Transport Phenomena II: Heat and Mass Transport CENG 3220, HKUST, Fall 2023 3. Differential Equations of Heat Transfer Yoonseob Kim yoonseobkim@ust.hk http://yoonseobkim.com/ Y. Kim | 1 Problem – composite The outside walls of a house are constructed of a 4-in. layer of brick, 1/2 in. of celotex, an air space 3 and 5/8 in. thick, and 1/4 in. of wood paneling. If the outside surface of the brick is at 30 ºF and the inner surface of the paneling at 75 ºF, what is the heat flux if a. the air space is assumed to transfer heat by conduction only? b. the equivalent conductance of the air space is 1.8 Btu/h ft ºF? c. the air space is filled with glass wool? ππππππ = 0.38 Btu/hftβ ππππππ‘ππ₯ = 0.028 Btu/hftβ ππππ = 0.015 Btu/hftβ ππ€πππ = 0.12 Btu/hftβ πππππ π π€πππ = 0.025 Btu/hftβ Y. Kim | 2 Problem solving skills 1. Identify the “Knowns” 2. Identify “To find” 3. Draw “Schematic”, if not given 4. Set appropriate “Assumptions” 5. “Analysis” Set your governing equation Find the conditions (either initial or boundary) Be careful about unit conversion Y. Kim | 3 Solution – composite π1 = ππ ; π2 = ππ π 1 = π π ; π 2 = π ππππ π ; π 3 = π πππ ; π 4 = π ππππ π ; π 5 = π π ; βπ π= σπ ππ₯ = πβ − ππ πΏ 1 πΏ1 πΏ 1 ( + + 2 + 3 + ) ββ π΄ π1 π΄ π2 π΄ π3 π΄ βπ π΄ Y. Kim | 4 Solution – composite a. the air space is assumed to transfer heat by conduction only? π 75 − 30 45 = = π΄ ( 1/3 + 1/24 + 29/96 + 1/48 ) (0.875 + 1.49 + 20.14 + 0.174) 0.38 0.028 0.015 0.12 Btu = 1.98 h ft2 **beware the unit conversion, from inch to feet ππππππ = 0.38 Btu/hftβ ππππππ‘ππ₯ = 0.028 Btu/hftβ ππππ = 0.015 Btu/hftβ ππ€πππ = 0.12 Btu/hftβ πππππ π π€πππ = 0.025 Btu/hftβ Y. Kim | 5 Solution – composite b. the equivalent conductance of the air space is 1.8 Btu/h ft ºF? π πππ βπ₯ 29/96 = = = 0.167 π 1.8 ΰ· π = 0.875 + 1.49 + 0.167 + 0.174 = 2.706 π 45 = = 16.63 π΅π‘π’/βππ‘2 π΄ 2.706 Y. Kim | 6 Solution – composite c. the air space is filled with glass wool? π ππππ π π€πππ = 29/96 = 12.1 0.025 ΰ· π = 14.64 π 45 = = 3.07π΅π‘π’/βππ‘2 π΄ 14.64 Y. Kim | 7 So we want to know heat transfer. The amount of heat transfer. It is very easy when the temperature information is given. π = −π∇π π΄ Then we only need the heat equations. What if, the numbers – temperature, are not given??? Y. Kim | 8 Goal of this chapter We now generate the fundamental heat equations, so, energy equations, then temperature profiles, for a differential control volume from a first-law-of thermodynamics approach. Y. Kim | 9 Our approach to the problems 1. Conservation – heat → Temperature profile 2. Appropriate assumptions – 1D, S-S, etc… 3. Balancing equations 4. Heat (Fourier’s) equations – governing equations 1. Find solutions – Some math. 1st ODE, 2nd ODE 2. Apply B.C.s 3. Complete the solutions 5. Plotting, if necessary. **The same for mass: Concentration profile then mass (Fick’s) equation Y. Kim | 10 Balancing energy/mass equation General balance equation: In – Out + Generation – Consumption = Accumulation For a system that does not do the “work” (consume): In – Out + Generation = Accumulation For a system without a chemical reaction: In – Out = Accumulation Y. Kim | 11 Steady-State and Unsteady-State Steady-state and unsteady-state processes describe the time interval that a process occurs over. Steady-state refers to the time where the variable of interest doesn't change. Unsteady-state is when the variable of interest changes over time. Note: Transience is used interchangeably with unsteady-state. Properties Steady-state Unsteady-state Time Y. Kim | 12 Law of Energy Conservation “The change of energy in a system as a function of time is equal to the amount of energy which enters the system minus the amount of energy which leaves the system.” ΔU = Q – W Y. Kim | 13 Conservation of Energy Q – W = ΔU πππ‘π ππ πππππ‘πππ πππ‘π ππ π€πππ ππππ ππ βπππ‘ π‘π ππππ‘πππ − ππ¦ ππππ‘πππ π£πππ’ππ Figure. A differential control volume π£πππ’ππ ππππ ππ‘π ππ ππ‘π π π’ππππ’ππππππ π π’ππππ’ππππππ πππ‘π ππ ππππππ¦ ππ’π‘ πππ‘π ππ ππππππ¦ πππ‘π πππ‘π ππ ππππ‘πππ π£πππ’ππ = ππππ‘πππ π£πππ’ππ ππ’π − + ππππ’ππ’πππ‘πππ ππ π‘π πππ’ππ ππππ€ ππ’π π‘π πππ’ππ ππππ€ ππππππ¦ πΏπ πΏππ πΏππ π π − − =ΰΆ΅ π+ π(v. n)ππ΄ + ΰΆΈ ππππ ππ‘ ππ‘ ππ‘ π ππ‘ π.π . π.π£. Heat generation Energy transfer Energy accumulation Work rate Viscous work rate Y. Kim | 14 General differential equations for energy transfer Conservation of energy πΏπ πΏππ πΏππ π π − − =ΰΆ΅ π+ π(v. n)ππ΄ + ΰΆΈ ππππ ππ‘ ππ‘ ππ‘ π ππ‘ π.π . π.π£. Heat generation Energy transfer Work rate Energy accumulation Viscous work rate Figure. A differential control volume Heat generation (1) **We have the Fourier’s law here. π:αΆ volumetric rate of thermal energy generation having units W/m3 Y. Kim | 15 Work rate The shaft work rate or power term will be taken as zero for our present purposes. This term is specifically related to work done by some effect within the control volume that, for the differential case, is not present. The power term is thus evaluated as: (2) πΏππ =0 ππ‘ Viscous work rate The viscous work rate, occurring at the control surface, is formally evaluated by integrating the dot product of the viscous stress and the velocity over the control surface. As this operation is tedious, we shall express the viscous work rate as Λ βπ₯ βπ¦ βπ§, where Λ is the viscous work rate per unit volume. Therefore, (3) πΏππ = Λ βπ₯ βπ¦ βπ§, ππ‘ Y. Kim | 16 Energy transfer The surface integral includes all energy transfer across the control surface due to fluid flow. All terms associated with the surface integral have been defined previously. The surface integral is π π+ π(π―. π§)ππ΄ π ΰΆ΅ π.π . = ππ£π₯ + ππ£π¦ + ππ£π§ π£2 π + ππ¦ + π’ + ΰΈ 2 π π£2 π + ππ¦ + π’ + ΰΈ 2 π − ππ£π₯ π₯+βπ₯ − ππ£π¦ π¦+βπ¦ π£2 π + ππ¦ + π’ + ΰΈ 2 π − ππ£π§ π§+βπ§ π£2 π + ππ¦ + π’ + ΰΈ 2 π βπ¦βπ§ π₯ π£2 π + ππ¦ + π’ + ΰΈ 2 π π£2 π + ππ¦ + π’ + ΰΈ 2 π (4) βπ₯βπ§ π¦ βπ₯βπ¦ π§ *Specific total energy, e, can include the kinetic, potential, and internal energy contributions, π£2 π = + ππ¦ + π’ 2 See Ch 6. Conservation of Energy: Control-Volume Approach, for more information. Y. Kim | 17 Energy accumulation The energy accumulation term, relating the variation in total energy within the control volume as a function of time, is π π π£2 ΰΆΈ ππππ = + ππ¦ + π’ πβπ₯ βπ¦ βπ§ ππ‘ π.π£. ππ‘ 2 (5) Y. Kim | 18 Conservation of energy πΏπ πΏππ πΏππ π π − − =ΰΆ΅ π+ π(v. n)ππ΄ + ΰΆΈ ππππ ππ‘ ππ‘ ππ‘ π ππ‘ π.π . π.π£. Combine equations (1) through (5). Performing this combination and dividing throughout by the volume of the element, we have Y. Kim | 19 Evaluated in the limit as βπ₯, βπ¦ and βπ§ approach zero, this equation becomes General Equation After expansion, rearrangement, and introducing Substantial derivative; Y. Kim | 20 With Continuity equation: π΅ ⋅ πv + ππ ππ‘ =0 Equation* π·v And an equation π π·π = ππ − π΅π + ππ΅π v, valid for incompressible flow of a fluid with constant π, the second term on the right-hand side of the above equation* becomes Also, for incompressible flow, the first term on the right-hand side of equation* becomes Substitution of the two equation into equation * results in, Y. Kim | 21 The previous equation further reduces to The function may be expressed in terms of the viscous portion of the normal- and shear-stress terms in equations from Fluid transport. For the case of incompressible flow, it is written as Finally, the energy equation becomes is a function of fluid viscosity and shear-strain rates, and is positivedefinite. The effect of viscous dissipation is always to increase internal energy at the expense of potential energy or stagnation pressure. Y. Kim | 22 General conservation law. The 1st law of thermodynamics: Q – W = ΔU Conservation law for a differential control volume: πΏπ πΏππ πΏππ π π − − =ΰΆ΅ π+ π(v. n)ππ΄ + ΰΆΈ ππππ ππ‘ ππ‘ ππ‘ π ππ‘ π.π£. π.π . Simplified energy equation for us to use: Y. Kim | 23 Special forms of the differential energy equations The applicable forms of the energy equation for some commonly encountered situations follow. In every case, the dissipation term is considered negligibly small. π:αΆ volumetric rate of thermal energy generation (W/m3) **In this course, we study cases under certain conditions that we can get analytical solutions. Y. Kim | 24 Special forms of the differential energy equations I. For an incompressible fluid without energy sources and with constant π π·π πππ£ = ππ΅2 π (6) π·π‘ II. For isobaric flow without energy sources and with constant π, π·π πππ£ = ππ΅2 π (7) π·π‘ Y. Kim | 25 Special forms of the differential energy equations III. In a situation where there is no fluid motion, all heat transfer is by conduction. If this situation exists, as it most certainly does in solids where ππ£ β ππ , the energy equation becomes: (8) π·π πππ = ∇ β π∇π + παΆ π·π‘ This equation applies in general to heat conduction. Y. Kim | 26 Special forms of the differential energy equations If the thermal conductivity is constant, the energy equation is ππ παΆ 2 = πΌπ΅ π + ππ‘ πππ (9) cp and cv: Specific heat at constant pressure and constant volume, respectively. π has been symbolised as πΌ and is designated as thermal diffusivity. πππ πΌ has dimension of πΏ2 /π‘ (π2 /π or ππ‘ 2 /β) Y. Kim | 27 General heat conduction equation with constant k: ππ παΆ = πΌπ΅2 π + ππ‘ πππ (9) β’ If the conducting medium contains no heat sources, this equation reduces to Fourier field equation; ππ (10) = πΌπ΅2 π ππ‘ β’ For a system in which heat sources present but there is no time variation (meaning the steady-state), the equation reduces to the Poisson equation παΆ 2 π΅ π+ =0 π (11) β’ The final form of the heat-conduction equation to be presented applies to a steady-state situation without heat sources. For this case, the temperature distribution must satisfy the Laplace equation π΅2 π = 0 **Remember, πΌ= π πππ (12) Y. Kim | 28 Each of equations (9) through (12) has been written in general form, thus each applies to any orthogonal coordinate system. Writing the Laplacian operator, π2 , in the appropriate form will accomplish the transformation to the desired coordinate system. The Eq (10) ππ can be written as = πΌπ΅2 π ππ‘ In cartesian coordinates; ππ π2π π2π π2π =πΌ + + ππ‘ ππ₯ 2 ππ¦ 2 ππ§ 2 In cylindrical coordinates; ππ π 2 π 1 ππ 1 π 2 π π 2 π =πΌ + + 2 2+ 2 2 ππ‘ ππ π ππ π ππ ππ§ In spherical coordinates; 2π ππ 1 π ππ 1 π ππ 1 π =πΌ 2 π2 + 2 sin π + 2 2 ππ‘ π ππ ππ π sin π ππ ππ π sin π ππ 2 **For Laplacian operator, see Appendix B Y. Kim | 29 Summary so far, π − π = π₯π First law of thermodynamics Conservation of energy, for a controlled volume πΏπ πΏππ πΏππ π π − − =ΰΆ΅ π+ π(v. n)ππ΄ + ΰΆΈ ππππ ππ‘ ππ‘ ππ‘ π ππ‘ π.π . π.π£. Energy equation, for a controlled volume • No heat source, no dissipation, and constant k ππ ππ‘ = πΌπ΅2 π (Fourier field equation) • Heat sources, no time variation (steady-state), no dissipation, and constant k π΅2 π παΆ π + = 0 (Poisson equation) • Steady-state, no heat sources, no dissipation, and constant k π΅2 π = 0 (Laplace equation) Y. Kim | 30 Energy equation • Temperature is our interest, because T is heat/energy. • T (dimension, time) → for 1D → T (x, t) • With steady-state assumption, T (x) • Temperature profile over x-direction can be obtained • For unsteady-state, T (x, t) • We keep both ∇2T and DT/Dt. Y. Kim | 31 Energy equation For a practical point, the above equation gives us an equation for a temperature profile. OK. But then why do we care? Because, the above equation, the temperature profile, can be applied into the Fourier equations to get the heat rate or flux. π = −π∇π π΄ **What about convection and radiation? Y. Kim | 32 1. Conservation – heat → Temperature profile 2. Appropriate assumptions – 1D, S-S, etc… 3. Balancing equations For example, rate of energy rate of energy rate of energy out conduction into + generation within − conduction out the element of the element the element rate of accumulation of = energy within the element 3.1. Conduction equations – governing equations 1. 2. 3. Find solutions – Some math. 1st ODE, 2nd ODE Apply B.C.s Complete the solutions 3.2. Other mechanisms can be combined 4. Plotting, if necessary. **The same for mass: Concentration profile then mass (Fick’s) equation Y. Kim | 33 Commonly encountered boundary conditions **Important for problem solving In solving one of the differential equations developed thus far, the existing physical situation will dictate the appropriate initial or boundary conditions, or both, which the final solutions must satisfy. Initial conditions refer specifically to the values of T and v at the start of the time interval of interest. Initial conditions may be as simply specified as stating that π»Θπ=π = π»π (a constant), or more complex if the temperature distribution at the start of time measurement is some function of the space variables. Y. Kim | 34 Boundary conditions refer to the values of T and v existing at specific positions on the boundaries of a system, that is, for given values of the significant space variables. Frequently encountered boundary conditions for temperature are the case of isothermal boundaries, along which the temperature is constant, and insulated boundaries, across which no heat conduction occurs, where according to the Fourier rate equation, the temperature derivative normal to the boundary is zero. Y. Kim | 35 Boundary conditions at the interface One situation often existing at a solid boundary is the equality between heat transfer (flux) to the surface by conduction and that leaving the surface by convection. This condition is illustrated in right Figure. **What assumptions are used here? At the left-hand surface, the boundary condition is: ππ ββ πβ − πα = −π α€ ππ₯ π₯=π π₯=π At the right-hand surface: βπ π α π₯=πΏ − ππ ππ = −π α€ ππ₯ π₯=πΏ Y. Kim | 36 Problem – Cylindrical coordinate 1. The Fourier field equation (conduction mechanism without heat source) in cylindrical coordinates is ππ ππ‘ =πΌ π2 π ππ 2 1 ππ + π ππ 1 π2 π + 2 2 π ππ − π2 π ππ§ 2 (r, θ, z) **Remember, • No heat source, no dissipation, and constant k ππ ππ‘ = πΌπ΅2 π (Fourier field equation) a. What form does this equation reduce to for the case of steady-state, radial heat transfer? b. Given the boundary conditions, obtain T profile. π = ππ at π = ππ π = ππ at π = ππ c. Generate an expression for the heat flow rate, ππ , using the result from part b. Y. Kim | 37 Solution – Cylindrical coordinate a. In cylindrical coordinates: ππ π 2 π 1 ππ 1 π 2 π π 2 π =πΌ + + − ππ‘ ππ 2 π ππ π 2 ππ 2 ππ§ 2 π 2 π 1 ππ 1π ππ + = 0 or π =0 2 ππ π ππ π ππ ππ b. From above equation we get: ππ π = πΆ1 ππ πΆ1 ππ = ππ π On integration π = πΆ1 πππ + πΆ2 Using Boundary Conditions: π΅πΆ1. π = ππ at π = ππ π΅πΆ2. π = ππ at π = ππ ππ = πΆ1 ππππ + πΆ2 ππ = πΆ1 ππππ + πΆ2 ππ − ππ πΆ1 = − ππ ππ /ππ πΆ2 = ππ − πΆ1 ππππ π ππ π = ππ − ππ − ππ π ππ π ππ ππ Y. Kim | 38 Solution – Cylindrical coordinate π ππ ππ π = ππ − ππ − ππ ππ ππ ππ c. We know that ππ ππ ππ = −ππ΄ = −π 2πππΏ ππ ππ = −π 2ππΏ πΆ1 2πππΏ = ππ ππ − ππ ln ππ (r, θ, z) We had T profile as below: π = πΆ1 πππ + πΆ2 We also obtained C1 as below ππ − ππ πΆ1 = − ππ ππ /ππ Y. Kim | 39 Problem – Cylinder with heat generation Heat is generated in a cylindrical fuel rod in a nuclear reactor according to the relationship where παΆ is the volumetric heat generation rate, kW/m3, and ro is the outside cylinder radius. Develop the equation that expresses the temperature difference between the rod center line and its surface. Y. Kim | 40 Solution – Cylinder with heat generation **Remember, • Heat sources, no time variation (steadystate), no dissipation, and constant k παΆ π π΅2 π + = 0 (Poisson equation) ro How does the three dimensions in a cylinder work? Poisson equation reduces to 2 **Note the change from partial derivative to the total derivative Y. Kim | 41 Solution – Cylinder with heat generation **Useful tips for problem solving. 1. Assume the nuclear reactor constantly generate heat. 2. Symmetry condition: ro 0 Y. Kim | 42 Solution – Cylinder with heat generation 0 π0 π0 ππππ₯ αΆ π π3 ΰΆ± ππ + ΰΆ± − 2 ππ = 0 π 2 4π0 ππ 0 **To will be a function of r, we can plot it. Y. Kim | 43 Problem – Sphere with heat generation Heat is generated in a spherical fuel element according to the relationship 3 π παΆ = παΆ πππ₯ 1 − ππ where παΆ is the volumetric heat generation rate, kW/m3 and ππ is the radius of the sphere. Develop the equation that expresses the temperature difference between the centre of the sphere and its surface. Y. Kim | 44 Solution – Sphere with heat generation **Remember, • Heat sources, no time variation (steady-state), no dissipation, and constant k παΆ π How does the three dimensions in a sphere work? π΅2 π + = 0 (Poisson equation) Heat generation in a sphere : Fourier field equation reduces to: 1 π ππ παΆ πππ₯ π 2 π + 1 − π2 ππ ππ π ππ 3 =0 First integration yields: π2 ππ παΆ πππ₯ π 3 π6 + − = πΆ1 ππ π 3 6ππ3 πΆ1 = 0 due to symmetry. dT/dr=0 @ r=0 ππ παΆ πππ₯ π 3 π6 2 π + − =0 ππ π 3 6ππ3 **The symmetry condition is useful for cylindrical and spherical systems. Y. Kim | 45 Solution – Sphere with heat generation **Remember, • Heat sources, no time variation (steady-state), no dissipation, and constant k παΆ π How does the three dimensions in a sphere work? π΅2 π + = 0 (Poisson equation) Second integration yields: ππ παΆ πππ₯ ππ π π4 ΰΆ± ππ + ΰΆ± − 3 ππ = 0 π 0 3 6ππ ππ παΆ πππ₯ 2 2 ππ − ππ = π π 15 π Y. Kim | 46 Problem – convection and radiation A 1-in.-thick steel plate measuring 10 in. in diameter is heated from below by a hot plate, its upper surface exposed to air at 80 °F. The heat-transfer coefficient on the upper surface is 5 Btu/h ft2 °F and k for steel is 25 Btu/h ft °F: a. How much heat must be supplied to the lower surface of the steel if its upper surface remains at 160 °F? (Include radiation.) b. What are the relative amounts of energy dissipated from the upper surface of the steel by convection and radiation? Tair = 80 °F; h = 5 Btu/h ft2 °F Tupper = 160 °F; k = 25 Btu/h ft °F Y. Kim | 47 Solution – convection and radiation π = ββπ π΄ q: rate of convective heat transfer (Watts or Btu/h), A: area normal to the heat flow (m2 or ft2) h: convective heat transfer coefficient (W/m2·K or Btu/h·ft2·°F) βT: temperature difference between the surface and the fluid (K or °F) Convection: π = ππ 4 π΄ T is the absolute temperature, in K or °R; and π is the Stefan–Boltzmann constant, which is equal to 5.676 x10–8 W/m2·K4 or 0.1714 X 10-8 Btu/h·ft2·°R4 ** conversion T (°R) = T (°F) + 459.67 Radiation : A, 80 B, 61.2 and 38.3 percent by convection and radiation, respectively. Y. Kim | 48