Uploaded by Shefali Singh

Amines

advertisement
Amines
3' Ammine
M-a-Dimethylethanamine
Chy-CH-M-ly
>N-N-etayl-N-methylethanamite
I
Senior functional
and
as
junior
of
functional
substituent
junior
.
functional
that
For
2
makes
group
the
group
Suffic
are
2
treated
naming
we
use
group
-
mine
group
Aminobutan 1 -0)
of
prefin
Order
alkyl
of
ammonia
with
Bond
reactivity
of
RUJR- BryR-I
R-F)
I
halide
Streth
RF <RU < RB
Reactivity
Reduction
Nitrile
of
LiAIHy
R-EN
>
Hulm
- it
r
in
;
Malieg)/(2+504
O
R
-
11
C
of
LI]
-
M12
is
↓
R-
Reduction
<R- I
CH-MH
2
Amide
FiAIHy
->
E kg0+
R
-
CH2-MHz
CBSE 2010/201L
Basicity
M
+Cs
Basicity
is
represented by
Basicity k
Alkanamines
Lis
R-
:
PKb
2
PKa
Us
Ammonia
3
t
H
-
It
Alkanamines
kn
Kod
pka=-logke
p
alt]
REH
Y
+
1
↓
&
How
distinguish
Ethylamine
&
Benzylamine
↓
↑ CHH
will
(i) Aniline
&
iis Aniline
(
m
~
I
-
Hd
↓
-
Hd
↓
Mamurthy
20 - 5 2)
-
X y on
It
Rxn
7
Ly
with Hinsberg
This
reagent
blo
1/2
blu
you
can
be
,
Mandon tha
(0-5'C)
+
M24
Reagent
used
·
distinguish
:
-(reagent)
Hinsberg
Download