#E#E¥¥¥ ¥E¥ ONE SHOT '" " ¥EE⑥§q§ed " """ " " " " By . , Bhagat Panchal Sir ÷÷÷÷÷÷÷: iii. NCERT Ques AMIA • Pry G . . . " B # Br 40,1 Bharat PanchalSir By . alkyl aryl derivatives of or H H - N' R H - - N' - RAI H CH - R H - N' - R n, * R . famine c) - trigonal beramidae • 3 Bond CH Cha ; NH ¥9 " - CH . -7 Pair -11 lone Pair Sps - Preparation , Reduction of Nitro compounds - CH or - , CH , I - Non amine d- , - cu - NH , , 2- Amino toluene - Reduction of Amides Bharat Pancha , - chemistry Guruji 2 :O - E - Mk 2- amine - - MHz FHL A '* Nitrobenzene R '¥¥E¥¥#I¥* Haired snlteceor Log N.me/hylethanamine EH Aniline Please subscribe propan - - R , NHL ) I -2013 told aniline → R cha - . qq.gg?Yid7. of Amines R NO - CHECK - Hybrid - - Dimethyl - But -3 en Nomenclature CH , CHS (A - ethan amine R - • Hg CH3 structure R ( - 1 N,N Structure of Amines - N CHS R amine Ldamine Ammonia - Toibrom . Ammonia R H ° aniline i 3 are 24,6 - Br C) These Kao 's ) inn - NH , Gg ↳ Hs , Trick Baby art - GHS , Brom amide Hoffmann • HAE NH - cha MHz - - Degradation Hoffmann Ammonolysis of Alkyl . atria El Base H Ny - - H R tr x - tr NIH - - x Halide R Tex tr × NIR - - Fantine qq.ie?nxR-Y-RR-C0-NHgtBrgt4K0H--iR-NH2 tamed - - - 2K Br kids - H - 2h20 - Nh - H 1- GHS - - U GHS The - calls U H + Ny famine - Tey - . ↳ Hs - CO - NH , + Brat 4 KOH Protean amide Trick - 747%623110 phthalimide synthesis : Gabriel steak Basement gits - - • ↳ Hs MHz £ , Ethan amide - - Hao UH I sniffing → - Hoo I%iniiiR physical State : but - higher amines X but → -12110 EIFFEL + R - MHz P.IR Aromatic I amines ' cant prepared be - R - CEN GHS - + Acid ⇐N teens R ¥5 - , - amines - N - , ↳ Hs GH.sEam Amines : - odour storage liquids lower aliphatic The Aryea mines on and gases . fishy with gases are solids are aliphatic lower they nip - H and due - - - . usually are due to ou - H - to H - amines form can secondary - - CH lower ' water ! GHS Tna - because primary of Nitriles U - colourless atmospheric . by . Reduction GHS . solubility : water by this . • 1- Imine coloured do not because aryl halides undergo sub with anion the formed nucleophilic method pnthalimide calls amines are get oxidation NR - Physical Properties of - MT R X Na - . - - pint - H H - amines - - - are Bond if - soluble in with water H are soluble in se amines bonding arewhile insoluble in water NH ↳ Hs , - cha nine - Please subscribe ¥E¥i¥E¥##¥¥ Bharat Panchal - cahuf.mji ss.to' . solubility The - of alcohol because and alcohols form Boiling - Bond By because H no - two because Ammonium salt → amines 30 is attached to maximum H - N - H of - Bonding lone of → are pair → to of amines Aliphatic due Fa sic +I → to - on nitrogen : e interplay of I effect weaker @ Hg Ctg ) Ange group , ammonia . effects of amines Niu NH Resonance in NH like Bharat Panchal > R effect, In - : effect ] 7 ath > : : - There steric is subtle and effect CHS CH , MHz > NH, ye CH, - > Nu , le CHIN > MHz 3- so - gaseous phase Aniline . Please subscribe : > GHz CHIN ) I than :#atia .su#i:oa.nemeectsaressiconance strength - +I zo @ Hs) ammonia . or - to . . amines > famines > NHS Le . than bases R - effect . are 2 Inductive solvation the presence atom are Besides inductive effect , ste due to stronger bases effect of Alkyl group Aromatic amines due in nature eo Acc aqueous phase . l③asic Character of Amines} Lemmerman Amines 7 : in However - MT → ni - - attached to N atom are amines > . amount atoms R Boding atom H in character of amines basic Order of C intermolecular . amines than ' have have amines mass Bharat Panchal Sir - salts form to R.in#ttHx-R-NtOHzX0 than that molecular amines 7 do not basic in nature and seats with are acids order of b.pt isomeric amines 23 amines a The Amines . Point ① 3. amines so H is less polar more are stronger se ④ comparable of size . solubility of amines The - increase in part with alkyl hydrophobic of P TR decrease cahuf.7iisst.io' " . a ' Carbylamine • - Reaction Acylation mm -- - R NH CHU, -13 KOH S R NIC -13kV + - , - GHS NHI - - NH • CHU, -13 KOH Is -1 , -- - + - RR> NH - CHS cuz + mm- MGI - MGI - Tertiary amines reagents active as H atoms - GHS NH, → CHR B → Cg Hot not GHS - + NHA - Br t - N - -13140 - with not contain - cow → - Br (GHS-72 j Ffg (GHA, Br ' . N - Coll -7 - N @ Hd , testes - + CH I , NH # CH + - p.FR - MSI Grignard ¥7 - HU HCl + Reaction onanism we go a for monobzomination , III C÷÷÷ " ; ' Es HII Foi " - ÷i÷÷: t ion:-, €014 pyridine - ⇐ %) A" MH Nth Hao t's Br no -1 . no , Cat 'D 12%3 p.gl/kocHgNHu ÷÷o Go ' ' , ¥¥E##¥i¥ . Br no Please subscribe fiefs :b "" " s , EI with treat aniline anhydride (CH, coho acetic Ciii Nitration Nt @ + Br NU CHI Ey - B¥¥?BI3HBr , Br , NH - co - %k+zBr IN Ha - - m m- nv m NH . - Ctf ' - NH ' rekaemgeammom.am bromide CHI -5 - Electrophilic Substitution Brominate on MSI - t - + Hasten - - CHS Nff +3110 MGI - react do they - t -13110 Bhlpgiaoatncnd - + do , . GHS 1- + Skee R NU Mutation - NC - Chat GHS MgI NH -1 NC -13 Kee → - , Piru - Grignard Reagent Reaction with R NH, -13150nF ↳ Hs CHU, t - NH Bharat Panchal no I - cahufnfiisst.io' or Sul phonation inHg ' + T ,NHs HS OF Tf → ii. so, x 1 Anilinium Hydrogen Sulphate Aniline 505 ⇐ Willer MHz ion ) x F- Basic 101 2 character 9 I Basic → ' character SO H Pkn , Hingberg Test ( I. ¥-502 Clt tf N - → - so - , ( soluble em alkali ) NH R - E- SEU 1- HN R , 3. Amines " → ⇐ SO , - NR , Cinsobk in alkali ) increasing the : If NHL - solution Give in the : , ↳ Hs an NH , - , CHINH Nucky NH - CCHD.NU is more - CH, s ( # NH , basic than more solution aqueous is C B .SE - - 2018 ) ( CHIN than ( CHIN in an due to less basic aqueous solution hindrance . - Soga T N - Rs No → Reaction 3- Amine NH L - fried al it form because used iii. + as nice . possible for Rxh are not craft salt catalyst - with anhy in Eiji the 's . Alas reaction . 69::ge7eI"Eau . as strong deactivating Gould . Please subscribe of - - reasons : steric - order cc.B.SE 20181 GHS Ntfs - in amine 2. is P Are - following Values Arrange Reagent famine 2 Amines that R • - ' Piru - ) sulbhonyl Chloride ⇐ sq Ce ( Heinsberg ) benzene Amines - Kb ¥E¥i¥###¥¥ Bharat Panchal - chemistry Guruji I :O PASSAGE s Spatafora Please subscribe ¥E¥¥E###¥¥ , Bharat Panchal - 8%7%34 Mcd of Amines Please subscribe ¥e¥¥€###¥¥ Bharat Panchal - cahuf.mji ss.to' PYQ OF AMINES ✓ ✓ y - ✓ ✓ ✓ : u n ✓ ✓ : " Please subscribe ¥E¥¥¥E##¥¥ , Bharat Panchal - chemistry Guruji I :O