Electronic Materials EECE 7296 – FALL 2023 V.G. Harris Introduction to X-ray Diffraction • Generation of x-rays • EM spectrum • Bragg’s law • Equipment • Consider-single crystal • Consider-polycrystal • Let’s look at bcc Fe – breakout problem 1 Hexaferrite (magnetoceramics) for RF nonlinear devices (unit cells) X-type (Ba2Me2Fe28O46) X-type b) U-type (Ba4Me2Fe36O60) a) U-type Iron (Fe) The Utility of X-ray Diffraction • Identifies reflected atomic planes • Allows for calculation of atomic dimensions of the sample’s phase • Provides identification of the sample’s crystal phase • Identifies crystal symmetry • Allows evaluation of defects and strain • Allows evaluation of crystal orientation • 40 Nobel Prizes awarded for X-ray research Electron collisions and transitions https://phys.libretexts.org/Bookshelves/University_Physics/Book%3A_University_Physics_(OpenStax)/Book %3A_University_Physics_III__Optics_and_Modern_Physics_(OpenStax)/08%3A_Atomic_Structure/8.06%3A_Atomic_Spectra_and_Xrays X-ray Tube (provides an affordable source of x-rays) Electromagnetic spectrum 7 Detector X-rays 1 1 2 2 d d Constructive interference A dsin dsin B Atomic planes Crystal (c) x + y = λ = nλ dsin = x dsin = y 2dsin = nλ n is the “order” of the wave n=1 is the 1st harmonic Monochromators are used to limit the X-ray beam to be monochromatic in most cases From Principles of Electronic Materials and Devices, Second Edition, S.O. Kasap (© McGraw-Hill, 2002) http://Materials.Usask.Ca http://www.upscale.utoronto.ca/GeneralInterest/Harrison/DoubleSlit/DoubleSlit.html 8 Detector X-rays 1 1 2 2 d A dsin dsin B d 1) (c) Atomic planes Crystal Bragg’s Law 2dsin = nλ hc λ= E E = energy of X-ray, KeV λ = wavelength of X-ray, nm hc = 1.240 KeV*nm Relate “d” to specific crystal structure (cubic systems): a d= a = lattice constant 2 2 2 ½ (h + k + l ) (hkl) = miller indices 1) From Principles of Electronic Materials and Devices, Second Edition, S.O. Kasap (© McGraw-Hill, 2002) http://Materials.Usask.Ca 9 Bragg condition for a cubic crystals From 2dsinθ = nλ d= a (h2 + k2 + l2)½ We obtain sin 2 n 2 2 2 h k l 2 4a 2 2 10 X-ray Diffraction Equipment 12 X-ray diffraction from a single crystal X-ray source Monochromatic X-rays Single crystal sample Goniometer Stage Hybrid Pixel Array Detector (HPAD) Output 13 X-ray powder diffraction Consider diffraction from a collection of misoriented crystals (polycrystalline) Intensity (Counts) Traditional -2 powder diffraction 2 (degrees) (for illustration- not a one to one comparison) 15 Protein X-ray Crystallography (game changer for rapid drug design) Theory X-rays Crystal Phase Diffraction Pattern Fitting Electrondensity map Atomic model "for their outstanding achievements in the development of direct methods for the determination of crystal structures" Herbert A. Hauptman Jerome Karle Break out problem • At what angles will these planes appear as peaks in the x-ray diffractogram if Cu ka radiation is used (=0.154 nm) and the lattice parameter of the sample (body centered cubic iron) is 0.2866 nm? 18 Solution for the first one is (110) a 0.2866nm d 2 2 2 2 h k l n 0.154nm sin 2d 2 * 0.2026nm arcsin(0.3799) 22.30 2 44.60 sin 2 n 2 2 2 2 2 h k l 4a 2 This expression of course provides the same answer 19 Consider bcc-Fe 44.67 65.02 82.33 20 Intensity (Counts) Consider: 2 (degrees) a What is scattering the x-rays? Explain why (110) intensity is greater than (211) which is greater than (200) – draw and calculate areal densities of planes XRD of bcc iron Triclinic XRD of SrTiO3 K2Ce(PO4)2 Triclinic structure XRD Study of BaM/MgO/AlN/SiC samples (008) Figure. Room temperature Cuka radiation q-2q diffraction pattern acquired from BaM film PLD grown on MgO/AlN/SiC heterostructure. The result demonstrates strong crystallographic texture with (00𝑙) diffracting planes aligned orthogonal to the growth axis. Inset pole figures for (008) planes confirm heteroepitaxy while similar data collected from the (107) peak confirm six-fold in-plane symmetry. “X” denotes unidentified low-angle diffraction peaks that have less than 1% relative intensity.