plating, textile, fertilizer, and metal refining industries. They are especially suited for chlorine dioxide towers, bleaching vats, trenches, sumps, pits, bleaching solutions of sodium hypochlorite, oxidizing solutions of nitric and chromic acids t o 20% concentrations, hydrobromic acid, potassium and sodium dichromates, bromine water, s a l t solutions t o pH 11. STERNCHEM Phenolic Mortar is formulated t o provide superior service for acid brick constructions requiring the chemical resistance of carbon/resinous phenolic systems. STERNCHEM CHEMICAL RESISTANCE GUIDE R - Resistant NR - Not Resistant U - Untestcd 2'7OC - Maximum Temperature Tested 30% - Resistant To All Concentrations Up To 30% - In 0 Bond Series Not Recommended For Frequent Or Continual Concentrations Below 10% - Talychem Epoxy Mortar - Refer To Talychem Chemical Resistance Guide (Table 3.4) EXPOSURE Acetaldehyde Acetic Acid, under 10% Acetic Acid, Glacial Acetic Anhydride Acetone Acetone Oil Acetyl-Bromide Acetyl-Chloride Acetylene-Dichloride Acetyl Salicylic Acid Aluminum Bromide Aluminum Chloride, Sulphate & Alums IN 0 BOND SERIES llO0OC P - goooc S - 4OO0C c- R FURABOND FURASET 175OC STERNCHEM SERIES POLYESTER PHENOLIC 120% NR 175OC R R R R NR 3OoC R NR R R R NR NR NR U NR NR U U NR R R R NR NR NR NR NR R NR R R R R R R R R NR R R R R 3OoC NR R (continued) 407 Cements, Mortars, and Asphalt TABLE 3.14: VARIOUS MORTARS-STERNSON (continued) I N 0 BOND SERIES llO0OC P goooc EXPOSURE c- - S Aluminum Alum Rmmonium Ammonium Ammonium Ammonium Ammonium Ammonium Fluoride Bromide Carbonate Chloride , Sulphate Fluoride Hydroxide Nitrate (Neutral S o l u t i o n s ) Ammonium P e r s u l p h a t e Ammonium Phosphates Ammonium Sulphide Ammonium Tungstate Amyl Acetate , Alcohol Aniline Aniline Hydrochloride Antimony Chloride Ant imo ny Oxych l o r i de Antimony Potassium T a r t r a t e Aqua Regia Arsenic Compounds, Neutral o r Acid B a r i u m Chloride B a r i u m Hydroxi de Barium N i t r a t e Barium Sulphide Benzaldehyde - Neutral o r Acid Benzene (Bensol ) Benzene Sulphonic A c i d , ( o r Chloride) Benzoic Acid Benzyl Acetate Benzyl Alcohol Benzyl Chloride Boric Acid Bromine Bromine Water, S a t u r a t e d Butanol Butyl Acetate Butyl C a r b i t o l Butyric Acid Cadmium Chloride Cadmium N i t r a t e Calcium Chloride Calcium Hydroxide Calcium Hypochlorite Calcium N i t r a t e ( N e u t r a l S o l u t i o n s ) Calcium Sulphate Carbon Bisulphide - 4OO0C FURABOND FURASET 175OC NR R R R R NR NR R R NR R R R R R R R R R R R R R R R R R R NR R NR R R R R R R R R R R R R R R R R R NR R R R R STERNCHEM SERIES POLYESTER PHENOLIC 12oOc 175OC R U R R U 35OC NR R NR R R R NR R R R R R R R U U R U R R U R U NR NR R R R R NR NR NR NR R R R NR R R R R R R R U R U U NR U R R R 3OoC NR NR R R R R NR NR NR R R R U R NR NR U U U NR NR R R R R NR NR R R R R R R R R R R R R NR R R NR R 3OoC U NR U NR NR NR 3OoC R 70°C R 3OoC R R R R R R R R NR U R R R (continued) 408 Corrosion Resistant Materials Handbook TAB LE 3.14: VAR 10US MORTAR S-STE R NSON (continued) EXPOSURE I N 0 BOND SERIES llO0OC P - 9oooc S - 400°C c - Carbon Dioxide Carbon Oxychloride ( Phosgene ) Carbon T e t r a c h l o r i d e C a u s t i c Soda & P o t a s h C h l o r o a c e t i c Acid Chloral (Trichloroacetic aldehyde) Chlorbenzene C h l o r i n e D i o x i d e , Water Solution Chlorine, Liquid C h l o r i n e , Gas C h l o r i n e Water, S a t u r a t e d Chloroform Chloronaphthalene C h l o r o s u l p h o n i c Acid Chromic Acid 10% Chromic Acid Chromic C h l o r i d e Chromium Potassium S u l p h a t e C i t r i c Acid Copper A c e t a t e , Chlorides & Sulphate Copper Nitrate ( N e u t r a l Solutions) Cresol Ether Ethyl Acetate E t h y l Alcohol E t h y l a m i ne E t h y l Bromide Ethyl Chloride & Ethylene Dichloride E t h y l e n e D i s u l p h o n i c Acid E t h y l e n e Oxide Ethyl Ether Ethyl Sulphate E t h y l S u l p h u r i c Acid F a t t y Acids F e r r i c C h l o r i d e , Nitrate, Sulphate F e r r i - & Ferrocyanides F l u o b o r i c Acid F l u o r i n e Gas F l u o s i l i c i c Acid Fo rmal d e hyde Formic Acid & Compounds, n o t a l l Furfural FURABOND FURASET 175OC STERNCHEN SERIES POLYESTER PHENOLIC 120oc 175OC R R U U R R U 30°C U N U R R R R R R R R R NR N NR NR 8OoC 35oc 35OC 20% N U U NR NR NR NR NR R 3OoC R R R R R R R R R R R R NR NR R R R NR 3OoC NR NR U NR U U R U R R R R R R R R R R R R R R R R R R R U U N 8OoC U NR R NR R 3OoC 30oC NR NR R R R R R R R R R R R R R R R R NR R R R U NR NR NR R R R 3OoC R R 25Oc NR R R U NR NR R R R NR NR NR 6ooc 3OoC NR 3OoC U U 25oc 3OoC U R U R 3OoC 3OoC R 3OoC U R R NR NR NR NR R R R NR (continued) 409 Cements, Mortars, and Asphalt TABLE 3.14: VARIOUS MORTARS-STERNSON EXPOSURE (continued) I N 0 BOND SERIES llO0OC P goooc S 400OC c - - G a l l i c Acid Gasoline Glycerine Glycol Monoacetate Hydrazine S u l p h a t e Hydriodic Acid Hydrobromic Acid Hexane Hydrochloric Acid Hydrocyanic Acid H y d r o f l u o r i c Acid Hydrogen P e r o x i d e 1% Hydrogen P e r o x i d e 10% Hydrogen P e r o x i d e 25% H y d r o f l u o s i l i c i c Acid Hydrogen P e r o x i d e 30% Hydrogen S u l p h i d e Hypochlorous Acid Iodine I r o n Chlorides I r o n Nitrates Iron Sulphates Isopropyl Ether Iodoform Kerosene L a c t i c Acid & Compounds Lead C h l o r i d e Lead Nitrate ( N e u t r a l Solufuions) Magnesium C h l o r i d e , N i t r a t e , Sulphate Maleic Acid & Compounds Manganese C h l o r i d e , Oxides & Sulphates Mercuric C h l o r i d e Methanol (Methyl A l c o h o l ) Methyl A c e t a t e M e t h y l b u t y l e n e g l y c o l Acetate Methyl Cyclohexanol ' Methylene C h l o r i d e Methyl S u l p h a t e Methyl Sulphonic Acid Mineral O i l ivlolybdenum Acids & Oxides Naphthalene ( S u l p h o n a t e d ) Naphthalenesulphonic Acid Naphtholsulphonic Acid Nickel C h l o r i d e & S u l p h a t e F'URABOND FURASET 175OC STERNCHEM SERIES POLYESTER PHENOLlC 12oOc 175OC U 25OC 70°C R R R NR NR NR NR R R R R NR NR NR R NR R NR NR R R R U NR R R R R R R R NR R R R R R R NR R R R R R R R R NR NR R R R R NR R NR R R R R R R R R R R R R NR R NR R R R R R R R NR R 7OoC R 25OC NR 25OC R R R R R R R U R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R 3OoC R R R 3OoC R U U U NR U NR NR NR R NR NR U U NR 3OoC 25OC R R NR 3OoC 3OoC 3OoC NR 25OC R U R N U R U R R U R U U U U U U U R R (continued) 4 10 Corrosion Resistant Materials Handbook TABLE 3.14: VARIOUS MORTARS-STERNSON (continued) EXPOSURE I N 0 BOND SERIES c P S N i t r i c Acid 5% N i t r i c Acid 20% N i t r i c Acid 40% Nitrobenzene Nitrogen Oxides Nitroglycerine Nitrophenol Nitrotoluene O i l s - V e g e t a b l e , M i n e r a l , Animal O l e i c Acids & Compounds ( E s t e r s ) Oxalic Acids & Compounds Paradimethylaminobenzophenone P a r a f f i n Wax P e r c h l o r i c Acid Phenol ( 2 0 % S o l u t i o n ) Phenol S u l f o a c i d s Phosphoric Acid Phosphorous Bromide Phosphorous C h l o r i d e & Oxychloride P h t h a l i c Acid P i c r i c Acid Potassium Bichromate Potassium Bromide Potassium Carbonate Potassium C h l o r a t e Potassium C h l o r i d e , Nitrate, Sulphate Potassium Cyanide Potassium F e r r i & F e r r o Cyanide Potassium Hydroxide Potassium Oxalate Potassium Permanganate Potassium P e r s u l p h a t e & S u l p h a t e Potassium Peroxide Pyridine S a l i c y l i c Acid Selenium Compounds Acid o r N e u t r a l Silicon Tetrachloride S i l v e r Nitrate Sodium A c e t a t e Sodium B i c a r b o n a t e Sodium Bichromate Sodium B i s u l p h a t e , B i s u l p h i t e Sodium Carbonate Sodium C h l o r i d e , Nitrate Sodium Chromate Sodium C h l o r o s u l p h o n a t e Sodium Cyanide - llO0OC goooc 40OoC FURABOND FURASET 175OC STERNCHEM SERIES POLYESTER PHENOLIC 120% 175OC 7OoC U NR NR NR R R R R R R R R R R R R R R R R R NR NR NR R NR NR NR NR R R R R R NR R R R NR R R R R R R R NR R NR R R U R R R R R R U R 3OoC 8OoC 8ooc 6ooc 30OC NR U R R NR NR R R R NR R NR R R R NR R R R R R R NR R R NR R R R NR NR R NR 80°C R R R U R R R R R R R R R 25OC NR NR NR NR U u R R R U R NR NR U R NR U R NR R U R U U R NR R U U 7OoC R R R R U R R U U 3OoC NR NR NR NR R R R U R NR NR U R NR U R NR R NR 3OoC R 3OoC U U R R R R R 3OoC R R U 25OC (continued) 41 1 Cements, Mortars, and Asphalt TAB LE 3.14: VARIOUS MORTARS-STE R NSON (continuedJ EXPOSURE I N 0 BOND SERIES c -llO0OC P S Sodium Hydroxide Sodium H y p o c h l o r i t e Sodium O x a l a t e Sodium P e r o x i d e Sodium S u l p h a t e Sodium S u l p h i d e Sodium S u l p h i t e Sodium T a r t r a t e Sbdium T h i o s u l p h a t e , T h i o s u l p h i t e Soya O i l S t e a r i c Acid S u l p h u r i c Acid 5% S u l p h u r i c Acid 50% S u l p h u r i c Acid 80% S u l p h u r i c Acid 93% Sulphur C h l o r i d e Sulphur Molten Sulpnurous Acid Sulphur Oxides Sulphur Dioxide (Wet o r Dry) S u l p h u r i c Acid, Fuming Sulphur T r i o x i d e (Wet) S u l f u r y l Chloride (Sulphur Oxychloride ) Tannic Acid T a r t a r i c Acid & Compounds Tetrachloroethane Tin Chlorides Tin Sulphates Titanium C h l o r i d e s , S u l p h a t e Toluene ( T o l u o l ) Toluenesulphonic Acid T r i c h l o r o a c e t i c Acid Trichloroethylene Trisodium Phosphate Tung O i l Urea U r i c Acid Xylene ( XyIol) Zinc C h l o r i d e , Nitrate, S u l p h a t e Zinc Nitrate - goooc - NR NR R NR R NR R R R R R NR R R R R R R R R R R R R R R R R R R R R R NR R R R R R R 40OoC F'URABOND FURASET 175OC R NR R NR R R R R R R R R R NR NR NR R R R R NR NR STERNCHEM SERIES POLYESTER PHENOLIC 120% 175OC NR R NR NR U U U R R R NR NR NR R NR R R R R R R R 25OC 25OC U U R R R R R E R R NR 25OC R 3OoC R R R U NR NR NR NR R R R R R R R R R R R R R R R R 125OC R R U R R R 80oc U NR U 3OoC R 3OoC U 30OC R R NR R R U R R R NR U U U NR R R U U R R Ferrous Alloys TABLE 4.1: AUSTENITIC ALLOY-ALLEGHENY LUDLUM AL-6X is an austenitic chromium, nickel, molybdenum-containing alloy developed for service in chloride and other pitting or crevice corrosion environments such as sea water. The 20% chromium and 6% molybdenum contained in the alloy produces outstanding resistance to pitting and crevice attack in chloride-containing solutions. The high nickel (24%) and molybdenum provide good resistance to stress corrosion cracking. The alloy content of the material produces excellent general corrosion resistance in a number of media. The alloy is readily welded by the inert gas processes. AL-6X possesses good ductility and high impact strength. AL-6X is available as welded tubing, sheet and strip. Typical Analysis L Carbon Manganese Phosphorus Sulfur Silicon Chromium Nickel Molybdenum .025 1.50 .025 .Ol0 2d.E 24.50 6.25 The following table illustrates the corrosion resistance of AL-6X in various solutions in comparison to AISI stainless steel grades. Tests were performed in boiling acid (concentrations in weight percent) for five 46-hour periods. The listed values are corrosion rates in IPM (inches per month): 45% Formic Acid 20% Acetic Acid 10% Oxalic Acid 10% Sodium Bisulfate 10% Sulfuric Acid 65% Nitric Acid (ASTM A-262 Practice C) AL-6X 12.0 .143 .025 947 .230 1.36 943 9002 906 ,014 .07f 9005 .OOOl .0009 .OOll ,010 .0007 9507 .0009 JO26 .61 9000 Alloy Crevices On Samples 0.45 Gram Weight Loss Severe Crevice Attack 0.45 Gram Weight Loss Severe Pitting 316 0.40 Gram Weight Loss Severe Crevice Attack 0.03 Gram Weight Loss Some Pitting, especially on sample edges AL-6X No Weight change to 0.000 Grams No Attack Samples initially weighed about 10 g, No Weight change to 0.000 Grams No Attack 316 1 Corrosion Rate, IPM Concentrations of H,SO, Weight % 15VF 175’F 2OfYF 5 AL-6X 316 904 .003 904 .007 905 .012 10 AL-6X 316 .CQ6 907 .004 .013 ,007 .016 20 AL-6X 316 .009 .016 905 .070 .013 .146 40 AL-6X 316 907 536 .OlO 1.646 .019 3.023 95 AL-6X 316 .031 905 .043 907 .056 .026 No Crevices On Samples 304 304 Data, including the boiling acid tests above, show that AL-6X is generally more corrosion resistant than Type 316. In environments such as sulfuric acid, concentrations and temperatures have a marked influence on corrosion rate, and specific conditions should be carefully determined. The following data determined for 2-hour coupon tests are illustrative: Temperatures TyPical Weiaht Changes and Sample Conditions Resuking Fibm 10 Per&t Fe& Chloride tixposure Tests72 Hours 70” F (21” C) We Type Type 446 Solution Ferrous Alloys TABLE 4.2: AUSTENITIC STAINLESS STEELS-JESSOP 413 STEEL Jessop Steel’s corrosion resistant engineering alloys, JS700 and JS777, less steels. These alloys are proven problem-solvers in many applications are high-alloy, fully austenitic, super stainwhere corrosive conditions are too severe for the standard grades of stainless steel. They have also provided cost-effective alternatives to more expensive nickel-base and titanium-base alloys. JS700 and JS777 are much more highly alloyed than the standard stainless steels. These grades contain nominally 25% nickel, 20% chromium and 4.5% molybdenum. The combination of the three major alloying elements gives JS700 and JS777 a high degree of resistance to stress corrosion cracking. Neither alloy is completely immune to this type of corrosion failure, as can be shown by such severe tests as stressed exposure to boiling magnesium chloride solutions. Corrosion Data (48 Hr. Laboratory Tests-All concentrations are by weight %I. Corrosion Environment Temperature OF JS700 20% Phosphoric Acid 54% Phosphoric Acid 60% Phosphoric Acid 85% Phosphoric Acid Sensitized Material 25% Phosphoric 2% HF Boiling 250 Boiling Boiling Boiling 167 Point 60% Acetic Acid 1.1 Acetic AcidIAnhydride Boiling Boiling Point Point co.002 0.001 5% Nitric Acid + 3% HF 25% Nitric Acid 65% Nitric Acid (Huey) 155 Boiling Boiling Point Point <0.002 co.002 co.020 5% Hydrochloric Acid 10% Hydrochloric Acid 10% Hydrochloric Acid 10% Hydrochloric Acid 10% HCI in EDA (1 I Boiling Point Room Temp. 140 Boiling Point Boiling Point 30% Sulfuric Acid Sensitized Material 50% Sulfuric Acid 50% Sulfuric Acid + %% HCI 70% Sulfuric Acid Boiling Boiling Boiling Boiling Boiling co.002 0.0024 0.059 0.122 0.124 0.008 Point Pomt Point J8777 0.012 0.067 0.080 0.150 0.160 0.247 0.880 57.6 0.036 0.031 0.102 0.298 27.6 Butyl Acetate Mixture (2) Boiling Point Boiling Point Stretcher Test (3) (I) 1 Volume cone I-ICI in 9 volumes Ethylene Diamine. 0.264 0.096 Chemical Nickel Chromium Molybdenum Columbium Carbon, max Slllcon. max Manganese, max Phosphorus, max Sulfur, max Copper Water-0.3% HPSO~. Composition 0.294 1 454 1.691 2.37 (4) (4) 0.962 0.540 (3) 50% Sulfuric Actd + 0.6% Fe+) as ferrtc sulfate InhIbItor. (4) Dissolved COmPletelY in 48 hours. [IIOtninai an&SiS) JS700 JS777 24.0-26.0% 190-230 43- 50 6 x carbon mm-O.40 max .04 1 .oo 2 00 .04 03 50 max 24 O-26 0% 19 O-23.0 43- 50 8 x carbon mm-80 40 max 04 1 00 2 00 04 03 1.90-2.50 The copper added to JS777 markedly Improves resistance to general corrosion in strongly acid environments. As shown In the tabulated corrosion test results, copper improves performance not only in oxidtzmg acids (e.g. sulfuric) but in media generally considered reducing (hydrochlorIcI as well However, m more nearly neutral media, where failure is by 0 196 co.002 Point Point Point Point Point Acetic Acid-4% 317L co.002 co.002 0.962 1% Butanol-10% 317L Plus co.002 1.491 0.018 0.150 4.51 <O.OOl (2) 75% Ester-l Rate IPY localized corrosion, copper seems to be actually detrimental to performance. Field exposure tests (e.g. the TAPPI program IIT pulp bleach washers) and electrochemical current decay tests show pits to propagate more rapldly in JS777. JS700 is therefore the recommended alloy where pitting or crevice corrosion IS the primary concern. Ferrous TABLE 4.3: FERRITIC STAINLESS STEELS-ALLEGHENY AL 29-4-2 Critical Pitting Potentials in Saturated Sodium Chloride Brine at 38C (lOOF) Data pH 10 PH6 pH2 +990 + 400 + 990 +420 + 860 +430 (continued) from one year field corrosion tests paper mill bleach Results”’ ---__~_~~___.~~i Ic I t Mill -~__ I ,I C (72h.) Numbers in paranlherer indicale described L--C_(250h.) in ASTM 1 C (4%72hd I II II II ~ II 11 / Ill II ’ Ill III Ill Ill Ii Ill Ill AL 29-4-2 Titanium Monel400 E-BRITE ~ 316L .._ 22C (72F) .00N’3) .OON .OON JJON OON ~ (1) One Year Exposure Chlorides: Up lo 4100 ppm : As low as 1.2 PH Temperature: Up to74C (lS*F) the test duration. Weight Loss, mg/cmz 1 sOC(14OF) j 107C (224F) / ; I I 1 .OON .OON .08c .12 c .Ol c I ’ .OON .OOC .29 c cl6C I / .I. .I. Oeirler. R. H. Heahy and L. L Edwards. ‘%onorion Resistance of Alloys 10 Bleach Plan, Enwonmene”. TAPPI, Nov. 1979. Vol. 62. No. 11, pp. 4%5l. .oic / Performance of AL 29-4-2 and Other Alloys in Boiling 65% Nitric Acid”’ Crevice Corrosion Tests in Boiling Brine with Sodium Carbonate”’ Alloy Al 29-4-2 E-BRITE Titanium Monel400 ; Weight Loss, mg/cm2 0.00 0.00 0.00 1.05 Alloy Visual Appearance ’ No Corrosion NoCorrosion No Corrosion Crevice Corrosion / / :/ (1)S&waled NaCl brine conlaining 10% N&CO,, pH 11. 72.hour test, abnospheric pressure. wewces wdh rubber bands and tellon spacers. (2) Corrosion Classdicabon: I O-9 mil pit depth and4 mpy general corrosion rate II S-20 mil pll depth o,>l lo IO mpy general corrosion rate 111 > 20 mil pit depth or>10 mpy general corrosion rate Source: A. I, Tuthill, J. D. R”6hlo”. I1 ) PH 7.0.72-ho”, test. crevices with rubber band and teflon soacers (2; brine composition (wt. %): 25% NaCI; 38% Na,SO.; .lS% &Cl,; .03% MgCI, No Corrosion; C Crevice Corrosion. (3) Visual appearance rating: N j II Ill Ill Ill A692). Crevice Corrosion Test”) in Synthetic Brine”’ __.__ Alloy _---..-..- i I/ (1) 1500 ppm Cl as NaCl (Procedure (Z)NC No Cracks: C Cracks. pulp are shown plants TAPPI (0 Stage),‘) Corrosion Stress COrrOSiOn Cracking in Various NaCl Tests /___ T&304 at nine below. In this program, nine different pulp mills exposed corrosion test spools for one year. The AL 29-4-2 alloy was among those demonstrating the highest degree of corrosion resistance. MillivoltsVs. Saturated Calomel Electrode AL 29-4-2 E-BRITE 415 Alloy (cont’d) and Alloy , LUDLUM Alloys boiling at Corn&n AL 29-4-2 1 E-BRITE Type 304 Type 347 Type 316 -- Type-._430 -....... (1) ASTM I I I .._.__ A 262. Practice i -.- ._ C. Five who”, _ . .._ Rate, mm/a (MPY) .05-.08 (2-3) .lO-.13 (4-51 .20-.61 (8-24) .25-.41 (10-16) .28-.89 (1 l-35) .51-.9l _...(2036) --.__. ..”_._. _ ^._.. _ periods. Corrosion of AL 29-4-2 and Other Alloys in Hot Geothermal Fluid”) Corrosion of AL 29-4-2 and Other Alloys in 50% Nitric Acid Containing Chlorides and Fluorides at 79C (175F) i_!?lp(i~~!~---. ~-..-; _-.. -- ~- .-__- Corrosion Rate(?),mm/a (MPY) F.RRIT ‘E1TVIX 3W [ %nium I.211.Ol; (0.6) ’ 091 (3.6) ,117 025 ,079 (3.1) (l.O), 1 .305 ,102 (4.0) i ,914 ,241 (9.5) i 1.115 AL 29-4-2 (1) 133C (271F) cl-776 ppm pH 7.23 lice; S4 ppm Nonaerated so: SO ppm 109 Day Exporure H,S 0.1 ppm (2) Penetrabon rate calculated from maxim”m (3) P-Present but not measured N-Not observed SO”,Ce: (l,Chlo,ides (2) Corrosion addedasH,& fluoride as HF. rate is the average 01 two 48-ho”, (4.6) (12.0) (36.0) (43.9) __I periods. pit o, crevice depth. D. W.~DeSe,,,. P. F EM nd C. C. Thomas. ‘Malenals Setec,ion Guidelines (0, Geothermal power Syrlemr’~, FM Ed.. Rad,w Cotp., lo, U. S. Dept. of Energy. Contract NO. EC-77-C-M-3904. Septembe,. 1978. (continued) I Corrosion Resistant Materials Handbook 416 (contrnued) AL 29-4-2 Alloy (cont’d) Other Alloys in Boiling Organic Acids <O.Ol AL 29-4-2 E-BRITE /m_Fm_._ -- (1) Average 01 five 48.hour j (2)’ 0.5 (18)’ 0.01 (0.4)’ j’ ~- periods A. I, Asphahani. P. E. Manning, W. L. Silence. F. G. Hedge. “Highly Alloyed Stainless Materials lor Seawater Applica- ‘Source: lions”, Illinois. Presented at NACE. March 3-7. 1980. CORROSION/80. Chicago, Intergranular Alloy Corrosion of AL 29-4-2 and Other Alloys in Boiling Dilute Sulfuric Acid Solutions Corresion _I--__-.. I t Alloy625 / NA IE-BRITE I A NA A NA /Type 316 I ’ 1 A F I% H2sOI .005(0.2) .07 (2.6) .07 (2.8) .06 i2.2j .02 (0.7) 13.7 (541) .55 (21 7) 66 (25.8) Desulfurization [ Corrosion Rate, mm/a (MPY) I Samole I .03 .27 .32 .23 .36 77 2.49 2.71 (1.3) (10 7) (12.7) (8 9) (14) (3020)‘3’ (98.2) (107) .02 .46 .52 Ferric ASTM ) Bolting ~ ASTM Weight Loss (mglcmr) -Test AL 29-4-2 Alloy 625 i Alloy 625 /Type316 ,Type316 !Allov G i~lio;C-276 / 1 72h 24h 72h 24h 72h 72h 72h 8.73 L- ASTM A763 (344) .HSOJ: 3 “OI “o “Cl. 7 I ---I 0.2 N - 20.6 C I Wt. % CuCI.. 1 WI. % F&t> .14 (5.6) .13 (5.0) None Practice Y Corrosion of AL 29-4-2 Alloy in Laboratory Caustic Solutions 4.2 C - (2)“,sualexam,nat,an.N NoCorrosion C CrertceCorrosion Sulfate-50% HzSO~ A763. Practice X 65% HNOI A262. Practm C I rot (158F) c I I Plain Containing Grain Sample Weld Dropping Test (0.8) (18.2) (20.6) Environmentn) 1 Corrosion Tests on AL 29-4-2 ‘em-mm/a (M ____~_ 5% Ihso, Crevice Corrosion of AL 29-4-2 Alloy and Other Metals In Simulated Flue Gas (1)7VCl (0.1) 0.01(0.4)’ r Compesitior ’F J =-----I 1 I_._ I 1 Temperature IIuration. Other -t- - C (F) Boiling Boding Boiling - I 1 - ’ Na&O., 149 (300) B”“‘ng 177 (350) Boilmg Boiling 177 (350) Rate I mm/a Days ‘1 WPv) 5 4 4 4 4 j o.m(o I)* j 0.02 (0 8) 4 4 I Corrosion 4 4 0.10 (3.8) i 0.00(0.0) I 0.04 (1 5) / 0.19 (7.4) j 0.00(0.0) 0.00(00) 0.14 (5.6) I .L (continued) i 417 Ferrous A llo ys TABLE 4.3: FERRITIC STAINLESS STEELS-ALLEGHENY LUDLUM (contmwd) The E-BRITE alloy is a high-purity specialty ferritic stainless steel which combines excellent resistance to corrosion with good fabrication characteristics. It offers outstanding resistance to stress corrosion cracking along with superior Pitting and crevice corrosion resistance, compared to conventional ferritic and austenitic stainless steels. General corrosion resistance is usually better than that provided by these standard materials and in some cases is even better than that of some nickel-base alloys. The E-BRITE alloy also is designed to provide excellent resisiance to intergranular corrosion. Added to all this corrosion resistance are unique ductility characteristics, particularly when compared E-BRITE to other ferritic Alloy Analysis __- j,,,, stainless steels. Crevice Corrosion Tests 10% Ferric Chloride ~_..~..__ -.._- ___. -. ._ _.__~____.._ .._~___~_ .. __-___- ~~~W%!!!!J!Jz!_!_;I.~~ Chromrum Molybdenum Nrckel Copper Manganese Phosphorus 26 0 10 15 02 05 01 01 20 002 ,010 10 Su’f:1r SIlIEOfl Carbon Nrtrogen Columbrum / 1 / 250 -27 5 0 75 - 1 50 50 max 20 max 40 max 02 max 02 max 40 max 010 max 015 max 005 -020 ._ _ ___#Weight Loss, mg/cm” 1 -____ RT _ -. _ 38C.11 DOF)m L----_A110y. , j E-BRITE T3’7L T316 03 50 11 5 ~QX2QCt&_ (1)72 1 hour __--. exposure. ASTM _.___.._21..~__ G-48 i_AtlOY__ _-Weight Chloride Stress Corrosion Annealed Sheet /r-----i Boiling I Solution j T304 J2OuMgCI, c300 LIC 26Oc NaCl (II F NF - Resistance Time to Failure (Hours)” _._______-.. E-BRITE T316 : -~ F (81 F (22, I F 1241 F 1221 F (221) F (J-31 Slress Corroston No Fatlure NF (2001 NF (500, NF (loot” Falure Critical Pitting Potentials at 38C (1OOF) (1) 96.hour Crevice Sodium I i_AhY. Saturate 8ampleAppearance No Corrosron Crevice Attack 05 95 ~~t21)Crevj~e&tack_. exposure Corrosion Carbonate Tests in Boiling Brine with ’ --.--- _-__ --_!--WeightLoss. brine containmg ..-. No Corroston No Corrosron 0 00 0 00 105 N&l -__-.- mgkmf-VisualAppearance- NaCl Brine ,‘I) at i’1C (160F) --.-- Loss,mg/cm*_ E-BRITE Titanium in Saturated ~_~._ _ _38.3- -. Procedures Crevice Corrosion Tests ’ 5.25% Sodium Hypochlorite E-BRITE Type 316 lyp&?Q__ 76 27.0 32 2 -Crevice= 10% N&O,. pH 11. 72.hour lest. boiling at Urrosion Rate /-Temperature_. Duration _#1B.-Days _-mm~.___UkWT) I kt?NaOH-/--CKMnOd-NaCI j 75 Pitting Tests ” 102 Resistance Containing (215) 5 0 000 (220) 5 0 001 (230) (240) 1290) 1315) 7 5 5 4 0 000 0 001 0 003 0 084 QZZ0 381 of E-BRITE Alloy to Caustic NaCl and NaC103 (0 01, to 04) to oi 1 10 05) (0 111 13 3) 16-151_ Solutions !ld!Lal~~,,3 1 (1) 2% (2) F - 20 45 50 KMnO.-24 N&I. Failure by pottmg no crev,ces (pH 7.5) j ’ 10 5 -‘5 5 5___. 5 50 50 i.SL 50 _ ! ~ 01 0; 02 ~~~~ 143 143 152 152 152 (290) (305) (290) 13051 13051 (305) / 0041 (1 6) 003 li 0 076 (3 to 01 0 069 (2 71 _OLd28__ 0 028 ~il~li 11 11 ~~_ (continued) ’ Corrosion Resistant Materials Handbook 418 TABLE 4.3: FERRITIC STAINLESS STEELS-ALLEGHENY E-BRITE Corrosion of E-BRITE In Pulp Liquors ’ and Austenitic Alloys 7 Alloy (contmued) (co&d) Performance of E-BRITE Alloy and Other Stainless Steels in Huey Test”’ Corrosion Rate, mm/y (MPY)“’ ik--------- LUDLUM 2 Parts White Liauor to 1 Part I / I / 1 i FcBpXZ Type347 Type316 Type430 i 010-013 0.20-O 61 0.25-041 028-O 89 0 51-o 91 _____ I I (1)ASTMA262. Pracltce C. Bollmg 65O~ HNO,. Influence Corrosion I--- Fwe 4%hour and Austenitic Alloys Conditions of Heat Flux 300 50% ~ 50% 300 !- 1000 Corros,on Corrosion rate 0005 0010 0025 0041 0089 I ; 20 / 20 '100 IS average of two 48.hour added as HCI. lluorlde in Boiling. ______ _- Rate, mm/y (MPY) ” 35 permds Dilute Sulfuric ___~.j_ Activated Alloy 1138) Acid Solutions (MPY)’ 5% lizSO NonActivated Activated’ I ___I (3 6) (4 61 1120) (360) 14391 as HF Non- (0 2) Titanium 106) 0091 ('0)'0117 (31),0305 (40) 0914 (95) 1115 (02) 0015 (04) 0025 (1 0) 0079 (16) 0102 (35),0241 1% H2S04 Alloy 005-005 periods Type304 Corrosion Rate, mm/y ,E-BRITE Type316Tt ,Type317L 1 ~~_. ‘5000 5O”w (2, Chloride Corrosion of E-BRITE In White Liquor Under (8-22:) (10-16) (11-Z) (20-261 ~____ of Chloride And/Or Fluoride On In 50% Nitric Acid at 79C (175F) __-..--. snD/o (A-51 /I / Corrosion Solution ” .__. . c_______-_ _. ..__. E-BRITE PPM F -IHNO, _ _----- PPM Cl (I, / 1 I Corrosion Rate, mm/y (MPY) Alloy I Activated’ I (1) Sample kept al 160C (32OF) immersed in while liquor at BOC (176F). (2) Sample temperature 160C (32OF). whde liquor jet at 8OC (176F) projected against sample. Corrosion In-Plant Corrosion Tests of E-BRITE Other Alloys in White Liquor”’ Corra E-BRITE NI-CrAlloy600 Type329StamlessSteel Type310StalnlessSteel NI-Fe-CrAlloy800 NI-'hAlloy400 NI-Fe-CrAlloy825 Type304StadessSteei NI-CrAlloy625 Type316StamlessSteel CarbonSteel Boilin Or anic Acids ~~ and ___ Alloy b 3n Rate __.___/ mm/y WY) 0 000 0 005 0 008 0010 0020 0023 0 041 0168 0173 0 516 0886 (0 0) (1) While Liquor: 26’0 (NaOH+Na,S). 7.8% NaCI. 1 5% NarCO,. Temperature: 127C (261F) Duratlon~ 154 Days (2) SCC - Slress Corroston Cracking Observed IO 21 10 31 (0 4) (0 81 ro 91 I 1 Comparison of E-BRITE and Other Alloys Boiling 88% Formic and 99% Acetic Acids I r 1 E-BRITE NI-Cr-MoAlloy276 Nt-Fe-CrAlloyG Nl-Fe-Cr Alloy825 NdZrAlloy600 Type304 StaInless Type 3:6 Stainless 1 Rate. mm/v 88% Formic <o 01 (‘-'O 1) 005 0 10 (1 8) 0 08 0 23 0 33 0 38 2 44 NJ-Cr Alloy 625 NI Alloy200 3OoNa.SO, Corrosion in 0.23 99% Acetic 0 01 001 004 005 001 010 020 (4 0) (3 (9 (13 (15 0) 0) 0) 0) (96 0) (9oj 1 IMPY) } 046 005 (0 5) (04) (1.6) (20) (04) (40) (80) (180) (20) Ferrous Alloys TABLE 4.3: FERRITIC STAINLESS STEELS-ALLEGHENY LUDLIJM 419 (continued) Allegheny Ludlum Stainless Steel Type 439, a titanium stabilized, 18% chromium alloy, also known as ASTM XM-8 and by the IJNS designation S43035, is a ferritic stainless steel designed to resist corrosion in a variety of oxidizing environments from fresh water to boiling acids. It may be used either annealed, cold formed or as welded in many applications where other stainless steel alloys such as Type 304, Type 410, Type 409 and Type 430 are used. Type 439 may also be used in many oxidizing environments where Type 304 is considered adequate in terms of general corrosion resistance but is considered subject to chloride stress corrosion cracking. TYPICAL Tvpical General Corrosion Data _. I ANALYSIS Standard Grade Corrosion Rates in Inches Per Month and Millimeters Per Annum ( ) ,025 .40 .025 ,003 .50 16.00 .30 .60 ______ ,025 Medium MSR Grade .018 .40 ,025 ,003 .50 18.00 .30 .50 ,014 10% Oxalic Acid Boiling ___- Corrosion Resistance Stress Corrosion Cracking Type 439 is resistant to attack by potable water and many mildly or moderately corrosive chemical environments which are oxidizing in nature. In various chloride solutions, study has shown pitting resistance of Type 439 superior to that of Type 304. In addition, Type 439 is not subject to stress corrosion cracking which may cause premature failure of austenitic steels in chloride bearing environments such as hot waters used in heat exchangers. One of the most important corrosion properties of Type 439 is resistance to chloride stress corrosion cracking beyond the capabilltles of ConventIonal austenitic grades. This resistance is provided by the ferritic structure and low nickel content of Type 439. Results are equivalent for annealed, U-bent and autogenously welded Type 439. MF-1 is the designation for a corrosion resisting steel developed by Allegheny Ludlum originally for automotive exhaust system applications. An 11% chromium alloy, MF-1 is a functional corrosion resistant material that has served outstandingly in strong acid condensates that form in automobile mufflers ard tailpipes. The functional uses of MF-1 as a corrosion resistant material for many other special applications can be equally attractive; suetas replacement for carbon steels, to avoid painting or other maintenance, or for galvanized steels under severe corrosive conditions. Corrosion Resistance TYPICAL of MF-1 C jRates in Inches Penetration/Month’ Medium .--~__ r- ; Carbon _---- 25% Boiling Nitric Acid 20% Boiling Phosphoric Acid 60% Boiling Acetic Acid 50% Potassium Hydroxide at 240°F 75% Potassium Hydroxide at 410°F --.-_______ “Welded samples show : Steel .__..____ _ I j j 1 MF-1 50.0 ; .0150 30.0 I .048 I I .159 20.0 j Type 304 I -/ I 1 .0002 1 I 1 / .0002 .0050 ; .00055* / ~ .00055 ,221 I .085* i no preferential corrosion. / I i I ,045 ANALYSIS Cr 11.0 Ti Fe .50 Bal. 420 Corrosion Resistant Materials Handbook TABLE 4.4: FERRITIC-AUSTENITIC STAINLESS FERRALIUM alloy 255 is a patented, ferritic-austenitic nickel, 2% copper and 3.3% molybdenum. It combines tance to corrosion and erosion. STEEL-CABOT WROUGHT stainless steel high mechanical containing strength, PRODUCTS 26%chromium,5% hardness with approximately ductility and resis- Comparative Aqueous Corrosion Data Media Acetic Acid Concentration, percent by $yt$mp., 0 weioht Average Corrosion Rate, mils (mm) per year FERRALIUM Type 317L allov 255 Stainless Steel 10 Borhng 0.2 (<O.Ol) 0.2 (10.01 50 Borlrnq NII 0.2 (<O.Ol) Glacial Borlrna 0.7 f<O.Ol) 2.9 10.071 Citric Acid 50 Borhng NII 0.2 (<O.Ol) formic Acid 20 Bowling 0.4 (0.01) 8.5 (0.22) 40 Bollinn 0.4 (0.01) 17 (0.43) 60 Boihna 0.1 (<O.Ol) 22 10.56) 88 Bowling 18 (0.46) 9.2 (0.23) 1 Room Nil NII 2.5 Room Nil 11 (0.28) 10 Borhng 1.9 (0.48) - 65 Borhng 8.0 (0.20) - Hydrochloric Acid Nitric Acid Phosphoric Acid 10 150 (66) Ntl Nil 10 Bollma NII NII 30 150 (66) 0.1 (<O.Ol) Nil 30 Bowling 0.2 (<O.Ol) 6.7 (0.17) 0.1 (<O.Ol) 55 150 (66) Nil 55 Boihna 0.1 (<O.Ol) 1.2 (0.03) 85 150 (66) 0.1 (<O.Ol) 0.2 (<O.Ol) Sodium Chloride 3 Bothng 0.4 (0.01) Sodium Chloride plus 200 ppm Cu 3 Room 0.4 (0.01) - Sodium Chloride plus 0.5% Acetic Acid 0.8 Boding 0.2 (<O.Ol) 0.3 (<O.Ol) Sodium Chloride plus 0.5% Citric Acid 0.8 Boiling 1.2 (0.03) 31 (0.79) Sodium Chloride plus 0.5% Oxalic Acid 0.8 Boiling 0.5 (<0.02) 22 (0.56) Sodium Chloride plus 0.5 % Ammonium Chloride 0.8 Boiling Nil NII Sodium Chloride plus 0.5% Phosphoric Acid 0.8 Boiling Nil 0.1 (<O.Ol) Sodium Chloride plus 0.1 N Sulfuric Acid 5 Boiling 1 .o (CO.03) 148 (3.8) Sodium Hydroxide 50 Borhng 1.8 (0.05) 29 (0.74) Sulfuric Acid 5 150 (66) NII NII 5 Boiling 12 (0.30) 200 (5.1) 10 150 (66) Nil 8.9 (0.23) 10 Boihnq 4OLl.O) 490 (12) 20 150 (66) NII 50 (1.3) I (continued) Ferrous TABLE 4.4: FERRITIC-AUSTENITIC STAINLESS Average STEEL-CABOT Corrosion Data in Mixed WROUGHT PRODUCTS Acids and Salts Average Corrosion Rate, per year mils mm 286 (141) 0.1 co.01 212 (100) 8.4 0.21 212 (100) 0.3 co.01 212 (100) 0.2 <O.Ol Stearic Acid DIUS 3% NaCl 212 (100) 0.3 -co.01 Stearic Acid plus 1% H2s0.1 212 (100) 8.3 0.21 Stearic Acid plus 1% H2S04 and 3% NaCl 212 (100) 0.4 0.01 44% Sulfuric Acid plus 6% HN03 86 0.2 co.01 5% Citric Acid plus Patmitic Acid plus 8% 1% NaCl H2S04 Palmitic Acid plus 3% NaCl Palmitic Acid PIUS 1% H2S04 and 3% NaCl (30) Corrosion Test Temp. “F “C Media ASTM Synthetic Seawater* ASTM Synthetic Seawater Saturated with Chlorine Gas* ASTM Synthetic Seawater Saturated with SO2 Gas ‘Averageofdupbcale, smooth specimens. Data in Seawater Average Corrosion Rate, mils (mm) per year 68 20 Nil 95 35 Nil 122 50 0.1 (<O.Ol) 149 65 0.1 (<O.Ol) 176 80 Nil 194 90 Nil 68 20 2 (0.05) 95 35 0.8 (0.02) 149 65 7 (0.18)“” 150 66 Nil 96.hr. exposure. +*lnltla1lon of ptts Data in Natural Crevice-Corrosion Maximum Depth of Attack, mm 14 0 co.01 57 14 81 1.2 30 86 30 1.6 co.08 30 86 30 28 1.9 30 86 30 76 1.9 30 86 30 97 1.1 30 86 30 41 3.1 30 126 52 0.8 <O.Ol 30 126 52 28 0.10 Y FERRALIUM alloy 255 Type 316 Stainless Steel 29 57 29 FERRALIUM alloy 255 Type 316 Stainless Steel Type 317 Stainless Steel Type 317LM Stainless Steel 20 Cb-3”“Alloy FERRALIUM alloy 255 Type 316 Stainless Steel . Number of Crewas lmtmted Number of Crewces Powble (120) Seawater Percent Crevices Initiated* Test Duration, Days Alloy “Trademark of Carpenter Technology 421 (continued) Test Temp., “F (“C) Media Alloys Temp., “C Corporation (continued) 422 Corrosion Resistant Materials Handbook TABLE 4.4: FERRITIC-AUSTENITIC Crevice-Corrosion STAINLESS STEEL-CABOT Data in 10% Ferric Chloride WROUGHT at Room PRODUCTS Temperature for 10 Days Maximum Depth of Penetration, Alloy Number of Attacked Crevices* mils mm FERRALIUM alloy 255 0 0 0 Type 317LM Stainless Steel 20 12 0.30 Allov No. 904L 23 19 0.48 Type 317L Stainless Steel 16 77 2.0 20 Cb-3 allov 24 76 1.9 Tvpe 316 Stainless Steel 24 76 1.9 (Perforated) ‘Maxamum poswble number 01 crewces fcontmuedf was 24 Crevice-Corrosion Tests in Simulated SO2 Scrubber Environment* Allov Corrosion Rate per year mm mils Number of Attacked Crevices** Maximum Depth of Crevice Attack, mils mm FERRALIUM alloy 255 0.4 0.01 0 0 0 Alloy No. 904L 57 1.4 24 6 0.15 Tvpe 317LM Stainless Steel 179 4.5 24 10 0.25 Allov No. 825 216 5.5 24 10 0.25 ‘45.000 “Maxnwm “‘0.003% ppmCl-“‘, 150°F WCI. ptf 2. SOz/O, I1 11 bubbled through solutmn. possible number of cw~ces was 24. F&h, 0.11% KCI, 0.5% MgCIz. 1.1% Cat&, 5.6% N&I. 0.02% CaFz and 2OOg11CaSO1.2fi10. Comparative Localized Allov Corrosion Temperature Data in Oxidizing Pitting Temperature, “C “F Crevice-Corrosion Temperature, “C “F FERRALIUM allov 255 50 122 35 95 Allov No. 904L 45 113 20 68 Tvoe 317LM Stainless Steel 35 95 15 59 Tvoe 317L Stainless Steel 25 77 10 54 523 CABOT allov No. 825 25 77 s-5 20 Cb-3 alloy 20 68 s-5 523 Type 316 Stainless Steel 20 68 1-5 523 ‘4% NaCl NaCI-HCI Solution* + O.OlM HCI + 0.1% Fez ISO,) 3. Comparative Stress-Corrosion Cracking Data Time to Failure, hrs. Media Test Temp., “F “C FERRALIUM alloy 255 Type 316L Stainless Steel Type 317L Stainless Steel 50% NaOH with NaCl Saturated 290 143 NC NC NC 70% NaOH with NaCl Saturated 350 177 NC 200,648 1031.1031 NC-No fadure in 1000 hours. All tests were run on dupbcate specmxens. (continued) Ferrous Alloys TABLE 4.4: FERRITIC-AUSTENITIC STAINLESS Comparative Media Stress-Corrosion Temp.,“C Pt WROUGHT STEEL-CABOT Cracking PRODUCTS Data TYpe 316 Stainless Steel FERRALIUM alloy 255 ASTM Synthetic Seawater 176 80 NC* NC 0.8% NaCl + 0.5% Oxalic Acid* 286 141 NC NC 0.8% NaCl + 0.5% Acetic Acid* 286 141 C NC 0.8% NaCl + 0.5% Citric Acid* 286 141 C NC Modified Wick TestXb 212 100 NC 25% NaCl*** 393 200 C - 30% NaCI”” Boiling 0.8% NaCl + COz* 286 Boiling 0.8% NaCl + 0.2% HaPOa* 286 45% Magnesium Boiling Chloride NC NC - NC 141 4% NaCl + 1% HIPO~* (continued) 141 - NC C C C C *U-bend specimen. 30.day exposure “U-bend spewne”, 100-day exposure “‘U-bend specmxn, 5OGhr. exposure NC-No Cracks C-Cracked -Not tested ‘Localued attack blOOO ppm Cl (as NaCll and 500 pp” FeCh Average Aqueous Corrosion Resistance of Weldments* Average Corrosion Rate Per Year, mils (mm) Media Test Temp., “F (“Cl Base Metal % in. (12.7mm) Plate, SMAW l/B in. (3.2mm) Plate, GTAW % in. (12.7mm) Plate, GTAW 75% Acetic Acid Bolllng 0.1 (<O.Ol) Ntl 0.2 (<O.Ol) 0.2 (<O.Ol) 2.5% Hydrochloric Acid Room 0.1 (<O.Ol) NII 1.7 (<0.05) Nil 10% Ferric Chloride 86°F (30°C) 0 2 (<O.Ol) 0.6 (<0.02) 0.7 (cO.02) - 6% Ferric Chloride (With Crevice) Room NII NII Nil Nil 65% Nitric Acid Boiling 4.7 (0.12) 8.3 (0.21) 7.6 (0.19) 11 (0.28) 10% Nitric Acid + 3% Hydrofluoric Acid Room 2.3 (0.06) 6.8 (0.17) - 55% Phosphoric Acid Boihng 1.4 (0.04) 1.6 (0.04) 4.1 (0 IO) 1.3 (<0.04) 10% Sulfuric Acid Bolllng 37 (0.94) 73 (I .9) 49 (I .2) 66 (I .7) 50% Sulfuric Acid + 42 g/l of Ferric Sulfate Boiling 13 (0.33) 19 (0.48) 18 (0.46) 23 (0.58) ‘FERRALIUM’ allay255lo ltsell Comparative Test Temp., Alloy 1; Stress-Corrosion Cracking Data* Calcium Chloride** 250 121 300 149 Sodium Chloride** 350 400 250 300 177 204 121 149 350 400 177 204 FERRALIUM alloy 255 NC NC NC C NC NC NC C Alloy No. 904L NC NC C C NC NC C C 20Cb-3 illov NC NC NC C NC NC C C *l-week exposure. C-shaped spewnens. like alloy holder. “Compositions were selected to provide the same chloride NC-No cracks C-Cracked content as a 25% NaCl solutmn. 423 424 TABLE Corrosion Resistant Materials Handbook 4.5: IRON ALLOY-CABOT WROUGHT PRODUCTS MULTIMET alloy is an iron-base alloy for use in applications involving high stresses at temperatures (816 C), and moderate stresses at up to 2000°F (1093°C). It has good oxidation resistance, ductility fabricated. Its high-temperature properties are inherent and are not dependent upon age hardening. CORROSION RESISTANCE OF MULTIMET@ up to 15OO’F and is readily ALLOY All results are expressed in mils (mm) penetration per year. Acid strengths are given in percent by weight. In some instances, no measurable penetration could be observed. These instances are noted by the word, “Nil.” All data are steady-state as calculated from a minimum of five 24-hr. test periods. All data were obtained using corrosion solution heat-treated sheet. TYPICAL PENETRATION RATES ACETIC specimens IN CORROSIVE ACID CHROMIC 99% 2% 10% 20% Room Nil Nil Nil Nil Nil Nil 150 deg. F (66 deg. C) Nil Nil Nil Ni’ (&S) (2%) 1 356’ 1 >lOOO 1 0.1 (<O.Ol) 1 0.1 (~0.01) 1 0.1 (cO.01) 1 6.0 (0.15) (9.09) FORMIC ACID 50% from 12-gage, Mils (mm) Per Year MEDIA, 10% Boiling prepared 20% I 30% 40% 60% Nif (<oo:bl) - 0.1 (CO.01) (<t-k!Ol) Nif (<%) - 10% 1 4.0 (>25.4) I ACID 1 (0.10) 6.0 (0.15) Nil 1_ 69% Nil Nil (<YOl) 1 (;;oo, 1 (zf5, ) (X0, *Rate is for the fifth (24-hour) test period, not steady state rate. CUPRIC 2% Room Nil 150 deg. F (66 deg. C) - Boiling - 5% 2% + NaCl CHLORIDE FERRIC 5% + 10% NaCl 10% 10% + 10% NaCl 2% 2% + 5% NaCl 5% + 10% NaCl 10% - - Nil - Nil - - Nil 160 (4.06) Nil - Nil - 193 (4.90) (725.4) - - - (725.4) - - 919 (23.3) 71000 Room 150 deg. F (66 deg. C) Boiling 0.1 (<O.Ol) 2% (co67.01) 71000 71000 (>25.4) - HYDROCHLORIC 1% CHLORIDE WET CHLORINE ACID 5% 10% 150/o 20% 25% 37% (E3, (fE3) $8) (EO) (K5) (A!28) 687 (17.4) >lOOO (B25.4) - - - - Nil Nil 343 (8.71) 572 (14.5) 431 (10.9) 424 (10.8) 370 (9.40) 934 (22.7) .>lOOO (725.4) >lOOO (725.4) 71000 (725.4) 71000 (725.4) 180 (4.57) (continued) Ferrous Alloys TABLE 4.5: IRON ALLOY-CABOT WROUGHT PRODUCTS 425 (continued) NITRIC ACID 10% 20% 30% 40% 50% 60% Room Nil Nil Nil Nil Nil Nil - Nil 150 deg. F (66 deg. C) Nil Nil Nil 0.1 (<O.Ol) 0.3 (CO.01) 0.4 (0.01) - 0.8 (0.02) (<od%l) 0.8 (0.02) 2.0 (0.05) 4.0 (0.10) 6.0 (0.15) (O!& Boiling PHOSPHORIC ACID 10% 30% 50% 65% / Nil / 150 deg. F (66 deg. C) I Nil I (CYOl, I (<oo:bl, I Boiling (<KY) TABLE 4.6: IRON ALLOYS-CABOT / 1 Nil Nil (&Ol) 0.3 (CO.01) 3.0 (0.08) STELLITE (01320) HYDROFLUORIC ACID Room Nil 65% 303 (7.70) 25% 5% 1 &?3, 1(iii[z I I - - 70% $6) SODIUM HYDROXIDE 45% I - - - DIVISION The TRISTELLE alloys were designed to resist corrosion and all forms of wear. In particular, they were developed to withstand galling, the gross damage commonly encountered in metal-to-metal sliding systems. By virtue of their excellent resistance to cavitation erosion, they are particularly recommended for valve service. Compositions Fe Cr Ni co Si C 30 10 12 5 1 TRISTELLE alloy TS-1 Bal TRISTELLE alloy TS-2 Bal TRISTELLE alloy TS-3 Bal 2 Resistance to Corrosion The following immersion test results relate to multilayer undiluted gas tungsten arc deposits. N/L represents an initial corrosion rate of greater than 50 mpy (1.27 mm/year) and a steady state corrosion rate of less than 5 mpy (0.13 mm/year). 30%CH&OOH Boilina 50%H,POd 66°C 65%HNOs 66°C 5%H2SOd 66°C TRISTELLE alloy TS-1 E E E E TRISTELLE alloy TS-2 U E G N/L TRISTELLE alloy TS-3 U U S U STELLITE alloy No. 1 G E E STELLITE alloy No. 6 E E E E = < 5 mpy (-c 0.13 mm/year) G = 5-20 mpy (0.13 - 0.51 mm/year) S = 20-50 mpy (0.51 - 1.27 mm/year) U = > 50 mpy (> 1.27 mm/year) 426 Corrosion Resistant Materials Handbook TABLE 4.7: IRON- AND NICKEL-BASE ALLOYS-STAINLESS Corrosion Specialty Alloy CFBM Erosion-Corrosion (Alloy 316 CFEM (316) 20) Alloy Modified ILLIUM PD _._._______,,..___ Fe Base Cr-Ni-Co Alloy ILLIUM ILLIUM 98 .._.....___.,,__. Ni Base Cr-Mo-Cu Alloy CN-7M Hardwood Spent Sulfite Typical Specific Gravity (25°C) liquor from ..... . ............ ................................................ 4.52% 0.18% ” ” Total Sulfur .......................... 5.95% ” ” Acid ...................................... 6.37% ” ” Formic Acid ...................................... 1.26% ” ” ................................................. 8.74% ” ” .25.00% ” ” 4.60% ” ” Reducing Sugars Sulfonic ............................. 1 % Sl ...................... Sulfur on Solids Corrosion Acid Nitric A 65% solution of boiling nitric acid test revealed to attack Tests: 316 (S-20) Erosion-Corrosion IRok Factor1 30.3646 0.65 32.1459 32.1437 0.57 29.7435 29.7420 0.41 31.4510 31.4491 0.37 ILLIUM PD 29.8805 29.8793 0.31 IltlUM 98 32.5120 32.5109 0.27 Erosion-Corrosion in Hardwood Spent Sulfite Liquors Metal Losr Due To Specimen All0y Weight fgmsl Erosion-Corrosion After Before IRate Fadorl ILLIUM 98 32.2792 ILLIUM PD 29.8990 29.8944 0.82 32.1 B 17 32.1722 1.73 Modified CN-7M 32.2789 0.51 (Alloy 20) PD Food Acids: PD is up to 10 times more resistant than CN-7M Resistance of ILLIUM Boiling that ILLIUM 30.3667 P fgmsl After 1 .048 ................................................ OCH Weight .2.3 - 3.0 MgO Acetic Liquor Digester Co0 Sl Causticized Analysis pH ................................................... ( '/. Specimen Before Alloy Alloy P ,_..______.________. Fe Base Cr-Ni-Cu IlllUM in Metal Lolr Due To Description ,...,.__.,..,___.._._ ..Cast CN-7M & ENGINEERING in Pulp and Paper Industry Alloys Designation Modified FOUNDRY stainless steel Test results Tests conducted in boiling vinegar naise demonstrate that ILLIUM cellent to attack resistance and mayon- PD exhibits ex- from food products. were: ILLIUM CF-8M PD 1 to 1.8 mills per year (316) 11.7 mills per year Fluosilicic ILLIUM PD passes the ASTM Sea water corrosion U. S. Navy at Portsmouth of corrosive to 75,000 attack B117 salt spray tests conducted resulted on specimens psi for a period Food processcrs are becoming severe corrosive nature of cleaning disinfectants. Sea Water and Salt Spray: test. Acid: for the in no evidence stressed at 55,000 corrosive Fluosilicic agents. mills per year. corrosion solution CF-8M ILLIUM rate of 0.25 chemicals acid is typical A 25% acid at 125” F corrodes more aware of the PD and of these of fluosilicic at a rate of 500 has a measured mills per year. of six months. (continued) Ferrous TABLE 4.7: IRON- AND NICKEL-BASE ALLOYS-STAINLESS Corrosion Analysis in Phosphoric of Discharge Phosphoric Acid Product MATERIAL Fluorine Sulfuric Acid 81 ENGINEERING Industry from Reactor Amount Phosphoric FOUNDRY Present (percent by weight) AVERAGE Acid RANGE 48% Compounds 47-49% 1% Acid 1-2 l-2% to Solids to Measured Reactor Corrosion Product Rate of Alloys at 180’ in CORROSION 98 0.5 lnconel 625 1.2 ILLIUM P 1.9 ILLIUM W 2.9 lnconel825 Alloy RATE ILLIUM Durimet Performance MPY 9.1 20 10.1 20 53.7 in Phosphoric (71% Phosphoric MATERIAL 5% 40% F MATERIAL Carpenter % Acid Evaporator Acid at 44O’F) MEASURED CORROSION IPY ILLIUM 98 .0066 ILLIUM G .0109 ILLIUM P .028 316 (sensitized) .067 317 (3.3 MO) ,079 316 (2.6 MO) ,131 316L (2.2 MO) ,160 RATE Alloys (continued) 427 428 Corrosion Resistant Materials Handbook TABLE 4.8: STAINLESS STEEL-ARMCO STAINLESS STEEL PRODUCTS Armco NITRONIC 50 Stainless Steel provides a combination of corrosion resistance and strength. This austenitic stainless steel has corrosion resistance greater than that provided by Types 316, 316L, 317 and even 317L. plus approximately twice the yield strength at room temperature. In addition, Armco NITRONIC 50 has very good mechanical properties at both elevated and sub-zero temperatures. This is the material for equipment requiring excellent corrosion resistance-including that in which Types 316 and 316L stainless steels are marginal. NITRONIC 50 is an effective material for the petroleum, petrochemical, chemical, pulp and paper, textile, food processing and marine industries. Components using the combination of excellent corrosion resistance and high strength currently include pumps, valves and fittings; fasteners, cables, chains, screens and wire cloth; marine hardware, boat shafting, heat exchanger parts, springs and photographic equipment. A wide range of additional applications is made possible by high strength and toughness at sub-zero temperatures, low magnetic permeability even after severe cold working or exposure to sub-zero temperatures, and excellent mechanical properties at temperatures up to 1200 “F (649°C). Composition % .06 max 4.00/6.00 0.040 max 0.030 max 1 .OOmax 20.50/23.50 Carbon Manganese Phosphorus Sulfur Silicon Chromium % Nickel Molybdenum Nitrogen Columbium Vanadium 11.50/13.50 1.50/3.00 .20/.40 .l o/.30 .l o/.30 CorrosionResistance Corrosion Rates in Inches per Year (IPY) Unless Otherwise Indicatedu) NITRONIC 50 Bar Test Medium Annealed 1950 F (1066 C) NITRONIC 50 Bar Annealed 2050 F (1121 C) NITRONIC 50 High-Strength (HS) Bar 10% FeCls, 25 C-plain(*) 10% FeCls, 25 C-creviced(*) <.OOl g/in* <.OOl g/in* <.OOl g/in* <.OOl g/in* <.OOl g/in* <.OOl g/in* 1% 2% 5% 10% 20% <.OOl <.OOl <.OOl - <.OOl <.OOl <.OOl 0.028 0.133 <.OOl <.OOl <.OOl 1% 2% 5% 10% 20% H2S04, H2S04, H2S04, H2S04, H2S04, HzS04, HaS04, HzS04, HzS04, HaS04, 80 80 80 80 80 C C C C C Boiling Boiling Boiling Boiling Boiling 1% HCI,35C 2% HCI, 35 C 1% HCI,80C 2% HCI,80C .194 <.OOl 0.024 - 0.027 0.064 0.131 0.356 1.64 0.296 - Types 316 & 316L Annealed Bar .Oll g/in* .186 g/in* Types 317 & 317L Annealed Bar - - 0.002 0.011 0.060 0.10 0.48 <.OOl <.OOl 0.036 0.049 0.155 0.12 0.26 0.73 2.20 0.013 0.027 0.093 0.465 1.30 <.OOl <.OOl <.OOl 0.027 0.012 0.021 0.002 0.023 <.OOl 0.439 0.239 0.452 - 0.148 0.263 65% HNOs, Boiling 0.010 0.012 0.012 70% HsP04, Boiling 0.203 0.202 0.201 33% Acetic Acid, Boiling <.OOl <.OOl <.OOl 20% Formic Acid, Boiling 40% Formic Acid, Boiling 10% HN03 + 1% HF, 35 C 10% HNOs + 1% HF,80C - 0.027 0.034 - 0.064 0.442 ft)lmmersion tests performed on W” dia. x %” (15.9 x 15.9 mm) long machined cylinders. Results are average of five 48-hour periods. Specimens tested at 35 C and 813 C were intentionally activated for third, fourth, and fifth periods. Where both active and passive conditions occurred, only active rates are shown. MExposure for 50 hours with rubber bands on some specimens to produce crevices. Ferrous TABLE 4.9: VARIOUS DUPLEX AND AUSTENITIC STAINLESS STEELS-CLIMAX 429 Alloys MOLYBDENUM Chemlcsl Analyses of Stainless Steels Studied. wt X Stainless Steel Type C N Si Mll P S Cr Ni Ho CU Others SK? 0.004 0.018 0.24 0.34 0.005 0.012 25.51 10.93 1.89 - Ti-0.54 s13 0.004 0.011 0.30 0.35 0.005 0.014 25.18 10.35 2.91 1.04 Ti-0.48 DP-3 0.018 0.12* 0.43 0.88 0.015 0.012 25.02 6.91 3.07 0.64 w-o.11 SAF 2205 0.012 0.14 0.34 0.65 0.017 '-0.003 22.13 5.70 3.05 - __ - 26.00* 5.52* 3.33* 1.73* -- - 26 3.7 2.3 9.25 0.24 FBRRALIDI@ alloy 255 VEW A905 0.019* 0.20* - 0.034* 0.36* - 5.8 T304 0.068 - 0.52 1.07 0.007 0.014 18.29 T316 0.03 0.052 0.43 1.58 0.017 0.014 17.2 11.2 2.2 55700 0.036 0.032 0.32 1.77 0.020 0.005 20.5 25.10 4.40 <0.1* __ 0.16 __ __ 0.28 Nb-0.32 * Analyzed at Climax Research Laboratory FERRALIDM is a rqistered trademark of Bonar Langley Alloys, Ltd. VBW A905 Is a trademark of Vereinlgte Edelstahlwerke SAF 2205 is a trademark of Sandvikens Jeroverks Aktiebolag DP-3 is s trademark of Sumitomo Metal Industries. Ltd. X700 is a trademark of Jessop Steel Company 512 and 513 ere trademarks of Nisshio Steel Co., Ltd. Critical Crevice Corrosion Temperature for the Duplex and some Austenitlc Stainless Steels in 10% FeClj.6H20 (pH 1)" Highest Temperature of No Crevice Corrosion 'C Stainless Steel TYPO Lowest Temperature of crevice Corrosion QC s12 2.5, 2.5 7.5, 7.5 s13 0, 0, 2.5 2.5 DP-3 10, 10 12.5. 12.5 SAF 2205 17.5, 17.5 20, 20 VEW A905 17.5, 17.5 20, 20 22.5, 22.5 25, 25 FEP..RALI& alloy 255 T304 -_ -2.5, -2.5 T316 __ -2.5, -2.5 10, 10 JS700 *Based on oneday exposure tests. 12.5, 12.5 (continued) 430 Corrosion Resistant Materials Handbook TABLE 4.9: VARIOUS DUPLEX AND AUSTENITIC STAINLESS STEELS-CLIMAX MOLYBDENUM (cont’d) Corrosion Rates and Deepest Penetration In the Creviced Area for Duplex and Austenitic T304, T316 end JS700 Stainless Steels in Dilute Chloride (600 pprcCl-, 5 ppm Cu++, 02) Solution at 90°C (194'F), One Week Exposure Stainless Steel TYPO Corrosion Rate rngdm-=/day 0.0, 0.1 NAB, 47 some etched E.pots 513 4.1, 1.9 49, NMPb pits, rust spots DP-3 0.0, 0.0 NA, NA SAF 2205 0.2, 0.3 28. 39 etched spots, small pits VEW A905 0.8, 39, 32 small pits, discoloration 0.9 T304 33, 28 206, 77 numerollspits, etched spots T316 7.7, 0.9 175, NMP pits. etched spots, rust spots JS700 0.1, 0.1 NA, NA - no attack bNMP- __ s13 0.120, 0.120 __ VEW A905 FERRALIlJt@ alloy 255 - no measurable penetration EDX Analysis of Austenitic and Ferritic Phases of the Duplex Stainless Steels pitting Potential Volts 50°C 60°C 0.100, 0.100 SAF 2205 __ NA, NA s12 DP-3 - 0.1, 0.1 Pitting Potentials for the Duplex Stainless Steels and T316 and 55700 in M NaCl Stainless Steel Type Remarks s12 FERRALIti alloy 255 ‘NA Deepest Penetration in Creviced Area, microns 0.320, 0.280, 0.240 Average 0.280 0.360, 0.320 Average 0.340 0.400, 0.340 Average 0.370 No pitting T316 0.060, 0.060 55700 No pitting SegregationRatio Stainless Steel TYPO % in Ferrite/% in Austenite CT Ni MO Other s12 1.41 0.56 1.03 -- s13 1.42 0.50 2.34 __ DP-3 1.29 0.43 2.39 -- SAF 2205 1.22 0.52 1.86 -- VEW A905 1.11 0.6 2.53 0.8 (Mn) 1.17 0.65 2.61 0.54 (Cu) -- -_ __ 0.080, 0.140 Average 0.110 __ FERRALIIJM@alloy 255 0.420 Ferrous TABLE 4.10: Relative VARIOUS Corrosion 304N 305 306 309 309s 310 310s 314 316 316F 316L 316N 317 317L 321 329 330 347 346 364 403 405 409 410 414 416 416 Se 420 420F 422 429 430 430F 430F Se 431 434 436 440A 4408 44oc 442 446 The “X” nolallons “Stainless Steels” Chemical Atmospheric industrial IRON AND STEEL INSTITUTE - Salt Water Marine Mild Oxidizing x x x x x x x x x x x x x x x Reducing x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x x lndlcale that a speck Manual STEELS-AMERICAN of AISI Stainless Mild Atmospheric and Fresh Water (S20100) (S20200) (S20500) (S30100) (S30200) (S30215) (S30300) (S.30323) (S30400) (530403) (530430) (S30451) (S30500) (s30800) (530900) (S30908) (S31000) (S31006) (S31400) (S31600) (S31620) (531603) (S31651) (S31700) (531703) (S32100) (S32900) (N06330) (S34700) (S34800) (538400) (540300) (S40500) (S40900) (S41000) (541400) (541600) (S41623) (S42000) (542020) (S42200) (S42900) (S43000) (S43020) (S43023) (543100) (543400) (S43600) (544002) (S44003) (S44004) (S44200) (S44600) (S13800) (S15500) (S17400) (Sl7700) 201 202 205 301 302 3028 303 303 Se 304 304L Products Resistance UNS Number TYPE Number *Steel STAINLESS 431 Alloys x x x x x x x x x x x x x x x Y x x x x x x x x Y x x x statnless steel type may be considered as reslstant to the corroswe enwonment and Heat Resisting Steels,” December 1974, American Iron and Steel Institute, categories. Washington,D.C. (continued) 432 Corrosion Resistant Materials Handbook TABLE 4.10: VARIOUS STAINLESS STEELS-AMERICAN Relative Corrosion Resistance of AlSl Stainless Acids Hydrochloric acid Nitric acid Type 304L or 430 is used. Phosphoricacid Type 304 is satisfactory for storing cold phosphoric acid up to 85% and for handling concentrations up to 5% in some unit processes of manufacture. Type 316 is more resistant and is generally used for storing and manufacture if the fluorine content is not too high. Type 317 is somewhat more resistant than Type 316. At concentrations up to 85%, the metal temperature should not exceed ‘212 F I100 Cl with Type 316 and slightly higher with Type 317. Oxidizing ions inhibit attack and other inlubitors such as arsenic may be added. Sulfuric acid Type 304 may be subject to pitting, particularly if some sulfuric acid is present. Type 316 is usable at moderate concentrations and temperatures. Bases Ammonium hydroxide, sodnrm hydroxide, caustic: solutions Steels in the 300 series generally have good corrosion resrstance at virtually all concentrations and temperatures in weak bases, such as ammonium hydroxide. In stronger bases, such as sodium hy droxide, there may be some attack, cracking or etching in more concentrated solutions and at high. er temperatures. Commercial purdy caustic solutions may contain chlorides, which will accentuate any attack and may cause pitting of Type 316 as well Type 304. Acetic acid is seldom pure in chemical plants but generally includes numerous and varied minor constituents. Type 304 is used for a wade variety of equipment including stills, base heaters, holding tanks, heat exchangers, pipelines, valves and pumps for concentrations up to 99% at temperatures up to about 120 F (50 0. Type 304 is also satisfactory for contact with 100% acetic acid vapors, and-if small amounts of turbidity or color prckup can be tolerated-for room temperature storage of glacial acetic acid. Types 316 and 317 have the broadest range of usefulness, especially if formic acid is also present or if solutions are unaerated. Type 316 is Steel and the CORROSION Chemical Industry, RATES OF STAINLESS ” Climax *Pitted specimens-average White, Materials pit depth. Protection, 2 (1963). t Specimens 47. Are Used* Aldehydes Type 304 is generally satisfactory. Amines Type 316 is usually preferred to Type 304. Cellulose acetate Type 304 is satisfactory for low temperatures, but Type 316 or Type 317 is needed for high tempera. tures. Citric, formic and tartaric acids Type 304 is generally acceptable at moderate temperatures, but Type 316 is resistant to all concen. trations at temperatures up to boding. Esters From the corrosion standpoint, esters are cornpar. able with organic acids. Fatty acids Up to about 300 F (150 C), Type 304 is resistant to fats and fatty acids, but Type 316 is needed at 300 to 500 F (150 to 260 C) and Type 317 at higher temperatures. Paint vehicles Type 316 may be needed if exact color and lack of contamination are important. Phthalic anhydride Type 316 is usually used for reactors, fractionating columns, traps, baffles, caps and piping. Soaps Type 304 is used for parts such as spray towers, but Type 316 may be preferred for spray nozzles and flake-drying belts to minimize offcolor product. Synthetic detergents Type 316 is used for preheat, piping, pumps and reactors in catalytic hydrogenation of fatty acids to give salts of sulfonated high molecular alcohols. Tail oil ipulp and paper industry) Type 304 has only limited usage in tall-oil distillation service. High.rosin-acid streams can be handled by Type 316L with a minimum molybdenum content of 2.75%. Type 316 can also be used in the more corrosive high-fattyacid streams at temperatures up to 475 (245 Cl, but Type 317 will probably be required at higher temperatures. Tar Tar distillation equipment is almost all Type 316 because coal tar has a high chloride content; Type 304 does not have adequate resistance to pittmg. Urea Type 316L is generally required. Pharma ceuticals Molybdenum Type 316 is usually selected for all parts in contact with the product because of its inherent corrosion resistance and greater assurance of product purity. Company, STEELS IN FLUE GASES ~~~ l*W.F. Grades used for fractionating equipment, for 30 to 99% concentrations where Type 304 cannot be used, for storage vessels, pumps and process equipment handling glacial acetic acid, which would be drscolored by Type 304. Type 316 is likewise applicable for parts having temperatures above 120 F (50 Cl, for dilute vapors and high pressures. Type 317 has somewhat greater corrosion resrstance than Type 316 under severely corrosive conditions. None of the stainless steels has adequate corrosion resistante to glacial acetic act@ at the boding temperature or at superheated vapor temperatures. Type 304 can be used at room temperature for concentrations over 80%. Type 316 can be used in contact with sulfuric acid up to 10% at temperatures up to 120 F (50 C) if the solutions are aerated: the attack is greater in airfree solutions. Type 317 may be used at temperatures as high as 150 F (65 Cl with up to 5% concentration. The presence of other materials may markedly change the corrosion rate. As lrttle as 500 to 2000 ppm of cupric ions make it possible to use Type 304 in hot solutions of moderate concentration. Other additives may have the op posite effect. Sulfurous acid Different (continued) Grades Stainless generally is not recommended except when solutcons are very dilute and at room temperature. There is usually no appreciable attack on Type 304 or 316 as long as sufficient nitric acid is present. *“Stainless Where Environment “Mixed acids” Organics Acetic acid Steels Grades Envrronment IRON AND STEEL INSTITUTE destroyed. 1966, Greenwich, (EXPOSURE CT. 3 MONTHS)** Ferrous TABLE 4.11: VARIOUS STAINLESS STEELS-CARPENTER CORROSION of inhibiting or accelerating contaminants. of recirculation, solids in suspension, velocity, of use, and equipment design. The corrosion RESISTANCE TABLE CODE infredata for all grades except Carpenter 20Cb3 are reprinted from Corrosion Data Survey, 1967 and 1974 Editions, published by the National Association of Corrosion Engineers. The corrosion rates for Carpenter 20Cb-3 stainless represent a composite of the NACE Corrosion Data Survey and more current data developed in Carpenter’s Corrosion Laboratory. 350 250 175 150--- fluence on corrosion, the conditions greatly. 125 When reviewing these the following in mind corrosion tables, per year 0 Corrosion RON less than 0.020” per ycor 0 Corrosion Rote lrom 0.020” to 0.050” X Corrosion RON greotcr than 0.050” par year 662 20 40 per year 80 60 100 462 347 , affect 257 it is good to keep : 100 212 _-------____ _.__ _.__._ ____ _-_-_____ ____. ______ ______.___________ Stainless Type 410 is resistant to mild atmospheres. 75 Stainless Type mospheres. Corrosion Rote less than 0.002” 212---- seldom found that will be free of all contaminants. However, the majority of these contaminants have no inthat do generally l 300--- The influence of contaminants is probably the most important from a commercial standpoint. Corrosive solutions are but the ones 433 TECHNOLOGY This table shows the resistance of a number of materials to the more common chemicals. Many factors influence the resistance of materials lo various solutions. Factors which must be given consideration for service in corrosive environments are: temperature, concentration, aeration, influence fluence quency Alto ys 430 is resistant to industrial at- to food processing and 167 50--- Stainless Type 304 is resistant mild corrodents. Stainless Type 316 is resistant to chemicals. 25 77 ’ C F ’ 20 ’ I 40 Percent Concentration I 1ou in Water 20Cb-3 stainless is resistant to severe corrodents. Footnotes 1 2 3 4 5 6 7 a 9 10 11 12 13 14 15 16 17 16 19 20 21 22 23 24 for Corrosives Toxic Explosrve Flammable lhgestlon p&on Inhalant poison Attacks skm lrntant Vaoor harmful lgmtes orgamcs Fummg liquid Hygroscoplc Ltberates I-ICI in water Narcotic Volatrle Hazardous under pressure lgmtes combustrbles Fire hazard Exolosrve over 70% lgnrtes m morst arr at 30°C Exothermrc m water Dust explodes Explosve dust Exothermic with water Footnotes for Data Squares 1 2 3 4 5 No water No arr. oxygen Low arr. oxygen Pits Stress cracks 6 7 6 9 10 11 12 13 14 15 16 17 16 19 20 21 22 23 24 25 26 27 26 29 30 31 32 33 34 35 36 37 36 39 40 Stress corrosion Drscolors Crevrce attack Intergranular attack No chlorides May discolor May catalyze May prl May stress crack Transgranular attack Vapor Aerated Catalyzes Static Agitated -7 pH <7 pH >7 pi-i No HCI. H&O+ NaCl No ferric chloride -0.1% acetic acid Also sludge No iron salts No sulfuric acid Explosive With HzSO4 With steam No sulfur No stress No ammonia 300 psi Stress relieved No HCI. Cu. Ni ions No Cu, Fe ions Over 70% air 41 42 43 44 46 46 47 46 49

CORROSION RESISTANT MATERIALS HANDBOOK 4TH ED

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