Energy 263 (2023) 125896 Contents lists available at ScienceDirect Energy journal homepage: www.elsevier.com/locate/energy Combined experimental-numerical analysis of hydrogen as a combustion enhancer applied to wankel engine Cheng Shi a, *, Sen Chai a, Liming Di a, Changwei Ji b, **, Yunshan Ge c, Huaiyu Wang c a School of Vehicle and Energy, Yanshan University, Qinhuangdao, 066004, China Department of Automotive Engineering, Key Lab of Regional Air Pollution Control and Beijing Lab of New Energy Vehicles, Beijing University of Technology, Beijing, 100124, China c School of Mechanical Engineering, Beijing Institute of Technology, Beijing, 100081, China b A R T I C L E I N F O A B S T R A C T Keywords: Hydrogen Combustion Wankel engine Numerical simulation Equivalent ratio Hydrogen is regarded as one of the most potential alternatives for high-efficiency and eco-friendly combustion. The influences of hydrogen fractions and equivalence ratios on chamber pressure, combustion phases, wall heat loss, brake thermal efficiency, and cyclic fluctuation of Wankel engines were studied by testbench measurement. The intrinsic mechanisms of these effects were analyzed through numerical investigation. Results indicated that increasing hydrogen fraction increased the mass fraction of high-temperature regions, the timings taken for formations of intermediate products were advanced, and the peak H2O2 and CH2O reduced while OH concen­ tration increased. These factors were responsible for increased chamber pressure and the shortened flame development and propagation periods in experiments. A close inverse relationship can be drawn between the wall heat loss and brake thermal efficiency with respect to hydrogen addition. A larger hydrogen fraction coupled with a smaller equivalence ratio manifested lower wall heat loss and higher thermal efficiency. Compared with hydrogen-free regimes, brake thermal efficiency of 6% hydrogen fraction was increased by 64.6%. There was a positive proportional correspondence between the initial flame development and cycle-to-cycle fluctuation. Increasing the hydrogen content caused the enhanced turbulent intensity during the initial combustion stage, which contributed to the stability improvement of engine operations. 1. Introduction curb weight and fuel consumption of the aircraft significantly. As a clean gaseous fuel that can be used in engines, hydrogen (H2) is an ideal alternative fuel and has been widely used in reciprocating piston engines [4] and rotary piston engines [5]. Unlike other fossil fuels, H2 is a zero-carbon secondary energy source, which contributes to the goal of emission peak and carbon neutrality [6]. H2 has drawn much attention due to its inherent advantages, such as a wide range of sources, fast flame propagation, low ignition energy, and high diffusion coeffi­ cient [7]. Much of the published meaningful work has demonstrated that adding a certain proportion of H2 to liquid fuels like gasoline, ethanol, and butanol is one of the effective ways to enhance thermal efficiency and emissions control of the engine, especially for Wankel rotary en­ gines [8]. Researchers have achieved significant achievements in H2 enrichment Wankel rotary engines [9]. The experiment and simulation results showed that the thermal efficiency, cyclic variation, and fuel consumption could be improved by H2 enrichment [10]. Besides, The Wankel rotary engine has gained extensive attention in aviation due to its simple structure, large power-to-weight ratio, favorable highspeed performance, low vibration and noise, and easy maintenance [1]. At present, rotary engines are primarily used in small-scale low-speed aircraft, such as unmanned aerial vehicles, gliders, powered parafoils, and helicopters [2]. The direct-injection stratified multi-fuel rotary en­ gine developed by Curtiss-Wright Corp. has successfully been placed into small aircraft production. UAV Engines Ltd., an unmanned aerial vehicle manufacturer in the United Kingdom, is well-known for its AR series rotary engines as an alternative unmanned aerial vehicle power source [3]. On the helicopter side, the rotary engine fueled with aviation gas­ oline of the unmanned helicopter S-100 Schiebel Corp. must be mentioned. The power unit for the simple flight from Cessna Ltd. applied rotary engines to the advanced airframe for the first time, reducing the * Corresponding author. ** Corresponding author. E-mail addresses: shicheng@ysu.edu.cn (C. Shi), chwji@bjut.edu.cn (C. Ji). https://doi.org/10.1016/j.energy.2022.125896 Received 13 August 2022; Received in revised form 15 October 2022; Accepted 24 October 2022 Available online 27 October 2022 0360-5442/© 2022 Elsevier Ltd. All rights reserved. C. Shi et al. Energy 263 (2023) 125896 unburned hydrocarbon (HC) and carbon monoxide (CO) emissions decreased, while nitrogen oxide (NOx) emissions increased [11]. This is mainly due to the fact that the H2 is very diffusive, and its dispersion into the medium presents faster than gasoline, which forms a more homo­ geneous mixture in the elongated combustion chamber and increases turbulent flow intensity, thus making it easier to ignite the fuel-air mixture [12]. The faster flame propagation speed of H2 enables the fuel to burn more completely within the rotor chamber of rotary en­ gines, reducing cooling losses, exhaust losses, and the content of incomplete combustion products in the exhaust port. H2 enrichment can shorten the quenching distance of the mixture so that it can be burned in the narrow space, the joint of the gap, and the end of the rotor, decreasing the unburned HC and CO generations caused by the narrow quenching gap [13]. Furthermore, the higher adiabatic flame tempera­ ture of H2 increases the average temperature in the rotor chamber, which is conducive to promoting the combustion rate and flame spread [14]. Extensive studies have pointed out the benefits of lean-burn oper­ ating conditions. Moreover, the H2-enriched fuel-air mixture aids in improving the cyclic variation when the engine is performed in a diluted mixture regime [15]. The reasons why the lean-burn condition enhances the engine’s thermal efficiency by reducing these limitations of stoi­ chiometric combustion are summarized as follows: Firstly, the smaller equivalence ratio enables more fuel-air mixture to be heated through intake charge for minimizing pumping losses and lowering the tem­ perature in the combustion chamber [16]. Secondly, compared with stoichiometric combustion, applying the lean operation leads to low cooling losses and better thermodynamic performance of the combus­ tion products [17]. The latter means a small specific heat capacity, thereby elevating the ratio of specific heat and work-extraction effi­ ciency of the expansion stroke [18]. Thirdly, adopting lean operation to completely burn in the vicinity of TDC because of oxidation of active radicals in the thermal H2-enriched mixture [19]. Fourthly, a leaner mixture can reduce the pressure rise rate by smoothing the reaction rates and thus has the benefit of extending the high-load operating range [20, 21]. The final attractive feature lies in the slow combustion process of the lean-burn mixture, which suppresses excessive heat release, hence reducing the exhaust temperature and NOx generation [22]. To sum up, H2 addition, coupled with the lean mixture, could ensure basic re­ quirements for spark-ignition engines concerning power output, but with the merit of enhancing combustion efficiency and decreasing unwished pollutant formations. Although previous investigations had illustrated significant infor­ mation on the intake H2-enriched lean-burn, these studies were only related to reciprocating piston engines [23]. Moreover, the literature survey implies that perhaps no effort was involved in H2 addition in Wankel engines by a combined experimental-numerical approach. Relevant studies on the correlation between H2 enrichment in spark-ignition rotary engines and different lean-burn operations using equivalence ratios are also unavailable. By adjusting the H2 fraction, it is imperative to optimize the lean-burn regime because of the direct in­ fluence on combustion characteristics and general engine thermody­ namics [24]. Additionally, the experimental measurement is difficult in analyzing flow field variation, initial flame development, combustion proceeding under different H2 concentrations and equivalence ratios, and the intrinsic mechanism of emission generations due to costs and devices. In comparison with engine experiments, the CFD modeling re­ cords transient responses, and it is hard to analyze mixture preparation and combustion behavior in detail [25]. The complete combustion process of spark-ignition gasoline Wankel rotary engines by the coupling function between H2 addition and equivalence ratio remains to be investigated. As stated above, the operation amelioration of hydrogen-enriched rotary engines has special importance. In existing studies, there is no combination investigation for rotary engines at different H2 fractions with equivalence ratios. This is essential for the determination of the operating parameters of rotary engines for UAV propulsions. Especially for hybrid UAVs, in which the rotary engine as a power source can output power continuously at a fixed speed [26]. In summary, based on a rotary engine prototype, the H2 enrichment is varied from the original gasoline rotary engine using a developed H2 injector in the intake port, and operations are performed at different equivalence ratios. A three-dimensional kinetic model of a Wankel engine coupled with the reaction mechanism is developed and calibrated under varying experi­ mental conditions. Based on the combined experimental–numerical investigation, the optimal match between H2 fraction and equivalence ratio is explored to provide theoretical guidance for rotary engines fueled with hydrogen enrichment in this study. 2. Materials and methods 2.1. Experimental setup To meet the experimental requirements, some experimental in­ stallations were used in this work: (1) To monitor the flow of air, Tociel 20N060 thermal flowmeter was employed in the course of this work. (2) To record the mean pressure within the cylinder, the Kistler 6117BFD17 piezoelectric pressure sensor was applied and embedded in the spark plug. The Kibox combustion analyzer was adopted in the experiment testbench to obtain the chamber pressure data. (3) To measure the excess air ratio (λ), a wide-range oxygen sensor and Horiba MEXA-730λ wide-range lambda analyzer were employed. (4) the Horiba MEXA-730λ wide-range lambda analyzer was used under n1/P mode in order to control the engine speed and throttle percentage of rotary engines. The schematic overview and measurement uncertainty of the above in­ stallations are shown in Fig. 1 and Table 1, respectively. As the main component of this experimental system, the engine is selected as a single-cylinder single-spark plug rotary engine, the major specifications of which have been listed in Table 2. Some modifications were made to meet the experimental requirements: (1) A self-developed optimized electronic control unit (ECU) is added to adjust the spark timing and H2 fraction. The optimized ECU intercepts the original en­ gine’s signals, including the spark-ignition signal and the H2-injected signal. Then the optimized ECU outputs the control signals according to the parameters input to the corresponding control software. (2) A H2 supply system, as shown in Fig. 1, was employed to take the place of the traditional gasoline supply system. The H2 purity and injection pressure in this work is 99.99% and 5 bar. (3) Limited by the version of Kibox, the original trigger wheel, which is unsymmetrical 36-2-2-2, can not be recognized. Hence, a trigger wheel with 24–1 gears was added to the center shaft. Besides, a photoelectron magnetic sensor communicating with Kibox was also added to identify the engine speed signals. To understand the role of H2 enrichment in combustion character­ istics of the gasoline Wankel rotary engine, a total of 21 operating points for which intake charged mixture cases with varying H2 enrichment and varying equivalence ratio (Φ) have been carried out in the present work. Seven equivalence ratios of 0.77, 0.80, 0.83, 0.87, 0.91, 0.95, and 1.00 were used, the corresponding excess air ratios were varied from 1.3 to 1.0 in 0.05 paces, respectively. The H2 volumetric fractions of 0%, 3%, and 6% were selected to contrast and clarify the H2 fraction effect. The equivalence ratio and H2 fraction are severally defined as the following equations. Where VH2 and Vair denote the volume of H2 and air sepa­ rately. ρH2 and ρair are the densities of H2 and air. AFst,H2 and AFst, gaso represent the stoichiometric air-to-fuel ratios of H2 and gasoline, respectively. mgaso is the mass flow rate of gasoline. The main operating conditions for the engine test bench are summarized in Table 3. Φ= VH2 ρH2 AFst,H2 + mgaso AFst,gaso Vair ρair αH2 = 2 VH2 × 100% VH2 + Vair (1) (2) C. Shi et al. Energy 263 (2023) 125896 Fig. 1. Schematic overview and actual display of the rotary engine testbench. Table 1 Summary of measurement sensitivities. Table 2 Summary of engine specifications. Parameter Instrument Manufacturer Uncertainty Parameter Value Engine speed Torque Cylinder pressure Gasoline mass flow rate H2 volumetric flow rate Air volumetric flow rate Air-to-fuel ratio CAC6 CAC6 6117BCD17 FC2210 D07-19BM 20N060 MEXA-730λ Power link Power link Kistler Power link Seven star Tociel Horiba ≤±1 rpm ≤±0.4% F⋅S. ≤±0.3 bar ≤0.8% F⋅S ≤±0.02 L/min ≤±0.1 L/min ≤±0.007 Engine type Fuel supplement Generating radius Eccentricity Rotor width Compression ratio Displacement Power output Intake opening Intake closure Exhaust opening Exhaust closure Side-ported, air-cooled Port fuel injection 69 mm 11 mm 40 mm 8:1 0.16 L 3.8 kW@4200 rpm − 465◦ EA ATDC − 209◦ EA ATDC 208◦ EA ATDC 250◦ EA ATDC 2.2. Computational models The CFD simulation is a numerical analysis method. Considering the computational accuracy and time cost, this numerical calculation used a 2 mm basic grid with adaptive encryption as the combustion chamber 3 C. Shi et al. Energy 263 (2023) 125896 Table 3 Summary of engine operating conditions. Parameter Value Engine speed MAP Spark timing Gasoline injection timing Hydrogen injection timing Gasoline injection pressure Hydrogen injection pressure Volumetric coefficient 4500 rpm 0.035 MPa 25◦ EA BTDC 195◦ EA BTDC 195◦ EA BTDC 0.3 MPa 0.3 MPa 0.78 grid size. At the moment of spark plug ignition, the total number of meshes in the working chamber was about 160,000. The calculated mesh model was post-processed using EnSight software to obtain the overall mesh model of the rotary engine with different geometric pro­ files and the local mesh model of rotor chambers, as depicted in Fig. 2. The mesh is automatically encrypted according to the temperature, ve­ locity field, etc. The computation in CONVERGE enhanced powerful features of AMR function (i.e., adaptive mesh refinement), fixed embedding, and acceleration algorithms, such as the Multi-zone source term, which aids in ensuring the computational accuracy and saving the simulation time [27]. Specifically, the Multi-zone model solves detailed chemistry (SAGE) in zones to accelerate the solution of detailed chem­ ical kinetics based on work by Babajimopoulos et al. [28]. In the Multi-zone model, at each discrete time t, every cell in CONVERGE is at some thermodynamic state. The cells are grouped into zones based on the thermodynamic state of the cells. More details of the procedure for grouping into zones are elaborated in Ref. [29]. The summary of the working routine of the current work is described in Fig. 3. Appropriate turbulence models, spray models, ignition models, combustion models, and emission generation models were selected ac­ cording to the engine operating conditions, and the engine was solved numerically to obtain detailed not only microscopic characteristics of the flow field in the working chamber but also effective macroscopic information of the engine operating characteristics. In CONVERGE code, the AMR is based on velocity and temperature used in intake, chamber, and spark regions [30]. The selection of each model is shown in Table 4. The appropriateness of boundary and initial conditions was directly involved in model reliability and calculation precision. In order to describe the specific engine modeling environment and meet the actual operating conditions, this study adopted the full transient processing method to set the boundary conditions and initial conditions of the operating conditions. The boundary and initial conditions are shown in Table 5. As a simplification in this work, the intake charge was assumed perfectly homogeneous, and the fuel thoroughly evaporated during the CFD calculation, and heat transfer with the environment was not taken Fig. 3. Summary of the working routine for numerical simulation. Table 4 Summary of computational models and chemical mechanisms. Description Models and mechanism Turbulence Wall heat transfer Ignition Combustion Reaction kinetics RNG k-ε model [31] Han and Reitz model [32] Spark-energy deposition model [33] SAGE model [34] PRF skeletal mechanism [35] Table 5 Summary of boundary and initial conditions. Region Type Value Air inlet Exhaust outlet Rotor Inlet port Outlet port Stator Spark plug Spark electrode Inflow Outflow Moving wall Fixed wall Fixed wall Fixed wall Fixed wall Fixed wall 0.035 MPa/293 K 0.1 MPa/700 K 550 K 293 K 293 K 550 K 750 K 850 K into account as well [36]. 2.3. Validation In order to verify the accuracy of the CFD model, the hydrogenenriched rotary engine were simulated under different operating con­ ditions. Fig. 4 compares the simulated and measured chamber pressure and heat release rate traces with various operating points, matching the experimental data. Although there are some differences between simu­ lated measured traces, the accuracy of the CFD model meets the re­ quirements of engineering applications. Fig. 2. Computational mesh of the operated rotary engine. 4 C. Shi et al. Energy 263 (2023) 125896 Fig. 4. Model validation for chamber pressure and heat release rates versus eccentric-shaft position. 3. Results and discussion Variation of the equivalence ratio does not affect the trend. For example, Fig. 5(a) illustrates that when the equivalence ratio is 0.8, the peak chamber pressure for αH2 = 0% is 0.89 MPa, while the peak chamber pressure for αH2 = 6% is 1.29 MPa. Their corresponding eccentric-shaft positions are 439.1◦ EA and 395.1◦ EA. At other equivalence ratio con­ ditions, as shown in Fig. 5(a) and (b), the variation tendency in the peak pressure is similar. Besides, as the hydrogen addition is increased, dif­ ferences in peak chamber pressure increase, despite the peak chamber pressure or corresponding eccentric-shaft position. Specifically, the 3.1. Analysis of combustion characteristics Fig. 5 plots the peak chamber pressure and the corresponding eccentric-shaft position under varying H2 fraction and equivalence ratio conditions based on the test bench measurement. As can be observed in Fig. 5, the peak chamber pressure increases, and the corresponding eccentric-shaft position is advanced as the H2 is enriched larger. Fig. 5. Peak chamber pressure and corresponding eccentric-shaft position under varying operating conditions. 5 C. Shi et al. Energy 263 (2023) 125896 pressure difference in the αH2 = 6% condition, 1.01 MPa, is greater than that of the H2-free condition (αH2 = 0%), 0.07 MPa. Fig. 6 shows the flame development period (EA0-10) and flame propagation period (EA10-90) versus the H2 fraction and equivalence ratio for measured rotary engines. As depicted in Fig. 6, the flame development period is slightly prolonged with a small equivalence ratio. It can also be found that the flame development period is significantly shortened with increasing H2 fractions. This phenomenon performs in all operating points of rotary engines. In addition, the flame propagation period reduces with the increment of H2 fractions at a specific equiva­ lence ratio. At a leaner point (0.77), the EA10-90 of (αH2)s = 3%, 6% cases are shortened by 25.5◦ EA and 28.9◦ EA compared with H2-free regimes, respectively. The flame propagation period and the flame development period have a similar trend of being shortened with the increase of the equivalence ratio. This demonstrates that the center of heat release shifts earlier, as seen in Fig. 5(b), and contributes to a rapid combustion process. Apparent is that the effect of the equivalent ratio on the flame development period of H2-free regimes is greater than that of hydrogen-enriched regimes. To further understand the experimental data and clarify the under­ lying mechanism of hydrogen enrichment effect on combustion char­ acteristics in rotary engines under varying equivalence ratio conditions, a three-dimensional comprehensive transient simulation is carried out based on CONVERGE code. The cut in Fig. 7 runs through the median plane of the rotary engine, which reveals the temperature distribution across the rotor chamber for each tested case at TDC. The flame spreads faster as the equivalence ratio is high. At TDC, when the equivalence ratio is 1.00 (stoichiometric operation), the flame has spread towards the leading part of the combustion chamber of the engine. Most of the flames of the other equivalence ratios are still mainly distributed in the vicinity of the spark plug. It is noteworthy to highlight that introducing H2 brings about the burning acceleration and temperature elevation obviously. Thus, a steep temperature difference is anticipated for the main phase of combustion. Subsequently, the combustion temperature in the expansion stroke is the crucial indicator in affecting the com­ bustion characteristics of this engine concept. Compared with the maximum in-cylinder temperature, the maximum mass fraction of the high-temperature domain above the fixed temperature (MMFT) can better reflect the combustion temperature inside the rotary engine [33]. A fixed temperature of 2500 K is used as a criterion for the ongoing research in Fig. 8. One can see that the significant MMFT enhancement happens with the 3% increment of the αH2, which explains the large influence on the chamber pressure and combustion rate. As can be seen in Fig. 8, when the equivalence ratio varies from 0.77 to 1.00, the MMFT exceeds 2500 K acts trend to the temperature distribution at TDC and intensifies the level of thermal atmosphere in the rotor chamber of the engine. Consequently, it is possible to shift the center of the heat release earlier and reduce the period of the combustion process. The underlying mechanism of these trends can also be clarified from a species variance point of view. As crucial points to reflect the ignition event and combustion intensity, several important combustion inter­ mediate products (H2O2, OH, and CH2O) are shown to reveal how H2 addition influences the combustion characteristics of the rotary engine fueled with stoichiometric and lean mixtures as plotted in Fig. 9. From H2-free to H2-enriched operations, the combustion velocity expedites with the increase in temperature in the rotor chamber (Fig. 7), the earlier eccentric-shaft position corresponding to the generation of some crucial intermediates are available, and the peak mass fractions of H2O2 and CH2O reduce whereas the peak value of OH increases. Apparent is the fact that with the increase in combustion temperature inside the engine, less time is taken in the decomposition reaction of H2O2 (M) ⇔ OH + OH (M); hence a large amount of H2O2 is consumed and dissolved in the high-temperature stage, thereafter decreasing the peak concen­ tration of H2O2. Then, at the higher temperature condition, OH is accumulated at a larger level (reflected by the slope of the decline curves of H2O2), and the eccentric-shaft position corresponding to the massive generation of the OH active radical is somewhat advanced. Due to CH2O is being mainly consumed via CH2O + OH ⇔ HCO + H2O, the eccentricshaft position corresponding to the consumption of CH2O shifts earlier at a higher OH concentration, and the peak mass fraction of CH2O de­ creases. Additionally, when the H2 fraction is constant, the peak mass fractions of H2O2, OH, and CH2O drastically reduce under a leaner operating condition. The reason is that the quantity of reactants declines and results in small-scale burning at a lower equivalence ratio tested point, which is attributed to the equivalence ratio effect on the measured data of combustion characteristics of the rotary engine in Figs. 5 and 6. 3.2. Analysis of combustion performance Based on the experiment results of the rotary engine, Fig. 10 shows the variations in the wall heat loss (Qw) and brake thermal efficiency versus the equivalence ratio at different H2 fractions. It is generally accepted that the Qw directly affects the thermal efficiency of the engine. For the determination of the Qw, the heat transfer coefficient adapted for the rotary engine is employed according to Ref. [37]. By adjusting the engine operation to lean-burn conditions, it is bound to cause less Qw than stoichiometric combustion. At a constant H2 content, decreasing the equivalence ratio within the cylinder almost linearly reduces the Qw, as shown in each subfigure of Fig. 10. As for brake thermal efficiency histories with the equivalence ratio, a direct proportional correspon­ dence of the Qw and brake thermal efficiency trend is presented. The difference in brake thermal efficiency at varying equivalence ratio conditions is more distinct under the H2-free condition. When the equivalence ratio changes from 0.77 to 1.00, brake thermal efficiency of αH2 = 6% cases was severally increased by 6.5%, 6.2%, 6.2%, 5.7%, 2.9%, 1.6%, and 1.0% compared with hydrogen-free regimes. However, as the H2 fraction increases, from Fig. 10(a)–(c), a sharp decrease of the Qw is noticeable, whereas the increased tendency is available in brake thermal efficiency. A close inverse correspondence can be obtained be­ tween the Qw and brake thermal efficiency indices provided with respect to H2 addition. It is reasonably considered that the Qw of the engine is generally determined by the heat transfer area, in-cylinder temperature, and duration of high-temperature combustion. Fig. 11 plots the duration of the mass fraction of the high-temperature domain (DMFT) above 2500 K under varying operating conditions by CFD modeling. Taken Fig. 8 together with Fig. 11, it can be confirmed that a higher MMFT and longer DMFT are capable of increasing Qw of the rotary engine for a Fig. 6. Flame development and flame propagation periods under varying operating conditions. 6 C. Shi et al. Energy 263 (2023) 125896 Fig. 7. Temperature distribution at TDC under varying operating conditions. the three mentioned factors in the Qw effect, the dropped heat transfer area outperforms, hence inflicting higher H2 fraction cases with lower Qw . The interpretation of brake thermal efficiency trends is possible by means of analyzing the distributions of unburned fuels and combustion products. Fig. 12 shows the spatial distribution of unburned iso-octane (IC8H18) at EA90 in the investigated rotary engine. Looking at the leading part of the rotor chamber at the end of the burning duration, it is found that this area still distributes unburned IC8H18 under the H2-free regime, which is responsible for worse combustion loss. The reason is that as the equivalence ratio increases, the area of unburned reactants becomes smaller. Particularly, the entire unburned IC8H18 in the leading corner has dissolved completely in the case of stoichiometric operation. This means a better combustion event is obtained if the burning pro­ ceeds to chemical equilibrium. As the combustion event continues, it is intuitively reasonable that brake thermal efficiency is limited by the level of complete combustion products immediately before the moment of the exhaust opening (568◦ EA), typically corresponding to the spatial distribution of CO2, as shown in Fig. 13. Enriching the air/fuel mixture leads to the increase of CO2 formation, as well as the enlargement of the burned area, which is partly because of flow motion. As shown in Fig. 14, more squish flow moves towards the leading side of the rotor chamber at a larger equivalence ratio, implying that compared with the leaner operation, the burned area could reach the leading edge. With regard to the H2 addition effect, increasing the H2 content in the com­ bustion chamber enlarges the spatial distribution of CO2, thus improving the level of complete combustion, which confirms the analysis above. Fig. 8. MMFT value (>2500 K) under varying operating conditions. specific H2 fraction level, which plays an important role in the com­ bustion performance of the rotary engine. But this effect is less pro­ nounced concerning the H2 adjustment. Although the DMFT is slightly prolonged by H2 enrichment, unexpectedly the Qw at a high H2-enriched level is reduced. The reason for this efficiency loss results from the substantially shortened flame development period and flame propaga­ tion period after H2 blending, and fewer amounts of fuel-air mixtures are combusted during the expansion stroke, which results in the dropped heat transfer area [38]. It can be deduced that in the competition among 3.3. Analysis of combustion stability On the basis of engine test-bench measurements, the COVPmax, COVn, 7 C. Shi et al. Energy 263 (2023) 125896 Fig. 9. Combustion intermediate products as a function of eccentric-shaft position. Fig. 10. Wall heat loss and brake thermal efficiency under varying operating conditions. and COVEA10-90 are imposed to assess the cycle-to-cycle fluctuation of the rotary engine, which denotes the coefficients of cycle-to-cycle vari­ ation (COV) of the peak chamber pressure, engine speed, flame propa­ gation period, as plotted in Fig. 15. In general, one can see that the combustion stability is more and more sensitive to engine operations as the equivalence ratio decreases, and rough burning is obtained by diluting the fuel-air mixture leaner. For the case that the equivalence ratio is 0.77, the COVPmax and COVEA10-90 increase significantly compared with a higher equivalence ratio. Of particular interest are the results from the COVn profile for αH2 = 6% cases, and there is a negli­ gible difference in the COVn under varying operating points. When the H2 fraction increases from 0% to 6%, the COVPmax and COVEA10-90 decrease sharply, hence enhancing the burning stability of the rotary engine. In addition, introducing H2 has less influence on the COVPmax, 8 C. Shi et al. Energy 263 (2023) 125896 COVn, and COVEA10-90 at the equivalence ratio of 1.00, but it has an evident effect under lean-burn operations. There is no denying the fact that the early combustion stage has an important effect on the combustion stability of the rotary engine [39]. However, the intrinsic mechanisms between early flame development and combustion stability are still unclear. In order to acquire intuitive information in detail, Fig. 16 gives the growth of the initial flame rep­ resented by the iso-contour of 2000 K (black line in Fig. 7). It is observed that the flame front location for different operating points is similar in the rotor chamber. The flame propagates chiefly in the same direction as the rotor rotation, whereas the flame spread is retarded in the opposite direction. This effect is most likely due to the existence of one-way mainstream characteristics from the trailing to the leading edge of the rotor chamber [40]. As shown in Fig. 16, the increase in the equivalence ratio could lead to the faster formation of the flame kernels, which contributes to a stable combustion initiation and shortened burning duration [41]. In addition, when the H2 fraction is 6%, the flame front has spread across the leading part of the combustion chamber after the spark timing of 20◦ EA (355◦ EA). The majority of the burning sources of remaining cases (0% and 3%) are mainly centralized in the vicinity of Fig. 11. DMFT value (>2500 K) under varying operating conditions. Fig. 12. Unburned iso-octane distribution at EA90 under varying operating conditions. 9 C. Shi et al. Energy 263 (2023) 125896 Fig. 13. CO2 distribution before exhaust opening moment under varying operating conditions. the spark-plug location yet. Although the coincidence of the initial flame growth and combustion stability, an acquisition of the combustion rate almost fails to succeed with observed initial kernels [42]. To evaluate the feature of early flame development, a quantitative analysis is carried out by the burned vol­ ume rise rate (BVRR), which is calculated by the following formula: BVRR = lim ΔEA→0 VEA+ΔEA − VEA ΔEA power stroke. As anticipated, the BVRR increases quickly with H2 addition, as can be inferred from the fact that initial flame development is accelerated, thus improving the combustion stability [43]. In addition to initial flame development, another probable cause is the variation in the flow motion of turbulence, which affects the stability of the rotary engine. For a better insight into the influences of the H2 fraction and equivalence ratio on the turbulent level inside the engine, Fig. 18 shows a high-resolution median cross-section plane of the rotor chamber using turbulent kinetic energy (TKE) and turbulent dissipation (EPS). It is evidently observed from Fig. 18(a) that with a 3% increment of the H2 fraction, the high region of TKE within the rotor chamber in­ creases to a certain degree. At spark timing, the turbulence level is intensified around the spark-plug location with hydrogen additive. In Fig. 18(b), when the H2 fraction augments from 3% to 6%, a higher EPS is concentrated in burning areas at the leading part of the combustion chamber, which contributes to an effective ignition and stable com­ bustion. Despite the minimal effect on TKE distribution in terms of the (3) where VEA is the volume of the burned area through flame propagation at an EA, and △EA is the increment of the EA. Specifically, the volume of the burned area is applied to quantify early flame development as the local volume of the region enclosed by the isothermal of 2000 K. It can be observed from Fig. 17 that fuel-burning speed decreases when the flame propagates towards the lean mixture, which contributes to the reduction of the BVRR. As the proceeding of combustion, the BVRR of the rich-mixture scheme becomes increasingly higher in the stage of the 10 C. Shi et al. Energy 263 (2023) 125896 4. Conclusions This research investigates H2 as a combustion enhancer applied to the gasoline rotary engine for UAV propulsion. The combined effect of H2n enrichment and equivalence ratio on combustion characteristics, thermal efficiency, and cyclic variations of the engine was measured through an engine test bench, and the mechanisms behind experimental data were revealed by CFD simulations. The present work gave a unique insight into the combustion characteristics, performance, and stability of the H2-enriched rotary engine under stoichiometric and lean conditions. The contribution of the present work elaborately addressed the flow phenomenon and combustion process in the rotor chamber. Also, they were compared with existing investigations to dig out the potential of improving combustion characteristics and thermal efficiency of rotary engines for UAV propulsion. Based on the comprehensive analysis, the conclusions available in the present work may be summarized as follows: Fig. 14. Velocity distribution before exhaust opening moment under varying operating conditions. (1) For a specific equivalence ratio, the mass fraction of hightemperature regions increased with the introduction of H2, the timings taken for the formations of intermediate products were notably advanced, and the peak mass fractions of H2O2 and CH2O reduced while the OH concentration increased. These factors contributed to increased chamber pressure and shortened com­ bustion phases in experiments. At a leaner point (0.77), the EA1090 of (αH2)s = 3%, 6% cases were shortened by 25.5◦ EA and 28.9◦ EA compared with H2-free regimes, respectively. (2) A close inverse correlation can be deduced between the wall heat loss and brake thermal efficiency indices provided in terms of H2 equivalence ratio effect, a remarkable difference in EPS can be observed with the variation of the equivalence ratio. According to Fig. 18(b), there is a lower EPS level at a leaner operation, and a high concentration of EPS can be seen on both sides of the rotor chamber. This means that the turbulent flow is not used for the combustion effect of the fuel but has rather been consumed by the friction with the cylinder wall [44], which inevitably aggravates the instability of the engine under the same H2-enriched condition. Fig. 15. COVPmax, COVn, and COVEA10-90 under varying operating conditions. 11 C. Shi et al. Energy 263 (2023) 125896 Fig. 16. Initial flame growth under varying operating conditions. enrichment. Due to the synergistic effects of the heat transfer area, combustion temperature, and the duration of hightemperature combustion, a larger H2 addition with leaner oper­ ation showed lower wall heat loss and higher brake thermal ef­ ficiency. When the equivalence ratio changes from 0.77 to 1.00, brake thermal efficiency of αH2 = 6% cases was severally increased by 6.5%, 6.2%, 6.2%, 5.7%, 2.9%, 1.6%, and 1.0% compared with hydrogen-free regimes. (3) There was a directly proportional correspondence between the initial flame growth and cyclic fluctuations. The increase of the equivalence ratio could lead to the faster formation of the flame kernels, which contributed to a stable combustion initiation and shortened burning duration. (4) Increasing the hydrogen content caused a higher turbulent ki­ netic energy and turbulent dissipation in burning areas around the spark-plug location during the initial combustion stage, which was responsible for the stability improvement of the rotary engine. (5) There is a lower turbulence level at a leaner operation, and a high concentration of turbulent dissipation can be seen on both sides of the rotor chamber. This means that the turbulent flow is not used for the combustion effect of the fuel but has rather been consumed by the friction with the cylinder wall, which inevitably Fig. 17. Burned volume rise rate as a function of eccentric-shaft position. 12 C. Shi et al. Energy 263 (2023) 125896 Fig. 18. TKE and EPS distributions under varying operating conditions. aggravates the instability of the engine at a specific H2-enriched regime. [2] Siadkowska K, Wendeker M, Majczak A, et al. The influence of some synthetic fuels on the performance and emissions in a Wankel engine. SAE Technical Paper 2014. 2014-01-2611. [3] Wang H, Ji C, Shi C, et al. Comparison and evaluation of advanced machine learning methods for performance and emissions prediction of a gasoline Wankel rotary engine. Energy 2022;248:123611. [4] Ma DS, Sun ZY. Progress on the studies about NOx emission in PFI-H2ICE. Int J Hydrogen Energy 2020;45:10580–91. [5] Wang H, Ji C, Su T, et al. Comparison and implementation of machine learning models for predicting the combustion phases of hydrogen-enriched Wankel rotary engines. Fuel 2022;310:122371. [6] Sun ZY, Xu C. Turbulent burning velocity of stoichiometric syngas flames with different hydrogen volumetric fractions upon constant-volume method with multizone model. Int J Hydrogen Energy 2020;45:4969–78. [7] Shi C, Zhang Z, Ji C, et al. Potential improvement in combustion and pollutant emissions of a hydrogen-enriched rotary engine by using novel recess configuration. Chemosphere 2022;299:134491. [8] Wang H, Ji C, Shi C, et al. Modeling and parametric study of the performanceemissions trade-off of a hydrogen Wankel rotary engine. Fuel 2022;318:123662. [9] Ozcanli M, Bas O, Akar MA, et al. Recent studies on hydrogen usage in Wankel SI engine. Int J Hydrogen Energy 2018;43:18037–45. [10] Gong C, Li Z, Yi L, et al. Comparative study on combustion and emissions between methanol port-injection engine and methanol direct-injection engine with H2enriched port-injection under lean-burn conditions. Energy Convers Manag 2019; 200:112096. [11] Gao J, Xing S, Tian G, et al. Numerical simulation on the combustion and NOx emission characteristics of a turbocharged opposed rotary piston engine fuelled with hydrogen under wide open throttle conditions. Fuel 2021;285:119210. [12] Yontar AA. Effects of ethanol, methyl tert-butyl ether and gasoline-hydrogen blend on performance parameters and HC emission at Wankel engine. Biofuels 2020;11: 377–88. [13] Shi C, Zhang P, Ji C, et al. Understanding the role of turbulence-induced blade configuration in improving combustion process for hydrogen-enriched rotary engine. Fuel 2022;319:123807. [14] Amrouche F, Erickson P, Park J, et al. Extending the lean operation limit of a gasoline Wankel rotary engine using hydrogen enrichment. Int J Hydrogen Energy 2016;41:14261–71. [15] Gong C, Li Z, Yi L, et al. Research on the performance of a hydrogen/methanol dual-injection assisted spark-ignition engine using late-injection strategy for methanol. Fuel 2020;260:116403. [16] Jung D, Iida N. An investigation of multiple spark discharge using multi-coil ignition system for improving thermal efficiency of lean SI engine operation. Appl Energy 2018;212:322–32. [17] Wang Z, Liu H, Reitz RD. Knocking combustion in spark-ignition engines. Prog Energy Combust Sci 2017;61:78–112. [18] Dale J, Checkel M, Smy P. Application of high energy ignition systems to engines. Prog Energy Combust Sci 1997;23:379–98. Author contribution Cheng Shi: Conceptualization, Data curation, Investigation, Meth­ odology, Software, Validation, Visualization, Writing – original draft, Writing – review & editing, Sen Chai: Investigation, Writing – review & editing, Liming Di: Formal analysis, Project administration, Changwei Ji: Funding acquisition, Project administration, Software, Yunshan Ge: Resources, Supervision, Huaiyu Wang: Investigation, Methodology. Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. Data availability Data will be made available on request. Acknowledgments This work was financially supported by the Fundamental Research Funds for the Central Universities, CHD (Grant No. 300102222512), National Natural Science Foundation of China (Grant No. 51976003), Natural Science Foundation of Hebei Province (Grant No. E2020203127), and Cultivation Project for Basic Research and Innova­ tion of Yanshan University (Grant No. 2021LGQN011). References [1] Fan B, Pan J, Yang W, et al. Combined effect of injection timing and injection angle on mixture formation and combustion process in a direct injection (DI) natural gas rotary engine. Energy 2017;128:519–30. 13 C. Shi et al. Energy 263 (2023) 125896 [32] Han Z, Reitz RD. A temperature wall function formulation for variable-density turbulent flows with application to engine convective heat transfer modeling. Int J Heat Mass Tran 1997;40:613–25. [33] Yang X, Solomon A, Kuo TW. Ignition and combustion simulations of spray-guided SIDI engine using Arrhenius combustion with spark-energy deposition model. SAE Technical Paper 2012. 2012-01-0147. [34] Senecal PK, Pomraning E, Richards KJ, et al. Multi-dimensional modeling of directinjection diesel spray liquid length and flame lift-off length using CFD and parallel detailed chemistry. SAE Technical Paper 2003. 2003-01-1043. [35] Liu Y, Jia M, Xie M, et al. Enhancement on a skeletal kinetic model for primary reference fuel oxidation by using a semidecoupling methodology. Energy Fuels 2012;26:7069–83. [36] Zambalov SD, Yakovlev IA, Skripnyak VA. Numerical simulation of hydrogen combustion process in rotary engine with laser ignition system. Int J Hydrogen Energy 2017;42:17251–9. [37] Wang W, Zuo Z, Liu J. Miniaturization limitations of rotary internal combustion engines. Energy Convers Manag 2016;112:101–14. [38] Wang S, Ji C, Zhang B, et al. Effect of CO2 dilution on combustion and emissions characteristics of the hydrogen-enriched gasoline engine. Energy 2016;96:118–26. [39] Kravos A, Seljak T, Oprešnik SR, et al. Operational stability of a spark ignition engine fuelled by low H2 content synthesis gas: thermodynamic analysis of combustion and pollutants formation. Fuel 2020;261:116457. [40] Shi C, Ji C, Ge Y, et al. Numerical study on ignition amelioration of a hydrogenenriched Wankel engine under lean-burn condition. Appl Energy 2019;255: 113800. [41] Spreitzer J, Zahradnik F, Geringer B. Implementation of a rotary engine (Wankel engine) in a CFD simulation tool with special emphasis on combustion and flow phenomena. SAE Technical Paper 2015. 2015–01-0382. [42] Chen W, Pan J, Liu Y, et al. Numerical investigation of direct injection stratified charge combustion in a natural gas-diesel rotary engine. Appl Energy 2019; 233–234:453–67. [43] Tartakovsky L, Baibikov V, Gutman M, et al. Simulation of Wankel engine performance using commercial software for piston engines. SAE Technical Paper 2012:2012–32. 0098. [44] Shi X, Qian W, Wang H, et al. Development and verification of a reduced dimethoxymethane/n-heptane/toluene kinetic mechanism and modelling for CI engines. Appl Therm Eng 2022;214:118855. [19] Gao J, Tian G, Ma C, et al. Numerical investigations of combustion and emissions characteristics of a novel small scale opposed rotary piston engine fuelled with hydrogen at wide open throttle and stoichiometric conditions. Energy Convers Manag 2020;221:113178. [20] Liu H, Zheng Z, Yao M, et al. Influence of temperature and mixture stratification on HCCI combustion using chemiluminescence images and CFD analysis. Appl Therm Eng 2012;33–34:135–43. [21] Tang Q, Liu H, Li M, et al. Study on ignition and flame development in gasoline partially premixed combustion using multiple optical diagnostics. Combust Flame 2017;177:98–108. [22] Amrouche F, Erickson PA, Park JW, et al. Extending the lean operation limit of a gasoline Wankel rotary engine using hydrogen enrichment. Int J Hydrogen Energy 2016;41:4261–71. [23] Sun ZY. Laminar explosion properties of syngas. Combust Sci Technol 2020;192: 166–81. [24] Zhou J, Richard S, Mounaïm-Rousselle C, et al. Effects of controlling oxygen concentration on the performance, emission and combustion characteristics in a downsized SI engine. SAE Technical Paper 2013. 2013-24-0056. [25] Fan B, Zeng Y, Zhang Y, et al. Research on the hydrogen injection strategy of a direct injection natural gas/hydrogen rotary engine considering apex seal leakage. Int J Hydrogen Energy 2021;46:9234–51. [26] Donateo T, Ficarella A, De Pascalis CL. Energy management-based design of a Wankel hybrid-electric UAV. Aircraft Eng Aero Technol 2020;92:701–15. [27] Shi C, Ji C, Ge Y, et al. Parametric analysis of hydrogen two-stage direct-injection on combustion characteristics, knock propensity, and emissions formation in a rotary engine. Fuel 2021;287:119418. [28] Babajimopoulos A, Assanis DN, Flowers DL, et al. A fully coupled computational fluid dynamics and multi-zone model with detailed chemical kinetics for the simulation of premixed charge compression ignition engines. Int J Engine Res 2005;6(5):497–512. [29] Convergent Science Corp. CONVERGE theory manual. 2014. [30] Shi C, Ji C, Wang S, et al. Combined influence of hydrogen direct-injection pressure and nozzle diameter on lean combustion in a spark-ignited rotary engine. Energy Convers Manag 2019;195:1124–37. [31] Wang H, Ji C, Yang J, et al. Towards a comprehensive optimization of the intake characteristics for side ported Wankel rotary engines by coupling machine learning with genetic algorithm. Energy 2022;261:125334. 14