CHEMICAL REACTIONS Chemical Reactions Chemical change = Chemical reaction Substance(s) is used up (disappear) New substance(s) is formed. What is a chemical reaction? A chemical reaction is a change that takes place when one or more substances (called reactants) form one or more new substances (called products). Main Ideas Chemical Reactions are represented by Chemical Equations. Chemical Equations are balanced to show the same number of atoms of each element on each side. The Law of Conservation of Mass says that atoms won’t be created or destroyed in a chemical reaction. That is why you have to balance chemical equations! How can you spot a chemical reaction? Chemical reactions can appear very different. As you observe a chemical reaction, you may detect: a colour change precipitate (solid) forming energy being produced (fizzing, burning) an odour being produced. evolution of gas (formation of bubbles) Signs/Demo of Chemical Reactions How do you know when a chemical reaction takes place? Temperature Change Change in Acidity Representing Chemical Reactions Chemists observe chemical reactions and have come up with a way to represent or model what is happening. Making NaCl Solid Sodium combines with Chlorine gas to make solid Sodium Chloride: 2Na (s) + Cl2 (g) 2NaCl Chemical Equations are different from Numerical Equations Numerical Equation: 3x + 2y = 47 Chemical Equation 2Na + Cl2 2NaCl ReactantA + Reactant B Product The reactants are used up in forming the product The arrow shows the direction of the reaction What is a word equation? What is a symbol equation? Meaning of Chemical Formula Symbols used in Chemical Equations Law of Conservation of Mass In a chemical reaction, matter is neither created nor destroyed. Atoms won’t change their identity (e.g. a Carbon atom can’t become an Iron atom) This means that you have to have the same number of each type of atom on each side of the chemical equation. Chemical Equations Because of the principle of the conservation of matter, An equation must be balanced It must have the same number of atoms of the same kind on both sides. Types of Chemical Reactions *Synthesis – The get together *Decomposition- The break up *Single Replacement- The Cheater *Double Replacement- The Swap *Combustion - The Lovable **The Red names are “helpful hints” Synthesis/Combination Decomposition Single Replacement Reactions Double Replacement Reaction Double Replacement Reaction Combustion How does this analogy break down? How does this analogy break down? Let’s look at the reactions in more detail Synthesis reaction (combination) • 2 or more reactants combine to form a single product • can be a combination of metal and a nonmetal forming ionic compound. 2Mg (s) + O2 (g) —> 2MgO (s) • can be a combination of nonmetals, producing a covalent compound. N2 (g) + 3H2 (g) —-> 2NH3 (g) addition of 2 compounds SO3 (g) + H2O (l) —-> H2SO4 (aq) Decomposition/Analysis • reverse of synthesis reactions • decomposition of ionic compounds 2CuCl2 (s) —-> 2Cu(s) + Cl2(g) • dissociation of covalent bond into its nonmetallic element 2H2O(l) —-> 2H2(g) + O2 (g) Single Replacement/Substitution A metal replaces a hydrogen. Mg (s) + HCL (aq) —-> MgCl2 (aq) + H2 (g) A more active free metal replaces less active one in a compound. Mg (s) + CuSO4 (aq) —> MgSO4 (aq) + Cu (s) Mg (s) + NaCl (aq) —-> NO REACTION A nonmetal X can also replace another nonmetal in a compound. 2NaBr (aq) + Cl2 (aq) —-> 2NaCl (aq) + Br2 (g) NaCl (aq) + Br2 (g) —-> NO EACTION Activity Series • The most active metals are at the top. These will replace metals below them. • The halogens are also listed in order of most active at the top to least active at the bottom. • More active elements replace less active elements in single replacement reactions • Double Replacement/Metathesis occurs when 2 ionic compounds exchange cations and anions with each other. AgNO3 (aq) + NaCl (aq) —> NaNO3 (aq) + Ag Cl (s)