Quiz 1 Q1 Choose the correct answer: 1) When the system A + B ⇄ C + D is at equilibrium: a) The sum of the concentrations of A and B must equal the sum of the concentrations of C and D. b) The forward reaction has stopped. c) Both the forward and the reverse reactions have stopped. d) The concentrations of the reactants and products are not changed 2) Henri in industry century, Châtelier’s would an have on N2(g) + a) There ammonia. b) More formed. c) It would ammonia. d) The less. 3) Le Châtelier studied equilibrium reactions in the late 19th According to Le principle, what effect increase in pressure the yield of ammonia at equilibrium? 3H2(g) = 2NH3(g) would be a greater yield of hydrogen and nitrogen are have no effect on the yield of yield of ammonia would be Consider the following equilibrium reaction which one of the following will cause a yellow color to predominate? a) Addition of sodium hydroxide (NaOH) b) Addition of hydrochloric acid (HCl) c) Removal of water d) Addition of sodium chromate (Na2CrO4) 4) Ammonia is formed in the Haber process according to the following balanced equation N2 + 3H2 ⇋ 2NH3+ Heat The table shows the percentages of ammonia present at equilibrium under different conditions of temperature T and pressure P when hydrogen and nitrogen gases were mixed in a 3:1 molar ratio. From the table, what conditions of temperature and pressure will give the highest yield of ammonia. a) 100 atm. and 573 K b) 1000 atm. and 573 K c) 1000 atm. and 773 K d) 10 atm. and 573 K 5) The reaction between hydrogen (H2) and nitrogen (N2) is described by the equation N2 + 3H2 ⇋ 2NH3 + Heat what will be the effect of increasing the concentration of ammonia (NH3)? a) The temperature increases b) More ammonia (NH3) is formed c) Less nitrogen (N2) is formed d) More hydrogen (H2) is formed 6) When a chemical reaction has reached chemical equilibrium: a) The products are forming faster than they are being converted back into reactants. b) The reactants are forming products while the products are forming reactants by the same rate c) There are no longer any reactants left. d) The reactants are no longer reacting. 7) When cobalt (II) chloride is added to water, the following equilibrium is set up , with the red color predominant. On adding dilute HCl, the color changes to blue. Why does this happen? a) Addition of chloride ions shifts the equilibrium to the left. b) More Cl ions were formed. c) Because water changes the color of the system to blue. d) The equilibrium shifted to the right. 8) Put these steps in the correct order to describe the creation of a dynamic equilibrium: a) T, P, R, S, Q b) T, P, S, R, Q c) P, T, S, R, Q d) P, T, R, S, Q e) T, P, S, Q, R 9) What does “dynamic” mean in the term dynamic equilibrium? a. The reaction is very exothermic b. The forward reaction and the backward reaction are still happening at equal rates. c. The yield of product per second is very high. d. The rate of reaction in both directions is very high. Reaction with dil.H2SO4 10) (A)(aq) Fe 700oc (B)(s) (C)(s) Reduction at 4000cCompounds A, B and C respectively represents: a) FeSO4 , Fe3O4 , FeO b) FeSO4 , Fe2O3 , FeO c) Fe2(SO4)3 , Fe2O3 , Fe3O4 d) Fe2(SO4)3 , Fe3O4 , Fe2O3 11) Which of the following statements regarding chemical equilibrium is false? a) At equilibrium, there is no change in the system apparently. b) At equilibrium, the concentrations of reactants and products stay the same c) At equilibrium, the forward and backward reactions cease to occur d) At equilibrium, the rates of forward and backward reactions are identical 12) In the following reaction: 2SO2(g) + O2(g)⇄2SO3(g) (In closed container) Which of the following graphs represents the relation between concentration and time? Products Reactants Reactants Products 13) What is the representation of a reversible reaction? a) single arrow b) double arrows c) bar d) none of above 14) Which of the statements regarding the effect of reactant or product concentration changes on equilibrium is false? a) Adding a reactant always shifts a reversible reaction in the direction of reactants. b) Removing a reactant always shifts a reversible reaction in the direction of reactants. c) Adding a product causes a reversible reaction to shift in the direction of the formation of the reactants. d) Removing a product shifts a reversible reaction in the direction of formation of products 15) Mixture is heated with Dil. HCl and the lead acetate paper turns black by the evolved gases, the mixture contains: a) sulphite b) sulphide c) sulphate d) thiosulphate 16) In the following reaction: 2Na3PO4(aq) + 3BaCl2(aq) Ba3(PO4)2(S) +6NaCl(aq) Which of the following graphs represents the relation between concentration and time? Products Reactants Reactants Products 17) The reaction of carbon monoxide and iodine pentoxide as represented by the equation Heat + 5 CO (g) + I2O5 (g) ⇄ I2 (g) + 5 CO2 (g). Carbon dioxide concentration could be increased by a) Increasing the pressure. b) Decreasing the pressure. c) Increasing the temperature. d) Decreasing the temperature. 18) The opposite chemical reaction is ………….. 2Cu (NO3)2 = 2CUO (s) + 4NO2(g) + O2(g) a. Complete b. Incomplete c. Irreversible d. Both (a) and (c) are correct 19) The opposite graphical figure represents the reaction of ammonia preparation from hydrogen and nitrogen elements: Number (1) represents: a) H2 b) NH3 c) N2 20) The opposite graphical figure represents the reaction of ammonia preparation from hydrogen and nitrogen elements: Number (2) represents: a) H2 b) NH3 c) N2 21) The opposite graphical figure represents the reaction of ammonia preparation from hydrogen and nitrogen elements: Does line (x) represents the equilibrium point: a) True b) False 22) In the following reaction: N2 (g) + O2 (g) ⇄ 2NO (g) On adding N2, the concentration of O2: a) Increases b) Decreases c) Remains unchanged 23) The reaction of iron with dil. hydrochloric acid is complete because ……………. a) It occurs at high temperature b) It occurs at high pressure c) Chlorine gas evolves d) Hydrogen gas evolves Mention wither the following statement is true or false: 24) At equilibrium, the concentrations of reactants and products will be equal a. True b. False 25) Using phenolphthalein to prove that the reaction between acetic acid and ethyl alcohol is reversible reaction is Useless a. True b. False Quiz 2 Q1 Choose the correct answer: 1) Element (24X) has electronic configuration: a. [Ar] 4s2 3d4 b. [Ar] 4s1 3d5 c. [Ar] 4s2 3d6 d. [Ar] 4s1 3d10 2) For the equation reaction 2HCl(aq) + H2O(l) + a. CaCO3 b. CaCO3 c. CaCO3 d.CaCO3 reaction shown in the below the fastest will occur between ... CaCO3(s) CaCl2(aq) + CO2(g) chips and 1M HCl powder and 1 M HCl powder and 2 M HCl chips and 2 M HCl 3) Increasing the concentration increases the speed of reaction by …………. a. Lowering activation energy b. Increasing collisions c. Speeding up the reactants d. Exposing more products 4) A lump of ignited charcoal which is glowing in air burns more vigorously when lowered into a bottle of pure oxygen. This is due to an increase in a. Surface area b. Temperature c. Concentration d. Volume 5) The mass of washing soda crystals before heating is 5 g and after strong heating at A constant temperature, the mass is 1.853g . What is the% of crystallization of water of washing soda? a.15% b. 62.9% c. 37% d. 50% 6) Products will form faster if …………………. a. the particle size of the reactants are larger b. Temperature is decreased. c. Concentration of the reactants are increased. d. Concentrations of products increases. 7) …………….. can be used in food safety technology which designed to eliminate disease causing germs from foods. a. Cobalt b. Scandium c. Cobalt 60 d. Zinc 8) The equilibrium constant for the reaction, 2 SO2 (g) + O2 (g) ⇄ 2 SO3 (g), is: a. { 2 [SO2] + [O2] } / 2 [SO3] b. { [SO2]2 x [O2] } / [SO3]2 c. 2 [SO3] / { 2 [SO2] + [O2] } d. [SO3]2/ { [SO2]2 x [O2] } 9) The conventional equilibrium constant expression (Kc) for the system below is: 2ICl(s) ⇄ I2(s) + Cl2(g) a. [I2][Cl2]/[ICl]2 b. [I2][Cl2]/2[ICl] c. [Cl2] d. [I2][Cl2] 10) Consider the following reversible reaction. In a 3.00 liter container, the following amounts are found in equilibrium at 400 oC: 0.0420 mole N2, 0.516 mole H2 and 0.0357 mole NH3. Evaluate Kc:0 N2 (g) + 3H2(g) ⇄ 2NH3(g) a. 0.202 b. 1.99 c. 16.0 d. 4.94 11) The following numbers represents HCl with different concentrations which acid would react faster with Magnesium? a. 0.1m b. 0.4m c. 1m d. 2m 12) In the reaction: 2KClO3(s) ⇄ 2KCl(s) + 3O2(g) Kc =27 The concentration of oxygen in this reaction equals ……………. (The reaction takes place in a closed vessel) b. 20 M c. 0.002 M d. 3 M a. 27 M 13) 2HBr (g) ⇄ H2 (g) + Br2 (v) Kc = 7.7x10-11 at 500k The predominant direction is …………….. direction. a. Forward b. Backward 14) In the following reaction: SnO2(s) + 2CO (g) ⇄ Sn(s) +2CO2(g) Using the concentrations given in the table below, the value (Kc) for the reaction equals SnO2 CO Sn CO2 0.5 mol/L 0.3 mol/L Mol/l 0.5 Mol/L a. 5.5x10-3 b. 2.77x10-3 c. 2.78 d. 5.7 15) You have 4 glass beakers, at each of them 2 cm of magnesium strip reacted with 200 ml of hydrochloric acid under the conditions in each beaker, which beaker has the highest reaction rate? a. Beaker a b. Beaker b c. Beaker c d.Beaker d 16) The relation that express the equilibrium constant for the reaction between sodium chloride solution and silver nitratre solution is ……………………… a. [��������3][��������] [��������][����������] b. [����������] [��������][����������] c. [����������][��������] d. [��������] [��������] [��������][����������] 17) In the balanced chemical reaction:PCl5 (g) ⇄ PCl3 (g) + Cl2 (g) ∆ H= (+) The dissociation of phosphorous pentachloride can increases by …………. a. Decreasing temperature b. Decreasing pressure c. The addition of excess chlorine d. Withdrawal of phosphorous pentachloride 18) 1 mole in an and of N2O4 (g) was placed empty 1L container allowed to reach equilibrium, to the following equation:N2O4 (g) ⇄ equilibrium, X mole had dissociated, value of the equilibrium Kc at the temperature of the experiment? according 2NO2 (g) At of N2O4 (g) what is the constant a.2�� (1−��) b. 2�� (1−��)2 c. 4��2 (1−��)2 d. 19) The constant Kc depends on: a. Temperature b. Concentrations of product c. Concentrations of product d. Pressure 4��2 (1−��) value of the equilibrium 20) The element which has the electronic configuration [Xe] 4f145d106s1is considered …………………. a. Paramagnetic in its atomic state b. Paramagnetic in oxidation state +2 c. Diamagnetic in its atomic state d. Both (b) and (c) are correct 21) On dissolving each of ………………….. In water, a colored solutions are formed. a. TiO2, FeCl3 b. FeCl2, CoCl2 c.ZnCl2, NiCl2 d.ScCl3 , ZnSO4 22) the reaction between Silver nitrate and sodium chloride takes time T1 while the reaction between plant oil and caustic soda takes time T2 then, ……………………… a. T1 = T2 b. T1>T2 c. T2>T1 Q2) Mention wither the following statement is true or false: 1) The value of equilibrium constant decreases to half by increasing the concentration at the same temperature. a. True b. False 2) On adding iron, III chloride solutions to ammonium thiocyanate solution the color of the reaction becomes blood red and on adding excess of ammonium chloride the intensity of the blood red color decreases a. True b. False 3) It is preferable to use nickel block instead of divided nickel in oil hydrogenation. a. True b. False Q1 Choose the correct answer: Quiz 3 1) Which of the following graphical figures represents the relation between Kc of exothermic reaction and temperature? a b c d 2) In the following reaction the rate of decomposition ……………………………. if we bring a flask filled with sulphur trioxide and placing it in cooling mixture. SO3 (g) ⇄ SO2 (g) + ����O2 (g) ΔH = (-ve) a) Increases b) Decreases c) Does not change 3) The following reaction has two equilibrium constants at two different temperatures. H2 (g) + I2 (g)⇄2HI(g) KC = 67 at 8500c H2 (g) + I2 (g) ⇄2HI(g) KC = 50 at 4480c The previous reaction is ……………………….. as ………………….. a) Endothermic, The value of Kc decreases as the temperature increases b) Exothermic, The value of Kc decreases as the temperature increases c) Endothermic, the value of Kc decreases as the temperature decreases d) Exothermic, the value of Kc decreases as the temperature decreases 4) …………… when burns in hot air , it produces carbon dioxide gas which reacts with the excess of coke producing carbon monoxide gas which acts as reducing agent for the iron oxide in …………….. Furnace. a) Coke , Midrex b) Coke , Blast c) Carbon monoxide , blast d) Carbon monoxide , midrex 5) Which of the following statements regarding the use of catalysts is false? a) Catalysts lower the activation energy for a reaction b) Catalysts decreases the proportion of molecules that possess sufficient energy to clear the activation energy barrier c) A Catalyst remains unchanged after the chemical reaction d) A catalyst increases the rate of both the forward & backward reaction equally 6) To get iron oxide which contain the most stable oxidation state of iron : a) Heating oxalate in of air b) Reaction ammonium of the iron III ammonium the product Reduction 7) On the reaction, iron II absence iron II chloride with hydroxide then heating product c) Reacting chloride with hydroxide then heating above 2000c d) of magnetite heating following the equilibrium constant value ……… N2 (g) + O2 (g) + heat ⇄2NO (g) a) Increases b) Decreases c) Remains constant 8) Which of the following figures represents the reaction rate on a adding a catalyst to a reversible reaction at the time t1? a b c d 9) Which of the following graphs represent the relation between Kp of a gaseous equilibrium reaction and the external; pressure applied to it at constant temperate? abcd 10) Consider the following reaction: 2H2O2(aq) → 2H2O(l) + O2(g) When 1.0 g of KI is added to the H2O2 , bubbles of O2 are produced at an increased rate. When the reaction is complete, the mass of KI is 1.0 g The KI is a a) Product. b) Catalyst c) Reactant. 11) Which activated graph shows the relationship between molecules and temperature? a bcd 12) Which of the following reactions when heated the value of KC increases? a) N2O4 + 59kj ⇄ 2NO2(g) b) 2H2(g) + O2(g) ⇄2H2O(l) + 572kj c) 2BrCl(g) – 29.3kj ⇄ Br2(g) + Cl2(g) d) C(s) + O2(g) ⇄2CO(g) H = - 394 kj 13) Which of the following would react most rapidly? a) Powdered Zn in 1.0 M HCl at 25° C b) Powdered Zn in 2.0 M HCl at 40° c) A lump of Zn in 2.0 M HCl at 25° C d) A lump of Zn in 1.0 M HCl at 40° C 14) In the equilibrium reaction: H2(g) + CO2(g)⇄CO(g) + H2O(v) H = +41kj What happen on heating the reaction with keeping the container volume constant? a) [CO] increase and KP value does not change b) [CO] increase and KP value increases c) [CO2] increases and KP value decreases d) [CO2] increases and KP value does not change 15) In the equilibrium reaction: [N2] can be increased by ……………….. a) Decreasing the amount of N2H4 b) Increasing the amount oh H2 c) Raising the temperature d) Reducing the pressure N2H4(g) ⇄ N2(g) + 2H2(g) + Heat 16) The percentage of Fe3O4 in magnetite, knowing that by treating 0.5 g of the ore in a certain is 55.8 , O a) 30% b) 70% c) 44.9% d) 80% way, 0.362 g of Fe2O3 precipitated. [Fe = =16] 17) According to the following diagram, and C are ………… a) Fe2O3 , b) Fe2O3 , FeO, Fe3O4 c) FeO , Fe3O4 , Fe2O3 d) Fe3O4 , Fe2O3 , FeO compounds A , B ….. , ……… and respectively FeO , Fe2O3 18) According to the following reaction: 2H2O(l) + energy ⇄ H3O+ OH-(aq) On decreasing the temperature the value of Kc ……………. a) Increases b) Decreases c) Remains unchanged 19) The time taken for the reaction to reach equilibrium equals ……… seconds. a) 1 b) 3 c) 4 d) 6 20) The partial pressure of oxygen gas in this equilibrium reaction: N2(g) + 2O2(g) ⇄ 2NO2(g) Kp= 40 Knowing that the partial pressures of nitrogen and nitrogen dioxide gases are 0.05 and 0.1 atm. respectively equals ………… a) 0.4 atm. b) 0.07 atm. c) 0.01 atm. d) 0.104 atm. 21) In the equilibrium reaction: 2H2O (v) ⇄ 2H2 (g) + O2 (g) at 5000c If the partial pressure of H2, O2 and water vapor are 3.66x10-8, 1.83x10-8 and 25.35 atm. respectively, the equilibrium constant KP equal a) 3.815x10-26 b) 0.104 c) 0.056 d) 1.5x10-3 Mention wither the following statement is true or false: 1) Water gas role in the midrex furnace differs from its role in (Fisher-Tropsch) method. a) True b) False 2) Collision theory states that all collisions lead to chemical reactions. a) True b) False 3) We can distinguish between dil. sulphuric acid and conc. Sulphuric acid using iron and acidified potassium dichromate solution. a) True b) False 4) Milk will go sour in a couple of days when left at room temperature, yet it can reaming unspoiled for 2 weeks when refrigerated. a) True b) False Quiz 4 1) Q1 Choose the correct answer: 1) The following relationship [OH-]= √����������can be used to determine the concentration of hydroxide ion for the solution of ……………………. a) NaOH b) NH3+ c) KOH d) Mg(OH)2 2) concentration for [H+] ions = concentration of the acid in the case of: a) H2CO3 b) CH3COOH c) HNO3 d) HCN 3) Which of the following represents the ionization of HCl: s f 100% n o o r i e d b n u v m a c n u s a) i o n e l s e t o e f l m r n i a R m a u s n e l e u v c i e t l a l o e m R HCl H+ Cl Before ionization 100% l o e d HCl e b f n o o r i e d b n m a u s 50% b) c) 25% 25% s n e l e v i u c t e a l l o e R s f o r e b m u n e v i t a l e d R n n o a i m HCl H+ Cl s e l 100% 100% u c e l o m HCl H+ Cl 4) Which of the graphical figures does represents the relation between [OH - ], [H3O+] in aqueous solution at 25oc? 5) For CH3COOH the correct graph is: Ka Ka Ka α a) α Ka b) α c) d)α 6) Electronic configuration of a transition element Z in +3 oxidation state is [Ar] 3d 5, element Z is used ............... a) In galvanization of other metals b) As a catalyst in Haber-Bosch method c) In dental implants d) Used in food preserving process 7) A liter of CH3COOH solution, we can increase its electrical conductivity by ……….. a) Dissolving the same mass of the solute in half liter b) Adding more solute to this liter c) Dissolving the same mass of the solute in 2 liters d) Both (b) and (c) are correct 8) On diluting of sulphuric acid solution , the strength of the illumination of the lamb connected to it ……….. a) Increases b) Decrease c) Remains constant 9) Which of the following aqueous solution will be the best conductor of electricity? (The concentration of all solutions equal 1 molar dissolved in the same amount of water) a) NH3 b) CH3COOH c) HCl d) C6H12O6 10) Ostwald’s dilution law is applicable on …………….. a) HCl b) CH3COOH c) KOH d) H2SO4 11) Which one of the elements with the following outer orbital configurations may exhibit the largest number of oxidations? a) 3d5 4s1 b) 3d54s2 c) 3d24s2 d) 3d34s2 12) Which of the following elements does not show variable oxidation state? a) Copper b) Iron c) Zinc d) Titanium 13) Which one of the following the lowest electric conductivity? a) 1 molar of HCl solution of HCl dissolved in benzene b) 1 molar of HCl solution dissolved in water c) 0.001 molar of acetic acid dissolved in water d) 0.01 molar of acetic acid dissolved in water 14) Which one of the following solutions have the highest electrical conductivity? a) 1 molar of HCl solution of HCl dissolved in benzene b) 1 molar of HCl solution dissolved in water dissolved in water d) 0.01 molar of acetic acid dissolved in benzene c) 0.001 molar of acetic acid 15) The [OH-] ion concentration of 0.1 M ammonium hydroxide solution. Knowing that its ionization constant = 1.8x10-5 a) 2.87 M b) 1.34 x10-3 M c) 2.04 x 10-6 M d) 3.08 x 10-10 M 16) Which in water? a) Ti3+ b) V3+ c) Cu3+ d) Sc3+ of the following is colorless 17) a) Pressure b) Volume c) Dilution d) None of Ionization depends upon 18) A acid, its 0.008 (at solution, ionization the same a) 0.001 b) 0.0098 c) 0.008 d) 0.2 weak monoprotic degree of ionization = 25oc) in 0.15 M the degree of in 0.1 M solution at temperature? these 19) Penicillin is used as an antibiotic, it is a weak acid and its degree of ionization = 2x10 -2 in 1 L volume solution which contains 0.25 mole. Of penicillin, the equilibrium constant of penicillin equals …………… a) 2x10-4 b) 1x10-2 c) 1x 10-4 d) 3x10-3 20) The hydroxyl ion concentration in 0.2 M solution of methyl amine CH3NH2 (at 25oc), knowing that its ionization constant = 3.6 x10-4 a) 1.2 x 10-3 M b) 3.7 x10-4 M d) 4.5 x10-1M c) 8.5x10-3 M 21) In the equilibrium process: CH3COOH (aq) + H2O(l) ⇄ CH3COO-(aq) + H3O+(aq) Adding drops of HCl …………… the concentration of acetate ion. a) Increases b) Decreases c) Does not change 22) The acetic a) 1.2 b) 1.34 c) 1.45 d) 1.9 x 23) ions of hydronium ion concentration in 0.1 M acid solution (25oc), knowing that its ionization percentage = 1.34% x10-8 M x10-3 M x 10-1 M 10-3 M When excess hydroxide where added to 1.0 liter CaCl2 solution, Ca(OH)2 precipitate was formed . the calcium ions in the were precipitated in 7.4 of Ca (OH) 2, then what initial concentration of CaCl2 solution? (Ca= 40 , O=16 , Cl =35.5) 0.05 molar b) 0.10 molar If all of solution grams was the the H=1 , a) c)0.15 molar d) 0.20 molar Q2. Choose the proper answer for each of the following (True or False): 1) Ostwald formulated a rule which predicts the effect of different factors on the system under equilibrium. a) True b) False 2) The electric conductivity of hydrofluoric acid increases by dilution a) True b) False Model Answer Quiz 1 1 D 2 A 3 A 4 B 5 D 6 B 7 A 8 B 9 B 10 B 11 C 12 C 13 B 14 A 15 B 16 B 17 C 18 D 19 A 20 B 21 A 22 B 23 D 24 B 25 A Model Answer Quiz 2 1 B 2 C 3 B 4 C 5 B 6 C 7 C 8 D 9 C 10 B 11 D 12 D 13 B 14 C 15 D 16 B 17 B 18 D 19 A 20 D 21 B 22 C 1 B 2 A 3 B Model Answer Quiz 3 1 A 2 A 3 C 4 B 5 B 6 C 7 A 8 D 9 C 10 B 11 C 12 A 13 B 14 B 15 D 16 B 17 D 18 B 19 D 20 B 21 A 1 A 2 B 3 A 4 A Model Answer Quiz 4 1 B 2 C 3 C 4 B 5 B 6 B 7 C 8 C 9 C 10 B 11 B 12 C 13 A 14 B 15 B 16 D 17 C 18 B 19 C 20 C 21 B 22 B 23 B 1 B 2 A