WELCOME TO CHEMISTRY INTRODUCTION Name : Mr. Gwishiri Contact : 0774 364 029 Course Code : 6031 Sections : 4 sections Topics to be covered : 24 topics Period : 4 terms ZIMSEC final examination consists of four papers Paper Sections & number of questions 1 Number of questions to be answered / Type of paper Questions are from the following / Duration Paper total marks Weighing A&B / 30:10 total Answer all / multiple 40 choice Core syllabus / 1hr 40 16 2 6 Answer all / structured Core syllabus / 1hr 30mins 60 24 3 A,B,C&D / 3:2:3:2 total 10 2-A, 1-B, 2-C & 1-D total 6/ free response Core syllabus / 2hrs 30mins 90 40 4 3 Answer all / practical Quantitative, qualitative analysis & design / 2hrs 30mins 50 20 Expectations ATTEND ALL THE LESSONS. To have 3 counter books 1 for notes, 1 for tests and 1 for practicals. Would rather prefer it if you have them with large number of pages especially Notes. This is to your advantage during revision. To have 2 exercise books 1 for exercises and the other for home work. Revisit the topics covered during the day/week/month/term and year. To work together as a group, the person next to you is now your brother/sister ‘You don’t leave a brother/sister behind’. To work extra hard, because chemistry as well as A level requires your whole attention. The above expectations will distinguish between an A and an O student. CHEMISTRY TERMINOLOGY AND MEANINGS 1 Define … means give the precise meaning of a word, phrase, or physical quantity. Example: Define the term isotopes. [1] Answer: Isotopes are atoms of the same element, with different numbers of neutrons 2 What do you understand by/What is meant by … is similar to Define. Example: What do you understand by the term cracking? [2] Answer: Cracking is the process in which molecules with long carbon chains are broken into more useful molecules with shorter chains. It always gives at least one product with a carbon-carbon double bond. 3 State … means give a specific name, value, or other brief answer without explanation or calculation. State and Name are very similar instructions. Example: State the chemical name for quicklime. [1] Answer: Calcium oxide 4 List … means give a sequence of names or other brief answers with no explanation. If the question asks for three points, give only three. Example: List three physical properties that metals tend to share. [3] Answer: Good conductors of electricity; malleable; high melting points. 5 Explain … means give a detailed account of causes, reasons, or mechanisms. Example: Explain why chlorine is added to water at water treatment works. [1] Answer: It kills bacteria, so it makes the water safer to drink. 6 Describe … means give a detailed account. If you are asked to describe a process, you could set the steps out as numbered points. You could include a diagram if that is appropriate. Example: Desribe how dry crystals of copper(II) sulfate could be obtained from an aqueous solution of copper(II) sulfate. [4] Answer: The crystals could be obtained by these steps: 1 Heat the solution to evaporate some of the water. 2 Leave the solution to cool. Crystals form. 3 Filter off the crystals and pour a little distilled water over them in the funnel, to rinse them... 4 Use filter paper to pat the crystals dry. 7 Describe and explain … means give a detailed account, including causes, reasons, or mechanisms. Example: Describe and explain the colour change, when orange bromine water is shaken with ethene gas. [2] Answer: The orange colour disappears. This is because the bromine molecules add on to the ethene molecules at the double bond, giving the colourless liquid 1,2dibromoethane. (Note: you could also explain here by drawing out the structural formulae.) 8 Outline … means give a brief account or summary. Example: Barium sulfate is an insoluble salt. Outline the preparation of pure, dry barium sulfate, starting from solid barium chloride. [4] Answer: These are the steps: 1 Prepare a solution of barium chloride. 2 Add a solution of a soluble sulfate, such as magnesium sulfate. A precipitate of barium sulfate forms. 3 Filter off the precipitate, and rinse it in the filter paper, using distilled water. 4 Dry it in a warm oven. 9 Predict … means suggest an answer, based on other pieces of information. If your answer is a number, you could write roughly, or about before the number. Example: The element caesium is two places below potassium in Group I of the Periodic Table. Using what you know about potassium, predict one physical and one chemical property of caesium. [2] Answer: Physical property: very soft metal. Chemical property: reacts explosively with water, giving an alkaline solution of caesium hydroxide. 10 Deduce … means to reach a conclusion from the information given. You should include a sentence to support your answer where you explain your reasoning, or refer to a principle or law that you have learnt. Example: The formulae for the first three members of the alkene family are: C2H4 C3H6 C4H8. Deduce the formulae for the next two members. [2] Answer: C5H10 and C6H12 (general formula for alkenes is CnH2n) 11 Suggest … means propose a hypothesis or other possible answer. You may have to use your general knowledge and apply it to a new situation. Example: Suggest a suitable method for obtaining sodium from sodium chloride. Answer: Electrolysis of the molten compound will give sodium at the cathode. 12 Calculate … find a numerical answer, showing the relevant stages in your working (unless you are instructed not to do so). The question will provide the data you need to complete the calculation. Example: Calculate the relative formula mass for ammonium nitrate, NH4NO3. The Ar values are: N = 14, H = 1, O = 16. Answer: 80 13 Find … means ‘work out’. You usually have to do a calculation. Example: Find the % of silicon by mass, in silicon dioxide, SiO2. The Ar values are: Si = 28, O = 16. [1] Answer: 46.7% (Mr for SiO2 pt = 28 + 2 x 16 = 60; the % which is silicon = 28/60 × 100 = 46.7%) 14 Determine … It usually means you have to do a calculation, by substituting known values into a formula. Example: 6 g of carbon reacts completely with 16 g of oxygen to give 22 g of carbon dioxide. Determine the masses of carbon and oxygen needed to give 55 g of carbon dioxide. Answer: 15 g of carbon and 48 g of oxygen (55/22 × 6 = 15, 55/22 × 16 = 40) 15 Estimate … find an approximate value for an unknown quantity. You may need to do a calculation. You should use the term about, approximately, or roughly, in your answer. Example The carboxylic acids form a homologous series. This table gives data for four of them. acid formula boiling point /°C methanoic HCOOH 101 ethanoic CH3COOH 118 butanoic C3H7COOH 164 pentanoic C4H9COOH 187 16 Sketch … means draw freehand. Your sketch can be quite rough, but make sure you show the key points correctly. Example: Excess hydrochloric acid is added to small lumps of calcium carbonate in a flask. Carbon dioxide bubbles off. The flask is weighed at intervals. Curve X below shows the results. On the same axes, sketch the curves obtained if the experiment is repeated: a) a more concentrated solution of acid. label this curve y. b) larger lumps of calcium carbonate, of the same mass. Label this curve Z. [2] Answer: Note that: - the curves all start at zero - the final loss of mass is the same each time - each curve gets less steep as the reaction proceeds - Y has the steepest slope, and Z the least steep, overall. 17 Discuss means give a critical account of the points involved in the topic. Example: Discuss the importance of adding a catalyst to a reaction. Answer: A catalyst speeds up the rate of a reaction which means it saves time, it is also retrieved after the reaction and that means it can be reused several times thus a catalyst is economical. 18 Comment is intended as an open-ended instruction, inviting candidates to recall or infer points of interest relevant to the context of the question, taking account of the number of marks available Example: Comment on the reactivity of phenol and nitrobenzene. [1] Answer: Phenol is more reactive than nitrobenzene because OH is an activating group and NO2 is deactivating. 19 Construct is often used in relation to chemical equations where a candidate is expected to write a balanced equation, not factual recall but by analogy or by using information in the question. Example: Ethanol can be oxidized to ethanoic acid by several oxidizing agents. Construct a half equation for the oxidation of ethanol. [2] Answer: CH3CH2OH + H2O → CH3COOH + 4H+ +4e20 Compare requires candidates to provide both the similarities and differences between things or concepts. Example: Compare the basicity of phenylamine and 1 butyl amine. Answer: 1butyl amine is more basic because the alkyl group (butyl) has positive inductive effect which makes the lone pair of electrons more available for dative bonding hence its more basic. 21 Classify requires candidates to group things based on common characteristics. Example: Classify the following organic compounds; 2 methyl butan2ol and ethanol Answer: 2 methyl butan2ol – tertiary alcohol and ethanol – primary alcohol