PLIINTWIDE DYMMIC SIMULATORS IN ClIEMICEIL PROCESSING and CONTROL CHEMICAL INDUSTRIES A Series of Reference Books and Textbooks Consulting Editor HEINZ HEINEMANN 1. Fluid Catalytic Cracking with Zeolite Catalysts, Paul B. Venuto and E. Thomas Habib, Jr. 2. Ethylene: Keystone to the Petrochemical Industry, Ludwig Kniel, Olaf Winter, and Karl Stork 3. 4. 5. 6. The Chemistry and Technology of Petroleum, James G. Speight The Desulfurization of Heavy Oils and Residua, James G. Speight Catalysis of Organic Reactions, edited by William R. Moser Acetylene-Based Chemicals from Coal and Other Natural Resources, Robert J. Tedeschi 7. Chemically Resistant Masonry, Walter Lee Sheppard, Jr. 8. Compressors and Expanders: Selection and Application for the Process Industry, Heinz P. Bloch, Joseph A. Cameron, Frank M. Danowski, Ralph James, Jr., Judson S. Swearingen, and Marilyn E. VVeightman 9. Metering Pumps: Selection and Application, James P. Poynton 10. Hydrocarbons from Methanol, Clarence D. Chang 11. Form Flotation: Theory and Applications, Ann N. Clarke and David J. Wilson 12. The Chemistry and Technology of Coal, James G. Speight 13. Pneumatic and Hydraulic Conveying of Solids, 0. A. Williams 14. Catalyst Manufacture: Laboratory and Commercial Preparations, Alvin B. Stiles 15. Characterization of Heterogeneous Catalysts, Delannay edited by Francis BASIC Programs for Chemical Engineering Design, James H. Weber Catalyst Poisoning. L. Louis Hegedus and Robert W. McCabe Catalysis of Organic Reactions, edited by John R. Kosak Adsorption Technology: A Step-by-Step Approach to Process Evaluation and Application, edited by Frank L. Slejko 20. Deactivation and Poisoning of Catalysts, edited by Jacques Oudar and 16. 17. 18. 19. Henry Wise 21. Catalysis and Surface Science: Developments in Chemicals from Methanol, Hydrotreating of Hydrocarbons, Catalyst Preparation, Monomers and Polymers, Photocatalysis and Photovoltaics, edited by Heinz Heinemann and Gabor A. Somorjai 22. Catalysis of Organic Reactions, edited by Robert L. Augustine 23. Modem Control Techniques for the Processing Industries, T. H. Tsai, J. W. Lane, and C. S. Lin 24. Temperature-Programmed Reduction for Solid Materials Character ization, Alan Jones and Brian McNichol 25. Catalytic Cracking: Catalysts, Chemistry, and Kinetics, Bohdan W. Wojciechowski and Avelino Corma 26. Chemical Reaction and Reactor Engineering, edited by J. J. Carberry and A. Varma 27. Filtration: Principles and Practices, Second Edition, edited by Michael J. Matteson and Clyde Orr 28. Corrosion Mechanisms, edited by Florian Mansfeld 29. Catalysis and Surface Properties of Liquid Metals and Alloys, Yoshisada Ogino 30. Catalyst Deactivation, edited by Eugene E. Petersen and Alexis T. Bell 31. Hydrogen Effects in Catalysis: Fundamentals and Practical Applications, edited by Zoltan Peal and P. G. Menon 32. Flow Management for Engineers and Scientists, Nicholas P. Chere- misinoff and Paul N. Cheremisinoff 33. Catalysis of Organic Reactions, edited by Paul N. Rylander, Harold Greenfield, and Robert L. Augustine 34. Powder and Bulk Solids Handling Processes: Instrumentation and Control, Koichi linoya, Hiroaki Masuda, and Kinnosuke Watanabe 35. Reverse Osmosis Technology: Applications for High-Purity-Water Production, edited by Bipin S. Parekh 36. Shape Selective Catalysis in Industrial Applications, N. Y. Chen, William E. Garwood, and Frank G. Dwyer 37. Alpha Olefins Applications Handbook, edited by George R. Lappin and Joseph L. Sauer 38. Process Modeling and Control in Chemical Industries, edited by Kaddour Najim 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. Clathrate Hydrates of Natural Gases, E. Dendy Sloan, Jr. Catalysis of Organic Reactions, edited by Dale W. Blackburn Fuel Science and Technology Handbook, edited by James G. Speight Octane-Enhancing Zeolitic FCC Catalysts, Julius Scherzer Oxygen in Catalysis, Adam Biefanski and Jerzy Haber The Chemistry and Technology of Petroleum: Second Edition, Revised and Expanded, James G. Speight Industrial Drying Equipment: Selection and Application, C. M. van't Land Novel Production Methods for Ethylene, Light Hydrocarbons, and Aromatics, edited by Lyle F. Albright, Billy L. Crynes, and Siegfried Nowak Catalysis of Organic Reactions, edited by William E. Pascoe Synthetic Lubricants and High-Performance Functional Fluids, edited by Ronald L. Shubkin 49. Acetic Acid and Its Derivatives, edited by Victor H. Agreda and Joseph R. Zoeller 50. Properties and Applications of Perovskite-Type Oxides, edited by L. G. Tejuca and J. L. G. Fierro 51. Computer-Aided Design of Catalysts, edited by E. Robert Becker and Carmo J. Pereira 52. Models for Thermodynamic and Phase Equilibria Calculations, edited by Stanley I. Sandler 53. Catalysis of Organic Reactions, edited by John R. Kosak and Thomas A. Johnson 54. Composition and Analysis of Heavy Petroleum Fractions, Klaus H. Altgelt and Mieczyslaw M. Boduszynski 55. NMR Techniques in Catalysis, edited by Alexis T. Bell and Alexander Pines 56. Upgrading Petroleum Residues and Heavy Oils, Murray R. Gray 57. Methanol Production and Use, edited by Wu-Hsun Cheng and Harold H. Kung 58. Catalytic Hydroprocessing of Petroleum and Distillates, edited by Michael C. Oballah and Stuart S. Shih 59. The Chemistry and Technology of Coal: Second Edition, Revised and Expanded, James G. Speight 60. Lubricant Base Oil and Wax Processing, Avilino Sequeira, Jr. 61. Catalytic Naphtha Reforming: Science and Technology, edited by George J. Antos, Abdullah M. Aitani, and Jose M. Parera 62. Catalysis of Organic Reactions, edited by Mike G. Scams and Michael L. Prunier 63. Catalyst Manufacture, Alvin B. Stiles and Theodore A. Koch 64. Handbook of Grignard Reagents, edited by Gary S. Silverman and Philip E. Rakita 65. Shape Selective Catalysis in Industrial Applications: Second Edition, Revised and Expanded, N. Y. Chen, William E. Garwood, and Francis G. Dwyer 66. Hydrocracking Science and Technology, Julius Scherzer and A. J. Gruia 67. Hydrotreating Technology for Pollution Control: Catalysts, Catalysis, and Processes, edited by Mario L. Occelli and Russell Chianelli 68. Catalysis of Organic Reactions, edited by Russell E. Malz, Jr. 69. Synthesis of Porous Materials: Zeolites, Clays, and Nanostructures, edited by Mario L. Occelli and Henri Kessler 70. Methane and Its Derivatives, Sunggyu Lee 71. Structured Catalysts and Reactors, edited by Andrzej Cybulski and Jacob Moulijn 72. Industrial Gases in Petrochemical Processing, Harold Gunardson 73. Clathrate Hydrates of Natural Gases: Second Edition, Revised and Expanded, E. Dendy Sloan, Jr. 74. Fluid Cracking Catalysts, edited by Mario L. Occelli and Paul O'Connor 75. Catalysis of Organic Reactions, edited by Frank E. Herkes 76. The Chemistry and Technology of Petroleum, Third Edition, Revised and Expanded, James G. Speight 77. Synthetic Lubricants and High-Performance Functional Fluids, Second Edition: Revised and Expanded, Leslie R. Rudnick and Ronald L. Shubkin 78. The Desulfunzation of Heavy Oils and Residua, Second Edition, Revised and Expanded, James G. Speight 79. Reaction Kinetics and Reactor Design: Second Edition, Revised and Expanded, John B. Butt 80. Regulatory Chemicals Handbook, Jennifer M. Spero, Bella Devito, and Louis Theodore 81. Applied Parameter Estimation for Chemical Engineers, Peter Englezos and Nicolas Kalogerakis 82. Catalysis of Organic Reactions, edited by Michael E. Ford 83. The Chemical Process Industries Infrastructure: Function and Economics, James R. Couper, 0. Thomas Beasley, and W. Roy Penney 84. Transport Phenomena Fundamentals, Joel L. Plawsky 85. Petroleum Refining Processes, James G. Speight and Baki Ozurn 86. Health, Safety, and Accident Management in the Chemical Process Industries, Ann Mahe Flynn and Louis Theodore 87. Plantwide Dynamic Simulators in Chemical Processing and Control, William L. Luyben ADDITIONAL VOLUMES IN PREPARATION Lubricant Additives: Chemistry and Applications, edited by Leslie R. Rudnick PIANTWIDE MIMIC SIMOLOTORS IN CHEMICAL PROCESSING and CONTROL William L. Layben Lehigh University Bethlehem, Pennsylvania CRC Press Taylor & Francis Group Boca Raton London New York Marcel Dekker, Inc., and the author make no warranty with regard to the accompanying software, its accuracy, or its suitability for any purpose other than as described in the preface- This software is licensed solely on an "as is" basis. The only warranty made with respect to the accompanying software is that the diskette medium on which the software is recorded is free of defects. Marcel Dekker, Inc., will replace a diskette found to be defective if such defect is not attributable to misuse by the purchaser or his agent. The defective diskette must be returned within 10 days to: Customer Service, Marcel Dekker, Inc., P.O. Box 5005, Cimarron Road, Monticello, NY 12701, (914) 796-1919. ISBN: 0-8247-0801-6 This book is printed on acid-free paper. Headquarters Marcel Dekker, Inc 270 Madison Avenue, New York, NY 1.0016 tel: 212-696-9000; fax: 212-6854540 Eastern Hemisphere Distribution Marcel Dekker AG Hutgasse 4, Postfach 812, CH-4001 Basel, Switzerland tel: 41-61-261-8482; fax: 41-61-261-8896 World Wide Web http.//www.clekker.com The publisher offers discounts on this book when ordered in bulk quantities. For more information, write to Special Sales/Professional Marketing at the headquarters address above. Copyright © 2002 by Marcel Dekker, Inc. All Rights Reserved. Neither this book nor any part may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopying, microfilming, and recording, or by any information storage and retrieval system, without permission in writing from the publisher. Current printing (last digit): 10 9 8 7 6 5 4 3 2 PRINTED IN TIRE UNITED STATES OF AMERICA This book is dedicated to Nathaniel, Trevor and Elizabeth Beatrice (Bops). Their granddad hopes they always do their best and leave the world a little better place than it was when they arrived. Preface Dynamic simulation has been used by chemical engineers for over a half century. The earliest studies used mechanical and electronic analog computers to study dynamic processes such as batch distillation, chemical reactors and feedeffluent heat exchangers. It took many hours to program and set up analog computers, and their maintenance was a never-ending job. The relatively small number of amplifiers limited the number of differential equations that could be used in the model, so only small-scale systems could be studied. A typical distillation column simulation (I00 to 200 ordinary differential equations) required a Iarge-scale and very expensive analog facility. However, despite the costs, most of the chemical and petroleum companies invested in equipment and manpower to operate large and well-staffed computing groups in their engineering research centers. The payoff in improved design and control justified the large expenditures. With the advent of the digital computer in the 1960s, limitations on problem size were relaxed by many orders of magnitude. Systems with thousands of differential equations could be studied. Programming difficulty decreased, but a new set of numerical methods had to be learned and developed as essential tools for successful simulations. The limitation became computing speed. The increases in computer speed over that last 30 years has been phenomenal, to say the least. So we can now tackle quite complex plantwide dynamic simulations. The dynamic models used in the early days were almost always "home grown." The engineer would sit down and write out the equations describing the system (algebraic and differential), using the fundamental laws and principles of physics and chemistry. One of the major benefits of deriving the model was the insight it provided into the behavior and structure of the process. The 1970s and 1980s saw the growth of commercial process simulation software that could analyze the steady-state behavior of chemical processes. Finally in the 1990s, the increase in computer speed permitted the development of commercial dynamic simulators. At the beginning of the new millennium, the current state of simulation reflects the widespread use of commercial simulators in both industry and universities. The most widely used simulators are HYSYSTM from Hyprotech inc. and AspenPlus"mIAspenDynamicsTM from Aspen Technology. Both of these simulators include dynamic analysis capability. The importance of investigating both the dynamic and the steady-state performance of chemical plants has been recognized for many years. This concept of "simultaneous design" was one of the central features of the pioneering work in process control by Page Buckley of Du Pont. In the past, the traditional capstone vi Preface design course in most universities only explored the steady-state aspects of process design. This limited treatment is rapidly giving way to a more comprehensive study of both dynamic controllability and steady-state economics. The steady-state simulation aspects of using commercial software are fairly well covered in textbooks and vendor tutorials. However, the dynamic aspects have received only sketchy coverage. There is no structured way for students and young engineers to learn how to use these commercial dynamic simulation packages to develop and test dynamic plantwide control structures. Learning how to use the dynamic simulators is a somewhat painful and slow process. The number of examples provided in vendor tutorials is small, and the processes are limited in scope. The documentation and help screens can often be unclear and offer little guidance. On-line technical assistance is usually not available to students, so unless a very knowledgeable faculty member or graduate student is available, students can struggle with dynamic simulations. Of course, time is one commodity that senior students have in very short supply. They have limited time to invest in learning the ins and outs of simulators since the typical design project must be completed in only a few months. The purpose of this book is to help students and inexperienced engineers learn how to rapidly and effectively use dynamic simulators. Using dynamic simulators requires more than just knowing the software. It requires the application of some good solid engineering principles. Remember the old saying "garbage in, garbage out!" The engineering steps that are necessary in moving from a steady-state simulation to a dynamic simulation are presented in this book. These include sizing equipment, getting the "plumbing" correct, sizing control valves, developing a basic regulatory control structure and tuning controllers. The development of a plantwide basic regulatory control scheme requires looking at the big picture and recognizing that all the units must "dance together." We must make sure that the structure balances the stoichiometry of the reactions by adjusting the flowrates of the fresh feed streams. Of course inert components must have a way to leave the system so that they do not accumulate and degrade the performance of the process. Once the overall scheme is in place, it is often more efficient to look at the individual units to do the controller tuning since simulations of a single unit run much more quickly than the simulation of the whole plant. The secret to successful simulations is "divide and conquer." Dynamic simulators can handle many of the important unit operations, but not all. However, the Iist of process units whose dynamics can be accurately simulated grows each year. The field is a rapidly changing one, so new capabilities are offered with each new version of the software. A number of case-study examples are provided in this book. They range from a simple single unit with two or three controllers to complex, interconnecting units in a plantwide system with dozens of controllers and a complex control structure. These case studies cover a broad range of systems. The accompanying CD contains the HYSYS and AspenDynamics files of all the cases. It also con- Preface vii tains MS® Word files that give alI the figures in the book. These can be useful in your reading because they are in color and because you can enlarge the figures in order to see more detail. It is hoped that this book will serve as an effective learning tool for students and inexperienced engineers and serve as an introduction to dynamic simulators. The intent is not to develop experts who know all the nitty-gritty details of the simulators and use all the bells and whistles. For example, there are typically three different ways to do a task. We only cover what I have found to be the simplest and most intuitive. There are also many advanced capabilities offered by the simulators, including writing your own models. We do not attempt to cover any of these advanced functionalities. The goal of this book is to provide a solid starting point for inexperienced engineers and to give students a good working knowledge of the basics. I would like to thank Cris Muhrer, Bryon Manor, and Oliver Smith of Air Products for their tutoring in AspenDynamics and AspenPlus. James Goom of AspenTech provided technical help with several aspects of using AspenDynamics. I thank Joe Sieben of Hyprotech for his help in applying UYSYS. Brad Price and Paul Bader of Lehigh University provided invaluable assistance with software and hardware issues. Thanks are also due to the many senior students at Lehigh University who have suffered through the pain of learning dynamic simulators. Their struggles are what have prompted the writing of this book. William L. Luyben Contents Preface Part I — Fundamentals I Chapter 1 — Introduction Chapter 2 — Moving from Steady-State to Dynamic Simulations Chapter 3 — Tuning Controllers 3 9 25 Part II — Single-Unit Dynamic Simulations 39 Chapter 4 — Tank Process Chapter 5 — Blending Process Chapter 6 — CSTR Reactor Process Chapter 7 — Plug-Flow Tubular Reactors Chapter 8 — Distillation Columns Chapter 9 — Heterogeneous Azeotropic Distillation Chapter I0 — Reactive Distillation 41 87 105 125 155 181 199 Part III — Multi-Unit Dynamic Simulations 225 Chapter 1 I — Pressure-Swing Azeotropic Distillation Columns Chapter 12 — Heat-Integrated Distillation Columns Chapter 13 — Tubular Reactor with Gas Recycle Process Chapter 14 — Reactor/Column with Liquid Recycle 227 249 27 I 283 Part IV — Complex Plantwide Processes 301 Chapter 15 — Hydrodealkylation Process Chapter 16 — Alkylation Process Chapter 17 — Ethyl Benzene Process Chapter 18 — Methyl Antilles Process Chapter 19 — Concluding Topics 303 329 357 375 403 index 427 ix PUINTWIDE DYNAMIC SIMULATORS IN CHEMICOL PROCESSING and CONTROL Part 1 Fundamentals Chapter 1 Introduction 1 . 1 Status Dynamic simulation has become increasingly important as processes become more complex and are designed and operated closer to constraints. The use of intermediate buffer tanks has been greatly reduced because of environmental and safety concerns. Increasing yields and suppressing the formation of undesirable and environmentally unfriendly by-products are often achieved by using complex flowsheets with many recycle streams. Increasing energy costs keep pushing design engineers toward more heat integration. All of these trends make dynamic control more difficult and dynamic simulation more important. It is vital that all the unit operations of a complex flowsheet be able to "dance" together in the face of the inevitable disturbances. These include production rate changes, feed composition variability, transitions to different product specifications and rapid ambient temperature changes during storms. Ideally the dynamics of the process should be considered at the very early stages of the development of a process. Certainly at the pilot-plant stage, trade-offs between design and control should be explored, and basic regulatory control structures should be developed and tested. The engineering time expended at the early stages can reap enormous economic benefits later in the project in terms of rapid, trouble-free startups, reduced product-quality variability, less-frequent emergency shutdowns, reduced environmental contamination and safer operation. Fortunately our ability to perform plantwide dynamic simulations has also increased. There are several commercial software packages that have dynamic capability. The two most widely used are "HYSYS" from Hyprotech Inc. and "AspenPlus/AspenDynarnics" from Aspen Technology. These two simulators will be used in this book. Although these simulators are far from perfect (we will highlight some of the weaknesses and "bugs" as we go through this book), they do provide a reasonably effective tool for studying process dynamics. Unfortunately, there are a variety of bugs in each new version of the software, but these are gradually being eliminated. We will only illustrate the development of conventional single-input-singleoutput control structures that use linear proportional-integral (PI) controllers. However, dynamic simulators are needed to test any control structure, whether it is 3 4 Chapter 1 a conventional P1 structure or more advanced control structures such as "Model Predictive Control" (MPC), nonlinear control or adaptive control. The dynamic simulators provide a rigorous nonlinear model of the process, which we hope captures the true behavior of the process. 1.2 Need Learning how to use steady-state simulators is reasonably well covered in several textbooks and vendor tutorials. The recent CD-ROM by Lewin et al. (ISBN: 0-411-44254-2) provides a good introduction to use of steady-state simulators. However, learning how to use dynamic simulators is not covered thoroughly in the existing textbooks. The purpose of this book is to fill this gap in the educational phase of the technology. There are some significant steps that must be taken and vital information that must be available to go from a steady-state simulation to a dynamic simulation. The details of these steps are covered in this book, and they are illustrated by a number of case-study examples. A second need that this book fills is making available a number of case studies. These range from very simple systems to complex flowsheets. The simple systems are useful for learning how to get started in using dynamic simulators. The complex systems are useful in illustrating how to apply the concepts of plantwide control to a realistic process. Control researchers should find these complex case studies useful in providing a challenging process on which to apply their newly developed advanced control methods. 1.3 Scope One effective pedagogical approach to learning how to use dynamic simulators is to start with a very simple dynamic system (for example, a single tank). This simple process has two or three control valves and the same number of controllers. It requires that we learn the basic operations of moving from a steadystate simulation to a dynamic simulation. 1.3.1 Equipment Sizing Sizing equipment is necessary so that the dynamic capacitance of the equipment (tank sizes, column liquid holdups, heat-exchanger volumes, etc.) is available to the simulator. It is not necessary to have all the details of the mechanical design of the equipment. Some good estimates of the gas volumes and liquid holdups in a system are all that are necessary to predict realistic dynamic responses. Introduction 5 Some equipment sizing (for example, distillation columns) is provided by the simulators. But many components are not automatically sized. In this book, we use simple heuristics to set the sizes of surge tanks, separators, column bases, etc. Conceptual equipment sizing is covered in Chapter 2. 1.3.2 Plumbing The dynamic simulators provide two modes of simulation: "flow-driven" and "pressure-driven." The latter type is strongly recommended, especially for students. It is a much more accurate representation of the real process in which hydraulics and fluid mechanics are of vital importance. Pumps, compressors and control valves are important parts of the design. For realistic dynamic simulations, the "plumbing" in the flowsheet must be correctly designed so streams can flow from one unit to the next. This is a major area of weakness of many students (and professors). They learn the theory of fluid mechanics in their undergraduate course, but their plumbing skills are typically poor. For example, students often put a control valve in the suction of a pump or put two control valves in a liquid-filled line. Controlling flow through a compressor cannot be achieved by putting a valve in the discharge line. Compressors are volumetric devices that pump "actual volume per minute" flows at suction conditions. The most realistic approach to controlling flow through a compressor in the simulator is to manipulate work to the compressor. This corresponds to changing compressor speed. A crucial part of the plumbing is control valve sizing. This means setting the percent valve opening and the pressure drop over the valve at steady-state design conditions. Most valves are designed to be 50% open at design conditions. However, valves that must be able to provide significant increases in flow (for example, a valve on the cooling water to the jacket of an exothermic chemical reactor) must be designed to have smaller design openings. The design pressure drop of a valve is one of the classical examples of the ever-present tradeoff between dynamic controllability and steady-state economics. The higher the valve pressure drop, the more the flow through the valve can be changed (improved rangeability). This translates into better control because more "power" is available to handle disturbances and valve saturation is reduced. However, larger valve pressure drops require pumps or compressors with higher discharge pressures, which means higher energy consumption. Since gas compression is much more expensive than liquid pumping, control valves are often eliminated in gas systems by the use of variable-speed compressor drives (typically steam turbines). This plumbing material is of vital practical importance in the design and operation of the real plant, and it should be part of the simulation. This material is covered in Chapter 2. 6 Chapter 1 1.3.3 Installing Controllers and Tuning Once the process equipment is established, controllers and strip-chart recorders must be added to the process flow diagram (PFD) in the simulation. The detailed mechanics of doing this are different in the two simulators. The "dragand-drop" approach is the usual method. Each controller requires several specifications to begin the simulation: 1. Initial values of the signal from the process sensor (the PV signal) and the signal to the control valve (the OP signal) must be made available. This requires establishing the ranges of the sensor/transmitter that is generating the PV signal arid establishing the range of the controller output signal. If the controller output signal is going to a valve, this range is 0 to 100%. Some of the manipulated variables are set directly from the controller (for example, reboiler heat input or coolant ternperature). In that case, the maximum and minimum values of the energy flow or the maximum and minimum coolant temperatures must be specified. 2. The correct "action" of the controller must be specified: direct or reverse. 3. The controller tuning constants must be set. Tuning of level and flow controllers is a "plug-in-the-numbers" operation, which requires no dynamic testing. On the other hand, most temperature and composition loops require dynamic testing (for example, the simple relayfeedback test) to develop controller tuning constants. It is important to use realistic lags and/or deadtimes in the temperature/composition loops so that the predicted performance is not overly optimistic. Using reasonable and conservative measurement lags in the temperature and composition loops helps to guarantee that effective control is possible in a real plant environment, not just on the simulator. Strip-chart recorders are useful in following the dynamic changes oc4. curring in the many variables. The variables to be observed need to be selected, and all the chart properties (axis scales, labels, etc.) must be specified. These issues are covered in Chapter 3. 1.3.4 Case Studies The rest of the book presents a series case studies. The approach is to start with very simple process units that require only two or three controllers. Then units with several controllers are considered. The complexity of the processes is Introduction 7 progressively increased until the flowsheets represent typically complex industrial processes. Each example is developed and discussed in detail. Simulations in both 1-1YSYS and AspenDynamics are given for each example. Chapter 4 studies a simple tank process in which we control liquid level and tank pressure by manipulating the flow of liquid and vapor leaving the tank for disturbances in the flow entering the tank. All the steps of converting from steady state to dynamics are covered in exhaustive detail. Controllers are installed and the simulation is run. Strip-chart recorders are installed so that we can see the dynamic transients in the variables of interest. We also discuss the case in which there is only a liquid stream leaving the tank. Chapter 5 considers another simple tank process in which there are two feed streams of differing compositions that are blended in the tank. In addition to controlling level, we control the composition of the stream leaving the tank by manipulating one of the feed streams. The steps in installing dynamic elements (deadtimes and lags) in the composition loop are illustrated. Controllers are tuned using the relay-feedback test. Performance is evaluated in the face of disturbances. In Chapters 6 and 7 common reactor systems are studied: a continuous stirred-tank reactor (CSTR) and a plug-flow reactor (PFR). The key issues in reactor systems are temperature control and heat transfer. Several alternative heattransfer models are available: direct heat-transfer rate Q, specified coolant temperature or specified coolant flowrate. These alternative models differ in the two simulators. The choice of what model to use is important in achieving realistic dynamic simulations of reaction systems. Unit operations with a larger number of loops are presented in Chapters 8 through 10. Distillation column control is one of the most important areas of process control. Even a simple single-feed, two-product distillation column has six control loops: feed flowrate, pressure, base level, reflux-drum level and two other variables (typically one flow and one temperature on some tray in the column). A conventional distillation example is given in Chapter 8, a heterogeneous azeotropic distillation column is discussed in Chapter 9 and two reactive distillation columns are studied in Chapter 10. Chapters 11 through 14 give examples of somewhat more complex processes with two units connected by recycle streams. Two-column distillation systems are discussed in Chapter 11 (pressure-swing azeotropic distillation) and Chapter 12 (heat-integrated columns). Chapter 13 explores a tubular reactor system with gas recycle, and Chapter 14 studies a similar reactor with a liquid recycle stream coming from a distillation column. In Chapters 15-18 complete multi-unit plantwide process structures are considered. There are several interconnected unit operations with dozens of controllers to be installed and tuned. In addition to having educational content, these cases should be useful to process control researchers by providing some realistically complex processes on which new control approaches can be tested. Chapter 19 wraps up a few loose ends and discusses some advanced methods and hardware issues. 8 Chapter 1 1.4 Software Stability and Bugs Both dynamic simulators are powerful tools and permit us to fairly easily explore the dynamics of chemical processes. They provide reasonably accurate models of a variety of industrially important unit operations. However, they are far from perfect. Sometimes the software crashes for no apparent reason, and error messages such as "The program has performed an illegal operation and will be shut down" are given. This software stability problem seems to improve with each version of the software, but its occurrence is still more frequent than it should be. The user should save the file quite frequently in order to avoid losing information. Software bugs are also more numerous than one would like. Things that should work sometimes do not for no apparent reason. These problems should be reporting to the software companies through their technical support or hot lines. As the software is improved over the next several years, these problems should occur less frequently, and this will make dynamic simulations easier and more reliable. The software used in this book is HYSYS.plant (version 2.4.1, Build 3870) and AspenPIus/AspenDynamics (version 10.2.2). 1.5 Conclusion In this chapter we have set the stage for the remaining chapters. The status of dynamic simulation, the additional information needed and the scope of the book have been discussed. We are ready to dig into the details of dynamic simulations. It should be emphasized that the goal of this book is provide an introduction to the use of commercial dynamic simulators. We do not attempt to provide all the voluminous material to transform the reader into a simulation expert. This requires many months of time and effort. Only the simple basic operations that are needed to get started in dynamic simulation are discussed. The commercial simulators offer many advanced features that can be useful after the engineer learns the basics. We hope this book is helpful in getting you off the ground in the important and fascinating activity of dynamic simulation.