Introduction
Strain
Stress
When clay minerals are present in fine-grained soil, the soil can be remolded in the presence of some moisture without crumbling. This cohesive nature is caused by the adsorbed
water surrounding the clay particles. In the early 1900s, a Swedish scientist named
Atterberg developed a method to describe the consistency of fine-grained soils with varying moisture contents. At a very low moisture content, soil behaves more like a solid. When
the moisture content is very high, the soil and water may flow like a liquid. Hence, on an
arbitrary basis, depending on the moisture content, the behavior of soil can be divided into
four basic states—solid, semisolid, plastic, and liquid—as shown in Figure 4.1.
The moisture content, in percent, at which the transition from solid to semisolid state
takes place is defined as the shrinkage limit. The moisture content at the point of transition
from semisolid to plastic state is the plastic limit, and from plastic to liquid state is the liquid limit. These parameters are also known as Atterberg limits. This chapter describes the
procedures to determine the Atterberg limits. Also discussed in this chapter are soil structure and geotechnical parameters, such as activity and liquidity index, which are related to
Atterberg limits.
Stress
4.1
Stress
4
Plasticity and Structure of Soil
Strain
Strain
Stress-strain diagrams at various states
Solid
Semisolid
Plastic
Liquid
Shrinkage limit, S L
Plastic limit, PL
Liquid limit, L L
Moisture
content
increasing
Figure 4.1 Atterberg limits
73
74 Chapter 4: Plasticity and Structure of Soil
4.2
Liquid Limit (LL)
A schematic diagram (side view) of a liquid limit device is shown in Figure 4.2a. This
device consists of a brass cup and a hard rubber base. The brass cup can be dropped onto
the base by a cam operated by a crank. To perform the liquid limit test, one must place a soil
46.8
mm
27 mm
54 mm
Soil pat
(a)
50 mm
8
mm
27
2 mm
11 mm
(b)
Section
11
mm
8 mm
2 mm
Plan
12.7 mm
(c)
(d)
Figure 4.2 Liquid limit
test: (a) liquid limit device;
(b) grooving tool; (c) soil
pat before test; (d) soil pat
after test
4.2 Liquid Limit (LL)
75
paste in the cup. A groove is then cut at the center of the soil pat with the standard grooving tool (Figure 4.2b). By the use of the crank-operated cam, the cup is lifted and dropped
from a height of 10 mm (0.394 in.). The moisture content, in percent, required to close a
distance of 12.7 mm (0.5 in.) along the bottom of the groove (see Figures 4.2c and 4.2d)
after 25 blows is defined as the liquid limit.
It is difficult to adjust the moisture content in the soil to meet the required
12.7 mm (0.5 in.) closure of the groove in the soil pat at 25 blows. Hence, at least three
tests for the same soil are conducted at varying moisture contents, with the number of
blows, N, required to achieve closure varying between 15 and 35. Figure 4.3 shows a
photograph of a liquid limit test device and grooving tools. Figure 4.4 shows photographs of the soil pat in the liquid limit device before and after the test. The moisture
content of the soil, in percent, and the corresponding number of blows are plotted on
semilogarithmic graph paper (Figure 4.5). The relationship between moisture content
and log N is approximated as a straight line. This line is referred to as the flow curve.
The moisture content corresponding to N ! 25, determined from the flow curve, gives
the liquid limit of the soil. The slope of the flow line is defined as the flow index and
may be written as
IF !
w1 " w2
N2
log a b
N1
Figure 4.3 Liquid limit test device and grooving tools (Courtesy of ELE International)
(4.1)
(a)
Figure 4.4
Photographs showing
the soil pat in the liquid
limit device: (a) before
test; (b) after test [Note:
The half-inch groove
closure in (b) is marked
for clarification]
(Courtesy of Braja M.
Das, Henderson,
Nevada)
(b)
Moisture content (%)
50
Flow curve
45
Liquid limit ! 42
40
35
30
10
76
20
25
30
Number of blows, N (log scale)
40
50
Figure 4.5
Flow curve for
liquid limit
determination of
a clayey silt
4.2 Liquid Limit (LL)
77
where IF ! flow index
w1 ! moisture content of soil, in percent, corresponding to N1 blows
w2 ! moisture content corresponding to N2 blows
Note that w2 and w1 are exchanged to yield a positive value even though the slope of
the flow line is negative. Thus, the equation of the flow line can be written in a general
form as
w ! "IF log N $ C
(4.2)
where C ! a constant.
From the analysis of hundreds of liquid limit tests, the U.S. Army Corps of
Engineers (1949) at the Waterways Experiment Station in Vicksburg, Mississippi, proposed an empirical equation of the form
LL ! wN a
N tan b
b
25
(4.3)
where N ! number of blows in the liquid limit device for a 12.7 mm (0.5 in.) groove
closure
wN ! corresponding moisture content
tan b ! 0.121 (but note that tan b is not equal to 0.121 for all soils)
Equation (4.3) generally yields good results for the number of blows between 20 and 30.
For routine laboratory tests, it may be used to determine the liquid limit when only one test
is run for a soil. This procedure is generally referred to as the one-point method and was
also adopted by ASTM under designation D-4318. The reason that the one-point
method yields fairly good results is that a small range of moisture content is involved
when N ! 20 to N ! 30.
Another method of determining liquid limit that is popular in Europe and Asia
is the fall cone method (British Standard—BS1377). In this test the liquid limit is defined as the moisture content at which a standard cone of apex angle 30# and weight of
0.78 N (80 gf) will penetrate a distance d ! 20 mm in 5 seconds when allowed to drop
from a position of point contact with the soil surface (Figure 4.6a). Due to the
difficulty in achieving the liquid limit from a single test, four or more tests can be conducted at various moisture contents to determine the fall cone penetration, d. A semilogarithmic graph can then be plotted with moisture content (w) versus cone
penetration d. The plot results in a straight line. The moisture content corresponding to
d ! 20 mm is the liquid limit (Figure 4.6b). From Figure 4.6(b), the flow index can be
defined as
IFC !
w2 1% 2 " w1 1 % 2
log d2 " log d1
where w1, w2 ! moisture contents at cone penetrations of d1 and d2, respectively.
(4.4)
78 Chapter 4: Plasticity and Structure of Soil
30°
Weight, W ! 0.78 N
Soil
d
40 mm
55 mm
(a)
Moisture content,
(%)
50
40
Liquid limit
30
10
20
40
Penetration, d(mm)
(b)
4.3
60
80 100
Figure 4.6
(a) Fall cone test (b) plot of moisture
content vs. cone penetration for
determination of liquid limit
Plastic Limit (PL)
The plastic limit is defined as the moisture content in percent, at which the soil
crumbles, when rolled into threads of 4.2 mm ( 18 in.) in diameter. The plastic limit is the
lower limit of the plastic stage of soil. The plastic limit test is simple and is performed
by repeated rollings of an ellipsoidal-sized soil mass by hand on a ground glass plate
(Figure 4.7). The procedure for the plastic limit test is given by ASTM in Test
Designation D-4318.
As in the case of liquid limit determination, the fall cone method can be used to
obtain the plastic limit. This can be achieved by using a cone of similar geometry but with
a mass of 2.35 N (240 gf). Three to four tests at varying moisture contents of soil are conducted, and the corresponding cone penetrations (d) are determined. The moisture content
corresponding to a cone penetration of d ! 20 mm is the plastic limit. Figure 4.8 shows
the liquid and plastic limit determination of Cambridge Gault clay reported by Wroth and
Wood (1978).
4.3 Plastic Limit (PL)
79
2
4
Figure 4.7 Rolling of soil mass on ground glass plate to determine plastic limit (Courtesy of
Braja M. Das, Henderson, Nevada)
W ! 0.78 N
70
Moisture content,
(%)
Liquid limit
60
Plastic limit
Cone weight,
W ! 2.35 N
50
40
1
2
5
10
20
Cone penetration, d(mm)
50
Figure 4.8
Liquid and plastic limits for
Cambridge Gault clay determined by fall cone test
The plasticity index (PI) is the difference between the liquid limit and the plastic limit
of a soil, or
PI ! LL " PL
(4.5)
Table 4.1 gives the ranges of liquid limit, plastic limit, and activity (Section 4.6) of
some clay minerals (Mitchell, 1976; Skempton, 1953).
80
Chapter 4: Plasticity and Structure of Soil
Table 4.1 Typical Values of Liquid Limit, Plastic Limit, and Activity of Some Clay Minerals
Mineral
Liquid limit, LL
Plastic limit, PL
Activity, A
Kaolinite
Illite
Montmorillonite
Halloysite (hydrated)
Halloysite (dehydrated)
Attapulgite
Allophane
35–100
60–120
100–900
50–70
40–55
150–250
200–250
20–40
35–60
50–100
40–60
30–45
100–125
120–150
0.3–0.5
0.5–1.2
1.5–7.0
0.1–0.2
0.4–0.6
0.4–1.3
0.4–1.3
Burmister (1949) classified the plasticity index in a qualitative manner as follows:
PI
Description
0
1–5
5–10
10–20
20–40
' 40
Nonplastic
Slightly plastic
Low plasticity
Medium plasticity
High plasticity
Very high plasticity
The plasticity index is important in classifying fine-grained soils. It is fundamental
to the Casagrande plasticity chart (presented in Section 4.7), which is currently the basis
for the Unified Soil Classification System. (See Chapter 5.)
Sridharan, et al. (1999) showed that the plasticity index can be correlated to
the flow index as obtained from the liquid limit tests (Section 4.2). According to
their study,
and
PI 1 % 2 ! 4.12IF 1% 2
(4.6)
PI 1% 2 ! 0.74IFC 1% 2
(4.7)
PL ! 0.04(LL) + 0.26(CF) + 10
(4.8)
PI ! 0.96(LL) " 0.26(CF) " 10
(4.9)
In a recent study by Polidori (2007) that involved six inorganic soils and their respective mixtures with fine silica sand, it was shown that
and
where CF ! clay fraction (% 2 &m) in %. The experimental results of Polidori (2007)
show that the preceding relationships hold good for CF approximately equal to or greater
than 30%.
4.4 Shrinkage Limit (SL)
Shrinkage Limit (SL)
Soil shrinks as moisture is gradually lost from it. With continuing loss of moisture, a stage
of equilibrium is reached at which more loss of moisture will result in no further volume
change (Figure 4.9). The moisture content, in percent, at which the volume of the soil mass
ceases to change is defined as the shrinkage limit.
Shrinkage limit tests (ASTM Test Designation D-427) are performed in the laboratory with a porcelain dish about 44 mm (1.75 in.) in diameter and about 12.7 mm (12 in.)
high. The inside of the dish is coated with petroleum jelly and is then filled completely
with wet soil. Excess soil standing above the edge of the dish is struck off with a straightedge. The mass of the wet soil inside the dish is recorded. The soil pat in the dish is then
oven-dried. The volume of the oven-dried soil pat is determined by the displacement of mercury. Because handling mercury may be hazardous, ASTM D-4943 describes a method of
dipping the oven-dried soil pat in a melted pot of wax. The wax-coated soil pat is then
cooled. Its volume is determined by submerging it in water.
By reference to Figure 4.9, the shrinkage limit can be determined as
SL ! wi 1 % 2 " ¢w 1% 2
(4.10)
where wi ! initial moisture content when the soil is placed in the shrinkage limit dish
(w ! change in moisture content (that is, between the initial moisture
content and the moisture content at the shrinkage limit)
However,
wi 1 % 2 !
M1 " M2
) 100
M2
(4.11)
where M1 ! mass of the wet soil pat in the dish at the beginning of the test (g)
M2 ! mass of the dry soil pat (g) (see Figure 4.10)
∆
Vi
Volume of soil
4.4
81
Vf
Shrinkage limit
Plastic limit
Moisture content (%)
Figure 4.9 Definition of shrinkage limit
Liquid limit
i
82 Chapter 4: Plasticity and Structure of Soil
Soil volume ! Vi
Soil mass ! M1
Soil volume ! Vf
Soil mass ! M2
Porcelain
dish
(a)
(b)
Figure 4.10 Shrinkage limit test: (a) soil pat before drying; (b) soil pat after drying
Also,
¢w 1% 2 !
1Vi " Vf 2rw
M2
) 100
(4.12)
where Vi ! initial volume of the wet soil pat (that is, inside volume of the dish, cm3)
Vf ! volume of the oven-dried soil pat (cm3)
rw ! density of water (g/cm3)
Finally, combining Eqs. (4.10), (4.11), and (4.12) gives
SL ! a
Vi " Vf
M1 " M2
b 1100 2 " a
b 1rw 2 1100 2
M2
M2
(4.13)
Another parameter that can be determined from a shrinkage limit test is the shrinkage ratio, which is the ratio of the volume change of soil as a percentage of the dry volume
to the corresponding change in moisture content, or
¢V
¢V
b
b
a
M2
Vf
Vf
!
!
SR !
¢Vrw
¢M
Vfrw
a
b
a
b
M2
M2
a
(4.14)
where (V ! change in volume
(M ! corresponding change in the mass of moisture
It can also be shown that
Gs !
1
1
SL
" a
b
SR
100
where Gs ! specific gravity of soil solids.
(4.15)
4.5 Liquidity Index and Consistency Index
83
Example 4.1
Following are the results of a shrinkage limit test:
•
•
•
•
Initial volume of soil in a saturated state ! 24.6 cm3
Final volume of soil in a dry state ! 15.9 cm3
Initial mass in a saturated state ! 44.0 g
Final mass in a dry state ! 30.1 g
Determine the shrinkage limit of the soil.
Solution
From Eq. (4.13),
SL ! a
Vi " Vf
M1 " M2
b 1100 2 " a
b 1rw 2 1100 2
M2
M2
M1 ! 44.0g
Vi ! 24.6 cm3
M2 ! 30.1g
Vf ! 15.9 cm3
SL ! a
rw ! 1 g/cm3
24.6 " 15.9
44.0 " 30.1
b 1100 2 " a
b 11 2 1100 2
30.1
30.1
! 46.18 " 28.9 ! 17.28%
■
Typical values of shrinkage limit for some clay minerals are as follows
(Mitchell, 1976).
4.5
Mineral
Shrinkage limit
Montmorillonite
Illite
Kaolinite
8.5–15
15–17
25–29
Liquidity Index and Consistency Index
The relative consistency of a cohesive soil in the natural state can be defined by a ratio called
the liquidity index, which is given by
LI !
w " PL
LL " PL
(4.16)
where w ! in situ moisture content of soil.
The in situ moisture content for a sensitive clay may be greater than the liquid limit.
In this case (Figure 4.11),
LI ' 1
These soils, when remolded, can be transformed into a viscous form to flow like a liquid.
84 Chapter 4: Plasticity and Structure of Soil
LI ! 0
LI ! 1
LI ' 1
PL
Moisture content,
LL
PI
Figure 4.11 Liquidity index
Soil deposits that are heavily overconsolidated may have a natural moisture content
less than the plastic limit. In this case (Figure 4.11),
LI % 0
Another index that is commonly used for engineering purposes is the consistency
index (CI), which may be defined as
CI !
LL " w
LL " PI
(4.17)
where w ! in situ moisture content. If w is equal to the liquid limit, the consistency index
is zero. Again, if w ! PI, then CI ! 1.
Activity
Because the plasticity of soil is caused by the adsorbed water that surrounds the clay particles, we can expect that the type of clay minerals and their proportional amounts in a soil will
affect the liquid and plastic limits. Skempton (1953) observed that the plasticity index of a
soil increases linearly with the percentage of clay-size fraction (% finer than 2 mm by weight)
present (Figure 4.12). The correlations of PI with the clay-size fractions for different clays
plot separate lines. This difference is due to the diverse plasticity characteristics of the
100
80
Plasticity index
4.6
60
40
20
+ +
++ +
+
0
0
20
40
60
80
Percentage of clay-size fraction (% 2 mm)
Shellhaven clay A ! 1.33
London clay A ! 0.95
Weald clay A ! 0.63
+ Horten clay A ! 0.42
100
Figure 4.12
Activity (Based on
Skempton, 1953 )
4.6 Activity
85
various types of clay minerals. On the basis of these results, Skempton defined a quantity
called activity, which is the slope of the line correlating PI and % finer than 2 mm. This activity may be expressed as
A!
PI
1%of clay-size fraction, by weight2
(4.18)
where A ! activity. Activity is used as an index for identifying the swelling potential of clay
soils. Typical values of activities for various clay minerals are given in Table 4.1.
Seed, Woodward, and Lundgren (1964a) studied the plastic property of several
artificially prepared mixtures of sand and clay. They concluded that, although the relationship of the plasticity index to the percentage of clay-size fraction is linear (as observed
by Skempton), it may not always pass through the origin. This is shown in Figures 4.13
and 4.14. Thus, the activity can be redefined as
A!
PI
%of clay-size fraction " C¿
(4.19)
where C* is a constant for a given soil.
500
A ! 5.4
Plasticity index
400
4.85
4.43
300
200
3.25
100
1.95
1.52
0.96
0.36
0
0
20
40
60
80
Percentage of clay-size fraction (% 2m)
Commercial bentonite
Bentonite/kaolinite — 4 : 1
Bentonite/kaolinite —1.5 : 1
Kaolinite/bentonite—1.5 : 1
100
Kaolinite/bentonite — 4 : 1
Kaolinite/bentonite— 9 : 1
Kaolinite/bentonite—19 : 1
Commercial kaolinite
Figure 4.13 Relationship between plasticity index and clay-size fraction by weight for kaolinite/
bentonite clay mixtures (After Seed, Woodward, and Lundgren, 1964a. With permission from ASCE.)
Chapter 4: Plasticity and Structure of Soil
500
A ! 5.4
Plasticity index
400
300
3.33
200
1.78
100
1.28
0.93
0
0
20
40
60
Percentage of clay-size fraction (% 2m)
Commercial bentonite
Bentonite/illite — 4 : 1
Bentonite/illite —1.5 : 1
80
100
Illite/ bentonite —1.5 : 1
Commercial illite
Figure 4.14 Relationship between plasticity index and clay-size fraction by weight for illite/
bentonite clay mixtures (After Seed, Woodward, and Lundgren, 1964a. With permission from ASCE.)
For the experimental results shown in Figures 4.13 and 4.14, C* ! 9.
Further works of Seed, Woodward, and Lundgren (1964b) have shown that
the relationship of the plasticity index to the percentage of clay-size fractions present in a
soil can be represented by two straight lines. This is shown qualitatively in Figure 4.15.
For clay-size fractions greater than 40%, the straight line passes through the origin when
it is projected back.
Plasticity index
86
0
10
40
Percentage of clay-size fraction (% 2 mm)
Figure 4.15 Simplified relationship
between plasticity index and percentage
of clay-size fraction by weight (After
Seed, Woodward, and Lundgren, 1964b.
With permission from ASCE.)
4.7 Plasticity Chart
87
Based on Eqs. (4.8) and (4.9), Polidori (2007) provided an empirical relationship for
activity as (for CF equal to or greater than 30%)
A!
0.961LL2 " 0.261CF2 " 10
CF
(4.20)
where CF is the clay fraction (% 2 &m)
Plasticity Chart
Liquid and plastic limits are determined by relatively simple laboratory tests that provide
information about the nature of cohesive soils. Engineers have used the tests extensively for
the correlation of several physical soil parameters as well as for soil identification.
Casagrande (1932) studied the relationship of the plasticity index to the liquid limit of a wide
variety of natural soils. On the basis of the test results, he proposed a plasticity chart as shown
in Figure 4.16. The important feature of this chart is the empirical A-line that is given by the
equation PI ! 0.73(LL " 20). An A-line separates the inorganic clays from the inorganic
silts. Inorganic clay values lie above the A-line, and values for inorganic silts lie below the
A-line. Organic silts plot in the same region (below the A-line and with LL ranging from 30
to 50) as the inorganic silts of medium compressibility. Organic clays plot in the same region
as inorganic silts of high compressibility (below the A-line and LL greater than 50). The
information provided in the plasticity chart is of great value and is the basis for the
classification of fine-grained soils in the Unified Soil Classification System. (See Chapter 5.)
70
60
50
Plasticity index
4.7
U-Line PI ! 0.9(LL " 8)
40
30
A-Line PI ! 0.73(LL " 20)
20
10
0
0
20
40
60
Liquid limit
80
Cohesionless soil
Inorganic clays of low plasticity
Inorganic silts of low compressibility
Inorganic clays of medium plasticity
Inorganic silts of medium compressibility and organic silts
Inorganic clays of high plasticity
Inorganic silts of high compressibility and organic clays
100
Figure 4.16 Plasticity
chart
88 Chapter 4: Plasticity and Structure of Soil
Note that a line called the U-line lies above the A-line. The U-line is approximately
the upper limit of the relationship of the plasticity index to the liquid limit for any currently
known soil. The equation for the U-line can be given as
PI ! 0.91LL " 8 2
(4.21)
There is another use for the A-line and the U-line. Casagrande has suggested that the
shrinkage limit of a soil can be approximately determined if its plasticity index and liquid
limit are known (see Holtz and Kovacs, 1981). This can be done in the following manner
with reference to Figure 4.17.
a
. Plot the plasticity index against the liquid limit of a given soil such as point A in
Figure 4.17.
b. Project the A-line and the U-line downward to meet at point B. Point B will have the
coordinates of LL ! "43.5 and PI ! "46.4.
c. Join points B and A with a straight line. This will intersect the liquid limit axis at
point C. The abscissa of point C is the estimated shrinkage limit.
Plasticity index
60
40
U-
20
0
B
e
lin
e
lin
A-
A
C
0
8
20
40
60
Liquid limit
80
100
120
LL ! " 43.5
PI ! " 46.5
Figure 4.17 Estimation of shrinkage from plasticity chart (Adapted from Holtz and Kovacs, 1981)
4.8
Soil Structure
Soil structure is defined as the geometric arrangement of soil particles with respect to one
another. Among the many factors that affect the structure are the shape, size, and mineralogical composition of soil particles, and the nature and composition of soil water. In general, soils can be placed into two groups: cohesionless and cohesive. The structures found
in soils in each group are described next.
4.8 Soil Structure
89
Void
Void
Soil solid
Soil solid
(a)
(b)
Figure 4.18
Single-grained
structure: (a) loose;
(b) dense
Structures in Cohesionless Soil
The structures generally encountered in cohesionless soils can be divided into two
major categories: single grained and honeycombed. In single-grained structures, soil
particles are in stable positions, with each particle in contact with the surrounding
ones. The shape and size distribution of the soil particles and their relative positions influence the denseness of packing (Figure 4.18); thus, a wide range of void ratios is
possible. To get an idea of the variation of void ratios caused by the relative positions
of the particles, let us consider the mode of packing of equal spheres shown in
Figure 4.19.
Figure 4.19a shows the case of a very loose state of packing. If we isolate a cube
with each side measuring d, which is equal to the diameter of each sphere as shown in the
figure, the void ratio can be calculated as
e!
V " Vs
Vv
!
Vs
Vs
d
(a)
2d
where V ! volume of the cube ! d 3
Vs ! volume of sphere (i.e., solid) inside the cube
d 2
(b)
Figure 4.19 Mode of packing of equal spheres (plan views): (a) very loose packing
(e ! 0.91); (b) very dense packing (e ! 0.35)
90
Chapter 4: Plasticity and Structure of Soil
Noting that V ! d 3 and Vs ! pd 3/6 yields
e!
pd3
b
6
! 0.91
pd3
a
b
6
d3 " a
Similarly, Figure 4.19b shows the case of a very dense state of packing. Figure 4.19b
also shows an isolated cube, for which each side measures d 12. It can be shown that, for
this case, e ! 0.35.
Real soil differs from the equal-spheres model in that soil particles are neither
equal in size nor spherical. The smaller-size particles may occupy the void spaces
between the larger particles, thus the void ratio of soils is decreased compared with that
for equal spheres. However, the irregularity in the particle shapes generally yields an
increase in the void ratio of soils. As a result of these two factors, the void ratios
encountered in real soils have approximately the same range as those obtained in equal
spheres.
In the honeycombed structure (Figure 4.20), relatively fine sand and silt form small
arches with chains of particles. Soils that exhibit a honeycombed structure have large void
ratios, and they can carry an ordinary static load. However, under a heavy load or when
subjected to shock loading, the structure breaks down, which results in a large amount of
settlement.
Structures in Cohesive Soils
To understand the basic structures in cohesive soils, we need to know the types of
forces that act between clay particles suspended in water. In Chapter 2, we discussed
the negative charge on the surface of the clay particles and the diffuse double layer surrounding each particle. When two clay particles in suspension come close to each other,
the tendency for interpenetration of the diffuse double layers results in repulsion
between the particles. At the same time, an attractive force exists between the clay particles that is caused by van der Waals forces and is independent of the characteristics of
water. Both repulsive and attractive forces increase with decreasing distance between
the particles, but at different rates. When the spacing between the particles is very
small, the force of attraction is greater than the force of repulsion. These are the forces
treated by colloidal theories.
Soil solid
Void
Figure 4.20 Honeycombed structure
4.8 Soil Structure
91
The fact that local concentrations of positive charges occur at the edges of clay particles was discussed in Chapter 2. If the clay particles are very close to each other, the
positively charged edges can be attracted to the negatively charged faces of the particles.
Let us consider the behavior of clay in the form of a dilute suspension. When the
clay is initially dispersed in water, the particles repel one another. This repulsion occurs
because with larger interparticle spacing, the forces of repulsion between the particles
are greater than the forces of attraction (van der Waals forces). The force of gravity on
each particle is negligible. Thus, the individual particles may settle very slowly or
remain in suspension, undergoing Brownian motion (a random zigzag motion of colloidal particles in suspension). The sediment formed by the settling of the individual particles has a dispersed structure, and all particles are oriented more or less parallel to one
another (Figure 4.21a).
If the clay particles initially dispersed in water come close to one another during random motion in suspension, they might aggregate into visible flocs with edge-to-face contact. In this instance, the particles are held together by electrostatic attraction of positively
charged edges to negatively charged faces. This aggregation is known as flocculation.
When the flocs become large, they settle under the force of gravity. The sediment formed
in this manner has a flocculent structure (Figure 4.21b).
When salt is added to a clay-water suspension that has been initially dispersed, the
ions tend to depress the double layer around the particles. This depression reduces the
interparticle repulsion. The clay particles are attracted to one another to form flocs and
settle. The flocculent structure of the sediments formed is shown in Figure 4.21c. In flocculent sediment structures of the salt type, the particle orientation approaches a large degree
of parallelism, which is due to van der Waals forces.
(a)
(b)
(c)
Figure 4.21 Sediment structures: (a) dispersion; (b) nonsalt flocculation; (c) salt flocculation
(Adapted from Lambe, 1958)
92 Chapter 4: Plasticity and Structure of Soil
Silt
Domain
Macropore
Cluster
Ped
Micropore
Silt
(a)
(b)
Figure 4.22 Soil structure: (a) arrangement of peds and macropore spaces; (b) arrangement of
domains and clusters with silt-sized particles
Clays that have flocculent structures are lightweight and possess high void
ratios. Clay deposits formed in the sea are highly flocculent. Most of the sediment
deposits formed from freshwater possess an intermediate structure between dispersed
and flocculent.
A deposit of pure clay minerals is rare in nature. When a soil has 50% or more particles with sizes of 0.002 mm or less, it is generally termed clay. Studies with scanning
electron microscopes (Collins and McGown, 1974; Pusch, 1978; Yong and Sheeran, 1973)
have shown that individual clay particles tend to be aggregated or flocculated in submicroscopic units. These units are referred to as domains. The domains then group together,
and these groups are called clusters. Clusters can be seen under a light microscope. This
grouping to form clusters is caused primarily by interparticle forces. The clusters, in turn,
group to form peds. Peds can be seen without a microscope. Groups of peds are
macrostructural features along with joints and fissures. Figure 4.22a shows the arrangement of the peds and macropore spaces. The arrangement of domains and clusters with
silt-size particles is shown in Figure 4.22b.
From the preceding discussion, we can see that the structure of cohesive soils is highly
complex. Macrostructures have an important influence on the behavior of soils from an
engineering viewpoint. The microstructure is more important from a fundamental viewpoint. Table 4.2 summarizes the macrostructures of clay soils.
Table 4.2 Structure of Clay Soils
Item
Remarks
Dispersed structures
Formed by settlement of individual clay particles; more or
less parallel orientation (see Figure 4.21a)
Formed by settlement of flocs of clay particles (see
Figures 4.21b and 4.21c)
Aggregated or flocculated submicroscopic units of clay
particles
Domains group to form clusters; can be seen under light
microscope
Clusters group to form peds; can be seen without microscope
Flocculent structures
Domains
Clusters
Peds
Problems
4.9
93
Summary
This chapter discussed two major components in the study of soil mechanics. They are (a) plasticity of soil and related topics (Sections 4.2 to 4.7), and (b) structure of soil (Section 4.8).
Liquid limit, plastic limit, and shrinkage limit tests of fine-grained soil are indicators
of the nature of its plasticity. The difference between the liquid limit and plastic limit is
called the plasticity index. Liquid limit and plasticity index are required parameters for
classification of fine-grained soils.
The structure of cohesionless soils can be single grained or honeycombed.
Honeycombed structures are encountered in relatively fine sands and silts. The macrostructure of clay soils can be broadly divided into categories such as dispersed structures,
flocculent structures, domains, clusters, and peds.
Problems
4.1
4.2
4.3
4.4
4.5
4.6
Following are the results from the liquid and plastic limit tests for a soil. Liquid
limit test:
Number of
blows, N
Moisture
content (%)
16
20
28
36.5
34.1
27.0
Plastic limit test: PL ! 12.2%
a. Draw the flow curve and obtain the liquid limit.
b. What is the plasticity index of the soil?
Determine the liquidity index of the soil described in Problem 4.1 if win situ ! 31%.
Following are the results from the liquid and plastic limit tests for a soil. Liquid
limit test:
Number of
blows, N
Moisture
content (%)
15
20
28
42
40.8
39.1
Plastic limit test: PL ! 18.7%
a. Draw the flow curve and obtain the liquid limit.
b. What is the plasticity index of the soil?
Refer to Problem 4.3. Determine the liquidity index of the soil when the in situ
moisture content is 26%.
A saturated soil has the following characteristics: initial volume (Vi ) ! 19.65 cm3,
final volume (Vf ) ! 13.5 cm3, mass of wet soil (Ml ) ! 36 g, and mass of dry soil
(M2 ) ! 25 g. Determine the shrinkage limit and the shrinkage ratio.
Repeat Problem 4.5 with the following: Vi ! 24.6 cm3, Vf ! 15.9 cm3,
Ml ! 44 g, and M2 ! 30.1 g.
94 Chapter 4: Plasticity and Structure of Soil
References
AMERICAN SOCIETY FOR TESTING AND MATERIALS (2007). Annual Book of ASTM Standards,
Sec. 4, Vol. 04.08, West Conshohocken, Pa.
BS:1377 (1990). British Standard Methods of Tests for Soil for Engineering Purposes, Part 2, BSI,
London.
BURMISTER, D. M. (1949). “Principles and Techniques of Soil Identification,” Proceedings, Annual
Highway Research Board Meeting, National Research Council, Washington, D.C., Vol. 29,
402–434.
CASAGRANDE, A. (1932). “Research of Atterberg Limits of Soils,” Public Roads, Vol. 13, No. 8,
121–136.
COLLINS, K., and MCGOWN, A. (1974). “The Form and Function of Microfabric Features in a Variety
of Natural Soils,” Geotechnique, Vol. 24, No. 2, 223–254.
HOLTZ, R. D., and KOVACS, W. D. (1981). An Introduction to Geotechnical Engineering,
Prentice-Hall, Englewood Cliffs, NJ.
LAMBE, T. W. (1958). “The Structure of Compacted Clay,” Journal of the Soil Mechanics and
Foundations Division, ASCE, Vol. 85, No. SM2, 1654-1 to 1654-35.
MITCHELL, J. K. (1976). Fundamentals of Soil Behavior, Wiley, New York.
POLIDORI, E. (2007). “Relationship between Atterberg Limits and Clay Contents,” Soils and
Foundations, Vol. 47, No. 5, 887–896.
PUSCH, R. (1978). “General Report on Physico-Chemical Processes Which Affect Soil Structure and
Vice Versa,” Proceedings, International Symposium on Soil Structure, Gothenburg, Sweden,
Appendix, 33.
SEED, H. B., WOODWARD, R. J., and LUNDGREN, R. (1964a). “Clay Mineralogical Aspects of
Atterberg Limits,” Journal of the Soil Mechanics and Foundations Division, ASCE, Vol. 90,
No. SM4, 107–131.
SEED, H. B., WOODWARD, R. J., and LUNDGREN, R. (1964b). “Fundamental Aspects of the Atterberg
Limits,” Journal of the Soil Mechanics and Foundations Division, ASCE, Vol. 90, No. SM6,
75–105.
SKEMPTON, A. W. (1953). “The Colloidal Activity of Clays,” Proceedings, 3rd International
Conference on Soil Mechanics and Foundation Engineering, London, Vol. 1, 57–61.
SRIDHARAN, A., NAGARAJ, H. B., and PRAKASH, K. (1999). “Determination of the Plasticity Index
from Flow Index,” Geotechnical Testing Journal, ASTM, Vol. 22, No. 2, 175–181.
U.S. ARMY CORPS OF ENGINEERS (1949). Technical Memo 3-286, U.S. Waterways Experiment
Station, Vicksburg, Miss.
WROTH, C. P., and WOOD, D. M. (1978). “The Correlation of Index Properties with Some Basic
Engineering Properties of Soils,” Canadian Geotechnical Journal, Vol. 15, No. 2, 137–145.
YONG, R. N., and SHEERAN, D. E. (1973). “Fabric Unit Interaction and Soil Behavior,” Proceedings,
International Symposium on Soil Structure, Gothenburg, Sweden, 176–184.