DEVELOPING A PROTOTYPE FOR SOLAR OPERATED CHILLER By RAGAB KASSEM MAHMOUD ALI 1 B. Sc. - Agric.“Agric. Engineering”, Fac. Agric., Al-Azhar University, 2005. THESIS Submitted in Partial Fulfillment of the Requirements for the Degree Of MASTER OF SCIENCE In AGRICULTURE (Agricultural Engineering) Agricultural Engineering Department Faculty of Agriculture Al-Azhar University Assiut Branch 1434 A.H. 2013 A.D. i PPROVAL SHEET NAME: RAGAB KASSEM MAHMOUD ALI TITLE: DEVELOPING A PROTOTYPE FOR SOLAR OPERATED CHILLER THESIS Submitted in Partial Fulfillment of the Requirements for the Degree Of MASTER OF SCIENCE In AGRICULTURAL SCIENCES (Agricultural Engineering) Agricultural Engineering Department Faculty of Agriculture Al-Azhar University Assiut Branch 1434 A.H. 2013 A.D. Approved By: Prof. Dr. MOHAMED NABIL EL AWADY…………... Prof. Emerit. of Ag. Eng., Fac. of Ag., Ain Shams U. Prof. Emt. Dr. SAMIR AHMED TAYEL……………... Prof. Emerit. of Ag. Eng., Fac., of Ag. Eng., Al-Azhar U., Cairo. Prof. Dr. AHMED M. EL- LITHY ……………………. Prof. of Ag. Eng., Fac. of Ag., Al-Azhar U., Assiut. Dr. MAHMOUD ZAKKY .EL- ATTAR……………… Lec. of Ag. Eng., Fac. of Ag., Ain Shams U. Date: 22/ 9/ 2013 A.D. ii 2 TITLE: DEVELOPING A PROTOTYPE FOR SOLAR OPERATED CHILLER NAME: RAGAB KASSEM MAHMOUD ALI 3 THESIS Submitted in Partial Fulfillment of the Requirements for the degree Of MASTER OF SCIENCE In AGRICULTURE (Agricultural Engineering) Agricultural Engineering Department Faculty of Agriculture Al-Azhar University Assiut Branch 1434 A.H. 2013 A.D. Supervisory Committee: Prof. Dr. HASSAN A. EL RAZIK A. MAWLA…………... Prof. and Head of Ag. Eng. Dpt., Fac. of Ag., Al-Azhar U., Assiut. Prof. Dr. AHMED M. EL- LITHY ………………………... Prof. of Ag. Eng., Fac. of Ag., Al-Azhar U., Assiut. Dr. MAHMOUD ZAKKY .EL- ATTAR…………………… Lec. of Ag. Eng., Fac. of Ag., Ain Shams U. iii 2.1 Importance of post-harvest treatments ...................... 3 2.2 Postharvest agricultural products deterioration .......... 3 2.3 Classification of absorption refrigeration cycles ......... 5 2.3.1 Single-effect absorption system. ........................ 5 2.3.2 Multi-effect absorption refrigeration cycle. ........... 6 2.3.3 The ammonia-water hydrogen cycle ................... 7 2.3.4 Adsorption refrigeration cycle. .......................... 8 5.3.2 Desiccant refrigeration system. ........................ 10 2.4 Chilling solar assissted systems ............................. 11 2.4.1 Vapor compression refrigeration systems. ........... 11 2.4.2 Chiller solar assisted coefficient of performance ... 14 2.5 Chillers solar assissted systems ............................. 21 3.1 Principle and system description ........................... 24 3.2 System configuration: ......................................... 25 3.2.1 Generator: solar flat-plate collector FPC ............ 25 3.2.2 Generator: vessel .......................................... 32 3.2.3 Chiller condenser- Evaporator.......................... 36 iv 3.3 Chilling- solar assisted system overall efficiency ....... 38 3.4 Thermal load and chilling system .......................... 38 3.5 Experimental setup ............................................ 40 4.1 Generator performance ....................................... 44 4.1.1 Generator: FPC thermal performance ................. 44 4.1.2 Generator: vessel thermal performance ............... 49 4.2 Condeser thermal performance.............................. 49 4.3 Evaporatore thermal performance and COP ............. 50 v LIST OF FIGURES FIGURE 2-1: THE EINSTEIN REFRIGERATION CYCLE. .............................................................. 4 FIGURE 2-2: A SINGLE-EFFECT LIBR/WATER ABSORPTION REFRIGERATION SYSTEM. .......................... 5 FIGURE 2-3: A DOUBLE-EFFECT WATER/LIBR ABSORPTION CYCLE. ............................................. 7 FIGURE 2-4: SIMPLE DIAGRAM OF THE ABSORPTION REFRIGERATION SYSTEM. ................................ 8 FIGURE 2-5: (A) THE DESORPTION (REGENERATION) PROCESS AND (B) THE ADSORPTION (REFRIGERATION) PROCESS. .................................................................................................. 9 FIGURE 2-6: DESICCANT COOLING SYSTEM. ..................................................................... 11 FIGURE 2-7: VAPOR COMPRESSION CYCLE....................................................................... 12 FIGURE 2-8: RANKINE REFRIGERATION SYSTEM. ................................................................ 13 FIGURE 2-9: A DOUBLE-EFFECT ABSORPTION CYCLE OPERATES WITH TWO PRESSURE LEVELS. ............... 20 FIGURE 3-1: BASIC VAPOR ABSORPTION REFRIGERATION CYCLE. .............................................. 25 FIGURE 3-2: FLAT-PLATE SOLAR COLLECTOR “FPC”. ........................................................... 26 FIGURE 3-3: FPC ABSORBER PLATE COMPONENTS AND OVERALL DIMENSIONS. .............................. 26 FIGURE 3-4: HEAT TRANSFER THROUGH LAYERS OF AIR, WOOD, GLASS WOOL AND ABSORBER PLATE. ..... 28 FIGURE 3-5: FPC CROSS SECTION OF ENERGY ABSORPTION PLATE AND ITS TWO TRANSPARENT POLYETHYLENE COVERS. ................................................................................. 30 FIGURE 3-6: FPC ABSORBER PLATE AND PLASTIC DUAL COVERS. .............................................. 31 FIGURE 3-7: SOLAR INTENSITY MEASURENING PYRANOMETER MODEL PSP. ................................. 31 FIGURE 3-8: CUP-COUNTER TYPE ANEMOMETER. .............................................................. 32 FIGURE 3-9: GENERATOR STORAGE VESSEL ..................................................................... 33 FIGURE 3-10: GENERATOR STORAGE VESSEL DIMENSIONS. .................................................... 34 FIGURE 3-11: HEAT TRANSFER THROUGH LAYER OF GLASS WOOL, AND GENERATOR VESSEL SURFACE. ..... 35 FIGURE 3-12: CONDENSER –EVAPORATOR DIMENSIONS IN CM. .............................................. 37 FIGURE 3-13: THERMAL LOAD AND CHILLING SYSTEM CALCULATIONS......................................... 39 FIGURE 3-14: CONFIGURATION OF THE EXPERIMENTAL SETUP................................................. 41 FIGURE 3-15: THE SOLAR REFRIGERATOR SYSTEM:1) FLAT PLATE SOLAR COLLECTOR, 2) GENERATOR VESSEL, 3) PRESSURE GAUGES, 4) EXPANSION VALVE. 5) EVAPORATOR-CONDENSER(IMMERSED IN A TANK OF WATER) 6) EVAPORATOR- CONDENSER (DRY) .......................................................... 42 FIGURE 3-17: THE SOLAR REFRIGERATION COMPONENT. ...................................................... 43 FIGURE 3-18: OVERVIEW OF THE SOLAR ASSISTED CHILLING SYSTEM. ......................................... 43 FIGURE 4-1: THE RELATIONSHIP BETWEEN AIR VELOCITY AND HEAT LOSSES................................... 44 FIGURE 4-2: FPC OPTICAL AND THERMAL EffiCIENCIES. ........................................................ 46 FIGURE 4-3: DALY HEAT TRANSFEAR FROM THE FPC TO THE WORKING FLUID IN CHILLING SYSTEM. ........ 47 FIGURE 4-4: THE RELATIONSHIP BETWEEN THE FPC ABOSRBER PLATE TEMPERATURE AND AMMONIA-WATER TEMPERATURE. ........................................................................................... 47 FIGURE 4-5:THE RELATIONSHIP BETWEEN THE FPC ABSORBER PLATE TEMPERATURE AND THE FPC EFFICIENCY. ............................................................................................... 48 vi FIGURE 4-6: HEAT REMOVAL RATE IN RELATION TO THE FPC ABSORBER PLATE TEMPRATURE DURING THE DAY........................................................................................................ 48 FIGURE 4-7: HEAT TRANSFER FROM THE GENERATOR FPC TO VESSEL IN RELATION TO TEMPRATURE DIFFERENCE. .............................................................................................. 49 FIGURE 4-8: HEAT TRANSFER FROM GENERATOR VESSEL THROUGH CONDENSER-EVAPORATOR. ........... 50 FIGURE 4-9 :HEAT TRANSFER THROUGH CHILLING SYSTEM AT SOLAR RADIATION INTENSITIES. .............. 51 FIGURE 4-10: HEAT TRANSFER FLOW FROM FPC ABSORBER PLATE THROUGH CHILLING SYSTEM AT DIFFERENT SYSTEM PRESSURE. .......................................................................... 51 FIGURE 4-11:CHILLING SOLAR ASSISETED SYSTEM EFFECIENCY AT SOLAR INTINSTIES DURING THE DAY TIME. ............................................................................................................ 52 FIGURE 4-12: CHILLING SOLAR ASSISETED SYSTEM ENERGY FLOW AT SOLAR INTENSITIES DURING THE DAY TIME....................................................................................................... 52 FIGURE 4-13: ENERGY TRANSFER THROUGH GENERATOR FPC, GENERATOR VESSEL, AND CONDENSER. .... 53 FIGURE 4-14: THE COEFFICIENT OF PERFORMANCE FOR THE CHILLING SOLAR ASSISTED SYSTEM. ........... 53 FIGURE 4-15: REQUIRED TIME FOR HEAT REMOVAL FROM THE EVAPORATOR WITHOUT LOAD “EMPTY” AND SYSTEM PRESSURE. ....................................................................................... 54 FIGURE 4-16: CALCULATED POTATOES HEAT LOAD AT DIFFERENT AMBIENT TEMPERATURE. ................ 55 FIGURE 4-17: POTATOES THERMAL LOAD ENERGY AND HEAT REMOVAL RESPONSE. ......................... 55 FIGURE 4-18: CALCULATED HEAT LOAD REMOVAL FROM KILOGRAM OF POTATOES AND ENERGY TRANSFER FROM CONDENSING TO EVAPORATING PROCESSES. .................................................... 56 FIGURE 4-19: CHILLING SOLAR ASSISTED POTATOES HOLDING CAPACITIES AT DIFFERENT CHILLING TEMPERATURE LEVELS.................................................................................... 56 FIGURE 4-20: REQUIRED TIME FOR HEAT REMOVAL FROM POTATOES AT DIFFERENT TEMPRATURE LEVELS. 57 FIGURE 7-1: OBSERVATION DURING REFRIGERATION TEST ON JUNE 25, 2011.............................. 78 FIGURE 7-2: ACTUAL AND THEORETICAL SYSTEM CYCLES FOR TEST ON JUNE 25, 2011. .................... 83 FIGURE 7-3.A: OBSERVATION DURING GENERATION TEST ON JUNE 26, 2011 .............................. 78 vii 1 INTRODUCTION Postharvest treatments are crucial in maintaining agricultural production quantity and quality. Egypt production of fruits and vegetables were estimated by 11,750,975 and 21,236,320 billion of Egyptian pounds annually, as stated in the Egyptian statistical survey published in 2010-2011. Due to lack or absence of postharvest treatments, experts evaluate 15.27% of fruit and 45.58% of vegetables drop in marketing value. Kurian (2012) refers 30-40% of the total loss of fresh food production to the inadequate of postharvest treatments and storage conditions. Eckert and Ogawa (1985) reviewed factors contribute to postharvest losses in fresh fruits and vegetables. They concluded that environmental conditions such as heat or drought, mechanical damage during harvesting and handling, improper postharvest sanitation, and poor cooling and environmental control were the most affecting factors in food deterioration. Harvested fresh vegetables and fruits undergo respiration, which involves enzymatic oxidation of sugar in the produce into CO2 and water accompanied by the release of energy. This causes overspending, deterioration and ultimate destruction of the fruit since low temperature retards the activity of enzymes, the commonly accepted measure is to remove the field heat from the product within a short period of time after harvesting (Tomkins and Woreko-Brobby, 1982). Energy supply to refrigeration and chilling systems constitutes a significant role in postharvest treatments in remote areas with poor energy distribution network. Utilizing solar energy in 1 postharvest treatments will reduced the total process costs and production quality and quantity losses. Application of solar assisted cooling saves electricity and thus conventional primary energy sources. It is also leads to a reduction of peak electricity demand, and additional cost savings. Using solar energy technologies is environmentally sound materials that have no ozone depletion and no (or very small) global warming potential (IEA, 2011). The aim of this study is to develop a prototype for dual purpose solar operated chilling and heating postharvest treatment for agricultural applications. 2 2 REVIEW OF LITERATURE 2.1 Importance of post-harvest treatments Terms of the amount of production available to the consumer of vegetables about 14970000 tons/year with the rate loss of the estimated 3044000 tons/year and the amount of production of fruit 6014000 tons/year with the rate loss by 868,000 tons/year and produce citrus 2,656,000 tons/year rate loss was 371,000 tons/year, As well as losses of starches estimated at around 636000 tons/year of total production for the consumer 3,861,000 tons/year (Statistics 2010). Kader (2002) pointed that quality loss can be minimized by using best harvest procedures, rapid cooling, refrigerated storage and proper handling techniques during transportation and distribution to market. 2.2 Postharvest agricultural products deterioration Environmental conditions, mainly temperature, affect the quality of the fresh horticultural produce. High temperature increases produce respiration rate and water loss through transpiration, causing loss in internal fresh quality, shriveling and premature softening (Tanner and Smale, 2005). Jorge (2006) stated that removing field heat can suppress enzymatic degradation (softening) and respiratory activity; slow down or inhibit water loss (wilting); slow down or inhibit the growth of decay-producing microorganisms (molds and bacteria); reduce the production of ethylene as a ripening agent. Widely encountered in air, water, soil, living organisms, and unprocessed food items. Microorganisms cause off-flavors and 3 odors, slime production, changes in the texture and appearances, and the eventual spoilage of foods. Holding perishable foods at warm temperatures is the primary cause of spoilage, and the prevention of food spoilage and the premature degradation of quality due to microorganisms is the largest application area of refrigeration. The Platen and Munters (1928) described a single pressure cycle utilizes ammonia for the refrigerant and water for the absorbent. The water separates the ammonia from the inert gas, hydrogen. A recently uncovered U.S. patent by the famed Albert Einstein (figure, 2-1) and Leo Szilard issued on 1930 discloses another single pressure thermally driven refrigeration cycle which uses butane, ammonia, and water. In the Einstein cycle ammonia acts as an inert gas to lower the partial pressure over the refrigerant, butane, and water later provides separation by absorbing the ammonia. Figure 2-1: The Einstein refrigeration cycle. 4 2.3 Classification of absorption refrigeration cycles 2.3.1 Single-effect absorption system. A single-effect absorption refrigeration system is the simplest and most commonly used design. There are two design configurations depending on the working fluids used. Figure (2-2) shows a single-effect system using non-volatility absorbent such as LiBr/water. Generator Condenser HX Evaporator Absorber Figure 2-2: A single-effect LiBr/water absorption refrigeration system. High temperature heat supplied to the generator is used to evaporate refrigerant out from the solution and is used to heat the solution from the absorber temperature. Thus, is caused as high temperature heat at the generator is wasted out at the absorber and the condenser. When volatility absorbent such as water/NH3 is used, the system requires an extra component called “a rectifier”, which will purify the refrigerant before entering the condenser. As the absorbent used (water) is highly volatile, it will be evaporated together with ammonia (refrigerant). Without the rectifier, this 5 water will be condensed and accumulate inside the evaporator, causing the performance to drop (Aphornratana, 1995).. 2.3.2 Multi-effect absorption refrigeration cycle. The main objective of a higher effect cycle is to increase system performance when high temperature heat source is available. By the term “multi-effect”, the cycle has to be configured in a way that heat rejected from a high-temperature stage is used as heat input in a low-temperature stage for generation of additional cooling effect in the low-temperature stage. Double-effect absorption refrigeration cycle was introduced during 1956 and 1958 (Vliet, Lawson and Lithgow, 1982). Figure (2-3) shows a system using LiBr/water. High temperature heat from an external source supplies to the firsteffect generator. The vapor refrigerant generated is condensed at high pressure in the second-effect generator. The heat rejected is used to produce addition refrigerant vapor from the solution coming from the first-effect generator. This system configuration is considered as a series-flow-double-effect absorption system. If LiBr/water is replaced with water/NH3, maximum pressure in the first-effect generator will be extremely high. Figure (2-2) shows a double-effect absorption system. 6 Generator I HX II Generator II Condenser HX I Absorber Evaporator Figure 2-3: A double-effect water/LiBr absorption cycle. 2.3.3 The ammonia-water hydrogen cycle Watheq (2008) described the main components of the absorption refrigeration system as an absorber, generator, a condenser, an expansion valve, a heat exchanger and a pump. As shown in figure (2-4), Watheq mentioned two kinds of working medium used at the same time in refrigeration and absorption processes. The refrigerant vapor flows to the condenser passing through a vapor-trap and condensed. Liquid refrigerant from the condenser goes through an expansion valve while the pressure is decreased to an evaporation pressure. At the evaporator, cooling effect is achieved by the vaporization of the refrigerant 7 at a low temperature. Refrigerant vapor from the evaporator continues to an absorber and dissolves in a weak refrigerant solution, and it becomes a stronger refrigerant solution, which is called “rich solution”. A pump is the only moving part in this system. Condenser Generator Expansion valve pump Evaporator Absorber Figure 2-4: Simple diagram of the absorption refrigeration system. 2.3.4 Adsorption refrigeration cycle. Watheq (2008) defined an adsorption is a preferential partitioning of substances from a gaseous or liquid phase onto a surface of a solid substrate. This process requires only thermal energy. The principles of the adsorption process provide two main processes, adsorption or refrigeration and desorption or regeneration. In case zeolite and water, as an example, the refrigerant (water) is vaporized by, the heat from cooling space and the generator (absorbent tank) is cooled by ambient air. The 8 vapor from the cooling space is leaded to the generator tank and absorbed by adsorbent (zeolite). a b Figure 2-5: (a) The desorption (regeneration) process and (b) the adsorption (refrigeration) process. The rest of the water is cooled or frozen. In the regeneration process, the zeolite is heated at a high temperature until the water vapor in the zeolite is desorbed out, goes back and condenses in the water tank, which is now acting as the condenser. For a discontinuous process (figure, 2-5:a), desorption process can be operated during daytime by solar energy, and the adsorption or the refrigeration process can be operated during night-time (figure, 2-5:b). The solar energy can be integrated with a generator. The single adsorber is required for a basic cycle. The number of adsorbers can be increased to enhance the efficiency, which depends on the cycle. This process can also be adapted to the continuous process. 9 2.3.5 Desiccant refrigeration system. Daou et al. (2006) stated that as natural or synthetic substances capable of absorbing or adsorbing water vapor due the difference of water vapor pressure between the surrounding air and the desiccant surface. Thus, in desiccant cooling systems desiccants are used to dehumidify the inlet air and then this dry air is cooled and humidified by evaporative cooling and followed sometimes by a vapor compression system for sensible cooling. Since desiccant cooling is utilized to handle latent loads, the vapor compression system’s energy demand decreases. Although the desiccant cooling system’s performance is strongly dependent on weather conditions, energy savings may reach up to 80% for dry climates. Energy savings decrease as humidity ratio increases. A schematic of a desiccant cooling system is presented in figure (2-6). The outside air stream at state 1 is passed through the desiccant wheel. Humidity of the air stream at state 2 is significantly decreased. Since adsorption or absorption of water vapor by the desiccant substance is an exothermic reaction, temperature of the air stream increases. Then by heat wheel the temperature of the air stream is decreased. If heat wheel is not enough for required cooling, vapor compression system should be used in conjunction with heat wheel. Finally, the temperature of the air stream is further decreased and humidity ratio of the air is increased by evaporative cooling according to thermal comfort conditions. A heater is used between state 7 and 8 in order to obtain high temperatures required for regeneration of the desiccant material. Solar energy or waste heat can be used for heating the exhaust air stream. Assuming no need for a vapor compression system. 10 A small amount of electricity is required for rotating the wheels. The desiccant materials for a solid-desiccant system are usually silica gel or Zeolite. For a liquid desiccant system, the desiccant dehumidifier’s hygroscopic aqueous solution can be tri-ethylene glycol (TEG), CaCl2-H2O, LiBr-H2O, LiCl-H2O. Figure 2-6: Desiccant cooling system. 2.4 Chilling solar assissted systems 2.4.1 Vapor compression refrigeration systems. As seen from figure (2-7), the ideal vapor compression cycle consists of four processes: isentropic compression in a compressor; constant pressure heat rejection in a condenser; throttling in an expansion valve; constant pressure heat absorption in an evaporator. 11 Figure 2-7: Vapor compression cycle. Wang (2000) summed up an adsorption ice-making system driven by generation temperatures from 90 to 100 oC with activated carbon–methanol as working pair. This system can reach an evaporation temperature as low as 15.5 o C. Assilzadeh et al. (2005) presented a H2O–LiBr absorption unit using evacuated tube solar collectors. After the modeling and simulation carried out with TRNSYS program, the author concluded that the optimum system for Malaysia’s climate for a 3.5 kW system consists of 35 m2 evacuated tubes solar collector sloped at 20 oC. Wimolsiri Pridasawas (2006) stated that the Rankine refrigeration system is the combination of the Rankine power cycle and vapor compression refrigeration cycle. The turbine work obtained from the Rankine cycle is used to drive the compressor in the vapor compression cycle. A schematic of a 12 Rankine refrigeration cycle is given in figure (2-6) Rankine refrigeration system’s COP is same as vapor compression cycle, but the efficiency of Rankine power cycle is directly related to the temperatures of the sink and source. In order to increase the overall system’s performance, high efficiency flat plate collectors, evacuated tube collectors or parabolic trough collector can be used. fluids such as R114 that give a positive slope of the saturated vapor line on a T-S diagram, the outlet temperature from the turbine is significantly higher than the condensation temperature gives the benefit to preheat the working fluid before it enters the boiler. Electricity Production Condenser Boiler pump Expansion valve Turbine Alienat or compressor Condenser Evaporator Figure 2-8: Rankine refrigeration system. 13 In general Rankine refrigeration systems are complex and suitable for large air conditioning applications system. Working However R114 is not environmental friendly; it has an ozone depleting potential due to a Chlorine atom the speed of the turbine and the compressor should be analogous. The alternator or other equipment that used to adjust the speed should be installed with the system. Abdellatif et al. (2009) the primary objectives of solar heating system are to increase the solar radiation converted into stored thermal energy and to investigate effective uses of that stored energy. A solar collector which is continuously orientated and tilted to maintain an incident solar angle of zero from sunrise to sunset will allow maximum values of both; the effective absorptance of the absorber surface and the effective transmittance of the glass cover to be reached. 2.4.2 Chiller solar assisted coefficient of performance Sierra et al. (1993) used a solar pond to power an intermittent absorption refrigerator with NH3–H2O solution. It is reported that generation temperatures as high as 73 o C and evaporation temperatures as low as –2 oC could be obtained. The thermal COP working under such conditions was in the range of 0.24– .28. Critop (1993) also built a laboratory scale activated carbon– ammonia refrigerator. The generator, of exposed surface area 1.4 m2, consisted of an array of 15 stainless steel tubes, each of 2 m length, 42 mm outside diameter and 1.1 mm thick, rated to 30 bar pressure. About 17 kg of 208 oC activated carbon granules were packed in the tubes. The condenser was a 4 m length of 14 12.5 mm diameter stainless steel tube coiled within a 100-liter water tank. The evaporator was a 10 mm diameter stainless steel coil immersed in 4 liters of water. The evaporator temperature attained was up to - 1 oC and about 3 kg of ice was manufactured. The peak collector temperature for the simulated day tests was 115 o C, and the solar COP was 0.04. Critoph (1994) built a small solid adsorption solar refrigerator in 1994. The collector was 1.4 m2 in area and contains 17 kg of active carbon. It was possible to produce up to 4 kg of ice per day in a diurnal cycle. Critoph(1996) studied a rapid cycling solar /biomasspowered adsorption refrigeration system with activated carbon –ammonia as working pair. The thermal COP was about 0.3 when the initial generator temperature was about 50 o C and evaporating temperature was about 0 oC. Bansal et al. (1997) reported a unit of 1.5 kWh/day using NH3 as refrigerant and IMPEX material (80% SrCl2 and 20% Graphite) as absorbent. Theoretical maximum overall COP of the unit is 0.143, and it depends upon the climatic conditions. Oertel and Fischer (1998) modified a commercially available low temperature (80–90oC) adsorption cooling system for air conditioning application, using methanol/silica gel as working pair for the cold storage of agricultural products at temperatures of 2–4 oC in India. Calculation and test results showed that the COP was about 0.30 when operating the system at a chilled water temperature of -2 oC, a heating water temperature of 85 oC and a condenser temperature of 30 oC. 15 Sumathy and Li (1999) operated a solar-powered ice-maker with the solid adsorption pair of activated carbon and methanol, using a flat-plate collector with an exposed area of 0.92 m2. This system could produce ice of about 4–5 kg/day with a solar COP of about 0.1–0. 12. Hammad and Habali (2000) designed a solar-powered absorption refrigeration cycle using NH3–H2O solution to cool a vaccine cabinet in the Middle East. A year round simulation indicated that thermal COP ranged between 0.5 and 0.65 with generation temperature at 100–120 oC and the cabinet inside temperature at 0–8 oC. Li et al. (2001) built a flat-plate solid-adsorption refrigeration ice maker with activated carbon methanol as working pair for demonstration purposes. The experimental results show that the thermal COP is about 0.45 and solar COP is about 0.12–.14, with approximately 5–6 kg of ice produced per m2 collector. Sumathy et al. (2002) developed a new model of two-stage H2O–LiBr absorption chiller. Test results have proved that the two-stage chiller could be driven by low temperature hot water ranging from 60 to 75 oC, which can be easily provided by conventional solar hot water systems. Compared to the singlestage chiller, the two-stage chiller could achieve roughly the same total COP as of the conventional system with a cost reduction of about 50%. De Francisco et al. (2002) developed and tested a prototype of 2 kW NH3–H2O absorption system in Madrid for solar powered refrigeration in small rural operations. The test results 16 showed unsatisfactory operation of the equipment with COP lower than 0.05. Anyanwu and Ezekwe (2003) designed, constructed and tested a solid adsorption solar refrigerator using activated carbon-methanol as the working pair. Its flat-plate type collector/generator/adsorber used clear plane glass sheet whose effective exposed area was 1.2 m2 with the efficiencies of 11.6–16.4%. The steel condenser tube with a square plan view was immersed in pool of stagnant water contained in a reinforced sand tank. The evaporator is a spirally coiled copper tube immersed in stagnant water. Ambient temperatures during the adsorbate generation and adsorption process varied over 18.5–3 4 oC. The refrigerator yielded evaporator temperatures ranging over 1.0–8.5 oC from water initially in the temperature range 24–28 oC. Accordingly, the maximum daily useful cooling produced was 266.8 kJ/m2 of collector area and the use full cycle and the useful overall COP ranged over 0.056– 0.093 and 0.007– 0.015, respectively. Khattab (2004) developed a solar-powered adsorption refrigeration module with the solid adsorption pair of local domestic type charcoal and methanol. The module consists of a modified glass tube having a generator (sorption bed) a t one end, a combined evaporator and condenser at the other end and simple arrange men t o f plane reflectors to heat the generator. Test results show that, the daily ice production is 6.9 and 9.4 kg/m2 and net solar COP is 0.136 and 0.159 for cold and hot climate respectively. 17 Hildbrand e t al. (2004) the adsorption pair is silica gel– water. Cylindrical tubes function as both the adsorber system and the solar collector (flat-plate, 2 m2 double glazed); the condenser is air-cooled (natural convection) and the evaporator contains 40 Liters of water that can freeze. This ice functions as a cold storage for the cabinet. This system has presented performances with a solar COP of 0.16. Li et al. (2004) developed a no valve solar icemaker. For this system, there are no any reservoirs, connecting valves or throttling valve. Experimental results showed that 6.0–7. 0 kg ice can be obtained under indoor conditions when radiation energy was about 17–20 MJ/m2. For these conditions, the solar COP of this system was about 0.13–.15. In outdoor conditions, the system could produce 4.0 kg ice and the solar COP was about 0.12 when the total insolation energy was about 16–18 M J/m2. And then, a new solar ice maker developed can produce about ice of 4–5 kg each sunny day under the condition of about 18– 22 MJ/m2 solar insolation. Syeda et al. (2005) studied solar cooling system for typical Spanish houses in Madrid. The system consisted of a flat -plate collector array with a surface area of 49.9 m2, a 35 kW nominal cooling capacity single-effect (H2O–LiBr) absorption chiller. This machine operated within the generation and absorption temperature ranges of 57–67 oC and 32–36 oC, respectively. The measured maximum instantaneous, daily average and period average COP were 0.60 (at maximum capacity), 0.42 and .3 respectively. 18 Lemmini and Errougani (2005) built and tested a solarpowered adsorption refrigerator using the pair AC35–methanol (figure, 2-10). The system consists of a flat-plate collector, a condenser and a cold chamber-evaporator. Experimental results showed that the unit can produce cold air even for rainy and cloudy days and the solar coefficient of performance (COP) ranges between 0.05 and 0.08 for an irradiation between 12,000 and 27,000 kJ/m2, a daily mean ambient temperature between 14 and 18 oC and lowest temperature achieved by the evaporator between 5 and 8 oC. Using water/NH3. In contrast to the system for LiBr/water, this system can be considered as a combination of two separated single-effect cycles. The evaporator and the condensers of both cycles are integrated together as a single unit. 19 Condenser Evaporator Rectifie Generator I HX I Absorber I Rectifi Heat of Absorption Generator II HX II Absorber II Figure 2-9: A double-effect absorption cycle operates with two pressure levels. 20 Thus, there are only two pressures level in this system and the maximum pressure can be limited to an acceptable level. Heat from external source supplies to generator II only. As water is an absorbent, there is no problem of crystallization in the absorber. Hence, absorber II can be operated at high temperature and rejects heat to the generator I. This system configuration is considered as a parallel-flow-double-effect absorption system (Kaushik and Chandra 1985). Yeung et al. (1992) designed and constructed a solarpowered absorption air-conditioning system to study the feasibility of utilizing solar power for comfort cooling in Hong Kong. The system consisted of a flat-plate collector array with a surface area of 38.2 m, a 4.7 kW nominal cooling capacity H2O– LiBr absorption chiller, a 2.75 m3 of hot-water storage tank, a cooling tower, a fan-coil unit, and an electrical auxiliary heated. I t had an annual system efficiency of 7.8% and an average solar fraction of 55%. 2.5 Chillers solar assissted systems Critoph and gong. (1992) In this version, two separate adsorption cycles are operated out of phase such that when one adsorber is being heated by the energy source, the other cools to ambient temperature, reabsorbing its refrigerant and producing useful cooling in the evaporator. The laboratory prototype rapid cycling ice maker consisted of two adsorbers: each consisting of seven 2 m long stainless steel tubes, with 1.04 kg of activated carbon in each tube, packed in a hexagonal cell and manifold together. Each hexagonal cell was contained in an outer copper shell of 150 mm diameter that contained steam at 2 bar pressure 21 during the heating phase. Each individual tube had a smaller diameter concentric tube that carried cooling water during the cool down mode. The condenser was water cooled and the evaporator consisted of a simple stainless steel coil soldered around a copper box containing up to 5 liters of water. The results of experiments conducted with this unit showed that the half cycle times for optimum ice production varied from 16 min with steam at 150 oC to 26 min with steam at 100 oC. Abou Karima (1992) designed and tested of a refrigeration system utilizing solar energy. He concluded that the intermittent absorption refrigeration system used ammonia-water as a working fluid by two methods for heating the working fluid in the generator, the first is the kerosene burner and the second is the solar energy. Erickson DC (1994) illustrates the use of solar energy in remote, non-grid-connected areas. The system consists of seven double intermittent ammonia–water absorption cycle ice makers, three of which are ground-mounted to generate ice for processing fish and transporting it to market, and four, mounted on the root of the storage building, to provide ice to cool a storage tank. Each double intermittent ammonia–water absorption cycle device is supplied with heat by a 12 m2 aperture area parabolic trough concentrating solar collector and has produced about 68 kg of ice daily since late 1992. The 84 m2 total parabolic trough solar collector area provides annually a 519 GJ heat input giving an annual 72.8 GJ of refrigeration. Jianlin and Yanzhon. (2007) The theoretical analysis on the performance characteristics was carried out for the novel cycle 22 with the refrigerant R141b. Compared with the conventional cycle, the simulation results show that the coefficient of performance (COP) of the novel cycle increases, respectively, by from 9.3 to 12.1% when generating temperature is in a range of 80 –160 oC, the condensing temperature is in a range of 35– 45 oC and the evaporating temperature is fixed at 10 oC. Especially due to the enhanced regeneration with increasing the pump outlet pressure, the improvement of COP of the novel cycle is approached to 17.8% compared with that in the conventional cycle under the operating condition that generating temperature is 100 oC, condensing temperature is 40 oC and evaporating temperature is 10 oC. Therefore, the characteristics of the novel cycle performance show its promise in using low grade thermal energy for the ejector refrigeration system. Zhang and Noam (2007) proposed several novel systems, based on ammonia–water working fluid. The proposed plants operate in a fully-integrated combined cycle mode with ammonia–water Rankine cycle(s) and an ammonia refrigeration cycle, interconnected by absorption, separation and heat transfer processes. It was found that the cogeneration systems have good performance, with energy and energy efficiencies of 28% and 55-60%, respectively, for the base-case studied (at maximum heat input temperature of 450 oC). 23 3 MATERIALS AND METHODS 3.1 Principle and system description Vapor absorption refrigeration cycle as shown in figure 3-1, consists in its basic configuration of a generator, condenser, evaporative, and absorber. A mixture of absorbent “water” and refrigerant “ammonia” fluids concentrated at 50% used as a working fluid. In the generator, heat is supplied from the solar flat- plate collector “FPC” to the fluids mixture to drive off vapor refrigerant and, as a result, the remaining mixture becomes diluted, poor in refrigerant, and flows to the absorber (appendix I). High-pressure vapor refrigerant flows to the condenser where it condenses to enter an expansion valve that reduces its pressure. The outlet of the expansion valve leads to the evaporator into which the liquid refrigerant flows and removes heat at low pressure turning into vapor again. In the absorber, the refrigerant vapor is absorbed into the poor liquid mixture. Absorber feeds from its two inlets, one for the refrigerant vapor that flows from the evaporator and the other is for the poor mixture that flows from the generator after passing through an expansion valve. Through the absorption process, heat is released due to the exothermic absorption reaction. The released heat is removed by a water-cooling medium. Finally, absorption process causes the mixture to become rich again in refrigerant. The circulating control valve, then, raises the pressure of the rich liquid mixture delivering it to the generator to repeat the cycle. 24 Figure 3-1: Basic vapor absorption refrigeration cycle. 3.2 System configuration: 3.2.1 Generator: solar flat-plate collector FPC The solar flat-plate collector has been built with major purpose to collect as much solar energy as possible at lower total cost using domestic materials. FPC performance tests were conducted at Asyut governorates, Egypt. Latitude 27.19 and longitude 31.18, with 14.08 hours daylong and G t = 8200 Wh /m2 per day for solar declination angle of 23.41°. 3.2.1.1 Generator: FPC dimensions and constructions The FPC main dimensions are illustrated in figure 3-2. 25 142 150 15 122 130 cm DIM in cm Figure 3-2: Flat-plate solar collector “FPC”. 3.2.1.2 Generator: FPC absorber plate The energy absorber plate transfers collected energy to the mixture fluids. The absorber plate was made of one millimeter thick black-coated steel sheet for efficient heat transfer. Fluids mixture were running through a steel tube, 2.5 cm in diameter, forming ten rows bounded to the absorber sheet by means of steel clips as shown in figure 3-3. 2.5 cm 0.25 cm 14.2 cm Steel bonding clip 0.1 cm FPC absorber dimensions length [Lp]: FPC width [wp]: FPC gross area [Ac]: FPC absorber area [Ap]: number of tubes: tubes inner diameter: tubes outer diameter: tube-to-tube spacing: 142 122 1.95 1.73 10.0 2.0 2.5 14.2 cm cm m2 m2 cm cm cm Figure 3-3: FPC absorber plate components and overall dimensions. 26 System fluids and its mixture flow rate were measured by the volume-time measuring method. Volumes were measured in 500 ml glass cup accurate to ±4 at 20 °C, and time was recorded with digital stop-watch accurate to 1/60 s. System pressure was measured by three stainless steel 25 bar pressure gauges. 3.2.1.3 Generator: FPC efficiency The FPC was constructed according to the assumption that the FPC performs under steady state conditions, thus, the thermal performance analysis can be used to maximize system efficiency 𝛈𝐅𝐏𝐂 (equation 3-1 and 19) using the system analysis methods described by Duffie and Beckman (1991); Kalogirou (2004); and Ashrea (2005) as follows: 𝜼𝑭𝑷𝑪 = ∫ 𝑸𝑼 𝒅𝒕 ...................................................... Equation 3-1 𝑨 ∫ 𝑰𝒅𝒕 where 𝐐𝐮 is the useful energy gain in a solar collector “W”, I is the solar radiation flux incident on the tilted surface of the FPC “W/m2”, 𝑸𝒊 = 𝑰. (𝝉𝜶). 𝑨 ................................................... Equation 3-2 where Qi is the absorbed solar energy, and A is the surface area of collector (m2), 𝝉 is the transmittance of the FPC covers, and 𝜶 is the absorptance of the FPC plate. Overall heat transfer coefficient U, was determined by the equations 3-7 to 10 (Awady, 1999). 𝑸𝒐 = 𝑼𝑨(𝑻𝒂 − 𝑻𝒎 )........................................... Equation 3-3 Q u = Q i − Q o = I(τα)A- UA(Ta − Tm ) 𝑸𝒖 = 𝒎𝑪𝒑 (𝑻𝒉 − 𝑻𝒄 ) ........................................ Equation 3-4 where 𝐐𝐢 is the collector heat input “W”, 𝐐𝐨 is the solar collector overall heat losses “W”, m is the fluid mass flow rate 27 (liters/s), 𝐓𝐜 is the temperature of fluid “oK”, 𝐓𝐡 is the temperature of hot fluid “oK”, Ta is the FPC average temperature “oK”, Tm is the temperature of ambient still air “oK”, and 𝐜𝐩 is the fluid heat capacity “kJ/kg °K”. 3.2.1.4 Generator: FPC thermal losses FPC average temperature is difficult to measure through the different components and layers, which differs in its thermal properties, as shown in figure 3-4, rather than evaluating the collector heat removal factor FR. Equations 3-5, and 3-6 describe FR calculation (appendix A). x1 x2 x3 x4 Tf T1 T2 T3 T4 T5 Tm Figure 3-4: Heat transfer through layers of air, wood, glass wool and absorber plate. 𝑭𝑹 = 𝒎𝑪𝒑 (𝑻𝒉 −𝑻𝒄 ) 𝑨(𝑰(𝝉𝜶)− 𝑼(𝑻𝒄 −𝑻𝒎 )) .................................... Equation 3-5 𝑸𝒖 =𝑭𝑹 𝑨(𝑰(𝝉𝜶) − 𝑼(𝑻𝒄 − 𝑻𝒎 ))................. Equation 3-6 𝑹=∑ 𝟏 𝑼𝑨 = 𝟏 𝑨𝟏 𝒉𝒂 + 𝑿𝟏 𝑨𝟏 𝑲 𝟏 +. . 𝑿𝒏 𝑨𝒏 𝑲 𝒏 + 𝟏 𝑨𝒏 𝒉𝒃 ...... Equation 3-7 𝑹 = 𝑹𝒂 + 𝑹𝒃 + 𝑹𝟏 + 𝑹𝟐 +𝑹𝒏 ........................ Equation 3-8 R overall = R glass wool+ R wood ............................... Equation 3-9 𝑼=∑ 𝟏 𝑨𝑹𝒐𝒗𝒆𝒓𝒂𝒍𝒍 ...................................................... Equation 3-10 28 where R is the thermal resistance of insulation “°K/W”, R1 is the thermal resistance of inner layer of insulation “°K/W”, R2 is the thermal resistance of second layer of insulation “°K/W”, Rn is the thermal resistance of nth layer of insulation “°K/W”, RS is the thermal resistance of outer surface of insulation “°K/W”, hb is the surface coefficient of outer surface “W/m2 °K”, ha is the surface coefficient of inner surface “W/m2 °K”, kI is the thermal conductivity of inner layer of insulation “W/m °K”, k2 is the thermal conductivity of second layer of insulation “W/m° K”, and kn is the thermal conductivity of nth layer of insulation “W/m °K”. 3.2.1.5 Generator: FPC thermal gain Egypt is one of countries with major potential of solar power (appendix B). Estimating the average of total solar radiation on the inclined surfaces of solar collector can be found using equations 3-11 to 18. 𝑰 = 𝑰𝒃 𝑹𝒃 + 𝑰𝒅 𝑹𝒅 + (𝑰𝒃 + 𝑰𝒅 )𝑹𝒓 ................. Equation 3-11 𝑰𝒅 = 𝑪 𝑰𝒃𝒏 ............................................................. Equation 3-12 𝑰𝒃𝒏 = 𝑨 𝑬𝒙𝒑 ( −𝜷 ) 𝒄𝒐𝒔 𝜽 .............................................. Equation 3-13 𝑰𝒃 = 𝑰𝒃𝒏 𝒄𝒐𝒔 𝜽 ................................................... Equation 3-14 𝑰𝒈 = 𝑰𝒃 + 𝑰𝒅 ....................................................... Equation 3-15 𝑹𝒃 = 𝝎𝒔𝒏 𝒔𝒊𝒏 𝜹 𝒔𝒊𝒏(𝝓−𝜷)+𝒄𝒐𝒔 𝜹 𝒔𝒊𝒏 𝝎𝒔 𝒄𝒐𝒔(𝝓−𝜷) 𝝎𝒔 𝒔𝒊𝒏 𝝓 𝒔𝒊𝒏 𝜹+𝒄𝒐𝒔 𝝓 𝒄𝒐𝒔 𝜹 𝒔𝒊𝒏 𝝎𝒔 . Equation 3-16 𝑹𝒅 = (𝟏 + 𝒄𝒐𝒔 𝜷)/𝟐 ....................................... Equation 3-17 𝟏−𝒄𝒐𝒔 𝜷 𝑹 𝒓 = 𝝆𝒈 ( 𝟐 )............................................... Equation 3-18 where A, B, C constants dependent the number of day and month, 𝜽 is zenith angle 𝑰𝒃𝒏 , 𝑰𝒅 and 𝑰𝒃 are the diffuse radiation and direct solar radiation respectively, where 𝝎𝒔 is sun rise 29 angle , 𝜷 collector tilt angle, 𝝓 latitude angle and 𝜹 declination angle, and 𝝆𝒈 is the reflectance of ground. FPC efficiency, equation 3-18, varies depending on inlet fluid temperature “Tc” relative to the ambient air temperature “Tm” and was calculated according to the equation 3-18 𝜼𝑭𝑷𝑪 = 𝑭𝑹 (𝝉𝜶) − 𝑭𝑹 𝑼 ( 𝑻𝒄 −𝑻𝒎 𝑰 ) ..................... Equation 3-19 3.2.1.6 Generator: FPC thermal and optical losses To minimize the heat losses from the FPC according to previous equations, a wooden frame and glass-wool layers were used to cover back and sides of the collector, figure 3-4. Heat transfer overall thermal conductivity will be the sum of the values of conductivity of air, wood glass wool, and absorber layers showed in figure 3-6, and solved by equations 3-7 to 10 (Awady, 1999). Figure 3-5: FPC cross section of energy absorption plate and its two transparent polyethylene covers. Polyethylene covers configuration and characteristics are illustrated in figure 3-7. 30 Polyethylene cover # 1 Polyethylene cover # 2 Iron absorbance plate Insulation material Properties of cover material -Plastic (Polyethylene) Solar spectrum refractive index: Transmittance: Long-wave absorbance: Long-wave transmittance: Number of covers: Cover-plate air spacing: Cover 1 – cover 2 air spacing: Plate material plain carbon steels conductivity: Thickness: Solar spectrum absorbance: Long-wave emittance: 1.46 0.70 0.05 0.78 2.00 6.00 cm 2.50 cm 60.50 W/m K 0.10 cm 0.88 0.15 Figure 3-6: FPC absorber plate and plastic dual covers. System temperatures were recorded by a glass-mercury thermometer. Ranged from -10 to 200 oC, with accuracy of 1oC. A Pyranometer model PSP was used to measure the solar radiation sensitive to 9 µV per W/m2. The Pyranometer readings were linear to ±0.5% in measurement ranged from 0 to 2800 W/m2, figure 3-7. Figure 3-7: Solar intensity measurening pyranometer model PSP. 31 The system ambient air speed was measured by a cupcounter type anemometer with accuracy of 1 m/s (±5%) in the measuring range 1- 67 m/s, as illustrated in figure 3-8. Figure 3-8: Cup-counter type anemometer. 3.2.2 Generator: vessel Generator vessel is the system component where chilling liquid fluids gain thermal energy. Heat is supplied from the FPC to the fluids mixture to drive off high-pressure vapor refrigerant to the condenser. And, as a result, the remaining mixture becomes diluted, poor in refrigerant, and flows back to the absorber. Since water–ammonia mixture chemically reacts with traditional materials used to construct FPC systems, such as copper or brass, the entire system was fabricated out of steel. 32 To the condenser The rectifying Charging line From the solar collector Pressure gauge Insulation From the evaporator To the solar collector Figure 3-9: Generator storage vessel Generator vessel was made of cylindrical steel pipe of 12.88 cm diameter, and 60 cm in height. The pipe was selected with 0.4 cm thick to withstand high pressure resulted from vapor expansion. Generator vessel -as shown figure 3-9 was leveled above the top of the FPC for circulating the fluids by gravitational force at desired flow rate. Generator volume = 𝝅𝑫𝟐 𝟒 𝑳 ............................. Equation 3-20 3.2.2.1 Generator: vessel thermal losses Thermal loss form natural convection represented as heat transfer coefficient hc, depends on: 1) fluid thermal properties: density𝝆, viscosity𝝁, conductivity k, specific heat at constant pressure cp and coefficient of thermal expansion 𝜷. 2) generator dimensions: diameter D and length L. 3) environmental factors: generator and ambient air temperature difference ∆T, and the gravitational acceleration g. 33 Figure 3-10: Generator storage vessel dimensions. Experimentally, convection heat transfer coefficient can be described in factors grouped in dimensionless numbers Nusselt number (𝑵𝒖) = Prandtl number (𝑷𝒓) = Grashof number (𝑮𝒓) = 𝒉𝒄 𝑫 𝑲 𝒄𝒑 𝝁 𝑲 ......................... Equation 3-21 .......................... Equation 3-22 𝑫𝟑 𝝆𝟐 𝒈𝜷∆𝑻 𝝁𝟐 ................ Equation 3-23 (Nu) = K(Pr)k(Gr)m(L/D)n ............................ Equation 3-24 The rate of convection-heat transfer can be obtained from calculating Nusselt number, by evaluating of K, k, m, n, (McAdams, 1954).The natural convection about vertical cylinders can be found from equations (Nu) = 0.53(Pr.Gr)0.25 ....................................... Equation 3-25 (Nu) = 0.12(Pr.Gr)0.33 ....................................... Equation 3-26 34 Equation 3-25 for the range 104 < (Pr.Gr) < 109 and equation 3-26 for the range 109 < (Pr.Gr) < 1012 3.2.2.2 Generator: vessel efficiency Generator vessel efficiency is a ratio of gained energy by the vessel heat exchanger 𝐐𝐠𝐯 to the input thermal energy 𝐐𝐮 (equation 8) gained from the FPC. The generator vessel efficiency ηgv , was calculated according to equation 𝜼𝒈𝒗 = 𝑸𝒈𝒗 𝑸𝒖 ............................................................ Equation 3-27 The generator vessel net energy gain Qgv, was obtained by equation 3-27. 𝑸𝒈𝒗 = 𝑸𝑼 − 𝑸𝒐 .................................................. Equation 3-28 𝑸𝒈𝒗 = 𝑼𝒈𝒗 𝑨 ∆𝑻 ................................................. Equation 3-29 𝑸𝑳 = 𝑻𝒊 −𝑻𝒐 ∑𝑹 ........................................................... Equation 3-30 r3, To Mineral wool r2 r1, Ti Iron cylinder T3 T2 T1 k2 k1 Figure 3-11: Heat transfer through layer of glass wool, and generator vessel surface. Σ R = R conv + R cyl + R insulation + R conv ............ quation 3-31 𝑹𝒄𝒐𝒗 𝒐 = 𝟏 𝑨𝒐 𝒉𝟎 .......................................................... Equation 3-32 𝑹𝒊𝒏𝒔𝒖𝒍𝒂𝒕𝒊𝒐𝒏 = 𝒓 𝑳𝒏 𝟑 𝒓𝟐 𝟐𝝅𝑲𝟐 𝑳 ........................................... Equation 3-33 35 𝒓 𝑳𝒏 𝟐 𝒓𝟏 𝑹𝒄𝒚𝒍 = 𝟐𝝅𝑲𝟏 𝑳 𝑹𝒄𝒐𝒗 𝒊 = 𝑼𝒈𝒗 = 𝟏 𝑨𝒊 𝒉𝒊 ........................................................ Equation 3-34 .......................................................... Equation 3-35 𝟏 𝒓 𝟏 𝒓𝒊 𝒍𝒏(𝒓𝒐 ⁄𝒓𝒑 ) 𝒓𝒊 𝒍𝒏(𝒓𝒑 ⁄𝒓𝒊 ) + + + 𝒊 +𝑹𝒇 𝒉𝒊 𝒌𝒊𝒏𝒔𝒖𝒍 𝒌𝒑𝒊𝒑𝒆 𝒓𝒐 𝒉𝒐 ............... Equation 3-36 where, mw is the mass of fluid in the storage tank “kg”, Tke and Tkb are the fluid temperatures in the generator vessel at the end and the beginning of each cycle “°K” respectively. 3.2.3 Chiller condenser- Evaporator Assuming that the heat-transfer coefficient is independent of the fluid constant temperature. 3.2.3.1 Condenser –Evaporator: dimension Two overlapping cylinders represent the condenser and the evaporator vessels as shown in figure (3-12). Outer cylinder is 30 cm in diameter and 40 cm of length. The inner cylinder is 10 cm in diameter and was cooled by running water in the outer cylinder space in the generation process. While in refrigeration process, the inner cylinder works as evaporator (without the cooling process and the outer cylinder is empty of water). 36 Absorber vessel Generator vessel Pressure gauge Expansion valve Water outlet Water cooling tank Insulation Water inlet Figure 3-12: Condenser –Evaporator dimensions in cm. 3.2.3.2 Condenser –Evaporator: efficiency In each one of the performed experiment the temperature of the cold fluid (water) and the hot vapor of ammonia was recorded and the efficiency of the condenser was estimated by Helmut Wolf (1983) equation for heat transfer 𝜼𝒄 = ( 𝑻𝒄𝒐 −𝑻𝒄𝒊 𝑻𝒉𝒊 −𝑻𝒄𝒊 )𝟏𝟎𝟎 .............................................. Equation 3-37 where Tco, Tci are the outlet and the inlet temperature of the fluid respectively “°K”, Thi is inlet temperature of the “oK”. According to Kassem et al. (1993) in order to calculate the effective cooling produced, it is necessary first to measure the maximum and minimum temperature of load and Qe can be calculated from equation 3-48. 𝑸𝒆 = 𝑾𝑷 𝑪𝑷𝑳 (𝑻𝒎𝒂𝒙 − 𝑻𝒎𝒊𝒏 )........................... Equation 3-38 37 where Qe is the total cooling obtainable “kJ”, Wp is the thermal mass load “kg”, CpL is the specific heat of load material “kj/kg”, Tmax is initial temperature of thermal load at which the cooling process starts °C, and Tmin is the minimum load temperature that can be reached °C. 𝑸𝒆 = 𝒉𝒗 − 𝒉𝑳 ...................................................... Equation 3-39 where hL is the enthalpy of liquefied ammonia at condensation temperature and pressure (kJ), and hv is the enthalpy of ammonia vapor at vaporization temperature and pressure (kJ). The cooling ratio of the cycle measures the performance of the system and is defined in equation 3-48. 𝑪𝒐𝒐𝒍𝒊𝒈 𝒓𝒂𝒕𝒊𝒐 = 𝑸𝒆 𝑸𝑼 ..................................... Equation 3-40 where Qe is the cooling available during refrigeration period, and Qa is the heat absorbed by ammonia-water in collector during regeneration process. 3.3 Chilling- solar assisted system overall efficiency The performance of the solar refrigerator is defined as mentioned by in equation (3-41) Mansoori and Patel (1979). 𝑪𝑶𝑷 = 𝜼𝑭𝑷𝑪 𝜼𝒈 𝜼𝒄 ........................................... Equation 3-41 3.4 Thermal load and chilling system Thermal load calculations summary is illustrated in figure (3-13). For experimental setup, the calculations of thermal load will cover field heat, heat of respiration, and heat leakage for potatoes crop. 38 Figure 3-13: Thermal load and chilling system calculations. 39 3.5 Experimental setup Experiments were conducted in Agricultural Engineering Department, Faculty of Agriculture, Al-Azhar University, Assiut branch. At the commencement of the generation process, valves I. III and V are closed and valves I is opened. The solar flat plate collector gain causes the ammonia-water mixture to heat up. Circulation of the fluid is up the pipes, and into the header than to the generation storage vessel. Ammonia vapor rises out of solution, than rectifying column and into condenser. At the condenser, the ammonia vapor condenses. At the end of the generation period, the condenser is isolated from the generator by closing valve I and the temperature the system allowed cooling to ambient conditions. The refrigeration period is started by opening valve III so liquid ammonia in the evaporator vaporizes back to the absorber, where it is reabsorbed by the weak solution. The evaporation of the ammonia extracts heat from cooling load in the box surrounding the evaporator sufficient heat is removed to chill the products. A photograph of the solar refrigeration is shown in figure (3-14), and the engineering drawing as shown in figure 3-15. 40 a-Generation b- Refrigeration Figure 3-14: Configuration of the experimental setup. 41 Figure 3-15: The solar refrigerator system:1) flat plate solar collector, 2) generator vessel, 3) pressure gauges, 4) expansion valve. 5) evaporator-condenser(immersed in a tank of water) 6) evaporator- condenser (dry) The detailed description of the essential parts of the solar refrigeration is shown in figure (3-17 and 18). These parts are flat plate solar collector, Generator storage vessel, Evaporator- 42 condenser (immersed in a tank of water) and Evaporatorcondenser (dry). Figure 3-16: The solar refrigeration component. Figure 3-17: Overview of the solar assisted chilling system. 43 4 RESULTS AND DISCUSSIONS 4.1 Generator performance 4.1.1 Generator: FPC thermal performance 4.1.1.1 Air speed thermal removal rate In FPC energy losses occur by natural and forced convection, as well as radiation. The FPC thermal losses were minimized by using two insulation materials. A wooden frame -4 cm thick- with thermal conductivity of 0.16 W/m°K. A glass wool layer -4 cm thick-with thermal conductivity of 0.0052 W/m°K. The FPC overall thermal condactivity at sides and bottom was 0.17 W/m°K , as illustrated in equations 3-7, 8, 9. Thermal losses (kWh) Figure (4-1) shows measured thermal losses from air flow around the FPC. The thermal losses were estimated by 2.0, 3.0, and 1.2 kWh for air speeds ranged between 1-4, 4-21, and 21-30 km/h respectively. Appendix A shows the Egypt climate graph, and air speed according to month of the year. 0.45 0.40 0.35 0.30 0.25 0.20 0.15 0.10 0.05 0.00 0.4 heat removal rate= 1,2 k Wh/ km/h 0.3 0.2 heat removal rate= 3.0 k Wh/ km/h 0.1 heat removal rate= 2.0 k Wh/ km/h 0 5 10 15 20 Air speed (km/h) 25 30 Figure 4-1: The relationship between air velocity and heat losses. 44 4.1.1.2 Generator: FPC: optical efficiency To maintain FPC top thermal loss at minimum level. FPC was covered by a dual polyethylene-plastic covers. The amount of absorbed solar energy by the FPC covers depended on the effective transmittance (solar spectrum τ= 0.7, and long-wave τ= 0.78), reflective index (n= 1.46), and absorptance (α =0.05) of the dual polyethylene plastic covers. Two transparent polyethylene-covers were used to reduce convection losses from the FPC through the restraint of the stagnant air layer between the absorber plate and the transparent covers. It also reduces radiation losses from the collector as the covers are transparent to the short wave radiation received by the sun but it is nearly opaque to longwave thermal radiation emitted by the absorber plate. 4.1.1.3 Generator: FPC overall heat removal coefficient The generator FPC overall heat removal coefficient U was 8.775 according to equation 3-10. FPC overall heat removal factor was 8.755 W/m2 °C, measured at solar intensity of 1002 W/m2, air ambient temperature 34 °C, air speed 5.7 m/s, and relative humidity 70%. 4.1.1.4 Generator: FPC overall heat removal factor FR FPC overall heat removal factor was used instead of FPC average temperature which is difficult to measure. FR importance is to measure effectiveness of thermal insulation materials as shown from the efficiency curve slope in figure (4-2). FPC overall heat removal factor FR was 0.3971 according to equation (3-5). 45 1.00 = −1,8215 0.80 = −5,3411 𝛈 𝐅𝐏𝐂 0.60 (𝑇𝑎𝑣 −𝑇𝑎 ) 2 − 𝐺𝑡 5,2294 (𝑇𝑎𝑣 −𝑇𝑎 ) 𝐺𝑡 + 0,2591 (𝑇𝑎𝑣 − 𝑇𝑎 ) + 0,2606 𝐺𝑡 0.40 0.20 theraml loss = 5.3411 0.00 0 0.01 0.02 0.03 0.04 0.05 0.06 Figure 4-2: FPC optical and thermal efficiencies. FPC is characterized by the intercept value of the efficiency curve, which reperesent optical efficiency of the FPC top cover materials (0= FR (𝜏𝛼) = 0.26). Typical value of the 0 for standard FPC type ranges between 0.65-0.80. Thermal insulation effectivness was found by the slope of the efficieny curve represeneted by FRU and equals to 5.3 W/m2 °C. Typical value of the FRUL for standard FPC type ranges between 3-8 W/m2 °C. Figure (4-3) illustrates the relationship of gained temperature of the working fluid measured at different time of the day. Figure (4-4) illustrates the relationship between the FPC absorber plate temperature TP, and ammonia-water mixture temperature Taw. 46 Temperature o C 100 90 80 70 60 50 40 30 9 AM 10 AM 11 AM 12 PM 1 PM 2 PM Time "hours" Figure 4-3: Daly heat transfear from the FPC to the working fluid in chilling system. Ammonia -water temperature oC 100 80 60 40 20 0 50 70 90 Plate temperature oC 110 Figure 4-4: The relationship between the FPC abosrber plate temperature and Ammonia-water temperature. 4.1.1.5 Generator: FPC thermal performance The generator FPC efficiency curver intercept with FPC absorber plate temprature at temprature euillpruim point. Temprature equilibruim means that usefule energy is no longer removed by the working fluid. That state of equilibrium can be reached when the working fluid is stoped to circulate through 47 the system. The equilibruim point was emerged when FPC absorber plate temprature was 93 °C, as shwon in figure (4-5). 30 25 20 15 10 5 0 44 54 64 74 84 94 FPC absorber plate temperature in °C 30 𝛈 𝐅𝐏𝐂 25 20 15 10 5 0 9 AM 10 AM 11 AM 12 PM 1 PM Time of the day. 100 90 80 70 60 50 40 30 20 2 PM Figure 4-6: Heat removal rate in relation to the FPC absorber plate temprature during the day. 48 Plate temperature oC Figure 4-5:The relationship between the FPC absorber plate temperature and the FPC efficiency. 4.1.2 Generator: vessel thermal performance To minimize thermal loss form generator vessel, a glass wool layer was cover the exposed surface of the generator vessel. Measurements were taken to calculate the amount of energy passed through the generator. Figure (4-7), showed the energy delivered to the generator vessel from the generator FPC. It was found that increased temperature difference will decrease the amount of useful energy passed through the generator vessel. The generator vessel heat transfer was decreased from 98% to 22.8% with increase temperature difference from 9 to 44 °C. generator FPC ηgenerator 300 1 250 0.8 generator vessel Energy W/h generator vessel 200 0.6 150 0.4 100 0.2 50 0 0 0 10 20 30 40 Tgenerator - T ambient in °C 50 Figure 4-7: Heat transfer from the generator FPC to vessel in relation to temprature difference. 4.2 Condeser thermal performance results of this experiment that the efficiency were varied between 55 to 25% through the day hours (appendix C). Figure (4-8) illustrates the energy gain from the generator 49 vessel to the condenser as a function of the temprature difference of fluid. 300 Energy W/h 250 200 150 100 50 0 1.0 2.3 2.0 1.7 Two - Twi 2.5 3.0 Figure 4-8: Heat transfer from generator vessel through Condenser-Evaporator. Energy losses depends on the difference between inlet and outlet temperature of the cold fluid and the difference between inlet temperature to each of cold and hot fluid during the process. Figure (4-9) showed the system temprature changed according to solar intensity during one day of operation (one cycle of genration and evaporation, appendices J and k). The system pressure changed as a function of system energy (figure 4-10). 4.3 Evaporatore thermal performance and COP Solar energy flows through the chilling system at different rates. System construction materials, system thermal insulations, fluids, and environmental factors are crucial in determining the system overall efficiency. Figure (4-11) demonstrate an efficiency comparison for the generator FPC, generator vessel, and for the condenser-evaporator, at different solar intensities (appendices E through H). 50 1200 90 80 900 Temperature °C 70 60 600 50 40 300 Solar radiation W/m2 100 30 20 0 9AM 10AM 11AM 12PM 1PM 2PM Time 12 80 10 Temperature oC 100 8 60 6 40 4 20 2 0 Pressure kg/cm2 Figure 4-9 :Heat transfer through chilling system at solar radiation intensities. 0 9 AM 10 AM 11 AM 12 PM 1 PM 2 PM Time Figure 4-10: Heat transfer flow from FPC absorber plate through chilling system at different system pressure. At average performance, the generator FPC delivered a 14.3% of the total available solar energy in one day of tests. While generator vessel passes 98% from the generator FPC energy or 13% from the total solar intensity to the condenserevaporator section. Net energy of the condenser unit reached 51 1.20 1.00 Efficiency % 0.80 0.60 0.40 0.20 0.00 8 AM 9 AM 10 AM 12 PM 1 PM Time 1800 1600 1400 1200 1000 800 600 400 200 0 2 PM Solar intensity (Gt) W/m2 55% form the energy delivered form generator vessel, and equals to 4.43 % from the total solar intensity (figure 4-12 and 4-13). Enrgy gain "W" 300 2000 250 1500 200 150 1000 100 500 50 0 8 AM Solar intensty (Gt) W/m2 Figure 4-11:Chilling solar assiseted system effeciency at solar intinsties during the day time. 0 9 AM 11 AM 12 PM Time 1 PM Figure 4-12: Chilling solar assiseted system energy flow at solar intensities during the day time. 52 9027.262872 1130.29094 1288.84395 399.782342 Figure 4-13: Energy transfer through generator FPC, generator vessel, and condenser. solar intensity "W/m2" 1800 0.14 1600 0.12 1400 0.1 1200 1000 0.08 800 0.06 600 0.04 400 0.02 200 0 0 COP, and ton of refrigeration The chilling-solar assisted system coefficient of performance COP relationship as found in figure (4-14) reached its maximum value at 0.21 (equivalent to 0.03 ton of refrigeration) and decreased as system temperature increased. 9:00 AM 10:00 AM 11:00 AM 12:00 PM 1:00 PM 2:00 PM Time Figure 4-14: The coefficient of performance for the chilling solar assisted system. 53 35 30 25 20 15 10 5 0 8 7 6 5 4 3 2 1 0 0 50 100 150 200 Chilling time "min" Pressure kg/cm2 Temprature °C Chilling solar assisted system was able to reduce evaporator temperature form 30 °C to 4 °C within 100 minutes without load as illustrated in figure (4-15). 250 Figure 4-15: Required time for heat removal from the evaporator without load “empty” and system pressure. Field growing crops suffered from heat gain of respiration, and from the surrounding environment. Calculated heat load for one kilogram of potatoes showed increase of energy load form 25 W to 35.4 W with increasing ambient air temperature form 5 °C to 25 °C (figure 4-16). Chilling solar assisted system was constructed for fast removal of crops’ field heat. The system capacities will depend on the desired final temperature for safe transport of the crop. Figure (4-17) compares the net energy to remove form one kilogram of potatoes crop to reduce its temperature from 30 °C to 4 °C. Summing up needed reduction of potatoes energy, cooling energy lost for surroundings, and potatoes respiration energies form integration of the area under curve in figure (418). It was found that cooling energy of one kilogram of potatoes will consume 119.65 W of the 399.8 W- evaporator 54 Potatoes heat load "W" available energy or 1.33% of the total solar intensity under the experimental conditions. 38 36 34 32 30 28 26 24 5 10 15 20 Ambiant air temprature °C 25 Figure 4-16: Calculated potatoes heat load at different ambient temperature. 50 45 40 35 30 25 20 15 10 5 0 30 Energy load "W" 20 15 10 5 respiration heat load 25 50 75 100 Time "min" 0 125 Figure 4-17: Potatoes thermal load energy and heat removal response. 55 Temprature "°C" 25 500 25 400 20 300 15 200 10 5 100 Energy "W" Temprature "°C" 30 heat load of kg potatoes "W" 0 0 25 50 75 100 Time "min" 125 Figure 4-18: Calculated heat load removal from kilogram of potatoes and energy transfer from condensing to evaporating processes. Chiller capacity in kg From figure (4-19) the evaporator capacity will be three kilograms of potatoes for temperature reduction form 30 °C to 5 °C, and 18 kilograms for temperature reduction form 30 °C to 20 °C. 20 18 15 10 10 7 3 5 0 5 10 15 Temprature °C 20 Figure 4-19: Chilling solar assisted potatoes holding capacities at different chilling temperature levels. 56 Chilling will take 45 minutes to reduce kilogram of potatoes from 30 °C to 20 °C and 120 minutes to reach 4 °C as seen in figure (4-20). 5 °C 10 °C 15 °C 20 °C Energy "W" 25 20 15 10 5 0 0 25 50 75 100 Chilling time "min" 125 Figure 4-20: Required time for heat removal from potatoes at different temprature levels. 57 5 SUMMARY AND CONCLUSION Small, remotes, and reclaimed agricultural lands sufferer from economical potential and poor or absent of power networks for post-harvest treatments. Solar assisted chiller was constructed for fast removal of field heat which causes rapid deteriorations in field crops. The system consisted of generator FPC and vessel, and a condenser- evaporator unit. And woks as intermittent chilling system. A mixture of absorbent “water” and refrigerant “ammonia” fluids concentrated at 50% was used as a working fluid. The power source was a solar flat plate collector FPC with gross area of 1.90 m2. The FPC accumulate the collected solar energy in the generator steel vessel by the ammonia-water mixture. Two overlapping steel cylinders represent the condenser and the evaporator vessels. The outer cylinder woks as a water cooler for the inner cylinder which works as a condenser in the condensing process. In the evaporating process (chilling) the outer cylinder is empty of water and the inner cylinder works as evaporator. Experiments of the solar assisted chiller was carried for determination of the system components and the overall thermal performance. It was found that the maximum system COP was 0.21 equals to 0.04 ton of refrigeration load. And can be used to reduce three kilograms of potatoes crop from 30 °C to 4 °C under the experiment conditions. And 18 kilograms of potatoes to 20 °C under the same conditions. Chilling system generator, consisted of FPC and generator vessel. FPC optical efficiency (0= FR (𝜏𝛼)) was 26% and varied according to ambient air temperature and the rate of fluid flow. The FPC average efficiency under the experimental 58 conditions was 13% at total solar intensity of 9027.26 W/m2/day and air speed of 5.3 m/s. The lowest obtained temperature in evaporator was 3.2 °C. FPC energy losses occur by natural and forced convection, as well as by radiation. To minimize these loses the collector was thermally insulated on its sides and bottom. While top of the collector was covered by a dual polyethylene-plastic covers. Measured thermal losses from air flow around the collector were estimated by 2.0, 3.0, and 1.2 kWh for air speeds ranged between 1-4, 4-21, and 21-30 km/h respectively. Installation of the system nearby agricultural facilities or vegetative canopies barrier should minimize energy losses alongside the collector’s perimeter. The barrier reduces the air velocities over the solar collector by creating a recirculation zone behind it. Polyethylene covers are limited in the temperatures they can sustain without deteriorating or undergoing dimensional changes, and the ability of polyethylene to withstand the sun’s ultraviolet radiation for long periods. These drawbacks of using polyethylene as FPC covers can be recovered by its low weight and cost with its ability to withstand shocks without being broken. The generator FPC overall heat removal coefficient U was 8.775 W/m2 °C and the overall heat removal factor FR was 0.3971. Typical value of the FRUL for standard FPC type ranges between 3-8 W/m2 °C. Due to the lower efficiency of the FPC and energy delivered by it. Further enhancement on optical efficiency must be mad, by changing the plastic cover 59 to non-iron glass cover. Focused and solar concentrator collectors are essential for large capacities of chilling load. Generator vessel, maximum thermal efficiency was 98% with ability to deliver 12% of the total solar intensity per day. The steel generator vessel was able to withstand system pressure (3.4 to 12.5 kg/cm2) and corrosions at all experiments. A rectifying column was fitted at the top of the generator storage vessel to prevent water from being carried over to the condenser. Condenser-evaporator, with 55% thermal efficiency was able to deliver 4.4% of the total solar intensity energy as chilling energy per cycle. The ammonia-water mixture has excellent thermodynamic and physical properties for chilling purposes. Toxicity might be the reason behind its limited usage, which can be vanished in open field applications. Solar assisted chilling system is a simple and cheap system to build. 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Solar Energy, 48:309–319. 65 7 APPENDICES APPENDIX .A The relationship between ambient air flow and heat losses from the FPC Day time 09:00 AM 09:30 AM 10:00 AM 10:30 AM 11:00 AM 11:30 AM 12:00 PM 12:30 PM 01:00 PM 01:30 PM 02:00 PM Air flow (km/h) Heat losses (kWh) FPC temp. °C Air flow temp. °C 18.36 0.121 38 30 18.36 0.211 43 30 24.12 0.333 51 32 24.12 0.391 56 32 25.92 0.499 63 34 25.92 0.557 66 34 29.52 0.575 68 35 29.52 0.610 70 35 27.72 0.645 73 36 27.72 0.679 75 36 25.92 0.732 78 36 66 APPENDIX .B Egypt Climate Graph Published on http://www.climatetemp.info/egypt/ 67 APPENDIX .C Condenser efficiency. 16/6/2011 9:00 AM 9:30 AM 10:00 AM 10:30 AM 11:00 AM 11:30 AM 12:00 PM 12:30 PM 1:00 PM 1:30 PM 2:00 PM η 0.556 0.5 0.477 0.417 0.333 0.27 0.236 0.25 0.257 0.263 0.272 Tho 26.6 27.5 28.5 29 29.7 30 30.8 31 32 32.4 33 Thi 27.8 29.2 31 32.5 33 34 35 36 38 38 40 Two 27 27.6 28.5 29 29 29.3 29.5 30 30.8 31 32 Twi 26 26 26.2 26.5 27 27.5 27.8 28 28.3 28.5 29 where Tco, Tci are outlet and inlet temperature of the water respectively ”oK”, Thi inlet temperature of the refrigerant fluid. 68 APPENDIX .D Relationship between plate temperature and water temperature day 16/6/2011 Day hours FPC temp. °C Air flow (km/h) T-plate o C T-Win o C T-out o C 9:00 AM 30 18.36 44 38 40 9:30 AM 30 18.36 51 43 46 10:00 AM 31 24.12 59 51 54 10:30 AM 33 24.12 64 56 58 11:00 AM 34 25.92 70 63 65 11:30 AM 34 25.92 74 66 68 12:00 PM 35 29.52 79 68 73 12:30 PM 35 29.52 82 70 77 1:00 PM 36 27.72 86 73 80 1:30 PM 36 27.72 90 75 83 2:00 PM 36 25.92 95 78 87 Twi, Two: Interring and exit cold water temperature respectively, oC 69 APPENDIX .E Observation during Generation and Refrigeration Test on June 16, 2011 Generation Pressure T-conde Kg/cm2 Co 5.5 26.6 6.2 27.5 7.4 28.5 8.9 29 10.6 29.7 11 30 11.4 30.8 11.4 31 11.5 32 11.6 32.4 11.7 33 10.34 30 T-water out Co 27 27.6 28.5 29 29 29.3 29.5 30 30.8 31 32 29.4 Refrigeration Time min Evaporator-temp. Co Absorber- temp. Co Absorber –press. kg/cm2 0 36 36 6.7 T-water in Co 26 26 26.2 26.5 27 27.5 27.8 28 28.3 28.5 29 27.345 15 32 36 5.8 30 29 36 5.6 T-solution Co 40 46 54 58 65 68 73 77 80 83 87 68.16 45 18 36 5.2 60 11 34 4.6 Fi Co 38 43 51 56 63 66 70 74 77 80 78.5 64.95 75 8.2 34 4.2 90 7.5 34 3.8 - 70 - T-plate Co 44 51 59 64 70 74 79 82 86 90 95 74 105 6.2 34 3.5 120 4.8 33 3.6 wind m/s 5.1 5.1 6.7 6.7 7.2 7.2 8.2 8.2 7.7 7.7 7.2 7.016 135 4.2 33 4 Amb temper Co 30 30 31 33 34 34 35 35 36 36 36 33.9 150 4.4 33 4.3 165 4.8 33 4.8 180 5 31 5 radiation W/m2 720.97 802.465 883.96 913.745 943.53 973.32 1003.11 973.32 943.53 913.745 883.96 896.51 195 5.3 31 5.6 210 5.7 31 5.9 Day hours 00 AM 9:30 AM 10:00 AM 10:30 AM 11:00 AM 11:30 AM 12:00 PM 12:30 PM 1:00 PM 1:30 PM 2:00 PM Ave 225 6.3 31 5.9 240 6.7 31 6.2 APPENDIX .F Observation during Generation and Refrigeration Test on June 18, 2011 Generation Pressure T-conde Kg/cm2 Co 5.1 27 5.5 27.8 7.2 28.3 8.2 29 10.3 30 10.8 30 11.3 30.8 11.5 31 11.4 31.7 11.6 32.4 11.6 32.8 10.125 30.1 Refrigeration Time min Evaporr-temp. Co Abso- temp. Co Abso –pres kg/cm2 T-water out Co 27 28.2 29 29.5 30 30 30.2 30.7 31 31.5 32 29.9 0 32 32 6.2 15 28 32 5.5 T-wa in Co 26 26 26.4 26.7 27.2 27.8 28 28.5 29 29.2 29.5 27.664 30 24 32 5.2 45 16 32 5.2 T-solu Co 38 44 55 57 63 66 71 75 78 84 86 66.9166 60 10 31 4.6 75 7.5 31 4.2 Fi Co 35 41 50 52 61 63 68 70 74 81 83 63.4166 90 6.4 31 3.8 105 6 31 3.4 71 T-pl Co 45 50 61 63 68 73 75 80 85 90 92 72.83 120 5.2 29 3.9 wind m/s 6.7 6.7 7.2 7.2 8.2 8.2 8.2 8.2 9.3 9.3 9.3 8.15 135 4.5 29 4.2 150 4.8 29 4.5 Amb tem Co 26 27 28 29 30 31 32 32 33 33 33 30.583 165 4.9 29 4.9 180 5.3 28 5.3 radiation W/m2 721.07 802.57 884.07 913.83 943.59 973.355 1003.12 973.355 943.59 913.83 884.07 896.585 195 5.8 28 5.5 210 6 28 5.5 Day hours 9:00 AM 9:30 AM 10:00 AM 10:30 AM 11:00 AM 11:30 AM 12:00 PM 12:30 PM 1:00 PM 1:30 PM 2:00 PM Ave 225 5.8 28 6.3 240 5.9 28 6.9 APPENDIX .G Observation during Generation and Refrigeration Test on June 22, 2011 Generation Pressure Kg/cm2 5.7 7.1 8.8 11.2 11.4 11.4 11.5 11.5 11.6 11.7 12.5 10.6667 T-cond Co 28 28.7 29.3 29.8 30 30.5 31 31.5 32 32.6 33 30.6 Refrigeration Time min Evaporator-temp. Co Absorber- temp. Co Abso –press. kg/cm2 T-out Co 28.5 29.2 30 30.5 31 31.6 32 32.8 33.2 33.8 34 31.5 0 35 39 6.5 15 30 39 6.1 T- in Co 28 28 28.2 28.5 28.8 29.5 30 30.5 30.5 30.8 31 29.436 30 25 39 5.8 45 18 39 5.2 T-solu Co 45 50 58 70 74 77 80 84 86 86 91 74.25 60 10.5 37 4.6 Fi Co T-p Co 42 47 55 67 70 74 78 82 84 84 86 71.3333 52 56 63 76 81 83 86 89 93 96 95 80.4167 75 7.5 37 4.2 90 6.2 37 3.8 72 105 5 37 3.4 120 4.3 35 3.6 wind m/s 4.1 4.1 4.6 4.6 5.7 5.7 6.7 6.7 5.7 5.7 4.6 5.23333 135 3.6 35 4.3 Amb temp Co 29 29 31 32 33 34 35 36 37 37 38 34.0833 150 3.8 35 4.9 165 4.1 35 5.2 180 4.4 33 5.2 radiation W/m2 721.14 802.63 884.12 913.88 943.64 973.41 1003.18 973.41 943.64 913.88 884.12 896.64 195 4.9 33 5.4 210 5.3 33 5.6 Day hours 9:00 AM 9:30 AM 10:00 AM 10:30 AM 11:00 AM 11:30 AM 12:00 PM 12:30 PM 1:00 PM 1:30 PM 2:00 PM Ave 225 5.7 33 5.9 240 6.3 32 6 APPENDIX .H Observation during Generation and Refrigeration Test on June 26, 2011 Generation Pressure T-cond oC Kg/cm2 5.5 28 7.1 28.8 9 29.5 10.8 29.8 11.4 30.6 11.4 31.3 11.6 32 11.7 32.2 11.8 32.5 12 32.8 11.5 34.4 10.7667 31.1 T- out o C 28 29 29.8 30 30.8 31.6 32 32.6 33 34 35 31.4 Refrigeration Time min Evaporator-temp. Co Absorber- temp. Co Abso –press. kg/cm2 0 34 38 6.7 15 28 38 6.4 T- in o C 26 26 26.6 26.8 27.2 27.6 27.8 28 28.4 28.6 29.4 27.491 30 21 38 5.9 T-solu o C 45 51 60 68 75 81 84 87 92 91 90 75.9167 45 14 38 5.5 60 9 37 4.8 Fi Co T-p oC 41 58 57 64 72 78 81 84 88 89 87 73.6667 51 56 65 74 82 86 90 93 95 95 94 81.0833 75 6.2 37 4.4 90 5.1 37 5 73 105 4.7 37 4.5 wind m/s 2.1 2.1 3.1 4.1 4.1 5.7 5.7 5.1 5.1 4.1 4.1 4.11667 120 4 35 3.9 135 3.2 35 3.5 Amb temp Co 31 32 33 34 35 35 35 36 36 37 37 34.9167 150 3.4 35 3.5 165 3.7 35 3.8 180 3.9 33 4.3 radiation W/m2 720.8 802.33 883.86 913.665 943.47 973.275 1003.08 973.275 943.47 913.665 883.86 896.4233 195 4.2 33 4.8 210 4.5 33 5.2 Day hours 9:00 AM 9:30 AM 10:00 AM 10:30 AM 11:00 AM 11:30 AM 12:00 PM 12:30 PM 1:00 PM 1:30 PM 2:00 PM Ave 225 4.8 33 5.5 240 5.5 30 5.5 APPENDIX .I Diagram of the mixture ammonia-water properties 74 APPENDIX .J Observation during Refrigeration Test on June 16, 2011 Absorber Temperature Absorber pressure 8 7 6 5 4 3 2 1 0 44 40 36 32 28 24 20 16 12 8 4 0 0 pressure kg/cm2 Temperature °C Evaporator Temperature 30 60 90 120 150 180 210 240 Time "min" Observation during Generation Test on June 22, 2011 T-condenser Pressure T-generator 120 12 100 10 80 8 60 6 40 4 20 2 0 0 9 AM 10 AM 11 AM 12 PM Time 75 1 PM 2 PM Pressuer kg/m2 Temprature °C T-plate Observation during Generation Test on June 22, 2011 T-plate T-condenser solar total 1200 1000 800 600 400 200 0 Temperature Co 120 100 80 60 40 20 0 9 AM 10 AM 11 AM 12 PM 1 PM solar radiation W/m2 T-generator 2 PM Time Observation during Refrigeration Test on June 22, 2011 240 210 180 150 120 90 60 30 Time "min" 76 0 o 44 40 36 32 28 24 20 16 12 8 4 0 C Absorber pressure Pressure kg/cm2 Absorber Temperature Temperature Evaporator Temperature 7 6 5 4 3 2 1 0 Observation during Generation Test on June 25, 2011 120 T-generator T-plate T-condenser Pressure 14 12 10 8 6 4 2 0 Pressure kg/cm2 100 Temperature Co 80 60 40 20 0 9 AM 10 AM 11 AM 12 PM 1 PM Time 2 PM Observation during Generation Test on June 25, 2011 T-plate T-condenser solar total 1200 100 1000 80 800 60 600 40 400 20 200 Temperature Co 120 0 0 9AM 10AM 11AM 12PM Time 77 1PM 2PM solar radiation W/m2 T-generator Observation during Refrigeration Test on June 25, 2011 7 Absorber Temperature Absorber pressure 44 40 36 32 28 24 20 16 12 8 4 0 Pressure kg/cm2 6 5 4 3 2 1 0 240 210 180 150 120 90 Time - min 60 30 0 Observation during Generation Test on June 26, 2011 T-plate T-condenser Pressure Temperature Co 100 14 12 10 8 6 4 2 0 80 60 40 20 0 9AM 10AM 11AM 12PM Time 78 1PM 2PM Pressure kg/cm2 T-generator Temperature Co Evaporator Temperature Observation during Generation Test on June 26, 2011 T-plate T-condenser solar total 100 90 80 70 60 50 40 30 20 10 0 1200 Temperature Co 1000 800 600 400 200 solar radiation W/m2 T-generator 0 9 AM 10 AM 11 AM 12 PM 1 PM 2 PM Time Observation during Refrigeration Test on June 26, 2011 Absorber Temperature Absorber pressure 44 40 36 32 28 24 20 16 12 8 4 0 Pressure kg/cm2 6 4 2 0 240 210 180 150 120 90 Time - min 79 60 30 0 Temperature Co Evaporator Temperature 8 Observation during Generation Test on June 28, 2011 T-generator T-plate T-condenser Pressure 12 10 8 6 4 2 0 Pressure kg/cm2 Temperature oC 100 80 60 40 20 0 9 AM 10 AM 11 AM 12 PM 1 PM 2 PM Time hours Observation during Generation Test on June 28, 2011 80 T-plate T-condenser solar total 1200 100 90 80 70 60 50 40 30 20 10 0 Temperature oC 1000 800 600 400 200 0 9 AM 10 AM 11 AM 12 PM Time 1 PM 2 PM Observation during Refrigeration Test on June 28, 2011 Absorber Temperature Absorber44 pressure 40 36 32 28 24 20 16 12 8 4 0 6 5 4 3 2 1 0 240 210 180 150 120 90 60 30 Time - min 81 0 Temperature Co Pressure kg/cm2 Evaporator Temperature 7 solar radiation W/m2 T-generator APPENDIX .K Actual and Theoretical system cycles for test on June 26, 2011 Temperature °C 11 k g/cm ² 12 k g/cm ² Actual Cycle 4.8 kg /cm ² 3.4 kg /cm ² Theoretical Cycle Concentration, kg (NH3)/kg(NH3 + H2O) 82 Actual and Theoretical system cycles for test on June 25, 2011. Temperature °C 11 k g/cm ² 12.5 kg/c m² Actual Cycle 3.5 kg /cm ² 4.8 kg /cm ² Theoretical Cycle Concentration, kg (NH3)/kg(NH3 + H2O) 83 Actual and Theoretical system cycles for test on June 22, 2011 Temperature °C 11 k g/cm ² 12 k g/cm ² Actual Cycle 3.4 kg /cm ² 4.8 kg /cm ² Theoretical Cycle Concentration, kg (NH3)/kg(NH3 + H2O) 84 Actual and Theoretical system cycles for test on June 28, 2011 Temperature °C 11 k g/cm ² 12 k g/cm ² Actual Cycle 3.4 4.8 kg /cm ² kg /cm ² Theoretical Cycle Concentration, kg (NH3)/kg(NH3 + H2O) 85 تطوير نموذج للتبريد بالطاقة الشمسية ملخص الدراسة تتعرض المحاصيل الزراعية للتلف بعد حصادها ،لنقص االهتمام باإلجراءات المناسبة من معامالت ما بعد الحصاد مثل التبريد المبدئى وخفض درجة ح اررتها بعد حصادها مباشرة .مما يتسبب في خسارة في إنتاجية الخضروات والفاكهة والموالح بجمهورية مصر العربية ،قدر بنحو 32،33مليار جنيه سنويا طبقا إلحصائيات العام .5122 وقد أرجع نقص االهتمام بإجراءات ما بعد الحصاد الح اررية الرتفاع تكلفة العمليات المرتبطة بها من أجهزة ومتطلبات الطاقة وما يتبعه من زيادة تكاليف اإلنتاج أو لغياب مصادر الطاقة المالئمة بالمناطق الزراعية وخصوصا النائية منها ،مما يحد من خطط التوسع فى الزراعات المستقبلية. لذا عمدت الدراسة على تطوير نموذج للمعاملة الح اررية بالتبريد يستمد قدرته من الطاقة الشمسية بواسطة مجمع شمسى مسطح ،بحيث يتميز بسهولة اإلنشاء والصيانة مع توافر المواد والتكنولوجيات الخاصة بها محليا ،واستخدام الطاقة الشمسية (الطاقة الخضراء) كمصدر للطاقة والرتباطها على نحو وثيق بمتطلبات طاقة التبريد المطلوبة .فكلما زادت طاقة اإلشعاع الشمسى وح اررة المنتج الز ارعى، زاد االحتياج للتبريد وزادت كفاءة تشغيل النموذج ،وفى ظروف انخفاض معدالت التعرض الشمسى يقل االحتياج للتبريد ،وما يتبعه من انخفاض كفاءة النموذج بما ال يؤثر على كفاءة عمليات ما بعد الحصاد الح اررية إجماالً. 1 بلغ معامل كفاءة المبرد الشمسى القصوى 1.20بما يعادل 1.13طن تبريد. تحت شدة إشعاع شمسى بلغ 6157.59وات/م 5لليوم وحركة هواء 2.3م/ث. وقد تم تخفيض درجة ح اررة المبخر إلى ثالثة درجات ونصف الدرجة عند نفس ظروف التشغيل. والتي تمكن نظام التبريد وحسب المتبع من الحسابات المرجعية لتبريد الحاصالت الزراعية ،من تبريد ثالثة كيلوجرامات من درنات البطاطس من °31م إلى °0م ،أو ما يعادل ثمانية عشرة كيلوجرامات من درنات البطاطس إلى °51م عند نفس ظروف التشغيل. تكون نظام التشغيل من مولد حرارى يتكون من جزيئين هما المجمع الشمسى، ووحدة استيعاب سائل التشغيل المسخن باإلضافة إلى أنبوبتين معدنيتين متداخلتين تعمالن كمكثف ومبخر على التوالى .حيث تعمل األنبوبة الداخلية عمل المكثف وتملئ األنبوبة الخارجية بالماء الجارى لتتم عملية التبريد .وفى مرحلة التبخير ،يتم منع دخول الماء إليقاف عمليات التبريد المائية إتاحة الفرصة لعمل المبخر في خفض درجة ح اررة المنتج الغذائي. تكون سائل التشغيل من مخلوط من األمونيا-ماء بتركيز .%21وعلى الرغم من المميزات المرغوبة لهذا الخليط ،إال انه يعاب عليه سميته واحداث تأكل في معظم المواد المنشأة لوحدات التبريد التقليدية المصنعة من النحاس .وباستخدام الوحدة في ظروف الحقل المفتوح وانشاء المكونات من معدن الحديد تم حل مشكالت التشغيل. 2 استخدمت وحدة تجميع شمسى من نوع المجمعات المسطحة بمساحة 2،62م ،5وقد بلغ متوسط كفاءة الوحدة الشمسية البصرية ،%59ومتوسط الكفاءة اليومية نحو ( %23تحت الظروف االختبارية) .بلغ معامل فقد الح اررة من المجمع الشمسى المسطح 3.722وات/م° 5م .ومعامل السخان الشمسى 1.3672 بحاصل يبلغ 3.2وات/م° 5م ،في حين تقع النسبة العيارية لهذه النوعية من المجمعات الشمسية في المدى بين 3-3وات/م° 5م. نظ اًر لتأثير سرعة الهواء حول المجمع الشمسى على كفاءته في استخالص الطاقة الح اررية من الطاقة الشمسية -وبالتالى على كفاءة عملية التبريد-حددت ثالثة معدالت للفقد الحراري من المجمع والذى سجل فقد مقداره 5.1ك.وات.س للهواء للسرعة التى تقع في المدى من 2إلى 0كم/س ،وزاد معدل الفقد الحرارى ليبلغ 3.1ك.وات.س بزيادة سرعة الهواء في المدى من 0إلى 52كم/س، وبمعدل فقد حرارى 2.5ك.وات.س للهواء المتحرك بسرعة واقعة فى المدى من 52إلى 31كم/س من خالل مسطح المجمع الشمسى بالمساحة المعرضة 2.62م .5وطبقا للنتائج ،ينصح باختيار موقع وحدة التبريد فى مكان مناسب - لقابلية النموذج للنقل – على مسافة من الغطاء النباتى أو المنشآت الزراعية حتى تعمل كمصد للرياح ،األمر الذي يعمل على اتزان عمل النموذج خالل إجراء المعامالت الح اررية. كما روعى أضفاء القدرة على نقل النموذج أثناء عمله بالحقل اإلنتاجى ،مما يضمن له الحصول على الطاقة الشمسية واجراء المعاملة الح اررية آنياً و حصاد المنتج الزراعى .مكن استخدام طبقتين من األغطية البالستيكية الشفافة أعلى 3 سطح المجمع الشمسى من خفض تكاليف اإلنشاء ،وتقليل أخطار تعرضه للكسر أو الشرخ عند صيانة أو نقل النموذج .أال أن النموذج المختبر كان أقل كفاءة، وتدنت نسبة الطاقة الشمسية المستخلصة .ويجب أن يراعى التحول إلى أنظمة التركيز الشمسية المختلفة عند الرغبة في زيادة الكفاءة أو زيادة السعة الكلية للمبرد. بلغت كفاءة وحدة االستيعاب الحديدية لسائل التشغيل بالمولد نحو ،%63 بما يساوى %25من إجمالي طاقة األشعة الشمسية في اليوم .وقد أمكن لوحدة االستيعاب من تحمل ضغوط التشغيل الواقعة في المدى 3.0إلى 25.2كيلوجرام/سم ،5وتالشى أخطار التآكل الناجمة عن تفاعل األمونيا مع معدن النحاس .كما استخدمت وحدة تصحيح أعلى وحدة االستيعاب لمنع المياه من الوصول إلى المكثف. بلغت كفاءة وحدة التكثيف – تبخير الح اررية %22من الطاقة الواردة إليها، وما يساوى % 0.0من إجمالي الطاقة الشمسية المجمعة في اليوم الواحد. يساعد النظام المختبر على الحد من الخسائر الناجمة لتدهور المنتجات الزراعية نتيجة غياب عمليات ما بعد الحصاد وخصوصا إزالة الح اررة الحقلية، كما يمكن االستفادة المزدوجة من النظام للحصول على الماء الساخن وظروف التبريد للتطبيقات الزراعية المختلفة. 4 تطوير نموذج للتبريد بالطاقة الشمسية رسالة مقدمة من رجب قاسم محمود على بكالوريوس العلوم الزراعية – كلية الزراعة -جامعة األزهر -أسيوط – 5002م استيفاء لمتطلبات الحصول على درجة التخصص (الماجستير) فى العلوم الزراعية (الهندسة الزراعية) قسم الهندسة الزراعية كلية الزراعة -جامعة األزهر فرع أسيوط 1131 8هـ 2113مـ 5 تطوير نموذج للتبريد بالطاقة الشمسية رسالة مقدمة من رجب قاسم محمود علي بكالوريوس في العلوم الزراعية (هندسة زراعية) كلية الزراعة بأسيوط -جامعة األزهر 5002م إستيفاء لمتطلبات الحصول على درجة التخصص (الماجستير) فى العلوم الزراعية (هندسة زراعية) قسم الهندسة الزراعية كلية الزراعة بأسيوط -جامعة األزهر 1131ه 2113م أجــــازهــا: أ.د.م /محمد نبيل محمد عبد العظيم العوضى....................................... أستاذ الهندســة الزراعيــة غير المتفرغ -كليـة الزراعة -جامعـة عين شمس. أ.د /سـمير أحمد محمد طايل........................................................... أستاذ الهندســة الزراعيــة المتفرغ -كليـة الهندسة الزراعية -جامعـة األزهر بالقاهرة. أ.د /أحمد ماهر محمد الليثى........................................................... أستاذ الهندســة الزراعيــة -كليـة الزراعة -جامعـة األزهر بأسيوط د/محمود زكى العطار................................................................... مدرس الهندســة الزراعيــة -كليـة الزراعة – جامعـة عين شمس-القاهرة تاريخ المناقشة 2113 / 9/ 22 :م 6 1131 / 11 / 11هـ تطوير نموذج للتبريد بالطاقة الشمسية رسالة مقدمة من رجب قاسم محمود على بكالوريوس العلوم الزراعية– كلية الزراعة -جامعة األزهر -أسيوط – 5002م استيفاء لمتطلبات الحصول على درجة التخصص (الماجستير) فى العلوم الزراعية (الهندسة الزراعية) قسم الهندسة الزراعية كلية الزراعة -جامعة األزهر فرع أسيوط 1131ه 2113م لجنة اإلشراف: ا.د /حسن عبد الرازق عبد المولى.................................................. أستاذ ورئيس قسم الهندســة الزراعية -كلية الزراعة – جامعـة األزهر -أسيوط. ا.د/أحمد ماهر محمد الليثي............................................................. .L أستاذ الهندســة الزراعيــة -كليـة الزراعة – جامعـة األزهر -أسيوط. د/محمود زكى العطار................................................................... مدرس الهندســة الزراعيــة -كليـة الزراعة – جامعـة عين شمس-القاهرة. 7