PETROLEUM SOCIETY PAPER 2005-115 CANADIAN INSTITUTE OF MINING, METALLURGY & PETROLEUM World's First SAGD Facility Using Evaporators, Drum Boilers, and Zero Discharge Crystallizers to Treat Produced Water W.F. HEINS Ionics RCC R. McNEILL S. ALBION Deer Creek Energy BDR Engineering This paper is to be presented at the Petroleum Society’s 6th Canadian International Petroleum Conference (56th Annual Technical Meeting), Calgary, Alberta, Canada, June 7 – 9, 2005. Discussion of this paper is invited and may be presented at the meeting if filed in writing with the technical program chairman prior to the conclusion of the meeting. This paper and any discussion filed will be considered for publication in Petroleum Society journals. Publication rights are reserved. This is a pre-print and subject to correction. operate, is more cost effective, and results in significant increases in equipment reliability, on-stream availability and, ultimately, in increased oil production. In conjunction with this process, Deer Creek Energy has taken the additional step of recovering all liquid waste streams for reuse in the plant, resulting in zero liquid discharge (ZLD). Designing the facility for ZLD eliminates the need for deep well injection, minimizes make-up water requirements, and simplifies the permitting process. Abstract Steam Assisted Gravity Drainage (SAGD) heavy oil recovery facilities have traditionally used a combination of warm or hot lime softening, filtration, and weak acid cation (WAC) ion exchange to pretreat de-oiled produced water. The pretreated water is directed to “once through” steam generators (OTSG) to produce 75-80% quality steam. The steam-water mixture goes through a series of vapour-liquid separators to produce the 100% quality steam required for injection into the oil well. The steam fluidizes the heavy oil and allows the oil/water mixture to be brought to the surface. The oil is recovered as product and the produced water is de-oiled and treated for reuse in the OTSG. An alternative method of produced water treatment and steam production, which has recently been implemented in Alberta by Deer Creek Energy, is mechanical vapour recompression evaporation followed by standard drum boilers. This method of SAGD steam production is much simpler to Introduction Water treatment and steam generation methods for heavy oil recovery processes have rapidly evolved over the past few years. Traditionally, once-through steam generators (OTSG) have been used to produce about 80% quality steam (80% vapour, 20% liquid) for injection into the well to fluidize the 1 transferring heat to the brine for evaporation, which produces steam for the compression cycle. A simplified vertical tube, falling film, vapour compression evaporator system used to treat produced water is shown in Figure 2. This system requires fewer components and is much simpler to operate than the traditional produced water treatment system depicted in Figure 1. Additional details showing the vapour compression cycle are shown in Figure 3 and Figure 4. A photograph of a typical falling film vapour compression evaporator, similar to those being implemented by Ionics RCC in Alberta SAGD applications, is presented in Figure 5. The water to be treated enters a feed tank where the pH is adjusted. The feedwater is pumped to a heat exchanger that raises its temperature to the boiling point. It then goes to a deaerator, which removes non-condensable gases such as oxygen. Hot deaerated feed enters the evaporator sump, where it combines with the recirculating brine slurry. The slurry is pumped to the top of a bundle of two-inch heat transfer tubes, where it flows through individual tube distributors which ensure a smooth, even flow of brine down each tube. As the brine flows down the tubes, a small portion evaporates and the rest falls into the sump to be recirculated. The vapour travels down the tubes with the brine, and is drawn up through mist eliminators on its way to the vapour compressor. Compressed vapour flows to the outside of the heat transfer tubes, where its latent heat is given up to the cooler brine slurry falling inside. As the vapour gives up heat, it condenses as distilled water. The distillate is pumped back through the heat exchanger, where it gives up sensible heat to the incoming wastewater. The distilled water stream is directed to the boiler system for use as feedwater. A small amount of the brine slurry is continuously released from the evaporator to control density. The evaporator blowdown is disposed of via deep well injection or treated further by a mixed waste salt ZLD crystallizer. heavy oil. However, the relatively new heavy oil recovery method referred to as steam assisted gravity drainage (SAGD), requires 100% quality steam for injection. In order to allow the continued use of OTSG for SAGD applications, a series of vapour-liquid separators is required to produce the required steam quality. For both SAGD and non-SAGD applications, pretreatment of the OTSG feedwater has consisted of silica reduction in a hot or warm lime softener, filtration, and hardness removal by weak acid cation (WAC) ion exchange. In most cases, the OTSG blowdown is disposed of by deep well injection. A simplified block flow diagram of this traditional approach to produced water treatment and steam generation is provided in Figure 1. As the use of the SAGD process became increasingly common for heavy oil recovery in Alberta and worldwide, the traditional methods of produced water treatment and steam generation were re-evaluated to determine whether other alternative methods may provide more technically and economically viable solutions. This paper compares the use of traditional methods with an alternate method being implemented in Alberta; the use of falling film, vertical tube vapour compression evaporation for produced water treatment, standard 100% quality drum boilers for steam production, and zero liquid discharge (ZLD) crystallizers to eliminate the need for deep well injection. Both technical and economic criteria are presented. This integrated approach is currently being implemented by Deer Creek Energy for the Joslyn Phase II SAGD facility located near Fort McMurray, Alberta. Vapour Compression Evaporator and Crystallizer Technology In order to understand the integration of vertical tube, falling film evaporators and ZLD crystallizers into the SAGD process, a brief description of each technology is provided. Vertical tube falling film evaporation is used to treat de-oiled produced water for use as boiler feedwater and can also be used to treat OTSG blowdown as part of a SAGD ZLD system. Forced circulation crystallizers are used to eliminate liquid waste streams, such as OTSG blowdown, achieving ZLD. The following section provides basic process descriptions for these two technologies. Mixed Waste Salt ZLD Crystallizers The crystallization process has long been used in the manufacture of commodity chemicals such as sodium chloride and sodium sulfate. However, unlike commodity production where only one salt precipitates, typical reduction of industrial waste, such as produced waters, to dryness involves crystallizing multiple salts, often in the presence of high levels of organic compounds. This type of mixed salt crystallizer requires significantly different design parameters to avoid problems such as severe foaming and rapid scaling. Furthermore, mixed salt solutions have significantly high boiling point elevations, requiring detailed attention to design parameters when sizing vapour compressors, should a vapour compression cycle be desired. Finally, innovative filtering and drying techniques have been developed to dewater the complex salts that are formed, allowing zero liquid discharge to be achieved. Crystallizers typically have an external heater, a two-pass horizontal or one-pass vertical, in which the solution is heated by steam in the shell. The heated solution then flashes into a large vessel called a vapour body. The heater tubes are flooded, with boiling water in the tubes suppressed by the liquid elevation in the vapour body (submergence). A slipstream is directed into a separation device (typically a centrifuge, automatic pressure filter, or drying device) and crystals are removed. A simplified process flow schematic for a ZLD crystallizer system is presented in Figure 6. Vertical Tube Falling Film Vapour Compression Evaporators Vertical tube falling film evaporators have the highest heat transfer characteristics of all evaporator types. A high heat transfer coefficient is needed to efficiently evaporate the water and save energy. The vertical tube, falling film arrangement also allows evaporation to occur with reduced fouling effects by keeping surfaces wetted at all times. Individual tube distributors are used to ensure an even falling film in these evaporators. The vapour compression cycle is the key to energy efficiency in these systems. The amount of energy input for the vapour compression evaporation cycle is about 1/20th the energy needed to evaporate water. This is because of the nature of the thermodynamic cycle, which does not have to provide the energy to vaporize the water. The compression energy is used to elevate the existing steam temperature without having to provide the initial energy to evaporate the water. The steam temperature (and pressure) is elevated, and is then condensed 2 reduction. The oil is removed to as low a level as is feasible by a polishing step prior to these inorganic reductions. The treated water is then directed to an OTSG that can produce high pressure steam (typically 1000-1600 psig) from water that has a high total dissolved solids (TDS) concentration (typically 2,000-8,000 mg/l). The TDS consists of a combination of dissolved inorganic and organic constituents. Figure 1 shows a traditional produced water treatment system after a variety of oil separation processes have been utilized to recover oil and remove oil from the water. This method of produced water treatment has been applied to both SAGD and non-SAGD applications. The process that reduces silica to low enough levels to be utilized in an OTSG is either a warm or hot lime softener (WLS or HLS) followed by a filtration system. Calcium and magnesium are also reduced in the lime softener, which lightens the load for the weak acid cation (WAC) ion exchange system. The major chemicals added in the softener are lime and magnesium oxide. These chemical systems require chemical silos and solids transport equipment. Other chemical additions are also required in the form of a coagulant and a polymer. The chemical additions reduce silica content to manageable levels for the OTSG. The clarate is filtered prior to being treated with the WAC ion exchange system, which reduces magnesium and calcium. Sludge produced from this softening process has high water content and is separated with a centrifuge. The sludge must be disposed of in some manner. Centrate is recycled back to the process. The WAC ion exchange system is regenerated with hydrochloric acid and caustic. Reduction of metals such as calcium, magnesium, and iron to low levels occurs in the exchange process. WAC does not reduce silica any further than the lime softening process. The strong regeneration waste is neutralized and possibly recycled to the softening system or disposed of in some other manner. The resin bed rinses are recycled back to the softening system. Conventional treatment of produced water being processed in a OTSG produces a blowdown which is about 20% of the boiler feedwater volume and results in a brine stream which is about fivefold the concentration of the boiler feed. This stream has historically been disposed of by deep well injection. Some of the OTSG blowdown can be recycled to the softener system, but as the solids are cycled up in the system, more maintenance issues are evident in the OTSG. Utilization of a crystallizer eliminates all liquid wastes making the process a zero discharge system. (The crystallizer produces a dry cake material for disposal.) A photograph of a typical zero liquid discharge crystallizer system, similar to those recently installed in Alberta and currently being installed at the Deer Creek Energy Joslyn Phase II facility, is presented in Figure 7. Evolution of Produced Water Treatment and Steam Generation Methods As the heavy oil recovery industry shifted further toward the use of the SAGD process, the unit operations which made up the produced water treatment and steam generation portions of the facility required re-evaluation. Initially, familiarity with the design and operation of the traditional processes tended toward the continued use of warm lime softeners and WAC ion exchange systems for produced water treatment and OTSG followed by deep well injection for steam generation and waste disposal. However, when the SAGD process was viewed from a fresh perspective, setting aside the historical approaches developed for non-SAGD facilities, several questions arose regarding the use of the traditional treatment scheme: (1) Does it make sense to continue to use OTSG, which only produce 70%-80% quality steam, when 100% quality steam is required? (2) Is the use of vapour-liquid separators following OTSG to achieve 100% quality steam a “force-fit” based on the historical use of OTSG in non-SAGD applications? (3) Should a simpler method of producing 100% quality steam be used, such as the use of standard drum boilers, as is done in other industries requiring 100% quality steam? (4) If standard drum boilers are used for steam production, can the produced water treatment scheme be simplified and made more economical while providing water of sufficient quality to use in drum boilers? (5) Can the entire produced water treatment and steam production process be simplified, made more reliable, and provide an increased on-stream availability? (6) Can the volume of liquid waste be minimized or eliminated in cases where deep well injection is not technically viable or is unattractive from a regulatory or community acceptance standpoint? Addition of Zero Liquid Discharge Systems to Eliminate Wastewater Discharge These are a few of the questions which led experts in the SAGD industry to investigate alternatives to the traditional produced water treatment and steam generation approaches. The following sections provide the history behind the evolution of SAGD water treatment from the traditional approach through the current integrated approach being implemented by Deer Creek Energy for their Joslyn Phase II project. The intermediate steps (i.e., the separate addition of ZLD systems and produced water evaporators feeding OTSG) taken at other facilities are also discussed to present the progression of the technologies over the past several years. The sequence of implementation of these technologies is provided for the heavy oil recovery industry in Alberta and worldwide. Since the SAGD process requires 100% quality steam to be injected into the well, a concentrated liquid waste stream is produced by the vapour-liquid separators downstream of the OTSG. In some instances, this liquid blowdown stream may be disposed of via deep well injection. However, several factors may preclude the possibility of deep well injection, resulting in the need to either reduce the volume of the waste stream or eliminate it completely. Potential factors which may eliminate the possibility of deep well injection include; (1) the presence of a geologically tight formation, (2) the presence of a fresh water aquifer in the vicinity of the potential deep well location, (3) increasingly stringent regulatory requirements, and (4) restrictions on the allowable amount of plant make-up water, necessitating maximum water re-use. Ionics RCC installed the world's first two SAGD ZLD systems in northern Alberta between 1999 and 2002, marking the first step in the evolution of SAGD evaporative produced Summary of Traditional Produced Water Treatment and Steam Generation Historically, in the majority of SAGD and non-SAGD heavy oil recovery applications, produced water is treated in multiple steps requiring silica, calcium, and magnesium 3 • water treatment. The Deer Creek Joslyn Phase II project will be the third such ZLD system installed in Alberta. A typical SAGD ZLD system, which consists of a vertical tube falling film evaporator and a crystallizer is presented in Figure 8. A photograph of a ZLD system of the size required for a SAGD facility producing about 10,000 bpd of heavy oil, similar to that being provided by Ionics RCC for the Deer Creek SAGD facility, is provided in Figure 9. • The use of vertical tube falling film evaporators to directly treat de-oiled produced water represents the second major advancement in the evolution of evaporative produced water treatment in SAGD (the first advancement being the implementation of evaporators and crystallizers to achieve ZLD). Use of Vertical Tube Falling Film Evaporators to Feed OTSG The traditional de-oiling, softening, filtration, and ion exchange produced water treatment scheme depicted in Figure 1 is complex, produces several waste streams requiring disposal, is labour intensive, and has relatively high operations and maintenance costs associated with it. In addition, upsets in the de-oiling and softening processes can make their way into the OTSG, resulting in unanticipated extended downtimes and decreased plant reliability. Therefore, an investigation of an alternate approach to produced water treatment which is simpler, more cost effective, and more reliable was desirable. Based on these investigations, falling film, vertical tube, vapour compression evaporation was implemented in Alberta and worldwide to obtain these objectives. This simplified method of produced water treatment is shown in Figure 2. This approach to produced water treatment involves direct treatment of the produced water in an evaporation system. The lime softener (WLS or HLS), filtration, WAC exchange systems, and certain de-oiling steps are eliminated. In the first three heavy oil recovery facilities using evaporation for produced water treatment, OTSG are used for steam generation. Standard drum boilers were not used at these facilities since, in some cases, 100% steam quality was not required and, in other cases, insufficient characterization of the distillate was available to properly specify the use of drum boilers. In each case, the evaluations concluded that the use of vertical tube falling film evaporators had a technical and economic advantage over traditional produced water treatment, even without the added advantages that would be realized with the use of drum boilers. Using evaporation as the treatment process instead of lime softening and WAC has several advantages: • • • • • • • • • • Boiler blowdown is recycled to the evaporator feed, eliminating boiler blowdown disposal requirements If zero liquid discharge (ZLD) is required due to a lack of disposal well capability, the evaporative approach to produced water treatment results in a ZLD system that is about 80% smaller than that required if the physicalchemical produced water treatment approach is used. Use of Standard Drum Boilers for SAGD Steam Generation The third significant step in the evolution of evaporative produced water treatment is the conversion from the use of OTSG to standard drum boilers for SAGD steam generation. This is possible since the distillate produced by these specially designed evaporators is of sufficient quality to be used as drum boiler feed without the need for further treatment. Use of vertical tube falling film evaporators followed by drum boilers provides several additional advantages: • Capital costs are reduced since drum boilers are significantly less expensive then OTSG • The need for vapour/liquid separators are eliminated since the drum boilers produce 100% quality steam. • An accelerated project schedule is possible due to shorter delivery times of drum boilers compared to OTSG. • The amount of boiler blowdown to be treated by the evaporator is significantly reduced since drum boilers can typically run at about 2-3% blowdown as compared to about 20% blowdown from the OTSG. This results in a reduction in the required size of the evaporation system and results in electrical cost savings. • These advantages are in addition to those previously stated for the use of evaporators in conjunction with OTSG (when comparing the use of evaporators and drum boilers to the traditional approach). Until recently, this final step in the evolution of SAGD evaporative produced water treatment had not been implemented. The following section describes how all the advancements in evaporative produced water treatment described in this paper are integrated into the Joslyn Phase II design. Evaporators effectively “decouple” the produced water system from the boiler feed system, such that upsets in de-oiling do not reach the steam generators Increases heavy oil recovery process and water treatment process availability and reliability by 2-3%, increasing oil production Overall life cycle costs are less for an evaporative produced water treatment system than for a traditional lime softening/WAC approach. Physical separation processes using solid chemical additions are eliminated. High water solids content sludges are eliminated. Waste streams requiring further disposal treatment are eliminated. Oil removal equipment may be reduced. Boiler blowdown and heat recovery equipment can be reduced in size. Overall operational and maintenance requirements are reduced. OTSG feed quality is dramatically improved (by more than three orders of magnitude), resulting in improved OTSG reliability. Integration of Evaporative Produced Water Treatment, Drum Boilers, and Zero Liquid Discharge at Joslyn Phase II Since 1999, there have been three major advancements in the use of evaporation for SAGD produced water treatment and steam generation; (1) implementation of ZLD systems at SAGD facilities, (2) use of vertical tube falling film evaporators to directly treat de-oiled produced water, and (3) use of standard drum boilers to generate steam for injection into the wells. Until recently, the full advantages of these advancements had not been realized since they have not been implemented simultaneously at any given installation. 4 Economics of the Produced Water Evaporator and Drum Boiler System Compared to the Traditional Approach In late 2004, Deer Creek Energy, BDR Engineering, and Ionics RCC proceeded with the execution of the Joslyn Phase II project which uses falling film evaporators for produced water treatment, drum boilers for steam generation, and a ZLD crystallizer system to eliminate liquid discharge from the facility. In addition to the technical advantages obtained using evaporative produced water treatment and drum boilers as compared to the traditional method of WLS, filtration, WAC, and OTSG, economic advantages are also realized. Deer Creek Energy and BDR Engineering performed a comprehensive economic evaluation and comparison of the two technical approaches. The following is a summary of the results of this evaluation: • Total installed capital cost of the evaporator and drum boiler system was estimated to be 10% less than the traditional approach • Annual operating costs, evaluated over the life of the facility, were determined to be 6% lower when using evaporative produced water treatment • Five year and ten year net present value analyses favored the evaporative approach • On-stream availability of the evaporative process was evaluated to be 2% higher than the traditional approach, resulting in an increase in oil production • The evaporator and drum boiler combination provides improved turndown capability as compared to the traditional approach, which significantly improves both economics and operability during the 18 month ramp-up phase of the SAGD facility • Simplicity of the evaporative produced water treatment system results in increased on-stream availability. One unit operation replaces six unit operations in the traditional approach. • Labour requirements were evaluated to be much lower in the evaporative produced water treatment approach • Standard package boiler total installed costs are significantly less than comparably sized OTSG • Overall project schedule can be shortened by up to six months based on shorter delivery times of packaged drum boilers compared to OTSG • Use of drum boilers provides the ability to consider the use of alternate fuels, which can result in significant energy savings compared to natural gas • Since the boiler feed water is so much higher in quality for the evaporative approach, boiler maintenance and cleaning was evaluated to be reduced • Energy savings for the drum boiler compared to the OTSG were approximately 3% Process Description of the Deer Creek Energy Joslyn Phase II Facility The Deer Creek Energy Joslyn Phase II facility, which is designed for approximately 10,000 barrels per day of oil production, is the first SAGD facility in the world to use the unique combination of produced water evaporators and drum boilers for water treatment and steam generation. This combination of technologies provides all the advantages previously presented. In addition, Joslyn Phase II, which is scheduled to start-up in late 2005, includes a ZLD crystallizer system. Designing the system for ZLD provides the following additional advantages: • Achieving ZLD eliminates the need for deep well injection and the associated risks associated with potential deep well plugging and geological constraints • Potential contamination of groundwater aquifers caused by deep well injection is eliminated • The volume of plant make-up water is reduced since virtually 100% of the plants wastewater is recycled for reuse • ZLD provides greater community acceptance since there is no wastewater stream requiring disposal • With increasingly stringent regulatory requirements, ZLD provides a more straightforward path for permitting of the facility Figure 10 provides a process flow schematic for the Joslyn Phase II facility. In order to achieve 10,000 barrels per day of oil production, approximately 205 m3/hr of drum boiler feed water is required to provide the necessary steam to fluidize the heavy oil. The 205 m3/hr of boiler feed is supplied by the distillate produced in two vertical tube, falling film evaporator systems operating in parallel. The distillate is a high quality stream which contains about 3 mg/l inorganic TDS and is suitable for use as drum boiler feed without further treatment. By providing 2 x 50% parallel evaporator systems, greater flexibility and on-stream availability is achievable. The evaporator systems are fed with de-oiled produced water at a rate slightly greater than the distillate rate required to support the drum boiler operation. The higher feed rate (approximately 5% - 10% above the 205 m3/day distillate rate) is required since a small amount of water is lost through system vents and a small amount of evaporator blowdown is required to control the evaporator solids level. This blowdown stream is directed to the ZLD crystallizer for further treatment, where the concentrated brine is reduced to a dry solid. The distillate produced by the crystallizer system is reused for various process needs of evaporator. The boiler blowdown stream, which is approximately 1% 5% of the boiler feed rate, is recycled and re-used in the process. The boiler blowdown stream only contains about 100 mg/l of TDS, so this water, which is of higher quality than the facility make-up water, is easily reused. Conclusions 1. The combination of vertical tube falling film evaporation and standard drum boilers has several technical advantages over the traditional approach including increased reliability, reduced maintenance and operations requirements, less chemical handling, and increased simplicity 2. Economic advantages of the produced water evaporator and drum boiler combination include reduced capital, operating, and lifecycle costs, and the potential for an accelerated project schedule 3. The addition of a ZLD system to a SAGD facility eliminates risks associated with deep well injection, reduces make-up water requirements, simplifies permitting, and results in greater community acceptance 5 NOMENCLATURE HLS OTSG SAGD TDS WAC WLS ZLD = = = = = = = Hot Lime Softening Once-Through Steam Generator(s) Steam Assisted Gravity Drainage Total Dissolved Solids Weak Acid Cation Warm Lime Softening Zero Liquid Discharge REFERENCES 1. HEINS, W. and SCHOOLEY, K., Achieving Zero Liquid Discharge in SAGD Heavy Oil Recovery, prepared for presentation at the Canadian International Petroleum Conference, June 11 – 13, 2002. 2. HEINS, W. and PETERSON, D., Use of Evaporation for Heavy Oil Produced Water Treatment, Journal of Canadian Petroleum Technology, Volume 44, No. 1, pp. 26-30, January 2005. 6 FIGURE 1 - Traditional Produced Water Treatment and Steam Generation System OTSG OR DRUM BOILER FIGURE 2 - Vertical Tube Falling Film SAGD Produced Water Evaporator System 7 FIGURE 3 -- Simplified Vapour Compression Falling Film Evaporator System FIGURE 4 Vertical Tube Falling Film Vapour Compression Evaporator Schematic 8 FIGURE 5 - Typical Vertical Tube Falling Film Vapour Compressor Evaporative System 9 Crystals to centrifuge, filter, or drying device FIGURE 6 - Vapour Compression Zero Liquid Discharge Crystallizer 10 FIGURE 7 - Typical Zero Liquid Discharge Crystallizer System 11 FIGURE 8 - MVR SAGD ZLD System Schematic FIGURE 9 - Typical MVR ZLD System 12 Distillate De-Oiled Produced Water Vertical Tube Falling Film Evaporator Drum Boiler 2-5% Blowdown Distillate 100% Quality Steam 1-5% Blowdown Zero Discharge Crystallizer Solids for Disposal FIGURE 10 - Deer Creek Joslyn Phase II Produced Water Treatment and Steam Generation System 13