lOMoARcPSD|37895460 Rate of evapoation of different liquids Chemistry (Indian High School) Scan to open on Studocu Studocu is not sponsored or endorsed by any college or university Downloaded by Aniket Rai (aniketrai20032005@gmail.com) lOMoARcPSD|37895460 CHEMISTRY INVESTIGATORY PROJECT RATE OF EVAPORATION OF DIFFERENT LIQUIDS Downloaded by Aniket Rai (aniketrai20032005@gmail.com) lOMoARcPSD|37895460 DONE BY – GRADE – 12 SCIENCE TABLE OF CONTENTS OBJECTIVE INTRODUCTION FACTORS AFFECTING RATE OF INFLUENCE USES OF DIFFERENT LIQUIDS EVAPORATION IN DAILY LIFE EXPERIMENTS EXP NO.1 EXP NO.2 EXP NO.3 EXP NO.4 BIBLIOGRAPHY Downloaded by Aniket Rai (aniketrai20032005@gmail.com) lOMoARcPSD|37895460 Downloaded by Aniket Rai (aniketrai20032005@gmail.com) lOMoARcPSD|37895460 OBJECTIVE In this project, we shall determine the Rate of Evaporation of different liquids and then Compare it with respect to different factors and density. INTRODUCTION Downloaded by Aniket Rai (aniketrai20032005@gmail.com) lOMoARcPSD|37895460 Evaporation is a process in which when a liquid on the surface turns into a gas or vapor. When liquid is placed in an open vessel. It slowly escapes into gaseous phase ventually leaving the vessel empty. Evaporation of liquids can be explained in the terms of kinetic molecular model although there are strong molecular attractive forces which hold molecules together. The molecules having sufficient kinetic energy can escape into gaseous phase. If such molecules happen to come near the surface in a sample of liquid all the molecules do not have same kinetic energy. There is a small fraction of molecules which have enough kinetic energy to overcome the attractive forces and escapes into gaseous phase. Evaporation causes cooling. This is due to the reason that the molecules which undergo evaporation have high kinetic energy therefore the kinetic energy of the molecules which are left behind is less. Downloaded by Aniket Rai (aniketrai20032005@gmail.com) lOMoARcPSD|37895460 FACTORS INFLUENCING RATE OF EVAPORATION 1. Concentration of the substance evaporating in the air: If the air already has a high concentration of the substance evaporating, then the given substance will evaporate more slowly. 2. Concentration of other substances in the air: If the air is already saturated with other substances, it can have a lower capacity forth substance evaporating. 3. Temperature of the substance: If the substance is hotter, then evaporation will be faster. 4. Flow rate of air: If fresh air is moving over the substance all the time, then the concentration of the substance in the air is less likely to go up with time, thus encouraging faster evaporation. In addition, molecules in motion have more energy than those at rest, and so Downloaded by Aniket Rai (aniketrai20032005@gmail.com) lOMoARcPSD|37895460 the stronger the flow of air, the greater the evaporating power of the air molecules. 5. Inter-molecular forces: The stronger the forces keeping the molecules together in the liquid or solid state the more energy that must be input in order to evaporate them. 6. Surface area and temperature: The rate of evaporation of liquids varies directly with temperature. With the increase in the temperature, fraction of molecules having sufficient kinetic energy to escape out from the surface also increases. Thus with the increase in temperature rate of evaporation also increases. Molecules that escape the surface of the liquids constitute the evaporation. Therefore larger surface area contributes accelerating evaporation. 7. Nature of Liquids: The magnitude of inter-molecular forces of attraction in liquid determines the speed of evaporation. Weaker the inter-molecular forces of attraction larger are the extent of evaporation. In diethyl ether rate of evaporation is greater than that of ethyl alcohol. 8. Composition of Environment: The rate of evaporation of liquids depends upon the flow of air currents above the surface of the liquid. Air current flowing over the surface of the liquid took away the molecules of the Downloaded by Aniket Rai (aniketrai20032005@gmail.com) lOMoARcPSD|37895460 substance in vapour state thereby preventing condensation. 9. Density: The higher the density, the slower a liquid evaporates. 10. Pressure: In an area of less pressure, evaporation happens faster because there is less exertion on the surface keeping the molecules from launching themselves. Downloaded by Aniket Rai (aniketrai20032005@gmail.com) lOMoARcPSD|37895460 USES OF DIFFERENT LIQUIDS WATER: Water has many distinct properties that are critical for the proliferation of life that set it apart from other substances. It carries out this role by allowing organic compounds to react in ways that ultimately allows replication. Water is vital both as a solvent in many ways and respiration. It is also central to acid base neutrality and enzyme function. ACETONE: Acetone is often the primary component in nail polish remover. It is used extensively for the safe transporting and storage of acetylene. Vessels containing a porous material are first filled with acetone followed by acetylene, which dissolves into acetone. It is a strong solvent for most plastics and synthetic fibers. It is also used as a drying agent, due to readiness with which it binds to water, and it volatility. Acetone can also be used on hair to remove buildup and oil. Downloaded by Aniket Rai (aniketrai20032005@gmail.com) lOMoARcPSD|37895460 ACETALDEHYDE: It is a flammable liquid with fruity smell. Acetaldehyde occurs naturally in ripe fruit, coffee and fresh bread and is produced by plants as a part of their normal metabolism. It is known as the chemical that causes hangovers. It is used as an intermediate in the production of acetic acid, certain esters and a number of other chemicals ETHANOL: The largest single use of ethanol is an a motor fuel and fuel additive. It may also be utilized as a rocket fuel and is currently used in lightweight rocked powered racing craft. Ethanol fuels flue-less, real flame fireplaces. Ethanol is kept in a burner containing a wick such as glass wool, a safety sheild to reduce the chances of accidents and an extinguisher such as plate or shutter to cut off oxygen. Downloaded by Aniket Rai (aniketrai20032005@gmail.com) lOMoARcPSD|37895460 Downloaded by Aniket Rai (aniketrai20032005@gmail.com) lOMoARcPSD|37895460 EVAPORATION IN DAILY LIFE After sweating, we get a cool feeling on our skin. This is due to the evaporation of the sweat generated from our bodies. Washed or wet clothes are dried by evaporation. When the clothes are hung outside in the sun, due to the heat of the sun, the water droplets present in the clothes get dried away due to evaporation. In food processing industries, the process of evaporation is used to dry out all the liquid contents and make the concentration of solid content high. Salt crystals are formed by creating a water solution, in which the deposit settles down and the liquid above is left to evaporate. Once the entire volume of the liquid gets evaporated we are left with the salt crystal present below. In the case of distillation, the mixtures with different boiling points are heated until one of the mixtures gets evaporated, hence the given mixtures are separated. Evaporation occurs in the water cycle in which the water from any water body on the surface of the earth is evaporated into the air. This water when cools down causes rain. The generation of steam in a hot. Downloaded by Aniket Rai (aniketrai20032005@gmail.com) lOMoARcPSD|37895460 EXPERIMENTS EXP NO.1 Aim : To compare the rates of evaporation of acetone, benzene and chloroform. Requirement : Three same size Petri dishes of diameter 10 cm., 10 ml. pipettes, stop watch, acetone benzene and chloroform. Procedure : 1. Clean and dry all Petri dishes and identify them as A, B and C. 2. Pipette out of 10 ml. acetone in Petri dish "A" with stopper similarly pipette out of 10 ml. of benzene and chloroform in each of Petri "B" and "C". 3. Remove the cover plates from all Petri dishes and start the stop watch. 4. Let the Petri dishes remain exposed for 10 minute. Now cover each of the petri dish and note the volume of remaining material in them. Downloaded by Aniket Rai (aniketrai20032005@gmail.com) lOMoARcPSD|37895460 Observation : Time : 10 min. = 600 Sec. Petri dishes Marked Liquid Taken (V1) ml. Volume remaining (V2) ml. Vol. Evap. V=V1–V2 Rate (V/T) ml./s A 10 2 8 8/600=0.0133 B 10 3 7 7/600=0.0116 C 10 4 6 6/600=0.010 Results : Rate of evaporation of Acetone is 0.0133 ml/s. Rate of evaporation of Benzene is 0.0166 ml/s. Rate of evaporation of Chloroform is 0.010 ml/s. Conclusion : The intermolecular forces of acetone, benzene and chloroform are in order. Chloroform > Benzene > Acetone. Downloaded by Aniket Rai (aniketrai20032005@gmail.com) lOMoARcPSD|37895460 EXP NO.2 Aim : To study the effect of surface area on the rate of evaporation of diethylether. Requirement : Three Petri dishes of diameter 2.5 cm., 5 cm., 7.5 cm. with cover, 10 ml. of pipette and stop watch. Procedure : 1. Clean and dry all Petri dishes and mark them as A, B and C. 2. Pipette out of 10 ml. diethylether in each of the Petri dishes A, B and C and cover them immediately. 3. Uncover all three Petri dishes and start the stop watch. 4. Note the remaining volume after 10 min. vaporization of diethyl ether from each Petri dish. Observation : Time : 10 min. = 600 Sec. Petri dishes Diameter of Volume Taken Remaining Vol. Downloaded by Aniket Rai (aniketrai20032005@gmail.com) Evaporated lOMoARcPSD|37895460 Marked P.T.Ds. (ml.) (ml.) volume A 2.5 10 4 6 B 5.0 10 2 8 C 7.5 10 0 10 Results : The order of evaporation of acetone in three petri dishes as 7.5 > 5.0 > 2.5 cm. Conclusion : Larger the surface area more is evaporation. EXP NO.3 Aim : To study the effect of temperature on the rate of evaporation of acetone. Requirement : Two Petri dishes of 5 cm. diameter each stop watch, 10 ml. pipette, thermometer, thermostat. Downloaded by Aniket Rai (aniketrai20032005@gmail.com) lOMoARcPSD|37895460 Procedure : 1. Wash and Clean, dry the Petri dishes and mark them as A, B. 2. Pipette out of 10 ml. of acetone to each of Petri dishes A and B and cover them. 3. Put one Petri dish at room temperature and to the other heat for same time. 4. Note the reading. Observation : Time : 10 min. = 600 Sec. Petri dishes Marked Time (Sec.) Temperature (0C) Volume Taken (ml.) Evaporated volume (ml.) A 10 30 10 10 B 20 40 10 10 Results : The order of evaporation of acetone in two Petri dishes as given Room Temperature < Heating. Conclusion : Observation clearly shows that the evaporation increases with temperature. Downloaded by Aniket Rai (aniketrai20032005@gmail.com) lOMoARcPSD|37895460 EXP NO.4 Aim : To study the effect of air current on the rate of evaporation of acetone. Requirement : Two Petri dishes acetone. Procedure : 1. Clean and dry the Petri dishes and mark them as A and B. 2. Keep one dish where no air current and other under a fast air current. 3. Note the reading. Observation : Initial Volume 10 ml. of Acetone. Petri dishes Marked Conditions Time (Sec.) volume Evaporated (ml.) A With fan 40 10 Downloaded by Aniket Rai (aniketrai20032005@gmail.com) lOMoARcPSD|37895460 B without fan 50 10 Results : The order of evaporation of acetone in two Petri dishes as given With fan > Without Fan.. Conclusion : The rate of evaporation of liquid increases with the increase in rate of flow of air current. BIBLIOGRAPHY www.byjus.com www.arcadiaacademy.ac.in www.slideshare.net https://en.wikipedia.org www.kupdf.com Downloaded by Aniket Rai (aniketrai20032005@gmail.com) lOMoARcPSD|37895460 Downloaded by Aniket Rai (aniketrai20032005@gmail.com)