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SEMICONDUCTORS NOTES

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PH101 ENGINEERING PHYSICS
DR. Chetan Barde
Department of Electronics and Communication Engineering,
Indian Institute of Information Technology Bhagalpur
1-Feb-22
Email:- cbarde.ece@iiitbh.ac.in
1
Prevention Is Better Then Cure
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Module IV
Introduction
• Thermal Voltage
• Electron Volt
• Energy Gap
• Electric Field Intensity
• Mobility of Charge Carrier
• Leakage Current
• Resistivity
• Conductivity
• Current Density
• Intrinsic Concentration
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Indian Institute of Information Technology Bhagalpur
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Module IV Cont.…
Introduction
• Mass Action Law
• Current
Drift
Diffusion
• Hall Effect
• Classification of Semiconductors
• Law of Electrical Neutrality
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Indian Institute of Information Technology Bhagalpur
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Module IV Cont.…
Thermal Voltage (VT) or (Vt)
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Indian Institute of Information Technology Bhagalpur
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Module IV Cont.…
Thermal Voltage (VT) or (Vt)
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Indian Institute of Information Technology Bhagalpur
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Module IV Cont.…
Electron Volt (eV) or (ev)
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Indian Institute of Information Technology Bhagalpur
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Module IV Cont.…
Electron Volt (eV) or (ev)
Vacuum
electrons
1 Volt
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Indian Institute of Information Technology Bhagalpur
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Module IV Cont.…
Electron Volt (eV) or (ev)
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Indian Institute of Information Technology Bhagalpur
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Module IV Cont.…
Energy Gap (EG) or (Eg)
• Larger the orbit, greater is the energy associated with it.
• Each orbit in a single isolated atom represent energy level.
L
M
Energy Level
K
Nucleu
s
M
L
K
• As the distance from the orbit are increasing the electrons present in the respective
orbit their energy also increase..
• Higher levels have less bonding with respect to the nucleus.
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Indian Institute of Information Technology Bhagalpur
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Module IV Cont.…
Energy Gap (EG) or (Eg)
• Range of energy possessed by an electrons in a solid is known as energy band.
Energy Band
Conduction
Band
Energy
Gap
Valence
Band
• Valence Band:- The range of energy possessed by the valence electrons.
• Electron in the outermost orbit of an atom are known as valence electron.
• Conduction Band:- The range of energy possessed by the conduction electrons.
• Free electron are called conduction electron.
• Energy Gap:- Gap between the conduction band and valence band is called band gap
or forbidden energy gap or energy gap.
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Indian Institute of Information Technology Bhagalpur
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Module IV Cont.…
Energy Gap (EG) or (Eg)
Metal/Conductor
Conduction
Band
Conduction
Band
Valence
Band
Valence
Band
At 0 Kelvin (Eg=0)
At 300 Kelvin
• As temperature increases gap between valence band and conduction band reduces
and both the band start overlapping each other, and more electron are now available
in the conduction band and hence current flow increases.
• Overlapping of valence band and conduction increases with temperature.
• In metal electron concentration increases with temperature.
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Indian Institute of Information Technology Bhagalpur
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Module IV Cont.…
Energy Gap (EG) or (Eg)
Insulator
Conduction
Band
Empty
Conduction
Band
Partially Filled
Valence
Band
At 300 Kelvin
Partially Filled
Energy Gap = 1 ev
Valence
Band
At 0 Kelvin
Filled
• At 0 Kelvin conduction band is empty i.e., no charge carrier is present hence conductivity
is 0.
• No electrons of a solid can stay in forbidden energy gap as there is no allowed energy
state in this region.
• At 300 Kelvin or room temperature charge carrier is available in conduction band and
therefore there will be small flow of current through semiconductor.
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Indian Institute of Information Technology Bhagalpur
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Module IV Cont.…
Energy Gap (EG) or (Eg)
Insulator
Conduction
Band
Empty
Conduction
Band
Empty
Conduction
Band
Filled
Valence
Band
Filled
Energy Gap = 5 to 15ev
Valence
Band
At 0 Kelvin
Filled
Valence
Band
At 300 Kelvin
Partially
Filled
At high temperature
• At 0 Kelvin conduction band is empty i.e., no charge carrier is present hence conductivity
is 0.
• At 300 Kelvin also conduction band is empty i.e., no charge carrier is present hence
conductivity is 0.
• If very high temperature is applied, then large amount of current flow and then insulator
get destroyed or burn out.
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Indian Institute of Information Technology Bhagalpur
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Module IV Cont.…
Energy Gap (EG) or (Eg)
Germanium (Ge)
Silicon (Si)
Gallium Arsenide (GaAs)
Eg (0 kelvin)
0.785 eV
1.21 eV
****
Eg (300 kelvin)
0.72 eV
1.1 eV
1.47 eV
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Module IV Cont.…
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Module IV Cont.…
Linearly Increases
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Module IV Cont.…
• For larger field intensity is applied in the semiconductor, the mobility of charge carrier
will be very small, and mobility of charge carrier will be remain almost constant.
• For smaller field intensity is applied in the semiconductor, the mobility of charge carrier
will linearly increase.
Germanium (Ge) Silicon (Si)
Gallium Arsenide (GaAs)
2.1:1
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2.6:1
Indian Institute of Information Technology Bhagalpur
14.5:1
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Module IV Cont.…
Germanium (Ge)
Silicon (Si)
Micro Ampere
Nano Ampere
Advantage of Small Leakage Current
I. Suitable for higher temperature applications.
II. Material or service having good thermal stability.
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